„სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ“ ევროპულ შეთანხმებასთან შეერთება"

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განმარტებითი ბარათი სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ ევროპის შეთანხმების (ADR) მიზანს წარმოადგენს სახიფათო ტვირთების საერთაშორისო გადაზიდვების უსაფრთხოების გაზრდა სახიფათო ტვირთების ტრანსპორტირების ეკონომიკურად მისაღები პირობებისა და გადაზიდვის უსაფრთხოების უმაღლესი დონის უზრუნველყოფის გზით. ADR განსაზღვრავს ნივთიერებებისა და საგნების (ნაკეთობების) ჩამონათვალს, რომლებიც განეკუთვნებიან სახიფათო ტვირთებს, ასევე იმას თუ რომელი მათგანი შეიძლება იყოს დაშვებული საერთაშორისო საავტომობილო გადაზიდვებისათვის და რომელი არა. იმ ტვირთებთან დაკავშირებით, რომლებიც არ შეიძლება იყოს დაშვებული საერთაშორისო საავტომობილო გადაზიდვებისათვის, ADR-ში მითითებულია სპეციალური პირობები, რომელთა დაცვითაც შეიძლება იქნეს გადაზიდული ასეთი ტვირთები. ეს პირობები მოიცავს ასევე სახიფათო ტვირთების კლასიფიკაციას მათი სპეციფიკური ტიპის (ფეთქებადი ნივთიერებები, აალებადი სითხეები, აალებადი აირები, მომწამლავი ნივთიერებები და სხვა) შესაბამისად, შეფუთვის სახესა და ტვირთის მარკირებას, აუცილებელ დოკუმენტაციას, აგრეთვე სპეციალურ მოთხოვნებს, რომლებიც წაეყენება ცისტერნებს, ტვირთის დატვირთვის, მისი წყობის, იზოლირების და გადმოტვირთვის მოთხოვნების ჩათვლით. ყველა ეს პირობა დაწვრილებითაა აღწერილი A დანართში. ამასთან, შეთანხმებაში მოყვანილია სხვა განსაკუთრებული მოთხოვნებიც, რომლებსაც მოიცავს В დანართი და ისინი ეხება ტრანსპორტირების ოპერაციებს, მძღოლთა მომზადებას და ასევე ავტოსატრანსპორტო საშუალებების კონსტრუქციას. შეთანხმება ავალდებულებს ქვეყნებს, რომლებიც არიან ხელშემკვრელი მხარეები, მიიღონ სხვა ქვეყნების (რომლებიც ასევე არიან ხელშემკვრელი მხარეები) ავტოსატრანსპორტო საშუალებები, თუ ისინი აკმაყოფილებენ ADR-ის მოთხოვნებს, მაგრამ შეთანხმება ხელშემკვრელ მხარეს უტოვებს უფლებას თავისი ქვეყნის ტერიტორიაზე აკრძალოს სახიფათო ტვირთების შეტანა (გადაზიდვის უსაფრთხოებისაგან განსხვავებული მიზეზით) ან შემოიღოს საავტომობილო გადაზიდვებისადმი უფრო მკაცრი მოთხოვნები, რომლებიც ასახული უნდა იყოს სხვა, ორმხრივ ან მრავალმხრივ, შეთანხმებებში. ADR-თან მიერთება არ გულისხმობს ქვეყნისათვის რაიმე ფინანსურ პირობებს (ვალდებულებებს), მაგრამ ექსპორტიორმა ქვეყნებმა უნდა განავითარონ ადმინისტრაციული სტრუქტურები, რათა მათ უზრუნველყონ შეფუთვის, ცისტერნების და სატრანსპორტო საშუალებების შემოწმება და დამტკიცება, ასევე ასევე მძღოლებისა და სახიფათო ტვირთების გადაზიდვაზე მრჩეველთა მომზადება და მათთვის სერტიფიკატების გადაცემა. ამასთან, გადაზიდვები, რომელთა მიმართაც გამოიყენება ზემოაღნიშნული შეთანხმება, საგზაო მოძრაობის წესების, საერთაშორისო საგზაო გადაზიდვების ან საერთაშორისო ვაჭრობის კუთხით, ასევე განეკუთვნებიან შიდასახელმწიფოებრივი ან საერთაშორისო დებულებებით რეგულირების სფეროს.

L,EGAL DIIPARTMENT OF STAFF OF PARILIAMENI] OII GEORGIA )56sq54c6.501, 5J5(4)l90b R$56.95006tb0 brj,:6ogq'rn' j. 4600, o. $$odob 6$b' 26 22891 68 - ldep@parliament'ge 3 3lenb t}ll 26 Abashidze Avenue,2f600, Kutaisi, Ge:orgia Tel:228 91 68 ge legaldeP(@Parliament' e-mail: sQrb336r btj5(1or6q,cdl0orl36<'rbob 0o36 066orgbobrcrr3ob $lf60cnqr63boq'o "bbbogloxn ,,lDb' oSbolrbls6oll0er6olrc'lblSjclc'lbJQJbo('33bobts3b.:b3b..336c'lSuqonSolltiboSbotl cc0erboqret , br3rber60sgCbqo o6o6o;$o3ob $3boor $l60erE536oq-6 "lrl;315 or;erbr%C" qQJ gob 0gbtbgb" lrljl6orsCqob 3l6er6tso ffiqoqCbolr ts36r6ob bljl6or33q'erb 33q'oq'3bc'lr 03q)l6ot' ot':cnblb3" 0cnd6rerbob ts3lrlbgb" 3l6er60o brjr6or3CqotJ 3r6q'':036$ob q,orlr 3rber6ob 36argj$9bob (07-2/496;03'06'2016) 0ubq'ob 0eurber36Sborrb ts Sbrb':Oobc'r bolr orrerb s'b g 1 45 - 6 g gq'l0 gb$ob 3 pa)b 3$q,.:03b$ob $r6r$ob o36oq9o5q'0r q93ilr6$r036$0r Srboboq'r 0ort36rnbotl0o96 0gS6cngbJsor3ob $s60erq96g6oq'o "blboglorar $3o6orgbotl orrbr0qrS3o' Urgfcm 64gst.,E33OoU n3Urb3b" 336er3gqo 01;or$b03bob .,"0.,g.,r,!.,3.,r1 $glii.t, ft60etq966oq'o ,,br':3$er0erboq'cn r$6rbb3rn66ob ::irli-tcq',i'r, :ioroa., .3qoqcbob tsgi'>6ob or':c'rt'rbc" s.r "t'5i5r>c'r tlcod6robob brjs6or3Sq'erb 3rber6olr ,, blj'6crr3C*,n'b 3tbc'r60o Ogq.q'Oob 0!6lOolr orlc'rlblb," r^1. 1/nR-^ 145-3 rb (07-2/496; 03.06.2016) br$6orSCqlertJ 3r6qrri335$ob 6g6qrr03Q)ob qg5 0ob':603$er6ocplq aorBbo'> 0erorber36gborr6 63brbr0obto.,b l$3oorbo j6gb ob 6s bboqSob J6o63qrg6ob qgr$ g g br' 3roerO.,tr l6erg 6812-3-9-3-201606131157 N 6812 13/06/2016 საქართველოს პარლამენტის საორგანიზაციო დეპარტამენტის უფროსს ქალბატონ ეთერ სვიანაიძეს დასკვნა საქართველოს მთავრობის მიერ შეერთებისათვის წარმოდგენილი „სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ“ ევროპული შეთანხმების თანამდევი, საკანონმდებლო ინიციატივის წესით წარმოდგენილი „საავტომობილო ტრანსპორტის შესახებ“ საქართველოს კანონში ცვლილების შეტანის თაობაზე“ და „საგზაო მოძრაობის შესახებ“ საქართველოს კანონში ცვლილების შეტანის თაობაზე“ საქართველოს კანონის პროექტების (07-2/496; 03.06.2016) საქართველოს პარლამენტის რეგლამენტის 145-ე მუხლის მე-2 პუნქტის „ბ“ ქვეპუნქტთან შესაბამისობის თაობაზე საქართველოს პარლამენტის საბიუჯეტო ოფისმა განიხილა საქართველოს მთავრობის მიერ შეერთებისათვის წარმოდგენილი „სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ“ ევროპული შეთანხმების თანამდევი, საკანონმდებლო ინიციატივის წესით წარმოდგენილი „საავტომობილო ტრანსპორტის შესახებ“ საქართველოს კანონში ცვლილების შეტანის თაობაზე“ და „საგზაო მოძრაობის შესახებ“ საქართველოს კანონში ცვლილების შეტანის თაობაზე“ საქართველოს კანონის პროექტების (07-2/496; 03.06.2016) საქართველოს პარლამენტის რეგლამენტის 145-ე მუხლის მე-2 პუნქტის „ბ“ ქვეპუნქტთან შესაბამისობის საკითხი და მიზანშეწონილად მიაჩნია აღნიშნული კანონის პროექტების განხილვის პროცედურის დაწყება. პატივისცემით, საბიუჯეტო ოფისის უფროსის მოვალეობის შემსრულებელი თათია ხეთაგური

შესწორებები Ref. Sales №E.14.VIII.1 (ECE/TRAN/242, ტომი I და II) 2014 წლის ნოემბერი ნიუ-იორკი და ჟენევა ევროპის შეთანხმება სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ (ADR) (ძალაშია 2015 წლის 1 იანვრიდან) შესწორებები შენიშვნა: იხილეთ წინამდებარე გამოცემაში შეტანილი შესწორებები, ასევე ADR-ის A და B დანართებში განხორციელებული ცვლილებები, რომლებიც შესაძლებელია წარმოდგენილი იყოს კანონიერ ძალაში მომდევნო გამოცემის გამოქვეყნებამდე, გაერთიანებული ერების ევროპის ეკონომიკური კომისიის ვებ-გვერდზე: http://www.unece.org/trans/danger/danger.htm ტომი I 1. თავი 2.2, 2.2.41.4, თვითრეაქტიულ ნივთიერებებთან დაკავშირებულ სვეტში 2,2’-აზოდი(იზობუთირონიტრილი ნაცვლად უნდა იყოს აზოდი(იზობუთირონიტრილი) 2.2’- 2. გვერდი 187, თავი 2.2, პუნქტი 2.2.61.1.8 შეცვალეთ არსებული სურათი შემდეგი სურათით ცვალებადობა მლ/მ3 ECE/TRANS/242/Corr.1 მხოლოდ ინგლისურ ენაზე GE.14- ECE/TRANS/242/Corr.1 გვერდი 2 3. გვერდები 324 და 325, თავი 3.2, ცხრილი A, გაეროს №1202, მეორე პოზიცია, სვეტი (2) EN 590:2004 ნაცვლად უნდა იყოს EN 590:2009 + A1:2010 4. გვერდი 326, თავი 3.2, ცხრილი A, გაეროს №1203, სვეტი (6) 534 363 ნაცვლად უნდა იყოს 363 534 5. გვერდი 334, თავი 3.2, ცხრილი A, გაეროს №1286, II შეფუთვის ჯგუფის მეორე პოზიცია, სვეტი (8) დასაწყისში, მიუთითეთ P001 6. გვერდი 334, თავი 3.2, ცხრილი A, გაეროს №1286, III შეფუთვის ჯგუფის ყველა პოზიცია, სვეტი (8) დასაწყისში, მიუთითეთ P001 7. გვერდი 369, თავი 3.2, ცხრილი A, გაეროს №1792, სვეტი (12) L4BN SGAN ნაცვლად უნდა იყოს SGAN L4BN 8. გვერდი 462, თავი 3.2, ცხრილი A, გაეროს №3090, სვეტი (6) 230-ის შემდეგ მიუთითეთ 310 9. გვერდი 462, თავი 3.2, ცხრილი A, გაეროს №3091, სვეტი (6) 230-ის შემდეგ მიუთითეთ 360 10. გვერდი 510, თავი 3.2, ცხრილი A, გაეროს №3481, სვეტი (6) 376 677 360 ნაცვლად უნდა იყოს 360 376 377 11. გვერდი 515, თავი 3.2, ცხრილი A, გაეროს №3509 გადაიტანეთ ასოებითა და ციფრებით წარმოდგენილი კოდი VC2 და AP10 (16) სვეტიდან (17) სვეტში. 12. გვერდი 514, თავი 3.2, ცხრილი A, გაეროს №3513, სვეტში (5) 2.2+5.5 ნაცვლად უნდა იყოს 2.2.+5.1 ტომი II 13. გვერდი x, სარჩევი, 7.3.3 ამოიღეთ სპეციალური 14. გვერდი 583, თავი 9.2, პუნქტი 9.2.3.1.1 ამოიღეთ ან დირექტივა 71/320/EEC3 ____________________

ECE/TRANS/242 (ტომი 1) ევროპული ეკონომიკური კომისიის სახმელეთო ტრანსპორტის კომიტეტი ADR ძალაშია 2015 წლის 1 იანვრიდან ევროპული შეთანხმება სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ ტომი I გაერთიანებული ერების ორგანიზაცია ნიუ-იორკი და ჟენევა, 2014 წელი i შენიშვნა წინამდებარე გამოცემაში გამოყენებული აღნიშვნები და წარმოდგენილი მასალები არ ნიშნავს გაერთიანებული ერების ორგანიზაციის სამდივნოს მხრიდან რაიმე მოსაზრების გამოხატვას ამა თუ იმ ქვეყნის, ტერიტორიის, ქალაქისა თუ რაიონის ან მისი ხელისუფლების ორგანოების იურიდიული სტატუსის, ასევე მისი საზღვრებისა თუ ფარგლების დადგენის შესახებ. ECE/TRANS/242 (ტომი 1) საავტორო უფლება© გაერთიანებული ერების ორგანიზაცია, 2014 წელი ყველა უფლება დაცულია დაუშვებელია გაყიდვის მიზნით წინამდებარე გამოცემის გამრავლება, საძიებო სისტემაში შენახვა ან ნებისმიერი ფორმით თუ საშუალებით, იქნება ეს ელექტრონული, ელექტროსტატიკური, მაგნიტური, მექანიკური, ფოტოკოპირების ან სხვა საშუალებები, გადაცემა გაერთიანებული ერების ორგანიზაციის წინასწარი წერილობითი ნებართვის გარეშე. გაერთიანებული ერების ორგანიზაციის გამოცემა გაყიდვაშია No.14.VIII.1 ISBN 978-92-1-139149-7 (2-ტომეულის სრული კრებული) e-ISBN 978-92-1-056691-9 I და II ტომები ცალ-ცალკე არ იყიდება. ii გაერთიანებული ერების ევროპის ეკონომიკური კომისია (UNECE) გაერთიანებული ერების ევროპის ეკონომიკური კომისია (UNECE) წარმოადგენს ეკონომიკური და სოციალური საბჭოს (ECOSOC) ფარგლებში შემავალი გაერთიანებული ერების ხუთი რეგიონალური კომისიიდან ერთ-ერთს. იგი დაფუძნდა 1947 წელს ომის შემდგომი ევროპის აღდგენის, ეკონომიკური საქმიანობის განვითარებისა და ევროპის ქვეყნებს შორის, ასევე ევროპასა და მსოფლიოს დანარჩენ ქვეყნებს შორის ეკონომიკური ურთიერთობების განმტკიცების ხელშეწყობის მიზნით. ცივი ომის განმავლობაში, UNECE წარმოადგენდა უნიკალურ ფორუმს აღმოსავლეთსა და დასავლეთს შორის ეკონომიკური დიალოგისა და თანამშრომლობისთვის. აღნიშნული პერიოდის სიმძიმის მიუხედავად, აღინიშნა მნიშვნელოვანი წარმატებები და მიღწეულ იქნა კონსენსუსი უამრავ შეთანხმებასთან დაკავშირებით შეთანხმებისა და სტანდარტიზაციის სფეროში. ცივი ომის დასრულების შემდგომ, UNECE-ს შეემატა არა მხოლოდ უამრავი ახალი წევრისახელმწიფო, არამედ ასევე ახალი ფუნქციებიც. 1990-იანი წლებიდან ორგანიზაციამ საკუთარი ძალები მიმართა გარდამავალი პროცესის ანალიზზე, ამისათვის გამოიყენა რა საკუთარი გამოცდილება ჰარმონიზაციის სფეროში ცენტრალური და აღმოსავლეთ ევროპის ქვეყნების გლობალურ ბაზრებზე ინტეგრირების მიზნით. UNECE წარმოადგენს ფორუმს, სადაც დასავლეთ, ცენტრალურ და აღმოსავლეთ ევროპის, ცენტრალური აზიისა და ჩრდილოეთ ამერიკის - სულ 56 ქვეყნის - წარმომადგენლებს შეუძლიათ შეიკრიბონ, რათა შეიმუშავონ შესაბამისი საშუალებები მათი ეკონომიკური თანამშრომლობის მიზნით. აღნიშნული თანამშრომლობა აერთიანებს ისეთ სფეროებს, როგორიცაა ეკონომიკა, სტატისტიკა, გარემო, ტრანსპორტი, ვაჭრობა, მდგრადი ენერგეტიკა, სატყეო მეურნეობა და მიწათსარგებლობა. კომისია განსაზღვრავს რეგიონალურ ჩარჩოებს კონვენციების, ნორმებისა და სტანდარტების შემუშავებისა და შეთანხმების მიზნით. კომისიის ექსპერტები უწევენ ტექნიკურ დახმარებას სამხრეთ-აღმოსავლეთისა და დამოუკიდებელ სახელმწიფოთა თანამეგობრობის ქვეყნებს. აღნიშნული დახმარება მდგომარეობს საკონსულტაციო მომსახურების გაწევაში, ტრენინგებისა და სემინარების ჩატარებაში, რომლის ფარგლებშიც ქვეყნებს ეძლევათ მათი გამოცდილებისა და საუკეთესო პრაქტიკის გაზიარების შესაძლებლობა. iii ტრანსპორტი გაერთიანებული ერების ევროპის ეკონომიკურ კომისიაში (UNECE) UNECE სახმელეთო ტრანსპორტის კომიტეტი (ITC) ხელს უწყობს ადამიანებისა და ტვირთის საერთაშორისო გადაადგილების გამარტივებას სახმელეთო სატრანსპორტო საშუალებების გამოყენებით. მის მიზანს წარმოადგენს სატრანსპორტო სექტორის კონკურენტუნარიანობის, უსაფრთხოებისა და ენერგოეფექტურობის გაუმჯობესება. ამავდროულად იგი ორიენტირებულია გარემოს მიმართ სატრანსპორტო საქმიანობის შედეგად მიყენებული უარყოფითი გავლენის შემცირებაზე და მდგრადი განვითარების ეფექტურ ხელშეწყობაზე. სახმელეთო ტრანსპორტის კომიტეტი წარმოადგენს: - ევროპასა და მის ფარგლებს მიღმა ტრანსპორტის, მაგალითად, სახიფათო ტვირთის გადაზიდვისა და მსოფლიო დონეზე საგზაო-სატრანსპორტო საშუალებების კონსტრუირების სფეროში მრავალმხრივი სტანდარტებისა და შეთანხმებების ცენტრს; - ტექნიკური დახმარების აღმოჩენისა და საუკეთესო პრაქტიკის გაზიარების პორტალს; - მრავალქვეყნიანი საინვესტიციო დაგეგმარების კოორდინატორს; - ძირითად პარტნიორს ტრანსპორტისა და ვაჭრობის ხელშეწყობის ინიციატივებთან დაკავშირებით; - სატრანსპორტო სტატისტიკის ისტორიულ ცენტრს. სახმელეთო ტრანსპორტის კომიტეტი ექვს ათწლეულზე მეტი ხნის მანძილზე წარმოადგენდა პლატფორმას მთავრობათაშორის თანამშრომლობისთვის, საერთაშორისო ტრანსპორტის გაადვილებისა და განვითარების მიზნით, მისი უსაფრთხოებისა და ეკოლოგიური მაჩვენებლების გაუმჯობესებასთან ერთად. აღნიშნული უწყვეტი და მნიშვნელოვანი სამუშაოების ძირითადი შედეგები ასახულია 50-ზე მეტ საერთაშორისო ხელშეკრულებასა და შეთანხმებაში, რომლებიც განსაზღვრავს საერთაშორისო სამართლებრივ ჩარჩოს და ტექნიკურ რეგლამენტებს საერთაშორისო საავტომობილო, სარკინიგზო, შიდა საწყალოსნო და ინტერმოდალური გადაზიდვების განვითარებისთვის, ასევე სახიფათო ტვირთების გადაზიდვისა და სატრანსპორტო საშუალებების კონსტრუირებისთვის. სატრანსპორტო სექტორისა და მისი საქმიანობის მარეგულირებელი ნორმატიული ბაზის გათვალისწინებით, UNECE წარმოადგენს დაბალანსებულ მიდგომას პროცედურების გამარტივების საკითხების გადაწყვეტასა და სათანადო უსაფრთხოების უზრუნველყოფასთან დაკავშირებით. iv წინასიტყვაობა ზოგადი ინფორმაცია ევროპული შეთანხმება სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ (ADR) გაფორმდა ჟენევაში 1957 წლის 30 სექტემბერს, გაერთიანებული ერების ორგანიზაციის ევროპული ეკონომიკური კომისიის ეგიდით და ძალაში შევიდა 1968 წლის 29 იანვარს. შეთანხმების ცვლილება განხორციელდა 1975 წლის 21 აგვისტოს ნიუ-იორკში გაფორმებული პროტოკოლით 14 (3) მუხლში ცვლილებების შეტანის შესახებ, რომელიც კანონიერ ძალაში შევიდა 1985 წლის 19 აპრილს. შეთანხმების მე-2 მუხლის თანახმად, A დანართით გათვალისწინებული სახიფათო ტვირთები, რომლებიც არ დაიშვება გადაზიდვებზე, არ ექვემდებარება საერთაშორისო ტრანსპორტირებას მაშინ, როდესაც სხვა სახიფათო ტვირთების საერთაშორისო გადაზიდვები ნებადართულია შემდეგი მოთხოვნების დაცვის შემთხვევაში: - - A დანართით გათვალისწინებული მოთხოვნები, რომლებსაც უნდა აკმაყოფილებდეს აღნიშნული ტვირთი, კერძოდ, მათ შეფუთვასა და მარკირებასთან დაკავშირებულ მოთხოვნებს; და B დანართით გათვალისწინებული მოთხოვნები, კერძოდ, აღნიშნული ტვირთების გადამზიდი ავტოსატრანპორტო საშუალებების კონსტრუირებასთან, აღჭურვასა და მოძრაობასთან დაკავშირებული მოთხოვნები. მიუხედავად ზემოაღნიშნულისა, მე-4 მუხლის თანახმად, ყოველი ხელშემკვრელი მხარე სარგებლობს მის ტერიტორიაზე სახიფათო ტვირთების შეტანის რეგულირების ან გადაზიდვის უსაფრთხოების დაცვის გარდა ასევე სხვა მიზეზებით აკრძალვის უფლებით.) ხელშემკვრელი მხარეები ასევე სარგებლობენ იმ საკითხის დარეგულირების უფლებით, ორმხრივი თუ მრავალმხრივი შეთანხმებების გაფორმების გზით, რომ განხორციელდეს გარკვეული სახიფათო ტვირთების, რომელთა გადაზიდვაც იკრძალება A დანართით, საერთაშორისო გადაზიდვა, გარკვეული პირობების საფუძველზე, მათ ტერიტორიებზე ან სახიფათო ტვირთების, რომელთა საერთაშორისო გადაზიდვაც დაშვებულია A დანართით, გადაზიდვა მათ ტერიტორიებზე იმაზე ნაკლებად მკაცრი მოთხოვნებით, ვიდრე გათვალისწინებულია A და B დანართებით. A და B დანართების რეგულარული შესწორება და განახლება მიმდინარეობს ADR-ის ძალაში შესვლის შემდეგაც. A და B დანართების სტრუქტურა ევროპული ეკონომიკური კომისიის სახმელეთო ტრანსპორტის კომიტეტის სახიფათო ტვირთების გადაზიდვებზე (WP.15) მომუშავე ჯგუფმა მის ორმოცდამეთერთმეტე სესიაზე (1992 წლის 26-30 ოქტომბერი) მიიღო გადაწყვეტილება A და B დანართების სტრუქტურის ცვლილების შესახებ, საგზაო ტრანსპორტის საერთაშორისო კავშირის მიერ წარმოდგენილი წინადადების საფუძველზე (TRANS/WP.15/124, 100-108 პუნქტები). მთავარ მიზნებს წარმოადგენდა მომხმარებლებისთვის მოთხოვნების უფრო მეტად ხელმისაწვდომობისა და გამოსაყენებლად უფრო მოსახერხებლობის უზრუნველყოფა, მათი უფრო მარტივი გამოყენების მიზნით არა მხოლოდ ADR-ს საფუძველზე საერთაშორისო საავტომობილო გადაზიდვების ოპერაციებში, არამედ აგრეთვე ევროპის ყველა სახელმწიფოში შიდა გადაზიდვებში ეროვნული თუ ევროპის გაერთიანების კანონმდებლობის საფუძველზე, და, საბოლოო ჯამში, მტკიცე მარეგულირებელი ჩარჩოს უზრუნველყოფა ევროპის დონეზე. გარდა ამისა, საჭიროდ ჩაითვალა სატრანსპორტო ჯაჭვში ჩართული სხვადასხვა მონაწილის მოვალეობების უფრო თვალსაჩინოდ განსაზღვრა, აღნიშნულ სხვადასხვა მონაწილეებთან დაკავშირებით არსებული მოთხოვნების უფრო სისტემატიური დაჯგუფება და ADR-ის სამართლებრივი მოთხოვნების დიფერენცირება v ევროპული ან საერთაშორისო სტანდარტებისგან, რომელთა გამოყენებაც შესაძლებელი იყო აღნიშნული მოთხოვნების დასაკმაყოფილებლად. ეს სტრუქტურა შეესაბამება ”სახიფათო ტვირთების გადაზიდვების შესახებ” გაერთიანებული ერების ორგანიზაციის რეკომენდაციებში მოყვანილ ტიპიურ წესებს, სახიფათო ტვირთის საზღვაო გადაზიდვების შესახებ საერთაშორისო კოდექსს (IMDG კოდექსი) და სახიფათო ტვირთების საერთაშორისო სარკინიგზო გადაზიდვების შესახებ წესებს (RID). იგი დაყოფილია ცხრა ნაწილად, თუმცა ხელშეკრულების მე-2 მუხლის თანახმად კვლავ დაჯგუფებულია ორ დანართად. მონახაზი წარმოდგენილია შემდეგი სახით: A დანართი: ზოგადი დებულებები დაკავშირებული დებულებები ნაწილი 1 ნაწილი 2 ნაწილი 3 მუხლი 4 მუხლი 5 მუხლი 6 მუხლი 7 და სახიფათო ნაკეთობებსა და ნივთიერებებთან ზოგადი დებულებები კლასიფიკაცია სახიფათო ტვირთების ჩამონათვალი, სპეციალური დებულებები და შეზღუდულ და გამოთავისუფლებულ რაოდენობებთან დაკავშირებული გამონაკლისები დებულებები შეფუთვისა და ცისტერნების შესახებ გაგზავნის პროცედურები ტარის, მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების (მტსტკ), მსხვილგაბარიტიანი ტარის, ცისტერნების და მასიური ტვირთის კონტეინერების კონსტრუირებასა და შემოწმებასთან დაკავშირებული მოთხოვნები ტვირთების გადაზიდვასთან, ჩატვირთვასთან, გადმოტვირთვასა და დამუშავებასთან დაკავშირებული დებულებები. B დანართი: სატრანსპორტო აღჭურვილობასა და სატრანსპორტო ოპერაციებთან დაკავშირებული დებულებები ნაწილი 8 ავტოსატრანსპორტო საშუალებების ეკიპაჟთან, აღჭურვილობასთან, ექსპლუატაციასა და დოკუმენტაციასთან დაკავშირებული მოთხოვნები ავტოსატრანსპორტო საშუალებების კონსტრუირებასა და მათ გადაზიდვებზე დაშვებასთან დაკავშირებული მოთხოვნები ნაწილი 9 ნაწილი 1, რომელშიც გათვალისწინებულია ზოგადი დებულებები და განმარტებები, წარმოადგენს ყველაზე მნიშვნელოვან ნაწილს, ვინაიდან იგი მოიცავს სხვა ნაწილებში გამოყენებული ყველა ტერმინის განმარტებას და ზედმიწევნით განსაზღვრავს ADR-ის სამოქმედო არეალსა და გამოყენებადობას, შესაძლო გამონაკლისების ჩათვლით, ასევე სხვა დებულებების გამოყენებადობას. გარდა ამისა, ის მოიცავს დებულებებს მომზადების, გამონაკლისებისა და გარდამავალი ღონისძიებების შესახებ, სახიფათო ტვირთის გადაზიდვების ჯაჭვის სხვადასხვა მონაწილის მიერ მიღებულ სათანადო უსაფრთხოების ზომებს, კონტროლის ზომებს, კონსულტანტებს უსაფრთხოების საკითხებში, სახიფათო ტვირთების გადაზიდვებთან დაკავშირებით არსებულ შეზღუდვებს ავტოსაგზაო გვირაბებში გავლით და სახიფათო ტვირთების გადაზიდვების უსაფრთხოებას. შეცვლილი სტრუქტურის მქონე ADR-ის გამოყენებაში მნიშვნელოვანი ადგილი უკავია 3.2. თავის A ცხრილს, რომელშიც გათვალისწინებულია სახიფათო ტვირთების ჩამონათვალი რიცხობრივი წესით დალაგებული გაეროს ნომრების მიხედვით. მას შემდეგ, რაც განისაზღვრება კონკრეტული სახიფათო ნივთიერების ან ნაკეთობის გაეროს ნომერი, ცხრილი უზრუნველყოფს vi მითითებას აღნიშნული ნივთიერებისა თუ ნაკეთობის გადაზიდვებთან დაკავშირებული კონკრეტულ მოთხოვნებსა და იმ თავებსა თუ პუნქტებზე, სადაც შესაძლებელია მოძიებულ იქნეს კონკრეტული მოთხოვნები. მიუხედავად აღნიშნულისა, მხედველობაში უნდა იქნეს მიღებული, რომ სხვადასხვა ნაწილების ზოგადი მოთხოვნებისა თუ კონკრეტული კლასის მოთხოვნების გამოყენება უნდა მოხდეს აღნიშნული კონკრეტული მოთხოვნების დამატების სახით, კონკრეტული სიტუაციიდან გამომდინარე. A ცხრილის გამოყენების გაადვილების მიზნით იმ შემთხვევაში, თუ გაეროს ნომერი უცნობია, სამდივნომ შეიმუშავა ანბანური მაჩვენებელი და შეიტანა 3.2 თავში B ცხრილის სახით, რომელიც მიუთითებს კონკრეტულ სახიფათო ტვირთებზე მინიჭებულ გაეროს ნომერს. აღნიშნული B ცხრილი არ წარმოადგენს ADR-ის ოფიციალურ ნაწილს და წინამდებარე გამოცემაში გათვალისწინებულია მხოლოდ საინფორმაციო მიზნით. იმ შემთხვევებში, თუ ტვირთები, რომლებიც ცნობილია ან ითვლება როგორც სახიფათო, შეუძლებელია მოძიებულ იქნეს სახელით A ან B ცხრილებიდან რომელიმეში, მათი კლასიფიცირება უნდა მოხდეს მე-2 ნაწილის შესაბამისად, რაც მოიცავს ყველა სათანადო პროცედურასა და კრიტერიუმს იმ ფაქტის განსაზღვრის მიზნით, არის თუ არა აღნიშნული ტვირთი სახიფათო და რომელი გაეროს ნომერი უნდა მიენიჭოს. გამოყენებული ტექსტები წინამდებარე ვერსია („2015 წლის ADR“) ითვალისწინებს WP.15-ს მიერ 2012, 2013 და 2014 წლებში განხორციელებულ და ECE/TRANS/WP.15/222 -/Corr.1 და -/Corr.2 და ECE/TRANS/WP.15/222/Add.1 და -/Corr.1 პირობითი აღნიშვნების მიხედვით გავრცელებულ ყველა ახალ შესწორებას, რომელიც ძალაში უნდა შევიდეს 2015 წლის 1 იანვარს, ხელშემკვრელი მხარეების მიერ მათი მიღების შესახებ შეთანხმების 14(3) მუხლის შესაბამისად. მიუხედავად აღნიშნულისა, A დანართის 1.6.1.1 პუნქტით გათვალისწინებული გარდამავალი ღონისძიებების გამო, წინა ვერსია („2013 წლის ADR“) შესაძლებელია კვლავ იქნეს გამოყენებულ 2015 წლის 30 ივნისამდე. ტერიტორიული გამოყენებადობა ADR წარმოადგენს შეთანხმებას სახელმწიფოებს შორის და არ ითვალისწინებს რაიმე საერთო მარეგულირებელ ორგანოს. პრაქტიკულად, ხელშემკვრელი მხარეები ახდენენ მაგისტრალების შემოწმებას, ხოლო რაიმე შეუსაბამობის აღმოჩენა გამოიწვევს ეროვნული ხელისუფლების ორგანოების მიერ სასამართლო სარჩელის აღძვრას დამრღვევების წინააღმდეგ მათი ქვეყნის კანონმდებლობის შესაბამისად. თავად ADR-ში არ არის გათვალისწინებული საჯარიმო სანქციები. აღნიშნული გამოცემის გამოქვეყნების დროისთვის ხელშემკვრელ მხარეებს წარმოადგენს ალბანეთი, ანდორა, ავსტრია, აზერბაიჯანი, ბელორუსია, ბელგია, ბოსნია და ჰერცოგოვინა, ბულგარეთი, ხორვატია, კვიპროსი, ჩეხეთის რესპუბლიკა, დანია, ესტონეთი, ფინეთი, საფრანგეთი, გერმანია, საბერძნეთი, უნგრეთი, ისლანდია, ირლანდია, იტალია, ყაზახეთი, ლატვია, ლიხტენშტეინი, ლიტვა, ლუქსემბურგი, მალტა, მონტენეგრო, მაროკო, ნიდერლანდები, ნორვეგია, პოლონეთი, პორტუგალია, მოლდოვის რესპუბლიკა, რუმინეთი, რუსეთის ფედერაცია, სერბეთი, სლოვაკეთი, სლოვენია, ესპანეთი, შვედეთი, შვეიცარია, ტაჯიკეთი, ყოფილი იუგოსლავიის რესპუბლიკა - მაკედონია, ტუნისი, თურქეთი, უკრაინა და გაერთიანებული სამეფო. ADR მოქმედებს მინიმუმ ორი ზემოაღნიშნული ხელშემკვრელი მხარის ტერიტორიებზე განხორციელებულ სატრანსპორტო ოპერაციებთან დაკავშირებით. გარდა ამისა, უნდა აღინიშნოს, vii რომ ევროკავშირის ფარგლებში არსებული თანასწორობისა და თავისუფალი ვაჭრობის ინტერესებიდან გამომდინარე, ADR-ის A და B დანართები ასევე მიღებულ იქნა ევროკავშირის წევრი სახელმწიფოების მიერ მათ ტერიტორიებზე და მათ შორის სახიფათო ტვირთების საგზაო გადაზიდვების შესახებ დებულების საფუძვლად (ევროპარლამენტისა და ევროსაბჭოს 2008 წლის 24 სექტემბრის 2008/68/EC შესწორებული დირექტივა სახიფათო ტვირთების შიდა გადაზიდვების შესახებ). იმ ქვეყნებმა, რომლებიც არ შედიან ევროკავშირის შემადგენლობაში, აგრეთვე მიიღეს ADR-ის A და B დანართები მათი ეროვნული კანონმდებლობის საფუძველზე. დამატებითი პრაქტიკული ინფორმაცია ნებისმიერი გამოკითხვა ADR-ის მიღებასთან დაკავშირებით უნდა წარედგინოს შესაბამის კომპეტენტურ ორგანოს. დამატებითი ინფორმაციის მოძიება შესაძლებელია გაერთიანებული ერების ორგანიზაციის ევროპული ეკონომიკური კომისიის (UNECE) სატრანსპორტო განყოფილების ვებ-გვერდზე: http://www.unece.org/trans/danger/danger.htm აღნიშნული ვებ-გვერდის განახლება რეგულარულად მიმდინარეობს და ითვალისწინებს შემდეგ ინფორმაციას: - ზოგადი ინფორმაცია ADR-ის შესახებ შეთანხმება (დანართების გარეშე) ხელმოწერის ოქმი ADR-ის მიმდინარე სტატუსი დეპოზიტარის შეტყობინებები ინფორმაცია ქვეყნების შესახებ (კომპეტენტური ორგანოები, შეტყობინებები) სხვადასხვა ენებზე შედგენილი ვერსიები (ADR, წერილობითი ინსტრუქცია) მრავალმხრივი შეთანხმებები 2015 წლის ADR (ფაილები) 2013 წლის ADR (ფაილები) 2013 წლის ADR (შესწორებები) ძველი ვერსიები (ფაილები და შესწორებები) დეტალური ინფორმაცია პუბლიკაციის შესახებ და შესწორებები viii სარჩევი ტომი I დანართი A ნაწილი 1 გვერდი ევროპული შეთანხმება სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ ................................................................................................... ........ xvii ხელმოწერის ოქმი ............................................................................................................ ........ xxiii ზოგადი დებულებები და სახიფათო ნივთიერებებისა და ნაკეთოებების შესახებ დებულებები ....................................................................................................... ....... 1 ზოგადი დებულებები ...................................................................................................... ....... 2 თავი 1.1 1.1.1 1.1.2 1.1.3 1.1.4 1.1.5 მოქმედების არეალი და გამოყენებადობა ..................................... ....... სტრუქტურა ........................................................................................... ......... მოქმედების არეალი ...................................................................................... გამონაკლისები ..................................................................................... ......... სხვა დებულებების გამოყენებადობა ............................................... ......... სტანდარტების მიღება ................................................................... ......... 5 5 5 6 15 17 თავი 1.2 1.2.1 1.2.2 განმარტებები და საზომი ერთეულები ........................................... ........ განმარტებები ........................................................................................ ......... საზომი ერთეულები ........................................................................... ......... 19 19 47 თავი 1.3 სახიფათო ტვირთების გადაზიდვაში მონაწილე პირების მომზადება ....... .................................................................................... ........ მოქმედების არეალი და გამოყენებადობა .................................................. მომზადების ხასიათი .......................................................................... .......... დოკუმენტაცია ...................................................................................... .......... 50 50 50 51 1.4.1 1.4.2 1.4.3 გადაზიდვების მონაწილეების ვალდებულებები უსაფრთხოებასთან დაკავშირებით ................................................ ........ უსაფრთხოების საერთო ზომები ..................................................... .......... ძირითადი მონაწილეების ვალდებულებები ................................ .......... სხვა მონაწილეების ვალდებულებები ............................................ .......... 52 52 52 55 თავი 1.5 1.5.1 1.5.2 გადახვევები დადგენილი წესებიდან .......................................... ........ დროებითი გადახვევები დადგენილი წესებიდან ............................... (რეზერვირებულია) ................................................................................ 59 59 59 თავი 1.6 1.6.1 1.6.2 1.6.3 გარდამავალი ღონისძიებები ........................................................... ........ ზოგადი დებულებები ........................................................................ ......... წნევის ჭურჭლები და ჭურჭლები მე-2 კლასთან დაკავშირებით ....... დამონტაჟებული ცისტერნები (ავტოცისტერნები), სახსნელი ცისტერნები და ავტოსატრანსპორტო საშუალება-ბატარეები .... ......... კონტეინერ-ცისტერნები, გადამზიდი ცისტერნები და მრავალელემენტიანი აირის კონტეინერები .......................................... ავტოსატრანსპორტო საშუალებები ........................................................ მე-7 კლასი .............................................................................................. ......... 60 60 64 1.3.1 1.3.2 1.3.3 თავი 1.4 1.6.4 1.6.5 1.6.6 ix 65 71 75 77 სარჩევი (გაგრძელება) გვერდი თავი 1.7 რადიოაქტიურ მასალასთან დაკავშირებული ზოგადი დებულებები .......................................................................... 80 1.7.1 მოქმედების არეალი და გამოყენებადობა ............................................. 1.7.2 რადიაციისგან დაცვის პროგრამა ........................................................... 1.7.3 მართვის სისტემა ...................................................................................... 1.7.4 სპეციალური პირობები ........................................................................... 1.7.5 სხვა სახიფათო თვისებების მქონე რადიოაქტიური მასალები ........... 1.7.6 შეუსაბამობა .............................................................................................. თავი 1.8 1.8.1 1.8.2 1.8.3 1.8.4 1.8.5 1.8.6 1.8.7 1.8.8 თავი 1.9 1.9.5 თავი 1.10 1.10.1 1.10.2 1.10.3 ნაწილი 2 80 82 83 83 84 84 შემოწმებები და სხვა დამხმარე ღონისძიებები, რომლებიც უზრუნველყოფს უსაფრთხოებასთან დაკავშირებულ მოთხოვნებთან შესაბამისობას ...................................................... ........ 86 სახიფათო ტვირთების ადმინისტრაციული კონტროლი .................... 86 ორმხრივი ადმინისტრაციული მხარდაჭერა ......................................... 86 კონსულტანტი უსაფრთხოების საკითხებში ......................................... 87 კომპეტენტური ორგანოებისა და მათ მიერ შერჩეული ორგანიზაციების ჩამონათვალი ............................................................... 95 ცნობები სახიფათო ტვირთებთან დაკავშირებული შემთხვევების შესახებ ....................................................................................................... 95 1.8.7 პუნქტში აღწერილი შესაბამისობის შეფასებებთან, პერიოდულ შემოწმებებთან, შუალედურ შემოწმებებსა და დაუგეგმავ შემოწმებებთან დაკავშირებული ადმინისტრაციული კონტროლის ზომები ................ 100 შესაბამისობის შეფასებისა და პერიოდული შემოწმებების პროცედურები ........................................................................................... 102 აირის ბალონების შესაბამისობის შეფასების პროცედურები .............. 112 კომპეტენტური ორგანოების მიერ დაწესებული შეზღუდვები გადაზიდვებთან დაკავშირებით ....................................................... .......... შუზღუდვები გვირაბებთან დაკავშირებით ......................................... 117 118 უსაფრთხოების უზრუნველყოფასთან დაკავშირებული დებულებები .. 123 ზოგადი დებულებები ............................................................................ 123 სწავლება უსაფრთხოების ზომების შესახებ ........................................ 123 დებულებები მნიშვნელოვანი სახიფათო ტვირთების გადაზიდვების შესახებ ........................................................................... 124 კლასიფიკაცია .................................................................................................................. ....... თავი 2.1 ზოგადი დებულებები ....................................................................... ........ 2.1.1 შესავალი .................................................................................................... 2.1.2 კლასიფიკაციის პრინციპები ................................................................... 2.1.3 ნივთიერებების კლასიფიკაცია, ხსნარებისა და ნარევების ჩათვლით (როგორიცაა პრეპარატები და მათი ნარჩენები), რომლებიც არ არის მოხსენებული მათი დასახელებით ........................................................ 2.1.4 ნიმუშების კლასიფიკაცია ....................................................................... 2.1.5 წუნდებული, ცარიელი, გაუსუფთავებელი ტარის კლასიფიკაცია ... 135 143 144 თავი 2.2 2.2.1 2.2.2 2.2.3 145 145 182 196 ცალკეული კლასისთვის დამახასიათებელი დებულებები ......... ........ კლასი 1 ფეთქებადი ნივთიერებები და ნაკეთობები .......................... კლასი 2 აირები ....................................................................................... კლასი 3 ადვილაალებადი სითხეები .................................................... x 131 133 133 134 სარჩევი (გაგრძელება) 2.2.41 2.2.42 2.2.43 2.2.51 2.2.52 2.2.61 2.2.62 2.2.7 2.2.8 2.2.9 თავი 2.3 2.3.0 2.3.1 2.3.2 2.3.3 2.3.4 2.3.5 ნაწილი 3 გვერდი კლასი 4.1 ადვილაალებადი მყარი ნივთიერებები, თვითრეაქტიული ნივთიერებები და მყარი დესენსიბილიზებული ფეთქებადი ნივთიერებები ................................................... კლასი 4.2 თვითაალების გამომწვევი ნივთიერებები .......................... კლასი 4.3 ნივთიერებები, რომლებიც წყალთან შეხებისას გამოყოფს ადვილაალებად აირებს ......................................................... კლასი 5.1 მჟანგავი ნივთიერებები ........................................................ კლასი 5.2 ორგანული პეროქსიდები ..................................................... კლასი 6.1 ტოქსიკური ნივთიერებები .................................................. კლასი 6.2 ინფექციური ნივთიერებები ................................................ კლასი 7 რადიოაქტიური ნივთიერებები ........................................... კლასი 8 კოროზიული ნივთიერებები ................................................ კლასი 9 სხვა სახიფათო ნივთიერებები და ნაკეთობები .................. 203 218 222 227 233 350 265 275 312 319 გამოცდის მეთოდები ........................................................................ ........ 344 ზოგადი დებულებები ............................................................................. 344 A ტიპის ბრიზანტული ფეთქებადი ნივთიერებების გამოცდა ექსუდაციაზე ............................................................................................. 344 4.1 კლასის ნიტროცელულოზას ნარევებთან დაკავშირებული ცდები .. 346 3, 6.1 და 8 კლასის ადვილაალებადი სითხეების გამოცდა .................. 348 დენადობის განმსაზღვრელი ცდები ....................................................... 350 ლითონორგანული ნივთიერებების კლასიფიკაცია 4.2 და 4.3 კლასებში .. 353 სახიფათო ტვირთების ჩამონათვალი, სპეციალური დებულებები და შეზღუდულ და გამოთავისუფლებულ რაოდენობებთან დაკავშირებული გამონაკლისები ...... 355 თავი 3.1 3.1.1 3.1.2 3.1.3 ზოგადი დებულებები .......................................................... ................... შესავალი .................................................................................................... გადაზიდვის შესაბამისი დასახელება .................................................... ხსნარები ან ნარევები ................................................................................ 357 357 357 360 სახიფათო ტვირთების ჩამონათვალი .............................................. ........ ცხრილი A: სახიფათო ტვირთების ჩამონათვალი ............................... ცხრილი B: ADR-ს ნივთიერებებისა და ნაკეთობების ანბანური მაჩვენებელი ............................................................................................. გარკვეულ ნაკეთობებსა თუ ნივთიერებებთან დაკავშირებული სპეციალური დებულებები ....................................................................... ....... 361 373 თავი 3.2 3.2.1 3.2.2 თავი 3.3 თავი 3.4 შეზღუდული ოდენობებით შეფუთული სახიფათო ტვირთები ...... ....... გამოთავისუფლებული ოდენობებით შეფუთული სახიფათო ტვირთები .................................................................................................. ....... 3.5.1 გამოთავისუფლებული რაოდენობები .................................................. 3.5.2 ტარა ........................................................................................................... 3.5.3 შეფუთვების ტესტირება ......................................................................... 3.5.4 შეფუთვების მარკირება ........................................................................... 3.5.5 შეფუთვების მაქსიმალური რაოდენობა ნებისმიერ სატრანსპორტო საშუალებაში ან კონტეინერში ................................................................ 3.5.6 დოკუმენტაცია .......................................................................................... 642 729 791 თავი 3.5 xi 795 795 795 797 798 799 799 სარჩევი ტომი II დანართი A გვერდი (გაგრძელება) ზოგადი დებულებები და სახიფათო ნივთიერებებსა და ნაკეთობებთან დაკავშირებული დებულებები ..................................................................................... ....... 1 ნაწილი 4 შეფუთვასა და ცისტერნებთან დაკავშირებული დებულებები .............................. ........ 3 თავი 4.1 ტარის გამოყენება, მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებისა და მსხვილგაბარიტიანი ტარის ჩათვლით .............. ....... 5 გადამზიდი ცისტერნებისა და გაეროს მრავალელემენტიანი აირის კონტეინერების (მეაკ) გამოყენება ................................................................ 167 დამონტაჟებული ცისტერნების (ავტოცისტერნების), სახსნელი ცისტერნების, კონტეინერ-ცისტერნებისა და ლითონის მასალისგან დამზადებული კორპუსის მქონე სახსნელი ძარა-ცისტერნების, ასევე ავტოსატრანსპორტო საშუალება-ბატარეებისა და მრავალელემენტიანი აირის კონტეინერების გამოყენება ........................................................... ........ 194 პლასტმასის არმირებული ბოჭკოსგან დამზადებული ცისტერნების, დამონტაჟებული ცისტერნების (ავტოცისტერნების), სახსნელი ცისტერნების, კონტეინერ-ცისტერნებისა და სახსნელი ძარაცისტერნების გამოყენება ....................................................................... ....... 221 თავი 4.5 ნარჩენების ვაკუუმური ცისტერნის გამოყენება ................................... ....... 222 თავი 4.6 (რეზერვირებულია)................................................................................ ........ 223 თავი 4.7 ფეთქებადი ნივთიერებების მობილური დანადგარის გამოყენება ... ……. 224 ტვირთის გაგზავნის პროცედურები ............................................................................ ........ 227 თავი 5.1 ზოგადი დებულებები .............................................................................. ........ 229 თავი 5.2 მარკირება და საშიშროების ნიშნები.................................................. ........ 237 თავი 5.3 კონტეინერებზე, მრავალელემენტიანი აირის კონტეინერებზე, ფეთქებადი ნივთიერებების მობილურ დანადგარებზე, კონტეინერ-ცისტერნებზე, გადამზიდ ცისტერნებსა და ავტოსატრანსპორტო საშუალებებზე საინფორმაციო ტაბლოებისა და აღნიშვნების განთავსება ......................................................... ……. 250 თავი 5.4 დოკუმენტაცია ......................................................................................... ....... 264 თავი 5.5 სპეციალური დებულებები ................................................................................ 287 თავი 4.2. თავი 4.3 თავი 4.4 თავი 5 xii სარჩევი (გაგრძელება) თავი 6 გვერდი ტარის, მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებისა და მსხვილგაბარიტიანი ტარის, ცისტერნებისა და მასიური ტვირთის კონტეინერების დამზადებასა და გამოცდასთან დაკავშირებული მოთხოვნები .. …………………………………………………………………………… თავი 6.1 თავი 6.2 თავი 6.3 თავი 6.4 თავი 6.5 თავი 6.6 295 ტარის დამზადებასა და გამოცდასთან დაკავშირებული მოთხოვნები ................................................................................................ ....... 297 წნევის ჭურჭლების, აეროზოლური გამფრქვევების, აირების (აირის ბალონების) შემცველი მცირე მოცულობის ჭურჭლებისა და გათხევადებული ადვილაალებადი აირების შემცველი საწვავი ელემენტების ბალონების დამზადებასა და გამოცდასთან დაკავშირებული მოთხოვნები ................................................................ ........ 337 6.2 კლასის ა კატეგორიის ინფექციური ნივთიერებებისთვის განკუთვნილი ტარის დამზადებასა და გამოცდასთან დაკავშირებული მოთხოვნები ....................... ............................................ 392 რადიოაქტიური მასალებისთვის განკუთვნილი შეფუთვებისა და აღნიშნული მასალების დამზადებასთან, გამოცდასა და დამტკიცებასთან დაკავშირებული მოთხოვნები .................................. ......... 400 მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების დამზადებასა და გამოცდასთან დაკავშირებული მოთხოვნები ...... ......... 438 მსხვილგაბარიტიანი ტარის დამზადებასა და გამოცდასთან დაკავშირებული მოთხოვნები ......................................................................... 477 თავი 6.7 გადამზიდავი ცისტერნებისა და გაეროს მრავალელემენტიანი აირის კონტეინერების დაპროექტებასთან, დამზადებასთან, შემოწმებასა და გამოცდასთან დაკავშირებული მოთხოვნები ............................................. 491 თავი 6.8 დამონტაჟებული ცისტერნების (ავტოცისტერნების), სახსნელი ცისტერნების, კონტეინერ-ცისტერნებისა და ლითონის მასალისგან დამზადებული კორპუსის მქონე სახსნელი ძარა-ცისტერნების, ასევე ავტოსატრანსპორტო საშუალება-ბატარეებისა და მრავალელემენტიანი აირის კონტეინერების დამზადებასთან, აღჭურვასთან, ტიპის დამტკიცებასთან, შემოწმებასთან, გამოცდასა და მარკირებასთან დაკავშირებული მოთხოვნები ................................ 569 პლასტმასის არმირებული ბოჭკოსგან დამზადებული ცისტერნების, დამონტაჟებული ცისტერნების (ავტოცისტერნების), სახსნელი ცისტერნების, კონტეინერ-ცისტერნებისა და სახსნელი ძარაცისტერნების დაპროექტებასთან, დამზადებასთან, აღჭურვასთან, ტიპის დამტკიცებასთან, გამოცდასა და მარკირებასთან დაკავშირებული მოთხოვნები .......................................................... ......... 631 ნარჩენების ვაკუუმური ცისტერნის დამზადებასთან, აღჭურვასთან, ტიპის დამტკიცებასთან, შემოწმებასა და მარკირებასთან დაკავშირებული მოთხოვნები .................................................................. ......... 641 თავი 6.9 თავი 6.10 xiii სარჩევი (გაგრძელება) თავი 6.11 მასიური ტვირთის კონტეინერების დაპროექტებასთან, დამზადებასთან, შემოწმებასა და გამოცდასთან დაკავშირებული მოთხოვნები ..................................................................................... ......... 646 ცისტერნების, მასიური ტვირთის კონტეინერებისა და ფეთქებადი ნივთიერებების მობილური დანადგარისთვის გამოყოფილი სპეციალური განყოფილებების დამზადებასთან, აღჭურვასთან, ტიპის დამტკიცებასთან, შემოწმებასა და გამოცდასთან, ასევე მარკირებასთან დაკავშირებული მოთხოვნები ................................. ......... 649 გადაზიდვებთან, დატვირთვასთან, გადმოტვირთვასა და ტვირთების დამუშავებასთან დაკავშირებული დებულებები ....................................................... ......... 653 თავი 7.1 ზოგადი დებულებები .............................................................................. ......... 655 თავი 7.2 შეფუთვებით გადაზიდვასთან დაკავშირებული დებულებები .......…….. 657 თავი 7.3 დაყრით გადაზიდვასთან დაკავშირებული დებულებები ................ …….. 662 თავი 7.4 ცისტერნებით გადაზიდვასთან დაკავშირებული დებულებები ............... 670 თავი 7.5 დატვირთვასთან, გადმოტვირთვასა და ტვირთის დამუშავებასთან დაკავშირებული დებულებები ............................................................. ......... 671 თავი 6.12 თავი 7 დანართი B ნაწილი 8 გვერდი სატრანსპორტო აღჭურვილობასა და სატრანპორტო ოპერაციებთან დაკავშირებული დებულებები ............................................................................. ......... 689 ავტოსატრანპორტო საშუალებების ეკიპაჟთან, აღჭურვილობასთან, ექსპლუატაციასა და დოკუმენტაციასთან დაკავშირებული დებულებები ........... ......... 691 თავი 8.1 თავი 8.2 თავი 8.3 თავი 8.4 თავი 8.5 თავი 8.6 სატრანსპორტო ერთეულებსა და მათ აღჭურვილობასთან დაკავშირებული ზოგადი მოთხოვნები .............................................. ......... 693 ავტოსატრანსპორტო საშუალებების ეკიპაჟის მომზადებასთან დაკავშირებული მოთხოვნები ................................................ .................... 697 ავტოსატრანსპორტო საშუალებების ეკიპაჟის მიერ შესასრულებელი სხვადასხვა მოთხოვნები ......................................................................... ......... 705 ავტოსატრანსპორტო საშუალებების ზედამხედველობასთან დაკავშირებული მოთხოვნები ............................................................. ......... 707 კონკრეტულ კლასებსა თუ ნივთიერებებთან დაკავშირებული დამატებითი მოთხოვნები ..................................................................... ......... 709 ავტოსაგზაო გვირაბში გავლით სახიფათო ტვირთების გადამზიდი ავტოსატრანსპორტო საშუალებების გასვლის შეზღუდვა .............. ......... 715 xiv სარჩევი (გაგრძელება) ნაწილი 9 გვერდი ავტოსატრანპორტო საშუალებების კონსტრუირებასა და გადაზიდვებზე დაშვებასთან დაკავშირებული მოთხოვნები .............................................................. ........ თავი 9.1 თავი 9.2 თავი 9.3 თავი 9.4 თავი 9.5 თავი 9.6 717 ავტოსატრანპორტო საშუალებების გადაზიდვებზე დაშვებასთან დაკავშირებული მოქმედების არეალი, განმარტებები და მოთხოვნები ................................................................................................ ........ 719 ავტოსატრანპორტო საშუალებების კონსტრუირებასთან დაკავშირებული მოთხოვნები ................................................................ ........ 726 ფეთქებადი ნივთიერებებისა და ნაკეთობების (1 კლასი) შეფუთვებში გადასაზიდად განკუთვნილ სრულ ან დასრულებულ EX/II ან EX/III ტიპის ავტოსატრანსპორტო საშუალებებთან დაკავშირებული დამატებითი მოთხოვნები ..................................................................... ......... 735 სახიფათო ტვირთების შეფუთვებში გადასაზიდად განკუთვნილ სრული ან დასრულებული ავტოსატრანსპორტო საშუალებების (გარდა EX/II ან EX/III ტიპის ავტოსატრანსპორტო საშუალებებისა) ძარის კონსტრუირებასთან დაკავშირებული დამატებითი მოთხოვნები ............................................................................................ ......... 737 მყარი ნივთიერებების დაყრით გადაზიდვისთვის განკუთვნილი სრული ან დასრულებული ავტოსატრანსპორტო საშუალებების ძარის კონსტრუირებასთან დაკავშირებული დამატებითი მოთხოვნები .............................................................................................. ......... 739 რეგულირებადი ტემპერატურის პირობებში ნივთიერებების გადასაზიდად განკუთვნილ სრულ ან დასრულებულ ავტოსატრანსპორტო საშუალებებთან დაკავშირებული დამატებითი მოთხოვნები ............................................................................................... ......... 741 თავი 9.7 დამონტაჟებულ ცისტერნებთან (ავტოცისტერნებთან), ავტოსატრანსპორტო საშუალება-ბატარეებსა და სრულ ან დასრულებულ ავტოსატრანსპორტო საშუალებებთან დაკავშირებული დამატებითი მოთხოვნები, რომლებიც გამოიყენება სახიფათო ტვირთების გადასაზიდად 1მ3-ზე მეტი მოცულობის სახსნელი ცისტერნებით ან 3მ3-ზე მეტი მოცულობის კონტეინერ-ცისტერნებით, გადამზიდი ცისტერნებითა თუ მრავალელემენტიანი აირის კონტეინერებით (EX/III, FL, OX და AT ტიპის ავტოსატრანსპორტო საშუალებები) .............. 743 თავი 9.8 სრულ და დასრულებულ ფეთქებადი ნივთიერებების მობილურ დანადგართან დაკავშირებული დამატებითი მოთხოვნები ............... …….. xv 747 xvi ევროპული შეთანხმება სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ (ADR) ხელშემკვრელი მხარეები, გამოხატავენ რა საერთაშორისო საგზაო გადაზიდვების უსაფრთხოების გაზრდის სურვილს, თანხმდებიან შემდეგზე: მუხლი 1 წინამდებარე შეთანხმების მიზნებიდან გამომდინარე, (ა) ტერმინი “ავტოსატრანსპორტო საშუალებები” გულისხმობს ძრავიან სატრანსპორტო საშუალებებს, საწევარებს, მისაბმელებს და ნახევარმისაბმელებს, როგორც ეს განსაზღვრულია საგზაო მოძრაობის შესახებ 1949 წლის 19 სექტემბრის კონვენციის მე-4 მუხლით, გარდა იმ ავტოსატრანსპორტო საშუალებებისა, რომლებიც მიეკუთვნება ან ექვემდებარება რომელიმე ხელშემკვრელი მხარის შეიარაღებულ ძალებს; (ბ) ტერმინი „სახიფათო ტვირთები“ ნიშნავს იმ ნივთიერებებსა და ნაკეთობებს, რომელთა საერთაშორისო საგზაო გადაზიდვაც იკრძალება A და B დანართების პირობებით ან დასაშვებია მხოლოდ გარკვეული პირობების დაცვით; (გ) ტერმინით „საერთაშორისო გადაზიდვა“ იგულისხმება ზემოაღნიშნული (ა) პუნქტით განსაზღვრული ავტოსატრანსპორტო საშუალებებით მინიმუმ ორი ხელშემკვრელი სახელმწიფოს ტერიტორიაზე განხორციელებული ნებისმიერი სატრანსპორტო ოპერაცია. მუხლი 2 1. მე-4 მუხლის მე-3 პუნქტით გათვალისწინებული დებულებების თანახმად, ის სახიფათო ტვირთები, რომლებიც A დანართის მიხედვით არ დაიშვება გადაზიდვებზე, არ წარმოადგენს საერთაშორისო გადაზიდვების საგანს. 2. სხვა საერთაშორისო ტვირთების საერთაშორისო გადაზიდვა ნებადართულია შემდეგი პირობების დაცვით: (ა) A დანართით გათვალისწინებული მოთხოვნები, რომელთაც უნდა აკმაყოფილებდნენ აღნიშნული ტვირთები, კერძოდ, მათ შეფუთვასა და მარკირებასთან დაკავშირებული მოთხოვნები, და (ბ) B დანართით გათვალისწინებული მოთხოვნები, კერძოდ, აღნიშნული ტვირთების გადამზიდი ავტოსატრანსპორტო საშუალებების კონსტრუირებასთან, აღჭურვასა და ექსპლუატაციასთან დაკავშირებული მოთხოვნები, მე-4 მუხლის მე-2 პუნქტის დებულებების შესაბამისად. მუხლი 3 წინამდებარე შეთანხმების დანართები წარმოადგენს შეთანხმების განუყოფელ ნაწილებს. მუხლი 4 1. ყოველი ხელშემკვრელი მხარე სარგებლობს სახიფათო ტვირთების მის ტერიტორიაზე შესვლის რეგლამენტირებისა თუ აკრძალვის უფლებით გადაზიდვის უსაფრთხოების დაცვის გარდა ასევე სხვა მიზეზებით. xvii 2. წინამდებარე შეთანხმების კანონიერ ძალაში შესვლის დროისთვის ერთ-ერთი ხელშემკვრელი მხარის ტერიტორიაზე ექსპლუატაციაში მყოფ ან მისი ძალაში შესვლიდან ორი თვის განმავლობაში აღნიშნულ ტერიტორიაზე ექსპლუატაციაში გაშვებულ ავტოსატრანსპორტო საშუალებებზე გაიცემა ნებართვა, რათა შეთანხმების კანონიერ ძალაში შესვლის დღიდან სამი წლის განმავლობაში უზრუნველყონ სახიფათო ტვირთების საერთაშორისო გადაზიდვა იმ შემთხვევაშიც კი, თუ მათი კონსტრუირება და აღჭურვა არ აკმაყოფილებს სრულად B დანართში გათვალისწინებულ მოთხოვნებს შესაბამის გადაზიდვებთან დაკავშირებით. თუმცა B დანართში არსებული სპეციალური პირობების გათვალისწინებით აღნიშნული პერიოდი შეიძლება შემცირდეს. 3. ხელშემკვრელი მხარეები სარგებლობენ უფლებით, რომ ორმხრივი თუ მრავალმხრივი შეთანხმებების გაფორმების გზით, უზრუნველყონ გარკვეული სახიფათო ტვირთების, რომელთა საერთაშორისო გადაზიდვაც იკრძალება წინამდებარე ხელშეკრულებით, დაშვება მათ ტერიტორიებზე საერთაშორისო გადაზიდვების განსახორციელებლად გარკვეული პირობებით ან რომ სახიფათო ტვირთები, რომელთა საერთაშორისო გადაზიდვაც დაშვებულია წინამდებარე შეთანხმების საფუძველზე მხოლოდ გარკვეული პირობებით, შესაძლებელია წარმოადგენდეს საერთაშორისო გადაზიდვების საგანს მათ ტერიტორიებზე იმაზე ნაკლებად მკაცრი პირობებით, ვიდრე გათვალისწინებულია წინამდებარე ხელშეკრულების დანართებით. მოცემულ პუნქტში მითითებული ორმხრივი თუ მრავალმხრივი შეთანხმებები წარედგინება გაერთიანებული ერების ორგანიზაციის გენერალურ მდივანს, რომელიც, თავის მხრივ, წარუდგენს მათ იმ ხელშემკვრელ მხარეებს, რომლებიც არ წარმოადგენენ ზემოაღნიშნული შეთანხმებების ხელმომწერებს. მუხლი 5 ის გადაზიდვები, რომლებთან დაკავშირებითაც გამოიყენება წინამდებარე შეთანხმება, ექვემდებარება ზოგადად საგზაო მოძრაობასთან, საერთაშორისო საგზაო გადაზიდვებსა და საერთაშორისო ვაჭრობასთან დაკავშირებით მოქმედ ეროვნულ თუ საერთაშორისო წესებს. მუხლი 6 1. ევროპული ეკონომიკური კომისიის წევრი ქვეყნები და კომისიის უფლებამოსილების ფარგლების მე-8 პუნქტის თანახმად კომისიის საქმიანობაში სათათბირო ხმის უფლებით მონაწილე ქვეყნები შესაძლებელია გახდნენ წინამდებარე შეთანხმების ხელშემკვრელი მხარეები: (ა) მისი ხელმოწერის გზით; (ბ) მისი ხელმოწერის შემდგომ სავალდებულო რატიფიცირების გზით; (გ) მასთან შეერთების გზით. 2. იმ ქვეყნებს, რომელთაც შეუძლიათ მონაწილეობა მიიღონ ევროპული ეკონომიკური კომისიის გარკვეულ სამუშაოებში, აღნიშნული კომისიის საქმიანობის ფარგლების მე-11 პუნქტის თანახმად, შეუძლიათ გახდნენ წინამდებარე შეთანხმების ხელშემკვრელი მხარეები, მისი კანონიერ ძალაში შესვლის შემდეგ მასთან შეერთების გზით. 3. შეთანხმება წარმოდგენილი იქნება ხელმოსაწერად 1957 წლის 15 დეკემბრამდე. ამ თარიღის შემდეგ ის ღია იქნება მისაერთებლად. xviii 4. რატიფიცირება ან შეერთება ხორციელდება რატიფიკაციის ან შეერთების ინსტრუმენტის გაერთიანებული ერების ორგანიზაციის გენერალურ მდივანთან დეპონირების გზით. მუხლი 7 1. წინამდებარე შეთანხმება ძალაში შედის იმ დღიდან ერთი თვის შემდეგ, როდესაც მე-6 მუხლის პირველი პუნქტით გათვალისწინებული სახელმწიფოების რაოდენობა, რომელთაც რატიფიცირების პირობის გარეშე მოაწერეს ხელი ამ შეთანხმებას ან მოახდინეს რატიფიკაციის ან შეერთების ინსტრუმენტების დეპონირება, საერთო ჯამში მიაღწევს ხუთს. თუმცა მისი დანართები არ გამოიყენება აღნიშნული შეთანხმების ძალაში შესვლის დღიდან ექვსი თვის განმავლობაში. 2. თითოეული ქვეყნისთვის, რომლებიც მოახდენენ წინამდებარე შეთანხმების რატიფიკაციას ან მიუერთდებიან მას, მას შემდეგ, რაც მე-6 მუხლის პირველი პუნქტით გათვალისწინებული ხუთი ქვეყანა რატიფიკაციის პირობის გარეშე მოაწერს ხელს ამ შეთანხმებას ან მოახდენს რატიფიკაციის ან შეერთების ინსტრუმენტების დეპონირებას, აღნიშნული შეთანხმება ძალაში შევა იმ დღიდან ერთი თვის განმავლობაში, როდესაც აღნიშნული ქვეყანა მოახდენს რატიფიკაციის ან შეერთების ინსტრუმენტის დეპონირებას, ხოლო შეთანხმების დანართები გამოიყენება აღნიშნულ ქვეყნებთან მიმართებით იმავე დღეს, თუ დანართები უკვე შესულია კანონიერ ძალაში მოცემული დღისთვის, ან, თუ არ ჯერ არ შესულა კანონიერ ძალაში აღნიშნული დღისთვის, იმ დღეს, როდესაც მოხდება მათი გამოყენება წინამდებარე მუხლის პირველი პუნქტის დებულებების თანახმად. მუხლი 8 1. თითოეულ ხელშემკვრელ მხარეს შეუძლია წინამდებარე შეთანხმების დენონსირება გაერთიანებული ერების ორგანიზაციის გენერალური მდივნის მიმართ შეტყობინების წარდგენის გზით. 2. დენონსაცია ძალაში შედის გენერალური მდივნის შეტყობინების მიღების დღიდან თორმეტი თვის შემდეგ. მიერ აღნიშნული დენონსაციის მუხლი 9 1. წინამდებარე შეთანხმება კარგავს ძალას იმ შემთხვევაში, თუ ხელშემკვრელი მხარეების რაოდენობა იქნება ხუთზე ნაკლები თორმეტი თანმიმდევრული თვის განმავლობაში. 2. სახიფათო ტვირთების გადაზიდვის რეგულირებასთან დაკავშირებით მსოფლიო მასშტაბის შეთანხმების გაფორმების შემთხვევაში, წინამდებარე შეთანხმების ნებისმიერი დებულება, რომელიც ეწინააღმდეგება ზემოაღნიშნული მსოფლიო მასშტაბის შეთანხმების რომელიმე დებულებას, ამ უკანასკნელის კანონიერ ძალაში შესვლის დღიდან ავტომატურად კარგავს ძალას მოცემული შეთანხმების იმ მხარეებს შორის ურთიერთობებთან დაკავშირებით, რომლებიც გახდნენ მსოფლიო მასშტაბის შეთანხმების მხარეები და ავტომატურად შეიცვლება აღნიშნული მსოფლიო მასშტაბის შეთანხმების შესაბამისი დებულებით. მუხლი 10 1. ნებისმიერ ქვეყანას შეუძლია წინამდებარე შეთანხმების რატიფიკაციის პირობის გარეშე ხელმოწერისას, რატიფიკაციის ან შეერთების ინსტრუმენტის დეპონირებისას, ან ნებისმიერ დროს შემდგომში, გაერთიანებული ერების ორგანიზაციის გენერალური მდივნის მიმართ xix შეტყობინების გაგზავნის გზით განაცხადოს, რომ წინამდებარე შეთანხმება გავრცელდება ყველა თუ ცალკეულ ტერიტორიაზე, რომელთა საერთაშორისო ურთიერთობებზე ის აგებს პასუხს. შეთანხმება და მისი დანართები ძალაში შევა შეტყობინებაში მითითებულ ტერიტორიასა თუ ტერიტორიებზე, გენერალური მდივნის მიერ აღნიშნული შეტყობინების მიღებიდან ერთი თვის შემდეგ. 2. ესა თუ ის ქვეყანა, რომელიც მიმდინარე მუხლის პირველი პუნქტის თანახმად განაცხადებს წინამდებარე შეთანხმების მოქმედების გავრცელების შესახებ იმ ტერიტორიაზე, რომლის საერთაშორისო ურთიერთობებზეც ის აგებს პასუხს, შეუძლია, მე-8 მუხლით გათვალისწინებული დებულებების შესაბამისად, მოახდინოს შეთანხმების დენონსირება მითითებულ ტერიტორიასთან მიმართებაში. მუხლი 11 1. წინამდებარე შეთანხმების განმარტებასა თუ მიღებასთან დაკავშირებით ორ ან რამდენიმე ხელშემკვრელ მხარეს შორის წარმოშობილი ნებისმიერი დავა შეძლებისდაგვარად უნდა გადაწყდეს აღნიშნულ მხარეებს შორის ურთიერთმოლაპარაკების გზით. 2. დავა, რომელიც ვერ გადაწყდება მოლაპარაკების გზით, უნდა წარედგინოს არბიტრაჟს იმ შემთხვევაში, თუ დავის მონაწილე ერთ-ერთი ხელშემკვრელი მხარე მოითხოვს ამას და, შესაბამისად, დავა გადაეცემა დავაში მონაწილე მხარეების შეთანხმებით შერჩეულ ერთ ან რამდენიმე არბიტრს. იმ შემთხვევაში, თუ არბიტრაჟის მოთხოვნის თარიღიდან სამი თვის განმავლობაში, დავის მონაწილე მხარეები ვერ შეთანხმდებიან არბიტრისა თუ არბიტრების შერჩევის შესახებ, აღნიშნული მხარეებიდან ნებისმიერს შეუძლია მიმართოს გაერთიანებული ერების ორგანიზაციის გენერალურ მდივანს თხოვნით, დაასახელოს ერთი არბიტრი, რომელსაც წარედგინება დავა გადასაწყვეტად. 3. წინამდებარე მუხლის მე-2 პუნქტის თანახმად დანიშნული არბიტრისა თუ არბიტრების მიერ მიღებული გადაწყვეტილება სავალდებულოა დავაში მონაწილე ხელშემკვრელი მხარეებისათვის. მუხლი 12 1. ყოველ ხელშემკვრელ მხარეს, წინამდებარე შეთანხმების ხელმოწერის, რატიფიცირებისა თუ შეერთების დროს, შეუძლია განაცხადოს, რომ სავალდებულოდ არ აღიარებს მე-11 მუხლს. იმ ნებისმიერ ხელშემკვრელ მხარესთან მიმართებით, რომელმაც გააკეთა აღნიშნული დათქმა, მე-11 მუხლი არ გავრცელდება დანაჩენ ხელშემკვრელ მხარეებზე. 2. ნებისმიერ ხელშემკვრელ მხარეს, რომელმაც გააკეთა დათქმა წინამდებარე მუხლის პირველი პუნქტის თანახმად, შეუძლია ნებისმიერ დროს გამოითხოვოს აღნიშნული დათქმა გაერთიანებული ერების ორგანიზაციის გენერალური მდივნისათვის შესაბამისი შეტყობინების გაგზავნის გზით. მუხლი 13 1. წინამდებარე შეთანხმების ძალაში შესვლის დღიდან სამი წლის განმავლობაში, ნებისმიერ ხელშემკვრელ მხარეს, გაერთიანებული ერების ორგანიზაციის გენერალური მდივნის მიმართ შეტყობინების წარდგენის გზით, შეუძლია მოითხოვოს კონფერენციის მოწვევა შეთანხმების ტექსტის გადასინჯვის მიზნით. გენერალური მდივანი შეატყობინებს მოთხოვნას ყველა ხელშემკვრელ მხარეს და მოიწვევს კონფერენციას შეთანხმების გადასინჯვის მიზნით იმ xx შემთხვევაში, თუ გენერალური მდივნის მიერ შეტყობინების გაცემის თარიღიდან ოთხი თვის განმავლობაში ხელშემკვრელი მხარეების არანაკლებ ერთი მეოთხედი აუწყებს მას, რომ ისინი ეთანხმებიან აღნიშნულ მოთხოვნას. 2. წინამდებარე მუხლის პირველი პუნქტის თანახმად კონფერენციის მოწვევის შემთხვევაში, გენერალური მდივანი აუწყებს აღნიშნულის შესახებ ყველა ხელშემკვრელ მხარეს და სთხოვს მათ წარმოადგინონ ის წინადადებები სამი თვის განმავლობაში, რომელთა განხილვასაც ისურვებდნენ კონფერენციაზე. გენერალური მდივანი წინასწარ აცნობებს კონფერენციის დღის წესრიგს ყველა ხელშემკვრელ მხარეს, ასევე აღნიშნული წინადადებების ტექსტს, კონფერენციის ჩატარების თარიღამდე მინიმუმ სამი თვის განმავლობაში. 3. წინამდებარე მუხლის თანახმად გამართულ ნებისმიერ კონფერენციაზე გენერალური მდივანი მოიწვევს მე-6 მუხლის პირველი პუნქტით გათვალისწინებულ ყველა ქვეყანას, ასევე იმ ქვეყნებს, რომლებიც გახდნენ ხელშემკვრელი მხარეები მე-6 მუხლის მე-2 პუნქტის თანახმად. მუხლი 14 1 1. მე-13 მუხლით გათვალისწინებული განხილვის პროცედურებისგან დამოუკიდებლად, ნებისმიერ ხელშემკვრელ მხარეს შეუძლია წარმოადგინოს წინადადება წინამდებარე შეთანხმების დანართებში ერთი ან რამდენიმე შესწორების შეტანის შესახებ. აღნიშნული მიზნით ის წარუდგენს შესაბამის ტექსტს გაერთიანებული ერების ორგანიზაციის გენერალურ მდივანს. გენერალურ მდივანს ასევე შეუძლია წარმოადგინოს წინადადება შეთანხმების დანართებში შესწორებების შეტანის შესახებ აღნიშნულ დანართებსა და სახიფათო ტვირთის გადაზიდვებთან დაკავშირებით არსებულ სხვა საერთაშორისო შეთანხმებებს შორის შესაბამისობის უზრუნველყოფის მიზნით. 2. გენერალური მდივანი აცნობებს წინამდებარე მუხლის პირველი პუნქტის თანახმად გაკეთებულ ნებისმიერ წინადადებას ყველა ხელშემკვრელ მხარეს, ასევე აცნობებს აღნიშნულს მე-6 მუხლის პირველი პუნქტით გათვალისწინებულ სხვა ქვეყნებს. 3. დანართებში წარმოდგენილი ნებისმიერი შესწორება ჩაითვლება მიღებულად იმ შემთხვევაში, თუ გენერალური მდივნის მიერ მისი გაცემის დღიდან სამი თვის განმავლობაში ხელშემკვრელი მხარეების მინიმუმ ერთი მესამედი ან ხუთი მათგანი, თუ ერთი მესამედი აღემატება აღნიშნულ ციფრს, არ წარუდგენს გენერალურ მდივანს მის უარს წარმოდგენილ შესწორებებზე წერილობითი შეტყობინების სახით. იმ შემთხვევაში, თუ შესწორება ჩაითვლება მიღებულად, ის კანონიერ ძალაში შევა ყველა ხელშემკვრელი მხარისთვის შემდგომი სამი თვის ამოწურვისას, გარდა შემდეგი შემთხვევებისა: (ა) იმ შემთხვევებში, თუ ანალოგიური სახის შესწორებები შევიდა ან შესაძლებელია ყოფილიყვნენ შეტანილნი წინამდებარე მუხლის პირველ პუნქტში გათვალისწინებულ სხვა საერთაშორისო შეთანხმებებში, შესწორება ძალაში შედის გენერალური მდივნის მიერ განსაზღვრული ვადის ამოწურვის შემდეგ, რათა შესაძლებლობის შემთხვევაში უზრუნველყოფილი იქნეს აღნიშნული შესწორებისა და იმ შესწორებების ერთდროულად შესვლა კანონიერ ძალაში, რომლებიც შევიდა ან 1 სამდივნოს შენიშვნა: მე-14 მუხლის მე-3 პუნქტში წარმოდგენილი ტექსტი ითვალისწინებს ცვლილებას, რომელიც ძალაში შევიდა 1985 წლის 19 აპრილს ხელშემკვრელი მხარეების მიმართ 1975 წლის 18 სექტემბრის C.N.229.1975.TREATIES-8 სადეპოზიტო უწყების სახით წარდგენილი ოქმის შესაბამისად. xxi სავარაუდოდ უნდა ყოფილიყვნენ შეტანილნი სხვა მსგავს შეთანხმებებში; თუმცა აღნიშნული ვადა არ უნდა იყოს ერთ თვეზე ნაკლები; (ბ) შესწორების წარმდგენ ხელშემკვრელ მხარეს შეუძლია მიუთითოს მის წინადადებაში სამ თვეზე მეტი ხანგრძლივობის ვადა, შესწორების მიღების შემთხვევაში მისი კანონიერ ძალაში შესვლის მიზნით. 4. გენერალური მდივანი შეძლებისდაგვარად სწრაფად აცნობებს ყველა ხელშემკვრელ მხარესა და მე-6 მუხლის პირველ პუნქტში გათვალისწინებულ ყველა ქვეყანას, ხელშემკვრელი მხარეების მიერ წარმოდგენილ შესწორებასთან დაკავშირებით გამოთქმული პროტესტის შესახებ. 5. იმ შემთხვევაში, თუ დანართებში წარმოდგენილი შესწორებები არ ჩაითვლება მიღებულად, თუმცა მინიმუმ ერთი ხელშემკვრელი მხარე, რომელიც არ წარმოადგენს შესწორების წარმომდგენ ხელშემკვრელ მხარეს, წერილობით შეატყობინებს გენერალურ მდივანს მის თანხმობას წინადადებასთან დაკავშირებით, გენერალური მდივანი მოიწვევს კრებას ყველა ხელშემკვრელი მხარისა და მე-6 პუნქტის პირველ მუხლში გათვალისწინებული ქვეყნების მონაწილეობით სამთვიანი ვადის ამოწურვიდან სამი თვის მანძილზე, რომლის განმავლობაშიც წინამდებარე მუხლის მე-3 პუნქტის თანახმად უნდა იქნეს წარმოდგენილი შეტყობინება შესწორების უარყოფის შესახებ. გენერალურ მდივანს ასევე შეუძლია მოიწვიოს აღნიშნულ კრებაზე შემდეგი ორგანიზაციების წარმომადგენლები: 6. (ა) სატრანპორტო სფეროში ჩართული საერთაშორისო სამთავრობო ორგანიზაციები; (ბ) საერთაშორისო არასამთავრობო ორგანიზაციები, რომელთა საქმიანობაც პირდაპირ არის დაკავშირებული სახიფათო ტვირთების გადაზიდვებთან ხელშემკვრელი მხარეების ტერიტორიაზე. მე-5 მუხლის თანახმად მოწვეულ კრებაზე ხელშემკვრელი მხარეების საერთო რაოდენობის ნახევარზე მეტის მიერ მიღებული ნებისმიერი შესწორება შედის კანონიერ ძალაში ყველა ხელშემკვრელი მხარის მიმართ, კრებაზე დამსწრე ხელშემკვრელი მხარეების უმრავლესობის მიერ შეთანხმებული წესის შესაბამისად. მუხლი 15 მე-13 და მე-14 მუხლებში გათვალისწინებული შეტყობინებების გარდა, გაერთიანებული ერების ორგანიზაციის გენერალური მდივანი შეატყობინებს მე-6 მუხლის პირველ პუნქტში გათვალისწინებულ ყველა ქვეყანას, ასევე იმ ქვეყნებს, რომლებიც მე-6 მუხლის მე-2 პუნქტის თანახმად გახდნენ ხელშემკვრელი მხარეები შემდეგს: (ა) ხელმოწერები, შეთანხმების რატიფიკაცია და მასთან შეერთება მე-6 მუხლის თანახმად; (ბ) თარიღები, როდესაც წინამდებარე შეთანხმება და მისი დანართები შევიდა კანონიერ ძალაში მე-7 მუხლის თანახმად; (გ) დენონსაცია მე-8 მუხლის თანახმად; (დ) შეთანხმების მოშლა მე-9 მუხლის თანახმად; (ე) მე-10 მუხლის თანახმად მიღებული შეტყობინებები და დენონსაციები; (ვ) მე-12 მუხლის პირველი და მე-2 პუნქტების თანახმად მიღებული დეკლარაციები და შეტყობინებები; xxii (ზ) მე-14 მუხლის მე-3 და მე-6 პუნქტების თანახმად შესწორებების მიღება და მათი ძალაში შესვლის თარიღი. მუხლი 16 1. წინამდებარე შეთანხმების ხელმოწერის ოქმს გააჩნია იგივე ძალა, მნიშვნელობა და მოქმედების ვადა, როგორც თავად შეთანხმებას, რომლის განუყოფელ ნაწილადაც ითვლება. 2. დაუშვებელია წინამდებარე შეთანხმებასთან მიმართებით რაიმე დათქმის გაკეთება, გარდა ხელმოწერის ოქმში მითითებული და მე-12 მუხლის თანახმად გაკეთებული დათქმებისა. მუხლი 17 1957 წლის 15 დეკემბრის შემდეგ წინამდებარე შეთანხმების დედანი შესანახად უნდა გადაეცეს გაერთიანებული ერების ორგანიზაციის გენერალურ მდივანს, რომელიც, თავის მხრივ, გადასცემს მის დამოწმებულ ეგზემპლარებს მე-6 მუხლის პირველ პუნქტში გათვალისწინებულ ყოველ ქვეყანას. აღნიშნულის დასტურად, ქვემორე სათანადოდ უფლებამოსილმა ხელმომწერებმა შეასრულეს ხელმოწერა წინამდებარე შეთანხმებაზე. შესრულებულია ჟენევაში, ათასცხრაას ორმოცდაჩვიდმეტი წლის ოცდაათ სექტემბერს, ერთ ეგზემპლარად, შეთანხმების ტექსტი შედგენილია ინგლისურ და ფრანგულ ენებზე, ხოლო დანართები - ფრანგულ ენაზე, შეთანხმების ორივე ტექსტი თანაბრად ავთენტიკურია. გაერთიანებული ერების ორგანიზაციის გენერალურ მდივანს ეთხოვა, უზრუნველყოს დანართების ოფიციალური თარგმანი ინგლისურ ენაზე და დაურთოს აღნიშნული თარგმანი მე-17 მუხლით გათვალისწინებულ დამოწმებულ ეგზემპლარებს. xxiii xxiv ხელმოწერის ოქმი xxv ხელმოწერის ოქმი ევროპული შეთანხმება სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ (ADR) სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვების შესახებ ევროპული შეთანხმების (ADR) ხელმოწერისას, ქვემორე სათანადოდ უფლებამოსილმა ხელმომწერებმა: 1. განიხილეს რა, რომ სახიფათო ტვირთის საზღვაო გადაზიდვების პირობები გაერთიანებულ სამეფოში ან მოცემული ქვეყნიდან, ძირეულად განსხვავდება ADR-ის A დანართში გათვალისწინებული პირობებისგან და უახლოეს მომავალში შეუძლებელია მათი შეცვლა ამ უკანასკნელთან მათი შესაბამისობის უზრუნველყოფის მიზნით; მხედველობაში მიიღეს რა, რომ გაერთიანებულმა სამეფომ იკისრა ვალდებულება წარადგინოს შესწორება აღნიშნულ A დანართში კონტინენტსა და გაერთიანებულ სამეფოს შორის სახიფათო ტვირთების საგზაო და საზღვაო გადაზიდვებთან დაკავშირებული სპეციალური დებულებების შემცველი სპეციალური დანართის სახით; შეთანხმდნენ რა, რომ აღნიშნული სპეციალური დანართის კანონიერ ძალაში შესვლამდე, ADR-ის საფუძველზე სახიფათო ტვირთების გადაზიდვა გაერთიანებულ სამეფოში ან აღნიშნული ქვეყნიდან, უნდა აკმაყოფილებდეს ADR-ის A დანართის დებულებებს, ასევე გაერთიანებულ სამეფოში მოქმედ პირობებს სახიფათო ტვირთის საზღვაო გადაზიდვების შესახებ; 2. მხედველობაში მიიღეს საფრანგეთის წარმომადგენლის მიერ გაკეთებული განცხადება, რომლის მიხედვითაც საფრანგეთის რესპუბლიკის ხელისუფლება ინარჩუნებს უფლებას, მე-4 მუხლის მე-2 პუნქტით გათვალისწინებული პირობების მიუხედავად, უარი თქვას იმ ავტოსატრანსპორტო საშუალებების გადაზიდვებზე დაშვებაზე, რომლებიც იმყოფება ექსპლუატაციაში სხვა ხელშემკვრელი მხარეების ტერიტორიაზე და მიუხედავად მათი ექსპლუატაციაში გაშვების დღისა, გამოყენებულ იქნან სახიფათო ტვირთების გადასაზიდად საფრანგეთის ტერიტორიაზე, თუ აღნიშნული ავტოსატრანსპორტო საშუალებები არ აკმაყოფილებს B დანართით გათვალისწინებულ პირობებს გადაზიდვებთან დაკავშირებით ან სახიფათო ტვირთების საგზაო გადაზიდვების შესახებ საფრანგეთის წესებში გათვალისწინებულ შესაბამისი ტვირთის გადაზიდვის პირობებს; 3. წარმოადგენენ რეკომენდაციას, რომ მე-14 მუხლის პირველი პუნქტისა თუ მე-13 მუხლის მე-2 პუნქტის თანახმად წინამდებარე შეთანხმებაში ან მის დანართებში შეთავაზებული შესწორებების წარდგენამდე, ისინი, რამდენადაც შესაძლებელია, უპირველეს ყოვლისა, განხილულ იქნეს ხელშემკვრელი მხარეების ექსპერტთა, ხოლო აუცილებლობის შემთხვევაში, შეთანხმების მე-6 მუხლის პირველ პუნქტში გათვალისწინებული ქვეყნების ექსპერტების შეხვედრებზე, ასევე მე-14 მუხლის მე-5 პუნქტში გათვალისწინებული საერთაშორისო ორგანიზაციების მიერ. xxvi

Corrigendum Ref. Sales No.: E.14.VIII.1 (ECE/TRANS/242, Vol. I and II) November 2014 New York and Geneva EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR) (applicable as from 1 January 2015) Corrigendum Note : Corrigenda to this edition, as well as any new amendments to Annexes A and B of ADR which might enter into force before the next edition is published, will be made available on the United Nations Economic Commission for Europe website at the following address: http://www.unece.org/trans/danger/danger.htm Volume I 1. Chapter 2.2, 2.2.41.4, in the column for SELF-REACTIVE SUBSTANCE For 2,2' -AZODI(ISOBUTYRONITRILE read 2,2' -AZODI(ISOBUTYRONITRILE) 2. Page 187, Chapter 2.2, para. 2.2.61.1.8 Replace the existing figure with the following 10.000 NOT DANGEROUS PACKING GROUP III PACKING GROUP II LC50 ml/m3 1.000 PACKING GROUP I 100 10 10 100 1.000 Volatility ml/m3 GE.14- 10.000 100.000 ECE/TRANS/242/Corr.1 English only ECE/TRANS/242/Corr.1 page 2 3. Pages 324 and 325, Chapter 3.2, Table A, UN No. 1202, second entry, column (2) For EN 590:2004 read EN 590:2009 + A1:2010 4. Page 326, Chapter 3.2, Table A, UN No. 1203, column (6) For 534 363 read 363 534 5. Page 334, Chapter 3.2, Table A, UN No. 1286, second entry for packing group II, column (8) At the beginning, insert P001 6. Page 334, Chapter 3.2, Table A, UN No. 1286, all entries for packing group III, column (8) At the beginning, insert P001 7. Page 369, Chapter 3.2, Table A, UN No. 1792, column (12) For L4BN SGAN read SGAN L4BN 8. Page 462, Chapter 3.2, Table A, UN No. 3090, column (6) After 230 insert 310 9. Page 462, Chapter 3.2, Table A, UN No. 3091, column (6) After 230 insert 360 10. Page 510, Chapter 3.2, Table A, UN No. 3481, column (6) For 376 377 360 read 360 376 377 11. Page 515, Chapter 3.2, Table A, UN No. 3509 Move the alphanumeric codes VC2 and AP10 from column (16) to column (17). 12. Page 514, Chapter 3.2, Table A, UN No. 3513 in column (5) For 2.2+5.5 read 2.2+5.1 Volume II 13. Page x, Table of Contents, 7.3.3 Delete Special 14. Page 583, Chapter 9.2, para. 9.2.3.1.1 Delete or Directive 71/320/EEC3

ECE/TRANS/242 (Vol.I) Economic Commission for Europe Committee on Inland Transport applicable as from 1 January 2015 European Agreement Concerning the International Carriage of Dangerous Goods by Road Volume I UNITED NATIONS New York and Geneva, 2014 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ECE/TRANS/242 (Vol.I) Copyright  United Nations, 2014 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS PUBLICATION Sales No.: 14.VIII.1 ISBN 978-92-1-139149-7 (complete set of 2 volumes) e-ISBN 978-92-1-056691-9 Volumes I and II not to be sold separately. United Nations Economic Commission for Europe (UNECE) The United Nations Economic Commission for Europe (UNECE) is one of the five United Nations regional commissions, administered by the Economic and Social Council (ECOSOC). It was established in 1947 with the mandate to help rebuild post-war Europe, develop economic activity and strengthen economic relations among European countries, and between Europe and the rest of the world. During the Cold War, UNECE served as a unique forum for economic dialogue and cooperation between East and West. Despite the complexity of this period, significant achievements were made, with consensus reached on numerous harmonization and standardization agreements. In the post-Cold War era, UNECE acquired not only many new member States, but also new functions. Since the early 1990s the organization has focused on analyses of the transition process, using its harmonization experience to facilitate the integration of central and eastern European countries into global markets. UNECE is the forum where the countries of western, central and eastern Europe, Central Asia and North America – 56 countries in all – come together to forge the tools of their economic cooperation. That cooperation concerns economics, statistics, environment, transport, trade, sustainable energy, timber and habitat. The Commission offers a regional framework for the elaboration and harmonization of conventions, norms and standards. The Commission's experts provide technical assistance to the countries of South-East Europe and the Commonwealth of Independent States. This assistance takes the form of advisory services, training seminars and workshops where countries can share their experiences and best practices. - iii - Transport in UNECE The UNECE Inland Transport Committee (ITC) facilitates the international movement of persons and goods by inland transport modes. It aims to improve competitiveness, safety, energy efficiency and security in the transport sector. At the same time it focuses on reducing the adverse effects of transport activities on the environment and contributing effectively to sustainable development. The ITC is a: - Centre for multilateral transport standards and agreements in Europe and beyond, e.g. regulations for dangerous goods transport and road vehicle construction at the global level - Gateway for technical assistance and exchange of best practices - Promoter of multi-country investment planning - Substantive partner for transport and trade facilitation initiatives - Historic centre for transport statistics. For more than six decades, ITC has provided a platform for intergovernmental cooperation to facilitate and develop international transport while improving its safety and environmental performance. The main results of this persevering and important work are reflected in more than 50 international agreements and conventions which provide an international legal framework and technical regulations for the development of international road, rail, inland water and intermodal transport, as well as dangerous goods transport and vehicle construction. Considering the needs of the transport sector and its regulators, UNECE offers a balanced approach to and treatment of facilitation and security issues alike. - iv - FOREWORD General The European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR) was done at Geneva on 30 September 1957 under the auspices of the United Nations Economic Commission for Europe, and it entered into force on 29 January 1968. The Agreement itself was amended by the Protocol amending article 14 (3) done at New York on 21 August 1975, which entered into force on 19 April 1985. According to article 2 of the Agreement, dangerous goods barred from carriage by Annex A shall not be accepted for international transport, while international transport of other dangerous goods shall be authorized subject to compliance with: - the conditions laid down in Annex A for the goods in question, in particular as regards their packaging and labelling; and - the conditions laid down in Annex B, in particular as regards the construction, equipment and operation of the vehicle carrying the goods in question. Nevertheless, according to article 4, each Contracting Party shall retain the right to regulate or prohibit, for reasons other than safety during carriage, the entry of dangerous goods into its territory. Contracting Parties also retain the right to arrange, by bilateral or multilateral agreements, that certain dangerous goods which are prohibited from carriage by Annex A be internationally carried, subject to certain conditions, on their territories, or that dangerous goods authorized to be carried internationally according to Annex A be carried on their territories under conditions less stringent than those specified in Annexes A and B. Annexes A and B have been regularly amended and updated since the entry into force of ADR. Structure of Annexes A and B The Working Party on the Transport of Dangerous Goods (WP.15) of the Economic Commission for Europe’s Committee on Inland Transport decided, at its fifty-first session (26-30 October 1992), to restructure Annexes A and B, on the basis of a proposal by the International Road Transport Union (TRANS/WP.15/124, paras. 100-108). The main objectives were to make the requirements more accessible and more user-friendly so that they could be applied more easily not only to international road transport operations under ADR, but also to domestic traffic in all European States through national or European Community legislation, and ultimately to ensure a consistent regulatory framework at European level. It was also considered necessary to identify more clearly the duties of the various participants in the transport chain, to group more systematically the requirements concerning these various participants, and to differentiate the legal requirements of ADR from the European or international standards that could be applied to meet such requirements. The structure is consistent with that of the United Nations Recommendations on the Transport of Dangerous Goods, Model Regulations, the International Maritime Dangerous Goods Code (IMDG Code) and the Regulations concerning the International Carriage of Dangerous Goods by Rail (RID). It has been split into nine parts, but still grouped under two annexes to align with the wording of article 2 of the Agreement itself. The layout is as follows: Annex A: General provisions and provisions concerning dangerous articles and substances Part 1 Part 2 Part 3 Part 4 General provisions Classification Dangerous goods list, special provisions and exemptions related to limited and excepted quantities Packing and tank provisions -v- Part 5 Consignment procedures Part 6 Requirements for the construction and testing of packagings, intermediate bulk containers (IBCs), large packagings, tanks and bulk containers Part 7 Provisions concerning the conditions of carriage, loading, unloading and handling Annex B: Provisions concerning transport equipment and transport operations Part 8 Requirements for vehicle crews, equipment, operation and documentation Part 9 Requirements concerning the construction and approval of vehicles Part 1, which contains general provisions and definitions, is an essential part, since it contains all definitions for terms used throughout the other parts, and it defines precisely the scope and applicability of ADR, including the possibility of exemptions, as well as the applicability of other regulations. It also contains provisions concerning training, derogations and transitional measures, the respective safety obligations of the various participants in a chain of transport of dangerous goods, control measures, safety advisers, restrictions for the passage of vehicles carrying dangerous goods through road tunnels and transport of dangerous goods security. Central to the use of the restructured ADR is table A of Chapter 3.2 which contains the dangerous goods list in the numerical order of UN numbers. Once the UN number of a specific dangerous substance or article has been determined, the table provides cross-references to specific requirements to be applied for the carriage of that substance or article, and to the chapters or sections where these specific requirements may be found. Nevertheless, it should be borne in mind that the general requirements or class specific requirements of the various Parts have to be applied in addition to specific requirements, as relevant. An alphabetical index which indicates the UN number assigned to specific dangerous goods has been prepared by the secretariat and added as table B of Chapter 3.2 to facilitate the access to table A when the UN number is unknown. This table B is not an official part of ADR and has been added in the publication for easy reference only. When goods which are known or suspected to be dangerous cannot be found by name in any of tables A or B, they have to be classified in accordance with Part 2, which contains all relevant procedures and criteria to determine whether such goods are deemed to be dangerous or not and which UN number should be assigned. Applicable texts This version ("2015 ADR") takes into account all new amendments adopted by WP.15 in 2012, 2013 and 2014, circulated under the symbols ECE/TRANS/WP.15/222 -/Corr.1 and -/Corr.2 and ECE/TRANS/WP.15/222/Add.1 and -/Corr.1, which, subject to acceptance by the Contracting Parties in accordance with article 14(3) of the Agreement, should enter into force on 1 January 2015. Nevertheless, due to the transitional measures provided for in 1.6.1.1 of Annex A, the previous version ("2013 ADR") may continue to be used until 30 June 2015. Territorial applicability ADR is an Agreement between States, and there is no overall enforcing authority. In practice, highway checks are carried out by Contracting Parties, and non-compliance may then result in legal action by national authorities against offenders in accordance with their domestic legislation. ADR itself does not prescribe any penalties. At the time of publishing, the Contracting Parties are Albania, Andorra, Austria, Azerbaijan, Belarus, Belgium, Bosnia and Herzegovina, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Kazakhstan, Latvia, Liechtenstein, Lithuania, Luxembourg, Malta, Montenegro, Morocco, Netherlands, Norway, Poland, Portugal, the Republic of Moldova, Romania, Russian Federation, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Tajikistan, the former Yugoslav Republic of Macedonia, Tunisia, Turkey, Ukraine and United Kingdom. - vi - ADR applies to transport operations performed on the territory of at least two of the above-mentioned Contracting Parties. In addition, it should be noted that, in the interest of uniformity and free trading across the European Union (EU), Annexes A and B of ADR have also been adopted by EU Member States as the basis for regulation of the carriage of dangerous goods by road within and between their territories (Directive 2008/68/EC of the European Parliament and of the Council of 24 September 2008 on the inland transport of dangerous goods, as amended). A number of non-EU countries have also adopted Annexes A and B of ADR as the basis for their national legislation. Additional practical information Any query concerning the application of ADR should be directed to the relevant competent authority. Additional information may be found on the UNECE Transport Division website on the following page: http://www.unece.org/trans/danger/danger.htm This website is regularly updated and contains the following information: - General information on ADR - Agreement (without annexes) - Protocol of signature - Present status of ADR - Depositary notifications - Country information (Competent Authorities, notifications) - Linguistic versions (ADR, instructions in writing) - Multilateral agreements - ADR 2015 (files) - ADR 2013 (files) - ADR 2013 (amendments) - Previous versions (files and amendments) - Publication details and Corrigenda - vii - TABLE OF CONTENTS VOLUME I Page Annex A Part 1 European Agreement concerning the international carriage of dangerous goods by road ............................................................................................ xvii Protocol of signature ........................................................................................................ xxiii General provisions and provisions concerning dangerous substances and articles .............................................................................................................. 1 General provisions ........................................................................................................... 3 Chapter 1.1 Scope and applicability ..................................................................... 5 Structure .............................................................................................. Scope ................................................................................................... Exemptions .......................................................................................... Applicability of other regulations ....................................................... Application of standards ...................................................................... 5 5 6 12 13 Definitions and units of measurement ............................................. 15 Definitions ........................................................................................... Units of measurement ......................................................................... 15 33 Training of persons involved in the carriage of dangerous goods ............................................................................ 35 Scope and applicability ....................................................................... Nature of the training .......................................................................... Documentation .................................................................................... 35 35 35 Safety obligations of the participants .............................................. 37 General safety measures ...................................................................... Obligations of the main participants ................................................... Obligations of the other participants ................................................... 37 37 39 Derogations ........................................................................................ 43 Temporary derogations ....................................................................... (Reserved) ........................................................................................... 43 43 Transitional measures ....................................................................... 45 General ................................................................................................ Pressure receptacles and receptacles for Class 2 ................................. Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles ................................................................................... Tank-containers, portable tanks and MEGCs ..................................... Vehicles ............................................................................................... Class 7 ................................................................................................. 45 47 1.1.1 1.1.2 1.1.3 1.1.4 1.1.5 Chapter 1.2 1.2.1 1.2.2 Chapter 1.3 1.3.1 1.3.2 1.3.3 Chapter 1.4 1.4.1 1.4.2 1.4.3 Chapter 1.5 1.5.1 1.5.2 Chapter 1.6 1.6.1 1.6.2 1.6.3 1.6.4 1.6.5 1.6.6 - ix - 48 51 54 55 Table of contents (cont'd) Chapter 1.7 1.7.1 1.7.2 1.7.3 1.7.4 1.7.5 1.7.6 Chapter 1.8 1.8.1 1.8.2 1.8.3 1.8.4 1.8.5 1.8.6 1.8.7 1.8.8 Chapter 1.9 Part 2 General provisions concerning radioactive material ..................... Page 57 Scope and application ......................................................................... Radiation protection programme ......................................................... Management system ............................................................................ Special arrangement ............................................................................ Radioactive material possessing other dangerous properties ........................................................................... Non-compliance ................................................................................... 59 60 Checks and other support measures to ensure compliance with safety requirements .............................................. 61 Administrative controls of dangerous goods ....................................... Mutual administrative support ............................................................ Safety adviser ...................................................................................... List of competent authorities and bodies designated by them .............................................................................. Notifications of occurrences involving dangerous goods ................... Administrative controls for application of the conformity assessments, periodic inspections, intermediate inspections and exceptional checks described in 1.8.7 ................................................................................. Procedures for conformity assessment and periodic inspection ........... Procedures for conformity assessment of gas cartridges...................... 57 58 59 59 61 61 61 67 67 73 75 81 Transport restrictions by the competent authorities ..................... 85 1.9.5 Tunnel restrictions ............................................................................... 85 Chapter 1.10 Security provisions ............................................................................. 89 1.10.1 1.10.2 1.10.3 General provisions ............................................................................... Security training ................................................................................... Provisions for high consequence dangerous goods .............................. 89 89 89 Classification .............................................................................................................. 95 Chapter 2.1 General provisions ............................................................................ 97 Introduction .......................................................................................... Principles of classification ................................................................... Classification of substances, including solutions and mixtures (such as preparations and wastes), not mentioned by name ................. Classification of samples...................................................................... Classification of packagings, discarded, empty, uncleaned 97 98 99 103 104 Class specific provisions ................................................................... 105 Class 1 Explosive substances and articles ......................................... Class 2 Gases ..................................................................................... Class 3 Flammable liquids ................................................................ Class 4.1 Flammable solids, self-reactive substances and solid desensitized explosives ......................................... Class 4.2 Substances liable to spontaneous combustion ...................... 105 131 141 2.1.1 2.1.2 2.1.3 2.1.4 2.1.5 Chapter 2.2 2.2.1 2.2.2 2.2.3 2.2.41 2.2.42 -x- 146 156 Table of contents (cont'd) Page 2.2.43 2.2.51 2.2.52 Class 4.3 Substances which, in contact with water, emit flammable gases............................................................ Class 5.1 Oxidizing substances ............................................................ Class 5.2 Organic peroxides ................................................................. 160 163 168 2.2.61 2.2.62 2.2.7 2.2.8 2.2.9 Class 6.1 Toxic substances ................................................................... Class 6.2 Infectious substances ............................................................ Class 7 Radioactive material ............................................................. Class 8 Corrosive substances ............................................................ Class 9 Miscellaneous dangerous substances and articles................. 184 197 204 234 239 Test methods ...................................................................................... 255 General ................................................................................................. Exudation test for blasting explosives of Type A ................................ Tests relating to nitrated cellulose mixtures of Class 4.1 ..................... Tests relating to flammable liquids of Classes 3, 6.1 and 8 ................. Test for determining fluidity ................................................................ Classification of organometallic substances in Classes 4.2 and 4.3 ..... 255 255 257 258 260 262 Dangerous goods list, special provisions and exemptions related to limited and excepted quantities ...................................................................................... 265 Chapter 3.1 General ............................................................................................... 267 Introduction .......................................................................................... Proper shipping name........................................................................... Solutions or mixtures ........................................................................... 267 267 269 Dangerous goods list ......................................................................... 271 Table A: Dangerous Goods List ........................................................... Table B: Alphabetic index of substances and articles of ADR ........... 271 518 Special provisions applicable to certain articles or substances ...................................................................................... 571 Dangerous goods packed in limited quantities ........................................................................... 609 Dangerous goods packed in excepted quantities ............................ 613 3.5.1 Excepted quantities .............................................................................................. 3.5.2 Packagings ........................................................................................................... 3.5.3 Tests for packages ............................................................................................... 3.5.4 Marking of packages ........................................................................................... 3.5.5 Maximum number of packages in any vehicle or container ................................ 3.5.6 Documentation ................................................................................................... 613 614 614 615 616 616 Chapter 2.3 2.3.0 2.3.1 2.3.2 2.3.3 2.3.4 2.3.5 Part 3 3.1.1 3.1.2 3.1.3 Chapter 3.2 3.2.1 3.2.2 Chapter 3.3 Chapter 3.4 Chapter 3.5 - xi - TABLE OF CONTENTS VOLUME II Page Annex A (cont’d) General provisions and provisions concerning dangerous substances and articles .............................................................................................................. 1 Part 4 Packing and tank provisions ........................................................................................... 3 Chapter 4.1 Use of packagings, including intermediate bulk containers (IBCs) and large packagings .......................................... 5 Use of portable tanks and UN multiple-element gas containers (MEGCs) ............................... 151 Use of fixed tanks (tank-vehicles), demountable tanks, tank-containers and tank swap bodies with shells made of metallic materials, and battery-vehicles and multiple-element gas containers (MEGCs) ..................................... 175 Use of fibre-reinforced plastics (FRP) tanks, fixed tanks (tank-vehicles), demountable tanks, tank containers and tank swap bodies ........................................................................ 199 Chapter 4.5 Use of vacuum operated waste tanks ............................................... 201 Chapter 4.6 (Reserved) ........................................................................................... 203 Chapter 4.7 Use of mobile explosives manufacturing units (MEMUs) ............. 205 Consignment procedures ................................................................................................. 207 Chapter 5.1 General provisions ............................................................................ 209 Chapter 5.2 Marking and labelling ...................................................................... 217 Chapter 5.3 Placarding and marking of containers, MEGCs, MEMUs, 261 tank-containers, portable tanks and vehicles ................................. 229 Chapter 5.4 Documentation .................................................................................. 239 Chapter 5.5 Special provisions .............................................................................. 259 Chapter 4.2 Chapter 4.3 Chapter 4.4 Part 5 - xii - Table of contents (cont'd) Page Part 6 Requirements for the construction and testing of packagings, intermediate bulk container (IBCs), large packagings, tanks and bulk containers .......................... Chapter 6.1 Chapter 6.2 Chapter 6.3 Chapter 6.4 Chapter 6.5 Chapter 6.6 Chapter 6.7 Chapter 6.8 Chapter 6.9 Chapter 6.10 Chapter 6.11 Chapter 6.12 268 Requirements for the construction and testing of packagings .......................................................................................... 267 Requirements for the construction and testing of pressure receptacles, aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas ..................................................................................... 297 Requirements for the construction and testing of packagings for Class 6.2 infectious substances of Category A ....... 337 Requirements for the construction, testing and approval of packages for radioactive material and for the approval of such material ................................................... 343 Requirements for the construction and testing of intermediate bulk containers (IBCs) ........................................... 369 Requirements for the construction and testing of large packagings ................................................................................ 393 Requirements for the design, construction, inspection and testing of portable tanks and UN multiple-element gas containers (MEGCs) ............................... 403 Requirements for the construction, equipment, type approval, inspections and tests, and marking of fixed tanks (tank-vehicles), demountable tanks and tank-containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple element gas containers (MEGCs) ..................................... 455 Requirements for the design, construction, equipment, type approval, testing and marking of fibre-reinforced plastics (FRP) fixed tanks (tank-vehicles), demountable tanks, tank-containers and tank swap bodies ........... 497 Requirements for the construction, equipment, type approval, inspection and marking of vacuum-operated waste tanks ......................................................................................... 505 Requirements for the design, construction, inspection and testing of bulk containers .......................................................... 509 Requirements for the construction, equipment, type approval, inspections and tests, and marking of tanks, bulk containers and special compartments for explosives of mobile explosives manufacturing units (MEMUs) ....................................................... 511 - xiii - Table of contents (cont'd) Page Part 7 Annex B Part 8 Provisions concerning the conditions of carriage, loading, unloading and handling .............................................................................................................. 515 Chapter 7.1 General provisions ............................................................................ 517 Chapter 7.2 Provisions concerning carriage in packages ................................... 519 Chapter 7.3 Provisions concerning carriage in bulk ........................................... 523 Chapter 7.4 Provisions concerning carriage in tanks ......................................... 529 Chapter 7.5 Provisions concerning loading, unloading and handling ...................................................................................... 531 Provisions concerning transport equipment and transport operations ........................................................................................................ 545 Requirements for vehicle crews, equipment, operation and documentation .............................................................................................................. 547 Chapter 8.1 General requirements concerning transport units and equipment on board ................................................................... 549 Requirements concerning the training of the vehicle crew .............................................................................. 553 Miscellaneous requirements to be complied with by the vehicle crew ................................................................................. 559 Chapter 8.4 Requirements concerning the supervision of vehicles..................... 561 Chapter 8.5 Additional requirements relating to particular classes or substances ...................................................................................... 563 Road tunnel restrictions for the passage of vehicles carrying Dangerous goods ............................................................................... 567 Requirements concerning the construction and approval of vehicles ......................... 569 Chapter 8.2 Chapter 8.3 Chapter 8.6 Part 9 Chapter 9.1 Chapter 9.2 Chapter 9.3 Chapter 9.4 Scope, definitions and requirements for the approval of vehicles ........................................................................... 571 Requirements concerning the construction of vehicles ............................................................................................... 577 Additional requirements concerning complete or completed EX/II or EX/III vehicles intended for the carriage of explosive substances and articles (Class 1) in packages ................. 587 Additional requirements concerning the construction of the bodies of complete or completed vehicles intended for the carriage of dangerous goods in packages (other than EX/II and EX/III vehicles) ........................................... 589 - xiv - Table of contents (cont'd) Page Chapter 9.5 Chapter 9.6 Chapter 9.7 Chapter 9.8 Additional requirements concerning the construction of the bodies of complete or completed vehicles intended for the carriage of dangerous solids in bulk ................................... 591 Additional requirements concerning complete or completed vehicles intended for the carriage of temperature controlled substances ................................................... 593 Additional requirements concerning fixed tanks (tank-vehicles), battery-vehicles and complete or completed vehicles used for the carriage of dangerous goods in demountable tanks with a capacity greater than 1 m3 or in tank-containers, portable tanks or MEGCs of a capacity greater than 3 m3 (EX/III, FL, OX and AT vehicles) ... 595 Additional requirements concerning complete and Completed MEMUs .......................................................................... 599 - xv - EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR) THE CONTRACTING PARTIES, DESIRING to increase the safety of international transport by road, HAVE AGREED as follows: Article 1 For the purpose of this Agreement, (a) the term "vehicle" shall mean motor vehicles, articulated vehicles, trailers and semi-trailers, as defined in article 4 of the Convention on Road Traffic of 19 September 1949, other than vehicles belonging to or under the orders of the armed forces of a Contracting Party; (b) the term "dangerous goods" shall mean those substances and articles the international carriage by road of which is prohibited by, or authorized only on certain conditions by, Annexes A and B; (c) the term "international transport" shall mean any transport operation performed on the territory of at least two Contracting Parties by vehicles defined in (a) above. Article 2 1. Subject to the provisions of article 4, paragraph 3, dangerous goods barred from carriage by Annex A shall not be accepted for international transport. 2. International transport of other dangerous goods shall be authorized subject to compliance with: (a) the conditions laid down in Annex A for the goods in question, in particular as regards their packaging and labelling, and (b) the conditions laid down in Annex B, in particular as regards the construction, equipment and operation of the vehicle carrying the goods in question, subject to the provisions of article 4, paragraph 2. Article 3 The Annexes to this Agreement shall form an integral part thereof. Article 4 1. Each Contracting Party shall retain the right to regulate or prohibit, for reasons other than safety during carriage, the entry of dangerous goods into its territory. 2. Vehicles in service on the territory of a Contracting Party at the time of entry into force of this Agreement or brought into service on such territory within two months after its entry into force shall be allowed, for a period of three years from such entry into force, to perform the international transport of dangerous goods even if their construction and equipment do not entirely conform to the requirements laid down in Annex B for the transport operation in question. Under special clauses of Annex B, however, this period may be reduced. 3. The Contracting Parties shall retain the right to arrange, by special bilateral or multilateral agreements, that certain of the dangerous goods which under this Agreement are barred from all international transport may, subject to certain conditions, be accepted for international transport on their territories, or that dangerous goods which under this Agreement are acceptable for international transport only on specified conditions may be accepted for international transport on their territories under conditions less stringent than those laid down in the Annexes to this Agreement. The special bilateral or multilateral agreements referred to in this paragraph shall be communicated to the Secretary-General of the United Nations, who shall communicate them to the Contracting Parties which are not signatories to the said agreements. - xvii - Article 5 The transport operations to which this Agreement applies shall remain subject to national or international regulations applicable in general to road traffic, international road transport and international trade. Article 6 1. Countries members of the Economic Commission for Europe and countries admitted to the Commission in a consultative capacity under paragraph 8 of the Commission's terms of reference may become Contracting Parties to this Agreement: (a) by signing it; (b) by ratifying it after signing it subject to ratification; (c) by acceding to it. 2. Such countries as may participate in certain activities of the Economic Commission for Europe in accordance with paragraph 11 of the Commission's terms of reference may become Contracting Parties to this Agreement by acceding to it after its entry into force. 3. The Agreement shall be open for signature until 15 December 1957. Thereafter, it shall be open for accession. 4. Ratification or accession shall be effected by the depositing of an instrument with the Secretary-General of the United Nations. Article 7 1. This agreement shall enter into force one month after the date on which the number of countries mentioned in article 6, paragraph 1, which have signed it without reservation of ratification or have deposited their instruments of ratification or accession has reached a total of five. However, the Annexes thereto shall not apply until six months after the entry into force of the Agreement itself. 2. For any country ratifying or acceding to this Agreement after five of the countries referred to in article 6, paragraph 1, have signed it without reservation of ratification or have deposited their instruments of ratification or accession, this Agreement shall enter into force one month after the said country has deposited its instrument of ratification or accession and the Annexes thereto shall apply for the said country either on the same date, if they are already in force by that date, or, if they are not in force by that date, on the date on which they apply under the provisions of paragraph 1 of this article. Article 8 1. Any contracting Party may denounce this Agreement by so notifying the Secretary-General of the United Nations. 2. Denunciation shall take effect twelve months after the date of receipt by the Secretary-General of the notification of denunciation. Article 9 1. This Agreement shall cease to have effect if, after its entry into force, the number of Contracting Parties is less than five during twelve consecutive months. 2. In the event of the conclusion of a worldwide agreement for the regulation of the transport of dangerous goods, any provision of this Agreement which is contrary to any provision of the said worldwide agreement shall, from the date on which the latter enters into force, automatically cease to apply to relations between the Parties to this Agreement which become parties to the worldwide agreement, and shall automatically be replaced by the relevant provision of the said worldwide agreement. Article 10 1. Any country may, at the time of signing this Agreement without reservation of ratification or of depositing its instrument of ratification or accession or at any time thereafter, declare by notification addressed to the Secretary-General of the United Nations that this Agreement shall extend to all or any of the territories for the international relations of which it is responsible. The Agreement and the annexes thereto shall extend to the territory or territories named in the notification one month after it is received by the Secretary-General. - xviii - 2. Any country which has made a declaration under paragraph 1 of this article extending this Agreement to any territory for whose international relations it is responsible may denounce the Agreement separately in respect of the said territory in accordance with the provisions of article 8. Article 11 1. Any dispute between two or more Contracting Parties concerning the interpretation or application of this Agreement shall so far as possible be settled by negotiation between them. 2. Any dispute which is not settled by negotiation shall be submitted to arbitration if any one of the Contracting Parties in dispute so requests and shall be referred accordingly to one or more arbitrators selected by agreement between the Parties in dispute. If within three months from the date of the request for arbitration the Parties in dispute are unable to agree on the selection of an arbitrator or arbitrators, any of those Parties may request the Secretary-General of the United Nations to nominate a single arbitrator to whom the dispute shall be referred for decision. 3. The decision of the arbitrator or arbitrators appointed under paragraph 2 of this article shall be binding on the Contracting Parties in dispute. Article 12 1. Each Contracting Party may, at the time of signing, ratifying, or acceding to, this Agreement, declare that it does not consider itself bound by article 11. Other Contracting Parties shall not be bound by article 11 in respect of any Contracting Party which has entered such a reservation. 2. Any Contracting Party having entered a reservation as provided for in paragraph 1 of this article may at any time withdraw such reservation by notifying the Secretary-General of the United Nations. Article 13 1. After this Agreement has been in force for three years, any Contracting Party may, by notification to the Secretary-General of the United Nations, request that a conference be convened for the purpose of reviewing the text of the Agreement. The Secretary-General shall notify all Contracting Parties of the request and a review conference shall be convened by the Secretary-General if, within a period of four months following the date of notification by the Secretary-General, not less than one-fourth of the Contracting Parties notify him of their concurrence with the request. 2. If a conference is convened in accordance with paragraph 1 of this article, the Secretary-General shall notify all the Contracting Parties and invite them to submit within a period of three months such proposals as they may wish the Conference to consider. The Secretary-General shall circulate to all Contracting Parties the provisional agenda for the conference, together with the texts of such proposals, at least three months before the date on which the conference is to meet. 3. The Secretary-General shall invite to any conference convened in accordance with this article all countries referred to in article 6, paragraph 1, and countries which have become Contracting Parties under article 6, paragraph 2. Article 141 1. Independently of the revision procedure provided for in article 13, any Contracting Party may propose one or more amendments to the Annexes to this Agreement. To that end it shall transmit the text thereof to the Secretary-General of the United Nations. The Secretary-General may also propose amendments to the Annexes to this Agreement for the purpose of ensuring concordance between those Annexes and other international agreements concerning the carriage of dangerous goods. 2. The Secretary-General shall transmit any proposal made under paragraph 1 of this article to all Contracting Parties and inform thereof the other countries referred to in article 6, paragraph 1. 3. Any proposed amendment to the Annexes shall be deemed to be accepted unless, within three months from the date on which the Secretary-General circulates it, at least one-third of the Contracting Parties, or five of them if one-third exceeds that figure, have given the Secretary-General written notification of their objection to the proposed amendment. If 1 Note by the Secretariat: The text of Article 14, paragraph 3 incorporates a modification which entered into force on 19 April 1985 in accordance with a Protocol transmitted to Contracting Parties under cover of Depositary Notification C.N.229.1975.TREATIES-8 of 18 September 1975. - xix - the amendment is deemed to be accepted, it shall enter into force for all the Contracting Parties, on the expiry of a further period of three months, except in the following cases: (a) In cases where similar amendments have been or are likely to be made to the other international agreements referred to in paragraph 1 of this article, the amendment shall enter into force on the expiry of a period the duration of which shall be determined by the Secretary-General in such a way as to allow, wherever possible, the simultaneous entry into force of the amendment and those that have been made or are likely to be made to such other agreements; such period shall not, however, be of less than one month's duration; (b) The Contracting Party submitting the proposed amendment may specify in its proposal, for the purpose of entry into force of the amendment, should it be accepted, a period of more than three months' duration. 4. The Secretary-General shall, as soon as possible, notify all Contracting Parties and all the countries referred to in article 6, paragraph 1, of any objection which may be received from the Contracting Parties to a proposed amendment. 5. If the proposed amendment to the Annexes is not deemed to be accepted, but if at least one Contracting Party other than the Contracting Party which proposed the amendment has given the Secretary-General written notification of its agreement to the proposal, a meeting of all the Contracting Parties and all the countries referred to in article 6, paragraph 1, shall be convened by the Secretary-General within three months after the expiry of the period of three months within which, under paragraph 3 of this article, notification must be given of objection to the amendment. The Secretary-General may also invite to such meeting representatives of: (a) intergovernmental organizations which are concerned with transport matters; (b) international non-governmental organizations whose activities are directly related to the transport of dangerous goods in the territories of the Contracting Parties. 6. Any amendment adopted by more than half the total number of Contracting Parties at a meeting convened in accordance with paragraph 5 of this article shall enter into force for all Contracting Parties in accordance with the procedure agreed at such meeting by the majority of the Contracting Parties attending it. Article 15 In addition to the notifications provided for in articles 13 and 14, the Secretary-General of the United Nations shall notify the countries referred to in article 6, paragraph 1, and the countries which have become Contracting Parties under article 6, paragraph 2, of (a) signatures, ratifications and accessions in accordance with article 6; (b) the dates on which this Agreement and the Annexes thereto enter into force in accordance with article 7; (c) denunciations in accordance with article 8; (d) the termination of the Agreement in accordance with article 9; (e) notifications and denunciations received in accordance with article 10; (f) declarations and notifications received in accordance with article 12, paragraphs 1 and 2; (g) the acceptance and date of entry into force of amendments in accordance with article 14, paragraphs 3 and 6. Article 16 1. The Protocol of Signature of this Agreement shall have the same force, effect and duration as the Agreement itself, of which it shall be considered to be an integral part. 2. No reservation to this Agreement, other than those entered in the Protocol of Signature and those made in accordance with article 12, shall be permitted. - xx - Article 17 After 15 December 1957, the original of this Agreement shall be deposited with the Secretary-General of the United Nations, who shall transmit certified true copies thereof to each of the countries referred to in article 6, paragraph 1. IN WITNESS WHEREOF the undersigned, being duly authorized thereto, have signed this Agreement. DONE at Geneva, this thirtieth day of September one thousand nine hundred and fifty-seven, in a single copy, in the English and French languages for the text of the Agreement proper, and in the French language for the Annexes, each text being equally authentic for the Agreement proper. The Secretary-General of the United Nations is requested to prepare an authoritative translation of the Annexes in the English language and attach it to the certified true copies referred to in article 17. - xxi - PROTOCOL OF SIGNATURE PROTOCOL OF SIGNATURE TO THE EUROPEAN AGREEMENT ON THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR) On proceeding to sign the European Agreement on the International Carriage of Dangerous Goods by Road (ADR) the undersigned, duly authorized, 1. CONSIDERING that the conditions governing the carriage of dangerous goods by sea to or from the United Kingdom differ basically from those set forth in Annex A to ADR and that it is impossible to modify them so as to conform to the latter in the near future; HAVING REGARD to the undertaking given by the United Kingdom to submit as an amendment to the said Annex A a special appendix containing special provisions for road-sea carriage of dangerous goods between the Continent and the United Kingdom; HAVE AGREED that, until the entry into force of such special appendix, dangerous goods carried under ADR to or from the United Kingdom shall comply with the provisions of Annex A to ADR and also with the United Kingdom conditions for the carriage of dangerous goods by sea; 2. TAKE NOTE OF a declaration by the representative of France to the effect that the Government of the French Republic reserves the right, notwithstanding the provisions of article 4, paragraph 2, to refuse to allow vehicles in service on the territory of another Contracting Party, whatever the date on which they were put into service, to be used for the carriage of dangerous goods on French territory unless such vehicles comply either with the conditions laid down for such carriage in Annex B or with the conditions laid down for the carriage of the goods in question in the French regulations governing the carriage of dangerous goods by road; 3. RECOMMEND that, before submission in accordance with article 14, paragraph 1, or article 13, paragraph 2, proposed amendments to this Agreement or its Annexes shall as far as possible first be discussed at meetings of experts of the Contracting Parties and, if necessary, of the other countries mentioned in article 6, paragraph 1, of the Agreement and of the international organizations mentioned in article 14, paragraph 5, of the Agreement. - xxiv - ANNEX A GENERAL PROVISIONS AND PROVISIONS CONCERNING DANGEROUS SUBSTANCES AND ARTICLES PART 1 General provision CHAPTER 1.1 SCOPE AND APPLICABILITY 1.1.1 Structure Annexes A and B of ADR are grouped into nine parts. Annex A consists of Parts 1 to 7, and Annex B of Parts 8 and 9. Each part is subdivided into chapters and each chapter into sections and sub-sections. Within each part the number of the part is included with the numbers of the chapters, sections and sub-sections, for example Part 4, Chapter 2, Section 1 is numbered "4.2.1". 1.1.2 Scope 1.1.2.1 For the purposes of Article 2 of ADR, Annex A specifies: 1.1.2.2 (a) Dangerous goods which are barred from international carriage; (b) Dangerous goods which are authorized for international carriage and the conditions attaching to them (including exemptions) particularly with regard to: - classification of goods, including classification criteria and relevant test methods; - use of packagings (including mixed packing); - use of tanks (including filling); - consignment procedures (including marking and labelling of packages and placarding and marking of means of transport as well as documentation and information required); - provisions concerning the construction, testing and approval of packagings and tanks; - use of means of transport (including loading, mixed loading and unloading). Annex A contains certain provisions which, according to Article 2 of ADR, pertain to Annex B or to both Annexes A and B, as follows: 1.1.1 1.1.2.3 1.1.2.4 1.1.3.1 1.1.3.6 1.1.4 1.1.4.5 Chapter 1.2 Chapter 1.3 Chapter 1.4 Chapter 1.5 Chapter 1.6 Chapter 1.8 Chapter 1.9 Chapter 1.10 Chapter 3.1 Chapter 3.2 1.1.2.3 Structure (Scope of Annex B) Exemptions related to the nature of the transport operation Exemptions related to quantities carried per transport unit Applicability of other regulations Carriage other than by road Definitions and units of measurements Training of persons involved in the carriage of dangerous goods Safety obligations of the participants Derogations Transitional measures Checks and other support measures to ensure compliance with safety requirements Transport restrictions by the competent authorities Security provisions General Columns (1), (2), (14), (15) and (19) (application of provisions of Parts 8 and 9 to individual substances or articles). For the purposes of Article 2 of ADR, Annex B specifies the conditions regarding the construction, equipment and operation of vehicles carrying dangerous goods authorized for carriage: -5- - requirements for vehicle crews, equipment, operation and documentation; - requirements concerning the construction and approval of vehicles. 1.1.2.4 In Article 1(c) of ADR, the word "vehicles" need not refer to one and the same vehicle. An international transport operation may be performed by several different vehicles provided that the operation takes place on the territory of at least two Contracting Parties to ADR between the consignor and the consignee indicated in the transport document. 1.1.3 Exemptions 1.1.3.1 Exemptions related to the nature of the transport operation The provisions laid down in ADR do not apply to: (a) The carriage of dangerous goods by private individuals where the goods in question are packaged for retail sale and are intended for their personal or domestic use or for their leisure or sporting activities provided that measures have been taken to prevent any leakage of contents in normal conditions of carriage. When these goods are flammable liquids carried in refillable receptacles filled by, or for, a private individual, the total quantity shall not exceed 60 litres per receptacle and 240 litres per transport unit. Dangerous goods in IBCs, large packagings or tanks are not considered to be packaged for retail sale; (b) The carriage of machinery or equipment not specified in this Annex and which happen to contain dangerous goods in their internal or operational equipment, provided that measures have been taken to prevent any leakage of contents in normal conditions of carriage; (c) The carriage undertaken by enterprises which is ancillary to their main activity, such as deliveries to or returns from building or civil engineering sites, or in relation to surveying, repairs and maintenance, in quantities of not more than 450 litres per packaging, including intermediate bulk containers (IBCs) and large packagings, and within the maximum quantities specified in 1.1.3.6. Measures shall be taken to prevent any leakage of contents in normal conditions of carriage. These exemptions do not apply to Class 7. Carriage undertaken by such enterprises for their supply or external or internal distribution does not fall within the scope of this exemption; (d) The carriage undertaken by the competent authorities for the emergency response or under their supervision, insofar as such carriage is necessary in relation to the emergency response, in particular carriage undertaken: - by breakdown vehicles carrying vehicles which have been involved in accidents or have broken down and contain dangerous goods; or - to contain and recover the dangerous goods involved in an incident or accident and move them to the nearest appropriate safe place; (e) Emergency transport intended to save human lives or protect the environment provided that all measures are taken to ensure that such transport is carried out in complete safety; (f) The carriage of uncleaned empty static storage vessels which have contained gases of Class 2, groups A, O or F, substances of Class 3 or Class 9 belonging to packing group II or III or pesticides of Class 6.1 belonging to packing group II or III, subject to the following conditions: - All openings with the exception of pressure relief devices (when fitted) are hermetically closed; - Measures have been taken to prevent any leakage of contents in normal conditions of carriage; and -6- - The load is fixed in cradles or crates or other handling devices or to the vehicle or container in such a way that they will not become loose or shift during normal conditions of carriage. This exemption does not apply to static storage vessels which have contained desensitized explosives or substances the carriage of which is prohibited by ADR. NOTE: For radioactive material, see also 1.7.1.4. 1.1.3.2 Exemptions related to the carriage of gases The provisions laid down in ADR do not apply to the carriage of: (a) Gases contained in the tanks of a vehicle, performing a transport operation and destined for its propulsion or for the operation of any of its equipment (e.g. refrigerating equipment); (b) Gases contained in the fuel tanks of vehicles transported. The fuel cock between gas tank and engine shall be closed and the electric contact open; (c) Gases of Groups A and O (according to 2.2.2.1), if the pressure of the gas in the receptacle or tank at a temperature of 20 °C does not exceed 200 kPa (2 bar) and if the gas is not a liquefied or a refrigerated liquefied gas. This includes every kind of receptacle or tank, e.g. also parts of machinery and apparatus; NOTE: This exemption does not apply to lamps. For lamps see 1.1.3.10. 1.1.3.3 (d) Gases contained in the equipment used for the operation of the vehicle (e.g. fire extinguishers), including in spare parts (e.g. inflated pneumatic tyres); this exemption also applies to inflated pneumatic tyres carried as a load; (e) Gases contained in the special equipment of vehicles and necessary for the operation of this special equipment during transport (cooling systems, fish-tanks, heaters, etc.) as well as spare receptacles for such equipment or uncleaned empty exchange receptacles, transported in the same transport unit; (f) Gases contained in foodstuffs (except UN 1950), including carbonated beverages; and (g) Gases contained in balls intended for use in sports. (h) (Deleted) Exemptions related to the carriage of liquid fuels The provisions laid down in ADR do not apply to the carriage of: (a) Fuel contained in the tanks of a vehicle performing a transport operation and destined for its propulsion or for the operation of any of its equipment used or intended for use during carriage. The fuel may be carried in fixed fuel tanks, directly connected to the vehicle’s engine and/or auxiliary equipment, which comply with the pertinent legal provisions, or may be carried in portable fuel containers (such as jerricans). The total capacity of the fixed tanks shall not exceed 1500 litres per transport unit and the capacity of a tank fitted to a trailer shall not exceed 500 litres. A maximum of 60 litres per transport unit may be carried in portable fuel containers. These restrictions shall not apply to vehicles operated by the emergency services; (b) Fuel contained in the tanks of vehicles or of other means of conveyance (such as boats) which are carried as a load, where it is destined for their propulsion or the operation of any of their equipment. Any fuel cocks between the engine or equipment and the fuel tank shall be closed during carriage unless it is essential for the equipment to remain operational. Where appropriate, the vehicles or other means of conveyance shall be loaded upright and secured against falling; -7- (c) 1.1.3.4 Fuel contained in the tanks of non-road mobile machinery1 which is carried as a load, when it is destined for its propulsion or the operation of any of its equipment. The fuel may be carried in fixed fuel tanks connected directly to the vehicle engine and/or equipment and which meet the legal requirements. Where appropriate, this machinery shall be loaded upright and secured against falling. Exemptions related to special provisions or to dangerous goods packed in limited or excepted quantities NOTE: For radioactive material, see also 1.7.1.4. 1.1.3.4.1 Certain special provisions of Chapter 3.3 exempt partially or totally the carriage of specific dangerous goods from the requirements of ADR. The exemption applies when the special provision is referred to in Column (6) of Table A of Chapter 3.2 against the dangerous goods entry concerned. 1.1.3.4.2 Certain dangerous goods may be subject to exemptions provided that the conditions of Chapter 3.4 are met. 1.1.3.4.3 Certain dangerous goods may be subject to exemptions provided that the conditions of Chapter 3.5 are met. 1.1.3.5 Exemptions related to empty uncleaned packagings Empty uncleaned packagings (including IBCs and large packagings) which have contained substances of Classes 2, 3, 4.1, 5.1, 6.1, 8 and 9 are not subject to the conditions of ADR if adequate measures have been taken to nullify any hazard. Hazards are nullified if adequate measures have been taken to nullify all hazards of Classes 1 to 9. 1.1.3.6 Exemptions related to quantities carried per transport unit 1.1.3.6.1 For the purposes of this sub-section, dangerous goods are assigned to transport categories 0, 1, 2, 3, or 4, as indicated in Column (15) of Table A of Chapter 3.2. Empty uncleaned packagings having contained substances assigned to transport category "0" are also assigned to transport category "0". Empty uncleaned packagings having contained substances assigned to a transport category other than "0" are assigned to transport category "4". 1.1.3.6.2 Where the quantity of dangerous goods carried on a transport unit does not exceed the values indicated in column (3) of the table in 1.1.3.6.3 for a given transport category (when the dangerous goods carried in the transport unit belong to the same category) or the value calculated in accordance with 1.1.3.6.4 (when the dangerous goods carried in the transport unit belong to different transport categories), they may be carried in packages in one transport unit without application of the following provisions: 1 For the definition of non-road mobile machinery see paragraph 2.7 of the Consolidated Resolution on the Construction of Vehicles (R.E.3) (United Nations document ECE/TRANS/WP.29/78/Rev.3) or Article 2 of Directive 97/68/EC of the European Parliament and of the Council of 16 December 1997 on the approximation of the laws of the Member States relating to measures against the emission of gaseous and particulate pollutants from internal combustion engines to be installed in non-road mobile machinery (Official Journal of the European Communities No. L 059 of 27 February 1998). -8- - - - Chapter 1.10 except for Class 1 explosives of UN Nos. 0029, 0030, 0059, 0065, 0073, 0104, 0237, 0255, 0267, 0288, 0289, 0290, 0360, 0361, 0364, 0365, 0366, 0439, 0440, 0441, 0455, 0456 and 0500 and except for Class 7 excepted packages of UN Nos. 2910 and 2911 if the activity level exceeds the A2 value; Chapter 5.3; Section 5.4.3; Chapter 7.2, except for V5 and V8 of 7.2.4; CV1 of 7.5.11; Part 8 except for 8.1.2.1 (a), 8.1.4.2 to 8.1.4.5, 8.2.3, 8.3.3, 8.3.4, 8.3.5, Chapter 8.4, S1(3) and (6), S2(1), S4; S5, S14 to S21 and S24 of Chapter 8.5; Part 9. -9- 1.1.3.6.3 Transport category Substances or articles packing group or classification code/group or UN No. (1) 0 (2) 1.1A/1.1L/1.2L/1.3L and UN No. 0190 UN No. 3343 Substances belonging to packing group I UN Nos. 1183, 1242, 1295, 1340, 1390, 1403, 1928, 2813, 2965, 2968, 2988, 3129, 3130, 3131, 3134, 3148, 3396, 3398 and 3399 Class 5.1: UN No. 2426 Class 6.1: UN Nos. 1051, 1600, 1613, 1614, 2312, 3250 and 3294 Class 6.2: UN Nos. 2814 and 2900 Class 7: UN Nos. 2912 to 2919, 2977, 2978 and 3321 to 3333 Class 8: UN No. 2215 (MALEIC ANHYDRIDE, MOLTEN) Class 9: UN Nos. 2315, 3151, 3152 and 3432 and apparatus containing such substances or mixtures and empty uncleaned packagings, except those classified under UN No. 2908, having contained substances classified in this transport category. Substances and articles belonging to packing group I and not classified in transport category 0 and substances and articles of the following classes: Class 1: 1.1B to 1.1J a /1.2B to 1.2J/1.3C/1.3G/1.3H/1.3J/1.5D a Class 2: groups T, TC a, TO, TF, TOC a and TFC aerosols: groups C, CO, FC, T, TF, TC, TO, TFC and TOC chemicals under pressure: UN Nos. 3502, 3503, 3504 and 3505 Class 4.1: UN Nos. 3221 to 3224 and 3231 to 3240 Class 5.2: UN Nos. 3101 to 3104 and 3111 to 3120 Substances or articles belonging to packing group II and not classified in transport categories 0, 1 or 4 and substances of the following classes: Class 1: 1.4B to 1.4G and 1.6N Class 2: group F aerosols: group F chemicals under pressure: UN No. 3501 Class 4.1: UN Nos. 3225 to 3230 Class 5.2: UN Nos. 3105 to 3110 Class 6.1: substances and articles belonging to packing group III Class 9: UN No. 3245 Substances and articles belonging to packing group III and not classified in transport categories 0, 2 or 4 and substances and articles of the following classes: Class 2: groups A and O aerosols: groups A and O chemicals under pressure: UN No. 3500 Class 3: UN No. 3473 Class 4.3: UN No. 3476 Class 8: UN Nos. 2794, 2795, 2800, 3028 and 3477 Class 9: UN Nos. 2990 and 3072 Class 1: 1.4S Class 4.1: UN Nos. 1331, 1345, 1944, 1945, 2254 and 2623 Class 4.2: UN Nos. 1361 and 1362 packing group III Class 7: UN Nos. 2908 to 2911 Class 9: UN Nos. 3268, 3499 and 3509 and empty, uncleaned packagings having contained dangerous goods, except for those classified in transport category 0 1 2 3 4 a Where the dangerous goods carried in the transport unit belong to the same category, the maximum total quantity per transport unit is indicated in column (3) of the table below. Class 1: Class 3: Class 4.2: Class 4.3: Maximum total quantity per transport unit (3) 0 20 333 1 000 unlimited For UN Nos. 0081, 0082, 0084, 0241, 0331, 0332, 0482, 1005 and 1017, the total maximum quantity per transport unit shall be 50 kg. - 10 - In the above table, "maximum total quantity per transport unit" means: 1.1.3.6.4 - For articles, gross mass in kilograms (for articles of Class 1, net mass in kilograms of the explosive substance; for dangerous goods in machinery and equipment specified in this Annex, the total quantity of dangerous goods contained therein in kilograms or litres as appropriate); - For solids, liquefied gases, refrigerated liquefied gases and dissolved gases, net mass in kilograms; - For liquids, the total quantity of dangerous goods contained in litres; - For compressed gases, adsorbed gases and chemicals under pressure, the water capacity of the receptacle in litres. Where dangerous goods of different transport categories are carried in the same transport unit, the sum of: - The quantity of substances and articles of transport category 1 multiplied by "50"; - The quantity of substances and articles of transport category 1 referred to in Note a to the table in 1.1.3.6.3 multiplied by "20"; - The quantity of substances and articles of transport category 2 multiplied by "3"; and - The quantity of substances and articles of transport category 3; shall not exceed "1 000". 1.1.3.6.5 For the purposes of this sub-section, dangerous goods exempted in accordance with 1.1.3.1 (a), (b) and (d) to (f), 1.1.3.2 to 1.1.3.5, 1.1.3.7, 1.1.3.9 and 1.1.3.10 shall not be taken into account. 1.1.3.7 Exemptions related to the carriage of electric energy storage and production systems The provisions laid down in ADR do not apply to electric energy storage and production systems (e.g., lithium batteries, electric capacitors, asymmetric capacitors, metal hydride storage systems and fuel cells): (a) installed in a vehicle, performing a transport operation and destined for its propulsion or for the operation of any of its equipment; (b) contained in equipment for the operation of this equipment used or intended for use during carriage (e.g. a laptop). 1.1.3.8 (Reserved) 1.1.3.9 Exemptions related to dangerous goods used as a coolant or conditioner during carriage When used in vehicles or containers for cooling or conditioning purposes, dangerous goods that are only asphyxiant (which dilute or replace the oxygen normally in the atmosphere) are only subject to the provisions of section 5.5.3. 1.1.3.10 Exemptions related to the carriage of lamps containing dangerous goods The following lamps are not subject to ADR provided that they do not contain radioactive material and do not contain mercury in quantities above those specified in special provision 366 of Chapter 3.3: (a) Lamps that are collected directly from individuals and households when carried to a collection or recycling facility; NOTE: This also includes lamps brought by individuals to a first collection point, and then carried to another collection point, intermediate processing or recycling facility. - 11 - (b) Lamps each containing not more than 1 g of dangerous goods and packaged so that there is not more than 30 g of dangerous goods per package, provided that: (i) the lamps are manufactured according to a certified quality management system; NOTE: ISO 9001:2008 may be used for this purpose. and (ii) each lamp is either individually packed in inner packagings, separated by dividers, or surrounded with cushioning material to protect the lamps and packed into strong outer packagings meeting the general provisions of 4.1.1.1 and capable of passing a 1.2 m drop test; (c) Used, damaged or defective lamps each containing not more than 1 g of dangerous goods with not more than 30 g of dangerous goods per package when carried from a collection or recycling facility. The lamps shall be packed in strong outer packagings sufficient for preventing release of the contents under normal conditions of carriage meeting the general provisions of 4.1.1.1 and that are capable of passing a drop test of not less than 1.2 m; (d) Lamps containing only gases of Groups A and O (according to 2.2.2.1) provided they are packaged so that the projectile effects of any rupture of the lamp will be contained within the package. NOTE: Lamps containing radioactive material are addressed in 2.2.7.2.2.2 (b). 1.1.4 Applicability of other regulations 1.1.4.1 (Reserved) 1.1.4.2 Carriage in a transport chain including maritime or air carriage 1.1.4.2.1 Packages, containers, portable tanks, tank-containers and MEGCs, which do not entirely meet the requirements for packing, mixed packing, marking, labelling of packages or placarding and orange plate marking, of ADR, but are in conformity with the requirements of the IMDG Code or the ICAO Technical Instructions shall be accepted for carriage in a transport chain including maritime or air carriage subject to the following conditions: (a) If the packages are not marked and labelled in accordance with ADR, they shall bear markings and danger labels in accordance with the requirements of the IMDG Code or the ICAO Technical Instructions; (b) The requirements of the IMDG Code or the ICAO Technical Instructions shall be applicable to mixed packing within a package; (c) For carriage in a transport chain including maritime carriage, if the containers, portable tanks, tank-containers or MEGCs are not marked and placarded in accordance with Chapter 5.3 of this Annex, they shall be marked and placarded in accordance with Chapter 5.3 of the IMDG Code. In such case, only 5.3.2.1.1 of this Annex is applicable to the marking of the vehicle itself. For empty, uncleaned portable tanks, tank-containers and MEGCs, this requirement shall apply up to and including the subsequent transfer to a cleaning station. This derogation does not apply in the case of goods classified as dangerous goods in classes 1 to 9 of ADR and considered as non-dangerous goods according to the applicable requirements of the IMDG Code or the ICAO Technical Instructions. 1.1.4.2.2 Transport units composed of a vehicle or vehicles other than those carrying containers, portable tanks, tank-containers or MEGCs as provided for in 1.1.4.2.1 (c), which are not placarded in accordance with the provisions of 5.3.1 of ADR but which are marked and placarded in accordance with Chapter 5.3 of the IMDG Code, shall be accepted for carriage in a transport chain including maritime transport provided that the orange-coloured plate marking provisions of 5.3.2 of ADR are complied with. - 12 - 1.1.4.2.3 For carriage in a transport chain including maritime or air carriage, the information required under 5.4.1 and 5.4.2 and under any special provision of Chapter 3.3 may be substituted by the transport document and information required by the IMDG Code or the ICAO Technical Instructions respectively provided that any additional information required by ADR is also included. NOTE: For carriage in accordance with 1.1.4.2.1, see also 5.4.1.1.7. For carriage in containers, see also 5.4.2. 1.1.4.3 Use of IMO type portable tanks approved for maritime transport IMO type portable tanks (types 1, 2, 5 and 7) which do not meet the requirements of Chapters 6.7 or 6.8, but which were built and approved before 1 January 2003 in accordance with the provisions of the IMDG Code (Amdt. 29-98) may continue to be used provided that they meet the applicable periodic inspection and test provisions of the IMDG Code2. In addition, they shall meet the provisions corresponding to the instructions set out in columns (10) and (11) of Table A in Chapter 3.2 and the provisions of Chapter 4.2 of ADR. See also 4.2.0.1 of the IMDG Code. 1.1.4.4 (Reserved) 1.1.4.5 Carriage other than by road 1.1.4.5.1 If the vehicle carrying out a transport operation subject to the requirements of ADR is conveyed over a section of the journey otherwise than by road haulage, then any national or international regulations which, on the said section, govern the carriage of dangerous goods by the mode of transport used for conveying the road vehicle shall alone be applicable to the said section of the journey. 1.1.4.5.2 In the cases referred to in 1.1.4.5.1 above, the involved ADR Contracting Parties may agree to apply the requirements of ADR to the section of a journey where a vehicle is conveyed otherwise than by road haulage, supplemented, if they consider it necessary, by additional requirements, unless such agreements between the involved ADR Contracting Parties would contravene clauses of the international conventions governing the carriage of dangerous goods by the mode of transport used for conveying the road vehicle on the said section of the journey, e.g. the International Convention for the Safety of Life at Sea (SOLAS), to which these ADR Contacting Parties would also be contracting parties. These agreements shall be notified by the Contracting Party which has taken the initiative thereof to the Secretariat of the United Nations Economic Commission for Europe which shall bring them to the attention of the Contracting Parties. 1.1.4.5.3 In cases where a transport operation subject to the provisions of ADR is likewise subject over the whole or a part of the road journey to the provisions of an international convention which regulates the carriage of dangerous goods by a mode of transport other than road carriage by virtue of clauses extending the applicability of that convention to certain motor-vehicle services, then the provisions of that international convention shall apply over the journey in question concurrently with those of ADR which are not incompatible with them; the other clauses of ADR shall not apply over the journey in question. 1.1.5 Application of standards Where the application of a standard is required and there is any conflict between the standard and the provisions of ADR, the provisions of ADR take precedence. The requirements of the standard that do not conflict with ADR shall be applied as specified, including the requirements of any other standard, or part of a standard, referenced within that standard as normative. 2 The International Maritime Organization (IMO) has issued “Guidance on the Continued Use of Existing IMO Type Portable Tanks and Road Tank Vehicles for the Transport of Dangerous Goods” as circular DSC.1/Circ.12 and Corrigenda. The text of this guidance can be found on the IMO website at: www.imo.org. - 13 - CHAPTER 1.2 DEFINITIONS AND UNITS OF MEASUREMENT 1.2.1 Definitions NOTE: This section contains all general or specific definitions. For the purposes of ADR: A "ADN" means the European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; "Aerosol or aerosol dispenser" means any non-refillable receptacle meeting the requirements of 6.2.6, made of metal, glass or plastics and containing a gas, compressed, liquefied or dissolved under pressure, with or without a liquid, paste or powder, and fitted with a release device allowing the contents to be ejected as solid or liquid particles in suspension in a gas, as a foam, paste or powder or in a liquid state or in a gaseous state; "Animal material" means animal carcasses, animal body parts, or animal foodstuffs; "Applicant" means, in the case of conformity assessment, the manufacturer or its authorised representative in a country Contracting Party. In the case of periodic inspections, intermediate inspections and exceptional checks, applicant means the testing facility, the operator or their authorised representative in a country Contracting Party; NOTE: Exceptionally a third party (for instance a tank-container operator in accordance with the definition of 1.2.1) may apply for the conformity assessment. "Approval" Multilateral approval, for the carriage of radioactive material, means approval by the relevant competent authority of the country of origin of the design or shipment, as applicable, and by the competent authority of each country through or into which the consignment is to be carried; Unilateral approval, for the carriage of radioactive material, means an approval of a design which is required to be given by the competent authority of the country of origin of the design only. If the country of origin is not a Contracting Party to ADR, the approval shall require validation by the competent authority of the first Contracting Party to ADR reached by the consignment (see 6.4.22.8); "ASTM" means the American Society for Testing and Materials (ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA, 19428-2959, United States of America); B "Bag" means a flexible packaging made of paper, plastics film, textiles, woven material or other suitable material; "Battery-vehicle" means a vehicle containing elements which are linked to each other by a manifold and permanently fixed to this vehicle. The following elements are considered to be elements of a battery-vehicle: cylinders, tubes, bundles of cylinders (also known as frames), pressure drums as well as tanks destined for the carriage of gases as defined in 2.2.2.1.1 with a capacity of more than 450 litres; "Body" (for all categories of IBC other than composite IBCs) means the receptacle proper, including openings and closures, but does not include service equipment; - 15 - "Box" means a packaging with complete rectangular or polygonal faces, made of metal, wood, plywood, reconstituted wood, fibreboard, plastics or other suitable material. Small holes for purposes of ease of handling or opening or to meet classification requirements, are permitted as long as they do not compromise the integrity of the packaging during carriage; "Bulk container" means a containment system (including any liner or coating) intended for the carriage of solid substances which are in direct contact with the containment system. Packagings, intermediate bulk containers (IBCs), large packagings and tanks are not included. A bulk container is: - of a permanent character and accordingly strong enough to be suitable for repeated use; - specially designed to facilitate the carriage of goods by one or more means of transport without intermediate reloading; - fitted with devices permitting its ready handling; - of a capacity of not less than 1.0 m3; Examples of bulk containers are containers, offshore bulk containers, skips, bulk bins, swap bodies, trough-shaped containers, roller containers, load compartments of vehicles; NOTE: This definition only applies to bulk containers meeting the requirements of Chapter 6.11. "Closed bulk container" means a totally closed bulk container having a rigid roof, sidewalls, end walls and floor (including hopper-type bottoms). The term includes bulk containers with an opening roof, side or end wall that can be closed during carriage. Closed bulk containers may be equipped with openings to allow for the exchange of vapours and gases with air and which prevent under normal conditions of carriage the release of solid contents as well as the penetration of rain and splash water; "Sheeted bulk container" means an open top bulk container with rigid bottom (including hopper-type bottom), side and end walls and a non-rigid covering; "Bundle of cylinders" means an assembly of cylinders that are fastened together and which are interconnected by a manifold and carried as a unit. The total water capacity shall not exceed 3 000 litres except that bundles intended for the carriage of toxic gases of Class 2 (groups starting with letter T according to 2.2.2.1.3) shall be limited to 1 000 litres water capacity; C "Calculation pressure" means a theoretical pressure at least equal to the test pressure which, according to the degree of danger exhibited by the substance being carried, may to a greater or lesser degree exceed the working pressure. It is used solely to determine the thickness of the walls of the shell, independently of any external or internal reinforcing device (see also "Discharge pressure", "Filling pressure", "Maximum working pressure (gauge pressure)" and "Test pressure"); NOTE: For portable tanks, see Chapter 6.7. "Capacity of shell or shell compartment" for tanks, means the total inner volume of the shell or shell compartment expressed in litres or cubic metres. When it is impossible to completely fill the shell or the shell compartment because of its shape or construction, this reduced capacity shall be used for the determination of the degree of filling and for the marking of the tank; "Cargo transport unit" means a vehicle, a container, a tank-container, portable tank or a MEGC; NOTE: This definition applies only for the application of special provision 302 of Chapter 3.3 and of 5.5.2. "Carriage" means the change of place of dangerous goods, including stops made necessary by transport conditions and including any period spent by the dangerous goods in vehicles, tanks and containers made necessary by traffic conditions before, during and after the change of place. - 16 - This definition also covers the intermediate temporary storage of dangerous goods in order to change the mode or means of transport (trans-shipment). This shall apply provided that transport documents showing the place of dispatch and the place of reception are presented on request and provided that packages and tanks are not opened during intermediate storage, except to be checked by the competent authorities; "Carriage in bulk" means the carriage of unpackaged solids or articles in vehicles, containers or bulk containers. The term does not apply to packaged goods nor to substances carried in tanks; "Carrier" means the enterprise which carries out the transport operation with or without a transport contract; "CGA" means the Compressed Gas Association (CGA, 4221 Walney Road, 5th Floor, Chantilly VA 20151-2923, United States of America); "CIM" means the Uniform Rules Concerning the Contract of International Carriage of Goods by Rail (Appendix B to the Convention concerning International Carriage by Rail (COTIF)), as amended; "Closed bulk container", see "Bulk container"; "Closed container", see "Container"; "Closed vehicle" means a vehicle having a body capable of being closed; "Closure" means a device which closes an opening in a receptacle; "CMR" means the Convention on the Contract for the International Carriage of Goods by Road (Geneva, 19 May 1956), as amended; "Collective entry" means an entry for a defined group of substances or articles (see 2.1.1.2, B, C and D); "Combination packaging" means a combination of packagings for carriage purposes, consisting of one or more inner packagings secured in an outer packaging in accordance with 4.1.1.5; NOTE: The term "inner packaging" used for combination packagings shall not be confused with the term "inner receptacle" used for composite packagings. "Combustion heater" means a device directly using liquid or gaseous fuel and not using the waste heat from the engine used for propulsion of the vehicle; "Competent authority" means the authority or authorities or any other body or bodies designated as such in each State and in each specific case in accordance with domestic law; "Compliance assurance" (radioactive material) means a systematic programme of measures applied by a competent authority which is aimed at ensuring that the requirements of ADR are met in practice; "Composite IBC with plastics inner receptacle" means an IBC comprising structural equipment in the form of a rigid outer casing encasing a plastics inner receptacle together with any service or other structural equipment. It is so constructed that the inner receptacle and outer casing once assembled form, and are used as, an integrated single unit to be filled, stored, transported or emptied as such; NOTE: "Plastics material", when used in connection with inner receptacles for composite IBCs, is taken to include other polymeric materials such as rubber. "Composite packaging" means a packaging consisting of an outer packaging and an inner receptacle so constructed that the inner receptacle and the outer packaging form an integral packaging. Once assembled it remains thereafter an integrated single unit; it is filled, stored, carried and emptied as such; - 17 - NOTE: The term "inner receptacle" used for composite packagings shall not be confused with the term "inner packaging" used for combination packagings. For example, the inner of a 6HA1 composite packaging (plastics material) is such an inner receptacle since it is normally not designed to perform a containment function without its outer packaging and is not therefore an inner packaging. Where a material is mentioned in brackets after the term "composite packaging", it refers to the inner receptacle. "Confinement system", for the carriage of radioactive material, means the assembly of fissile material and packaging components specified by the designer and agreed to by the competent authority as intended to preserve criticality safety; "Conformity assessment" means the process of verifying the conformity of a product according to the provisions of sections 1.8.6 and 1.8.7 related to type approval, supervision of manufacture and initial inspection and testing; "Consignee" means the consignee according to the contract for carriage. If the consignee designates a third party in accordance with the provisions applicable to the contract for carriage, this person shall be deemed to be the consignee within the meaning of ADR. If the transport operation takes place without a contract for carriage, the enterprise which takes charge of the dangerous goods on arrival shall be deemed to be the consignee; "Consignment" means any package or packages, or load of dangerous goods, presented by a consignor for carriage; "Consignor" means the enterprise which consigns dangerous goods either on its own behalf or for a third party. If the transport operation is carried out under a contract for carriage, consignor means the consignor according to the contract for carriage; "Container" means an article of transport equipment (lift van or other similar structure): - of a permanent character and accordingly strong enough to be suitable for repeated use; - specially designed to facilitate the carriage of goods, by one or more means of transport, without breakage of load; - fitted with devices permitting its ready stowage and handling, particularly when being transloaded from one means of transport to another; - so designed as to be easy to fill and empty; - having an internal volume of not less than 1 m3, except for containers for the carriage of radioactive material. In addition: "Small container" means a container which has an internal volume of not more than 3 m3; "Large container" means (a) A container which does not meet the definition of a small container; (b) In the meaning of the CSC, a container of a size such that the area enclosed by the four outer bottom corners is either (i) at least 14 m2 (150 square feet); or (ii) at least 7 m2 (75 square feet) if fitted with top corner fittings; "Closed container" means a totally enclosed container having a rigid roof, rigid side walls, rigid end walls and a floor. The term includes containers with an opening roof where the roof can be closed during transport; - 18 - "Open container" means an open top container or a platform based container; "Sheeted container" means an open container equipped with a sheet to protect the goods loaded; A "swap body" is a container which, in accordance with EN 283:1991 has the following characteristics: - from the point of view of mechanical strength, it is only built for carriage on a wagon or a vehicle on land or by roll-on roll-of ship; - it cannot be stacked; - it can be removed from vehicles by means of equipment on board the vehicle and on its own supports, and can be reloaded; NOTE: The term "container" does not cover conventional packagings, IBCs, tank-containers or vehicles. Nevertheless, a container may be used as a packaging for the carriage of radioactive material. "Containment system", for the carriage of radioactive material, means the assembly of components of the packaging specified by the designer as intended to retain the radioactive material during carriage; "Control temperature" means the maximum temperature at which the organic peroxide or the selfreactive substance can be safely carried; "Conveyance" means, for carriage by road or by rail, a vehicle or a wagon; "Criticality safety index (CSI) assigned to a package, overpack or container containing fissile material", for the carriage of radioactive material, means a number which is used to provide control over the accumulation of packages, overpacks or containers containing fissile material; "CSC" means the International Convention for Safe Containers (Geneva, 1972) as amended and published by the International Maritime Organization (IMO), London; "Crate" means an outer packaging with incomplete surfaces; "Critical temperature" means the temperature above which the substance cannot exist in the liquid state; "Cryogenic receptacle" means a transportable thermally insulated pressure receptacle for refrigerated liquefied gases of a water capacity of not more than 1 000 litres (see also "Open cryogenic receptacle"); "Cylinder" means a transportable pressure receptacle of a water capacity not exceeding 150 litres (see also "Bundle of cylinders"); D "Dangerous goods" means those substances and articles the carriage of which is prohibited by ADR, or authorized only under the conditions prescribed therein; "Dangerous reaction" means: (a) Combustion or evolution of considerable heat; (b) Evolution of flammable, asphyxiant, oxidizing or toxic gases; (c) The formation of corrosive substances; (d) The formation of unstable substances; or (e) Dangerous rise in pressure (for tanks only); - 19 - "Demountable tank" means a tank, other than a fixed tank, a portable tank, a tank-container or an element of a battery-vehicle or a MEGC which has a capacity of more than 450 litres, is not designed for the carriage of goods without breakage of load, and normally can only be handled when it is empty; "Design", for the carriage of radioactive material, means the description of fissile material excepted under 2.2.7.2.3.5 (f), special form radioactive material, low dispersible radioactive material, package or packaging which enables such an item to be fully identified. The description may include specifications, engineering drawings, reports demonstrating compliance with regulatory requirements, and other relevant documentation; "Discharge pressure" means the maximum pressure actually built up in the tank when it is being discharged under pressure (see also "Calculation pressure", "Filling pressure", "Maximum working pressure (gauge pressure)" and "Test pressure"); "Drum" means a flat-ended or convex-ended cylindrical packaging made out of metal, fibreboard, plastics, plywood or other suitable materials. This definition also includes packagings of other shapes, e.g. round, taper-necked packagings or pail-shaped packagings. Wooden barrels and jerricans are not covered by this definition; E "EC Directive" means provisions decided by the competent institutions of the European Community and which are binding, as to the result to be achieved, upon each Member State to which it is addressed, but shall leave to the national authorities the choice of form and methods; "ECE Regulation" means a regulation annexed to the Agreement concerning the adoption of uniform technical prescriptions for wheeled vehicles equipment and parts which can be fitted and or used on wheeled vehicles and the conditions for reciprocal recognition of approvals granted on the basis of these prescriptions (1958 Agreement, as amended); "Emergency temperature" means the temperature at which emergency procedures shall be implemented in the event of loss of temperature control; "EN" (standard) means a European standard published by the European Committee for Standardization (CEN) (CEN, Avenue Marnix 17, B-1000 Brussels); "Enterprise" means any natural person, any legal person, whether profit-making or not, any association or group of persons without legal personality, whether profit-making or not, or any official body, whether it has legal personality itself or is dependent upon an authority that has such personality; "Exclusive use", for the carriage of radioactive material, means the sole use, by a single consignor, of a vehicle or of a large container, in respect of which all initial, intermediate and final loading and unloading and shipment are carried out in accordance with the directions of the consignor or consignee, where so required by ADR; F "Fibreboard IBC" means a fibreboard body with or without separate top and bottom caps, if necessary an inner liner (but no inner packagings), and appropriate service and structural equipment; "Filler" means any enterprise which loads dangerous goods into a tank (tank-vehicle, demountable tank, portable tank or tank-container) and/or into a vehicle, large container or small container for carriage in bulk, or into a battery-vehicle or MEGC; "Filling pressure" means the maximum pressure actually built up in the tank when it is being filled under pressure (see also "Calculation pressure", "Discharge pressure", "Maximum working pressure (gauge pressure)" and "Test pressure"); "Filling ratio" means the ratio of the mass of gas to the mass of water at 15 °C that would fill completely a pressure receptacle fitted ready for use; - 20 - "Fixed tank" means a tank having a capacity of more than 1 000 litres which is permanently attached to a vehicle (which then becomes a tank-vehicle) or is an integral part of the frame of such vehicle; "Flammable component" (for aerosols) means flammable liquids, flammable solids or flammable gases and gas mixtures as defined in Notes 1 to 3 of sub-section 31.1.3 of Part III of the Manual of Tests and Criteria. This designation does not cover pyrophoric, self-heating or water-reactive substances. The chemical heat of combustion shall be determined by one of the following methods ASTM D 240, ISO/FDIS 13943:1999 (E/F) 86.1 to 86.3 or NFPA 30B; "Flash-point" means the lowest temperature of a liquid at which its vapours form a flammable mixture with air; "Flexible IBC" means a body constituted of film, woven fabric or any other flexible material or combinations thereof, and if necessary, an inner coating or liner, together with any appropriate service equipment and handling devices; "Fuel cell" means an electrochemical device that converts the chemical energy of a fuel to electrical energy, heat and reaction products; "Fuel cell engine" means a device used to power equipment and which consists of a fuel cell and its fuel supply, whether integrated with or separate from the fuel cell, and includes all appurtenances necessary to fulfil its function; "Full load" means any load originating from one consignor for which the use of a vehicle or of a large container is exclusively reserved and all operations for the loading and unloading of which are carried out in conformity with the instructions of the consignor or of the consignee; NOTE: The corresponding term for radioactive material is "exclusive use". G "Gas" means a substance which: (a) At 50 °C has a vapour pressure greater than 300 kPa (3 bar); or (b) Is completely gaseous at 20 °C under standard pressure of 101.3 kPa; "Gas cartridge", see "Small receptacle containing gas"; "GHS" means the fifth revised edition of the Globally Harmonized System of Classification and Labelling of Chemicals, published by the United Nations as document ST/SG/AC.10/30/Rev.5; H "Handling device" (for flexible IBCs) means any sling, loop, eye or frame attached to the body of the IBC or formed from the continuation of the IBC body material; "Hermetically closed tank" means a tank intended for the carriage of liquid substances with a calculation pressure of at least 4 bar or intended for the carriage of solid substances (powdery or granular) regardless of its calculation pressure, the openings of which are hermetically closed and which: - is not equipped with safety valves, bursting discs, other similar safety devices or vacuum valves; or - is not equipped with safety valves, bursting discs or other similar safety devices, but is equipped with vacuum valves, in accordance with the requirements of 6.8.2.2.3; or - is equipped with safety valves preceded by a bursting disc according to 6.8.2.2.10, but is not equipped with vacuum valves; or - is equipped with safety valves preceded by a bursting disc according to 6.8.2.2.10 and vacuum valves, in accordance with the requirements of 6.8.2.2.3; - 21 - I "IAEA" means the International Atomic Energy Agency (IAEA), (IAEA, P.O. Box 100 – A -1400 Vienna); "IBC", see "Intermediate bulk container"; "ICAO" means the International Civil Aviation Organization (ICAO, 999 University Street, Montreal, Quebec H3C 5H7, Canada); "ICAO Technical Instructions" means the Technical Instructions for the Safe Transport of Dangerous Goods by Air, which complement Annex 18 to the Chicago Convention on International Civil Aviation (Chicago 1944), published by the International Civil Aviation Organization (ICAO) in Montreal; "IMDG Code" means the International Maritime Dangerous Goods Code, for the implementation of Chapter VII, Part A, of the International Convention for the Safety of Life at Sea, 1974 (SOLAS Convention), published by the International Maritime Organization (IMO), London; "IMO" means the International Maritime Organization (IMO, 4 Albert Embankment, London SE1 7SR, United Kingdom); "Inner packaging" means a packaging for which an outer packaging is required for carriage; "Inner receptacle" means a receptacle which requires an outer packaging in order to perform its containment function; "Inspection body" means an independent inspection and testing body approved by the competent authority; "Intermediate bulk container" (IBC) means a rigid, or flexible portable packaging, other than those specified in Chapter 6.1, that: (a) Has a capacity of: (i) not more than 3 m3 for solids and liquids of packing groups II and III; (ii) not more than 1.5 m3 for solids of packing group I when packed in flexible, rigid plastics, composite, fibreboard and wooden IBCs; (iii) not more than 3 m3 for solids of packing group I when packed in metal IBCs; (iv) not more than 3 m3 for radioactive material of Class 7; (b) Is designed for mechanical handling; (c) Is resistant to the stresses produced in handling and transport as determined by the tests specified in Chapter 6.5; (see also "Composite IBC with plastics inner receptacle", "Fibreboard IBC", "Flexible IBC", "Metal IBC", "Rigid plastics IBC" and "Wooden IBC"). NOTE 1: Portable tanks or tank-containers that meet the requirements of Chapter 6.7 or 6.8 respectively are not considered to be intermediate bulk containers (IBCs). NOTE 2: Intermediate bulk containers (IBCs) which meet the requirements of Chapter 6.5 are not considered to be containers for the purposes of ADR. "Remanufactured IBC" means a metal, rigid plastics or composite IBC that: (a) Is produced as a UN type from a non-UN type; or (b) Is converted from one UN design type to another UN design type. - 22 - Remanufactured IBCs are subject to the same requirements of ADR that apply to new IBCs of the same type (see also design type definition in 6.5.6.1.1); "Repaired IBC" means a metal, rigid plastics or composite IBC that, as a result of impact or for any other cause (e.g. corrosion, embrittlement or other evidence of reduced strength as compared to the design type) is restored so as to conform to the design type and to be able to withstand the design type tests. For the purposes of ADR, the replacement of the rigid inner receptacle of a composite IBC with a receptacle conforming to the original design type from the same manufacturer is considered repair. However, routine maintenance of rigid IBCs is not considered repair. The bodies of rigid plastics IBCs and the inner receptacles of composite IBCs are not repairable. Flexible IBCs are not repairable unless approved by the competent authority; "Routine maintenance of flexible IBCs" means the routine performance on plastics or textile flexible IBCs of operations, such as: (a) Cleaning; or (b) Replacement of non-integral components, such as non-integral liners and closure ties, with components conforming to the original manufacturer's specification; provided that these operations do not adversely affect the containment function of the flexible IBC or alter the design type. "Routine maintenance of rigid IBCs" means the routine performance on metal, rigid plastics or composite IBCs of operations such as: (a) Cleaning; (b) Removal and reinstallation or replacement of body closures (including associated gaskets), or of service equipment, conforming to the original manufacturer’s specifications, provided that the leaktightness of the IBC is verified; or (c) Restoration of structural equipment not directly performing a dangerous goods containment or discharge pressure retention function so as to conform to the design type (e.g. the straightening of legs or lifting attachments) provided that the containment function of the IBC is not affected; "Intermediate packaging" means a packaging placed between inner packagings or articles, and an outer packaging; "ISO" (standard) means an international standard published by the International Organization for Standardization (ISO) (ISO - 1, rue de Varembé. CH-1204 Geneva 20); J "Jerrican" means a metal or plastics packaging of rectangular or polygonal cross-section with one or more orifices; L "Large container ", see "Container"; "Large packaging" means a packaging consisting of an outer packaging which contains articles or inner packagings and which (a) Is designed for mechanical handling; (b) Exceeds 400 kg net mass or 450 litres capacity but has a volume of not more than 3 m3; "Large salvage packaging" means a special packaging which (a) is designed for mechanical handling; and (b) exceeds 400 kg net mass or 450 litres capacity but has a volume of not more than 3 m³; - 23 - into which damaged, defective or leaking dangerous goods packages, or dangerous goods that have spilled or leaked are placed for purposes of carriage for recovery or disposal; "Leakproofness test" means a test to determine the leakproofness of a tank, a packaging or an IBC and of the equipment and closure devices; NOTE: For portable tanks, see Chapter 6.7. "Light-gauge metal packaging" means a packaging of circular, elliptical, rectangular or polygonal cross-section (also conical) and taper-necked and pail-shaped packaging made of metal, having a wall thickness of less than 0.5 mm (e.g. tinplate), flat or convex bottomed and with one or more orifices, which is not covered by the definitions for drums or jerricans; "Liner" means a tube or bag inserted into a packaging, including large packagings or IBCs, but not forming an integral part of it, including the closures of its openings; "Liquid" means a substance which at 50 °C has a vapour pressure of not more than 300 kPa (3 bar), which is not completely gaseous at 20 °C and 101.3 kPa, and which (a) Has a melting point or initial melting point of 20 °C or less at a pressure of 101.3 kPa; or (b) Is liquid according to the ASTM D 4359-90 test method; or (c) Is not pasty according to the criteria applicable to the test for determining fluidity (penetrometer test) described in 2.3.4; NOTE: "Carriage in the liquid state", for the purpose of tank requirements, means: - Carriage of liquids according to the above definition; or - Solids handed over for carriage in the molten state. "Liquefied Petroleum Gas (LPG)" means a low pressure liquefied gas composed of one or more light hydrocarbons which are assigned to UN Nos. 1011, 1075, 1965, 1969 or 1978 only and which consists mainly of propane, propene, butane, butane isomers, butene with traces of other hydrocarbon gases; NOTE 1: Flammable gases assigned to other UN numbers shall not be regarded as LPG. NOTE 2: For UN No. 1075 see NOTE 2 under 2F, UN No. 1965, in the table for Liquefied gases in 2.2.2.3. "Loader" means any enterprise which: (a) Loads packaged dangerous goods, small containers or portable tanks into or onto a vehicle or a container; or (b) Loads a container, bulk-container, MEGC, tank-container or portable tank onto a vehicle. M "Management system", for the carriage of radioactive material, means a set of interrelated or interacting elements (system) for establishing policies and objectives and enabling the objectives to be achieved in an efficient and effective manner; "Manual of Tests and Criteria" means the fifth revised edition of the Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, published by the United Nations (ST/SG/AC.10/11/Rev.5 as amended by documents ST/SG/AC.10/11/Rev.5/Amend.1 and ST/SG/AC.10/11/Rev.5/Amend.2); "Mass of package" means gross mass of the package unless otherwise stated. The mass of containers and tanks used for the carriage of goods is not included in the gross mass; - 24 - "Maximum capacity" means the maximum inner volume of receptacles or packagings including intermediate bulk containers (IBCs) and large packagings expressed in cubic metres or litres; "Maximum net mass" means the maximum net mass of contents in a single packaging or maximum combined mass of inner packagings and the contents thereof expressed in kilograms; "Maximum normal operating pressure", for the carriage of radioactive material, means the maximum pressure above atmospheric pressure at mean sea-level that would develop in the containment system in a period of one year under the conditions of temperature and solar radiation corresponding to environmental conditions in the absence of venting, external cooling by an ancillary system, or operational controls during carriage; "Maximum permissible gross mass" (a) (for IBCs) means the mass of the IBC and any service or structural equipment together with the maximum net mass; (b) (for tanks) means the tare of the tank and the heaviest load authorized for carriage; NOTE: For portable tanks, see Chapter 6.7. "Maximum working pressure (gauge pressure)" means the highest of the following three pressures: (a) The highest effective pressure allowed in the tank during filling (maximum filling pressure allowed); (b) The highest effective pressure allowed in the tank during discharge (maximum discharge pressure allowed); and (c) The effective gauge pressure to which the tank is subjected by its contents (including such extraneous gases as it may contain) at the maximum working temperature. Unless the special requirements prescribed in Chapter 4.3 provide otherwise, the numerical value of this working pressure (gauge pressure) shall not be lower than the vapour pressure (absolute pressure) of the filling substance at 50 °C. For tanks equipped with safety valves (with or without bursting disc) other than tanks for the carriage of compressed, liquefied or dissolved gases of Class 2, the maximum working pressure (gauge pressure) shall however be equal to the prescribed opening pressure of such safety valves. (See also "Calculation pressure", "Discharge pressure", "Filling pressure" and "Test pressure"); NOTE 1: For portable tanks, see Chapter 6.7. NOTE 2: For closed cryogenic receptacles, see NOTE to 6.2.1.3.6.5. "MEGC", see "Multiple-element gas container"; "Member of a vehicle crew" means a driver or any other person accompanying the driver for safety, security, training or operational reasons; "MEMU", see "Mobile explosives manufacturing unit"; "Metal hydride storage system" means a single complete hydrogen storage system, including a receptacle, metal hydride, pressure relief device, shut-off valve, service equipment and internal components used for the carriage of hydrogen only; "Metal IBC" means a metal body together with appropriate service and structural equipment; "Mild steel" means a steel having a minimum tensile strength between 360 N/mm2 and 440 N/mm2; NOTE: For portable tanks, see Chapter 6.7. - 25 - "Mobile explosives manufacturing unit" (MEMU) means a unit, or a vehicle mounted with a unit, for manufacturing and charging explosives from dangerous goods that are not explosives. The unit consists of various tanks and bulk containers and process equipment as well as pumps and related equipment. The MEMU may have special compartments for packaged explosives; NOTE: Even though the definition of MEMU includes the expression "manufacturing and charging explosives" the requirements for MEMUs apply only to carriage and not to manufacturing and charging of explosives. "Multiple-element gas container" (MEGC) means a unit containing elements which are linked to each other by a manifold and mounted on a frame. The following elements are considered to be elements of a multiple-element gas container: cylinders, tubes, pressure drums or bundles of cylinders as well as tanks for the carriage of gases as defined in 2.2.2.1.1 having a capacity of more than 450 litres; NOTE: For UN MEGCs, see Chapter 6.7. N "Net explosive mass (NEM)" means the total mass of the explosive substances, without the packagings, casings, etc. (Net explosive quantity (NEQ), net explosive contents (NEC), net explosive weight (NEW) or net mass of explosive contents are often used to convey the same meaning; "Neutron radiation detector" means a device that detects neutron radiation. In such a device, a gas may be contained in a hermetically sealed electron tube transducer that converts neutron radiation into a measureable electric signal; "N.O.S. entry (not otherwise specified entry)" means a collective entry to which substances, mixtures, solutions or articles may be assigned if they: (a) Are not mentioned by name in Table A of Chapter 3.2; and (b) Exhibit chemical, physical and/or dangerous properties corresponding to the Class, classification code, packing group and the name and description of the n.o.s. entry; O "Offshore bulk container" means a bulk container specially designed for repeated use for carriage to, from and between offshore facilities. An offshore bulk container is designed and constructed in accordance with the guidelines for the approval of offshore containers handled in open seas specified by the International Maritime Organization (IMO) in document MSC/Circ.860; "Open container", see "Container"; "Open cryogenic receptacle" means a transportable thermally insulated receptacle for refrigerated liquefied gases maintained at atmospheric pressure by continuous venting of the refrigerated liquefied gas; "Open vehicle" means a vehicle the platform of which has no superstructure or is merely provided with side boards and a tailboard; "Outer packaging" means the outer protection of the composite or combination packaging together with any absorbent materials, cushioning and any other components necessary to contain and protect inner receptacles or inner packagings; "Overpack" means an enclosure used (by a single consignor in the case of radioactive material) to contain one or more packages, consolidated into a single unit easier to handle and stow during carriage; Examples of overpacks: (a) A loading tray such as a pallet, on which several packages are placed or stacked and secured by a plastics strip, shrink or stretch wrapping or other appropriate means; or - 26 - (b) An outer protective packaging such as a box or a crate; P "Package" means the complete product of the packing operation, consisting of the packaging or large packaging or IBC and its contents prepared for dispatch. The term includes receptacles for gases as defined in this section as well as articles which, because of their size, mass or configuration may be carried unpackaged or carried in cradles, crates or handling devices. Except for the carriage of radioactive material, the term does not apply to goods which are carried in bulk, nor to substances carried in tanks; NOTE: For radioactive material, see 2.2.7.2, 4.1.9.1.1 and Chapter 6.4. "Packaging" means one or more receptacles and any other components or materials necessary for the receptacles to perform their containment and other safety functions (see also "Combination packaging", "Composite packaging", "Inner packaging", "Intermediate bulk container (IBC)", "Intermediate packaging", "Large packaging", "Light-gauge metal packaging", "Outer packaging", "Reconditioned packaging", "Remanufactured packaging", "Reused packaging", "Salvage packaging" and "Sift-proof packaging"); "Packer" means any enterprise which puts dangerous goods into packagings, including large packagings and intermediate bulk containers (IBCs) and, where necessary, prepares packages for carriage; "Packing group" means a group to which, for packing purposes, certain substances may be assigned in accordance with their degree of danger. The packing groups have the following meanings which are explained more fully in Part 2: Packing group I: Substances presenting high danger; Packing group II: Substances presenting medium danger; and Packing group III: Substances presenting low danger; NOTE: Certain articles containing dangerous goods are assigned to a packing group. "Portable tank" means a multimodal tank having, when used for the carriage of gases as defined in 2.2.2.1.1, a capacity of more than 450 litres in accordance with the definitions in Chapter 6.7 or the IMDG Code and indicated by a portable tank instruction (T-Code) in Column (10) of Table A of Chapter 3.2; "Portable tank operator", see "Tank-container/portable tank operator"; "Pressure drum" means a welded transportable pressure receptacle of a water capacity exceeding 150 litres and of not more than1 000 litres, (e.g. cylindrical receptacles equipped with rolling hoops, spheres on skids);" "Pressure receptacle" means a collective term that includes cylinders, tubes, pressure drums, closed cryogenic receptacles, metal hydride storage systems, bundles of cylinders and salvage pressure receptacles; "Pressurized gas cartridge", see "Aerosol or aerosol dispenser"; "Protected IBC" (for metal IBCs) means an IBC provided with additional protection against impact, the protection taking the form of, for example, a multi-layer (sandwich) or double-wall construction, or a frame with a metal lattice-work casing; Q "Quality assurance" means a systematic programme of controls and inspections applied by any organization or body which is aimed at providing confidence that the safety prescriptions in ADR are met in practice; - 27 - R "Radiation detection system" means an apparatus that contains radiation detectors as components; "Radiation level", for the carriage of radioactive material, means the corresponding dose rate expressed in millisieverts per hour or microsieverts per hour; "Radioactive contents", for the carriage of radioactive material, mean the radioactive material together with any contaminated or activated solids, liquids, and gases within the packaging; "Receptacle" (Class 1) includes boxes, bottles, cans, drums, jars and tubes, including any means of closure used in the inner or intermediate packaging; "Receptacle" means a containment vessel for receiving and holding substances or articles, including any means of closing. This definition does not apply to shells (see also "Cryogenic receptacle", "Inner receptacle", "Pressure receptacle", "Rigid inner receptacle" and "Gas cartridge"); "Reconditioned packaging" means in particular (a) (b) Metal drums that are: (i) cleaned to original materials of construction, with all former contents, internal and external corrosion, and external coatings and labels removed; (ii) restored to original shape and contour, with chimes (if any) straightened and sealed and all non-integral gaskets replaced; and (iii) inspected after cleaning but before painting, with rejection of packagings with visible pitting, significant reduction in the material thickness, metal fatigue, damaged threads or closures or other significant defects; Plastics drums and jerricans that: (i) are cleaned to original materials of construction, with all former contents, external coatings and labels removed; (ii) have all non-integral gaskets replaced; and (iii) are inspected after cleaning with rejection of packagings with visible damage such as tears, creases or cracks, or damaged threads or closures or other significant defects; "Recycled plastics material" means material recovered from used industrial packagings that has been cleaned and prepared for processing into new packagings; "Reel" (Class 1) means a device made of plastics, wood, fibreboard, metal or other suitable material comprising a central spindle with, or without, side walls at each end of the spindle. Articles and substances can be wound onto the spindle and may be retained by side walls; "Reference steel" means a steel with a tensile strength of 370 N/mm2 and an elongation at fracture of 27%; "Remanufactured IBC", see "Intermediate Bulk Container (IBC)"; "Remanufactured large packaging" means a metal or rigid plastics large packaging that: (a) Is produced as a UN type from a non-UN type; or (b) Is converted from one UN design type to another UN design type. Remanufactured large packagings are subject to the same requirements of ADR that apply to new large packagings of the same type (see also design type definition in 6.6.5.1.2); "Remanufactured packaging" means in particular - 28 - (a) (b) Metal drums that: (i) are produced as a UN type complying with the requirements of Chapter 6.1 from a nonUN type; (ii) are converted from one UN type complying with the requirements of Chapter 6.1 to another UN type; or (iii) undergo the replacement of integral structural components (such as non-removable heads); Plastics drums that: (i) are converted from one UN type to another UN type (e.g. 1H1 to 1H2); or (ii) undergo the replacement of integral structural components. Remanufactured drums are subject to the requirements of Chapter 6.1 which apply to new drums of the same type; "Repaired IBC", see "Intermediate Bulk Container (IBC)"; "Reused large packaging" means a large packaging to be refilled which has been examined and found free of defects affecting the ability to withstand the performance tests; the term includes those which are refilled with the same or similar compatible contents and are carried within distribution chains controlled by the consignor of the product; "Reused packaging" means a packaging which has been examined and found free of defects affecting the ability to withstand the performance tests. The term includes those which are refilled with the same or similar compatible contents and are carried within distribution chains controlled by the consignor of the product; "RID" means Regulations concerning the International Carriage of Dangerous Goods by Rail (Appendix C of COTIF (Convention concerning international carriage by rail)); "Rigid inner receptacle" (for composite IBCs) means a receptacle which retains its general shape when empty without its closures in place and without benefit of the outer casing. Any inner receptacle that is not "rigid" is considered to be "flexible"; "Rigid plastics IBC" means a rigid plastics body, which may have structural equipment together with appropriate service equipment; "Routine maintenance of flexible IBCs", see "Intermediate Bulk Container (IBC)"; "Routine maintenance of rigid IBCs", see "Intermediate Bulk Container (IBC)"; S "Safety valve" means a spring-loaded device which is activated automatically by pressure the purpose of which is to protect the tank against unacceptable excess internal pressure; "SADT" see "Self-accelerating decomposition temperature"; "Salvage packaging" means a special packaging into which damaged, defective, leaking or nonconforming dangerous goods packages, or dangerous goods that have spilled or leaked are placed for purposes of carriage for recovery or disposal; "Salvage pressure receptacle" means a pressure receptacle with a water capacity not exceeding 1 000 litres into which are placed damaged, defective, leaking or non-conforming pressure receptacle(s) for the purpose of carriage e.g. for recovery or disposal; "Self-accelerating decomposition temperature" (SADT), means the lowest temperature at which selfaccelerating decomposition may occur with substance in the packaging as used during carriage. Provisions for determining the SADT and the effects of heating under confinement are contained in Part II of the Manual of Tests and Criteria; - 29 - "Service equipment" (a) Of the tank means filling and discharge, breather, safety heating, heat insulating and additive devices and measuring instruments; (b) Of the elements of a battery-vehicle or of a MEGC means filling and discharge devices, including the manifold, safety devices and measuring instruments; (c) Of an IBC means the filling and discharge devices and any pressure-relief or venting, safety, heating and heat insulating devices and measuring instruments; NOTE: For portable tanks, see Chapter 6.7. "Settled pressure" means the pressure of the contents of a pressure receptacle in thermal and diffusive equilibrium; "Sheeted bulk container", see "Bulk container"; "Sheeted container", see "Container"; "Sheeted vehicle" means an open vehicle provided with a sheet to protect the load; "Shell" (for tanks), means the part of the tank which retains the substance intended for carriage, including openings and their closures, but does not include service equipment or external structural equipment; NOTE: For portable tanks, see Chapter 6.7. "Sift-proof packaging" means a packaging impermeable to dry contents, including fine solid material produced during carriage; "Small container", see "Container"; "Small receptacle containing gas (gas cartridge)" means a non-refillable receptacle having a water capacity not exceeding 1000 ml for receptacles made of metal and not exceeding 500 ml for receptacles made of synthetic material or glass, containing, under pressure, a gas or a mixture of gases. It may be fitted with a valve; "Solid" means: (a) A substance with a melting point or initial melting point of more than 20 °C at a pressure of 101.3 kPa; or (b) A substance which is not liquid according to the ASTM D 4359-90 test method or which is pasty according to the criteria applicable to the test for determining fluidity (penetrometer test) described in 2.3.4; "Structural equipment" (a) For tanks of a tank-vehicle or demountable tank, means the external or internal reinforcing, fastening, protective or stabilizing members of the shell; (b) For tanks of a tank-container, means the external or internal reinforcing, fastening, protective or stabilizing members of the shell; (c) For elements of a battery-vehicle or an MEGC means the external or internal reinforcing, fastening, protective or stabilizing members of the shell or receptacle; (d) For IBCs other than flexible IBCs means the reinforcing, fastening, handling, protective or stabilizing members of the body (including the base pallet for composite IBCs with plastics inner receptacle); NOTE: For portable tanks, see Chapter 6.7. - 30 - "Swap body", see "Container"; T "Tank" means a shell, including its service and structural equipment. When used alone, the term tank means a tank-container, portable tank, demountable tank or fixed tank as defined in this Section, including tanks forming elements of battery-vehicles or MEGCs (see also "Demountable tank", "Fixed tank", "Portable tank" and "Multiple-element gas container"); NOTE: For portable tanks, see 6.7.4.1. "Tank-container" means an article of transport equipment meeting the definition of a container, and comprising a shell and items of equipment, including the equipment to facilitate movement of the tank-container without significant change of attitude, used for the carriage of gases, liquid, powdery or granular substances and, when used for the carriage of gases as defined in 2.2.2.1.1, having a capacity of more than 0.45 m3 (450 litres); NOTE: IBCs which meet the requirements of Chapter 6.5 are not considered to be tank-containers. "Tank-container/portable tank operator" means any enterprise in whose name the tankcontainer/portable tank is registered; "Tank record" means a file containing all the important technical information concerning a tank, a battery-vehicle or a MEGC, such as certificates referred to in 6.8.2.3, 6.8.2.4 and 6.8.3.4; "Tank swap body" is considered to be a tank-container; "Tank-vehicle" means a vehicle built to carry liquids, gases or powdery or granular substances and comprising one or more fixed tanks. In addition to the vehicle proper, or the units of running gear used in its stead, a tank-vehicle comprises one or more shells, their items of equipment and the fittings for attaching them to the vehicle or to the running-gear units; "Technical name" means a recognized chemical name, if relevant a biological name, or other name currently used in scientific and technical handbooks, journals and texts (see 3.1.2.8.1.1); "Test pressure" means the required pressure applied during a pressure test for initial or periodic inspection (see also "Calculation pressure", "Discharge pressure", "Filling pressure" and "Maximum working pressure (gauge pressure)"); NOTE: For portable tanks, see Chapter 6.7. "Through or into", for the carriage of radioactive material, means through or into the countries in which a consignment is carried but specifically excludes countries "over" which a consignment is carried by air provided that there are no scheduled stops in those countries; "Transport index (TI) assigned to a package, overpack or container, or to unpackaged LSA-I or SCOI", for the carriage of radioactive material, means a number which is used to provide control over radiation exposure; "Transport unit" means a motor vehicle without an attached trailer, or a combination consisting of a motor vehicle and an attached trailer; "Tray" (Class 1) means a sheet of metal, plastics, fibreboard or other suitable material which is placed in the inner, intermediate or outer packaging and achieves a close-fit in such packaging. The surface of the tray may be shaped so that packagings or articles can be inserted, held secure and separated from each other; "Tube" (Class 2) means a seamless transportable pressure receptacle of a water capacity exceeding 150 litres and of not more than 3 000 litres; U "UIC" means the International Union of Railways (UIC, 16 rue Jean Rey, F-75015 Paris, France); - 31 - "UNECE" means the United Nations Economic Commission for Europe (UNECE, Palais des Nations, 8-14 avenue de la Paix, CH-1211 Geneva 10, Switzerland); "Undertaking", see "Enterprise"; "Unloader" means any enterprise which: (a) Removes a container, bulk-container, MEGC, tank-container or portable tank from a vehicle; or (b) Unloads packaged dangerous goods, small containers or portable tanks out of or from a vehicle or a container; or (c) Discharges dangerous goods from a tank (tank-vehicle, demountable tank, portable tank or tank-container) or from a battery-vehicle, MEMU or MEGC or from a vehicle, large container or small container for carriage in bulk or a bulk-container; "UN Model Regulations" means the Model Regulations annexed to the eighteenth revised edition of the Recommendations on the Transport of Dangerous Goods published by the United Nations (ST/SG/AC.10/1/Rev.18); "UN number" means the four-figure identification number of the substance or article taken from the UN Model Regulations; V "Vacuum-operated waste tank" means a fixed tank, demountable tank, tank-container or tank swap body primarily used for the carriage of dangerous wastes, with special constructional features and/or equipment to facilitate the loading and unloading of wastes as specified in Chapter 6.10. A tank which fully complies with the requirements of Chapter 6.7 or 6.8 is not considered to be a vacuum-operated waste tank; "Vacuum valve" means a spring-loaded device which is activated automatically by pressure the purpose of which is to protect the tank against unacceptable negative internal pressure; "Vehicle" see "Battery-vehicle", "Closed vehicle", "Open vehicle", "Sheeted vehicle" and "Tankvehicle"; W "Wastes" means substances, solutions, mixtures or articles for which no direct use is envisaged but which are transported for reprocessing, dumping, elimination by incineration or other methods of disposal; "Wooden barrel" means a packaging made of natural wood, of round cross-section, having convex walls, consisting of staves and heads and fitted with hoops; "Wooden IBC" means a rigid or collapsible wooden body, together with an inner liner (but no inner packaging) and appropriate service and structural equipment; "Working pressure" means the settled pressure of a compressed gas at a reference temperature of 15 °C in a full pressure receptacle; NOTE: For tanks, see "Maximum working pressure". "Woven plastics" (for flexible IBCs) means a material made from stretch tapes or monofilaments of suitable plastics material. - 32 - 1.2.2 Units of measurement 1.2.2.1 The following units of measurement a are applicable in ADR: SI Unit b Acceptable alternative unit Length Area Volume Time m (metre) m2 (square metre) m3 (cubic metre) s (second) Mass kg (kilogram) Mass density Temperature Temperature difference Force Pressure kg/m3 K (kelvin) K (kelvin) N (newton) Pa (pascal) l c (litre) min (minute) h (hour) d (day) g (gram) t (ton) kg/l °C (degree Celsius) °C (degree Celsius) - Stress Work Energy Quantity of heat Power Kinematic viscosity Dynamic viscosity Activity Dose equivalent N/m2 Measurement of a bar (bar) N/mm2 kWh (kilowatt hours) J (joule) eV (electronvolt) mm2/s mPa.s W (watt) m2/s Pa.s Bq (becquerel) Sv (sievert) Relationship between units 1 l = 10-3 m3 1 min = 60 s 1 h = 3 600 s 1 d = 86 400 s 1g = 10-3 kg 1 t = 103 kg 1 kg/l = 103 kg/m3 0 °C = 273.15 K 1 °C = 1 K 1 N = 1 kg.m/s2 1 Pa = 1 N/m2 1 bar = 105 Pa 1 N/mm2 = 1 MPa 1 kWh = 3.6 MJ 1 J = 1 N.m = 1 W.s 1 eV = 0.1602  10-18J 1 W = 1 J/s = 1 N.m/s 1 mm2/s = 10-6 m2/s 1 mPa.s = 10-3 Pa.s The following round figures are applicable for the conversion of the units hitherto used into SI Units. Force 1 kg 1N = = Pressure 1 Pa = 1 bar = 1 kg/cm2 = 1 torr = Stress 1 kg/mm2 1 N/mm2 9.807 N 0.102 kg = 9.807 N/mm2 = 0.102 kg/mm2 1 N/m2 105 Pa 9.807  104 Pa 1.33  102 Pa = = = = 10-5 bar 1.02 kg/cm2 0.9807 bar 1.33  10-3 bar = = = = 1.02  10-5 kg/cm2 750 torr 736 torr 1.36  10-3 kg/cm2 = 0.75  10-2 torr Energy, Work, Quantity of heat 1J = 1 N.m 1 kWh = 3.6  106 J 1 kgm = 9.807 J 1 kcal = 4.19  103 J = = = = 0.278  10-6 kWh 367  103 kgm 2.72  10-6 kWh 1.16  10-3 kWh = = = = 0.102 kgm 860 kcal 2.34  10-3 kcal 427 kgm = 0.239  10-3 kcal Power 1W 1 kgm/s 1 kcal/h 0.102 kgm/s 9.807 W 1.16 W = = = 0.86 kcal/h 8.43 kcal/h 0.119 kgm/s Dynamic viscosity 1 Pa.s = 1 N.s/m2 1P = 0.1 Pa.s 1 kg.s/m2 = 9.807 Pa.s = = = 10 P (poise) 0.1 N.s/m2 9.807 N.s/m2 = = = Kinematic viscosity 1 m2/s = 104 St (Stokes) 1 St = 10-4 m2/s = = = 0.102 kg.s/m2 1.02  10-2 kg.s/m2 98.07 P b The International System of Units (SI) is the result of decisions taken at the General Conference on Weights and Measures (Address: Pavillon de Breteuil, Parc de St-Cloud, F-92 310 Sèvres). c The abbreviation "L" for litre may also be used in place of the abbreviation "l" when a typewriter cannot distinguish between figure "1" and letter "l". - 33 - The decimal multiples and sub-multiples of a unit may be formed by prefixes or symbols, having the following meanings, placed before the name or symbol of the unit: Factor 1 000 000 000 000 000 000 1 000 000 000 000 000 1 000 000 000 000 1 000 000 000 1 000 000 1 000 100 10 0.1 0.01 0.001 0.000 001 0.000 000 001 0.000 000 000 001 0.000 000 000 000 001 0.000 000 000 000 000 001 = 1018 = 1015 = 1012 = 109 = 106 = 103 = 102 = 101 = 10-1 = 10-2 = 10-3 = 10-6 = 10-9 = 10-12 = 10-15 = 10-18 quintillion quadrillion trillion billion million thousand hundred ten tenth hundredth thousandth millionth billionth trillionth quadrillionth quintillionth Prefix Symbol exa peta tera giga mega kilo hecto deca deci centi milli micro nano pico femto atto E P T G M k h da d c m  n p f a NOTE: 109 billion is United Nations usage in English. By analogy, so is 10-9 = 1 billionth. 1.2.2.2 Unless expressly stated otherwise, the sign "%" in ADR represents: (a) In the case of mixtures of solids or of liquids, and also in the case of solutions and of solids wetted by a liquid, a percentage mass based on the total mass of the mixture, the solution or the wetted solid; (b) In the case of mixtures of compressed gases, when filled by pressure, the proportion of the volume indicated as a percentage of the total volume of the gaseous mixture, or, when filled by mass, the proportion of the mass indicated as a percentage of the total mass of the mixture; (c) In the case of mixtures of liquefied gases and dissolved gases, the proportion of the mass indicated as a percentage of the total mass of the mixture. 1.2.2.3 Pressures of all kinds relating to receptacles (such as test pressure, internal pressure, safety valve opening pressure) are always indicated in gauge pressure (pressure in excess of atmospheric pressure); however, the vapour pressure of substances is always expressed in absolute pressure. 1.2.2.4 Where ADR specifies a degree of filling for receptacles, this is always related to a reference temperature of the substances of 15 °C, unless some other temperature is indicated. - 34 - CHAPTER 1.3 TRAINING OF PERSONS INVOLVED IN THE CARRIAGE OF DANGEROUS GOODS 1.3.1 Scope and applicability Persons employed by the participants referred to in Chapter 1.4, whose duties concern the carriage of dangerous goods, shall be trained in the requirements governing the carriage of such goods appropriate to their responsibilities and duties. Employees shall be trained in accordance with 1.3.2 before assuming responsibilities and shall only perform functions, for which required training has not yet been provided, under the direct supervision of a trained person. Training requirements specific to security of dangerous goods in Chapter 1.10 shall also be addressed. NOTE 1: With regard to the training for the safety adviser, see 1.8.3 instead of this section. NOTE 2: With regard to the training of the vehicle crew, see Chapter 8.2 instead of this section. NOTE 3: For training with regard to Class 7, see also 1.7.2.5. 1.3.2 Nature of the training The training shall take the following form, appropriate to the responsibility and duties of the individual concerned. 1.3.2.1 General awareness training Personnel shall be familiar with the general requirements of the provisions for the carriage of dangerous goods. 1.3.2.2 Function-specific training Personnel shall be trained, commensurate directly with their duties and responsibilities in the requirements of the regulations concerning the carriage of dangerous goods. Where the carriage of dangerous goods involves a multimodal transport operation, the personnel shall be aware of the requirements concerning other transport modes. 1.3.2.3 Safety training Commensurate with the degree of risk of injury or exposure arising from an incident involving the carriage of dangerous goods, including loading and unloading, personnel shall be trained in the hazards and dangers presented by dangerous goods. The training provided shall aim to make personnel aware of the safe handling and emergency response procedures. 1.3.2.4 The training shall be periodically supplemented with refresher training to take account of changes in regulations. 1.3.3 Documentation Records of training received according to this Chapter shall be kept by the employer and made available to the employee or competent authority, upon request. Records shall be kept by the employer for a period of time established by the competent authority. Records of training shall be verified upon commencing a new employment. - 35 - CHAPTER 1.4 SAFETY OBLIGATIONS OF THE PARTICIPANTS 1.4.1 General safety measures 1.4.1.1 The participants in the carriage of dangerous goods shall take appropriate measures according to the nature and the extent of foreseeable dangers, so as to avoid damage or injury and, if necessary, to minimize their effects. They shall, in all events, comply with the requirements of ADR in their respective fields. 1.4.1.2 When there is an immediate risk that public safety may be jeopardized, the participants shall immediately notify the emergency services and shall make available to them the information they require to take action. 1.4.1.3 ADR may specify certain of the obligations falling to the various participants. If a Contracting Party considers that no lessening of safety is involved, it may in its domestic legislation transfer the obligations falling to a specific participant to one or several other participants, provided that the obligations of 1.4.2 and 1.4.3 are met. These derogations shall be communicated by the Contracting Party to the Secretariat of the United Nations Economic Commission for Europe which will bring them to the attention of the Contracting Parties. The requirements of 1.2.1, 1.4.2 and 1.4.3 concerning the definitions of participants and their respective obligations shall not affect the provisions of domestic law concerning the legal consequences (criminal nature, liability, etc.) stemming from the fact that the participant in question is e.g. a legal entity, a self-employed worker, an employer or an employee. 1.4.2 Obligations of the main participants NOTE 1: Several participants to which safety obligations are assigned in this section may be one and the same enterprise. Also, the activities and the corresponding safety obligations of a participant can be assumed by several enterprises. NOTE 2: For radioactive material, see also 1.7.6. 1.4.2.1 Consignor 1.4.2.1.1 The consignor of dangerous goods is required to hand over for carriage only consignments which conform to the requirements of ADR. In the context of 1.4.1, he shall in particular: (a) Ascertain that the dangerous goods are classified and authorized for carriage in accordance with ADR; (b) Furnish the carrier with information and data in a traceable form and, if necessary, the required transport documents and accompanying documents (authorizations, approvals, notifications, certificates, etc.), taking into account in particular the requirements of Chapter 5.4 and of the tables in Part 3; (c) Use only packagings, large packagings, intermediate bulk containers (IBCs) and tanks (tankvehicles, demountable tanks, battery-vehicles, MEGCs, portable tanks and tank-containers) approved for and suited to the carriage of the substances concerned and bearing the markings prescribed by ADR; (d) Comply with the requirements on the means of dispatch and on forwarding restrictions; (e) Ensure that even empty uncleaned and not degassed tanks (tank-vehicles, demountable tanks, battery-vehicles, MEGCs, portable tanks and tank-containers) or empty uncleaned vehicles and large and small bulk containers are appropriately marked and labelled and that empty uncleaned tanks are closed and present the same degree of leakproofness as if they were full. - 37 - 1.4.2.1.2 If the consignor uses the services of other participants (packer, loader, filler, etc.), he shall take appropriate measures to ensure that the consignment meets the requirements of ADR. He may, however, in the case of 1.4.2.1.1 (a), (b), (c) and (e), rely on the information and data made available to him by other participants. 1.4.2.1.3 When the consignor acts on behalf of a third party, the latter shall inform the consignor in writing that dangerous goods are involved and make available to him all the information and documents he needs to perform his obligations. 1.4.2.2 Carrier 1.4.2.2.1 In the context of 1.4.1, where appropriate, the carrier shall in particular: (a) Ascertain that the dangerous goods to be carried are authorized for carriage in accordance with ADR; (b) Ascertain that all information prescribed in ADR related to the dangerous goods to be carried has been provided by the consignor before carriage, that the prescribed documentation is on board the transport unit or if electronic data processing (EDP) or if electronic data interchange (EDI) techniques are used instead of paper documentation, that data is available during transport in a manner at least equivalent to that of paper documentation; (c) Ascertain visually that the vehicles and loads have no obvious defects, leakages or cracks, missing equipment, etc.; (d) Ascertain that the deadline for the next test for tank-vehicles, battery-vehicles, demountable tanks, portable tanks, tank-containers and MEGCs has not expired; NOTE: Tanks, battery-vehicles and MEGCs may however be carried after the expiry of this deadline under the conditions of 4.1.6.10 (in the case of battery-vehicles and MEGCs containing pressure receptacles as elements), 4.2.4.4, 4.3.2.4.4, 6.7.2.19.6, 6.7.3.15.6 or 6.7.4.14.6. (e) verify that the vehicles are not overloaded; (f) ascertain that the placards and markings prescribed for the vehicles have been affixed; (g) ascertain that the equipment prescribed in the written instructions for the driver is on board the vehicle. Where appropriate, this shall be done on the basis of the transport documents and accompanying documents, by a visual inspection of the vehicle or the containers and, where appropriate, the load. 1.4.2.2.2 1.4.2.2.3 1.4.2.2.4 The carrier may, however, in the case of 1.4.2.2.1 (a), (b), (e) and (f), rely on information and data made available to him by other participants. If the carrier observes an infringement of the requirements of ADR, in accordance with 1.4.2.2.1, he shall not forward the consignment until the matter has been rectified. If, during the journey, an infringement which could jeopardize the safety of the operation is observed, the consignment shall be halted as soon as possible bearing in mind the requirements of traffic safety, of the safe immobilisation of the consignment, and of public safety. The transport operation may only be continued once the consignment complies with applicable regulations. The competent authority(ies) concerned by the rest of the journey may grant an authorization to pursue the transport operation. In case the required compliance cannot be achieved and no authorization is granted for the rest of the journey, the competent authority(ies) shall provide the carrier with the necessary administrative assistance. The same shall apply in case the carrier informs this/these competent authority(ies) that the dangerous nature of the goods carried was not communicated to him by the consignor and that he wishes, by virtue of the law applicable in particular to the contract of carriage, to unload, destroy or render the goods harmless. 1.4.2.2.5 (Reserved) - 38 - 1.4.2.3 Consignee 1.4.2.3.1 The consignee has the obligation not to defer acceptance of the goods without compelling reasons and to verify, after unloading, that the requirements of ADR concerning him have been complied with. 1.4.2.3.2 If, in the case of a container, this verification brings to light an infringement of the requirements of ADR, the consignee shall return the container to the carrier only after the infringement has been remedied. 1.4.2.3.3 If the consignee makes use of the services of other participants (unloader, cleaner, decontamination facility, etc.) he shall take appropriate measures to ensure that the requirements of 1.4.2.3.1 and 1.4.2.3.2 of ADR have been complied with. 1.4.3 Obligations of the other participants A non-exhaustive list of the other participants and their respective obligations is given below. The obligations of the other participants flow from section 1.4.1 above insofar as they know or should have known that their duties are performed as part of a transport operation subject to ADR. 1.4.3.1 Loader 1.4.3.1.1 In the context of 1.4.1, the loader has the following obligations in particular: (a) He shall hand the dangerous goods over to the carrier only if they are authorized for carriage in accordance with ADR; (b) He shall, when handing over for carriage packed dangerous goods or uncleaned empty packagings, check whether the packaging is damaged. He shall not hand over a package the packaging of which is damaged, especially if it is not leakproof, and there are leakages or the possibility of leakages of the dangerous substance, until the damage has been repaired; this obligation also applies to empty uncleaned packagings; (c) He shall, when loading dangerous goods in a vehicle, or a large or small container, comply with the special requirements concerning loading and handling; (d) He shall, after loading dangerous goods into a container comply with the requirements concerning danger markings conforming to Chapter 5.3; (e) He shall, when loading packages, comply with the prohibitions on mixed loading taking into account dangerous goods already in the vehicle or large container and requirements concerning the separation of foodstuffs, other articles of consumption or animal feedstuffs. 1.4.3.1.2 The loader may, however, in the case of 1.4.3.1.1 (a), (d) and (e), rely on information and data made available to him by other participants. 1.4.3.2 Packer In the context of 1.4.1, the packer shall comply with in particular: 1.4.3.3 (a) The requirements concerning packing conditions, or mixed packing conditions; and (b) When he prepares packages for carriage, the requirements concerning marking and labelling of the packages. Filler In the context of 1.4.1, the filler has the following obligations in particular: (a) He shall ascertain prior to the filling of tanks that both they and their equipment are technically in a satisfactory condition; (b) He shall ascertain that the date of the next test for tank-vehicles, battery-vehicles, demountable tanks, portable tanks, tank-containers and MEGCs has not expired; - 39 - 1.4.3.4 (c) He shall only fill tanks with the dangerous goods authorized for carriage in those tanks; (d) He shall, in filling the tank, comply with the requirements concerning dangerous goods in adjoining compartments; (e) He shall, during the filling of the tank, observe the maximum permissible degree of filling or the maximum permissible mass of contents per litre of capacity for the substance being filled; (f) He shall, after filling the tank, ensure that all closures are in a closed position and that there is no leakage; (g) He shall ensure that no dangerous residue of the filling substance adheres to the outside of the tanks filled by him; (h) He shall, in preparing the dangerous goods for carriage, ensure that the orange plates, labels or placards as well as marks for elevated temperature substances and environmentally hazardous substances prescribed are affixed on the tanks, on the vehicles and on the large and small containers for carriage in bulk in accordance with the requirements; (i) (Reserved); (j) He shall, when filling vehicles or containers with dangerous goods in bulk, ascertain that the relevant provisions of Chapter 7.3 are complied with. Tank-container/portable tank operator In the context of 1.4.1, the tank-container/portable tank operator shall in particular: (a) Ensure compliance with the requirements for construction, equipment, tests and marking; (b) Ensure that the maintenance of shells and their equipment is carried out in such a way as to ensure that, under normal operating conditions, the tank-container/portable tank satisfies the requirements of ADR until the next inspection; (c) Have an exceptional check made when the safety of the shell or its equipment is liable to be impaired by a repair, an alteration or an accident. 1.4.3.5 and 1.4.3.6 1.4.3.7 (Reserved) Unloader NOTE: In this sub-section, unloading covers removal, unloading and discharging as indicated in the definition of unloader in 1.2.1. 1.4.3.7.1 In the context of 1.4.1, the unloader shall in particular: (a) Ascertain that the correct goods are unloaded by comparing the relevant information on the transport document with the information on the package, container, tank, MEMU, MEGC or vehicle; (b) Before and during unloading, check whether the packagings, the tank, the vehicle or container have been damaged to an extent which would endanger the unloading operation. If this is the case, ascertain that unloading is not carried out until appropriate measures have been taken; (c) Comply with all relevant requirements concerning unloading; (d) Immediately following the unloading of the tank, vehicle or container: (i) Remove any dangerous residues which have adhered to the outside of the tank, vehicle or container during the process of unloading; and (ii) Ensure the closure of valves and inspection openings; - 40 - 1.4.3.7.2 (e) Ensure that the prescribed cleaning and decontamination of the vehicles or containers is carried out; and (f) Ensure that the containers once completely unloaded, cleaned and decontaminated, no longer display danger markings conforming to Chapter 5.3. If the unloader makes use of the services of other participants (cleaner, decontamination facility, etc.) he shall take appropriate measures to ensure that the requirements of ADR have been complied with. - 41 - CHAPTER 1.5 DEROGATIONS 1.5.1 Temporary derogations 1.5.1.1 In accordance with Article 4, paragraph 3 of ADR, the competent authorities of the Contracting Parties may agree directly among themselves to authorize certain transport operations in their territories by temporary derogation from the requirements of ADR, provided that safety is not compromised thereby. The authority which has taken the initiative with respect to the temporary derogation shall notify such derogations to the Secretariat of the United Nations Economic Commission for Europe which shall bring them to the attention of the Contracting Parties1. NOTE: "Special arrangement" in accordance with 1.7.4 is not considered to be a temporary derogation in accordance with this section. 1.5.1.2 The period of validity of the temporary derogation shall not be more than five years from the date of its entry into force. The temporary derogation shall automatically cease as from the date of the entry into force of a relevant amendment to ADR. 1.5.1.3 Transport operations on the basis of temporary derogations shall constitute transport operations in the sense of ADR. 1.5.2 (Reserved) 1 Note by the Secretariat: The special agreements concluded under this Chapter may be consulted on the web site of the Secretariat of the United Nations Economic Commission for Europe (http://www.unece.org/trans/danger/danger.htm). - 43 - CHAPTER 1.6 TRANSITIONAL MEASURES 1.6.1 General 1.6.1.1 Unless otherwise provided, the substances and articles of ADR may be carried until 30 June 2015 in accordance with the requirements of ADR applicable up to 31 December 2014. 1.6.1.2 (Deleted) 1.6.1.3 Substances and articles of Class 1, belonging to the armed forces of a Contracting Party, that were packaged prior to 1 January 1990 in accordance with the requirements of ADR in effect at that time may be carried after 31 December 1989 provided the packagings maintain their integrity and are declared in the transport document as military goods packaged prior to 1 January 1990. The other requirements applicable as from 1 January 1990 for this class shall be complied with. 1.6.1.4 Substances and articles of Class 1 that were packaged between 1 January 1990 and 31 December 1996 in accordance with the requirements of ADR in effect at that time may be carried after 31 December 1996, provided the packagings maintain their integrity and are declared in the transport document as goods of Class 1 packaged between 1 January 1990 and 31 December 1996. 1.6.1.5 (Reserved) 1.6.1.6 Intermediate bulk containers (IBCs) manufactured before 1 January 2003 in accordance with the requirements of marginal 3612 (1) applicable up to 30 June 2001 and which do not conform to the requirements of 6.5.2.1.1 regarding the height of letters, numerals and symbols applicable as from 1 July 2001 may continue to be used. 1.6.1.7 Type approvals for drums, jerricans and composite packagings made of high or medium molecular mass polyethylene issued before 1 July 2005 in accordance with the requirements of 6.1.5.2.6 in force up to 31 December 2004, but which are not in accordance with the requirements of 4.1.1.21, continue to be valid until 31 December 2009. Any such packagings manufactured and marked on the basis of these type approvals may be used until the end of their period of use determined in 4.1.1.15. 1.6.1.8 Existing orange-coloured plates which meet the requirements of sub-section 5.3.2.2 applicable up to 31 December 2004 may continue to be used provided that the requirements of 5.3.2.2.1 and 5.3.2.2.2 that the plate, numbers and letters shall remain affixed irrespective of the orientation of the vehicle are met. 1.6.1.9 and 1.6.1.10 1.6.1.11 (Deleted) Type approvals for drums, jerricans and composite packagings made of high or medium molecular mass polyethylene, and for high molecular mass polyethylene IBCs, issued before 1 July 2007 in accordance with the requirements of 6.1.6.1 (a) in force up to 31 December 2006, but which are not in accordance with the requirements of 6.1.6.1 (a) applicable as from 1 January 2007, continue to be valid. 1.6.1.12 and 1.6.1.13 (Deleted) 1.6.1.14 IBCs manufactured before 1 January 2011 and conforming to a design type which has not passed the vibration test of 6.5.6.13 or which was not required to meet the criteria of 6.5.6.9.5 (d) at the time it was subjected to the drop test, may still be used. 1.6.1.15 IBCs manufactured, remanufactured or repaired before 1 January 2011 need not be marked with the maximum permitted stacking load in accordance with 6.5.2.2.2. Such IBCs, not marked in accordance with 6.5.2.2.2, may still be used after 31 December 2010 but must be marked in accordance with 6.5.2.2.2 if they are remanufactured or repaired after that date. IBCs manufactured, remanufactured or repaired between 1 January 2011 and 31 December 2016 and marked with the maximum permitted stacking load in accordance with 6.5.2.2.2 in force up to 31 December 2014 may continue to be used. - 45 - 1.6.1.16 to 1.6.1.19 (Deleted) 1.6.1.20 Notwithstanding the requirements of Chapter 3.4 applicable as from 1 January 2011, dangerous goods packed in limited quantities, other than those which are assigned figure "0" in column (7a) of Table A of Chapter 3.2, may continue to be carried until 30 June 2015 in accordance with the provisions of Chapter 3.4 in force up to 31 December 2010. However, in such a case, the provisions of 3.4.12 to 3.4.15 in force as from 1 January 2011 may be applied as from 1 January 2011. For the purposes of the application of the last sentence of 3.4.13 (b), if the container carried is marked with the mark required in paragraph 3.4.12 applicable until 31 December 2010, the transport unit may be marked with the mark required in paragraph 3.4.15 applicable as from 1 January 2011. 1.6.1.21 Training certificates for drivers conforming to the model applicable until 31 December 2010 issued by Contracting Parties until 31 December 2012, instead of those conforming to the requirements of 8.2.2.8.5, may continue in use to the end of their five year validity. 1.6.1.22 Inner receptacles of composite IBCs manufactured before 1 July 2011 and marked in accordance with the requirements of 6.5.2.2.4 in force up to 31 December 2010 may still be used. 1.6.1.23 Fire extinguishers constructed before 1 July 2011 in accordance with the requirements of 8.1.4.3 applicable until 31 December 2010 may continue to be used. 1.6.1.24 (Deleted) 1.6.1.25 Packages and overpacks marked with a UN number in accordance with the provisions of ADR applicable up to 31 December 2012 and which do not conform to the requirements of 5.2.1.1 regarding the size of the UN number and of the letters "UN" applicable as from 1 January 2013 may continue to be used until 31 December 2013, and, for cylinders of 60 litres water capacity or less, until the next periodic inspection but no later than 30 June 2018. 1.6.1.26 Large packagings manufactured or remanufactured before 1 January 2014 and which do not conform to the requirements of 6.6.3.1 regarding the height of letters, numerals and symbols applicable as from 1 January 2013 may continue to be used. Those manufactured or remanufactured before 1 January 2015 need not be marked with the maximum permitted stacking load in accordance with 6.6.3.3. Such large packagings not marked in accordance with 6.6.3.3 may still be used after 31 December 2014 but must be marked in accordance with 6.6.3.3 if they are remanufactured after that date. Large packagings manufactured or remanufactured between 1 January 2011 and 31 December 2016 and marked with the maximum permitted stacking load in accordance with 6.6.3.3 in force up to 31 December 2014 may continue to be used. 1.6.1.27 Means of containment integral to equipment or machinery containing liquid fuels of UN Nos. 1202, 1203, 1223, 1268, 1863 and 3475 constructed before 1 July 2013, which do not conform to the requirements of paragraph (a) of special provision 363 of Chapter 3.3 applicable as from 1 January 2013, may still be used. 1.6.1.28 As an exception to the provisions of 1.6.1.1, accreditations in accordance with EN ISO/IEC 17020:2004 for the purposes of 1.8.6.8, 6.2.2.11, 6.2.3.6.1 and special provisions TA4 and TT9 of 6.8.4 shall not be recognised after 28 February 2015. 1.6.1.29 Lithium cells and batteries manufactured according to a type meeting the requirements of sub-section 38.3 of the Manual of Tests and Criteria, Revision 3, Amendment 1 or any subsequent revision and amendment applicable at the date of the type testing may continue to be carried, unless otherwise provided in ADR. Lithium cells and batteries manufactured before 1 July 2003 meeting the requirements of the Manual of Tests and Criteria, Revision 3, may continue to be carried if all other applicable requirements are fulfilled. 1.6.1.30 Labels, placards and markings which meet the requirements of 3.4.7, 3.4.8, 3.5.4.2, 5.2.1.8.3, 5.2.2.2.1.1, 5.3.1.7.1, 5.3.3, 5.3.6, 5.5.2.3.2 and 5.5.3.6.2 applicable up to 31 December 2014 may continue to be used until 31 December 2016. 1.6.1.31 Overpacks marked with the word "OVERPACK" in accordance with the provisions of ADR applicable up to 31 December 2014 and which do not conform to the requirements of 5.1.2.1 (a) - 46 - regarding the size of the letters applicable as from 1 January 2015 may continue to be used until 31 December 2015. 1.6.1.32 Salvage packagings and salvage pressure receptacles marked with the word "SALVAGE" in accordance with the provisions of ADR applicable up to 31 December 2014 and which do not conform to the requirements of 5.2.1.3 regarding the size of the letters applicable as from 1 January 2015 may continue to be used until 31 December 2015. 1.6.1.33 Electric double layer capacitors of UN No. 3499, manufactured before 1 January 2014, need not be marked with the energy storage capacity in Wh as required by sub-paragraph (e) of special provision 361 of Chapter 3.3. 1.6.1.34 Asymmetric capacitors of UN No. 3508, manufactured before 1 January 2016, need not be marked with the energy storage capacity in Wh as required by sub-paragraph (c) of special provision 372 of Chapter 3.3. 1.6.1.35: The instructions in writing in accordance with the requirements of ADR applicable up to 31 December 2014, but which do not however conform to the requirements of 5.4.3 applicable as from 1 January 2015, may continue to be used until 30 June 2017. 1.6.1.36 Driver training certificates issued before 1 January 2014 that do not comply with the requirements under 8.2.2.8.5 applicable from 1 January 2013 in respect of the sequence used for the presentation of dates under numbers 4. and 8., the colour (white with black lettering), and the use of the numbers 9. and 10. on the back of the certificate to introduce the corresponding lists of classes for which the certificate is valid, may continue to be used until their date of expiry. 1.6.2 Pressure receptacles and receptacles for Class 2 1.6.2.1 Receptacles built before 1 January 1997 and which do not conform to the requirements of ADR applicable as from 1 January 1997, but the carriage of which was permitted under the requirements of ADR applicable up to 31 December 1996, may continue to be transported after that date if the periodic test requirements in packing instructions P200 and P203 are complied with. 1.6.2.2 (Deleted) 1.6.2.3 Receptacles intended for the carriage of Class 2 substances constructed before 1 January 2003, may continue to bear, after 1 January 2003, the markings conforming to the requirements applicable until 31 December 2002. 1.6.2.4 Pressure receptacles designed and constructed in accordance with technical codes no longer recognized according to 6.2.5 may still be used. 1.6.2.5 Pressure receptacles and their closures designed and constructed in accordance with standards applicable at the time of their construction (see 6.2.4) according to the provisions of ADR which were applicable at that time may still be used unless restricted by a specific transitional measure. 1.6.2.6 Pressure receptacles for substances other than those of Class 2, built before 1 July 2009 in accordance with the requirements of 4.1.4.4 in force up to 31 December 2008, but which do not conform to the requirements of 4.1.3.6 applicable as from 1 January 2009, may continue to be used provided that the requirements of 4.1.4.4 in force up to 31 December 2008 are complied with. 1.6.2.7 and 1.6.2.8 (Deleted) 1.6.2.9 The provisions of packing instruction P200 (10), special packing provision v of 4.1.4.1 applicable until 31 December 2010 may be applied by Contracting Parties to ADR to cylinders constructed before 1 January 2015. 1.6.2.10 Refillable welded steel cylinders for the carriage of gases of UN Nos. 1011, 1075, 1965, 1969 or 1978, granted 15 year intervals for periodic inspection in accordance with packing instruction P200 (10), special packing provision v of 4.1.4.1 as applicable until 31 December 2010 by the competent authority of the country (countries) of carriage, may continue to be periodically inspected according to those provisions. - 47 - 1.6.2.11 Gas cartridges constructed and prepared for carriage before 1 January 2013 for which the requirements of 1.8.6, 1.8.7 or 1.8.8 for the conformity assessment of gas cartridges have not been applied may still be carried after this date, provided all the other applicable provisions of ADR are met. 1.6.2.12 Salvage pressure receptacles may continue to be constructed and approved according to national regulations up to 31 December 2013. Salvage pressure receptacles constructed and approved in accordance with national regulations before 1 January 2014 may continue to be used with the approval of the competent authorities of the countries of use. 1.6.2.13 Bundles of cylinders manufactured before 1 July 2013 which are not marked in accordance with 6.2.3.9.7.2 and 6.2.3.9.7.3 applicable from 1 January 2013 or 6.2.3.9.7.2 applicable from 1 January 2015 may be used until the next periodic inspection after 1 July 2015. 1.6.2.14 Cylinders constructed before 1 January 2016 in accordance with 6.2.3 and a specification approved by the competent authorities of the countries of transport and use, but not in accordance with ISO 11513:2011 or ISO 9809-1:2010 as required in 4.1.4.1, packing instruction P208 (1), may be used for the carriage of adsorbed gases provided the general packing requirements of 4.1.6.1 are met. 1.6.2.15 Bundles of cylinders periodically inspected before 1 July 2015 which are not marked in accordance with 6.2.3.9.7.3 applicable from 1 January 2015 may be used until the next periodic inspection after 1 July 2015. 1.6.3 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles 1.6.3.1 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles built before the entry into force of the requirements applicable as from 1 October 1978 may be kept in service if the equipment of the shell meets the requirements of Chapter 6.8. The thickness of the shell wall, except in the case of shells intended for the carriage of refrigerated liquefied gases of Class 2, shall be appropriate to a calculation pressure of not less than 0.4 MPa (4 bar) (gauge pressure) in the case of mild steel or of not less than 200 kPa (2 bar) (gauge pressure) in the case of aluminium and aluminium alloys. For other than circular cross-sections of tanks, the diameter to be used as a basis for calculation shall be that of a circle whose area is equal to that of the actual cross-section of the tank. 1.6.3.2 The periodic tests for fixed tanks (tank-vehicles), demountable tanks and battery-vehicles kept in service under these transitional requirements shall be conducted in accordance with the requirements of 6.8.2.4 and 6.8.3.4 and with the pertinent special requirements for the various classes. Unless the earlier requirements prescribed a higher test pressure, a test pressure of 200 kPa (2 bar) (gauge pressure) shall suffice for aluminium shells and aluminium alloy shells. 1.6.3.3 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles which meet the transitional requirements in 1.6.3.1 and 1.6.3.2 may be used until 30 September 1993 for the carriage of the dangerous goods for which they have been approved. This transitional period shall not apply to fixed tanks (tank-vehicles), demountable tanks and battery-vehicles intended for the carriage of substances of Class 2, or to fixed tanks (tank-vehicles), demountable tanks and battery-vehicles whose wall thickness and items of equipment meet the requirements of Chapter 6.8. 1.6.3.4 (a) Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed before 1 May 1985 in accordance with the requirements of ADR in force between 1 October 1978 and 30 April 1985 but not conforming to the requirements applicable as from 1 May 1985 may continue to be used after that date; (b) Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles, constructed between 1 May 1985 and the entry into force of the requirements applicable as from 1 January 1988 which do not conform to those requirements but were constructed according to the requirements of ADR in force until that date, may continue to be used after that date. 1.6.3.5 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles, constructed before 1 January 1993 in accordance with the requirements in force up to 31 December 1992 but which do not conform to the requirements applicable as from 1 January 1993 may still be used. - 48 - 1.6.3.6 (a) Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed between 1 January 1978 and 31 December 1984, if used after 31 December 2004, shall conform to the requirements of marginal 211 127 (5), applicable as from 1 January 1990, concerning shell thickness and protection against damage; (b) Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed between 1 January 1985 and 31 December 1989, if used after 31 December 2010, shall conform to the requirements of marginal 211 127 (5), applicable as from 1 January 1990, concerning shell thickness and protection against damage. 1.6.3.7 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed before 1 January 1999 in accordance with the requirements in force up to 31 December 1998 but which do not, however, conform to the requirements applicable as from 1 January 1999 may still be used. 1.6.3.8 When, because of amendments to ADR, some proper shipping names of gases have been modified, it is not necessary to modify the names on the plate or on the shell itself (see 6.8.3.5.2 or 6.8.3.5.3), provided that the names of the gases on the fixed tanks (tank-vehicles), demountable tanks and battery-vehicles or on the plates (see 6.8.3.5.6 (b) or (c)) are adapted at the first periodic test thereafter. 1.6.3.9 and 1.6.3.10 (Reserved) 1.6.3.11 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 January 1997 in accordance with the requirements in force up to 31 December 1996 but which do not, however, conform to the requirements of marginals 211 332 and 211 333 applicable as from 1 January 1997, may still be used. 1.6.3.12 (Reserved) 1.6.3.13 (Deleted) 1.6.3.14 (Reserved) 1.6.3.15 (Deleted) 1.6.3.16 For fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed before 1 January 2007 which do not conform to the requirements of 4.3.2, 6.8.2.3, 6.8.2.4 and 6.8.3.4 concerning the tank record, the retention of files for the tank record shall start at the latest at the next periodic inspection. 1.6.3.17 Fixed tanks (tank-vehicles) and demountable tanks intended for the carriage of substances of Class 3, packing group I having a vapour pressure of not more than 175 kPa (1.75 bar) (absolute) at 50 °C, constructed before 1 July 2007 in accordance with the requirements applicable up to 31 December 2006, to which tank code L1.5BN had been assigned in accordance with the requirements applicable up to 31 December 2006, may continue to be used for the carriage of the substances mentioned above, until 31 December 2018. 1.6.3.18 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles constructed before 1 January 2003 in accordance with the requirements in force up to 30 June 2001, but which do not, however, conform to the requirements applicable as from 1 July 2001, may still be used provided that the assignment to the relevant tank code has been carried out. 1.6.3.19 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 January 2003 in accordance with the requirements of 6.8.2.1.21 in force up to 31 December 2002 but which do not, however, conform to the requirements applicable as from 1 January 2003 may still be used. 1.6.3.20 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2003 in accordance with the requirements in force up to 31 December 2002 but which do not, however, conform to the requirements of 6.8.2.1.7 applicable as from 1 January 2003 and special provision TE15 of 6.8.4 (b) applicable from 1 January 2003 to 31 December 2006 may still be used. 1.6.3.21 (Deleted) 1.6.3.22 to 1.6.3.24 (Reserved) - 49 - 1.6.3.25 (Deleted) 1.6.3.26 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 January 2007 in accordance with the requirements in force up to 31 December 2006 but which do not, however, conform to the requirements applicable as from 1 January 2007 regarding the marking of the external design pressure in accordance with 6.8.2.5.1, may still be used. 1.6.3.27 to 1.6.3.29 (Reserved) 1.6.3.30 Vacuum-operated waste fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2005 in accordance with the requirements applicable up to 31 December 2004 but which do not conform to the requirements of 6.10.3.9 applicable as from 1 January 2005, may still be used. 1.6.3.31 Fixed tanks (tank-vehicles), demountable tanks and tanks forming elements of battery-vehicles designed and constructed in accordance with a technical code which was recognized at the time of their construction according to the provisions of 6.8.2.7 which were applicable at that time may still be used. 1.6.3.32 Fixed tanks (tank vehicles) and demountable tanks constructed before 1 July 2007 in accordance with the requirements in force up to 31 December 2006, equipped with manhole cover assemblies in accordance with the provisions of standard EN 13317:2002 referred to in the table of paragraph 6.8.2.6, applicable until 31 December 2006, including those of the figure and table B.2 of annex B of the said standard which are no longer accepted as from 1 January 2007, or the material of which does not meet the requirements of EN 13094:2004, paragraph 5.2, may still be used. 1.6.3.33 When the shell of a fixed tank (tank-vehicle) or demountable tank was already divided by partitions or surge plates into sections of not more than 7 500 litres capacity before 1 January 2009, the capacity of the shell need not be supplemented with the symbol "S" in the particulars required by 6.8.2.5.1 until the next periodic inspection according to 6.8.2.4.2 is performed. 1.6.3.34 Notwithstanding the provisions of 4.3.2.2.4, fixed tanks (tank-vehicles) and demountable tanks intended for the carriage of liquefied gases or refrigerated liquefied gases, which meet the applicable construction requirements of ADR but which were divided, before 1 July 2009, by partitions or surge plates into sections of more than 7 500 litres capacity may still be filled to more than 20% and less than 80% of their capacity. 1.6.3.35 (Deleted) 1.6.3.36 Fixed tanks (tank-vehicles) intended for the carriage of liquefied non-toxic flammable gases constructed before 1 July 2011 and which are equipped with non-return valves instead of internal stop-valves and which do not conform to the requirements of 6.8.3.2.3, may still be used. 1.6.3.37 (Deleted) 1.6.3.38 Fixed tanks (tank-vehicles), demountable tanks and battery-vehicles designed and constructed in accordance with standards applicable at the time of their construction (see 6.8.2.6 and 6.8.3.6) according to the provisions of ADR which were applicable at that time may still be used unless restricted by a specific transitional measure. 1.6.3.39 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2011 in accordance with the requirements of 6.8.2.2.3 in force up to 31 December 2010 but which do not, however, conform to the requirements of 6.8.2.2.3, third paragraph, concerning the position of the flame trap or flame arrester may still be used. 1.6.3.40 For toxic by inhalation substances of UN Nos. 1092, 1238, 1239, 1244, 1251, 1510, 1580, 1810, 1834, 1838, 2474, 2486, 2668, 3381, 3383, 3385, 3387 and 3389, the tank code specified in column (12) of Table A of Chapter 3.2 applicable up to 31 December 2010 may continue to be applied until 31 December 2016 for fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2011. - 50 - 1.6.3.41 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2013 in accordance with the requirements in force up to 31 December 2012, but which do not, however, meet the marking provisions of 6.8.2.5.2 or 6.8.3.5.6 applicable as from 1 January 2013, may continue to be marked in accordance with the requirements applicable up to 31 December 2012 until the next periodic inspection after 1 July 2013. 1.6.3.42 For UN No. 2381, the tank code specified in column (12) of Table A of Chapter 3.2 applicable up to 31 December 2012 may continue to be applied until 31 December 2018 for fixed tanks (tank-vehicles) and demountable tanks constructed before 1 July 2013. 1.6.3.43 Fixed tanks (tank-vehicles) and demountable tanks constructed before 1 January 2012 in accordance with the requirements in force up to 31 December 2012, but which do not however conform to the requirements of 6.8.2.6 relating to standards EN 14432:2006 and EN 14433:2006 applicable as from 1 January 2011, may still be used. 1.6.3.44 Fixed tanks (tank-vehicles) and demountable tanks intended for the carriage of UN Nos. 1202, 1203, 1223, 3475 and aviation fuel classified under UN Nos. 1268 or 1863, equipped with additive devices designed and constructed before 1 July 2015 in accordance with national provisions, but which do not, however, conform to the construction, approval and testing requirements of special provision 664 of Chapter 3.3 applicable as from 1 January 2015, may continue to be used until their first intermediate or periodic inspection after 31 December 2015. After this date, they shall only be used with the agreement of the competent authorities in the countries of use. 1.6.3.45 to 1.6.3.49 1.6.3.50 (Reserved) Fibre-reinforced plastics (FRP) tanks FRP tanks which have been constructed before 1 July 2002 in conformity with a design type approved before 1 July 2001 in accordance with the requirements of Appendix B.1c which were in force until 30 June 2001 may continue to be used until the end of their lifetime provided that all the requirements in force up to 30 June 2001 have been and continue to be complied with. However, as from 1 July 2001, no new design type may be approved in accordance with the requirements in force until 30 June 2001. 1.6.4 Tank-containers, portable tanks and MEGCs 1.6.4.1 Tank-containers constructed before 1 January 1988 in accordance with the requirements in force up to 31 December 1987 but which do not, however, conform to the requirements applicable as from 1 January 1988, may still be used. 1.6.4.2 Tank-containers constructed before 1 January 1993 in accordance with the requirements in force up to 31 December 1992 but which do not, however, conform to the requirements applicable as from 1 January 1993, may still be used. 1.6.4.3 Tank-containers constructed before 1 January 1999 in accordance with the requirements in force up to 31 December 1998 but which do not, however, conform to the requirements applicable as from 1 January 1999, may still be used. 1.6.4.4 (Reserved) 1.6.4.5 When, because of amendments to ADR, some proper shipping names of gases have been modified, it is not necessary to modify the names on the plate or on the shell itself (see 6.8.3.5.2 or 6.8.3.5.3), provided that the names of the gases on the tank-containers and MEGCs or on the plates [see 6.8.3.5.6 (b) or (c)] are adapted at the first periodic test thereafter. Tank-containers constructed before 1 January 2007 in accordance with the requirements in force up to 31 December 2006 but which do not, however, conform to the requirements applicable as from 1 January 2007 regarding the marking of the external design pressure in accordance with 6.8.2.5.1, may still be used. 1.6.4.6 - 51 - 1.6.4.7 Tank-containers constructed before 1 January 1997 in accordance with the requirements in force up to 31 December 1996 but which do not, however, conform to the requirements of marginals 212 332 and 212 333 applicable as from 1 January 1997, may still be used. 1.6.4.8 (Reserved) 1.6.4.9 Tank-containers and MEGCs designed and constructed in accordance with a technical code which was recognized at the time of their construction according to the provisions of 6.8.2.7 which were applicable at that time may still be used. 1.6.4.10 (Deleted) 1.6.4.11 (Reserved) 1.6.4.12 Tank-containers and MEGCs constructed before 1 January 2003 in accordance with the requirements applicable up to 30 June 2001, but which do not, however, conform to the requirements applicable as from 1 July 2001, may still be used. However, they shall be marked with the relevant tank code and if applicable the relevant alphanumeric codes of special provisions TC and TE in accordance with 6.8.4. 1.6.4.13 Tank-containers constructed before 1 July 2003 in accordance with the requirements in force up to 31 December 2002 but which do not, however, conform to the requirements of 6.8.2.1.7 applicable as from 1 January 2003 and special provision TE15 of 6.8.4 (b) applicable from 1 January 2003 to 31 December 2006 may still be used. 1.6.4.14 (Reserved) 1.6.4.15 The type of the test ("P" or "L") required by 6.8.2.5.1 need not be added to the tank plate until the first test after 1 January 2007 is performed. 1.6.4.16 (Deleted) 1.6.4.17 (Deleted) 1.6.4.18 For tank-containers and MEGCs constructed before 1 January 2007 which do not conform to the requirements of 4.3.2, 6.8.2.3, 6.8.2.4 and 6.8.3.4 concerning the tank record, the retention of files for the tank record shall start at the latest at the next periodic inspection. 1.6.4.19 Tank-containers intended for the carriage of substances of Class 3, packing group I having a vapour pressure of not more than 175 kPa (1.75 bar) (absolute) at 50 °C, constructed before 1 July 2007 in accordance with the requirements applicable up to 31 December 2006, to which tank code L1.5BN had been assigned in accordance with the requirements applicable up to 31 December 2006, may continue to be used for the carriage of the substances mentioned above until 31 December 2016. Vacuum-operated waste tank-containers constructed before 1 July 2005 in accordance with the requirements applicable up to 31 December 2004 but which do not conform to the requirements of 6.10.3.9 applicable as from 1 January 2005, may still be used. 1.6.4.20 1.6.4.21 to 1.6.4.29 (Reserved) 1.6.4.30 Portable tanks and UN MEGCs which do not meet the design requirements applicable as from 1 January 2007 but which have been constructed according to a design approval certificate which has been issued before 1 January 2008 may continue to be used. 1.6.4.31 (Deleted) - 52 - 1.6.4.32 When the shell of a tank-container was already divided by partitions or surge plates into sections of not more than 7 500 litres capacity before 1 January 2009, the capacity of the shell need not be supplemented with the symbol "S" in the particulars required by 6.8.2.5.1 until the next periodic inspection according to 6.8.2.4.2 is performed. 1.6.4.33 Notwithstanding the provisions of 4.3.2.2.4, tank-containers intended for the carriage of liquefied gases or refrigerated liquefied gases, which meet the applicable construction requirements of ADR but which were divided, before 1 July 2009, by partitions or surge plates into sections of more than 7 500 litres capacity may still be filled to more than 20% and less than 80% of their capacity. 1.6.4.34 and 1.6.4.35 (Deleted) 1.6.4.36 For substances where TP37 is assigned in column (11) of Table A of Chapter 3.2, the portable tank instruction prescribed in ADR applicable up to 31 December 2010 may continue to be applied until 31 December 2016. 1.6.4.37 Portable tanks and MEGCs manufactured before 1 January 2012, that conform to the marking requirements of 6.7.2.20.1, 6.7.3.16.1, 6.7.4.15.1 or 6.7.5.13.1 applicable up to 31 December 2010, as relevant, may continue to be used if they comply with all other relevant requirements of ADR applicable as from 1 January 2011 including, when applicable, the requirement of 6.7.2.20.1 (g) for marking the symbol "S" on the plate when the shell or the compartment is divided by surge plates into sections of not more than 7 500 litres capacity. When the shell, or the compartment, was already divided by surge plates into sections of not more than 7 500 litres capacity before 1 January 2012, the capacity of the shell, or respectively of the compartment, need not be supplemented with the symbol "S" until the next periodic inspection or test according to 6.7.2.19.5 is performed. 1.6.4.38 Portable tanks manufactured before 1 January 2014 need not be marked with the portable tank instruction as required in 6.7.2.20.2, 6.7.3.16.2 and 6.7.4.15.2 until the next periodic inspection and test. 1.6.4.39 Tank-containers and MEGCs designed and constructed in accordance with standards applicable at the time of their construction (see 6.8.2.6 and 6.8.3.6) according to the provisions of ADR which were applicable at that time may still be used unless restricted by a specific transitional measure. 1.6.4.40 Tank-containers constructed before 1 July 2011 in accordance with the requirements of 6.8.2.2.3 in force up to 31 December 2010 but which do not, however, conform to the requirements of 6.8.2.2.3, third paragraph, concerning the position of the flame trap or flame arrester may still be used. 1.6.4.41 For toxic by inhalation substances of UN Nos. 1092, 1238, 1239, 1244, 1251, 1510, 1580, 1810, 1834, 1838, 2474, 2486, 2668, 3381, 3383, 3385, 3387 and 3389, the tank code specified in column (12) of Table A of Chapter 3.2 applicable up to 31 December 2010 may continue to be applied until 31 December 2016 for tank-containers constructed before 1 July 2011. 1.6.4.42 Tank-containers constructed before 1 July 2013 in accordance with the requirements in force up to 31 December 2012, but which do not, however, meet the marking provisions of 6.8.2.5.2 or 6.8.3.5.6 applicable as from 1 January 2013, may continue to be marked in accordance with the requirements applicable up to 31 December 2012 until the next periodic inspection after 1 July 2013. 1.6.4.43 Portable tanks and MECGs manufactured before 1 January 2014 need not comply with the requirements of 6.7.2.13.1 (f), 6.7.3.9.1 (e), 6.7.4.8.1 (e) and 6.7.5.6.1 (d) concerning the marking of the pressure relief devices. 1.6.4.44 For substances where TP38 or TP39 is assigned in column (11) of Table A of Chapter 3.2, the portable tank instruction prescribed in ADR applicable up to 31 December 2012 may continue to be applied until 31 December 2018. 1.6.4.45 For UN No. 2381, the tank code specified in column (12) of Table A of Chapter 3.2 applicable up to 31 December 2012 may continue to be applied until 31 December 2018 for tank-containers constructed before 1 July 2013. 1.6.4.46 Tank-containers constructed before 1 January 2012 in accordance with the requirements in force up to 31 December 2012, but which do not however conform to the requirements of 6.8.2.6 relating to standards EN 14432:2006 and EN 14433:2006 applicable as from 1 January 2011, may still be used. - 53 - 1.6.5 Vehicles 1.6.5.1 and 1.6.5.2 (Reserved) 1.6.5.3 (Deleted) 1.6.5.4 As regards the construction of EX/II, EX/III, FL, OX and AT vehicles, the requirements of Part 9 in force up to 31 December 2014 may be applied until 31 March 2016. 1.6.5.5 Vehicles registered or entering into service before 1 January 2003 the electric equipment of which does not comply with the requirements of 9.2.2, 9.3.7 or 9.7.8 but complies with the requirements applicable until 30 June 2001 may still be used. 1.6.5.6 (Deleted) 1.6.5.7 Complete or completed vehicles which have been type-approved before 31 December 2002 according to ECE Regulation No. 1051 as amended by the 01 series of amendments or the corresponding provisions of Directive 98/91/EC2 and which do not comply with the requirements of Chapter 9.2 but comply with the requirements applicable to the construction of base vehicles (marginals 220 100 to 220 540 of Appendix B.2) applicable until 30 June 2001 may continue to be approved and used provided they are first registered or they entered into service before 1 July 2003. 1.6.5.8 EX/II and EX/III vehicles which have been first approved before 1 July 2005 and which comply with the requirements of Part 9 in force up to 31 December 2004 but which do not however conform to the requirements applicable as from 1 January 2005 may still be used. 1.6.5.9 Tank-vehicles with fixed tanks with a capacity of more than 3 m3 intended for the carriage of dangerous goods in the liquid or molten state tested with a pressure of less than 4 bar, which do not comply with the requirements of 9.7.5.2, first registered (or which entered into service if the registration is not mandatory) before 1 July 2004, may still be used. 1.6.5.10 Certificates of approval which conform to the model shown in 9.1.3.5 applicable up to 31 December 2006 and those which conform to the model shown in 9.1.3.5 applicable from 1 January 2007 to 31 December 2008 may continue to be used. Certificates of approval which conform to the model shown in 9.1.3.5 applicable from 1 January 2009 up to 31 December 2014 may continue to be used. 1.6.5.11 MEMUs which have been constructed and approved before 1 July 2009 in accordance with the provisions of national law but which do not, however, conform to the construction and approval requirements applicable as from 1 January 2009 may be used with the approval of the competent authorities in the countries of use. 1.6.5.12 EX/III and FL vehicles registered or entering into service before 1 April 2012, the electrical connections of which do not comply with the requirements of 9.2.2.6.3, but comply with the requirements applicable until 31 December 2010, may still be used. 1.6.5.13 Trailers first registered (or which entered into service if registration was not mandatory) before 1 July 1995 equipped with anti-lock braking system in conformity with ECE Regulation No. 13, 06 series of amendments but which do not comply with the technical requirements for category A anti-lock braking system may still be used. 1.6.5.14 MEMUs which have been approved before 1 July 2013 in accordance with the provisions of ADR in force up to 31 December 2012, but which do not conform to the requirements of 6.12.3.1.2 or 6.12.3.2.2 applicable as from 1 January 2013, may still be used. 1 ECE Regulation No. 105 (Uniform provisions concerning the approval of vehicles intended for the carriage of dangerous goods with regard to their specific constructional features). 2 Directive 98/91/EC of the European Parliament and of the Council of 14 December 1998 relating to motor vehicles and their trailers intended for the transport of dangerous goods by road and amending Directive 70/156/EEC relating to the type approval of motor vehicles and their trailers (Official Journal of the European Communities No. L 011 of 16 January 1999, pp. 0025-0036). - 54 - 1.6.5.15 As regards the application of the provisions of Part 9, vehicles first registered or entered into service before 1 November 2014 and which have been approved according to the provisions of the directives repealed by the Regulation (EC) No. 661/20093, may continue to be used. 1.6.6 Class 7 1.6.6.1 Packages not requiring competent authority approval of design under the 1985 and 1985 (as amended 1990) editions of IAEA Safety Series No. 6 Packages not requiring competent authority approval of design (excepted packages, Type IP-1, Type IP-2, Type IP-3 and Type A packages) shall meet the requirements of ADR in full, except that packages that meet the requirements of the 1985 or 1985 (as amended 1990) Editions of IAEA Regulations for the Safe Transport of Radioactive Material (IAEA Safety Series No.6): (a) May continue in carriage provided that they were prepared for carriage prior to 31 December 2003, and subject to the requirements of 1.6.6.3, if applicable; (b) May continue to be used provided that: (i) They were not designed to contain uranium hexafluoride; (ii) The applicable requirements of 1.7.3 are applied; (iii) The activity limits and classification in 2.2.7 are applied; (iv) The requirements and controls for carriage in Parts 1, 3, 4, 5 and 7 are applied; (v) The packaging was not manufactured or modified after 31 December 2003. 1.6.6.2 Packages approved under the 1973, 1973 (as amended), 1985 and 1985 (as amended 1990) editions of IAEA Safety Series No. 6 1.6.6.2.1 Packages requiring competent authority approval of the design shall meet the requirements of ADR in full unless the following conditions are met: (a) The packagings were manufactured to a package design approved by the competent authority under the provisions of the 1973 or 1973 (as amended) or the 1985 or 1985 (as amended 1990) Editions of IAEA Safety Series No.6; (b) The package design is subject to multilateral approval; (c) The applicable requirements of 1.7.3 are applied; (d) The activity limits and classification in 2.2.7 are applied; (e) The requirements and controls for carriage in Parts 1, 3, 4, 5 and 7 are applied; (f) (Reserved) 3 Regulation (EC) 661/2009 of 13 July 2009 concerning type-approval requirements for the general safety of motor vehicles, their trailers and systems, components and separate technical units intended therefor (Official Journal L 200 of 31.7.2009, p. 1). - 55 - (g) For packages that meet the requirements of the 1973 or 1973 (as amended) Editions of IAEA Safety Series No. 6: (i) The packages retain sufficient shielding to ensure that the radiation level at 1 m from the surface of the package would not exceed 10 mSv/h in the accident conditions of carriage defined in the 1973 Revised or 1973 Revised (as amended) Editions of IAEA Safety Series No.6 with the maximum radioactive contents which the package is authorized to contain; (ii) The packages do not utilize continuous venting; (iii) A serial number in accordance with the provision of 5.2.1.7.5 is assigned to and marked on the outside of each packaging. 1.6.6.2.2 No new manufacture of packagings to a package design meeting the provisions of the 1973, 1973 (as amended), 1985, and 1985 (as amended 1990) Editions of IAEA Safety Series No.6 shall be permitted to commence. 1.6.6.3 Packages excepted from the requirements for fissile materials under the 2011 and 2013 editions of ADR (2009 Edition of IAEA Safety Standard Series No.TS-R-1) Packages containing fissile material that is excepted from classification as "FISSILE" according to 2.2.7.2.3.5 (a) (i) or (iii) of the 2011 and 2013 editions of ADR (paras. 417 (a) (i) or (iii) of the 2009 Edition of IAEA Regulations for the Safe Transport of Radioactive Material) prepared for carriage before 31 December 2014 may continue in carriage and may continue to be classified as non-fissile or fissile-excepted except that the consignment limits in Table 2.2.7.2.3.5 of these editions shall apply to the vehicle. The consignment shall be carried under exclusive use. 1.6.6.4 Special form radioactive material approved under the 1973, 1973 (as amended), 1985 and 1985 (as amended 1990) Editions of IAEA Safety Series No. 6 Special form radioactive material manufactured to a design which had received unilateral approval by the competent authority under the 1973, 1973 (as amended), 1985 or 1985 (as amended 1990) Editions of IAEA Safety Series No. 6 may continue to be used when in compliance with the mandatory management system in accordance with the applicable requirements of 1.7.3. No new manufacture of such special form radioactive material shall be permitted to commence. - 56 - CHAPTER 1.7 GENERAL PROVISIONS CONCERNING RADIOACTIVE MATERIAL 1.7.1 Scope and application NOTE 1: In the event of accidents or incidents during the carriage of radioactive material, emergency provisions, as established by relevant national and/or international organizations, shall be observed to protect persons, property and the environment. Appropriate guidelines for such provisions are contained in "Planning and Preparing for Emergency Response to Transport Accidents Involving Radioactive Material", Safety Standard Series No. TS-G-1.2 (ST-3), IAEA, Vienna (2002). NOTE 2: Emergency procedures shall take into account the formation of other dangerous substances that may result from the reaction between the contents of a consignment and the environment in the event of an accident. 1.7.1.1 ADR establishes standards of safety which provide an acceptable level of control of the radiation, criticality and thermal hazards to persons, property and the environment that are associated with the carriage of radioactive material. These standards are based on the IAEA Regulations for the Safe Transport of Radioactive material, 2012 Edition, IAEA Safety Standards Series No. SSR–6, IAEA, Vienna (2012). Explanatory material can be found in “Advisory Material for the IAEA Regulations for the Safe Transport of Radioactive Material (2012 Edition)”, IAEA Safety Standards Series No. SSG-26, IAEA, Vienna (2014). 1.7.1.2 The objective of ADR is to establish requirements that shall be satisfied to ensure safety and to protect persons, property and the environment from the effects of radiation in the carriage of radioactive material. This protection is achieved by requiring: (a) Containment of the radioactive contents; (b) Control of external radiation levels; (c) Prevention of criticality; and (d) Prevention of damage caused by heat. These requirements are satisfied firstly by applying a graded approach to contents limits for packages and vehicles and to performance standards applied to package designs depending upon the hazard of the radioactive contents. Secondly, they are satisfied by imposing conditions on the design and operation of packages and on the maintenance of packagings, including a consideration of the nature of the radioactive contents. Finally, they are satisfied by requiring administrative controls including, where appropriate, approval by competent authorities. 1.7.1.3 1.7.1.4 ADR applies to the carriage of radioactive material by road including carriage which is incidental to the use of the radioactive material. Carriage comprises all operations and conditions associated with and involved in the movement of radioactive material; these include the design, manufacture, maintenance and repair of packaging, and the preparation, consigning, loading, carriage including intransit storage, unloading and receipt at the final destination of loads of radioactive material and packages. A graded approach is applied to the performance standards in ADR that are characterized by three general severity levels: (a) Routine conditions of carriage (incident free); (b) Normal conditions of carriage (minor mishaps); (c) Accident conditions of carriage. The provisions laid down in ADR do not apply to any of the following: (a) Radioactive material that is an integral part of the means of transport; - 57 - (b) Radioactive material moved within an establishment which is subject to appropriate safety regulations in force in the establishment and where the movement does not involve public roads or railways; (c) Radioactive material implanted or incorporated into a person or live animal for diagnosis or treatment; (d) Radioactive material in or on a person who is to be transported for medical treatment because the person has been subject to accidental or deliberate intake of radioactive material or to contamination; (e) Radioactive material in consumer products which have received regulatory approval, following their sale to the end user; (f) Natural material and ores containing naturally occurring radionuclides (which may have been processed), provided the activity concentration of the material does not exceed 10 times the values specified in Table 2.2.7.2.2.1, or calculated in accordance with 2.2.7.2.2.2 (a) and 2.2.7.2.2.3 to 2.2.7.2.2.6. For natural materials and ores containing naturally occurring radionuclides that are not in secular equilibrium the calculation of the activity concentration shall be performed in accordance with 2.2.7.2.2.4; (g) Non-radioactive solid objects with radioactive substances present on any surfaces in quantities not in excess of the limit set out in the definition for "contamination" in 2.2.7.1.2. 1.7.1.5 Specific provisions for the carriage of excepted packages 1.7.1.5.1 Excepted packages which may contain radioactive material in limited quantities, instruments, manufactured articles or empty packagings as specified in 2.2.7.2.4.1 shall be subject only to the following provisions of Parts 5 to 7: (a) The applicable provisions specified in 5.1.2.1, 5.1.3.2, 5.1.5.2.2, 5.1.5.2.3, 5.1.5.4, 5.2.1.9, 7.5.11 CV33 (3.1), (5.1) to (5.4) and (6); and (b) The requirements for excepted packages specified in 6.4.4. except when the radioactive material possesses other hazardous properties and has to be classified in a class other than Class 7 in accordance with special provision 290 or 369 of Chapter 3.3, where the provisions listed in (a) and (b) above apply only as relevant and in addition to those relating to the main class. 1.7.1.5.2 Excepted packages are subject to the relevant provisions of all other parts of ADR. If the excepted package contains fissile material, one of the fissile exceptions provided by 2.2.7.2.3.5 shall apply and the requirements of 7.5.11 CV33 (4.3) shall be met. 1.7.2 Radiation protection programme 1.7.2.1 The carriage of radioactive material shall be subject to a Radiation protection programme which shall consist of systematic arrangements aimed at providing adequate consideration of radiation protection measures. 1.7.2.2 Doses to persons shall be below the relevant dose limits. Protection and safety shall be optimized in order that the magnitude of individual doses, the number of persons exposed and the likelihood of incurring exposure shall be kept as low as reasonably achievable, economic and social factors being taken into account within the restriction that the doses to individuals be subject to dose constraints. A structured and systematic approach shall be adopted and shall include consideration of the interfaces between carriage and other activities. 1.7.2.3 The nature and extent of the measures to be employed in the programme shall be related to the magnitude and likelihood of radiation exposures. The programme shall incorporate the requirements in 1.7.2.2, 1.7.2.4, 1.7.2.5 and 7.5.11 CV33 (1.1). Programme documents shall be available, on request, for inspection by the relevant competent authority. - 58 - 1.7.2.4 For occupational exposures arising from transport activities, where it is assessed that the effective dose either: (a) Is likely to be between 1 mSv and 6 mSv in a year, a dose assessment programme via work place monitoring or individual monitoring shall be conducted; or (b) Is likely to exceed 6 mSv in a year, individual monitoring shall be conducted. When individual monitoring or work place monitoring is conducted, appropriate records shall be kept. NOTE: For occupational exposures arising from transport activities, where it is assessed that the effective dose is most unlikely to exceed 1 mSv in a year, no special work patterns, detailed monitoring, dose assessment programmes or individual record keeping need be required. 1.7.2.5 Workers (see 7.5.11, CV33 Note 3) shall be appropriately trained in radiation protection including the precautions to be observed in order to restrict their occupational exposure and the exposure of other persons who might be affected by their actions. 1.7.3 Management system A management system based on international, national or other standards acceptable to the competent authority shall be established and implemented for all activities within the scope of ADR, as identified in 1.7.1.3, to ensure compliance with the relevant provisions of ADR. Certification that the design specification has been fully implemented shall be available to the competent authority. The manufacturer, consignor or user shall be prepared: (a) To provide facilities for inspection during manufacture and use; and (b) To demonstrate compliance with ADR to the competent authority. Where competent authority approval is required, such approval shall take into account and be contingent upon the adequacy of the management system. 1.7.4 Special arrangement 1.7.4.1 Special arrangement shall mean those provisions, approved by the competent authority, under which consignments which do not satisfy all the requirements of ADR applicable to radioactive material may be transported. NOTE: Special arrangement is not considered to be a temporary derogation in accordance with 1.5.1. 1.7.4.2 Consignments for which conformity with any provision applicable to radioactive material is impracticable shall not be transported except under special arrangement. Provided the competent authority is satisfied that conformity with the radioactive material provisions of ADR is impracticable and that the requisite standards of safety established by ADR have been demonstrated through alternative means the competent authority may approve special arrangement transport operations for single or a planned series of multiple consignments. The overall level of safety in carriage shall be at least equivalent to that which would be provided if all the applicable requirements had been met. For international consignments of this type, multilateral approval shall be required. 1.7.5 Radioactive material possessing other dangerous properties In addition to the radioactive and fissile properties, any subsidiary risk of the contents of the package, such as explosiveness, flammability, pyrophoricity, chemical toxicity and corrosiveness, shall also be taken into account in the documentation, packing, labelling, marking, placarding, stowage, segregation and carriage, in order to be in compliance with all relevant provisions for dangerous goods of ADR. - 59 - 1.7.6 Non-compliance 1.7.6.1 In the event of non-compliance with any limit in ADR applicable to radiation level or contamination, (a) (b) (c) The consignor, consignee, carrier and any organization involved during carriage who may be affected, as appropriate, shall be informed of the non-compliance by: (i) the carrier if the non-compliance is identified during carriage; or (ii) the consignee if the non-compliance is identified at receipt; The carrier, consignor or consignee, as appropriate shall: (i) take immediate steps to mitigate the consequences of the non-compliance; (ii) investigate the non-compliance and its causes, circumstances and consequences; (iii) take appropriate action to remedy the causes and circumstances that led to the noncompliance and to prevent a recurrence of similar circumstances that led to the noncompliance; and (iv) communicate to the competent authority(ies) on the causes of the non-compliance and on corrective or preventive actions taken or to be taken; The communication of the non-compliance to the consignor and competent authority(ies), respectively, shall be made as soon as practicable and it shall be immediate whenever an emergency exposure situation has developed or is developing. - 60 - CHAPTER 1.8 CHECKS AND OTHER SUPPORT MEASURES TO ENSURE COMPLIANCE WITH SAFETY REQUIREMENTS 1.8.1 Administrative controls of dangerous goods 1.8.1.1 The competent authorities of the Contracting Parties may, on their national territory, at any time, conduct spot checks to verify whether the requirements concerning the carriage of dangerous goods have been met including, in accordance with 1.10.1.5, those concerning security measures. These checks shall, however, be made without endangering persons, property or the environment and without major disruption of road services. 1.8.1.2 Participants in the carriage of dangerous goods (Chapter 1.4) shall, without delay, in the context of their respective obligations, provide the competent authorities and their agents with the necessary information for carrying out the checks. 1.8.1.3 The competent authorities may also, for the purposes of carrying out checks on the premises of the enterprises participating in the carriage of dangerous goods (Chapter 1.4), make inspections, consult the necessary documents and remove samples of dangerous goods or packagings for examination, provided that safety is not jeopardized thereby. The participants in the carriage of dangerous goods (Chapter 1.4) shall also make the vehicles or parts of vehicles and the equipment and installations accessible for the purpose of checking where this is possible and reasonable. They may, if they deem necessary, designate a person from the enterprise to accompany the representative of the competent authority. 1.8.1.4 If the competent authorities observe that the requirements of ADR have not been met, they may prohibit a consignment or interrupt a transport operation until the defects observed are rectified, or they may prescribe other appropriate measures. Immobilization may take place on the spot or at another place selected by the authorities for safety reasons. These measures shall not cause a major disruption in road services. 1.8.2 Mutual administrative support 1.8.2.1 The Contracting Parties shall agree on mutual administrative support for the implementation of ADR. 1.8.2.2 When a Contracting Party has reasons to observe that the safety of the carriage of dangerous goods on its territory is compromised as a result of very serious or repeated infringements by an enterprise which has its headquarters on the territory of another Contracting Party, it shall notify the competent authorities of this Contracting Party of such infringements. The competent authorities of the Contracting Party on the territory of which the very serious or repeated infringements were observed may request the competent authorities of the Contracting Party on the territory of which the enterprise has its headquarters to take appropriate measures against the offender(s). The transmission of data referring to persons shall not be permitted unless it is necessary for the prosecution of very serious or repeated infringements. 1.8.2.3 The authorities notified shall communicate to the competent authorities of the Contracting Party on the territory of which the infringements were observed, the measures which have, if necessary, been taken with respect to the enterprise. 1.8.3 Safety adviser 1.8.3.1 Each undertaking, the activities of which include the carriage, or the related packing, loading, filling or unloading, of dangerous goods by road shall appoint one or more safety advisers for the carriage of dangerous goods, responsible for helping to prevent the risks inherent in such activities with regard to persons, property and the environment. - 61 - 1.8.3.2 1.8.3.3 The competent authorities of the Contracting Parties may provide that these requirements shall not apply to undertakings: (a) The activities of which concern quantities in each transport unit smaller than those referred to in 1.1.3.6, 1.7.1.4 and in Chapters 3.3, 3.4 and 3.5; or (b) The main or secondary activities of which are not the carriage or the related loading or unloading of dangerous goods but which occasionally engage in the national carriage or the related loading or unloading of dangerous goods posing little danger or risk of pollution. The main task of the adviser shall be, under the responsibility of the head of the undertaking, to seek by all appropriate means and by all appropriate action, within the limits of the relevant activities of that undertaking, to facilitate the conduct of those activities in accordance with the requirements applicable and in the safest possible way. With regard to the undertaking’s activities, the adviser has the following duties in particular: - monitoring compliance with the requirements governing the carriage of dangerous goods; - advising his undertaking on the carriage of dangerous goods; - preparing an annual report to the management of his undertaking or a local public authority, as appropriate, on the undertaking's activities in the carriage of dangerous goods. Such annual reports shall be preserved for five years and made available to the national authorities at their request. The adviser's duties also include monitoring the following practices and procedures relating to the relevant activities of the undertaking: - the procedures for compliance with the requirements governing the identification of dangerous goods being transported; - the undertaking's practice in taking account, when purchasing means of transport, of any special requirements in connection with the dangerous goods being transported; - the procedures for checking the equipment used in connection with the carriage, loading or unloading of dangerous goods; - the proper training of the undertaking’s employees, including on the changes to the regulations, and the maintenance of records of such training; - the implementation of proper emergency procedures in the event of any accident or incident that may affect safety during the carriage, loading or unloading of dangerous goods; - investigating and, where appropriate, preparing reports on serious accidents, incidents or serious infringements recorded during the carriage, loading or unloading of dangerous goods; the implementation of appropriate measures to avoid the recurrence of accidents, incidents or serious infringements; - the account taken of the legal prescriptions and special requirements associated with the carriage of dangerous goods in the choice and use of sub-contractors or third parties; - verification that employees involved in the carriage, loading or unloading of dangerous goods have detailed operational procedures and instructions; - the introduction of measures to increase awareness of the risks inherent in the carriage, loading and unloading of dangerous goods; - the implementation of verification procedures to ensure the presence on board the means of transport of the documents and safety equipment which must accompany transport and the compliance of such documents and equipment with the regulations; - 62 - - the implementation of verification procedures to ensure compliance with the requirements governing loading and unloading; - the existence of the security plan indicated in 1.10.3.2. 1.8.3.4 The adviser may also be the head of the undertaking, a person with other duties in the undertaking, or a person not directly employed by that undertaking, provided that that person is capable of performing the duties of adviser. 1.8.3.5 Each undertaking concerned shall, on request, inform the competent authority or the body designated for that purpose by each Contracting Party of the identity of its adviser. 1.8.3.6 Whenever an accident affects persons, property or the environment or results in damage to property or the environment during carriage, loading or unloading carried out by the undertaking concerned, the adviser shall, after collecting all the relevant information, prepare an accident report to the management of the undertaking or to a local public authority, as appropriate. That report shall not replace any report by the management of the undertaking which might be required under any other international or national legislation. 1.8.3.7 An adviser shall hold a vocational training certificate, valid for transport by road. That certificate shall be issued by the competent authority or the body designated for that purpose by each Contracting Party. 1.8.3.8 To obtain a certificate, a candidate shall undergo training and pass an examination approved by the competent authority of the Contracting Party. 1.8.3.9 The main aims of the training shall be to provide candidates with sufficient knowledge of the risks inherent in the carriage of dangerous goods, of the applicable laws, regulations and administrative provisions and of the duties listed in 1.8.3.3. 1.8.3.10 The examination shall be organized by the competent authority or by an examining body designated by the competent authority. The examining body shall not be a training provider. The examining body shall be designated in writing. This approval may be of limited duration and shall be based on the following criteria: 1.8.3.11 - competence of the examining body; - specifications of the form of the examinations the examining body is proposing; - measures intended to ensure that examinations are impartial; - independence of the body from all natural or legal persons employing safety advisers. The aim of the examination is to ascertain whether candidates possess the necessary level of knowledge to carry out the duties incumbent upon a safety adviser as listed in 1.8.3.3, for the purpose of obtaining the certificate prescribed in sub-section 1.8.3.7, and it shall cover at least the following subjects: (a) Knowledge of the types of consequences which may be caused by an accident involving dangerous goods and knowledge of the main causes of accidents; (b) Requirements under national law, international conventions and agreements, with regard to the following in particular: - classification of dangerous goods (procedure for classifying solutions and mixtures, structure of the list of substances, classes of dangerous goods and principles for their classification, nature of dangerous goods transported, physical, chemical and toxicological properties of dangerous goods); - general packing provisions, provisions for tanks and tank-containers (types, code, marking, construction, initial and periodic inspection and testing); - 63 - - marking and labelling, placarding and orange plates marking (marking and labelling of packages, placing and removal of placards and orange plates); - particulars in transport documents (information required); - method of consignment and restrictions on dispatch (full load, carriage in bulk, carriage in intermediate bulk containers, carriage in containers, carriage in fixed or demountable tanks); - transport of passengers; - prohibitions and precautions relating to mixed loading; - segregation of goods; - limitation of the quantities carried and quantities exemptions; - handling and stowage (loading and unloading - filling ratios -, stowage and segregation); - cleaning and/or degassing before loading and after unloading; - crews, vocational training; - vehicle documents (transport documents, instructions in writing, vehicle approval certificate, driver training certificate, copies of any derogations, other documents); - instructions in writing (implementation of the instructions and crew protection equipment); - supervision requirements (parking); - traffic regulations and restrictions; - operational discharges or accidental leaks of pollutants; - requirements relating to transport equipment. 1.8.3.12 Examinations 1.8.3.12.1 The examination shall consist of a written test which may be supplemented by an oral examination. 1.8.3.12.2 The use in the written test of documentation other than international or national regulations is not permitted. 1.8.3.12.3 Electronic media may be used only if provided by the examining body. There shall be no means of a candidate introducing further data to the electronic media provided; the candidate may only answer the questions posed. 1.8.3.12.4 The written test shall consist of two parts: (a) Candidates shall receive a questionnaire. It shall include at least 20 open questions covering at least the subjects mentioned in the list in 1.8.3.11. However, multiple choice questions may be used. In this case, two multiple choice questions count as one open question. Amongst these subjects particular attention shall be paid to the following subjects: - general preventive and safety measures; - classification of dangerous goods; - general packing provisions, including tanks, tank-containers, tank-vehicles, etc.; - danger markings and labels; - 64 - (b) 1.8.3.13 - information in transport document; - handling and stowage; - crew, vocational training; - vehicle documents and transport certificates; - instructions in writing; - requirements concerning transport equipment; Candidates shall undertake a case study in keeping with the duties of the adviser referred to in 1.8.3.3, in order to demonstrate that they have the necessary qualifications to fulfil the task of adviser. The Contracting Parties may decide that candidates who intend working for undertakings specializing in the carriage of certain types of dangerous goods need only be questioned on the substances relating to their activities. These types of goods are: - Class 1; - Class 2; - Class 7; - Classes 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 8 and 9; - UN Nos. 1202, 1203, 1223, 3475, and aviation fuel classified under UN Nos. 1268 or 1863. The certificate prescribed in 1.8.3.7 shall clearly indicate that it is only valid for one type of the dangerous goods referred to in this sub-section and on which the adviser has been questioned under the conditions defined in 1.8.3.12. 1.8.3.14 The competent authority or the examining body shall keep a running list of the questions that have been included in the examination. 1.8.3.15 The certificate prescribed in 1.8.3.7 shall take the form laid down in 1.8.3.18 and shall be recognized by all Contracting Parties. 1.8.3.16 Validity and renewal of certificates 1.8.3.16.1 The certificate shall be valid for five years. The period of the validity of a certificate shall be extended from the date of its expiry for five years at a time where, during the year before its expiry, its holder has passed an examination. The examination shall be approved by the competent authority. 1.8.3.16.2 The aim of the examination is to ascertain that the holder has the necessary knowledge to carry out the duties set out in 1.8.3.3. The knowledge required is set out in 1.8.3.11 (b) and shall include the amendments to the regulations introduced since the award of the last certificate. The examination shall be held and supervised on the same basis as in 1.8.3.10 and 1.8.3.12 to 1.8.3.14. However, holders need not undertake the case study specified in 1.8.3.12.4 (b). 1.8.3.17 (Deleted) - 65 - 1.8.3.18 Form of certificate Certificate of training as safety adviser for the transport of dangerous goods Certificate No: .................................................................................................................................................................. Distinguishing sign of the State issuing the certificate: .................................................................................................... Surname: ........................................................................................................................................................................... Forename(s): ..................................................................................................................................................................... Date and place of birth: ..................................................................................................................................................... Nationality: ....................................................................................................................................................................... Signature of holder: .......................................................................................................................................................... Valid until ............... for undertakings which transport dangerous goods and for undertakings which carry out related loading or unloading: □ by road □ by rail □ by inland waterway Issued by: ........................................... Date: .................................................. ............................... Signature: ............................................................................ Extended until: ......................... ........................................ By: ....................................................................................... Date: ................................................................................. Signature: ............................................................................ - 66 - 1.8.4 List of competent authorities and bodies designated by them The Contracting Parties shall communicate to the Secretariat of the United Nations Economic Commission for Europe the addresses of the authorities and bodies designated by them which are competent in accordance with national law to implement ADR, referring in each case to the relevant requirement of ADR and giving the addresses to which the relevant applications should be made. The Secretariat of the United Nations Economic Commission for Europe shall establish a list on the basis of the information received and shall keep it up-to-date. It shall communicate this list and the amendments thereto to the Contracting Parties. 1.8.5 Notifications of occurrences involving dangerous goods 1.8.5.1 If a serious accident or incident takes place during loading, filling, carriage or unloading of dangerous goods on the territory of a Contracting Party, the loader, filler, carrier or consignee, respectively, shall ascertain that a report conforming to the model prescribed in 1.8.5.4 is made to the competent authority of the Contracting Party concerned at the latest one month after the occurrence. 1.8.5.2 The Contracting Party shall in turn, if necessary, make a report to the Secretariat of the United Nations Economic Commission for Europe with a view to informing the other Contracting Parties. 1.8.5.3 An occurrence subject to report in accordance with 1.8.5.1 has occurred if dangerous goods were released or if there was an imminent risk of loss of product, if personal injury, material or environmental damage occurred, or if the authorities were involved and one or more of the following criteria has/have been met: Personal injury means an occurrence in which death or injury directly relating to the dangerous goods carried has occurred, and where the injury (a) Requires intensive medical treatment; (b) Requires a stay in hospital of at least one day; or (c) Results in the inability to work for at least three consecutive days. Loss of product means the release of dangerous goods (a) Of transport category 0 or 1 in quantities of 50 kg / 50 l or more; (b) Of transport category 2 in quantities of 333 kg / 333 l or more; or (c) Of transport category 3 or 4 in quantities of 1 000 kg / 1 000 l or more. The loss of product criterion also applies if there was an imminent risk of loss of product in the abovementioned quantities. As a rule, this has to be assumed if, owing to structural damage, the means of containment is no longer suitable for further carriage or if, for any other reason, a sufficient level of safety is no longer ensured (e.g. owing to distortion of tanks or containers, overturning of a tank or fire in the immediate vicinity). If dangerous goods of Class 6.2 are involved, the obligation to report applies without quantity limitation. - 67 - In occurrences involving radioactive material, the criteria for loss of product are: (a) Any release of radioactive material from the packages; (b) Exposure leading to a breach of the limits set out in the regulations for protection of workers and members of the public against ionizing radiation (Schedule II of IAEA Safety Series No. 115 – "International Basic Safety Standards for Protection Against Ionizing Radiation and for Safety of Radiation Sources"); or (c) Where there is reason to believe that there has been a significant degradation in any package safety function (containment, shielding, thermal protection or criticality) that may have rendered the package unsuitable for continued carriage without additional safety measures. NOTE: See the requirements of 7.5.11 CV33 (6) for undeliverable consignments. Material damage or environmental damage means the release of dangerous goods, irrespective of the quantity, where the estimated amount of damage exceeds 50,000 Euros. Damage to any directly involved means of carriage containing dangerous goods and to the modal infrastructure shall not be taken into account for this purpose. Involvement of authorities means the direct involvement of the authorities or emergency services during the occurrence involving dangerous goods and the evacuation of persons or closure of public traffic routes (roads/railways) for at least three hours owing to the danger posed by the dangerous goods. If necessary, the competent authority may request further relevant information. 1.8.5.4 Model for report on occurrences during the carriage of dangerous goods - 68 - Report on occurrences during the carriage of dangerous goods in accordance with RID/ADR section 1.8.5 Carrier/Railway infrastructure operator: ............................................................................................................................…………………………………………. Address: ............................................................................................................................................................….………………… Contact name: .......................................………… Telephone: ............................ Fax: ................................…….…. (The competent authority shall remove this cover sheet before forwarding the report) - 69 - 1. Mode □ Rail □ Road Wagon number (optional) Vehicle registration (optional) .........................................................……………………… ............................................................…………………... 2. Date and location of occurrence Year: ………………….. Month: …………………. Day: …………………. Time: …………………………... Rail Road □ Station □ Built-up area □ Shunting/marshalling yard □ Loading/unloading/transhipment site □ Loading/unloading/transhipment site □ Open road Location / Country: …………………………………… Location / Country: ……………………………….… or □ Open line: Description of line: …………………………………… Kilometres: ………………………………….………... 3. Topography □ Gradient/incline □ Tunnel □ Bridge/Underpass □ Crossing 4. Particular weather conditions □ Rain □ Snow □ Ice □ Fog □ Thunderstorm □ Storm Temperature: ..... °C 5. Description of occurrence □ Derailment/Leaving the road □ Collision □ Overturning/Rolling over □ Fire □ Explosion □ Loss □ Technical fault Additional description of occurrence: ..........................................................................................................................................…………………....................... ............................................................................................................................................................................................. ............................................................................................................................................................................................. ............................................................................................................................................................................................. ............................................................................................................................................................................................. ............................................................................................................................................................................................. ............………………………………………………………………………………………………………………….… ………………………………………………………………………………………………………………………….… ……………………………………………………………………………………………………………………………. - 71 - 6. Dangerous goods involved UN Number (1) Class Packing Estimated quantity of Group loss of products (kg or l) (2) Means of containment (3) Means of containment material Type of failure of means of containment (4) (1) For dangerous goods assigned to collective entries to (2) For Class 7, indicate values according to the criteria in which special provision 274 applies, also the technical 1.8.5.3. name shall be indicated. (3) (4) Indicate the appropriate number Indicate the appropriate number 1 Packaging 1 Loss 2 IBC 2 Fire 3 Large packaging 3 Explosion 4 Small container 4 Structural failure 5 Wagon 6 Vehicle 7 Tank-wagon 8 Tank-vehicle 9 Battery-wagon 10 Battery-vehicle 11 Wagon with demountable tanks 12 Demountable tank 13 Large container 14 Tank-container 15 MEGC 16 Portable tank 7. Cause of occurrence (if clearly known) □ Technical fault □ Faulty load securing □ Operational cause (rail operation) □ Other: ............................................................................................................................................................................................. ...............................................................................................................................................…………………………….. ……………………………………………………………………………………………………………………………. 8. Consequences of occurrence Personal injury in connection with the dangerous goods involved: □ Deaths (number: ......) □ Injured (number: ......) Loss of product: □ Yes □ No □ Imminent risk of loss of product Material/Environmental damage: □ Estimated level of damage  50,000 Euros □ Estimated level of damage > 50,000 Euros Involvement of authorities: □ Yes □ Evacuation of persons for a duration of at least three hours caused by the dangerous goods involved □ Closure of public traffic routes for a duration of at least three hours caused by the dangerous goods involved □ No If necessary, the competent authority may request further relevant information. - 72 - 1.8.6 Administrative controls for application of the conformity assessments, inspections, intermediate inspections and exceptional checks described in 1.8.7 1.8.6.1 Approval of inspection bodies periodic The competent authority may approve inspection bodies for conformity assessments, periodic inspections, intermediate inspections, exceptional checks and surveillance of the in-house inspection service as specified in 1.8.7. 1.8.6.2 Operational obligations for the competent authority, its delegate or inspection body 1.8.6.2.1 The competent authority, its delegate or inspection body shall carry out conformity assessments, periodic inspections, intermediate inspections and exceptional checks in a proportionate manner, avoiding unnecessary burdens. The competent authority, its delegate or inspection body shall perform its activities taking into consideration the size, the sector and the structure of the undertakings involved, the relative complexity of the technology and the serial character of production. 1.8.6.2.2 Nevertheless the competent authority, its delegate or inspection body shall respect the degree of rigour and the level of protection required for the compliance of the transportable pressure equipment by the provisions of parts 4 and 6 as applicable. 1.8.6.2.3 Where a competent authority, its delegate or inspection body finds out that requirements laid down in parts 4 or 6 have not been met by the manufacturer, it shall require the manufacturer to take appropriate corrective measures and it shall not issue any type approval certificate or certificate of conformity. 1.8.6.3 Information obligation Contracting Parties to ADR shall publish their national procedures for the assessment, appointment and monitoring of inspection bodies and of any changes to that information. 1.8.6.4 Delegation of inspection tasks NOTE: In-house inspection services according to 1.8.7.6 are not covered by 1.8.6.4. 1.8.6.4.1 Where an inspection body uses the services of any other entity (e.g. subcontractor, subsidiary), to carry out specific tasks connected with the conformity assessment, periodic inspection, intermediate inspection or exceptional checks, this entity shall be included in the accreditation of the inspection body, or it shall be accredited separately. In the case of separate accreditation, this entity shall be duly accredited according to standard EN ISO/IEC 17025:2005 and shall be recognised by the inspection body as an independent and impartial testing laboratory in order to perform testing tasks in accordance with its accreditation, or it shall be accredited according to standard EN ISO/IEC 17020:2012 (except clause 8.1.3). The inspection body shall ensure that this entity meets the requirements set out for the tasks given to it with the same level of competence and safety as laid down for inspection bodies (see 1.8.6.8) and the inspection body shall monitor it. The inspection body shall inform the competent authority about the above mentioned arrangements. 1.8.6.4.2 The inspection body shall take full responsibility for the tasks performed by such entities wherever the tasks are performed by them. 1.8.6.4.3 The inspection body shall not delegate the whole task of conformity assessment, periodic inspection, intermediate inspection or exceptional checks. In any case, the assessment and the issue of certificates shall be carried out by the inspection body itself. 1.8.6.4.4 Activities shall not be delegated without the agreement of the applicant. 1.8.6.4.5 The inspection body shall keep at the disposal of the competent authority the relevant documents concerning the assessment of the qualifications and the work carried out by the above mentioned entities. - 73 - 1.8.6.5 Information obligations for inspection bodies Any inspection body shall inform the competent authority, which had approved it, of the following: (a) Except when the provisions of 1.8.7.2.4 apply, any refusal, restriction, suspension or withdrawal of type approval certificates; (b) Any circumstance(s) affecting the scope of and conditions for the approval as granted by the competent authority; (c) Any request for information on conformity assessment activities performed which they have received from competent authorities monitoring compliance according to 1.8.1 or 1.8.6.6; (d) On request, conformity assessment activities performed within the scope of their approval and any other activity performed, including delegation of tasks. 1.8.6.6 The competent authority shall ensure the monitoring of the inspection bodies and shall revoke or restrict the approval given, if it notes that an approved body is no longer in compliance with the approval and the requirements of 1.8.6.8 or does not follow the procedures specified in the provisions of ADR. 1.8.6.7 If the approval of the inspection body is revoked or restricted or if the inspection body ceased activity, the competent authority shall take the appropriate steps to ensure that the files are either processed by another inspection body or kept available. 1.8.6.8 The inspection body shall: (a) Have a staff with an organizational structure, capable, trained, competent and skilled, to satisfactorily perform its technical functions; (b) Have access to suitable and adequate facilities and equipment; (c) Operate in an impartial manner and be free from any influence which could prevent it from doing so; (d) Ensure commercial confidentiality of the commercial and proprietary activities of the manufacturer and other bodies; (e) Maintain clear demarcation between actual inspection body functions and unrelated functions; (f) Have a documented quality system; (g) Ensure that the tests and inspections specified in the relevant standard and in ADR are performed; and (h) Maintain an effective and appropriate report and record system in accordance with 1.8.7 and 1.8.8. The inspection body shall additionally be accredited according to the standard EN ISO/IEC 17020:2012 (except clause 8.1.3), as specified in 6.2.2.11, 6.2.3.6 and TA4 and TT9 of 6.8.4. An inspection body starting a new activity may be approved temporarily. Before temporary designation, the competent authority shall ensure that the inspection body meets the requirements of the standard EN ISO/IEC 17020:2012 (except clause 8.1.3). The inspection body shall be accredited in its first year of activity to be able to continue this new activity. - 74 - 1.8.7 Procedures for conformity assessment and periodic inspection NOTE: In this section, "relevant body" means a body assigned in 6.2.2.11 when certifying UN pressure receptacles, in 6.2.3.6 when approving non-UN pressure receptacles and in special provisions TA4 and TT9 of 6.8.4. 1.8.7.1 General provisions 1.8.7.1.1 The procedures in section 1.8.7 shall be applied according to 6.2.3.6 when approving non-UN pressure receptacles and according to TA4 and TT9 of 6.8.4 when approving tanks, battery-vehicles and MEGCs. The procedures in section 1.8.7 may be applied according to the table in 6.2.2.11 when certifying UN pressure receptacles. 1.8.7.1.2 Each application for (a) The type approval in accordance with 1.8.7.2 or; (b) The supervision of manufacture in accordance with 1.8.7.3 and the initial inspection and test in accordance with 1.8.7.4; or (c) The periodic inspection, intermediate inspection and exceptional checks in accordance with 1.8.7.5 shall be lodged by the applicant with a single competent authority, its delegate or an approved inspection body of his choice. 1.8.7.1.3 The application shall include: (a) The name and address of the applicant; (b) For conformity assessment where the applicant is not the manufacturer, the name and address of the manufacturer; (c) A written declaration that the same application has not been lodged with any other competent authority, its delegate or inspection body; (d) The relevant technical documentation specified in 1.8.7.7; (e) A statement allowing the competent authority, its delegate or inspection body access for inspection purposes to the locations of manufacture, inspection, testing and storage and providing it with all necessary information. 1.8.7.1.4 Where the applicant can demonstrate to the satisfaction of the competent authority or its delegated inspection body conformity with 1.8.7.6 the applicant may establish an in-house inspection service which may perform part or all of the inspections and tests when specified in 6.2.2.11 or 6.2.3.6. 1.8.7.1.5 Design type approval certificates and certificates of conformity - including the technical documentation - shall be retained by the manufacturer or by the applicant for the type approval, if he is not the manufacturer, and by the inspection body, who issued the certificate, for a period of at least 20 years starting from the last date of production of products of the same type. 1.8.7.1.6 When a manufacturer or owner intends to cease operation, he shall send the documentation to the competent authority. The competent authority shall then retain the documentation for the rest of the period specified in 1.8.7.1.5. 1.8.7.2 Type approval Type approvals authorise the manufacture of pressure receptacles, tanks, battery-vehicles or MEGCs within the period of validity of that approval. - 75 - 1.8.7.2.1 1.8.7.2.2 The applicant shall: (a) In the case of pressure receptacles, place at the disposal of the relevant body representative samples of the production envisaged. The relevant body may request further samples if required by the test programme; (b) In the case of tanks, battery-vehicles or MEGCs, give access to the prototype for type testing. The relevant body shall: (a) Examine the technical documentation specified in 1.8.7.7.1 to verify that the design is in accordance with the relevant provisions of ADR, and the prototype or the prototype lot has been manufactured in conformity with the technical documentation and is representative of the design; (b) Perform the examinations and witness the tests specified in ADR, to determine that the provisions have been applied and fulfilled, and the procedures adopted by the manufacturer meet the requirements; (c) Check the certificate(s) issued by the materials manufacturer(s) against the relevant provisions of ADR; (d) As applicable, approve the procedures for the permanent joining of parts or check that they have been previously approved, and verify that the staff undertaking the permanent joining of parts and the non-destructive tests are qualified or approved; (e) Agree with the applicant the location and testing facilities where the examinations and necessary tests are to be carried out. The relevant body shall issue a type-examination report to the applicant. 1.8.7.2.3 Where the type satisfies all applicable provisions, the competent authority, its delegate or the inspection body, shall issue a type approval certificate to the applicant. This certificate shall contain: (a) The name and address of the issuer; (b) The name and address of the manufacturer and of the applicant when the applicant is not the manufacturer; (c) A reference to the version of ADR and standards used for the type examination; (d) Any requirements resulting from the examination; (e) (f) The necessary data for identification of the type and variation, as defined by the relevant standard; The reference to the type examination report(s); and (g) The maximum period of validity of the type approval. A list of the relevant parts of the technical documentation shall be annexed to the certificate (see 1.8.7.7.1). 1.8.7.2.4 The type approval shall be valid for a maximum of ten years. If within that period the relevant technical requirements of ADR (including referenced standards) have changed so that the approved type is no longer in conformity with them, the relevant body which issued the type approval shall withdraw it and inform the holder of the type approval. NOTE: For the ultimate dates for withdrawal of existing type approvals, see column (5) of the tables in 6.2.4 and 6.8.2.6 or 6.8.3.6 as appropriate. - 76 - If a type approval has expired or has been withdrawn, the manufacture of the pressure receptacles, tanks, battery-vehicles or MEGCs according to that type approval is no longer authorised. In such a case, the relevant provisions concerning the use, periodic inspection and intermediate inspection of pressure receptacles, tanks, battery-vehicles or MEGCs contained in the type approval which has expired or has been withdrawn shall continue to apply to these pressure receptacles, tanks, battery-vehicles or MEGCs constructed before the expiry or the withdrawal if they may continue to be used. They may continue to be used as long as they remain in conformity with the requirements of ADR. If they are no longer in conformity with the requirements of ADR they may continue to be used only if such use is permitted by relevant transitional measures in Chapter 1.6. Type approvals may be renewed by a complete review and assessment for conformity with the provisions of ADR applicable at the date of renewal. Renewal is not permitted after a type approval has been withdrawn. Interim amendments of an existing type approval (e.g. for pressure receptacles minor amendments such as the addition of further sizes or volumes not affecting conformity, or for tanks see 6.8.2.3.2) do not extend or modify the original validity of the certificate. NOTE: The review and assessment of conformity can be done by a body other than the one which issued the original type approval. The issuing body shall keep all documents for the type approval (see 1.8.7.7.1) for the whole period of validity including its renewals if granted. 1.8.7.2.5 In the case of a modification of a pressure receptacle, tank, battery-vehicle or MEGC with a valid, expired or withdrawn type approval, the testing, inspection and approval are limited to the parts of the pressure receptacle, tank, battery-vehicle or MEGC that have been modified. The modification shall meet the provisions of ADR applicable at the time of the modification. For all parts of the pressure receptacle, tank, battery-vehicle or MEGC not affected by the modification, the documentation of the initial type approval remains valid. A modification may apply to one or more pressure receptacles, tanks, battery-vehicles or MEGCs covered by a type approval. A certificate approving the modification shall be issued to the applicant by the competent authority of any Contracting Party to ADR or by a body designated by this authority. For tanks, battery-vehicles or MEGCs, a copy shall be kept as part of the tank record. Each application for an approval certificate for a modification shall be lodged by the applicant with a single competent authority or body designated by this authority. 1.8.7.3 Supervision of manufacture 1.8.7.3.1 The manufacturing process shall be subject to a survey by the relevant body to ensure the product is produced in conformity with the provisions of the type approval. 1.8.7.3.2 The applicant shall take all the necessary measures to ensure that the manufacturing process complies with the applicable provisions of ADR and of the type approval certificate and its annexes. 1.8.7.3.3 The relevant body shall: (a) Verify the conformity with the technical documentation specified in 1.8.7.7.2; (b) Verify that the manufacturing process produces products in conformity with the requirements and the documentation which apply to it; (c) Verify the traceability of materials and check the material certificate(s) against the specifications; (d) As applicable, verify that the personnel undertaking the permanent joining of parts and the non-destructive tests are qualified or approved; - 77 - (e) Agree with the applicant on the location where the examinations and necessary tests are to be carried out; and (f) Record the results of its survey. 1.8.7.4 Initial inspection and tests 1.8.7.4.1 The applicant shall: 1.8.7.4.2 (a) Affix the marks specified in ADR; and (b) Supply to the relevant body the technical documentation specified in 1.8.7.7. The relevant body shall: (a) Perform the necessary examinations and tests in order to verify that the product is manufactured in accordance with the type approval and the relevant provisions; (b) Check the certificates supplied by the manufacturers of service equipment against the service equipment; (c) Issue an initial inspection and test report to the applicant relating to the detailed tests and verifications carried out and the verified technical documentation; (d) Draw up a written certificate of conformity of the manufacture and affix its registered mark when the manufacture satisfies the provisions; and (e) Check if the type approval remains valid after provisions of ADR (including referenced standards) relevant to the type approval have changed. The certificate in (d) and report in (c) may cover a number of items of the same type (group certificate or report). 1.8.7.4.3 The certificate shall contain as a minimum: (a) The name and address of the relevant body; (b) The name and address of the manufacturer and the name and address of the applicant, if not the manufacturer; (c) A reference to the version of the ADR and standards used for the initial inspections and tests; (d) The results of the inspections and tests; (e) The data for identification of the inspected product(s), at least the serial number or for non refillable cylinders the batch number; and (f) The type approval number. 1.8.7.5 Periodic inspection, intermediate inspection and exceptional checks 1.8.7.5.1 The relevant body shall: (a) Perform the identification and verify the conformity with the documentation; (b) Carry out the inspections and witness the tests in order to check that the requirements are met; (c) Issue reports of the results of the inspections and tests, which may cover a number of items; and (d) Ensure that the required marks are applied. - 78 - 1.8.7.5.2 Reports of periodic inspections and tests of pressure receptacles shall be retained by the applicant at least until the next periodic inspection. NOTE: For tanks, see provisions for tank records in 4.3.2.1.7. 1.8.7.6 Surveillance of the applicant’s in-house inspection service 1.8.7.6.1 The applicant shall: 1.8.7.6.2 1.8.7.6.3 (a) Implement an in-house inspection service with a quality system for inspections and tests documented in 1.8.7.7.5 and subject to surveillance; (b) Fulfil the obligations arising out of the quality system as approved and to ensure that it remains satisfactory and efficient; (c) Appoint trained and competent personnel for the in-house inspection service; and (d) Affix the registered mark of the inspection body where appropriate. The inspection body shall carry out an initial audit. If satisfactory the inspection body shall issue an authorisation for a period not exceeding three years. The following provisions shall be met: (a) This audit shall confirm that the inspections and tests performed on the product are in compliance with the requirements of ADR; (b) The inspection body may authorise the in-house inspection service of the applicant to affix the registered mark of the inspection body to each approved product; (c) The authorisation may be renewed after a satisfactory audit in the last year prior to the expiry. The new period of validity shall begin with the date of expiry of the authorisation; and (d) The auditors of the inspection body shall be competent to carry out the assessment of conformity of the product covered by the quality system. The inspection body shall carry out periodic audits within the duration of the authorisation to make sure that the applicant maintains and applies the quality system. The following provisions shall be met: (a) A minimum of two audits shall be carried out in a 12 month period; (b) The inspection body may require additional visits, training, technical changes, modifications of the quality system, restrict or prohibit the inspections and tests to be done by the applicant; (c) The inspection body shall assess any changes in the quality system and decide whether the modified quality system will still satisfy the requirements of the initial audit or whether a full reassessment is required; (d) The auditors of the inspection body shall be competent to carry out the assessment of conformity of the product covered by the quality system; and (e) The inspection body shall provide the applicant with a visit or audit report and, if a test has taken place, with a test report. 1.8.7.6.4 In cases of non conformity with the relevant requirements the inspection body shall ensure that corrective measures are taken. If corrective measures are not taken in due time, the inspection body shall suspend or withdraw the permission for the in-house inspection service to carry out its activities. The notice of suspension or withdrawal shall be transmitted to the competent authority. A report shall be provided to the applicant giving detailed reasons for the decisions taken by the inspection body. 1.8.7.7 Documents The technical documentation shall enable an assessment to be made of conformity with the relevant requirements. - 79 - 1.8.7.7.1 Documents for type approval The applicant shall provide as appropriate: (a) The list of standards used for the design and manufacture; (b) A description of the type including all variations; (c) The instructions according to the relevant column of table A of Chapter 3.2 or a list of dangerous goods to be transported for dedicated products; (d) A general assembly drawing or drawings; (e) The detailed drawings, including the dimensions used for the calculations, of the product, the service equipment, the structural equipment, the marking and/or the labelling necessary to verify the conformity; The calculation notes, results and conclusions; (f) 1.8.7.7.2 (g) The list of the service equipment with the relevant technical data and information on the safety devices including the calculation of the relief capacity if relevant; (h) The list of material requested in the standard for manufacture used for every part, sub-part, lining, service and structural equipment and the corresponding material specifications or the corresponding declaration of conformity to ADR; (i) The approved qualification of permanent joining process; (j) The description of the heat treatment process(es); and (k) The procedures, descriptions and records of all relevant tests listed in the standards or ADR for the type approval and for the manufacture. Documents for the supervision of manufacture The applicant shall make available as appropriate: 1.8.7.7.3 (a) The documents listed in 1.8.7.7.1; (b) A copy of the type approval certificate; (c) The manufacturing procedures including test procedures; (d) The manufacturing records; (e) The approved qualifications of permanent joining operators; (f) The approved qualifications of the non destructive test operators; (g) The reports of the destructive and non destructive tests; (h) The heat treatment records; and (i) The calibration records. Documents for initial inspection and tests The applicant shall make available as appropriate: (a) The documents listed in 1.8.7.7.1 and 1.8.7.7.2; (b) The material certificates of the product and any sub-parts; (c) The declarations of conformity and material certificates of the service equipment; and - 80 - (d) 1.8.7.7.4 A declaration of conformity including the description of the product and all the variations adopted from the type approval. Documents for periodic inspections, intermediate inspections and exceptional checks The applicant shall make available as appropriate: 1.8.7.7.5 (a) For pressure receptacles, the documents specifying special requirements when the manufacturing and periodic inspections and tests standards so require; (b) For tanks: (i) the tank record; and (ii) one or more of the documents mentioned in 1.8.7.7.1 to 1.8.7.7.3. Documents for the assessment of in-house inspection service The applicant for in-house inspection service shall make available the quality system documentation as appropriate: 1.8.7.8 (a) The organizational structure and responsibilities; (b) The relevant inspection and test, quality control, quality assurance and process operation instructions, and systematic actions that will be used; (c) The quality records, such as inspection reports, test data, calibration data and certificates; (d) The management reviews to ensure the effective operation of the quality system arising from the audits in accordance with 1.8.7.6; (e) The process describing how customer and regulation requirements are met; (f) The process for control of documents and their revision; (g) The procedures for dealing with non-conforming products; and (h) The training programmes and qualification procedures for relevant personnel. Products manufactured, approved, inspected and tested according to standards The requirements of 1.8.7.7 are considered to have been complied with if the following standards, as relevant, are applied: 1.8.8 Applicable subsection and paragraph References Title of the document 1.8.7.7.1 to 1.8.7.7.4 EN 12972:2007 Tanks for transport of dangerous goods - Testing, inspection and marking of metallic tanks Procedures for conformity assessment of gas cartridges When assessing the conformity of gas cartridges, one of the following procedures shall be applied: (a) The procedure in section 1.8.7 for non-UN pressure receptacles, with the exception of 1.8.7.5; or (b) The procedure in sub-sections 1.8.8.1 to 1.8.8.7. - 81 - 1.8.8.1 General provisions 1.8.8.1.1 The supervision of manufacture shall be carried out by an Xa body and the tests as required in 6.2.6 shall be carried out either by that Xa body or by an IS-body approved by that Xa body; for definition of Xa and IS bodies see definitions in 6.2.3.6.1. Conformity assessment shall be carried out by the competent authority, its delegate or its approved inspection body of a Contracting Party to ADR. 1.8.8.1.2 By the application of 1.8.8, the applicant shall demonstrate, ensure and declare on his sole responsibility the conformity of gas cartridges with the provisions of 6.2.6 and all further applicable provisions of ADR. 1.8.8.1.3 The applicant shall (a) Carry out a design type examination of each type of gas cartridges (including materials to be used and variations of that type, e.g. volumes, pressures, drawings and closing and release devices) according to 1.8.8.2; (b) Operate an approved quality system for design, manufacture, inspection and testing according to 1.8.8.3; (c) Operate an approved testing regime according to 1.8.8.4 for the tests required in 6.2.6; (d) Apply for the approval of his quality system for supervision of manufacture and for testing to one Xa body of his choice of the Contracting Party; if the applicant is not established in a Contracting Party he shall apply to one Xa body of a Contracting Party prior to first transport into a Contracting Party; (e) If the gas cartridge is finally assembled from parts manufactured by the applicant by one or more other enterprise(s), provide written instructions how to assemble and fill the gas cartridges to meet the provisions of his type examination certificate. 1.8.8.1.4 Where the applicant and enterprises assembling or filling gas cartridges according to the instructions of the applicant, can demonstrate to the satisfaction of the Xa body conformity with the provisions of 1.8.7.6 excluding 1.8.7.6.1 (d) and 1.8.7.6.2 (b), they may establish an in-house inspection service which may perform part or all of the inspections and tests specified in 6.2.6. 1.8.8.2 Design type examination 1.8.8.2.1 The applicant shall establish a technical documentation for each type of gas cartridges including the technical standard(s) applied. If he chooses to apply a standard not referenced in 6.2.6, he shall add the standard applied to the documentation. 1.8.8.2.2 The applicant shall retain the technical documentation together with samples of that type at the disposal of the Xa body during production and afterwards for a period of minimum five years starting from the last date of production of gas cartridges according to that type examination certificate. 1.8.8.2.3 The applicant shall after careful examination issue a design type certificate which shall be valid for a maximum period of ten years; he shall add this certificate to the documentation. This certificate authorises him to produce gas cartridges of that type for that period. 1.8.8.2.4 If within that period the relevant technical requirements of ADR (including referenced standards) have changed so that the design type is no longer in conformity with them, the applicant shall withdraw his type examination certificate and inform the Xa body. 1.8.8.2.5 The applicant may after careful and complete review reissue the certificate for another period of maximum ten years. - 82 - 1.8.8.3 Supervision of manufacture 1.8.8.3.1 The procedure of design type examination as well as the manufacturing process shall be subject to a survey by the Xa body to ensure the type certified by the applicant and the product as produced are in conformity with the provisions of the design type certificate and the applicable provisions of ADR. If 1.8.8.1.3 (e) applies, the assembling and filling enterprises shall be included in that procedure. 1.8.8.3.2 The applicant shall take all the necessary measures to ensure that the manufacturing process complies with the applicable provisions of ADR and of his design type certificate and its annexes. If 1.8.8.1.3 (e) applies, the assembling and filling enterprises shall be included in that procedure. 1.8.8.3.3 The Xa body shall: (a) Verify the conformity of the design type examination of the applicant and conformity of the type of gas cartridges with the technical documentation specified in 1.8.8.2; (b) Verify that the manufacturing process produces products in conformity with the requirements and the documentation which apply to it; if the gas cartridge is finally assembled from parts manufactured by the applicant by one or more enterprise(s), the Xa body shall also verify that the gas cartridges are in full conformity with all applicable provisions after final assembly and filling and that the instructions of the applicant are correctly applied; (c) Verify that the personnel undertaking the permanent joining of parts and the tests are qualified or approved; (d) Record the results of its surveys. 1.8.8.3.4 If the findings of the Xa body show non-conformity of the design type certificate of the applicant or the manufacturing process, he shall require appropriate corrective measures or withdrawal of the certificate from the applicant. 1.8.8.4 Leakproofness test 1.8.8.4.1 The applicant and enterprises finally assembling and filling gas cartridges according to the instructions of the applicant shall: 1.8.8.4.2 (a) Carry out the tests required in 6.2.6; (b) Record the test results; (c) Issue a certificate of conformity only for gas cartridges, which are in full compliance with the provisions of his design type examination and the applicable provisions of ADR and have successfully passed the tests as required in 6.2.6; (d) Retain the documentation as specified in 1.8.8.7 during production and afterwards for a period of minimum five years from the last date of production of gas cartridges belonging to one type approval for inspection by the Xa body at random intervals; (e) Affix a durable and legible mark identifying the type of gas cartridge, the applicant and the date of production or batch number; where due to limited available space the mark cannot be fully applied to the body of the gas cartridge, he shall affix a durable tag with this information to the gas cartridge or place it together with a gas cartridge in an inner packaging. The Xa body shall: (a) Perform the necessary examinations and tests at random intervals, but at least shortly after starting of manufacture of a type of gas cartridges and thereafter at least once every three years, in order to verify that the procedure for design type examination of the applicant as well as that the manufacture and testing of the product are carried out in accordance with the design type certificate and the relevant provisions; - 83 - 1.8.8.4.3 (b) Check the certificates supplied by the applicant; (c) Carry out the tests as required in 6.2.6 or approve the program of testing and the in-house inspection service to carry out the tests. The certificate shall contain as a minimum: (a) The name and address of the applicant and, when the final assembly is not carried out by the applicant but by an enterprise or enterprises in accordance with the written instructions of the applicant, the name(s) and address(es) of these enterprises; (b) A reference to the version of ADR and the standard(s) used for manufacture and tests; (c) The result of inspections and tests; (d) The data for the marking as required in 1.8.8.4.1 (e). 1.8.8.5 (Reserved) 1.8.8.6 Surveillance of the in-house inspection service When the applicant or enterprise assembling or filling gas cartridges has established an in-house inspection service, the provisions of 1.8.7.6 excluding 1.8.7.6.1 (d) and 1.8.7.6.2 (b) shall be applied. The enterprise assembling or filling gas cartridges shall comply with the provisions relevant to the applicant. 1.8.8.7 Documents The provisions of 1.8.7.7.1, 1.8.7.7.2, 1.8.7.7.3 and 1.8.7.7.5 shall be applied. - 84 - CHAPTER 1.9 TRANSPORT RESTRICTIONS BY THE COMPETENT AUTHORITIES 1.9.1 In accordance with Article 4, paragraph 1 of ADR, the entry of dangerous goods into the territory of Contracting Parties may be subject to regulations or prohibitions imposed for reasons other than safety during carriage. Such regulations or prohibitions shall be published in an appropriate form. 1.9.2 Subject to the provisions of 1.9.3, a Contracting Party may apply to vehicles engaged in the international carriage of dangerous goods by road on its territory certain additional provisions not included in ADR, provided that those provisions do not conflict with Article 2, paragraph 2 of the Agreement, and are contained in its domestic legislation applying equally to vehicles engaged in the domestic carriage of dangerous goods by road on the territory of that Contracting Party. 1.9.3 Additional provisions falling within the scope of 1.9.2 are as follows: (a) Additional safety requirements or restrictions concerning vehicles using certain structures such as bridges, vehicles using combined transport modes such as ferries or trains, or vehicles entering or leaving ports or other transport terminals; (b) Requirements for vehicles to follow prescribed routes to avoid commercial or residential areas, environmentally sensitive areas, industrial zones containing hazardous installations or roads presenting severe physical hazards; (c) Emergency requirements regarding routeing or parking of vehicles carrying dangerous goods resulting from extreme weather conditions, earthquake, accident, industrial action, civil disorder or military hostilities; (d) Restrictions on movement of dangerous goods traffic on certain days of the week or year. 1.9.4 The competent authority of the Contracting Party applying on its territory any additional provisions within the scope of 1.9.3 (a) and (d) above shall notify the secretariat of the United Nations Economic Commission for Europe of the additional provisions, which secretariat shall bring them to the attention of the Contracting Parties1. 1.9.5 Tunnel restrictions NOTE: Provisions concerning restrictions for the passage of vehicles through road tunnels are also included in Chapter 8.6. 1.9.5.1 General provisions When applying restrictions to the passage of vehicles carrying dangerous goods through tunnels, the competent authority shall assign the road tunnel to one of the tunnel categories defined in 1.9.5.2.2. Account should be taken of the tunnel characteristics, risk assessment including availability and suitability of alternative routes and modes and traffic management considerations. The same tunnel may be assigned to more than one tunnel category, e.g. depending on the hours of the day, or the day of the week etc. 1.9.5.2 Categorization 1.9.5.2.1 The categorization shall be based on the assumption that in tunnels there are three major dangers which may cause numerous victims or serious damage to the tunnel structure: 1 A General Guideline for the Calculation of Risks in the Transport of Dangerous Goods by Road may be consulted on the website of the secretariat of the United Nations Economic Commission for Europe (http://www.unece.org/trans/danger/danger.htm). - 85 - 1.9.5.2.2 (a) Explosions; (b) Release of toxic gas or volatile toxic liquid; (c) Fires. The five tunnel categories are the following: Tunnel category A: No restrictions for the carriage of dangerous goods; Tunnel category B: Restriction for the carriage of dangerous goods which may lead to a very large explosion; The following dangerous goods are considered to fulfil this criterion2: Class 1: Class 3: Class 4.1: Compatibility groups A and L; Classification code D (UN Nos. 1204, 2059, 3064, 3343, 3357 and 3379); Classification codes D and DT; and Self-reactive substances, type B (UN Nos. 3221, 3222, 3231 and 3232); Class 5.2: Organic peroxides, type B (UN Nos. 3101, 3102, 3111 and 3112). When the total net explosive mass per transport unit is greater than 1000 kg: Class 1: Divisions 1.1, 1.2 and 1.5 (except compatibility groups A and L). When carried in tanks: Class 2: Classification codes F, TF and TFC; Class 4.2: Packing group I; Class 4.3: Packing group I; Class 5.1: Packing group I. Class 6.1: UN No. 1510 Tunnel category C: Restriction for the carriage of dangerous goods which may lead to a very large explosion, a large explosion or a large toxic release; The following dangerous goods are considered to fulfil this criterion2: - the dangerous goods restricted in tunnel category B, and - the following dangerous goods: Class 1: Divisions 1.1, 1.2 and 1.5 (except compatibility groups A and L); and Division 1.3 (compatibility groups H and J); Class 7: UN Nos. 2977 and 2978. When the net explosive mass per transport unit is greater than 5000 kg: Class 1: Division 1.3 (compatibility groups C and G). When carried in tanks: Classification codes 2A, 2O, 3A and 3O, and classification codes containing the Class 2: letter T only or letter groups TC, TO and TOC Class 3: Packing group I for classification codes FC, FT1, FT2 and FTC; Class 6.1: Packing group I, except UN No. 1510 Class 8: Packing group I for classification codes CT1, CFT and COT. 2 The assessment is based on the intrinsic dangerous properties of the goods, the type of containment and the quantity carried. - 86 - Tunnel category D: Restriction for the carriage of dangerous goods which may lead to a very large explosion, to a large explosion, to a large toxic release or to a large fire; The following dangerous goods are considered to fulfil this criterion2: - the dangerous goods restricted in tunnel category C, and - the following dangerous goods: Class 1: Class 2: Class 4.1: Division 1.3 (compatibility groups C and G); Classification codes F, FC, T, TF, TC, TO, TFC and TOC; Self-reactive substances, types C, D, E and F; and UN Nos. 2956, 3241, 3242 and 3251; Class 5.2: Organic peroxides, types C, D, E and F; Class 6.1: Packing group I for classification codes TF1, TFC and TFW; and Toxic by inhalation entries for which special provision 354 is assigned in column (6) of Table A of Chapter 3.2 and toxic by inhalation entries of UN Nos. 3381 to 3390; Class 8: Packing group I for classification codes CT1, CFT and COT and UN No. 3507; Class 9: Classification codes M9 and M10. When carried in bulk or in tanks: Class 3 Class 4.2: Packing group II; Class 4.3: Packing group II; Class 6.1: Packing group II; and Packing group III for classification code TF2; Class 8: Packing group I for classification codes CF1, CFT and CW1; and Packing group II for classification codes CF1 and CFT Class 9: Classification codes M2 and M3. Tunnel category E: Restriction for the carriage of all dangerous goods other than UN Nos. 2919, 3291, 3331, 3359 and 3373 and for all dangerous goods in accordance with the provisions of Chapter 3.4 if the quantities carried exceed 8 tonnes total gross mass per transport unit. NOTE: For the dangerous goods assigned to UN Nos. 2919 and 3331, restrictions to the passage through tunnels may, however, be part of the special arrangement approved by the competent authority(ies) on the basis of 1.7.4.2. 1.9.5.3 Provisions for road signs and notification of restrictions 1.9.5.3.1 Contracting Parties shall indicate tunnel prohibitions and alternative routes by means of signs and signals. 1.9.5.3.2 For this purpose, they may use signs C, 3h and D, 10a, 10b and 10c and signals according to the Vienna Convention on Road Signs and Signals (Vienna, 1968) and the European Agreement supplementing the Convention on Road Signs and Signals (Geneva, 1971) as interpreted by the Resolution on Road Signs and Signals (R.E.2) of the UNECE Inland Transport Committee Principal Working Party on Road Transport, as amended. 1.9.5.3.3 In order to facilitate international understanding of signs, the system of signs and signals prescribed in the Vienna Convention is based on the use of shapes, and colours characteristic of each class of signs and wherever possible, on the use of graphic symbols rather than inscriptions. Where Contracting Parties consider it necessary to modify the signs and symbols prescribed, the modifications made shall not alter their essential characteristics. Where Contracting Parties do not apply the Vienna 2 The assessment is based on the intrinsic dangerous properties of the goods, the type of containment and the quantity carried. - 87 - Convention, the prescribed signs and symbols may be modified, provided that the modifications made shall not alter their essential intent. 1.9.5.3.4 Traffic signs and signals intended to prohibit access of vehicles carrying dangerous goods to road tunnels shall be affixed at a place where the choice of alternative routes is possible. 1.9.5.3.5 When access to tunnels is restricted or alternative routes are prescribed, the signs shall be displayed with additional panels as follows: No sign: no restriction Sign with additional panel bearing the letter B: applies to vehicles carrying dangerous goods not allowed in tunnels of category B; Sign with additional panel bearing the letter C: applies to vehicles carrying dangerous goods not allowed in tunnels of category C; Sign with additional panel bearing the letter D: applies to vehicles carrying dangerous goods not allowed in tunnels of category D; Sign with additional panel bearing the letter E: applies to vehicles carrying dangerous goods not allowed in tunnels of category E. 1.9.5.3.6 Tunnel restrictions shall apply to transport units for which an orange-coloured plate marking in accordance with 5.3.2 is required, except for the carriage of dangerous goods for which ‘(-)’ is marked in Column (15) of Table A of Chapter 3.2. For the dangerous goods assigned to UN Nos. 2919 and 3331, restrictions to the passage through tunnels may, however, be part of the special arrangement approved by the competent authority(ies) on the basis of 1.7.4.2. For tunnels of category E, they shall apply also to transport units for which a marking in accordance with 3.4.13 is required or carrying containers for which a marking in accordance with 3.4.13 is required. Tunnel restrictions shall not apply when dangerous goods are carried in accordance with 1.1.3, except when transport units carrying such goods are marked in accordance with 3.4.13 subject to 3.4.143. 1.9.5.3.7 Restrictions shall be published officially and made publicly available. Contracting Parties shall notify the secretariat of UNECE of such restrictions and the secretariat shall make this information publicly available on its website. 1.9.5.3.8 When Contracting Parties apply specific operating measures designed to reduce the risks and related to some or all vehicles using tunnels, such as declaration before entering or passage in convoys escorted by accompanying vehicles, such operating measures shall be published officially and made publicly available. 3 or in accordance with 3.4.10 subject to 3.4.11 of ADR as applicable until 31 December 2010 if the transitional measures of 1.6.1.20 are applied. - 88 - CHAPTER 1.10 SECURITY PROVISIONS NOTE: For the purposes of this Chapter, security means measures or precautions to be taken to minimise theft or misuse of dangerous goods that may endanger persons, property or the environment. 1.10.1 General provisions 1.10.1.1 All persons engaged in the carriage of dangerous goods shall consider the security requirements set out in this Chapter commensurate with their responsibilities. 1.10.1.2 Dangerous goods shall only be offered for carriage to carriers that have been appropriately identified. 1.10.1.3 Areas within temporary storage terminals, temporary storage sites, vehicle depots, berthing areas and marshalling yards used for the temporary storage during carriage of dangerous goods shall be properly secured, well lit and, where possible and appropriate, not accessible to the general public. 1.10.1.4 Each member of a vehicle crew shall carry with them means of identification, which includes their photograph, during carriage of dangerous goods. 1.10.1.5 Safety inspections in accordance with 1.8.1 and 7.5.1.1 shall cover appropriate security measures. 1.10.1.6 The competent authority shall maintain up-to-date registers of all valid training certificates for drivers stipulated in 8.2.1 issued by it or by any recognized organization. 1.10.2 Security training 1.10.2.1 The training and the refresher training specified in Chapter 1.3 shall also include elements of security awareness. The security refresher training need not be linked to regulatory changes only. 1.10.2.2 Security awareness training shall address the nature of security risks, recognising security risks, methods to address and reduce such risks and actions to be taken in the event of a security breach. It shall include awareness of security plans (if appropriate) commensurate with the responsibilities and duties of individuals and their part in implementing security plans. 1.10.2.3 Such training shall be provided or verified upon employment in a position involving dangerous goods transport and shall be periodically supplemented with refresher training. 1.10.2.4 Records of all security training received shall be kept by the employer and made available to the employee or competent authority, upon request. Records shall be kept by the employer for a period of time established by the competent authority. 1.10.3 Provisions for high consequence dangerous goods 1.10.3.1 Definition of high consequence dangerous goods 1.10.3.1.1 High consequence dangerous goods are those which have the potential for misuse in a terrorist event and which may, as a result, produce serious consequences such as mass casualties, mass destruction or, particularly for Class 7, mass socio-economic disruption. 1.10.3.1.2 High consequence dangerous goods in classes other than Class 7 are those listed in Table 1.10.3.1.2 below and carried in quantities greater than those indicated therein. - 89 - Table 1.10.3.1.2: List of high consequence dangerous goods Class 1 Division 1.1 1.2 1.3 1.4 1.5 2 3 4.1 4.2 4.3 5.1 6.1 6.2 8 a b c d Substance or article Explosives Explosives Compatibility group C explosives Explosives of UN Nos. 0104, 0237, 0255, 0267, 0289, 0361, 0365, 0366, 0440, 0441, 0455, 0456 and 0500 Explosives Flammable gases (classification codes including only the letter F) Toxic gases (classification codes including letters T, TF, TC, TO, TFC or TOC) excluding aerosols Flammable liquids of packing groups I and II Desensitized explosives Desensitized explosives Packing group I substances Packing group I substances Oxidizing liquids of packing group I Perchlorates, ammonium nitrate, ammonium nitrate fertilisers and ammonium nitrate emulsions or suspensions or gels Toxic substances of packing group I Infectious substances of Category A (UN Nos. 2814 and 2900, except for animal material) Corrosive substances of packing group I Tank (l) c Quantity Bulk (kg) d a a a a a a a a 0 3000 a 0 a b 0 a 0 3000 0 a b a a a 0 0 3000 3000 3000 3000 a b a b a b 3000 b 0 a a 0 0 0 3000 a b Packages (kg) 0 0 0 0 Not relevant. The provisions of 1.10.3 do not apply, whatever the quantity is. A value indicated in this column is applicable only if carriage in tanks is authorized, in accordance with Chapter 3.2, Table A, column (10) or (12). For substances that are not authorized for carriage in tanks, the instruction in this column is not relevant. A value indicated in this column is applicable only if carriage in bulk is authorized, in accordance with Chapter 3.2, Table A, column (10) or (17). For substances that are not authorized for carriage in bulk, the instruction in this column is not relevant. - 90 - 1.10.3.1.3 For dangerous goods of Class 7, high consequence radioactive material is that with an activity equal to or greater than a transport security threshold of 3 000 A2 per single package (see also 2.2.7.2.2.1) except for the following radionuclides where the transport security threshold is given in Table 1.10.3.1.3 below. Table 1.10.3.1.3: Transport security thresholds for specific radionuclides 1.10.3.1.4 Element Radionuclide Americium Gold Cadmium Californium Curium Cobalt Cobalt Caesium Iron Germanium Gadolinium Iridium Nickel Palladium Promethium Polonium Plutonium Plutonium Radium Ruthenium Selenium Strontium Thallium Thulium Ytterbium Am-241 Au-198 Cd-109 Cf-252 Cm-244 Co-57 Co-60 Cs-137 Fe-55 Ge-68 Gd-153 Ir-192 Ni-63 Pd-103 Pm-147 Po-210 Pu-238 Pu-239 Ra-226 Ru-106 Se-75 Sr-90 Tl-204 Tm-170 Yb-169 Transport security threshold (TBq) 0.6 2 200 0.2 0.5 7 0.3 1 8000 7 10 0.8 600 900 400 0.6 0.6 0.6 0.4 3 2 10 200 200 3 For mixtures of radionuclides, determination of whether or not the transport security threshold has been met or exceeded can be calculated by summing the ratios of activity present for each radionuclide divided by the transport security threshold for that radionuclide. If the sum of the fractions is less than 1, then the radioactivity threshold for the mixture has not been met nor exceeded. This calculation can be made with the formula: Ai  T 1 i i Where: Ai = activity of radionuclide i that is present in a package (TBq) Ti = transport security threshold for radionuclide i (TBq). 1.10.3.1.5 When radioactive material possesses subsidiary risks of other classes, the criteria of table 1.10.3.1.2 shall also be taken into account (see also 1.7.5). - 91 - 1.10.3.2 Security plans 1.10.3.2.1 Carriers, consignors and other participants specified in 1.4.2 and 1.4.3 engaged in the carriage of high consequence dangerous goods (see Table 1.10.3.1.2) or high consequence radioactive material (see 1.10.3.1.3) shall adopt, implement and comply with a security plan that addresses at least the elements specified in 1.10.3.2.2. 1.10.3.2.2 The security plan shall comprise at least the following elements: (a) Specific allocation of responsibilities for security to competent and qualified persons with appropriate authority to carry out their responsibilities; (b) Records of dangerous goods or types of dangerous goods concerned; (c) Review of current operations and assessment of security risks, including any stops necessary to the transport operation, the keeping of dangerous goods in the vehicle, tank or container before, during and after the journey and the intermediate temporary storage of dangerous goods during the course of intermodal transfer or transhipment between units as appropriate; (d) Clear statement of measures that are to be taken to reduce security risks, commensurate with the responsibilities and duties of the participant, including: - training; - security policies (e.g. response to higher threat conditions, new employee/employment verification, etc.); - operating practices (e.g. choice/use of routes where known, access to dangerous goods in intermediate temporary storage (as defined in (c)), proximity to vulnerable infrastructure etc.); - equipment and resources that are to be used to reduce security risks; (e) Effective and up to date procedures for reporting and dealing with security threats, breaches of security or security incidents; (f) Procedures for the evaluation and testing of security plans and procedures for periodic review and update of the plans; (g) Measures to ensure the physical security of transport information contained in the security plan; and (h) Measures to ensure that the distribution of information relating to the transport operation contained in the security plan is limited to those who need to have it. Such measures shall not preclude the provision of information required elsewhere in ADR. NOTE: Carriers, consignors and consignees should co-operate with each other and with competent authorities to exchange threat information, apply appropriate security measures and respond to security incidents. 1.10.3.3 Devices, equipment or arrangements to prevent the theft of the vehicle carrying high consequence dangerous goods (see Table 1.10.3.1.2) or high consequence radioactive material (see 1.10.3.1.3) and its cargo, shall be applied and measures taken to ensure that these are operational and effective at all times. The application of these protective measures shall not jeopardize emergency response. NOTE: When appropriate and already fitted, the use of transport telemetry or other tracking methods or devices should be used to monitor the movement of high consequence dangerous goods (see Table 1.10.3.1.2) or high consequence radioactive material (see 1.10.3.1.3). 1.10.4 In accordance with the provisions of 1.1.3.6, the requirements of 1.10.1, 1.10.2, 1.10.3 and 8.1.2.1 (d) do not apply when the quantities carried in packages on a transport unit do not exceed those referred to in 1.1.3.6.3, except for UN Nos. 0029, 0030, 0059, 0065, 0073, 0104, 0237, 0255, 0267, 0288, 0289, 0290, 0360, 0361, 0364, 0365, 0366, 0439, 0440, 0441, 0455, 0456 and 0500 and except for UN Nos. 2910 and 2911 if the activity level exceeds the A2 value (see first indent of 1.1.3.6.2). In addition, the requirements of 1.10.1, 1.10.2, 1.10.3 and 8.1.2.1 (d) do not apply when the quantities - 92 - carried in tanks or in bulk on a transport unit do not exceed those referred to in 1.1.3.6.3. In addition the provisions of this Chapter do not apply to the carriage of UN No. 2912 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I) and UN No. 2913 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I). 1.10.5 1 2 For radioactive material, the provisions of this Chapter are deemed to be complied with when the provisions of the Convention on Physical Protection of Nuclear Material1 and the IAEA circular on "The Physical Protection of Nuclear Material and Nuclear Facilities"2 are applied. INFCIRC/274/Rev.1, IAEA, Vienna (1980). INFCIRC/225/Rev.4 (Corrected), IAEA, Vienna (1999). - 93 - PART 2 Classification CHAPTER 2.1 GENERAL PROVISIONS 2.1.1 Introduction 2.1.1.1 The classes of dangerous goods according to ADR are the following: Class 1 Class 2 Class 3 Class 4.1 Class 4.2 Class 4.3 Class 5.1 Class 5.2 Class 6.1 Class 6.2 Class 7 Class 8 Class 9 2.1.1.2 Explosive substances and articles Gases Flammable liquids Flammable solids, self-reactive substances and solid desensitized explosives Substances liable to spontaneous combustion Substances which, in contact with water, emit flammable gases Oxidizing substances Organic peroxides Toxic substances Infectious substances Radioactive material Corrosive substances Miscellaneous dangerous substances and articles Each entry in the different classes has been assigned a UN number. The following types of entries are used: A. Single entries for well defined substances or articles including entries for substances covering several isomers, e.g.: UN No. 1090 ACETONE UN No. 1104 AMYL ACETATES UN No. 1194 ETHYL NITRITE SOLUTION B. Generic entries for a well defined group of substances or articles, which are not n.o.s. entries, e.g.: UN No. 1133 ADHESIVES UN No. 1266 PERFUMERY PRODUCTS UN No. 2757 CARBAMATE PESTICIDE, SOLID, TOXIC UN No. 3101 ORGANIC PEROXIDE TYPE B, LIQUID C. Specific n.o.s. entries covering a group of substances or articles of a particular chemical or technical nature, not otherwise specified, e.g.: UN No. 1477 NITRATES, INORGANIC, N.O.S. UN No. 1987 ALCOHOLS, N.O.S. D. General n.o.s. entries covering a group of substances or articles having one or more dangerous properties, not otherwise specified, e.g.: UN No. 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. UN No. 1993 FLAMMABLE LIQUID, N.O.S. The entries defined under B., C. and D. are defined as collective entries. 2.1.1.3 For packing purposes, substances other than those of Classes 1, 2, 5.2, 6.2 and 7, and other than selfreactive substances of Class 4.1 are assigned to packing groups in accordance with the degree of danger they present: Packing group I: Substances presenting high danger; Packing group II: Substances presenting medium danger; Packing group III: Substances presenting low danger. - 97 - The packing group(s) to which a substance is assigned is (are) indicated in Table A of Chapter 3.2. Articles are not assigned to packing groups. For packing purposes any requirement for a specific packaging performance level is set out in the applicable packing instruction. 2.1.2 Principles of classification 2.1.2.1 The dangerous goods covered by the heading of a class are defined on the basis of their properties according to sub-section 2.2.x.1 of the relevant class. Assignment of dangerous goods to a class and a packing group is made according to the criteria mentioned in the same sub-section 2.2.x.1. Assignment of one or several subsidiary risk(s) to a dangerous substance or article is made according to the criteria of the class or classes corresponding to those risks, as mentioned in the appropriate subsection(s) 2.2.x.1. 2.1.2.2 All dangerous goods entries are listed in Table A of Chapter 3.2 in the numerical order of their UN Number. This table contains relevant information on the goods listed, such as name, class, packing group(s), label(s) to be affixed, packing and carriage provisions1. 2.1.2.3 A substance may contain technical impurities (for example those deriving from the production process) or additives for stability or other purposes that do not affect their classification. However, a substance mentioned by name, i.e. listed as a single entry in Table A of Chapter 3.2, containing technical impurities or additives for stability or other purposes affecting its classification shall be considered a solution or mixture (see 2.1.3.3). 2.1.2.4 Dangerous goods which are listed or defined in sub-section 2.2.x.2 of each class are not to be accepted for carriage. 2.1.2.5 Goods not mentioned by name, i.e. goods not listed as single entries in Table A of Chapter 3.2 and not listed or defined in one of the above-mentioned sub-sections 2.2.x.2 shall be assigned to the relevant class in accordance with the procedure of section 2.1.3. In addition, the subsidiary risk (if any) and the packing group (if any) shall be determined. Once the class, subsidiary risk (if any) and packing group (if any) have been established the relevant UN number shall be determined. The decision trees in subsections 2.2.x.3 (list of collective entries) at the end of each class indicate the relevant parameters for selecting the relevant collective entry (UN number). In all cases the most specific collective entry covering the properties of the substance or article shall be selected, according to the hierarchy indicated in 2.1.1.2 by the letters B, C and D respectively. If the substance or article cannot be classified under entries of type B or C according to 2.1.1.2, then, and only then shall it be classified under an entry of type D. 2.1.2.6 On the basis of the test procedures of Chapter 2.3 and the criteria set out in sub-sections 2.2.x.1 of classes when it is so specified, it may be determined that a substance, solution or mixture of a certain class, mentioned by name in Table A of Chapter 3.2, does not meet the criteria of that class. In such a case, the substance, solution or mixture is deemed not to belong to that class. 2.1.2.7 For the purposes of classification, substances with a melting point or initial melting point of 20 °C or lower at a pressure of 101.3 kPa shall be considered to be liquids. A viscous substance for which a specific melting point cannot be determined shall be subjected to the ASTM D 4359-90 test or to the test for determining fluidity (penetrometer test) prescribed in 2.3.4. Note by the Secretariat: An alphabetic list of these entries has been prepared by the secretariat and is reproduced in Table B of Chapter 3.2. This table is not an official part of the ADR. 1 - 98 - 2.1.3 Classification of substances, including solutions and mixtures (such as preparations and wastes), not mentioned by name 2.1.3.1 Substances including solutions and mixtures not mentioned by name shall be classified according to their degree of danger on the basis of the criteria mentioned in sub-section 2.2.x.1 of the various classes. The danger(s) presented by a substance shall be determined on the basis of its physical and chemical characteristics and physiological properties. Such characteristics and properties shall also be taken into account when such experience leads to a more stringent assignment. 2.1.3.2 A substance not mentioned by name in Table A of Chapter 3.2 presenting a single hazard shall be classified in the relevant class under a collective entry listed in sub-section 2.2.x.3 of that class. 2.1.3.3 A solution or mixture meeting the classification criteria of ADR composed of a single predominant substance mentioned by name in Table A of Chapter 3.2 and one or more substances not subject to ADR or traces of one or more substances mentioned by name in Table A of Chapter 3.2, shall be assigned the UN number and proper shipping name of the predominant substance mentioned by name in Table A of Chapter 3.2 unless: (a) The solution or mixture is mentioned by name in Table A of Chapter 3.2; (b) The name and description of the substance mentioned by name in Table A of Chapter 3.2 specifically indicate that they apply only to the pure substance; (c) The class, classification code, packing group, or physical state of the solution or mixture is different from that of the substance mentioned by name in Table A of Chapter 3.2; or (d) The hazard characteristics and properties of the solution or mixture necessitate emergency response measures that are different from those required for the substance mentioned by name in Table A of Chapter 3.2. In those other cases, except the one described in (a), the solution or mixture shall be classified as a substance not mentioned by name in the relevant class under a collective entry listed in sub-section 2.2.x.3 of that class taking account of the subsidiary risks presented by that solution or mixture, if any, unless the solution or mixture does not meet the criteria of any class, in which case it is not subject to ADR. 2.1.3.4 Solutions and mixtures containing substances belonging to one of the entries mentioned in 2.1.3.4.1 or 2.1.3.4.2 shall be classified in accordance with the provisions of these paragraphs. 2.1.3.4.1 Solutions and mixtures containing one of the following substances mentioned by name shall always be classified under the same entry as the substance they contain, provided they do not have the hazard characteristics as indicated in 2.1.3.5.3: - Class 3 UN No. 1921 PROPYLENEIMINE, STABILIZED; UN No. 3064 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin; - Class 6.1 UN No. 1051 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water; UN No. 1185 ETHYLENEIMINE, STABILIZED; UN No. 1259 NICKEL CARBONYL; UN No. 1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION), with not more than 20% hydrogen cyanide; UN No. 1614 HYDROGEN CYANIDE, STABILIZED, containing not more than 3% water and absorbed in a porous inert material; UN No. 1994 IRON PENTACARBONYL; UN No. 2480 METHYL ISOCYANATE; UN No. 2481 ETHYL ISOCYANATE; UN No. 3294 HYDROGEN CYANIDE, SOLUTION IN ALCOHOL, with not more than 45% hydrogen cyanide; - 99 - - Class 8 UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS; UN No. 1744 BROMINE or UN No. 1744 BROMINE SOLUTION; UN No. 1790 HYDROFLUORIC ACID with more than 85% hydrogen fluoride; UN No. 2576 PHOSPHORUS OXYBROMIDE, MOLTEN; 2.1.3.4.2 Solutions and mixtures containing a substance belonging to one of the following entries of Class 9: UN No. 2315 POLYCHLORINATED BIPHENYLS, LIQUID; UN No. 3151 POLYHALOGENATED BIPHENYLS, LIQUID; UN No. 3151 POLYHALOGENATED TERPHENYLS, LIQUID; UN No. 3152 POLYHALOGENATED BIPHENYLS, SOLID; UN No. 3152 POLYHALOGENATED TERPHENYLS, SOLID; or UN No. 3432 POLYCHLORINATED BIPHENYLS, SOLID shall always be classified under the same entry of Class 9 provided that: - they do not contain any additional dangerous component other than components of packing group III of classes 3, 4.1, 4.2, 4.3, 5.1, 6.1 or 8; and - they do not have the hazard characteristics as indicated in 2.1.3.5.3. 2.1.3.5 Substances not mentioned by name in Table A of Chapter 3.2, having more than one hazard characteristic and solutions or mixtures meeting the classification criteria of ADR containing several dangerous substances shall be classified under a collective entry (see 2.1.2.5) and packing group of the appropriate class in accordance with their hazard characteristics. Such classification according to the hazard characteristics shall be carried out as follows: 2.1.3.5.1 The physical and chemical characteristics and physiological properties shall be determined by measurement or calculation and the substance, solution or mixture shall be classified according to the criteria mentioned in sub-section 2.2.x.1 of the various classes. 2.1.3.5.2 If this determination is not possible without disproportionate cost or effort (as for some kinds of wastes), the substance, solution or mixture shall be classified in the class of the component presenting the major hazard. 2.1.3.5.3 If the hazard characteristics of the substance, solution or mixture fall within more than one class or group of substances listed below then the substance, solution or mixture shall be classified in the class or group of substances corresponding to the major hazard on the basis of the following order of precedence: (a) Material of Class 7 (apart from radioactive material in excepted packages for which, except for UN 3507 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE, special provision 290 of Chapter 3.3 applies , where the other hazardous properties take precedence); (b) Substances of Class 1; (c) Substances of Class 2; (d) Liquid desensitized explosives of Class 3; (e) Self-reactive substances and solid desensitized explosives of Class 4.1; (f) Pyrophoric substances of Class 4.2; (g) Substances of Class 5.2; - 100 - (h) Substances of Class 6.1 meeting the inhalation toxicity criteria of packing group I (Substances meeting the classification criteria of Class 8 and having an inhalation toxicity of dust and mist (LC50) in the range of Packing group I and a toxicity through oral ingestion or dermal contact only in the range of Packing group III or less, shall be allocated to Class 8); (i) Infectious substances of Class 6.2. 2.1.3.5.4 If the hazard characteristics of the substance fall within more than one class or group of substances not listed in 2.1.3.5.3 above, the substance shall be classified in accordance with the same procedure but the relevant class shall be selected according to the precedence of hazards table in 2.1.3.10. 2.1.3.5.5 If the substance to be carried is a waste, with a composition that is not precisely known, its assignment to a UN number and packing group in accordance with 2.1.3.5.2 may be based on the consignor’s knowledge of the waste, including all available technical and safety data as requested by safety and environmental legislation in force2. In case of doubt, the highest danger level shall be taken. If however, on the basis of the knowledge of the composition of the waste and the physical and chemical properties of the identified components, it is possible to demonstrate that the properties of the waste do not correspond to the properties of the packing group I level, the waste may be classified by default in the most appropriate n.o.s. entry of packing group II. However, if it is known that the waste possesses only environmentally hazardous properties, it may be assigned to packing group III under UN Nos. 3077 or 3082. This procedure may not be used for wastes containing substances mentioned in 2.1.3.5.3, substances of Class 4.3, substances of the case mentioned in 2.1.3.7 or substances which are not accepted for carriage in accordance with 2.2.x.2. 2.1.3.6 The most specific applicable collective entry (see 2.1.2.5) shall always be used, i.e. a general n.o.s. entry shall only be used if a generic entry or a specific n.o.s. entry cannot be used. 2.1.3.7 Solutions and mixtures of oxidizing substances or substances with an oxidizing subsidiary risk may have explosive properties. In such a case they are not to be accepted for carriage unless they meet the requirements for Class 1. 2.1.3.8 Substances of classes 1 to 6.2, 8 and 9, other than those assigned to UN Nos. 3077 and 3082, meeting the criteria of 2.2.9.1.10 are additionally to their hazards of classes 1 to 6.2, 8 and 9 considered to be environmentally hazardous substances. Other substances meeting the criteria of no other class, but those of 2.2.9.1.10 are to be assigned to UN Nos. 3077 and 3082 as appropriate. 2.1.3.9 Wastes that do not meet the criteria for classification in classes 1 to 9 but are covered by the Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal may be carried under UN Nos. 3077 or 3082. Such legislation is for instance the Commission Decision 2000/532/EC of 3 May 2000 replacing Decision 94/3/EC establishing a list of wastes pursuant to Article 1(a) of Council Directive 75/442/EEC on waste (replaced by the Directive 2006/12/EC of the European Parliament and of the Council (Official Journal of the European Union No. L 114 of 27 April 2006, page 9)) and Council Decision 94/904/EC establishing a list of hazardous wastes pursuant to Article 1(4) of Council Directive 91/689/EEC on hazardous wastes (Official Journal of the European Communities No. L 226 of 6 September 2000, page 3). 2 - 101 - - 102 - SOL LIQ 4.1 3, I SOL LIQ 4.1 3, I SOL LIQ 4.1 3, II SOL LIQ 4.1 3, II 3, I 3, II 3, III SOL LIQ 5.1, II 3, II SOL LIQ 5.1, I 3, I 5.1, III 5.1, II 4.3, II 4.3, I 5.1, II 4.2, II 4.1, II 4.1, II 4.3, III 4.3, II 4.3, I 4.2, III 4.2, II 4.1, III 4.1, II 8, I 5.1, I 8, II 5.1, II 8, I 6.1, III 8, III 8, III 8, III 8, II 6.1, II 6.1, II 6.1, II 6.1, I 6.1, I 5.1, III 5.1, II 5.1, I 4.3, III 4.3, II 4.3, I 4.2, III 8, II 8, I 6.1, II 6.1, II 6.1, II 6.1, I 6.1, I 6.1, II 6.1, I 5.1, III 5.1, II 5.1, I 4.3, III 4.3, II 4.3, I 4.2, III 4.2, II 4.1, III 4.1, II 3, III 3, II 3, I 9 8, II 8, I 6.1, III LIQ 8, III LIQ 8, II 4.2, II SOL 4.1, III SOL 4.1, II 3, III 3, II 3, I 8, III 6.1, I SOL LIQ SOL LIQ 6.1, I 8, I 6.1, II 8, II 8.1 SOL LIQ 6.1, II 8, II 5.1, III 8, I 5.1, I 8, II 4.3, II 4.3, I 8, II 4.2, II 8, II SOL LIQ 4.1, II 8, II 8, II 3, II 3, I 8, II 6.1, II DERMAL 6.1, II ORAL 6.1, II 5.1, I 5.1, II 8, I 8, I 4.3, I 8, I 8, I 8, I 8, I 8, I 8, I 3, I 8, I SOL LIQ 6.1, I 8, I 6.1, I 5.1, I 5.1, II 4.3, III 4.3, II 4.3, I 4.2, III 4.2, II SOL LIQ 4.1, III 6.1, III SOL LIQ 4.1, II 6.1, II 3, III a 3, II 3, I 6.1, III 6.1, II INHAL 6.1, I 5.1, III 5.1, I 5.1, I 6.1, II 4.3, II 4.3, I 6.1, II 4.2, II 6.1, II SOL LIQ 4.1, II 6.1, II 6.1, II 3, II 3, I 6.1, II SOL LIQ 6.1, I 8, I SOL LIQ 6.1, I 8, I 6.1, I 6.1, I 4.3, I 4.3, I 6.1, I 6.1, I 6.1, I 6.1, I 6.1, I 3, I 3, I 6.1, I ORAL 6.1, I DERMAL 6.1, I ORAL 5.1, I 5.1, II 6.1, I 6.1, I 6.1, I 6.1, I 6.1, I 6.1, I 6.1, I 6.1, I 3, I 3, I 6.1, I DERMAL 5.1, I Solid substances and mixtures Liquid substances, mixtures and solutions Dermal toxicity Oral toxicity Inhalation toxicity 5.1, I 4.3, III 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I SOL = LIQ = DERMAL = ORAL = INHAL = a Class 6.1 for pesticides SOL LIQ 5.1, II 3, II SOL LIQ 5.1, I 3, I 5.1, II SOL LIQ SOL LIQ SOL LIQ 5.1, I 3, I 5.1, II 3, II 5.1, III 3, III SOL LIQ 5.1, I 3, I SOL LIQ 5.1, I 3, I 5.1, I 4.3, II 4.3, III 4.3, II 4.3, III 4.3, II 4.3, III 4.3, II 4.3, I 4.3, III 5.1, I 4.3, II 4.3, II 4.3, II 4.3, II 4.3, II 4.3, II 4.3, I 4.3, II 4.3, I 4.3, I 4.3, I 4.2, III 4.2, III 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.2, II 4.1, III 4.2, II SOL LIQ 4.2 3, III SOL LIQ 4.2 3, II SOL LIQ 4.2 3, I 4.2, III 4.2, II 4.2, II SOL LIQ 4.2 3, II SOL LIQ 4.2 3, II SOL LIQ 4.2 3, I 4.2, II 4.1, II SOL LIQ 4.1 3, III SOL LIQ 4.1 3, II 4.1, III Table of precedence of hazards 4.1, II Class and packing group 2.1.3.10 NOTE 1: Examples to explain the use of the table Classification of a single substance Description of the substance to be classified: An amine not mentioned by name meeting the criteria for Class 3, packing group II as well as those for Class 8, packing group I. Procedure: The intersection of line 3 II with column 8 I gives 8 I. This amine has therefore to be classified in Class 8 under: UN No. 2734 AMINES LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or UN No. 2734 POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. packing group I Classification of a mixture Description of the mixture to be classified: Mixture consisting of a flammable liquid classified in Class 3, packing group III, a toxic substance in Class 6.1, packing group II and a corrosive substance in Class 8, packing group I. Procedure: The intersection of line 3 III with column 6.1 II gives 6.1 II. The intersection of line 6.1 II with column 8 I gives 8 I LIQ. This mixture not further defined has therefore to be classified in Class 8 under: UN No. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. packing group I. NOTE 2: Examples for the classification of mixtures and solutions under a class and a packing group: A phenol solution of Class 6.1, (II), in benzene of Class 3, (II) is to be classified in Class 3, (II); this solution is to be classified under UN No. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S., Class 3, (II), by virtue of the toxicity of the phenol. A solid mixture of sodium arsenate of Class 6.1, (II) and sodium hydroxide of Class 8, (II) is to be classified under UN No. 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S., in Class 6.1 (II). A solution of crude or refined naphthalene of Class 4.1, (III) in petrol of Class 3, (II), is to be classified under UN No. 3295 HYDROCARBONS, LIQUID, N.O.S. in Class 3, (II). A mixture of hydrocarbons of Class 3, (III), and of polychlorinated biphenyls (PCB) of Class 9, (II), is to be classified under UN No. 2315 POLYCHLORINATED BIPHENYLS LIQUID or UN No. 3432 POLYCHLORINATED BIPHENYLS SOLID in Class 9, (II). A mixture of propyleneimine of Class 3, and polychlorinated biphenyls (PCB) of Class 9, (II), is to be classified under UN No. 1921 PROPYLENEIMINE, INHIBITED in Class 3. 2.1.4 Classification of samples 2.1.4.1 When the class of a substance is uncertain and it is being carried for further testing, a tentative class, proper shipping name and UN number shall be assigned on the basis of the consignor's knowledge of the substance and application of: (a) the classification criteria of Chapter 2.2; and (b) the requirements of this Chapter. The most severe packing group possible for the proper shipping name chosen shall be used. - 103 - Where this provision is used the proper shipping name shall be supplemented with the word "SAMPLE" (e.g., "FLAMMABLE LIQUID, N.O.S., SAMPLE"). In certain instances, where a specific proper shipping name is provided for a sample of a substance considered to meet certain classification criteria (e.g., GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, UN No. 3167) that proper shipping name shall be used. When an N.O.S. entry is used to carry the sample, the proper shipping name need not be supplemented with the technical name as required by special provision 274 of Chapter 3.3. 2.1.4.2 2.1.5 Samples of the substance shall be carried in accordance with the requirements applicable to the tentative assigned proper shipping name provided: (a) The substance is not considered to be a substance not accepted for carriage by sub-sections 2.2.x.2 of Chapter 2.2 or by Chapter 3.2; (b) The substance is not considered to meet the criteria for Class 1 or considered to be an infectious substance or a radioactive material; (c) The substance is in compliance with 2.2.41.1.15 or 2.2.52.1.9 if it is a self-reactive substance or an organic peroxide, respectively; (d) The sample is carried in a combination packaging with a net mass per package not exceeding 2.5 kg; and (e) The sample is not packed together with other goods. Classification of packagings, discarded, empty, uncleaned Empty uncleaned packagings, large packagings or IBCs, or parts thereof, carried for disposal, recycling or recovery of their material, other than reconditioning, repair, routine maintenance, remanufacturing or reuse, may be assigned to UN 3509 if they meet the requirements for this entry. - 104 - CHAPTER 2.2 CLASS SPECIFIC PROVISIONS 2.2.1 Class 1 2.2.1.1 Criteria 2.2.1.1.1 The heading of Class 1 covers: (a) Explosive substances and articles Explosive substances: solid or liquid substances (or mixtures of substances) capable by chemical reaction of producing gases at such a temperature and pressure and at such a speed as to cause damage to the surroundings. Pyrotechnic substances: substances or mixtures of substances designed to produce an effect by heat, light, sound, gas or smoke or a combination of these as the result of non-detonating self-sustaining exothermic chemical reactions; NOTE 1: Substances which are not themselves explosive but which may form an explosive mixture of gas, vapour or dust are not substances of Class 1. NOTE 2: Also excluded from Class 1 are: water- or alcohol-wetted explosives of which the water or alcohol content exceeds the limits specified and those containing plasticizers - these explosives are assigned to Class 3 or Class 4.1 - and those explosives which, on the basis of their predominant hazard, are assigned to Class 5.2. (b) Explosive articles: articles containing one or more explosive or pyrotechnic substances; NOTE: Devices containing explosive or pyrotechnic substances in such small quantity or of such a character that their inadvertent or accidental ignition or initiation during carriage would not cause any manifestation external to the device by projection, fire, smoke, heat or loud noise are not subject to the requirements of Class 1. (c) Substances and articles not mentioned above which are manufactured with a view to producing a practical effect by explosion or a pyrotechnic effect. For the purposes of Class 1, the following definition applies: Phlegmatized means that a substance (or "phlegmatizer") has been added to an explosive to enhance its safety in handling and carriage. The phlegmatizer renders the explosive insensitive, or less sensitive, to the following actions: heat, shock, impact, percussion or friction. Typical phlegmatizing agents include, but are not limited to: wax, paper, water, polymers (such as chlorofluoropolymers), alcohol and oils (such as petroleum jelly and paraffin). 2.2.1.1.2 Any substance or article having or suspected of having explosive properties shall be considered for assignment to Class 1 in accordance with the tests, procedures and criteria prescribed in Part I, Manual of Tests and Criteria. A substance or article assigned to Class 1 can only be accepted for carriage when it has been assigned to a name or n.o.s. entry listed in Table A of Chapter 3.2 and meets the criteria of the Manual of Tests and Criteria. 2.2.1.1.3 The substances and articles of Class 1 shall be assigned to a UN Number and a name or n.o.s. entry listed in Table A of Chapter 3.2. Interpretation of the names of substances and articles in Table A of Chapter 3.2 shall be based upon the glossary in 2.2.1.4. Samples of new or existing explosive substances or articles carried for purposes including: testing, classification, research and development quality control, or as a commercial sample, other than initiating explosive, may be assigned to UN No. 0190 SAMPLES, EXPLOSIVE. - 105 - The assignment of explosive substances and articles not mentioned by name as such in Table A of Chapter 3.2 to an n.o.s entry of Class 1 or UN No. 0190 SAMPLES, EXPLOSIVE as well as the assignment of certain substances the carriage of which is subject to a specific authorization by the competent authority according to the special provisions referred to in Column (6) of Table A of Chapter 3.2 shall be made by the competent authority of the country of origin. This competent authority shall also approve in writing the conditions of carriage of these substances and articles. If the country of origin is not a Contracting Party to ADR, the classification and the conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. 2.2.1.1.4 Substances and articles of Class 1 shall have been assigned to a division in accordance with 2.2.1.1.5 and to a compatibility group in accordance with 2.2.1.1.6. The division shall be based on the results of the tests described in 2.3.0 and 2.3.1 applying the definitions in 2.2.1.1.5. The compatibility group shall be determined in accordance with the definitions in 2.2.1.1.6. The classification code shall consist of the division number and the compatibility group letter. 2.2.1.1.5 Definition of divisions Division 1.1 Substances and articles which have a mass explosion hazard (a mass explosion is an explosion which affects almost the entire load virtually instantaneously). Division 1.2 Substances and articles which have a projection hazard but not a mass explosion hazard. Division 1.3 Substances and articles which have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but not a mass explosion hazard: (a) combustion of which gives rise to considerable radiant heat; or (b) which burn one after another, producing minor blast or projection effects or both. Division 1.4 Substances and articles which present only a slight risk of explosion in the event of ignition or initiation during carriage. The effects are largely confined to the package and no projection of fragments of appreciable size or range is to be expected. An external fire shall not cause virtually instantaneous explosion of almost the entire contents of the package. Division 1.5 Very insensitive substances having a mass explosion hazard which are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of carriage. As a minimum requirement they must not explode in the external fire test. Division 1.6 Extremely insensitive articles which do not have a mass explosion hazard. The articles contain only extremely insensitive substances and demonstrate a negligible probability of accidental initiation or propagation. NOTE: The risk from articles of Division 1.6 is limited to the explosion of a single article. 2.2.1.1.6 Definition of compatibility groups of substances and articles A Primary explosive substance. B Article containing a primary explosive substance and not having two or more effective protective features. Some articles, such as detonators for blasting, detonator assemblies for blasting and primers, cap-type, are included, even though they do not contain primary explosives. C Propellant explosive substance or other deflagrating explosive substance or article containing such explosive substance. - 106 - D Secondary detonating explosive substance or black powder or article containing a secondary detonating explosive substance, in each case without means of initiation and without a propelling charge, or article containing a primary explosive substance and having two or more effective protective features. E Article containing a secondary detonating explosive substance, without means of initiation, with a propelling charge (other than one containing a flammable liquid or gel or hypergolic liquids). F Article containing a secondary detonating explosive substance with its own means of initiation, with a propelling charge (other than one containing a flammable liquid or gel or hypergolic liquids) or without a propelling charge. G Pyrotechnic substance, or article containing a pyrotechnic substance, or article containing both an explosive substance and an illuminating, incendiary, tear- or smoke-producing substance (other than a water-activated article or one which contains white phosphorus, phosphides, a pyrophoric substance, a flammable liquid or gel or hypergolic liquids). H Article containing both an explosive substance and white phosphorus. J Article containing both an explosive substance and a flammable liquid or gel. K Article containing both an explosive substance and a toxic chemical agent. L Explosive substance or article containing an explosive substance and presenting a special risk (e.g. due to water activation or the presence of hypergolic liquids, phosphides or a pyrophoric substance) necessitating isolation of each type. N Articles containing only extremely insensitive substances. S Substance or article so packed or designed that any hazardous effects arising from accidental functioning are confined within the package unless the package has been degraded by fire, in which case all blast or projection effects are limited to the extent that they do not significantly hinder or prevent fire-fighting or other emergency response efforts in the immediate vicinity of the package. NOTE 1: Each substance or article, packed in a specified packaging, may be assigned to one compatibility group only. Since the criterion of compatibility group S is empirical, assignment to this group is necessarily linked to the tests for assignment of a classification code. NOTE 2: Articles of compatibility groups D and E may be fitted or packed together with their own means of initiation provided that such means have at least two effective protective features designed to prevent an explosion in the event of accidental functioning of the means of initiation. Such articles and packages shall be assigned to compatibility groups D or E. NOTE 3: Articles of compatibility groups D and E may be packed together with their own means of initiation, which do not have two effective protective features (i.e. means of initiation assigned to compatibility group B), provided that they comply with mixed packing provision MP21 of Section 4.1.10. Such packages shall be assigned to compatibility groups D or E. NOTE 4: Articles may be fitted or packed together with their own means of ignition provided that the means of ignition cannot function during normal conditions of carriage. NOTE 5: Articles of compatibility groups C, D and E may be packed together. Such packages shall be assigned to compatibility group E. 2.2.1.1.7 Assignment of fireworks to divisions 2.2.1.1.7.1 Fireworks shall normally be assigned to divisions 1.1, 1.2, 1.3, and 1.4 on the basis of test data derived from Test Series 6 of the Manual of Tests and Criteria. However, since the range of such articles is very extensive and the availability of test facilities may be limited, assignment to divisions may also be made in accordance with the procedure in 2.2.1.1.7.2. - 107 - 2.2.1.1.7.2 Assignment of fireworks to UN Nos. 0333, 0334, 0335 and 0336 may be made on the basis of analogy, without the need for Test Series 6 testing, in accordance with the default fireworks classification table in 2.2.1.1.7.5. Such assignment shall be made with the agreement of the competent authority. Items not specified in the table shall be classified on the basis of test data derived from Test Series 6. NOTE 1: The addition of other types of fireworks to column 1 of the table in 2.2.1.1.7.5 shall only be made on the basis of full test data submitted to the UN Sub-Committee of Experts on the Transport of Dangerous Goods for consideration. NOTE 2: Test data derived by competent authorities which validates, or contradicts the assignment of fireworks specified in column 4 of the table in 2.2.1.1.7.5 to divisions in column 5 should be submitted to the UN Sub-Committee of Experts on the Transport of Dangerous Goods for information. 2.2.1.1.7.3 Where fireworks of more than one division are packed in the same package, they shall be classified on the basis of the most dangerous division unless test data derived from Test Series 6 indicate otherwise. 2.2.1.1.7.4 The classification shown in the table in 2.2.1.1.7.5 applies only for articles packed in fibreboard boxes (4G). 2.2.1.1.7.5 Default fireworks classification table1 NOTE 1: References to percentages in the table, unless otherwise stated, are to the mass of all pyrotechnic substances (e.g. rocket motors, lifting charge, bursting charge and effect charge). NOTE 2: "Flash composition" in this table refers to pyrotechnic substances in powder form or as pyrotechnic units as presented in the firework that are used to produce an aural effect or used as a bursting charge, or propellant charge unless the time taken for the pressure rise is demonstrated to be more than 6 ms for 0.5 g of pyrotechnic substance in the HSL Flash Composition Test in Appendix 7 of the Manual of Tests and Criteria. NOTE 3: Dimensions in mm refer to: - for spherical and peanut shells the diameter of the sphere of the shell; for cylinder shells the length of the shell; for a shell in mortar, Roman candle, shot tube firework or mine the inside diameter of the tube comprising or containing the firework; for a bag mine or cylinder mine, the inside diameter of the mortar intended to contain the mine. This table contains a list of firework classifications which may be used in the absence of Test Series 6 data (see 2.2.1.1.7.2). 1 - 108 - - 109 - 1.1G 1.1G 1.3G 1.4G Colour shell:  180 mm Colour shell: < 180 mm with > 25% flash composition, as loose powder and/or report effects Colour shell: < 180 mm with  25% flash composition, as loose powder and/or report effects Colour shell:  50 mm, or  60 g pyrotechnic substance, with  2% flash composition as loose powder and/or report effects Device with two or more spherical aerial shells in a common wrapper propelled by the same propellant charge with separate external delay fuses Assembly comprising a spherical or cylindrical shell inside a mortar from which the shell is designed to be projected Peanut shell Preloaded mortar, shell in mortar 1.1G 1.1G 1.1G 1.2G 1.3G All report shells Colour shell:  180 mm Colour shell: > 25% flash composition as loose powder and/or report effects Colour shell: > 50 mm and < 180 mm Colour shell:  50 mm, or  60 g pyrotechnic substance, with  25% flash composition as loose powder and/or report effects The most hazardous spherical aerial shell determines the classification 1.1G All report shells Device with or without propellant charge, with delay fuse and bursting charge, pyrotechnic unit(s) or loose pyrotechnic substance and designed to be projected from a mortar Spherical display shell: aerial shell, colour shell, dye shell, multi-break shell, multi-effect shell, nautical shell, parachute shell, smoke shell, star shell; report shell: maroon, salute, sound shell, thunderclap, aerial shell kit Shell, spherical or cylindrical Classification Specification Definition Includes: / Synonym: Type - 110 - Battery/ combination (cont'd) Shell of shells (spherical) Shell, spherical or cylindrical Barrage, bombardos, cakes, finale box, flowerbed, hybrid, multiple tubes, shell cakes, banger batteries, flash banger batteries (Reference to percentages for shell of shells are to the gross mass of the fireworks article) Includes: / Synonym: Type > 200 mm and ≤ 300 mm Device without propellant charge, with delay fuse and bursting charge, containing colour shells ≤ 70mm and/or pyrotechnic units, with ≤ 25% flash composition and ≤ 60% pyrotechnic substance and designed to be projected from a mortar Assembly including several elements either containing the same type or several types each corresponding to one of the types of fireworks listed in this table, with one or two points of ignition 1.3G 1.3G 1.1G 1.3G 1.1G Classification The most hazardous firework type determines the classification ≤ 200 mm > 300 mm Device without propellant charge, with delay fuse and bursting charge, containing colour shells and/or pyrotechnic units and designed to be projected from a mortar Device with propellant charge, with delay fuse and bursting charge, containing colour shells ≤ 70 mm and/or pyrotechnic units, with ≤ 25% flash composition and ≤ 60% pyrotechnic substance and designed to be projected from a mortar ≤ 120 mm > 120 mm Specification Device without propellant charge, with delay fuse and bursting charge, containing report shells ≤ 25g flash composition per report unit, with ≤ 33% flash composition and  60% inert materials and designed to be projected from a mortar Device without propellant charge, with delay fuse and bursting charge, containing report shells and inert materials and designed to be projected from a mortar Definition - 111 - Single shot Roman candle, small preloaded mortar Shot tube Avalanche rocket, signal rocket, whistling rocket, bottle rocket, sky rocket, missile type rocket, table rocket Exhibition candle, candle, bombettes Roman candle Rocket Includes: / Synonym: Type Tube containing pyrotechnic substance and/or pyrotechnic units, equipped with stick(s) or other means for stabilization of flight, and designed to be propelled into the air Tube containing a pyrotechnic unit consisting of pyrotechnic substance, propellant charge with or without transmitting fuse Tube containing a series of pyrotechnic units consisting of alternate pyrotechnic substance, propellant charge, and transmitting fuse Definition 1.1G 1.1G 1.3G 1.4G Flash composition effects only Flash composition > 25% of the pyrotechnic substance > 20 g pyrotechnic substance and flash composition ≤ 25%  20 g pyrotechnic substance, black powder bursting charge and ≤ 0.13 g flash composition per report and ≤ 1 g in total 1.4G 1.4G  30 mm inner diameter, each pyrotechnic unit ≤ 25 g and ≤ 5% flash composition  30 mm inner diameter, pyrotechnic unit ≤ 25 g and ≤ 5% flash composition 1.3G < 50 mm inner diameter and ≤ 25% flash composition 1.3G 1.2G  50 mm inner diameter, containing no flash composition ≤ 30 mm inner diameter and pyrotechnic unit > 25 g, or > 5% and ≤ 25% flash composition 1.1G Classification  50 mm inner diameter, containing flash composition, or < 50 mm with > 25% flash composition Specification - 112 - Includes: / Synonym: Pot-a-feu, ground mine, bag mine, cylinder mine Volcanos, gerbs, showers, lances, Bengal fire, flitter sparkle, cylindrical fountains, cone fountains, illuminating torch Handheld sparklers, non-handheld sparklers, wire sparklers Dipped stick Type Mine Fountain Sparkler Bengal stick Non-metallic stick partially coated (along one end) with slow-burning pyrotechnic substance and designed to be held in the hand Rigid wire partially coated (along one end) with slow burning pyrotechnic substance with or without an ignition tip Non-metallic case containing pressed or consolidated pyrotechnic substance producing sparks and flame Cloth or paper bag or cloth or paper cylinder containing propellant charge and pyrotechnic units, designed to be placed in a mortar and to function as a mine Tube containing propellant charge and pyrotechnic units and designed to be placed on the ground or to be fixed in the ground. The principal effect is ejection of all the pyrotechnic units in a single burst producing a widely dispersed visual and/or aural effect in the air or: Definition 1.3G 1.4G  1 kg pyrotechnic substance < 1 kg pyrotechnic substance Nitrate based sparklers: ≤ 30 g per item Perchlorate based items: > 5 g per item or > 10 items per pack Perchlorate based items: ≤ 5 g per item and ≤ 10 items per pack; nitrate based items: ≤ 30 g per item 1.4G 1.3 G 1.4G 1.4G  150 g pyrotechnic substance, containing  5% flash composition as loose powder and/ or report effects. Each pyrotechnic unit  25 g, each report effect < 2g; each whistle, if any,  3 g Perchlorate based sparklers: ≤ 5 g per item and ≤ 10 items per pack; 1.3G < 180 mm and  25% flash composition, as loose powder and/ or report effects 1.3G 1.1G  180 mm and  25% flash composition, as loose powder and/ or report effects Perchlorate based sparklers: > 5 g per item or > 10 items per pack 1.1G Classification > 25% flash composition, as loose powder and/ or report effects Specification - 113 - Flying Saxon, UFO's, rising crown Aerial wheel Aerial spinner, helicopter, chaser, ground spinner Spinner Catherine wheels, Saxon Table bombs, throwdowns, crackling granules, smokes, fog, snakes, glow worm, serpents, snaps, party poppers Low hazard fireworks and novelties Wheels Includes: / Synonym: Type Tubes containing propellant charges and sparksflame- and/or noise producing pyrotechnic substances, the tubes being fixed to a supporting ring Assembly including drivers containing pyrotechnic substance and provided with a means of attaching it to a support so that it can rotate Non-metallic tube or tubes containing gas- or spark-producing pyrotechnic substance, with or without noise producing composition, with or without aerofoils attached Device designed to produce very limited visible and/ or audible effect which contains small amounts of pyrotechnic and/or explosive composition. Definition > 200 g total pyrotechnic substance or > 60 g pyrotechnic substance per driver,  3% flash composition as report effects, each whistle (if any)  25 g and ≤ 50 g whistle composition per wheel Throwdowns and snaps may contain up to 1.6 mg of silver fulminate; snaps and party poppers may contain up to 16 mg of potassium chlorate/red phosphorous mixture; other articles may contain up to 5 g of pyrotechnic substance, but no flash composition Pyrotechnic substance per item > 20 g, containing  3% flash composition as report effects, or whistle composition  5 g Pyrotechnic substance per item  20 g, containing  3% flash composition as report effects, or whistle composition  5 g  1 kg total pyrotechnic substance, no report effect, each whistle (if any)  25 g and ≤ 50 g whistle composition per wheel < 1 kg total pyrotechnic substance, no report effect, each whistle (if any)  5 g and ≤ 10 g whistle composition per wheel Specification 1.3G 1.4G 1.3G 1.4G 1.3G 1.4G Classification - 114 - Includes: / Synonym: Display selection box, display selection pack, garden selection box, indoor selection box; assortment Celebration cracker, celebration roll, string cracker Salute, flash banger, lady cracker Type Selection pack Firecracker Banger Non-metallic tube containing report composition intended to produce an aural effect Assembly of tubes (paper or cardboard) linked by a pyrotechnic fuse, each tube intended to produce an aural effect A pack of more than one type each corresponding to one of the types of fireworks listed in this table Definition 1.4G Classification 1.4G 1.3G  2 g flash composition per item and ≤ 10 g per inner packaging  1 g flash composition per item and ≤ 10 g per inner packaging or ≤ 10 g black powder per item 1.1G 1.4G > 2 g flash composition per item Each tube ≤ 140 mg of flash composition or ≤ 1 g black powder The most hazardous firework type determines the classification  200 g total pyrotechnic substance and  60 g pyrotechnic substance per driver,  3% flash composition as report effects, each whistle (if any)  5 g and ≤ 10 g whistle composition per wheel Specification 2.2.1.1.8 Exclusion from Class 1 2.2.1.1.8.1 An article or a substance may be excluded from Class 1 by virtue of test results and the Class 1 definition with the approval of the competent authority of any ADR Contracting Party who may also recognize an approval granted by the competent authority of a country which is not an ADR Contracting Party provided that this approval has been granted in accordance with the procedures applicable according to RID, ADR, ADN, the IMDG Code or the ICAO Technical Instructions. 2.2.1.1.8.2 With the approval of the competent authority in accordance with 2.2.1.1.8.1, an article may be excluded from Class 1 when three unpackaged articles, each individually activated by its own means of initiation or ignition or external means to function in the designed mode, meet the following test criteria: (a) No external surface shall have a temperature of more than 65 °C. A momentary spike in temperature up to 200 ºC is acceptable; (b) No rupture or fragmentation of the external casing or movement of the article or detached parts thereof of more than one metre in any direction; NOTE: Where the integrity of the article may be affected in the event of an external fire these criteria shall be examined by a fire test, such as described in ISO 12097-3. (c) No audible report exceeding 135 dB(C) peak at a distance of one metre; (d) No flash or flame capable of igniting a material such as a sheet of 80 ± 10 g/m² paper in contact with the article; and (e) No production of smoke, fumes or dust in such quantities that the visibility in a one cubic metre chamber equipped with appropriately sized blow out panels is reduced more than 50% as measured by a calibrated light (lux) meter or radiometer located one metre from a constant light source located at the midpoint on opposite walls. The general guidance on Optical Density Testing in ISO 5659-1 and the general guidance on the Photometric System described in Section 7.5 in ISO 5659-2 may be used or similar optical density measurement methods designed to accomplish the same purpose may also be employed. A suitable hood cover surrounding the back and sides of the light meter shall be used to minimize effects of scattered or leaking light not emitted directly from the source. NOTE 1: If during the tests addressing criteria (a), (b), (c) and (d) no or very little smoke is observed the test described in (e) may be waived. NOTE 2: The competent authority referred to in 2.2.1.1.8.1 may require testing in packaged form if it is determined that, as packaged for carriage, the article may pose a greater risk. 2.2.1.2 Substances and articles not accepted for carriage 2.2.1.2.1 Explosive substances which are unduly sensitive according to the criteria of the Manual of Tests and Criteria, Part I, or are liable to spontaneous reaction, as well as explosive substances and articles which cannot be assigned to a name or n.o.s. entry listed in Table A of Chapter 3.2, shall not be accepted for carriage. 2.2.1.2.2 Articles of compatibility group K shall not be accepted for carriage (1.2K, UN No. 0020 and 1.3K, UN No. 0021). - 115 - 2.2.1.3 List of collective entries UN Name of the substance or article Classification code (see 2.2.1.1.4) No. 1.1A 0473 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1B 0461 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.1C 0474 SUBSTANCES, EXPLOSIVE, N.O.S. 0497 PROPELLANT, LIQUID 0498 PROPELLANT, SOLID 0462 ARTICLES, EXPLOSIVE, N.O.S. 0475 SUBSTANCES, EXPLOSIVE, N.O.S. 0463 ARTICLES, EXPLOSIVE, N.O.S. 1.1E 0464 ARTICLES, EXPLOSIVE, N.O.S. 1.1F 0465 ARTICLES, EXPLOSIVE, N.O.S. 1.1G 0476 SUBSTANCES, EXPLOSIVE, N.O.S. 1.1L 0357 SUBSTANCES, EXPLOSIVE, N.O.S. 0354 ARTICLES, EXPLOSIVE, N.O.S. 1.2B 0382 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.2C 0466 ARTICLES, EXPLOSIVE, N.O.S. 1.2D 0467 ARTICLES, EXPLOSIVE, N.O.S. 1.2E 0468 ARTICLES, EXPLOSIVE, N.O.S. 1.2F 0469 ARTICLES, EXPLOSIVE, N.O.S. 1.2L 0358 SUBSTANCES, EXPLOSIVE, N.O.S. 0248 CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge 0355 ARTICLES, EXPLOSIVE, N.O.S. 0132 DEFLAGRATING METAL SALTS OF AROMATIC NITRO-DERIVATIVES, N.O.S. 0477 SUBSTANCES, EXPLOSIVE, N.O.S. 0495 PROPELLANT, LIQUID 1.1D 1.3C 0499 PROPELLANT, SOLID 0470 ARTICLES, EXPLOSIVE, N.O.S. 1.3G 0478 SUBSTANCES, EXPLOSIVE, N.O.S. 1.3L 0359 SUBSTANCES, EXPLOSIVE, N.O.S. 0249 CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge 0356 ARTICLES, EXPLOSIVE, N.O.S. 0350 ARTICLES, EXPLOSIVE, N.O.S. 0383 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 0479 SUBSTANCES, EXPLOSIVE, N.O.S. 0501 PROPELLANT, SOLID 0351 ARTICLES, EXPLOSIVE, N.O.S. 0480 SUBSTANCES, EXPLOSIVE, N.O.S. 0352 ARTICLES, EXPLOSIVE, N.O.S. 1.4E 0471 ARTICLES, EXPLOSIVE, N.O.S. 1.4F 0472 ARTICLES, EXPLOSIVE, N.O.S. 1.4G 0485 SUBSTANCES, EXPLOSIVE, N.O.S. 1.4B 1.4C 1.4D - 116 - Classification code (see 2.2.1.1.4) 1.4S 1.5D 1.6N UN Name of the substance or article No. 0353 ARTICLES, EXPLOSIVE, N.O.S. 0481 SUBSTANCES, EXPLOSIVE, N.O.S. 0349 ARTICLES, EXPLOSIVE, N.O.S. 0384 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 0482 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI) N.O.S. 0486 ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI) 0190 SAMPLES, EXPLOSIVE other than initiating explosive NOTE: Division and Compatibility Group shall be defined as directed by the competent authority and according to the principles in 2.2.1.1.4. - 117 - 2.2.1.4 Glossary of names NOTE 1: The descriptions in the glossary are not intended to replace the test procedures, nor to determine the hazard classification of a substance or article of Class 1. Assignment to the correct division and a decision on whether Compatibility Group S is appropriate shall be based on testing of the product in accordance with the Manual of Tests and Criteria, Part I or by analogy with similar products which have already been tested and assigned in accordance with the procedures of the Manual of Tests and Criteria. NOTE 2: The figures given after the names refer to the relevant UN numbers (Column 1 of Table A of Chapter 3.2). For the classification code, see 2.2.1.1.4. AMMUNITION, ILLUMINATING, with or without burster, expelling charge or propelling charge: UN Nos. 0171, 0254, 0297 Ammunition designed to produce a single source of intense light for lighting up an area. The term includes illuminating cartridges, grenades and projectiles; and illuminating and target identification bombs. NOTE: The following articles: CARTRIDGES, SIGNAL; SIGNAL DEVICES HAND; SIGNALS, DISTRESS; FLARES, AERIAL; FLARES, SURFACE are not included in this definition. They are listed separately. AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge: UN No. 0247 Ammunition containing liquid or gelatinous incendiary substance. Except when the incendiary substance is an explosive per se, it also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge: UN Nos. 0243, 0244 Ammunition containing white phosphorus as incendiary substance. It also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge: UN Nos. 0009, 0010, 0300 Ammunition containing incendiary composition. Except when the composition is an explosive per se, it also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, PRACTICE: UN Nos. 0362, 0488 Ammunition without a main bursting charge, containing a burster or expelling charge. Normally it also contains a fuze and a propelling charge. NOTE: GRENADES, PRACTICE are not included in this definition. They are listed separately. AMMUNITION, PROOF: UN No. 0363 Ammunition containing pyrotechnic substances, used to test the performance or strength of new ammunition, weapon components or assemblies. AMMUNITION, SMOKE, WHITE PHOSPHORUS, with burster, expelling charge or propelling charge: UN Nos. 0245, 0246 Ammunition containing white phosphorus as a smoke-producing substance. It also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. The term includes grenades, smoke. - 118 - AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge: UN Nos. 0015, 0016, 0303 Ammunition containing a smoke-producing substance such as chlorosulphonic acid mixture or titanium tetrachloride; or a smoke-producing pyrotechnic composition based on hexachloroethane or red phosphorus. Except when the substance is an explosive per se, the ammunition also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. The term includes grenades, smoke. NOTE: SIGNALS, SMOKE are not included in this definition. They are listed separately. AMMUNITION, TEAR-PRODUCING, with burster, expelling charge or propelling charge: UN Nos. 0018, 0019, 0301 Ammunition containing a tear-producing substance. It also contains one or more of the following: a pyrotechnic substance; a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES EEI): UN No. 0486 Articles containing only extremely insensitive substances which demonstrate a negligible probability of accidental initiation or propagation under normal conditions of transport, and which have passed Test Series 7. ARTICLES, PYROPHORIC: UN No. 0380 Articles which contain a pyrophoric substance (capable of spontaneous ignition when exposed to air) and an explosive substance or component. The term excludes articles containing white phosphorus. ARTICLES, PYROTECHNIC, for technical purposes: UN Nos. 0428, 0429, 0430, 0431, 0432 Articles which contain pyrotechnic substances and are used for technical purposes such as heat generation, gas generation, theatrical effects, etc. NOTE: The following articles: all ammunition; CARTRIDGES, SIGNAL; CUTTERS, CABLE, EXPLOSIVE; FIREWORKS; FLARES, AERIAL; FLARES, SURFACE; RELEASE DEVICES, EXPLOSIVE; RIVETS, EXPLOSIVE; SIGNAL DEVICES, HAND; SIGNALS, DISTRESS; SIGNALS, RAILWAY TRACK, EXPLOSIVES; SIGNALS, SMOKE are not included in this definition. They are listed separately. BLACK POWDER (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS: UN No. 0028 Substance consisting of a pelletized form of black powder. BLACK POWDER (GUNPOWDER), granular or as meal: UN No. 0027 Substance consisting of an intimate mixture of charcoal or other carbon and either potassium nitrate or sodium nitrate, with or without sulphur. BOMBS, WITH FLAMMABLE LIQUID, with bursting charge: UN Nos. 0399, 0400 Articles which are dropped from aircraft, consisting of a tank filled with inflammable liquid and bursting charge. BOMBS, PHOTO-FLASH: UN No. 0038 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a charge of detonating explosive without means of initiation or with means of initiation containing two or more effective protective features. - 119 - BOMBS, PHOTO-FLASH: UN No. 0037 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a charge of detonating explosive with means of initiation not containing two or more effective protective features. BOMBS, PHOTO-FLASH: UN Nos. 0039, 0299 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a photo-flash composition. BOMBS with bursting charge: UN Nos. 0034; 0035 Explosive articles which are dropped from aircraft, without means of initiation or with means of initiation containing two or more effective protective features. BOMBS with bursting charge: UN Nos. 0033, 0291 Explosive articles which are dropped from aircraft, with means of initiation not containing two or more effective protective features. BOOSTERS WITH DETONATOR: UN Nos. 0225, 0268 Articles consisting of a charge of detonating explosive with means of initiation. They are used to increase the initiating power of detonators or detonating cord. BOOSTERS without detonator: UN Nos. 0042, 0283 Articles consisting of a charge of detonating explosive without means of initiation. They are used to increase the initiating power of detonators or detonating cord. BURSTERS, explosive: UN No. 0043 Articles consisting of a small charge of explosive used to open projectiles or other ammunition in order to disperse their contents. CARTRIDGES, FLASH: UN Nos. 0049, 0050 Articles consisting of a casing, a primer and flash powder, all assembled in one piece ready for firing. CARTRIDGES FOR TOOLS, BLANK: UN No. 0014 Article, used in tools, consisting of a closed cartridge case with a centre or rim fire primer with or without a charge of smokeless or black powder but with no projectile. CARTRIDGES FOR WEAPONS, BLANK: UN Nos. 0326, 0413, 0327, 0338, 0014 Ammunition consisting of a closed cartridge case with a centre or rim fire primer and a charge of smokeless or black powder but no projectile. It produces a loud noise and is used for training, saluting, propelling charge, starter pistols, etc. The term includes ammunition, blank. CARTRIDGES FOR WEAPONS, INERT PROJECTILE: UN Nos. 0328, 0417, 0339, 0012 Ammunition consisting of a projectile without bursting charge but with a propelling charge with or without a primer. The articles may include a tracer, provided that the predominant hazard is that of the propelling charge. CARTRIDGES FOR WEAPONS with bursting charge: UN Nos. 0006, 0321, 0412 Ammunition consisting of a projectile with a bursting charge without means of initiation or with means of initiation containing two or more effective protective features; and a propelling charge with or without a primer. The term includes fixed (assembled) ammunition, semi-fixed (partially assembled) ammunition and separate loading ammunition when the components are packed together. - 120 - CARTRIDGES FOR WEAPONS with bursting charge: UN Nos. 0005, 0007, 0348 Ammunition consisting of a projectile with a bursting charge with means of initiation not containing two or more effective protective features; and a propelling charge with or without a primer. The term includes fixed (assembled) ammunition, semi-fixed (partially assembled) ammunition and separate loading ammunition when the components are packed together. CARTRIDGES, OIL WELL: UN Nos. 0277, 0278 Articles consisting of a thin casing of fibreboard, metal or other material containing only propellant powder which projects a hardened projectile to perforate an oil well casing. NOTE: CHARGES, SHAPED are not included in this definition. They are listed separately. CARTRIDGES, POWER DEVICE: UN Nos. 0275, 0276, 0323, 0381 Articles designed to accomplish mechanical actions. They consist of a casing with a charge of deflagrating explosive and a means of ignition. The gaseous products of the deflagration produce inflation, linear or rotary motion or activate diaphragms, valves or switches or project fastening devices or extinguishing agents. CARTRIDGES, SIGNAL: UN Nos. 0054, 0312, 0405 Articles designed to fire coloured flares or other signals from signal pistols, etc. CARTRIDGES, SMALL ARMS: UN Nos. 0417, 0339, 0012 Ammunition consisting of a cartridge case fitted with a centre or rim fire primer and containing both a propelling charge and solid projectile. They are designed to be fired in weapons of calibre not larger than 19.1 mm. Shot-gun cartridges of any calibre are included in this description. NOTE: CARTRIDGES, SMALL ARMS, BLANK, are not included in this definition. They are listed separately. Some military small arms cartridges are not included in this definition. They are listed under CARTRIDGES FOR WEAPONS, INERT PROJECTILE. CARTRIDGES, SMALL ARMS, BLANK: UN Nos. 0014, 0327, 0338 Ammunition consisting of a closed cartridge case with a centre or rim fire primer and a charge of smokeless or black powder. The cartridge cases contain no projectiles. The cartridges are designed to be fired from weapons with a calibre of at most 19.1 mm and serve to produce a loud noise and are used for training, saluting, propelling charge, starter pistols, etc. CASES, CARTRIDGE, EMPTY, WITH PRIMER: UN Nos. 0379; 0055 Articles consisting of a cartridge case made from metal, plastics or other non-inflammable material, in which the only explosive component is the primer. CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER: UN Nos. 0447, 0446 Articles consisting of a cartridge case made partly or entirely from nitrocellulose. CHARGES, BURSTING, PLASTICS BONDED: UN Nos. 0457, 0458, 0459, 0460 Articles consisting of a charge of detonating explosive, plastics bonded, manufactured in a specific form without a casing and without means of initiation. They are designed as components of ammunition such as warheads. CHARGES, DEMOLITION: UN No. 0048 Articles containing a charge of a detonating explosive in a casing of fibreboard, plastics, metal or other material. The articles are without means of initiation or with means of initiation containing two or more effective protective features. - 121 - NOTE: The following articles: BOMBS; MINES; PROJECTILES are not included in this definition. They are listed separately. CHARGES, DEPTH: UN No. 0056 Articles consisting of a charge of detonating explosive contained in a drum or projectile without means of initiation or with means of initiation containing two or more effective protective features. They are designed to detonate under water. CHARGES, EXPLOSIVE, COMMERCIAL without detonator: UN Nos. 0442, 0443, 0444, 0445 Articles consisting of a charge of detonating explosive without means of initiation, used for explosive welding, jointing, forming and other metallurgical processes. CHARGES, PROPELLING, FOR CANNON: UN Nos. 0242, 0279, 0414 Charges of propellant in any physical form for separate-loading ammunition for cannon. CHARGES, PROPELLING: UN Nos. 0271, 0272, 0415, 0491 Articles consisting of a charge of a propellant charge in any physical form, with or without a casing, as a component of rocket motors or for reducing the drag of projectiles. CHARGES, SHAPED, without detonator: UN Nos. 0059, 0439, 0440, 0441 Articles consisting of a casing containing a charge of detonating explosive with a cavity lined with rigid material, without means of initiation. They are designed to produce a powerful, penetrating jet effect. CHARGES, SHAPED, FLEXIBLE, LINEAR: UN Nos. 0237, 0288 Articles consisting of a V-shaped core of a detonating explosive clad by a flexible sheath. CHARGES, SUPPLEMENTARY, EXPLOSIVE: UN No. 0060 Articles consisting of a small removable booster placed in the cavity of a projectile between the fuze and the bursting charge. COMPONENTS, EXPLOSIVE TRAIN, N.O.S.: UN Nos. 0382, 0383, 0384, 0461 Articles containing an explosive designed to transmit detonation or deflagration within an explosive train. CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge: UN Nos. 0248, 0249 Articles whose functioning depends upon physico-chemical reaction of their contents with water. CORD, DETONATING, flexible: UN Nos. 0065, 0289 Article consisting of a core of detonating explosive enclosed in spun fabric and a plastics or other covering. The covering is not necessary if the spun fabric is sift-proof. CORD (FUSE) DETONATING, metal clad: UN Nos. 0102, 0290 Article consisting of a core of detonating explosive clad by a soft metal tube with or without protective covering. CORD (FUSE) DETONATING, MILD EFFECT, metal clad: UN No. 0104 Article consisting of a core of detonating explosive clad by a soft metal tube with or without a protective covering. The quantity of explosive substance is so small that only a mild effect is manifested outside the cord. - 122 - CORD, IGNITER: UN No. 0066 Article consisting of textile yarns covered with black powder or another fast burning pyrotechnic composition and of a flexible protective covering; or it consists of a core of black powder surrounded by a flexible woven fabric. It burns progressively along its length with an external flame and is used to transmit ignition from a device to a charge or primer. CUTTERS, CABLE, EXPLOSIVE: UN No. 0070 Articles consisting of a knife-edged device which is driven by a small charge of deflagrating explosive into an anvil. DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting: UN Nos. 0360, 0361, 0500 Non-electric detonators assembled with and activated by such means as safety fuse, shock tube, flash tube or detonating cord. They may be of instantaneous design or incorporate delay elements. Detonating relays incorporating detonating cord are included. DETONATORS, ELECTRIC for blasting: UN Nos. 0030, 0255, 0456 Articles specially designed for the initiation of blasting explosives. These detonators may be constructed to detonate instantaneously or may contain a delay element. Electric detonators are activated by an electric current. DETONATORS FOR AMMUNITION: UN Nos. 0073, 0364, 0365, 0366 Articles consisting of a small metal or plastics tube containing explosives such as lead azide, PETN or combinations of explosives. They are designed to start a detonation train. DETONATORS, NON-ELECTRIC for blasting: UN Nos. 0029, 0267, 0455 Articles specially designed for the initiation of blasting explosives. These detonators may be constructed to detonate instantaneously or may contain a delay element. Non-electric detonators are activated by such means as shock tube, flash tube, safety fuse, other igniferous device or flexible detonating cord. Detonating relays without detonating cord are included. EXPLOSIVE, BLASTING, TYPE A: UN No. 0081 Substances consisting of liquid organic nitrates such as nitroglycerine or a mixture of such ingredients with one or more of the following: nitrocellulose; ammonium nitrate or other inorganic nitrates; aromatic nitro-derivatives, or combustible materials, such as wood-meal and aluminium powder. They may contain inert components such as kieselguhr, and additives such as colouring agents and stabilizers. Such explosives shall be in powdery, gelatinous or elastic form. The term includes dynamite; gelatine, blasting and gelatine dynamites. EXPLOSIVE, BLASTING, TYPE B: UN Nos. 0082, 0331 Substances consisting of (a) a mixture of ammonium nitrate or other inorganic nitrates with an explosive such as trinitrotoluene, with or without other substances such as wood-meal and aluminium powder; or (b) a mixture of ammonium nitrate or other inorganic nitrates with other combustible substances which are not explosive ingredients. In both cases they may contain inert components such as kieselguhr, and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine, similar liquid organic nitrates or chlorates. EXPLOSIVE, BLASTING, TYPE C: UN No. 0083 Substances consisting of a mixture of either potassium or sodium chlorate or potassium, sodium or ammonium perchlorate with organic nitro-derivatives or combustible materials such as wood-meal or aluminium powder or a hydrocarbon. They may contain inert components such as kieselguhr and - 123 - additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine or similar liquid organic nitrates. EXPLOSIVE, BLASTING, TYPE D: UN No. 0084 Substances consisting of a mixture of organic nitrated compounds and combustible materials such as hydrocarbons and aluminium powder. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine, similar liquid organic nitrates, chlorates and ammonium nitrate. The term generally includes plastic explosives. EXPLOSIVES, BLASTING, TYPE E: UN Nos. 0241, 0332 Substances consisting of water as an essential ingredient and high proportions of ammonium nitrate or other oxidizers, some or all of which are in solution. The other constituents may include nitro-derivatives such as trinitrotoluene, hydrocarbons or aluminium powder. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. The term includes explosives, emulsion, explosives, slurry and explosives, watergel. FIREWORKS: UN Nos. 0333, 0334, 0335, 0336, 0337 Pyrotechnic articles designed for entertainment. FLARES, AERIAL: UN Nos. 0093, 0403, 0404, 0420, 0421 Articles containing pyrotechnic substances which are designed to be dropped from an aircraft to illuminate, identify, signal or warn. FLARES, SURFACE: UN Nos. 0092, 0418, 0419 Articles containing pyrotechnic substances which are designed for use on the surface to illuminate, identify, signal or warn. FLASH POWDER: UN Nos. 0094, 0305 Pyrotechnic substance which, when ignited, produces an intense light. FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells: UN No. 0099 Articles consisting of a charge of detonating explosive contained in a casing without means of initiation. They are used to fracture the rock around a drill shaft to assist the flow of crude oil from the rock. FUSE, IGNITER, tubular, metal clad: UN No. 0103 Article consisting of a metal tube with a core of deflagrating explosive. FUSE, NON-DETONATING: UN No. 0101 Article consisting of cotton yarns impregnated with fine black powder (quickmatch). It burns with an external flame and is used in ignition trains for fireworks, etc. FUSE, SAFETY: UN No. 0105 Article consisting of a core of fine grained black powder surrounded by a flexible woven fabric with one or more protective outer coverings. When ignited, it burns at a predetermined rate without any external explosive effect. FUZES, DETONATING: UN Nos. 0106, 0107, 0257, 0367 Articles with explosive components designed to produce a detonation in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to initiate the detonation. They generally incorporate protective features. - 124 - FUZES, DETONATING with protective features: UN Nos. 0408, 0409, 0410 Articles with explosive components designed to produce a detonation in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to initiate the detonation. The detonating fuze must incorporate two or more effective protective features. FUZES, IGNITING: UN Nos. 0316, 0317, 0368 Articles with primary explosive components designed to produce a deflagration in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to start the deflagration. They generally incorporate protective features. GRENADES, hand or rifle, with bursting charge: UN Nos. 0284, 0285 Articles which are designed to be thrown by hand or to be projected by a rifle. They are without means of initiation or with means of initiation containing two or more effective protective features. GRENADES, hand or rifle, with bursting charge: UN Nos. 0292, 0293 Articles which are designed to be thrown by hand or to be projected by a rifle. They are with means of initiation not containing two or more effective protective features. GRENADES, PRACTICE, hand or rifle: UN Nos. 0110, 0372, 0318, 0452 Articles without a main bursting charge which are designed to be thrown by hand or to be projected by a rifle. They contain the priming device and may contain a spotting charge. HEXOTONAL: UN No. 0393 Substance consisting of an intimate trinitrotoluene (TNT) and aluminium. mixture of cyclotrimethylene-trinitramine (RDX), HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass: UN No. 0118 Substance consisting of an intimate mixture of cyclotrimethylene-trinitramine (RDX) and trinitrotoluene (TNT). The term includes "Composition B". IGNITERS: UN Nos. 0121, 0314, 0315, 0325, 0454 Articles containing one or more explosive substances designed to produce a deflagration in an explosive train. They may be actuated chemically, electrically or mechanically. NOTE: The following articles: CORD, IGNITER; FUSE, IGNITER; FUSE, NON-DETONATING; FUZES, IGNITING; LIGHTERS, FUSE; PRIMERS, CAP TYPE; PRIMERS, TUBULAR are not included in this definition. They are listed separately. JET PERFORATING GUNS, CHARGED, oil well, without detonator: UN Nos. 0124, 0494 Articles consisting of a steel tube or metallic strip, into which are inserted shaped charges connected by detonating cord, without means of initiation. LIGHTERS, FUSE: UN No. 0131 Articles of various design actuated by friction, percussion or electricity and used to ignite a safety fuse. MINES with bursting charge: UN Nos. 0137, 0138 Articles consisting normally of metal or composition receptacles filled with a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be operated by the passage of ships, vehicles or personnel. The term includes "Bangalore torpedoes". - 125 - MINES with bursting charge: UN Nos. 0136, 0294 Articles consisting normally of metal or composition receptacles filled with a detonating explosive, with means of initiation not containing two or more effective protective features. They are designed to be operated by the passage of ships, vehicles or personnel. The term includes "Bangalore torpedoes". OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass: UN No. 0266 Substance consisting of an intimate mixture of cyclotetramethylene-tetranitramine (HMX) and trinitrotoluene (TNT). OCTONAL: UN No. 0496 Substance consisting of an intimate mixture of cyclotetramethylenetetranitramine (HMX), trinitrotoluene (TNT) and aluminium. PENTOLITE, dry or wetted with less than 15% water, by mass: UN No. 0151 Substance consisting of an intimate mixture of pentaerythrite tetranitrate (PETN) and trinitrotoluene (TNT). POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass; POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass: UN Nos. 0433, 0159 Substance consisting of nitrocellulose impregnated with not more than 60% of nitroglycerine or other liquid organic nitrates or a mixture of these. POWDER, SMOKELESS: UN Nos. 0160, 0161, 0509 Substance based on nitrocellulose used as propellant. The term includes propellants with a single base (nitrocellulose (NC) alone), those with a double base (such as NC and nitroglycerine/(NG)) and those with a triple base (such as NC/NG/nitroguanidine). NOTE: Cast, pressed or bag-charges of smokeless powder are listed under CHARGES, PROPELLING or CHARGES, PROPELLING, FOR CANON. PRIMERS, CAP TYPE: UN Nos. 0044, 0377, 0378 Articles consisting of a metal or plastics cap containing a small amount of primary explosive mixture that is readily ignited by impact. They serve as igniting elements in small arms cartridges and in percussion primers for propelling charges. PRIMERS, TUBULAR: UN Nos. 0319, 0320, 0376 Articles consisting of a primer for ignition and an auxiliary charge of deflagrating explosive such as black powder used to ignite the propelling charge in a cartridge case for cannon, etc. PROJECTILES, inert with tracer: UN Nos. 0345, 0424, 0425 Articles such as a shell or bullet, which are projected from a cannon or other gun, rifle or other small arm. PROJECTILES with burster or expelling charge: UN Nos. 0346, 0347 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are without means of initiation or with means of initiation containing two or more effective protective features. They are used to scatter dyes for spotting or other inert materials. - 126 - PROJECTILES with burster or expelling charge: UN Nos. 0426, 0427 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are with means of initiation not containing two or more effective protective features. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with burster or expelling charge: UN Nos. 0434, 0435 Articles such as a shell or bullet, which are projected from a cannon or other gun, rifle or other small arm. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with bursting charge: UN Nos. 0168, 0169, 0344 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are without means of initiation or with means of initiation containing two or more effective protective features. PROJECTILES with bursting charge: UN Nos. 0167, 0324 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are with means of initiation not containing two or more effective protective features. PROPELLANT, LIQUID: UN Nos. 0495, 0497 Substance consisting of a deflagrating liquid explosive, used for propulsion. PROPELLANT, SOLID: UN Nos. 0498, 0499, 0501 Substance consisting of a deflagrating solid explosive, used for propulsion. RELEASE DEVICES, EXPLOSIVE: UN No. 0173 Articles consisting of a small charge of explosive with means of initiation and rods or links. They sever the rods or links to release equipment quickly. RIVETS, EXPLOSIVE: UN No. 0174 Articles consisting of a small charge of explosive inside a metallic rivet. ROCKET MOTORS: UN Nos. 0186, 0280, 0281 Articles consisting of a charge of explosive, generally a solid propellant, contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKET MOTORS, LIQUID FUELLED: UN Nos. 0395, 0396 Articles consisting of a liquid fuel within a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge: UN Nos. 0322, 0250 Articles consisting of a hypergolic fuel contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKETS, LINE THROWING: UN Nos. 0238, 0240, 0453 Articles consisting of a rocket motor which is designed to extend a line. ROCKETS, LIQUID FUELLED with bursting charge: UN Nos. 0397, 0398 Articles consisting of a liquid fuel within a cylinder fitted with one or more nozzles and fitted with a warhead. The term includes guided missiles. - 127 - ROCKETS with bursting charge: UN Nos. 0181, 0182 Articles consisting of a rocket motor and a warhead without means of initiation or with means of initiation containing two or more effective protective features. The term includes guided missiles. ROCKETS with bursting charge: UN Nos. 0180, 0295 Articles consisting of a rocket motor and a warhead with means of initiation not containing two or more effective protective features. The term includes guided missiles. ROCKETS with expelling charge: UN Nos. 0436, 0437, 0438 Articles consisting of a rocket motor and a charge to expel the payload from a rocket head. The term includes guided missiles. ROCKETS with inert head: UN Nos. 0183, 0502 Articles consisting of a rocket motor and an inert head. The term includes guided missiles. SAFETY DEVICES, PYROTECHNIC: UN No. 0503 Articles which contain pyrotechnic substances or dangerous goods of other classes and are used in vehicles, vessels or aircraft to enhance safety to persons. Examples are: air bag inflators, air bag modules, seat-belt pretensioners and pyromechanical devices. These pyromechanical devices are assembled components for tasks such as but not limited to separation, locking, or occupant restraint. SAMPLES, EXPLOSIVE, other than initiating explosive UN No. 0190 New or existing explosive substances or articles, not yet assigned to a name in Table A of Chapter 3.2 and carried in conformity with the instructions of the competent authority and generally in small quantities, inter alia, for the purposes of testing, classification, research and development, or quality control, or as commercial samples. NOTE: Explosive substances or articles already assigned to another name in Table A of Chapter 3.2 are not included in this definition. SIGNAL DEVICES, HAND: UN Nos. 0191, 0373 Portable articles containing pyrotechnic substances which produce visual signals or warnings. The term includes small surface flares such as highway or railway flares and small distress flares. SIGNALS, DISTRESS, ship: UN Nos. 0194, 0195, 0505, 0506 Articles containing pyrotechnic substances designed to produce signals by means of sound, flame or smoke or any combination thereof. SIGNALS, RAILWAY TRACK, EXPLOSIVE: UN Nos. 0192, 0193, 0492, 0493 Articles containing a pyrotechnic substance which explodes with a loud report when the article is crushed. They are designed to be placed on a rail. SIGNALS, SMOKE: UN Nos. 0196, 0197, 0313, 0487, 0507 Articles containing pyrotechnic substances which emit smoke. In addition they may contain devices for emitting audible signals. SOUNDING DEVICES, EXPLOSIVE: UN Nos. 0374, 0375 Articles consisting of a charge of detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are dropped from ships and function when they reach a predetermined depth or the sea bed. - 128 - SOUNDING DEVICES, EXPLOSIVE: UN Nos. 0204, 0296 Articles consisting of a charge of detonating explosive with means of initiation not containing two or more effective protective features. They are dropped from ships and function when they reach a predetermined depth or the sea bed. SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (Substances, EVI), N.O.S.: UN No. 0482 Substances presenting a mass explosion hazard but which are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of transport, and which have passed Test Series 5. TORPEDOES, LIQUID FUELLED with inert head: UN No. 0450 Articles consisting of a liquid explosive system to propel the torpedo through the water, with an inert head. TORPEDOES, LIQUID FUELLED with or without bursting charge: UN No. 0449 Articles consisting of either a liquid explosive system to propel the torpedo through the water, with or without a warhead; or a liquid non-explosive system to propel the torpedo through the water, with a warhead. TORPEDOES with bursting charge: UN No. 0451 Articles consisting of a non-explosive system to propel the torpedo through the water, and a warhead without means of initiation or with means of initiation containing two or more effective protective features. TORPEDOES with bursting charge: UN No. 0329 Articles consisting of an explosive system to propel the torpedo through the water, and a warhead without means of initiation or with means of initiation containing two or more effective protective features. TORPEDOES with bursting charge: UN No. 0330 Articles consisting of an explosive or non-explosive system to propel the torpedo through the water, and a warhead with means of initiation not containing two or more effective protective features. TRACERS FOR AMMUNITION: UN Nos. 0212, 0306 Sealed articles containing pyrotechnic substances, designed to reveal the trajectory of a projectile. TRITONAL: UN No. 0390 Substance consisting of trinitrotoluene (TNT) mixed with aluminium. WARHEADS, ROCKET with burster or expelling charge: UN No. 0370 Articles consisting of an inert payload and a small charge of detonating or deflagrating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a rocket motor to scatter inert material. The term includes warheads for guided missiles. WARHEADS, ROCKET with burster or expelling charge: UN No. 0371 Articles consisting of an inert payload and a small charge of detonating or deflagrating explosive, with means of initiation not containing two or more effective protective features. They are designed to be fitted to a rocket motor to scatter inert material. The term includes warheads for guided missiles. - 129 - WARHEADS, ROCKET with bursting charge: UN Nos. 0286, 0287 Articles consisting of a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a rocket. The term includes warheads for guided missiles. WARHEADS, ROCKET with bursting charge: UN No. 0369 Articles consisting of a detonating explosive, with means of initiation not containing two or more effective protective features. They are designed to be fitted to a rocket. The term includes warheads for guided missiles. WARHEADS, TORPEDO with bursting charge: UN No. 0221 Articles consisting of a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a torpedo. - 130 - 2.2.2 Class 2 Gases 2.2.2.1 Criteria 2.2.2.1.1 The heading of Class 2 covers pure gases, mixtures of gases, mixtures of one or more gases with one or more other substances and articles containing such substances. A gas is a substance which: (a) at 50 °C has a vapour pressure greater than 300 kPa (3 bar); or (b) is completely gaseous at 20 °C at the standard pressure of 101.3 kPa. NOTE 1: UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS is nevertheless classified in Class 8. NOTE 2: A pure gas may contain other components deriving from its production process or added to preserve the stability of the product, provided that the level of these components does not change its classification or its conditions of carriage, such as filling ratio, filling pressure, test pressure. NOTE 3: N.O.S. entries in 2.2.2.3 may cover pure gases as well as mixtures. 2.2.2.1.2 The substances and articles of Class 2 are subdivided as follows: 1. Compressed gas: a gas which when packaged under pressure for carriage is entirely gaseous at -50 °C; this category includes all gases with a critical temperature less than or equal to -50 °C; 2. Liquefied gas: a gas which when packaged under pressure for carriage is partially liquid at temperatures above -50 °C. A distinction is made between: High pressure liquefied gas: a gas with a critical temperature above -50 °C and equal to or below +65 °C; and Low pressure liquefied gas: a gas with a critical temperature above +65 °C; 2.2.2.1.3 3. Refrigerated liquefied gas: a gas which when packaged for carriage is made partially liquid because of its low temperature; 4. Dissolved gas: a gas which when packaged under pressure for carriage is dissolved in a liquid phase solvent; 5. Aerosol dispensers and receptacles, small, containing gas (gas cartridges); 6. Other articles containing gas under pressure; 7. Non-pressurized gases subject to special requirements (gas samples); 8. Chemicals under pressure: liquids, pastes or powders, pressurized with a propellant that meets the definition of a compressed or liquefied gas and mixtures thereof. 9. Adsorbed gas: a gas which when packaged for carriage is adsorbed onto a solid porous material resulting in an internal receptacle pressure of less than 101.3 kPa at 20 C and less than 300 kPa at 50 C. Substances and articles (except aerosols and chemicals under pressure) of Class 2 are assigned to one of the following groups according to their hazardous properties, as follows: A asphyxiant; O oxidizing; F flammable; - 131 - T toxic; TF toxic, flammable; TC toxic, corrosive; TO toxic, oxidizing; TFC toxic, flammable, corrosive; TOC toxic, oxidizing, corrosive. For gases and gas mixtures presenting hazardous properties associated with more than one group according to the criteria, the groups designated by letter T take precedence over all other groups. The groups designated by letter F take precedence over the groups designated by letters A or O. NOTE 1: In the UN Model Regulations, the IMDG Code and the ICAO Technical Instructions, gases are assigned to one of the following three divisions, based on the primary hazard: Division 2.1: flammable gases (corresponding to the groups designated by the capital letter F); Division 2.2: non-flammable, non-toxic gases (corresponding to the groups designated by the capital letters A or O); Division 2.3: toxic gases (corresponding to the groups designated by the capital letter T i.e. T, TF, TC, TO, TFC and TOC). NOTE 2: Receptacles, small containing gas (UN No. 2037) shall be assigned to the groups A to TOC according to the hazard of the contents. For aerosols (UN No. 1950), see 2.2.2.1.6. For chemicals under pressure (UN Nos. 3500 to 3505), see 2.2.2.1.7. NOTE 3: Corrosive gases are considered to be toxic, and are therefore assigned to the group TC, TFC or TOC. 2.2.2.1.4 If a mixture of Class 2 mentioned by name in Table A of Chapter 3.2 meets different criteria as mentioned in 2.2.2.1.2 and 2.2.2.1.5, this mixture shall be classified according to the criteria and assigned to an appropriate N.O.S. entry. 2.2.2.1.5 Substances and articles (except aerosols and chemicals under pressure) of Class 2 which are not mentioned by name in Table A of Chapter 3.2 shall be classified under a collective entry listed in 2.2.2.3 in accordance with 2.2.2.1.2 and 2.2.2.1.3. The following criteria shall apply: Asphyxiant gases Gases which are non-oxidizing, non-flammable and non-toxic and which dilute or replace oxygen normally in the atmosphere. Flammable gases Gases which at 20 °C and a standard pressure of 101.3 kPa: (a) are ignitable when in a mixture of 13% or less by volume with air; or (b) have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Flammability shall be determined by tests or by calculation, in accordance with methods adopted by ISO (see ISO 10156:2010). Where insufficient data are available to use these methods, tests by a comparable method recognized by the competent authority of the country of origin may be used. - 132 - If the country of origin is not a Contracting Party to ADR these methods shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. Oxidizing gases Gases, which may, generally by providing oxygen, cause or contribute to the combustion of other material more than air does. These are pure gases or gas mixtures with an oxidizing power greater than 23.5% as determined by a method specified in ISO 10156:2010. Toxic gases NOTE: Gases meeting the criteria for toxicity in part or completely owing to their corrosivity are to be classified as toxic. See also the criteria under the heading "Corrosive gases" for a possible subsidiary corrosivity risk. Gases which: (a) are known to be so toxic or corrosive to humans as to pose a hazard to health; or (b) are presumed to be toxic or corrosive to humans because they have a LC50 value for acute toxicity equal to or less than 5 000 ml/m³ (ppm) when tested in accordance with 2.2.61.1. In the case of gas mixtures (including vapours of substances from other classes) the following formula may be used: LC50 Toxic (mixture) = 1 n  Tf i i =1 where i fi = mole fraction of the ith component substance of the mixture; Ti = toxicity index of the ith component substance of the mixture. The Ti equals the LC50 value as found in packing instruction P200 of 4.1.4.1. When no LC50 value is listed in packing instruction P200 of 4.1.4.1, a LC50 value available in scientific literature shall be used. When the LC50 value is unknown, the toxicity index is determined by using the lowest LC50 value of substances of similar physiological and chemical effects, or through testing if this is the only practical possibility. Corrosive gases Gases or gas mixtures meeting the criteria for toxicity completely owing to their corrosivity are to be classified as toxic with a subsidiary corrosivity risk. A gas mixture that is considered to be toxic due to the combined effects of corrosivity and toxicity has a subsidiary risk of corrosivity when the mixture is known by human experience to be destructive to the skin, eyes or mucous membranes or when the LC50 value of the corrosive components of the mixture is equal to or less than 5 000 ml/m3 (ppm) when the LC50 is calculated by the formula: LC50 Corrosive (mixture) = n 1  Tfcici i =1 where fci = mole fraction of the ith corrosive component substance of the mixture; Tci = toxicity index of the ith corrosive component substance of the mixture. - 133 - The Tci equals the LC50 value as found in packing instruction P200 of 4.1.4.1. When no LC50 value is listed in packing instruction P200 of 4.1.4.1, a LC50 value available in scientific literature shall be used. When the LC50 value is unknown the toxicity index is determined by using the lowest LC50 value of substances of similar physiological and chemical effects, or through testing if this is the only practical possibility. 2.2.2.1.6 Aerosols Aerosols (UN No. 1950) are assigned to one of the following groups according to their hazardous properties, as follows: A asphyxiant; O oxidizing; F flammable; T toxic; C corrosive; CO corrosive, oxidizing; FC flammable, corrosive; TF toxic, flammable; TC toxic, corrosive; TO toxic, oxidizing; TFC toxic, flammable, corrosive; TOC toxic, oxidizing, corrosive. The classification depends on the nature of the contents of the aerosol dispenser. NOTE: Gases, which meet the definition of toxic gases according to 2.2.2.1.5 and gases identified as "Considered as pyrophoric" by table note c of Table 2 of packing instruction P200 in 4.1.4.1, shall not be used as a propellant in an aerosol dispenser. Aerosols with contents meeting the criteria for packing group I for toxicity or corrosivity shall not be accepted for carriage (see also 2.2.2.2.2). The following criteria shall apply: (a) Assignment to group A shall apply when the contents do not meet the criteria for any other group according to sub-paragraphs (b) to (f) below; (b) Assignment to group O shall apply when the aerosol contains an oxidizing gas according to 2.2.2.1.5; (c) Assignment to group F shall apply if the contents include 85% by mass or more flammable components and the chemical heat of combustion is 30 kJ/g or more. It shall not apply if the contents contain 1% by mass or less flammable components and the heat of combustion is less than 20 kJ/g. Otherwise the aerosol shall be tested for flammability in accordance with the tests described in the Manual of Tests and Criteria, Part III, section 31. Extremely flammable and flammable aerosols shall be assigned to group F; NOTE: Flammable components are flammable liquids, flammable solids or flammable gases and gas mixtures as defined in Notes 1 to 3 of sub-section 31.1.3 of Part III of the Manual of Tests and Criteria. This designation does not cover pyrophoric, self-heating or - 134 - water-reactive substances. The chemical heat of combustion shall be determined by one of the following methods ASTM D 240, ISO/FDIS 13943:1999 (E/F) 86.1 to 86.3 or NFPA 30B. 2.2.2.1.7 (d) Assignment to group T shall apply when the contents, other than the propellant of aerosol dispensers to be ejected, are classified as Class 6.1, packing groups II or III; (e) Assignment to group C shall apply when the contents, other than the propellant of aerosol dispensers to be ejected, meet the criteria for Class 8, packing groups II or III; (f) When the criteria for more than one group amongst groups O, F, T, and C are met, assignment to groups CO, FC, TF, TC TO, TFC or TOC shall apply, as relevant. Chemicals under pressure Chemicals under pressure (UN Nos. 3500 to 3505) are assigned to one of the following groups according to their hazardous properties, as follows: A asphyxiant; F flammable; T toxic; C corrosive; FC flammable, corrosive; TF toxic, flammable. The classification depends on the hazard characteristics of the components in the different states: The propellant; The liquid; or The solid. NOTE 1: Gases, which meet the definition of toxic gases or of oxidizing gases according to 2.2.2.1.5 or gases identified as "Considered as pyrophoric" by table note c of Table 2 of packing instruction P200 in 4.1.4.1, shall not be used as a propellant in chemicals under pressure. NOTE 2: Chemicals under pressure with contents meeting the criteria for packing group I for toxicity or corrosivity or with contents meeting both the criteria for packing group II or III for toxicity and for packing group II or III for corrosivity shall not be accepted for carriage under these UN numbers. NOTE 3: Chemicals under pressure with components meeting the properties of Class 1; liquid desensitized explosives of Class 3; self-reactive substances and solid desensitized explosives of Class 4.1; Class 4.2; Class 4.3; Class 5.1; Class 5.2; Class 6.2; or Class 7, shall not be used for carriage under these UN numbers. NOTE 4: A chemical under pressure in an aerosol dispenser shall be carried under UN No. 1950. The following criteria shall apply: (a) Assignment to group A shall apply when the contents do not meet the criteria for any other group according to sub-paragraphs (b) to (e) below; - 135 - (b) Assignment to group F shall apply if one of the components, which can be a pure substance or a mixture, needs to be classified as flammable. Flammable components are flammable liquids and liquid mixtures, flammable solids and solid mixtures or flammable gases and gas mixtures meeting the following criteria: (i) A flammable liquid is a liquid having a flashpoint of not more than 93 °C; (ii) A flammable solid is a solid which meets the criteria in 2.2.41.1; (iii) A flammable gas is a gas which meets the criteria in 2.2.2.1.5; (c) Assignment to group T shall apply when the contents, other than the propellant, are classified as dangerous goods of Class 6.1, packing groups II or III; (d) Assignment to group C shall apply when the contents, other than the propellant, are classified as dangerous goods of Class 8, packing groups II or III; (e) When the criteria for two groups amongst groups F, T, and C are met, assignment to groups FC or TF shall apply, as relevant. 2.2.2.2 Gases not accepted for carriage 2.2.2.2.1 Chemically unstable substances of Class 2 shall not be accepted for carriage, unless the necessary steps have been taken to prevent all possibility of a dangerous reaction e.g. decomposition, dismutation or polymerisation under normal conditions during transport. To this end particular care shall be taken to ensure that receptacles and tanks do not contain any substances liable to promote these reactions. 2.2.2.2.2 The following substances and mixtures shall not be accepted for carriage: - UN No. 2186 HYDROGEN CHLORIDE, REFRIGERATED LIQUID; - UN No. 2421 NITROGEN TRIOXIDE; - UN No. 2455 METHYL NITRITE; - Refrigerated liquefied gases which cannot be assigned to classification codes 3A, 3O or 3F; - Dissolved gases which cannot be classified under UN Nos. 1001, 2073 or 3318; - Aerosols where gases which are toxic according to 2.2.2.1.5 or pyrophoric according to packing instruction P200 in 4.1.4.1 are used as propellants; - Aerosols with contents meeting the criteria for packing group I for toxicity or corrosivity (see 2.2.61 and 2.2.8); - Receptacles, small, containing gases which are very toxic (LC50 lower than 200 ppm) or pyrophoric according to packing instruction P200 in 4.1.4.1. - 136 - 2.2.2.3 List of collective entries Compressed gases Classification UN code No. 1956 1A 3156 1O 1964 1F 1954 1955 1T 1953 1 TF 3304 1 TC 3303 1 TO 3305 1 TFC 3306 1 TOC Liquefied gases Classification code 2A UN No. 1058 1078 2O 1968 3163 3157 2F 1010 1060 Name of the substance or article COMPRESSED GAS, N.O.S. COMPRESSED GAS, OXIDIZING, N.O.S. HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. COMPRESSED GAS, FLAMMABLE, N.O.S. COMPRESSED GAS, TOXIC, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. Name of the substance or article LIQUEFIED GASES, non-flammable, charged with nitrogen, carbon dioxide or air REFRIGERANT GAS, N.O.S. such as mixtures of gases, indicated by the letter R..., which as: Mixture F1, have a vapour pressure at 70 °C not exceeding 1.3 MPa (13 bar) and a density at 50 °C not lower than that of dichlorofluoromethane (1.30 kg/l); Mixture F2, have a vapour pressure at 70 °C not exceeding 1.9 MPa (19 bar) and a density at 50 °C not lower than that of dichlorodifluoromethane (1.21 kg/l); Mixture F3, have a vapour pressure at 70 °C not exceeding 3 MPa (30 bar) and a density at 50 °C not lower than that of chlorodifluoromethane (1.09 kg/l). NOTE: Trichlorofluoromethane (Refrigerant R 11), 1,1,2-trichloro-1,2,2trifluoroethane (Refrigerant R 113), 1,1,1-trichloro-2,2,2-trifluoroethane (Refrigerant R 113a), 1-chloro-1,2,2-trifluoroethane (Refrigerant R 133) and 1-chloro-1,1,2trifluoroethane (Refrigerant R 133b) are not substances of Class 2. They may, however, enter into the composition of mixtures F1 to F3. INSECTICIDE GAS, N.O.S. LIQUEFIED GAS, N.O.S. LIQUEFIED GAS, OXIDIZING, N.O.S. BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l. NOTE: Butadienes, stabilized are also classified under UN No. 1010, see Table A of Chapter 3.2. METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED such as mixtures of methylacetylene and propadiene with hydrocarbons, which as: Mixture P1, contain not more than 63% methylacetylene and propadiene by volume and not more than 24% propane and propylene by volume, the percentage of C4- saturated hydrocarbons being not less than 14% by volume; and as Mixture P2, contain not more than 48% methylacetylene and propadiene by volume and not more than 50% propane and propylene by volume, the percentage of C4- saturated hydrocarbons being not less than 5% by volume, as well as mixtures of propadiene with 1 to 4% methylacetylene. - 137 - Liquefied gases (cont'd) Classification UN code No. 1965 2F (cont'd) 2T 2 TF 2 TC 2 TO 2 TFC 2 TOC 3354 3161 1967 3162 3355 3160 3308 3307 3309 3310 Name of the substance or article HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S such as mixtures, which as: Mixture A, have a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l; Mixture A01, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a relative density at 50 °C not lower than 0.516 kg/l; Mixture A02, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a relative density at 50 °C not lower than 0.505 kg/l; Mixture A0, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a density at 50 °C not lower than 0.495 kg/l; Mixture A1, have a vapour pressure at 70 °C not exceeding 2.1 MPa (21 bar) and a density at 50 °C not lower than 0.485 kg/l; Mixture B1 have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a relative density at 50 °C not lower than 0.474 kg/l; Mixture B2 have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a relative density at 50 °C not lower than 0.463 kg/l; Mixture B, have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a density at 50 °C not lower than 0.450 kg/l; Mixture C, have a vapour pressure at 70 °C not exceeding 3.1 MPa (31 bar) and a relative density at 50 °C not lower than 0.440 kg/l; NOTE 1: In the case of the foregoing mixtures, the use of the following names customary in the trade is permitted for describing these substances: for mixtures A, A01, A02 and A0: BUTANE; for mixture C: PROPANE. NOTE 2: UN No. 1075 PETROLEUM GASES, LIQUEFIED may be used as an alternative entry for UN No. 1965 HYDROCARBON GAS MIXTURE LIQUEFIED, N.O.S. for carriage prior to or following maritime or air carriage. INSECTICIDE GAS, FLAMMABLE, N.O.S. LIQUEFIED GAS, FLAMMABLE, N.O.S. INSECTICIDE GAS, TOXIC, N.O.S. LIQUEFIED GAS, TOXIC, N.O.S. INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. Refrigerated liquefied gases Name of the substance or article Classification UN code No. 3158 GAS, REFRIGERATED LIQUID, N.O.S. 3A 3311 GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. 3O 3312 GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. 3F Dissolved gases Classification code 4 UN No. Name of the substance or article Only substances listed in Table A of Chapter 3.2 are to be accepted for carriage. - 138 - Aerosols and receptacles, small, containing gas Name of the substance or article Classification UN code No. 1950 AEROSOLS 5 2037 RECEPTACLES, SMALL CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable Other articles containing gas under pressure Name of the substance or article Classification UN code No. 2857 REFRIGERATING MACHINES containing non-flammable, non-toxic gases or 6A ammonia solutions (UN 2672) 3164 ARTICLES, PRESSURIZED, PNEUMATIC (containing non-flammable gas) or 3164 ARTICLES, PRESSURIZED, HYDRAULIC (containing non-flammable gas) 3150 DEVICES, SMALL, HYDROCARBON GAS POWERED or 6F 3150 HYDROCARBON GAS REFILLS FOR SMALL DEVICES, with release device 3478 FUEL CELL CARTRIDGES, containing liquefied flammable gas or 3478 FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT, containing liquefied flammable gas or 3478 FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing liquefied flammable gas 3479 FUEL CELL CARTRIDGES, containing hydrogen in metal hydride or 3479 FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT, containing hydrogen in metal hydride or 3479 FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing hydrogen in metal hydride Gas samples Classification code 7F 7T 7 TF UN No. 3167 3169 3168 Name of the substance or article GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S., not refrigerated liquid GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid Chemicals under pressure Name of the substance or article UN Classification code No. 3500 CHEMICAL UNDER PRESSURE, N.O.S. 8A 3501 CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S. 8F 3502 CHEMICAL UNDER PRESSURE, TOXIC, N.O.S. 8T 3503 CHEMICAL UNDER PRESSURE, CORROSIVE, N.O.S. 8C 3504 CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S. 8TF 3505 CHEMICAL UNDER PRESSURE, FLAMMABLE, CORROSIVE, N.O.S. 8FC - 139 - Adsorbed gases Classification code 9A 9O 9F 9T 9TF 9TC 9TO 9TFC 9TOC UN No. 3511 3513 3510 3512 3514 3516 3515 3517 3518 Name of the substance or article ADSORBED GAS, N.O.S. ADSORBED GAS, OXIDIZING, N.O.S. ADSORBED GAS, FLAMMABLE, N.O.S. ADSORBED GAS, TOXIC, N.O.S. ADSORBED GAS, TOXIC, FLAMMABLE, N.O.S. ADSORBED GAS, TOXIC, CORROSIVE, N.O.S. ADSORBED GAS, TOXIC, OXIDIZING, N.O.S. ADSORBED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. - 140 - 2.2.3 Class 3 Flammable liquids 2.2.3.1 Criteria 2.2.3.1.1 The heading of Class 3 covers substances and articles containing substances of this Class which: - are liquids according to subparagraph (a) of the definition for "liquid" in 1.2.1; - have at 50 °C a vapour pressure of not more than 300 kPa (3 bar) and are not completely gaseous at 20 °C and at standard pressure of 101.3 kPa; and - have a flash-point of not more than 60 °C (see 2.3.3.1 for the relevant test). The heading of Class 3 also covers liquid substances and molten solid substances with a flash-point of more than 60°C and which are carried or handed over for carriage whilst heated at temperatures equal to or higher than their flash-point. These substances are assigned to UN No. 3256. The heading of Class 3 also covers liquid desensitized explosives. Liquid desensitized explosives are explosive substances which are dissolved or suspended in water or other liquid substances, to form an homogeneous liquid mixture to suppress their explosive properties. Such entries in Table A of Chapter 3.2 are UN Nos. 1204, 2059, 3064, 3343, 3357 and 3379. NOTE 1: Substances having a flash-point above 35 °C, which do not sustain combustion according to the criteria of sub-section 32.2.5 of Part III of the Manual of Tests and Criteria, are not substances of Class 3; if, however, these substances are handed over for carriage and carried whilst heated at temperatures equal to or higher than their flash-point, they are substances of Class 3. NOTE 2: By derogation from paragraph 2.2.3.1.1 above, diesel fuel, gasoil, heating oil (light) including synthetically manufactured products having a flash-point above 60 °C and not more than 100 °C shall be deemed substances of Class 3, UN No. 1202. NOTE 3: Flammable liquids which are highly toxic by inhalation, as defined in 2.2.61.1.4 to 2.2.61.1.9, and toxic substances having a flash-point of 23 °C or above are substances of Class 6.1 (see 2.2.61.1). Liquids which are highly toxic by inhalation are indicated as “toxic by inhalation” in their proper shipping name in Column (2) or by special provision 354 in Column (6) of Table A of Chapter 3.2. NOTE 4: Flammable liquid substances and preparations used as pesticides, which are highly toxic, toxic or slightly toxic and have a flash-point of 23 °C or above are substances of Class 6.1 (see 2.2.61.1). 2.2.3.1.2 The substances and articles of Class 3 are subdivided as follows: F Flammable liquids, without subsidiary risk and articles containing such substances: F1 F2 F3 FT Flammable liquids, toxic: FT1 FT2 FC Flammable liquids having a flash-point of or below 60 °C; Flammable liquids having a flash-point above 60 °C which are carried or handed over for carriage at or above their flash-point (elevated temperature substances); Articles containing flammable liquids; Flammable liquids, toxic; Pesticides; Flammable liquids, corrosive; FTC Flammable liquids, toxic, corrosive; D Liquid desensitized explosives. - 141 - 2.2.3.1.3 Substances and articles classified in Class 3 are listed in Table A of Chapter 3.2. Substances not mentioned by name in Table A of Chapter 3.2 shall be assigned to the relevant entry of 2.2.3.3 and the relevant packing group in accordance with the provisions of this section. Flammable liquids shall be assigned to one of the following packing groups according to the degree of danger they present for carriage: Packing group Flash point (closed cup) --  35°C II a < 23°C > 35°C III a  23°C  60°C > 35°C I a Initial boiling point See also 2.2.3.1.4. For a liquid with (a) subsidiary risk(s), the packing group determined in accordance with the table above and the packing group based on the severity of the subsidiary risk(s) shall be considered; the classification and packing group shall then be determined in accordance with the table of precedence of hazards in 2.1.3.10. 2.2.3.1.4 Viscous flammable liquids such as paints, enamels, lacquers, varnishes, adhesives and polishes having a flash-point of less than 23 °C may be assigned to packing group III in conformity with the procedures prescribed in the Manual of Tests and Criteria, Part III, sub-section 32.3, provided that: (a) the viscosity2 and flash-point are in accordance with the following table: Kinematic viscosity (extrapolated)  (at near-zero shear rate) mm2/s at 23°C Flow-time t in seconds Jet diameter (mm) Flash-point, closed-cup (°C) 20 <   80 20 < t  60 4 above 17 80 <   135 60 < t  100 4 above 10 135 <   220 20 < t  32 6 above 5 220 <   300 32 < t  44 6 above -1 300 <   700 44 < t  100 6 above -5 700 <  100 < t 6 no limit (b) Less than 3% of the clear solvent layer separates in the solvent separation test; (c) The mixture or any separated solvent does not meet the criteria for Class 6.1 or Class 8; (d) The substances are packed in receptacles of not more than 450 litre capacity. NOTE: These provisions also apply to mixtures containing no more than 20% nitrocellulose with a nitrogen content not exceeding 12.6% by dry mass. Mixtures containing more than 20% but not more than 55% nitrocellulose with a nitrogen content not exceeding 12.6% by dry mass are substances assigned to UN No. 2059. Mixtures having a flash-point below 23 °C and containing: – more than 55% nitrocellulose, whatever their nitrogen content; or – not more than 55% nitrocellulose with a nitrogen content above 12.6% by dry mass, are substances of Class 1 (UN Nos. 0340 or 0342) or of Class 4.1 (UN Nos. 2555, 2556 or2557). Viscosity determination: Where the substance concerned is non-Newtonian, or where a flow cup method of viscosity determination is otherwise unsuitable, a variable shear-rate viscometer shall be used to determine the dynamic viscosity coefficient of the substance, at 23 °C, at a number of shear rates. The values obtained are plotted against shear rate and then extrapolated to zero shear rate. The dynamic viscosity thus obtained, divided by the density, gives the apparent kinematic viscosity at near-zero shear rate. 2 - 142 - 2.2.3.1.5 Viscous liquids which: - have a flash-point of 23 °C or above and less than or equal to 60 °C; - are not toxic, corrosive or environmentally hazardous; - contain not more than 20% nitrocellulose provided the nitrocellulose contains not more than 12.6% nitrogen by dry mass; and - are packed in receptacles of not more than 450 litre capacity; are not subject to ADR, if: 2.2.3.1.6 (a) in the solvent separation test (see Manual of Tests and Criteria, Part III, sub-section 32.5.1), the height of the separated layer of solvent is less than 3% of the total height; and (b) the flowtime in the viscosity test (see Manual of Tests and Criteria, Part III, subsection 32.4.3), with a jet diameter of 6 mm is equal to or greater than: (i) 60 seconds; or (ii) 40 seconds if the viscous liquid contains not more than 60% of Class 3 substances. If substances of Class 3, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes) see also 2.1.3. 2.2.3.1.7 On the basis of the test procedures in accordance with 2.3.3.1 and 2.3.4, and the criteria set out in 2.2.3.1.1, it may also be determined whether the nature of a solution or a mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the provisions for this Class (see also 2.1.3). 2.2.3.2 Substances not accepted for carriage 2.2.3.2.1 Substances of Class 3 which are liable to form peroxides easily (as happens with ethers or with certain heterocyclic oxygenated substances) shall not be accepted for carriage if their peroxide content, calculated as hydrogen peroxide (H2O2), exceeds 0.3%. The peroxide content shall be determined as indicated in 2.3.3.3. 2.2.3.2.2 The chemically unstable substances of Class 3 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall be ensured in particular that receptacles and tanks do not contain any substance liable to promote these reactions. 2.2.3.2.3 Liquid desensitized explosives other than those listed in Table A of Chapter 3.2 shall not be accepted for carriage as substances of Class 3. - 143 - 2.2.3.3 List of collective entries Flammable liquids and articles containing such substances F1 Without subsidiary risk F 1133 ADHESIVES containing flammable liquid 1136 COAL TAR DISTILLATES, FLAMMABLE 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining) 1169 EXTRACTS, AROMATIC, LIQUID 1197 EXTRACTS, FLAVOURING, LIQUID 1210 PRINTING INK, flammable or 1210 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or 1263 PAINT RELATED MATERIAL (including paint thinning or reducing compound) 1266 PERFUMERY PRODUCTS with flammable solvents 1293 TINCTURES, MEDICINAL 1306 WOOD PRESERVATIVES, LIQUID 1866 RESIN SOLUTION, flammable 1999 TARS, LIQUID, including road oils, and cutback bitumens 3065 ALCOHOLIC BEVERAGES 1224 KETONES, LIQUID, N.O.S. 1268 PETROLEUM DISTILLATES, N.O.S. or 1268 PETROLEUM PRODUCTS, N.O.S. 1987 ALCOHOLS, N.O.S. 1989 ALDEHYDES, N.O.S. 2319 TERPENE HYDROCARBONS, N.O.S. 3271 ETHERS, N.O.S. 3272 ESTERS, N.O.S. 3295 HYDROCARBONS, LIQUID, N.O.S. 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or 3336 MERCAPTANS MIXTURE, LIQUID, FLAMMABLE, N.O.S. 1993 FLAMMABLE LIQUID, N.O.S. F2 3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S., with flash-point above 60 °C, elevated at or above its flash-point temperature F3 articles 3269 POLYESTER RESIN KIT 3473 FUEL CELL CARTRIDGES or 3473 FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or 3473 FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT (cont'd on next page) - 144 - 2.2.3.3 List of collective entries (cont'd) FT1 Toxic FT FT2 pesticide (f.p<23 °C) Liquid desensitised explosive 2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE TOXIC 3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S. NOTE: The classification of a pesticide under an entry shall be effected on the basis of the active ingredient, of the physical state of the pesticide and any subsidiary risks it may exhibit. FC 3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or 3469 PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or 2733 POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 2985 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. 3274 ALCOHOLATES SOLUTION, N.O.S., in alcohol 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. FTC 3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. Corrosive Toxic, corrosive 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or 1228 MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or 2478 ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. 3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. D 3343 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin by mass 3357 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin by mass 3379 DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. - 145 - 2.2.41 Class 4.1 Flammable solids, self-reactive substances and solid desensitized explosives 2.2.41.1 Criteria 2.2.41.1.1 The heading of Class 4.1 covers flammable substances and articles, desensitized explosives which are solids according to subparagraph (a) of the definition "solid" in 1.2.1 and self-reactive liquids or solids. The following are assigned to Class 4.1: 2.2.41.1.2 - readily flammable solid substances and articles (see paragraphs 2.2.41.1.3 to 2.2.41.1.8); - self-reactive solids or liquids (see paragraphs 2.2.41.1.9 to 2.2.41.1.17); - solid desensitized explosives (see 2.2.41.1.18); - substances related to self-reactive substances (see 2.2.41.1.19). The substances and articles of Class 4.1 are subdivided as follows: F Flammable solids, without subsidiary risk: F1 F2 F3 Organic; Organic, molten; Inorganic; FO Flammable solids, oxidizing; FT Flammable solids, toxic: FT1 FT2 FC Organic, toxic; Inorganic, toxic; Flammable solids, corrosive: FC1 FC2 Organic, corrosive; Inorganic, corrosive; D Solid desensitized explosives without subsidiary risk; DT Solid desensitized explosives, toxic; SR Self-reactive substances: SR1 SR2 Not requiring temperature control; Requiring temperature control. Flammable solids Definition and properties 2.2.41.1.3 Flammable solids are readily combustible solids and solids which may cause fire through friction. Readily combustible solids are powdered, granular, or pasty substances which are dangerous if they can be easily ignited by brief contact with an ignition source, such as a burning match, and if the flame spreads rapidly. The danger may come not only from the fire but also from toxic combustion products. Metal powders are especially dangerous because of the difficulty of extinguishing a fire since normal extinguishing agents such as carbon dioxide or water can increase the hazard. Classification 2.2.41.1.4 Substances and articles classified as flammable solids of Class 4.1 are listed in Table A of Chapter 3.2. The assignment of organic substances and articles not mentioned by name in Table A of - 146 - Chapter 3.2 to the relevant entry of sub-section 2.2.41.3 in accordance with the provisions of Chapter 2.1 can be based on experience or on the results of the test procedures in accordance with Part III, subsection 33.2.1 of the Manual of Tests and Criteria. The assignment of inorganic substances not mentioned by name shall be based on the results of the test procedures in accordance with Part III, sub-section 33.2.1 of the Manual of Tests and Criteria; experience shall also be taken into account when it leads to a more stringent assignment. 2.2.41.1.5 When substances not mentioned by name are assigned to one of the entries listed in 2.2.41.3 on the basis of the test procedures in accordance with the Manual of Tests and Criteria, Part III, sub-section 33.2.1, the following criteria apply: (a) With the exception of metal powders or powders of metal alloys, powdery, granular or pasty substances shall be classified as readily flammable substances of Class 4.1 if they can be easily ignited by brief contact with an ignition source (e.g. a burning match), or if, in the event of ignition, the flame spreads rapidly, the burning time is less than 45 seconds for a measured distance of 100 mm or the rate of burning is greater than 2.2 mm/s; (b) Metal powders or powders of metal alloys shall be assigned to Class 4.1 if they can be ignited by a flame and the reaction spreads over the whole length of the sample in 10 minutes or less. Solids which may cause fire through friction shall be classified in Class 4.1 by analogy with existing entries (e.g. matches) or in accordance with any appropriate special provision. 2.2.41.1.6 On the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part III, Section 33.2.1 and the criteria set out in 2.2.41.1.4 and 2.2.41.1.5, it may also be determined whether the nature of a substance mentioned by name is such that the substance is not subject to the provisions for this Class. 2.2.41.1.7 If substances of Class 4.1, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. Assignment of packing groups 2.2.41.1.8 Flammable solids classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, sub-section 33.2.1, in accordance with the following criteria: (a) (b) Readily flammable solids which, when tested, have a burning time of less than 45 seconds over a measured distance of 100 mm shall be assigned to: Packing group II: if the flame passes the wetted zone; Packing group III: if the wetted zone stops the flame for at least four minutes; Metal powders or powders of metal alloys shall be assigned to: Packing group II: if, when tested, the reaction spreads over the whole length of the sample in five minutes or less; Packing group III: if, when tested, the reaction spreads over the whole length of the sample in more than five minutes. For solids which may cause fire through friction, the packing group shall be assigned by analogy with existing entries or in accordance with any special provision. - 147 - Self-reactive substances Definitions 2.2.41.1.9 For the purposes of ADR, self-reactive substances are thermally unstable substances liable to undergo a strongly exothermic decomposition even without participation of oxygen (air). Substances are not considered to be self-reactive substances of Class 4.1, if: (a) they are explosives according to the criteria of Class 1; (b) they are oxidizing substances according to the classification procedure for Class 5.1 (see 2.2.51.1) except that mixtures of oxidizing substances which contain 5% or more of combustible organic substances shall be subjected to the classification procedure defined in Note 2; (c) they are organic peroxides according to the criteria of Class 5.2 (see 2.2.52.1); (d) their heat of decomposition is less than 300 J/g; or (e) their self-accelerating decomposition temperature (SADT) (see Note 3 below) is greater than 75 °C for a 50 kg package. NOTE 1: The heat of decomposition can be determined using any internationally recognised method e.g. differential scanning calorimetry and adiabatic calorimetry. NOTE 2: Mixtures of oxidizing substances meeting the criteria of Class 5.1 which contain 5% or more of combustible organic substances, which do not meet the criteria mentioned in (a), (c), (d) or (e) above, shall be subjected to the self-reactive substance classification procedure. A mixture showing the properties of a self-reactive substance, type B to F, shall be classified as a selfreactive substance of Class 4.1. A mixture showing the properties of a self-reactive substance, type G, according to the principle given in sub-section 20.4.3 (g) of Part II of the Manual of Tests and Criteria shall be considered for classification as a substance of Class 5.1 (see 2.2.51.1). NOTE 3: The self-accelerating decomposition temperature (SADT) is the lowest temperature at which self-accelerating decomposition may occur with a substance in the packaging as used during carriage. Requirements for the determination of the SADT are given in the Manual of Tests and Criteria, Part II, Chapter 20 and section 28.4. NOTE 4: Any substance which shows the properties of a self-reactive substance shall be classified as such, even if this substance gives a positive test result according to 2.2.42.1.5 for inclusion in Class 4.2. Properties 2.2.41.1.10 The decomposition of self-reactive substances can be initiated by heat, contact with catalytic impurities (e.g. acids, heavy-metal compounds, bases), friction or impact. The rate of decomposition increases with temperature and varies with the substance. Decomposition, particularly if no ignition occurs, may result in the evolution of toxic gases or vapours. For certain self-reactive substances, the temperature shall be controlled. Some self-reactive substances may decompose explosively, particularly if confined. This characteristic may be modified by the addition of diluents or by the use of appropriate packagings. Certain self-reactive substances burn vigorously. Self-reactive substances are, for example, some compounds of the types listed below: aliphatic azo compounds (-C-N=N-C-); organic azides (-C-N3); diazonium salts (-CN2+ Z-); N-nitroso compounds (-N-N=O); and aromatic sulphohydrazides (-SO2-NH-NH2). - 148 - This list is not exhaustive and substances with other reactive groups and some mixtures of substances may have similar properties. Classification 2.2.41.1.11 Self-reactive substances are classified into seven types according to the degree of danger they present. The types of self-reactive substances range from type A, which is not accepted for carriage in the packaging in which it is tested, to type G, which is not subject to the provisions for self-reactive substances of Class 4.1. The classification of types B to F is directly related to the maximum quantity allowed in one packaging. The principles to be applied for classification as well as the applicable classification procedures, test methods and criteria and an example of a suitable test report are given in Part II of the Manual of Tests and Criteria. 2.2.41.1.12 Self-reactive substances which have already been classified and are already permitted for carriage in packagings are listed in 2.2.41.4, those already permitted for carriage in IBCs are listed in 4.1.4.2, packing instruction IBC520 and those already permitted for carriage in tanks according to Chapter 4.2 are listed in 4.2.5.2, portable tank instruction T23. Each permitted substance listed is assigned to a generic entry of Table A of Chapter 3.2 (UN Nos. 3221 to 3240), and appropriate subsidiary risks and remarks providing relevant transport information are given. The collective entries specify: - self-reactive substances types B to F, see 2.2.41.1.11 above; - physical state (liquid/solid); and - temperature control (when required), see 2.2.41.1.17 below. The classification of the self-reactive substances listed in 2.2.41.4 is based on the technically pure substance (except where a concentration of less than 100% is specified). 2.2.41.1.13 Classification of self-reactive substances not listed in 2.2.41.4, 4.1.4.2, packing instruction IBC520 or 4.2.5.2, portable tank instruction T23 and assignment to a collective entry shall be made by the competent authority of the country of origin on the basis of a test report. The statement of approval shall contain the classification and the relevant conditions of carriage. If the country of origin is not a Contracting Party to ADR, the classification and the conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. 2.2.41.1.14 Activators, such as zinc compounds, may be added to some self-reactive substances to change their reactivity. Depending on both the type and the concentration of the activator, this may result in a decrease in thermal stability and a change in explosive properties. If either of these properties is altered, the new formulation shall be assessed in accordance with the classification procedure. 2.2.41.1.15 Samples of self-reactive substances or formulations of self-reactive substances not listed in 2.2.41.4, for which a complete set of test results is not available and which are to be carried for further testing or evaluation, shall be assigned to one of the appropriate entries for self-reactive substances type C provided the following conditions are met: - the available data indicate that the sample would be no more dangerous than self-reactive substances type B; - the sample is packaged in accordance with packing method OP2 and the quantity per transport unit is limited to 10 kg; - the available data indicate that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation. Desensitization 2.2.41.1.16 In order to ensure safety during carriage, self-reactive substances are in many cases desensitized by use of a diluent. Where a percentage of a substance is stipulated, this refers to the percentage by mass, rounded to the nearest whole number. If a diluent is used, the self-reactive substance shall be tested with the diluent present in the concentration and form used in carriage. Diluents which may allow a - 149 - self-reactive substance to concentrate to a dangerous extent in the event of leakage from a packaging shall not be used. Any diluent shall be compatible with the self-reactive substance. In this regard, compatible diluents are those solids or liquids which have no detrimental influence on the thermal stability and hazard type of the self-reactive substance. Liquid diluents in formulations requiring temperature control (see 2.2.41.1.14) shall have a boiling point of at least 60 °C and a flash-point not less than 5 °C. The boiling point of the liquid shall be at least 50 °C higher than the control temperature of the self-reactive substance. Temperature control requirements 2.2.41.1.17 Certain self-reactive substances may only be carried under temperature controlled conditions. The control temperature is the maximum temperature at which the self-reactive substance can be safely carried. It is assumed that the temperature of the immediate surroundings of a package only exceeds 55 °C during carriage for a relatively short time in a 24 hour period. In the event of loss of temperature control, it may be necessary to implement emergency procedures. The emergency temperature is the temperature at which such procedures shall be implemented. The control and emergency temperatures are derived from the SADT (see table 1). The SADT shall be determined in order to decide whether a substance shall be subjected to temperature control during carriage. Provisions for the determination of the SADT are given in the Manual of Tests and Criteria, Part II, Chapter 20 and Section 28.4. Table 1: Derivation of control and emergency temperatures SADT a Type of receptacle Single packagings and IBCs Tanks a Control temperature 20 °C or less 20 °C below SADT Emergency temperature 10 °C below SADT over 20 °C to 35 °C over 35 °C not greater than 50 °C 15 °C below SADT 10 °C below SADT 10 °C below SADT 10 °C below SADT 5 °C below SADT 5 °C below SADT SADT of the substance as packaged for carriage. Self-reactive substances with an SADT not greater than 55 °C shall be subject to temperature control during carriage. Where applicable, control and emergency temperatures are listed in 2.2.41.4. The actual temperature during carriage may be lower than the control temperature but shall be selected so as to avoid dangerous separation of phases. Solid desensitized explosives 2.2.41.1.18 Solid desensitized explosives are substances which are wetted with water or alcohols or are diluted with other substances to suppress their explosive properties. Such entries in Table A of Chapter 3.2 are: UN Nos. 1310, 1320, 1321, 1322, 1336, 1337, 1344, 1347, 1348, 1349, 1354, 1355, 1356, 1357, 1517, 1571, 2555, 2556, 2557, 2852, 2907, 3317, 3319, 3344, 3364, 3365, 3366, 3367, 3368, 3369, 3370, 3376, 3380 and 3474. Substances related to self-reactive substances 2.2.41.1.19 Substances that: (a) have been provisionally accepted into Class 1 according to Test Series 1 and 2 but exempted from Class 1 by Test Series 6; (b) are not self-reactive substances of Class 4.1; and (c) are not substances of Classes 5.1 or 5.2; are also assigned to Class 4.1. UN Nos. 2956, 3241, 3242 and 3251 are such entries. - 150 - 2.2.41.2 Substances not accepted for carriage 2.2.41.2.1 The chemically unstable substances of Class 4.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall in particular be ensured that receptacles and tanks do not contain any substance liable to promote these reactions. 2.2.41.2.2 Flammable solids, oxidizing, assigned to UN No. 3097 shall not be accepted for carriage unless they meet the requirements for Class 1 (see also 2.1.3.7). 2.2.41.2.3 The following substances shall not be accepted for carriage: - Self-reactive substances of type A (see Manual of Tests and Criteria, Part II, paragraph 20.4.2 (a)); - Phosphorus sulphides which are not free from yellow and white phosphorus; - Solid densitized explosives other than those listed in Table A of Chapter 3.2; - Inorganic flammable substances in the molten form other than UN No. 2448 SULPHUR, MOLTEN. - 151 - 2.2.41.3 List of collective entries without subsidiary risk 3175 SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. 1353 FIBRES IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. or 1353 FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. organic F1 organic molten F2 3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. F3 3089 METAL POWDER, FLAMMABLE, N.O.S. 3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. a b inorganic c 3182 METAL HYDRIDES, FLAMMABLE,N.O.S. 3178 FLAMMABLE SOLID, INORGANIC, N.O.S. Flammable solids FO 3097 FLAMMABLE SOLID, OXIDIZING, N.O.S. (not allowed, see para. 2.2.41.2.2) organic FT1 2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. inorganic FT2 3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. organic FC1 2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. inorganic FC2 3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. D 3319 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin by mass 3344 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE, PETN) MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN by mass 3380 DESENSITIZED EXPLOSIVE, SOLID, N.O.S. oxidizing toxic FT corrosive FC without subsidiary risk Solid desensitized explosives toxic not requiring temperature control DT SR1 Self-reactive substances SR requiring temperature control SR2 Only substances listed in Table A of Chapter 3.2 are to be accepted for carriage as substances of Class 4.1 3221 3222 3223 3224 3225 3226 3227 3228 3229 3230 3231 3232 3233 3234 3235 3236 3237 3238 3239 3240 SELF-REACTIVE LIQUID TYPE A SELF-REACTIVE SOLID TYPE A SELF-REACTIVE LIQUID TYPE B SELF-REACTIVE SOLID TYPE B SELF-REACTIVE LIQUID TYPE C SELF-REACTIVE SOLID TYPE C SELF-REACTIVE LIQUID TYPE D SELF-REACTIVE SOLID TYPE D SELF-REACTIVE LIQUID TYPE E SELF-REACTIVE SOLID TYPE E SELF-REACTIVE LIQUID TYPE F SELF-REACTIVE SOLID TYPE F SELF-REACTIVE LIQUID TYPE G SELF-REACTIVE SOLID TYPE G accepted for carriage, } Not see 2.2.41.2.3 subject to the provisions applicable to } Not Class 4.1, see 2.2.41.1.11 SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED Metals and metal alloys in powdered or other flammable form, liable to spontaneous combustion, are substances of Class 4.2. b Metals and metal alloys in powdered or other flammable form, which in contact with water, emit flammable gases, are substances of Class 4.3. c Metals hydrides which, in contact with water, emit flammable gases, are substances of Class 4.3. Aluminium borohydride or aluminium borohydride in devices are substances of Class 4.2, UN No. 2870. a - 152 - 2.2.41.4 List of currently assigned self-reactive substances in packagings In the column "Packing Method" codes "OP1" to "OP8" refer to packing methods in 4.1.4.1, packing instruction P520 (see also 4.1.7.1). Self-reactive substances to be carried shall fulfil the classification and the control and emergency temperatures (derived from the SADT) as listed. For substances permitted in IBCs, see 4.1.4.2, packing instruction IBC520 and, for those permitted in tanks according to Chapter 4.2, see 4.2.5.2, portable tank instruction T23. NOTE: The classification given in this table is based on the technically pure substance (except where a concentration of less than 100% is specified). For other concentrations, the substance may be classified differently following the procedures given in Part II of the Manual of Tests and Criteria and in 2.2.41.1.17. SELF-REACTIVE SUBSTANCE Concentration (%) Packing method ACETONE-PYROGALLOL COPOLYMER 2-DIAZO-1-NAPHTHOL-5-SULPHONATE AZODICARBONAMIDE FORMULATION TYPE B, TEMPERATURE CONTROLLED AZODICARBONAMIDE FORMULATION TYPE C AZODICARBONAMIDE FORMULATION TYPE C, TEMPERATURE CONTROLLED AZODICARBONAMIDE FORMULATION TYPE D AZODICARBONAMIDE FORMULATION TYPE D, TEMPERATURE CONTROLLED 2,2' -AZODI(2,4-DIMETHYL- 4-METHOXYVALERONITRILE) 2,2' -AZODI(2,4-DIMETHYL- VALERONITRILE) 2,2' -AZODI(ETHYL- 2-METHYL-PROPIONATE) 1,1-AZODI(HEXAHYDROBENZONITRILE) 2,2' -AZODI(ISOBUTYRONITRILE 2,2' -AZODI(ISOBUTYRONITRILE) as a water based paste 2,2' -AZODI(2-METHYLBUTYRONITRILE) BENZENE-1,3-DISULPHONYL HYDRAZIDE, as a paste BENZENE SULPHONYL HYDRAZIDE 4-(BENZYL(ETHYL)AMINO)-3-ETHOXYBENZENEDIAZONIUM ZINC CHLORIDE 4-(BENZYL(METHYL)AMINO)-3-ETHOXYBENZENEDIAZONIUM ZINC CHLORIDE 3-CHLORO-4-DIETHYLAMINOBENZENEDIAZONIUM ZINC CHLORIDE 2-DIAZO-1-NAPHTHOL-4-SULPHONYL CHLORIDE 2-DIAZO-1-NAPHTHOL-5-SULPHONYL CHLORIDE 2-DIAZO-1-NAPHTHOL SULPHONIC ACID ESTER MIXTURE, TYPE D 2,5-DIBUTOXY-4-(4-MORPHOLINYL)BENZENEDIAZONIUM, TETRACHLOROZINCATE (2:1) 2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE 2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE 2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM TETRAFLUOROBORATE 2,5-DIETHOXY-4-(4-MORPHOLINYL)BENZENEDIAZONIUM SULPHATE 100 OP8 < 100 OP5 3232 (1) (2) < 100 < 100 OP6 OP6 3224 3234 (3) (4) < 100 < 100 OP7 OP7 3226 3236 (5) (6) 100 OP7 -5 +5 3236 100 100 100 100 +10 +20 +15 +25 +40 +45  50% OP7 OP7 OP7 OP6 OP6 3236 3235 3226 3234 3224 100 52 OP7 OP7 +35 +40 100 100 OP7 OP7 100 OP7 100 OP7 3226 100 100 < 100 OP5 OP5 OP7 3222 3222 3226 100 OP8 3228 67-100 OP7 +35 +40 3236 66 OP7 +40 +45 3236 100 OP7 +30 +35 3236 100 OP7 - 153 - Control Emergency UN Remarks tempera- tempera- generic ture ture entry (°C) (°C) 3228 3236 3226 3226 3226 +40 +45 3236 3226 (2) (2) (9) SELF-REACTIVE SUBSTANCE Concentration (%) Packing method 2,5-DIETHOXY-4-(PHENYLSULPHONYL)BENZENEDIAZONIUM ZINC CHLORIDE DIETHYLENEGLYCOL BIS (ALLYL CARBONATE) + DI- ISOPROPYL-PEROXYDICARBONATE 2,5-DIMETHOXY-4-(4-METHYLPHENYLSULPHONYL)BENZENE- DIAZONIUM ZINC CHLORIDE 4-(DIMETHYLAMINO)-BENZENE-DIAZONIUM TRICHLOROZINCATE (-1) 4-DIMETHYLAMINO-6-(2-DIMETHYLAMINOETHOXY) TOLUENE- 2-DIAZONIUM ZINC CHLORIDE N,N'-DINITROSO-N,N'- DIMETHYL TEREPHTHALAMIDE, as a paste N,N'-DINITROSOPENTAMETHYLENETETRAMINE DIPHENYLOXIDE-4,4'-DISULPHONYL HYDRAZIDE 4-DIPROPYLAMINOBENZENE- DIAZONIUM ZINC CHLORIDE 2-(N,N-ETHOXYCARBONYLPHENYLAMINO)-3-METHOXY-4(N-METHYL-N-CYCLOHEXYLAMINO) BENZENEDIAZONIUM ZINC CHLORIDE 2-(N,N-ETHOXYCARBONYLPHENYLAMINO)-3-METHOXY-4(N-METHYL-N-CYCLOHEXYLAMINO) BENZENEDIAZONIUM ZINC CHLORIDE N-FORMYL-2-(NITROMETHYLENE) -1,3-PERHYDROTHIAZINE 2-(2-HYDROXYETHOXY)-1(PYRROLIDIN-1-YL)BENZENE-4- DIAZONIUM ZINC CHLORIDE 3-(2-HYDROXYETHOXY)-4- (PYRROLIDIN-1-YL) BENZENE DIAZONIUM ZINC CHLORIDE 2-(N,N-METHYLAMINOETHYLCARBONYL)4-(3,4-DIMETHYLPHENYLSULPHONYL) BENZENEDIAZONIUM HYDROGEN SULPHATE 4-METHYLBENZENESULPHONYLHYDRAZIDE 3-METHYL-4-(PYRROLIDIN-1-YL) BENZENEDIAZONIUM TETRAFLUOROBORATE 4-NITROSOPHENOL SELF-REACTIVE LIQUID, SAMPLE SELF-REACTIVE LIQUID, SAMPLE, TEMPERATURE CONTROLLED SELF-REACTIVE SOLID, SAMPLE SELF-REACTIVE SOLID, SAMPLE, TEMPERATURE CONTROLLED SODIUM 2-DIAZO-1-NAPHTHOL- 4-SULPHONATE SODIUM 2-DIAZO-1-NAPHTHOL- 5-SULPHONATE TETRAMINE PALLADIUM (II) NITRATE 67 OP7 Control Emergency UN Remarks tempera- tempera- generic ture ture entry (°C) (°C) +40 +45 3236  88+ 12 OP8 -10 0 3237 79 OP7 +40 +45 3236 100 OP8 100 OP7 72 OP6 3224 82 OP6 3224 100 OP7 3226 100 OP7 3226 63-92 OP7 + 40 + 45 3236 62 OP7 + 35 + 40 3236 100 OP7 +45 +50 3236 100 OP7 + 45 + 50 3236 100 OP7 +40 +45 3236 96 OP7 +45 +50 3236 100 95 OP7 OP6 +45 +50 3226 3234 100 OP7 OP2 OP2 +35 +40 100 100 100 - 154 - 3228 +40 +45 3236 (7) 3236 3223 3233 (8) (8) OP2 OP2 3224 3234 (8) (8) OP7 OP7 OP6 3226 3226 3234 +30 +35 Remarks (1) Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (b) of the Manual of Tests and Criteria. The control and emergency temperatures shall be determined by the procedure given in 2.2.41.1.17. (2) "EXPLOSIVE" subsidiary risk label required (Model No. 1, see 5.2.2.2.2). (3) Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (c) of the Manual of Tests and Criteria. (4) Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (c) of the Manual of Tests and Criteria. The control and emergency temperatures shall be determined by the procedure given in 2.2.41.1.17. (5) Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (d) of the Manual of Tests and Criteria. (6) Azodicarbonamide formulations which fulfil the criteria of paragraph 20.4.2 (d) of the Manual of Tests and Criteria. The control and emergency temperatures shall be determined by the procedure given in 2.2.41.1.17. (7) With a compatible diluent having a boiling point of not less than 150 °C. (8) See 2.2.41.1.15. (9) This entry applies to mixtures of esters of 2-diazo-1-naphthol-4-sulphonic acid and 2-diazo-1naphthol-5-sulphonic acid which fulfil the criteria of paragraph 20.4.2 (d) of the Manual of Test and Criteria. - 155 - 2.2.42 Class 4.2 2.2.42.1 Criteria 2.2.42.1.1 The heading of Class 4.2 covers: 2.2.42.1.2 Substances liable to spontaneous combustion - Pyrophoric substances which are substances, including mixtures and solutions (liquid or solid), which even in small quantities ignite on contact with air within five minutes. These are the Class 4.2 substances the most liable to spontaneous combustion; and - Self-heating substances and articles which are substances and articles, including mixtures and solutions, which, on contact with air, without energy supply, are liable to self-heating. These substances will ignite only in large amounts (kilograms) and after long periods of time (hours or days). The substances and articles of Class 4.2 are subdivided as follows: S Substances liable to spontaneous combustion, without subsidiary risk: S1 S2 S3 S4 S5 Organic, liquid; Organic, solid; Inorganic, liquid; Inorganic, solid; Organometallic; SW Substances liable to spontaneous combustion, which, in contact with water, emit flammable gases; SO Substances liable to spontaneous combustion, oxidizing; ST Substances liable to spontaneous combustion, toxic: ST1 ST2 ST3 ST4 SC Organic, toxic, liquid; Organic, toxic, solid; Inorganic, toxic, liquid; Inorganic, toxic, solid; Substances liable to spontaneous combustion, corrosive: SC1 SC2 SC3 SC4 Organic, corrosive, liquid; Organic, corrosive, solid; Inorganic, corrosive, liquid; Inorganic, corrosive, solid. Properties 2.2.42.1.3 Self-heating of a substance is a process where the gradual reaction of that substance with oxygen (in air) generates heat. If the rate of heat production exceeds the rate of heat loss, then the temperature of the substance will rise which, after an induction time, may lead to self-ignition and combustion. Classification 2.2.42.1.4 Substances and articles classified in Class 4.2 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant specific N.O.S. entry of 2.2.42.3 in accordance with the provisions of Chapter 2.1 can be based on experience or the results of the test procedures in accordance with the Manual of Tests and Criteria, Part III, Section 33.3. Assignment to general N.O.S. entries of Class 4.2 shall be based on the results of the test procedures in accordance with the Manual of Tests and Criteria, Part III, section 33.3; experience shall also be taken into account when it leads to a more stringent assignment. - 156 - 2.2.42.1.5 When substances or articles not mentioned by name are assigned to one of the entries listed in 2.2.42.3 on the basis of the test procedures in accordance with the Manual of Tests and Criteria, Part III, section 33.3, the following criteria shall apply: (a) Solids liable to spontaneous combustion (pyrophoric) shall be assigned to Class 4.2 when they ignite on falling from a height of 1 m or within five minutes; (b) Liquids liable to spontaneous combustion (pyrophoric) shall be assigned to Class 4.2 when: (c) (i) on being poured on an inert carrier, they ignite within five minutes, or (ii) in the event of a negative result of the test according to (i), when poured on a dry, indented filter paper (Whatman No. 3 filter), they ignite or carbonize it within five minutes; Substances in which, in a 10 cm sample cube, at 140 °C test temperature, spontaneous combustion or a rise in temperature to over 200 °C is observed within 24 hours shall be assigned to Class 4.2. This criterion is based on the temperature of the spontaneous combustion of charcoal, which is at 50 °C for a sample cube of 27 m3. Substances with a temperature of spontaneous combustion higher than 50 °C for a volume of 27 m3 are not to be assigned to Class 4.2. NOTE 1: Substances carried in packages with a volume of not more than 3 m3 are exempted from Class 4.2 if, tested with a 10 cm sample cube at 120 °C, no spontaneous combustion nor a rise in temperature to over 180 °C is observed within 24 hours. NOTE 2: Substances carried in packages with a volume of not more than 450 litres are exempted from Class 4.2 if, tested with a 10 cm sample cube at 100 °C, no spontaneous combustion nor a rise in temperature to over 160 °C is observed within 24 hours. NOTE 3: Since organometallic substances can be classified in Class 4.2 or 4.3 with additional subsidiary risks, depending on their properties, a specific classification flow chart for these substances is given in 2.3.5. 2.2.42.1.6 If substances of Class 4.2, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. 2.2.42.1.7 On the basis of the test procedure in the Manual of Tests and Criteria, Part III, section 33.3 and the criteria set out in 2.2.42.1.5, it may also be determined whether the nature of a substance mentioned by name is such that the substance is not subject to the provisions for this Class. Assignment of packing groups 2.2.42.1.8 Substances and articles classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, section 33.3, in accordance with the following criteria: (a) Substances liable to spontaneous combustion (pyrophoric) shall be assigned to packing group I; (b) Self-heating substances and articles in which, in a 2.5 cm sample cube, at 140 °C test temperature, spontaneous combustion or a rise in temperature to over 200 °C is observed within 24 hours, shall be assigned to packing group II; Substances with a temperature of spontaneous combustion higher than 50 °C for a volume of 450 litres are not to be assigned to packing group II; - 157 - (c) 2.2.42.2 Slightly self-heating substances in which, in a 2.5 cm sample cube, the phenomena referred to under (b) are not observed, in the given conditions, but in which in a 10 cm sample cube at 140 °C test temperature spontaneous combustion or a rise in temperature to over 200 °C is observed within 24 hours, shall be assigned to packing group III. Substances not accepted for carriage The following substances shall not be accepted for carriage: - UN No. 3255 tert-BUTYL HYPOCHLORITE; and - Self-heating solids, oxidizing, assigned to UN No. 3127 unless they meet the requirements for Class 1 (see 2.1.3.7). - 158 - 2.2.42.3 List of collective entries Substances liable to spontaneous combustion liquid S1 2845 3183 PYROPHORIC LIQUID, ORGANIC, N.O.S. SELF-HEATING LIQUID, ORGANIC, N.O.S. 1373 organic solid S2 2006 3313 2846 3088 FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC, N.O.S. with oil PLASTICS, NITROCELLULOSE-BASED, SELF-HEATING, N.O.S. ORGANIC PIGMENTS, SELF HEATING PYROPHORIC SOLID, ORGANIC, N.O.S. SELF-HEATING SOLID, ORGANIC, N.O.S. liquid S3 3194 3186 PYROPHORIC LIQUID, INORGANIC, N.O.S. SELF-HEATING LIQUID, INORGANIC, N.O.S. 1383 1383 1378 2881 3189a 3205 3200 3190 PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. METAL CATALYST, WETTED with a visible excess of liquid METAL CATALYST, DRY METAL POWDER, SELF-HEATING, N.O.S. ALKALINE EARTH METAL ALCOHOLATES, N.O.S. PYROPHORIC SOLID, INORGANIC, N.O.S. SELF-HEATING SOLID, INORGANIC, N.O.S. 3392 3391 3400 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC ORGANOMETALLIC SUBSTANCE, SOLID, SELF-HEATING Without subsidiary risk S inorganic solid S4 organometallic S5 Water-reactive SW 3394 3393 Oxidizing SO ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATER-REACTIVE 3127 SELF-HEATING SOLID, OXIDIZING, N.O.S. (not allowed, see 2.2.42.2) liquid ST1 3184 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. solid ST2 3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. liquid ST3 3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. solid ST4 3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. liquid SC1 3185 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. solid SC2 3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. liquid SC3 3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. 3206 solid SC4 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. organic Toxic ST inorganic organic Corrosive SC inorganic 3192 Dust and powder of metals, non toxic in a non-spontaneous combustible form which nevertheless, in contact with water, emit flammable gases, are substances of Class 4.3. a - 159 - 2.2.43 Class 4.3 2.2.43.1 Criteria 2.2.43.1.1 The heading of Class 4.3 covers substances which react with water to emit flammable gases liable to form explosive mixtures with air, and articles containing such substances. 2.2.43.1.2 Substances and articles of Class 4.3 are subdivided as follows: W Substances which, in contact with water, emit flammable gases Substances which, in contact with water, emit flammable gases, without subsidiary risk, and articles containing such substances: W1 W2 W3 Liquid; Solid; Articles; WF1 Substances which, in contact with water, emit flammable gases, liquid, flammable; WF2 Substances which, in contact with water, emit flammable gases, solid, flammable; WS Substances which, in contact with water, emit flammable gases, solid, self-heating; WO Substances which, in contact with water, emit flammable gases, oxidizing, solid; WT Substances which, in contact with water, emit flammable gases, toxic: WT1 Liquid; WT2 Solid; WC Substances which, in contact with water, emit flammable gases, corrosive: WC1 Liquid; WC2 Solid; WFC Substances which, in contact with water, emit flammable gases, flammable, corrosive. Properties 2.2.43.1.3 Certain substances in contact with water may emit flammable gases that can form explosive mixtures with air. Such mixtures are easily ignited by all ordinary sources of ignition, for example naked lights, sparking handtools or unprotected lamps. The resulting blast wave and flames may endanger people and the environment. The test method referred to in 2.2.43.1.4 below is used to determine whether the reaction of a substance with water leads to the development of a dangerous amount of gases which may be flammable. This test method shall not be applied to pyrophoric substances. Classification 2.2.43.1.4 Substances and articles classified in Class 4.3 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of 2.2.43.3 in accordance with the provisions of Chapter 2.1 shall be based on the results of the test procedure in accordance with the Manual of Tests and Criteria, Part III, Section 33.4; experience shall also be taken into account when it leads to a more stringent assignment. 2.2.43.1.5 When substances not mentioned by name are assigned to one of the entries listed in 2.2.43.3 on the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part III, Section 33.4, the following criteria shall apply: A substance shall be assigned to Class 4.3 if: (a) spontaneous ignition of the gas emitted takes place in any step of the test procedure; or - 160 - (b) there is an evolution of flammable gas at a rate greater than 1 litre per kilogram of the substance to be tested per hour. NOTE: Since organometallic substances can be classified in Class 4.2 or 4.3 with additional subsidiary risks, depending on their properties, a specific classification flow chart for these substances is given in 2.3.5. 2.2.43.1.6 If substances of Class 4.3, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes) see also 2.1.3. 2.2.43.1.7 On the basis of the test procedures in accordance with the Manual of Tests and Criteria, Part III, Section 33.4, and the criteria set out in paragraph 2.2.43.1.5, it may also be determined whether the nature of a substance mentioned by name is such that the substance is not subject to the provisions for this Class. Assignment of packing groups 2.2.43.1.8 2.2.43.2 Substances and articles classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, section 33.4, in accordance with the following criteria: (a) Packing group I shall be assigned to any substance which reacts vigorously with water at ambient temperature and generally demonstrates a tendency for the gas produced to ignite spontaneously, or one which reacts readily with water at ambient temperatures such that the rate of evolution of flammable gas is equal to or greater than 10 litres per kilogram of substance over any one minute period; (b) Packing group II shall be assigned to any substance which reacts readily with water at ambient temperature such that the maximum rate of evolution of flammable gas is equal to or greater than 20 litres per kilogram of substance per hour, and which does not meet the criteria of packing group I; (c) Packing group III shall be assigned to any substance which reacts slowly with water at ambient temperature such that the maximum rate of evolution of flammable gas is greater than 1 litre per kilogram of substance per hour, and which does not meet the criteria of packing groups I or II. Substances not accepted for carriage Water-reactive solids, oxidizing, assigned to UN No. 3133 shall not be accepted for carriage unless they meet the requirements for Class 1 (see also 2.1.3.7). - 161 - 2.2.43.3 List of collective entries Substances which, in contact with water, emit flammable gases liquid Without subsidiary risk W W1 solid W2 a articles W3 1389 1391 1391 1392 1420 1421 1422 3398 3148 ALKALI METAL AMALGAM, LIQUID ALKALI METAL DISPERSION or ALKALINE EARTH METAL DISPERSION ALKALINE EARTH METAL AMALGAM, LIQUID POTASSIUM METAL ALLOYS, LIQUID ALKALI METAL ALLOY, LIQUID, N.O.S. POTASSIUM SODIUM ALLOYS, LIQUID ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE WATER-REACTIVE LIQUID, N.O.S. 1390 3401 3402 3170 3170 3403 3404 1393 1409 3208 3395 2813 ALKALI METAL AMIDES ALKALI METAL AMALGAM, SOLID ALKALINE EARTH METAL AMALGAM, SOLID ALUMINIUM SMELTING BY-PRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS POTASSIUM METAL ALLOYS, SOLID POTASSIUM SODIUM ALLOYS, SOLID ALKALINE EARTH METAL ALLOY, N.O.S. METAL HYDRIDES, WATER-REACTIVE, N.O.S. METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE WATER-REACTIVE SOLID, N.O.S. 3292 BATTERIES, CONTAINING SODIUM or 3292 CELLS, CONTAINING SODIUM Liquid, flammable WF1 3482 ALKALI METAL DISPERSION, FLAMMABLE or 3482 ALKALINE EARTH METAL DISPERSION, FLAMMABLE 3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE Solid, flammable WF2 3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE 3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. WS b Solid, self-heating 3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, SELF-HEATING 3209 METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. 3135 WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. WO 3133 WATER-REACTIVE SOLID, OXIDIZING, N.O.S. (not allowed, see 2.2.43.2) liquid WT1 3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. solid WT2 3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. liquid WC1 3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. solid WC2 3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. WFC c 2988 CHLOROSILANES, WATER-REACTIVE, FLAMMABLE, CORROSIVE, NO.S. Solid, oxidizing Toxic WT Corrosive WC Flammable, corrosive (No other collective entry with this classification code available, if need be, classification under a collective entry with a classification code to be determined according to the table of precedence of hazard in 2.1.3.10.) Metals and metal alloys which, in contact with water, do not emit flammable gases and are not pyrophoric or self-heating, but which are readily flammable, are substances of Class 4.1. Alkaline-earth metals and alkaline-earth metal alloys in pyrophoric form are substances of Class 4.2 Dust and powders of metals in pyrophoric form are substances of Class 4.2. Metals and metal alloys in pyrophoric form are substances of Class 4.2. Compounds of phosphorus with heavy metals such as iron, copper, etc. are not subject to the provisions of ADR. a b Metals and metal alloys in pyrophoric form are substances of Class 4.2. Chlorosilanes, having a flash-point of less than 23 °C and which, in contact with water, do not emit flammable gases, are substances of Class 3. Chlorosilanes, having a flash-point equal to or greater than 23 °C and which, in contact with water, do not emit flammable gases, are substances of Class 8. c - 162 - 2.2.51 Class 5.1 2.2.51.1 Criteria 2.2.51.1.1 The heading of Class 5.1 covers substances which, while in themselves not necessarily combustible, may, generally by yielding oxygen, cause or contribute to the combustion of other material, and articles containing such substances. 2.2.51.1.2 The substances of Class 5.1 and articles containing such substances are subdivided as follows: O Oxidizing substances Oxidizing substances without subsidiary risk or articles containing such substances: O1 O2 O3 Liquid; Solid; Articles; OF Oxidizing substances, solid, flammable; OS Oxidizing substances, solid, self-heating; OW Oxidizing substances, solid which, in contact with water, emit flammable gases; OT Oxidizing substances, toxic: OT1 OT2 OC Liquid; Solid; Oxidizing substances, corrosive: OC1 Liquid; OC2 Solid; OTC Oxidizing substances, toxic, corrosive. 2.2.51.1.3 Substances and articles classified in Class 5.1 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of 2.2.51.3 in accordance with the provisions of Chapter 2.1 can be based on the tests, methods and criteria in paragraphs 2.2.51.1.6-2.2.51.1.9 below and the Manual of Tests and Criteria, Part III, Section 34.4. In the event of divergence between test results and known experience, judgement based on known experience shall take precedence over test results. 2.2.51.1.4 If substances of Class 5.1, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also Section 2.1.3. 2.2.51.1.5 On the basis of the test procedures in the Manual of Tests and Criteria, Part III, Section 34.4 and the criteria set out in 2.2.51.1.6 to 2.2.51.1.9 it may also be determined whether the nature of a substance mentioned by name in Table A of Chapter 3.2 is such that the substance is not subject to the provisions for this class. - 163 - Oxidizing solids Classification 2.2.51.1.6 When oxidizing solid substances not mentioned by name in Table A of Chapter 3.2 are assigned to one of the entries listed in 2.2.51.3 on the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part III, sub-section 34.4.1 (test O.1) or alternatively, sub section 34.4.3 (test O.3), the following criteria shall apply: (a) In the test O.1, a solid substance shall be assigned to Class 5.1 if, in the 4:1 or the 1:1 sampleto-cellulose ratio (by mass) tested, it ignites or burns or exhibits mean burning times equal to or less than that of a 3:7 mixture (by mass) of potassium bromate and cellulose; or (b) In the test O.3, a solid substance shall be assigned to Class 5.1 if, in the 4:1 or the 1:1 sampleto-cellulose ratio (by mass) tested, it exhibits a mean burning rate equal to or greater than the mean burning rate of a 1:2 mixture (by mass) of calcium peroxide and cellulose. Assignment of packing groups 2.2.51.1.7 Oxidizing solids classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, sub-section 34.4.1 (test O.1) or sub-section 34.4.3 (test O.3), in accordance with the following criteria: (a) (b) Test O.1: (i) Packing group I: any substance which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time less than the mean burning time of a 3:2 mixture, by mass, of potassium bromate and cellulose; (ii) Packing group II: any substance which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 2:3 mixture (by mass) of potassium bromate and cellulose and the criteria for packing group I are not met; (iii) Packing group III: any substance which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 3:7 mixture (by mass) of potassium bromate and cellulose and the criteria for packing groups I and II are not met; Test O.3: (i) Packing group I: any substance which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning rate greater than the mean burning rate of a 3:1 mixture (by mass) of calcium peroxide and cellulose; (ii) Packing group II: any substance which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning rate equal to or greater than the mean burning rate of a 1:1 mixture (by mass) of calcium peroxide and cellulose, and the criteria for packing group I are not met; (iii) Packing group III: any substance which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning rate equal to or greater than the mean burning rate of a 1:2 mixture (by mass) of calcium peroxide and cellulose, and the criteria for packing groups I and II are not met. Oxidizing liquids Classification 2.2.51.1.8 When oxidizing liquid substances not mentioned by name in Table A of Chapter 3.2 are assigned to one of the entries listed in sub-section 2.2.51.3 on the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part III, sub-section 34.4.2, the following criteria shall apply: - 164 - A liquid substance shall be assigned to Class 5.1 if, in the 1:1 mixture, by mass, of substance and cellulose tested, it exhibits a pressure rise of 2070 kPa gauge or more and a mean pressure rise time equal to or less than the mean pressure rise time of a 1:1 mixture, by mass, of 65% aqueous nitric acid and cellulose. Assignment of packing groups 2.2.51.1.9 Oxidizing liquids classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups I, II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, section 34.4.2, in accordance with the following criteria: (a) Packing group I: any substance which, in the 1:1 mixture, by mass, of substance and cellulose tested, spontaneously ignites; or the mean pressure rise time of a 1:1 mixture, by mass, of substance and cellulose is less than that of a 1:1 mixture, by mass, of 50% perchloric acid and cellulose; (b) Packing group II: any substance which, in the 1:1 mixture, by mass, of substance and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture, by mass, of 40% aqueous sodium chlorate solution and cellulose; and the criteria for packing group I are not met; (c) Packing group III: any substance which, in the 1:1 mixture, by mass, of substance and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture, by mass, of 65% aqueous nitric acid and cellulose; and the criteria for packing groups I and II are not met. 2.2.51.2 Substances not accepted for carriage 2.2.51.2.1 The chemically unstable substances of Class 5.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end it shall in particular be ensured that receptacles and tanks do not contain any material liable to promote these reactions. 2.2.51.2.2 The following substances and mixtures shall not be accepted for carriage: - oxidizing solids, self-heating, assigned to UN No. 3100, oxidizing solids, water-reactive, assigned to UN No. 3121 and oxidizing solids, flammable, assigned to UN No. 3137, unless they meet the requirements for Class 1 (see also 2.1.3.7); - hydrogen peroxide, not stabilized or hydrogen peroxide, aqueous solutions, not stabilized containing more than 60% hydrogen peroxide; - tetranitromethane not free from combustible impurities; - perchloric acid solutions containing more than 72% (mass) acid, or mixtures of perchloric acid with any liquid other than water; - chloric acid solution containing more than 10% chloric acid or mixtures of chloric acid with any liquid other than water; - halogenated fluor compounds other than UN Nos. 1745 BROMINE PENTAFLUORIDE; 1746 BROMINE TRIFLUORIDE and 2495 IODINE PENTAFLUORIDE of Class 5.1 as well as UN Nos. 1749 CHLORINE TRIFLUORIDE and 2548 CHLORINE PENTAFLUORIDE of Class 2; - ammonium chlorate and its aqueous solutions and mixtures of a chlorate with an ammonium salt; - ammonium chlorite and its aqueous solutions and mixtures of a chlorite with an ammonium salt; - mixtures of a hypochlorite with an ammonium salt; - 165 - - ammonium bromate and its aqueous solutions and mixtures of a bromate with an ammonium salt; - ammonium permanganate and its aqueous solutions and mixtures of a permanganate with an ammonium salt; - ammonium nitrate containing more than 0.2% combustible substances (including any organic substance calculated as carbon) unless it is a constituent of a substance or article of Class 1; - fertilizers having an ammonium nitrate content (in determining the ammonium nitrate content, all nitrate ions for which a molecular equivalent of ammonium ions is present in the mixture shall be calculated as ammonium nitrate) or a content in combustible substances exceeding the values specified in special provision 307 except under the conditions applicable to Class 1; - ammonium nitrite and its aqueous solutions and mixtures of an inorganic nitrite with an ammonium salt; - mixtures of potassium nitrate, sodium nitrite and an ammonium salt. - 166 - 2.2.51.3 List of collective entries Oxidizing substances and articles containing such substances liquid O1 3210 3211 3213 3214 3216 3218 3219 3139 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. OXIDIZING LIQUID, N.O.S. BROMATES, INORGANIC, N.O.S CHLORATES, INORGANIC, N.O.S. CHLORITES, INORGANIC, N.O.S. NITRATES, INORGANIC, N.O.S PERCHLORATES, INORGANIC, N.O.S. PERMANGANATES, INORGANIC, N.O.S. PEROXIDES, INORGANIC, N.O.S NITRITES, INORGANIC, N.O.S. HYPOCHLORITES, INORGANIC, N.O.S. PERSULPHATES, INORGANIC, N.O.S. OXIDIZING SOLID, N.O.S. solid O2 1450 1461 1462 1477 1481 1482 1483 2627 3212 3215 1479 articles O3 3356 OXYGEN GENERATOR, CHEMICAL Solid, flammable OF 3137 OXIDIZING SOLID, FLAMMABLE, N.O.S. (not allowed, see 2.2.51.2) Solid, self-heating OS 3100 OXIDIZING SOLID, SELF-HEATING, N.O.S. (not allowed, see 2.2.51.2) OW 3121 OXIDIZING SOLID, WATER REACTIVE, N.O.S. (not allowed, see 2.2.51.2) liquid OT1 3099 OXIDIZING LIQUID, TOXIC, N.O.S. solid OT2 3087 OXIDIZING SOLID, TOXIC, N.O.S. liquid OC1 3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. solid OC2 3085 OXIDIZING SOLID, CORROSIVE, N.O.S. Without subsidiary risk O Solid, water reactive Toxic OT Corrosive OC Toxic, corrosive OTC (No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to the table of precedence of hazard in 2.1.3.10.) - 167 - 2.2.52 Class 5.2 2.2.52.1 Criteria 2.2.52.1.1 The heading of Class 5.2 covers organic peroxides and formulations of organic peroxides. 2.2.52.1.2 The substances of Class 5.2 are subdivided as follows: P1 P2 Organic peroxides Organic peroxides, not requiring temperature control; Organic peroxides, requiring temperature control. Definition 2.2.52.1.3 Organic peroxides are organic substances which contain the bivalent -O-O- structure and may be considered derivatives of hydrogen peroxide, where one or both of the hydrogen atoms have been replaced by organic radicals. Properties 2.2.52.1.4 Organic peroxides are liable to exothermic decomposition at normal or elevated temperatures. The decomposition can be initiated by heat, contact with impurities (e.g. acids, heavy-metal compounds, amines), friction or impact. The rate of decomposition increases with temperature and varies with the organic peroxide formulation. Decomposition may result in the evolution of harmful, or flammable, gases or vapours. For certain organic peroxides the temperature shall be controlled during carriage. Some organic peroxides may decompose explosively, particularly if confined. This characteristic may be modified by the addition of diluents or by the use of appropriate packagings. Many organic peroxides burn vigorously. Contact of organic peroxides with the eyes is to be avoided. Some organic peroxides will cause serious injury to the cornea, even after brief contact, or will be corrosive to the skin. NOTE: Test methods for determining the flammability of organic peroxides are set out in the Manual of Tests and Criteria, Part III, sub-section 32.4. Because organic peroxides may react vigorously when heated, it is recommended to determine their flash-point using small sample sizes such as described in ISO 3679:1983. Classification 2.2.52.1.5 Any organic peroxide shall be considered for classification in Class 5.2 unless the organic peroxide formulation contains: (a) Not more than 1.0% available oxygen from the organic peroxides when containing not more than 1.0% hydrogen peroxide; (b) Not more than 0.5% available oxygen from the organic peroxides when containing more than 1.0% but not more than 7.0% hydrogen peroxide. NOTE: The available oxygen content (%) of an organic peroxide formulation is given by the formula 16 × ∑ (ni × ci /mi) where: ni = ci = mi = 2.2.52.1.6 number of peroxygen groups per molecule of organic peroxide i; concentration (mass %) of organic peroxide i; and molecular mass of organic peroxide i. Organic peroxides are classified into seven types according to the degree of danger they present. The types of organic peroxide range from type A, which is not accepted for carriage in the packaging in which it is tested, to type G, which is not subject to the provisions of Class 5.2. The classification of types B to F is directly related to the maximum quantity allowed in one packaging. The principles to be applied to the classification of substances not listed in 2.2.52.4 are set out in the Manual of Tests and Criteria, Part II. - 168 - 2.2.52.1.7 Organic peroxides which have already been classified and are already permitted for carriage in packagings are listed in 2.2.52.4, those already permitted for carriage in IBCs are listed in 4.1.4.2, packing instruction IBC520 and those already permitted for carriage in tanks in accordance with Chapters 4.2 and 4.3 are listed in 4.2.5.2, portable tank instruction T23. Each permitted substance listed is assigned to a generic entry of Table A of Chapter 3.2 (UN Nos. 3101 to 3120) and appropriate subsidiary risks and remarks providing relevant transport information are given. These generic entries specify: - the type (B to F) of organic peroxide (see 2.2.52.1.6 above); - physical state (liquid/solid); and - temperature control (when required), see 2.2.52.1.15 to 2.2.52.1.18. Mixtures of these formulations may be classified as the same type of organic peroxide as that of the most dangerous component and be carried under the conditions of carriage given for this type. However, as two stable components can form a thermally less stable mixture, the self-accelerating decomposition temperature (SADT) of the mixture shall be determined and, if necessary, the control and emergency temperatures derived from the SADT in accordance with 2.2.52.1.16. 2.2.52.1.8 Classification of organic peroxides not listed in 2.2.52.4, 4.1.4.2 packing instruction IBC520 or 4.2.5.2, portable tank instruction T23, and assignment to a collective entry shall be made by the competent authority of the country of origin. The statement of approval shall contain the classification and the relevant conditions of carriage. If the country of origin is not a Contracting Party to ADR, the classification and conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. 2.2.52.1.9 Samples of organic peroxides or formulations of organic peroxides not listed in 2.2.52.4, for which a complete set of test results is not available and which are to be carried for further testing or evaluation, shall be assigned to one of the appropriate entries for organic peroxides type C provided the following conditions are met: - the available data indicate that the sample would be no more dangerous than organic peroxides type B; - the sample is packaged in accordance with packing method OP2 and the quantity per transport unit is limited to 10 kg; - the available data indicate that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation. Desensitization of organic peroxides 2.2.52.1.10 In order to ensure safety during carriage, organic peroxides are in many cases desensitized by organic liquids or solids, inorganic solids or water. Where a percentage of a substance is stipulated, this refers to the percentage by mass, rounded to the nearest whole number. In general, desensitization shall be such that, in case of spillage, the organic peroxide will not concentrate to a dangerous extent. 2.2.52.1.11 Unless otherwise stated for the individual organic peroxide formulation, the following definition(s) shall apply to diluents used for desensitization: - diluents type A are organic liquids which are compatible with the organic peroxide and which have a boiling point of not less than 150 °C. Type A diluents may be used for desensitizing all organic peroxides; - diluents type B are organic liquids which are compatible with the organic peroxide and which have a boiling point of less than 150 °C but not less than 60 °C and a flash-point of not less than 5 °C. Type B diluents may be used for desensitization of all organic peroxides provided that the boiling point of the liquid is at least 60 °C higher than the SADT in a 50 kg package. - 169 - 2.2.52.1.12 Diluents, other than type A or type B, may be added to organic peroxide formulations as listed in 2.2.52.4 provided that they are compatible. However, replacement of all or part of a type A or type B diluent by another diluent with differing properties requires that the organic peroxide formulation be re-assessed in accordance with the normal acceptance procedure for Class 5.2. 2.2.52.1.13 Water may only be used for the desensitization of organic peroxides which are listed in 2.2.52.4 or in the competent authority decision according to 2.2.52.1.8 as being "with water" or "as a stable dispersion in water". Samples of organic peroxides or formulations of organic peroxides not listed in 2.2.52.4 may also be desensitized with water provided the requirements of 2.2.52.1.9 are met. 2.2.52.1.14 Organic and inorganic solids may be used for desensitization of organic peroxides provided that they are compatible. Compatible liquids and solids are those which have no detrimental influence on the thermal stability and hazard type of the organic peroxide formulation. Temperature control requirements 2.2.52.1.15 Certain organic peroxides may only be carried under temperature-controlled conditions. The control temperature is the maximum temperature at which the organic peroxide can be safely carried. It is assumed that the temperature of the immediate surroundings of a package only exceeds 55 °C during carriage for a relatively short time in a 24 hour period. In the event of loss of temperature control, it may be necessary to implement emergency procedures. The emergency temperature is the temperature at which such procedures shall be implemented. 2.2.52.1.16 The control and emergency temperatures are derived from the SADT which is defined as the lowest temperature at which self-accelerating decomposition may occur with a substance in the packaging as used during carriage (see Table 1). The SADT shall be determined in order to decide whether a substance shall be subjected to temperature control during carriage. Provisions for the determination of the SADT are given in the Manual of Tests and Criteria, Part II, Sections 20 and 28.4. Table 1: Derivation of control and emergency temperatures Type of receptacle SADT a Single packagings and IBCs 20 °C or less 20 °C below SADT 10 °C below SADT over 20 °C to 35 °C 15 °C below SADT 10 °C below SADT over 35 °C 10 °C below SADT 5 °C below SADT not greater than 50 °C 10 °C below SADT 5 °C below SADT Tanks a Control temperature Emergency temperature SADT of the substance as packaged for carriage 2.2.52.1.17 The following organic peroxides shall be subject to temperature control during carriage: - organic peroxides types B and C with an SADT ≤ 50 °C; - organic peroxides type D showing a medium effect when heated under confinement with an SADT ≤ 50 °C or showing a low or no effect when heated under confinement with an SADT ≤ 45 °C; and - organic peroxides types E and F with an SADT ≤ 45 °C. NOTE: Provisions for the determination of the effects of heating under confinement are given in the Manual of Tests and Criteria, Part II, Section 20 and Sub-section 28.4. 2.2.52.1.18 Where applicable, control and emergency temperatures are listed in 2.2.52.4. The actual temperature during carriage may be lower than the control temperature but shall be selected so as to avoid dangerous separation of phases. - 170 - 2.2.52.2 Substances not accepted for carriage Organic peroxides, type A, shall not be accepted for carriage under the provisions of Class 5.2 (see Manual of Tests and Criteria, Part II, paragraph 20.4.3 (a)). 2.2.52.3 List of collective entries Organic peroxides Not requiring temperature control P1 3101 3102 3103 3104 3105 3106 3107 3108 3109 3110 ORGANIC PEROXIDE TYPE A, LIQUID ORGANIC PEROXIDE TYPE A, SOLID ORGANIC PEROXIDE TYPE B, LIQUID ORGANIC PEROXIDE TYPE B, SOLID ORGANIC PEROXIDE TYPE C, LIQUID ORGANIC PEROXIDE TYPE C, SOLID ORGANIC PEROXIDE TYPE D, LIQUID ORGANIC PEROXIDE TYPE D, SOLID ORGANIC PEROXIDE TYPE E, LIQUID ORGANIC PEROXIDE TYPE E, SOLID ORGANIC PEROXIDE TYPE F, LIQUID ORGANIC PEROXIDE TYPE F, SOLID ORGANIC PEROXIDE TYPE G, LIQUID ORGANIC PEROXIDE TYPE G, SOLID accepted for carriage, }Not see 2.2.52.2 subject to the provisions } Not applicable to Class 5.2, see 2.2.52.1.6 Requiring temperature control 2.2.52.4 P2 3111 3112 3113 3114 3115 3116 3117 3118 3119 3120 ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED List of currently assigned organic peroxides in packagings In the column "Packing Method", codes "OP1" to "OP8" refer to packing methods in 4.1.4.1, packing instruction P520 (see also 4.1.7.1). Organic peroxides to be carried shall fulfil the classification and the control and emergency temperatures (derived from the SADT) as listed. For substances permitted in IBCs, see 4.1.4.2, packing instruction IBC520 and, for those permitted in tanks according to Chapters 4.2 and 4.3, see 4.2.5.2, portable tank instruction T23. - 171 - - 172 ≥ 48 ≤ 72 " < 82 + >9 ≤ 79 " tert-BUTYL HYDROPEROXIDE + DI-tert-BUTYLPEROXIDE ≤ 80 >79 - 90 ≤ 52 > 52 - 100 ≤ 52 " tert-BUTYL HYDROPEROXIDE " n-BUTYL-4,4-DI-(tert-BUTYLPEROXY)VALERATE " > 42 - 100 ≤ 100 tert-AMYLPEROXY-3,5,5-TRIMETHYLHEXANOATE tert-BUTYL CUMYL PEROXIDE ≤ 77 tert-AMYL PEROXYPIVALATE ≥ 20 ≥ 53 ≥ 48 ≥7 ≥ 28 > 14 ≥ 10 ≤ 77 tert-AMYL PEROXYNEODECANOATE  23 ≥ 23  77 tert-AMYL PEROXY ISOPROPYL CARBONATE ≤ 47 OP5 ≤ 100 tert-AMYL PEROXY-2-ETHYLHEXYL CARBONATE " OP7 ≤ 100 tert-AMYL PEROXY-2-ETHYLHEXANOATE OP5 OP8 OP8 OP7 OP5 OP8 OP5 OP8 OP8 OP7 OP5 OP8 OP7 OP7 OP5 OP7 OP8 OP7 OP4 OP7 OP7 Packing Method ≤ 100 ≥6 ≥ 12 ≥8 Water tert-AMYL PEROXYBENZOATE ≥ 38 ≥ 23 Inert solid (%) ≤ 62 ≥ 68 Diluent type B (%) 1) tert-AMYL PEROXYACETATE ≥6 ≥ 48 Diluent type A (%) ≤ 88 ≤ 32 ≤ 82 ≤ 32 as a paste ≤ 42 Concentration (%) tert-AMYL HYDROPEROXIDE " ACETYL CYCLOHEXANESULPHONYL PEROXIDE " ACETYL ACETONE PEROXIDE ORGANIC PEROXIDE +10 0 0 +20 -10 -10 Control temperature (°C) +15 + 10 +10 +25 0 0 Emergency temperature (°C) 3103 3109 3107 3105 3103 3108 3103 3108 3107 3105 3113 3119 3115 3103 3105 3115 3103 3105 3107 3115 3112 3106 3105 Number (Generic entry) 13) 13) 13) 23) 4) 13) 13) 3) 20) 2) Subsidiary risks and remarks - 173 - ≤ 52 as a paste " ≤ 32 " tert-BUTYLPEROXY ISOPROPYLCARBONATE " tert-BUTYL PEROXYISOBUTYRATE tert-BUTYL PEROXY-2-ETHYLHEXYLCARBONATE " ≤ 77 ≤ 52 > 52 - 77 ≤ 100 ≤ 31 + ≤ 36 ≤ 12 +≤ 14 ≤ 52 " tert-BUTYL PEROXY-2-ETHYLHEXANOATE + 2,2-DI-(tert-BUTYLPEROXY)BUTANE > 32 - 52 > 52 – 100 " tert-BUTYL PEROXY-2-ETHYLHEXANOATE ≤ 100 ≤ 77 tert-BUTYL PEROXYCROTONATE tert-BUTYL PEROXYDIETHYLACETATE ≤ 52 ≤ 52 " tert-BUTYL PEROXYBUTYL FUMARATE > 52 - 77 " > 77 - 100 ≤ 32 " tert-BUTYL PEROXYBENZOATE > 32 - 52 " > 52 - 77 ≤ 52 " tert-BUTYL PEROXYACETATE ≤ 52 > 52 - 100 Concentration (%) " tert-BUTYL MONOPEROXYMALEATE ORGANIC PEROXIDE ≥ 23 ≥ 14 ≥ 23 ≥ 48 ≥23 ≥ 48 ≥ 23 ≥ 48 Diluent type A (%) ≥ 48 ≥ 23 ≥ 33 ≥ 68 ≥ 48 ≥ 68 Diluent type B (%) 1) ≥ 60 ≥ 48 ≥ 48 ≥ 48 Inert solid (%) Water OP5 OP7 OP5 OP7 OP7 OP7 OP8 OP8 OP8 OP6 OP5 OP7 OP7 OP7 OP7 OP5 OP8 OP6 OP5 OP8 OP8 OP6 OP5 Packing Method +15 +15 +35 +40 +20 +30 +20 +20 Control temperature (°C) +20 +20 +40 +45 +25 +35 +25 +25 Emergency temperature (°C) 3103 3115 3111 3105 3115 3106 3119 3118 3117 3113 3113 3105 3105 3106 3105 3103 3109 3103 3101 3108 3108 3103 3102 Number (Generic entry) 3) 3) 3) Subsidiary risks and remarks - 174 - ≤ 42 as a stable dispersion in water (frozen) ≤ 32 " " CUMYL PEROXYNEODECANOATE " ≤ 87 ≤ 90 > 90 - 98 ≤ 77 " CUMYL HYDROPEROXIDE ≤ 57 " > 57 - 86 ≤ 32 " 3-CHLOROPEROXYBENZOIC ACID ≤ 42 > 32 - 100 " tert-BUTYL PEROXY-3,5,5-TRIMETHYLHEXANOATE ≤ 100 ≤ 27 " tert-BUTYLPEROXY STEARYLCARBONATE > 27 - 67 > 67 - 77  42 as a stable dispersion in water " tert-BUTYL PEROXYPIVALATE " ≤ 77 ≤ 52 as a stable dispersion in water " tert-BUTYL PEROXYNEOHEPTANOATE ≤ 77 > 77 - 100 ≤ 100 ≤ 42 ≤ 77 Concentration (%) " tert-BUTYL PEROXYNEODECANOATE tert-BUTYL PEROXY-2-METHYLBENZOATE " ISOPROPENYLBENZENE 1-(2-tert-BUTYLPEROXY ISOPROPYL)-3- ORGANIC PEROXIDE ≥ 13 ≥ 10 ≤10 ≥ 23 ≥ 23 ≥ 68 ≥ 23 Diluent type A (%) ≥ 68 ≥ 73 ≥ 33 ≥ 23 Diluent type B (%) 1) ≥6 ≥3 ≥ 14 ≥ 58 ≥ 58 Inert solid (%) ≥ 17 ≥ 40 Water OP7 OP8 OP8 OP7 OP7 OP1 OP8 OP7 OP7 OP7 OP8 OP7 OP5 OP8 OP7 OP8 OP8 OP8 OP7 OP7 OP5 OP8 OP7 Packing Method - 10 +30 0 0 0 0 0 0 0 0 -5 Control temperature (°C) 0 +35 +10 +10 +10 +10 +10 +10 +10 +10 +5 Emergency temperature (°C) 3115 3109 3107 3106 3106 3102 3109 3106 3105 3106 3119 3115 3113 3117 3115 3119 3118 3119 3115 3115 3103 3108 3105 Number (Generic entry) 13) 18) 13) 3) Subsidiary risks and remarks - 175 - ≤ 27 ≤ 100 ≤ 57 ≤ 82 DIACETYL PEROXIDE DI-tert-AMYL PEROXIDE 2,2-DI-(tert-AMYLPEROXY)BUTANE 1,1-DI-(tert-AMYLPEROXY)CYCLOHEXANE > 77 - 94 ≤ 77 ≤ 62 > 52 – 62 as a paste > 35 - 52 > 36 - 42 ≤ 56.5 as a paste ≤ 52 as a paste ≤ 42 as a stable dispersion in water ≤ 35 " " " " " " " " " " > 51 - 100 ≤ 57 DIACETONE ALCOHOL PEROXIDES DIBENZOYL PEROXIDE ≤ 100 ≤ 32 " ([3R-(3R,5aS,6S,8aS,9R,10R,12S,12aR**)]DECAHYDRO-10-METHOXY-3,6,9-TRIMETHYL-3,12EPOXY-12H-PYRANO[4,3-j]-1,2-BENZODIOXEPIN) ≤ 72 as a paste " ≤ 91 CYCLOHEXANONE PEROXIDE(S) ≤ 72 ≤ 77 CUMYL PEROXYPIVALATE " ≤ 77 ≤ 52 as a stable dispersion in water " CUMYL PEROXYNEOHEPTANOATE ≤ 77 Concentration (%) " ORGANIC PEROXIDE ≥ 18 ≥ 18 ≥ 43 ≥ 28 ≥ 23 Diluent type A (%) ≥ 73 ≥ 26 ≥ 23 ≥ 23 Diluent type B (%) 1) ≥ 65 ≥ 48 ≥ 28 ≤ 48 ≥ 68 Inert solid (%) ≥ 15 ≤ 40 ≥ 10 ≥ 23 ≥6 ≥8 ≥9 Water OP8 OP8 OP8 OP8 OP7 OP7 OP7 OP6 OP4 OP2 OP6 OP7 OP8 OP7 OP7 OP7 OP7 OP7 OP6 OP7 OP7 OP8 OP7 Packing Method +20 +40 -5 -10 -10 -10 Control temperature (°C) +25 +45 +5 0 0 0 Emergency temperature (°C) Exempt 3109 3108 3108 3107 3106 3106 3106 3104 3102 3102 3103 3105 3107 3115 3115 3106 Exempt 3106 3105 3104 3115 3115 3119 3115 Number (Generic entry) 29) 20) 20) 3) 3) 7) 13) 6) 29) 5) 20) 5) 13) Subsidiary risks and remarks - 176 ≤ 42 ≤ 42 ≤ 27 ≤ 13 " " " " " ≤ 52 > 52 - 100 ≤ 42 as a stable dispersion in water (frozen) " DI-sec-BUTYL PEROXYDICARBONATE ≤ 27 > 27 - 52 " DI-n-BUTYL PEROXYDICARBONATE ≤ 43 + ≤ 16 > 42 - 52 " 1,1-DI-(tert-BUTYLPEROXY) CYCLOHEXANE + tert-BUTYL PEROXY-2-ETHYLHEXANOATE > 52 - 80 > 80 - 100 1,1-DI-(tert-BUTYLPEROXY) CYCLOHEXANE " ≤ 72 1,6-Di-(tert-BUTYLPEROXYCARBONYLOXY) HEXANE ≤ 72 ≤ 52 2,2-DI-(tert-BUTYLPEROXY)BUTANE " ≤ 52 ≤ 52 > 52 - 100 ≤ 42 as a stable dispersion in water ≤ 100 Concentration (%) DI-tert-BUTYL PEROXYAZELATE " DI-tert-BUTYL PEROXIDE " DI-(4-tert-BUTYLCYCLOHEXYL) PEROXYDICARBONATE ORGANIC PEROXIDE ≥ 41 ≥ 13 ≥ 25 ≥ 58 ≥ 13 ≥ 48 ≥ 20 ≥ 28 ≥ 48 ≥ 48 Diluent type A (%) ≥ 48 ≥ 73 ≥ 48 ≥ 74 ≥ 28 ≥ 48 Diluent type B (%) 1) ≥ 45 Inert solid (%) Water OP7 OP4 OP8 OP8 OP7 OP 7 OP8 OP8 OP8 OP7 OP7 OP5 OP5 OP5 OP5 OP6 OP7 OP8 OP8 OP8 OP6 Packing Method -15 -20 -15 -10 -15 +30 +30 Control temperature (°C) -5 -10 -5 0 -5 +35 +35 Emergency temperature (°C) 3115 3113 3118 3117 3115 3105 3109 3107 3109 3106 3105 3103 3103 3101 3103 3103 3105 3109 3107 3119 3114 Number (Generic entry) 21) 30) 3) 25) Subsidiary risks and remarks - 177 - ≤ 77 ≤ 57 ≤ 57 ≤ 32 " " " " ≤ 91  42 as a stable dispersion in water " > 91 - 100 ≤ 52 " DICYCLOHEXYL PEROXYDICARBONATE " > 52 - 100 ≤ 32 " DICUMYL PEROXIDE ≤ 52 as a paste ≤ 77 ≤ 42 as a stable dispersion in water " DI-4-CHLOROBENZOYL PEROXIDE " ≤ 100 > 57 - 90 " DICETYL PEROXYDICARBONATE ≤ 90 > 90 - 100 ≤ 42 " 1,1-DI-(tert-BUTYLPEROXY)-3,3,5TRIMETHYLCYCLOHEXANE " ≤ 52 ≤ 42 " 2,2-DI-(tert-BUTYLPEROXY)PROPANE ≤ 52 as a paste > 42 - 52 ≤ 42 > 42 - 100 Concentration (%) " DI-(tert-BUTYLPEROXY) PHTHALATE " DI-(tert-BUTYLPEROXYISOPROPYL)BENZENE(S) ORGANIC PEROXIDE ≥ 26 ≥ 43 ≥ 10 ≥ 13 ≥ 48 ≥ 58 ≥ 48 Diluent type A (%) ≥ 42 ≥ 23 ≥ 10 Diluent type B (%) 1) ≥ 48 ≥ 68 ≥ 43 ≥ 45 ≥ 58 ≤ 57 Inert solid (%) ≥9 ≥ 23 Water OP8 OP5 OP3 OP8 OP7 OP5 OP8 OP7 OP8 OP8 OP8 OP5 OP5 OP5 OP5 OP7 OP7 OP8 OP7 OP7 OP7 Packing Method +15 +10 +10 +30 +30 Control temperature (°C) +20 +15 +15 +35 +35 Emergency temperature (°C) 3119 3114 3112 Exempt 3110 Exempt 3106 3102 3119 3116 3107 3107 3110 3103 3103 3103 3101 3106 3105 3107 3106 3105 Exempt 3106 Number (Generic entry) 3) 29) 12) 29) 20) 3) 30) 3) 20) 29) Subsidiary risks and remarks - 178 ≤ 52 ≤ 87 DI-(2-METHYLBENZOYL) PEROXIDE ≤ 42 as a stable dispersion in water DI-(3-METHOXYBUTYL) PEROXYDICARBONATE " ≤ 100 ≤ 32 " DILAUROYL PEROXIDE ≤ 52 > 52-100 ≤ 82 ≤ 32 > 32 – 52 " DIISOPROPYL PEROXYDICARBONATE DIISOPROPYLBENZENE DIHYDROPEROXIDE " DIISOBUTYRYL PEROXIDE ≤ 100 DI-(1-HYDROXYCYCLOHEXYL) PEROXIDE ≤ 52 as a stable dispersion in water (frozen) " ≤ 27 ≤ 62 as a stable dispersion in water " 2,2-DIHYDROPEROXYPROPANE ≤ 77 > 77 – 100 DI-(2-ETHYLHEXYL) PEROXYDICARBONATE " ≤ 52 ≤ 52 as a paste with silicon oil " DI-(2-ETHOXYETHYL) PEROXYDICARBONATE ≤ 52 as a paste ≤ 77 " DI-2,4-DICHLOROBENZOYL PEROXIDE ≤ 22 ≤ 42 2,2-DI-(4,4-DI (tert-BUTYLPEROXY) CYCLOHEXYL) PROPANE " ≤ 100 Concentration (%) DIDECANOYL PEROXIDE ORGANIC PEROXIDE ≥ 68 ≥5 Diluent type A (%) ≥ 48 ≥ 48 ≥ 68 ≥ 48 ≥ 23 ≥ 48 ≥ 78 Diluent type B (%) 1) ≥ 73 ≥ 58 Inert solid (%) ≥ 13 ≥5 ≥ 23 Water OP5 OP7 OP8 OP7 OP7 OP7 OP2 OP7 OP7 OP5 OP7 OP5 OP8 OP8 OP7 OP5 OP7 OP7 OP8 OP5 OP8 OP7 OP6 Packing Method +30 -5 -15 -20 -15 -20 -20 -15 -15 -15 -20 -10 + 20 +30 Control temperature (°C) +35 +5 -5 -10 -5 -10 -10 -5 -5 -5 -10 0 + 25 +35 Emergency temperature (°C) 3112 3115 3109 3106 3115 3115 3112 3106 3115 3111 3106 3102 3120 3119 3115 3113 3115 3106 3118 3102 3107 3106 3114 Number (Generic entry) 3) 3) 24) 3) 3) 3) Subsidiary risks and remarks - 179 - ≤ 52 " ≤ 77 ≤ 52 ≤ 100 2,5-DIMETHYL-2,5-DI-(3,5,5TRIMETHYLHEXANOYLPEROXY)HEXANE 1,1-DIMETHYL-3-HYDROXYBUTYL PEROXYNEOHEPTANOATE DIMYRISTYL PEROXYDICARBONATE DI-(2-NEODECANOYLPEROXYISOPROPYL) BENZENE ≤ 52 ≤ 42 as a stable dispersion in water ≤ 82 2,5-DIMETHYL-2,5-DIHYDROPEROXYHEXANE " ≤ 100 ≤ 52 " 2,5-DIMETHYL-2,5-DI(2-ETHYLHEXANOYLPEROXY)HEXANE >52-86 > 86-100 " 2,5-DIMETHYL-2,5-DI(tert-BUTYLPEROXY)HEXYNE-3 ≤ 47 as a paste ≤ 77 " " > 52 - 90 " > 90 - 100 ≤ 82 " 2,5-DIMETHYL-2,5-DI(tert-BUTYLPEROXY)HEXANE ≤ 82 " > 82-100 ≤ 52 as a paste with silicon oil DI-(4-METHYLBENZOYL) PEROXIDE 2,5-DIMETHYL-2,5-DI(BENZOYLPEROXY)HEXANE ≤ 20 + ≤ 18 + ≤ 4 Concentration (%) DI-(3-METHYLBENZOYL) PEROXIDE + BENZOYL (3-METHYLBENZOYL) PEROXIDE + DIBENZOYL PEROXIDE ORGANIC PEROXIDE ≥ 48 ≥ 48 ≥ 23 ≥ 14 ≥ 48 ≥ 10 Diluent type A (%) ≥ 58 Diluent type B (%) 1) ≥ 48 ≥ 23 ≥ 18 Inert solid (%) ≥ 18 ≥ 18 Water OP7 OP8 OP7 OP8 OP7 OP6 OP5 OP7 OP5 OP5 OP8 OP8 OP8 OP7 OP5 OP5 OP7 OP5 OP7 OP7 Packing Method -10 +20 +20 0 +20 +35 Control temperature (°C) 0 +25 +25 +10 +25 +40 Emergency temperature (°C) 3115 3119 3116 3117 3105 3104 3113 3106 3103 3101 3108 3109 3108 3105 3103 3104 3106 3102 3106 3115 Number (Generic entry) 26) 3) 3) Subsidiary risks and remarks - 180 ≤ 52 as a stable dispersion in water ≤ 77 3-HYDROXY-1,1-DIMETHYLBUTYL PEROXYNEODECANOATE " ≤ 72 tert-HEXYL PEROXYPIVALATE ≤ 52 ≤ 71 tert-HEXYL PEROXYNEODECANOATE " ≤ 52 ≤ 52 " 1-(2-ETHYLHEXANOYLPEROXY)-1,3DIMETHYLBUTYL PEROXYPIVALATE ≤ 77 " > 77 - 100 ETHYL 3,3-DI-(tert-BUTYLPEROXY)BUTYRATE ≤ 38 " ≤ 67 > 38-52 " ETHYL 3,3-DI-(tert-AMYLPEROXY)BUTYRATE ≤ 52 as a stable dispersion in water > 52-82 ≤ 72 > 72-100 " DI-(3,5,5-TRIMETHYLHEXANOYL) PEROXIDE " DISUCCINIC ACID PEROXIDE ≤ 77 ≤ 100 DI-n-PROPYL PEROXYDICARBONATE " ≤ 27 ≤ 85 DIPROPIONYL PEROXIDE " >85-100 ≤ 100 DI-n-OCTANOYL PEROXIDE DI-(2-PHENOXYETHYL) PEROXYDICARBONATE ≤ 100 Concentration (%) DI-n-NONANOYL PEROXIDE ORGANIC PEROXIDE ≥ 48 ≥ 23 ≥ 29 ≥ 45 ≥ 23 ≥ 33 ≥ 62 ≥ 48 ≥ 18 Diluent type A (%) ≥ 28 ≥ 10 ≥ 23 ≥ 73 Diluent type B (%) 1) ≥ 48 Inert solid (%) ≥ 28 ≥ 15 Water OP 8 OP 8 OP 7 OP7 OP7 OP7 OP7 OP7 OP5 OP7 OP8 OP8 OP8 OP7 OP7 OP4 OP5 OP3 OP8 OP7 OP5 OP5 OP7 Packing Method -5 -5 -5 +10 0 -20 +20 +10 +10 0 +10 -20 -25 +15 +10 0 Control temperature (°C) +5 +5 +5 +15 +10 -10 +25 +15 +15 +10 +15 -10 -15 +20 +15 +10 Emergency temperature (°C) 3119 3117 3115 3115 3115 3115 3106 3105 3103 3105 3119 3119 3119 3115 3116 3102 3113 3113 3117 3106 3102 3114 3116 Number (Generic entry) 3) 17) 3) Subsidiary risks and remarks - 181 OP8 ≤ 43 ≤ 43  100 PEROXYACETIC ACID, TYPE E, stabilized PEROXYACETIC ACID, TYPE F, stabilized PEROXYLAURIC ACID  48 OP8 ≤ 43 PEROXYACETIC ACID, TYPE D, stabilized POLYETHER POLY-tert-BUTYLPEROXYCARBONATE "  52 ≤ 56 > 56 – 100 OP8 ≤ 100 3,3,5,7,7-PENTAMETHYL-1,2,4-TRIOXEPANE PINANYL HYDROPEROXIDE OP2 ORGANIC PEROXIDE, SOLID, SAMPLE, TEMPERATURE CONTROLLED OP8 OP8 OP7 OP8 OP7 OP2 OP8 OP7 OP8 OP7 OP5 OP7 OP8 OP7 OP8 OP5 OP7 Packing Method ORGANIC PEROXIDE, SOLID, SAMPLE Water OP2 Inert solid (%) ORGANIC PEROXIDE, LIQUID, SAMPLE, TEMPERATURE CONTROLLED ≥ 44 ≥ 70 ≥ 33 Diluent type B (%) 1) OP2 see remark 31) METHYL ISOPROPYL KETONE PEROXIDE(S) ≥ 19 ≥ 60 ≥ 55 ≥ 48 ≥ 28 ≥ 28 ≥ 38 Diluent type A (%) ORGANIC PEROXIDE, LIQUID, SAMPLE ≤ 62 see remark 10) " METHYL ISOBUTYL KETONE PEROXIDE(S) see remark 9) see remark 8) ≤ 67 ≤ 72 > 72 - 100 ≤ 72 ≤ 52 + ≤ 28 + ≤ 22 ≤ 32 + ≤ 15 – 18 ≤ 12 – 15 Concentration (%) " METHYL ETHYL KETONE PEROXIDE(S) METHYLCYCLOHEXANONE PEROXIDE(S) " p-MENTHYL HYDROPEROXIDE ISOPROPYLCUMYL HYDROPEROXIDE " ISOPROPYL sec-BUTYL PEROXYDICARBONATE +DI-sec-BUTYL PEROXYDICARBONATE +DI-ISOPROPYL PEROXYDICARBONATE ORGANIC PEROXIDE +35 +35 -20 -20 Control temperature (°C) +40 +40 -10 -10 Emergency temperature (°C) 3107 3109 3105 3118 3109 3107 3105 3107 3114 3104 3113 3103 3109 3105 3107 3105 3101 3115 3109 3105 3109 3111 3115 Number (Generic entry) 13) 13) 16) 19) 13) 15) 19) 13) 14) 19) 11) 11) 11) 11) 31) 22) 10) 9) 3) 8) 13) 27) 13) 13) 3) Subsidiary risks and remarks - 182 - ≥ 58 OP7 OP8 ≤ 42 ≥ 65 3,6,9-TRIETHYL-3,6,9-TRIMETHYL -1,4,7 TRIPEROXONANE ≥ 18 ≤ 17 3,6,9-TRIETHYL-3,6,9-TRIMETHYL-1,4,7 TRIPEROXONANE OP7 OP7 OP7 Packing Method OP7 Water  77  23 Inert solid (%) 1,1,3,3-TETRAMETHYLBUTYL PEROXYPIVALATE ≥ 28 Diluent type B (%) 1) OP8 ≤ 72 1,1,3,3- TETRAMETHYLBUTYL PEROXYNEODECANOATE Diluent type A (%) ≤ 52 as a stable dispersion in water ≤ 100 1,1,3,3-TETRAMETHYLBUTYL PEROXY-2ETHYLHEXANOATE " ≤ 100 Concentration (%) 1,1,3,3-TETRAMETHYLBUTYL HYDROPEROXIDE ORGANIC PEROXIDE 0 -5 -5 +15 Control temperature (°C) +10 +5 +5 +20 Emergency temperature (°C) 3105 3110 3115 3119 3115 3115 3105 Number (Generic entry) 28) Subsidiary risks and remarks Remarks (refer to the last column of the Table in 2.2.52.4): 1) Diluent type B may always be replaced by diluent type A. The boiling point of diluent type B shall be at least 60°C higher than the SADT of the organic peroxide. 2) Available oxygen  4.7%. 3) "EXPLOSIVE" subsidiary risk label required (Model No.1, see 5.2.2.2.2). 4) Diluent may be replaced by di-tert-butyl peroxide. 5) Available oxygen  9%. 6) With  9% hydrogen peroxide; available oxygen  10%. 7) Only non-metallic packagings allowed. 8) Available oxygen > 10% and  10.7%, with or without water. 9) Available oxygen  10% , with or without water. 10) Available oxygen  8.2% , with or without water. 11) See 2.2.52.1.9. 12) Up to 2000 kg per receptacle assigned to ORGANIC PEROXIDE TYPE F on the basis of large scale trials. 13) "CORROSIVE" subsidiary risk label required (Model No.8, see 5.2.2.2.2). 14) Peroxyacetic acid formulations which fulfil the criteria of the Manual of Tests and Criteria, paragraph 20.4.3 (d). 15) Peroxyacetic acid formulations which fulfil the criteria of the Manual of Tests and Criteria, paragraph 20.4.3 (e). 16) Peroxyacetic acid formulations which fulfil the criteria of the Manual of Tests and Criteria, paragraph 20.4.3 (f). 17) Addition of water to this organic peroxide will decrease its thermal stability. 18) No "CORROSIVE" subsidiary risk label (Model No.8, see 5.2.2.2.2) required for concentrations below 80%. 19) Mixtures with hydrogen peroxide, water and acid(s). 20) With diluent type A, with or without water. 21) With  25% diluent type A by mass, and in addition ethylbenzene. 22) With  19%, diluent type A by mass, and in addition methyl isobutyl ketone. 23) With < 6% di-tert-butyl peroxide. 24) With  8% 1-isopropylhydroperoxy-4-isopropylhydroxybenzene. 25) Diluent type B with boiling point > 110 °C. 26) With < 0.5% hydroperoxides content. 27) For concentrations more than 56%, "CORROSIVE" subsidiary risk label required (Model No.8, see 5.2.2.2.2). 28) Available active oxygen  7.6% in diluent type A having a 95% boil-off point in the range of 200 - 260 °C. 29) Not subject to the requirements of ADR for Class 5.2. 30) Diluent type B with boiling point > 130 °C. 31) Active oxygen  6.7%. - 183 - 2.2.61 Class 6.1 Toxic substances 2.2.61.1 Criteria 2.2.61.1.1 The heading of Class 6.1 covers substances of which it is known by experience or regarding which it is presumed from experiments on animals that in relatively small quantities they are able by a single action or by action of short duration to cause damage to human health, or death, by inhalation, by cutaneous absorption or by ingestion. NOTE: Genetically modified microorganisms and organisms shall be assigned to this Class if they meet the conditions for this Class. 2.2.61.1.2 Substances of Class 6.1 are subdivided as follows: T Toxic substances without subsidiary risk: T1 T2 T3 T4 T5 T6 T7 T8 T9 TF Organic, liquid; Organic, solid; Organometallic substances; Inorganic, liquid; Inorganic, solid; Liquid, used as pesticides; Solid, used as pesticides; Samples; Other toxic substances; Toxic substances, flammable: TF1 TF2 TF3 Liquid; Liquid, used as pesticides; Solid; TS Toxic substances, self-heating, solid; TW Toxic substances, which, in contact with water, emit flammable gases: TW1 Liquid; TW2 Solid; TO Toxic substances, oxidizing: TO1 TO2 TC Liquid; Solid; Toxic substances, corrosive: TC1 TC2 TC3 TC4 Organic, liquid; Organic, solid; Inorganic, liquid; Inorganic, solid; TFC Toxic substances, flammable, corrosive; TFW Toxic substances, flammable, which, in contact with water, emit flammable gases. - 184 - Definitions 2.2.61.1.3 For the purposes of ADR: LD50 (median lethal dose) for acute oral toxicity is the statistically derived single dose of a substance that can be expected to cause death within 14 days in 50 per cent of young adult albino rats when administered by the oral route. The LD50 value is expressed in terms of mass of test substance per mass of test animal (mg/kg); LD50 for acute dermal toxicity is that dose of the substance which, administered by continuous contact for 24 hours with the bare skin of albino rabbits, is most likely to cause death within 14 days in one half of the animals tested. The number of animals tested shall be sufficient to give a statistically significant result and be in conformity with good pharmacological practice. The result is expressed in milligrams per kg body mass; LC50 for acute toxicity on inhalation is that concentration of vapour, mist or dust which, administered by continuous inhalation to both male and female young adult albino rats for one hour, is most likely to cause death within 14 days in one half of the animals tested. A solid substance shall be tested if at least 10% (by mass) of its total mass is likely to be dust in a respirable range, e.g. the aerodynamic diameter of that particle-fraction is 10 µm or less. A liquid substance shall be tested if a mist is likely to be generated in a leakage of the transport containment. Both for solid and liquid substances more than 90% (by mass) of a specimen prepared for inhalation toxicity shall be in the respirable range as defined above. The result is expressed in milligrams per litre of air for dusts and mists or in millilitres per cubic metre of air (parts per million) for vapours. Classification and assignment of packing groups 2.2.61.1.4 Substances of Class 6.1 shall be classified in three packing groups according to the degree of danger they present for carriage, as follows: Packing group I: Packing group II: Packing group III: highly toxic substances toxic substances slightly toxic substances. 2.2.61.1.5 Substances, mixtures, solutions and articles classified in Class 6.1 are listed in Table A of Chapter 3.2. The assignment of substances, mixtures and solutions not mentioned by name in Table A of Chapter 3.2 to the relevant entry of sub-section 2.2.61.3 and to the relevant packing group in accordance with the provisions of Chapter 2.1, shall be made according to the following criteria in 2.2.61.1.6 to 2.2.61.1.11. 2.2.61.1.6 To assess the degree of toxicity, account shall be taken of human experience of instances of accidental poisoning, as well as special properties possessed by any individual substances: liquid state, high volatility, any special likelihood of cutaneous absorption, and special biological effects. - 185 - 2.2.61.1.7 In the absence of observations on humans, the degree of toxicity shall be assessed using the available data from animal experiments in accordance with the table below: I Oral toxicity LD50 (mg/kg) ≤5 Dermal toxicity LD50 (mg/kg)  50 Inhalation toxicity by dusts and mists LC50 (mg/l)  0.2 II III a > 5 and  50 > 50 and  300 > 50 and  200 > 200 and  1 000 > 0.2 and  2 > 2 and  4 Packing group Highly toxic Toxic Slightly toxic Tear gas substances shall be included in packing group II even if data concerning their toxicity correspond to packing group III criteria. a 2.2.61.1.7.1 Where a substance exhibits different degrees of toxicity for two or more kinds of exposure, it shall be classified under the highest such degree of toxicity. 2.2.61.1.7.2 Substances meeting the criteria of Class 8 and with an inhalation toxicity of dusts and mists (LC50) leading to packing group I shall only be accepted for an allocation to Class 6.1 if the toxicity through oral ingestion or dermal contact is at least in the range of packing groups I or II. Otherwise an assignment to Class 8 shall be made if appropriate (see 2.2.8.1.5). 2.2.61.1.7.3 The criteria for inhalation toxicity of dusts and mists are based on LC50 data relating to 1-hour exposure, and where such information is available it shall be used. However, where only LC50 data relating to 4-hour exposure are available, such figures can be multiplied by four and the product substituted in the above criteria, i.e. LC50 value multiplied by four (4 hour) is considered the equivalent of LC50 (1 hour). Inhalation toxicity of vapours 2.2.61.1.8 Liquids giving off toxic vapours shall be classified into the following groups where "V" is the saturated vapour concentration (in ml/m3 of air) (volatility) at 20 °C and standard atmospheric pressure: Highly toxic Packing group I Where V ≥ 10 LC50 and LC50 ≤ 1 000 ml/m3 Toxic II Where V ≥ LC50 and LC50 ≤ 3 000 ml/m3 and the criteria for packing group I are not met Slightly toxic IIIa Where V ≥ 1/5 LC50 and LC50 ≤ 5 000 ml/m3 and the criteria for packing groups I and II are not met Tear gas substances shall be included in packing group II even if data concerning their toxicity correspond to packing group III criteria. a These criteria for inhalation toxicity of vapours are based on LC50 data relating to 1-hour exposure, and where such information is available, it shall be used. However, where only LC50 data relating to 4-hour exposure to the vapours are available, such figures can be multiplied by two and the product substituted in the above criteria, i.e. LC50 (4 hour) × 2 is considered the equivalent of LC50 (1 hour). - 186 - In this figure, the criteria are expressed in graphical form, as an aid to easy classification. However, due to approximations inherent in the use of graphs, substances falling on or near group borderlines shall be checked using numerical criteria. GROUP BORDERLINES INHALATION TOXICITY OF VAPOURS 10.000 NOT DANGEROUS FOR TRANSPORT PACKING GROUP III PACKING GROUP II LC50 1.000 PACKING GROUP I 100 10 10 100 1.000 10.000 Volatility Mixtures of liquids 2.2.61.1.9 Mixtures of liquids which are toxic on inhalation shall be assigned to packing groups according to the following criteria: - 187 - 2.2.61.1.9.1 If LC50 is known for each of the toxic substances constituting the mixture, the packing group may be determined as follows: (a) calculation of the LC50 of the mixture: LC 50 (mixture)  where fi = LC50i = (b) molar fraction of constituent i of the mixture; average lethal concentration of constituent i in ml/m3. calculation of volatility of each mixture constituent: Vi  Pi  where Pi (c) 1 f  i i 1 LC 50 i 1 = 10 6 (ml/m 3 ) 101.3 partial pressure of constituent i in kPa at 20 °C and at standard atmospheric pressure. calculation of the ratio of volatility to LC50: Vi i  1 LC 50i n R  (d) the values calculated for LC50 (mixture) and R are then used to determine the packing group of the mixture: Packing group I R  10 and LC50 (mixture)  1 000 ml/m3; Packing group II R ≥ 1 and LC50 (mixture)  3 000 ml/m3, if the mixture does not meet the criteria for packing group I; Packing group III R  1/5 and LC50 (mixture)  5 000 ml/m3, if the mixture does not meet the criteria of packing groups I or II. 2.2.61.1.9.2 In the absence of LC50 data on the toxic constituent substances, the mixture may be assigned to a group based on the following simplified threshold toxicity tests. When these threshold tests are used, the most restrictive group shall be determined and used for carrying the mixture. 2.2.61.1.9.3 A mixture is assigned to packing group I only if it meets both of the following criteria: (a) A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 1 000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LC50 equal to or less than 1 000 ml/m3; (b) A sample of vapour in equilibrium with the liquid mixture is diluted with 9 equal volumes of air to form a test atmosphere. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have a volatility equal to or greater than 10 times the mixture LC50. - 188 - 2.2.61.1.9.4 2.2.61.1.9.5 A mixture is assigned to packing group II only if it meets both of the following criteria, and does not meet the criteria for packing group I: (a) A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 3 000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LC50 equal to or less than 3 000 ml/m3; (b) A sample of the vapour in equilibrium with the liquid mixture is used to form a test atmosphere. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have a volatility equal to or greater than the mixture LC50. A mixture is assigned to packing group III only if it meets both of the following criteria, and does not meet the criteria for packing groups I or II: (a) A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 5 000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LC50 equal to or less than 5 000 ml/m3; (b) The vapour concentration (volatility) of the liquid mixture is measured and if the vapour concentration is equal to or greater than 1 000 ml/m3, the mixture is presumed to have a volatility equal to or greater than 1/5 the mixture LC50. Methods for determining oral and dermal toxicity of mixtures 2.2.61.1.10 When classifying and assigning the appropriate packing group to mixtures in Class 6.1 in accordance with the oral and dermal toxicity criteria (see 2.2.61.1.3), it is necessary to determine the acute LD50 of the mixture. 2.2.61.1.10.1 If a mixture contains only one active substance, and the LD50 of that constituent is known, in the absence of reliable acute oral and dermal toxicity data on the actual mixture to be carried, the oral or dermal LD50 may be obtained by the following method: LD 50 value of preparation  2.2.61.1.10.2 LD 50 value of active substance  100 percentage of active substance by mass If a mixture contains more than one active constituent, there are three possible approaches that may be used to determine the oral or dermal LD50 of the mixture. The preferred method is to obtain reliable acute oral and dermal toxicity data on the actual mixture to be carried. If reliable, accurate data are not available, then either of the following methods may be performed: (a) Classify the formulation according to the most hazardous constituent of the mixture as if that constituent were present in the same concentration as the total concentration of all active constituents; or - 189 - (b) Apply the formula: CA CB C 100   ...  Z  TA TB TZ TM where: C = the percentage concentration of constituent A, B, ..., Z in the mixture; T = the oral LD50 values of constituent A, B, ... Z; TM = the oral LD50 value of the mixture. NOTE: This formula can also be used for dermal toxicities provided that this information is available on the same species for all constituents. The use of this formula does not take into account any potentiation or protective phenomena. Classification of pesticides 2.2.61.1.11 All active pesticide substances and their preparations for which the LC50 and/or LD50 values are known and which are classified in Class 6.1 shall be classified under appropriate packing groups in accordance with the criteria given in 2.2.61.1.6 to 2.2.61.1.9. Substances and preparations which are characterized by subsidiary risks shall be classified according to the precedence of hazard Table in 2.1.3.10 with the assignment of appropriate packing groups. 2.2.61.1.11.1 If the oral or dermal LD50 value for a pesticide preparation is not known, but the LD50 value of its active substance(s) is known, the LD50 value for the preparation may be obtained by applying the procedures in 2.2.61.1.10. NOTE: LD50 toxicity data for a number of common pesticides may be obtained from the most current edition of the document "The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification" available from the International Programme on Chemical Safety, World Health Organisation (WHO), 1211 Geneva 27, Switzerland. While that document may be used as a source of LD50 data for pesticides, its classification system shall not be used for purposes of transport classification of, or assignment of packing groups to, pesticides, which shall be in accordance with the requirements of ADR. 2.2.61.1.11.2 The proper shipping name used in the carriage of the pesticide shall be selected on the basis of the active ingredient, of the physical state of the pesticide and any subsidiary risks it may exhibit (see 3.1.2). 2.2.61.1.12 If substances of Class 6.1, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. 2.2.61.1.13 On the basis of the criteria of 2.2.61.1.6 to 2.2.61.1.11, it may also be determined whether the nature of a solution or mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the requirements for this Class. - 190 - 2.2.61.1.14 Substances, solutions and mixtures, with the exception of substances and preparations used as pesticides, which do not meet the criteria of Directives 67/548/EEC3 or 1999/45/EC4 as amended and which are not therefore classified as highly toxic, toxic or harmful according to these directives, as amended, may be considered as substances not belonging to Class 6.1. 2.2.61.2 Substances not accepted for carriage 2.2.61.2.1 Chemically unstable substances of Class 6.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall in particular be ensured that receptacles and tanks do not contain any substance(s) likely to cause such a reaction. 2.2.61.2.2 The following substances and mixtures shall not be accepted for carriage: - Hydrogen cyanide, anhydrous or in solution, which do not meet the descriptions of UN Nos. 1051, 1613, 1614 and 3294; - metal carbonyls, having a flash-point below 23 °C, other than UN Nos. 1259 NICKEL CARBONYL and 1994 IRON PENTACARBONYL; - 2,3,7,8-TETRACHLORODIBENZO-P-DIOXINE (TCDD) in concentrations considered highly toxic in accordance with the criteria in 2.2.61.1.7; - UN No. 2249 DICHLORODIMETHYL ETHER, SYMMETRICAL; - preparations of phosphides without additives inhibiting the emission of toxic flammable gases. Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L 196 of 16.08.1967). 4 Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 on the approximation of laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations (Official Journal of the European Communities No. L 200 of 30 July 1999). 3 - 191 - 2.2.61.3 List of collective entries Toxic substances without subsidiary risk(s) liquid a T1 Organic solid a, b Organometallic c, d T2 T3 1583 1602 1602 1693 1851 2206 2206 3140 3140 3142 3144 3144 3172 3276 3278 3381 CHLOROPICRIN MIXTURE, N.O.S. DYE, LIQUID, TOXIC, N.O.S., or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. TEAR GAS SUBSTANCE, LIQUID, N.O.S. MEDICINE, LIQUID, TOXIC, N.O.S. ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. DISINFECTANT, LIQUID, TOXIC, N.O.S. NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. NITRILES, LIQUID, TOXIC, N.O.S. ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. TOXIC BY INHALATION LIQUID, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3382 TOXIC BY INHALATION LIQUID, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 2810 TOXIC LIQUID, ORGANIC, N.O.S. 1544 1544 1601 1655 1655 3448 3143 3143 3462 3249 3464 3439 2811 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. DISINFECTANT, SOLID, TOXIC, N.O.S. NICOTINE COMPOUND, SOLID, N.O.S., or NICOTINE PREPARATION, SOLID, N.O.S. TEAR GAS SUBSTANCE, SOLID, N.O.S. DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. MEDICINE, SOLID, TOXIC, N.O.S. ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. NITRILES, SOLID, TOXIC, N.O.S. TOXIC SOLID, ORGANIC, N.O.S. 2026 2788 3146 3280 3465 3281 3466 3282 3467 PHENYLMERCURIC COMPOUND, N.O.S. ORGANOTIN COMPOUND, LIQUID, N.O.S. ORGANOTIN COMPOUND, SOLID, N.O.S. ORGANOARSENIC COMPOUND, LIQUID, N.O.S. ORGANOARSENIC COMPOUND, SOLID, N.O.S. METAL CARBONYLS, LIQUID, N.O.S. METAL CARBONYLS, SOLID, N.O.S. ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. (cont'd on next page) Substances and preparations containing alkaloids or nicotine used as pesticides shall be classified under UN No. 2588 PESTICIDES, SOLID, TOXIC, N.O.S., UN No. 2902 PESTICIDES, LIQUID, TOXIC, N.O.S. or UN No. 2903 PESTICIDES, LIQUID, TOXIC, FLAMMABLE, N.O.S. a Active substances and triturations or mixtures of substances intended for laboratories and experiments and for the manufacture of pharmaceutical products with other substances shall be classified according to their toxicity (see 2.2.61.1.7 to 2.2.61.1.11). b Self-heating substances, slightly toxic and spontaneously combustible organometallic compounds, are substances of Class 4.2. c Water-reactive substances, slightly toxic, and water-reactive organometallic compounds, are substances of Class 4.3. d - 192 - 2.2.61.3 List of collective entries (cont'd) Toxic substances without subsidiary risk(s) (cont'd) liquid e T4 Inorganic solids f, g T5 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1935 CYANIDE SOLUTION, N.O.S. 2024 MERCURY COMPOUND, LIQUID, N.O.S. 3141 ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. 3440 SELENIUM COMPOUND, LIQUID, N.O.S. 3381 TOXIC BY INHALATION LIQUID, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3382 TOXIC BY INHALATION LIQUID, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3287 TOXIC LIQUID, INORGANIC, N.O.S. 1549 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S 1557 ARSENIC COMPOUND, SOLID, N.O.S., including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1564 BARIUM COMPOUND, N.O.S. 1566 BERYLLIUM COMPOUND, N.O.S. 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 1707 THALLIUM COMPOUND, N.O.S. 2025 MERCURY COMPOUND, SOLID, N.O.S. 2291 LEAD COMPOUND, SOLUBLE, N.O.S. 2570 CADMIUM COMPOUND 2630 SELENATES or 2630 SELENITES 2856 FLUOROSILICATES, N.O.S. 3283 SELENIUM COMPOUND, SOLID, N.O.S. 3284 TELLURIUM COMPOUND, N.O.S. 3285 VANADIUM COMPOUND, N.O.S. 3288 TOXIC SOLID, INORGANIC, N.O.S. 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC liquidh T6 3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 3352 PYRETHROID PESTICIDE, LIQUID, TOXIC Pesticides 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. (cont'd on next page) Mercury fulminate, wetted with not less than 20% water, or mixture of alcohol and water by mass is a substance of Class 1, UN No. 0135. e Ferricyanides, ferrocyanides, alkaline thiocyanates and ammonium thiocyanates are not subject to the provisions of ADR. f Lead salts and lead pigments which, when mixed in a ratio of 1:1,000 with 0.07M hydrochloric acid and stirred for one hour at a temperature of 23 °C ± 2 °C, exhibit a solubility of 5% or less, are not subject to the provisions of ADR. g Articles impregnated with this pesticide, such as fibreboard plates, paper strips, cotton-wool balls, sheets of plastics material, in hermetically closed wrappings, are not subject to the provisions of ADR. h - 193 - 2.2.61.3 List of collective entries (cont'd) Toxic substances without subsidiary risk(s) (cont'd) Pesticides (cont'd) Solidh Samples Other toxic substances i T7 2757 2759 2761 2763 2771 2775 2777 2779 2781 2783 2786 3027 3048 3345 3349 2588 CARBAMATE PESTICIDE, SOLID, TOXIC ARSENICAL PESTICIDE, SOLID, TOXIC ORGANOCHLORINE PESTICIDE, SOLID, TOXIC TRIAZINE PESTICIDE, SOLID, TOXIC THIOCARBAMATE PESTICIDE, SOLID, TOXIC COPPER BASED PESTICIDE, SOLID, TOXIC MERCURY BASED PESTICIDE, SOLID, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC BIPYRIDILIUM PESTICIDE, SOLID, TOXIC ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC ORGANOTIN PESTICIDE, SOLID, TOXIC COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC ALUMINIUM PHOSPHIDE PESTICIDE PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC PYRETHROID PESTICIDE, SOLID, TOXIC PESTICIDE, SOLID, TOXIC, N.O.S. T8 3315 CHEMICAL SAMPLE, TOXIC T9 3243 SOLIDS CONTAINING TOXIC LIQUID, N.O.S. Toxic substances with subsidiary risk(s) Liquid j, k Flammable TF TF1 3071 3071 3080 3080 3275 3279 3383 MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. NITRILES, TOXIC, FLAMMABLE, N.O.S. ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3384 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. (cont'd on next page) Articles impregnated with this pesticide, such as fibreboard plates, paper strips, cotton-wool balls, sheets of plastics material, in hermetically closed wrappings, are not subject to the provisions of ADR. h Mixtures of solids which are not subject to the provisions of ADR and of toxic liquids may be carried under UN No. 3243 without first applying the classification criteria of Class 6.1, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, container or transport unit is closed. Each packaging shall correspond to a design type that has passed a leakproofness test at the packing group II level. This entry shall not be used for solids containing a packing group I liquid. i j Highly toxic and toxic flammable liquids having a flash-point below 23 °C are substances of Class 3 except those which are highly toxic by inhalation, as defined in 2.2.61.1.4 to 2.2.61.1.9. Liquids which are highly toxic by inhalation are indicated as "toxic by inhalation" in their proper shipping name in Column (2) or by special provision 354 in Column (6) of Table A of Chapter 3.2. Flammable liquids, slightly toxic, with the exception of substances and preparations used as pesticides, having a flash-point between 23 °C and 60 °C inclusive, are substances of Class 3. k - 194 - 2.2.61.3 List of collective entries (cont'd) Toxic substances with subsidiary risk(s) (cont'd) Flammable TF (cont'd) pesticides, liquid TF2 (flashpoint not less than 23 °C) solid TF3 Solid, self-heating c TS Water-reactive d TW Oxidizing l TO 2991 2993 2995 2997 3005 3009 3011 3013 3015 3017 3019 3025 3347 3351 2903 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. 1700 2930 TEAR GAS CANDLES TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 3124 TOXIC SOLID, SELF-HEATING, N.O.S. liquid TW1 3385 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3386 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3123 TOXIC LIQUID, WATER-REACTIVE, N.O.S. solid n TW2 3125 TOXIC SOLID, WATER-REACTIVE, N.O.S. liquid TO1 3387 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3388 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3122 TOXIC LIQUID, OXIDIZING, N.O.S. solid TO2 3086 TOXIC SOLID, OXIDIZING, N.O.S. liquid TC1 3277 CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. 3361 CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. 3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. solid TC2 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. organic Corron sive m TC (cont'd on next page) Self-heating substances, slightly toxic and spontaneously combustible organometallic compounds, are substances of Class 4.2. c Water-reactive substances, slightly toxic, and water-reactive organometallic compounds, are substances of Class 4.3. d l Oxidizing substances, slightly toxic, are substances of Class 5.1. m Substances slightly toxic and slightly corrosive, are substances of Class 8. n Metal phosphides assigned to UN Nos. 1360, 1397, 1432, 1714, 2011 and 2013 are substances of Class 4.3. - 195 - 2.2.61.3 List of collective entries (cont'd) Toxic substances with subsidiary risk(s) (cont'd) Corrosive m TC (cont'd) liquid TC3 solid TC4 inorganic Flammable, corrosive TFC Flammable, water-reactive TFW m 3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 2742 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 3362 CHLOROSILANES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 3488 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC50 lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 3489 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC50 lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 3490 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 3491 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 Substances slightly toxic and slightly corrosive, are substances of Class 8. - 196 - 2.2.62 Class 6.2 Infectious substances 2.2.62.1 Criteria 2.2.62.1.1 The heading of Class 6.2 covers infectious substances. For the purposes of ADR, infectious substances are substances which are known or are reasonably expected to contain pathogens. Pathogens are defined as microorganisms (including bacteria, viruses, rickettsiae, parasites, fungi) and other agents such as prions, which can cause disease in humans or animals. NOTE 1: Genetically modified microorganisms and organisms, biological products, diagnostic specimens and infected live animals shall be assigned to this Class if they meet the conditions for this class. NOTE 2: Toxins from plant, animal or bacterial sources which do not contain any infectious substances or organisms or which are not contained in them are substances of Class 6.1, UN Nos. 3172 or 3462. 2.2.62.1.2 Substances of Class 6.2 are subdivided as follows: I1 Infectious substances affecting humans; I2 Infectious substances affecting animals only; I3 Clinical waste; I4 Biological substances. Definitions 2.2.62.1.3 For the purposes of ADR, "Biological products" are those products derived from living organisms which are manufactured and distributed in accordance with the requirements of appropriate national authorities, which may have special licensing requirements, and are used either for prevention, treatment, or diagnosis of disease in humans or animals, or for development, experimental or investigational purposes related thereto. They include, but are not limited to, finished or unfinished products such as vaccines; "Cultures" are the result of a process by which pathogens are intentionally propagated. This definition does not include human or animal patient specimens as defined in this paragraph; "Medical or clinical wastes" are wastes derived from the medical treatment of animals or humans or from bio-research; "Patient specimens" are human or animal materials, collected directly from humans or animals, including, but not limited to, excreta, secreta, blood and its components, tissue and tissue fluid swabs, and body parts being carried for purposes such as research, diagnosis, investigational activities, disease treatment and prevention. - 197 - Classification 2.2.62.1.4 Infectious substances shall be classified in Class 6.2 and assigned to UN Nos. 2814, 2900, 3291 or 3373, as appropriate. Infectious substances are divided into the following categories: 2.2.62.1.4.1 Category A: An infectious substance which is carried in a form that, when exposure to it occurs, is capable of causing permanent disability, life-threatening or fatal disease in otherwise healthy humans or animals. Indicative examples of substances that meet these criteria are given in the table in this paragraph. NOTE: An exposure occurs when an infectious substance is released outside of the protective packaging, resulting in physical contact with humans or animals. (a) Infectious substances meeting these criteria which cause disease in humans or both in humans and animals shall be assigned to UN No. 2814. Infectious substances which cause disease only in animals shall be assigned to UN No. 2900; (b) Assignment to UN No. 2814 or UN No. 2900 shall be based on the known medical history and symptoms of the source human or animal, endemic local conditions, or professional judgement concerning individual circumstances of the source human or animal. NOTE 1: The proper shipping name for UN No. 2814 is "INFECTIOUS SUBSTANCE, AFFECTING HUMANS". The proper shipping name for UN No. 2900 is "INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only". NOTE 2: The following table is not exhaustive. Infectious substances, including new or emerging pathogens, which do not appear in the table but which meet the same criteria shall be assigned to Category A. In addition, if there is doubt as to whether or not a substance meets the criteria it shall be included in Category A. NOTE 3: In the following table, the microorganisms written in italics are bacteria, mycoplasmas, rickettsia or fungi. - 198 - INDICATIVE EXAMPLES OF INFECTIOUS SUBSTANCES INCLUDED IN CATEGORY A IN ANY FORM UNLESS OTHERWISE INDICATED (2.2.62.1.4.1) UN Number and Microorganism name Bacillus anthracis (cultures only) UN No. 2814 Infectious Brucella abortus (cultures only) substances affecting Brucella melitensis (cultures only) humans Brucella suis (cultures only) Burkholderia mallei - Pseudomonas mallei – Glanders (cultures only) Burkholderia pseudomallei – Pseudomonas pseudomallei (cultures only) Chlamydia psittaci - avian strains (cultures only) Clostridium botulinum (cultures only) Coccidioides immitis (cultures only) Coxiella burnetii (cultures only) Crimean-Congo haemorrhagic fever virus Dengue virus (cultures only) Eastern equine encephalitis virus (cultures only) Escherichia coli, verotoxigenic (cultures only) a Ebola virus Flexal virus Francisella tularensis (cultures only) Guanarito virus Hantaan virus Hantavirus causing haemorrhagic fever with renal syndrome Hendra virus Hepatitis B virus (cultures only) Herpes B virus (cultures only) Human immunodeficiency virus (cultures only) Highly pathogenic avian influenza virus (cultures only) Japanese Encephalitis virus (cultures only) Junin virus Kyasanur Forest disease virus Lassa virus Machupo virus Marburg virus Monkeypox virus Mycobacterium tuberculosis (cultures only) a Nipah virus Omsk haemorrhagic fever virus Poliovirus (cultures only) Rabies virus (cultures only) Rickettsia prowazekii (cultures only) Rickettsia rickettsii (cultures only) Rift Valley fever virus (cultures only) Russian spring-summer encephalitis virus (cultures only) Sabia virus Shigella dysenteriae type 1 (cultures only) a Tick-borne encephalitis virus (cultures only) Variola virus Venezuelan equine encephalitis virus (cultures only) West Nile virus (cultures only) Yellow fever virus (cultures only) Yersinia pestis (cultures only) Nevertheless, when the cultures are intended for diagnostic or clinical purposes, they may be classified as infectious substances of Category B. a - 199 - INDICATIVE EXAMPLES OF INFECTIOUS SUBSTANCES INCLUDED IN CATEGORY A IN ANY FORM UNLESS OTHERWISE INDICATED (2.2.62.1.4.1) UN Number Microorganism and name African swine fever virus (cultures only) UN No. 2900 Infectious Avian paramyxovirus Type 1 - Velogenic Newcastle disease virus (cultures only) substances affecting Classical swine fever virus (cultures only) animals only Foot and mouth disease virus (cultures only) Lumpy skin disease virus (cultures only) Mycoplasma mycoides - Contagious bovine pleuropneumonia (cultures only) Peste des petits ruminants virus (cultures only) Rinderpest virus (cultures only) Sheep-pox virus (cultures only) Goatpox virus (cultures only) Swine vesicular disease virus (cultures only) Vesicular stomatitis virus (cultures only) 2.2.62.1.4.2 Category B: An infectious substance which does not meet the criteria for inclusion in Category A. Infectious substances in Category B shall be assigned to UN No. 3373. NOTE: The proper shipping name of UN No. 3373 is "BIOLOGICAL SUBSTANCE, CATEGORY B ". 2.2.62.1.5 Exemptions 2.2.62.1.5.1 Substances which do not contain infectious substances or substances which are unlikely to cause disease in humans or animals are not subject to the provisions of ADR unless they meet the criteria for inclusion in another class. 2.2.62.1.5.2 Substances containing microorganisms which are non-pathogenic to humans or animals are not subject to ADR unless they meet the criteria for inclusion in another class. 2.2.62.1.5.3 Substances in a form that any present pathogens have been neutralized or inactivated such that they no longer pose a health risk are not subject to ADR unless they meet the criteria for inclusion in another class. NOTE: Medical equipment which has been drained of free liquid is deemed to meet the requirements of this paragraph and is not subject to the provisions of ADR. 2.2.62.1.5.4 Substances where the concentration of pathogens is at a level naturally encountered (including foodstuff and water samples) and which are not considered to pose a significant risk of infection are not subject to ADR unless they meet the criteria for inclusion in another class. 2.2.62.1.5.5 Dried blood spots, collected by applying a drop of blood onto absorbent material, are not subject to ADR. 2.2.62.1.5.6 Faecal occult blood screening samples are not subject to ADR. 2.2.62.1.5.7 Blood or blood components which have been collected for the purposes of transfusion or for the preparation of blood products to be used for transfusion or transplantation and any tissues or organs intended for use in transplantation as well as samples drawn in connection with such purposes are not subject to ADR. 2.2.62.1.5.8 Human or animal specimens for which there is minimal likelihood that pathogens are present are not subject to ADR if the specimen is carried in a packaging which will prevent any leakage and which is marked with the words "Exempt human specimen" or "Exempt animal specimen", as appropriate. - 200 - The packaging is deemed to comply with the above requirements if it meets the following conditions: (a) The packaging consists of three components: (i) a leak-proof primary receptacle(s); (ii) a leak-proof secondary packaging; and (iii) an outer packaging of adequate strength for its capacity, mass and intended use, and with at least one surface having minimum dimensions of 100 mm × 100 mm; (b) For liquids, absorbent material in sufficient quantity to absorb the entire contents is placed between the primary receptacle(s) and the secondary packaging so that, during carriage, any release or leak of a liquid substance will not reach the outer packaging and will not compromise the integrity of the cushioning material; (c) When multiple fragile primary receptacles are placed in a single secondary packaging, they are either individually wrapped or separated to prevent contact between them. NOTE 1: An element of professional judgment is required to determine if a substance is exempt under this paragraph. That judgment should be based on the known medical history, symptoms and individual circumstances of the source, human or animal, and endemic local conditions. Examples of specimens which may be carried under this paragraph include the blood or urine tests to monitor cholesterol levels, blood glucose levels, hormone levels, or prostate specific antibodies (PSA); those required to monitor organ function such as heart, liver or kidney function for humans or animals with non-infectious diseases, or for therapeutic drug monitoring; those conducted for insurance or employment purposes and are intended to determine the presence of drugs or alcohol; pregnancy test; biopsies to detect cancer; and antibody detection in humans or animals in the absence of any concern for infection (e.g. evaluation of vaccine induced immunity, diagnosis of autoimmune disease, etc.). NOTE 2: For air transport, packagings for specimens exempted under this paragraph shall meet the conditions in (a) to (c). 2.2.62.1.5.9 Except for: (a) Medical waste (UN No. 3291); (b) Medical devices or equipment contaminated with or containing infectious substances in Category A (UN No. 2814 or UN No. 2900); and (c) Medical devices or equipment contaminated with or containing other dangerous goods that meet the definition of another class, medical devices or equipment potentially contaminated with or containing infectious substances which are being carried for disinfection, cleaning, sterilization, repair, or equipment evaluation are not subject to provisions of ADR other than those of this paragraph if packed in packagings designed and constructed in such a way that, under normal conditions of carriage, they cannot break, be punctured or leak their contents. Packagings shall be designed to meet the construction requirements listed in 6.1.4 or 6.6.4. These packagings shall meet the general packing requirements of 4.1.1.1 and 4.1.1.2 and be capable of retaining the medical devices and equipment when dropped from a height of 1.2 m. The packagings shall be marked "USED MEDICAL DEVICE" or "USED MEDICAL EQUIPMENT". When using overpacks, these shall be marked in the same way, except when the inscription remains visible. 2.2.62.1.6 to 2.2.62.1.8 (Reserved) - 201 - 2.2.62.1.9 Biological products For the purposes of ADR, biological products are divided into the following groups: (a) those which are manufactured and packaged in accordance with the requirements of appropriate national authorities and carried for the purposes of final packaging or distribution, and use for personal health care by medical professionals or individuals. Substances in this group are not subject to the provisions of ADR; (b) those which do not fall under paragraph (a) and are known or reasonably believed to contain infectious substances and which meet the criteria for inclusion in Category A or Category B. Substances in this group shall be assigned to UN Nos. 2814, 2900 or 3373, as appropriate. NOTE: Some licensed biological products may present a biohazard only in certain parts of the world. In that case, competent authorities may require these biological products to be in compliance with local requirements for infectious substances or may impose other restrictions. 2.2.62.1.10 Genetically modified microorganisms and organisms Genetically modified microorganisms not meeting the definition of infectious substance shall be classified according to section 2.2.9. 2.2.62.1.11 Medical or clinical wastes 2.2.62.1.11.1 Medical or clinical wastes containing Category A infectious substances shall be assigned to UN No. 2814 or UN No. 2900 as appropriate. Medical or clinical wastes containing infectious substances in Category B shall be assigned to UN No. 3291. NOTE: Medical or clinical wastes assigned to number 18 01 03 (Wastes from human or animal health care and/or related research – wastes from natal care, diagnosis, treatment or prevention of disease in humans – wastes whose collection and disposal is subject to special requirements in order to prevent infection) or 18 02 02 (Wastes from human or animal health care and/or related research – wastes from research, diagnosis, treatment or prevention of disease involving animals – wastes whose collection and disposal is subject to special requirements in order to prevent infection) according to the list of wastes annexed to the Commission Decision 2000/532/EC5 as amended, shall be classified according to the provisions set out in this paragraph, based on the medical or veterinary diagnosis concerning the patient or the animal. 2.2.62.1.11.2 Medical or clinical wastes which are reasonably believed to have a low probability of containing infectious substances shall be assigned to UN No. 3291. For the assignment, international, regional or national waste catalogues may be taken into account. NOTE 1: The proper shipping name for UN No. 3291 is "CLINICAL WASTE, UNSPECIFIED, N.O.S." or "(BIO) MEDICAL WASTE, N.O.S". or "REGULATED MEDICAL WASTE, N.O.S.". NOTE 2: Notwithstanding the classification criteria set out above, medical or clinical wastes assigned to number 18 01 04 (Wastes from human or animal health care and/or related research – wastes from natal care, diagnosis, treatment or prevention of disease in humans – wastes whose collection and disposal is not subject to special requirements in order to prevent infection) or 18 02 03 (Wastes from human or animal health care and/or related research – wastes from research, diagnosis, treatment or prevention of disease involving animals – wastes whose collection and disposal is not subject to special requirements in order to prevent infection) according to the list of wastes annexed to the Commission Decision 2000/532/EC5 as amended, are not subject to the provisions of ADR. Commission Decision 2000/532/EC of 3 May 2000 replacing Decision 94/3/EC establishing a list of wastes pursuant to Article 1(a) of Council Directive 75/442/EEC on waste (replaced by the Directive 2006/12/EC of the European Parliament and of the Council (Official Journal of the European Union No. L 114 of 27 April 2006, page 9)) and Council Decision 94/904/EC establishing a list of hazardous waste pursuant to Article 1(4) of Council Directive 91/689/EEC on hazardous waste (Official Journal of the European Communities No. L 226 of 6 September 2000, page 3). 5 - 202 - 2.2.62.1.11.3 Decontaminated medical or clinical wastes which previously contained infectious substances are not subject to the provisions of ADR unless they meet the criteria for inclusion in another class. 2.2.62.1.11.4 Medical or clinical wastes assigned to UN No. 3291 are assigned to packing group II. 2.2.62.1.12 Infected animals 2.2.62.1.12.1 Unless an infectious substance cannot be consigned by any other means, live animals shall not be used to consign such a substance. A live animal which has been intentionally infected and is known or suspected to contain an infectious substance shall only be carried under terms and conditions approved by the competent authority 6. 2.2.62.1.12.2 Animal material affected by pathogens of Category A or by pathogens which would be assigned to Category A in cultures only, shall be assigned to UN 2814 or UN 2900 as appropriate. Animal material affected by pathogens of Category B, other than those which would be assigned to Category A if they were in cultures, shall be assigned to UN 3373. 2.2.62.2 Substances not accepted for carriage Live vertebrate or invertebrate animals shall not be used to carry an infectious agent unless the agent cannot be carried by other means or unless this carriage has been approved by the competent authority (see 2.2.62.1.12.1). 2.2.62.3 List of collective entries Effects on humans I1 2814 INFECTIOUS SUBSTANCE, AFFECTING HUMANS Effects on animals only I2 2900 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only Clinical waste I3 3291 3291 3291 CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S. Biological substances I4 3373 BIOLOGICAL SUBSTANCE, CATEGORY B Regulations governing the carriage of live animals are contained in, e.g. Directive 91/628/EEC of 19 November 1991 on the protection of animals during transport (Official Journal of the European Communities No. L 340 of 11.12.1991, p.17) and in the Recommendations of the Council of Europe (Ministerial Committee) on the carriage of certain animal species. 6 - 203 - 2.2.7 Class 7 Radioactive material 2.2.7.1 Definitions 2.2.7.1.1 Radioactive material means any material containing radionuclides where both the activity concentration and the total activity in the consignment exceed the values specified in 2.2.7.2.2.1 to 2.2.7.2.2.6. 2.2.7.1.2 Contamination Contamination means the presence of a radioactive substance on a surface in quantities in excess of 0.4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 0.04 Bq/cm2 for all other alpha emitters. Non-fixed contamination means contamination that can be removed from a surface during routine conditions of carriage. Fixed contamination means contamination other than non-fixed contamination. 2.2.7.1.3 Definitions of specific terms A1 and A2 A1 means the activity value of special form radioactive material which is listed in the Table in 2.2.7.2.2.1 or derived in 2.2.7.2.2.2 and is used to determine the activity limits for the requirements of ADR. A2 means the activity value of radioactive material, other than special form radioactive material, which is listed in the Table in 2.2.7.2.2.1 or derived in 2.2.7.2.2.2 and is used to determine the activity limits for the requirements of ADR. Fissile nuclides means uranium-233, uranium-235, plutonium-239 and plutonium-241. Fissile material means a material containing any of the fissile nuclides. Excluded from the definition of fissile material are the following: (a) Natural uranium or depleted uranium which is unirradiated; (b) Natural uranium or depleted uranium which has been irradiated in thermal reactors only; (c) Material with fissile nuclides less than a total of 0.25 g; (d) Any combination of (a), (b) and/or (c). These exclusions are only valid if there is no other material with fissile nuclides in the package or in the consignment if shipped unpackaged. Low dispersible radioactive material means either a solid radioactive material or a solid radioactive material in a sealed capsule, that has limited dispersibility and is not in powder form. Low specific activity (LSA) material means radioactive material which by its nature has a limited specific activity, or radioactive material for which limits of estimated average specific activity apply. External shielding materials surrounding the LSA material shall not be considered in determining the estimated average specific activity. Low toxicity alpha emitters are: natural uranium; depleted uranium; natural thorium; uranium-235 or uranium-238; thorium-232; thorium-228 and thorium-230 when contained in ores or physical and chemical concentrates; or alpha emitters with a half-life of less than 10 days. - 204 - Special form radioactive material means either: (a) An indispersible solid radioactive material; or (b) A sealed capsule containing radioactive material. Specific activity of a radionuclide means the activity per unit mass of that nuclide. The specific activity of a material shall mean the activity per unit mass of the material in which the radionuclides are essentially uniformly distributed. Surface contaminated object (SCO) means a solid object which is not itself radioactive but which has radioactive material distributed on its surface. Unirradiated thorium means thorium containing not more than 10-7 g of uranium-233 per gram of thorium-232. Unirradiated uranium means uranium containing not more than 2  103 Bq of plutonium per gram of uranium-235, not more than 9  106 Bq of fission products per gram of uranium-235 and not more than 5  10-3 g of uranium-236 per gram of uranium-235. Uranium - natural, depleted, enriched means the following: Natural uranium means uranium (which may be chemically separated) containing the naturally occurring distribution of uranium isotopes (approximately 99.28% uranium-238, and 0.72% uranium-235 by mass). Depleted uranium means uranium containing a lesser mass percentage of uranium-235 than in natural uranium. Enriched uranium means uranium containing a greater mass percentage of uranium-235 than 0.72%. In all cases, a very small mass percentage of uranium-234 is present. 2.2.7.2 Classification 2.2.7.2.1 General provisions 2.2.7.2.1.1 Radioactive material shall be assigned to one of the UN numbers specified in Table 2.2.7.2.1.1, in accordance with 2.2.7.2.4 and 2.2.7.2.5, taking into account the material characteristics determined in 2.2.7.2.3. - 205 - Table 2.2.7.2.1.1 Assignment of UN numbers UN No. Proper shipping name and descriptiona Excepted packages (1.7.1.5) UN 2908 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING UN 2909 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM UN 2910 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL UN 2911 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - INSTRUMENTS or ARTICLES UN 3507 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE less than 0.1 kg per package, non-fissile or fissile-exceptedb,c Low specific activity radioactive material (2.2.7.2.3.1) UN 2912 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I), non fissile or fissile-exceptedb UN 3321 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), non fissile or fissile-exceptedb UN 3322 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-III), non fissile or fissile-exceptedb UN 3324 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), FISSILE UN 3325 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (LSA-III), FISSILE Surface contaminated objects (2.2.7.2.3.2) UN 2913 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), non fissile or fissile-exceptedb UN 3326 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSILE Type A packages (2.2.7.2.4.4) UN 2915 RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissileexceptedb UN 3327 RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non-special form UN 3332 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, non fissile or fissileexceptedb UN 3333 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE Type B(U) packages (2.2.7.2.4.6) UN 2916 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile or fissile-exceptedb UN 3328 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE Type B(M) packages (2.2.7.2.4.6) UN 2917 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, non fissile or fissile-exceptedb UN 3329 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE Type C packages (2.2.7.2.4.6) UN 3323 RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissile-exceptedb UN 3330 RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE - 206 - UN Nos. Proper shipping name and descriptiona Special arrangement (2.2.7.2.5) UN 2919 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-exceptedb UN 3331 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE Uranium hexafluoride (2.2.7.2.4.5) UN 2977 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE UN 2978 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non fissile or fissile-exceptedb UN 3507 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE less than 0.1 kg per package, non-fissile or fissile-exceptedb,c a The proper shipping name is found in the column “proper shipping name and description” and is restricted to that part shown in capital letters. In the cases of UN Nos. 2909, 2911, 2913 and 3326, where alternative proper shipping names are separated by the word “or” only the relevant proper shipping name shall be used. b The term "fissile-excepted" refers only to material excepted under 2.2.7.2.3.5. c For UN No. 3507, see also special provision 369 in Chapter 3.3. 2.2.7.2.2 Determination of basic radionuclide values 2.2.7.2.2.1 The following basic values for individual radionuclides are given in Table 2.2.7.2.2.1: (a) A1 and A2 in TBq; (b) Activity concentration limits for exempt material in Bq/g; and (c) Activity limits for exempt consignments in Bq. Table 2.2.7.2.2.1: Basic radionuclides values for individual radionuclides Radionuclide (atomic number) Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 6 × 10-3 1 × 101 1 × 104 9 × 10-1 9 × 10-5 1 × 10-1 1 × 103 6 × 10-1 5 × 10-1 1 × 101 1 × 106 Ag-105 2 × 100 2 × 100 1 × 102 1 × 106 Ag-108m (a) 7 × 10-1 7 ×10-1 1 ×101 (b) 1 × 106 (b) Ag-110m (a) 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Ag-111 2 × 100 6 × 10-1 1 × 103 1 × 106 1 × 10-1 1 × 10-1 1 × 101 1 × 105 Am-241 1 × 101 1 × 10-3 1 × 100 1 × 104 Am-242m (a) 1 × 101 1 × 10-3 1 × 100 (b) 1 × 104 (b) A1 A2 (TBq) (TBq) Ac-225 (a) 8 × 10-1 Ac-227 (a) Ac-228 Actinium (89) Silver (47) Aluminium (13) Al-26 Americium (95) - 207 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 1 × 10-3 1 × 100 (b) 1 × 103 (b) 4 × 101 4 × 101 1 × 106 1 × 108 Ar-39 4 × 101 2 × 101 1 × 107 1 × 104 Ar-41 3 × 10-1 3 × 10-1 1 × 102 1 × 109 As-72 3 × 10-1 3 × 10-1 1 × 101 1 × 105 As-73 4 × 101 4 × 101 1 × 103 1 × 107 As-74 1 × 100 9 × 10-1 1 × 101 1 × 106 As-76 3 × 10-1 3 × 10-1 1 × 102 1 × 105 As-77 2 × 101 7 × 10-1 1 × 103 1 × 106 2 × 101 5 × 10-1 1 × 103 1 × 107 Au-193 7 × 100 2 × 100 1 × 102 1 × 107 Au-194 1 × 100 1 × 100 1 × 101 1 × 106 Au-195 1 × 101 6 × 100 1 × 102 1 × 107 Au-198 1 × 100 6 × 10-1 1 × 102 1 × 106 Au-199 1 × 101 6 × 10-1 1 × 102 1 × 106 Ba-131 (a) 2 × 100 2 × 100 1 × 102 1 × 106 Ba-133 3 × 100 3 × 100 1 × 102 1 × 106 Ba-133m 2 × 101 6 × 10-1 1 × 102 1 × 106 Ba-140 (a) 5 × 10-1 3 × 10-1 1 × 101 (b) 1 × 105 (b) Be-7 2 × 101 2 × 101 1 × 103 1 × 107 Be-10 4 × 101 6 × 10-1 1 × 104 1 × 106 Bi-205 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Bi-206 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Bi-207 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Bi-210 1 × 100 6 × 10-1 1 × 103 1 × 106 Bi-210m (a) 6 × 10-1 2 × 10-2 1 × 101 1 × 105 Radionuclide (atomic number) A1 A2 (TBq) (TBq) 5 × 100 Ar-37 Am-243 (a) Argon (18) Arsenic (33) Astatine (85) At-211 (a) Gold (79) Barium (56) Beryllium (4) Bismuth (83) - 208 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 6 × 10-1 1 × 101 (b) 1 × 105 (b) 8 × 100 8 × 10-4 1 × 100 1 × 104 4 × 101 3 × 10-1 1 × 103 1 × 106 Br-76 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Br-77 3 × 100 3 × 100 1 × 102 1 × 106 Br-82 4 × 10-1 4 × 10-1 1 × 101 1 × 106 C-11 1 × 100 6 × 10-1 1 × 101 1 × 106 C-14 4 × 101 3 × 100 1 × 104 1 × 107 Ca-41 Unlimited Unlimited 1 × 105 1 × 107 Ca-45 4 × 101 1 × 100 1 × 104 1 × 107 Ca-47 (a) 3 × 100 3 × 10-1 1 × 101 1 × 106 Cd-109 3 × 101 2 × 100 1 × 104 1 × 106 Cd-113m 4 × 101 5 × 10-1 1 × 103 1 × 106 Cd-115 (a) 3 × 100 4 × 10-1 1 × 102 1 × 106 Cd-115m 5 × 10-1 5 × 10-1 1 × 103 1 × 106 Ce-139 7 × 100 2 × 100 1 × 102 1 × 106 Ce-141 2 × 101 6 × 10-1 1 × 102 1 × 107 Ce-143 9 × 10-1 6 × 10-1 1 × 102 1 × 106 Ce-144 (a) 2 × 10-1 2 × 10-1 1 × 102 (b) 1 × 105 (b) Cf-248 4 × 101 6 × 10-3 1 × 101 1 × 104 Cf-249 3 × 100 8 × 10-4 1 × 100 1 × 103 Cf-250 2 × 101 2 × 10-3 1 × 101 1 × 104 Cf-251 7 × 100 7 × 10-4 1 × 100 1 × 103 Cf-252 1 × 10-1 3 × 10-3 1 × 101 1 × 104 Cf-253 (a) 4 × 101 4 × 10-2 1 × 102 1 × 105 Cf-254 1 × 10-3 1 × 10-3 1 × 100 1 × 103 Radionuclide (atomic number) A1 A2 (TBq) (TBq) 7 × 10-1 Bk-247 Bk-249 (a) Bi-212 (a) Berkelium (97) Bromine (35) Carbon (6) Calcium (20) Cadmium (48) Cerium (58) Californium (98) - 209 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 6 × 10-1 1 × 104 1 × 106 2 × 10-1 2 × 10-1 1 × 101 1 × 105 Cm-240 4 × 101 2 × 10-2 1 × 102 1 × 105 Cm-241 2 × 100 1 × 100 1 × 102 1 × 106 Cm-242 4 × 101 1 × 10-2 1 × 102 1 × 105 Cm-243 9 × 100 1 × 10-3 1 × 100 1 × 104 Cm-244 2 × 101 2 × 10-3 1 × 101 1 × 104 Cm-245 9 × 100 9 × 10-4 1 × 100 1 × 103 Cm-246 9 × 100 9 × 10-4 1 × 100 1 × 103 Cm-247 (a) 3 × 100 1 × 10-3 1 × 100 1 × 104 Cm-248 2 × 10-2 3 × 10-4 1 × 100 1 × 103 Co-55 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Co-56 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Co-57 1 × 101 1 × 101 1 × 102 1 × 106 Co-58 1 × 100 1 × 100 1 × 101 1 × 106 Co-58m 4 × 101 4 × 101 1 × 104 1 × 107 Co-60 4 × 10-1 4 × 10-1 1 × 101 1 × 105 3 × 101 3 × 101 1 × 103 1 × 107 Cs-129 4 × 100 4 × 100 1 × 102 1 × 105 Cs-131 3 × 101 3 × 101 1 × 103 1 × 106 Cs-132 1 × 100 1 × 100 1 × 101 1 × 105 Cs-134 7 × 10-1 7 × 10-1 1 × 101 1 × 104 Cs-134m 4 × 101 6 × 10-1 1 × 103 1 × 105 Cs-135 4 × 101 1 × 100 1 × 104 1 × 107 Cs-136 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Cs-137 (a) 2 × 100 6 × 10-1 1 × 101 (b) 1 × 104 (b) Radionuclide (atomic number) A1 A2 (TBq) (TBq) Cl-36 1 × 101 Cl-38 Chlorine (17) Curium (96) Cobalt (27) Chromium (24) Cr-51 Caesium (55) - 210 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 1 × 100 1 × 102 1 × 106 1 × 101 7 × 10-1 1 × 102 1 × 106 Dy-159 2 × 101 2 × 101 1 × 103 1 × 107 Dy-165 9 × 10-1 6 × 10-1 1 × 103 1 × 106 Dy-166 (a) 9 × 10-1 3 × 10-1 1 × 103 1 × 106 Er-169 4 × 101 1 × 100 1 × 104 1 × 107 Er-171 8 × 10-1 5 × 10-1 1 × 102 1 × 106 Eu-147 2 × 100 2 × 100 1 × 102 1 × 106 Eu-148 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Eu-149 2 × 101 2 × 101 1 × 102 1 × 107 Eu-150(short lived) 2 × 100 7 × 10-1 1 × 103 1 × 106 Eu-150(long lived) 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Eu-152 1 × 100 1 × 100 1 × 101 1 × 106 Eu-152m 8 × 10-1 8 × 10-1 1 × 102 1 × 106 Eu-154 9 × 10-1 6 × 10-1 1 × 101 1 × 106 Eu-155 2 × 101 3 × 100 1 × 102 1 × 107 Eu-156 7 × 10-1 7 × 10-1 1 × 101 1 × 106 1 × 100 6 × 10-1 1 × 101 1 × 106 Fe-52 (a) 3 × 10-1 3 × 10-1 1 × 101 1 × 106 Fe-55 4 × 101 4 × 101 1 × 104 1 × 106 Fe-59 9 × 10-1 9 × 10-1 1 × 101 1 × 106 Fe-60 (a) 4 × 101 2 × 10-1 1 × 102 1 × 105 Ga-67 7 × 100 3 × 100 1 × 102 1 × 106 Ga-68 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Ga-72 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Cu-64 6 × 100 Cu-67 Copper (29) Dysprosium (66) Erbium (68) Europium (63) Fluorine (9) F-18 Iron (26) Gallium (31) Gadolinium (64) - 211 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 5 × 10-1 1 × 101 1 × 106 2 × 101 2 × 10-3 1 × 101 1 × 104 Gd-153 1 × 101 9 × 100 1 × 102 1 × 107 Gd-159 3 × 100 6 × 10-1 1 × 103 1 × 106 Ge-68 (a) 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Ge-71 4 × 101 4 × 101 1 × 104 1 × 108 Ge-77 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Hf-172 (a) 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Hf-175 3 × 100 3 × 100 1 × 102 1 × 106 Hf-181 2 × 100 5 × 10-1 1 × 101 1 × 106 Hf-182 Unlimited Unlimited 1 × 102 1 × 106 Hg-194 (a) 1 × 100 1 × 100 1 × 101 1 × 106 Hg-195m (a) 3 × 100 7 × 10-1 1 × 102 1 × 106 Hg-197 2 × 101 1 × 101 1 × 102 1 × 107 Hg-197m 1 × 101 4 × 10-1 1 × 102 1 × 106 Hg-203 5 × 100 1 × 100 1 × 102 1 × 105 Ho-166 4 × 10-1 4 × 10-1 1 × 103 1 × 105 Ho-166m 6 × 10-1 5 × 10-1 1 × 101 1 × 106 I-123 6 × 100 3 × 100 1 × 102 1 × 107 I-124 1 × 100 1 × 100 1 × 101 1 × 106 I-125 2 × 101 3 × 100 1 × 103 1 × 106 I-126 2 × 100 1 × 100 1 × 102 1 × 106 I-129 Unlimited Unlimited 1 ×102 1 × 105 I-131 3 × 100 7 × 10-1 1 × 102 1 × 106 I-132 4 × 10-1 4 × 10-1 1 × 101 1 × 105 I-133 7 × 10-1 6 × 10-1 1 × 101 1 × 106 I-134 3 × 10-1 3 × 10-1 1 × 101 1 × 105 I-135 (a) 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Gd-146 (a) 5 × 10-1 Gd-148 Germanium (32) Hafnium (72) Mercury (80) Holmium (67) Iodine (53) - 212 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 3 × 100 1 × 102 1 × 106 4 × 100 2 × 100 1 × 102 1 × 106 In-114m (a) 1 × 101 5 × 10-1 1 × 102 1 × 106 In-115m 7 × 100 1 × 100 1 × 102 1 × 106 Ir-189 (a) 1 × 101 1 × 101 1 × 102 1 × 107 Ir-190 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Ir-192 1 × 100(c) 6 × 10-1 1 × 101 1 × 104 Ir-194 3 × 10-1 3 × 10-1 1 × 102 1 × 105 K-40 9 × 10-1 9 × 10-1 1 × 102 1 × 106 K-42 2 × 10-1 2 × 10-1 1 × 102 1 × 106 K-43 7 × 10-1 6 × 10-1 1 × 101 1 × 106 Kr-79 4 × 100 2 × 100 1 × 103 1 × 105 Kr-81 4 × 101 4 × 101 1 × 104 1 × 107 Kr-85 1 × 101 1 × 101 1 × 105 1 × 104 Kr-85m 8 × 100 3 × 100 1 × 103 1 × 1010 Kr-87 2 × 10-1 2 × 10-1 1 × 102 1 × 109 La-137 3 × 101 6 × 100 1 × 103 1 × 107 La-140 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Lu-172 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Lu-173 8 × 100 8 × 100 1 × 102 1 × 107 Lu-174 9 × 100 9 × 100 1 × 102 1 × 107 Lu-174m 2 × 101 1 × 101 1 × 102 1 × 107 Lu-177 3 × 101 7 × 10-1 1 × 103 1 × 107 3 × 10-1 3 × 10-1 1 × 101 1 × 105 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Radionuclide (atomic number) A1 A2 (TBq) (TBq) In-111 3 × 100 In-113m Indium (49) Iridium (77) Potassium (19) Krypton (36) Lanthanum (57) Lutetium (71) Magnesium (12) Mg-28 (a) Manganese (25) Mn-52 - 213 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) Unlimited 1 × 104 1 × 109 1 × 100 1 × 100 1 × 101 1 × 106 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Mo-93 4 × 101 2 × 101 1 × 103 1 × 108 Mo-99 (a) 1 × 100 6 × 10-1 1 × 102 1 × 106 9 × 10-1 6 × 10-1 1 × 102 1 × 109 Na-22 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Na-24 2 × 10-1 2 × 10-1 1 × 101 1 × 105 Nb-93m 4 × 101 3 × 101 1 × 104 1 × 107 Nb-94 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Nb-95 1 × 100 1 × 100 1 × 101 1 × 106 Nb-97 9 × 10-1 6 × 10-1 1 × 101 1 × 106 Nd-147 6 × 100 6 × 10-1 1 × 102 1 × 106 Nd-149 6 × 10-1 5 × 10-1 1 × 102 1 × 106 Ni-59 Unlimited Unlimited 1 × 104 1 × 108 Ni-63 4 × 101 3 × 101 1 × 105 1 × 108 Ni-65 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Np-235 4 × 101 4 × 101 1 × 103 1 × 107 Np-236(short-lived) 2 × 101 2 × 100 1 × 103 1 × 107 Np-236(long-lived) 9 × 100 2 × 10-2 1 × 102 1 × 105 Np-237 2 × 101 2 × 10-3 1 × 100 (b) 1 × 103 (b) Np-239 7 × 100 4 × 10-1 1 × 102 1 × 107 Os-185 1 × 100 1 × 100 1 × 101 1 × 106 Os-191 1 × 101 2 × 100 1 × 102 1 × 107 Os-191m 4 × 101 3 × 101 1 × 103 1 × 107 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Mn-53 Unlimited Mn-54 Mn-56 Molybdenum (42) Nitrogen (7) N-13 Sodium (11) Niobium (41) Neodymium (60) Nickel (28) Neptunium (93) Osmium (76) - 214 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 6 × 10-1 1 × 102 1 × 106 3 × 10-1 3 × 10-1 1 × 102 1 × 105 P-32 5 × 10-1 5 × 10-1 1 × 103 1 × 105 P-33 4 × 101 1 × 100 1 × 105 1 × 108 Pa-230 (a) 2 × 100 7 × 10-2 1 × 101 1 × 106 Pa-231 4 × 100 4 × 10-4 1 × 100 1 × 103 Pa-233 5 × 100 7 × 10-1 1 × 102 1 × 107 Pb-201 1 × 100 1 × 100 1 × 101 1 × 106 Pb-202 4 × 101 2 × 101 1 × 103 1 × 106 Pb-203 4 × 100 3 × 100 1 × 102 1 × 106 Pb-205 Unlimited Unlimited 1 × 104 1 × 107 Pb-210 (a) 1 × 100 5 × 10-2 1 × 101 (b) 1 × 104 (b) Pb-212 (a) 7 × 10-1 2 × 10-1 1 × 101 (b) 1 × 105 (b) Pd-103 (a) 4 × 101 4 × 101 1 × 103 1 × 108 Pd-107 Unlimited Unlimited 1 × 105 1 × 108 Pd-109 2 × 100 5 × 10-1 1 × 103 1 × 106 Pm-143 3 × 100 3 × 100 1 × 102 1 × 106 Pm-144 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Pm-145 3 × 101 1 × 101 1 × 103 1 × 107 Pm-147 4 × 101 2 × 100 1 × 104 1 × 107 Pm-148m (a) 8 × 10-1 7 × 10-1 1 × 101 1 × 106 Pm-149 2 × 100 6 × 10-1 1 × 103 1 × 106 Pm-151 2 × 100 6 × 10-1 1 × 102 1 × 106 4 × 101 2 × 10-2 1 × 101 1 × 104 Pr-142 4 × 10-1 4 × 10-1 1 × 102 1 × 105 Pr-143 3 × 100 6 × 10-1 1 × 104 1 × 106 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Os-193 2 × 100 Os-194 (a) Phosphorus (15) Protactinium (91) Lead (82) Palladium (46) Promethium (61) Polonium (84) Po-210 Praseodymium (59) - 215 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 8 × 10-1 1 × 101 1 × 106 4 × 100 3 × 100 1 × 102 1 × 106 Pt-193 4 × 101 4 × 101 1 × 104 1 × 107 Pt-193m 4 × 101 5 × 10-1 1 × 103 1 × 107 Pt-195m 1 × 101 5 × 10-1 1 × 102 1 × 106 Pt-197 2 × 101 6 × 10-1 1 × 103 1 × 106 Pt-197m 1 × 101 6 × 10-1 1 × 102 1 × 106 Pu-236 3 × 101 3 × 10-3 1 × 101 1 × 104 Pu-237 2 × 101 2 × 101 1 × 103 1 × 107 Pu-238 1 × 101 1 × 10-3 1 × 100 1 × 104 Pu-239 1 × 101 1 × 10-3 1 × 100 1 × 104 Pu-240 1 × 101 1 × 10-3 1 × 100 1 × 103 Pu-241 (a) 4 × 101 6 × 10-2 1 × 102 1 × 105 Pu-242 1 × 101 1 × 10-3 1 × 100 1 × 104 Pu-244 (a) 4 × 10-1 1 × 10-3 1 × 100 1 × 104 Ra-223 (a) 4 × 10-1 7 × 10-3 1 × 102 (b) 1 × 105 (b) Ra-224 (a) 4 × 10-1 2 × 10-2 1 × 101 (b) 1 × 105 (b) Ra-225 (a) 2 × 10-1 4 × 10-3 1 × 102 1 × 105 Ra-226 (a) 2 × 10-1 3 × 10-3 1 × 101 (b) 1 × 104 (b) Ra-228 (a) 6 × 10-1 2 × 10-2 1 × 101 (b) 1 × 105 (b) Rb-81 2 × 100 8 × 10-1 1 × 101 1 × 106 Rb-83 (a) 2 × 100 2 × 100 1 × 102 1 × 106 Rb-84 1 × 100 1 × 100 1 × 101 1 × 106 Rb-86 5 × 10-1 5 × 10-1 1 × 102 1 × 105 Rb-87 Unlimited Unlimited 1 × 104 1 × 107 Rb(nat) Unlimited Unlimited 1 × 104 1 × 107 Re-184 1 × 100 1 × 100 1 × 101 1 × 106 Re-184m 3 × 100 1 × 100 1 × 102 1 × 106 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Pt-188 (a) 1 × 100 Pt-191 Platinum (78) Plutonium (94) Radium (88) Rubidium (37) Rhenium (75) - 216 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 6 × 10-1 1 × 103 1 × 106 Unlimited Unlimited 1 × 106 1 × 109 Re-188 4 × 10-1 4 × 10-1 1 × 102 1 × 105 Re-189 (a) 3 × 100 6 × 10-1 1 × 102 1 × 106 Re(nat) Unlimited Unlimited 1 × 106 1 × 109 Rh-99 2 × 100 2 × 100 1 × 101 1 × 106 Rh-101 4 × 100 3 × 100 1 × 102 1 × 107 Rh-102 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Rh-102m 2 × 100 2 × 100 1 × 102 1 × 106 Rh-103m 4 × 101 4 × 101 1 × 104 1 × 108 Rh-105 1 × 101 8 × 10-1 1 × 102 1 × 107 3 × 10-1 4 × 10-3 1 × 101 (b) 1 × 108 (b) Ru-97 5 × 100 5 × 100 1 × 102 1 × 107 Ru-103 (a) 2 × 100 2 × 100 1 × 102 1 × 106 Ru-105 1 × 100 6 × 10-1 1 × 101 1 × 106 Ru-106 (a) 2 × 10-1 2 × 10-1 1 × 102 (b) 1 × 105 (b) 4 × 101 3 × 100 1 × 105 1 × 108 Sb-122 4 × 10-1 4 × 10-1 1 × 102 1 × 104 Sb-124 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Sb-125 2 × 100 1 × 100 1 × 102 1 × 106 Sb-126 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Sc-44 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Sc-46 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Sc-47 1 × 101 7 × 10-1 1 × 102 1 × 106 Sc-48 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Re-186 2 × 100 Re-187 Rhodium (45) Radon (86) Rn-222 (a) Ruthenium (44) Sulphur (16) S-35 Antimony (51) Scandium (21) - 217 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 3 × 100 1 × 102 1 × 106 4 × 101 2 × 100 1 × 104 1 × 107 Si-31 6 × 10-1 6 × 10-1 1 × 103 1 × 106 Si-32 4 × 101 5 × 10-1 1 × 103 1 × 106 Sm-145 1 × 101 1 × 101 1 × 102 1 × 107 Sm-147 Unlimited Unlimited 1 × 101 1 × 104 Sm-151 4 × 101 1 × 101 1 × 104 1 × 108 Sm-153 9 × 100 6 × 10-1 1 × 102 1 × 106 Sn-113 (a) 4 × 100 2 × 100 1 × 103 1 × 107 Sn-117m 7 × 100 4 × 10-1 1 × 102 1 × 106 Sn-119m 4 × 101 3 × 101 1 × 103 1 × 107 Sn-121m (a) 4 × 101 9 × 10-1 1 × 103 1 × 107 Sn-123 8 × 10-1 6 × 10-1 1 × 103 1 × 106 Sn-125 4 × 10-1 4 × 10-1 1 × 102 1 × 105 Sn-126 (a) 6 × 10-1 4 × 10-1 1 × 101 1 × 105 Sr-82 (a) 2 × 10-1 2 × 10-1 1 × 101 1 × 105 Sr-85 2 × 100 2 × 100 1 × 102 1 × 106 Sr-85m 5 × 100 5 × 100 1 × 102 1 × 107 Sr-87m 3 × 100 3 × 100 1 × 102 1 × 106 Sr-89 6 × 10-1 6 × 10-1 1 × 103 1 × 106 Sr-90 (a) 3 × 10-1 3 × 10-1 1 × 102 (b) 1 × 104 (b) Sr-91 (a) 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Sr-92 (a) 1 × 100 3 × 10-1 1 × 101 1 × 106 4 × 101 4 × 101 1 × 106 1 × 109 Ta-178(long-lived) 1 × 100 8 × 10-1 1 × 101 1 × 106 Ta-179 3 × 101 3 × 101 1 × 103 1 × 107 Radionuclide (atomic number) A1 A2 (TBq) (TBq) Se-75 3 × 100 Se-79 Selenium (34) Silicon (14) Samarium (62) Tin (50) Strontium (38) Tritium (1) T(H-3) Tantalum (73) - 218 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 5 × 10-1 1 × 101 1 × 104 4 × 101 4 × 101 1 × 104 1 × 107 Tb-158 1 × 100 1 × 100 1 × 101 1 × 106 Tb-160 1 × 100 6 × 10-1 1 × 101 1 × 106 Tc-95m (a) 2 × 100 2 × 100 1 × 101 1 × 106 Tc-96 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Tc-96m (a) 4 × 10-1 4 × 10-1 1 × 103 1 × 107 Tc-97 Unlimited Unlimited 1 × 103 1 × 108 Tc-97m 4 × 101 1 × 100 1 × 103 1 × 107 Tc-98 8 × 10-1 7 × 10-1 1 × 101 1 × 106 Tc-99 4 × 101 9 × 10-1 1 × 104 1 × 107 Tc-99m 1 × 101 4 × 100 1 × 102 1 × 107 Te-121 2 × 100 2 × 100 1 × 101 1 × 106 Te-121m 5 × 100 3 × 100 1 × 102 1 × 106 Te-123m 8 × 100 1 × 100 1 × 102 1 × 107 Te-125m 2 × 101 9 × 10-1 1 × 103 1 × 107 Te-127 2 × 101 7 × 10-1 1 × 103 1 × 106 Te-127m (a) 2 × 101 5 × 10-1 1 × 103 1 × 107 Te-129 7 × 10-1 6 × 10-1 1 × 102 1 × 106 Te-129m (a) 8 × 10-1 4 × 10-1 1 × 103 1 × 106 Te-131m (a) 7 × 10-1 5 × 10-1 1 × 101 1 × 106 Te-132 (a) 5 × 10-1 4 × 10-1 1 × 102 1 × 107 Th-227 1 × 101 5 × 10-3 1 × 101 1 × 104 Th-228 (a) 5 × 10-1 1 × 10-3 1 × 100 (b) 1 × 104 (b) Th-229 5 × 100 5 × 10-4 1 × 100 (b) 1 × 103 (b) Th-230 1 × 101 1 × 10-3 1 × 100 1 × 104 Th-231 4 × 101 2 × 10-2 1 × 103 1 × 107 Th-232 Unlimited Unlimited 1 × 101 1 × 104 Th-234 (a) 3 × 10-1 3 × 10-1 1 × 103 (b) 1 × 105 (b) Radionuclide (atomic number) A1 A2 (TBq) (TBq) 9 × 10-1 Tb-157 Ta-182 Terbium (65) Technetium (43) Tellurium (52) Thorium (90) - 219 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) Unlimited 1 × 100 (b) 1 × 103 (b) 5 × 10-1 4 × 10-1 1 × 101 1 × 105 Tl-200 9 × 10-1 9 × 10-1 1 × 101 1 × 106 Tl-201 1 × 101 4 × 100 1 × 102 1 × 106 Tl-202 2 × 100 2 × 100 1 × 102 1 × 106 Tl-204 1 × 101 7 × 10-1 1 × 104 1 × 104 Tm-167 7 × 100 8 × 10-1 1 × 102 1 × 106 Tm-170 3 × 100 6 × 10-1 1 × 103 1 × 106 Tm-171 4 × 101 4 × 101 1 × 104 1 × 108 U-230 (fast lung absorption) (a)(d) 4 × 101 1 × 10-1 1 × 101 (b) 1 × 105 (b) U-230 (medium lung absorption) (a)(e) 4 × 101 4 × 10-3 1 × 101 1 × 104 U-230 (slow lung absorption) (a)(f) 3 × 101 3 × 10-3 1 × 101 1 × 104 U-232 (fast lung absorption) (d) 4 × 101 1 × 10-2 1 × 100 (b) 1 × 103 (b) U-232 (medium lung absorption) (e) 4 × 101 7 × 10-3 1 × 101 1 × 104 U-232 (slow lung absorption) (f) 1 × 101 1 × 10-3 1 × 101 1 × 104 U-233 (fast lung absorption) (d) 4 × 101 9 × 10-2 1 × 101 1 × 104 U-233 (medium lung absorption) (e) 4 × 101 2 × 10-2 1 × 102 1 × 105 U-233 (slow lung absorption) (f) 4 × 101 6 × 10-3 1 × 101 1 × 105 U-234 (fast lung absorption) (d) 4 × 101 9 × 10-2 1 × 101 1 × 104 U-234 (medium lung absorption) (e) 4 × 101 2 × 10-2 1 × 102 1 × 105 U-234 (slow lung absorption) (f) 4 × 101 6 × 10-3 1 × 101 1 × 105 Unlimited Unlimited 1 × 101 (b) 1 × 104 (b) U-236 (fast lung absorption) (d) Unlimited Unlimited 1 × 101 1 × 104 U-236 (medium lung absorption) (e) 4 × 101 2 × 10-2 1 × 102 1 × 105 U-236 (slow lung absorption) (f) 4 × 101 6 × 10-3 1 × 101 1 × 104 U-238 (all lung absorption types) (d)(e)(f) Unlimited Unlimited 1 × 101 (b) 1 × 104 (b) U (nat) Unlimited Unlimited 1 × 100 (b) 1 × 103 (b) U (enriched to 20% or less) (g) Unlimited Unlimited 1 × 100 1 × 103 U (dep) Unlimited Unlimited 1 × 100 1 × 103 Radionuclide (atomic number) Th(nat) A1 A2 (TBq) (TBq) Unlimited Titanium (22) Ti-44 (a) Thallium (81) Thulium (69) Uranium (92) U-235 (all (a)(d)(e)(f) lung absorption types) - 220 - Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) 4 × 10-1 1 × 101 1 × 105 4 × 101 4 × 101 1 × 104 1 × 107 W-178 (a) 9 × 100 5 × 100 1 × 101 1 × 106 W-181 3 × 101 3 × 101 1 × 103 1 × 107 W-185 4 × 101 8 × 10-1 1 × 104 1 × 107 W-187 2 × 100 6 × 10-1 1 × 102 1 × 106 W-188 (a) 4 × 10-1 3 × 10-1 1 × 102 1 × 105 Xe-122 (a) 4 × 10-1 4 × 10-1 1 × 102 1 × 109 Xe-123 2 × 100 7 × 10-1 1 × 102 1 × 109 Xe-127 4 × 100 2 × 100 1 × 103 1 × 105 Xe-131m 4 × 101 4 × 101 1 × 104 1 × 104 Xe-133 2 × 101 1 × 101 1 × 103 1 × 104 Xe-135 3 × 100 2 × 100 1 × 103 1 × 1010 Y-87 (a) 1 × 100 1 × 100 1 × 101 1 × 106 Y-88 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Y-90 3 × 10-1 3 × 10-1 1 × 103 1 × 105 Y-91 6 × 10-1 6 × 10-1 1 × 103 1 × 106 Y-91m 2 × 100 2 × 100 1 × 102 1 × 106 Y-92 2 × 10-1 2 × 10-1 1 × 102 1 × 105 Y-93 3 × 10-1 3 × 10-1 1 × 102 1 × 105 Yb-169 4 × 100 1 × 100 1 × 102 1 × 107 Yb-175 3 × 101 9 × 10-1 1 × 103 1 × 107 Zn-65 2 × 100 2 × 100 1 × 101 1 × 106 Zn-69 3 × 100 6 × 10-1 1 × 104 1 × 106 Zn-69m (a) 3 × 100 6 × 10-1 1 × 102 1 × 106 3 × 100 3 × 100 1 × 102 1 × 106 Radionuclide (atomic number) A1 A2 (TBq) (TBq) V-48 4 × 10-1 V-49 Vanadium (23) Tungsten (74) Xenon (54) Yttrium (39) Ytterbium (70) Zinc (30) Zirconium (40) Zr-88 - 221 - Radionuclide (atomic number) Activity concentration limit for exempt material (Bq/g) Activity limit for an exempt consignment (Bq) Unlimited 1 × 103 (b) 1 × 107 (b) 2 × 100 8 × 10-1 1 × 101 1 × 106 4 × 10-1 4 × 10-1 1 × 101 (b) 1 × 105 (b) A1 A2 (TBq) (TBq) Zr-93 Unlimited Zr-95 (a) Zr-97 (a) (a) A1 and/or A2 values for these parent radionuclides include contributions from their progeny with half-lives less than 10 days, as listed in the following: Mg-28 Ar-42 Ca-47 Ti-44 Fe-52 Fe-60 Zn-69m Ge-68 Rb-83 Sr-82 Sr-90 Sr-91 Sr-92 Y-87 Zr-95 Zr-97 Mo-99 Tc-95m Tc-96m Ru-103 Ru-106 Pd-103 Ag-108m Ag-110m Cd-115 In-114m Sn-113 Sn-121m Sn-126 Te-118 Te-127m Te-129m Te-131m Te-132 I-135 Xe-122 Cs-137 Ba-131 Ba-140 Ce-144 Pm-148m Gd-146 Dy-166 Hf-172 W-178 W-188 Re-189 Os-194 Al-28 K-42 Sc-47 Sc-44 Mn-52m Co-60m Zn-69 Ga-68 Kr-83m Rb-82 Y-90 Y-91m Y-92 Sr-87m Nb-95m Nb-97m, Nb-97 Tc-99m Tc-95 Tc-96 Rh-103m Rh-106 Rh-103m Ag-108 Ag-110 In-115m In-114 In-113m Sn-121 Sb-126m Sb-118 Te-127 Te-129 Te-131 I-132 Xe-135m I-122 Ba-137m Cs-131 La-140 Pr-144m, Pr-144 Pm-148 Eu-146 Ho-166 Lu-172 Ta-178 Re-188 Os-189m Ir-194 - 222 - (b) Ir-189 Pt-188 Hg-194 Hg-195m Pb-210 Pb-212 Bi-210m Bi-212 At-211 Rn-222 Ra-223 Ra-224 Ra-225 Ra-226 Ra-228 Ac-225 Ac-227 Th-228 Th-234 Pa-230 U-230 U-235 Pu-241 Pu-244 Am-242m Am-243 Os-189m Ir-188 Au-194 Hg-195 Bi-210 Bi-212, Tl-208, Po-212 Tl-206 Tl-208, Po-212 Po-211 Po-218, Pb-214, At-218, Bi-214, Po-214 Rn-219, Po-215, Pb-211, Bi-211, Po-211, Tl-207 Rn-220, Po-216, Pb-212, Bi-212, Tl-208, Po-212 Ac-225, Fr-221, At-217, Bi-213, Tl-209, Po-213, Pb-209 Rn-222, Po-218, Pb-214, At-218, Bi-214, Po-214 Ac-228 Fr-221, At-217, Bi-213, Tl-209, Po-213, Pb-209 Fr-223 Ra-224, Rn-220, Po-216, Pb-212, Bi-212, Tl-208, Po-212 Pa-234m, Pa-234 Ac-226, Th-226, Fr-222, Ra-222, Rn-218, Po-214 Th-226, Ra-222, Rn-218, Po-214 Th-231 U-237 U-240, Np-240m Am-242, Np-238 Np-239 Cm-247 Bk-249 Cf-253 Pu-243 Am-245 Cm-249 Parent nuclides and their progeny included in secular equilibrium are listed in the following: Sr-90 Zr-93 Zr-97 Ru-106 Ag-108m Cs-137 Ce-144 Ba-140 Bi-212 Pb-210 Pb-212 Rn-222 Ra-223 Ra-224 Ra-226 Ra-228 Th-228 Th-229 Th-nat Th-234 U-230 U-232 U-235 U-238 U-nat Np-237 Am-242m Am-243 Y-90 Nb-93m Nb-97 Rh-106 Ag-108 Ba-137m Pr-144 La-140 Tl-208 (0.36), Po-212 (0.64) Bi-210, Po-210 Bi-212, Tl-208 (0.36), Po-212 (0.64) Po-218, Pb-214, Bi-214, Po-214 Rn-219, Po-215, Pb-211, Bi-211, Tl-207 Rn-220, Po-216, Pb-212, Bi-212, Tl-208 (0.36), Po-212 (0.64) Rn-222, Po-218, Pb-214, Bi-214, Po-214, Pb-210, Bi-210, Po-210 Ac-228 Ra-224, Rn-220, Po-216, Pb212, Bi-212, Tl208 (0.36), Po-212 (0.64) Ra-225, Ac-225, Fr-221, At-217, Bi-213, Po-213, Pb-209 Ra-228, Ac-228, Th-228, Ra-224, Rn-220, Po-216, Pb-212, Bi-212, l208 (0.36), Po-212 (0.64) Pa-234m Th-226, Ra-222, Rn-218, Po-214 Th-228, Ra-224, Rn-220, Po-216, Pb-212, Bi-212, Tl-208 (0.36), Po-212 (0.64) Th-231 Th-234, Pa-234m Th-234, Pa-234m, U-234, Th-230, Ra-226, Rn-222, Po-218, Pb-214, Bi-214, Po-214, Pb-210, Bi-210, Po-210 Pa-233 Am-242 Np-239 - 223 - 2.2.7.2.2.2 (c) The quantity may be determined from a measurement of the rate of decay or a measurement of the radiation level at a prescribed distance from the source. (d) These values apply only to compounds of uranium that take the chemical form of UF6, UO2F2 and UO2(NO3)2 in both normal and accident conditions of carriage. (e) These values apply only to compounds of uranium that take the chemical form of UO3, UF4, UCl4 and hexavalent compounds in both normal and accident conditions of carriage. (f) These values apply to all compounds of uranium other than those specified in (d) and (e) above. (g) These values apply to unirradiated uranium only. For individual radionuclides: (a) Which are not listed in Table 2.2.7.2.2.1 the determination of the basic radionuclide values referred to in 2.2.7.2.2.1 shall require multilateral approval. For these radionuclides, activity concentration limits for exempt material and activity limits for exempt consignments shall be calculated in accordance with the principles established in the International Basic Safety Standards for Protection against Ionizing Radiation and for the Safety of Radiation Sources, Safety Series No.115, IAEA, Vienna (1996). It is permissible to use an A2 value calculated using a dose coefficient for the appropriate lung absorption type as recommended by the International Commission on Radiological Protection, if the chemical forms of each radionuclide under both normal and accident conditions of carriage are taken into consideration. Alternatively, the radionuclide values in Table 2.2.7.2.2.2 may be used without obtaining competent authority approval; (b) In instruments or articles in which the radioactive material is enclosed or is included as a component part of the instrument or other manufactured article and which meet 2.2.7.2.4.1.3 (c), alternative basic radionuclide values to those in Table 2.2.7.2.2.1 for the activity limit for an exempt consignment are permitted and shall require multilateral approval. Such alternative activity limits for an exempt consignment shall be calculated in accordance with the principles set out in the International Basic Safety Standards for Protection against Ionizing Radiation and for the Safety of Radiation Sources, Safety Series No.115, IAEA, Vienna (1996). Table 2.2.7.2.2.2: Basic radionuclide values for unknown radionuclides or mixtures A1 (TBq) A2 (TBq) Activity concentration limit for exempt material (Bq/g) Only beta or gamma emitting nuclides are known to be present 0.1 0.02 1  101 1  104 Alpha emitting nuclides but no neutron emitters are known to be present 0.2 9  10-5 1  10-1 1  103 Neutron emitting nuclides are known to be present or no relevant data are available 0.001 9  10-5 1  10-1 1  103 Radioactive contents 2.2.7.2.2.3 Activity limit for exempt consignments (Bq) In the calculations of A1 and A2 for a radionuclide not in Table 2.2.7.2.2.1, a single radioactive decay chain in which the radionuclides are present in their naturally occurring proportions, and in which no daughter nuclide has a half-life either longer than 10 days or longer than that of the parent nuclide, shall be considered as a single radionuclide; and the activity to be taken into account and the A1 or A2 value to be applied shall be those corresponding to the parent nuclide of that chain. In the case of radioactive decay chains in which any daughter nuclide has a half-life either longer than 10 days or greater than that of the parent nuclide, the parent and such daughter nuclides shall be considered as mixtures of different nuclides. - 224 - 2.2.7.2.2.4 For mixtures of radionuclides, the basic radionuclide values referred to in 2.2.7.2.2.1 may be determined as follows: m = 1 f(i) i X(i) where, f(i) is the fraction of activity or activity concentration of radionuclide i in the mixture; X(i) is the appropriate value of A1 or A2, or the activity concentration limit for exempt material or the activity limit for an exempt consignment as appropriate for the radionuclide i; and Xm is the derived value of A1 or A2, or the activity concentration limit for exempt material or the activity limit for an exempt consignment in the case of a mixture. 2.2.7.2.2.5 When the identity of each radionuclide is known but the individual activities of some of the radionuclides are not known, the radionuclides may be grouped and the lowest radionuclide value, as appropriate, for the radionuclides in each group may be used in applying the formulas in 2.2.7.2.2.4 and 2.2.7.2.4.4. Groups may be based on the total alpha activity and the total beta/gamma activity when these are known, using the lowest radionuclide values for the alpha emitters or beta/gamma emitters, respectively. 2.2.7.2.2.6 For individual radionuclides or for mixtures of radionuclides for which relevant data are not available, the values shown in Table 2.2.7.2.2.2 shall be used. 2.2.7.2.3 Determination of other material characteristics 2.2.7.2.3.1 Low specific activity (LSA) material 2.2.7.2.3.1.1 (Reserved) 2.2.7.2.3.1.2 LSA material shall be in one of three groups: (a) LSA-I (i) uranium and thorium ores and concentrates of such ores, and other ores containing naturally occurring radionuclides; (ii) natural uranium, depleted uranium, natural thorium or their compounds or mixtures, that are unirradiated and in solid or liquid form; (iii) radioactive material for which the A2 value is unlimited. Fissile material may be included only if excepted under 2.2.7.2.3.5; (iv) (b) (c) other radioactive material in which the activity is distributed throughout and the estimated average specific activity does not exceed 30 times the values for activity concentration specified in 2.2.7.2.2.1 to 2.2.7.2.2.6. Fissile material may be included only if excepted under 2.2.7.2.3.5; LSA-II (i) water with tritium concentration up to 0.8 TBq/l; (ii) other material in which the activity is distributed throughout and the estimated average specific activity does not exceed 10-4 A2/g for solids and gases, and 10-5 A2/g for liquids; LSA-III - Solids (e.g. consolidated wastes, activated materials), excluding powders, that meet the requirements of 2.2.7.2.3.1.3, in which: - 225 - (i) the radioactive material is distributed throughout a solid or a collection of solid objects, or is essentially uniformly distributed in a solid compact binding agent (such as concrete, bitumen and ceramic); (ii) the radioactive material is relatively insoluble, or it is intrinsically contained in a relatively insoluble matrix, so that, even under loss of packaging, the loss of radioactive material per package by leaching when placed in water for seven days would not exceed 0.1 A2; and (iii) the estimated average specific activity of the solid, excluding any shielding material, does not exceed 2  10-3 A2/g. 2.2.7.2.3.1.3 LSA-III material shall be a solid of such a nature that if the entire contents of a package were subjected to the test specified in 2.2.7.2.3.1.4 the activity in the water would not exceed 0.1 A2. 2.2.7.2.3.1.4 LSA-III material shall be tested as follows: A solid material sample representing the entire contents of the package shall be immersed for 7 days in water at ambient temperature. The volume of water to be used in the test shall be sufficient to ensure that at the end of the 7 day test period the free volume of the unabsorbed and unreacted water remaining shall be at least 10% of the volume of the solid test sample itself. The water shall have an initial pH of 6-8 and a maximum conductivity of 1 mS/m at 20 °C. The total activity of the free volume of water shall be measured following the 7 day immersion of the test sample. 2.2.7.2.3.1.5 Demonstration of compliance with the performance standards in 2.2.7.2.3.1.4 shall be in accordance with 6.4.12.1 and 6.4.12.2. 2.2.7.2.3.2 Surface contaminated object (SCO) SCO is classified in one of two groups: (a) (b) SCO-I: A solid object on which: (i) the non-fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 0.4 Bq/cm2 for all other alpha emitters; and (ii) the fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 4  104 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 4  103 Bq/cm2 for all other alpha emitters; and (iii) the non-fixed contamination plus the fixed contamination on the inaccessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 4  104 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 4  103 Bq/cm2 for all other alpha emitters; SCO-II: A solid object on which either the fixed or non-fixed contamination on the surface exceeds the applicable limits specified for SCO-I in (a) above and on which: (i) the non-fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 400 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 40 Bq/cm2 for all other alpha emitters; and (ii) the fixed contamination on the accessible surface, averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 8  105 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 8  104 Bq/cm2 for all other alpha emitters; and - 226 - (iii) the non-fixed contamination plus the fixed contamination on the inaccessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 8  105 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 8  104 Bq/cm2 for all other alpha emitters. 2.2.7.2.3.3 Special form radioactive material 2.2.7.2.3.3.1 Special form radioactive material shall have at least one dimension not less than 5 mm. When a sealed capsule constitutes part of the special form radioactive material, the capsule shall be so manufactured that it can be opened only by destroying it. The design for special form radioactive material requires unilateral approval. 2.2.7.2.3.3.2 Special form radioactive material shall be of such a nature or shall be so designed that if it is subjected to the tests specified in 2.2.7.2.3.3.4 to 2.2.7.2.3.3.8, it shall meet the following requirements: (a) It would not break or shatter under the impact, percussion and bending tests 2.2.7.2.3.3.5 (a), (b), (c) and 2.2.7.2.3.3.6 (a) as applicable; (b) It would not melt or disperse in the applicable heat test 2.2.7.2.3.3.5 (d) or 2.2.7.2.3.3.6 (b) as applicable; and (c) The activity in the water from the leaching tests specified in 2.2.7.2.3.3.7 and 2.2.7.2.3.3.8 would not exceed 2 kBq; or alternatively for sealed sources, the leakage rate for the volumetric leakage assessment test specified in ISO 9978:1992 "Radiation Protection - Sealed Radioactive Sources - Leakage Test Methods", would not exceed the applicable acceptance threshold acceptable to the competent authority. 2.2.7.2.3.3.3 Demonstration of compliance with the performance standards in 2.2.7.2.3.3.2 shall be in accordance with 6.4.12.1 and 6.4.12.2. 2.2.7.2.3.3.4 Specimens that comprise or simulate special form radioactive material shall be subjected to the impact test, the percussion test, the bending test, and the heat test specified in 2.2.7.2.3.3.5 or alternative tests as authorized in 2.2.7.2.3.3.6. A different specimen may be used for each of the tests. Following each test, a leaching assessment or volumetric leakage test shall be performed on the specimen by a method no less sensitive than the methods given in 2.2.7.2.3.3.7 for indispersible solid material or 2.2.7.2.3.3.8 for encapsulated material. 2.2.7.2.3.3.5 The relevant test methods are: (a) Impact test: The specimen shall drop onto the target from a height of 9 m. The target shall be as defined in 6.4.14; (b) Percussion test: The specimen shall be placed on a sheet of lead which is supported by a smooth solid surface and struck by the flat face of a mild steel bar so as to cause an impact equivalent to that resulting from a free drop of 1.4 kg through 1 m. The lower part of the bar shall be 25 mm in diameter with the edges rounded off to a radius of (3.0  0.3) mm. The lead, of hardness number 3.5 to 4.5 on the Vickers scale and not more than 25 mm thick, shall cover an area greater than that covered by the specimen. A fresh surface of lead shall be used for each impact. The bar shall strike the specimen so as to cause maximum damage; (c) Bending test: The test shall apply only to long, slender sources with both a minimum length of 10 cm and a length to minimum width ratio of not less than 10. The specimen shall be rigidly clamped in a horizontal position so that one half of its length protrudes from the face of the clamp. The orientation of the specimen shall be such that the specimen will suffer maximum damage when its free end is struck by the flat face of a steel bar. The bar shall strike the specimen so as to cause an impact equivalent to that resulting from a free vertical drop of 1.4 kg through 1 m. The lower part of the bar shall be 25 mm in diameter with the edges rounded off to a radius of (3.0  0.3) mm; (d) Heat test: The specimen shall be heated in air to a temperature of 800 °C and held at that temperature for a period of 10 minutes and shall then be allowed to cool. - 227 - 2.2.7.2.3.3.6 Specimens that comprise or simulate radioactive material enclosed in a sealed capsule may be excepted from: (a) (b) 2.2.7.2.3.3.7 2.2.7.2.3.3.8 The tests prescribed in 2.2.7.2.3.3.5 (a) and (b) provided that the specimens are alternatively subjected to the impact test prescribed in ISO 2919:2012: "Radiation Protection - Sealed Radioactive Sources - General requirements and classification": (i) The Class 4 impact test if the mass of the special form radioactive material is equal to or less than 200 g; (ii) The Class 5 impact test if the mass of the special form radioactive material is equal to or more than 200 g but is less than 500 g; The test prescribed in 2.2.7.2.3.3.5 (d) provided they are alternatively subjected to the Class 6 temperature test specified in ISO 2919:2012 "Radiation protection - Sealed radioactive sources - General requirements and classification". For specimens which comprise or simulate indispersible solid material, a leaching assessment shall be performed as follows: (a) The specimen shall be immersed for 7 days in water at ambient temperature. The volume of water to be used in the test shall be sufficient to ensure that at the end of the 7 day test period the free volume of the unabsorbed and unreacted water remaining shall be at least 10% of the volume of the solid test sample itself. The water shall have an initial pH of 6-8 and a maximum conductivity of 1 mS/m at 20 °C; (b) The water with specimen shall then be heated to a temperature of (50  5) °C and maintained at this temperature for 4 hours; (c) The activity of the water shall then be determined; (d) The specimen shall then be kept for at least 7 days in still air at not less than 30 °C and relative humidity not less than 90%; (e) The specimen shall then be immersed in water of the same specification as in (a) above and the water with the specimen heated to (50  5) °C and maintained at this temperature for 4 hours; (f) The activity of the water shall then be determined. For specimens which comprise or simulate radioactive material enclosed in a sealed capsule, either a leaching assessment or a volumetric leakage assessment shall be performed as follows: (a) (b) The leaching assessment shall consist of the following steps: (i) the specimen shall be immersed in water at ambient temperature. The water shall have an initial pH of 6-8 with a maximum conductivity of 1 mS/m at 20 °C; (ii) the water and specimen shall be heated to a temperature of (50  5) °C and maintained at this temperature for 4 hours; (iii) the activity of the water shall then be determined; (iv) the specimen shall then be kept for at least 7 days in still air at not less than 30 °C and relative humidity of not less than 90%; (v) the process in (i), (ii) and (iii) shall be repeated; The alternative volumetric leakage assessment shall comprise any of the tests prescribed in ISO 9978:1992 "Radiation Protection - Sealed radioactive sources - Leakage test methods", provided that they are acceptable to the competent authority. - 228 - 2.2.7.2.3.4 Low dispersible radioactive material 2.2.7.2.3.4.1 The design for low dispersible radioactive material shall require multilateral approval. Low dispersible radioactive material shall be such that the total amount of this radioactive material in a package, taking into account the provisions of 6.4.8.14, shall meet the following requirements: 2.2.7.2.3.4.2 (a) The radiation level at 3 m from the unshielded radioactive material does not exceed 10 mSv/h; (b) If subjected to the tests specified in 6.4.20.3 and 6.4.20.4, the airborne release in gaseous and particulate forms of up to 100 μm aerodynamic equivalent diameter would not exceed 100 A2. A separate specimen may be used for each test; and (c) If subjected to the test specified in 2.2.7.2.3.1.4 the activity in the water would not exceed 100 A2. In the application of this test, the damaging effects of the tests specified in (b) above shall be taken into account. Low dispersible radioactive material shall be tested as follows: A specimen that comprises or simulates low dispersible radioactive material shall be subjected to the enhanced thermal test specified in 6.4.20.3 and the impact test specified in 6.4.20.4. A different specimen may be used for each of the tests. Following each test, the specimen shall be subjected to the leach test specified in 2.2.7.2.3.1.4. After each test it shall be determined if the applicable requirements of 2.2.7.2.3.4.1 have been met. 2.2.7.2.3.4.3 Demonstration of compliance with the performance standards in 2.2.7.2.3.4.1 and 2.2.7.2.3.4.2 shall be in accordance with 6.4.12.1 and 6.4.12.2. 2.2.7.2.3.5 Fissile material Fissile material and packages containing fissile material shall be classified under the relevant entry as “FISSILE” in accordance with Table 2.2.7.2.1.1 unless excepted by one of the provisions of subparagraphs (a) to (f) below and carried subject to the requirements of 7.5.11 CV33 (4.3). All provisions apply only to material in packages that meets the requirements of 6.4.7.2 unless unpackaged material is specifically allowed in the provision. (a) Uranium enriched in uranium-235 to a maximum of 1% by mass, and with a total plutonium and uranium-233 content not exceeding 1% of the mass of uranium-235, provided that the fissile nuclides are distributed essentially homogeneously throughout the material. In addition, if uranium-235 is present in metallic, oxide or carbide forms, it shall not form a lattice arrangement; (b) Liquid solutions of uranyl nitrate enriched in uranium-235 to a maximum of 2% by mass, with a total plutonium and uranium-233 content not exceeding 0.002% of the mass of uranium, and with a minimum nitrogen to uranium atomic ratio (N/U) of 2; (c) Uranium with a maximum uranium enrichment of 5% by mass uranium-235 provided: (i) There is no more than 3.5 g of uranium-235 per package; (ii) The total plutonium and uranium-233 content does not exceed 1% of the mass of uranium-235 per package; (iii) Carriage of the package is subject to the consignment limit provided in 7.5.11 CV33 (4.3) (c); (d) Fissile nuclides with a total mass not greater than 2.0 g per package provided the package is carried subject to the consignment limit provided in 7.5.11 CV33 (4.3) (d); (e) Fissile nuclides with a total mass not greater than 45 g either packaged or unpackaged subject to limits provided in 7.5.11 CV33 (4.3) (e); (f) A fissile material that meets the requirements of 7.5.11 CV33 (4.3) (b), 2.2.7.2.3.6 and 5.1.5.2.1. - 229 - 2.2.7.2.3.6 2.2.7.2.4 A fissile material excepted from classification as “FISSILE” under 2.2.7.2.3.5 (f) shall be subcritical without the need for accumulation control under the following conditions: (a) The conditions of 6.4.11.1 (a); (b) The conditions consistent with the assessment provisions stated in 6.4.11.12 (b) and 6.4.11.13 (b) for packages. Classification of packages or unpacked material The quantity of radioactive material in a package shall not exceed the relevant limits for the package type as specified below. 2.2.7.2.4.1 Classification as excepted package 2.2.7.2.4.1.1 A package may be classified as an excepted package if it meets one of the following 2.2.7.2.4.1.2 conditions: (a) It is an empty package having contained radioactive material; (b) It contains instruments or articles not exceeding the activity limits specified in columns (2) and (3) of Table 2.2.7.2.4.1.2; (c) It contains articles manufactured of natural uranium, depleted uranium or natural thorium; (d) It contains radioactive material not exceeding the activity limits specified in column (4) of Table 2.2.7.2.4.1.2; or (e) It contains less than 0.1 kg of uranium hexafluoride not exceeding the activity limits specified in column (4) of Table 2.2.7.2.4.1.2. A package containing radioactive material may be classified as an excepted package provided that the radiation level at any point on its external surface does not exceed 5 μSv/h. Table 2.2.7.2.4.1.2: Activity limits for excepted packages Physical state of contents (1) Solids special form other form Liquids Instruments or articles Item limits a Package limits a (2) (3) 10-2 A1 10-2 A2 A1 A2 10-3 A1 10-3 A2 10-3 A2 10-1 A2 10-4 A2 Gases tritium 2  10-2 A2 2  10-1 A2 -3 special form 10 A1 10-2 A1 -3 other forms 10 A2 10-2 A2 a For mixtures of radionuclides, see 2.2.7.2.2.4 to 2.2.7.2.2.6. 2.2.7.2.4.1.3 Materials Package limits a (4) 2  10-2 A2 10-3 A1 10-3 A2 Radioactive material which is enclosed in or is included as a component part of an instrument or other manufactured article may be classified under UN No. 2911 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - INSTRUMENTS or ARTICLES provided that: (a) The radiation level at 10 cm from any point on the external surface of any unpackaged instrument or article is not greater than 0.1 mSv/h; (b) Each instrument or manufactured article bears the marking “RADIOACTIVE” on its external surface except for the following: (i) radioluminescent time-pieces or devices; (ii) consumer products that have either received regulatory approval in accordance with 1.7.1.4 (e) or do not individually exceed the activity limit for an exempt consignment in - 230 - Table 2.2.7.2.2.1 (column 5), provided such products are transported in a package that bears the marking “RADIOACTIVE” on its internal surface in such a manner that a warning of the presence of radioactive material is visible on opening the package; and (iii) 2.2.7.2.4.1.4 2.2.7.2.4.1.5 other instruments or articles too small to bear the marking “RADIOACTIVE”, provided that they are transported in a package that bears the marking “RADIOACTIVE” on its internal surface in such a manner that a warning of the presence of radioactive material is visible on opening the package; (c) The active material is completely enclosed by non-active components (a device performing the sole function of containing radioactive material shall not be considered to be an instrument or manufactured article); and (d) The limits specified in columns 2 and 3 of Table 2.2.7.2.4.1.2 are met for each individual item and each package, respectively. Radioactive material in forms other than as specified in 2.2.7.2.4.1.3 and with an activity not exceeding the limits specified in column 4 of Table 2.2.7.2.4.1.2, may be classified under UN No. 2910 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL provided that: (a) The package retains its radioactive contents under routine conditions of carriage; and (b) The package bears the marking "RADIOACTIVE" on either: (i) An internal surface in such a manner that a warning of the presence of radioactive material is visible on opening the package; or (ii) The outside of the package, where it is impractical to mark an internal surface. Uranium hexafluoride not exceeding the limits specified in Column 4 of Table 2.2.7.2.4.1.2 may be classified under UN 3507 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE, less than 0.1 kg per package, non-fissile or fissile-excepted provided that: (a) The mass of uranium hexafluoride in the package is less than 0.1 kg; (b) The conditions of 2.2.7.2.4.5.1 and 2.2.7.2.4.1.4 (a) and (b) are met. 2.2.7.2.4.1.6 Articles manufactured of natural uranium, depleted uranium or natural thorium and articles in which the sole radioactive material is unirradiated natural uranium, unirradiated depleted uranium or unirradiated natural thorium may be classified under UN No. 2909 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM, provided that the outer surface of the uranium or thorium is enclosed in an inactive sheath made of metal or some other substantial material. 2.2.7.2.4.1.7 An empty packaging which had previously contained radioactive material may be classified under UN No. 2908 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING, provided that: (a) It is in a well-maintained condition and securely closed; (b) The outer surface of any uranium or thorium in its structure is covered with an inactive sheath made of metal or some other substantial material; (c) The level of internal non-fixed contamination, when averaged over any 300 cm2, does not exceed: (d) (i) 400 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters; and (ii) 40 Bq/cm2 for all other alpha emitters; and Any labels which may have been displayed on it in conformity with 5.2.2.1.11.1 are no longer visible. - 231 - 2.2.7.2.4.2 Classification as Low specific activity (LSA) material Radioactive material may only be classified as LSA material if the definition of LSA in 2.2.7.1.3 and the conditions of 2.2.7.2.3.1, 4.1.9.2 and 7.5.11 CV33 (2) are met. 2.2.7.2.4.3 Classification as Surface contaminated object (SCO) Radioactive material may be classified as SCO if the definition of SCO in 2.2.7.1.3 and the conditions of 2.2.7.2.3.2, 4.1.9.2 and 7.5.11 CV33 (2) are met. 2.2.7.2.4.4 Classification as Type A package Packages containing radioactive material may be classified as Type A packages provided that the following conditions are met: Type A packages shall not contain activities greater than either of the following: (a) For special form radioactive material - A1; (b) For all other radioactive material - A2. For mixtures of radionuclides whose identities and respective activities are known, the following condition shall apply to the radioactive contents of a Type A package: i where B(i) B(i) C(j) + j 1 A1 (i) A 2 (j) is the activity of radionuclide i as special form radioactive material; A1(i) is the A1 value for radionuclide i; C(j) is the activity of radionuclide j as other than special form radioactive material; A2(j) is the A2 value for radionuclide j. 2.2.7.2.4.5 Classification of uranium hexafluoride 2.2.7.2.4.5.1 Uranium hexafluoride shall only be assigned to: 2.2.7.2.4.5.2 (a) UN No. 2977, RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE; (b) UN No. 2978, RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non-fissile or fissile-excepted; or (c) UN No. 3507, URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE less than 0.1 kg per package, non-fissile or fissile-excepted. The contents of a package containing uranium hexafluoride shall comply with the following requirements: (a) For UN Nos. 2977 and 2978, the mass of uranium hexafluoride shall not be different from that allowed for the package design, and for UN No. 3507, the mass of uranium hexafluoride shall be less than 0.1 kg; (b) The mass of uranium hexafluoride shall not be greater than a value that would lead to an ullage smaller than 5% at the maximum temperature of the package as specified for the plant systems where the package shall be used; and (c) The uranium hexafluoride shall be in solid form and the internal pressure shall not be above atmospheric pressure when presented for carriage. - 232 - 2.2.7.2.4.6 Classification as Type B(U), Type B(M) or Type C packages 2.2.7.2.4.6.1 Packages not otherwise classified in 2.2.7.2.4 (2.2.7.2.4.1 to 2.2.7.2.4.5) shall be classified in accordance with the competent authority certificate of approval for the package issued by the country of origin of design. 2.2.7.2.4.6.2 The contents of a Type B(U), Type B(M) or Type C package shall be as specified in the certificate of approval. 2.2.7.2.5 Special arrangements Radioactive material shall be classified as transported under special arrangement when it is intended to be carried in accordance with 1.7.4. - 233 - 2.2.8 Class 8 Corrosive substances 2.2.8.1 Criteria 2.2.8.1.1 The heading of Class 8 covers substances and articles containing substances of this class which by chemical action attack epithelial tissue - of skin or mucous membranes - with which they are in contact, or which in the event of leakage are capable of damaging or destroying other goods, or means of transport. The heading of this class also covers other substances which form a corrosive liquid only in the presence of water, or which produce corrosive vapour or mist in the presence of natural moisture of the air. 2.2.8.1.2 Substances and articles of Class 8 are subdivided as follows: C1-C11 Corrosive substances without subsidiary risk and articles containing such substances: C1-C4 Acid substances: C1 Inorganic, liquid; C2 Inorganic, solid; C3 Organic, liquid; C4 Organic, solid; C5-C8 Basic substances: C5 Inorganic, liquid; C6 Inorganic, solid; C7 Organic, liquid; C8 Organic, solid; C9-C10 Other corrosive substances: C9 Liquid; C10 Solid; C11 Articles; CF Corrosive substances, flammable: CF1 Liquid; CF2 Solid; CS Corrosive substances, self-heating: CS1 Liquid; CS2 Solid; CW Corrosive substances which, in contact with water, emit flammable gases: CW1 Liquid; CW2 Solid; CO Corrosive substances, oxidizing: CO1 Liquid; CO2 Solid; CT Corrosive substances, toxic and articles containing such substances: CT1 Liquid; CT2 Solid; CT3 Articles; CFT Corrosive substances, flammable, liquid, toxic; COT Corrosive substances, oxidizing, toxic. - 234 - Classification and assignment of packing groups 2.2.8.1.3 Substances of Class 8 shall be classified in three packing groups according to the degree of danger they present for carriage, as follows: Packing group I: Packing group II: Packing group III: highly corrosive substances corrosive substances slightly corrosive substances. 2.2.8.1.4 Substances and articles classified in Class 8 are listed in Table A of Chapter 3.2. Allocation of substances to packing groups I, II and III has been made on the basis of experience taking into account such additional factors as inhalation risk (see 2.2.8.1.5) and reactivity with water (including the formation of dangerous decomposition products). 2.2.8.1.5 A substance or preparation meeting the criteria of Class 8 having an inhalation toxicity of dusts and mists (LC50) in the range of packing group I, but toxicity through oral ingestion or dermal contact only in the range of packing group III or less, shall be allocated to Class 8. 2.2.8.1.6 Substances, including mixtures, not mentioned by name in Table A of Chapter 3.2 can be assigned to the relevant entry of sub-section 2.2.8.3, and to the relevant packing group on the basis of the length of time of contact necessary to produce full thickness destruction of human skin in accordance with the criteria of (a) to (c) below. Liquids, and solids which may become liquid during carriage, which are judged not to cause full thickness destruction of human skin shall still be considered for their potential to cause corrosion to certain metal surfaces. In assigning the packing group, account shall be taken of human experience in instances of accidental exposure. In the absence of human experience, the grouping shall be based on data obtained from experiments in accordance with OECD Test Guideline 4047 or 4358. A substance which is determined not to be corrosive in accordance with OECD Test Guideline 4309 or 43110 may be considered not to be corrosive to skin for the purposes of ADR without further testing. (a) Packing group I is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 60 minutes starting after the exposure time of 3 minutes or less; (b) Packing group II is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 3 minutes but not more than 60 minutes; (c) Packing group III is assigned to substances that: - cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 60 minutes but not more than 4 hours; or - are judged not to cause full thickness destruction of intact skin tissue, but which exhibit a corrosion rate on either steel or aluminium surfaces exceeding 6.25 mm a year at a test temperature of 55 °C when tested on both materials. For the purposes of testing steel, type S235JR+CR (1.0037 resp. St 37-2), S275J2G3+CR (1.0144 resp. St 44-3), ISO 3574, Unified Numbering System (UNS) G10200 or SAE 1020, and for testing aluminium, non-clad, types 7075-T6 or AZ5GU-T6 shall be used. An acceptable test is prescribed in the Manual of Tests and Criteria, Part III, Section 37. NOTE: Where an initial test on either steel or aluminium indicates the substance being tested is corrosive the follow up test on the other metal is not required. 7 8 9 10 OECD Guideline for the testing of chemicals No. 404 "Acute Dermal Irritation/Corrosion" 2002. OECD Guideline for the testing of chemicals No. 435 "In Vitro Membrane Barrier Test Method for Skin Corrosion" 2006. OECD Guideline for the testing of chemicals No. 430 "In Vitro Skin Corrosion: Transcutaneous Electrical Resistance Test (TER)" 2004. OECD Guideline for the testing of chemicals No. 431 "In Vitro Skin Corrosion: Human Skin Model Test" 2004. - 235 - Table 2.2.8.1.6: Table summarizing the criteria in 2.2.8.1.6 2.2.8.1.7 Packing Group Exposure Time Observation Period Effect I ≤ 3 min ≤ 60 min Full thickness destruction of intact skin II > 3 min ≤ 1 h ≤ 14 d Full thickness destruction of intact skin III >1h≤4h ≤ 14 d Full thickness destruction of intact skin III - - Corrosion rate on either steel or aluminium surfaces exceeding 6.25 mm a year at a test temperature of 55 ºC when tested on both materials If substances of Class 8, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong, on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. 2.2.8.1.8 On the basis of the criteria set out in paragraph 2.2.8.1.6, it may also be determined whether the nature of a solution or mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the provisions for this class. 2.2.8.1.9 Substances, solutions and mixtures, which - do not meet the criteria of Directives 67/548/EEC 3 or 1999/45/EC 4 as amended and therefore are not classified as corrosive according to these directives, as amended; and - do not exhibit a corrosive effect on steel or aluminium; may be considered as substances not belonging to Class 8. NOTE: UN No. 1910 calcium oxide and UN No. 2812 sodium aluminate, listed in the UN Model Regulations, are not subject to the provisions of ADR. 2.2.8.2 Substances not accepted for carriage 2.2.8.2.1 The chemically unstable substances of Class 8 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end it shall in particular be ensured that receptacles and tanks do not contain any substance liable to promote these reactions. 2.2.8.2.2 The following substances shall not be accepted for carriage: - UN No. 1798 NITROHYDROCHLORIC ACID; - chemically unstable mixtures of spent sulphuric acid; - chemically unstable mixtures of nitrating acid or mixtures of residual sulphuric and nitric acids, not denitrated; - perchloric acid aqueous solution with more than 72% pure acid, by mass, or mixtures of perchloric acid with any liquid other than water. 3 Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L 196 of 16.08.1967). 4 Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 on the approximation of laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations (Official Journal of the European Communities No. L 200 of 30 July 1999). - 236 - 2.2.8.3 List of collective entries Corrosive substances without subsidiary risk and articles containing such substances liquid C1 2584 2584 2693 2837 3264 ALKYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid BISULPHITES, AQUEOUS SOLUTION, N.O.S. BISULPHATES, AQUEOUS SOLUTION CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 1740 2583 2583 3260 HYDROGENDIFLUORIDES, SOLID, N.O.S. ALKYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 2586 2586 2987 3145 3265 ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid CHLOROSILANES, CORROSIVE, N.O.S. ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S 2430 2585 2585 3261 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) ALKYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid or ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. inorganic solid C2 Acid C1-C4 liquid C3 organic solid C4 liquid C5 1719 CAUSTIC ALKALI LIQUID, N.O.S. 2797 BATTERY FLUID, ALKALI 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. solid C6 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. liquid C7 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or 2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. inorganic Basic C5-C8 organic solid C8 liquid C9 Other corrosive substances C9-C10 3259 AMINES, SOLID, CORROSIVE, N.O.S., or 3259 POLYAMINES, SOLID, CORROSIVE, N.O.S. 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 1903 2801 2801 3066 DISINFECTANT, LIQUID, CORROSIVE, N.O.S DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. PAINT (including paint, enamel, stain, shellac, varnish, polish, liquid filler and lacquer base) or 3066 PAINT RELATED MATERIAL (including paint thinning or reducing compound) 1760 CORROSIVE LIQUID, N.O.S. 3147 DYE, SOLID, CORROSIVE, N.O.S. or 3147 DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 3244 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. solida Articles (cont'd on next page) C10 C11 1759 CORROSIVE SOLID, N.O.S. 2794 2795 2800 3028 1774 2028 3477 3477 BATTERIES, WET, FILLED WITH ACID, electric storage BATTERIES, WET, FILLED WITH ALKALI, electric storage BATTERIES, WET, NON-SPILLABLE, electric storage BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE SOLID, electric storage FIRE EXTINGUISHER CHARGES, corrosive liquid BOMBS, SMOKE, NON-EXPLOSIVE with corrosive liquid, without initiating device FUEL CELL CARTRIDGES containing corrosive substances, or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT, containing corrosive substances, or 3477 FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing corrosive substances a Mixtures of solids which are not subject to the provisions of ADR and of corrosive liquids may be carried under UN No. 3244 without being subject to the classification criteria of Class 8, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, container or transport unit is closed. Each packaging shall correspond to a design type which has passed the leakproofness test for Packing group II level. - 237 - Corrosive substances with subsidiary risk(s) and articles containing such substances (cont'd) 3470 PAINT, CORROSIVE, FLAMMABLE (including paint, enamel, stain, shellac, varnish, polish, liquid filler and lacquer base) or 3470 PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE (including paint thinning or reducing compound) 2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or 2734 POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 2986 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. 2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. liquid CF1 solid CF2 2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. liquid CS1 3301 CORROSIVE LIQUID, SELF-HEATING, N.O.S. solid CS2 3095 CORROSIVE SOLID, SELF-HEATING, N.O.S. liquid b CW1 3094 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. solid CW2 3096 CORROSIVE SOLID, WATER-REACTIVE, N.O.S. liquid CO1 3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. solid CO2 3084 CORROSIVE SOLID, OXIDIZING, N.O.S. liquid c CT1 3471 2922 HYDROGENDIFLUORIDES SOLUTION, N.O.S. CORROSIVE LIQUID, TOXIC, N.O.S. solid e CT2 2923 CORROSIVE SOLID, TOXIC, N.O.S. articles CT3 3506 MERCURY CONTAINED IN MANUFACTURED ARTICLES Flammable, liquid, toxic d CFT No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to table of precedence of hazard in 2.1.3.10. Oxidizing, toxic d, e COT No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to table of precedence of hazard in 2.1.3.10. Flammable b CF Self-heating CS Water-reactive CW Oxidizing CO c Toxic d CT b Chlorosilanes which, in contact with water or moist air, emit flammable gases, are substances of Class 4.3. c Chloroformates having predominantly toxic properties are substances of Class 6.1. d Corrosive substances which are highly toxic by inhalation, as defined in 2.2.61.1.4 to 2.2.61.1.9 are substances of Class 6.1. e UN No. 2505 AMMONIUM FLUORIDE, UN No. 1812 POTASSIUM FLUORIDE, SOLID, UN No. 1690 SODIUM FLUORIDE, SOLID, UN No. 2674 SODIUM FLUOROSILICATE, UN No. 2856 FLUOROSILICATES, N.O.S., UN No. 3415 SODIUM FLUORIDE SOLUTION and UN No. 3422 POTASSIUM FLUORIDE SOLUTION are substances of Class 6.1. - 238 - 2.2.9 Class 9 Miscellaneous dangerous substances and articles 2.2.9.1 Criteria 2.2.9.1.1 The heading of Class 9 covers substances and articles which, during carriage, present a danger not covered by the heading of other classes. 2.2.9.1.2 The substances and articles of Class 9 are subdivided as follows: M1 Substances which, on inhalation as fine dust, may endanger health; M2 Substances and apparatus which, in the event of fire, may form dioxins; M3 Substances evolving flammable vapour; M4 Lithium batteries; M5 Life-saving appliances; M6-M8 Environmentally hazardous substances: M6 M7 M8 M9-M10 Pollutant to the aquatic environment, liquid; Pollutant to the aquatic environment, solid; Genetically modified microorganisms and organisms; Elevated temperature substances: M9 Liquid; M10 Solid; M11 Other substances presenting a danger during carriage, but not meeting the definitions of another class. Definitions and classification 2.2.9.1.3 Substances and articles classified in Class 9 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of that Table or of sub-section 2.2.9.3 shall be done in accordance with 2.2.9.1.4 to 2.2.9.1.14 below. Substances which, on inhalation as fine dust, may endanger health 2.2.9.1.4 Substances which, on inhalation as fine dust, may endanger health include asbestos and mixtures containing asbestos. Substances and apparatus which, in the event of fire, may form dioxins 2.2.9.1.5 Substances and apparatus which, in the event of fire, may form dioxins include polychlorinated biphenyls (PCBs) and terphenyls (PCTs) and polyhalogenated biphenyls and terphenyls and mixtures containing these substances, as well as apparatus such as transformers, condensers and apparatus containing those substances or mixtures. NOTE: Mixtures with a PCB or PCT content of not more than 50 mg/kg are not subject to the provisions of ADR. Substances evolving flammable vapour 2.2.9.1.6 Substances evolving flammable vapour include polymers containing flammable liquids with a flashpoint not exceeding 55 °C. - 239 - Lithium batteries 2.2.9.1.7 Cells and batteries, cells and batteries contained in equipment, or cells and batteries packed with equipment, containing lithium in any form shall be assigned to UN Nos. 3090, 3091, 3480 or 3481 as appropriate. They may be carried under these entries if they meet the following provisions: (a) Each cell or battery is of the type proved to meet the requirements of each test of the Manual of Tests and Criteria, Part III, sub-section 38.3; NOTE: Batteries shall be of a type proved to meet the testing requirements of the Manual of Tests and Criteria, part III, sub-section 38.3, irrespective of whether the cells of which they are composed are of a tested type. (b) Each cell and battery incorporates a safety venting device or is designed to preclude a violent rupture under normal conditions of carriage; (c) Each cell and battery is equipped with an effective means of preventing external short circuits; (d) Each battery containing cells or series of cells connected in parallel is equipped with effective means as necessary to prevent dangerous reverse current flow (e.g., diodes, fuses, etc.); (e) Cells and batteries shall be manufactured under a quality management programme that includes: (i) A description of the organizational structure and responsibilities of personnel with regard to design and product quality; (ii) The relevant inspection and test, quality control, quality assurance, and process operation instructions that will be used; (iii) Process controls that should include relevant activities to prevent and detect internal short circuit failure during manufacture of cells; (iv) Quality records, such as inspection reports, test data, calibration data and certificates. Test data shall be kept and made available to the competent authority upon request; (v) Management reviews to ensure the effective operation of the quality management programme; (vi) A process for control of documents and their revision; (vii) A means for control of cells or batteries that are not conforming to the type tested as mentioned in (a) above; (viii) Training programmes and qualification procedures for relevant personnel; and (ix) Procedures to ensure that there is no damage to the final product. NOTE: In house quality management programmes may be accepted. Third party certification is not required, but the procedures listed in (i) to (ix) above shall be properly recorded and traceable. A copy of the quality management programme shall be made available to the competent authority upon request. - 240 - Lithium batteries are not subject to the provisions of ADR if they meet the requirements of special provision 188 of Chapter 3.3. NOTE: The entry UN 3171 Battery-powered vehicle or UN 3171 Battery-powered equipment only applies to vehicles powered by wet batteries, sodium batteries, lithium metal batteries or lithium ion batteries and equipment powered by wet batteries or sodium batteries transported with these batteries installed. For the purpose of this UN number, vehicles are self-propelled apparatus designed to carry one or more persons or goods. Examples of such vehicles are electrically-powered cars, motorcycles, scooters, three- and four-wheeled vehicles or motorcycles, e-bikes, wheel-chairs, lawn tractors, boats and aircraft. Examples of equipment are lawnmowers, cleaning machines or model boats and model aircraft. Equipment powered by lithium metal batteries or lithium ion batteries shall be consigned under the entries UN 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT or UN 3091 LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT or UN 3481 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT or UN 3481 LITHIUM ION BATTERIES PACKED WITH EQUIPMENT, as appropriate. Hybrid electric vehicles powered by both an internal combustion engine and wet batteries, sodium batteries, lithium metal batteries or lithium ion batteries, transported with the battery(ies) installed shall be classified under the entries UN 3166 vehicle, flammable gas powered or UN 3166 vehicle, flammable liquid powered, as appropriate. Vehicles which contain a fuel cell shall be classified under the entries UN 3166 vehicle, fuel cell, flammable gas powered or UN 3166 vehicle, fuel cell, flammable liquid powered, as appropriate. Life-saving appliances 2.2.9.1.8 Life-saving appliances include life-saving appliances and motor vehicle components which meet the descriptions of special provisions 235 or 296 of Chapter 3.3. Environmentally hazardous substances 2.2.9.1.9 (Deleted) Pollutants to the aquatic environment 2.2.9.1.10 Environmentally hazardous substances (aquatic environment) 2.2.9.1.10.1 General definitions 2.2.9.1.10.1.1 Environmentally hazardous substances include, inter alia, liquid or solid substances pollutant to the aquatic environment and solutions and mixtures of such substances (such as preparations and wastes). For the purposes of 2.2.9.1.10, "substance" means chemical elements and their compounds in the natural state or obtained by any production process, including any additive necessary to preserve the stability of the product and any impurities deriving from the process used, but excluding any solvent which may be separated without affecting the stability of the substance or changing its composition. 2.2.9.1.10.1.2 The aquatic environment may be considered in terms of the aquatic organisms that live in the water, and the aquatic ecosystem of which they are part11. The basis, therefore, of the identification of hazard is the aquatic toxicity of the substance or mixture, although this may be modified by further information on the degradation and bioaccumulation behaviour. 2.2.9.1.10.1.3 While the following classification procedure is intended to apply to all substances and mixtures, it is recognised that in some cases, e.g. metals or poorly soluble inorganic compounds, special guidance will be necessary12. 11 This does not address aquatic pollutants for which there may be a need to consider effects beyond the aquatic environment such as the impacts on human health etc. 12 This can be found in Annex 10 of the GHS. - 241 - 2.2.9.1.10.1.4 The following definitions apply for acronyms or terms used in this section: - BCF: Bioconcentration Factor; BOD: Biochemical Oxygen Demand; COD: Chemical Oxygen Demand; GLP: Good Laboratory Practices; ECx: the concentration associated with x% response; EC50: the effective concentration of substance that causes 50% of the maximum response; ErC50: EC50 in terms of reduction of growth; Kow: octanol/water partition coefficient; LC50 (50% lethal concentration): the concentration of a substance in water which causes the death of 50% (one half) in a group of test animals; L(E)C50: LC50 or EC50; NOEC (No Observed Effect Concentration): the test concentration immediately below the lowest tested concentration with statistically significant adverse effect. The NOEC has no statistically significant adverse effect compared to the control; OECD Test Guidelines: Test guidelines published by the Organization for Economic Cooperation and Development (OECD). 2.2.9.1.10.2 Definitions and data requirements 2.2.9.1.10.2.1 The basic elements for classification of environmentally hazardous substances (aquatic environment) are: (a) (b) (c) (d) Acute aquatic toxicity; Chronic aquatic toxicity; Potential for or actual bioaccumulation; and Degradation (biotic or abiotic) for organic chemicals. 2.2.9.1.10.2.2 While data from internationally harmonised test methods are preferred, in practice, data from national methods may also be used where they are considered as equivalent. In general, it has been agreed that freshwater and marine species toxicity data can be considered as equivalent data and are preferably to be derived using OECD Test Guidelines or equivalent according to the principles of Good Laboratory Practices (GLP). Where such data are not available, classification shall be based on the best available data. 2.2.9.1.10.2.3 Acute aquatic toxicity means the intrinsic property of a substance to be injurious to an organism in a short-term aquatic exposure to that substance. Acute (short-term) hazard, for classification purposes, means the hazard of a chemical caused by its acute toxicity to an organism during short-term aquatic exposure to that chemical. Acute aquatic toxicity shall normally be determined using a fish 96 hour LC50 (OECD Test Guideline 203 or equivalent), a crustacea species 48 hour EC50 (OECD Test Guideline 202 or equivalent) and/or an algal species 72 or 96 hour EC50 (OECD Test Guideline 201 or equivalent). These species are considered as surrogate for all aquatic organisms and data on other species such as Lemna may also be considered if the test methodology is suitable. 2.2.9.1.10.2.4 Chronic aquatic toxicity means the intrinsic property of a substance to cause adverse effects to aquatic organisms during aquatic exposures which are determined in relation to the life-cycle of the organism. Long-term hazard, for classification purposes, means the hazard of a chemical caused by its chronic toxicity following long-term exposure in the aquatic environment. Chronic toxicity data are less available than acute data and the range of testing procedures less standardised. Data generated according to the OECD Test Guidelines 210 (Fish Early Life Stage) or 211 (Daphnia Reproduction) and 201 (Algal Growth Inhibition) may be accepted. Other validated and internationally accepted tests may also be used. The NOECs or other equivalent ECx shall be used. 2.2.9.1.10.2.5 Bioaccumulation means net result of uptake, transformation and elimination of a substance in an organism due to all routes of exposure (i.e. air, water, sediment/soil and food). - 242 - The potential for bioaccumulation shall normally be determined by using the octanol/water partition coefficient, usually reported as a log Kow determined according to OECD Test Guideline 107 or 117. While this represents a potential to bioaccumulate, an experimentally determined Bioconcentration Factor (BCF) provides a better measure and shall be used in preference when available. A BCF shall be determined according to OECD Test Guideline 305. 2.2.9.1.10.2.6 Degradation means the decomposition of organic molecules to smaller molecules and eventually to carbon dioxide, water and salts. Environmental degradation may be biotic or abiotic (e.g. hydrolysis) and the criteria used reflect this fact. Ready biodegradation is most easily defined using the biodegradability tests (A-F) of OECD Test Guideline 301. A pass level in these tests may be considered as indicative of rapid degradation in most environments. These are freshwater tests and thus the use of the results from OECD Test Guideline 306, which is more suitable for marine environments, has also been included. Where such data are not available, a BOD(5 days)/COD ratio  0.5 is considered as indicative of rapid degradation. Abiotic degradation such as hydrolysis, primary degradation, both abiotic and biotic, degradation in non-aquatic media and proven rapid degradation in the environment may all be considered in defining rapid degradability13. Substances are considered rapidly degradable in the environment if the following criteria are met: (a) In 28-day ready biodegradation studies, the following levels of degradation are achieved: (i) Tests based on dissolved organic carbon: 70%; (ii) Tests based on oxygen depletion or carbon dioxide generation: 60% of theoretical maxima; These levels of biodegradation shall be achieved within 10 days of the start of degradation which point is taken as the time when 10% of the substance has been degraded ", unless the substance is identified as a complex, multi-component substance with structurally similar constituents. In this case, and where there is sufficient justification, the 10-day window condition may be waived and the pass level applied at 28 days14; or (b) In those cases where only BOD and COD data are available, when the ratio of BOD5/COD is  0.5; or (c) If other convincing scientific evidence is available to demonstrate that the substance or mixture can be degraded (biotically and/or abiotically) in the aquatic environment to a level above 70% within a 28 day period. 2.2.9.1.10.3 Substance classification categories and criteria 2.2.9.1.10.3.1 Substances shall be classified as "environmentally hazardous substances (aquatic environment)", if they satisfy the criteria for Acute 1, Chronic 1 or Chronic 2, according to Table 2.2.9.1.10.3.1. These criteria describe in detail the classification categories. They are diagrammatically summarized in Table 2.2.9.1.10.3.2. 13 14 Special guidance on data interpretation is provided in Chapter 4.1 and Annex 9 of the GHS. See Chapter 4.1 and Annex 9, paragraph A9.4.2.2.3 of the GHS. - 243 - Table 2.2.9.1.10.3.1: Categories for substances hazardous to the aquatic environment (see Note 1) (a) Acute (short-term) aquatic hazard Category Acute 1: (see Note 2) 96 hr LC50 (for fish)  1 mg/l and/or 48 hr EC50 (for crustacea)  1 mg/l and/or 72 or 96hr ErC50 (for algae or other aquatic plants)  1 mg/l (see Note 3) (b) Long-term aquatic hazard (see also Figure 2.2.9.1.10.3.1) (i) Non-rapidly degradable substances (see Note 4) for which there are adequate chronic toxicity data available Category Chronic 1: (see Note 2) Chronic NOEC or ECx (for fish)  0.1 mg/l and/or Chronic NOEC or ECx (for crustacea)  0.1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants)  0.1 mg/l Category Chronic 2: Chronic NOEC or ECx (for fish)  1 mg/l and/or  1 mg/l and/or Chronic NOEC or ECx (for crustacea)  1 mg/l Rapidly degradable substances for which there are adequate chronic toxicity data available Chronic NOEC or ECx (for algae or other aquatic plants) (ii) Category Chronic 1: (see Note 2) Chronic NOEC or ECx (for fish)  0.01 mg/l and/or Chronic NOEC or ECx (for crustacea)  0.01 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants)  0.01 mg/l Category Chronic 2: Chronic NOEC or ECx (for fish) (iii)  0.1 mg/l and/or Chronic NOEC or ECx (for crustacea)  0.1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants)  0.1 mg/l Substances for which adequate chronic toxicity data are not available Category Chronic 1: (see Note 2) 96 hr LC50 (for fish)  1 mg/l and/or 48 hr EC50 (for crustacea)  1 mg/l and/or 72 or 96hr ErC50 (for algae or other aquatic plants)  1 mg/l (see Note 3) and the substance is not rapidly degradable and/or the experimentally determined BCF is  500 (or, if absent the log Kow  4) (see Notes 4 and 5). Category Chronic 2: 96 hr LC50 (for fish) >1 but  10 mg/l and/or 48 hr EC50 (for crustacea) >1 but  10 mg/l and/or 72 or 96hr ErC50 (for algae or other aquatic plants) >1 but  10 mg/l (see Note 3) and the substance is not rapidly degradable and/or the experimentally determined BCF is  500 (or, if absent the log Kow  4 (see Notes 4 and 5). NOTE 1: The organisms fish, crustacea and algae are tested as surrogate species covering a range of trophic levels and taxa, and the test methods are highly standardized. Data on other organisms may also be considered, however, provided they represent equivalent species and test endpoints. NOTE 2: When classifying substances as Acute 1 and/or Chronic 1 it is necessary at the same time to indicate an appropriate M factor (see 2.2.9.1.10.4.6.4 ) to apply the summation method. NOTE 3: Where the algal toxicity ErC50 (= EC50 (growth rate)) falls more than 100 times below the next most sensitive species and results in a classification based solely on this effect, consideration shall be given to whether this toxicity is representative of the toxicity to aquatic plants. Where it can be shown that this is not the case, professional judgment shall be used in deciding if classification shall be applied. Classification shall be based on the ErC50. In circumstances where the basis of the EC50 is not specified and no ErC50 is recorded, classification shall be based on the lowest EC50 available. - 244 - NOTE 4: Lack of rapid degradability is based on either a lack of ready biodegradability or other evidence of lack of rapid degradation. When no useful data on degradability are available, either experimentally determined or estimated data, the substance shall be regarded as not rapidly degradable. NOTE 5: Potential to bioaccumulate, based on an experimentally derived BCF  500 or, if absent, a log Kow  4 provided log Kow is an appropriate descriptor for the bioaccumulation potential of the substance. Measured log Kow values take precedence over estimated values and measured BCF values take precedence over log Kow values. Figure 2.2.9.1.10.3.1: Categories for substances long-term hazardous to the aquatic environment Are there adequate chronic toxicity data available for all three trophic levels? See Note 2 to Table 2.2.9.1.10.3.1 Yes Classify according to the criteria given in Table 2.2.9.1.10.3.1 (b) (i) or 2.2.9.1.10.3.1 (b)(ii) depending on information on rapid degradation No Are there adequate chronic toxicity data available for one or two trophic levels? Yes Assess both: (a) according to the criteria given in Table2.2.9.1.10.3.1 (b)(i) or 2.2.9.1.10.3.1(b)(ii) (depending on information on rapid degradation), and (b) (if for the other trophic level(s) adequate acute toxicity data are available) according to the criteria given in Table 2.2.9.1.10.3.1(b) (iii), and classify according to the most stringent outcome No Are there adequate acute toxicity data available? Yes Classify according to the criteria given in Table 2.2.9.1.10.3.1(b) (iii) - 245 - 2.2.9.1.10.3.2 The classification scheme in Table 2.2.9.1.10.3.2 below summarizes the classification criteria for substances. Table 2.2.9.1.10.3.2: Classification scheme for substances hazardous to the aquatic environment Acute hazard (see Note 1) Category: Acute 1 L(E)C50  1.00 Classification categories Long-term hazard (see Note 2) Adequate chronic toxicity data available Adequate chronic toxicity data not Non-rapidly Rapidly available (see Note 1) degradable substances degradable substances (see Note 3) (see Note 3) Category: Chronic 1 Category: Chronic 1 Category: Chronic 1 L(E)C50  1.00 and lack of rapid NOEC or ECx  0.1 NOEC or ECx  0.01 degradability and/or BCF  500 or, if absent log Kow  4 Category: Chronic 2 Category: Chronic 2 Category: Chronic 2 1.00 < L(E)C50  10.0 and lack of rapid degradability and/or 0.1 < NOEC or ECx  1 0.01 < NOEC or ECx  0.1 BCF  500 or, if absent log Kow  4 NOTE 1: Acute toxicity band based on L(E)C50 values in mg/l for fish, crustacea and/or algae or other aquatic plants (or Quantitative Structure Activity Relationships (QSAR) estimation if no experimental data15). NOTE 2: Substances are classified in the various chronic categories unless there are adequate chronic toxicity data available for all three trophic levels above the water solubility or above 1 mg/l. ("Adequate" means that the data sufficiently cover the endpoint of concern. Generally this would mean measured test data, but in order to avoid unnecessary testing it can on a case by case basis also be estimated data, e.g. (Q)SAR, or for obvious cases expert judgment). NOTE 3: Chronic toxicity band based on NOEC or equivalent ECx values in mg/l for fish or crustacea or other recognized measures for chronic toxicity. 2.2.9.1.10.4 Mixtures classification categories and criteria 2.2.9.1.10.4.1 The classification system for mixtures covers the classification categories which are used for substances, meaning categories Acute 1 and Chronic 1 and 2. In order to make use of all available data for purposes of classifying the aquatic environmental hazards of the mixture, the following assumption is made and is applied where appropriate: The "relevant ingredients" of a mixture are those which are present in a concentration equal to or greater than 0.1% (by mass) for ingredients classified as Acute and/or Chronic 1 and equal to or greater than 1% for other ingredients, unless there is a presumption (e.g. in the case of highly toxic ingredients) that an ingredient present at less than 0.1% can still be relevant for classifying the mixture for aquatic environmental hazards. 2.2.9.1.10.4.2 15 The approach for classification of aquatic environmental hazards is tiered, and is dependent upon the type of information available for the mixture itself and for its ingredients. Elements of the tiered approach include: (a) Classification based on tested mixtures; (b) Classification based on bridging principles; (c) The use of "summation of classified ingredients" and/or an "additivity formula". Special guidance is provided in Chapter 4.1, paragraph 4.1.2.13 and Annex 9, Section A9.6 of the GHS. - 246 - Figure 2.2.9.1.10.4.2 below outlines the process to be followed. Figure 2.2.9.1.10.4.2: Tiered approach to classification of mixtures for acute and long-term aquatic environmental hazards Aquatic toxicity test data available on the mixture as a whole No Sufficient data available on similar mixtures to estimate hazards Yes Yes Apply bridging principles (2.2.9.1.10.4.4) CLASSIFY for acute/ long-term hazard (2.2.9.1.10.4.3) CLASSIFY For acute/long-term hazard No Either aquatic toxicity or classification data available for all relevant ingredients Yes Apply Summation Method (2.2.9.1.10.4.6.1 to 2.2.9.1.10.4.6.4) using: (a) Percentage of all ingredients classified as "Chronic" (b) Percentage of ingredients classified as "Acute" (c) Percentage of ingredients with acute toxicity data: apply additivity formulas (2.2.9.1.10.4.5.2) and convert the derived L(E)C50 or EqNOECm to the appropriate "Acute" or "Chronic" Category CLASSIFY For acute/long-term hazard Apply Summation Method and additivity formula (2.2.9.1.10.4.6.1 to 2.2.9.1.10.4.6.4) and apply 2.2.9.1.10.4.6.5 CLASSIFY For acute/long-term hazard No Use available hazard data of known ingredients 2.2.9.1.10.4.3 Classification of mixtures when toxicity data are available for the complete mixture 2.2.9.1.10.4.3.1 When the mixture as a whole has been tested to determine its aquatic toxicity, this information shall be used for classifying the mixture according to the criteria that have been agreed for substances. The classification is normally based on the data for fish, crustacea and algae/plants (see 2.2.9.1.10.2.3 and 2.2.9.1.10.2.4). When adequate acute or chronic data for the mixture as a whole are lacking, "bridging principles" or "summation method" shall be applied (see 2.2.9.1.10.4.4 to 2.2.9.1.10.4.6). 2.2.9.1.10.4.3.2 The long-term hazard classification of mixtures requires additional information on degradability and in certain cases bioaccumulation. There are no degradability and bioaccumulation data for mixtures as a whole. Degradability and bioaccumulation tests for mixtures are not used as they are usually difficult to interpret, and such tests may be meaningful only for single substances. 2.2.9.1.10.4.3.3 Classification for category Acute 1 (a) When there are adequate acute toxicity test data (LC50 or EC50) available for the mixture as a whole showing L(E)C50  1 mg/l: Classify the mixture as Acute 1 in accordance with Table 2.2.9.1.10.3.1 (a); (b) When there are acute toxicity test data (LC50(s) or EC50(s) available for the mixture as a whole showing L(E)C50(s)  1 mg/l, or above the water solubility: No need to classify for acute hazard under ADR. - 247 - 2.2.9.1.10.4.3.4 Classification for categories Chronic 1 and 2 (a) (b) When there are adequate chronic toxicity data (ECx or NOEC) available for the mixture as a whole showing ECx or NOEC of the tested mixture ≤ 1mg/l: (i) classify the mixture as Chronic 1 or 2 in accordance with Table 2.2.9.1.10.3.1 (b) (ii) (rapidly degradable) if the available information allows the conclusion that all relevant ingredients of the mixture are rapidly degradable; (ii) classify the mixture as Chronic 1 or 2 in all other cases in accordance with Table 2.2.9.1.10.3.1 (b) (i) (non-rapidly degradable); When there are adequate chronic toxicity data (ECx or NOEC) available for the mixture as a whole showing ECx(s) or NOEC(s) of the tested mixture > 1mg/l or above the water solubility: No need to classify for long-term hazard under ADR. 2.2.9.1.10.4.4 Classification of mixtures when toxicity data are not available for the complete mixture: bridging principles 2.2.9.1.10.4.4.1 Where the mixture itself has not been tested to determine its aquatic environmental hazard, but there are sufficient data on the individual ingredients and similar tested mixtures to adequately characterise the hazards of the mixture, these data shall be used in accordance with the following agreed bridging rules. This ensures that the classification process uses the available data to the greatest extent possible in characterising the hazards of the mixture without the necessity for additional testing in animals. 2.2.9.1.10.4.4.2 Dilution Where a new mixture is formed by diluting a tested mixture or a substance with a diluent which has an equivalent or lower aquatic hazard classification than the least toxic original ingredient and which is not expected to affect the aquatic hazards of other ingredients, then the resulting mixture shall be classified as equivalent to the original tested mixture or substance. Alternatively, the method explained in 2.2.9.1.10.4.5 may be applied. 2.2.9.1.10.4.4.3 Batching The aquatic hazard classification of a tested production batch of a mixture shall be assumed to be substantially equivalent to that of another untested production batch of the same commercial product when produced by or under the control of the same manufacturer, unless there is reason to believe there is significant variation such that the aquatic hazard classification of the untested batch has changed. If the latter occurs, new classification is necessary. 2.2.9.1.10.4.4.4 Concentration of mixtures which are classified with the most severe classification categories (Chronic 1 and Acute 1) If a tested mixture is classified as Chronic 1 and/or Acute 1, and the ingredients of the mixture which are classified as Chronic 1 and/or Acute 1 are further concentrated, the more concentrated untested mixture shall be classified with the same classification category as the original tested mixture without additional testing. 2.2.9.1.10.4.4.5 Interpolation within one toxicity category For three mixtures (A, B and C) with identical ingredients, where mixtures A and B have been tested and are in the same toxicity category, and where untested mixture C has the same toxicologically active ingredients as mixtures A and B but has concentrations of toxicologically active ingredients intermediate to the concentrations in mixtures A and B, then mixture C is assumed to be in the same category as A and B. - 248 - 2.2.9.1.10.4.4.6 Substantially similar mixtures Given the following: (a) Two mixtures: (i) A + B; (ii) C + B; (b) The concentration of ingredient B is essentially the same in both mixtures; (c) The concentration of ingredient A in mixture (i) equals that of ingredient C in mixture (ii); (d) Data on aquatic hazards for A and C are available and are substantially equivalent, i.e. they are in the same hazard category and are not expected to affect the aquatic toxicity of B. If mixture (i) or (ii) is already classified based on test data, then the other mixture can be assigned the same hazard category. 2.2.9.1.10.4.5 Classification of mixtures when toxicity data are available for all ingredients or only for some ingredients of the mixture 2.2.9.1.10.4.5.1 The classification of a mixture shall be based on summation of the concentrations of its classified ingredients. The percentage of ingredients classified as "Acute" or "Chronic" will feed straight into the summation method. Details of the summation method are described in 2.2.9.1.10.4.6.1 to 2.2.9.1.10.4.6.4. 2.2.9.1.10.4.5.2 Mixtures may be made of a combination of both ingredients that are classified (as Acute 1 and/or Chronic 1, 2) and those for which adequate toxicity test data are available. When adequate toxicity data are available for more than one ingredient in the mixture, the combined toxicity of those ingredients shall be calculated using the following additivity formulas (a) or (b), depending on the nature of the toxicity data: (a) Based on acute aquatic toxicity: C i L(E)C50 m where: = Ci L(E)C50i = n = L(E)C50m = Ci n L( E )C 50 i  concentration of ingredient i (mass percentage); LC50 or EC50 for ingredient i (mg/l); number of ingredients, and i is running from 1 to n; L(E)C50 of the part of the mixture with test data; The calculated toxicity shall be used to assign that portion of the mixture an acute hazard category which is then subsequently used in applying the summation method; (b) Based on chronic aquatic toxicity: C  C   i EqNOECm j Cj Ci  n NOECi n 0.1  NOEC j where: Ci = concentration of ingredient i (mass percentage) covering the rapidly degradable ingredients; Cj = concentration of ingredient j (mass percentage) covering the non rapidly degradable ingredients; NOECi = NOEC (or other recognized measures for chronic toxicity) for ingredient i covering the rapidly degradable ingredients, in mg/l; NOECj = NOEC (or other recognized measures for chronic toxicity) for ingredient j covering the non-rapidly degradable ingredients, in mg/l; n = number of ingredients, and i and j are running from 1 to n; EqNOECm = equivalent NOEC of the part of the mixture with test data; - 249 - The equivalent toxicity thus reflects the fact that non-rapidly degrading substances are classified one hazard category level more "severe" than rapidly degrading substances. The calculated equivalent toxicity shall be used to assign that portion of the mixture a longterm hazard category, in accordance with the criteria for rapidly degradable substances (Table 2.2.9.1.10.3.1 (b) (ii)), which is then subsequently used in applying the summation method. 2.2.9.1.10.4.5.3 When applying the additivity formula for part of the mixture, it is preferable to calculate the toxicity of this part of the mixture using for each ingredient toxicity values that relate to the same taxonomic group (i.e. fish, crustacea or algae) and then to use the highest toxicity (lowest value) obtained (i.e. use the most sensitive of the three groups). However, when toxicity data for each ingredient are not available in the same taxonomic group, the toxicity value of each ingredient shall be selected in the same manner that toxicity values are selected for the classification of substances, i.e. the higher toxicity (from the most sensitive test organism) is used. The calculated acute and chronic toxicity shall then be used to classify this part of the mixture as Acute 1 and/or Chronic 1 or 2 using the same criteria described for substances. 2.2.9.1.10.4.5.4 If a mixture is classified in more than one way, the method yielding the more conservative result shall be used. 2.2.9.1.10.4.6 Summation method 2.2.9.1.10.4.6.1 Classification procedure In general a more severe classification for mixtures overrides a less severe classification, e.g. a classification with Chronic 1 overrides a classification with Chronic 2. As a consequence the classification procedure is already completed if the results of the classification is Chronic 1. A more severe classification than Chronic 1 is not possible; therefore, it is not necessary to pursue the classification procedure further. 2.2.9.1.10.4.6.2 Classification for category Acute 1 2.2.9.1.10.4.6.2.1 First, all ingredients classified as Acute 1 are considered. If the sum of the concentrations (in %) of these ingredients is greater than or equal to 25% the whole mixture shall be classified as Acute 1. If the result of the calculation is a classification of the mixture as Acute 1, the classification process is completed. 2.2.9.1.10.4.6.2.2 The classification of mixtures for acute hazards based on this summation of the concentrations of classified ingredients is summarized in Table 2.2.9.1.10.4.6.2.2 below. Table 2.2.9.1.10.4.6.2.2: Classification of a mixture for acute hazards based on summation of the concentrations of classified ingredients Sum of the concentrations (in %) of ingredients classified as: Acute 1  M a  25% a For explanation of the M factor, see 2.2.9.1.10.4.6.4. Mixture classified as: Acute 1 2.2.9.1.10.4.6.3 Classification for categories Chronic 1 and 2 2.2.9.1.10.4.6.3.1 First, all ingredients classified as Chronic 1 are considered. If the sum of the concentrations (in %) of these ingredients is greater than or equal to 25% the mixture shall be classified as Chronic 1. If the result of the calculation is a classification of the mixture as Chronic 1 the classification procedure is completed. 2.2.9.1.10.4.6.3.2 In cases where the mixture is not classified as Chronic 1, classification of the mixture as Chronic 2 is considered. A mixture shall be classified as Chronic 2 if 10 times the sum of the concentrations (in %) of all ingredients classified as Chronic 1 plus the sum of the concentrations (in %) of all ingredients classified as Chronic 2 is greater than or equal to 25%. If the result of the calculation is classification of the mixture as Chronic 2, the classification process is completed. - 250 - 2.2.9.1.10.4.6.3.3 The classification of mixtures for long-term hazards based on this summation of the concentrations of classified ingredients is summarized in Table 2.2.9.1.10.4.6.3.3 below. Table 2.2.9.1.10.4.6.3.3: Classification of a mixture for long-term hazards based on summation of the concentrations of classified ingredients Sum of the concentrations (in %) of ingredients classified as: Chronic 1  M a a Mixture classified as:  25% Chronic 1 (M  10  Chronic 1) + Chronic 2  25% For explanation of the M factor, see 2.2.9.1.10.4.6.4. 2.2.9.1.10.4.6.4 Chronic 2 Mixtures with highly toxic ingredients Acute 1 or Chronic 1 ingredients with acute toxicities well below 1 mg/l and/or chronic toxicities well below 0.1 mg/l (if non-rapidly degradable) and 0.01 mg/l (if rapidly degradable) may influence the toxicity of the mixture and are given increased weight in applying the summation method. When a mixture contains ingredients classified as acute or Chronic 1, the tiered approach described in 2.2.9.1.10.4.6.2 and 2.2.9.1.10.4.6.3 shall be applied using a weighted sum by multiplying the concentrations of Acute 1 and Chronic 1 ingredients by a factor, instead of merely adding up the percentages. This means that the concentration of "Acute 1" in the left column of Table 2.2.9.1.10.4.6.2.2 and the concentration of "Chronic 1" in the left column of Table 2.2.9.1.10.4.6.3.3 are multiplied by the appropriate multiplying factor. The multiplying factors to be applied to these ingredients are defined using the toxicity value, as summarised in Table 2.2.9.1.10.4.6.4 below. Therefore, in order to classify a mixture containing Acute 1 and/or Chronic 1 ingredients, the classifier needs to be informed of the value of the M factor in order to apply the summation method. Alternatively, the additivity formula (see 2.2.9.1.10.4.5.2) may be used when toxicity data are available for all highly toxic ingredients in the mixture and there is convincing evidence that all other ingredients, including those for which specific acute and/or chronic toxicity data are not available, are of low or no toxicity and do not significantly contribute to the environmental hazard of the mixture. Table 2.2.9.1.10.4.6.4: Multiplying factors for highly toxic ingredients of mixtures Acute toxicity M factor L(E)C50 value Chronic toxicity NOEC value M factor a NRD ingredients RD b ingredients 0.1 < L(E)C50 ≤ 1 1 0.01 < NOEC ≤ 0.1 1 − 0.01 < L(E)C50  0.1 10 0.001 < NOEC ≤ 0.01 10 1 0.001 < L(E)C50  0.01 100 0.0001 < NOEC ≤ 0.001 100 10 0.0001 < L(E)C50  0.001 1 000 0.00001 < NOEC ≤ 0.0001 1 000 100 0.00001 < L(E)C50  0.0001 10 000 0.000001 < NOEC ≤ 0.00001 10 000 1 000 (continue in factor 10 intervals) Non-rapidly degradable. b Rapidly degradable. (continue in factor 10 intervals) a 2.2.9.1.10.4.6.5 Classification of mixtures with ingredients without any useable information In the event that no useable information on acute and/or chronic aquatic toxicity is available for one or more relevant ingredients, it is concluded that the mixture cannot be attributed (a) definitive hazard category(ies). In this situation the mixture shall be classified based on the known ingredients only with the additional statement that: "x percent of the mixture consists of ingredient(s) of unknown hazard to the aquatic environment. - 251 - 2.2.9.1.10.5 Substances or mixtures classified as environmentally hazardous substances (aquatic environment) on the basis of Regulation 1272/2008/EC16 If data for classification according to the criteria of 2.2.9.1.10.3 and 2.2.9.1.10.4 are not available, a substance or mixture: (a) Shall be classified as an environmentally hazardous substance (aquatic environment) if it has to be assigned category(ies) Aquatic Acute 1, Aquatic Chronic 1 or Aquatic Chronic 2 according to Regulation 1272/2008/EC16 or, if still relevant according to the said Regulation, risk phrase(s) R50, R50/53 or R51/53 according to the Directives 67/548/EEC3 or 1999/45/EC4; (b) 2.2.9.1.10.6 May be regarded as not being an environmentally hazardous substance (aquatic environment) if it does not have to be assigned such a risk phrase or category according to the said Directives or Regulation. Assignment of substances or mixtures classified as environmentally hazardous substances (aquatic environment) according to the provisions in 2.2.9.1.10.3, 2.2.9.1.10.4 or 2.2.9.1.10.5 Substances or mixtures classified as environmentally hazardous substances (aquatic environment), not otherwise classified under ADR shall be designated: UN No. 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.; or UN No. 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. They shall be assigned to packing group III. Genetically modified microorganisms or organisms 2.2.9.1.11 Genetically modified microorganisms (GMMOs) and genetically modified organisms (GMOs) are microorganisms and organisms in which genetic material has been purposely altered through genetic engineering in a way that does not occur naturally. They are assigned to Class 9 (UN No. 3245) if they do not meet the definition of toxic substances or of infectious substances, but are capable of altering animals, plants or microbiological substances in a way not normally the result of natural reproduction. NOTE 1: GMMOs and GMOs which are infectious are substances of Class 6.2, UN Nos. 2814, 2900 or 3373. NOTE 2: GMMOs or GMOs are not subject to the provisions of ADR when authorized for use by the competent authorities of the countries of origin, transit and destination17. NOTE 3: Live animals shall not be used to carry genetically modified microorganisms classified in Class 9 unless the substance can be carried no other way. Genetically modified live animals shall be carried under terms and conditions of the competent authorities of the countries of origin and destination. 2.2.9.1.12 (Deleted) 3 Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L 196 of 16 August 1967). 4 Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations (Official Journal of the European Communities No. L 200 of 30 July 1999). 16 Regulation 1272/2008/EC of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (Official Journal of the European Union No. L 353 of 30 December 2008). 17 See in particular Part C of Directive 2001/18/EC of the European Parliament and of the Council on the deliberate release into the environment of genetically modified organisms and repealing Council Directive 90/220/EEC (Official Journal of the European Communities, No. L 106, of 17 April 2001, pp. 8-14), which sets out the authorization procedures for the European Community. - 252 - Elevated temperature substances 2.2.9.1.13 Elevated temperature substances include substances which are carried or handed over for carriage in the liquid state at or above 100 °C and, in the case of those with a flash-point, below their flash-point. They also include solids which are carried or handed over for carriage at or above 240 °C. NOTE: Elevated temperature substances may be assigned to Class 9 only if they do not meet the criteria of any other class. Other substances presenting a danger during carriage but not meeting the definitions of another class. 2.2.9.1.14 The following other miscellaneous substances not meeting the definitions of another class are assigned to Class 9: Solid ammonia compounds having a flash-point below 60 °C; Low hazard dithionites; Highly volatile liquids; Substances emitting noxious fumes; Substances containing allergens; Chemical kits and first aid kits; Electric double layer capacitors (with an energy storage capacity greater than 0.3 Wh) NOTE: UN No. 1845 carbon dioxide, solid (dry ice)18, UN No. 2071 ammonium nitrate fertilizers, UN No. 2216 fish meal (fish scrap), stabilized, UN No. 2807 magnetized material, UN No. 3166 engine, internal combustion or 3166 vehicle, flammable gas powered or 3166 vehicle, flammable liquid powered or 3166 engine, fuel cell, flammable gas powered or 3166 engine, fuel cell, flammable liquid powered or 3166 vehicle, fuel cell, flammable gas powered or 3166 vehicle, fuel cell, flammable liquid powered, UN No. 3171 battery-powered vehicle or 3171 battery-powered equipment (wet battery) (see also the NOTE at the end of 2.2.9.1.7), UN No. 3334 aviation regulated liquid, n.o.s., UN No. 3335 aviation regulated solid, n.o.s. and UN No. 3363 dangerous goods in machinery or dangerous goods in apparatus listed in the UN Model Regulations, are not subject to the provisions of ADR. Assignment of the packing groups 2.2.9.1.15 When indicated in column (4) of Table A of Chapter 3.2, substances and articles of Class 9 are assigned to one of the following packing groups according to their degree of danger: Packing group II: substances presenting medium danger; Packing group III: substances presenting low danger. 2.2.9.2 Substances and articles not accepted for carriage The following substances and articles shall not be accepted for carriage: 18 - Lithium batteries which do not meet the relevant conditions of special provisions 188, 230, 310 or 636 of Chapter 3.3; - Uncleaned empty containment vessels for apparatus such as transformers, condensers and hydraulic apparatus containing substances assigned to UN Nos. 2315, 3151, 3152 or 3432. For UN No. 1845 carbon dioxide, solid (dry ice) used as a coolant, see 5.5.3. - 253 - 2.2.9.3 List of entries Substances which, on inhalation as fine dust, may endanger health 2212 ASBESTOS, AMPHIBOLE (amosite, tremolite, actinolite, anthophyllite, crocidolite) M1 2590 ASBESTOS, CHRYSOTILE Substances and apparatus which, in the event of fire, may form dioxins 2315 POLYCHLORINATED BIPHENYLS, LIQUID 3432 POLYCHLORINATED BIPHENYLS, SOLID 3151 POLYHALOGENATED BIPHENYLS, LIQUID or M2 3151 POLYHALOGENATED TERPHENYLS, LIQUID 3152 POLYHALOGENATED BIPHENYLS, SOLID or 3152 POLYHALOGENATED TERPHENYLS, SOLID Substances evolving flammable vapour 3090 LITHIUM METAL BATTERIES (including lithium alloy batteries) 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT (including lithium alloy batteries) or 3091 LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries) M4 3480 LITHIUM ION BATTERIES (including lithium ion polymer batteries) 3481 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT (including lithium ion polymer batteries) or 3481 LITHIUM ION BATTERIES PACKED WITH EQUIPMENT (including lithium ion polymer batteries) Lithium batteries 2990 LIFE-SAVING APPLIANCES, SELF-INFLATING 3072 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment M5 3268 SAFETY DEVICES, electrically initiated Live-saving appliances pollutant to the aquatic environment, liquid Environmentally hazardous substances 2211 POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour M3 3314 PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour M6 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. pollutant to the aquatic environment, solid M7 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. genetically modified microorganisms and organisms 3245 GENETICALLY MODIFIED MICROORGANISMS or M8 3245 GENETICALLY MODIFIED ORGANISMS liquid M9 3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash-point (including molten metal, molten salts, etc.) Elevated temperature substances solid Other substances or articles presenting a danger during carriage, but not meeting the definitions of another class M10 3258 ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 °C No collective entry available. Only substances listed in Table A of Chapter 3.2 are subject to the provisions for Class 9 under this classification code, as follows: 1841 ACETALDEHYDE AMMONIA 1931 ZINC DITHIONITE (ZINC HYDROSULPHITE) 1941 DIBROMODIFLUOROMETHANE 1990 BENZALDEHYDE 2969 CASTOR BEANS, or 2969 CASTOR MEAL, or 2969 CASTOR POMACE, or 2969 CASTOR FLAKE M11 3316 CHEMICAL KIT, or 3316 FIRST AID KIT 3359 FUMIGATED UNIT 3499 CAPACITOR, ELECTRIC DOUBLE LAYER (with an energy storage capacity greater than 0.3Wh) 3508 CAPACITOR, ASYMMETRIC (with an energy storage capacity greater than 0.3Wh) 3509 PACKAGINGS, DISCARDED, EMPTY, UNCLEANED - 254 - CHAPTER 2.3 TEST METHODS 2.3.0 General Unless otherwise provided for in Chapter 2.2 or in this Chapter, the test methods to be used for the classification of dangerous goods are those described in the Manual of Tests and Criteria. 2.3.1 Exudation test for blasting explosives of Type A 2.3.1.1 Blasting explosives of type A (UN No. 0081) shall, if they contain more than 40% liquid nitric ester, in addition to the testing specified in the Manual of Tests and Criteria, satisfy the following exudation test. 2.3.1.2 The apparatus for testing blasting explosive for exudation (figs. 1 to 3) consists of a hollow bronze cylinder. This cylinder, which is closed at one end by a plate of the same metal, has an internal diameter of 15.7 mm and a depth of 40 mm. It is pierced by 20 holes 0.5 mm in diameter (four sets of five holes) on the circumference. A bronze piston, cylindrically fashioned over a length of 48 mm and having a total length of 52 mm, slides into the vertically placed cylinder. The piston, whose diameter is 15.6 mm, is loaded with a mass of 2 220 g so that a pressure of 120 kPa (1.20 bar) is exerted on the base of the cylinder. 2.3.1.3 A small plug of blasting explosive weighing 5 to 8 g, 30 mm long and 15 mm in diameter, is wrapped in very fine gauze and placed in the cylinder; the piston and its loading mass are then placed on it so that the blasting explosive is subjected to a pressure of 120 kPa (1.20 bar). The time taken for the appearance of the first signs of oily droplets (nitroglycerine) at the outer orifices of the cylinder holes is noted. 2.3.1.4 The blasting explosive is considered satisfactory if the time elapsing before the appearance of the liquid exudations is more than five minutes, the test having been carried out at a temperature of 15 °C to 25 °C. - 255 - Test of blasting explosive for exudation 24 4 14 3 88 120º 4 8 56 2 Fig.1: Bell-form charge, mass 2220 g, capable of being suspended from a bronze piston 100 106 Fig.2: Cylindrical bronze piston, dimensions in mm 52 48 120º 9 15,6 5 40 20 15.7 Fig.3: Hollow bronze cylinder, closed at one end; Plan and cut dimensions in mm 15 5 5 55 5 1 1 72º 72º 1 Fig. 1 to 3 (1) 4 series of 5 holes at 0.5  (2) copper (3) iron plate with centre cone at the inferior face (4) 4 openings, approximately 46x56, set at even intervals on the periphery 97 - 256 - 2.3.2 Tests relating to nitrated cellulose mixtures of Class 4.1 2.3.2.1 Nitrocellulose heated for half an hour at 132 °C shall not give off visible yellowish-brown nitrous fumes (nitrous gases). The ignition temperature shall be above 180 °C. See 2.3.2.3 to 2.3.2.8, 2.3.2.9 (a) and 2.3.2.10 below. 2.3.2.2 3 g of plasticized nitrocellulose, heated for one hour at 132 °C, shall not give off visible yellowish-brown nitrous fumes (nitrous gases). The ignition temperature shall be above 170 °C. See 2.3.2.3 to 2.3.2.8, 2.3.2.9 (b) and 2.3.2.10 below. 2.3.2.3 The test procedures set out below are to be applied when differences of opinion arise as to the acceptability of substances for carriage by road. 2.3.2.4 If other methods or test procedures are used to verify the conditions of stability prescribed above in this section, those methods shall lead to the same findings as could be reached by the methods specified below. 2.3.2.5 In carrying out the stability tests by heating described below, the temperature of the oven containing the sample under test shall not deviate by more than 2 °C from the prescribed temperature; the prescribed duration of a 30-minute or 60-minute test shall be observed to within two minutes. The oven shall be such that the required temperature is restored not more than five minutes after insertion of the sample. 2.3.2.6 Before undergoing the tests in 2.3.2.9 and 2.3.2.10, the samples shall be dried for not less than 15 hours at the ambient temperature in a vacuum desiccator containing fused and granulated calcium chloride, the sample substance being spread in a thin layer; for this purpose, substances which are neither in powder form nor fibrous shall be ground, or grated, or cut into small pieces. The pressure in the desiccator shall be brought below 6.5 kPa (0.065 bar). 2.3.2.7 Before being dried as prescribed in 2.3.2.6 above, substances conforming to 2.3.2.2 shall undergo preliminary drying in a well-ventilated oven, with its temperature set at 70 °C, until the loss of mass per quarter-hour is less than 0.3% of the original mass. 2.3.2.8 Weakly nitrated nitrocellulose conforming to 2.3.2.1 shall first undergo preliminary drying as prescribed in 2.3.2.7 above; drying shall then be completed by keeping the nitrocellulose for at least 15 hours over concentrated sulphuric acid in a desiccator. 2.3.2.9 Test of chemical stability under heat (a) Test of the substance listed in paragraph 2.3.2.1 above. (i) In each of two glass test tubes having the following dimensions: length internal diameter thickness of wall 350 mm 16 mm 1.5 mm is placed 1 g of substance dried over calcium chloride (if necessary the drying shall be carried out after reducing the substance to pieces weighing not more than 0.05 g each). Both test tubes, completely covered with loose-fitting closures, are then so placed in an oven that at least four-fifths of their length is visible, and are kept at a constant temperature of 132 °C for 30 minutes. It is observed whether nitrous gases in the form of yellowish-brown fumes clearly visible against a white background are given off during this time; (ii) In the absence of such fumes the substance is deemed to be stable; - 257 - (b) 2.3.2.10 Test of plasticized nitrocellulose (see 2.3.2.2) (i) 3 g of plasticized nitrocellulose are placed in glass test tubes, similar to those referred to in (a), which are then placed in an oven kept at a constant temperature of 132 °C; (ii) The test tubes containing the plasticized nitrocellulose are kept in the oven for one hour. During this time no yellowish-brown nitrous fumes (nitrous gases) shall be visible. Observation and appraisal as in (a). Ignition temperature (see 2.3.2.1 and 2.3.2.2) (a) The ignition temperature is determined by heating 0.2 g of substance enclosed in a glass test tube immersed in a Wood's alloy bath. The test tube is placed in the bath when the latter has reached 100 °C. The temperature of the bath is then progressively increased by 5 °C per minute; (b) The test tubes must have the following dimensions: length internal diameter thickness of wall 125 mm 15 mm 0.5 mm and shall be immersed to a depth of 20 mm; (c) The test shall be repeated three times, the temperature at which ignition of the substance occurs, i.e., slow or rapid combustion, deflagration or detonation, being noted each time; (d) The lowest temperature recorded in the three tests is the ignition temperature. 2.3.3 Tests relating to flammable liquids of Classes 3, 6.1 and 8 2.3.3.1 Determination of flash-point 2.3.3.1.1 The following methods for determining the flash-point of flammable liquids may be used: International standards: ISO 1516 (Determination of flash/no flash – Closed cup equilibrium method) ISO 1523 (Determination of flash point – Closed cup equilibrium method) ISO 2719 (Determination of flash point – Pensky-Martens closed cup method) ISO 13736 (Determination of flash point – Abel closed-cup method) ISO 3679 (Determination of flash point – Rapid equilibrium closed cup method) ISO 3680 (Determination of flash/no flash – Rapid equilibrium closed cup method) National standards: American Society for Testing Materials International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, Pennsylvania, USA 19428-2959: ASTM D3828-07a, Standard Test Methods for Flash Point by Small Scale Closed-Cup Tester ASTM D56-05, Standard Test Method for Flash Point by Tag Closed-Cup Tester ASTM D3278-96(2004)e1, Standard Test Methods for Flash Point of Liquids by Small Scale ClosedCup Apparatus ASTM D93-08, Standard Test Methods for Flash Point by Pensky-Martens Closed-Cup Tester Association française de normalisation, AFNOR, 11, rue de Pressensé, F-93571 La Plaine SaintDenis Cedex: French standard NF M 07 - 019 French standards NF M 07 - 011 / NF T 30 - 050 / NF T 66 - 009 French standard NF M 07 - 036 Deutsches Institut für Normung, Burggrafenstr. 6, D-10787 Berlin: Standard DIN 51755 (flash-points below 65 °C) - 258 - State Committee of the Council of Ministers for Standardization, RUS-113813, GSP, Moscow, M-49 Leninsky Prospect, 9: GOST 12.1.044-84 2.3.3.1.2 To determine the flash-point of paints, gums and similar viscous products containing solvents, only apparatus and test methods suitable for determining the flash-point for viscous liquids shall be used, in accordance with the following standards: (a) (b) (c) (d) International Standard ISO 3679: 1983; International Standard ISO 3680: 1983; International Standard ISO 1523: 1983; International standards EN ISO 13736 and EN ISO 2719, Method B. 2.3.3.1.3 The standards listed in 2.3.3.1.1 shall only be used for flash-point ranges which are specified therein. The possibility of chemical reactions between the substance and the sample holder shall be considered when selecting the standard to be used. The apparatus shall, as far as is consistent with safety, be placed in a draught-free position. For safety, a method utilizing a small sample size, around 2 ml, shall be used for organic peroxides and self-reactive substances (also known as "energetic" substances), or for toxic substances. 2.3.3.1.4 When the flash-point, determined by a non-equilibrium method is found to be 23 ± 2 °C or 60 ± 2 °C, it shall be confirmed for each temperature range by an equilibrium method. 2.3.3.1.5 In the event of a dispute as to the classification of a flammable liquid, the classification proposed by the consignor shall be accepted if a check-test of the flash-point, yields a result not differing by more than 2 °C from the limits (23 °C and 60 °C respectively) stated in 2.2.3.1. If the difference is more than 2 °C, a second check-test shall be carried out, and the lowest figure of the flash-points obtained in either check-test shall be adopted. 2.3.3.2 Determination of initial boiling point The following methods for determining the initial boiling point of flammable liquids may be used: International standards: ISO 3924 (Petroleum products – Determination of boiling range distribution – Gas chromatography method) ISO 4626 (Volatile organic liquids – Determination of boiling range of organic solvents used as raw materials) ISO 3405 (Petroleum products – Determination of distillation characteristics at atmospheric pressure) National standards: American Society for Testing Materials International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, Pennsylvania, USA 19428-2959: ASTM D86-07a, Standard Test Method for Distillation of Petroleum Products at Atmospheric Pressure ASTM D1078-05, Standard Test Method for Distillation Range of Volatile Organic Liquids Further acceptable methods: Method A.2 as described in Part A of the Annex to Commission Regulation (EC) No 440/20081. 1 Commission Regulation (EC) No 440/2008 of 30 May 2008 laying down test methods pursuant to Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (Official Journal of the European Union, No. L 142 of 31.05.2008, p.1-739 and No. L 143 of 03.06.2008, p.55). - 259 - 2.3.3.3 Test for determining peroxide content To determine the peroxide content of a liquid, the procedure is as follows: A quantity p (about 5 g, weighed to the nearest 0.01 g) of the liquid to be titrated is placed in an Erlenmeyer flask; 20 cm3 of acetic anhydride and about 1 g of powdered solid potassium iodide are added; the flask is shaken and, after 10 minutes, heated for 3 minutes to about 60 °C. When it has been left to cool for 5 minutes, 25 cm3 of water are added. After this, it is left standing for half an hour, then the liberated iodine is titrated with a decinormal solution of sodium thiosulphate, no indicator being added; complete discoloration indicates the end of the reaction. If n is the number of cm3 of thiosulphate solution required, the percentage of peroxide (calculated as H2O2) present in the sample is obtained by the formula: 17 n 100p 2.3.4 Test for determining fluidity To determine the fluidity of liquid, viscous or pasty substances and mixtures, the following test method shall be used. 2.3.4.1 Test apparatus Commercial penetrometer conforming to ISO 2137:1985, with a guide rod of 47.5 g ± 0.05 g; sieve disc of duralumin with conical bores and a mass of 102.5 g ± 0.05 g (see Figure 1); penetration vessel with an inside diameter of 72 mm to 80 mm for reception of the sample. 2.3.4.2 Test procedure The sample is poured into the penetration vessel not less than half an hour before the measurement. The vessel is then hermetically closed and left standing until the measurement. The sample in the hermetically closed penetration vessel is heated to 35 °C ± 0.5 °C and is placed on the penetrometer table immediately prior to measurement (not more than two minutes). The point S of the sieve disc is then brought into contact with the surface of the liquid and the rate of penetration is measured. 2.3.4.3 Evaluation of test results A substance is pasty if, after the centre S has been brought into contact with the surface of the sample, the penetration indicated by the dial gauge: (a) after a loading time of 5 s ± 0.1 s, is less than 15.0 mm ± 0.3 mm; or (b) after a loading time of 5 s ± 0.1 s, is greater than 15.0 mm ± 0.3 mm, but the additional penetration after another 55 s ± 0.5 s is less than 5.0 mm ± 0.5 mm. NOTE: In the case of samples having a flow point, it is often impossible to produce a steady level surface in the penetration vessel and, hence, to establish satisfactory initial measuring conditions for the contact of the point S. Furthermore, with some samples, the impact of the sieve disc can cause an elastic deformation of the surface and, in the first few seconds, simulate a deeper penetration. In all these cases, it may be appropriate to make the evaluation in paragraph (b) above. - 260 - Figure 1 – Penetrometer 3.2 0.02 12.7 3 82.6 Adjust mass to 102.5g 0.05g 9 0.5 12.7 7.4 0.02 3.2 10.3 16 052' S Press fit S 69.9 50.8 19.05 40 ° 120 ° Tolerances not specified are ± 0.1 mm. - 261 - 2.3.5 Classification of organometallic substances in Classes 4.2 and 4.3 Depending on their properties as determined in accordance with tests N.1 to N.5 of the Manual of Tests end Criteria, Part III, section 33, organometallic substances may be classified in Class 4.2 or 4.3, as appropriate, in accordance with the flowchart scheme given in Figure 2.3.5. NOTE 1: Depending on their other properties and on the precedence of hazard table (see 2.1.3.10), organometallic substances may have to be classified in other classes as appropriate. NOTE 2: Flammable solutions with organometallic compounds in concentrations which are not liable to spontaneous combustion or, in contact with water, do not emit flammable gases in dangerous quantities, are substances of Class 3. - 262 - Figure 2.3.5: Flowchart scheme for the classification of organometallic substances in Classes 4.2 and 4.3ab Organometallic substance/formulation/solutiona Organometallic substance, solid, pyrophoric UN 3391 Solid No Is the substance pyrophoric? Test N.2 (solid) Test N.3 (liquid) Yes Is the substance water-reactive? Test N.5 Liquid Organometallic substance, liquid, pyrophoric UN 3392 Solid Organometallic substance, solid, pyrophoric, water-reactive UN 3393 Yes No Organometallic substance, liquid, pyrophoric, water-reactive UN 3394 Liquid No Is the substance a flammable solid? Test N.1 Yes Organometallic substance, solid, water-reactive UN 3395 Organometallic substance, solid, water-reactive, flammable UN 3396 No Is the substance self-heating? Test N.4 Yes Yes Is the substance water-reactive? Test N.5 Class 4.3, PG I, II or III. Is the substance a solid? No No Is the substance a self-heating solid? Test N.4 Yes No Does the substance contain a diluent with a flash point  60ºC? Yes Organometallic substance, solid, water reactive, self-heating UN 3397 Organometallic substance, liquid, water-reactive UN 3398 Organometallic substance, liquid, water-reactive, flammable UN 3399 Organometallic substance, solid, self-heating UN 3400 Yes No Substance does not have to be classified in Class 4.2 or in Class 4.3 a If applicable and testing is relevant, taking into account reactivity properties, class 6.1 and 8 properties should be considered according to the precedence of hazard table of 2.1.3.10. b Test methods N.1 to N.5 can be found in the Manual of Tests and Criteria, Part III, Section 33. - 263 - PART 3 Dangerous goods list, special provisions and exemptions related to limited and excepted quantities CHAPTER 3.1 GENERAL 3.1.1 Introduction In addition to the provisions referred to or given in the tables of this Part, the general requirements of each Part, Chapter and/or Section are to be observed. These general requirements are not given in the tables. When a general requirement is contradictory to a special provision, the special provision prevails. 3.1.2 Proper shipping name NOTE: For proper shipping names used for the carriage of samples, see 2.1.4.1. 3.1.2.1 The proper shipping name is that portion of the entry most accurately describing the goods in Table A in Chapter 3.2, which is shown in upper case characters (plus any numbers, Greek letters, "sec", "tert", and the letters "m", "n", "o", "p", which form an integral part of the name). An alternative proper shipping name may be shown in brackets following the main proper shipping name [e.g., ETHANOL (ETHYL ALCOHOL)]. Portions of an entry appearing in lower case need not be considered as part of the proper shipping name. 3.1.2.2 When conjuncti ons such as "and" or "or" are in lower case or when segments of the name are punctuated by commas, the entire name of the entry need not necessarily be shown in the transport document or package markings. This is the case particularly when a combination of several distinct entries are listed under a single UN Number. Examples illustrating the selection of the proper shipping name for such entries are: (a) UN 1057 LIGHTERS or LIGHTER REFILLS - The proper shipping name is the appropriate of the following possible combinations: most LIGHTERS LIGHTER REFILLS; (b) UN 2793 FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to self-heating. The proper shipping name is the most appropriate of the following combinations: FERROUS METAL BORINGS FERROUS METAL SHAVINGS FERROUS METAL TURNINGS FERROUS METAL CUTTINGS. 3.1.2.3 Proper shipping names may be used in the singular or plural as appropriate. In addition, when qualifying words are used as part of the proper shipping name, their sequence on documentation or package markings is optional. For instance, "DIMETHYLAMINE AQUEOUS SOLUTION" may alternatively be shown "AQUEOUS SOLUTION OF DIMETHYLAMINE". Commercial or military names for goods of Class 1 which contain the proper shipping name supplemented by additional descriptive text may be used. 3.1.2.4 Many substances have an entry for both the liquid and solid state (see definitions for liquid and solid in 1.2.1), or for the solid and solution. These are allocated separate UN numbers which are not necessarily adjacent to each other1. 1 Details are provided in the alphabetical index (Table B of Chapter 3.2), e.g.: NITROXYLENES, LIQUID 6.1 1665; NITROXYLENES, SOLID 6.1 3447. - 267 - 3.1.2.5 Unless it is already included in capital letters in the name indicated in Table A in Chapter 3.2, the qualifying word "MOLTEN" shall be added as part of the proper shipping name when a substance, which is a solid in accordance with the definition in 1.2.1, is offered for carriage in the molten state (e.g. ALKYLPHENOL, SOLID, N.O.S., MOLTEN). 3.1.2.6 Except for self-reactive substances and organic peroxides and unless it is already included in capital letters in the name indicated in Column (2) of Table A of Chapter 3.2, the word "STABILIZED" shall be added as part of the proper shipping name of a substance which without stabilization would be forbidden from carriage in accordance with paragraphs 2.2.X.2 due to it being liable to dangerously react under conditions normally encountered in carriage (e.g.: "TOXIC LIQUID, ORGANIC, N.O.S., STABILIZED"). When temperature control is used to stabilize such substances to prevent the development of any dangerous excess pressure, then: (a) For liquids: where the SADT is less than or equal to 50 °C, the provisions of 2.2.41.1.17, the special provision V8 of Chapter 7.2, the special provision S4 of Chapter 8.5 and the requirements of Chapter 9.6 shall apply; for carriage in IBCs and tanks, all the provisions applicable to UN No. 3239 apply (see in particular 4.1.7.2, packing instruction IBC520 et 4.2.1.13); (b) For gases: the conditions of carriage shall be approved by the competent authority. 3.1.2.7 Hydrates may be carried under the proper shipping name for the anhydrous substance. 3.1.2.8 Generic or "not otherwise specified" (N.O.S.) names 3.1.2.8.1 Generic and "not otherwise specified" proper shipping names that are assigned to special provision 274 or 318 in Column (6) of Table A in Chapter 3.2 shall be supplemented with the technical name of the goods unless a national law or international convention prohibits its disclosure if it is a controlled substance. For explosives of Class 1, the dangerous goods description may be supplemented by additional descriptive text to indicate commercial or military names. Technical names shall be entered in brackets immediately following the proper shipping name. An appropriate modifier, such as "contains" or "containing" or other qualifying words such as "mixture", "solution", etc. and the percentage of the technical constituent may also be used. For example: "UN 1993 FLAMMABLE LIQUID, N.O.S. (CONTAINS XYLENE AND BENZENE), 3, II". 3.1.2.8.1.1 The technical name shall be a recognized chemical name or biological name, or other name currently used in scientific and technical handbooks, journals and texts. Trade names shall not be used for this purpose. In the case of pesticides, only ISO common name(s), other name(s) in the World Health Organization (WHO) Recommended Classification of Pesticides by Hazard and Guidelines to Classification, or the name(s) of the active substance(s) may be used. 3.1.2.8.1.2 When a mixture of dangerous goods is described by one of the "N.O.S." or "generic" entries to which special provision 274 has been allocated in Column (6) of Table A in Chapter 3.2, not more than the two constituents which most predominantly contribute to the hazard or hazards of a mixture need to be shown, excluding controlled substances when their disclosure is prohibited by national law or international convention. If a package containing a mixture is labelled with any subsidiary risk label, one of the two technical names shown in parentheses shall be the name of the constituent which compels the use of the subsidiary risk label. NOTE: See 5.4.1.2.2. 3.1.2.8.1.3 Examples illustrating the selection of the proper shipping name supplemented with the technical name of goods for such N.O.S. entries are: UN 2902 UN 3394 PESTICIDE, LIQUID, TOXIC, N.O.S. (drazoxolon); ORGANOMETALLIC SUBSTANCE, LIQUID, REACTIVE (trimethylgallium). - 268 - PYROPHORIC, WATER- 3.1.3 Solutions or mixtures NOTE: Where a substance is specifically mentioned by name in Table A of Chapter 3.2, it shall be identified in carriage by the proper shipping name in Column (2) of Table A of Chapter 3.2. Such substances may contain technical impurities (for example those deriving from the production process) or additives for stability or other purposes that do not affect its classification. However, a substance mentioned by name containing technical impurities or additives for stability or other purposes affecting its classification shall be considered a solution or mixture (see 2.1.3.3). 3.1.3.1 A solution or mixture is not subject to ADR if the characteristics, properties, form or physical state of the solution or mixture are such that it does not meet the criteria, including human experience criteria, for inclusion in any class. 3.1.3.2 A solution or mixture meeting the classification criteria of ADR composed of a single predominant substance mentioned by name in Table A of Chapter 3.2 and one or more substances not subject to ADR or traces of one or more substances mentioned by name in Table A of Chapter 3.2, shall be assigned the UN number and proper shipping name of the predominant substance mentioned by name in Table A of Chapter 3.2 unless: (a) The solution or mixture is mentioned by name in Table A of Chapter 3.2; (b) The name and description of the substance mentioned by name in Table A of Chapter 3.2 specifically indicate that they apply only to the pure substance; (c) The class, classification code, packing group, or physical state of the solution or mixture is different from that of the substance mentioned by name in Table A of Chapter 3.2; or (d) The hazard characteristics and properties of the solution or mixture necessitate emergency response measures that are different from those required for the substance mentioned by name in Table A of Chapter 3.2. Qualifying words such as "SOLUTION" or "MIXTURE", as appropriate, shall be added as part of the proper shipping name, for example, "ACETONE SOLUTION". In addition, the concentration of the mixture or solution may also be indicated after the basic description of the mixture or solution, for example, "ACETONE 75% SOLUTION". 3.1.3.3 A solution or mixture meeting the classification criteria of ADR that is not mentioned by name in Table A of Chapter 3.2 and that is composed of two or more dangerous goods shall be assigned to an entry that has the proper shipping name, description, class, classification code and packing group that most precisely describe the solution or mixture. - 269 - CHAPTER 3.2 DANGEROUS GOODS LIST 3.2.1 Table A: Dangerous Goods List Explanations As a rule, each row of Table A of this Chapter deals with the substance(s) or article(s) covered by a specific UN number. However, when substances or articles belonging to the same UN number have different chemical properties, physical properties and/or carriage conditions, several consecutive rows may be used for that UN number. Each column of Table A is dedicated to a specific subject as indicated in the explanatory notes below. The intersection of columns and rows (cell) contains information concerning the subject treated in that column, for the substance(s) or article(s) of that row: - The first four cells identify the substance(s) or article(s) belonging to that row (additional information in that respect may be given by the special provisions referred to in Column (6); - The following cells give the applicable special provisions, either in the form of complete information or in coded form. The codes cross-refer to detailed information that is to be found in the Part, Chapter, Section and/or Sub-section indicated in the explanatory notes below. An empty cell means either that there is no special provision and that only the general requirements apply, or that the carriage restriction indicated in the explanatory notes is in force. When used in this table, an alphanumeric code starting with the letters "SP" designates a special provision of Chapter 3.3. The applicable general requirements are not referred to in the corresponding cells. The explanatory notes below indicate for every column the Part(s), Chapter(s), Section(s) and/or Sub-section(s) where these are to be found. Explanatory notes for each column: Column (1) "UN No." Contains the UN number: Column (2) - of the dangerous substance or article if the substance or article has been assigned its own specific UN number; or - of the generic or n.o.s. entry to which the dangerous substances or articles not mentioned by name shall be assigned in accordance with the criteria ("decision trees") of Part 2. "Name and description" Contains, in upper case characters, the name of the substance or article, if the substance or article has been assigned its own specific UN number, or of the generic or n.o.s. entry to which it has been assigned in accordance with the criteria ("decision trees") of Part 2. This name shall be used as the proper shipping name or, when applicable, as part of the proper shipping name (see 3.1.2 for further details on the proper shipping name). A descriptive text in lower case characters is added after the proper shipping name to clarify the scope of the entry if the classification and/or carriage conditions of the substance or article may be different under certain conditions. - 271 - Column (3a) "Class" Contains the number of the class, whose heading covers the dangerous substance or article. This class number is assigned in accordance with the procedures and criteria of Part 2. Column (3b) "Classification code" Contains the classification code of the dangerous substance or article. Column (4) - For dangerous substances or articles of Class 1, the code consists of a division number and compatibility group letter, which are assigned in accordance with the procedures and criteria of 2.2.1.1.4; - For dangerous substances or articles of Class 2, the code consists of a number and hazardous property group, which are explained in 2.2.2.1.2 and 2.2.2.1.3; - For dangerous substances or articles of Classes 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 8 and 9, the codes are explained in 2.2.x.1.2 1; - Dangerous substances or articles of Class 7 do not have a classification code. "Packing group" Contains the packing group number(s) (I, II or III) assigned to the dangerous substance. These packing group numbers are assigned on the basis of the procedures and criteria of Part 2. Certain articles and substances are not assigned to packing groups. Column (5) "Labels" Contains the model number of the labels/placards (see 5.2.2.2 and 5.3.1.7) that have to be affixed to packages, containers, tank-containers, portable tanks, MEGCs and vehicles. However, for substances or articles of Class 7, 7X means label model No.7A, 7B or 7C as appropriate according to the category (see 5.1.5.3.4 and 5.2.2.1.11.1) or placard No. 7D (see 5.3.1.1.3 and 5.3.1.7.2). The general provisions on labelling/placarding (e.g. number of labels, their location) are to be found in 5.2.2.1 for packages, and in 5.3.1, for containers, tank-containers, MEGCs, portable tanks and vehicles. NOTE: Special provisions, indicated in Column (6), may change the above labelling provisions. Column (6) "Special provisions" Contains the numeric codes of special provisions that have to be met. These provisions concern a wide array of subjects, mainly connected with the contents of Columns (1) to (5) (e.g. carriage prohibitions, exemptions from requirements, explanations concerning the classification of certain forms of the dangerous goods concerned and additional labelling or marking provisions), and are listed in Chapter 3.3 in numerical order. If Column (6) is empty, no special provisions apply to the contents of Columns (1) to (5) for the dangerous goods concerned. Column (7a) "Limited Quantities" Provides the maximum quantity per inner packaging or article for carrying dangerous goods as limited quantities in accordance with Chapter 3.4. 1 x = the class number of the dangerous substance or article, without dividing point if applicable. - 272 - Column (7b) "Excepted Quantities" Contains an alphanumeric code with the following meaning: Column (8) - "E0" signifies that no exemption from the provisions of ADR exists for the dangerous goods packed in excepted quantities; - All the other alphanumerical codes starting with the letter "E" signify that the provisions of ADR are not applicable if the conditions indicated in Chapter 3.5 are fulfilled. "Packing instructions" Contains the alphanumeric codes of the applicable packing instructions: - Alphanumeric codes starting with the letter "P", which refers to packing instructions for packagings and receptacles (except IBCs and large packagings), or "R", which refers to packing instructions for light gauge metal packagings. These are listed in 4.1.4.1 in numerical order, and specify the packagings and receptacles that are authorized. They also indicate which of the general packing provisions of 4.1.1, 4.1.2 and 4.1.3, and which of the special packing provisions of 4.1.5, 4.1.6, 4.1.7, 4.1.8 and 4.1.9 have to be met. If Column (8) does not contain a code starting with the letters "P" or "R", the dangerous goods concerned may not be carried in packagings; - Alphanumeric codes starting with the letters "IBC" refer to packing instructions for IBCs. These are listed in 4.1.4.2 in numerical order, and specify the IBCs that are authorized. They also indicate which of the general packing provisions of 4.1.1, 4.1.2 and 4.1.3, and which of the special packing provisions of 4.1.5, 4.1.6, 4.1.7, 4.1.8 and 4.1.9 have to be met. If Column (8) does not contain a code starting with the letters "IBC", the dangerous goods concerned may not be carried in IBCs; - Alphanumeric codes starting with the letters "LP" refer to packing instructions for large packagings. These are listed in 4.1.4.3 in numerical order, and specify the large packagings that are authorized. They also indicate which of the general packing provisions of 4.1.1, 4.1.2 and 4.1.3, and which of the special packing provisions of 4.1.5, 4.1.6, 4.1.7, 4.1.8 and 4.1.9 have to be met. If Column (8) does not contain a code starting with the letters "LP", the dangerous goods concerned cannot be carried in large packagings; NOTE: Special packing provisions, indicated in Column (9a), may change the above packing instructions. Column (9a) "Special packing provisions" Contains the alphanumeric codes of the applicable special packing provisions: - Alphanumeric codes starting with the letters "PP" or "RR" refer to special packing provisions for packagings and receptacles (except IBCs and large packagings) that have additionally to be met. These are to be found in 4.1.4.1, at the end of the relevant packing instruction (with the letter "P" or " R") referred to in Column (8). If Column (9a) does not contain a code starting with the letters "PP" or "RR", none of the special packing provisions listed at the end of the relevant packing instruction apply; - Alphanumeric codes starting with the letter "B" or the letters "BB" refer to special packing provisions for IBCs that have additionally to be met. These are to be found in 4.1.4.2, at the end of the relevant packing instruction (with the letters "IBC") referred to in Column (8). If Column (9a) does not contain a code starting with the letter "B" or the letters "BB", none of the special packing provisions listed at the end of the relevant packing instruction apply; - 273 - - Column (9b) Alphanumeric codes starting with the letter "L" refer to special packing provisions for large packagings that have additionally to be met. These are to be found in 4.1.4.3, at the end of the relevant packing instruction (with the letters "LP") referred to in Column (8). If Column (9a) does not contain a code starting with the letter "L", none of the special packing provisions listed at the end of the relevant packing instruction apply. "Mixed packing provisions" Contains the alphanumeric codes starting with the letters "MP" of the applicable mixed packing provisions. These are listed in 4.1.10 in numerical order. If Column (9b) does not contain a code starting with the letters "MP", only the general requirements apply (see 4.1.1.5 and 4.1.1.6). Column (10) "Portable tank and bulk container instructions" Contains an alphanumeric code assigned to a portable tank instruction, in accordance with 4.2.5.2.1 to 4.2.5.2.4 and 4.2.5.2.6. This portable tank instruction corresponds to the least stringent provisions that are acceptable for the carriage of the substance in portable tanks. The codes identifying the other portable tank instructions that are also permitted for the carriage of the substance are to be found in 4.2.5.2.5. If no code is given, carriage in portable tanks is not permitted unless a competent authority approval is granted as detailed in 6.7.1.3. The general requirements for the design, construction, equipment, type approval, testing and marking of portable tanks are to be found in Chapter 6.7. The general requirements for the use (e.g. filling) are to be found in 4.2.1 to 4.2.4. The indication of a "(M)" means that the substance may be carried in UN MEGCs. NOTE: Special provisions, indicated in Column (11), may change the above requirements. May also contain alphanumeric codes starting with the letters "BK" referring to types of bulk containers described in Chapter 6.11 which may be used for the carriage of bulk goods in accordance with 7.3.1.1 (a) and 7.3.2. Column (11) "Portable tank and bulk container special provisions" Contains the alphanumeric codes of the portable tank special provisions that have additionally to be met. These codes, starting with the letters "TP" refer to special provisions for the construction or use of these portable tanks. They are to be found in 4.2.5.3. NOTE: If technically relevant, these special provisions are not only applicable to the portable tanks specified in column (10), but also to the portable tanks that may be used according to the table in 4.2.5.2.5. Column (12) "Tank codes for ADR tanks" Contains an alphanumeric code describing a tank type, in accordance with 4.3.3.1.1 (for gases of Class 2) or 4.3.4.1.1 (for substances of Classes 3 to 9). This tank type corresponds to the least stringent tank provisions that are acceptable for the carriage of the relevant substance in ADR tanks. The codes describing the other permitted tank types are to be found in 4.3.3.1.2 (for gases of Class 2) or 4.3.4.1.2 (for substances of Classes 3 to 9). If no code is given, carriage in ADR tanks is not permitted. If in this column a tank code for solids (S) and for liquids (L) is indicated, this means that this substance may be offered for carriage in tanks in the solid or the liquid (molten) state. In general this provision is applicable to substances having melting points from 20 °C to 180 °C. - 274 - If for a solid, only a tank code for liquids (L) is indicated in this column, this means that this substance is only offered for carriage in tanks in the liquid (molten) state. The general requirements for the construction, equipment, type approval, testing and marking that are not indicated in the tank code are to be found in 6.8.1, 6.8.2, 6.8.3 and 6.8.5. The general requirements for the use (e.g. maximum degree of filling, minimum test pressure) are to be found in 4.3.1 to 4.3.4. The indication of a "(M)" after the tank code means that the substance can also be carried in battery-vehicles or MEGCs. The indication of a (+) after the tank code means that the alternative use of the tanks is permitted only where this is specified in the certificate of type approval. For fibre-reinforced plastic tanks, see 4.4.1 and Chapter 6.9; for vacuum operated waste tanks, see 4.5.1 and Chapter 6.10. NOTE: Special provisions, indicated in Column (13), may change the above requirements. Column (13) "Special provisions for ADR tanks" Contains the alphanumeric codes of the special provisions for ADR tanks that have additionally to be met: - Alphanumeric codes starting with the letters "TU" refer to special provisions for the use of these tanks. These are to be found in 4.3.5; - Alphanumeric codes starting with the letters "TC" refer to special provisions for the construction of these tanks. These are to be found in 6.8.4 (a); - Alphanumeric codes starting with the letters "TE" refer to special provisions concerning the items of equipment of these tanks. These are to be found in 6.8.4 (b); - Alphanumeric codes starting with the letters "TA" refer to special provisions for the type approval of these tanks. These are to be found in 6.8.4 (c); - Alphanumeric codes starting with the letters "TT" refer to special provisions for the testing of these tanks. These are to be found in 6.8.4 (d); - Alphanumeric codes starting with the letters "TM" refer to special provisions for the marking of these tanks. These are to be found in 6.8.4 (e). NOTE: If technically relevant, these special provisions are not only applicable to the tanks specified in column (12), but also to the tanks that may be used according to the hierarchies in 4.3.3.1.2 and 4.3.4.1.2. - 275 - Column (14) "Vehicle for tank carriage" Contains a code designating the vehicle (including the drawing vehicle of trailers or semi-trailers) (see 9.1.1) to be used for the carriage of the substance in tank in accordance with 7.4.2. The requirements concerning the construction and approval of vehicles are to be found in Chapters 9.1, 9.2 and 9.7. Column (15) "Transport category / (Tunnel restriction code)" Contains at the top of the cell a figure indicating the transport category to which the substance or article is assigned for the purposes of exemption related to quantities carried per transport unit (see 1.1.3.6). Contains at the bottom of the cell, between brackets, the tunnel restriction code that refers to the applicable restriction for the passage of vehicles carrying the substance or article through road tunnels. These are to be found in Chapter 8.6. When no tunnel restriction code has been assigned, this is indicated by the mention ‘(─)’. Column (16) "Special provisions for carriage - Packages" Contains the alphanumeric code(s), starting with letter "V", of the applicable special provisions (if any) for carriage in packages. These are listed in 7.2.4. General provisions concerning the carriage in packages are to be found in Chapters 7.1 and 7.2. NOTE: In addition, special provisions indicated in Column (18), concerning loading, unloading and handling, shall be observed. Column (17) "Special provisions for carriage - Bulk" Contains the alphanumeric code(s), starting with letters "VC", as well as the alphanumeric code(s) starting with letters "AP", of the applicable provisions for carriage in bulk. These are listed in 7.3.3. If no code or a reference to a specific paragraph is given, carriage in bulk is not permitted. General and additional provisions concerning carriage in bulk are to be found in Chapters 7.1 and 7.3. NOTE: In addition, special provisions indicated in Column (18), concerning loading, unloading and handling, shall be observed. Column (18) "Special provisions for carriage - Loading and unloading" Contains the alphanumeric code(s), starting with letters "CV", of the applicable special provisions for loading, unloading and handling. These are listed in 7.5.11. If no code is given, only the general provisions apply (see 7.5.1 to 7.5.10). Column (19) "Special provisions for carriage - Operation" Contains the alphanumeric code(s), starting with letter "S", of the applicable special provisions for operation which are listed in Chapter 8.5. These provisions shall be applied in addition to the requirements of Chapters 8.1 to 8.4 but in the event of conflict with the requirements of Chapters 8.1 to 8.4, the special provisions shall take precedence. Column (20) "Hazard identification number" Contains a two or three figure number (preceded in certain cases by the letter "X") for substances and articles of classes 2 to 9, and for substances and articles of Class 1, the classification code (see column (3b)). In the cases described in 5.3.2.1, this number shall appear in the upper half of the orange-coloured marking. The meaning of the hazard identification numbers is explained in 5.3.2.3. - 276 - TABLE A DANGEROUS GOODS LIST - 277 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.1D 1 1.1F 0006 CARTRIDGES FOR WEAPONS with bursting charge 1 0007 CARTRIDGES FOR WEAPONS with bursting charge 2.1.1.3 (4) 5.2.2 (5) 1 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0004 AMMONIUM PICRATE dry or wetted with less than 10% water, by mass 0005 CARTRIDGES FOR WEAPONS with bursting charge Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P112(a) P112(b) P112(c) P130 4.1.4 (9a) PP26 1 0 E0 1.1E 1 0 1 1.2F 1 0009 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0010 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0012 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0014 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK or CARTRIDGE FOR TOOLS, BLANK 1 1.2G 1 E0 P130 LP101 PP67 L1 0 E0 P130 1 0 E0 P130 LP101 PP67 L1 MP23 1.3G 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.4S 1.4 364 5 kg E0 P130 MP23 MP24 1 1.4S 1.4 364 5 kg E0 P130 MP23 MP24 0015 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0015 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge, containing corrosive substances 0016 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0016 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge, containing corrosive substances 0018 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 1 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.2G 1 +8 0 E0 P130 LP101 PP67 L1 MP23 1 1.3G 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.3G 1 +8 0 E0 P130 LP101 PP67 L1 MP23 1 1.2G 1 +6.1 +8 0 E0 P130 LP101 PP67 L1 MP23 0019 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 1 1.3G 1 +6.1 +8 0 E0 P130 LP101 PP67 L1 MP23 0020 AMMUNITION, TOXIC with burster, expelling charge or propelling charge 0021 AMMUNITION, TOXIC with burster, expelling charge or propelling charge 0027 BLACK POWDER (GUNPOWDER), granular or as a meal 0028 BLACK POWDER (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS 0029 DETONATORS, NON-ELECTRIC for blasting 1 1.2K CARRIAGE PROHIBITED 1 1.3K CARRIAGE PROHIBITED 1 1.1D 1 0 E0 P113 PP50 MP20 MP24 1 1.1D 1 0 E0 P113 PP51 MP20 MP24 1 1.1B 1 0 E0 P131 PP68 MP23 0030 DETONATORS, ELECTRIC for blasting 1 1.1B 1 0 E0 P131 MP23 0033 BOMBS with bursting charge 1 1.1F 1 0 E0 P130 MP23 0034 BOMBS with bursting charge 1 1.1D 1 0 E0 P130 LP101 PP67 L1 MP21 0035 BOMBS with bursting charge 1 1.2D 1 0 E0 P130 LP101 PP67 L1 MP21 - 278 - 4.1.10 (9b) MP20 MP23 MP21 MP23 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (B1000C) 7.2.4 (16) V2 V3 7.3.3 (17) 8.5 (19) S1 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 4 (E) 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 1 (B1000C) V2 1 (C5000D) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV28 S1 0006 CARTRIDGES FOR WEAPONS with bursting charge S1 0007 CARTRIDGES FOR WEAPONS with bursting charge S1 0009 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0010 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0012 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0014 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK or CARTRIDGE FOR TOOLS, BLANK S1 S1 S1 S1 S1 S1 S1 S1 CARRIAGE PROHIBITED V2 V3 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 - 279 - 3.1.2 (1) (2) 0004 AMMONIUM PICRATE dry or wetted with less than 10% water, by mass 0005 CARTRIDGES FOR WEAPONS with bursting charge S1 CARRIAGE PROHIBITED 1 (B1000C) 5.3.2.3 (20) Name and description S1 S1 S1 0015 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0015 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge, containing corrosive substances 0016 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0016 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge, containing corrosive substances 0018 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 0019 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 0020 AMMUNITION, TOXIC with burster, expelling charge or propelling charge 0021 AMMUNITION, TOXIC with burster, expelling charge or propelling charge 0027 BLACK POWDER (GUNPOWDER), granular or as a meal 0028 BLACK POWDER (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS 0029 DETONATORS, NON-ELECTRIC for blasting S1 0030 DETONATORS, ELECTRIC for blasting S1 0033 BOMBS with bursting charge S1 0034 BOMBS with bursting charge S1 0035 BOMBS with bursting charge UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.1F 0038 BOMBS, PHOTO-FLASH 1 1.1D 0039 BOMBS, PHOTO-FLASH 1 0042 BOOSTERS without detonator 2.1.1.3 (4) 5.2.2 (5) 1 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0037 BOMBS, PHOTO-FLASH Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P130 4.1.4 (9a) 4.1.10 (9b) MP23 1 0 E0 P130 LP101 PP67 L1 MP21 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.1D 1 0 E0 P132(a) P132(b) 0043 BURSTERS, explosive 1 1.1D 1 0 E0 P133 0044 PRIMERS, CAP TYPE 1 1.4S 1.4 0 E0 P133 0048 CHARGES, DEMOLITION 1 1.1D 1 0 E0 P130 LP101 0049 CARTRIDGES, FLASH 1 1.1G 1 0 E0 P135 MP23 0050 CARTRIDGES, FLASH 1 1.3G 1 0 E0 P135 MP23 0054 CARTRIDGES, SIGNAL 1 1.3G 1 0 E0 P135 MP23 MP24 0055 CASES, CARTRIDGE, EMPTY, WITH PRIMER 1 1.4S 1.4 5 kg E0 P136 MP23 0056 CHARGES, DEPTH 1 1.1D 1 0 E0 P130 LP101 PP67 L1 MP21 0059 CHARGES, SHAPED without detonator 1 1.1D 1 0 E0 P137 PP70 MP21 0060 CHARGES, SUPPLEMENTARY, EXPLOSIVE 1 1.1D 1 0 E0 P132(a) P132(b) 0065 CORD, DETONATING, flexible 1 1.1D 1 0 E0 P139 0066 CORD, IGNITER 1 1.4G 1.4 0 E0 P140 MP23 0070 CUTTERS, CABLE, EXPLOSIVE 1 1.4S 1.4 0 E0 P134 LP102 MP23 0072 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX), WETTED with not less than 15% water, by mass 1 1.1D 1 0 E0 P112(a) 0073 DETONATORS FOR AMMUNITION 1 1.1B 1 0 E0 P133 0074 DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass 0075 DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile, waterinsoluble phlegmatizer, by mass 1 1.1A 1 266 0 E0 P110(b) PP42 MP20 1 1.1D 1 266 0 E0 P115 PP53 PP54 PP57 PP58 MP20 0076 DINITROPHENOL, dry or wetted with less than 15% water, by mass 1 1.1D 1 +6.1 0 E0 P112(a) P112(b) P112(c) PP26 MP20 0077 DINITROPHENOLATES, alkali metals, dry or wetted with less than 15% water, by mass 1 1.3C 1 +6.1 0 E0 P114(a) P114(b) PP26 MP20 364 266 - 280 - MP21 PP69 MP21 MP23 MP24 PP67 L1 MP21 MP21 PP71 PP72 PP45 MP21 MP20 MP23 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (B1000C) 7.2.4 (16) V2 7.3.3 (17) 8.5 (19) S1 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 4 (E) 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 0037 BOMBS, PHOTO-FLASH S1 0038 BOMBS, PHOTO-FLASH S1 0039 BOMBS, PHOTO-FLASH S1 0042 BOOSTERS without detonator S1 0043 BURSTERS, explosive S1 0044 PRIMERS, CAP TYPE S1 0048 CHARGES, DEMOLITION S1 0049 CARTRIDGES, FLASH S1 0050 CARTRIDGES, FLASH S1 0054 CARTRIDGES, SIGNAL S1 0055 CASES, CARTRIDGE, EMPTY, WITH PRIMER S1 0056 CHARGES, DEPTH S1 0059 CHARGES, SHAPED without detonator S1 0060 CHARGES, SUPPLEMENTARY, EXPLOSIVE S1 0065 CORD, DETONATING, flexible S1 0066 CORD, IGNITER S1 0070 CUTTERS, CABLE, EXPLOSIVE S1 0072 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX), WETTED with not less than 15% water, by mass CV1 CV2 CV3 CV1 CV2 CV3 S1 0073 DETONATORS FOR AMMUNITION S1 0074 DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass 0075 DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile, waterinsoluble phlegmatizer, by mass 1 (B1000C) V2 1 (B1000C) V2 0 (B) V2 1 (B1000C) V2 CV1 CV2 CV3 S1 1 (B1000C) V2 V3 S1 0076 DINITROPHENOL, dry or wetted with less than 15% water, by mass 1 (C5000D) V2 V3 CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV28 S1 0077 DINITROPHENOLATES, alkali metals, dry or wetted with less than 15% water, by mass - 281 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.1D 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P112(a) P112(b) P112(c) P112(b) P112(c) 4.1.4 (9a) PP26 1 1.1D 1 0 E0 1 1.1D 1 616 617 0 E0 P116 PP63 PP66 MP20 0082 EXPLOSIVE, BLASTING, TYPE B 1 1.1D 1 617 0 E0 P116 PP61 PP62 MP20 0083 EXPLOSIVE, BLASTING, TYPE C 1 1.1D 1 0 E0 IBC100 P116 B9 267 617 0084 EXPLOSIVE, BLASTING, TYPE D 1 1.1D 1 617 0 E0 P116 MP20 0092 FLARES, SURFACE 1 1.3G 1 0 E0 P135 MP23 0093 FLARES, AERIAL 1 1.3G 1 0 E0 P135 MP23 0094 FLASH POWDER 1 1.1G 1 0 E0 P113 0099 FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells 0101 FUSE, NON-DETONATING 1 1.1D 1 0 E0 P134 LP102 1 1.3G 1 0 E0 P140 PP74 PP75 MP23 0102 CORD (FUSE), DETONATING, metal clad 1 1.2D 1 0 E0 P139 PP71 MP21 0103 FUSE, IGNITER, tubular, metal clad 1 1.4G 1.4 0 E0 P140 0104 CORD (FUSE), DETONATING, MILD EFFECT, metal clad 1 1.4D 1.4 0 E0 P139 PP71 MP21 0105 FUSE, SAFETY 1 1.4S 1.4 0 E0 P140 PP73 MP23 0106 FUZES, DETONATING 1 1.1B 1 0 E0 P141 MP23 0107 FUZES, DETONATING 1 1.2B 1 0 E0 P141 MP23 0110 GRENADES, PRACTICE, hand or rifle 1 1.4S 1.4 0 E0 P141 MP23 0113 GUANYLNITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass 0114 GUANYLNITROSAMINOGUANYLTETRAZENE (TETRAZENE), WETTED with not less than 30% water, or mixture of alcohol and water, by mass 1 1.1A 1 266 0 E0 P110(b) PP42 MP20 1 1.1A 1 266 0 E0 P110(b) PP42 MP20 0118 HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass 0121 IGNITERS 1 1.1D 1 0 E0 1 1.1G 1 0 E0 P112(a) P112(b) P112(c) P142 MP23 1 1.1D 1 0 E0 P101 MP21 1 1.1A 1 0 E0 P110(b) 0124 JET PERFORATING GUNS, CHARGED, oil well, without detonator 0129 LEAD AZIDE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 2.1.1.3 (4) 5.2.2 (5) 1 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0078 DINITRORESORCINOL, dry or wetted with less than 15% water, by mass 0079 HEXANITRODIPHENYLAMINE (DIPICRYLAMINE; HEXYL) 0081 EXPLOSIVE, BLASTING, TYPE A Packaging 266 - 282 - 4.1.10 (9b) MP20 MP20 MP20 PP49 MP20 MP21 MP23 MP20 PP42 MP20 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (B1000C) 7.2.4 (16) V2 V3 7.3.3 (17) 8.5 (19) S1 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 V12 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0082 EXPLOSIVE, BLASTING, TYPE B 1 (B1000C) V2 V3 S1 0083 EXPLOSIVE, BLASTING, TYPE C 1 (B1000C) V2 S1 0084 EXPLOSIVE, BLASTING, TYPE D 1 (C5000D) V2 S1 0092 FLARES, SURFACE 1 (C5000D) V2 S1 0093 FLARES, AERIAL 1 (B1000C) V2 V3 S1 0094 FLASH POWDER 1 (B1000C) V2 S1 1 (C5000D) V2 0099 FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells 0101 FUSE, NON-DETONATING 1 (B1000C) V2 2 (E) V2 2 (E) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 4 (E) 1 (B1000C) V2 1 (B1000C) V2 4 (E) S1 S1 S1 3.1.2 (1) (2) 0078 DINITRORESORCINOL, dry or wetted with less than 15% water, by mass 0079 HEXANITRODIPHENYLAMINE (DIPICRYLAMINE; HEXYL) 0081 EXPLOSIVE, BLASTING, TYPE A S1 0102 CORD (FUSE), DETONATING, metal clad S1 0103 FUSE, IGNITER, tubular, metal clad S1 0104 CORD (FUSE), DETONATING, MILD EFFECT, metal clad S1 0105 FUSE, SAFETY S1 0106 FUZES, DETONATING S1 0107 FUZES, DETONATING S1 0110 GRENADES, PRACTICE, hand or rifle S1 0113 GUANYLNITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass 0114 GUANYLNITROSAMINOGUANYLTETRAZENE (TETRAZENE), WETTED with not less than 30% water, or mixture of alcohol and water, by mass 0 (B) V2 0 (B) V2 CV1 CV2 CV3 S1 1 (B1000C) V2 V3 S1 1 (B1000C) V2 1 (B1000C) V2 0 (B) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 - 283 - 5.3.2.3 (20) S1 S1 S1 0118 HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass 0121 IGNITERS 0124 JET PERFORATING GUNS, CHARGED, oil well, without detonator 0129 LEAD AZIDE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.1A 2.1.1.3 (4) 5.2.2 (5) 1 1 1.4S 1.4 0132 DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES, N.O.S. 0133 MANNITOL HEXANITRATE (NITROMANNITE), WETTED with not less than 40% water, or mixture of alcohol and water, by mass 1 1.3C 1 1 1.1D 0135 MERCURY FULMINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0136 MINES with bursting charge 1 3.3 (6) 266 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0130 LEAD STYPHNATE (LEAD TRINITRORESORCINATE), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0131 LIGHTERS, FUSE Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P110(b) 0 E0 P142 274 0 E0 P114(a) P114(b) 1 266 0 E0 P112(a) 1.1A 1 266 0 E0 P110(b) 1 1.1F 1 0 E0 P130 0137 MINES with bursting charge 1 1.1D 1 0 E0 P130 LP101 PP67 L1 MP21 0138 MINES with bursting charge 1 1.2D 1 0 E0 P130 LP101 PP67 L1 MP21 0143 NITROGLYCERIN, DESENSITIZED with not less than 40% non-volatile water-insoluble phlegmatizer, by mass 0144 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 10% nitroglycerin 1 1.1D 1 +6.1 266 271 0 E0 P115 PP53 PP54 PP57 PP58 MP20 1 1.1D 1 358 0 E0 P115 PP45 PP55 PP56 PP59 PP60 MP20 0146 NITROSTARCH, dry or wetted with less than 20% water, by mass 1 1.1D 1 0 E0 0147 NITRO UREA 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) P112(b) 0150 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN), WETTED with not less than 25% water, by mass, or DESENSITIZED with not less than 15% phlegmatizer, by mass 0151 PENTOLITE, dry or wetted with less than 15% water, by mass 1 1.1D 1 0 E0 P112(a) P112(b) MP20 1 1.1D 1 0 E0 MP20 0153 TRINITROANILINE (PICRAMIDE) 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) P112(b) P112(c) 0154 TRINITROPHENOL (PICRIC ACID), dry or wetted with less than 30% water, by mass 0155 TRINITROCHLORO-BENZENE (PICRYL CHLORIDE) 1 1.1D 1 0 E0 1 1.1D 1 0 E0 0159 POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass 0160 POWDER, SMOKELESS 1 1.3C 1 0 1 1.1C 1 0161 POWDER, SMOKELESS 1 1.3C 0167 PROJECTILES with bursting charge 1 1.1F 266 4.1.4 (9a) PP42 4.1.10 (9b) MP20 MP23 PP26 MP2 MP20 PP42 MP20 MP23 MP20 MP20 MP20 P112(a) P112(b) P112(c) P112(b) P112(c) PP26 E0 P111 PP43 0 E0 P114(b) PP50 PP52 MP20 MP24 1 0 E0 P114(b) PP50 PP52 MP20 MP24 1 0 E0 P130 MP23 266 - 284 - MP20 MP20 MP20 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) 1.1.3.6 (15) 0 (B) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 7.2.4 (16) V2 7.3.3 (17) 7.5.11 (18) CV1 CV2 CV3 8.5 (19) S1 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 4 (E) 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 0130 LEAD STYPHNATE (LEAD TRINITRORESORCINATE), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0131 LIGHTERS, FUSE 1 (C5000D) V2 V3 1 (B1000C) V2 0 (B) V2 CV1 CV2 CV3 S1 1 (B1000C) V2 S1 1 (B1000C) V2 S1 0137 MINES with bursting charge 1 (B1000C) V2 S1 0138 MINES with bursting charge 1 (B1000C) V2 S1 1 (B1000C) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV28 CV1 CV2 CV3 0135 MERCURY FULMINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0136 MINES with bursting charge 0143 NITROGLYCERIN, DESENSITIZED with not less than 40% non-volatile water-insoluble phlegmatizer, by mass 0144 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 10% nitroglycerin 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (C5000D) V2 1 (B1000C) V2 V3 1 (C5000D) V2 V3 1 (B1000C) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 - 285 - S1 S1 S1 0132 DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES, N.O.S. 0133 MANNITOL HEXANITRATE (NITROMANNITE), WETTED with not less than 40% water, or mixture of alcohol and water, by mass S1 0146 NITROSTARCH, dry or wetted with less than 20% water, by mass S1 0147 NITRO UREA S1 0150 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN), WETTED with not less than 25% water, by mass, or DESENSITIZED with not less than 15% phlegmatizer, by mass 0151 PENTOLITE, dry or wetted with less than 15% water, by mass S1 S1 0153 TRINITROANILINE (PICRAMIDE) S1 0154 TRINITROPHENOL (PICRIC ACID), dry or wetted with less than 30% water, by mass 0155 TRINITROCHLORO-BENZENE (PICRYL CHLORIDE) S1 S1 S1 0159 POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass 0160 POWDER, SMOKELESS S1 0161 POWDER, SMOKELESS S1 0167 PROJECTILES with bursting charge UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.1D 0169 PROJECTILES with bursting charge 1 1.2D 0171 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 1 0173 RELEASE DEVICES, EXPLOSIVE 2.1.1.3 (4) 5.2.2 (5) 1 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0168 PROJECTILES with bursting charge Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P130 LP101 4.1.4 (9a) PP67 L1 4.1.10 (9b) MP21 1 0 E0 P130 LP101 PP67 L1 MP21 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.4S 1.4 0 E0 P134 LP102 MP23 0174 RIVETS, EXPLOSIVE 1 1.4S 1.4 0 E0 P134 LP102 MP23 0180 ROCKETS with bursting charge 1 1.1F 1 0 E0 P130 MP23 0181 ROCKETS with bursting charge 1 1.1E 1 0 E0 P130 LP101 PP67 L1 MP21 0182 ROCKETS with bursting charge 1 1.2E 1 0 E0 P130 LP101 PP67 L1 MP21 0183 ROCKETS with inert head 1 1.3C 1 0 E0 P130 LP101 PP67 L1 MP22 0186 ROCKET MOTORS 1 1.3C 1 0 E0 P130 LP101 PP67 L1 MP22 MP24 0190 SAMPLES, EXPLOSIVE, other than initiating explosive 1 0 E0 P101 MP2 0191 SIGNAL DEVICES, HAND 1 1.4G 1.4 0 E0 P135 MP23 MP24 0192 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1 1.1G 1 0 E0 P135 MP23 0193 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1 1.4S 1.4 0 E0 P135 MP23 0194 SIGNALS, DISTRESS, ship 1 1.1G 1 0 E0 P135 MP23 MP24 0195 SIGNALS, DISTRESS, ship 1 1.3G 1 0 E0 P135 MP23 MP24 0196 SIGNALS, SMOKE 1 1.1G 1 0 E0 P135 MP23 0197 SIGNALS, SMOKE 1 1.4G 1.4 0 E0 P135 MP23 MP24 0204 SOUNDING DEVICES, EXPLOSIVE 1 1.2F 1 0 E0 P134 LP102 MP23 0207 TETRANITROANILINE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0208 TRINITROPHENYLMETHYLNITRAMINE (TETRYL) 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0209 TRINITROTOLUENE (TNT), dry or wetted with less than 30% water, by mass 0212 TRACERS FOR AMMUNITION 1 1.1D 1 0 E0 P112(b) P112(c) PP46 MP20 1 1.3G 1 0 E0 P133 PP69 MP23 0213 TRINITROANISOLE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0214 TRINITROBENZENE, dry or wetted with less than 30% water, by mass 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) MP20 16 274 - 286 - 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (B1000C) 7.2.4 (16) V2 7.3.3 (17) 8.5 (19) S1 1 (B1000C) V2 1 (B1000C) V2 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 4 (E) 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 0 (E) V2 2 (E) V2 1 (B1000C) V2 4 (E) 1 (B1000C) V2 1 (C5000D) V2 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (C5000D) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 - 287 - 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 0168 PROJECTILES with bursting charge S1 0169 PROJECTILES with bursting charge S1 0171 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge S1 0173 RELEASE DEVICES, EXPLOSIVE S1 0174 RIVETS, EXPLOSIVE S1 0180 ROCKETS with bursting charge S1 0181 ROCKETS with bursting charge S1 0182 ROCKETS with bursting charge S1 0183 ROCKETS with inert head S1 0186 ROCKET MOTORS S1 0190 SAMPLES, EXPLOSIVE, other than initiating explosive S1 0191 SIGNAL DEVICES, HAND S1 0192 SIGNALS, RAILWAY TRACK, EXPLOSIVE S1 0193 SIGNALS, RAILWAY TRACK, EXPLOSIVE S1 0194 SIGNALS, DISTRESS, ship S1 0195 SIGNALS, DISTRESS, ship S1 0196 SIGNALS, SMOKE S1 0197 SIGNALS, SMOKE S1 0204 SOUNDING DEVICES, EXPLOSIVE S1 0207 TETRANITROANILINE S1 0208 TRINITROPHENYLMETHYLNITRAMINE (TETRYL) S1 S1 0209 TRINITROTOLUENE (TNT), dry or wetted with less than 30% water, by mass 0212 TRACERS FOR AMMUNITION S1 0213 TRINITROANISOLE S1 0214 TRINITROBENZENE, dry or wetted with less than 30% water, by mass UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.1D 1 1.1D 0217 TRINITRONAPHTHALENE 1 0218 TRINITROPHENETOLE 2.1.1.3 (4) 5.2.2 (5) 1 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0215 TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass 0216 TRINITRO-m-CRESOL Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 1 0 E0 1.1D 1 0 E0 P112(b) P112(c) MP20 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0219 TRINITRORESORCINOL (STYPHNIC ACID), dry or wetted with less than 20% water, or mixture of alcohol and water, by mass 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) 0220 UREA NITRATE, dry or wetted with less than 20% water, by mass 1 1.1D 1 0 E0 0221 WARHEADS, TORPEDO with bursting charge 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) P130 LP101 0222 AMMONIUM NITRATE 1 1.1D 1 0 E0 0224 BARIUM AZIDE, dry or wetted with less than 50% water, by mass 1 1.1A 1 +6.1 0 0225 BOOSTERS WITH DETONATOR 1 1.1B 1 0226 CYCLOTETRAMETHYLENETETRANITRAMINE (HMX; OCTOGEN), WETTED with not less than 15% water, by mass 0234 SODIUM DINITRO-oCRESOLATE, dry or wetted with less than 15% water, by mass 0235 SODIUM PICRAMATE, dry or wetted with less than 20% water, by mass 0236 ZIRCONIUM PICRAMATE, dry or wetted with less than 20% water, by mass 0237 CHARGES, SHAPED, FLEXIBLE, LINEAR 1 1.1D 1 1 1.3C 1 370 4.1.4 (8) P112(a) P112(b) P112(c) P112(b) P112(c) 4.1.4 (9a) 4.1.10 (9b) MP20 PP26 MP20 PP26 MP20 MP20 PP67 L1 MP21 PP47 MP20 E0 P112(b) P112(c) IBC100 P110(b) B3 B17 PP42 MP20 0 E0 P133 PP69 MP23 0 E0 P112(a) PP45 MP20 1 0 E0 P114(a) P114(b) PP26 MP20 1.3C 1 0 E0 P114(a) P114(b) PP26 MP20 1 1.3C 1 0 E0 P114(a) P114(b) PP26 MP20 1 1.4D 1.4 0 E0 P138 MP21 0238 ROCKETS, LINE-THROWING 1 1.2G 1 0 E0 P130 MP23 MP24 0240 ROCKETS, LINE-THROWING 1 1.3G 1 0 E0 P130 MP23 MP24 0241 EXPLOSIVE, BLASTING, TYPE E 1 1.1D 1 0 E0 P116 PP61 PP62 1 1.3C 1 0 E0 IBC100 P130 B10 0242 CHARGES, PROPELLING, FOR CANNON 0243 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 1 1.2H 1 0 E0 P130 LP101 PP67 L1 MP23 0244 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 1 1.3H 1 0 E0 P130 LP101 PP67 L1 MP23 0245 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 1 1.2H 1 0 E0 P130 LP101 PP67 L1 MP23 0246 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 1 1.3H 1 0 E0 P130 LP101 PP67 L1 MP23 266 617 - 288 - MP20 MP22 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (B1000C) 7.2.4 (16) V2 V3 7.3.3 (17) 8.5 (19) S1 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 1 (B1000C) V2 V3 1 (B1000C) V2 1 (B1000C) V2 V3 0 (B) V2 V3 1 (B1000C) V2 1 (B1000C) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV1 CV2 CV3 1 (C5000D) V2 V3 1 (C5000D) V2 V3 1 (C5000D) V2 V3 2 (E) V2 1 (B1000C) V2 1 (C5000D) V2 1 (B1000C) V2 V12 1 (C5000D) V2 1 (B1000C) V2 1 (C) V2 1 (B1000C) 1 (C) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 3.1.2 (1) (2) 0215 TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass 0216 TRINITRO-m-CRESOL S1 0217 TRINITRONAPHTHALENE S1 0218 TRINITROPHENETOLE S1 0219 TRINITRORESORCINOL (STYPHNIC ACID), dry or wetted with less than 20% water, or mixture of alcohol and water, by mass S1 0220 UREA NITRATE, dry or wetted with less than 20% water, by mass S1 0221 WARHEADS, TORPEDO with bursting charge S1 0222 AMMONIUM NITRATE S1 0224 BARIUM AZIDE, dry or wetted with less than 50% water, by mass S1 0225 BOOSTERS WITH DETONATOR S1 0226 CYCLOTETRAMETHYLENETETRANITRAMINE (HMX; OCTOGEN), WETTED with not less than 15% water, by mass 0234 SODIUM DINITRO-oCRESOLATE, dry or wetted with less than 15% water, by mass 0235 SODIUM PICRAMATE, dry or wetted with less than 20% water, by mass 0236 ZIRCONIUM PICRAMATE, dry or wetted with less than 20% water, by mass 0237 CHARGES, SHAPED, FLEXIBLE, LINEAR S1 S1 S1 S1 5.3.2.3 (20) Name and description S1 0238 ROCKETS, LINE-THROWING S1 0240 ROCKETS, LINE-THROWING S1 0241 EXPLOSIVE, BLASTING, TYPE E S1 0242 CHARGES, PROPELLING, FOR CANNON S1 0243 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge CV1 CV2 CV3 S1 0244 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge V2 CV1 CV2 CV3 S1 0245 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge V2 CV1 CV2 CV3 S1 0246 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge CV1 CV2 CV3 CV1 CV2 CV3 - 289 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.3J 0248 CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge 1 0249 CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0247 AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge Packaging 5.2.2 (5) 1 3.3 (6) 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P101 4.1.4 (9a) 4.1.10 (9b) MP23 1.2L 1 274 0 E0 P144 PP77 MP1 1 1.3L 1 274 0 E0 P144 PP77 MP1 0250 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge 1 1.3L 1 0 E0 P101 0254 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 1 1.3G 1 0 E0 P130 LP101 0255 DETONATORS, ELECTRIC for blasting 1 1.4B 1.4 0 E0 P131 MP23 0257 FUZES, DETONATING 1 1.4B 1.4 0 E0 P141 MP23 0266 OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass 1 1.1D 1 0 E0 MP20 0267 DETONATORS, NON-ELECTRIC for blasting 1 1.4B 1.4 0 E0 P112(a) P112(b) P112(c) P131 PP68 MP23 0268 BOOSTERS WITH DETONATOR 1 1.2B 1 0 E0 P133 PP69 MP23 0271 CHARGES, PROPELLING 1 1.1C 1 0 E0 P143 PP76 MP22 0272 CHARGES, PROPELLING 1 1.3C 1 0 E0 P143 PP76 MP22 0275 CARTRIDGES, POWER DEVICE 1 1.3C 1 0 E0 P134 LP102 MP22 0276 CARTRIDGES, POWER DEVICE 1 1.4C 1.4 0 E0 P134 LP102 MP22 0277 CARTRIDGES, OIL WELL 1 1.3C 1 0 E0 P134 LP102 MP22 0278 CARTRIDGES, OIL WELL 1 1.4C 1.4 0 E0 P134 LP102 MP22 0279 CHARGES, PROPELLING, FOR CANNON 1 1.1C 1 0 E0 P130 MP22 0280 ROCKET MOTORS 1 1.1C 1 0 E0 P130 LP101 PP67 L1 MP22 0281 ROCKET MOTORS 1 1.2C 1 0 E0 P130 LP101 PP67 L1 MP22 0282 NITROGUANIDINE (PICRITE), dry or wetted with less than 20% water, by mass 0283 BOOSTERS without detonator 1 1.1D 1 0 E0 MP20 1 1.2D 1 0 E0 P112(a) P112(b) P112(c) P132(a) P132(b) 0284 GRENADES, hand or rifle, with bursting charge 1 1.1D 1 0 E0 P141 MP21 0285 GRENADES, hand or rifle, with bursting charge 1 1.2D 1 0 E0 P141 MP21 0286 WARHEADS, ROCKET with bursting charge 1 1.1D 1 0 E0 P130 LP101 - 290 - MP1 PP67 L1 MP23 MP21 PP67 L1 MP21 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (C) 7.2.4 (16) V2 7.3.3 (17) 7.5.11 (18) CV1 CV2 CV3 8.5 (19) S1 0 (B) V2 S1 0248 CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge 0 (B) V2 S1 0249 CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge 0 (B) V2 S1 0250 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge 1 (C5000D) V2 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 S1 0254 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 2 (E) V2 S1 0255 DETONATORS, ELECTRIC for blasting 2 (E) V2 S1 0257 FUZES, DETONATING 1 (B1000C) V2 V3 S1 0266 OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass 2 (E) V2 S1 0267 DETONATORS, NON-ELECTRIC for blasting 1 (B1000C) V2 S1 0268 BOOSTERS WITH DETONATOR 1 (B1000C) V2 S1 0271 CHARGES, PROPELLING 1 (C5000D) V2 S1 0272 CHARGES, PROPELLING 1 (C5000D) V2 S1 0275 CARTRIDGES, POWER DEVICE 2 (E) V2 S1 0276 CARTRIDGES, POWER DEVICE 1 (C5000D) V2 S1 0277 CARTRIDGES, OIL WELL 2 (E) V2 S1 0278 CARTRIDGES, OIL WELL 1 (B1000C) V2 S1 0279 CHARGES, PROPELLING, FOR CANNON 1 (B1000C) V2 S1 0280 ROCKET MOTORS 1 (B1000C) V2 S1 0281 ROCKET MOTORS 1 (B1000C) V2 V3 S1 1 (B1000C) V2 0282 NITROGUANIDINE (PICRITE), dry or wetted with less than 20% water, by mass 0283 BOOSTERS without detonator 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 - 291 - S1 5.3.2.3 (20) 3.1.2 (1) (2) 0247 AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge S1 0284 GRENADES, hand or rifle, with bursting charge S1 0285 GRENADES, hand or rifle, with bursting charge S1 0286 WARHEADS, ROCKET with bursting charge UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.2D 0288 CHARGES, SHAPED, FLEXIBLE, LINEAR 1 1.1D 0289 CORD, DETONATING, flexible 1 0290 CORD (FUSE), DETONATING, metal clad 2.1.1.3 (4) 5.2.2 (5) 1 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0287 WARHEADS, ROCKET with bursting charge Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P130 LP101 1 0 E0 P138 1.4D 1.4 0 E0 P139 PP71 PP72 MP21 1 1.1D 1 0 E0 P139 PP71 MP21 0291 BOMBS with bursting charge 1 1.2F 1 0 E0 P130 MP23 0292 GRENADES, hand or rifle, with bursting charge 1 1.1F 1 0 E0 P141 MP23 0293 GRENADES, hand or rifle, with bursting charge 1 1.2F 1 0 E0 P141 MP23 0294 MINES with bursting charge 1 1.2F 1 0 E0 P130 MP23 0295 ROCKETS with bursting charge 1 1.2F 1 0 E0 P130 MP23 0296 SOUNDING DEVICES, EXPLOSIVE 1 1.1F 1 0 E0 P134 LP102 MP23 0297 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 0299 BOMBS, PHOTO-FLASH 1 1.3G 1 0 E0 P130 LP101 PP67 L1 MP23 0300 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0301 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 1 1.4G 1.4 +6.1 +8 0 E0 P130 LP101 PP67 L1 MP23 0303 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0303 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge, containing corrosive substances 0305 FLASH POWDER 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 1 1.4G 1.4 +8 0 E0 P130 LP101 PP67 L1 MP23 1 1.3G 1 0 E0 P113 PP49 MP20 0306 TRACERS FOR AMMUNITION 1 1.4G 1.4 0 E0 P133 PP69 MP23 0312 CARTRIDGES, SIGNAL 1 1.4G 1.4 0 E0 P135 MP23 MP24 0313 SIGNALS, SMOKE 1 1.2G 1 0 E0 P135 MP23 0314 IGNITERS 1 1.2G 1 0 E0 P142 MP23 0315 IGNITERS 1 1.3G 1 0 E0 P142 MP23 0316 FUZES, IGNITING 1 1.3G 1 0 E0 P141 MP23 0317 FUZES, IGNITING 1 1.4G 1.4 0 E0 P141 MP23 0318 GRENADES, PRACTICE, hand or rifle 1 1.3G 1 0 E0 P141 MP23 - 292 - 4.1.4 (9a) PP67 L1 4.1.10 (9b) MP21 MP21 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (B1000C) 7.2.4 (16) V2 7.3.3 (17) 8.5 (19) S1 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 1 (C5000D) V2 2 (E) V2 2 (E) V2 2 (E) V2 2 (E) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV1 CV2 CV3 1 (C5000D) V2 V3 2 (E) V2 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 2 (E) V2 1 (C5000D) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 - 293 - 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 0287 WARHEADS, ROCKET with bursting charge S1 0288 CHARGES, SHAPED, FLEXIBLE, LINEAR S1 0289 CORD, DETONATING, flexible S1 0290 CORD (FUSE), DETONATING, metal clad S1 0291 BOMBS with bursting charge S1 0292 GRENADES, hand or rifle, with bursting charge S1 0293 GRENADES, hand or rifle, with bursting charge S1 0294 MINES with bursting charge S1 0295 ROCKETS with bursting charge S1 0296 SOUNDING DEVICES, EXPLOSIVE S1 0297 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge S1 0299 BOMBS, PHOTO-FLASH S1 0300 AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0301 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge S1 S1 S1 0303 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0303 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge, containing corrosive substances 0305 FLASH POWDER S1 0306 TRACERS FOR AMMUNITION S1 0312 CARTRIDGES, SIGNAL S1 0313 SIGNALS, SMOKE S1 0314 IGNITERS S1 0315 IGNITERS S1 0316 FUZES, IGNITING S1 0317 FUZES, IGNITING S1 0318 GRENADES, PRACTICE, hand or rifle S1 UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.3G 0320 PRIMERS, TUBULAR 1 1.4G 0321 CARTRIDGES FOR WEAPONS with bursting charge 1 0322 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge 2.1.1.3 (4) 5.2.2 (5) 1 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0319 PRIMERS, TUBULAR Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P133 1.4 0 E0 P133 1.2E 1 0 E0 P130 LP101 1 1.2L 1 0 E0 P101 MP1 0323 CARTRIDGES, POWER DEVICE 1 1.4S 1.4 0 E0 P134 LP102 MP23 0324 PROJECTILES with bursting charge 1 1.2F 1 0 E0 P130 MP23 0325 IGNITERS 1 1.4G 1.4 0 E0 P142 MP23 0326 CARTRIDGES FOR WEAPONS, BLANK 1 1.1C 1 0 E0 P130 MP22 0327 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 0328 CARTRIDGES FOR WEAPONS, INERT PROJECTILE 1 1.3C 1 0 E0 P130 MP22 1 1.2C 1 0 E0 P130 LP101 PP67 L1 MP22 0329 TORPEDOES with bursting charge 1 1.1E 1 0 E0 P130 LP101 PP67 L1 MP21 0330 TORPEDOES with bursting charge 1 1.1F 1 0 E0 P130 0331 EXPLOSIVE, BLASTING, TYPE B (AGENT, BLASTING, TYPE B) 1 1.5D 1.5 0 E0 P116 347 617 4.1.4 (9a) 4.1.10 (9b) MP23 4.2.5.2 (10) 4.2.5.3 (11) MP23 PP67 L1 MP21 MP23 PP61 PP62 PP64 MP20 T1 TP1 TP17 TP32 PP61 PP62 MP20 T1 TP1 TP17 TP32 IBC100 0332 EXPLOSIVE, BLASTING, TYPE E (AGENT, BLASTING, TYPE E) 1 1.5D 1.5 617 0 E0 P116 0333 FIREWORKS 1 1.1G 1 645 0 E0 IBC100 P135 0334 FIREWORKS 1 1.2G 1 645 0 E0 P135 MP23 MP24 0335 FIREWORKS 1 1.3G 1 645 0 E0 P135 MP23 MP24 0336 FIREWORKS 1 1.4G 1.4 645 651 0 E0 P135 MP23 MP24 0337 FIREWORKS 1 1.4S 1.4 645 0 E0 P135 MP23 MP24 0338 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 0339 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0340 NITROCELLULOSE, dry or wetted with less than 25% water (or alcohol), by mass 0341 NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass 0342 NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass 1 1.4C 1.4 0 E0 P130 MP22 1 1.4C 1.4 0 E0 P130 MP22 1 1.1D 1 0 E0 P112(a) P112(b) MP20 1 1.1D 1 0 E0 P112(b) MP20 1 1.3C 1 0 E0 P114(a) 105 - 294 - MP23 MP24 PP43 MP20 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage TU3 TU12 TU41 TC8 TA1 TA5 Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (C5000D) 7.2.4 (16) V2 7.3.3 (17) 8.5 (19) S1 2 (E) V2 1 (B1000C) V2 0 (B) V2 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 1.5D 0331 EXPLOSIVE, BLASTING, TYPE B (AGENT, BLASTING, TYPE B) 1.5D 0332 EXPLOSIVE, BLASTING, TYPE E (AGENT, BLASTING, TYPE E) 4 (E) S2.65AN(+) Hazard UN No. identification No. Operation 5.3.2.3 (20) 3.1.2 (1) (2) 0319 PRIMERS, TUBULAR S1 0320 PRIMERS, TUBULAR S1 0321 CARTRIDGES FOR WEAPONS with bursting charge S1 0322 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge S1 0323 CARTRIDGES, POWER DEVICE S1 0324 PROJECTILES with bursting charge S1 0325 IGNITERS S1 0326 CARTRIDGES FOR WEAPONS, BLANK S1 0327 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 0328 CARTRIDGES FOR WEAPONS, INERT PROJECTILE 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 1 (C5000D) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 EX/III 1 (B1000C) V2 V12 EX/III 1 (B1000C) V2 V12 CV1 CV2 CV3 S1 1 (B1000C) V2 V3 S1 0333 FIREWORKS 1 (B1000C) V2 V3 S1 0334 FIREWORKS 1 (C5000D) V2 V3 S1 0335 FIREWORKS 2 (E) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0336 FIREWORKS S1 0337 FIREWORKS S1 0338 CARTRIDGES FOR WEAPONS, BLANK or CARTRIDGES, SMALL ARMS, BLANK 0339 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0340 NITROCELLULOSE, dry or wetted with less than 25% water (or alcohol), by mass 0341 NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass 0342 NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass 4 (E) 2 (E) V2 2 (E) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (C5000D) V2 - 295 - S1 S1 0329 TORPEDOES with bursting charge S1 0330 TORPEDOES with bursting charge S1 S1 S1 S1 UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.3C 0344 PROJECTILES with bursting charge 1 1.4D 0345 PROJECTILES, inert with tracer 1 0346 PROJECTILES with burster or expelling charge 2.1.1.3 (4) 5.2.2 (5) 1 3.3 (6) 105 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0343 NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance, by mass Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P111 4.1.4 (9a) 4.1.10 (9b) MP20 1.4 0 E0 P130 LP101 PP67 L1 MP21 1.4S 1.4 0 E0 P130 LP101 PP67 L1 MP23 1 1.2D 1 0 E0 P130 LP101 PP67 L1 MP21 0347 PROJECTILES with burster or expelling charge 1 1.4D 1.4 0 E0 P130 LP101 PP67 L1 MP21 0348 CARTRIDGES FOR WEAPONS with bursting charge 1 1.4F 1.4 0 E0 P130 MP23 0349 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4S 1.4 178 274 0 E0 P101 MP2 0350 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4B 1.4 178 274 0 E0 P101 MP2 0351 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4C 1.4 178 274 0 E0 P101 MP2 0352 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4D 1.4 178 274 0 E0 P101 MP2 0353 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4G 1.4 178 274 0 E0 P101 MP2 0354 ARTICLES, EXPLOSIVE, N.O.S. 1 1.1L 1 178 274 0 E0 P101 MP1 0355 ARTICLES, EXPLOSIVE, N.O.S. 1 1.2L 1 178 274 0 E0 P101 MP1 0356 ARTICLES, EXPLOSIVE, N.O.S. 1 1.3L 1 178 274 0 E0 P101 MP1 0357 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1L 1 178 274 0 E0 P101 MP1 0358 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.2L 1 178 274 0 E0 P101 MP1 0359 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.3L 1 178 274 0 E0 P101 MP1 0360 DETONATOR ASSEMBLIES, NONELECTRIC for blasting 1 1.1B 1 0 E0 P131 MP23 0361 DETONATOR ASSEMBLIES, NONELECTRIC for blasting 1 1.4B 1.4 0 E0 P131 MP23 0362 AMMUNITION, PRACTICE 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 0363 AMMUNITION, PROOF 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 0364 DETONATORS FOR AMMUNITION 1 1.2B 1 0 E0 P133 MP23 0365 DETONATORS FOR AMMUNITION 1 1.4B 1.4 0 E0 P133 MP23 - 296 - 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (C5000D) 7.2.4 (16) V2 7.3.3 (17) 7.5.11 (18) CV1 CV2 CV3 8.5 (19) S1 2 (E) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0344 PROJECTILES with bursting charge S1 0345 PROJECTILES, inert with tracer S1 0346 PROJECTILES with burster or expelling charge S1 0347 PROJECTILES with burster or expelling charge S1 0348 CARTRIDGES FOR WEAPONS with bursting charge S1 0349 ARTICLES, EXPLOSIVE, N.O.S. S1 0350 ARTICLES, EXPLOSIVE, N.O.S. S1 0351 ARTICLES, EXPLOSIVE, N.O.S. S1 0352 ARTICLES, EXPLOSIVE, N.O.S. S1 0353 ARTICLES, EXPLOSIVE, N.O.S. S1 0354 ARTICLES, EXPLOSIVE, N.O.S. S1 0355 ARTICLES, EXPLOSIVE, N.O.S. S1 0356 ARTICLES, EXPLOSIVE, N.O.S. S1 0357 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0358 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0359 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0360 DETONATOR ASSEMBLIES, NONELECTRIC for blasting S1 0361 DETONATOR ASSEMBLIES, NONELECTRIC for blasting S1 0362 AMMUNITION, PRACTICE S1 0363 AMMUNITION, PROOF S1 0364 DETONATORS FOR AMMUNITION S1 0365 DETONATORS FOR AMMUNITION 4 (E) 1 (B1000C) V2 2 (E) V2 2 (E) V2 4 (E) 2 (E) V2 2 (E) V2 2 (E) V2 2 (E) V2 0 (B) V2 0 (B) V2 0 (B) V2 0 (B) V2 0 (B) V2 0 (B) V2 1 (B1000C) V2 2 (E) V2 2 (E) V2 2 (E) V2 1 (B1000C) V2 2 (E) V2 - 297 - 5.3.2.3 (20) 3.1.2 (1) (2) 0343 NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance, by mass UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.4S 0367 FUZES, DETONATING 1 1.4S 0368 FUZES, IGNITING 1 0369 WARHEADS, ROCKET with bursting charge 2.1.1.3 (4) 5.2.2 (5) 1.4 3.3 (6) 347 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0366 DETONATORS FOR AMMUNITION Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P133 1.4 0 E0 P141 MP23 1.4S 1.4 0 E0 P141 MP23 1 1.1F 1 0 E0 P130 MP23 0370 WARHEADS, ROCKET with burster or expelling charge 1 1.4D 1.4 0 E0 P130 LP101 0371 WARHEADS, ROCKET with burster or expelling charge 1 1.4F 1.4 0 E0 P130 MP23 0372 GRENADES, PRACTICE, hand or rifle 1 1.2G 1 0 E0 P141 MP23 0373 SIGNAL DEVICES, HAND 1 1.4S 1.4 0 E0 P135 MP23 MP24 0374 SOUNDING DEVICES, EXPLOSIVE 1 1.1D 1 0 E0 P134 LP102 MP21 0375 SOUNDING DEVICES, EXPLOSIVE 1 1.2D 1 0 E0 P134 LP102 MP21 0376 PRIMERS, TUBULAR 1 1.4S 1.4 0 E0 P133 MP23 0377 PRIMERS, CAP TYPE 1 1.1B 1 0 E0 P133 MP23 0378 PRIMERS, CAP TYPE 1 1.4B 1.4 0 E0 P133 MP23 0379 CASES, CARTRIDGE, EMPTY, WITH PRIMER 1 1.4C 1.4 0 E0 P136 MP22 0380 ARTICLES, PYROPHORIC 1 1.2L 1 0 E0 P101 MP1 0381 CARTRIDGES, POWER DEVICE 1 1.2C 1 0 E0 P134 LP102 MP22 0382 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1 1.2B 1 178 274 0 E0 P101 MP2 0383 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1 1.4B 1.4 178 274 0 E0 P101 MP2 0384 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1 1.4S 1.4 178 274 0 E0 P101 MP2 0385 5-NITROBENZOTRIAZOL 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0386 TRINITROBENZENE-SULPHONIC ACID 1 1.1D 1 0 E0 P112(b) P112(c) 0387 TRINITROFLUORENONE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0388 TRINITROTOLUENE (TNT) AND TRINITROBENZENE MIXTURE or TRINITROTOLUENE (TNT) AND HEXANITROSTILBENE MIXTURE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0389 TRINITROTOLUENE (TNT) MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 - 298 - 4.1.4 (9a) PP67 L1 PP26 4.1.10 (9b) MP23 MP21 MP20 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) 1.1.3.6 (15) 4 (E) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV4 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 8.5 (19) S1 CV1 CV2 CV3 4 (E) 4 (E) 1 (B1000C) V2 2 (E) V2 2 (E) V2 1 (B1000C) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 4 (E) 1 (B1000C) V2 2 (E) V2 2 (E) V2 0 (B) V2 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 4 (E) 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 - 299 - 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 0366 DETONATORS FOR AMMUNITION S1 0367 FUZES, DETONATING S1 0368 FUZES, IGNITING S1 0369 WARHEADS, ROCKET with bursting charge S1 0370 WARHEADS, ROCKET with burster or expelling charge S1 0371 WARHEADS, ROCKET with burster or expelling charge S1 0372 GRENADES, PRACTICE, hand or rifle S1 0373 SIGNAL DEVICES, HAND S1 0374 SOUNDING DEVICES, EXPLOSIVE S1 0375 SOUNDING DEVICES, EXPLOSIVE S1 0376 PRIMERS, TUBULAR S1 0377 PRIMERS, CAP TYPE S1 0378 PRIMERS, CAP TYPE S1 0379 CASES, CARTRIDGE, EMPTY, WITH PRIMER S1 0380 ARTICLES, PYROPHORIC S1 0381 CARTRIDGES, POWER DEVICE S1 0382 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. S1 0383 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. S1 0384 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. S1 0385 5-NITROBENZOTRIAZOL S1 0386 TRINITROBENZENE-SULPHONIC ACID S1 0387 TRINITROFLUORENONE S1 0388 TRINITROTOLUENE (TNT) AND TRINITROBENZENE MIXTURE or TRINITROTOLUENE (TNT) AND HEXANITROSTILBENE MIXTURE S1 0389 TRINITROTOLUENE (TNT) MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.1D 5.2.2 (5) 1 3.3 (6) 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P112(b) P112(c) 0391 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX) AND CYCLOTETRAMETHYLENETETRANITRAMINE (HMX; OCTOGEN) MIXTURE, WETTED with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegmatiser by mass 1 1.1D 1 266 0 E0 P112(a) P112(b) MP20 0392 HEXANITROSTILBENE 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0393 HEXOTONAL 1 1.1D 1 0 E0 P112(b) MP20 0394 TRINITRORESORCINOL (STYPHNIC ACID), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 1 1.1D 1 0 E0 P112(a) 0395 ROCKET MOTORS, LIQUID FUELLED 1 1.2J 1 0 E0 P101 MP23 0396 ROCKET MOTORS, LIQUID FUELLED 1 1.3J 1 0 E0 P101 MP23 0397 ROCKETS, LIQUID FUELLED with bursting charge 1 1.1J 1 0 E0 P101 MP23 0398 ROCKETS, LIQUID FUELLED with bursting charge 1 1.2J 1 0 E0 P101 MP23 0399 BOMBS WITH FLAMMABLE LIQUID with bursting charge 1 1.1J 1 0 E0 P101 MP23 0400 BOMBS WITH FLAMMABLE LIQUID with bursting charge 1 1.2J 1 0 E0 P101 MP23 0401 DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass 0402 AMMONIUM PERCHLORATE 1 1.1D 1 0 E0 MP20 1 1.1D 1 0 E0 P112(a) P112(b) P112(c) P112(b) P112(c) 0403 FLARES, AERIAL 1 1.4G 1.4 0 E0 P135 MP23 0404 FLARES, AERIAL 1 1.4S 1.4 0 E0 P135 MP23 0405 CARTRIDGES, SIGNAL 1 1.4S 1.4 0 E0 P135 MP23 MP24 0406 DINITROSOBENZENE 1 1.3C 1 0 E0 P114(b) MP20 0407 TETRAZOL-1-ACETIC ACID 1 1.4C 1.4 0 E0 P114(b) MP20 0408 FUZES, DETONATING with protective features 1 1.1D 1 0 E0 P141 MP21 0409 FUZES, DETONATING with protective features 1 1.2D 1 0 E0 P141 MP21 0410 FUZES, DETONATING with protective features 1 1.4D 1.4 0 E0 P141 MP21 0411 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) with not less than 7% wax, by mass 1 1.1D 1 0 E0 P112(b) P112(c) MP20 (1) 0390 TRITONAL 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (2) Packaging 152 131 - 300 - 4.1.4 (9a) PP26 4.1.10 (9b) MP20 MP20 MP20 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (B1000C) 7.2.4 (16) V2 V3 7.3.3 (17) 8.5 (19) S1 1 (B1000C) V2 V3 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 S1 0391 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX) AND CYCLOTETRAMETHYLENETETRANITRAMINE (HMX; OCTOGEN) MIXTURE, WETTED with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegmatiser by mass 1 (B1000C) V2 V3 S1 0392 HEXANITROSTILBENE 1 (B1000C) V2 V3 S1 0393 HEXOTONAL 1 (B1000C) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0394 TRINITRORESORCINOL (STYPHNIC ACID), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 1 (B1000C) V2 S1 0395 ROCKET MOTORS, LIQUID FUELLED 1 (C) V2 S1 0396 ROCKET MOTORS, LIQUID FUELLED 1 (B1000C) V2 S1 0397 ROCKETS, LIQUID FUELLED with bursting charge 1 (B1000C) V2 S1 0398 ROCKETS, LIQUID FUELLED with bursting charge 1 (B1000C) V2 S1 0399 BOMBS WITH FLAMMABLE LIQUID with bursting charge 1 (B1000C) V2 S1 0400 BOMBS WITH FLAMMABLE LIQUID with bursting charge 1 (B1000C) V2 V3 S1 1 (B1000C) V2 V3 S1 0401 DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass 0402 AMMONIUM PERCHLORATE 2 (E) V2 S1 0403 FLARES, AERIAL S1 0404 FLARES, AERIAL S1 0405 CARTRIDGES, SIGNAL S1 0406 DINITROSOBENZENE S1 0407 TETRAZOL-1-ACETIC ACID S1 0408 FUZES, DETONATING with protective features S1 0409 FUZES, DETONATING with protective features S1 0410 FUZES, DETONATING with protective features S1 0411 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) with not less than 7% wax, by mass 4 (E) 4 (E) 1 (C5000D) V2 V3 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 V3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 - 301 - 5.3.2.3 (20) (1) 0390 TRITONAL 3.1.2 (2) UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.4E 0413 CARTRIDGES FOR WEAPONS, BLANK 1 1.2C 0414 CHARGES, PROPELLING, FOR CANNON 1 0415 CHARGES, PROPELLING 0417 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0418 FLARES, SURFACE 2.1.1.3 (4) 5.2.2 (5) 1.4 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0412 CARTRIDGES FOR WEAPONS with bursting charge Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P130 LP101 1 0 E0 P130 MP22 1.2C 1 0 E0 P130 MP22 1 1.2C 1 0 E0 P143 1 1.3C 1 0 E0 P130 MP22 1 1.1G 1 0 E0 P135 MP23 0419 FLARES, SURFACE 1 1.2G 1 0 E0 P135 MP23 0420 FLARES, AERIAL 1 1.1G 1 0 E0 P135 MP23 0421 FLARES, AERIAL 1 1.2G 1 0 E0 P135 MP23 0424 PROJECTILES, inert with tracer 1 1.3G 1 0 E0 P130 LP101 PP67 L1 MP23 0425 PROJECTILES, inert with tracer 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 0426 PROJECTILES with burster or expelling charge 1 1.2F 1 0 E0 P130 MP23 0427 PROJECTILES with burster or expelling charge 1 1.4F 1.4 0 E0 P130 MP23 0428 ARTICLES, PYROTECHNIC for technical purposes 1 1.1G 1 0 E0 P135 MP23 MP24 0429 ARTICLES, PYROTECHNIC for technical purposes 1 1.2G 1 0 E0 P135 MP23 MP24 0430 ARTICLES, PYROTECHNIC for technical purposes 1 1.3G 1 0 E0 P135 MP23 MP24 0431 ARTICLES, PYROTECHNIC for technical purposes 1 1.4G 1.4 0 E0 P135 MP23 MP24 0432 ARTICLES, PYROTECHNIC for technical purposes 1 1.4S 1.4 0 E0 P135 MP23 MP24 0433 POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass 0434 PROJECTILES with burster or expelling charge 1 1.1C 1 0 E0 P111 MP20 1 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 0435 PROJECTILES with burster or expelling charge 1 1.4G 1.4 0 E0 P130 LP101 PP67 L1 MP23 0436 ROCKETS with expelling charge 1 1.2C 1 0 E0 P130 LP101 PP67 L1 MP22 0437 ROCKETS with expelling charge 1 1.3C 1 0 E0 P130 LP101 PP67 L1 MP22 0438 ROCKETS with expelling charge 1 1.4C 1.4 0 E0 P130 LP101 PP67 L1 MP22 0439 CHARGES, SHAPED, without detonator 1 1.2D 1 0 E0 P137 PP70 MP21 0440 CHARGES, SHAPED, without detonator 1 1.4D 1.4 0 E0 P137 PP70 MP21 266 - 302 - 4.1.4 (9a) PP67 L1 PP76 4.1.10 (9b) MP21 MP22 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (E) 7.2.4 (16) V2 7.3.3 (17) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 2 (E) V2 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 2 (E) V2 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 4 (E) 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 1 (B1000C) V2 1 (C5000D) V2 2 (E) V2 1 (B1000C) V2 2 (E) V2 - 303 - Hazard UN No. identification No. Operation 8.5 (19) S1 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 0412 CARTRIDGES FOR WEAPONS with bursting charge S1 0413 CARTRIDGES FOR WEAPONS, BLANK S1 0414 CHARGES, PROPELLING, FOR CANNON S1 0415 CHARGES, PROPELLING S1 S1 0417 CARTRIDGES FOR WEAPONS, INERT PROJECTILE or CARTRIDGES, SMALL ARMS 0418 FLARES, SURFACE S1 0419 FLARES, SURFACE S1 0420 FLARES, AERIAL S1 0421 FLARES, AERIAL S1 0424 PROJECTILES, inert with tracer S1 0425 PROJECTILES, inert with tracer S1 0426 PROJECTILES with burster or expelling charge S1 0427 PROJECTILES with burster or expelling charge S1 0428 ARTICLES, PYROTECHNIC for technical purposes S1 0429 ARTICLES, PYROTECHNIC for technical purposes S1 0430 ARTICLES, PYROTECHNIC for technical purposes S1 0431 ARTICLES, PYROTECHNIC for technical purposes S1 0432 ARTICLES, PYROTECHNIC for technical purposes S1 0433 POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass 0434 PROJECTILES with burster or expelling charge S1 S1 0435 PROJECTILES with burster or expelling charge S1 0436 ROCKETS with expelling charge S1 0437 ROCKETS with expelling charge S1 0438 ROCKETS with expelling charge S1 0439 CHARGES, SHAPED, without detonator S1 0440 CHARGES, SHAPED, without detonator UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.4S 0442 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 1 1.1D 0443 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 1 0444 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 2.1.1.3 (4) 5.2.2 (5) 1.4 3.3 (6) 347 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0441 CHARGES, SHAPED, without detonator Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P137 1 0 E0 P137 MP21 1.2D 1 0 E0 P137 MP21 1 1.4D 1.4 0 E0 P137 MP21 0445 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 1 1.4S 1.4 0 E0 P137 MP23 0446 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER 1 1.4C 1.4 0 E0 P136 MP22 0447 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER 1 1.3C 1 0 E0 P136 MP22 0448 5-MERCAPTOTETRAZOL-1ACETIC ACID 1 1.4C 1.4 0 E0 P114(b) MP20 0449 TORPEDOES, LIQUID FUELLED with or without bursting charge 1 1.1J 1 0 E0 P101 MP23 0450 TORPEDOES, LIQUID FUELLED with inert head 1 1.3J 1 0 E0 P101 MP23 0451 TORPEDOES with bursting charge 1 1.1D 1 0 E0 P130 LP101 0452 GRENADES, PRACTICE, hand or rifle 1 1.4G 1.4 0 E0 P141 MP23 0453 ROCKETS, LINE-THROWING 1 1.4G 1.4 0 E0 P130 MP23 0454 IGNITERS 1 1.4S 1.4 0 E0 P142 MP23 0455 DETONATORS, NON-ELECTRIC for blasting 1 1.4S 1.4 347 0 E0 P131 0456 DETONATORS, ELECTRIC for blasting 1 1.4S 1.4 347 0 E0 P131 MP23 0457 CHARGES, BURSTING, PLASTICS BONDED 1 1.1D 1 0 E0 P130 MP21 0458 CHARGES, BURSTING, PLASTICS BONDED 1 1.2D 1 0 E0 P130 MP21 0459 CHARGES, BURSTING, PLASTICS BONDED 1 1.4D 1.4 0 E0 P130 MP21 0460 CHARGES, BURSTING, PLASTICS BONDED 1 1.4S 1.4 347 0 E0 P130 MP23 0461 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1 1.1B 1 178 274 0 E0 P101 MP2 0462 ARTICLES, EXPLOSIVE, N.O.S. 1 1.1C 1 178 274 0 E0 P101 MP2 0463 ARTICLES, EXPLOSIVE, N.O.S. 1 1.1D 1 178 274 0 E0 P101 MP2 0464 ARTICLES, EXPLOSIVE, N.O.S. 1 1.1E 1 178 274 0 E0 P101 MP2 0465 ARTICLES, EXPLOSIVE, N.O.S. 1 1.1F 1 178 274 0 E0 P101 MP2 0466 ARTICLES, EXPLOSIVE, N.O.S. 1 1.2C 1 178 274 0 E0 P101 MP2 347 - 304 - 4.1.4 (9a) PP70 PP67 L1 PP68 4.1.10 (9b) MP23 MP21 MP23 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 4 (E) 7.2.4 (16) 7.3.3 (17) 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 4 (E) 2 (E) V2 1 (C5000D) V2 2 (E) V2 1 (B1000C) V2 1 (C) V2 1 (B1000C) V2 2 (E) V2 2 (E) V2 4 (E) 4 (E) 4 (E) 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 - 305 - Hazard UN No. identification No. Operation 8.5 (19) S1 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 0441 CHARGES, SHAPED, without detonator S1 0442 CHARGES, EXPLOSIVE, COMMERCIAL without detonator S1 0443 CHARGES, EXPLOSIVE, COMMERCIAL without detonator S1 0444 CHARGES, EXPLOSIVE, COMMERCIAL without detonator S1 0445 CHARGES, EXPLOSIVE, COMMERCIAL without detonator S1 0446 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER S1 0447 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER S1 0448 5-MERCAPTOTETRAZOL-1ACETIC ACID S1 0449 TORPEDOES, LIQUID FUELLED with or without bursting charge S1 0450 TORPEDOES, LIQUID FUELLED with inert head S1 0451 TORPEDOES with bursting charge S1 0452 GRENADES, PRACTICE, hand or rifle S1 0453 ROCKETS, LINE-THROWING S1 0454 IGNITERS S1 0455 DETONATORS, NON-ELECTRIC for blasting S1 0456 DETONATORS, ELECTRIC for blasting S1 0457 CHARGES, BURSTING, PLASTICS BONDED S1 0458 CHARGES, BURSTING, PLASTICS BONDED S1 0459 CHARGES, BURSTING, PLASTICS BONDED S1 0460 CHARGES, BURSTING, PLASTICS BONDED S1 0461 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. S1 0462 ARTICLES, EXPLOSIVE, N.O.S. S1 0463 ARTICLES, EXPLOSIVE, N.O.S. S1 0464 ARTICLES, EXPLOSIVE, N.O.S. S1 0465 ARTICLES, EXPLOSIVE, N.O.S. S1 0466 ARTICLES, EXPLOSIVE, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.2D 0468 ARTICLES, EXPLOSIVE, N.O.S. 1 0469 ARTICLES, EXPLOSIVE, N.O.S. 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0467 ARTICLES, EXPLOSIVE, N.O.S. Packaging 5.2.2 (5) 1 3.3 (6) 178 274 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P101 1.2E 1 178 274 0 E0 P101 MP2 1 1.2F 1 178 274 0 E0 P101 MP2 0470 ARTICLES, EXPLOSIVE, N.O.S. 1 1.3C 1 178 274 0 E0 P101 MP2 0471 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4E 1.4 178 274 0 E0 P101 MP2 0472 ARTICLES, EXPLOSIVE, N.O.S. 1 1.4F 1.4 178 274 0 E0 P101 MP2 0473 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1A 1 178 274 0 E0 P101 MP2 0474 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1C 1 178 274 0 E0 P101 MP2 0475 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1D 1 178 274 0 E0 P101 MP2 0476 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1G 1 178 274 0 E0 P101 MP2 0477 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.3C 1 178 274 0 E0 P101 MP2 0478 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.3G 1 178 274 0 E0 P101 MP2 0479 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.4C 1.4 178 274 0 E0 P101 MP2 0480 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.4D 1.4 178 274 0 E0 P101 MP2 0481 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.4S 1.4 178 274 0 E0 P101 MP2 0482 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI), N.O.S. 0483 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX), DESENSITIZED 1 1.5D 1.5 178 274 0 E0 P101 MP2 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0484 CYCLOTETRAMETHYLENETETRA-NITRAMINE (HMX; OCTOGEN), DESENSITIZED 0485 SUBSTANCES, EXPLOSIVE, N.O.S. 1 1.1D 1 0 E0 P112(b) P112(c) MP20 1 1.4G 1.4 0 E0 P101 MP2 0486 ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI) 0487 SIGNALS, SMOKE 1 1.6N 1.6 0 E0 P101 MP23 1 1.3G 1 0 E0 P135 MP23 0488 AMMUNITION, PRACTICE 1 1.3G 1 0 E0 P130 LP101 0489 DINITROGLYCOLURIL (DINGU) 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0490 NITROTRIAZOLONE (NTO) 1 1.1D 1 0 E0 P112(b) P112(c) MP20 0491 CHARGES, PROPELLING 1 1.4C 1.4 0 E0 P143 178 274 - 306 - 4.1.4 (9a) PP67 L1 PP76 4.1.10 (9b) MP2 MP23 MP22 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (B1000C) 7.2.4 (16) V2 7.3.3 (17) 8.5 (19) S1 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 2 (E) V2 2 (E) V2 0 (B) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (B1000C) V2 V3 1 (C5000D) V2 V3 1 (C5000D) V2 V3 2 (E) V2 2 (E) V2 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 4 (E) 1 (B1000C) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 2 (E) V2 V3 2 (E) V2 1 (C5000D) V2 1 (C5000D) V2 1 (B1000C) V2 V3 1 (B1000C) V2 V3 2 (E) V2 - 307 - 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 0467 ARTICLES, EXPLOSIVE, N.O.S. S1 0468 ARTICLES, EXPLOSIVE, N.O.S. S1 0469 ARTICLES, EXPLOSIVE, N.O.S. S1 0470 ARTICLES, EXPLOSIVE, N.O.S. S1 0471 ARTICLES, EXPLOSIVE, N.O.S. S1 0472 ARTICLES, EXPLOSIVE, N.O.S. S1 0473 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0474 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0475 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0476 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0477 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0478 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0479 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0480 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0481 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0482 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI), N.O.S. 0483 CYCLOTRIMETHYLENETRINITRAMINE (CYCLONITE; HEXOGEN; RDX), DESENSITIZED S1 S1 S1 0484 CYCLOTETRAMETHYLENETETRA-NITRAMINE (HMX; OCTOGEN), DESENSITIZED 0485 SUBSTANCES, EXPLOSIVE, N.O.S. S1 0486 ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI) 0487 SIGNALS, SMOKE S1 0488 AMMUNITION, PRACTICE S1 0489 DINITROGLYCOLURIL (DINGU) S1 0490 NITROTRIAZOLONE (NTO) S1 0491 CHARGES, PROPELLING UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 1 2.2 (3b) 1.3G 0493 SIGNALS, RAILWAY TRACK, EXPLOSIVE 1 1.4G 0494 JET PERFORATING GUNS, CHARGED, oil well, without detonator 0495 PROPELLANT, LIQUID 1 2.1.1.3 (4) 5.2.2 (5) 1 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 0492 SIGNALS, RAILWAY TRACK, EXPLOSIVE Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P135 1.4 0 E0 P135 MP23 1.4D 1.4 0 E0 P101 MP21 1 1.3C 1 0 E0 P115 0496 OCTONAL 1 1.1D 1 0 E0 P112(b) P112(c) 0497 PROPELLANT, LIQUID 1 1.1C 1 0 E0 P115 0498 PROPELLANT, SOLID 1 1.1C 1 0 E0 P114(b) MP20 0499 PROPELLANT, SOLID 1 1.3C 1 0 E0 P114(b) MP20 0500 DETONATOR ASSEMBLIES, NONELECTRIC for blasting 1 1.4S 1.4 0 E0 P131 MP23 0501 PROPELLANT, SOLID 1 1.4C 1.4 0 E0 P114(b) MP20 0502 ROCKETS with inert head 1 1.2C 1 0 E0 P130 LP101 0503 SAFETY DEVICES, PYROTECHNIC 1 1.4G 1.4 0 E0 P135 0504 1H-TETRAZOLE 1 1.1D 1 0 E0 P112(c) 0505 SIGNALS, DISTRESS, ship 1 1.4G 1.4 0 E0 P135 MP23 MP24 0506 SIGNALS, DISTRESS, ship 1 1.4S 1.4 0 E0 P135 MP23 MP24 0507 SIGNALS, SMOKE 1 1.4S 1.4 0 E0 P135 MP23 MP24 0508 1-HYDROXY-BENZOTRIAZOLE, ANHYDROUS, dry or wetted with less than 20% water, by mass 1 1.3C 1 0 E0 P114(b) PP48 PP50 MP20 0509 POWDER, SMOKELESS 1 1.4C 1.4 0 E0 P114(b) MP20 1001 ACETYLENE, DISSOLVED 2 4F 2.1 662 0 E0 P200 MP9 1002 AIR, COMPRESSED 2 1A 2.2 655 662 120 ml E1 P200 MP9 (M) 1003 AIR, REFRIGERATED LIQUID 2 3O 2.2 +5.1 0 E0 P203 MP9 T75 1005 AMMONIA, ANHYDROUS 2 2TC 2.3 +8 23 0 E0 P200 MP9 (M) T50 1006 ARGON, COMPRESSED 2 1A 2.2 653 662 120 ml E1 P200 MP9 (M) 1008 BORON TRIFLUORIDE 2 2TC 2.3 +8 373 0 E0 P200 MP9 (M) 1009 BROMOTRIFLUORO-METHANE (REFRIGERANT GAS R 13B1) 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 224 224 347 235 289 - 308 - 4.1.4 (9a) PP53 PP54 PP57 PP58 4.1.10 (9b) MP23 4.2.5.2 (10) 4.2.5.3 (11) MP20 MP20 PP53 PP54 PP57 PP58 PP67 L1 MP20 MP22 MP23 PP48 PP48 MP20 TP5 TP22 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (C5000D) 7.2.4 (16) V2 7.3.3 (17) 8.5 (19) S1 2 (E) V2 2 (E) V2 1 (C5000D) V2 7.5.11 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 1 (B1000C) V2 V3 1 (B1000C) V2 CV1 CV2 CV3 CV1 CV2 CV3 1 (B1000C) V2 1 (C5000D) V2 4 (E) 2 (E) V2 1 (B1000C) 2 (E) V2 V2 1 (B1000C) V2 V3 2 (E) V2 4 (E) 4 (E) PxBN(M) CxBN(M) RxBN PxBH(M) TU17 TA4 TT9 TA4 TT9 TU7 TU19 TA4 TT9 TA4 TT8 TT9 1 (C5000D) V2 V3 2 (E) V2 FL 2 (B/D) AT 3 (E) 3 (C/E) AT AT 1 (C/D) CxBN(M) TA4 TT9 AT 3 (E) PxBH(M) TA4 TT9 TT10 TA4 TT9 AT 1 (C/D) AT 3 (C/E) PxBN(M) Hazard UN No. identification No. Operation V5 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV9 CV10 CV36 CV9 CV10 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 - 309 - 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 0492 SIGNALS, RAILWAY TRACK, EXPLOSIVE S1 0493 SIGNALS, RAILWAY TRACK, EXPLOSIVE S1 S1 0494 JET PERFORATING GUNS, CHARGED, oil well, without detonator 0495 PROPELLANT, LIQUID S1 0496 OCTONAL S1 0497 PROPELLANT, LIQUID S1 0498 PROPELLANT, SOLID S1 0499 PROPELLANT, SOLID S1 0500 DETONATOR ASSEMBLIES, NONELECTRIC for blasting S1 0501 PROPELLANT, SOLID S1 0502 ROCKETS with inert head S1 0503 SAFETY DEVICES, PYROTECHNIC S1 0504 1H-TETRAZOLE S1 0505 SIGNALS, DISTRESS, ship S1 0506 SIGNALS, DISTRESS, ship S1 0507 SIGNALS, SMOKE S1 0508 1-HYDROXY-BENZOTRIAZOLE, ANHYDROUS, dry or wetted with less than 20% water, by mass S1 0509 POWDER, SMOKELESS S2 239 1001 ACETYLENE, DISSOLVED 20 1002 AIR, COMPRESSED S20 225 1003 AIR, REFRIGERATED LIQUID S14 268 1005 AMMONIA, ANHYDROUS 20 1006 ARGON, COMPRESSED 268 1008 BORON TRIFLUORIDE 20 1009 BROMOTRIFLUORO-METHANE (REFRIGERANT GAS R 13B1) S14 UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 2F 2 1012 BUTYLENES MIXTURE or 1-BUTYLENE or cis-2-BUTYLENE or trans-2-BUTYLENE 1013 CARBON DIOXIDE 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1010 BUTADIENES, STABILIZED or BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 Mpa (11 bar) and a density at 50 °C not lower than 0.525 kg/l 1011 BUTANE Packaging 5.2.2 (5) 2.1 3.3 (6) 618 662 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P200 2F 2.1 0 E0 2 2F 2.1 652 657 660 662 662 0 2 2A 2.2 4.1.10 (9b) MP9 4.2.5.2 (10) (M) T50 P200 MP9 (M) T50 E0 P200 MP9 (M) T50 120 ml E1 P200 MP9 (M) 1016 CARBON MONOXIDE, COMPRESSED 2 1TF 2.3 +2.1 0 E0 P200 MP9 (M) 1017 CHLORINE 2 2TOC 0 E0 P200 MP9 (M) T50 2A 2.3 +5.1 +8 2.2 1018 CHLORODIFLUORO-METHANE (REFRIGERANT GAS R 22) 2 662 120 ml E1 P200 MP9 (M) T50 1020 CHLOROPENTAFLUOROETHANE (REFRIGERANT GAS R 115) 1021 1-CHLORO-1,2,2,2TETRAFLUOROETHANE (REFRIGERANT GAS R 124) 1022 CHLOROTRIFLUORO-METHANE (REFRIGERANT GAS R 13) 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 2 2A 2.2 662 120 ml E1 P200 MP9 (M) 1023 COAL GAS, COMPRESSED 2 1TF 2.3 +2.1 0 E0 P200 MP9 (M) 1026 CYANOGEN 2 2TF 2.3 +2.1 0 E0 P200 MP9 (M) 1027 CYCLOPROPANE 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1028 DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) 1029 DICHLOROFLUORO-METHANE (REFRIGERANT GAS R 21) 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 1030 1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152a) 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1032 DIMETHYLAMINE, ANHYDROUS 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1033 DIMETHYL ETHER 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1035 ETHANE 2 2F 2.1 662 0 E0 P200 MP9 (M) 1036 ETHYLAMINE 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1037 ETHYL CHLORIDE 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1038 ETHYLENE, REFRIGERATED LIQUID 2 3F 2.1 0 E0 P203 MP9 T75 1039 ETHYL METHYL ETHER 2 2F 2.1 0 E0 P200 MP9 (M) 584 653 662 662 - 310 - 4.1.4 (9a) 4.2.5.3 (11) TP19 TP5 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) PxBN(M) 4.3.5, 6.8.4 (13) TA4 TT9 9.1.1.2 (14) FL 1.1.3.6 (15) 2 (B/D) PxBN(M) TA4 TT9 TT11 FL PxBN(M) TA4 TT9 PxBN(M) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV9 CV10 CV36 8.5 (19) S2 S20 5.3.2.3 (20) 239 2 (B/D) CV9 CV10 CV36 S2 S20 23 FL 2 (B/D) CV9 CV10 CV36 S2 S20 23 TA4 TT9 AT 3 (C/E) CxBH(M) TA4 TT9 FL 1 (B/D) P22DH(M) TA4 TT9 TT10 TA4 TT9 AT 1 (C/D) AT 3 (C/E) CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 PxBN(M) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 AT 3 (C/E) CxBH(M) TA4 TT9 FL 1 (B/D) PxBH(M) TA4 TT9 FL 1 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) RxBN TU18 TA4 TT9 TA4 TT9 FL 2 (B/D) FL 2 (B/D) PxBN(M) V5 - 311 - 20 Name and description 3.1.2 (1) (2) 1010 BUTADIENES, STABILIZED or BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 Mpa (11 bar) and a density at 50 °C not lower than 0.525 kg/l 1011 BUTANE 1012 BUTYLENES MIXTURE or 1-BUTYLENE or cis-2-BUTYLENE or trans-2-BUTYLENE 1013 CARBON DIOXIDE S2 S14 263 1016 CARBON MONOXIDE, COMPRESSED S14 265 1017 CHLORINE 20 1018 CHLORODIFLUORO-METHANE (REFRIGERANT GAS R 22) 20 1020 CHLOROPENTAFLUOROETHANE (REFRIGERANT GAS R 115) 1021 1-CHLORO-1,2,2,2TETRAFLUOROETHANE (REFRIGERANT GAS R 124) 1022 CHLOROTRIFLUORO-METHANE (REFRIGERANT GAS R 13) 20 20 S2 S14 263 1023 COAL GAS, COMPRESSED S2 S14 263 1026 CYANOGEN S2 S20 23 1027 CYCLOPROPANE 20 1028 DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) 1029 DICHLOROFLUORO-METHANE (REFRIGERANT GAS R 21) 20 S2 S20 23 1030 1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152a) S2 S20 23 1032 DIMETHYLAMINE, ANHYDROUS S2 S20 23 1033 DIMETHYL ETHER S2 S20 23 1035 ETHANE S2 S20 23 1036 ETHYLAMINE S2 S20 23 1037 ETHYL CHLORIDE S2 S17 223 1038 ETHYLENE, REFRIGERATED LIQUID S2 S20 23 1039 ETHYL METHYL ETHER UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 2TF 1040 ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50 °C 1041 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide 1043 FERTILIZER AMMONIATING SOLUTION with free ammonia 1044 FIRE EXTINGUISHERS with compressed or liquefied gas 1045 FLUORINE, COMPRESSED 2 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1040 ETHYLENE OXIDE Packaging 5.2.2 (5) 2.3 +2.1 3.3 (6) 342 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P200 2TF 2.3 +2.1 342 0 E0 2 2F 2.1 662 0 2 4A 2.2 642 2 6A 2.2 225 594 2 1TOC 1046 HELIUM, COMPRESSED 2 1A 2.3 +5.1 +8 2.2 4.1.10 (9b) MP9 4.2.5.2 (10) (M) 4.2.5.3 (11) P200 MP9 (M) T50 TP20 E0 P200 MP9 (M) T50 120 ml E0 P003 0 E0 P200 MP9 120 ml E1 P200 MP9 (M) 1048 HYDROGEN BROMIDE, ANHYDROUS 2 2TC 2.3 +8 0 E0 P200 MP9 (M) 1049 HYDROGEN, COMPRESSED 2 1F 2.1 0 E0 P200 MP9 (M) 1050 HYDROGEN CHLORIDE, ANHYDROUS 2 2TC 2.3 +8 0 E0 P200 MP9 (M) 1051 HYDROGEN CYANIDE, STABILIZED containing less than 3% water 1052 HYDROGEN FLUORIDE, ANHYDROUS 6.1 TF1 I 6.1 +3 0 E0 P200 MP2 8 CT1 I 8 +6.1 0 E0 P200 MP2 T10 1053 HYDROGEN SULPHIDE 2 2TF 2.3 +2.1 0 E0 P200 MP9 (M) 1055 ISOBUTYLENE 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1056 KRYPTON, COMPRESSED 2 1A 2.2 662 120 ml E1 P200 MP9 (M) 1057 LIGHTERS or LIGHTER REFILLS containing flammable gas 2 6F 2.1 0 E0 P002 1058 LIQUEFIED GASES, nonflammable, charged with nitrogen, carbon dioxide or air 1060 METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED such as mixture P1 or mixture P2 1061 METHYLAMINE, ANHYDROUS 2 2A 2.2 201 654 658 662 120 ml E1 P200 MP9 (M) 2 2F 2.1 581 662 0 E0 P200 MP9 (M) T50 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1062 METHYL BROMIDE with not more than 2% chloropicrin 2 2T 2.3 23 0 E0 P200 MP9 (M) T50 1063 METHYL CHLORIDE (REFRIGERANT GAS R 40) 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1064 METHYL MERCAPTAN 2 2TF 2.3 +2.1 0 E0 P200 MP9 (M) T50 1065 NEON, COMPRESSED 2 1A 2.2 662 120 ml E1 P200 MP9 (M) 1066 NITROGEN, COMPRESSED 2 1A 2.2 653 662 120 ml E1 P200 MP9 (M) 1067 DINITROGEN TETROXIDE (NITROGEN DIOXIDE) 2 2TOC 2.3 +5.1 +8 0 E0 P200 MP9 T50 653 662 660 662 603 - 312 - 4.1.4 (9a) PP91 PP84 RR5 MP9 TP2 MP9 TP21 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) 9.1.1.2 (14) FL 1.1.3.6 (15) 1 (B/D) PxBH(M) TA4 TT9 FL 1 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) (E) 3 (E) 1 (D) CxBN(M) TA4 TT9 AT 3 (E) PxBH(M) TA4 TT9 TT10 TA4 TT9 AT 1 (C/D) FL 2 (B/D) TA4 TT9 TT10 AT 1 (C/D) CxBN(M) PxBH(M) 0 (D) L21DH(+) PxDH(M) PxBN(M) CxBN(M) TU14 TU34 TC1 TE21 TA4 TT9 TM3 TA4 TT9 TT10 TA4 TT9 AT 1 (C/D) FL 1 (B/D) FL 2 (B/D) TA4 TT9 AT 3 (E) 2 (D) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBH(M) TA4 TT9 AT 1 (C/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxDH(M) TA4 TT9 FL 1 (B/D) CxBN(M) TA4 TT9 AT 3 (E) CxBN(M) TA4 TT9 AT 3 (E) PxBH(M) TU17 TA4 TT9 AT 1 (C/D) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 Hazard UN No. identification No. Operation 8.5 (19) S2 S14 5.3.2.3 (20) 263 3.1.2 (1) (2) 1040 ETHYLENE OXIDE S2 S14 263 S2 S20 239 1040 ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50 °C 1041 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide 1043 FERTILIZER AMMONIATING SOLUTION with free ammonia 1044 FIRE EXTINGUISHERS with compressed or liquefied gas 1045 FLUORINE, COMPRESSED CV9 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV1 CV13 CV28 CV13 CV28 CV34 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 - 313 - Name and description S14 20 1046 HELIUM, COMPRESSED S14 268 1048 HYDROGEN BROMIDE, ANHYDROUS S2 S20 23 1049 HYDROGEN, COMPRESSED S14 268 1050 HYDROGEN CHLORIDE, ANHYDROUS S2 S9 S10 S14 1051 HYDROGEN CYANIDE, STABILIZED containing less than 3% water 1052 HYDROGEN FLUORIDE, ANHYDROUS S14 886 S2 S14 263 1053 HYDROGEN SULPHIDE S2 S20 23 1055 ISOBUTYLENE 20 1056 KRYPTON, COMPRESSED S2 1057 LIGHTERS or LIGHTER REFILLS containing flammable gas 20 1058 LIQUEFIED GASES, nonflammable, charged with nitrogen, carbon dioxide or air 1060 METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED such as mixture P1 or mixture P2 1061 METHYLAMINE, ANHYDROUS S2 S20 239 S2 S20 23 S14 26 1062 METHYL BROMIDE with not more than 2% chloropicrin S2 S20 23 1063 METHYL CHLORIDE (REFRIGERANT GAS R 40) S2 S14 263 1064 METHYL MERCAPTAN 20 1065 NEON, COMPRESSED 20 1066 NITROGEN, COMPRESSED 265 1067 DINITROGEN TETROXIDE (NITROGEN DIOXIDE) S14 UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 2TC 1070 NITROUS OXIDE 2 1071 OIL GAS, COMPRESSED 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1069 NITROSYL CHLORIDE Packaging 5.2.2 (5) 2.3 +8 3.3 (6) 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P200 2O 2.2 +5.1 584 662 0 E0 2 1TF 2.3 +2.1 0 1072 OXYGEN, COMPRESSED 2 1O 2.2 +5.1 4.1.10 (9b) MP9 4.2.5.2 (10) P200 MP9 (M) E0 P200 MP9 (M) 0 E0 P200 MP9 (M) 1073 OXYGEN, REFRIGERATED LIQUID 2 3O 2.2 +5.1 0 E0 P203 MP9 T75 1075 PETROLEUM GASES, LIQUEFIED 2 2F 2.1 0 E0 P200 MP9 (M) T50 1076 PHOSGENE 2 2TC 2.3 +8 0 E0 P200 MP9 1077 PROPYLENE 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1078 REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 1079 SULPHUR DIOXIDE 2 2A 2.2 274 582 662 120 ml E1 P200 MP9 (M) T50 2 2TC 2.3 +8 0 E0 P200 MP9 (M) T50 1080 SULPHUR HEXAFLUORIDE 2 2A 2.2 662 120 ml E1 P200 MP9 (M) 1081 TETRAFLUOROETHYLENE, STABILIZED 2 2F 2.1 662 0 E0 P200 MP9 (M) 1082 TRIFLUOROCHLOROETHYLENE, STABILIZED (REFRIGERANT GAS R 1113) 1083 TRIMETHYLAMINE, ANHYDROUS 2 2TF 2.3 +2.1 0 E0 P200 MP9 (M) T50 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1085 VINYL BROMIDE, STABILIZED 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1086 VINYL CHLORIDE, STABILIZED 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1087 VINYL METHYL ETHER, STABILIZED 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 1088 ACETAL 3 F1 II 3 1L E2 MP19 T4 TP1 1089 ACETALDEHYDE 3 F1 I 3 0 E0 P001 IBC02 R001 P001 T11 1090 ACETONE 3 F1 II 3 1L E2 TP2 TP7 TP1 1091 ACETONE OILS 3 F1 II 3 1L E2 MP19 T4 TP1 TP8 1092 ACROLEIN, STABILIZED 6.1 TF1 I 6.1 +3 0 E0 P001 IBC02 R001 P001 IBC02 R001 P601 MP7 MP17 MP19 MP8 MP17 T22 TP2 TP7 TP35 1093 ACRYLONITRILE, STABILIZED 3 FT1 I 0 E0 P001 TP2 6.1 TF1 I 0 E0 P602 MP7 MP17 MP8 MP17 T14 1098 ALLYL ALCOHOL 3 +6.1 6.1 +3 T20 TP2 TP35 1099 ALLYL BROMIDE 3 FT1 I 0 E0 P001 T14 TP2 1100 ALLYL CHLORIDE 3 FT1 I 0 E0 P001 T14 TP2 355 655 662 274 583 639 660 662 354 354 3 +6.1 3 +6.1 - 314 - 4.1.4 (9a) MP7 MP17 MP7 MP17 T4 4.2.5.3 (11) TP5 TP22 TP19 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) 9.1.1.2 (14) 1.1.3.6 (15) 1 (D) PxBN(M) TA4 TT9 AT 3 (C/E) CxBH(M) TA4 TT9 FL 1 (B/D) CxBN(M) TA4 TT9 AT 3 (E) RxBN TU7 TU19 TA4 TT9 TA4 TT9 TT11 AT 3 (C/E) FL 2 (B/D) TU17 TA4 TT9 TA4 TT9 AT 1 (C/D) FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) PxDH(M) TA4 TT9 TT10 TA4 TT9 AT 1 (C/D) AT 3 (C/E) TU40 TA4 TT9 TA4 TT9 FL 2 (B/D) FL 1 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) FL FL PxBN(M) P22DH(M) PxBN(M) PxBN(M) PxBN(M) PxBH(M) LGBF L4BN TU8 7.3.3 (17) 7.5.11 (18) CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 V5 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 8.5 (19) S14 5.3.2.3 (20) 3.1.2 (1) (2) 1069 NITROSYL CHLORIDE 25 1070 NITROUS OXIDE 263 1071 OIL GAS, COMPRESSED 25 1072 OXYGEN, COMPRESSED S20 225 1073 OXYGEN, REFRIGERATED LIQUID S2 S20 23 1075 PETROLEUM GASES, LIQUEFIED S14 268 1076 PHOSGENE S2 S20 23 1077 PROPYLENE 20 268 1078 REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 1079 SULPHUR DIOXIDE 20 1080 SULPHUR HEXAFLUORIDE S2 S14 S14 S2 S20 1081 TETRAFLUOROETHYLENE, STABILIZED S2 S20 239 1085 VINYL BROMIDE, STABILIZED S2 S20 239 1086 VINYL CHLORIDE, STABILIZED S2 S20 239 1087 VINYL METHYL ETHER, STABILIZED 2 (D/E) S2 S20 33 1088 ACETAL 1 (D/E) 2 (D/E) S2 S20 33 1089 ACETALDEHYDE S2 S20 33 1090 ACETONE S2 S20 33 1091 ACETONE OILS S2 S9 S14 663 1092 ACROLEIN, STABILIZED S2 S22 336 1093 ACRYLONITRILE, STABILIZED S2 S9 S14 663 1098 ALLYL ALCOHOL S2 S22 336 1099 ALLYL BROMIDE S2 S22 336 1100 ALLYL CHLORIDE 2 (D/E) L15CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10CH TU14 TU15 TE21 TU14 TU15 TE19 TE21 FL 1 (C/E) 1 (C/D) TU14 TU15 TE21 TU14 TU15 TE21 FL FL 7.2.4 (16) 23 FL L10CH Loading, unloading and handling S2 S20 LGBF L10CH Bulk Name and description 239 263 FL FL Packages Hazard UN No. identification No. Operation S2 S14 LGBF L10CH Special provisions for carriage 1 (C/E) 1 (C/E) CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 - 315 - 1082 TRIFLUOROCHLOROETHYLENE, STABILIZED (REFRIGERANT GAS R 1113) 1083 TRIMETHYLAMINE, ANHYDROUS UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) III 5.2.2 (5) 3 1105 PENTANOLS 3 F1 II 1105 PENTANOLS 3 F1 1106 AMYLAMINE 3 1106 AMYLAMINE 3.3 (6) 3.4 (7a) 5L 3.5.1.2 (7b) E1 3 1L E2 III 3 5L E1 FC II 1L E2 3 FC III 3 +8 3 +8 5L E1 1107 AMYL CHLORIDE 3 F1 II 3 1L E2 1108 1-PENTENE (n-AMYLENE) 3 F1 I 3 0 E3 1109 AMYL FORMATES 3 F1 III 3 5L E1 1110 n-AMYL METHYL KETONE 3 F1 III 3 5L E1 1111 AMYL MERCAPTAN 3 F1 II 3 1L E2 1112 AMYL NITRATE 3 F1 III 3 5L E1 1113 AMYL NITRITE 3 F1 II 3 1L E2 1114 BENZENE 3 F1 II 3 1L E2 1120 BUTANOLS 3 F1 II 3 1L E2 1120 BUTANOLS 3 F1 III 3 5L E1 1123 BUTYL ACETATES 3 F1 II 3 1L E2 1123 BUTYL ACETATES 3 F1 III 3 5L E1 1125 n-BUTYLAMINE 3 FC II 1L E2 1126 1-BROMOBUTANE 3 F1 II 3 +8 3 1L E2 1127 CHLOROBUTANES 3 F1 II 3 1L E2 1128 n-BUTYL FORMATE 3 F1 II 3 1L E2 1129 BUTYRALDEHYDE 3 F1 II 3 1L E2 1130 CAMPHOR OIL 3 F1 III 3 5L E1 1131 CARBON DISULPHIDE 3 FT1 I 3 +6.1 0 E0 - 316 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1104 AMYL ACETATES Packaging 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 R001 P001 IBC02 R001 P001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 4.1.4 (9a) PP31 4.1.10 (9b) MP19 4.2.5.2 (10) T2 4.2.5.3 (11) TP1 MP19 T4 TP1 TP29 MP19 T2 TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T4 TP1 MP7 MP17 MP19 T11 TP2 T2 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 TP29 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP7 MP17 T14 TP2 TP7 ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) L4BH FL L4BN FL 2 (D/E) 3 (D/E) LGBF FL L4BN FL LGBF FL LGBF FL 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL LGBF Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 5.3.2.3 (20) 30 S2 S20 33 1105 PENTANOLS S2 30 1105 PENTANOLS S2 S20 338 1106 AMYLAMINE S2 38 1106 AMYLAMINE 2 (D/E) S2 S20 33 1107 AMYL CHLORIDE 1 (D/E) 3 (D/E) S2 S20 33 1108 1-PENTENE (n-AMYLENE) V12 S2 30 1109 AMYL FORMATES V12 S2 30 1110 n-AMYL METHYL KETONE S2 S20 33 1111 AMYL MERCAPTAN S2 30 1112 AMYL NITRATE 2 (D/E) S2 S20 33 1113 AMYL NITRITE FL 2 (D/E) S2 S20 33 1114 BENZENE LGBF FL 2 (D/E) S2 S20 33 1120 BUTANOLS LGBF FL 3 (D/E) S2 30 1120 BUTANOLS LGBF FL 2 (D/E) S2 S20 33 1123 BUTYL ACETATES LGBF FL 3 (D/E) S2 30 1123 BUTYL ACETATES L4BH FL S2 S20 338 1125 n-BUTYLAMINE LGBF FL 2 (D/E) 2 (D/E) S2 S20 33 1126 1-BROMOBUTANE LGBF FL 2 (D/E) S2 S20 33 1127 CHLOROBUTANES LGBF FL 2 (D/E) S2 S20 33 1128 n-BUTYL FORMATE LGBF FL 2 (D/E) S2 S20 33 1129 BUTYRALDEHYDE LGBF FL 3 (D/E) S2 30 1130 CAMPHOR OIL FL 1 (C/E) S2 S22 336 1131 CARBON DISULPHIDE L10CH TU2 TU14 TU15 TE21 V12 V12 V12 V12 V12 V12 CV13 CV28 - 317 - 3.1.2 (1) (2) 1104 AMYL ACETATES UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1133 ADHESIVES containing flammable liquid 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) I 5.2.2 (5) 3 3.3 (6) 3.4 (7a) 500 ml 3.5.1.2 (7b) E3 4.1.4 (8) P001 4.1.4 (9a) 4.1.10 (9b) MP7 MP17 4.2.5.2 (10) T11 1133 ADHESIVES containing flammable liquid (vapour pressure at 50 °C more than 110 kPa) 1133 ADHESIVES containing flammable liquid (vapour pressure at 50 °C not more than 110 kPa) 3 F1 II 3 640C 5L E2 P001 PP1 MP19 T4 3 F1 II 3 640D 5L E2 P001 IBC02 R001 PP1 MP19 T4 TP1 TP8 1133 ADHESIVES containing flammable liquid 3 F1 III 3 640E 5L E1 PP1 MP19 T2 TP1 1133 ADHESIVES containing flammable liquid (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 F1 III 3 5L E1 P001 IBC03 LP01 R001 P001 R001 PP1 MP19 1133 ADHESIVES containing flammable liquid (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 III 3 5L E1 P001 IBC02 R001 PP1 BB4 MP19 1134 CHLOROBENZENE 3 F1 III 3 5L E1 MP19 T2 TP1 1135 ETHYLENE CHLOROHYDRIN 6.1 TF1 I 6.1 +3 0 E0 P001 IBC03 LP01 R001 P602 MP8 MP17 T20 TP2 TP37 1136 COAL TAR DISTILLATES, FLAMMABLE 3 F1 II 3 1L E2 MP19 T4 TP1 1136 COAL TAR DISTILLATES, FLAMMABLE 3 F1 III 3 5L E1 MP19 T4 TP1 TP29 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (vapour pressure at 50 °C more than 110 kPa) 3 F1 I 3 500 ml E3 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 MP7 MP17 T11 TP1 TP8 TP27 3 F1 II 3 640C 5L E2 P001 MP19 T4 TP1 TP8 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 II 3 640D 5L E2 P001 IBC02 R001 MP19 T4 TP1 TP8 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 F1 III 3 640E 5L E1 P001 IBC03 LP01 R001 MP19 T2 TP1 3 F1 III 3 5L E1 P001 R001 MP19 354 - 318 - 4.2.5.3 (11) TP1 TP8 TP27 TP1 TP8 ADR tank Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 1 (D/E) L1.5BN FL LGBF LGBF LGBF Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 S20 5.3.2.3 (20) 33 3.1.2 (1) (2) 1133 ADHESIVES containing flammable liquid 2 (D/E) S2 S20 33 FL 2 (D/E) S2 S20 33 1133 ADHESIVES containing flammable liquid (vapour pressure at 50 °C more than 110 kPa) 1133 ADHESIVES containing flammable liquid (vapour pressure at 50 °C not more than 110 kPa) FL 3 (D/E) S2 30 V12 1133 ADHESIVES containing flammable liquid 3 (E) S2 1133 ADHESIVES containing flammable liquid (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 (E) S2 1133 ADHESIVES containing flammable liquid (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) FL 3 (D/E) S2 30 1134 CHLOROBENZENE FL 1 (C/D) S2 S9 S14 663 1135 ETHYLENE CHLOROHYDRIN LGBF FL 2 (D/E) S2 S20 33 1136 COAL TAR DISTILLATES, FLAMMABLE LGBF FL 3 (D/E) S2 30 1136 COAL TAR DISTILLATES, FLAMMABLE L4BN FL 1 (D/E) S2 S20 33 FL 2 (D/E) S2 S20 33 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (vapour pressure at 50 °C more than 110 kPa) L1.5BN LGBF FL 2 (D/E) S2 S20 33 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (vapour pressure at 50 °C not more than 110 kPa) LGBF FL 3 (D/E) S2 30 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) L10CH TU14 TU15 TE19 TE21 V12 CV1 CV13 CV28 V12 V12 3 (E) S2 - 319 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) III 5.2.2 (5) 3 1143 CROTONALDEHYDE or CROTONALDEHYDE, STABILIZED 1144 CROTONYLENE 6.1 TF1 I 6.1 +3 3 F1 I 1145 CYCLOHEXANE 3 F1 1146 CYCLOPENTANE 3 1147 DECAHYDRO-NAPHTHALENE 3.3 (6) 324 354 3.4 (7a) 5L Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) Packaging 3.5.1.2 (7b) E1 4.1.4 (8) P001 IBC02 R001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) 4.2.5.3 (11) BB4 0 E0 P602 MP8 MP17 T20 TP2 TP35 3 0 E3 P001 T11 TP2 II 3 1L E2 T4 TP1 F1 II 3 1L E2 MP19 T7 TP1 3 F1 III 3 5L E1 MP19 T2 TP1 1148 DIACETONE ALCOHOL 3 F1 II 3 1L E2 MP19 T4 TP1 1148 DIACETONE ALCOHOL 3 F1 III 3 5L E1 MP19 T2 TP1 1149 DIBUTYL ETHERS 3 F1 III 3 5L E1 MP19 T2 TP1 1150 1,2-DICHLOROETHYLENE 3 F1 II 3 1L E2 MP19 T7 TP2 1152 DICHLOROPENTANES 3 F1 III 3 5L E1 MP19 T2 TP1 1153 ETHYLENE GLYCOL DIETHYL ETHER 3 F1 II 3 1L E2 MP19 T4 TP1 1153 ETHYLENE GLYCOL DIETHYL ETHER 3 F1 III 3 5L E1 MP19 T2 TP1 1154 DIETHYLAMINE 3 FC II 1L E2 MP19 T7 TP1 1155 DIETHYL ETHER (ETHYL ETHER) 1156 DIETHYL KETONE 3 F1 I 3 +8 3 0 E3 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 MP7 MP17 MP19 T11 TP2 3 F1 II 3 1L E2 T4 TP1 1157 DIISOBUTYL KETONE 3 F1 III 3 5L E1 MP19 T2 TP1 1158 DIISOPROPYLAMINE 3 FC II 1L E2 MP19 T7 TP1 1159 DIISOPROPYL ETHER 3 F1 II 3 +8 3 1L E2 MP19 T4 TP1 1160 DIMETHYLAMINE AQUEOUS SOLUTION 1161 DIMETHYL CARBONATE 3 FC II 1L E2 MP19 T7 TP1 3 F1 II 1L E2 MP19 T4 TP1 1162 DIMETHYLDICHLORO-SILANE 3 FC II 0 E0 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 R001 P001 IBC02 P001 IBC02 R001 P010 MP7 MP17 MP19 MP19 T10 1163 DIMETHYLHYDRAZINE, UNSYMMETRICAL 6.1 TFC I 0 E0 P602 MP8 MP17 T20 TP2 TP7 TP2 TP35 1164 DIMETHYL SULPHIDE 3 F1 II 1L E2 P001 IBC02 MP19 T7 3 +8 3 3 +8 6.1 +3 +8 3 354 - 320 - B8 TP2 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) 9.1.1.2 (14) 1.1.3.6 (15) 3 (E) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L4BN FL LGBF FL 1 (D/E) 2 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) L4BH FL L4BN FL LGBF FL 2 (D/E) 1 (D/E) 2 (D/E) LGBF FL 3 (D/E) L4BH FL LGBF FL 2 (D/E) 2 (D/E) L4BH FL LGBF FL L4BH FL L10CH L1.5BN TU14 TU15 TE19 TE21 FL FL Special provisions for carriage Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) 8.5 (19) S2 5.3.2.3 (20) 3.1.2 (1) (2) 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) CV1 CV13 CV28 S2 S9 S14 663 S2 S20 339 1143 CROTONALDEHYDE or CROTONALDEHYDE, STABILIZED 1144 CROTONYLENE S2 S20 33 1145 CYCLOHEXANE S2 S20 33 1146 CYCLOPENTANE S2 30 1147 DECAHYDRO-NAPHTHALENE S2 S20 33 1148 DIACETONE ALCOHOL V12 S2 30 1148 DIACETONE ALCOHOL V12 S2 30 1149 DIBUTYL ETHERS S2 S20 33 1150 1,2-DICHLOROETHYLENE S2 30 1152 DICHLOROPENTANES S2 S20 33 1153 ETHYLENE GLYCOL DIETHYL ETHER S2 30 1153 ETHYLENE GLYCOL DIETHYL ETHER S2 S20 338 1154 DIETHYLAMINE S2 S20 33 S2 S20 33 1155 DIETHYL ETHER (ETHYL ETHER) 1156 DIETHYL KETONE S2 30 1157 DIISOBUTYL KETONE S2 S20 338 1158 DIISOPROPYLAMINE S2 S20 33 1159 DIISOPROPYL ETHER S2 S20 338 S2 S20 33 1160 DIMETHYLAMINE AQUEOUS SOLUTION 1161 DIMETHYL CARBONATE S2 S20 X338 1162 DIMETHYLDICHLORO-SILANE S2 S9 S14 663 1163 DIMETHYLHYDRAZINE, UNSYMMETRICAL S2 S20 33 1164 DIMETHYL SULPHIDE V12 V12 V12 V12 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/D) Hazard UN No. identification No. Operation CV1 CV13 CV28 2 (D/E) - 321 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) II 5.2.2 (5) 3 3.4 (7a) 1L 3.5.1.2 (7b) E2 3 1L E2 I 3 0 E3 4.1.4 (8) P001 IBC02 R001 P001 IBC02 R001 P001 1166 DIOXOLANE 3 F1 II 1167 DIVINYL ETHER, STABILIZED 3 F1 1169 EXTRACTS, AROMATIC, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1169 EXTRACTS, AROMATIC, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1169 EXTRACTS, AROMATIC, LIQUID 3 F1 II 3 601 640C 5L E2 P001 3 F1 II 3 601 640D 5L E2 3 F1 III 3 601 640E 5L E1 1169 EXTRACTS, AROMATIC, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 F1 III 3 601 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 R001 1169 EXTRACTS, AROMATIC, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 III 3 601 5L E1 1170 ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) 1170 ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) 3 F1 II 3 144 601 1L E2 3 F1 III 3 144 601 5L E1 1171 ETHYLENE GLYCOL MONOETHYL ETHER 3 F1 III 3 5L E1 1172 ETHYLENE GLYCOL MONOETHYL ETHER ACETATE 3 F1 III 3 5L E1 1173 ETHYL ACETATE 3 F1 II 3 1L E2 1175 ETHYLBENZENE 3 F1 II 3 1L E2 1176 ETHYL BORATE 3 F1 II 3 1L E2 1177 2-ETHYLBUTYL ACETATE 3 F1 III 3 5L E1 1178 2-ETHYLBUTYRALDEHYDE 3 F1 II 3 1L E2 1179 ETHYL BUTYL ETHER 3 F1 II 3 1L E2 1180 ETHYL BUTYRATE 3 F1 III 3 5L E1 1181 ETHYL CHLOROACETATE 6.1 TF1 II 100 ml E4 1182 ETHYL CHLOROFORMATE 6.1 TFC I 0 E0 1183 ETHYLDICHLOROSILANE 4.3 WFC I 0 E0 P401 1184 ETHYLENE DICHLORIDE 3 FT1 II 6.1 +3 6.1 +3 +8 4.3 +3 +8 3 +6.1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P602 1L E2 P001 IBC02 (1) 1165 DIOXANE 3.3 (6) 354 - 322 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (2) Packaging P001 IBC02 R001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP19 T4 TP1 MP7 MP17 MP19 T11 TP2 T4 TP1 TP8 MP19 T4 TP1 TP8 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP15 T7 TP2 MP8 MP17 T20 TP2 TP37 MP2 T14 TP2 TP7 MP19 T7 TP1 MP19 MP19 BB4 RR7 ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 2 (D/E) LGBF FL L4BN FL L1.5BN FL LGBF FL 2 (D/E) LGBF FL 3 (D/E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 S20 5.3.2.3 (20) 33 (1) 1165 DIOXANE 2 (D/E) S2 S20 33 1166 DIOXOLANE 1 (D/E) 2 (D/E) S2 S20 339 1167 DIVINYL ETHER, STABILIZED S2 S20 33 S2 S20 33 S2 30 1169 EXTRACTS, AROMATIC, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1169 EXTRACTS, AROMATIC, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1169 EXTRACTS, AROMATIC, LIQUID V12 3.1.2 (2) 3 (E) S2 1169 EXTRACTS, AROMATIC, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 (E) S2 1169 EXTRACTS, AROMATIC, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) S2 S20 33 LGBF FL 2 (D/E) LGBF FL 3 (D/E) V12 S2 30 LGBF FL 3 (D/E) V12 S2 30 1171 ETHYLENE GLYCOL MONOETHYL ETHER LGBF FL 3 (D/E) V12 S2 30 1172 ETHYLENE GLYCOL MONOETHYL ETHER ACETATE LGBF FL 2 (D/E) S2 S20 33 1173 ETHYL ACETATE LGBF FL 2 (D/E) S2 S20 33 1175 ETHYLBENZENE LGBF FL 2 (D/E) S2 S20 33 1176 ETHYL BORATE LGBF FL 3 (D/E) S2 30 1177 2-ETHYLBUTYL ACETATE LGBF FL 2 (D/E) S2 S20 33 1178 2-ETHYLBUTYRALDEHYDE LGBF FL 2 (D/E) S2 S20 33 1179 ETHYL BUTYL ETHER LGBF FL 3 (D/E) S2 30 1180 ETHYL BUTYRATE 2 (D/E) 1 (C/D) CV13 CV28 CV1 CV13 CV28 CV23 S2 S9 S19 63 1181 ETHYL CHLOROACETATE S2 S9 S14 663 1182 ETHYL CHLOROFORMATE S2 S20 X338 1183 ETHYLDICHLOROSILANE CV13 CV28 S2 S19 336 1184 ETHYLENE DICHLORIDE L4BH TU15 TE19 FL L10CH TU14 TU15 TE19 TE21 FL L10DH TU14 TU23 TE21 TM2 TM3 TU15 FL 0 (B/E) FL 2 (D/E) L4BH V12 V12 V1 - 323 - 1170 ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) 1170 ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) TF1 2.1.1.3 (4) I 5.2.2 (5) 6.1 +3 1188 ETHYLENE GLYCOL MONOMETHYL ETHER 3 F1 III 1189 ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE 3 F1 1190 ETHYL FORMATE 3 1191 OCTYL ALDEHYDES 3.3 (6) 354 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1185 ETHYLENEIMINE, STABILIZED Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P601 3 5L E1 III 3 5L E1 F1 II 3 1L E2 3 F1 III 3 5L E1 1192 ETHYL LACTATE 3 F1 III 3 5L E1 1193 ETHYL METHYL KETONE (METHYL ETHYL KETONE) 3 F1 II 3 1L E2 1194 ETHYL NITRITE SOLUTION 3 FT1 I 0 E0 1195 ETHYL PROPIONATE 3 F1 II 3 +6.1 3 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 1L E2 1196 ETHYLTRICHLOROSILANE 3 FC II 0 1197 EXTRACTS, FLAVOURING, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1197 EXTRACTS, FLAVOURING, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1197 EXTRACTS, FLAVOURING, LIQUID 3 F1 II 3 +8 3 601 640C 3 F1 II 3 3 F1 III 1197 EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 1197 EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 3 F1 4.1.10 (9b) MP2 4.2.5.2 (10) T22 4.2.5.3 (11) TP2 MP19 T2 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T4 TP1 T4 TP1 E0 P001 IBC02 R001 P010 MP7 MP17 MP19 MP19 T10 5L E2 P001 MP19 T4 TP2 TP7 TP1 TP8 601 640D 5L E2 MP19 T4 TP1 TP8 3 601 640E 5L E1 MP19 T2 TP1 III 3 601 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 R001 III 3 601 5L E1 1198 FORMALDEHYDE SOLUTION, FLAMMABLE 3 FC III 3 +8 5L E1 MP19 T4 TP1 1199 FURALDEHYDES 6.1 TF1 II 100 ml E4 1201 FUSEL OIL 3 F1 II 6.1 +3 3 MP15 T7 TP2 1L E2 MP19 T4 TP1 1201 FUSEL OIL 3 F1 III 3 5L E1 MP19 T2 TP1 1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flash-point not more than 60 °C) 3 F1 III 3 363 640K 664 5L E1 MP19 T2 TP1 1202 DIESEL FUEL complying with standard EN 590:2004 or GAS OIL or HEATING OIL, LIGHT with a flashpoint as specified in EN 590:2009 + A1:2010 3 F1 III 3 363 640L 664 5L E1 MP19 T2 TP1 - 324 - P001 IBC02 R001 P001 IBC03 R001 P001 IBC02 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 4.1.4 (9a) MP19 MP19 BB4 ADR tank Tank code Special provisions 4.3 (12) L15CH 4.3.5, 6.8.4 (13) TU14 TU15 TE19 TE21 Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.3.3 (17) 7.5.11 (18) CV1 CV13 CV28 9.1.1.2 (14) FL 1.1.3.6 (15) 1 (C/D) 7.2.4 (16) LGBF FL 3 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) FL 1 (C/E) 2 (D/E) L10CH TU14 TU15 TE21 5.3.2.3 (20) 663 V12 S2 30 1188 ETHYLENE GLYCOL MONOMETHYL ETHER V12 S2 30 1189 ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE S2 S20 33 1190 ETHYL FORMATE V12 S2 30 1191 OCTYL ALDEHYDES V12 S2 30 1192 ETHYL LACTATE S2 S20 33 1193 ETHYL METHYL KETONE (METHYL ETHYL KETONE) S2 S22 336 1194 ETHYL NITRITE SOLUTION S2 S20 33 1195 ETHYL PROPIONATE 2 (D/E) 2 (D/E) S2 S20 X338 1196 ETHYLTRICHLOROSILANE S2 S20 33 S2 S20 33 S2 30 1197 EXTRACTS, FLAVOURING, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1197 EXTRACTS, FLAVOURING, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1197 EXTRACTS, FLAVOURING, LIQUID FL L4BH FL L1.5BN FL LGBF FL 2 (D/E) LGBF FL 3 (D/E) L4BH TU15 TE19 Name and description 8.5 (19) S2 S9 S14 LGBF L4BN Hazard UN No. identification No. Operation CV13 CV28 V12 3 (E) S2 3 (E) S2 FL 3 (D/E) FL 2 (D/E) 2 (D/E) V12 CV13 CV28 3.1.2 (1) (2) 1185 ETHYLENEIMINE, STABILIZED 1197 EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 1197 EXTRACTS, FLAVOURING, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) S2 38 1198 FORMALDEHYDE SOLUTION, FLAMMABLE S2 S9 S19 63 1199 FURALDEHYDES S2 S20 33 1201 FUSEL OIL LGBF FL LGBF FL 3 (D/E) V12 S2 30 1201 FUSEL OIL LGBF FL 3 (D/E) V12 S2 30 1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flash-point not more than 60 °C) LGBF AT 3 (D/E) V12 S2 30 1202 DIESEL FUEL complying with standard EN 590:2004 or GAS OIL or HEATING OIL, LIGHT with a flashpoint as specified in EN 590:2009 + A1:2010 - 325 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flash-point more than 60 °C and not more than 100 °C) 1203 MOTOR SPIRIT or GASOLINE or PETROL 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) III 5.2.2 (5) 3 3.3 (6) 363 640M 664 3.4 (7a) 5L 3.5.1.2 (7b) E1 3 F1 II 3 1L E2 1204 NITROGLYCERIN SOLUTION IN ALCOHOL with not more than 1% nitroglycerin 1206 HEPTANES 3 D II 3 243 534 363 664 601 3 F1 II 1207 HEXALDEHYDE 3 F1 1208 HEXANES 3 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (vapour pressure at 50 °C more than 110 kPa) 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (vapour pressure at 50 °C not more than 110 kPa) 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC02 R001 4.1.4 (9a) PP5 4.1.10 (9b) MP19 4.2.5.2 (10) T2 4.2.5.3 (11) TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP7 MP17 T11 TP1 TP8 BB2 1L E0 P001 IBC02 3 1L E2 III 3 5L E1 F1 II 3 1L E2 3 F1 I 3 163 367 500 ml E3 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 3 F1 II 3 163 367 640C 5L E2 P001 PP1 MP19 T4 TP1 TP8 3 F1 II 3 163 367 640D 5L E2 P001 IBC02 R001 PP1 MP19 T4 TP1 TP8 3 F1 III 3 163 367 640E 5L E1 P001 IBC03 LP01 R001 PP1 MP19 T2 TP1 3 F1 III 3 163 367 5L E1 P001 R001 PP1 MP19 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 III 3 163 367 5L E1 P001 IBC02 R001 PP1 BB4 MP19 1212 ISOBUTANOL (ISOBUTYL ALCOHOL) 3 F1 III 3 5L E1 MP19 T2 TP1 1213 ISOBUTYL ACETATE 3 F1 II 3 1L E2 MP19 T4 TP1 1214 ISOBUTYLAMINE 3 FC II 1L E2 MP19 T7 TP1 1216 ISOOCTENES 3 F1 II 3 +8 3 1L E2 MP19 T4 TP1 1218 ISOPRENE, STABILIZED 3 F1 I 3 0 E3 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 P001 IBC02 R001 P001 MP7 MP17 T11 TP2 - 326 - MP2 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) LGBV 4.3.5, 6.8.4 (13) 9.1.1.2 (14) AT 1.1.3.6 (15) 3 (D/E) LGBF TU9 FL Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation Name and description 8.5 (19) 5.3.2.3 (20) 30 3.1.2 (1) (2) 1202 GAS OIL or DIESEL FUEL or HEATING OIL, LIGHT (flash-point more than 60 °C and not more than 100 °C) 1203 MOTOR SPIRIT or GASOLINE or PETROL 2 (D/E) S2 S20 33 2 (B) S2 S14 S2 S20 33 1204 NITROGLYCERIN SOLUTION IN ALCOHOL with not more than 1% nitroglycerin 1206 HEPTANES S2 30 1207 HEXALDEHYDE LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) S2 S20 33 1208 HEXANES L4BN FL 1 (D/E) S2 S20 33 L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (vapour pressure at 50 °C more than 110 kPa) 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (vapour pressure at 50 °C not more than 110 kPa) 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) V12 V12 3 (E) S2 3 (E) S2 LGBF FL 3 (D/E) LGBF FL L4BH FL LGBF FL L4BN FL V12 1210 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) S2 30 1212 ISOBUTANOL (ISOBUTYL ALCOHOL) 2 (D/E) S2 S20 33 1213 ISOBUTYL ACETATE 2 (D/E) 2 (D/E) S2 S20 338 1214 ISOBUTYLAMINE S2 S20 33 1216 ISOOCTENES S2 S20 339 1218 ISOPRENE, STABILIZED 1 (D/E) - 327 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) II 5.2.2 (5) 3 1220 ISOPROPYL ACETATE 3 F1 II 1221 ISOPROPYLAMINE 3 FC I 1222 ISOPROPYL NITRATE 3 F1 II 3.3 (6) 601 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1219 ISOPROPANOL (ISOPROPYL ALCOHOL) Packaging 3.4 (7a) 1L 3.5.1.2 (7b) E2 3 1L E2 3 +8 3 0 E0 1L E2 4.1.4 (8) P001 IBC02 R001 P001 IBC02 R001 P001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP19 T4 TP1 MP7 MP17 MP19 T11 TP2 MP19 T2 TP2 MP19 T7 MP19 T7 MP19 T4 TP1 TP8 TP28 TP1 TP8 TP28 TP1 TP29 MP19 T11 TP2 TP27 B7 1223 KEROSENE 3 F1 III 3 363 664 5L E1 1224 KETONES, LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 3 F1 II 3 274 640C 1L E2 1224 KETONES, LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1224 KETONES, LIQUID, N.O.S. 3 F1 II 3 274 640D 1L E2 3 F1 III 3 274 5L E1 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 FT1 II 3 +6.1 274 1L E0 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 FT1 III 3 +6.1 274 5L E1 P001 IBC03 R001 MP19 T7 TP1 TP28 1229 MESITYL OXIDE 3 F1 III 3 5L E1 MP19 T2 TP1 1230 METHANOL 3 FT1 II 1L E2 MP19 T7 TP2 1231 METHYL ACETATE 3 F1 II 3 +6.1 3 1L E2 MP19 T4 TP1 1233 METHYLAMYL ACETATE 3 F1 III 3 5L E1 MP19 T2 TP1 1234 METHYLAL 3 F1 II 3 1L E2 MP19 T7 TP2 MP19 T7 TP1 MP19 T4 TP1 MP8 MP17 T22 TP2 TP35 MP8 MP17 T22 TP2 TP35 MP2 T14 TP2 TP7 MP7 MP17 MP8 MP17 T11 TP2 T22 TP2 TP35 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 1L E2 1L E2 354 0 E0 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 P001 IBC02 R001 P602 354 0 E0 P602 0 E0 P401 0 E3 P001 0 E0 P602 1L E2 3 1L E2 3 1L E2 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 1235 METHYLAMINE, AQUEOUS SOLUTION 1237 METHYL BUTYRATE 3 FC II 3 F1 II 1238 METHYL CHLOROFORMATE 6.1 TFC I 1239 METHYL CHLORO-METHYL ETHER 6.1 TF1 I 1242 METHYLDICHLOROSILANE 4.3 WFC I 1243 METHYL FORMATE 3 F1 I 1244 METHYLHYDRAZINE 6.1 TFC I 1245 METHYL ISOBUTYL KETONE 3 F1 II 6.1 +3 +8 3 1246 METHYL ISOPROPENYL KETONE, STABILIZED 3 F1 II 1247 METHYL METHACRYLATE MONOMER, STABILIZED 3 F1 II 279 3 +8 3 6.1 +3 +8 6.1 +3 4.3 +3 +8 3 354 - 328 - B8 RR7 ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) LGBF L10CH TU14 TE21 Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 2 (D/E) FL FL Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) 5.3.2.3 (20) 33 2 (D/E) S2 S20 33 1220 ISOPROPYL ACETATE 1 (C/E) 2 (E) S2 S20 338 1221 ISOPROPYLAMINE FL 3 (D/E) L1.5BN FL LGBF LGBF S2 S20 V12 1223 KEROSENE 2 (D/E) S2 S20 33 1224 KETONES, LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) FL 2 (D/E) S2 S20 33 FL 3 (D/E) S2 30 1224 KETONES, LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1224 KETONES, LIQUID, N.O.S. CV13 CV28 S2 S19 336 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. CV13 CV28 S2 36 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. S2 30 1229 MESITYL OXIDE S2 S19 336 1230 METHANOL S2 S20 33 1231 METHYL ACETATE S2 30 1233 METHYLAMYL ACETATE S2 S20 33 1234 METHYLAL S2 S20 338 S2 S20 33 1235 METHYLAMINE, AQUEOUS SOLUTION 1237 METHYL BUTYRATE S2 S9 S14 663 1238 METHYL CHLOROFORMATE S2 S9 S14 663 1239 METHYL CHLORO-METHYL ETHER S2 S20 X338 1242 METHYLDICHLOROSILANE S2 S20 33 1243 METHYL FORMATE S2 S9 S14 663 1244 METHYLHYDRAZINE V12 FL 2 (D/E) L4BH TU15 FL 3 (D/E) V12 FL 3 (D/E) V12 FL 2 (D/E) 2 (D/E) LGBF FL LGBF FL 3 (D/E) L1.5BN FL L4BH FL LGBF FL 2 (D/E) 2 (D/E) 2 (D/E) L15CH TU14 TU15 TE19 TE21 FL 1 (C/D) L15CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10DH TU14 TU24 TE21 TM2 TM3 FL 0 (B/E) FL 1 (D/E) 1 (C/D) L4BN L15CH TU14 TU15 TE19 TE21 1222 ISOPROPYL NITRATE 30 TU15 TU15 3.1.2 (1) (2) 1219 ISOPROPANOL (ISOPROPYL ALCOHOL) S2 L4BH L4BH Name and description 8.5 (19) S2 S20 LGBF LGBF Hazard UN No. identification No. Operation FL CV13 CV28 V12 V1 CV1 CV13 CV28 CV1 CV13 CV28 CV23 CV1 CV13 CV28 LGBF FL 2 (D/E) S2 S20 33 1245 METHYL ISOBUTYL KETONE LGBF FL 2 (D/E) S2 S20 339 1246 METHYL ISOPROPENYL KETONE, STABILIZED LGBF FL 2 (D/E) S2 S20 339 1247 METHYL METHACRYLATE MONOMER, STABILIZED - 329 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) II 5.2.2 (5) 3 1249 METHYL PROPYL KETONE 3 F1 II 1250 METHYLTRICHLORO-SILANE 3 FC II 1251 METHYL VINYL KETONE, STABILIZED 6.1 TFC I 1259 NICKEL CARBONYL 6.1 TF1 I 1261 NITROMETHANE 3 F1 II 1262 OCTANES 3 F1 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) 3 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (vapour pressure at 50 °C more than 110 kPa) 3.3 (6) 3.4 (7a) 1L 3.5.1.2 (7b) E2 4.1.4 (9a) E0 4.1.4 (8) P001 IBC02 R001 P001 IBC02 R001 P010 3 1L E2 3 +8 6.1 +3 +8 6.1 +3 0 0 E0 P601 RR7 0 E0 P601 3 1L E0 RR2 II 3 1L E2 F1 I 3 163 367 650 500 ml E3 P001 R001 P001 IBC02 R001 P001 3 F1 II 3 163 367 640C 650 5L E2 P001 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 II 3 163 367 640D 650 5L E2 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) 3 F1 III 3 163 367 640E 650 5L 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 F1 III 3 163 367 650 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 III 3 163 367 650 1264 PARALDEHYDE 3 F1 III 3 354 - 330 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1248 METHYL PROPIONATE Packaging 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP19 T4 TP1 MP19 T10 MP8 MP17 T22 TP2 TP7 TP2 TP37 MP2 MP19 MP19 T4 TP1 MP7 MP17 T11 TP1 TP8 TP27 PP1 MP19 T4 TP1 TP8 TP28 P001 IBC02 R001 PP1 MP19 T4 TP1 TP8 TP28 E1 P001 IBC03 LP01 R001 PP1 MP19 T2 TP1 TP29 5L E1 P001 R001 PP1 MP19 5L E1 P001 IBC02 R001 PP1 BB4 MP19 5L E1 P001 IBC03 LP01 R001 T2 TP1 MP19 ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 2 (D/E) LGBF FL L4BH FL L15CH TU14 TU15 TE19 TE21 FL L15CH TU14 TU15 TU31 TE19 TE21 TM3 FL LGBF FL L4BN FL L1.5BN Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 S20 5.3.2.3 (20) 33 2 (D/E) S2 S20 33 1249 METHYL PROPYL KETONE 2 (D/E) 1 (C/D) S2 S20 X338 1250 METHYLTRICHLORO-SILANE S2 S9 S14 639 1251 METHYL VINYL KETONE, STABILIZED S2 S9 S14 663 1259 NICKEL CARBONYL CV1 CV13 CV28 CV1 CV13 CV28 1 (C/D) 2 (E) 2 (D/E) S2 S20 3.1.2 (1) (2) 1248 METHYL PROPIONATE 1261 NITROMETHANE S2 S20 33 1262 OCTANES 1 (D/E) S2 S20 33 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) FL 2 (D/E) S2 S20 33 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (vapour pressure at 50 °C more than 110 kPa) LGBF FL 2 (D/E) S2 S20 33 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (vapour pressure at 50 °C not more than 110 kPa) LGBF FL 3 (D/E) S2 30 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) LGBF FL V12 3 (E) S2 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 (E) S2 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 3 (D/E) V12 S2 - 331 - 30 1264 PARALDEHYDE UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) I 5.2.2 (5) 3 1265 PENTANES, liquid 3 F1 II 3 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1265 PENTANES, liquid Packaging 3.4 (7a) 0 3.5.1.2 (7b) E3 4.1.4 (8) P001 1L E2 P001 IBC02 P001 4.1.4 (9a) 4.1.10 (9b) MP7 MP17 MP19 4.2.5.2 (10) T11 4.2.5.3 (11) TP2 T4 TP1 MP19 T4 TP1 TP8 B8 1266 PERFUMERY PRODUCTS with flammable solvents (vapour pressure at 50 °C more than 110 kPa) 3 F1 II 3 163 640C 5L E2 1266 PERFUMERY PRODUCTS with flammable solvents (vapour pressure at 50 °C not more than 110 kPa) 3 F1 II 3 163 640D 5L E2 P001 IBC02 R001 MP19 T4 TP1 TP8 1266 PERFUMERY PRODUCTS with flammable solvents 3 F1 III 3 163 640E 5L E1 MP19 T2 TP1 1266 PERFUMERY PRODUCTS with flammable solvents (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 1266 PERFUMERY PRODUCTS with flammable solvents (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1267 PETROLEUM CRUDE OIL 3 F1 III 3 163 5L E1 P001 IBC03 LP01 R001 P001 R001 3 F1 III 3 163 5L E1 MP7 MP17 MP19 T11 TP1 TP8 TP1 TP8 P001 IBC02 R001 MP19 MP19 BB4 3 F1 I 3 357 500 ml E3 P001 1267 PETROLEUM CRUDE OIL (vapour pressure at 50 °C more than 110 kPa) 3 F1 II 3 357 640C 1L E2 P001 1267 PETROLEUM CRUDE OIL (vapour pressure at 50 °C not more than 110 kPa) 1267 PETROLEUM CRUDE OIL 3 F1 II 3 357 640D 1L E2 MP19 T4 TP1 TP8 3 F1 III 3 357 5L E1 MP19 T2 TP1 3 F1 I 3 363 664 500 ml E3 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 MP7 MP17 T11 TP1 TP8 3 F1 II 3 363 640C 664 1L E2 P001 MP19 T7 TP1 TP8 TP28 3 F1 II 3 363 640D 664 1L E2 P001 IBC02 R001 MP19 T7 TP1 TP8 TP28 3 F1 III 3 363 664 5L E1 MP19 T4 TP1 TP29 1272 PINE OIL 3 F1 III 3 5L E1 MP19 T2 TP1 1274 n-PROPANOL (PROPYL ALCOHOL, NORMAL) 3 F1 II 3 1L E2 MP19 T4 TP1 1274 n-PROPANOL (PROPYL ALCOHOL, NORMAL) 3 F1 III 3 5L E1 MP19 T2 TP1 1275 PROPIONALDEHYDE 3 F1 II 3 1L E2 MP19 T7 TP1 1276 n-PROPYL ACETATE 3 F1 II 3 1L E2 MP19 T4 TP1 1277 PROPYLAMINE 3 FC II 1L E2 MP19 T7 TP1 1278 1-CHLOROPROPANE 3 F1 II 3 +8 3 1L E0 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 P001 IBC02 MP19 T7 TP2 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. - 332 - B8 T4 ADR tank Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) FL Transport category (Tunnel restriction code) 1.1.3.6 (15) 1 (D/E) 2 (D/E) 2 (D/E) L1.5BN FL L1.5BN FL LGBF FL 2 (D/E) LGBF FL 3 (D/E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) V12 Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 S20 5.3.2.3 (20) 33 3.1.2 (1) (2) 1265 PENTANES, liquid S2 S20 33 1265 PENTANES, liquid S2 S20 33 1266 PERFUMERY PRODUCTS with flammable solvents (vapour pressure at 50 °C more than 110 kPa) S2 S20 33 1266 PERFUMERY PRODUCTS with flammable solvents (vapour pressure at 50 °C not more than 110 kPa) S2 30 1266 PERFUMERY PRODUCTS with flammable solvents 3 (E) S2 1266 PERFUMERY PRODUCTS with flammable solvents (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 1266 PERFUMERY PRODUCTS with flammable solvents (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1267 PETROLEUM CRUDE OIL 3 (E) S2 1 (D/E) 2 (D/E) S2 S20 33 S2 S20 33 1267 PETROLEUM CRUDE OIL (vapour pressure at 50 °C more than 110 kPa) S2 S20 33 S2 30 1267 PETROLEUM CRUDE OIL (vapour pressure at 50 °C not more than 110 kPa) 1267 PETROLEUM CRUDE OIL L4BN FL L1.5BN FL LGBF FL 2 (D/E) LGBF FL 3 (D/E) L4BN FL 1 (D/E) S2 S20 33 L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) V12 S2 30 LGBF FL 3 (D/E) V12 S2 30 1272 PINE OIL LGBF FL 2 (D/E) S2 S20 33 1274 n-PROPANOL (PROPYL ALCOHOL, NORMAL) LGBF FL 3 (D/E) S2 30 1274 n-PROPANOL (PROPYL ALCOHOL, NORMAL) LGBF FL 2 (D/E) S2 S20 33 1275 PROPIONALDEHYDE LGBF FL 2 (D/E) S2 S20 33 1276 n-PROPYL ACETATE L4BH FL S2 S20 338 1277 PROPYLAMINE L1.5BN FL 2 (D/E) 2 (D/E) S2 S20 33 1278 1-CHLOROPROPANE V12 V12 - 333 - 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1268 PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) II 5.2.2 (5) 3 1280 PROPYLENE OXIDE 3 F1 I 1281 PROPYL FORMATES 3 F1 1282 PYRIDINE 3 1286 ROSIN OIL (vapour pressure at 50 °C more than 110 kPa) 1286 ROSIN OIL (vapour pressure at 50 °C not more than 110 kPa) 1286 ROSIN OIL 3.3 (6) 3.4 (7a) 1L 3.5.1.2 (7b) E2 3 0 E3 II 3 1L E2 F1 II 3 1L E2 3 F1 II 3 640C 5L E2 3 F1 II 3 640D 5L E2 3 F1 III 3 640E 5L E1 1286 ROSIN OIL (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 1286 ROSIN OIL (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 III 3 5L E1 3 F1 III 3 5L E1 IBC02 R001 1287 RUBBER SOLUTION (vapour pressure at 50 °C more than 110 kPa) 1287 RUBBER SOLUTION (vapour pressure at 50 °C not more than 110 kPa) 1287 RUBBER SOLUTION 3 F1 II 3 640C 5L E2 P001 3 F1 II 3 640D 5L E2 3 F1 III 3 640E 5L E1 1287 RUBBER SOLUTION (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 F1 III 3 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 R001 1287 RUBBER SOLUTION (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1288 SHALE OIL 3 F1 III 3 5L E1 3 F1 II 3 1L E2 1288 SHALE OIL 3 F1 III 3 5L E1 1289 SODIUM METHYLATE SOLUTION in alcohol 1289 SODIUM METHYLATE SOLUTION in alcohol 3 FC II 1L E2 3 FC III 3 +8 3 +8 5L E1 1292 TETRAETHYL SILICATE 3 F1 III 3 5L E1 1293 TINCTURES, MEDICINAL 3 F1 II 3 601 1L E2 1293 TINCTURES, MEDICINAL 3 F1 III 3 601 5L E1 1294 TOLUENE 3 F1 II 3 1L E2 1295 TRICHLOROSILANE 4.3 WFC I 4.3 +3 +8 0 E0 - 334 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1279 1,2-DICHLOROPROPANE Packaging 4.1.4 (8) P001 IBC02 R001 P001 4.1.4 (9a) P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 IBC03 LP01 R001 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P401 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP7 MP17 MP19 T11 T4 TP2 TP7 TP1 MP19 T4 TP2 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 TP8 MP19 T4 TP1 TP8 MP19 T2 TP1 MP19 T4 TP1 TP8 MP19 T2 TP1 MP19 T7 MP19 T4 TP1 TP8 TP1 MP19 T2 TP1 MP19 T4 TP1 TP8 MP19 T2 TP1 MP19 T4 TP1 MP2 T14 TP2 TP7 MP19 BB4 MP19 MP19 MP19 BB4 RR7 ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 2 (D/E) L4BN FL LGBF FL 1 (D/E) 2 (D/E) LGBF FL L1.5BN FL LGBF FL LGBF FL Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation 8.5 (19) S2 S20 5.3.2.3 (20) 33 S2 S20 33 1280 PROPYLENE OXIDE S2 S20 33 1281 PROPYL FORMATES 2 (D/E) S2 S20 33 1282 PYRIDINE 2 (D/E) 2 (D/E) 3 (D/E) S2 S20 33 S2 S20 33 S2 30 1286 ROSIN OIL (vapour pressure at 50 °C more than 110 kPa) 1286 ROSIN OIL (vapour pressure at 50 °C not more than 110 kPa) 1286 ROSIN OIL V12 3 (E) S2 3 (E) S2 FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1287 RUBBER SOLUTION (vapour pressure at 50 °C more than 110 kPa) 1287 RUBBER SOLUTION (vapour pressure at 50 °C not more than 110 kPa) 1287 RUBBER SOLUTION 3 (E) S2 1287 RUBBER SOLUTION (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 (E) S2 S2 S20 33 1287 RUBBER SOLUTION (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1288 SHALE OIL S2 30 1288 SHALE OIL S2 S20 338 S2 38 1289 SODIUM METHYLATE SOLUTION in alcohol 1289 SODIUM METHYLATE SOLUTION in alcohol S2 30 1292 TETRAETHYL SILICATE S2 S20 33 1293 TINCTURES, MEDICINAL S2 30 1293 TINCTURES, MEDICINAL S2 S20 33 1294 TOLUENE S2 S20 X338 1295 TRICHLOROSILANE LGBF FL 2 (D/E) LGBF FL 3 (D/E) L4BH FL L4BN FL 2 (D/E) 3 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) FL 0 (B/E) TU14 TU25 TE21 TM2 TM3 V12 3.1.2 (1) (2) 1279 1,2-DICHLOROPROPANE 1286 ROSIN OIL (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 1286 ROSIN OIL (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) L1.5BN L10DH Name and description V12 V12 V12 V1 CV23 - 335 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) FC 2.1.1.3 (4) II 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 3 FC I 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 3 FC II 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 3 FC 1298 TRIMETHYLCHLORO-SILANE 3 1299 TURPENTINE 5.2.2 (5) 3 +8 3 +8 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1296 TRIETHYLAMINE Packaging 3.4 (7a) 1L 3.5.1.2 (7b) E2 0 E0 3 +8 1L E2 III 3 +8 5L FC II 3 F1 III 3 +8 3 1300 TURPENTINE SUBSTITUTE 3 F1 II 1300 TURPENTINE SUBSTITUTE 3 F1 1301 VINYL ACETATE, STABILIZED 3 1302 VINYL ETHYL ETHER, STABILIZED 1303 VINYLIDENE CHLORIDE, STABILIZED 1304 VINYL ISOBUTYL ETHER, STABILIZED 4.1.10 (9b) MP19 4.2.5.2 (10) T7 4.2.5.3 (11) TP1 MP7 MP17 T11 TP1 P001 IBC02 MP19 T7 TP1 E1 P001 IBC03 R001 MP19 T7 TP1 0 E0 P010 MP19 T10 5L E1 MP19 T2 3 1L E2 MP19 T4 TP1 III 3 5L E1 MP19 T2 TP1 F1 II 3 1L E2 MP19 T4 TP1 3 F1 I 3 0 E3 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 TP2 TP7 TP1 T11 TP2 3 F1 I 3 0 E3 P001 T12 3 F1 II 3 1L E2 TP2 TP7 TP1 1305 VINYLTRICHLOROSILANE 3 FC II 0 E0 MP19 T10 1306 WOOD PRESERVATIVES, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1306 WOOD PRESERVATIVES, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1306 WOOD PRESERVATIVES, LIQUID 3 F1 II 3 +8 3 P001 IBC02 R001 P010 MP7 MP17 MP7 MP17 MP19 640C 5L E2 P001 MP19 T4 3 F1 II 3 640D 5L E2 MP19 T4 TP1 TP8 3 F1 III 3 640E 5L E1 MP19 T2 TP1 1306 WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 F1 III 3 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 R001 1306 WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 III 3 5L E1 1307 XYLENES 3 F1 II 3 1L E2 MP19 T4 TP1 1307 XYLENES 3 F1 III 3 5L E1 MP19 T2 TP1 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID (vapour pressure at 50 °C more than 110 kPa) 3 F1 I 3 0 E0 3 F1 II 3 640C 1L E2 P001 R001 PP33 MP7 MP17 MP19 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID (vapour pressure at 50 °C not more than 110 kPa) 3 F1 II 3 640D 1L E2 P001 R001 PP33 MP19 - 336 - 4.1.4 (8) P001 IBC02 P001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 4.1.4 (9a) T4 TP2 TP7 TP1 TP8 MP19 MP19 BB4 PP33 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) L4BH 4.3.5, 6.8.4 (13) 9.1.1.2 (14) FL L10CH TU14 TE21 FL Transport category (Tunnel restriction code) 1.1.3.6 (15) 2 (D/E) 1 (C/E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 S20 5.3.2.3 (20) 338 3.1.2 (1) (2) 1296 TRIETHYLAMINE S2 S20 338 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass S2 S20 338 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass S2 38 1297 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass S2 S20 X338 1298 TRIMETHYLCHLORO-SILANE S2 30 1299 TURPENTINE S2 S20 33 1300 TURPENTINE SUBSTITUTE S2 30 1300 TURPENTINE SUBSTITUTE L4BH FL 2 (D/E) L4BN FL 3 (D/E) L4BH FL LGBF FL 2 (D/E) 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) S2 S20 339 1301 VINYL ACETATE, STABILIZED L4BN FL S2 S20 339 L4BN FL S2 S20 339 LGBF FL 1 (D/E) 1 (D/E) 2 (D/E) S2 S20 339 1302 VINYL ETHYL ETHER, STABILIZED 1303 VINYLIDENE CHLORIDE, STABILIZED 1304 VINYL ISOBUTYL ETHER, STABILIZED L4BH FL S2 S20 X338 1305 VINYLTRICHLOROSILANE L1.5BN FL S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1306 WOOD PRESERVATIVES, LIQUID (vapour pressure at 50 °C more than 110 kPa) 1306 WOOD PRESERVATIVES, LIQUID (vapour pressure at 50 °C not more than 110 kPa) 1306 WOOD PRESERVATIVES, LIQUID V12 V12 V12 2 (D/E) 2 (D/E) V12 3 (E) S2 1306 WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 (E) S2 1306 WOOD PRESERVATIVES, LIQUID (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) S2 S20 33 1307 XYLENES S2 30 1307 XYLENES S2 S20 33 S2 S20 33 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID (vapour pressure at 50 °C more than 110 kPa) S2 S20 33 LGBF FL 2 (D/E) LGBF FL 3 (D/E) L4BN FL L1.5BN FL 1 (D/E) 2 (D/E) LGBF FL V12 2 (D/E) - 337 - 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID (vapour pressure at 50 °C not more than 110 kPa) UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) III 5.2.2 (5) 3 4.1 F3 II 1309 ALUMINIUM POWDER, COATED 4.1 F3 1310 AMMONIUM PICRATE, WETTED with not less than 10% water, by mass 1312 BORNEOL 4.1 4.1 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID 1309 ALUMINIUM POWDER, COATED Packaging 3.4 (7a) 5L 3.5.1.2 (7b) E1 4.1 1 kg E2 III 4.1 5 kg E1 D I 4.1 0 E0 F1 III 4.1 5 kg E1 4.1.4 (8) P001 R001 P002 IBC08 P002 IBC08 LP02 R001 P406 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) 4.2.5.3 (11) PP38 B4 PP11 B3 MP11 T3 TP33 MP11 T1 TP33 PP26 MP2 MP10 T1 TP33 MP11 T1 TP33 MP11 T1 TP33 MP11 T1 TP33 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP11 T3 TP33 MP10 T1 TP33 MP11 T1 TP33 T1 TP33 T1 BK1 BK2 TP33 MP11 T1 TP33 MP11 T3 TP33 1313 CALCIUM RESINATE 4.1 F3 III 4.1 5 kg E1 1314 CALCIUM RESINATE, FUSED 4.1 F3 III 4.1 5 kg E1 1318 COBALT RESINATE, PRECIPITATED 4.1 F3 III 4.1 5 kg E1 1320 DINITROPHENOL, WETTED with not less than 15% water, by mass 4.1 DT I 4.1 +6.1 0 E0 P002 IBC08 LP02 R001 P002 IBC06 R001 P002 IBC04 R001 P002 IBC06 R001 P406 1321 DINITROPHENOLATES, WETTED with not less than 15% water, by mass 1322 DINITRORESORCINOL, WETTED with not less than 15% water, by mass 1323 FERROCERIUM 4.1 DT I 4.1 +6.1 0 E0 P406 PP26 MP2 4.1 D I 4.1 0 E0 P406 PP26 MP2 4.1 F3 II 4.1 1 kg E2 P002 IBC08 P002 R001 B4 PP15 1324 FILMS, NITROCELLULOSE BASE, gelatin coated, except scrap 4.1 F1 III 4.1 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 4.1 F1 II 4.1 4.1 F1 III 1326 HAFNIUM POWDER, WETTED with not less than 25% water 1327 Hay, Straw or Bhusa 1328 HEXAMETHYLENETE-TRAMINE 4.1 F3 4.1 4.1 1330 MANGANESE RESINATE 249 5 kg E1 274 1 kg E2 4.1 274 5 kg II 4.1 586 1 kg F1 F1 III 4.1 5 kg 4.1 F3 III 4.1 5 kg 1331 MATCHES, 'STRIKE ANYWHERE' 4.1 F1 III 4.1 1332 METALDEHYDE 4.1 F1 III 4.1 293 5 kg 1334 NAPHTHALENE, CRUDE or NAPHTHALENE, REFINED 4.1 1336 NITROGUANIDINE (PICRITE), WETTED with not less than 20% water, by mass 1337 NITROSTARCH, WETTED with not less than 20% water, by mass 1338 PHOSPHORUS, AMORPHOUS 4.1 D I 4.1 0 E0 4.1 D I 4.1 0 E0 P406 4.1 F3 III 4.1 5 kg E1 P410 IBC08 R001 P410 IBC04 1339 PHOSPHORUS HEPTASULPHIDE, free from yellow and white phosphorus 4.1 4.1 F3 F1 F3 II III II 4.1 4.1 4.1 1 kg 501 602 - 338 - 5 kg 1 kg PP26 MP2 MP11 P002 IBC08 B4 E1 P002 IBC08 B3 LP02 R001 E2 P410 PP40 IBC06 NOT SUBJECT TO ADR E1 P002 IBC08 B3 R001 E1 P002 IBC06 R001 E0 P407 PP27 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P406 1333 CERIUM, slabs, ingots or rods 5 kg B3 E1 E2 E1 E2 MP11 MP12 MP10 B3 MP11 B4 MP10 B3 MP2 MP2 B3 ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) FL SGAN AT SGAV AT Transport category (Tunnel restriction code) 1.1.3.6 (15) 3 (D/E) 2 (E) 3 (E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation 8.5 (19) S2 V11 VC1 VC2 1 (B) 5.3.2.3 (20) 30 Name and description 40 3.1.2 (1) (2) 1308 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID 1309 ALUMINIUM POWDER, COATED 40 1309 ALUMINIUM POWDER, COATED S14 SGAV AT 3 (E) VC1 VC2 40 1310 AMMONIUM PICRATE, WETTED with not less than 10% water, by mass 1312 BORNEOL SGAV AT 3 (E) VC1 VC2 40 1313 CALCIUM RESINATE SGAV AT 3 (E) VC1 VC2 40 1314 CALCIUM RESINATE, FUSED SGAV AT 3 (E) VC1 VC2 40 1318 COBALT RESINATE, PRECIPITATED 1 (B) CV28 S14 1320 DINITROPHENOL, WETTED with not less than 15% water, by mass 1 (B) CV28 S14 1321 DINITROPHENOLATES, WETTED with not less than 15% water, by mass 1322 DINITRORESORCINOL, WETTED with not less than 15% water, by mass 1323 FERROCERIUM 1 (B) SGAN AT SGAN AT SGAV AT SGAN AT SGAV AT SGAV AT SGAV SGAV AT AT SGAV AT SGAN AT S14 2 (E) 3 (E) V11 2 (E) 3 (E) V11 40 1324 FILMS, NITROCELLULOSE BASE, gelatin coated, except scrap 40 VC1 VC2 40 2 V11 (E) NOT SUBJECT TO ADR 3 VC1 VC2 (E) 40 3 (E) VC1 VC2 4 (E) 3 (E) 2 (E) 3 (E) 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. 40 1326 HAFNIUM POWDER, WETTED with not less than 25% water 1327 Hay, Straw or Bhusa 1328 HEXAMETHYLENETE-TRAMINE 40 1330 MANGANESE RESINATE 1331 MATCHES, 'STRIKE ANYWHERE' VC1 VC2 40 V11 1332 METALDEHYDE 1333 CERIUM, slabs, ingots or rods VC1 VC2 AP1 40 1 (B) S14 1 (B) 3 (E) S14 VC1 VC2 40 2 (E) 40 - 339 - 1334 NAPHTHALENE, CRUDE or NAPHTHALENE, REFINED 1336 NITROGUANIDINE (PICRITE), WETTED with not less than 20% water, by mass 1337 NITROSTARCH, WETTED with not less than 20% water, by mass 1338 PHOSPHORUS, AMORPHOUS 1339 PHOSPHORUS HEPTASULPHIDE, free from yellow and white phosphorus UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 2.2 (1) (2) (3a) 1340 PHOSPHORUS PENTASULPHIDE, 4.3 free from yellow and white phosphorus 1341 PHOSPHORUS SESQUISULPHIDE, 4.1 free from yellow and white phosphorus 1343 PHOSPHORUS TRISULPHIDE, free 4.1 from yellow and white phosphorus 2.2 (3b) WF2 2.1.1.3 (4) II 5.2.2 (5) 4.3 +4.1 3.3 (6) 602 3.4 (7a) 500 g 3.5.1.2 (7b) E2 4.1.4 (8) P410 IBC04 F3 II 4.1 602 1 kg E2 F3 II 4.1 602 1 kg 1344 TRINITROPHENOL (PICRIC ACID), WETTED with not less than 30% water, by mass 1345 RUBBER SCRAP or RUBBER SHODDY, powdered or granulated 4.1 D I 4.1 4.1 F1 II 4.1 1346 SILICON POWDER, AMORPHOUS 4.1 F3 III 4.1 1347 SILVER PICRATE, WETTED with not less than 30% water, by mass 4.1 D I 1348 SODIUM DINITRO-oCRESOLATE, WETTED with not less than 15% water, by mass 1349 SODIUM PICRAMATE, WETTED with not less than 20% water, by mass 1350 SULPHUR 4.1 DT 4.1 4.1 32 Portable tanks and bulk containers 4.1.4 (9a) 4.1.10 (9b) MP14 4.2.5.2 (10) T3 4.2.5.3 (11) TP33 P410 IBC04 MP11 T3 TP33 E2 P410 IBC04 MP11 T3 TP33 0 E0 P406 PP26 1 kg E2 P002 IBC08 MP11 T3 TP33 B4 MP11 T1 TP33 MP11 T1 BK1 BK2 TP33 MP11 T3 TP33 T3 TP33 MP2 5 kg E1 4.1 0 E0 P002 IBC08 B3 LP02 R001 P406 PP25 PP26 I 4.1 +6.1 0 E0 P406 PP26 MP2 D I 4.1 0 E0 P406 PP26 MP2 F3 III 4.1 5 kg E1 P002 IBC08 LP02 R001 P410 IBC06 P410 IBC08 R001 242 1352 TITANIUM POWDER, WETTED with not less than 25% water 1353 FIBRES or FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 1354 TRINITROBENZENE, WETTED with not less than 30% water, by mass 1355 TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass 1356 TRINITROTOLUENE (TNT), WETTED with not less than 30% water, by mass 1357 UREA NITRATE, WETTED with not less than 20% water, by mass 1358 ZIRCONIUM POWDER, WETTED with not less than 25% water 4.1 F3 II 4.1 586 1 kg E2 4.1 F1 III 4.1 502 5 kg E1 MP2 B3 PP40 MP11 B3 4.1 D I 4.1 0 E0 P406 MP2 4.1 D I 4.1 0 E0 P406 MP2 4.1 D I 4.1 0 E0 P406 MP2 4.1 D I 4.1 227 0 E0 P406 MP2 4.1 F3 II 4.1 586 1 kg E2 P410 IBC06 1360 CALCIUM PHOSPHIDE 4.3 WT2 I 0 E0 P403 1361 CARBON, animal or vegetable origin 4.2 S2 II 4.3 +6.1 4.2 0 E0 1361 CARBON, animal or vegetable origin 4.2 S2 III 4.2 0 E0 1362 CARBON, ACTIVATED 4.2 S2 III 4.2 0 E1 1363 COPRA 4.2 S2 III 4.2 0 E0 1364 COTTON WASTE, OILY 4.2 S2 III 4.2 0 E0 1365 COTTON, WET 4.2 S2 III 4.2 0 E0 1369 p-NITROSODIMETHYL-ANILINE 4.2 S2 II 4.2 0 E2 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P003 IBC08 LP02 R001 P003 IBC08 LP02 R001 P003 IBC08 LP02 R001 P410 IBC06 646 - 340 - PP40 MP11 MP2 PP12 MP14 T3 TP33 PP12 B3 MP14 T1 TP33 PP11 B3 MP14 T1 TP33 PP20 B3 B6 MP14 PP19 B3 B6 MP14 PP19 B3 B6 MP14 T3 TP33 MP14 ADR tank Tank code Special provisions 4.3 (12) SGAN 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) V1 7.3.3 (17) 7.5.11 (18) CV23 Hazard UN No. identification No. Operation 9.1.1.2 (14) AT 1.1.3.6 (15) 0 (D/E) SGAN AT 2 (E) 40 SGAN AT 2 (E) 40 1 (B) SGAN AT 4 (E) SGAV AT 3 (E) V11 40 VC1 VC2 1 (B) 40 CV28 1 (B) AT 3 (E) SGAN AT 2 (E) 3 (E) SGAN SGAN AT TU11 AT SGAV AT SGAV AT SGAN AT 1348 SODIUM DINITRO-oCRESOLATE, WETTED with not less than 15% water, by mass 1349 SODIUM PICRAMATE, WETTED with not less than 20% water, by mass 1350 SULPHUR 40 V11 40 S14 1 (B) S14 1 (B) S14 1 (B) 2 (E) S14 V11 V1 V13 V1 V13 1346 SILICON POWDER, AMORPHOUS S14 VC1 VC2 40 CV23 CV28 1344 TRINITROPHENOL (PICRIC ACID), WETTED with not less than 30% water, by mass 1345 RUBBER SCRAP or RUBBER SHODDY, powdered or granulated 1347 SILVER PICRATE, WETTED with not less than 30% water, by mass S14 V1 3.1.2 (1) (2) 1340 PHOSPHORUS PENTASULPHIDE, free from yellow and white phosphorus 1341 PHOSPHORUS SESQUISULPHIDE, free from yellow and white phosphorus 1343 PHOSPHORUS TRISULPHIDE, free from yellow and white phosphorus S14 1 (B) 1 (E) 2 (D/E) 4 (E) 5.3.2.3 (20) 423 S14 1 (B) SGAV 8.5 (19) Name and description S20 1352 TITANIUM POWDER, WETTED with not less than 25% water 1353 FIBRES or FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 1354 TRINITROBENZENE, WETTED with not less than 30% water, by mass 1355 TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass 1356 TRINITROTOLUENE (TNT), WETTED with not less than 30% water, by mass 1357 UREA NITRATE, WETTED with not less than 20% water, by mass 1358 ZIRCONIUM POWDER, WETTED with not less than 25% water 1360 CALCIUM PHOSPHIDE 40 1361 CARBON, animal or vegetable origin VC1 VC2 AP1 40 1361 CARBON, animal or vegetable origin 4 (E) V1 VC1 VC2 AP1 40 1362 CARBON, ACTIVATED 3 (E) V1 VC1 VC2 AP1 40 1363 COPRA 3 (E) V1 VC1 VC2 AP1 40 1364 COTTON WASTE, OILY 3 (E) V1 VC1 VC2 AP1 40 1365 COTTON, WET 2 (D/E) V1 40 1369 p-NITROSODIMETHYL-ANILINE - 341 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3b) S2 2.1.1.3 (4) 5.2.2 (5) S2 III 4.2 1378 METAL CATALYST, WETTED with a visible excess of liquid 1379 PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper) 1380 PENTABORANE 4.2 S4 II 4.2 4.2 S2 III 4.2 3.3 (6) 3.4 (7a) 3.5.1.2 4.1.4 4.1.4 (7b) (8) (9a) NOT SUBJECT TO ADR 4.2.5.2 (10) 4.2.5.3 (11) MP14 T1 TP33 MP14 T3 TP33 MP14 T1 BK2 TP33 MP14 T3 TP33 0 E0 503 0 E0 P405 MP2 T9 TP3 TP31 4.2 +6.1 503 0 E0 P405 MP2 T9 TP3 TP31 II 4.2 504 0 E2 P410 IBC06 MP14 T3 TP33 S4 I 4.2 274 0 E0 P404 MP13 T21 4.2 S4 II 4.2 0 E2 MP14 T3 4.2 S4 II 4.2 0 E2 P410 IBC06 P410 IBC06 TP7 TP33 TP33 MP14 T3 TP33 4.2 S2 III 4.2 0 E0 4.2 4.3 S2 W1 I 4.3 182 0 4.3 W2 II 4.3 500 g E2 TP33 W1 I 4.3 0 E0 P410 IBC07 P402 T3 4.3 4.3 W1 I 4.3 0 E0 P402 MP2 4.3 W2 II 4.3 182 505 182 183 506 183 506 183 506 500 g E2 MP14 T3 TP33 4.3 W2 II 4.3 500 g E2 P410 IBC07 P410 IBC07 MP14 T3 TP33 1395 ALUMINIUM FERROSILICON POWDER 1396 ALUMINIUM POWDER, UNCOATED 1396 ALUMINIUM POWDER, UNCOATED 4.3 WT2 II 500 g E2 PP40 MP14 T3 TP33 4.3 W2 II 4.3 +6.1 4.3 500 g E2 PP40 MP14 T3 TP33 4.3 W2 III 4.3 1 kg E1 MP14 T1 TP33 1397 ALUMINIUM PHOSPHIDE 4.3 WT2 I 1398 ALUMINIUM SILICON POWDER, UNCOATED 4.3 W2 III MP14 T1 TP33 1400 BARIUM 4.3 W2 II 4.3 500 g E2 MP14 T3 TP33 1401 CALCIUM 4.3 W2 II 4.3 500 g E2 MP14 T3 TP33 1402 CALCIUM CARBIDE 4.3 W2 I 4.3 0 E0 MP2 T9 TP7 TP33 1402 CALCIUM CARBIDE 4.3 W2 II 4.3 500 g E2 MP14 T3 TP33 S4 II III 4.2 ST3 I 1381 PHOSPHORUS, WHITE or YELLOW, UNDER WATER or IN SOLUTION 1381 PHOSPHORUS, WHITE or YELLOW, DRY 4.2 ST3 I 4.2 ST4 I 1382 POTASSIUM SULPHIDE, ANHYDROUS or POTASSIUM SULPHIDE with less than 30% water of crystallization 1383 PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. 1384 SODIUM DITHIONITE (SODIUM HYDROSULPHITE) 1385 SODIUM SULPHIDE, ANHYDROUS or SODIUM SULPHIDE with less than 30% water of crystallization 1386 SEED CAKE with more than 1.5% oil and not more than 11% moisture 4.2 S4 4.2 1387 Wool waste, wet 1389 ALKALI METAL AMALGAM, LIQUID 1390 ALKALI METAL AMIDES 1391 ALKALI METAL DISPERSION or ALKALINE EARTH METAL DISPERSION 1392 ALKALINE EARTH METAL AMALGAM, LIQUID 1393 ALKALINE EARTH METAL ALLOY, N.O.S. 1394 ALUMINIUM CARBIDE 4.2 4.2 4.2 +6.1 4.2 +6.1 4.3 +6.1 4.3 300 592 274 504 0 0 E0 4.1.10 (9b) P410 IBC08 R001 P410 IBC08 P002 IBC08 LP02 R001 P410 IBC01 P410 IBC08 R001 P601 S2 0 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 2.2 (1) (2) (3a) 1372 Fibres, animal or fibres, vegetable 4.2 burnt, wet or damp 1373 FIBRES or FABRICS, ANIMAL or 4.2 VEGETABLE or SYNTHETIC, N.O.S. with oil 1374 FISH MEAL (FISH SCRAP), 4.2 UNSTABILIZED 1376 IRON OXIDE, SPENT or IRON 4.2 SPONGE, SPENT obtained from coal gas purification Packaging E2 E0 0 E0 0 E0 B4 B3 PP39 MP14 B3 MP2 P003 PP20 IBC08 B3 B6 LP02 R001 NOT SUBJECT TO ADR E0 P402 RR8 507 0 E0 37 1 kg E1 - 342 - B3 P410 IBC05 P410 IBC07 P410 IBC08 R001 P403 P410 IBC08 R001 P410 IBC07 P410 IBC07 P403 IBC04 P410 IBC07 MP14 MP2 MP14 RR8 MP2 B4 MP2 B4 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) AT 2 (D/E) 3 (E) V1 AT L10DH(+) SGAN AT AT AT SGAN AT SGAN AT SGAN AT SGAN AT SGAN AT SGAN AT SGAN AT SGAN AT S2.65AN(+) SGAN TU4 TU22 TM2 TA5 AT AT 40 VC1 VC2 AP1 40 46 CV28 S20 46 V1 TU1 TE5 TT3 TM2 40 S20 3 (E) L10BN(+) VC1 VC2 AP1 CV28 V1 AT 40 V1 0 (B/E) 2 (D/E) 2 (D/E) TU1 TE5 TT3 TM2 40 333 AT L10BN(+) VC1 VC2 AP1 5.3.2.3 (20) S20 V1 AT 8.5 (19) CV28 2 (D/E) AT 7.5.11 (18) V1 AT AT SGAN V1 V1 SGAN TU1 TE5 TT3 TM2 0 (B/E) 0 (B/E) Loading, unloading and handling Hazard UN No. identification No. Operation V1 0 (B/E) AT L10BN(+) 2 (D/E) 3 (E) V1 AT SGAN Bulk 1.1.3.6 7.2.4 7.3.3 (15) (16) (17) NOT SUBJECT TO ADR V1 SGAN L10DH(+) Packages 3 (E) AT TU14 TC1 TE21 TM1 TU14 TU16 TU21 TE3 TE21 TU14 TU16 TU21 TE3 TE21 Special provisions for carriage AT SGAV L21DH Transport category (Tunnel restriction code) 40 S20 43 V1 40 V1 40 VC1 VC2 AP1 NOT SUBJECT TO ADR 1 V1 (B/E) 0 V1 (D/E) 1 V1 (B/E) 40 CV23 S20 CV23 X323 423 CV23 S20 X323 S20 X323 1 (B/E) 2 (D/E) 2 (D/E) V1 CV23 V1 CV23 423 CV23 423 2 (D/E) 2 (D/E) 3 (E) V1 CV23 CV28 CV23 462 423 CV23 423 1 (E) 3 (E) V1 2 (D/E) 2 (D/E) 1 (B/E) V1 2 (D/E) V1 VC1 VC2 AP3 AP4 AP5 V1 V1 V1 VC2 AP4 AP5 S20 3.1.2 (1) (2) 1372 Fibres, animal or fibres, vegetable burnt, wet or damp 1373 FIBRES or FABRICS, ANIMAL or VEGETABLE or SYNTHETIC, N.O.S. with oil 1374 FISH MEAL (FISH SCRAP), UNSTABILIZED 1376 IRON OXIDE, SPENT or IRON SPONGE, SPENT obtained from coal gas purification 1378 METAL CATALYST, WETTED with a visible excess of liquid 1379 PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper) 1380 PENTABORANE 1381 PHOSPHORUS, WHITE or YELLOW, UNDER WATER or IN SOLUTION 1381 PHOSPHORUS, WHITE or YELLOW, DRY 1382 POTASSIUM SULPHIDE, ANHYDROUS or POTASSIUM SULPHIDE with less than 30% water of crystallization 1383 PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. 1384 SODIUM DITHIONITE (SODIUM HYDROSULPHITE) 1385 SODIUM SULPHIDE, ANHYDROUS or SODIUM SULPHIDE with less than 30% water of crystallization 1386 SEED CAKE with more than 1.5% oil and not more than 11% moisture 1387 Wool waste, wet 1389 ALKALI METAL AMALGAM, LIQUID 1390 ALKALI METAL AMIDES 1391 ALKALI METAL DISPERSION or ALKALINE EARTH METAL DISPERSION 1392 ALKALINE EARTH METAL AMALGAM, LIQUID 1393 ALKALINE EARTH METAL ALLOY, N.O.S. 1394 ALUMINIUM CARBIDE 1395 ALUMINIUM FERROSILICON POWDER 1396 ALUMINIUM POWDER, UNCOATED 1396 ALUMINIUM POWDER, UNCOATED 1397 ALUMINIUM PHOSPHIDE 423 1398 ALUMINIUM SILICON POWDER, UNCOATED CV23 423 1400 BARIUM V1 CV23 423 1401 CALCIUM V1 CV23 X423 1402 CALCIUM CARBIDE 423 1402 CALCIUM CARBIDE V1 VC2 AP4 AP5 CV23 CV28 CV23 Name and description VC1 VC2 AP3 AP4 AP5 CV23 - 343 - S20 UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 5.2.2 (5) 4.3 3.1.2 2.2 (1) (2) (3a) 1403 CALCIUM CYANAMIDE with more 4.3 than 0.1% calcium carbide 2.2 (3b) W2 1404 CALCIUM HYDRIDE 4.3 W2 I 4.3 0 E0 1405 CALCIUM SILICIDE 4.3 W2 II 4.3 500 g E2 P410 IBC07 1405 CALCIUM SILICIDE 4.3 W2 III 4.3 1 kg E1 P410 IBC08 R001 P403 IBC04 1407 CAESIUM 4.3 W2 I 4.3 1408 FERROSILICON with 30% or more but less than 90% silicon 4.3 WT2 III 4.3 +6.1 1409 METAL HYDRIDES, WATERREACTIVE, N.O.S. 1409 METAL HYDRIDES, WATERREACTIVE, N.O.S. 1410 LITHIUM ALUMINIUM HYDRIDE 4.3 W2 I 4.3 4.3 W2 II 4.3 4.3 W2 I 1411 LITHIUM ALUMINIUM HYDRIDE, 4.3 ETHEREAL 1413 LITHIUM BOROHYDRIDE 4.3 WF1 I W2 1414 LITHIUM HYDRIDE 4.3 1415 LITHIUM 3.3 (6) 38 3.4 (7a) 1 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 2.1.1.3 (4) III Packaging 3.5.1.2 (7b) E1 4.1.4 (8) P410 IBC08 R001 P403 4.1.4 (9a) 4.1.10 (9b) MP14 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP14 T3 TP33 MP14 T1 TP33 T1 BK2 TP33 T3 TP33 T3 TP33 MP14 T3 TP33 MP14 T1 TP33 T9 TP3 TP7 TP31 B4 MP2 B4 0 E0 39 1 kg E1 274 508 274 508 0 E0 500 g E2 4.3 0 E0 P410 IBC04 P403 0 E0 P402 I 4.3 +3 4.3 0 E0 P403 MP2 W2 I 4.3 0 E0 P403 MP2 4.3 W2 I 4.3 0 E0 MP2 1417 LITHIUM SILICON 4.3 W2 II 4.3 500 g E2 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 4.3 WS I 4.3 +4.2 0 E0 P403 IBC04 P410 IBC07 P403 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 4.3 WS II 4.3 +4.2 0 E2 P410 IBC05 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER 4.3 WS III 4.3 +4.2 0 E1 1419 MAGNESIUM ALUMINIUM PHOSPHIDE 1420 POTASSIUM METAL ALLOYS, LIQUID 1421 ALKALI METAL ALLOY, LIQUID, N.O.S. 1422 POTASSIUM SODIUM ALLOYS, LIQUID 1423 RUBIDIUM 4.3 WT2 I 0 E0 4.3 W1 I 4.3 +6.1 4.3 P410 IBC08 R001 P403 0 E0 P402 4.3 W1 I 4.3 0 E0 P402 4.3 W1 I 4.3 0 E0 P402 MP2 4.3 W2 I 4.3 0 E0 P403 IBC04 MP2 1426 SODIUM BOROHYDRIDE 4.3 W2 I 4.3 0 E0 P403 MP2 1427 SODIUM HYDRIDE 4.3 W2 I 4.3 0 E0 P403 MP2 1428 SODIUM 4.3 W2 I 4.3 0 E0 MP2 T9 1431 SODIUM METHYLATE 4.2 SC4 II 0 E2 MP14 T3 TP7 TP33 TP33 1432 SODIUM PHOSPHIDE 4.3 WT2 I 0 E0 1433 STANNIC PHOSPHIDES 4.3 WT2 I 0 E0 P403 MP2 1435 ZINC ASHES 4.3 W2 III 4.2 +8 4.3 +6.1 4.3 +6.1 4.3 P403 IBC04 P410 IBC05 P403 1 kg E1 P002 IBC08 R001 P403 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP11 T3 TP33 1436 ZINC POWDER or ZINC DUST 4.3 WS I 1436 ZINC POWDER or ZINC DUST 4.3 WS II 1436 ZINC POWDER or ZINC DUST 4.3 WS III 1437 ZIRCONIUM HYDRIDE 4.1 F3 II 182 4.3 +4.2 4.3 +4.2 4.3 +4.2 0 E0 0 E2 0 E1 4.1 1 kg - 344 - E2 P003 IBC08 R001 P403 P410 IBC07 P410 IBC08 R001 P410 IBC04 MP2 PP20 B4 B6 MP14 MP2 MP14 MP2 RR8 MP2 MP14 MP2 B4 MP2 MP2 RR8 MP2 MP2 MP14 B4 MP2 PP40 B4 PP40 ADR tank Tank code Special provisions 4.3 (12) SGAN 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) AT Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 0 (E) 7.2.4 (16) V1 7.3.3 (17) 7.5.11 (18) CV23 8.5 (19) 1 (E) 2 (D/E) V1 CV23 S20 1404 CALCIUM HYDRIDE AT SGAN AT 3 (E) V1 AT 1 (B/E) V1 AT 3 (E) V1 1 (E) 2 (D/E) 1 (E) 1 (E) 1 (E) 1 (E) 1 (B/E) 2 (D/E) 1 (E) V1 CV23 V1 CV23 V1 CV23 S20 V1 CV23 S2 S20 V1 CV23 S20 1411 LITHIUM ALUMINIUM HYDRIDE, ETHEREAL 1413 LITHIUM BOROHYDRIDE V1 CV23 S20 1414 LITHIUM HYDRIDE V1 CV23 S20 V1 CV23 V1 CV23 CV23 423 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER CV23 423 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER TU2 TU14 TE5 TE21 TT3 TM2 SGAN SGAN L10BN(+) AT TU1 TE5 TT3 TM2 SGAN AT AT SGAN AT 2 (D/E) V1 SGAN AT 3 (E) V1 1 (E) 1 (B/E) 1 (B/E) 1 (B/E) 1 (B/E) V1 L10BN(+) L10BN(+) L10BN(+) L10CH(+) L10BN(+) SGAN SGAN TU1 TE5 TT3 TM2 TU1 TE5 TT3 TM2 TU1 TE5 TT3 TM2 TU2 TU14 TE5 TE21 TT3 TM2 TU1 TE5 TT3 TM2 AT AT AT AT AT AT AT SGAN AT SGAN AT SGAN AT 1 (E) 1 (E) 1 (B/E) 2 (D/E) 1 (E) 1 (E) 3 (E) 1 (E) 2 (D/E) 3 (E) VC1 VC2 AP3 AP4 AP5 VC1 VC2 AP3 AP4 AP5 3.1.2 (1) (2) 1403 CALCIUM CYANAMIDE with more than 0.1% calcium carbide SGAN L10CH(+) V1 5.3.2.3 (20) 423 Name and description CV23 423 1405 CALCIUM SILICIDE CV23 423 1405 CALCIUM SILICIDE X423 1407 CAESIUM 462 1408 FERROSILICON with 30% or more but less than 90% silicon CV23 VC1 VC2 AP3 AP4 AP5 VC2 AP4 AP5 S20 CV23 CV28 S20 423 1409 METAL HYDRIDES, WATERREACTIVE, N.O.S. 1409 METAL HYDRIDES, WATERREACTIVE, N.O.S. 1410 LITHIUM ALUMINIUM HYDRIDE X423 1415 LITHIUM 423 1417 LITHIUM SILICON S20 1418 MAGNESIUM POWDER or MAGNESIUM ALLOYS POWDER V1 CV23 CV28 CV23 S20 S20 X323 V1 CV23 S20 X323 V1 CV23 S20 X323 V1 CV23 S20 X423 V1 CV23 S20 1426 SODIUM BOROHYDRIDE V1 CV23 S20 1427 SODIUM HYDRIDE V1 CV23 S20 V1 V1 1419 MAGNESIUM ALUMINIUM PHOSPHIDE 1420 POTASSIUM METAL ALLOYS, LIQUID 1421 ALKALI METAL ALLOY, LIQUID, N.O.S. 1422 POTASSIUM SODIUM ALLOYS, LIQUID 1423 RUBIDIUM X423 1428 SODIUM 48 1431 SODIUM METHYLATE CV23 CV28 CV23 CV28 CV23 S20 1432 SODIUM PHOSPHIDE S20 1433 STANNIC PHOSPHIDES V1 CV23 S20 V1 CV23 423 1436 ZINC POWDER or ZINC DUST CV23 423 1436 ZINC POWDER or ZINC DUST 40 1437 ZIRCONIUM HYDRIDE V1 V1 V1 VC1 VC2 AP3 AP4 AP5 VC2 AP4 AP5 2 (E) - 345 - 423 1435 ZINC ASHES 1436 ZINC POWDER or ZINC DUST UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 1439 AMMONIUM DICHROMATE 2.2 (3a) 5.1 5.1 2.2 (3b) O2 O2 2.1.1.3 (4) III II 5.2.2 (5) 5.1 5.1 1442 AMMONIUM PERCHLORATE 5.1 O2 II 5.1 1444 AMMONIUM PERSULPHATE 5.1 O2 III 5.1 1445 BARIUM CHLORATE, SOLID 5.1 OT2 II 1446 BARIUM NITRATE 5.1 OT2 II 1447 BARIUM PERCHLORATE, SOLID 5.1 OT2 II 1448 BARIUM PERMANGANATE 5.1 OT2 II 1449 BARIUM PEROXIDE 5.1 OT2 II 1450 BROMATES, INORGANIC, N.O.S. 5.1 O2 II 1451 CAESIUM NITRATE 1452 CALCIUM CHLORATE 1453 CALCIUM CHLORITE 1454 CALCIUM NITRATE 5.1 5.1 5.1 5.1 O2 O2 O2 O2 III II II III 3.3 (6) 5.1 +6.1 5.1 +6.1 5.1 +6.1 5.1 +6.1 5.1 +6.1 5.1 1 kg 152 274 350 5.1 5 kg E1 1 kg E2 1 kg E2 1 kg E2 1 kg E2 1 kg E2 1 kg E2 1 kg 208 E2 E2 1 kg 5.1 3.5.1.2 (7b) E1 1 kg 5 kg 5.1 5.1 3.4 (7a) 5 kg 5 kg E1 E2 E2 E1 1455 CALCIUM PERCHLORATE 5.1 O2 II 5.1 1 kg E2 1456 CALCIUM PERMANGANATE 5.1 O2 II 5.1 1 kg E2 1457 CALCIUM PEROXIDE 5.1 O2 II 5.1 1 kg E2 1458 CHLORATE AND BORATE MIXTURE 1458 CHLORATE AND BORATE MIXTURE 5.1 O2 II 5.1 1 kg E2 1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 5.1 1461 CHLORATES, INORGANIC, N.O.S. 5.1 O2 II 5.1 1462 CHLORITES, INORGANIC, N.O.S. 5.1 O2 II 5.1 1463 CHROMIUM TRIOXIDE, ANHYDROUS 5.1 OTC II 1465 DIDYMIUM NITRATE 5.1 5.1 +6.1 +8 5.1 1466 FERRIC NITRATE 1467 GUANIDINE NITRATE 1469 LEAD NITRATE 1470 LEAD PERCHLORATE, SOLID 5.1 5.1 5.1 5.1 5.1 5.1 O2 O2 O2 O2 O2 O2 OT2 OT2 III II III III III III II II 5.1 5 kg 5.1 1 kg 5.1 5 kg 274 351 274 352 509 510 5.1 E2 1 kg E2 1 kg 1 kg - 346 - E1 1 kg 5 kg 5.1 +6.1 5.1 +6.1 E2 E2 5 kg 5.1 E1 1 kg 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1438 ALUMINIUM NITRATE Packaging E1 E1 E1 E2 E2 4.1.4 (8) P002 IBC08 LP02 R001 P002 IBC08 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 P002 IBC06 P002 IBC06 P002 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC06 P002 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC06 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T1 BK1 BK2 4.2.5.3 (11) TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 BK1 BK2 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP10 T1 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 B3 B4 B3 B4 B4 B3 B4 B4 B3 B4 B3 B4 B3 B4 B3 B3 B3 B4 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) SGAV 4.3.5, 6.8.4 (13) TU3 9.1.1.2 (14) AT SGAN TU3 AT AT Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 3 (E) 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP6 AP7 7.5.11 (18) CV24 2 (E) 2 (E) 3 (E) V11 SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAN TU3 AT SGAN TU3 AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT 2 (E) SGAV TU3 AT 3 (E) SGAV TU3 AT SGAV TU3 SGAN SGAN 2 (E) 2 (E) 2 (E) 2 (E) 2 (E) 2 (E) 3 (E) 2 (E) 2 (E) 3 (E) 2 (E) 2 (E) 2 (E) 2 (E) 3 (E) V11 3.1.2 (1) (2) 1438 ALUMINIUM NITRATE 1439 AMMONIUM DICHROMATE 50 1442 AMMONIUM PERCHLORATE CV24 50 1444 AMMONIUM PERSULPHATE CV24 CV28 CV24 CV28 CV24 CV28 CV24 CV28 CV24 CV28 CV24 56 1445 BARIUM CHLORATE, SOLID 56 1446 BARIUM NITRATE 56 1447 BARIUM PERCHLORATE, SOLID 56 1448 BARIUM PERMANGANATE 56 1449 BARIUM PEROXIDE 50 1450 BROMATES, INORGANIC, N.O.S. CV24 50 1451 CAESIUM NITRATE CV24 50 1452 CALCIUM CHLORATE CV24 50 1453 CALCIUM CHLORITE VC1 VC2 AP6 AP7 CV24 50 1454 CALCIUM NITRATE VC1 VC2 AP6 AP7 CV24 50 1455 CALCIUM PERCHLORATE VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 V11 V11 V11 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 V11 V11 5.3.2.3 (20) 50 Name and description 50 V11 V11 8.5 (19) CV24 V11 V11 Hazard UN No. identification No. Operation CV24 S23 S23 S23 V11 CV24 50 1456 CALCIUM PERMANGANATE V11 CV24 50 1457 CALCIUM PEROXIDE CV24 50 CV24 50 1458 CHLORATE AND BORATE MIXTURE 1458 CHLORATE AND BORATE MIXTURE CV24 50 CV24 50 CV24 50 1461 CHLORATES, INORGANIC, N.O.S. V11 CV24 50 1462 CHLORITES, INORGANIC, N.O.S. V11 CV24 CV28 568 1463 CHROMIUM TRIOXIDE, ANHYDROUS VC1 VC2 AP6 AP7 CV24 50 1465 DIDYMIUM NITRATE 3 (E) VC1 VC2 AP6 AP7 CV24 50 1466 FERRIC NITRATE AT 3 (E) VC1 VC2 AP6 AP7 CV24 50 1467 GUANIDINE NITRATE TU3 AT 1469 LEAD NITRATE AT CV24 CV28 CV24 CV28 56 TU3 2 (E) 2 (E) 56 1470 LEAD PERCHLORATE, SOLID V11 2 (E) 3 (E) V11 2 (E) 2 (E) V11 V11 V11 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 - 347 - S23 1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 1459 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (1) (2) 1471 LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE 1471 LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE 2.2 (3a) 5.1 1472 LITHIUM PEROXIDE 5.1 O2 II 5.1 1 kg E2 1473 MAGNESIUM BROMATE 5.1 O2 II 5.1 1 kg E2 1474 MAGNESIUM NITRATE 5.1 5.1 O2 O2 2.1.1.3 (4) II III III 5.2.2 (5) 5.1 3.3 (6) 5.1 5.1 3.4 (7a) 1 kg 5 kg 332 5 kg 3.5.1.2 (7b) E2 E1 E1 1475 MAGNESIUM PERCHLORATE 5.1 O2 II 5.1 1 kg E2 1476 MAGNESIUM PEROXIDE 5.1 O2 II 5.1 1 kg E2 1477 NITRATES, INORGANIC, N.O.S. 5.1 O2 II 5.1 1 kg E2 1477 NITRATES, INORGANIC, N.O.S. 5.1 O2 III 5.1 511 511 5 kg E1 1479 OXIDIZING SOLID, N.O.S. 5.1 O2 I 5.1 274 0 E0 1479 OXIDIZING SOLID, N.O.S. 5.1 O2 II 5.1 274 1 kg E2 1479 OXIDIZING SOLID, N.O.S. 5.1 O2 III 5.1 274 5 kg E1 1481 PERCHLORATES, INORGANIC, N.O.S. 1481 PERCHLORATES, INORGANIC, N.O.S. 5.1 O2 II 5.1 1 kg E2 5.1 O2 III 5.1 5 kg E1 1482 PERMANGANATES, INORGANIC, N.O.S. 1482 PERMANGANATES, INORGANIC, N.O.S. 5.1 O2 II 5.1 5.1 O2 III 5.1 274 353 274 353 1 kg E2 5 kg E1 1483 PEROXIDES, INORGANIC, N.O.S. 5.1 O2 II 5.1 1 kg E2 1483 PEROXIDES, INORGANIC, N.O.S. 5.1 O2 III 5.1 5 kg E1 1484 POTASSIUM BROMATE 1485 POTASSIUM CHLORATE 1486 POTASSIUM NITRATE 1487 POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE 1488 POTASSIUM NITRITE 5.1 5.1 5.1 5.1 5.1 O2 O2 O2 O2 O2 II II III II II 5.1 1 kg 5.1 1 kg 5.1 5.1 5 kg 607 5.1 1 kg 1 kg E2 E2 E1 E2 E2 1489 POTASSIUM PERCHLORATE 5.1 O2 II 5.1 1 kg E2 1490 POTASSIUM PERMANGANATE 5.1 O2 II 5.1 1 kg E2 1491 POTASSIUM PEROXIDE 5.1 O2 I 5.1 0 E0 1492 POTASSIUM PERSULPHATE 5.1 O2 III 5.1 5 kg E1 1493 SILVER NITRATE 1494 SODIUM BROMATE 5.1 5.1 O2 O2 II II 5.1 1 kg 5.1 1 kg - 348 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 2.2 (3b) O2 Packaging E2 E2 4.1.4 (8) P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P503 IBC05 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC06 P002 IBC08 P503 IBC06 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) 4.2.5.3 (11) MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 BK1 BK2 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 BK1 BK2 TP33 MP10 T3 TP33 MP10 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 MP2 T3 TP33 B4 B3 B4 B3 B4 B3 MP2 B4 B3 B3 B3 B3 B4 B4 B3 B4 B4 B4 MP2 B3 B4 B4 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) SGAN 4.3.5, 6.8.4 (13) TU3 9.1.1.2 (14) AT 1.1.3.6 (15) 2 (E) SGAV TU3 AT 3 (E) SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT 2 (E) 2 (E) 3 (E) SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAN TU3 AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT 2 (E) 2 (E) 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) V11 7.3.3 (17) 7.5.11 (18) CV24 V11 V11 V11 5.3.2.3 (20) 50 3.1.2 (1) (2) 1471 LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE 1471 LITHIUM HYPOCHLORITE, DRY or LITHIUM HYPOCHLORITE MIXTURE CV24 50 CV24 50 1472 LITHIUM PEROXIDE CV24 50 1473 MAGNESIUM BROMATE CV24 50 1474 MAGNESIUM NITRATE 50 1475 MAGNESIUM PERCHLORATE CV24 S23 CV24 50 1476 MAGNESIUM PEROXIDE V11 CV24 50 1477 NITRATES, INORGANIC, N.O.S. CV24 50 1477 NITRATES, INORGANIC, N.O.S. VC1 VC2 AP6 AP7 V10 CV24 V11 CV24 50 1479 OXIDIZING SOLID, N.O.S. CV24 50 1479 OXIDIZING SOLID, N.O.S. 1481 PERCHLORATES, INORGANIC, N.O.S. 1481 PERCHLORATES, INORGANIC, N.O.S. V11 2 (E) 3 (E) V11 2 (E) 3 (E) V11 2 (E) 2 (E) 3 (E) V11 2 (E) 2 (E) VC1 VC2 AP6 AP7 8.5 (19) Name and description V11 2 (E) 3 (E) 2 (E) 2 (E) 2 (E) 2 (E) 1 (E) 3 (E) VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 Hazard UN No. identification No. Operation V11 V11 V11 V11 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 S23 50 CV24 S23 50 CV24 50 CV24 50 CV24 50 1483 PEROXIDES, INORGANIC, N.O.S. CV24 50 1483 PEROXIDES, INORGANIC, N.O.S. CV24 50 1484 POTASSIUM BROMATE CV24 50 1485 POTASSIUM CHLORATE CV24 50 1486 POTASSIUM NITRATE CV24 50 CV24 50 1487 POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE 1488 POTASSIUM NITRITE 50 1489 POTASSIUM PERCHLORATE 50 1490 POTASSIUM PERMANGANATE CV24 CV24 V10 CV24 V11 1479 OXIDIZING SOLID, N.O.S. CV24 V11 V11 S20 S23 S20 1482 PERMANGANATES, INORGANIC, N.O.S. 1482 PERMANGANATES, INORGANIC, N.O.S. 1491 POTASSIUM PEROXIDE VC1 VC2 AP6 AP7 CV24 50 1492 POTASSIUM PERSULPHATE VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 CV24 50 1493 SILVER NITRATE CV24 50 1494 SODIUM BROMATE - 349 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 1496 SODIUM CHLORITE 1498 SODIUM NITRATE 2.2 (3a) 5.1 5.1 5.1 1499 SODIUM NITRATE AND POTASSIUM NITRATE MIXTURE 5.1 1500 SODIUM NITRITE 5.1 2.2 (3b) O2 O2 O2 O2 OT2 2.1.1.3 (4) II II III III III 5.2.2 (5) 5.1 3.3 (6) 5.1 3.4 (7a) 1 kg 1 kg 5.1 5 kg 5.1 5 kg 5.1 +6.1 5 kg 3.5.1.2 (7b) E2 E2 E1 E1 E1 1502 SODIUM PERCHLORATE 5.1 O2 II 5.1 1 kg E2 1503 SODIUM PERMANGANATE 5.1 O2 II 5.1 1 kg E2 1504 SODIUM PEROXIDE 5.1 O2 I 5.1 0 E0 1505 SODIUM PERSULPHATE 5.1 O2 III 5.1 5 kg E1 1506 STRONTIUM CHLORATE 1507 STRONTIUM NITRATE 5.1 5.1 O2 O2 II III 5.1 1 kg 5.1 5 kg E2 E1 1508 STRONTIUM PERCHLORATE 5.1 O2 II 5.1 1 kg E2 1509 STRONTIUM PEROXIDE 5.1 O2 II 5.1 1 kg E2 1510 TETRANITROMETHANE 6.1 TO1 I 6.1 +5.1 0 E0 1511 UREA HYDROGEN PEROXIDE 5.1 OC2 III 5.1 +8 5 kg E1 5.1 1 kg 354 609 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1495 SODIUM CHLORATE Packaging 4.1.4 (8) P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 R001 P002 IBC06 P002 IBC06 P503 IBC05 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC06 P602 4.1.4 (9a) 4.1.10 (9b) MP2 4.2.5.2 (10) T3 BK1 BK2 T3 4.2.5.3 (11) TP33 MP10 T1 BK1 BK2 TP33 MP10 T1 BK1 BK2 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP2 T3 TP33 MP2 T1 TP33 MP10 T3 TP33 MP2 T3 TP33 MP10 T3 TP33 MP2 T3 TP33 MP2 T3 TP33 B4 MP2 TP33 B4 B3 B3 B3 MP2 B3 B4 B3 MP8 MP17 1515 ZINC PERMANGANATE 5.1 O2 II 5.1 1 kg E2 1516 ZINC PEROXIDE 5.1 O2 II 5.1 1 kg E2 1517 ZIRCONIUM PICRAMATE, WETTED with not less than 20% water, by mass 1541 ACETONE CYANOHYDRIN, STABILIZED 4.1 D I 4.1 0 E0 P002 IBC08 R001 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC06 P002 IBC06 P406 6.1 T1 I 6.1 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 6.1 T2 I 6.1 43 274 0 E5 P002 IBC07 MP18 T6 TP33 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 6.1 T2 II 6.1 43 274 500 g E4 P002 IBC08 MP10 T3 TP33 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. 6.1 43 274 5 kg MP10 T1 TP33 1545 ALLYL ISOTHIOCYANATE, STABILIZED 1546 AMMONIUM ARSENATE 6.1 TF1 II MP15 T7 TP2 6.1 T5 II MP10 T3 TP33 MP15 T7 TP2 1512 ZINC AMMONIUM NITRITE 1513 ZINC CHLORATE 1514 ZINC NITRATE 1547 ANILINE 5.1 5.1 5.1 6.1 O2 O2 O2 T2 T1 II II II III II 5.1 1 kg 5.1 6.1 1 kg 6.1 +3 6.1 6.1 279 - 350 - E2 E2 E2 E1 100 ml E0 500 g E4 100 ml E4 P002 IBC08 LP02 R001 P001 IBC02 P002 IBC08 P001 IBC02 B3 B4 B4 B4 PP26 MP2 B4 B3 B4 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) SGAV 4.3.5, 6.8.4 (13) TU3 9.1.1.2 (14) AT SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT 3 (E) SGAN TU3 AT 3 (E) SGAV TU3 AT SGAN TU3 AT 2 (E) 2 (E) 1 (E) 3 (E) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (E) 7.2.4 (16) V11 7.3.3 (17) VC1 VC2 AP6 AP7 7.5.11 (18) CV24 2 (E) 3 (E) V11 SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAN TU3 AT L10CH TU14 TU15 TE19 TE21 AT SGAN TU3 AT 3 (E) SGAN TU3 AT SGAV TU3 AT SGAN TU3 AT SGAN TU3 AT SGAN TU3 AT 2 (E) 2 (E) 2 (E) 2 (E) 2 (E) 1 (B) V11 Hazard UN No. identification No. Operation 5.3.2.3 (20) 50 3.1.2 (1) (2) 1495 SODIUM CHLORATE CV24 50 1496 SODIUM CHLORITE VC1 VC2 AP6 AP7 CV24 50 1498 SODIUM NITRATE VC1 VC2 AP6 AP7 CV24 50 1499 SODIUM NITRATE AND POTASSIUM NITRATE MIXTURE CV24 CV28 56 1500 SODIUM NITRITE 50 1502 SODIUM PERCHLORATE 50 1503 SODIUM PERMANGANATE VC1 VC2 AP6 AP7 CV24 8.5 (19) Name and description S23 V11 CV24 CV24 V10 S20 1504 SODIUM PEROXIDE VC1 VC2 AP6 AP7 CV24 50 1505 SODIUM PERSULPHATE VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 CV24 50 1506 STRONTIUM CHLORATE CV24 50 1507 STRONTIUM NITRATE 50 1508 STRONTIUM PERCHLORATE 50 1509 STRONTIUM PEROXIDE 665 1510 TETRANITROMETHANE CV24 58 1511 UREA HYDROGEN PEROXIDE CV24 50 1512 ZINC AMMONIUM NITRITE CV24 50 1513 ZINC CHLORATE V11 CV24 50 1514 ZINC NITRATE V11 CV24 50 1515 ZINC PERMANGANATE V11 CV24 50 1516 ZINC PEROXIDE 2 (E) 3 (E) V11 2 (E) 2 (E) 1 (B/D) V11 VC1 VC2 AP6 AP7 V11 CV24 CV24 CV1 CV13 CV28 V11 V11 S23 VC1 VC2 AP6 AP7 S9 S14 S14 L10CH TU14 TU15 TE19 TE21 AT 1 (C/D) S10AH TU15 TE19 AT 1 (C/E) V10 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 SGAH L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 FL SGAH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (D/E) VC1 VC2 AP7 V11 1517 ZIRCONIUM PICRAMATE, WETTED with not less than 20% water, by mass 1541 ACETONE CYANOHYDRIN, STABILIZED CV1 CV13 CV28 S9 S14 669 CV1 CV13 CV28 CV13 CV28 S9 S14 66 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. S9 S19 60 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. CV13 CV28 S9 60 1544 ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. CV13 CV28 CV13 CV28 CV13 CV28 S2 S9 S19 639 S9 S19 60 1545 ALLYL ISOTHIOCYANATE, STABILIZED 1546 AMMONIUM ARSENATE S9 S19 60 1547 ANILINE - 351 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 1549 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. 6.1 1550 ANTIMONY LACTATE 6.1 2.2 (3b) T2 T5 T5 III III 6.1 3.3 (6) 45 274 512 6.1 3.4 (7a) 5 kg 5 kg 5 kg E1 6.1 T4 I 6.1 0 E5 1554 ARSENIC ACID, SOLID 6.1 T5 II 6.1 500 g E4 II 5 kg E1 1553 ARSENIC ACID, LIQUID T5 6.1 3.5.1.2 (7b) E1 6.1 6.1 III 5.2.2 (5) 6.1 1551 ANTIMONY POTASSIUM TARTRATE 1555 ARSENIC BROMIDE T5 2.1.1.3 (4) III 6.1 500 g Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1548 ANILINE HYDROCHLORIDE Packaging E1 E4 4.1.4 (8) P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P001 P002 IBC08 P002 IBC08 P001 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP10 T1 TP33 MP10 T1 TP33 MP10 T1 TP33 MP8 MP17 T20 TP2 TP7 MP10 T3 TP33 MP10 T3 TP33 MP8 MP17 T14 TP2 TP27 B3 B3 B3 B3 B4 B4 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 T4 I 6.1 43 274 0 E5 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 T4 II 6.1 43 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 T4 III 6.1 43 274 5L E1 P001 IBC03 LP01 R001 MP19 T7 TP2 TP28 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 T5 I 6.1 43 274 0 E5 P002 IBC07 MP18 T6 TP33 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 T5 II 6.1 43 274 500 g E4 P002 IBC08 MP10 T3 TP33 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 43 274 5 kg MP10 T1 TP33 1558 ARSENIC 6.1 MP10 T3 TP33 MP10 T3 TP33 MP8 MP17 T14 TP2 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP18 T6 TP33 MP10 T3 TP33 1559 ARSENIC PENTOXIDE 6.1 T5 T5 T5 III II II 6.1 6.1 500 g 6.1 500 g E1 E4 E4 1560 ARSENIC TRICHLORIDE 6.1 T4 I 6.1 0 E0 1561 ARSENIC TRIOXIDE 6.1 T5 II 6.1 500 g E4 1562 ARSENICAL DUST 1564 BARIUM COMPOUND, N.O.S. 1564 BARIUM COMPOUND, N.O.S. 6.1 6.1 6.1 T5 T5 T5 II II III 6.1 6.1 6.1 1565 BARIUM CYANIDE 6.1 T5 I 6.1 1566 BERYLLIUM COMPOUND, N.O.S. 6.1 T5 II 6.1 500 g 177 274 513 587 177 274 513 587 274 514 - 352 - 500 g 5 kg E4 E4 E1 0 E5 500 g E4 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P602 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 B4 B3 B4 B4 B4 B4 B4 B3 B4 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) SGAH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT 1.1.3.6 (15) 2 (E) SGAH L4BH TU15 TE19 AT SGAH L4BH TU15 TE19 SGAH L4BH Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) CV13 CV28 8.5 (19) S9 5.3.2.3 (20) 60 3.1.2 (1) (2) 1548 ANILINE HYDROCHLORIDE 2 (E) VC1 VC2 AP7 CV13 CV28 S9 60 1549 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. AT 2 (E) VC1 VC2 AP7 CV13 CV28 S9 60 1550 ANTIMONY LACTATE TU15 TE19 AT 2 (E) VC1 VC2 AP7 CV13 CV28 S9 60 1551 ANTIMONY POTASSIUM TARTRATE L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 1553 ARSENIC ACID, LIQUID SGAH L4BH SGAH L4BH L10CH TU15 TE19 AT S9 S19 60 1554 ARSENIC ACID, SOLID TU15 TE19 AT S9 S19 60 1555 ARSENIC BROMIDE TU14 TU15 TE19 TE21 AT 2 (D/E) 2 (D/E) 1 (C/E) CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 S9 S14 66 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. L4BH TU15 TE19 AT 2 (D/E) CV13 CV28 S9 S19 60 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. S10AH L10CH TU15 TE19 AT 1 (C/E) V10 CV1 CV13 CV28 S9 S14 66 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV13 CV28 S9 S19 60 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 1557 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. SGAH TU15 TE19 AT 60 1558 ARSENIC TU15 TE19 AT S9 S19 60 1559 ARSENIC PENTOXIDE L10CH TU14 TU15 TE19 TE21 AT S9 S14 66 1560 ARSENIC TRICHLORIDE SGAH TU15 TE19 AT S9 S19 60 1561 ARSENIC TRIOXIDE SGAH TU15 TE19 AT S9 S19 60 1562 ARSENICAL DUST SGAH L4BH TU15 TE19 AT CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 SGAH 2 (D/E) 2 (D/E) 1 (C/E) S9 S19 60 1564 BARIUM COMPOUND, N.O.S. SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 1564 BARIUM COMPOUND, N.O.S. S10AH TU15 TE19 AT 1 (C/E) V10 S9 S14 66 1565 BARIUM CYANIDE SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 S9 S19 60 1566 BERYLLIUM COMPOUND, N.O.S. 2 (D/E) 2 (D/E) 2 (D/E) V11 V11 VC1 VC2 AP7 V11 V11 V11 V11 V11 VC1 VC2 AP7 - 353 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 1567 BERYLLIUM POWDER 2.2 (3a) 6.1 6.1 2.2 (3b) T5 TF3 2.1.1.3 (4) III II 1569 BROMOACETONE 6.1 TF1 II 1570 BRUCINE 6.1 T2 I 1571 BARIUM AZIDE, WETTED with not less than 50% water, by mass 1572 CACODYLIC ACID 4.1 DT I 6.1 T5 II 1573 CALCIUM ARSENATE 1574 CALCIUM ARSENATE AND CALCIUM ARSENITE MIXTURE, SOLID 1575 CALCIUM CYANIDE 6.1 6.1 T5 T5 II II 5.2.2 (5) 6.1 6.1 +4.1 6.1 +3 6.1 4.1 +6.1 6.1 I 6.1 1577 CHLORODINITRO-BENZENES, LIQUID 1578 CHLORONITROBENZENES, SOLID 1579 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLID 6.1 T1 II 6.1 6.1 T2 II 6.1 1580 CHLOROPICRIN 6.1 T1 1581 CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more than 2% chloropicrin 1582 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE 2 2T 2 2T 1583 CHLOROPICRIN MIXTURE, N.O.S. 6.1 T1 I 6.1 1583 CHLOROPICRIN MIXTURE, N.O.S. 1583 CHLOROPICRIN MIXTURE, N.O.S. 6.1 T1 II 6.1 6.1 T1 III 6.1 1585 COPPER ACETOARSENITE 6.1 T5 II 6.1 1586 COPPER ARSENITE 1587 COPPER CYANIDE 6.1 6.1 T2 T5 T5 III I II II 3.5.1.2 (7b) E1 E4 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP10 T3 TP33 MP15 T20 TP2 T6 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 B3 B4 0 E5 P002 IBC07 MP18 568 0 E0 P406 MP2 500 g E4 P002 IBC08 P002 IBC08 P002 IBC08 500 g 500 g E4 E4 B4 B4 B4 0 E5 P002 IBC07 MP18 T6 TP33 279 100 ml E4 MP15 T7 TP2 279 500 g E4 MP10 T3 TP33 MP10 T1 TP33 MP8 MP17 T22 TP2 TP37 0 E0 P001 IBC02 P002 IBC08 P002 IBC08 LP02 R001 P601 2.3 0 E0 P200 MP9 (M) T50 2.3 0 E0 P200 MP9 (M) T50 274 315 515 0 E0 P602 MP8 MP17 274 515 274 515 100 ml E0 MP15 5L E0 500 g E4 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC07 6.1 6.1 5 kg 354 6.1 500 g 6.1 500 g E1 E4 E4 T5 I 6.1 47 274 0 E5 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 T5 II 6.1 47 274 47 274 500 g E4 1589 CYANOGEN CHLORIDE, STABILIZED 2 2TC 1590 DICHLOROANILINES, LIQUID 6.1 T1 II 6.1 1591 o-DICHLOROBENZENE 6.1 T1 III 6.1 III 4.1.10 (9b) MP10 43 6.1 T5 4.1.4 (9a) E0 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 4.1.4 (8) P002 IBC08 LP02 R001 P002 IBC08 P602 0 6.1 T5 3.4 (7a) 5 kg 500 g 6.1 6.1 6.1 3.3 (6) 274 514 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1566 BERYLLIUM COMPOUND, N.O.S. Packaging 6.1 2.3 +8 5 kg E1 0 E0 279 100 ml E4 279 5L E1 - 354 - P002 IBC08 P002 IBC08 LP02 R001 P200 P001 IBC02 P001 IBC03 LP01 R001 B4 B3 MP19 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP15 T7 TP2 MP19 T4 TP1 B4 B4 B4 B4 B3 MP9 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) SGAH L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT SGAH TU15 TE19 AT L4BH TU15 TE19 FL S10AH L10CH TU14 TU15 TE19 TE21 AT Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (E) 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) CV13 CV28 8.5 (19) S9 5.3.2.3 (20) 60 2 (D/E) 2 (D/E) 1 (C/E) V11 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV28 S9 S19 64 1567 BERYLLIUM POWDER S2 S9 S19 63 1569 BROMOACETONE S9 S14 66 1570 BRUCINE S9 S19 60 1571 BARIUM AZIDE, WETTED with not less than 50% water, by mass 1572 CACODYLIC ACID S9 S19 60 1573 CALCIUM ARSENATE S9 S19 60 S9 S14 66 1574 CALCIUM ARSENATE AND CALCIUM ARSENITE MIXTURE, SOLID 1575 CALCIUM CYANIDE S9 S19 60 S9 S19 60 S9 60 1 (B) 2 (D/E) 2 (D/E) 2 (D/E) V10 SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT S10AH TU15 TE19 AT 1 (C/E) L4BH TU15 TE19 AT SGAH TU15 TE19 AT SGAH L4BH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (E) L15CH TU14 TU15 TE19 TE21 AT 1 (C/D) CV1 CV13 CV28 S9 S14 66 1580 CHLOROPICRIN PxBH(M) TA4 TT9 AT 1 (C/D) S14 26 PxBH(M) TA4 TT9 AT 1 (C/D) S14 26 1581 CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more than 2% chloropicrin 1582 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) CV9 CV10 CV36 CV9 CV10 CV36 CV1 CV13 CV28 S9 S14 66 1583 CHLOROPICRIN MIXTURE, N.O.S. L4BH TU15 TE19 AT 60 TU15 TE19 AT CV13 CV28 CV13 CV28 S9 S19 L4BH 2 (D/E) 2 (E) S9 60 1583 CHLOROPICRIN MIXTURE, N.O.S. 1583 CHLOROPICRIN MIXTURE, N.O.S. SGAH TU15 TE19 AT S9 S19 60 1585 COPPER ACETOARSENITE SGAH TU15 TE19 AT S9 S19 60 1586 COPPER ARSENITE SGAH TU15 TE19 AT S9 S19 60 1587 COPPER CYANIDE S10AH TU15 TE19 AT S9 S14 66 1588 CYANIDES, INORGANIC, SOLID, N.O.S. SGAH TU15 TE19 AT S9 S19 60 SGAH TU15 TE19 AT CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 60 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/E) 2 (D/E) 2 (E) V11 V11 V11 V10 V11 VC1 VC2 AP7 V12 V11 V11 V11 V10 V11 VC1 VC2 AP7 1 (D) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) CV13 CV28 CV13 CV28 CV13 CV28 S14 3.1.2 (1) (2) 1566 BERYLLIUM COMPOUND, N.O.S. V12 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV9 CV10 CV36 CV13 CV28 CV13 CV28 - 355 - S14 1577 CHLORODINITRO-BENZENES, LIQUID 1578 CHLORONITROBENZENES, SOLID 1579 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLID 1589 CYANOGEN CHLORIDE, STABILIZED S9 S19 60 1590 DICHLOROANILINES, LIQUID S9 60 1591 o-DICHLOROBENZENE UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) T1 2.1.1.3 (4) III 5.2.2 (5) 6.1 1594 DIETHYL SULPHATE 6.1 T1 II 6.1 1595 DIMETHYL SULPHATE 6.1 TC1 I 6.1 +8 1596 DINITROANILINES 6.1 T2 II 6.1 3.3 (6) 516 354 3.4 (7a) 5L 3.5.1.2 (7b) E1 100 ml E4 0 E0 500 g E4 1597 DINITROBENZENES, LIQUID 6.1 T1 II 6.1 100 ml E4 1597 DINITROBENZENES, LIQUID 6.1 T1 III 6.1 5L E1 1598 DINITRO-o-CRESOL 6.1 T2 II 6.1 500 g E4 43 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1593 DICHLOROMETHANE Packaging 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC02 P602 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T7 4.2.5.3 (11) TP2 MP15 T7 TP2 MP8 MP17 T20 TP2 TP35 MP10 T3 TP33 MP15 T7 TP2 MP19 T7 TP2 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 T7 TP3 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP15 T7 TP2 MP15 T7 TP2 MP8 MP17 T20 TP2 TP37 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP15 T7 TP2 MP9 (M) MP8 MP17 T14 B8 B4 B4 1599 DINITROPHENOL SOLUTION 6.1 T1 II 6.1 100 ml E4 1599 DINITROPHENOL SOLUTION 6.1 T1 III 6.1 5L E1 1600 DINITROTOLUENES, MOLTEN 6.1 T1 II 6.1 0 E0 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 6.1 T2 I 6.1 274 0 E5 P002 IBC07 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 6.1 T2 II 6.1 274 500 g E4 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 6.1 T1 I 6.1 274 0 E5 P002 IBC08 P002 IBC08 LP02 R001 P001 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 6.1 T1 II 6.1 274 100 ml E4 P001 IBC02 MP15 6.1 T1 III 6.1 274 5L E1 MP19 1603 ETHYL BROMOACETATE 6.1 TF1 II 100 ml E0 1604 ETHYLENEDIAMINE 8 CF1 II 1L E2 1605 ETHYLENE DIBROMIDE 6.1 T1 I 6.1 +3 8 +3 6.1 0 E0 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 P602 1606 FERRIC ARSENATE 6.1 T5 II 6.1 500 g E4 1607 FERRIC ARSENITE 1608 FERROUS ARSENATE 6.1 6.1 6.1 T2 T5 T5 III II II 274 354 5 kg E1 6.1 100 ml E4 2.3 0 E0 P002 IBC08 P002 IBC08 P002 IBC08 P001 IBC02 P200 48 0 E0 P601 603 0 E0 P099 P601 6.1 500 g 6.1 1611 HEXAETHYL TETRAPHOSPHATE 6.1 T1 1612 HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE 1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION) with not more than 20% hydrogen cyanide 2 1T 6.1 TF1 I 6.1 +3 6.1 TF1 I 6.1 +3 1614 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water and absorbed in a porous inert material II 6.1 500 g - 356 - E4 E4 B4 B3 MP8 MP17 B4 B4 B4 MP2 RR10 TP2 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT 1.1.3.6 (15) 2 (E) L4BH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 1 (C/D) SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT L4BH TU15 TE19 AT SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT S10AH L10CH TU15 TE19 AT SGAH L4BH SGAH L4BH TU15 TE19 AT TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 FL 2 (D/E) 2 (D/E) 1 (C/D) L4BN FL L10CH TU14 TU15 TE19 TE21 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT L4BH TU15 TE19 AT CxBH(M) TA4 TT9 AT L15DH(+) TU14 TU15 TE19 TE21 FL 2 (D/E) 2 (D/E) 2 (E) 2 (D/E) 2 (D/E) 2 (E) 0 (D/E) 1 (C/E) 2 (D/E) 2 (E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/D) 0 (C/D) 0 (D) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) CV13 CV28 8.5 (19) S9 5.3.2.3 (20) 60 3.1.2 (1) (2) 1593 DICHLOROMETHANE CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 1594 DIETHYL SULPHATE S9 S14 668 1595 DIMETHYL SULPHATE S9 S19 60 1596 DINITROANILINES S9 S19 60 1597 DINITROBENZENES, LIQUID S9 60 1597 DINITROBENZENES, LIQUID CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 1598 DINITRO-o-CRESOL S9 S19 60 1599 DINITROPHENOL SOLUTION S9 60 1599 DINITROPHENOL SOLUTION CV13 S9 S19 60 1600 DINITROTOLUENES, MOLTEN CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 S14 66 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. S9 S19 60 S9 60 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. CV1 CV13 CV28 S9 S14 66 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. CV13 CV28 S9 S19 60 CV13 CV28 S9 60 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 1602 DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. CV13 CV28 S2 S9 S19 63 1603 ETHYL BROMOACETATE S2 83 1604 ETHYLENEDIAMINE S9 S14 66 1605 ETHYLENE DIBROMIDE S9 S19 60 1606 FERRIC ARSENATE S9 S19 60 1607 FERRIC ARSENITE S9 S19 60 1608 FERROUS ARSENATE S9 S19 60 1611 HEXAETHYL TETRAPHOSPHATE S14 26 S2 S9 S14 663 1612 HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE 1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION) with not more than 20% hydrogen cyanide V11 V12 V11 V12 V10 V11 VC1 VC2 AP7 V12 V11 V11 V11 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV9 CV10 CV36 CV1 CV13 CV28 CV1 CV13 CV28 - 357 - S2 S9 S10 S14 1614 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water and absorbed in a porous inert material UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 1617 LEAD ARSENATES 1618 LEAD ARSENITES 1620 LEAD CYANIDE 1621 LONDON PURPLE 1622 MAGNESIUM ARSENATE 1623 MERCURIC ARSENATE 1624 MERCURIC CHLORIDE 1625 MERCURIC NITRATE 2.2 (3a) 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 2.2 (3b) T5 T5 T5 T5 T5 T5 T5 T5 T5 2.1.1.3 (4) III II II II II II II II II 5.2.2 (5) 6.1 3.3 (6) 6.1 500 g 6.1 500 g 6.1 6.1 3.4 (7a) 5 kg 500 g 43 6.1 500 g 500 g 6.1 500 g 6.1 500 g 6.1 500 g 3.5.1.2 (7b) E1 E4 E4 E4 E4 E4 E4 E4 E4 1626 MERCURIC POTASSIUM CYANIDE 6.1 T5 I 6.1 0 E5 1627 MERCUROUS NITRATE 6.1 T5 II 6.1 500 g E4 1629 MERCURY ACETATE 1630 MERCURY AMMONIUM CHLORIDE 1631 MERCURY BENZOATE 1634 MERCURY BROMIDES 1636 MERCURY CYANIDE 1637 MERCURY GLUCONATE 1638 MERCURY IODIDE 1639 MERCURY NUCLEATE 1640 MERCURY OLEATE 1641 MERCURY OXIDE 1642 MERCURY OXYCYANIDE, DESENSITIZED 1643 MERCURY POTASSIUM IODIDE 1644 MERCURY SALICYLATE 1645 MERCURY SULPHATE 1646 MERCURY THIOCYANATE 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 T5 II II II II II II II II II II II II II II II 6.1 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 500 g 6.1 1649 MOTOR FUEL ANTI-KNOCK MIXTURE 6.1 T3 1650 beta-NAPHTHYLAMINE, SOLID 6.1 T2 T5 500 g 6.1 II 6.1 500 g 6.1 F1 1653 NICKEL CYANIDE 500 g 6.1 3 T2 500 g 6.1 6.1 6.1 500 g 6.1 I 1652 NAPHTHYLUREA 500 g 6.1 T1 T2 500 g 6.1 6.1 6.1 500 g 6.1 1647 METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID 1648 ACETONITRILE 1651 NAPHTHYLTHIOUREA 500 g 500 g E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 E4 0 E0 3 1L E2 I 6.1 0 E0 II 6.1 500 g E4 II II II 6.1 354 43 6.1 500 g 6.1 1654 NICOTINE 6.1 T1 II 6.1 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 6.1 T2 I 6.1 500 g 500 g 43 274 - 358 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1616 LEAD ACETATE Packaging E4 E4 E4 100 ml E4 0 E5 4.1.4 (8) P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC07 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P602 4.1.4 (9a) 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP8 MP17 T20 TP2 MP19 T7 TP2 MP8 MP17 T14 TP2 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 T6 TP33 B3 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 B4 P001 IBC02 R001 P602 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P001 IBC02 P002 IBC07 4.1.10 (9b) MP10 B4 B4 B4 B4 MP15 MP18 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) SGAH L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT S10AH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT LGBF Transport category (Tunnel restriction code) Loading, unloading and handling 1.1.3.6 (15) 2 (E) 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) CV13 CV28 8.5 (19) S9 5.3.2.3 (20) 60 3.1.2 (1) (2) 1616 LEAD ACETATE 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/E) V11 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 S9 S19 60 1617 LEAD ARSENATES S9 S19 60 1618 LEAD ARSENITES S9 S19 60 1620 LEAD CYANIDE S9 S19 60 1621 LONDON PURPLE S9 S19 60 1622 MAGNESIUM ARSENATE S9 S19 60 1623 MERCURIC ARSENATE S9 S19 60 1624 MERCURIC CHLORIDE S9 S19 60 1625 MERCURIC NITRATE S9 S14 66 1626 MERCURIC POTASSIUM CYANIDE S9 S19 60 1627 MERCUROUS NITRATE S9 S19 60 1629 MERCURY ACETATE S9 S19 60 S9 S19 60 1630 MERCURY AMMONIUM CHLORIDE 1631 MERCURY BENZOATE S9 S19 60 1634 MERCURY BROMIDES S9 S19 60 1636 MERCURY CYANIDE S9 S19 60 1637 MERCURY GLUCONATE S9 S19 60 1638 MERCURY IODIDE S9 S19 60 1639 MERCURY NUCLEATE S9 S19 60 1640 MERCURY OLEATE S9 S19 60 1641 MERCURY OXIDE S9 S19 60 S9 S19 60 1642 MERCURY OXYCYANIDE, DESENSITIZED 1643 MERCURY POTASSIUM IODIDE S9 S19 60 1644 MERCURY SALICYLATE S9 S19 60 1645 MERCURY SULPHATE S9 S19 60 1646 MERCURY THIOCYANATE S9 S14 66 S2 S20 33 1647 METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID 1648 ACETONITRILE S9 S14 66 1649 MOTOR FUEL ANTI-KNOCK MIXTURE S9 S19 60 1650 beta-NAPHTHYLAMINE, SOLID S9 S19 60 1651 NAPHTHYLTHIOUREA S9 S19 60 1652 NAPHTHYLUREA S9 S19 60 1653 NICKEL CYANIDE S9 S19 60 1654 NICOTINE S9 S14 66 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/D) TU14 TU15 TE19 TE21 TT6 TU15 TE19 AT 1 (C/E) AT TU15 TE19 AT SGAH TU15 TE19 AT SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/E) S10AH L10CH Name and description Bulk 2 (D/E) SGAH L4BH SGAH Hazard UN No. identification No. Operation Packages FL L10CH Special provisions for carriage V11 V11 V11 V11 V11 V11 V11 V10 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V11 V10 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 - 359 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 6.1 T1 II 6.1 T1 1657 NICOTINE SALICYLATE 6.1 T2 6.1 2.2 (3b) T2 T2 2.1.1.3 (4) II 3.3 (6) 43 274 3.4 (7a) 500 g 43 274 5 kg 6.1 43 100 ml E4 III 6.1 43 5L E1 II 6.1 500 g E4 III 5.2.2 (5) 6.1 6.1 3.5.1.2 (7b) E4 E1 1658 NICOTINE SULPHATE, SOLUTION 1658 NICOTINE SULPHATE, SOLUTION 6.1 T1 II 6.1 100 ml E4 6.1 T1 III 6.1 5L E1 1659 NICOTINE TARTRATE 6.1 T2 II 6.1 500 g E4 1660 NITRIC OXIDE, COMPRESSED 2 1TOC 1661 NITROANILINES (o-, m-, p-) 6.1 T2 II 2.3 +5.1 +8 6.1 279 0 E0 500 g E4 1662 NITROBENZENE 6.1 T1 II 6.1 279 100 ml E4 1663 NITROPHENOLS (o-, m-, p-) 6.1 T2 III 6.1 279 5 kg E1 1664 NITROTOLUENES, LIQUID 6.1 T1 II 6.1 100 ml E4 1665 NITROXYLENES, LIQUID 6.1 T1 II 6.1 100 ml E4 1669 PENTACHLOROETHANE 6.1 T1 II 6.1 100 ml E4 1670 PERCHLOROMETHYL MERCAPTAN 6.1 T1 I 6.1 354 0 E0 1671 PHENOL, SOLID 6.1 T2 II 6.1 279 500 g E4 1672 PHENYLCARBYLAMINE CHLORIDE 6.1 T1 I 6.1 1673 PHENYLENEDIAMINES (o-, m-, p-) 6.1 T2 III 6.1 1674 PHENYLMERCURIC ACETATE 6.1 1677 POTASSIUM ARSENATE 1678 POTASSIUM ARSENITE 1679 POTASSIUM CUPROCYANIDE 6.1 6.1 6.1 T3 T5 T5 T5 II II II II 6.1 279 43 6.1 0 E0 5 kg E1 500 g 500 g 6.1 500 g 6.1 500 g E4 E4 E4 E4 1680 POTASSIUM CYANIDE, SOLID 6.1 T5 I 6.1 0 E5 1683 SILVER ARSENITE 6.1 T5 II 6.1 500 g E4 1684 SILVER CYANIDE 1685 SODIUM ARSENATE 6.1 6.1 T5 T5 II II 6.1 500 g 6.1 500 g E4 E4 1686 SODIUM ARSENITE, AQUEOUS SOLUTION 1686 SODIUM ARSENITE, AQUEOUS SOLUTION 6.1 T4 II 6.1 43 100 ml E4 6.1 T4 III 6.1 43 5L E1 1687 SODIUM AZIDE 6.1 T5 II 6.1 500 g E4 - 360 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. Packaging 4.1.4 (8) P002 IBC08 P002 IBC08 LP02 R001 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P200 P002 IBC08 P001 IBC02 P002 IBC08 LP02 R001 P001 IBC02 P001 IBC02 P001 IBC02 P602 P002 IBC08 P602 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC07 P002 IBC08 P002 IBC08 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T3 4.2.5.3 (11) TP33 MP10 T1 TP33 MP10 T3 TP33 MP15 T7 TP2 MP19 T7 TP2 MP10 T3 TP33 MP10 T3 TP33 MP15 T7 TP2 MP10 T1 TP33 MP15 T7 TP2 MP15 T7 TP2 MP15 T7 TP2 MP8 MP17 T20 TP2 TP37 MP10 T3 TP33 MP8 MP17 T14 TP2 MP10 T1 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP2 B4 B3 MP15 MP19 B4 B4 MP9 B4 B3 B4 B3 B4 B4 B4 B4 B4 B4 B4 MP10 B4 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) SGAH L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT 1.1.3.6 (15) 2 (D/E) SGAH L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT L4BH TU15 TE19 AT SGAH L4BH TU15 TE19 AT SGAH L4BH L4BH 2 (D/E) 2 (D/E) 2 (E) Special provisions for carriage Bulk Loading, unloading and handling 7.2.4 (16) V11 7.3.3 (17) 7.5.11 (18) CV13 CV28 8.5 (19) S9 S19 5.3.2.3 (20) 60 VC1 VC2 AP7 CV13 CV28 S9 60 CV13 CV28 CV13 CV28 S9 S19 60 S9 60 CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 1657 NICOTINE SALICYLATE S9 S19 60 S9 60 1658 NICOTINE SULPHATE, SOLUTION 1658 NICOTINE SULPHATE, SOLUTION S9 S19 60 VC1 VC2 AP7 CV13 CV28 CV9 CV10 CV36 CV13 CV28 CV13 CV28 CV13 CV28 VC1 VC2 AP7 V12 V11 V12 V11 2 (D/E) 2 (D/E) 2 (E) V11 AT TU15 TE19 AT SGAH L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT SGAH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT SGAH L4BH TU15 TE19 AT 2 (E) SGAH L4BH SGAH TU15 TE19 AT TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT S10AH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/E) SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/D) 2 (D/E) 1 (C/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (E) 2 (D/E) Name and description Packages 2 (D/E) 1 (D) TU15 TE19 Hazard UN No. identification No. Operation V11 V11 V11 V11 V11 V10 V11 V11 V11 V12 V11 S14 3.1.2 (1) (2) 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S. 1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 1656 NICOTINE HYDROCHLORIDE, LIQUID or SOLUTION 1659 NICOTINE TARTRATE 1660 NITRIC OXIDE, COMPRESSED S9 S19 60 1661 NITROANILINES (o-, m-, p-) S9 S19 60 1662 NITROBENZENE S9 60 1663 NITROPHENOLS (o-, m-, p-) CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 S9 S19 60 1664 NITROTOLUENES, LIQUID S9 S19 60 1665 NITROXYLENES, LIQUID S9 S19 60 1669 PENTACHLOROETHANE S9 S14 66 1670 PERCHLOROMETHYL MERCAPTAN S9 S19 60 1671 PHENOL, SOLID S9 S14 66 1672 PHENYLCARBYLAMINE CHLORIDE S9 60 1673 PHENYLENEDIAMINES (o-, m-, p-) CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 1674 PHENYLMERCURIC ACETATE S9 S19 60 1677 POTASSIUM ARSENATE S9 S19 60 1678 POTASSIUM ARSENITE S9 S19 60 1679 POTASSIUM CUPROCYANIDE S9 S14 66 1680 POTASSIUM CYANIDE, SOLID S9 S19 60 1683 SILVER ARSENITE S9 S19 60 1684 SILVER CYANIDE S9 S19 60 1685 SODIUM ARSENATE S9 S19 60 S9 60 1686 SODIUM ARSENITE, AQUEOUS SOLUTION 1686 SODIUM ARSENITE, AQUEOUS SOLUTION CV13 CV28 - 361 - S9 S19 1687 SODIUM AZIDE UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) T5 2.1.1.3 (4) II 5.2.2 (5) 6.1 1689 SODIUM CYANIDE, SOLID 6.1 T5 I 1690 SODIUM FLUORIDE, SOLID 6.1 T5 III 1691 STRONTIUM ARSENITE 6.1 T5 II 3.3 (6) 3.4 (7a) 500 g 3.5.1.2 (7b) E4 6.1 0 E5 6.1 5 kg E1 6.1 500 g 1692 STRYCHNINE or STRYCHNINE SALTS 6.1 T2 I 6.1 1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 6.1 T1 I 6.1 1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 1694 BROMOBENZYL CYANIDES, LIQUID 6.1 T1 II 6.1 T1 1695 CHLOROACETONE, STABILIZED 6.1 1697 CHLOROACETOPHENONE, SOLID 1698 DIPHENYLAMINE CHLOROARSINE 6.1 6.1 T3 I 6.1 0 1699 DIPHENYLCHLORO-ARSINE, LIQUID 6.1 T3 I 6.1 1700 TEAR GAS CANDLES 6.1 TF3 1701 XYLYL BROMIDE, LIQUID 6.1 T1 II 6.1 +4.1 6.1 1702 1,1,2,2-TETRACHLOROETHANE 6.1 T1 II 6.1 1704 TETRAETHYL DITHIOPYROPHOSPHATE 1707 THALLIUM COMPOUND, N.O.S. 6.1 T1 II 6.1 6.1 T5 II 6.1 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1688 SODIUM CACODYLATE Packaging E4 4.1.4 (8) P002 IBC08 P002 IBC07 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC07 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T3 4.2.5.3 (11) TP33 MP18 T6 TP33 MP10 T1 TP33 MP10 T3 TP33 MP18 T6 TP33 B4 B3 B4 0 E5 274 0 E0 P001 MP8 MP17 6.1 274 0 E0 MP15 I 6.1 138 0 E0 P001 IBC02 P001 MP8 MP17 T14 TP2 TFC I 354 0 E0 P602 MP8 MP17 T20 TP2 TP35 T2 II 6.1 +3 +8 6.1 0 E0 MP10 T3 TP33 E0 P002 IBC08 P002 MP18 T6 TP33 0 E0 P001 0 E0 P600 0 E0 MP15 T7 TP2 100 ml E4 MP15 T7 TP2 43 100 ml E4 MP15 T7 TP2 43 274 279 500 g E4 P001 IBC02 P001 IBC02 P001 IBC02 P002 IBC08 P001 IBC02 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 MP10 T3 TP33 MP15 T7 TP2 MP10 T1 TP33 MP19 T4 TP1 MP15 T7 TP2 MP10 T3 TP33 T6 TP33 1708 TOLUIDINES, LIQUID 6.1 T1 II 6.1 1709 2,4-TOLUYLENEDIAMINE, SOLID 6.1 T2 III 6.1 100 ml E4 5 kg E1 B4 MP8 MP17 B4 B3 1710 TRICHLOROETHYLENE 6.1 T1 III 6.1 5L E1 1711 XYLIDINES, LIQUID 6.1 T1 II 6.1 100 ml E4 1712 ZINC ARSENATE, ZINC ARSENITE or ZINC ARSENATE AND ZINC ARSENITE MIXTURE 6.1 T5 II 6.1 500 g E4 1713 ZINC CYANIDE 6.1 T5 I 6.1 0 E5 P002 IBC07 MP18 1714 ZINC PHOSPHIDE 4.3 WT2 I 0 E0 P403 MP2 1715 ACETIC ANHYDRIDE 8 CF1 II 1L E2 T7 TP2 8 C3 II 1L E2 MP15 T8 TP2 1717 ACETYL CHLORIDE 3 FC II 1L E2 MP19 T8 TP2 1718 BUTYL ACID PHOSPHATE 8 C3 III 3 +8 8 5L E1 MP19 T4 TP1 1719 CAUSTIC ALKALI LIQUID, N.O.S. 8 C5 II 8 1L E2 P001 IBC02 P001 IBC02 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 MP15 1716 ACETYL BROMIDE 4.3 +6.1 8 +3 8 MP15 T11 TP2 TP27 274 - 362 - B4 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) SGAH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT S10AH TU15 TE19 AT SGAH TU15 TE19 AT 2 (E) SGAH TU15 TE19 AT S10AH TU15 TE19 AT 2 (D/E) 1 (C/E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 1 (C/E) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) SGAH L4BH S10AH TU15 TE19 AT TU15 TE19 AT 2 (D/E) 1 (C/E) TU14 TU15 TE19 TE21 AT L10CH 1.1.3.6 (15) 2 (D/E) 1 (C/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (E) TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT SGAH L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT SGAH TU15 TE19 AT 2 (D/E) 2 (D/E) S10AH TU15 TE19 AT FL L4BN AT L4BH FL L4BN AT L4BN AT Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) V11 7.3.3 (17) 8.5 (19) S9 S19 5.3.2.3 (20) 60 3.1.2 (1) (2) 1688 SODIUM CACODYLATE S9 S14 66 1689 SODIUM CYANIDE, SOLID VC1 VC2 AP7 7.5.11 (18) CV13 CV28 CV1 CV13 CV28 CV13 CV28 S9 60 1690 SODIUM FLUORIDE, SOLID S9 S19 60 1691 STRONTIUM ARSENITE S9 S14 66 1692 STRYCHNINE or STRYCHNINE SALTS S9 S14 66 1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. S9 S19 60 S9 S14 66 1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 1694 BROMOBENZYL CYANIDES, LIQUID S2 S9 S14 663 1695 CHLOROACETONE, STABILIZED S9 S19 60 S9 S14 66 1697 CHLOROACETOPHENONE, SOLID 1698 DIPHENYLAMINE CHLOROARSINE S9 S14 66 VC1 VC2 AP7 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 V10 V11 V10 V11 1 (C/E) L4BH L4BN Special provisions for carriage V11 V12 V11 1 (C/E) V10 1 (E) 2 (D/E) 2 (E) 2 (D/E) 3 (E) V1 S9 S19 1699 DIPHENYLCHLORO-ARSINE, LIQUID 1700 TEAR GAS CANDLES S9 S19 60 1701 XYLYL BROMIDE, LIQUID S9 S19 60 1702 1,1,2,2-TETRACHLOROETHANE S9 S19 60 S9 S19 60 1704 TETRAETHYL DITHIOPYROPHOSPHATE 1707 THALLIUM COMPOUND, N.O.S. S9 S19 60 1708 TOLUIDINES, LIQUID S9 60 1709 2,4-TOLUYLENEDIAMINE, SOLID CV13 CV28 S9 60 1710 TRICHLOROETHYLENE CV13 CV28 CV13 CV28 S9 S19 60 1711 XYLIDINES, LIQUID S9 S19 60 1712 ZINC ARSENATE, ZINC ARSENITE or ZINC ARSENATE AND ZINC ARSENITE MIXTURE S9 S14 66 1713 ZINC CYANIDE CV1 CV13 CV28 CV23 CV28 S14 S2 S2 S20 V12 2 (E) - 363 - 1714 ZINC PHOSPHIDE 83 1715 ACETIC ANHYDRIDE 80 1716 ACETYL BROMIDE X338 1717 ACETYL CHLORIDE 80 1718 BUTYL ACID PHOSPHATE 80 1719 CAUSTIC ALKALI LIQUID, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (1) (2) 1719 CAUSTIC ALKALI LIQUID, N.O.S. 2.2 (3a) 8 2.2 (3b) C5 2.1.1.3 (4) III 5.2.2 (5) 8 1722 ALLYL CHLOROFORMATE 6.1 TFC I 1723 ALLYL IODIDE 3 FC II 1724 ALLYLTRICHLOROSILANE, STABILIZED 1725 ALUMINIUM BROMIDE, ANHYDROUS 1726 ALUMINIUM CHLORIDE, ANHYDROUS 1727 AMMONIUM HYDROGENDIFLUORIDE, SOLID 8 CF1 II 8 C2 II 6.1 +3 +8 3 +8 8 +3 8 1728 AMYLTRICHLOROSILANE 8 C3 II 8 0 E0 P010 1729 ANISOYL CHLORIDE 8 C4 II 8 1 kg E2 P002 IBC08 P001 IBC02 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 P001 IBC02 P001 IBC02 P001 IBC02 P001 8 8 C2 C2 II II 8 588 588 8 3.4 (7a) 5L 3.5.1.2 (7b) E1 0 E0 1L E2 0 E0 1 kg E2 1 kg 1 kg E2 E2 1730 ANTIMONY PENTACHLORIDE, LIQUID 1731 ANTIMONY PENTACHLORIDE SOLUTION 1731 ANTIMONY PENTACHLORIDE SOLUTION 8 C1 II 8 1L E2 8 C1 II 8 1L E2 8 C1 III 8 5L E1 1732 ANTIMONY PENTAFLUORIDE 8 CT1 II 1L E0 1733 ANTIMONY TRICHLORIDE 8 C2 II 8 +6.1 8 1 kg E2 1736 BENZOYL CHLORIDE 8 C3 II 8 1L E2 1737 BENZYL BROMIDE 6.1 TC1 II 0 E4 1738 BENZYL CHLORIDE 6.1 TC1 II 0 E4 1739 BENZYL CHLOROFORMATE 8 C9 I 6.1 +8 6.1 +8 8 0 E0 1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. 1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. 8 C2 II 8 1 kg E2 1741 BORON TRICHLORIDE 2 2TC 1742 BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID 1743 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID 1744 BROMINE or BROMINE SOLUTION 8 C3 8 8 C2 III 8 517 517 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.3 (6) 274 Packaging E1 4.1.4 (8) P001 IBC03 R001 P001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T7 4.2.5.3 (11) TP1 TP28 MP8 MP17 T14 TP2 MP19 T7 TP2 MP15 T10 MP10 T3 TP2 TP7 TP33 MP10 T3 TP33 MP10 T3 TP33 MP15 T10 MP10 T3 TP2 TP7 TP33 MP15 T7 TP2 MP15 T7 TP2 MP19 T4 TP1 MP15 T7 TP2 MP10 T3 TP33 MP15 T8 TP2 MP15 T8 TP2 MP15 T8 TP2 MP8 MP17 MP10 T10 TP2 T3 TP33 MP10 T1 TP33 MP9 (M) P001 IBC02 P001 IBC02 MP15 T8 TP2 MP15 T8 TP2 P001 IBC02 P010 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P200 B4 B4 B4 B4 B4 B4 B3 2.3 +8 0 E0 II 8 1L E2 C3 II 8 1L E2 8 CT1 I 8 +6.1 0 E0 P804 MP2 T22 TP2 TP10 1745 BROMINE PENTAFLUORIDE 5.1 OTC I 0 E0 P200 MP2 T22 TP2 1746 BROMINE TRIFLUORIDE 5.1 OTC I 0 E0 P200 MP2 T22 TP2 1747 BUTYLTRICHLOROSILANE 8 CF1 II 0 E0 P010 MP15 T10 TP2 TP7 1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) 5.1 O2 II 5.1 +6.1 +8 5.1 +6.1 +8 8 +3 5.1 1 kg E2 P002 IBC08 314 - 364 - MP10 B4 B13 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) 9.1.1.2 (14) AT 1.1.3.6 (15) 3 (E) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L4BH FL L4BN FL SGAN AT SGAN AT SGAN AT 2 (D/E) 2 (D/E) 2 (E) 2 (E) 2 (E) L4BN AT SGAN L4BN L4BN AT AT L4BN AT L4BN AT L4BN AT SGAN L4BN L4BN AT AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L10BH AT SGAN AT SGAV AT 2 (E) 2 (E) 2 (E) 2 (E) 3 (E) 2 (E) 2 (E) 2 (E) 2 (D/E) 2 (D/E) 1 (E) 2 (E) 3 (E) AT 1 (C/D) L4BN AT L4BN AT 2 (E) 2 (E) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) 8.5 (19) 5.3.2.3 (20) 80 3.1.2 (1) (2) 1719 CAUSTIC ALKALI LIQUID, N.O.S. CV1 CV13 CV28 S2 S9 S14 668 1722 ALLYL CHLOROFORMATE S2 S20 338 1723 ALLYL IODIDE S2 X839 1724 ALLYLTRICHLOROSILANE, STABILIZED 1725 ALUMINIUM BROMIDE, ANHYDROUS 1726 ALUMINIUM CHLORIDE, ANHYDROUS 1727 AMMONIUM HYDROGENDIFLUORIDE, SOLID V11 80 V11 80 V11 80 V11 X80 1728 AMYLTRICHLOROSILANE 80 1729 ANISOYL CHLORIDE X80 1730 ANTIMONY PENTACHLORIDE, LIQUID 1731 ANTIMONY PENTACHLORIDE SOLUTION 1731 ANTIMONY PENTACHLORIDE SOLUTION 80 V12 80 CV13 CV28 86 1732 ANTIMONY PENTAFLUORIDE 80 1733 ANTIMONY TRICHLORIDE 80 1736 BENZOYL CHLORIDE S9 S19 68 1737 BENZYL BROMIDE S9 S19 68 1738 BENZYL CHLORIDE S20 88 1739 BENZYL CHLOROFORMATE 80 1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. 1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. V11 CV13 CV28 CV13 CV28 V11 VC1 VC2 AP7 80 CV9 CV10 CV36 S14 268 1741 BORON TRICHLORIDE 80 1742 BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID 1743 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID 1744 BROMINE or BROMINE SOLUTION 80 AT 1 (C/D) CV13 CV28 S14 886 L10DH TU14 TU33 TC5 TE21 TT2 TM3 TM5 TU3 AT 1 (B/E) CV24 CV28 S14 568 1745 BROMINE PENTAFLUORIDE L10DH TU3 AT 1 (B/E) CV24 CV28 S14 568 1746 BROMINE TRIFLUORIDE FL 2 (D/E) 2 (E) S2 X83 1747 BUTYLTRICHLOROSILANE 50 1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) L21DH(+) L4BN SGAN TU3 AT V11 CV24 CV35 - 365 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 5.1 2.2 (3b) O2 2.1.1.3 (4) III 1749 CHLORINE TRIFLUORIDE 2 2TOC 1750 CHLOROACETIC ACID SOLUTION 1751 CHLOROACETIC ACID, SOLID 6.1 TC1 II 6.1 TC2 II 5.2.2 (5) 5.1 2.3 +5.1 +8 6.1 +8 6.1 +8 6.1 +8 3.3 (6) 316 3.4 (7a) 5 kg 3.5.1.2 (7b) E1 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) 4.2.5.3 (11) B4 B13 0 E0 P200 MP9 (M) 100 ml E4 MP15 T7 TP2 500 g E4 MP10 T3 TP33 MP8 MP17 T20 TP2 TP35 0 E0 8 0 E0 P010 MP15 T10 I 8 0 E0 P001 T20 C1 II 8 518 1L E2 T8 TP2 8 C1 III 8 518 5L E1 MP19 T4 TP1 8 C2 II 8 1 kg E2 P001 IBC02 P001 IBC02 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P001 MP8 MP17 MP15 TP2 TP7 TP2 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 MP8 MP17 MP18 T10 TP2 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP8 MP17 MP15 T14 T11 MP19 T7 TP2 TP27 TP2 TP27 TP1 TP28 MP15 T7 TP2 6.1 TC1 I 1753 CHLOROPHENYLTRICHLOROSILANE 1754 CHLOROSULPHONIC ACID (with or without sulphur trioxide) 1755 CHROMIC ACID SOLUTION 8 C3 II 8 C1 8 1755 CHROMIC ACID SOLUTION 1756 CHROMIC FLUORIDE, SOLID 354 1757 CHROMIC FLUORIDE SOLUTION 8 C1 II 8 1L E2 1757 CHROMIC FLUORIDE SOLUTION 8 C1 III 8 5L E1 1758 CHROMIUM OXYCHLORIDE 8 C1 I 8 0 E0 1759 CORROSIVE SOLID, N.O.S. 8 C10 I 8 274 0 E0 1759 CORROSIVE SOLID, N.O.S. 8 C10 II 8 274 1 kg E2 8 C10 III 8 274 5 kg E1 1760 CORROSIVE LIQUID, N.O.S. 8 C9 I 8 274 0 E0 1760 CORROSIVE LIQUID, N.O.S. 8 C9 II 8 274 1L E2 1760 CORROSIVE LIQUID, N.O.S. 8 C9 III 8 274 5L E1 1761 CUPRIETHYLENEDIAMINE SOLUTION 1761 CUPRIETHYLENEDIAMINE SOLUTION 8 CT1 II 1L E2 8 CT1 III 8 +6.1 8 +6.1 5L E1 1762 CYCLOHEXENYLTRICHLOROSILANE 1763 CYCLOHEXYLTRICHLOROSILANE 1764 DICHLOROACETIC ACID 8 C3 II 8 0 8 C3 II 8 8 C3 II 1765 DICHLOROACETYL CHLORIDE 8 C3 1766 DICHLOROPHENYLTRICHLOROSILANE 1767 DIETHYLDICHLORO-SILANE 8 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P001 B4 B4 B4 B3 MP19 T7 TP1 TP28 E0 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 R001 P010 MP15 T10 0 E0 P010 MP15 T10 8 1L E2 MP15 T8 II 8 1L E2 MP15 T7 TP2 C3 II 8 0 E0 P001 IBC02 P001 IBC02 P010 TP2 TP7 TP2 TP7 TP2 MP15 T10 8 CF1 II 0 E0 P010 MP15 T10 1L E2 P001 IBC02 P010 MP15 T8 TP2 TP7 TP2 TP7 TP2 MP15 T10 MP10 T3 MP15 T10 1768 DIFLUOROPHOSPHORIC ACID, ANHYDROUS 1769 DIPHENYLDICHLORO-SILANE 8 C1 II 8 +3 8 8 C3 II 8 0 E0 1770 DIPHENYLMETHYL BROMIDE 8 C10 II 8 1 kg E2 1771 DODECYLTRICHLORO-SILANE 4.1.4 (8) P002 IBC08 R001 P001 IBC02 P002 IBC08 P602 1752 CHLOROACETYL CHLORIDE 1759 CORROSIVE SOLID, N.O.S. Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) Packaging 8 C3 II 8 0 - 366 - E0 P002 IBC08 P010 TP2 TP7 TP33 B4 TP2 TP7 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) SGAV 4.3.5, 6.8.4 (13) TU3 9.1.1.2 (14) AT 1.1.3.6 (15) 3 (E) PxBH(M) TA4 TT9 AT 1 (C/D) L4BH TU15 TE19 AT SGAH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 2 (D/E) 1 (C/D) L4BN AT L10BH AT L4BN AT L4BN AT SGAN AT L4BN AT L4BN AT L10BH AT S10AN L10BH SGAN L4BN SGAV L4BN AT AT AT L10BH AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN FL L4BN AT L4BN AT SGAN L4BN L4BN AT AT Special provisions for carriage 1 (E) 1 (E) 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) 2 (E) 3 (E) 2 (E) 2 (E) 2 (E) 2 (E) 2 (E) 2 (D/E) 2 (E) 2 (E) 2 (E) 2 (E) Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV24 CV35 8.5 (19) 5.3.2.3 (20) 50 3.1.2 (1) (2) 1748 CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) CV9 CV10 CV36 CV13 CV28 CV13 CV28 CV1 CV13 CV28 S14 265 1749 CHLORINE TRIFLUORIDE S9 S19 68 S9 S19 68 1750 CHLOROACETIC ACID SOLUTION 1751 CHLOROACETIC ACID, SOLID S9 S14 668 1752 CHLOROACETYL CHLORIDE X80 80 1753 CHLOROPHENYLTRICHLOROSILANE 1754 CHLOROSULPHONIC ACID (with or without sulphur trioxide) 1755 CHROMIC ACID SOLUTION 80 1755 CHROMIC ACID SOLUTION 80 1756 CHROMIC FLUORIDE, SOLID 80 1757 CHROMIC FLUORIDE SOLUTION 80 1757 CHROMIC FLUORIDE SOLUTION S20 X88 1758 CHROMIUM OXYCHLORIDE S20 88 1759 CORROSIVE SOLID, N.O.S. 80 1759 CORROSIVE SOLID, N.O.S. 80 1759 CORROSIVE SOLID, N.O.S. 88 1760 CORROSIVE LIQUID, N.O.S. 80 1760 CORROSIVE LIQUID, N.O.S. 80 1760 CORROSIVE LIQUID, N.O.S. 86 1761 CUPRIETHYLENEDIAMINE SOLUTION 1761 CUPRIETHYLENEDIAMINE SOLUTION V11 2 (E) 1 (E) 2 (E) 3 (E) 2 (E) 2 (E) 3 (E) Hazard UN No. identification No. Operation S20 V11 V12 V10 V11 VC1 VC2 AP7 S20 V12 V12 CV13 CV28 CV13 CV28 X88 86 X80 80 1762 CYCLOHEXENYLTRICHLOROSILANE 1763 CYCLOHEXYLTRICHLOROSILANE 1764 DICHLOROACETIC ACID X80 1765 DICHLOROACETYL CHLORIDE X80 1766 DICHLOROPHENYLTRICHLOROSILANE 1767 DIETHYLDICHLORO-SILANE X80 S2 X83 80 V11 - 367 - X80 1768 DIFLUOROPHOSPHORIC ACID, ANHYDROUS 1769 DIPHENYLDICHLORO-SILANE 80 1770 DIPHENYLMETHYL BROMIDE X80 1771 DODECYLTRICHLORO-SILANE UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.1.1.3 (4) III 5.2.2 (5) 8 3.3 (6) 590 3.4 (7a) 5 kg 3.1.2 (1) (2) 1773 FERRIC CHLORIDE, ANHYDROUS 2.2 (3a) 8 1774 FIRE EXTINGUISHER CHARGES, corrosive liquid 1775 FLUOROBORIC ACID 8 C11 II 8 1L E0 8 C1 II 8 1L E2 3.5.1.2 (7b) E1 4.1.4 (8) P002 IBC08 LP02 R001 P001 8 C1 II 8 1L E2 8 C1 I 8 0 E0 1778 FLUOROSILICIC ACID 8 C1 II 8 1L E2 1779 FORMIC ACID with more than 85% acid by mass 1780 FUMARYL CHLORIDE 8 CF1 II 1L E2 8 C3 II 8 +3 8 1L E2 1781 HEXADECYLTRICHLOROSILANE 1782 HEXAFLUORO-PHOSPHORIC ACID 1783 HEXAMETHYLENE-DIAMINE SOLUTION 1783 HEXAMETHYLENE-DIAMINE SOLUTION 8 C3 II 8 0 E0 8 C1 II 8 1L E2 8 C7 II 8 1L E2 8 C7 III 8 5L E1 1784 HEXYLTRICHLOROSILANE 8 C3 II 8 0 E0 P001 IBC02 P001 IBC02 P001 IBC03 LP01 R001 P010 1786 HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE 1787 HYDRIODIC ACID 8 CT1 I 0 E0 P001 8 C1 II 8 +6.1 8 1L E2 1787 HYDRIODIC ACID 8 C1 III 8 5L E1 1788 HYDROBROMIC ACID 8 C1 II 8 519 1L E2 1788 HYDROBROMIC ACID 8 C1 III 8 519 5L E1 1789 HYDROCHLORIC ACID 8 C1 II 8 520 1L E2 1789 HYDROCHLORIC ACID 8 C1 III 8 520 5L E1 1790 HYDROFLUORIC ACID with more than 85% hydrogen fluoride 8 CT1 I 8 +6.1 640I 0 E0 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P802 1790 HYDROFLUORIC ACID with more than 60% but not more than 85% hydrogen fluoride 1790 HYDROFLUORIC ACID with not more than 60% hydrogen fluoride 1791 HYPOCHLORITE SOLUTION 8 CT1 I 8 +6.1 640J 0 E0 P001 8 CT1 II 1L E2 8 C9 II 8 +6.1 8 521 1L E2 1791 HYPOCHLORITE SOLUTION 8 C9 III 8 521 5L E1 P001 IBC02 P001 IBC02 P001 IBC02 LP01 R001 P002 IBC08 P001 IBC02 LP01 R001 P002 IBC08 P001 8 C2 II 8 1793 ISOPROPYL ACID PHOSPHATE 8 C3 III 8 1794 LEAD SULPHATE with more than 3% free acid 1796 NITRATING ACID MIXTURE with more than 50% nitric acid 1796 NITRATING ACID MIXTURE with not more than 50% nitric acid 8 C2 II 8 8 CO1 I 8 C1 II 1 kg 591 8 +5.1 8 - 368 - E0 5L E1 1 kg E2 0 E0 1L E0 4.1.4 (9a) 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP15 T7 TP2 MP15 T8 TP2 MP8 MP17 MP15 T10 TP2 T8 TP2 MP15 T7 TP2 MP15 T7 TP2 MP15 T10 MP15 T8 TP2 TP7 TP2 MP15 T7 TP2 MP19 T4 TP1 MP15 T10 MP8 MP17 MP15 T10 TP2 TP7 TP2 T7 TP2 MP19 T4 TP1 MP15 T7 TP2 MP19 T4 TP1 MP15 T8 TP2 MP19 T4 TP1 MP2 T10 TP2 MP8 MP17 T10 TP2 MP15 T8 TP2 MP15 T7 MP19 T4 TP2 TP24 TP2 TP24 MP10 T7 TP2 MP19 T4 TP1 MP10 T3 TP33 MP8 MP17 MP15 T10 TP2 T8 TP2 PP4 P001 IBC02 P001 IBC02 P001 IBC02 P010 P001 IBC02 4.1.10 (9b) MP10 B3 P001 IBC02 P001 IBC02 P001 1776 FLUOROPHOSPHORIC ACID, ANHYDROUS 1777 FLUOROSULPHONIC ACID 1792 IODINE MONOCHLORIDE, SOLID Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 2.2 (3b) C2 Packaging PP81 PP10 B5 B5 B4 B4 ADR tank Tank code Special provisions 4.3 (12) SGAV 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) AT L4BN AT L4BN AT L10BH AT L4BN AT L4BN FL L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L10DH TU14 TE21 AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L21DH(+) Transport category (Tunnel restriction code) 1.1.3.6 (15) 3 (E) 2 (E) 2 (E) 2 (E) 1 (E) 2 (E) 2 (D/E) 2 (E) 2 (E) 2 (E) 2 (E) 3 (E) 2 (E) 1 (C/D) 2 (E) 3 (E) 2 (E) 3 (E) 2 (E) 3 (E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) Hazard UN No. identification No. Operation 8.5 (19) 5.3.2.3 (20) 80 80 80 S20 S2 80 1778 FLUOROSILICIC ACID 83 1779 FORMIC ACID with more than 85% acid by mass 1780 FUMARYL CHLORIDE 80 80 80 S14 V12 V12 V12 1774 FIRE EXTINGUISHER CHARGES, corrosive liquid 1775 FLUOROBORIC ACID 88 X80 CV13 CV28 3.1.2 (1) (2) 1773 FERRIC CHLORIDE, ANHYDROUS 1776 FLUOROPHOSPHORIC ACID, ANHYDROUS 1777 FLUOROSULPHONIC ACID 80 V12 Name and description 1781 HEXADECYLTRICHLOROSILANE 1782 HEXAFLUORO-PHOSPHORIC ACID 1783 HEXAMETHYLENE-DIAMINE SOLUTION 1783 HEXAMETHYLENE-DIAMINE SOLUTION X80 1784 HEXYLTRICHLOROSILANE 886 80 1786 HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE 1787 HYDRIODIC ACID 80 1787 HYDRIODIC ACID 80 1788 HYDROBROMIC ACID 80 1788 HYDROBROMIC ACID 80 1789 HYDROCHLORIC ACID 80 1789 HYDROCHLORIC ACID AT 1 (C/D) CV13 CV28 S14 886 1790 HYDROFLUORIC ACID with more than 85% hydrogen fluoride L10DH TU14 TU34 TC1 TE21 TA4 TT9 TM3 TU14 TE21 AT 1 (C/D) CV13 CV28 S14 886 L4DH TU14 TE21 AT CV13 CV28 L4BV(+) TE11 AT 80 L4BV(+) TE11 AT 2 (E) 2 (E) 3 (E) 1790 HYDROFLUORIC ACID with more than 60% but not more than 85% hydrogen fluoride 1790 HYDROFLUORIC ACID with not more than 60% hydrogen fluoride 1791 HYPOCHLORITE SOLUTION 80 1791 HYPOCHLORITE SOLUTION 80 1792 IODINE MONOCHLORIDE, SOLID 80 1793 ISOPROPYL ACID PHOSPHATE 80 1794 LEAD SULPHATE with more than 3% free acid 1796 NITRATING ACID MIXTURE with more than 50% nitric acid 1796 NITRATING ACID MIXTURE with not more than 50% nitric acid L4BN SGAN L4BN AT SGAN AT L10BH L4BN AT TC6 TT1 AT AT 2 (E) 3 (E) V11 2 (E) 1 (E) 2 (E) V11 86 VC1 VC2 AP7 CV24 S14 885 80 - 369 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (1) (2) 1798 NITROHYDROCHLORIC ACID 1799 NONYLTRICHLOROSILANE 2.2 (3a) 8 8 2.2 (3b) COT C3 2.1.1.3 (4) 5.2.2 (5) II 8 0 1800 OCTADECYLTRICHLOROSILANE 1801 OCTYLTRICHLOROSILANE 8 C3 II 8 0 E0 8 C3 II 8 0 8 CO1 II 3.5.1.2 4.1.4 4.1.4 (7b) (8) (9a) CARRIAGE PROHIBITED E0 P010 4.1.10 (9b) 4.2.5.2 (10) 4.2.5.3 (11) MP15 T10 P010 MP15 T10 E0 P010 MP15 T10 1L E0 MP3 T7 1L E2 P001 IBC02 P001 IBC02 P010 TP2 TP7 TP2 TP7 TP2 TP7 TP2 MP15 T7 TP2 MP15 T10 MP19 T4 TP2 TP7 TP1 MP10 T3 TP33 MP10 T3 TP33 MP15 T7 TP2 MP8 MP17 T20 TP2 TP35 MP8 MP17 T20 TP2 TP37 MP10 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 MP19 T7 TP1 MP15 T10 MP15 T8 TP2 TP7 TP2 MP15 T10 MP15 T7 TP2 TP7 TP2 MP19 T4 TP1 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 MP10 T3 TP33 MP8 MP17 T10 TP2 1802 PERCHLORIC ACID with not more than 50% acid, by mass 1803 PHENOLSULPHONIC ACID, LIQUID 1804 PHENYLTRICHLORO-SILANE 8 C3 II 8 +5.1 8 8 C3 II 8 0 E0 1805 PHOSPHORIC ACID, SOLUTION 8 C1 III 8 5L E1 1806 PHOSPHORUS PENTACHLORIDE 8 C2 II 8 1 kg E0 1807 PHOSPHORUS PENTOXIDE 8 C2 II 1L E0 354 0 E0 P001 IBC03 LP01 R001 P002 IBC08 P002 IBC08 P001 IBC02 P602 354 0 E0 P602 8 +6.1 1 kg E2 P002 IBC08 6.1 5 kg 8 1808 PHOSPHORUS TRIBROMIDE 8 C1 II 8 1809 PHOSPHORUS TRICHLORIDE 6.1 TC3 I 6.1 +8 1810 PHOSPHORUS OXYCHLORIDE 6.1 TC3 I 6.1 +8 1811 POTASSIUM HYDROGENDIFLUORIDE, SOLID 8 CT2 II 1812 POTASSIUM FLUORIDE, SOLID 6.1 1813 POTASSIUM HYDROXIDE, SOLID 8 T5 C6 III II 522 3.4 (7a) 1 kg 8 1 kg E2 E1 E2 1814 POTASSIUM HYDROXIDE SOLUTION 1814 POTASSIUM HYDROXIDE SOLUTION 8 C5 II 8 1L E2 8 C5 III 8 5L E1 1815 PROPIONYL CHLORIDE 3 FC II 1L E2 1816 PROPYLTRICHLORO-SILANE 8 CF1 II 0 E0 1817 PYROSULPHURYL CHLORIDE 8 C1 II 3 +8 8 +3 8 1L E2 1818 SILICON TETRACHLORIDE 8 C1 II 8 0 E0 1819 SODIUM ALUMINATE SOLUTION 8 C5 II 8 1L E2 1819 SODIUM ALUMINATE SOLUTION 8 C5 III 8 5L E1 1823 SODIUM HYDROXIDE, SOLID 8 C6 II 8 1 kg E2 1824 SODIUM HYDROXIDE SOLUTION 8 C5 II 8 1L E2 1824 SODIUM HYDROXIDE SOLUTION 8 C5 III 8 5L E1 1825 SODIUM MONOXIDE 8 C6 II 8 1 kg E2 1826 NITRATING ACID MIXTURE, SPENT, with more than 50% nitric acid 1826 NITRATING ACID MIXTURE, SPENT, with not more than 50% nitric acid 1827 STANNIC CHLORIDE, ANHYDROUS 1828 SULPHUR CHLORIDES Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.3 (6) Packaging P002 IBC08 LP02 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P010 B4 B4 B4 B3 B4 P001 IBC02 P010 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P001 B4 B4 8 CO1 I 8 +5.1 113 0 E0 8 C1 II 8 113 1L E0 P001 IBC02 MP15 T8 TP2 8 C1 II 8 1L E2 MP15 T7 TP2 8 C1 I 8 0 E0 P001 IBC02 P602 MP8 MP17 T20 TP2 - 370 - ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT L4BN AT SGAN AT SGAN AT L4BN AT Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk 1.1.3.6 7.2.4 7.3.3 (15) (16) (17) CARRIAGE PROHIBITED 2 (E) 2 (E) 2 (E) 2 (E) 2 (E) 2 (E) 3 V12 (E) 2 (E) 2 (E) 2 (E) 1 (C/D) Loading, unloading and handling 7.5.11 (18) Hazard UN No. identification No. Operation 8.5 (19) 5.3.2.3 (20) X80 X80 X80 CV24 85 80 1805 PHOSPHORIC ACID, SOLUTION V11 80 1806 PHOSPHORUS PENTACHLORIDE V11 80 1807 PHOSPHORUS PENTOXIDE X80 1808 PHOSPHORUS TRIBROMIDE AT L10CH TU14 TU15 TE19 TE21 AT 1 (C/D) AT 2 (E) AT 2 (E) SGAN AT L4BN AT L4BN AT 2 (E) 2 (E) 3 (E) L4BH FL L4BN FL L4BN AT L4BN AT L4BN AT L4BN AT SGAN AT L4BN AT L4BN AT SGAN AT L10BH AT L4BN AT 2 (E) 80 L4BN AT X80 L10BH AT 2 (E) 1 (E) TU15 TE19 2 (D/E) 2 (D/E) 2 (E) 2 (E) 2 (E) 3 (E) 2 (E) 2 (E) 3 (E) 2 (E) 1 (E) 1800 OCTADECYLTRICHLOROSILANE 1801 OCTYLTRICHLOROSILANE X80 80 TU14 TU15 TE19 TE21 SGAH 3.1.2 (1) (2) 1798 NITROHYDROCHLORIC ACID 1799 NONYLTRICHLOROSILANE 1802 PERCHLORIC ACID with not more than 50% acid, by mass 1803 PHENOLSULPHONIC ACID, LIQUID 1804 PHENYLTRICHLORO-SILANE L10CH SGAN Name and description V11 VC1 VC2 AP7 CV1 CV13 CV28 CV1 CV13 CV28 CV13 CV28 S9 S14 668 1809 PHOSPHORUS TRICHLORIDE S9 S14 X668 1810 PHOSPHORUS OXYCHLORIDE 86 1811 POTASSIUM HYDROGENDIFLUORIDE, SOLID CV13 CV28 S9 60 1812 POTASSIUM FLUORIDE, SOLID 80 1813 POTASSIUM HYDROXIDE, SOLID 80 1814 POTASSIUM HYDROXIDE SOLUTION 1814 POTASSIUM HYDROXIDE SOLUTION V11 V12 80 S2 S20 338 1815 PROPIONYL CHLORIDE S2 X83 1816 PROPYLTRICHLORO-SILANE X80 1817 PYROSULPHURYL CHLORIDE X80 1818 SILICON TETRACHLORIDE 80 1819 SODIUM ALUMINATE SOLUTION V12 80 1819 SODIUM ALUMINATE SOLUTION V11 80 1823 SODIUM HYDROXIDE, SOLID 80 1824 SODIUM HYDROXIDE SOLUTION V12 80 1824 SODIUM HYDROXIDE SOLUTION V11 80 1825 SODIUM MONOXIDE 885 1826 NITRATING ACID MIXTURE, SPENT, with more than 50% nitric acid 1826 NITRATING ACID MIXTURE, SPENT, with not more than 50% nitric acid 1827 STANNIC CHLORIDE, ANHYDROUS 1828 SULPHUR CHLORIDES CV24 S14 S20 - 371 - X88 UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 8 2.2 (3b) C1 2.1.1.3 (4) I 5.2.2 (5) 8 1830 SULPHURIC ACID with more than 51% acid 1831 SULPHURIC ACID, FUMING 8 C1 II 8 CT1 I 1832 SULPHURIC ACID, SPENT 8 C1 1833 SULPHUROUS ACID 8 1834 SULPHURYL CHLORIDE 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P001 8 1L E2 0 E0 II 8 +6.1 8 P001 IBC02 P602 1L E0 C1 II 8 1L E2 6.1 TC3 I 6.1 +8 0 E0 1835 TETRAMETHYL-AMMONIUM HYDROXIDE SOLUTION 1835 TETRAMETHYL-AMMONIUM HYDROXIDE SOLUTION 8 C7 II 8 1L E2 8 C7 III 8 5L E1 1836 THIONYL CHLORIDE 8 C1 I 8 0 E0 1837 THIOPHOSPHORYL CHLORIDE 8 C1 II 8 1L E0 1838 TITANIUM TETRACHLORIDE 6.1 TC3 I 6.1 +8 0 E0 1839 TRICHLOROACETIC ACID 8 C4 II 8 1 kg E2 1840 ZINC CHLORIDE SOLUTION 8 C1 III 8 1841 ACETALDEHYDE AMMONIA 9 M11 III 9 1843 AMMONIUM DINITRO-oCRESOLATE, SOLID 1845 Carbon dioxide, solid (Dry ice) 1846 CARBON TETRACHLORIDE 6.1 T2 II 6.1 9 6.1 M11 T1 II 6.1 1847 POTASSIUM SULPHIDE, HYDRATED with not less than 30% water of crystallization 1848 PROPIONIC ACID with not less than 10% and less than 90% acid by mass 8 C6 II 8 8 C3 III 8 1849 SODIUM SULPHIDE, HYDRATED with not less than 30% water 8 C6 II 8 1851 MEDICINE, LIQUID, TOXIC, N.O.S. 1851 MEDICINE, LIQUID, TOXIC, N.O.S. 6.1 T1 II 6.1 6.1 T1 III 6.1 1854 BARIUM ALLOYS, PYROPHORIC 4.2 S4 I 1855 CALCIUM, PYROPHORIC or CALCIUM ALLOYS, PYROPHORIC 1856 Rags, oily 1857 Textile waste, wet 1858 HEXAFLUOROPROPYLENE (REFRIGERANT GAS R 1216) 4.2 S4 I 4.2 4.2 2 S2 S2 2A 4.1.10 (9b) MP8 MP17 4.2.5.2 (10) T20 4.2.5.3 (11) TP4 TP25 TP26 MP15 T8 TP2 MP8 MP17 MP15 T20 TP2 T8 TP2 MP15 T7 TP2 MP8 MP17 T20 TP2 MP15 T7 TP2 MP19 T7 TP2 MP8 MP17 MP15 T10 TP2 T7 TP2 MP8 MP17 T20 TP2 TP37 P002 MP10 IBC08 B4 5L E1 P001 MP19 IBC03 LP01 R001 5 kg E1 P002 MP10 IBC08 B3 B6 LP02 R001 500 g E4 P002 MP10 IBC08 B4 NOT SUBJECT TO ADR - When used as a coolant, see 5.5.3 100 ml E4 P001 MP15 IBC02 523 1 kg E2 P002 MP10 IBC08 B4 T3 TP33 T4 TP1 T1 TP33 T3 TP33 T7 TP2 T3 TP33 MP19 T4 TP1 MP10 T3 TP33 T21 TP7 TP33 1859 SILICON TETRAFLUORIDE 2 2TC 2.3 +8 1860 VINYL FLUORIDE, STABILIZED 2 2F 2.1 1862 ETHYL CROTONATE 3 F1 113 354 354 523 221 601 221 601 5L E1 1 kg E2 4.1.4 (9a) P001 IBC02 P001 IBC02 P602 P001 IBC02 P001 IBC03 LP01 R001 P802 P001 IBC02 P602 P001 IBC03 LP01 R001 P002 IBC08 B4 100 ml E4 P001 MP15 5L E1 MP19 4.2 0 E0 P001 LP01 R001 P404 MP13 4.2 0 E0 P404 MP13 2.2 II 3.3 (6) 623 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1829 SULPHUR TRIOXIDE, STABILIZED Packaging 662 662 3 - 372 - 120 ml NOT SUBJECT TO ADR NOT SUBJECT TO ADR E1 P200 MP9 (M) T50 0 E0 P200 MP9 (M) 0 E0 P200 MP9 (M) 1L E2 P001 IBC02 R001 MP19 T4 TP2 ADR tank Tank code Special provisions 4.3 (12) L10BH 4.3.5, 6.8.4 (13) TU32 TE13 TT5 TM3 Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) AT 1.1.3.6 (15) 1 (E) L4BN AT L10BH AT L4BN AT L4BN AT 2 (E) 1 (C/D) 2 (E) 2 (E) 1 (C/D) L10CH TU14 TU15 TE19 TE21 AT L4BN AT L4BN AT L10BH AT L4BN AT L10CH TU14 TU15 TE19 TE21 AT SGAN L4BN L4BN AT AT SGAV AT SGAH TU15 TE19 L4BH TU15 TE19 SGAN L4BN 2 (E) 3 (E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) 8.5 (19) S20 5.3.2.3 (20) X88 80 CV13 CV28 CV1 CV13 CV28 S14 S9 S14 V12 S20 Name and description 3.1.2 (1) (2) 1829 SULPHUR TRIOXIDE, STABILIZED X886 1830 SULPHURIC ACID with more than 51% acid 1831 SULPHURIC ACID, FUMING 80 1832 SULPHURIC ACID, SPENT 80 1833 SULPHUROUS ACID X668 1834 SULPHURYL CHLORIDE 80 1835 TETRAMETHYL-AMMONIUM HYDROXIDE SOLUTION 1835 TETRAMETHYL-AMMONIUM HYDROXIDE SOLUTION 80 1 (E) 2 (E) 1 (C/D) 2 (E) 3 (E) Hazard UN No. identification No. Operation X88 1836 THIONYL CHLORIDE X80 1837 THIOPHOSPHORYL CHLORIDE X668 1838 TITANIUM TETRACHLORIDE V11 80 1839 TRICHLOROACETIC ACID V12 80 1840 ZINC CHLORIDE SOLUTION 90 1841 ACETALDEHYDE AMMONIA S9 S19 60 S9 S19 60 1843 AMMONIUM DINITRO-oCRESOLATE, SOLID 1845 Carbon dioxide, solid (Dry ice) 1846 CARBON TETRACHLORIDE CV1 CV13 CV28 3 (E) S9 S14 VC1 VC2 AT 2 V11 CV13 (D/E) CV28 NOT SUBJECT TO ADR - When used as a coolant, see 5.5.3 AT 2 CV13 (D/E) CV28 AT 2 V11 (E) 80 1847 POTASSIUM SULPHIDE, HYDRATED with not less than 30% water of crystallization 1848 PROPIONIC ACID with not less than 10% and less than 90% acid by mass L4BN AT 3 (E) V12 80 SGAN L4BN AT 2 (E) V11 80 1849 SODIUM SULPHIDE, HYDRATED with not less than 30% water 2 (D/E) 2 (E) S9 S19 60 S9 60 1851 MEDICINE, LIQUID, TOXIC, N.O.S. 1851 MEDICINE, LIQUID, TOXIC, N.O.S. L4BH TU15 TE19 AT L4BH TU15 TE19 AT AT 0 (B/E) 0 (E) CV13 CV28 CV13 CV28 V1 S20 1854 BARIUM ALLOYS, PYROPHORIC 43 V1 S20 NOT SUBJECT TO ADR NOT SUBJECT TO ADR PxBN(M) TA4 TT9 AT 3 (C/E) PxBH(M) TA4 TT9 AT 1 (C/D) PxBN(M) TA4 TT9 FL 2 (B/D) FL 2 (D/E) LGBF CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 - 373 - 20 1855 CALCIUM, PYROPHORIC or CALCIUM ALLOYS, PYROPHORIC 1856 Rags, oily 1857 Textile waste, wet 1858 HEXAFLUOROPROPYLENE (REFRIGERANT GAS R 1216) S14 268 1859 SILICON TETRAFLUORIDE S2 S20 239 1860 VINYL FLUORIDE, STABILIZED S2 S20 33 1862 ETHYL CROTONATE UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1863 FUEL, AVIATION, TURBINE ENGINE 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) I 5.2.2 (5) 3 3.3 (6) 363 664 3.4 (7a) 500 ml 3.5.1.2 (7b) E3 4.1.4 (8) P001 1863 FUEL, AVIATION, TURBINE ENGINE (vapour pressure at 50 °C more than 110 kPa) 1863 FUEL, AVIATION, TURBINE ENGINE (vapour pressure at 50 °C not more than 110 kPa) 1863 FUEL, AVIATION, TURBINE ENGINE 3 F1 II 3 1L E2 3 F1 II 3 1L E2 3 F1 III 3 363 640C 664 363 640D 664 363 664 5L E1 1865 n-PROPYL NITRATE 3 F1 II 3 1L E2 4.1.10 (9b) MP7 MP17 4.2.5.2 (10) T11 4.2.5.3 (11) TP1 TP8 TP28 TP1 TP8 P001 MP19 T4 MP19 T4 TP1 TP8 MP19 T2 TP1 MP7 MP17 T11 TP1 TP8 TP28 TP1 TP8 500 ml E3 640C 5L E2 P001 PP1 MP19 T4 3 640D 5L E2 PP1 MP19 T4 TP1 TP8 III 3 640E 5L E1 PP1 MP19 T2 TP1 F1 III 3 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 R001 PP1 MP19 3 F1 III 3 5L E1 P001 IBC02 R001 PP1 BB4 MP19 4.1 FT2 II 1 kg E0 T3 TP33 F3 III 5 kg E1 P002 IBC06 P002 IBC08 LP02 R001 P403 MP10 4.1 4.1 +6.1 4.1 MP11 T1 TP33 MP11 T3 TP33 MP2 T1 TP33 MP3 T10 TP1 MP10 T1 TP33 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 MP19 T7 TP2 MP18 T6 TP33 MP15 T7 TP2 3 F1 I 3 1866 RESIN SOLUTION, flammable (vapour pressure at 50 °C more than 110 kPa) 1866 RESIN SOLUTION, flammable (vapour pressure at 50 °C not more than 110 kPa) 1866 RESIN SOLUTION, flammable 3 F1 II 3 3 F1 II 3 F1 1866 RESIN SOLUTION, flammable (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 1866 RESIN SOLUTION, flammable (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1868 DECABORANE 3 1869 MAGNESIUM or MAGNESIUM ALLOYS with more than 50% magnesium in pellets, turnings or ribbons 1870 POTASSIUM BOROHYDRIDE 4.3 W2 I 4.3 0 E0 1871 TITANIUM HYDRIDE 4.1 F3 II 4.1 1 kg E2 1872 LEAD DIOXIDE 5.1 OT2 III 5.1 +6.1 5 kg E1 1885 BENZIDINE 4.1.4 (9a) P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 1866 RESIN SOLUTION, flammable 1873 PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass 1884 BARIUM OXIDE Portable tanks and bulk containers 5.1 OC1 I 5.1 +8 6.1 T5 III 6.1 6.1 T2 II 59 60 6.1 0 E0 5 kg E1 500 g E4 1886 BENZYLIDENE CHLORIDE 6.1 T1 II 6.1 100 ml E4 1887 BROMOCHLOROMETHANE 6.1 T1 III 6.1 5L E1 1888 CHLOROFORM 6.1 T1 III 6.1 5L E1 1889 CYANOGEN BROMIDE 6.1 TC2 I 6.1 +8 0 E0 1891 ETHYL BROMIDE 6.1 T1 II 6.1 100 ml E4 - 374 - P410 IBC04 P002 IBC08 LP02 R001 P502 P002 IBC08 LP02 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P002 P001 IBC02 MP19 B7 B3 MP2 PP40 B3 PP28 B3 B4 B8 ADR tank Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 1 (D/E) L1.5BN FL LGBF LGBF Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation 8.5 (19) S2 S20 5.3.2.3 (20) 33 2 (D/E) S2 S20 33 FL 2 (D/E) S2 S20 33 FL 3 (D/E) S2 30 V12 2 (E) S2 S20 Name and description 3.1.2 (1) (2) 1863 FUEL, AVIATION, TURBINE ENGINE 1863 FUEL, AVIATION, TURBINE ENGINE (vapour pressure at 50 °C more than 110 kPa) 1863 FUEL, AVIATION, TURBINE ENGINE (vapour pressure at 50 °C not more than 110 kPa) 1863 FUEL, AVIATION, TURBINE ENGINE 1865 n-PROPYL NITRATE L4BN FL 1 (D/E) S2 S20 33 1866 RESIN SOLUTION, flammable L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1866 RESIN SOLUTION, flammable (vapour pressure at 50 °C more than 110 kPa) 1866 RESIN SOLUTION, flammable (vapour pressure at 50 °C not more than 110 kPa) 1866 RESIN SOLUTION, flammable 46 1866 RESIN SOLUTION, flammable (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 1866 RESIN SOLUTION, flammable (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1868 DECABORANE SGAN AT SGAV AT SGAN AT V12 3 (E) S2 3 (E) S2 2 (E) 3 (E) V11 1 (E) 2 (E) 3 (E) V1 SGAN TU3 AT L4DN(+) TU3 TU28 AT 1 (B/E) SGAH L4BH TU15 TE19 AT 2 (E) SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (E) L4BH TU15 TE19 AT 2 (E) S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) CV28 VC1 VC2 CV23 V11 V12 V12 1869 MAGNESIUM or MAGNESIUM ALLOYS with more than 50% magnesium in pellets, turnings or ribbons 1870 POTASSIUM BOROHYDRIDE 40 1871 TITANIUM HYDRIDE 56 1872 LEAD DIOXIDE S20 CV24 CV28 VC1 VC2 AP7 40 CV24 S20 558 CV13 CV28 S9 60 1873 PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass 1884 BARIUM OXIDE CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 1885 BENZIDINE S9 S19 60 1886 BENZYLIDENE CHLORIDE S9 60 1887 BROMOCHLOROMETHANE CV13 CV28 S9 60 1888 CHLOROFORM CV1 CV13 CV28 CV13 CV28 S9 S14 668 1889 CYANOGEN BROMIDE S9 S19 60 1891 ETHYL BROMIDE - 375 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) T3 2.1.1.3 (4) I 5.2.2 (5) 6.1 1894 PHENYLMERCURIC HYDROXIDE 6.1 T3 II 6.1 1895 PHENYLMERCURIC NITRATE 6.1 T3 II 3.3 (6) 354 6.1 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P602 500 g E4 P002 IBC08 P002 IBC08 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 500 g Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1892 ETHYLDICHLOROARSINE Packaging E4 4.1.4 (9a) 4.1.10 (9b) MP8 MP17 4.2.5.2 (10) T20 4.2.5.3 (11) TP2 TP37 MP10 T3 TP33 MP10 T3 TP33 MP19 T4 TP1 MP15 T7 TP2 MP19 T4 TP1 MP18 T6 TP33 MP15 T8 MP10 T1 TP2 TP28 TP33 MP15 T7 MP19 T4 B4 B4 1897 TETRACHLOROETHYLENE 6.1 T1 III 6.1 5L E1 1898 ACETYL IODIDE 8 C3 II 8 1L E2 1902 DIISOOCTYL ACID PHOSPHATE 8 C3 III 8 5L E1 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 8 C9 I 8 274 0 E0 8 C9 II 8 274 1L E2 8 C9 III 8 274 5L 1905 SELENIC ACID 8 C2 I 8 0 1906 SLUDGE ACID 8 C1 II 8 1L 1907 SODA LIME with more than 4% sodium hydroxide 8 C6 III 8 62 5 kg 1908 CHLORITE SOLUTION 8 C9 II 8 521 1L 1908 CHLORITE SOLUTION 8 C9 III 8 521 5L 1910 Calcium oxide 1911 DIBORANE 8 2 C6 2TF 1912 METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE 1913 NEON, REFRIGERATED LIQUID 2 2F 2.1 228 662 0 E0 P200 MP9 (M) T50 2 3A 2.2 593 120 ml E1 P203 MP9 T75 TP5 1914 BUTYL PROPIONATES 3 F1 III 3 5L E1 MP19 T2 TP1 1915 CYCLOHEXANONE 3 F1 III 3 5L E1 MP19 T2 TP1 1916 2,2'-DICHLORODIETHYL ETHER 6.1 TF1 II 100 ml E4 MP15 T7 TP2 1917 ETHYL ACRYLATE, STABILIZED 3 F1 II 6.1 +3 3 1L E2 MP19 T4 TP1 1918 ISOPROPYLBENZENE 3 F1 III 3 5L E1 MP19 T2 TP1 1919 METHYL ACRYLATE, STABILIZED 3 F1 II 3 1L E2 MP19 T4 TP1 1920 NONANES 3 F1 III 3 5L E1 MP19 T2 TP1 1921 PROPYLENEIMINE, STABILIZED 3 FT1 I 0 E0 MP2 T14 TP2 1922 PYRROLIDINE 3 FC II 3 +6.1 3 +8 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 1L E2 MP19 T7 TP1 2.3 +2.1 0 - 376 - P001 IBC02 E1 P001 IBC03 LP01 R001 E0 P002 IBC07 E0 P001 IBC02 E1 P002 IBC08 B3 LP02 R001 E2 P001 IBC02 E1 P001 IBC03 LP01 R001 NOT SUBJECT TO ADR E0 P200 P001 IBC02 MP8 MP17 MP15 MP19 TP2 TP24 TP2 TP24 MP9 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) L10CH 4.3.5, 6.8.4 (13) TU14 TU15 TE19 TE21 9.1.1.2 (14) AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT L4BH TU15 TE19 AT L4BN AT L4BN AT L10BH AT L4BN AT L4BN AT S10AN AT L4BN AT SGAV AT L4BV(+) TE11 AT L4BV(+) TE11 AT Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (C/D) 7.2.4 (16) 7.3.3 (17) 2 (D/E) 2 (D/E) 2 (E) V11 7.5.11 (18) CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) 2 (E) 3 (E) V11 V12 RxBN TU19 TA4 TT9 AT 3 (C/E) V5 LGBF FL 3 (D/E) LGBF FL 3 (D/E) FL 2 (D/E) 2 (D/E) FL 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) FL 1 (C/E) 2 (D/E) L15CH L4BH TU14 TU15 TE21 FL S9 S19 60 1895 PHENYLMERCURIC NITRATE S9 60 1897 TETRACHLOROETHYLENE 80 1898 ACETYL IODIDE 80 1902 DIISOOCTYL ACID PHOSPHATE 88 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 80 S20 V12 2 (B/D) LGBF 1894 PHENYLMERCURIC HYDROXIDE VC1 VC2 AP7 FL FL 60 V12 TA4 TT9 LGBF S9 S19 80 PxBN(M) TU15 TE19 5.3.2.3 (20) 66 S20 V10 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV11 CV36 Name and description 8.5 (19) S9 S14 V12 NOT SUBJECT TO ADR 1 (D) L4BH Hazard UN No. identification No. Operation 3.1.2 (1) (2) 1892 ETHYLDICHLOROARSINE 88 1905 SELENIC ACID 80 1906 SLUDGE ACID 80 1907 SODA LIME with more than 4% sodium hydroxide 80 1908 CHLORITE SOLUTION 80 1908 CHLORITE SOLUTION 1910 Calcium oxide 1911 DIBORANE S2 S14 S2 S20 23 S20 22 1912 METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE 1913 NEON, REFRIGERATED LIQUID V12 S2 30 1914 BUTYL PROPIONATES V12 S2 30 1915 CYCLOHEXANONE S2 S9 S19 63 1916 2,2'-DICHLORODIETHYL ETHER S2 S20 339 1917 ETHYL ACRYLATE, STABILIZED S2 30 1918 ISOPROPYLBENZENE S2 S20 339 1919 METHYL ACRYLATE, STABILIZED S2 30 1920 NONANES S2 S22 336 1921 PROPYLENEIMINE, STABILIZED S2 S20 338 1922 PYRROLIDINE CV13 CV28 V12 V12 CV13 CV28 - 377 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 4.2 2.2 (3b) S4 2.1.1.3 (4) II 5.2.2 (5) 4.2 4.3 WF1 I 1929 POTASSIUM DITHIONITE (POTASSIUM HYDROSULPHITE) 4.2 S4 1931 ZINC DITHIONITE (ZINC HYDROSULPHITE) 9 M11 1932 ZIRCONIUM SCRAP 4.2 S4 3.4 (7a) 0 3.5.1.2 (7b) E2 4.3 +3 0 E0 II 4.2 0 E2 P410 IBC06 III 9 5 kg E1 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P001 III 4.2 3.3 (6) 524 592 0 E0 1935 CYANIDE SOLUTION, N.O.S. 6.1 T4 I 6.1 274 525 0 E5 1935 CYANIDE SOLUTION, N.O.S. 6.1 T4 II 6.1 100 ml E4 1935 CYANIDE SOLUTION, N.O.S. 6.1 T4 III 6.1 274 525 274 525 5L E1 1938 BROMOACETIC ACID SOLUTION 8 C3 II 8 1L E2 1938 BROMOACETIC ACID SOLUTION 8 C3 III 8 5L E1 1939 PHOSPHORUS OXYBROMIDE 8 C2 II 8 1 kg E0 1940 THIOGLYCOLIC ACID 8 C3 II 8 1L E2 1941 DIBROMODIFLUORO-METHANE 9 M11 III 9 5L E1 1942 AMMONIUM NITRATE with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance 1944 MATCHES, SAFETY (book, card or strike on box) 1945 MATCHES, WAX 'VESTA' 5.1 O2 III 5.1 306 611 5 kg E1 4.1 F1 III 4.1 293 5 kg E1 4.1 F1 III 4.1 293 5 kg E1 1950 AEROSOLS, asphyxiant 2 5A 2.2 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 1L E0 1950 AEROSOLS, corrosive 1950 AEROSOLS, corrosive, oxidizing 1950 AEROSOLS, flammable 1950 AEROSOLS, flammable, corrosive 1950 AEROSOLS, oxidizing 1950 AEROSOLS, toxic 2 2 2 2 2 2 5C 5CO 5F 5FC 5O 5T 2.2 +8 2.2 +5.1 +8 2.1 2.1 +8 2.2 +5.1 2.2 +6.1 - 378 - 4.1.4 (8) P410 IBC06 P402 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 LP01 R001 P002 IBC08 P001 IBC02 P001 LP01 R001 P002 IBC08 LP02 R001 P407 R001 P407 R001 P207 LP02 1L E0 P207 LP02 1L E0 P207 LP02 1L E0 P207 LP02 1L E0 P207 LP02 1L E0 P207 LP02 120 ml Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1923 CALCIUM DITHIONITE (CALCIUM HYDROSULPHITE) 1928 METHYL MAGNESIUM BROMIDE IN ETHYL ETHER Packaging E0 P207 LP02 4.1.4 (9a) 4.1.10 (9b) MP14 4.2.5.2 (10) T3 4.2.5.3 (11) TP33 RR8 MP2 MP14 T3 TP33 MP10 T1 TP33 MP14 T1 TP33 MP8 MP17 T14 TP2 TP27 MP15 T11 MP19 T7 TP2 TP27 TP2 TP28 MP15 T7 TP2 MP19 T7 TP2 MP10 T3 TP33 MP15 T7 TP2 MP15 T11 TP2 MP10 T1 BK1 BK2 TP33 B3 B3 B4 B3 MP11 MP11 PP87 RR6 L2 MP9 PP87 RR6 L2 MP9 PP87 RR6 L2 MP9 PP87 RR6 L2 MP9 PP87 RR6 L2 MP9 PP87 RR6 L2 MP9 PP87 RR6 L2 MP9 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) SGAN 4.3.5, 6.8.4 (13) 9.1.1.2 (14) AT L10DH TU4 TU14 TU22 TE21 TM2 FL Transport category (Tunnel restriction code) Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (D/E) 0 (B/E) 7.2.4 (16) V1 7.3.3 (17) 7.5.11 (18) 8.5 (19) 5.3.2.3 (20) 40 CV23 S2 S20 X323 V1 AT 2 (D/E) SGAV AT 3 (E) SGAN AT 3 (E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) AT L4BN AT SGAN AT L4BN AT L4BN AT SGAV TU3 AT Hazard UN No. identification No. Operation Packages SGAN L4BN Special provisions for carriage V1 V1 1929 POTASSIUM DITHIONITE (POTASSIUM HYDROSULPHITE) VC1 VC2 90 1931 ZINC DITHIONITE (ZINC HYDROSULPHITE) VC1 VC2 AP1 40 1932 ZIRCONIUM SCRAP S9 S14 66 1935 CYANIDE SOLUTION, N.O.S. S9 S19 60 1935 CYANIDE SOLUTION, N.O.S. S9 60 1935 CYANIDE SOLUTION, N.O.S. 80 1938 BROMOACETIC ACID SOLUTION 80 1938 BROMOACETIC ACID SOLUTION 80 1939 PHOSPHORUS OXYBROMIDE 80 1940 THIOGLYCOLIC ACID 90 1941 DIBROMODIFLUORO-METHANE 50 1942 AMMONIUM NITRATE with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance 1944 MATCHES, SAFETY (book, card or strike on box) 1945 MATCHES, WAX 'VESTA' CV1 CV13 CV28 CV13 CV28 CV13 CV28 V12 V11 3 (E) 4 (E) 4 (E) 3 (E) 3.1.2 (1) (2) 1923 CALCIUM DITHIONITE (CALCIUM HYDROSULPHITE) 1928 METHYL MAGNESIUM BROMIDE IN ETHYL ETHER 40 2 (E) 3 (E) 2 (E) 2 (E) 3 (E) Name and description VC1 VC2 AP6 AP7 CV24 S23 V14 CV9 CV12 1950 AEROSOLS, asphyxiant 1 (E) V14 CV9 CV12 1950 AEROSOLS, corrosive 1 (E) V14 CV9 CV12 1950 AEROSOLS, corrosive, oxidizing 2 (D) V14 CV9 CV12 S2 1950 AEROSOLS, flammable 1 (D) V14 CV9 CV12 S2 1950 AEROSOLS, flammable, corrosive 3 (E) V14 CV9 CV12 1950 AEROSOLS, oxidizing 1 (D) V14 CV9 CV12 CV28 1950 AEROSOLS, toxic - 379 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 1950 AEROSOLS, toxic, flammable 1950 AEROSOLS, toxic, flammable, corrosive 1950 AEROSOLS, toxic, oxidizing 1950 AEROSOLS, toxic, oxidizing, corrosive 2.2 (3a) 2 2 2 2 2 2.2 (3b) 5TC 5TF 5TFC 5TO 5TOC 2.1.1.3 (4) 5.2.2 (5) 2.2 +6.1 +8 2.1 +6.1 2.1 +6.1 +8 2.2 +5.1 +6.1 3.4 (7a) 120 ml 3.3 (6) 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 190 327 344 625 593 3.5.1.2 (7b) E0 4.1.4 (8) P207 120 ml E1 P203 LP02 120 ml E0 P207 LP02 120 ml E0 P207 LP02 120 ml Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1950 AEROSOLS, toxic, corrosive Packaging E0 P207 LP02 4.1.4 (9a) PP87 RR6 L2 4.1.10 (9b) MP9 4.2.5.2 (10) 4.2.5.3 (11) PP87 RR6 L2 MP9 PP87 RR6 L2 MP9 PP87 RR6 L2 MP9 PP87 RR6 L2 MP9 MP9 T75 TP5 1951 ARGON, REFRIGERATED LIQUID 2 3A 2.2 +5.1 +6.1 +8 2.2 1952 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide 2 2A 2.2 662 120 ml E1 P200 MP9 (M) 1953 COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. 2 1TF 2.3 +2.1 274 0 E0 P200 MP9 (M) 1954 COMPRESSED GAS, FLAMMABLE, N.O.S. 2 1F 2.1 0 E0 P200 MP9 (M) 1955 COMPRESSED GAS, TOXIC, N.O.S. 2 1T 2.3 274 660 662 274 0 E0 P200 MP9 (M) 1956 COMPRESSED GAS, N.O.S. 2 1A 2.2 120 ml E1 P200 MP9 (M) 1957 DEUTERIUM, COMPRESSED 2 1F 2.1 274 655 662 662 0 E0 P200 MP9 (M) 1958 1,2-DICHLORO-1,1,2,2TETRAFLUOROETHANE (REFRIGERANT GAS R 114) 1959 1,1-DIFLUOROETHYLENE (REFRIGERANT GAS R 1132a) 1961 ETHANE, REFRIGERATED LIQUID 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 2 2F 2.1 662 0 E0 P200 MP9 (M) 2 3F 2.1 0 E0 P203 MP9 T75 1962 ETHYLENE 2 2F 2.1 662 0 E0 P200 MP9 (M) 1963 HELIUM, REFRIGERATED LIQUID 2 3A 2.2 593 120 ml E1 P203 MP9 T75 1964 HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. 2 1F 2.1 274 662 0 E0 P200 MP9 (M) 1965 HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. such as mixtures A, A01, A02, A0, A1, B1, B2, B or C 2 2F 2.1 274 583 652 660 662 0 E0 P200 MP9 (M) T50 1966 HYDROGEN, REFRIGERATED LIQUID 2 3F 2.1 0 E0 P203 MP9 T75 1967 INSECTICIDE GAS, TOXIC, N.O.S. 2 2T 2.3 274 0 E0 P200 MP9 (M) 1968 INSECTICIDE GAS, N.O.S. 2 2A 2.2 274 662 120 ml E1 P200 MP9 (M) 1969 ISOBUTANE 2 2F 2.1 657 660 662 0 E0 P200 MP9 (M) T50 - 380 - 120 ml E0 P207 LP02 TP5 TP5 TP34 TP5 TP23 TP34 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (D) 7.2.4 (16) V14 7.3.3 (17) 7.5.11 (18) CV9 CV12 CV28 8.5 (19) 1 (D) V14 CV9 CV12 CV28 S2 1950 AEROSOLS, toxic, flammable 1 (D) V14 CV9 CV12 CV28 S2 1950 AEROSOLS, toxic, flammable, corrosive 1 (D) V14 CV9 CV12 CV28 1950 AEROSOLS, toxic, oxidizing 1 (D) V14 CV9 CV12 CV28 1950 AEROSOLS, toxic, oxidizing, corrosive AT 3 (C/E) V5 S20 AT 3 (C/E) CV9 CV11 CV36 CV9 CV10 CV36 TU6 TA4 TT9 TA4 TT9 FL 1 (B/D) FL 2 (B/D) TU6 TA4 TT9 TA4 TT9 AT 1 (C/D) AT 3 (E) CxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 FL 2 (B/D) RxBN TU18 TA4 TT9 TA4 TT9 FL 2 (B/D) FL 2 (B/D) TU19 TA4 TT9 TA4 TT9 AT 3 (C/E) FL 2 (B/D) PxBN(M) TA4 TT9 TT11 FL 2 (B/D) CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 RxBN TU18 TA4 TT9 TU6 TA4 TT9 TA4 TT9 FL 2 (B/D) AT 1 (C/D) AT 3 (C/E) FL 2 (B/D) RxBN PxBN(M) CxBH(M) CxBN(M) CxBH(M) CxBN(M) PxBN(M) RxBN CxBN(M) PxBH(M) PxBN(M) PxBN(M) TU19 TA4 TT9 TA4 TT9 TA4 TT9 TT11 9.1.1.2 (14) V5 V5 V5 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 - 381 - 5.3.2.3 (20) 3.1.2 (1) (2) 1950 AEROSOLS, toxic, corrosive 22 1951 ARGON, REFRIGERATED LIQUID 20 1952 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide S2 S14 263 1953 COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. S2 S20 23 1954 COMPRESSED GAS, FLAMMABLE, N.O.S. S14 26 1955 COMPRESSED GAS, TOXIC, N.O.S. 20 1956 COMPRESSED GAS, N.O.S. 23 1957 DEUTERIUM, COMPRESSED 20 1958 1,2-DICHLORO-1,1,2,2TETRAFLUOROETHANE (REFRIGERANT GAS R 114) 1959 1,1-DIFLUOROETHYLENE (REFRIGERANT GAS R 1132a) 1961 ETHANE, REFRIGERATED LIQUID S2 S20 S2 S20 239 S2 S17 223 S2 S20 23 1962 ETHYLENE S20 22 1963 HELIUM, REFRIGERATED LIQUID S2 S20 23 1964 HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. S2 S20 23 1965 HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. such as mixtures A, A01, A02, A0, A1, B1, B2, B or C S2 S17 223 1966 HYDROGEN, REFRIGERATED LIQUID S14 26 1967 INSECTICIDE GAS, TOXIC, N.O.S. 20 1968 INSECTICIDE GAS, N.O.S. 23 1969 ISOBUTANE S2 S20 UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 3A 1971 METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content 1972 METHANE, REFRIGERATED LIQUID or NATURAL GAS, REFRIGERATED LIQUID with high methane content 1973 CHLORODIFLUORO-METHANE AND CHLOROPENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502) 1974 CHLORODIFLUOROBROMOMETHANE (REFRIGERANT GAS R 12B1) 1975 NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE (NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE) 2 5.2.2 (5) 2.2 3.3 (6) 593 3.4 (7a) 120 ml 3.5.1.2 (7b) E1 4.1.4 (8) P203 4.1.10 (9b) MP9 4.2.5.2 (10) T75 1F 2.1 660 662 0 E0 P200 MP9 (M) 2 3F 2.1 660 0 E0 P203 MP9 T75 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 2 2TOC 2.3 +5.1 +8 0 E0 P200 MP9 1976 OCTAFLUOROCYCLO-BUTANE (REFRIGERANT GAS RC 318) 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 1977 NITROGEN, REFRIGERATED LIQUID 2 3A 2.2 120 ml E1 P203 MP9 T75 0 E0 P200 MP9 (M) T50 2.2 345 346 593 652 657 660 662 662 1978 PROPANE 2 2F 2.1 1982 TETRAFLUOROMETHANE (REFRIGERANT GAS R 14) 2 2A 120 ml E1 P200 MP9 (M) 1983 1-CHLORO-2,2,2TRIFLUOROETHANE (REFRIGERANT GAS R 133a) 1984 TRIFLUOROMETHANE (REFRIGERANT GAS R 23) 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 2 2A 2.2 662 120 ml E1 P200 MP9 (M) 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 3 FT1 I 274 0 E0 P001 FT1 II 274 1L E2 T11 3 FT1 III 274 5L E1 MP19 T7 3 F1 II 3 1L E2 MP19 T7 3 F1 II 3 1L E2 MP19 T7 3 F1 III 3 274 601 640C 274 601 640D 274 601 P001 IBC02 P001 IBC03 R001 P001 MP7 MP17 MP19 T14 3 3 +6.1 3 +6.1 3 +6.1 5L E1 MP19 T4 3 FT1 I 274 0 E0 FT1 II 274 1L E2 T11 3 FT1 III 274 5L E1 MP19 T7 1989 ALDEHYDES, N.O.S. 3 F1 I 3 274 0 E3 P001 IBC02 P001 IBC03 R001 P001 MP7 MP17 MP19 T14 3 3 +6.1 3 +6.1 3 +6.1 T11 1989 ALDEHYDES, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1989 ALDEHYDES, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 3 F1 II 3 274 640C 1L E2 P001 MP7 MP17 MP19 3 F1 II 3 274 640D 1L E2 P001 IBC02 R001 MP19 T7 1987 ALCOHOLS, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1987 ALCOHOLS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1987 ALCOHOLS, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1970 KRYPTON, REFRIGERATED LIQUID Packaging - 382 - P001 IBC02 R001 P001 IBC03 LP01 R001 P001 4.1.4 (9a) T7 4.2.5.3 (11) TP5 TP5 TP5 TP2 TP27 TP2 TP27 TP1 TP28 TP1 TP8 TP28 TP1 TP8 TP28 TP1 TP29 TP2 TP27 TP2 TP27 TP1 TP28 TP1 TP27 TP1 TP8 TP28 TP1 TP8 TP28 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Tank code Special provisions 4.3 (12) RxBN 4.3.5, 6.8.4 (13) TU19 TA4 TT9 TA4 TT9 9.1.1.2 (14) AT 1.1.3.6 (15) 3 (C/E) FL 2 (B/D) RxBN TU18 TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 20 PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 CV9 CV10 CV36 20 CxBN(M) Packages Bulk Loading, unloading and handling 7.2.4 (16) V5 7.3.3 (17) 7.5.11 (18) CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV11 CV36 Hazard UN No. identification No. Operation V5 1 (D) PxBN(M) TA4 TT9 AT 3 (C/E) RxBN TU19 TA4 TT9 TA4 TT9 TT11 AT 3 (C/E) FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 AT 3 (C/E) L10CH FL L4BH TU14 TU15 TE21 TU15 L4BH TU15 FL 1 (C/E) 2 (D/E) 3 (D/E) PxBN(M) FL V5 V12 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV13 CV28 CV13 CV28 CV13 CV28 8.5 (19) S20 5.3.2.3 (20) 22 S2 S20 23 S2 S17 223 S14 Name and description 3.1.2 (1) (2) 1970 KRYPTON, REFRIGERATED LIQUID 1971 METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content 1972 METHANE, REFRIGERATED LIQUID or NATURAL GAS, REFRIGERATED LIQUID with high methane content 1973 CHLORODIFLUORO-METHANE AND CHLOROPENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502) 1974 CHLORODIFLUOROBROMOMETHANE (REFRIGERANT GAS R 12B1) 1975 NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE (NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE) 20 1976 OCTAFLUOROCYCLO-BUTANE (REFRIGERANT GAS RC 318) S20 22 1977 NITROGEN, REFRIGERATED LIQUID S2 S20 23 1978 PROPANE 20 1982 TETRAFLUOROMETHANE (REFRIGERANT GAS R 14) 20 1983 1-CHLORO-2,2,2TRIFLUOROETHANE (REFRIGERANT GAS R 133a) 1984 TRIFLUOROMETHANE (REFRIGERANT GAS R 23) 20 S2 S22 336 S2 S22 336 S2 36 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 FL 336 S2 S22 336 L4BH TU15 FL 1 (C/E) 2 (D/E) 3 (D/E) S2 S22 L4BH TU14 TU15 TE21 TU15 S2 36 S2 S20 33 1989 ALDEHYDES, N.O.S. S2 S20 33 S2 S20 33 1989 ALDEHYDES, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1989 ALDEHYDES, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) L10CH FL L4BN FL L1.5BN FL LGBF FL V12 V12 CV13 CV28 CV13 CV28 CV13 CV28 1 (D/E) 2 (D/E) 2 (D/E) - 383 - 1987 ALCOHOLS, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1987 ALCOHOLS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1987 ALCOHOLS, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) III 5.2.2 (5) 3 1990 BENZALDEHYDE 9 M11 III 1991 CHLOROPRENE, STABILIZED 3 FT1 I 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 3 FT1 I 3 FT1 II 3 FT1 III 1993 FLAMMABLE LIQUID, N.O.S. 3 F1 I 1993 FLAMMABLE LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1993 FLAMMABLE LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1993 FLAMMABLE LIQUID, N.O.S. 3 F1 3 1993 FLAMMABLE LIQUID, N.O.S. (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 1993 FLAMMABLE LIQUID, N.O.S. (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1994 IRON PENTACARBONYL 3.3 (6) 274 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 1989 ALDEHYDES, N.O.S. Packaging 3.4 (7a) 5L 3.5.1.2 (7b) E1 9 5L E1 3 +6.1 3 +6.1 3 +6.1 3 +6.1 0 E0 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 274 0 E0 P001 274 1L E2 274 5L E1 3 274 0 E3 P001 IBC02 P001 IBC03 R001 P001 II 3 1L E2 P001 F1 II 3 1L E2 3 F1 III 3 274 601 640C 274 601 640D 274 601 640E 5L E1 3 F1 III 3 274 601 5L E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 R001 3 F1 III 3 274 601 5L E1 P001 IBC02 R001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 TP29 MP15 T2 TP1 MP7 MP17 MP7 MP17 MP19 T14 TP2 TP6 TP2 TP27 TP2 MP19 T7 TP1 TP28 MP7 MP17 MP19 T11 MP19 T7 MP19 T4 TP1 TP27 TP1 TP8 TP28 TP1 TP8 TP28 TP1 TP29 T14 T7 T7 MP19 MP19 BB4 6.1 TF1 I 6.1 +3 354 0 E0 P601 MP2 T22 TP2 1999 TARS, LIQUID, including road oils, and cutback bitumens (vapour pressure at 50 °C more than 110 kPa) 3 F1 II 3 640C 5L E2 P001 MP19 T3 TP3 TP29 1999 TARS, LIQUID, including road oils, and cutback bitumens (vapour pressure at 50 °C not more than 110 kPa) 1999 TARS, LIQUID, including road oils, and cutback bitumens 3 F1 II 3 640D 5L E2 P001 IBC02 R001 MP19 T3 TP3 TP29 3 F1 III 3 640E 5L E1 MP19 T1 TP3 1999 TARS, LIQUID, including road oils, and cutback bitumens (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 F1 III 3 5L E1 P001 IBC03 LP01 R001 P001 R001 1999 TARS, LIQUID, including road oils, and cutback bitumens (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 2000 CELLULOID in block, rods, rolls, sheets, tubes, etc., except scrap 3 F1 III 3 5L E1 T1 TP33 4.1 F1 III 4.1 2001 COBALT NAPHTHENATES, POWDER 4.1 F3 III 4.1 2002 CELLULOID, SCRAP 4.2 S2 III 4.2 502 526 592 - 384 - 5 kg E1 5 kg E1 0 E0 P001 IBC02 R001 P002 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 MP19 MP19 BB4 PP7 MP11 MP11 B3 PP8 B3 MP14 ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.3.3 (17) 7.5.11 (18) 9.1.1.2 (14) FL 1.1.3.6 (15) 3 (D/E) 7.2.4 (16) V12 AT 3 (E) V12 FL L4BH TU14 TU15 TE21 TU14 TU15 TE21 TU15 L4BH TU15 FL 1 (C/E) 1 (C/E) 2 (D/E) 3 (D/E) LGBV L10CH L10CH FL FL L4BN FL L1.5BN FL LGBF FL 2 (D/E) LGBF FL 3 (D/E) L15CH TU14 TU15 TU31 TE19 TE21 TM3 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 V12 1 (D/E) 2 (D/E) V12 Hazard UN No. identification No. Operation 8.5 (19) S2 5.3.2.3 (20) 30 3.1.2 (1) (2) 1989 ALDEHYDES, N.O.S. 90 1990 BENZALDEHYDE S2 S22 336 1991 CHLOROPRENE, STABILIZED S2 S22 336 S2 S22 336 S2 36 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. S2 S20 33 1993 FLAMMABLE LIQUID, N.O.S. S2 S20 33 S2 S20 33 S2 30 1993 FLAMMABLE LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 1993 FLAMMABLE LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 1993 FLAMMABLE LIQUID, N.O.S. S2 S9 S14 663 1993 FLAMMABLE LIQUID, N.O.S. (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 1993 FLAMMABLE LIQUID, N.O.S. (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 1994 IRON PENTACARBONYL 3 (E) S2 3 (E) S2 CV1 CV13 CV28 Name and description FL 1 (C/D) L1.5BN FL 2 (D/E) S2 S20 33 1999 TARS, LIQUID, including road oils, and cutback bitumens (vapour pressure at 50 °C more than 110 kPa) LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 1999 TARS, LIQUID, including road oils, and cutback bitumens (vapour pressure at 50 °C not more than 110 kPa) 1999 TARS, LIQUID, including road oils, and cutback bitumens V12 3 (E) S2 1999 TARS, LIQUID, including road oils, and cutback bitumens (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 (E) S2 1999 TARS, LIQUID, including road oils, and cutback bitumens (having a flashpoint below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 2000 CELLULOID in block, rods, rolls, sheets, tubes, etc., except scrap 3 (E) SGAV AT 3 (E) 3 (E) VC1 VC2 40 V1 2001 COBALT NAPHTHENATES, POWDER 2002 CELLULOID, SCRAP - 385 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2004 MAGNESIUM DIAMIDE 2.2 (3a) 4.2 2.2 (3b) S4 2.1.1.3 (4) II 5.2.2 (5) 4.2 3.3 (6) 3.4 (7a) 0 3.5.1.2 (7b) E2 2006 PLASTICS, NITROCELLULOSEBASED, SELF-HEATING, N.O.S. 2008 ZIRCONIUM POWDER, DRY 4.2 S2 III 4.2 0 E0 4.2 S4 I 4.2 0 E0 2008 ZIRCONIUM POWDER, DRY 4.2 S4 II 4.2 0 E2 2008 ZIRCONIUM POWDER, DRY 4.2 S4 III 4.2 274 528 524 540 524 540 524 540 0 E1 4.1.4 (8) P410 IBC06 P002 R001 P404 4.1.4 (9a) 4.1.10 (9b) MP14 4.2.5.2 (10) T3 4.2.5.3 (11) TP33 MP13 T21 MP14 T3 TP7 TP33 TP33 MP14 T1 TP33 MP15 T7 TP2 TP6 TP24 MP14 0 E1 4.3 0 E0 P410 IBC06 P002 IBC08 LP02 R001 P002 LP02 R001 P403 4.3 +6.1 4.3 +6.1 4.3 +6.1 5.1 +8 0 E0 P403 MP2 0 E0 P403 MP2 0 E0 P403 MP2 1L E2 P504 IBC02 640N 0 E0 P501 MP2 T9 TP2 TP6 TP24 640O 0 E0 P501 MP2 T9 TP2 TP6 TP24 6.1 0 E0 P600 MP10 6.1 +8 0 E0 P600 6.1 500 g E4 P002 IBC08 P001 IBC02 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 P001 MP10 T3 TP33 MP15 T7 TP2 MP10 T1 TP33 MP19 T4 TP1 MP15 T7 TP2 MP15 T7 TP2 MP18 T6 TP33 MP10 T3 TP33 2009 ZIRCONIUM, DRY, finished sheets, strip or coiled wire 4.2 S4 III 4.2 2010 MAGNESIUM HYDRIDE 4.3 W2 I 2011 MAGNESIUM PHOSPHIDE 4.3 WT2 I 2012 POTASSIUM PHOSPHIDE 4.3 WT2 I 2013 STRONTIUM PHOSPHIDE 4.3 WT2 I 2014 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) 2015 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 70% hydrogen peroxide 2015 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 60% hydrogen peroxide and not more than 70% hydrogen peroxide 5.1 OC1 II 5.1 OC1 I 5.1 +8 5.1 OC1 I 5.1 +8 2016 AMMUNITION, TOXIC, NONEXPLOSIVE without burster or expelling charge, non-fuzed 2017 AMMUNITION, TEARPRODUCING, NON-EXPLOSIVE without burster or expelling charge, non-fuzed 2018 CHLOROANILINES, SOLID 6.1 T2 6.1 TC2 6.1 T2 II Packaging 2019 CHLOROANILINES, LIQUID 6.1 T1 II 6.1 2020 CHLOROPHENOLS, SOLID 6.1 T2 III 6.1 524 592 205 100 ml E4 5 kg E1 2021 CHLOROPHENOLS, LIQUID 6.1 T1 III 6.1 5L E1 2022 CRESYLIC ACID 6.1 TC1 II 100 ml E4 2023 EPICHLOROHYDRIN 6.1 TF1 II 279 100 ml E4 2024 MERCURY COMPOUND, LIQUID, N.O.S. 6.1 T4 I 6.1 +8 6.1 +3 6.1 43 274 0 E5 2024 MERCURY COMPOUND, LIQUID, N.O.S. 2024 MERCURY COMPOUND, LIQUID, N.O.S. 6.1 T4 II 6.1 100 ml E4 6.1 T4 III 6.1 43 274 43 274 5L E1 2025 MERCURY COMPOUND, SOLID, N.O.S. 6.1 T5 I 6.1 0 E5 2025 MERCURY COMPOUND, SOLID, N.O.S. 6.1 T5 II 6.1 43 66 274 529 43 66 274 529 500 g E4 - 386 - B3 MP14 MP2 PP10 B5 B4 B3 MP8 MP17 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC07 P002 IBC08 MP15 MP19 B4 ADR tank Tank code Special provisions 4.3 (12) SGAN 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) AT AT SGAN AT SGAN AT Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (D/E) 3 (E) 0 (B/E) 2 (D/E) 3 (E) 7.2.4 (16) V1 7.3.3 (17) 7.5.11 (18) V1 3 (E) V1 1 (E) 1 (E) 1 (E) 1 (E) 2 (E) V1 CV23 S20 2010 MAGNESIUM HYDRIDE V1 CV23 CV28 CV23 CV28 CV23 CV28 CV24 S20 2011 MAGNESIUM PHOSPHIDE S20 2012 POTASSIUM PHOSPHIDE S20 2013 STRONTIUM PHOSPHIDE 8.5 (19) 5.3.2.3 (20) 40 V1 V1 3.1.2 (1) (2) 2004 MAGNESIUM DIAMIDE 2006 PLASTICS, NITROCELLULOSEBASED, SELF-HEATING, N.O.S. 2008 ZIRCONIUM POWDER, DRY S20 43 40 2008 ZIRCONIUM POWDER, DRY VC1 VC2 AP1 40 2008 ZIRCONIUM POWDER, DRY VC1 VC2 AP1 40 2009 ZIRCONIUM, DRY, finished sheets, strip or coiled wire V1 V1 V1 L4BV(+) TU3 TC2 TE8 TE11 TT1 AT L4DV(+) TU3 TU28 TC2 TE8 TE9 TT1 OX 1 (B/E) V5 CV24 S20 559 L4BV(+) TU3 TU28 TC2 TE7 TE8 TE9 TT1 OX 1 (B/E) V5 CV24 S20 559 2 (D/E) CV13 CV28 S9 S19 2 (D/E) CV13 CV28 S9 S19 CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 2016 AMMUNITION, TOXIC, NONEXPLOSIVE without burster or expelling charge, non-fuzed 2017 AMMUNITION, TEARPRODUCING, NON-EXPLOSIVE without burster or expelling charge, non-fuzed 2018 CHLOROANILINES, SOLID S9 S19 60 2019 CHLOROANILINES, LIQUID S9 60 2020 CHLOROPHENOLS, SOLID CV13 CV28 S9 60 2021 CHLOROPHENOLS, LIQUID CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 68 2022 CRESYLIC ACID S2 S9 S19 63 2023 EPICHLOROHYDRIN S9 S14 66 2024 MERCURY COMPOUND, LIQUID, N.O.S. S9 S19 60 S9 60 2024 MERCURY COMPOUND, LIQUID, N.O.S. 2024 MERCURY COMPOUND, LIQUID, N.O.S. SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT SGAH TU15 TE19 AT L4BH TU15 TE19 L4BH 58 2014 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) 2015 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 70% hydrogen peroxide 2015 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 60% hydrogen peroxide and not more than 70% hydrogen peroxide 2 (D/E) 2 (D/E) 2 (E) V11 AT 2 (E) V12 TU15 TE19 AT L4BH TU15 TE19 FL L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 2 (D/E) 1 (C/E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT S10AH TU15 TE19 AT 1 (C/E) V10 CV1 CV13 CV28 S9 S14 66 2025 MERCURY COMPOUND, SOLID, N.O.S. SGAH TU15 TE19 AT 2 (D/E) V11 CV13 CV28 S9 S19 60 2025 MERCURY COMPOUND, SOLID, N.O.S. 2 (D/E) 2 (E) VC1 VC2 AP7 V12 - 387 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) T5 2.1.1.3 (4) III 5.2.2 (5) 6.1 2026 PHENYLMERCURIC COMPOUND, N.O.S. 6.1 T3 I 6.1 2026 PHENYLMERCURIC COMPOUND, N.O.S. 2026 PHENYLMERCURIC COMPOUND, N.O.S. 6.1 T3 II 6.1 2027 SODIUM ARSENITE, SOLID 6.1 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2025 MERCURY COMPOUND, SOLID, N.O.S. Packaging 3.3 (6) 43 66 274 529 43 274 3.4 (7a) 5 kg 3.5.1.2 (7b) E1 0 E5 43 274 43 274 500 g E4 43 500 g 4.1.4 (8) P002 IBC08 LP02 R001 P002 IBC07 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 B3 8 C11 II 8 0 E0 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P803 8 CFT I 0 E0 P001 MP8 MP17 8 CT1 I 8 +3 +6.1 8 +6.1 530 0 E0 P001 MP8 MP17 T10 TP2 8 CT1 II 8 +6.1 530 1L E0 P001 IBC02 MP15 T7 TP2 8 CT1 III 8 +6.1 530 5L E1 MP19 T4 TP1 2031 NITRIC ACID, other than red fuming, with more than 70% nitric acid 2031 NITRIC ACID, other than red fuming, with at least 65%, but not more than 70% nitric acid 2031 NITRIC ACID, other than red fuming, with less than 65% nitric acid 8 CO1 I 8 +5.1 0 E0 P001 IBC03 LP01 R001 P001 PP81 MP8 MP17 T10 TP2 8 CO1 II 8 +5.1 1L E2 P001 IBC02 PP81 B15 MP15 T8 TP2 8 C1 II 8 1L E2 P001 IBC02 PP81 B15 MP15 T8 TP2 2032 NITRIC ACID, RED FUMING 8 COT I 0 E0 P602 MP8 MP17 T20 TP2 2033 POTASSIUM MONOXIDE 8 C6 II 8 +5.1 +6.1 8 1 kg E2 MP10 T3 TP33 MP9 (M) 2028 BOMBS, SMOKE, NONEXPLOSIVE with corrosive liquid, without initiating device 2029 HYDRAZINE, ANHYDROUS 2030 HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass 2030 HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass 2030 HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass 6.1 T3 T5 III II 6.1 6.1 5 kg E1 E4 B4 B3 B4 2034 HYDROGEN AND METHANE MIXTURE, COMPRESSED 2 1F 2.1 662 0 E0 P002 IBC08 P200 2035 1,1,1-TRIFLUOROETHANE (REFRIGERANT GAS R 143a) 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 2036 XENON 2 2A 2.2 662 120 ml E1 P200 MP9 (M) 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2 5A 2.2 191 303 344 1L E0 P003 PP17 RR6 MP9 2 5F 2.1 191 303 344 1L E0 P003 PP17 RR6 MP9 2 5O 2.2 +5.1 191 303 344 1L E0 P003 PP17 RR6 MP9 2 5T 2.3 303 344 120 ml E0 P003 PP17 RR6 MP9 2 5TC 2.3 +8 303 344 120 ml E0 P003 PP17 RR6 MP9 2 5TF 2.3 +2.1 303 344 120 ml E0 P003 PP17 RR6 MP9 - 388 - B4 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) SGAH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT S10AH L10CH TU14 TU15 TE19 TE21 SGAH L4BH SGAH L4BH SGAH Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (E) 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) CV13 CV28 8.5 (19) S9 5.3.2.3 (20) 60 AT 1 (C/E) V10 S9 S14 66 2026 PHENYLMERCURIC COMPOUND, N.O.S. TU15 TE19 AT V11 S9 S19 60 TU15 TE19 AT 2 (D/E) 2 (E) VC1 VC2 AP7 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 60 2026 PHENYLMERCURIC COMPOUND, N.O.S. 2026 PHENYLMERCURIC COMPOUND, N.O.S. TU15 TE19 AT 2 (D/E) 2 (E) V11 S9 S19 60 CV13 CV28 1 (E) CV13 CV28 S2 S14 S14 AT 1 (C/D) CV13 CV28 L4BN AT 2 (E) CV13 CV28 86 L4BN AT 3 (E) CV13 CV28 86 AT 1 (E) L4BN AT 2 (E) 85 L4BN AT 2 (E) 80 AT 1 (C/D) AT 2 (E) 2 (B/D) L10BH TC6 TT1 TC6 TT1 SGAN CxBN(M) TA4 TT9 FL PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) V12 CV24 CV13 CV24 CV28 S14 S14 V11 3.1.2 (1) (2) 2025 MERCURY COMPOUND, SOLID, N.O.S. 2027 SODIUM ARSENITE, SOLID 2028 BOMBS, SMOKE, NONEXPLOSIVE with corrosive liquid, without initiating device 2029 HYDRAZINE, ANHYDROUS L10BH L10BH Name and description 886 885 2030 HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass 2030 HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass 2030 HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass 2031 NITRIC ACID, other than red fuming, with more than 70% nitric acid 2031 NITRIC ACID, other than red fuming, with at least 65%, but not more than 70% nitric acid 2031 NITRIC ACID, other than red fuming, with less than 65% nitric acid 856 2032 NITRIC ACID, RED FUMING 80 2033 POTASSIUM MONOXIDE S2 S20 23 2034 HYDROGEN AND METHANE MIXTURE, COMPRESSED S2 S20 23 2035 1,1,1-TRIFLUOROETHANE (REFRIGERANT GAS R 143a) 20 2036 XENON 3 (E) CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV12 2 (D) CV9 CV12 S2 3 (E) CV9 CV12 1 (D) CV9 CV12 1 (D) CV9 CV12 1 (D) CV9 CV12 - 389 - S2 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 5TFC 2 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2038 DINITROTOLUENES, LIQUID Packaging 5.2.2 (5) 2.3 +2.1 +8 3.3 (6) 303 344 3.4 (7a) 120 ml 3.5.1.2 (7b) E0 4.1.4 (8) P003 4.1.4 (9a) PP17 RR6 4.1.10 (9b) MP9 5TO 2.3 +5.1 303 344 120 ml E0 P003 PP17 RR6 MP9 2 5TOC 2.3 +5.1 +8 303 344 120 ml E0 P003 PP17 RR6 MP9 6.1 T1 100 ml E4 2044 2,2-DIMETHYLPROPANE 2 2F 0 E0 P001 IBC02 P200 2045 ISOBUTYRALDEHYDE (ISOBUTYL ALDEHYDE) 3 F1 II 3 1L E2 2046 CYMENES 3 F1 III 3 5L E1 2047 DICHLOROPROPENES 3 F1 II 3 1L E2 2047 DICHLOROPROPENES 3 F1 III 3 5L E1 2048 DICYCLOPENTADIENE 3 F1 III 3 5L E1 2049 DIETHYLBENZENE 3 F1 III 3 5L E1 2050 DIISOBUTYLENE, ISOMERIC COMPOUNDS 3 F1 II 3 1L E2 2051 2-DIMETHYLAMINOETHANOL 2052 DIPENTENE 8 CF1 II 1L E2 3 F1 III 8 +3 3 5L E1 2053 METHYL ISOBUTYL CARBINOL 3 F1 III 3 5L E1 2054 MORPHOLINE 8 CF1 I 0 E0 2055 STYRENE MONOMER, STABILIZED 3 F1 III 8 +3 3 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 5L E1 2056 TETRAHYDROFURAN 3 F1 II 3 1L E2 2057 TRIPROPYLENE 3 F1 II 3 1L E2 2057 TRIPROPYLENE 3 F1 III 3 5L E1 2058 VALERALDEHYDE 3 F1 II 3 1L E2 2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose 3 D I 3 0 E0 II 6.1 2.1 662 198 531 - 390 - P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 4.2.5.2 (10) 4.2.5.3 (11) MP15 T7 TP2 MP9 (M) MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T4 TP1 MP15 T7 TP2 MP19 T2 TP1 MP19 T2 TP1 MP8 MP17 MP19 T10 TP2 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP7 MP17 T11 TP1 TP8 TP27 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) L4BH TU15 TE19 AT PxBN(M) TA4 TT9 FL Transport category (Tunnel restriction code) 1.1.3.6 (15) 1 (D) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV9 CV12 1 (D) CV9 CV12 1 (D) CV9 CV12 2 (D/E) 2 (B/D) CV13 CV28 CV9 CV10 CV36 Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 5.3.2.3 (20) S9 S19 60 3.1.2 (1) (2) 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2037 RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable 2038 DINITROTOLUENES, LIQUID S2 S20 23 2044 2,2-DIMETHYLPROPANE S2 S20 33 2045 ISOBUTYRALDEHYDE (ISOBUTYL ALDEHYDE) S2 30 2046 CYMENES S2 S20 33 2047 DICHLOROPROPENES LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) V12 S2 30 2047 DICHLOROPROPENES LGBF FL 3 (D/E) V12 S2 30 2048 DICYCLOPENTADIENE LGBF FL 3 (D/E) V12 S2 30 2049 DIETHYLBENZENE LGBF FL 2 (D/E) S2 S20 33 2050 DIISOBUTYLENE, ISOMERIC COMPOUNDS L4BN FL S2 83 LGBF FL 2 (D/E) 3 (D/E) V12 S2 30 2051 2-DIMETHYLAMINOETHANOL 2052 DIPENTENE LGBF FL 3 (D/E) V12 S2 30 2053 METHYL ISOBUTYL CARBINOL L10BH FL S2 S14 883 2054 MORPHOLINE LGBF FL 1 (D/E) 3 (D/E) S2 39 2055 STYRENE MONOMER, STABILIZED LGBF FL 2 (D/E) S2 S20 33 2056 TETRAHYDROFURAN LGBF FL 2 (D/E) S2 S20 33 2057 TRIPROPYLENE LGBF FL 3 (D/E) S2 30 2057 TRIPROPYLENE LGBF FL 2 (D/E) S2 S20 33 2058 VALERALDEHYDE L4BN FL 1 (B) S2 S14 33 2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose V12 V12 V12 - 391 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose (vapour pressure at 50 °C more than 110 kPa) 2.2 (3a) 3 2.2 (3b) D 2.1.1.3 (4) II 5.2.2 (5) 3 3.3 (6) 198 531 640C 3.4 (7a) 1L 3.5.1.2 (7b) E0 4.1.4 (8) P001 IBC02 2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose (vapour pressure at 50 °C not more than 110 kPa) 2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose 3 D II 3 198 531 640D 1L E0 3 D III 3 198 531 5L E0 2067 AMMONIUM NITRATE BASED FERTILIZER 5.1 O2 III 5.1 186 306 307 5 kg E1 2071 Ammonium nitrate based fertilizer, uniform mixtures of the nitrogen/phosphate, nitrogen/potash or nitrogen/phosphate/potash type, containing not more than 70% ammonium nitrate and not more than 0.4% total combustible/organic material calculated as carbon or with not more than 45% ammonium nitrate and unrestricted combustible material 9 M11 2073 AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 35% but not more than 50% ammonia 2074 ACRYLAMIDE, SOLID 2 4A 2.2 532 120 ml E0 6.1 T2 III 6.1 5 kg E1 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 TP8 P001 IBC02 R001 MP19 T4 TP1 TP8 P001 IBC03 LP01 R001 MP19 T2 TP1 MP10 T1 BK1 BK2 TP33 MP9 (M) MP10 T1 TP33 MP15 T7 TP2 MP15 T7 TP2 MP10 T1 TP33 MP15 T7 TP2 MP15 T7 TP2 T75 TP5 P002 IBC08 B3 LP02 R001 NOT SUBJECT TO ADR P200 P002 IBC08 B3 LP02 R001 E4 P001 IBC02 E4 P001 IBC02 E1 P002 IBC08 B3 LP02 R001 E4 P001 IBC02 E2 P001 IBC02 CARRIAGE PROHIBITED 2075 CHLORAL, ANHYDROUS, STABILIZED 2076 CRESOLS, LIQUID 6.1 T1 II 6.1 100 ml 6.1 TC1 II 100 ml 2077 alpha-NAPHTHYLAMINE 6.1 T2 III 6.1 +8 6.1 2078 TOLUENE DIISOCYANATE 6.1 T1 II 6.1 2079 DIETHYLENETRIAMINE 8 C7 II 8 1L 2186 HYDROGEN CHLORIDE, REFRIGERATED LIQUID 2187 CARBON DIOXIDE, REFRIGERATED LIQUID 2 3TC 2 3A 2.2 120 ml E1 P203 MP9 2188 ARSINE 2 2TF 2.3 +2.1 0 E0 P200 MP9 2189 DICHLOROSILANE 2 2TFC 0 E0 P200 MP9 2190 OXYGEN DIFLUORIDE, COMPRESSED 2 1TOC 0 E0 P200 MP9 2191 SULPHURYL FLUORIDE 2 2T 2.3 +2.1 +8 2.3 +5.1 +8 2.3 0 E0 P200 MP9 (M) 2192 GERMANE 2 2TF 2.3 +2.1 632 0 E0 P200 MP9 (M) 2193 HEXAFLUOROETHANE (REFRIGERANT GAS R 116) 2 2A 2.2 662 120 ml E1 P200 MP9 (M) 5 kg 279 - 392 - 100 ml (M) ADR tank Tank code Special provisions 4.3 (12) L1.5BN 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 2 (B) LGBF FL 2 (B) LGBF FL 3 (B) AT 3 (E) SGAV TU3 Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) V12 VC1 VC2 AP6 AP7 CV24 Hazard UN No. identification No. Operation 8.5 (19) S2 S14 5.3.2.3 (20) 33 3.1.2 (1) (2) 2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose (vapour pressure at 50 °C more than 110 kPa) S2 S14 33 S2 S14 30 2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose (vapour pressure at 50 °C not more than 110 kPa) 2059 NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose S23 50 NOT SUBJECT TO ADR PxBN(M) TA4 TT9 AT 3 (E) SGAH L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT SGAH L4BH TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (E) L4BH TU15 TE19 AT L4BN RxBN AT TU19 TA4 TT9 AT TA4 TT9 FL PxBN(M) TA4 TT9 TA4 TT9 2071 Ammonium nitrate based fertilizer, uniform mixtures of the nitrogen/phosphate, nitrogen/potash or nitrogen/phosphate/potash type, containing not more than 70% ammonium nitrate and not more than 0.4% total combustible/organic material calculated as carbon or with not more than 45% ammonium nitrate and unrestricted combustible material CV9 CV10 20 2073 AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 35% but not more than 50% ammonia 2074 ACRYLAMIDE, SOLID CV13 CV28 S9 60 S9 S19 69 S9 S19 68 2075 CHLORAL, ANHYDROUS, STABILIZED 2076 CRESOLS, LIQUID VC1 VC2 AP7 CV13 CV28 CV13 CV28 CV13 CV28 S9 60 2077 alpha-NAPHTHYLAMINE 2 (D/E) 2 (E) CARRIAGE PROHIBITED CV13 CV28 S9 S19 60 2078 TOLUENE DIISOCYANATE 80 2079 DIETHYLENETRIAMINE 3 (C/E) CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 1 (B/D) 1 (D) PxBH(M) 2067 AMMONIUM NITRATE BASED FERTILIZER VC1 VC2 AP7 1 (D) PxBH(M) Name and description AT 1 (C/D) FL 1 (B/D) AT 3 (C/E) V5 - 393 - S20 22 S2 S14 S2 S14 2186 HYDROGEN CHLORIDE, REFRIGERATED LIQUID 2187 CARBON DIOXIDE, REFRIGERATED LIQUID 2188 ARSINE 263 S14 2189 DICHLOROSILANE 2190 OXYGEN DIFLUORIDE, COMPRESSED S14 26 2191 SULPHURYL FLUORIDE S2 S14 263 2192 GERMANE 20 2193 HEXAFLUOROETHANE (REFRIGERANT GAS R 116) UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 2TC 2195 TELLURIUM HEXAFLUORIDE 2 2TC 2196 TUNGSTEN HEXAFLUORIDE 2 2197 HYDROGEN IODIDE, ANHYDROUS 2.1.1.3 (4) 5.2.2 (5) 2.3 +8 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2194 SELENIUM HEXAFLUORIDE Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P200 2.3 +8 0 E0 P200 MP9 2TC 2.3 +8 0 E0 P200 MP9 2 2TC 2.3 +8 0 E0 P200 MP9 2198 PHOSPHORUS PENTAFLUORIDE 2 2TC 2.3 +8 0 E0 P200 MP9 2199 PHOSPHINE 2 2TF 2.3 +2.1 632 0 E0 P200 MP9 2200 PROPADIENE, STABILIZED 2 2F 2.1 662 0 E0 P200 MP9 (M) 2201 NITROUS OXIDE, REFRIGERATED LIQUID 2 3O 2.2 +5.1 0 E0 P203 MP9 T75 2202 HYDROGEN SELENIDE, ANHYDROUS 2 2TF 2.3 +2.1 0 E0 P200 MP9 2203 SILANE 2 2F 2.1 0 E0 P200 MP9 (M) 2204 CARBONYL SULPHIDE 2 2TF 2.3 +2.1 0 E0 P200 MP9 (M) 2205 ADIPONITRILE 6.1 T1 III 6.1 5L E1 MP19 T3 TP1 2206 ISOCYANATES, TOXIC, N.O.S. or 6.1 ISOCYANATE SOLUTION, TOXIC, N.O.S. 2206 ISOCYANATES, TOXIC, N.O.S. or 6.1 ISOCYANATE SOLUTION, TOXIC, N.O.S. T1 II 6.1 274 551 100 ml E4 P001 IBC03 LP01 R001 P001 IBC02 MP15 T11 TP2 TP27 T1 III 6.1 274 551 5L E1 MP19 T7 TP1 TP28 2208 CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 10% but not more than 39% available chlorine 2209 FORMALDEHYDE SOLUTION with not less than 25% formaldehyde 5.1 O2 III 5.1 314 5 kg E1 8 C9 III 8 533 5L E1 MP19 T4 TP1 2210 MANEB or MANEB PREPARATION with not less than 60% maneb 2211 POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour 2212 ASBESTOS, AMPHIBOLE (amosite, tremolite, actinolite, anthophyllite, crocidolite) 2213 PARAFORMALDEHYDE 4.2 SW III 4.2 +4.3 273 0 E1 MP14 T1 TP33 9 M3 III None 207 633 5 kg E1 PP14 B3 B6 MP10 T1 TP33 9 M1 II 9 168 274 1 kg E0 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P002 IBC06 R001 P002 IBC08 R001 P002 IBC08 PP37 B4 MP10 T3 TP33 4.1 F1 III 4.1 5 kg E1 PP12 B3 MP10 T1 BK1 BK2 TP33 2214 PHTHALIC ANHYDRIDE with more than 0.05% of maleic anhydride 8 C4 III 8 5 kg E1 MP10 T1 TP33 2215 MALEIC ANHYDRIDE, MOLTEN 8 C3 III 8 0 E0 T4 TP3 2215 MALEIC ANHYDRIDE 8 C4 III 8 5 kg E1 T1 TP33 2216 Fish meal (Fish scrap), stabilized 9 M11 632 662 169 - 394 - P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 4.1.4 (9a) 4.1.10 (9b) MP9 4.2.5.2 (10) 4.2.5.3 (11) (M) TP5 TP22 MP10 B3 B13 L3 B3 P002 IBC08 B3 R001 NOT SUBJECT TO ADR MP10 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) 1.1.3.6 (15) 1 (D) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV13 CV28 1 (D) 1 (D) PxBH(M) TA4 TT9 AT 1 (C/D) 1 (D) 1 (D) PxBN(M) TA4 TT9 FL 2 (B/D) RxBN TU7 TU19 TA4 TT9 AT 3 (C/E) V5 1 (D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBH(M) TA4 TT9 FL 1 (B/D) L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) SGAN TU3 AT 3 (E) L4BN AT 3 (E) V12 SGAN AT 3 (E) V1 V12 V12 Hazard UN No. identification No. Operation 8.5 (19) S14 TE20 AT 3 (D/E) SGAH TU15 AT 2 (E) V11 SGAV AT 3 (E) V13 SGAV L4BN AT 3 (E) L4BN AT SGAV AT 0 (E) 3 (E) 3.1.2 (1) (2) 2194 SELENIUM HEXAFLUORIDE S14 2195 TELLURIUM HEXAFLUORIDE S14 2196 TUNGSTEN HEXAFLUORIDE S14 268 2197 HYDROGEN IODIDE, ANHYDROUS S14 2198 PHOSPHORUS PENTAFLUORIDE S2 S14 2199 PHOSPHINE S2 S20 239 2200 PROPADIENE, STABILIZED S20 225 2201 NITROUS OXIDE, REFRIGERATED LIQUID S2 S14 2202 HYDROGEN SELENIDE, ANHYDROUS S2 S20 23 2203 SILANE S2 S14 263 2204 CARBONYL SULPHIDE S9 60 2205 ADIPONITRILE CV13 CV28 S9 S19 60 CV13 CV28 S9 60 2206 ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. 2206 ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. CV24 CV35 SGAN 5.3.2.3 (20) Name and description 50 80 VC1 VC2 AP1 40 VC1 VC2 AP2 90 CV1 CV13 CV28 S19 90 2208 CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 10% but not more than 39% available chlorine 2209 FORMALDEHYDE SOLUTION with not less than 25% formaldehyde 2210 MANEB or MANEB PREPARATION with not less than 60% maneb 2211 POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour 2212 ASBESTOS, AMPHIBOLE (amosite, tremolite, actinolite, anthophyllite, crocidolite) 2213 PARAFORMALDEHYDE VC1 VC2 40 VC1 VC2 AP7 80 2214 PHTHALIC ANHYDRIDE with more than 0.05% of maleic anhydride 80 2215 MALEIC ANHYDRIDE, MOLTEN 80 2215 MALEIC ANHYDRIDE VC1 VC2 AP7 NOT SUBJECT TO ADR 2216 Fish meal (Fish scrap), stabilized - 395 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 4.2 2.2 (3b) S2 2.1.1.3 (4) III 5.2.2 (5) 4.2 2218 ACRYLIC ACID, STABILIZED 8 CF1 II 2219 ALLYL GLYCIDYL ETHER 3 F1 2222 ANISOLE 3 2224 BENZONITRILE 3.3 (6) 142 3.4 (7a) 0 3.5.1.2 (7b) E0 1L E2 III 8 +3 3 5L E1 F1 III 3 5L E1 6.1 T1 II 6.1 100 ml E4 2225 BENZENESULPHONYL CHLORIDE 8 C3 III 8 5L E1 2226 BENZOTRICHLORIDE 8 C9 II 8 1L E2 2227 n-BUTYL METHACRYLATE, STABILIZED 3 F1 III 3 5L E1 2232 2-CHLOROETHANAL 6.1 T1 I 6.1 0 E0 2233 CHLOROANISIDINES 6.1 T2 III 6.1 5 kg E1 354 2234 CHLOROBENZOTRI-FLUORIDES 3 F1 III 3 5L E1 2235 CHLOROBENZYL CHLORIDES, LIQUID 6.1 T1 III 6.1 5L E1 2236 3-CHLORO-4-METHYLPHENYL ISOCYANATE, LIQUID 2237 CHLORONITROANILINES 6.1 T1 II 6.1 100 ml E4 6.1 T2 III 6.1 5 kg E1 2238 CHLOROTOLUENES 3 F1 III 3 5L E1 2239 CHLOROTOLUIDINES, SOLID 6.1 T2 III 6.1 5 kg E1 2240 CHROMOSULPHURIC ACID 8 C1 I 8 0 E0 2241 CYCLOHEPTANE 3 F1 II 3 1L E2 2242 CYCLOHEPTENE 3 F1 II 3 1L E2 2243 CYCLOHEXYL ACETATE 3 F1 III 3 5L E1 2244 CYCLOPENTANOL 3 F1 III 3 5L E1 2245 CYCLOPENTANONE 3 F1 III 3 5L E1 2246 CYCLOPENTENE 3 F1 II 3 1L E2 - 396 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2217 SEED CAKE with not more than 1.5% oil and not more than 11% moisture Packaging 4.1.4 (8) P002 IBC08 LP02 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P602 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 4.1.4 (9a) PP20 B3 B6 4.1.10 (9b) MP14 4.2.5.2 (10) 4.2.5.3 (11) MP15 T7 TP2 MP19 T2 TP1 MP19 T2 TP1 MP15 T7 TP2 MP19 T4 TP1 MP15 T7 TP2 MP19 T2 TP1 MP8 MP17 T20 TP2 TP37 MP10 T1 TP33 MP19 T2 TP1 MP19 T4 TP1 MP10 T1 TP33 MP19 T2 TP1 MP10 T1 TP33 MP8 MP17 MP19 T10 TP2 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T7 TP2 B3 MP15 B3 B3 B8 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) 1.1.3.6 (15) 3 (E) L4BN FL LGBF FL 2 (D/E) 3 (D/E) LGBF FL 3 (D/E) AT 2 (D/E) 3 (E) L4BH TU15 TE19 L4BN AT L4BN AT LGBF FL 2 (E) 3 (D/E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) V1 7.3.3 (17) VC1 VC2 AP1 7.5.11 (18) 5.3.2.3 (20) 40 3.1.2 (1) (2) 2217 SEED CAKE with not more than 1.5% oil and not more than 11% moisture S2 839 2218 ACRYLIC ACID, STABILIZED V12 S2 30 2219 ALLYL GLYCIDYL ETHER V12 S2 30 2222 ANISOLE S9 S19 60 2224 BENZONITRILE 80 2225 BENZENESULPHONYL CHLORIDE 80 2226 BENZOTRICHLORIDE S2 39 2227 n-BUTYL METHACRYLATE, STABILIZED S9 S14 66 2232 2-CHLOROETHANAL S9 60 2233 CHLOROANISIDINES S2 30 2234 CHLOROBENZOTRI-FLUORIDES CV13 CV28 S9 60 2235 CHLOROBENZYL CHLORIDES, LIQUID CV13 CV28 CV13 CV28 S9 S19 60 S9 60 2236 3-CHLORO-4-METHYLPHENYL ISOCYANATE, LIQUID 2237 CHLORONITROANILINES S2 30 2238 CHLOROTOLUENES S9 60 2239 CHLOROTOLUIDINES, SOLID S20 88 2240 CHROMOSULPHURIC ACID S2 S20 33 2241 CYCLOHEPTANE S2 S20 33 2242 CYCLOHEPTENE CV13 CV28 V12 V12 TU14 TU15 TE19 TE21 AT 1 (C/D) SGAH L4BH TU15 TE19 AT 2 (E) FL 3 (D/E) V12 V12 L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT SGAH L4BH TU15 TE19 AT 2 (D/E) 2 (E) LGBF Name and description 8.5 (19) L10CH LGBF Hazard UN No. identification No. Operation VC1 VC2 AP7 VC1 VC2 AP7 CV1 CV13 CV28 CV13 CV28 FL 3 (D/E) AT 2 (E) L10BH AT LGBF FL 1 (E) 2 (D/E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) V12 S2 30 2243 CYCLOHEXYL ACETATE LGBF FL 3 (D/E) V12 S2 30 2244 CYCLOPENTANOL LGBF FL 3 (D/E) V12 S2 30 2245 CYCLOPENTANONE L1.5BN FL 2 (D/E) S2 S20 33 2246 CYCLOPENTENE SGAH L4BH TU15 TE19 V12 VC1 VC2 AP7 CV13 CV28 - 397 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (2) 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) III 5.2.2 (5) 3 2248 DI-n-BUTYLAMINE 8 CF1 II 8 +3 1L 2249 DICHLORODIMETHYL ETHER, SYMMETRICAL 2250 DICHLOROPHENYL ISOCYANATES 2251 BICYCLO[2.2.1]HEPTA-2,5DIENE, STABILIZED (2,5NORBORNADIENE, STABILIZED) 6.1 TF1 6.1 T2 II 6.1 500 g 3 F1 II 3 1L E2 2252 1,2-DIMETHOXYETHANE 3 F1 II 3 1L E2 2253 N,N-DIMETHYLANILINE 6.1 T1 II 6.1 100 ml E4 2254 MATCHES, FUSEE 4.1 F1 III 4.1 5 kg E0 2256 CYCLOHEXENE 3 F1 II 3 1L E2 2257 POTASSIUM 4.3 W2 I 4.3 0 E0 2258 1,2-PROPYLENEDIAMINE 8 CF1 II 1L E2 2259 TRIETHYLENETETRAMINE 8 C7 II 8 +3 8 1L E2 2260 TRIPROPYLAMINE 3 FC III 3 +8 5L E1 2261 XYLENOLS, SOLID 6.1 T2 II 6.1 500 g E4 2262 DIMETHYLCARBAMOYL CHLORIDE 2263 DIMETHYL-CYCLOHEXANES 3.3 (6) 293 3.4 (7a) 5L 3.5.1.2 (7b) E1 4.1.4 4.1.4 (8) (9a) P001 IBC03 LP01 R001 E2 P001 IBC02 CARRIAGE PROHIBITED E4 8 C3 II 8 1L E2 3 F1 II 3 1L E2 8 +3 3 1L E2 5L E1 1L E2 100 ml E4 5L E1 2264 N,N-DIMETHYLCYCLOHEXYLAMINE 2265 N,N-DIMETHYL-FORMAMIDE 8 CF1 II 3 F1 III 2266 DIMETHYL-N-PROPYLAMINE 3 FC II 2267 DIMETHYL THIOPHOSPHORYL CHLORIDE 2269 3,3'-IMINODIPROPYLAMINE 6.1 TC1 II 8 C7 III 2270 ETHYLAMINE, AQUEOUS SOLUTION with not less than 50% but not more than 70% ethylamine 3 FC II 3 +8 1L E2 2271 ETHYL AMYL KETONE 3 F1 III 3 5L E1 2272 N-ETHYLANILINE 6.1 T1 III 6.1 5L E1 2273 2-ETHYLANILINE 6.1 T1 III 6.1 5L E1 2274 N-ETHYL-N-BENZYLANILINE 6.1 T1 III 6.1 5L E1 2275 2-ETHYLBUTANOL 3 F1 III 3 5L E1 3 +8 6.1 +8 8 - 398 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities (1) 2247 n-DECANE Packaging P002 IBC08 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 P407 R001 P001 IBC02 R001 P403 IBC04 P001 IBC02 P001 IBC02 P001 IBC03 R001 P002 IBC08 P001 IBC02 P001 IBC02 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 4.1.10 (9b) MP19 4.2.5.2 (10) T2 4.2.5.3 (11) TP1 MP15 T7 TP2 MP10 T3 TP33 MP19 T7 TP2 MP19 T4 TP1 MP15 T7 TP2 MP19 T4 TP1 MP2 T9 MP15 T7 TP7 TP33 TP2 MP15 T7 TP2 MP19 T4 TP1 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 MP15 T7 TP2 MP19 T2 TP2 MP19 T7 TP2 MP15 T7 TP2 MP19 T4 TP2 MP19 T7 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 B4 MP11 B4 ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) L4BN SGAH L4BH LGBF TU15 TE19 AT FL TU15 TE19 LGBF L10BN(+) 9.1.1.2 (14) FL FL LGBF L4BH Vehicle for tank carriage 2 (D/E) 4 (E) 2 (D/E) FL L4BN AT L4BN FL TU15 TE19 AT AT LGBF FL L4BN FL LGBF FL L4BH FL L4BH TU15 TE19 2 (D/E) 2 (D/E) AT AT AT Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) 2 (D/E) CARRIAGE PROHIBITED 2 (D/E) L4BN SGAH L4BH L4BN 1.1.3.6 (15) 3 (D/E) FL FL TU1 TE5 TT3 TM2 Transport category (Tunnel restriction code) 1 (B/E) 2 (D/E) 2 (E) 3 (D/E) 2 (D/E) 2 (E) 2 (D/E) 2 (D/E) 3 (D/E) 2 (D/E) 2 (D/E) 3 (E) V11 CV13 CV28 CV13 CV28 Hazard UN No. identification No. Operation 8.5 (19) S2 5.3.2.3 (20) 30 S2 83 Name and description (1) 2247 n-DECANE 3.1.2 (2) 2248 DI-n-BUTYLAMINE 2249 DICHLORODIMETHYL ETHER, SYMMETRICAL 2250 DICHLOROPHENYL ISOCYANATES 2251 BICYCLO[2.2.1]HEPTA-2,5DIENE, STABILIZED (2,5NORBORNADIENE, STABILIZED) S9 S19 60 S2 S20 339 S2 S20 33 2252 1,2-DIMETHOXYETHANE S9 S19 60 2253 N,N-DIMETHYLANILINE 2254 MATCHES, FUSEE V1 CV23 V12 V11 CV13 CV28 V12 CV13 CV28 L4BN AT L4BH FL 2 (D/E) LGBF FL 3 (D/E) V12 S2 S20 33 2256 CYCLOHEXENE S20 X423 2257 POTASSIUM S2 83 2258 1,2-PROPYLENEDIAMINE 80 2259 TRIETHYLENETETRAMINE S2 38 2260 TRIPROPYLAMINE S9 S19 60 2261 XYLENOLS, SOLID 80 2262 DIMETHYLCARBAMOYL CHLORIDE 2263 DIMETHYL-CYCLOHEXANES S2 S20 33 S2 83 S2 30 2264 N,N-DIMETHYLCYCLOHEXYLAMINE 2265 N,N-DIMETHYL-FORMAMIDE S2 S20 338 2266 DIMETHYL-N-PROPYLAMINE S9 S19 68 2267 DIMETHYL THIOPHOSPHORYL CHLORIDE 2269 3,3'-IMINODIPROPYLAMINE V12 80 S2 S20 338 2270 ETHYLAMINE, AQUEOUS SOLUTION with not less than 50% but not more than 70% ethylamine S2 30 2271 ETHYL AMYL KETONE L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2272 N-ETHYLANILINE L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2273 2-ETHYLANILINE L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2274 N-ETHYL-N-BENZYLANILINE FL 3 (D/E) V12 S2 30 2275 2-ETHYLBUTANOL LGBF - 399 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (1) (2) 2276 2-ETHYLHEXYLAMINE 2.2 (3a) 3 2.2 (3b) FC 2.1.1.3 (4) III 5.2.2 (5) 3 +8 3.4 (7a) 5L 3.5.1.2 (7b) E1 2277 ETHYL METHACRYLATE, STABILIZED 3 F1 II 3 1L E2 2278 n-HEPTENE 3 F1 II 3 1L E2 2279 HEXACHLOROBUTADIENE 6.1 T1 III 6.1 5L E1 2280 HEXAMETHYLENE-DIAMINE, SOLID 8 C8 III 8 5 kg E1 2281 HEXAMETHYLENE DIISOCYANATE 2282 HEXANOLS 6.1 T1 II 6.1 100 ml E4 3 F1 III 3 5L E1 2283 ISOBUTYL METHACRYLATE, STABILIZED 3 F1 III 3 5L E1 2284 ISOBUTYRONITRILE 3 FT1 II 1L E2 2285 ISOCYANATOBENZOTRIFLUORIDES 2286 PENTAMETHYLHEPTANE 6.1 TF1 II 100 ml E4 3 F1 III 3 +6.1 6.1 +3 3 5L E1 2287 ISOHEPTENE 3 F1 II 3 1L E2 2288 ISOHEXENE 3 F1 II 3 1L E2 2289 ISOPHORONEDIAMINE 8 C7 III 8 5L E1 2290 ISOPHORONE DIISOCYANATE 6.1 T1 III 6.1 5L E1 2291 LEAD COMPOUND, SOLUBLE, N.O.S. 6.1 T5 III 6.1 5 kg E1 2293 4-METHOXY-4-METHYLPENTAN2-ONE 3 F1 III 3 5L E1 2294 N-METHYLANILINE 6.1 T1 III 6.1 5L E1 2295 METHYL CHLOROACETATE 6.1 TF1 I 6.1 +3 0 E0 2296 METHYLCYCLOHEXANE 3 F1 II 3 1L E2 2297 METHYLCYCLO-HEXANONE 3 F1 III 3 5L E1 2298 METHYLCYCLOPENTANE 3 F1 II 3 1L E2 2299 METHYL DICHLOROACETATE 6.1 T1 III 6.1 5L E1 199 274 535 - 400 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.3 (6) Packaging 4.1.4 (8) P001 IBC03 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP10 T1 TP33 MP15 T7 TP2 MP19 T2 TP1 MP19 T2 TP1 MP19 T7 TP2 MP15 T7 TP2 MP19 T2 TP1 MP19 T4 TP1 MP19 T11 TP1 MP19 T4 TP1 MP19 T4 TP2 MP10 T1 TP33 MP19 T2 TP1 MP19 T4 TP1 MP8 MP17 T14 TP2 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 B3 B8 B3 ADR tank Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 3 (D/E) LGBF FL LGBF L4BH TU15 TE19 SGAV L4BN L4BH TU15 TE19 Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 5.3.2.3 (20) 38 3.1.2 (1) (2) 2276 2-ETHYLHEXYLAMINE 2 (D/E) S2 S20 339 2277 ETHYL METHACRYLATE, STABILIZED FL 2 (D/E) S2 S20 33 2278 n-HEPTENE AT 2 (E) S9 60 2279 HEXACHLOROBUTADIENE AT 3 (E) 80 2280 HEXAMETHYLENE-DIAMINE, SOLID AT 2 (D/E) 3 (D/E) S9 S19 60 V12 S2 30 2281 HEXAMETHYLENE DIISOCYANATE 2282 HEXANOLS V12 S2 39 2283 ISOBUTYL METHACRYLATE, STABILIZED S2 S19 336 2284 ISOBUTYRONITRILE S2 S9 S19 63 S2 30 2285 ISOCYANATOBENZOTRIFLUORIDES 2286 PENTAMETHYLHEPTANE LGBF FL LGBF FL 3 (D/E) 2 (D/E) 2 (D/E) 3 (D/E) L4BH TU15 FL L4BH TU15 TE19 FL V12 CV13 CV28 VC1 VC2 AP7 CV13 CV28 CV13 CV28 CV13 CV28 LGBF FL V12 LGBF FL 2 (D/E) S2 S20 33 2287 ISOHEPTENE LGBF FL 2 (D/E) S2 S20 33 2288 ISOHEXENE L4BN AT 3 (E) V12 80 2289 ISOPHORONEDIAMINE V12 L4BH TU15 TE19 AT 2 (E) SGAH L4BH TU15 TE19 AT 2 (E) FL 3 (D/E) V12 V12 LGBF L4BH TU15 TE19 AT 2 (E) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) AT 2 (E) L4BH TU15 TE19 VC1 VC2 AP7 CV13 CV28 S9 60 2290 ISOPHORONE DIISOCYANATE CV13 CV28 S9 60 2291 LEAD COMPOUND, SOLUBLE, N.O.S. S2 30 2293 4-METHOXY-4-METHYLPENTAN2-ONE CV13 CV28 S9 60 2294 N-METHYLANILINE CV1 CV13 CV28 S2 S9 S14 663 2295 METHYL CHLOROACETATE S2 S20 33 2296 METHYLCYCLOHEXANE S2 30 2297 METHYLCYCLO-HEXANONE S2 S20 33 2298 METHYLCYCLOPENTANE S9 60 2299 METHYL DICHLOROACETATE V12 V12 CV13 CV28 - 401 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) T1 2.1.1.3 (4) III 5.2.2 (5) 6.1 2301 2-METHYLFURAN 3 F1 II 2302 5-METHYLHEXAN-2-ONE 3 F1 2303 ISOPROPENYLBENZENE 3 2304 NAPHTHALENE, MOLTEN 2305 NITROBENZENE-SULPHONIC ACID 2306 NITROBENZOTRI-FLUORIDES, LIQUID 2307 3-NITRO-4-CHLOROBENZOTRIFLUORIDE 2308 NITROSYLSULPHURIC ACID, LIQUID 2309 OCTADIENES 3.3 (6) 3.4 (7a) 5L 3.5.1.2 (7b) E1 3 1L E2 III 3 5L E1 F1 III 3 5L E1 4.1 F2 III 4.1 0 E0 8 C4 II 8 1 kg E2 536 6.1 T1 II 6.1 100 ml E4 6.1 T1 II 6.1 100 ml E4 8 C1 II 8 1L E2 3 F1 II 3 1L E2 2310 PENTANE-2,4-DIONE 3 FT1 III 3 +6.1 5L E1 2311 PHENETIDINES 6.1 T1 III 6.1 5L E1 2312 PHENOL, MOLTEN 6.1 T1 II 6.1 0 E0 2313 PICOLINES 3 F1 III 3 5L E1 2315 POLYCHLORINATED BIPHENYLS, LIQUID 9 M2 II 9 1L E2 2316 SODIUM CUPROCYANIDE, SOLID 6.1 T5 I 6.1 0 2317 SODIUM CUPROCYANIDE SOLUTION 6.1 T4 I 6.1 2318 SODIUM HYDROSULPHIDE with less than 25% water of crystallization 4.2 S4 II 4.2 2319 TERPENE HYDROCARBONS, N.O.S. 3 F1 III 2320 TETRAETHYLENE-PENTAMINE 8 C7 2321 TRICHLOROBENZENES, LIQUID 6.1 2322 TRICHLOROBUTENE 279 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2300 2-METHYL-5-ETHYLPYRIDINE Packaging 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC02 P001 IBC02 P001 IBC02 R001 P001 IBC03 R001 P001 IBC03 LP01 R001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T2 TP1 T1 TP3 MP10 T3 TP33 MP15 T7 TP2 MP10 T7 TP2 MP15 T8 TP2 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 T7 TP3 B4 P001 IBC03 LP01 R001 P906 IBC02 MP19 T4 TP1 MP15 T4 TP1 E5 P002 IBC07 MP18 T6 TP33 0 E5 P001 MP8 MP17 T14 TP2 0 E2 P410 IBC06 MP14 T3 TP33 3 5L E1 MP19 T4 TP1 TP29 III 8 5L E1 MP19 T4 TP1 T1 III 6.1 5L E1 MP19 T4 TP1 6.1 T1 II 6.1 100 ml E4 MP15 T7 TP2 2323 TRIETHYL PHOSPHITE 3 F1 III 3 5L E1 MP19 T2 TP1 2324 TRIISOBUTYLENE 3 F1 III 3 5L E1 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 MP19 T4 TP1 305 504 - 402 - ADR tank Tank code Special provisions 4.3 (12) L4BH 4.3.5, 6.8.4 (13) TU15 TE19 Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) AT 1.1.3.6 (15) 2 (E) LGBF FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 3 (D/E) AT 3 (E) 2 (E) 2 (D/E) 2 (D/E) 2 (E) 2 (D/E) LGBV TU27 TE4 TE6 SGAN L4BN L4BH AT TU15 TE19 AT L4BH TU15 TE19 AT L4BN AT LGBF FL Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) CV13 CV28 Hazard UN No. identification No. Operation Name and description 8.5 (19) S9 5.3.2.3 (20) 60 S2 S20 33 2301 2-METHYLFURAN V12 S2 30 2302 5-METHYLHEXAN-2-ONE V12 S2 30 2303 ISOPROPENYLBENZENE 44 2304 NAPHTHALENE, MOLTEN 80 V11 CV13 CV28 CV13 CV28 3.1.2 (1) (2) 2300 2-METHYL-5-ETHYLPYRIDINE S2 S20 33 2305 NITROBENZENE-SULPHONIC ACID 2306 NITROBENZOTRI-FLUORIDES, LIQUID 2307 3-NITRO-4-CHLOROBENZOTRIFLUORIDE 2308 NITROSYLSULPHURIC ACID, LIQUID 2309 OCTADIENES S9 S19 60 S9 S19 60 X80 L4BH TU15 FL 3 (D/E) V12 CV13 CV28 S2 36 2310 PENTANE-2,4-DIONE L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2311 PHENETIDINES L4BH TU15 TE19 AT 0 (D/E) 3 (D/E) CV13 S9 S19 60 2312 PHENOL, MOLTEN S2 30 2313 PICOLINES S19 90 2315 POLYCHLORINATED BIPHENYLS, LIQUID S9 S14 66 2316 SODIUM CUPROCYANIDE, SOLID S9 S14 66 2317 SODIUM CUPROCYANIDE SOLUTION 40 2318 SODIUM HYDROSULPHIDE with less than 25% water of crystallization 30 2319 TERPENE HYDROCARBONS, N.O.S. 80 2320 TETRAETHYLENE-PENTAMINE LGBF FL V12 L4BH TU15 AT 0 (D/E) S10AH TU15 TE19 AT 1 (C/E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) SGAN AT 2 (D/E) V1 LGBF FL 3 (D/E) V12 L4BN AT 3 (E) V12 V12 L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT 2 (D/E) 3 (D/E) LGBF FL LGBF FL 3 (D/E) VC1 VC2 AP9 V10 CV1 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 S2 CV13 CV28 S9 60 2321 TRICHLOROBENZENES, LIQUID CV13 CV28 S9 S19 60 2322 TRICHLOROBUTENE V12 S2 30 2323 TRIETHYL PHOSPHITE V12 S2 30 2324 TRIISOBUTYLENE - 403 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) III 5.2.2 (5) 3 2326 TRIMETHYLCYCLOHEXYLAMINE 8 C7 III 2327 TRIMETHYLHEXAMETHYLENEDIAMINES 8 C7 2328 TRIMETHYLHEXA-METHYLENE DIISOCYANATE 6.1 2329 TRIMETHYL PHOSPHITE 3.3 (6) 3.4 (7a) 5L 3.5.1.2 (7b) E1 8 5L E1 III 8 5L E1 T1 III 6.1 5L E1 3 F1 III 3 5L E1 2330 UNDECANE 3 F1 III 3 5L E1 2331 ZINC CHLORIDE, ANHYDROUS 8 C2 III 8 5 kg E1 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC02 P602 2332 ACETALDEHYDE OXIME 3 F1 III 3 5L E1 2333 ALLYL ACETATE 3 FT1 II 1L E2 2334 ALLYLAMINE 6.1 TF1 I 3 +6.1 6.1 +3 0 E0 2335 ALLYL ETHYL ETHER 3 FT1 II 1L E2 2336 ALLYL FORMATE 3 FT1 I 0 E0 P001 IBC02 P001 2337 PHENYL MERCAPTAN 6.1 TF1 I 0 E0 P602 2338 BENZOTRIFLUORIDE 3 F1 II 3 1L E2 2339 2-BROMOBUTANE 3 F1 II 3 1L E2 2340 2-BROMOETHYL ETHYL ETHER 3 F1 II 3 1L E2 2341 1-BROMO-3-METHYLBUTANE 3 F1 III 3 5L E1 2342 BROMOMETHYL-PROPANES 3 F1 II 3 1L E2 2343 2-BROMOPENTANE 3 F1 II 3 1L E2 2344 BROMOPROPANES 3 F1 II 3 1L E2 2344 BROMOPROPANES 3 F1 III 3 5L E1 2345 3-BROMOPROPYNE 3 F1 II 3 1L E2 2346 BUTANEDIONE 3 F1 II 3 1L E2 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 3 +6.1 3 +6.1 6.1 +3 354 354 - 404 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2325 1,3,5-TRIMETHYLBENZENE Packaging 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T2 4.2.5.3 (11) TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP2 MP19 T2 TP1 MP19 T2 TP1 MP10 T1 TP33 MP19 T4 TP1 MP19 T7 TP1 MP8 MP17 T20 TP2 TP35 MP19 T7 TP1 MP7 MP17 MP8 MP17 T14 TP2 T20 TP2 TP35 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 B3 ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation 9.1.1.2 (14) FL 1.1.3.6 (15) 3 (D/E) 7.2.4 (16) V12 L4BN AT 3 (E) V12 80 2326 TRIMETHYLCYCLOHEXYLAMINE L4BN AT 3 (E) V12 80 2327 TRIMETHYLHEXAMETHYLENEDIAMINES AT 2 (E) V12 S9 60 2328 TRIMETHYLHEXA-METHYLENE DIISOCYANATE LGBF FL 3 (D/E) V12 S2 30 2329 TRIMETHYL PHOSPHITE LGBF FL 3 (D/E) V12 S2 30 2330 UNDECANE SGAV AT 3 (E) 80 2331 ZINC CHLORIDE, ANHYDROUS LGBF FL 3 (D/E) S2 30 2332 ACETALDEHYDE OXIME 2 (D/E) 1 (C/D) S2 S19 336 2333 ALLYL ACETATE S2 S9 S14 663 2334 ALLYLAMINE S2 S19 336 2335 ALLYL ETHYL ETHER S2 S22 336 2336 ALLYL FORMATE S2 S9 S14 663 2337 PHENYL MERCAPTAN L4BH TU15 TE19 L4BH TU15 FL L10CH TU14 TU15 TE19 TE21 FL L4BH TU15 FL L10CH TU14 TU15 TE21 TU14 TU15 TE19 TE21 FL L10CH FL CV13 CV28 8.5 (19) S2 VC1 VC2 AP7 V12 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 2 (D/E) 1 (C/E) 1 (C/D) 5.3.2.3 (20) 30 Name and description 3.1.2 (1) (2) 2325 1,3,5-TRIMETHYLBENZENE LGBF FL 2 (D/E) S2 S20 33 2338 BENZOTRIFLUORIDE LGBF FL 2 (D/E) S2 S20 33 2339 2-BROMOBUTANE LGBF FL 2 (D/E) S2 S20 33 2340 2-BROMOETHYL ETHYL ETHER LGBF FL 3 (D/E) S2 30 2341 1-BROMO-3-METHYLBUTANE LGBF FL 2 (D/E) S2 S20 33 2342 BROMOMETHYL-PROPANES LGBF FL 2 (D/E) S2 S20 33 2343 2-BROMOPENTANE LGBF FL 2 (D/E) S2 S20 33 2344 BROMOPROPANES LGBF FL 3 (D/E) S2 30 2344 BROMOPROPANES LGBF FL 2 (D/E) S2 S20 33 2345 3-BROMOPROPYNE LGBF FL 2 (D/E) S2 S20 33 2346 BUTANEDIONE V12 V12 - 405 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) II 5.2.2 (5) 3 2348 BUTYL ACRYLATES, STABILIZED 3 F1 III 2350 BUTYL METHYL ETHER 3 F1 2351 BUTYL NITRITES 3 2351 BUTYL NITRITES 3.3 (6) 3.4 (7a) 1L 3.5.1.2 (7b) E2 3 5L E1 II 3 1L E2 F1 II 3 1L E2 3 F1 III 3 5L E1 2352 BUTYL VINYL ETHER, STABILIZED 3 F1 II 3 1L E2 2353 BUTYRYL CHLORIDE 3 FC II 1L E2 2354 CHLOROMETHYL ETHYL ETHER 3 FT1 II 1L E2 2356 2-CHLOROPROPANE 3 F1 I 3 +8 3 +6.1 3 0 E3 2357 CYCLOHEXYLAMINE 8 CF1 II 1L E2 2358 CYCLOOCTATETRAENE 3 F1 II 8 +3 3 1L E2 2359 DIALLYLAMINE 3 FTC II 1L E2 2360 DIALLYL ETHER 3 FT1 II 1L E2 2361 DIISOBUTYLAMINE 3 FC III 3 +6.1 +8 3 +6.1 3 +8 5L E1 2362 1,1-DICHLOROETHANE 3 F1 II 3 1L E2 2363 ETHYL MERCAPTAN 3 F1 I 3 0 E0 2364 n-PROPYLBENZENE 3 F1 III 3 5L E1 2366 DIETHYL CARBONATE 3 F1 III 3 5L E1 2367 alpha-METHYLVALERALDEHYDE 3 F1 II 3 1L E2 2368 alpha-PINENE 3 F1 III 3 5L E1 2370 1-HEXENE 3 F1 II 3 1L E2 2371 ISOPENTENES 3 F1 I 3 0 E3 2372 1,2-DI-(DIMETHYLAMINO) ETHANE 3 F1 II 3 1L E2 2373 DIETHOXYMETHANE 3 F1 II 3 1L E2 2374 3,3-DIETHOXYPROPENE 3 F1 II 3 1L E2 2375 DIETHYL SULPHIDE 3 F1 II 3 1L E2 - 406 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2347 BUTYL MERCAPTAN Packaging 4.1.4 (8) P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 P001 IBC02 P001 P001 IBC02 P001 IBC02 R001 P001 IBC02 P001 IBC02 P001 IBC03 R001 P001 IBC02 R001 P001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 R001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T8 TP2 MP19 T7 TP1 MP7 MP17 MP15 T11 TP2 T7 TP2 MP19 T4 TP1 MP19 T7 TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T4 TP1 MP7 MP17 MP19 T11 TP2 T2 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP7 MP17 MP19 T11 TP2 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T7 TP1 ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.3.3 (17) 7.5.11 (18) 9.1.1.2 (14) FL 1.1.3.6 (15) 2 (D/E) 7.2.4 (16) LGBF FL 3 (D/E) V12 LGBF FL LGBF Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 S20 5.3.2.3 (20) 33 3.1.2 (1) (2) 2347 BUTYL MERCAPTAN S2 39 2348 BUTYL ACRYLATES, STABILIZED 2 (D/E) S2 S20 33 2350 BUTYL METHYL ETHER FL 2 (D/E) S2 S20 33 2351 BUTYL NITRITES LGBF FL 3 (D/E) S2 30 2351 BUTYL NITRITES LGBF FL 2 (D/E) S2 S20 339 2352 BUTYL VINYL ETHER, STABILIZED L4BH FL 2 (D/E) 2 (D/E) 1 (D/E) 2 (D/E) 2 (D/E) S2 S20 338 2353 BUTYRYL CHLORIDE S2 S19 336 2354 CHLOROMETHYL ETHYL ETHER S2 S20 33 2356 2-CHLOROPROPANE S2 83 2357 CYCLOHEXYLAMINE S2 S20 33 2358 CYCLOOCTATETRAENE L4BH TU15 FL L4BN FL L4BN FL LGBF FL V12 CV13 CV28 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S19 338 2359 DIALLYLAMINE L4BH TU15 FL 2 (D/E) 3 (D/E) CV13 CV28 S2 S19 336 2360 DIALLYL ETHER S2 38 2361 DIISOBUTYLAMINE L4BN FL V12 LGBF FL 2 (D/E) S2 S20 33 2362 1,1-DICHLOROETHANE L4BN FL S2 S20 33 2363 ETHYL MERCAPTAN LGBF FL 1 (D/E) 3 (D/E) V12 S2 30 2364 n-PROPYLBENZENE LGBF FL 3 (D/E) V12 S2 30 2366 DIETHYL CARBONATE LGBF FL 2 (D/E) S2 S20 33 2367 alpha-METHYLVALERALDEHYDE LGBF FL 3 (D/E) S2 30 2368 alpha-PINENE LGBF FL 2 (D/E) S2 S20 33 2370 1-HEXENE L4BN FL S2 S20 33 2371 ISOPENTENES LGBF FL 1 (D/E) 2 (D/E) S2 S20 33 2372 1,2-DI-(DIMETHYLAMINO) ETHANE LGBF FL 2 (D/E) S2 S20 33 2373 DIETHOXYMETHANE LGBF FL 2 (D/E) S2 S20 33 2374 3,3-DIETHOXYPROPENE LGBF FL 2 (D/E) S2 S20 33 2375 DIETHYL SULPHIDE V12 - 407 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) II 5.2.2 (5) 3 2377 1,1-DIMETHOXYETHANE 3 F1 II 2378 2-DIMETHYLAMINOACETONITRILE 2379 1,3-DIMETHYLBUTYLAMINE 3 FT1 II 3 FC II 2380 DIMETHYLDIETHOXY-SILANE 3 F1 II 2381 DIMETHYL DISULPHIDE 3 FT1 II 3 +6.1 2382 DIMETHYLHYDRAZINE, SYMMETRICAL 6.1 TF1 I 6.1 +3 2383 DIPROPYLAMINE 3 FC II 2384 DI-n-PROPYL ETHER 3 F1 II 3 +8 3 2385 ETHYL ISOBUTYRATE 3 F1 II 2386 1-ETHYLPIPERIDINE 3 FC II 2387 FLUOROBENZENE 3 F1 2388 FLUOROTOLUENES 3 2389 FURAN 3.3 (6) 3.4 (7a) 1L 3.5.1.2 (7b) E2 3 1L E2 3 +6.1 3 +8 3 1L E2 1L E2 1L E2 1L E0 0 E0 1L E2 1L E2 3 1L E2 1L E2 II 3 +8 3 1L E2 F1 II 3 1L E2 3 F1 I 3 0 E3 2390 2-IODOBUTANE 3 F1 II 3 1L E2 2391 IODOMETHYLPROPANES 3 F1 II 3 1L E2 2392 IODOPROPANES 3 F1 III 3 5L E1 2393 ISOBUTYL FORMATE 3 F1 II 3 1L E2 2394 ISOBUTYL PROPIONATE 3 F1 III 3 5L E1 2395 ISOBUTYRYL CHLORIDE 3 FC II 1L E2 2396 METHACRYLALDEHYDE, STABILIZED 2397 3-METHYLBUTAN-2-ONE 3 FT1 II 1L E2 3 F1 II 3 +8 3 +6.1 3 1L E2 2398 METHYL tert-BUTYL ETHER 3 F1 II 3 1L E2 2399 1-METHYLPIPERIDINE 3 FC II 1L E2 2400 METHYL ISOVALERATE 3 F1 II 3 +8 3 1L E2 2401 PIPERIDINE 8 CF1 I 2402 PROPANETHIOLS 3 F1 2403 ISOPROPENYL ACETATE 3 F1 354 0 E0 II 8 +3 3 1L E2 II 3 1L E2 - 408 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2376 2,3-DIHYDROPYRAN Packaging 4.1.4 (8) P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 P001 IBC02 P001 IBC02 R001 P001 IBC02 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP19 T7 TP1 MP19 T7 TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T7 TP2 TP39 P602 MP8 MP17 T20 TP2 TP37 P001 IBC02 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 P001 IBC02 R001 P001 IBC02 R001 P001 MP19 T7 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T4 TP1 MP7 MP17 MP19 T12 TP2 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T7 TP2 MP19 T7 TP1 MP19 T4 TP1 MP19 T7 TP1 MP19 T7 TP1 MP19 T4 TP1 MP8 MP17 MP19 T10 TP2 T4 TP1 MP19 T4 TP1 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC02 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 P001 IBC02 R001 P001 P001 IBC02 R001 P001 IBC02 R001 4.1.4 (9a) ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) LGBF L4BH TU15 Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) 9.1.1.2 (14) FL 1.1.3.6 (15) 2 (D/E) FL 2 (D/E) FL 2 (D/E) 2 (D/E) 2 (D/E) CV13 CV28 L4BH FL LGBF FL Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 S20 5.3.2.3 (20) 33 3.1.2 (1) (2) 2376 2,3-DIHYDROPYRAN S2 S20 33 2377 1,1-DIMETHOXYETHANE S2 S19 336 S2 S20 338 2378 2-DIMETHYLAMINOACETONITRILE 2379 1,3-DIMETHYLBUTYLAMINE S2 S20 33 2380 DIMETHYLDIETHOXY-SILANE L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 2381 DIMETHYL DISULPHIDE L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) CV1 CV13 CV28 S2 S9 S14 663 2382 DIMETHYLHYDRAZINE, SYMMETRICAL L4BH FL S2 S20 338 2383 DIPROPYLAMINE LGBF FL 2 (D/E) 2 (D/E) S2 S20 33 2384 DI-n-PROPYL ETHER LGBF FL 2 (D/E) S2 S20 33 2385 ETHYL ISOBUTYRATE L4BH FL S2 S20 338 2386 1-ETHYLPIPERIDINE LGBF FL 2 (D/E) 2 (D/E) S2 S20 33 2387 FLUOROBENZENE LGBF FL 2 (D/E) S2 S20 33 2388 FLUOROTOLUENES L4BN FL S2 S20 33 2389 FURAN LGBF FL 1 (D/E) 2 (D/E) S2 S20 33 2390 2-IODOBUTANE LGBF FL 2 (D/E) S2 S20 33 2391 IODOMETHYLPROPANES LGBF FL 3 (D/E) S2 30 2392 IODOPROPANES LGBF FL 2 (D/E) S2 S20 33 2393 ISOBUTYL FORMATE LGBF FL 3 (D/E) S2 30 2394 ISOBUTYL PROPIONATE L4BH FL 2 (D/E) 2 (D/E) 2 (D/E) S2 S20 338 2395 ISOBUTYRYL CHLORIDE S2 S19 336 S2 S20 33 2396 METHACRYLALDEHYDE, STABILIZED 2397 3-METHYLBUTAN-2-ONE L4BH TU15 FL V12 V12 CV13 CV28 LGBF FL LGBF FL 2 (D/E) S2 S20 33 2398 METHYL tert-BUTYL ETHER L4BH FL S2 S20 338 2399 1-METHYLPIPERIDINE LGBF FL 2 (D/E) 2 (D/E) S2 S20 33 2400 METHYL ISOVALERATE L10BH FL S2 S14 883 2401 PIPERIDINE LGBF FL S2 S20 33 2402 PROPANETHIOLS LGBF FL S2 S20 33 2403 ISOPROPENYL ACETATE 1 (D/E) 2 (D/E) 2 (D/E) - 409 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) FT1 2.1.1.3 (4) II 2405 ISOPROPYL BUTYRATE 3 F1 III 5.2.2 (5) 3 +6.1 3 2406 ISOPROPYL ISOBUTYRATE 3 F1 II 3 2407 ISOPROPYL CHLOROFORMATE 6.1 TFC I 2409 ISOPROPYL PROPIONATE 3 F1 II 6.1 +3 +8 3 2410 1,2,3,6-TETRAHYDROPYRIDINE 3 F1 II 2411 BUTYRONITRILE 3 FT1 II 2412 TETRAHYDROTHIOPHENE 3 F1 2413 TETRAPROPYL ORTHOTITANATE 3 2414 THIOPHENE 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2404 PROPIONITRILE Packaging 3.4 (7a) 1L 3.5.1.2 (7b) E0 5L E1 1L E2 0 E0 1L E2 3 1L E2 1L E2 II 3 +6.1 3 1L E2 F1 III 3 5L E1 3 F1 II 3 1L E2 2416 TRIMETHYL BORATE 3 F1 II 3 1L E2 2417 CARBONYL FLUORIDE 2 2TC 2.3 +8 0 E0 P001 IBC02 R001 P001 IBC02 R001 P001 IBC02 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P200 2418 SULPHUR TETRAFLUORIDE 2 2TC 2.3 +8 0 E0 P200 MP9 2419 BROMOTRIFLUORO-ETHYLENE 2 2F 2.1 0 E0 P200 MP9 (M) 2420 HEXAFLUOROACETONE 2 2TC 2.3 +8 0 E0 P200 MP9 (M) 2421 NITROGEN TRIOXIDE 2422 OCTAFLUOROBUT-2-ENE (REFRIGERANT GAS R 1318) 2424 OCTAFLUOROPROPANE (REFRIGERANT GAS R 218) 2 2 2TOC 2A 2.2 662 120 ml MP9 (M) 2 2A 2.2 662 120 ml E1 MP9 (M) T50 2426 AMMONIUM NITRATE, LIQUID, hot concentrated solution, in a concentration of more than 80% but not more than 93% 5.1 O1 5.1 252 644 0 E0 2427 POTASSIUM CHLORATE, AQUEOUS SOLUTION 2427 POTASSIUM CHLORATE, AQUEOUS SOLUTION 5.1 O1 II 5.1 1L E2 5.1 O1 III 5.1 5L E1 2428 SODIUM CHLORATE, AQUEOUS SOLUTION 2428 SODIUM CHLORATE, AQUEOUS SOLUTION 5.1 O1 II 5.1 1L E2 5.1 O1 III 5.1 5L E1 2429 CALCIUM CHLORATE, AQUEOUS SOLUTION 2429 CALCIUM CHLORATE, AQUEOUS SOLUTION 5.1 O1 II 5.1 1L E2 5.1 O1 III 5.1 5L E1 2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) 2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) 8 C4 I 8 0 E0 8 C4 II 8 1 kg E2 354 662 - 410 - 4.1.4 (8) P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 R001 P602 4.1.4 (9a) 4.2.5.2 (10) T7 4.2.5.3 (11) TP1 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T7 TP1 MP9 (M) MP8 MP17 CARRIAGE PROHIBITED E1 P200 P200 P504 IBC02 P504 IBC02 R001 P504 IBC02 P504 IBC02 R001 P504 IBC02 P504 IBC02 R001 P002 IBC07 P002 IBC08 4.1.10 (9b) MP19 B4 T7 TP1 TP16 TP17 MP2 T4 TP1 MP2 T4 TP1 MP2 T4 TP1 MP2 T4 TP1 MP2 T4 TP1 MP2 T4 TP1 MP18 T6 TP33 MP10 T3 TP33 ADR tank Tank code Special provisions 4.3 (12) L4BH 4.3.5, 6.8.4 (13) TU15 Vehicle for tank carriage 9.1.1.2 (14) FL LGBF FL LGBF FL Transport category (Tunnel restriction code) 1.1.3.6 (15) 2 (D/E) 3 (D/E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV13 CV28 V12 2 (D/E) 1 (D) CV1 CV13 CV28 Hazard UN No. identification No. Operation Name and description 8.5 (19) S2 S19 5.3.2.3 (20) 336 S2 30 2405 ISOPROPYL BUTYRATE S2 S20 33 2406 ISOPROPYL ISOBUTYRATE S2 S9 S14 3.1.2 (1) (2) 2404 PROPIONITRILE 2407 ISOPROPYL CHLOROFORMATE LGBF FL 2 (D/E) S2 S20 33 2409 ISOPROPYL PROPIONATE LGBF FL 2 (D/E) S2 S20 33 2410 1,2,3,6-TETRAHYDROPYRIDINE FL 2 (D/E) 2 (D/E) S2 S19 336 2411 BUTYRONITRILE S2 S20 33 2412 TETRAHYDROTHIOPHENE S2 30 2413 TETRAPROPYL ORTHOTITANATE L4BH TU15 CV13 CV28 LGBF FL LGBF FL 3 (D/E) LGBF FL 2 (D/E) S2 S20 33 2414 THIOPHENE LGBF FL 2 (D/E) S2 S20 33 2416 TRIMETHYL BORATE AT 1 (C/D) S14 268 2417 CARBONYL FLUORIDE PxBH(M) TA4 TT9 V12 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 1 (D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBH(M) TA4 TT9 AT 1 (C/D) PxBN(M) TA4 TT9 AT PxBN(M) TA4 TT9 AT 3 (C/E) L4BV(+) TU3 TU12 TU29 TC3 TE9 TE10 TA1 AT 0 (E) L4BN TU3 AT LGBV TU3 AT 2 (E) 3 (E) L4BN TU3 AT LGBV TU3 AT L4BN TU3 AT LGBV TU3 AT S10AN L10BH SGAN L4BN AT AT CARRIAGE PROHIBITED 3 (C/E) S14 2418 SULPHUR TETRAFLUORIDE S2 S20 23 2419 BROMOTRIFLUORO-ETHYLENE S14 268 2420 HEXAFLUOROACETONE CV9 CV10 CV36 CV9 CV10 CV36 20 20 59 2426 AMMONIUM NITRATE, LIQUID, hot concentrated solution, in a concentration of more than 80% but not more than 93% CV24 50 CV24 50 2427 POTASSIUM CHLORATE, AQUEOUS SOLUTION 2427 POTASSIUM CHLORATE, AQUEOUS SOLUTION 2 (E) 3 (E) CV24 50 CV24 50 2 (E) 3 (E) CV24 50 CV24 50 1 (E) 2 (E) S23 2421 NITROGEN TRIOXIDE 2422 OCTAFLUOROBUT-2-ENE (REFRIGERANT GAS R 1318) 2424 OCTAFLUOROPROPANE (REFRIGERANT GAS R 218) V10 S20 V11 88 80 - 411 - 2428 SODIUM CHLORATE, AQUEOUS SOLUTION 2428 SODIUM CHLORATE, AQUEOUS SOLUTION 2429 CALCIUM CHLORATE, AQUEOUS SOLUTION 2429 CALCIUM CHLORATE, AQUEOUS SOLUTION 2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) 2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 8 5L E1 5L E1 6.1 5L E1 II 8 0 E0 4.1.4 (8) P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P010 2431 ANISIDINES 6.1 T1 III 6.1 2432 N,N-DIETHYLANILINE 6.1 T1 III 6.1 2433 CHLORONITROTOLUENES, LIQUID 6.1 T1 III 2434 DIBENZYL-DICHLOROSILANE 8 C3 2435 ETHYLPHENYLDICHLOROSILANE 2436 THIOACETIC ACID 8 C3 II 8 0 E0 P010 MP15 T10 3 F1 II 3 1L E2 MP19 T4 8 C3 II 8 0 E0 P001 IBC02 R001 P010 MP15 T10 6.1 TFC I 0 E0 P001 MP8 MP17 T14 2439 SODIUM HYDROGENDIFLUORIDE 2440 STANNIC CHLORIDE PENTAHYDRATE 8 C2 II 6.1 +3 +8 8 TP2 TP7 TP2 1 kg E2 MP10 T3 TP33 MP10 T1 TP33 2441 TITANIUM TRICHLORIDE, PYROPHORIC or TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC 2442 TRICHLOROACETYL CHLORIDE 4.2 SC4 I 4.2 +8 8 C3 II 2443 VANADIUM OXYTRICHLORIDE 8 C1 2444 VANADIUM TETRACHLORIDE 8 2446 NITROCRESOLS, SOLID 6.1 2437 METHYLPHENYLDICHLOROSILANE 2438 TRIMETHYLACETYL CHLORIDE 8 2.2 (3b) C4 2.1.1.3 (4) III 5.2.2 (5) 8 3.3 (6) 279 3.4 (7a) 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) Packaging 3.5.1.2 (7b) E1 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP15 T10 TP2 TP7 TP2 TP7 TP1 B3 0 E0 P002 IBC08 P002 IBC08 LP02 R001 P404 8 0 E0 P001 MP15 T7 TP2 II 8 1L E0 MP15 T7 TP2 C1 I 8 0 E0 P001 IBC02 P802 T10 TP2 T2 III 6.1 5 kg E1 MP8 MP17 MP10 T1 TP33 C2 III 8 2447 PHOSPHORUS, WHITE, MOLTEN 4.2 ST3 I 4.2 +6.1 2448 SULPHUR, MOLTEN 4.1 F3 III 4.1 2451 NITROGEN TRIFLUORIDE 2 2O 2452 ETHYLACETYLENE, STABILIZED 2 2453 ETHYL FLUORIDE (REFRIGERANT GAS R 161) 5 kg 537 E1 P002 IBC08 LP02 R001 B4 B3 MP13 B3 0 E0 T21 TP3 TP7 TP26 538 0 E0 T1 TP3 2.2 +5.1 662 0 E0 P200 MP9 (M) 2F 2.1 662 0 E0 P200 MP9 (M) 2 2F 2.1 662 0 E0 P200 MP9 (M) 2454 METHYL FLUORIDE (REFRIGERANT GAS R 41) 2 2F 2.1 662 0 E0 P200 MP9 (M) 2455 METHYL NITRITE 2456 2-CHLOROPROPENE 2 3 2A F1 I 3 0 T11 TP2 2457 2,3-DIMETHYLBUTANE 3 F1 II 3 1L E2 MP7 MP17 MP19 T7 TP1 2458 HEXADIENES 3 F1 II 3 1L E2 MP19 T4 TP1 2459 2-METHYL-1-BUTENE 3 F1 I 3 0 E3 T11 TP2 2460 2-METHYL-2-BUTENE 3 F1 II 3 1L E2 MP7 MP17 MP19 T7 TP1 - 412 - CARRIAGE PROHIBITED E3 P001 P001 IBC02 R001 P001 IBC02 R001 P001 P001 IBC02 B8 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) SGAV L4BN 4.3.5, 6.8.4 (13) 9.1.1.2 (14) AT L4BH TU15 TE19 L4BH L4BH Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 3 (E) 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) 8.5 (19) 5.3.2.3 (20) 80 AT 2 (E) V12 CV13 CV28 S9 60 2431 ANISIDINES TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2432 N,N-DIETHYLANILINE TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2433 CHLORONITROTOLUENES, LIQUID L4BN AT X80 2434 DIBENZYL-DICHLOROSILANE L4BN AT X80 LGBF FL 2 (E) 2 (E) 2 (D/E) 2435 ETHYLPHENYLDICHLOROSILANE 2436 THIOACETIC ACID L4BN AT L10CH TU14 TU15 TE19 TE21 FL SGAN AT SGAV AT L4BN AT L4BN AT L10BH AT 2 (E) 1 (C/D) 0 (E) V1 TU15 TE19 AT L10DH(+) TU14 TU16 TU21 TE3 TE21 TU27 TE4 TE6 TA4 TT9 AT 0 (B/E) AT 3 (E) 3 (C/E) PxBN(M) AT CV1 CV13 CV28 V11 2 (E) 2 (E) 1 (E) 2 (E) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) 33 X80 2 (E) 3 (E) SGAH L4BH LGBV(+) S2 S20 S2 S9 S14 663 80 VC1 VC2 AP7 80 S20 VC1 VC2 AP7 CV13 CV28 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CARRIAGE PROHIBITED 1 (D/E) 2 (D/E) 3.1.2 (1) (2) 2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) 2437 METHYLPHENYLDICHLOROSILANE 2438 TRIMETHYLACETYL CHLORIDE 2439 SODIUM HYDROGENDIFLUORIDE 2440 STANNIC CHLORIDE PENTAHYDRATE X80 2441 TITANIUM TRICHLORIDE, PYROPHORIC or TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC 2442 TRICHLOROACETYL CHLORIDE 80 2443 VANADIUM OXYTRICHLORIDE S20 X88 2444 VANADIUM TETRACHLORIDE S9 60 2446 NITROCRESOLS, SOLID S20 446 2447 PHOSPHORUS, WHITE, MOLTEN 44 2448 SULPHUR, MOLTEN 25 2451 NITROGEN TRIFLUORIDE S2 S20 239 2452 ETHYLACETYLENE, STABILIZED S2 S20 23 2453 ETHYL FLUORIDE (REFRIGERANT GAS R 161) S2 S20 23 2454 METHYL FLUORIDE (REFRIGERANT GAS R 41) S2 S20 33 2455 METHYL NITRITE 2456 2-CHLOROPROPENE S2 S20 33 2457 2,3-DIMETHYLBUTANE L4BN FL LGBF FL LGBF FL 2 (D/E) S2 S20 33 2458 HEXADIENES L4BN FL S2 S20 33 2459 2-METHYL-1-BUTENE L1.5BN FL 1 (D/E) 2 (D/E) S2 S20 33 2460 2-METHYL-2-BUTENE - 413 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) II 5.2.2 (5) 3 2463 ALUMINIUM HYDRIDE 4.3 W2 I 2464 BERYLLIUM NITRATE 5.1 OT2 II 2465 DICHLOROISOCYANURIC ACID, DRY or DICHLOROISOCYANURIC ACID SALTS 2466 POTASSIUM SUPEROXIDE 2468 TRICHLOROISOCYANURIC ACID, DRY 2469 ZINC BROMATE 5.1 O2 II 3.3 (6) 3.4 (7a) 1L 3.5.1.2 (7b) E2 4.3 0 E0 5.1 +6.1 5.1 1 kg E2 135 1 kg E2 5.1 O2 I 5.1 0 E0 5.1 O2 II 5.1 1 kg E2 5.1 O2 III 5.1 5 kg E1 2470 PHENYLACETONITRILE, LIQUID 6.1 T1 III 6.1 5L E1 2471 OSMIUM TETROXIDE 6.1 T5 I 6.1 0 E5 2473 SODIUM ARSANILATE 6.1 T3 III 6.1 5 kg E1 2474 THIOPHOSGENE 6.1 T1 I 6.1 2475 VANADIUM TRICHLORIDE 8 C2 III 8 279 354 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2461 METHYLPENTADIENE Packaging 0 E0 5 kg E1 4.1.4 (8) P001 IBC02 R001 P403 P002 IBC08 P002 IBC08 P503 IBC06 P002 IBC08 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P002 IBC07 P002 IBC08 LP02 R001 P602 P002 IBC08 LP02 R001 P602 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP2 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP19 T4 TP1 MP18 T6 TP33 MP10 T1 TP33 MP8 MP17 T20 TP2 TP37 MP10 T1 TP33 MP8 MP17 T20 TP2 TP37 MP2 B4 B4 MP2 B4 B3 PP30 B3 B3 2477 METHYL ISOTHIOCYANATE 6.1 TF1 I 6.1 +3 354 0 E0 2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. 2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. 2480 METHYL ISOCYANATE 3 FT1 II 3 +6.1 274 539 1L E2 P001 IBC02 MP19 T11 TP2 TP27 3 FT1 III 3 +6.1 274 5L E1 P001 IBC03 R001 MP19 T7 TP1 TP28 6.1 TF1 I 6.1 +3 354 0 E0 P601 MP2 T22 TP2 2481 ETHYL ISOCYANATE 6.1 TF1 I 6.1 +3 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 2482 n-PROPYL ISOCYANATE 6.1 TF1 I 6.1 +3 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 2483 ISOPROPYL ISOCYANATE 6.1 TF1 I 6.1 +3 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 2484 tert-BUTYL ISOCYANATE 6.1 TF1 I 6.1 +3 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 2485 n-BUTYL ISOCYANATE 6.1 TF1 I 6.1 +3 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 2486 ISOBUTYL ISOCYANATE 6.1 TF1 I 6.1 +3 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 2487 PHENYL ISOCYANATE 6.1 TF1 I 6.1 +3 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 2488 CYCLOHEXYL ISOCYANATE 6.1 TF1 I 6.1 +3 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 2490 DICHLOROISOPROPYL ETHER 6.1 T1 II 6.1 100 ml E4 P001 IBC02 MP15 T7 TP2 - 414 - ADR tank Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) FL SGAN TU3 AT SGAN TU3 AT Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (D/E) 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) 8.5 (19) S2 S20 1 (E) 2 (E) 2 (E) V1 CV23 S20 V11 V11 CV24 CV28 CV24 V10 CV24 V11 1 (E) 2 (E) 3 (E) 5.3.2.3 (20) 33 Name and description 3.1.2 (1) (2) 2461 METHYLPENTADIENE 2463 ALUMINIUM HYDRIDE 56 2464 BERYLLIUM NITRATE 50 2465 DICHLOROISOCYANURIC ACID, DRY or DICHLOROISOCYANURIC ACID SALTS 2466 POTASSIUM SUPEROXIDE CV24 50 CV24 50 2468 TRICHLOROISOCYANURIC ACID, DRY 2469 ZINC BROMATE S20 SGAN TU3 AT SGAV TU3 AT L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2470 PHENYLACETONITRILE, LIQUID S10AH TU15 TE19 AT 1 (C/E) V10 S9 S14 66 2471 OSMIUM TETROXIDE SGAH L4BH TU15 TE19 AT 2 (E) CV1 CV13 CV28 CV13 CV28 S9 60 2473 SODIUM ARSANILATE L10CH TU14 TU15 TE19 TE21 AT 1 (C/D) CV1 CV13 CV28 S9 S14 66 2474 THIOPHOSGENE AT 3 (E) 80 2475 VANADIUM TRICHLORIDE SGAV L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L4BH TU15 FL 2 (D/E) L4BH TU15 FL 3 (D/E) L15CH TU14 TU15 TE19 TE21 FL 1 (C/D) L15CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L4BH TU15 TE19 AT 2 (D/E) VC1 VC2 AP6 AP7 VC1 VC2 AP7 VC1 VC2 AP7 V12 CV1 CV13 CV28 CV13 CV28 S2 S9 S14 663 2477 METHYL ISOTHIOCYANATE S2 S19 336 CV13 CV28 S2 36 CV1 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV13 CV28 S2 S9 S14 663 2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. 2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. 2480 METHYL ISOCYANATE S2 S9 S14 663 2481 ETHYL ISOCYANATE S2 S9 S14 663 2482 n-PROPYL ISOCYANATE S2 S9 S14 663 2483 ISOPROPYL ISOCYANATE S2 S9 S14 663 2484 tert-BUTYL ISOCYANATE S2 S9 S14 663 2485 n-BUTYL ISOCYANATE S2 S9 S14 663 2486 ISOBUTYL ISOCYANATE S2 S9 S14 663 2487 PHENYL ISOCYANATE S2 S9 S14 663 2488 CYCLOHEXYL ISOCYANATE S9 S19 60 2490 DICHLOROISOPROPYL ETHER - 415 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 8 2.2 (3b) C7 2.1.1.3 (4) III 5.2.2 (5) 8 2493 HEXAMETHYLENEIMINE 3 FC II 2495 IODINE PENTAFLUORIDE 5.1 OTC I 2496 PROPIONIC ANHYDRIDE 8 C3 III 3 +8 5.1 +6.1 +8 8 2498 1,2,3,6-TETRAHYDROBENZALDEHYDE 3 F1 III 2501 TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION 2501 TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION 6.1 T1 6.1 2502 VALERYL CHLORIDE 2503 ZIRCONIUM TETRACHLORIDE 3.3 (6) 3.4 (7a) 5L 3.5.1.2 (7b) E1 1L E2 0 E0 5L E1 3 5L E1 II 6.1 100 ml E4 T1 III 6.1 5L E1 8 CF1 II 1L E2 8 C2 III 8 +3 8 5 kg E1 2504 TETRABROMOETHANE 6.1 T1 III 6.1 5L E1 2505 AMMONIUM FLUORIDE 6.1 T5 III 6.1 5 kg E1 2506 AMMONIUM HYDROGEN SULPHATE 2507 CHLOROPLATINIC ACID, SOLID 8 8 C2 C2 C2 II III 8 2509 POTASSIUM HYDROGEN SULPHATE 2511 2-CHLOROPROPIONIC ACID 8 8 C3 III 8 2512 AMINOPHENOLS (o-, m-, p-) 6.1 T2 III 6.1 II 1 kg 8 2508 MOLYBDENUM PENTACHLORIDE C2 III 8 5 kg 8 5 kg 8 1 kg 279 E2 E1 E1 E2 5L E1 5 kg E1 2513 BROMOACETYL BROMIDE 8 C3 II 8 1L E2 2514 BROMOBENZENE 3 F1 III 3 5L E1 2515 BROMOFORM 6.1 T1 III 6.1 5L E1 2516 CARBON TETRABROMIDE 6.1 T2 III 6.1 5 kg E1 2517 1-CHLORO-1,1DIFLUOROETHANE (REFRIGERANT GAS R 142b) 2 2F 2.1 662 - 416 - 0 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2491 ETHANOLAMINE or ETHANOLAMINE SOLUTION Packaging E0 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC02 P200 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P200 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T2 TP1 MP15 T7 TP2 MP19 T4 TP1 MP15 T7 TP2 MP10 T1 TP33 MP19 T4 TP1 MP10 T1 TP33 MP10 T3 TP33 MP10 T1 TP33 MP10 T1 TP33 MP10 T3 TP33 MP19 T4 TP2 MP10 T1 TP33 MP15 T8 TP2 MP19 T2 TP1 MP19 T4 TP1 MP10 T1 TP33 MP9 (M) T50 MP2 B3 B3 B4 B3 B3 B4 B3 B3 ADR tank Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) L4BH L10DH TU3 Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) AT 1.1.3.6 (15) 3 (E) FL 2 (D/E) 1 (B/E) AT Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) CV24 CV28 L4BN AT 3 (E) V12 LGBF FL 3 (D/E) V12 2 (D/E) 2 (E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BN FL SGAV AT TU15 TE19 AT 2 (E) SGAH TU15 TE19 AT 2 (E) SGAV AT SGAV AT 2 (E) 3 (E) SGAV AT 3 (E) SGAV AT L4BN AT 2 (E) 3 (E) SGAH L4BH TU15 TE19 V12 2 (D/E) 3 (E) L4BH AT 2 (E) L4BN AT LGBF FL 2 (E) 3 (D/E) L4BH TU15 TE19 AT 2 (E) SGAH L4BH TU15 TE19 AT 2 (E) PxBN(M) TA4 TT9 FL 2 (B/D) CV13 CV28 CV13 CV28 Hazard UN No. identification No. Operation 8.5 (19) 5.3.2.3 (20) 80 3.1.2 (1) (2) 2491 ETHANOLAMINE or ETHANOLAMINE SOLUTION S2 S20 338 2493 HEXAMETHYLENEIMINE S20 568 2495 IODINE PENTAFLUORIDE 80 2496 PROPIONIC ANHYDRIDE S2 30 2498 1,2,3,6-TETRAHYDROBENZALDEHYDE S9 S19 60 S9 60 2501 TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION 2501 TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION S2 83 2502 VALERYL CHLORIDE 80 2503 ZIRCONIUM TETRACHLORIDE VC1 VC2 AP7 V12 VC1 VC2 AP7 V11 V11 Name and description CV13 CV28 S9 60 2504 TETRABROMOETHANE CV13 CV28 S9 60 2505 AMMONIUM FLUORIDE 80 2506 AMMONIUM HYDROGEN SULPHATE 2507 CHLOROPLATINIC ACID, SOLID VC1 VC2 AP7 VC1 VC2 AP7 80 VC1 VC2 AP7 80 2508 MOLYBDENUM PENTACHLORIDE VC1 VC2 AP7 80 80 2509 POTASSIUM HYDROGEN SULPHATE 2511 2-CHLOROPROPIONIC ACID 60 2512 AMINOPHENOLS (o-, m-, p-) X80 2513 BROMOACETYL BROMIDE S2 30 2514 BROMOBENZENE CV13 CV28 S9 60 2515 BROMOFORM CV13 CV28 S9 60 2516 CARBON TETRABROMIDE CV9 CV10 CV36 S2 S20 23 2517 1-CHLORO-1,1DIFLUOROETHANE (REFRIGERANT GAS R 142b) V12 VC1 VC2 AP7 CV13 CV28 V12 V12 VC1 VC2 AP7 - 417 - S9 UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) T1 2.1.1.3 (4) III 5.2.2 (5) 6.1 2520 CYCLOOCTADIENES 3 F1 III 3 2521 DIKETENE, STABILIZED 6.1 TF1 I 6.1 +3 2522 2-DIMETHYLAMINOETHYL METHACRYLATE 2524 ETHYL ORTHOFORMATE 6.1 T1 II 3 F1 2525 ETHYL OXALATE 6.1 2526 FURFURYLAMINE 3.3 (6) 3.4 (7a) 5L 3.5.1.2 (7b) E1 5L E1 0 E0 6.1 100 ml E4 III 3 5L E1 T1 III 6.1 5L E1 3 FC III 3 +8 5L E1 2527 ISOBUTYL ACRYLATE, STABILIZED 3 F1 III 3 5L E1 2528 ISOBUTYL ISOBUTYRATE 3 F1 III 3 5L E1 2529 ISOBUTYRIC ACID 3 FC III 3 +8 5L E1 2531 METHACRYLIC ACID, STABILIZED 8 C3 II 8 1L E2 2533 METHYL TRICHLOROACETATE 6.1 T1 III 6.1 5L E1 2534 METHYLCHLOROSILANE 2 2TFC 0 E0 2535 4-METHYLMORPHOLINE (N-METHYLMORPHOLINE) 2536 METHYLTETRAHYDRO-FURAN 3 FC II 1L E2 3 F1 II 2.3 +2.1 +8 3 +8 3 1L E2 2538 NITRONAPHTHALENE 4.1 F1 III 4.1 5 kg E1 354 2541 TERPINOLENE 3 F1 III 3 5L E1 2542 TRIBUTYLAMINE 6.1 T1 II 6.1 100 ml E4 2545 HAFNIUM POWDER, DRY 4.2 S4 I 4.2 540 0 E0 2545 HAFNIUM POWDER, DRY 4.2 S4 II 4.2 540 0 E2 2545 HAFNIUM POWDER, DRY 4.2 S4 III 4.2 540 0 E1 2546 TITANIUM POWDER, DRY 4.2 S4 I 4.2 540 0 E0 2546 TITANIUM POWDER, DRY 4.2 S4 II 4.2 540 0 E2 2546 TITANIUM POWDER, DRY 4.2 S4 III 4.2 540 0 E1 2547 SODIUM SUPEROXIDE 5.1 O2 I 5.1 0 - 418 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2518 1,5,9-CYCLODODECATRIENE Packaging E0 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P602 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP19 T2 TP1 MP8 MP17 T20 TP2 TP37 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 R001 P001 IBC02 LP01 P001 IBC03 LP01 R001 P200 MP15 T7 TP2 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T4 TP1 MP15 T7 MP19 T4 TP2 TP18 TP30 TP1 MP9 (M) P001 IBC02 P001 IBC02 R001 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC02 P404 MP19 T7 TP1 MP19 T4 TP1 MP10 T1 TP33 MP19 T2 TP1 MP15 T7 TP2 MP14 T3 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 P410 IBC06 P002 IBC08 LP02 R001 P404 P410 IBC06 P002 IBC08 LP02 R001 P503 IBC06 4.1.4 (9a) B3 MP13 B3 MP13 B3 MP2 ADR tank Tank code Special provisions 4.3 (12) L4BH 4.3.5, 6.8.4 (13) TU15 TE19 LGBF Vehicle for tank carriage Transport category (Tunnel restriction code) Loading, unloading and handling 7.3.3 (17) 7.5.11 (18) CV13 CV28 7.2.4 (16) V12 FL 3 (D/E) V12 FL 1 (C/D) L4BH TU15 TE19 AT 2 (D/E) 3 (D/E) FL CV1 CV13 CV28 CV13 CV28 V12 Name and description 8.5 (19) S9 5.3.2.3 (20) 60 3.1.2 (1) (2) 2518 1,5,9-CYCLODODECATRIENE S2 30 2520 CYCLOOCTADIENES S2 S9 S14 663 2521 DIKETENE, STABILIZED S9 S19 69 S2 30 2522 2-DIMETHYLAMINOETHYL METHACRYLATE 2524 ETHYL ORTHOFORMATE S9 60 2525 ETHYL OXALATE 2 (E) V12 L4BN FL 3 (D/E) V12 S2 38 2526 FURFURYLAMINE LGBF FL 3 (D/E) V12 S2 39 2527 ISOBUTYL ACRYLATE, STABILIZED LGBF FL 3 (D/E) V12 S2 30 2528 ISOBUTYL ISOBUTYRATE L4BN FL 3 (D/E) V12 S2 38 2529 ISOBUTYRIC ACID L4BN AT 2 (E) 89 2531 METHACRYLIC ACID, STABILIZED AT 2 (E) FL 1 (B/D) L4BH FL LGBF FL 2 (D/E) 2 (D/E) SGAV AT 3 (E) LGBF FL 3 (D/E) AT 2 (D/E) 0 (E) 2 (D/E) 3 (E) L4BH TU15 TE19 TU15 TE19 SGAN AT SGAN AT SGAN AT SGAN AT CV13 CV28 Hazard UN No. identification No. Operation AT L4BH TU15 TE19 Bulk 1.1.3.6 (15) 2 (E) TU14 TU15 TE19 TE21 L4BH Packages 9.1.1.2 (14) AT L10CH LGBF Special provisions for carriage V12 CV13 CV28 S9 60 2533 METHYL TRICHLOROACETATE CV9 CV10 CV36 S2 S14 263 2534 METHYLCHLOROSILANE S2 S20 338 S2 S20 33 2535 4-METHYLMORPHOLINE (N-METHYLMORPHOLINE) 2536 METHYLTETRAHYDRO-FURAN 40 2538 NITRONAPHTHALENE S2 30 2541 TERPINOLENE S9 S19 60 2542 TRIBUTYLAMINE VC1 VC2 V12 CV13 CV28 V1 S20 V1 V1 0 (E) 2 (D/E) 3 (E) V1 1 (E) V10 VC1 VC2 AP1 40 2545 HAFNIUM POWDER, DRY 40 2545 HAFNIUM POWDER, DRY S20 V1 V1 2545 HAFNIUM POWDER, DRY VC1 VC2 AP1 CV24 - 419 - S20 2546 TITANIUM POWDER, DRY 40 2546 TITANIUM POWDER, DRY 40 2546 TITANIUM POWDER, DRY 2547 SODIUM SUPEROXIDE UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 2TOC 2.1.1.3 (4) 2552 HEXAFLUOROACETONE HYDRATE, LIQUID 2554 METHYLALLYL CHLORIDE 6.1 T1 II 5.2.2 (5) 2.3 +5.1 +8 6.1 3 F1 II 3 2555 NITROCELLULOSE WITH WATER 4.1 (not less than 25% water, by mass) D II 4.1 2556 NITROCELLULOSE WITH ALCOHOL (not less than 25% alcohol, by mass, and not more than 12.6% nitrogen, by dry mass) 4.1 D II 2557 NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH or WITHOUT PLASTICIZER, WITH or WITHOUT PIGMENT 2558 EPIBROMOHYDRIN 4.1 D 6.1 2560 2-METHYLPENTAN-2-OL 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P200 100 ml E4 1L E2 541 0 E0 P001 IBC02 P001 IBC02 R001 P406 4.1 541 0 E0 P406 MP2 II 4.1 241 541 0 E0 P406 MP2 TF1 I 6.1 +3 0 E0 P001 3 F1 III 3 5L E1 2561 3-METHYL-1-BUTENE 3 F1 I 3 0 E3 P001 IBC03 LP01 R001 P001 2564 TRICHLOROACETIC ACID SOLUTION 2564 TRICHLOROACETIC ACID SOLUTION 8 C3 II 8 1L E2 8 C3 III 8 5L E1 2565 DICYCLOHEXYLAMINE 8 C7 III 8 5L E1 2567 SODIUM PENTACHLOROPHENATE 2570 CADMIUM COMPOUND 6.1 T2 II 6.1 500 g E4 6.1 T5 I 6.1 274 596 0 E5 2570 CADMIUM COMPOUND 6.1 T5 II 6.1 274 596 274 596 500 g E4 2570 CADMIUM COMPOUND 6.1 T5 III 6.1 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2548 CHLORINE PENTAFLUORIDE Packaging 5 kg E1 2571 ALKYLSULPHURIC ACIDS 8 C3 II 8 1L E2 2572 PHENYLHYDRAZINE 6.1 T1 II 6.1 100 ml E4 2573 THALLIUM CHLORATE 5.1 OT2 II 1 kg E2 2574 TRICRESYL PHOSPHATE with more than 3% ortho isomer 2576 PHOSPHORUS OXYBROMIDE, MOLTEN 2577 PHENYLACETYL CHLORIDE 6.1 T1 II 5.1 +6.1 6.1 100 ml E4 8 C1 II 8 0 E0 8 C3 II 8 1L E2 2578 PHOSPHORUS TRIOXIDE 8 C2 III 8 5 kg E1 2579 PIPERAZINE 2580 ALUMINIUM BROMIDE SOLUTION 8 8 C8 C1 III III 8 5 kg 8 5L - 420 - E1 E1 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P002 IBC08 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P001 IBC02 P001 IBC02 P002 IBC06 P001 IBC02 P001 IBC02 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 4.1.4 (9a) 4.1.10 (9b) MP9 4.2.5.2 (10) 4.2.5.3 (11) MP15 T7 TP2 MP19 T4 TP1 MP8 MP17 T14 TP2 MP19 T2 TP1 MP7 MP17 MP15 T11 TP2 T7 TP2 MP19 T4 TP1 MP19 T4 TP1 MP10 T3 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP15 T8 MP15 T7 TP2 TP28 TP2 MP2 T3 TP33 MP15 T7 TP2 T7 TP3 MP15 T7 TP2 MP10 T1 TP33 MP10 T1 TP33 MP19 T4 TP1 MP2 B4 B4 B3 B3 B3 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) 9.1.1.2 (14) 1.1.3.6 (15) 1 (D) L4BH TU15 TE19 AT 2 (D/E) 2 (D/E) LGBF L10CH FL TU14 TU15 TE19 TE21 L4BN AT L4BN AT L4BN AT AT TU15 TE19 AT L4BN AT L4BH TU15 TE19 AT SGAN TU3 AT L4BH TU15 TE19 AT 5.3.2.3 (20) 3.1.2 (1) (2) 2548 CHLORINE PENTAFLUORIDE S9 S19 60 S2 S20 33 2552 HEXAFLUOROACETONE HYDRATE, LIQUID 2554 METHYLALLYL CHLORIDE S14 1 (D/E) 2 (E) 3 (E) TU15 TE19 8.5 (19) S14 2 (B) FL SGAH L4BH SGAH L4BH 7.5.11 (18) CV9 CV10 CV36 CV13 CV28 2556 NITROCELLULOSE WITH ALCOHOL (not less than 25% alcohol, by mass, and not more than 12.6% nitrogen, by dry mass) L4BN AT 7.3.3 (17) S14 3 (D/E) TU14 TU15 TE19 TE21 7.2.4 (16) 2 (B) FL S10AH L10CH Loading, unloading and handling 2555 NITROCELLULOSE WITH WATER (not less than 25% water, by mass) LGBF AT Bulk Name and description S14 1 (C/D) TU15 TE19 Packages Hazard UN No. identification No. Operation 2 (B) FL SGAH Special provisions for carriage CV1 CV13 CV28 V12 S2 S9 S14 663 2557 NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH or WITHOUT PLASTICIZER, WITH or WITHOUT PIGMENT 2558 EPIBROMOHYDRIN S2 30 2560 2-METHYLPENTAN-2-OL S2 S20 33 2561 3-METHYL-1-BUTENE 80 2564 TRICHLOROACETIC ACID SOLUTION 2564 TRICHLOROACETIC ACID SOLUTION V12 80 3 (E) V12 80 2565 DICYCLOHEXYLAMINE 2 (D/E) 1 (C/E) V11 S9 S19 60 S9 S14 66 2567 SODIUM PENTACHLOROPHENATE 2570 CADMIUM COMPOUND S9 S19 60 2570 CADMIUM COMPOUND S9 60 2570 CADMIUM COMPOUND 80 2571 ALKYLSULPHURIC ACIDS 60 2572 PHENYLHYDRAZINE 56 2573 THALLIUM CHLORATE 60 80 2574 TRICRESYL PHOSPHATE with more than 3% ortho isomer 2576 PHOSPHORUS OXYBROMIDE, MOLTEN 2577 PHENYLACETYL CHLORIDE VC1 VC2 AP7 80 2578 PHOSPHORUS TRIOXIDE VC1 VC2 AP7 80 2579 PIPERAZINE 80 2580 ALUMINIUM BROMIDE SOLUTION 2 (D/E) 2 (E) 2 (E) 2 (D/E) 2 (E) 2 (D/E) 2 (E) 2 (E) 3 (E) L4BN AT L4BN AT SGAV AT SGAV L4BN AT 3 (E) L4BN AT 3 (E) V10 V11 VC1 VC2 AP7 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV24 CV28 CV13 CV28 V11 S9 S19 S9 S19 80 V12 - 421 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 8 2.2 (3b) C1 2.1.1.3 (4) III 5.2.2 (5) 8 2582 FERRIC CHLORIDE SOLUTION 8 C1 III 2583 ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid 2584 ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid 2585 ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid 2586 ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid 2587 BENZOQUINONE 8 C2 II 3.4 (7a) 5L 3.5.1.2 (7b) E1 8 5L E1 8 1 kg E2 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P002 IBC08 8 C1 II 8 1L E2 P001 IBC02 8 C4 III 8 5 kg E1 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P002 IBC08 P002 IBC02 8 C3 III 8 5L E1 6.1 T2 II 6.1 500 g E4 2588 PESTICIDE, SOLID, TOXIC, N.O.S. 6.1 T7 I 6.1 2588 PESTICIDE, SOLID, TOXIC, N.O.S. 6.1 T7 II 6.1 2588 PESTICIDE, SOLID, TOXIC, N.O.S. 3.3 (6) 6.1 T7 III 6.1 61 274 648 61 274 648 61 274 648 0 E5 500 g E4 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP19 T4 TP1 MP10 T3 TP33 MP15 T8 TP2 MP10 T1 TP33 MP19 T4 TP1 MP10 T3 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP15 T7 TP2 MP10 T1 TP33 MP9 T75 TP5 B4 B3 B4 B4 100 ml E4 168 542 5 kg E1 2.2 593 120 ml E1 2A 2.2 662 120 ml E1 P200 MP9 (M) 2 2F 2.1 662 0 E0 P200 MP9 (M) 2602 DICHLORODIFLUOROMETHANE AND 1,1-DIFLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane (REFRIGERANT GAS R 500) 2603 CYCLOHEPTATRIENE 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 3 FT1 II 1L E2 MP19 T7 TP1 2604 BORON TRIFLUORIDE DIETHYL ETHERATE 2605 METHOXYMETHYL ISOCYANATE 8 CF1 I 0 E0 P001 IBC02 P001 T10 TP2 6.1 TF1 I 354 0 E0 P602 MP8 MP17 MP8 MP17 T20 TP2 TP37 2606 METHYL ORTHOSILICATE 6.1 TF1 I 6.1 +3 354 0 E0 P602 MP8 MP17 T20 TP2 TP37 2607 ACROLEIN DIMER, STABILIZED 3 F1 III 3 5L E1 P001 IBC03 LP01 R001 MP19 T2 TP1 6.1 TF1 II 2590 ASBESTOS, CHRYSOTILE 9 M1 III 2591 XENON, REFRIGERATED LIQUID 2 3A 2599 CHLOROTRIFLUORO-METHANE AND TRIFLUOROMETHANE AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane (REFRIGERANT GAS R 503) 2 2601 CYCLOBUTANE 6.1 +3 9 3 +6.1 8 +3 6.1 +3 - 422 - E1 P002 IBC08 4.1.4 (9a) P002 IBC08 LP02 R001 P001 IBC02 P002 IBC08 R001 P203 2589 VINYL CHLOROACETATE 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2581 ALUMINIUM CHLORIDE SOLUTION Packaging B3 PP37 B4 ADR tank Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation 9.1.1.2 (14) AT 1.1.3.6 (15) 3 (E) 7.2.4 (16) V12 L4BN AT 3 (E) V12 80 2582 FERRIC CHLORIDE SOLUTION SGAN L4BN AT 2 (E) V11 80 L4BN AT 2 (E) SGAV AT 3 (E) L4BN AT 3 (E) V12 TU15 TE19 AT V11 TU14 TU15 TE19 TE21 AT 2 (D/E) 1 (C/E) SGAH L4BH TU15 TE19 AT 2 (D/E) V11 SGAH L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 FL SGAH TU15 AT 2 (D/E) 3 (E) RxBN TU19 TA4 TT9 TA4 TT9 AT 3 (C/E) AT 3 (C/E) SGAH L4BH S10AH L10CH PxBN(M) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 AT 3 (C/E) L4BH TU15 FL 2 (D/E) 1 (D/E) 1 (C/D) L10BH FL L10CH TU14 TU15 TE19 TE21 FL L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) FL 3 (D/E) LGBF 8.5 (19) 5.3.2.3 (20) 80 Name and description S9 S19 60 2583 ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid 2584 ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid 2585 ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid 2586 ALKYLSULPHONIC ACIDS, LIQUID or ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid 2587 BENZOQUINONE S9 S14 66 2588 PESTICIDE, SOLID, TOXIC, N.O.S. S9 S19 60 2588 PESTICIDE, SOLID, TOXIC, N.O.S. CV13 CV28 S9 60 2588 PESTICIDE, SOLID, TOXIC, N.O.S. CV13 CV28 CV13 CV28 S2 S9 S19 63 2589 VINYL CHLOROACETATE 90 2590 ASBESTOS, CHRYSOTILE CV9 CV11 CV36 CV9 CV10 CV36 S20 22 2591 XENON, REFRIGERATED LIQUID 20 2599 CHLOROTRIFLUORO-METHANE AND TRIFLUOROMETHANE AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane (REFRIGERANT GAS R 503) CV9 CV10 CV36 CV9 CV10 CV36 S2 S20 23 2601 CYCLOBUTANE 20 CV13 CV28 S2 S19 336 2602 DICHLORODIFLUOROMETHANE AND 1,1-DIFLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane (REFRIGERANT GAS R 500) 2603 CYCLOHEPTATRIENE S2 S14 883 S2 S9 S14 663 S2 S9 S14 663 2606 METHYL ORTHOSILICATE S2 39 2607 ACROLEIN DIMER, STABILIZED 80 VC1 VC2 AP7 V11 V5 80 80 CV13 CV28 CV1 CV13 CV28 CV13 CV28 VC1 VC2 AP7 3.1.2 (1) (2) 2581 ALUMINIUM CHLORIDE SOLUTION CV1 CV13 CV28 CV1 CV13 CV28 V12 - 423 - 2604 BORON TRIFLUORIDE DIETHYL ETHERATE 2605 METHOXYMETHYL ISOCYANATE UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) III 5.2.2 (5) 3 2609 TRIALLYL BORATE 6.1 T1 III 2610 TRIALLYLAMINE 3 FC 2611 PROPYLENE CHLOROHYDRIN 6.1 2612 METHYL PROPYL ETHER 3 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2608 NITROPROPANES Packaging 3.4 (7a) 5L 3.5.1.2 (7b) E1 6.1 5L E1 III 3 +8 5L E1 TF1 II 100 ml E4 F1 II 6.1 +3 3 1L E2 2614 METHALLYL ALCOHOL 3 F1 III 3 5L E1 2615 ETHYL PROPYL ETHER 3 F1 II 3 1L E2 2616 TRIISOPROPYL BORATE 3 F1 II 3 1L E2 2616 TRIISOPROPYL BORATE 3 F1 III 3 5L E1 2617 METHYLCYCLO-HEXANOLS, flammable 3 F1 III 3 5L E1 2618 VINYLTOLUENES, STABILIZED 3 F1 III 3 5L E1 2619 BENZYLDIMETHYLAMINE 8 CF1 II 1L E2 2620 AMYL BUTYRATES 3 F1 III 8 +3 3 5L E1 2621 ACETYL METHYL CARBINOL 3 F1 III 3 5L E1 2622 GLYCIDALDEHYDE 3 FT1 II 1L E2 5 kg E1 500 g E2 2623 FIRELIGHTERS, SOLID with flammable liquid 4.1 F1 III 3 +6.1 4.1 2624 MAGNESIUM SILICIDE 4.3 W2 II 4.3 2626 CHLORIC ACID, AQUEOUS SOLUTION with not more than 10% chloric acid 2627 NITRITES, INORGANIC, N.O.S. 5.1 O1 II 5.1 613 1L E0 5.1 O2 II 5.1 103 274 1 kg E2 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 R001 P001 IBC02 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P002 LP02 R001 P410 IBC07 P504 IBC02 P002 IBC08 P002 IBC07 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T2 4.2.5.3 (11) TP1 MP19 T4 TP1 MP15 T7 TP2 MP19 T7 TP2 MP19 T2 TP1 MP19 T4 TP1 MP19 T4 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T2 TP1 MP15 T7 TP2 MP19 T2 TP1 MP19 T2 TP1 MP19 T7 TP1 MP14 T3 TP33 MP2 T4 TP1 MP10 T3 TP33 MP18 T6 TP33 MP19 B8 B8 PP15 MP11 B4 2628 POTASSIUM FLUOROACETATE 6.1 T2 I 6.1 0 E5 2629 SODIUM FLUOROACETATE 6.1 T2 I 6.1 0 E5 P002 IBC07 MP18 T6 TP33 2630 SELENATES or SELENITES 6.1 T5 I 6.1 0 E5 P002 IBC07 MP18 T6 TP33 2642 FLUOROACETIC ACID 6.1 T2 I 6.1 0 E5 P002 IBC07 MP18 T6 TP33 2643 METHYL BROMOACETATE 6.1 T1 II 6.1 100 ml E4 MP15 T7 TP2 2644 METHYL IODIDE 6.1 T1 I 6.1 0 E0 P001 IBC02 P602 MP8 MP17 T20 TP2 TP37 2645 PHENACYL BROMIDE 6.1 T2 II 6.1 500 g E4 MP10 T3 TP33 274 354 - 424 - P002 IBC08 B4 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) 9.1.1.2 (14) FL L4BH TU15 TE19 L4BN L4BH TU15 TE19 Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 3 (D/E) 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) 8.5 (19) S2 5.3.2.3 (20) 30 3.1.2 (1) (2) 2608 NITROPROPANES AT 2 (E) V12 CV13 CV28 S9 60 2609 TRIALLYL BORATE FL 3 (D/E) V12 S2 38 2610 TRIALLYLAMINE FL 2 (D/E) 2 (D/E) 3 (D/E) S2 S9 S19 63 2611 PROPYLENE CHLOROHYDRIN S2 S20 33 2612 METHYL PROPYL ETHER S2 30 2614 METHALLYL ALCOHOL CV13 CV28 L1.5BN FL LGBF FL LGBF FL 2 (D/E) S2 S20 33 2615 ETHYL PROPYL ETHER LGBF FL 2 (D/E) S2 S20 33 2616 TRIISOPROPYL BORATE LGBF FL 3 (D/E) V12 S2 30 2616 TRIISOPROPYL BORATE LGBF FL 3 (D/E) V12 S2 30 2617 METHYLCYCLO-HEXANOLS, flammable LGBF FL 3 (D/E) V12 S2 39 2618 VINYLTOLUENES, STABILIZED L4BN FL S2 83 2619 BENZYLDIMETHYLAMINE LGBF FL 2 (D/E) 3 (D/E) V12 S2 30 2620 AMYL BUTYRATES LGBF FL 3 (D/E) V12 S2 30 2621 ACETYL METHYL CARBINOL FL 2 (D/E) 4 (E) S2 S19 336 2622 GLYCIDALDEHYDE L4BH TU15 SGAN AT V12 CV13 CV28 2623 FIRELIGHTERS, SOLID with flammable liquid 2 (D/E) 2 (E) V1 CV23 423 2624 MAGNESIUM SILICIDE CV24 50 V11 CV24 50 2626 CHLORIC ACID, AQUEOUS SOLUTION with not more than 10% chloric acid 2627 NITRITES, INORGANIC, N.O.S. 2 (E) 1 (C/E) V10 CV1 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 S9 S14 66 2628 POTASSIUM FLUOROACETATE S9 S14 66 2629 SODIUM FLUOROACETATE S9 S14 66 2630 SELENATES or SELENITES S9 S14 66 2642 FLUOROACETIC ACID S9 S19 60 2643 METHYL BROMOACETATE S9 S14 66 2644 METHYL IODIDE S9 S19 60 2645 PHENACYL BROMIDE L4BN TU3 AT SGAN TU3 AT S10AH TU15 TE19 AT S10AH TU15 TE19 AT 1 (C/E) V10 S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 L4BH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 1 (C/D) SGAH L4BH TU15 TE19 AT 2 (D/E) V11 - 425 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) T1 2.1.1.3 (4) I 5.2.2 (5) 6.1 2647 MALONONITRILE 6.1 T2 II 6.1 3.3 (6) 354 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P602 500 g E4 P002 IBC08 P001 IBC02 P002 IBC08 P001 IBC02 P002 IBC08 LP02 R001 P001 IBC02 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P602 2648 1,2-DIBROMOBUTAN-3-ONE 6.1 T1 II 6.1 100 ml E4 2649 1,3-DICHLOROACETONE 6.1 T2 II 6.1 500 g E4 2650 1,1-DICHLORO-1-NITROETHANE 6.1 T1 II 6.1 100 ml E4 2651 4,4'-DIAMINODIPHENYLMETHANE 6.1 T2 III 6.1 5 kg E1 2653 BENZYL IODIDE 6.1 T1 II 6.1 100 ml E4 2655 POTASSIUM FLUOROSILICATE 6.1 T5 III 6.1 5 kg E1 2656 QUINOLINE 6.1 T1 III 6.1 5L E1 2657 SELENIUM DISULPHIDE 6.1 T5 II 6.1 500 g E4 2659 SODIUM CHLOROACETATE 2660 NITROTOLUIDINES (MONO) 6.1 6.1 T2 T2 III III 6.1 5 kg 6.1 5 kg E1 E1 2661 HEXACHLOROACETONE 6.1 T1 III 6.1 5L E1 2664 DIBROMOMETHANE 6.1 T1 III 6.1 5L E1 2667 BUTYLTOLUENES 6.1 T1 III 6.1 5L E1 2668 CHLOROACETONITRILE 6.1 TF1 I 6.1 +3 0 E0 2669 CHLOROCRESOLS SOLUTION 6.1 T1 II 6.1 100 ml E4 2669 CHLOROCRESOLS SOLUTION 6.1 T1 III 6.1 5L E1 2670 CYANURIC CHLORIDE 8 C4 II 8 1 kg E2 2671 AMINOPYRIDINES (o-, m-, p-) 2672 AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia 6.1 8 C5 III 8 2673 2-AMINO-4-CHLOROPHENOL 6.1 T2 II 6.1 2674 SODIUM FLUOROSILICATE 6.1 T2 T5 2676 STIBINE 2 2TF 2677 RUBIDIUM HYDROXIDE SOLUTION 8 C5 II III II 354 6.1 500 g 543 6.1 E4 5L E1 500 g E4 5 kg E1 2.3 +2.1 0 E0 8 1L E2 - 426 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2646 HEXACHLOROCYCLOPENTADIENE Packaging P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P002 IBC08 P001 IBC03 LP01 R001 P002 IBC08 P002 IBC08 LP02 R001 P200 P001 IBC02 4.1.4 (9a) 4.1.10 (9b) MP8 MP17 4.2.5.2 (10) T20 4.2.5.3 (11) TP2 TP35 MP10 T3 TP33 MP10 T3 TP33 MP15 T7 TP2 MP10 T1 TP33 MP15 T7 TP2 MP10 T1 TP33 MP19 T4 TP1 MP10 T3 TP33 MP10 T1 TP33 MP10 T1 TP33 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP8 MP17 T20 TP2 TP37 MP15 T7 TP2 MP19 T7 TP2 MP10 T3 TP33 MP10 T3 TP33 MP19 T7 TP1 MP10 T3 TP33 MP10 T1 TP33 T7 TP2 B4 MP15 B4 B3 B3 B4 B3 B3 B4 B4 B4 B3 MP9 MP15 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) L10CH 4.3.5, 6.8.4 (13) TU14 TU15 TE19 TE21 9.1.1.2 (14) AT SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT TU15 TE19 AT TU15 TE19 AT SGAH L4BH TU15 TE19 AT L4BH TU15 TE19 AT SGAH L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (E) SGAH L4BH SGAH TU15 TE19 AT TU15 TE19 AT 2 (D/E) 2 (E) SGAH L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT L4BH TU15 TE19 L10CH Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (C/D) 7.2.4 (16) 7.3.3 (17) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (E) V11 VC1 VC2 AP7 7.5.11 (18) CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 VC1 VC2 AP7 Hazard UN No. identification No. Operation Name and description 8.5 (19) S9 S14 5.3.2.3 (20) 66 S9 S19 60 2647 MALONONITRILE S9 S19 60 2648 1,2-DIBROMOBUTAN-3-ONE S9 S19 60 2649 1,3-DICHLOROACETONE S9 S19 60 2650 1,1-DICHLORO-1-NITROETHANE S9 60 2651 4,4'-DIAMINODIPHENYLMETHANE CV13 CV28 CV13 CV28 S9 S19 60 2653 BENZYL IODIDE S9 60 2655 POTASSIUM FLUOROSILICATE V12 CV13 CV28 S9 60 2656 QUINOLINE V11 S9 S19 60 2657 SELENIUM DISULPHIDE VC1 VC2 AP7 CV13 CV28 CV13 CV28 S9 60 2659 SODIUM CHLOROACETATE VC1 VC2 AP7 CV13 CV28 S9 60 2660 NITROTOLUIDINES (MONO) V12 CV13 CV28 S9 60 2661 HEXACHLOROACETONE 2 (E) V12 CV13 CV28 S9 60 2664 DIBROMOMETHANE AT 2 (E) V12 CV13 CV28 S9 60 2667 BUTYLTOLUENES TU14 TU15 TE19 TE21 FL 1 (C/D) S2 S9 S14 663 2668 CHLOROACETONITRILE L4BH TU15 TE19 AT S9 S19 60 2669 CHLOROCRESOLS SOLUTION L4BH TU15 TE19 AT 2 (D/E) 2 (E) CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 60 2669 CHLOROCRESOLS SOLUTION 80 2670 CYANURIC CHLORIDE 60 2671 AMINOPYRIDINES (o-, m-, p-) 2672 AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia SGAH L4BH L4BH SGAN L4BN SGAH L4BH L4BN SGAH L4BH SGAH L4BH AT TU15 TE19 AT AT TU15 TE19 AT TU15 TE19 AT 2 (D/E) 2 (E) 2 (E) 2 (D/E) 3 (E) 2 (D/E) 2 (E) 1 (D) L4BN AT V11 V12 V11 V11 CV13 CV28 S9 S19 V12 80 V11 VC1 VC2 AP7 3.1.2 (1) (2) 2646 HEXACHLOROCYCLOPENTADIENE CV13 CV28 CV13 CV28 S9 S19 60 2673 2-AMINO-4-CHLOROPHENOL S9 60 2674 SODIUM FLUOROSILICATE CV9 CV10 CV36 S2 S14 2 (E) 2676 STIBINE 80 - 427 - 2677 RUBIDIUM HYDROXIDE SOLUTION UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 8 2.2 (3b) C5 2.1.1.3 (4) III 5.2.2 (5) 8 2678 RUBIDIUM HYDROXIDE 8 C6 II 8 3.3 (6) 3.4 (7a) 5L 3.5.1.2 (7b) E1 1 kg E2 2679 LITHIUM HYDROXIDE SOLUTION 2679 LITHIUM HYDROXIDE SOLUTION 8 C5 II 8 1L E2 8 C5 III 8 5L E1 2680 LITHIUM HYDROXIDE 8 C6 II 8 1 kg E2 2681 CAESIUM HYDROXIDE SOLUTION 2681 CAESIUM HYDROXIDE SOLUTION 8 C5 II 8 1L E2 8 C5 III 8 5L E1 2682 CAESIUM HYDROXIDE 8 C6 II 8 1 kg E2 2683 AMMONIUM SULPHIDE SOLUTION 8 CFT II 8 +3 +6.1 3 +8 1L E2 2684 3-DIETHYLAMINOPROPYLAMINE 3 FC III 5L E1 2685 N,N-DIETHYLETHYLENEDIAMINE 2686 2-DIETHYLAMINO-ETHANOL 8 CF1 II 8 +3 8 +3 4.1 1L E2 8 CF1 II 1L E2 2687 DICYCLOHEXYL-AMMONIUM NITRITE 4.1 F3 III 5 kg E1 2688 1-BROMO-3-CHLOROPROPANE 6.1 T1 III 6.1 5L E1 2689 GLYCEROL alphaMONOCHLOROHYDRIN 6.1 T1 III 6.1 5L E1 2690 N,n-BUTYLIMIDAZOLE 6.1 T1 II 6.1 100 ml E4 2691 PHOSPHORUS PENTABROMIDE 8 C2 II 8 1 kg E0 2692 BORON TRIBROMIDE 8 C1 I 8 2693 BISULPHITES, AQUEOUS SOLUTION, N.O.S. 8 C1 III 8 2698 TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% of maleic anhydride 8 C4 III 8 2699 TRIFLUOROACETIC ACID 8 C3 I 2705 1-PENTOL 8 C9 2707 DIMETHYLDIOXANES 3 2707 DIMETHYLDIOXANES 0 E0 274 5L E1 169 5 kg E1 8 0 E0 II 8 1L E2 F1 II 3 1L E2 3 F1 III 3 5L E1 2709 BUTYLBENZENES 3 F1 III 3 5L E1 2710 DIPROPYL KETONE 3 F1 III 3 5L E1 - 428 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2677 RUBIDIUM HYDROXIDE SOLUTION Packaging 4.1.4 (8) P001 IBC03 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC08 P001 IBC01 P001 IBC03 R001 P001 IBC02 P001 IBC02 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 P602 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P001 P001 IBC02 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP2 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 MP10 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 MP15 T7 TP2 MP15 T7 TP2 MP11 T1 TP33 MP19 T4 TP1 MP19 T4 TP1 MP15 T7 TP2 MP10 T3 TP33 MP8 MP17 MP19 T20 TP2 T7 TP1 TP28 MP10 T1 TP33 MP8 MP17 MP15 T10 TP2 T7 TP2 MP19 T4 TP1 MP19 T2 TP1 MP19 T2 TP1 MP19 T2 TP1 B4 B4 B4 B3 B4 PP14 B3 ADR tank Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.3.3 (17) 7.5.11 (18) 9.1.1.2 (14) AT 1.1.3.6 (15) 3 (E) 7.2.4 (16) V12 SGAN AT V11 L4BN AT L4BN AT 2 (E) 2 (E) 3 (E) SGAN AT L4BN AT L4BN AT SGAN AT L4BN FL L4BN 2 (E) 2 (E) 3 (E) Hazard UN No. identification No. Operation 8.5 (19) Name and description 5.3.2.3 (20) 80 3.1.2 (1) (2) 2677 RUBIDIUM HYDROXIDE SOLUTION 80 2678 RUBIDIUM HYDROXIDE 80 2679 LITHIUM HYDROXIDE SOLUTION 2679 LITHIUM HYDROXIDE SOLUTION V12 80 V11 80 2680 LITHIUM HYDROXIDE 80 2681 CAESIUM HYDROXIDE SOLUTION 2681 CAESIUM HYDROXIDE SOLUTION V12 80 2 (E) 2 (D/E) V11 80 2682 CAESIUM HYDROXIDE S2 86 2683 AMMONIUM SULPHIDE SOLUTION FL 3 (D/E) V12 S2 38 2684 3-DIETHYLAMINOPROPYLAMINE L4BN FL S2 83 L4BN FL S2 83 2685 N,N-DIETHYLETHYLENEDIAMINE 2686 2-DIETHYLAMINO-ETHANOL SGAV AT 2 (D/E) 2 (D/E) 3 (E) CV13 CV28 VC1 VC2 40 2687 DICYCLOHEXYL-AMMONIUM NITRITE L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2688 1-BROMO-3-CHLOROPROPANE L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2689 GLYCEROL alphaMONOCHLOROHYDRIN L4BH TU15 TE19 AT 2 (D/E) 2 (E) 1 (E) 3 (E) CV13 CV28 S9 S19 60 2690 N,n-BUTYLIMIDAZOLE 80 2691 PHOSPHORUS PENTABROMIDE X88 2692 BORON TRIBROMIDE 80 2693 BISULPHITES, AQUEOUS SOLUTION, N.O.S. 80 2698 TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% of maleic anhydride 88 2699 TRIFLUOROACETIC ACID 80 2705 1-PENTOL S2 S20 33 2707 DIMETHYLDIOXANES SGAN AT V11 L10BH AT L4BN AT SGAV L4BN AT 3 (E) L10BH AT L4BN AT LGBF FL 1 (E) 2 (E) 2 (D/E) LGBF FL 3 (D/E) V12 S2 30 2707 DIMETHYLDIOXANES LGBF FL 3 (D/E) V12 S2 30 2709 BUTYLBENZENES LGBF FL 3 (D/E) V12 S2 30 2710 DIPROPYL KETONE S20 V12 VC1 VC2 AP7 S20 - 429 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (2) 2.2 (3a) 6.1 2.2 (3b) T2 2.1.1.3 (4) III 5.2.2 (5) 6.1 3.3 (6) 3.4 (7a) 5 kg 3.5.1.2 (7b) E1 2714 ZINC RESINATE 4.1 F3 III 4.1 5 kg E1 2715 ALUMINIUM RESINATE 4.1 F3 III 4.1 5 kg E1 2716 1,4-BUTYNEDIOL 6.1 T2 III 6.1 5 kg E1 2717 CAMPHOR, synthetic 2719 BARIUM BROMATE 2720 CHROMIUM NITRATE 2721 COPPER CHLORATE 2722 LITHIUM NITRATE 2723 MAGNESIUM CHLORATE 2724 MANGANESE NITRATE 2725 NICKEL NITRATE 2726 NICKEL NITRITE 4.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 F1 OT2 O2 O2 O2 O2 O2 O2 O2 III II III II III II III III III 2727 THALLIUM NITRATE 6.1 TO2 II 2728 ZIRCONIUM NITRATE 5.1 O2 III 2729 HEXACHLOROBENZENE 6.1 T2 III 4.1 5 kg 5.1 +6.1 5.1 1 kg 5 kg 5.1 1 kg 5.1 5 kg 5.1 1 kg 5.1 5 kg 5.1 5 kg 5.1 5 kg 6.1 +5.1 5.1 6.1 2730 NITROANISOLES, LIQUID 6.1 T1 III 6.1 2732 NITROBROMOBENZENES, LIQUID 6.1 T1 III 6.1 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 3 FC I 3 +8 3 FC II 3 FC III 279 E1 E2 E1 E2 E1 E2 E1 E1 E1 500 g E4 5 kg E1 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities (1) 2713 ACRIDINE Packaging E1 4.1.4 (8) P002 IBC08 LP02 R001 P002 IBC06 R001 P002 IBC06 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP11 T1 TP33 MP11 T1 TP33 MP10 T1 TP33 MP10 T1 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP10 T1 TP33 MP2 T3 TP33 MP10 T1 TP33 MP10 T1 TP33 MP10 T1 TP33 MP10 T3 TP33 MP10 T1 TP33 MP10 T1 TP33 MP19 T4 TP1 MP19 T4 TP1 MP7 MP17 T14 TP1 TP27 B3 B3 B3 B4 B3 B4 B3 B4 B3 B3 B3 B3 B3 5L E1 5L E1 274 544 0 E0 3 +8 274 544 1L E2 P001 IBC02 MP19 T11 TP1 TP27 3 +8 274 544 5L E1 P001 IBC03 R001 MP19 T7 TP1 TP28 - 430 - ADR tank Tank code Special provisions 4.3 (12) SGAH L4BH 4.3.5, 6.8.4 (13) TU15 TE19 Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) CV13 CV28 Hazard UN No. identification No. Operation 9.1.1.2 (14) AT 1.1.3.6 (15) 2 (E) SGAV AT 3 (E) VC1 VC2 40 2714 ZINC RESINATE SGAV AT 3 (E) VC1 VC2 40 2715 ALUMINIUM RESINATE AT 2 (E) VC1 VC2 AP7 60 2716 1,4-BUTYNEDIOL AT 3 (E) VC1 VC2 40 2717 CAMPHOR, synthetic 2 (E) 3 (E) V11 2 (E) 3 (E) V11 2 (E) 3 (E) V11 SGAH L4BH TU15 TE19 SGAV SGAN TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT SGAV TU3 AT 3 (E) SGAV TU3 AT 3 (E) SGAH TU15 TE19 AT SGAV TU3 AT 2 (D/E) 3 (E) SGAH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT 2 (E) L10CH TU14 TE21 FL L4BH L4BN CV13 CV28 8.5 (19) S9 S9 5.3.2.3 (20) 60 Name and description (1) 2713 ACRIDINE 3.1.2 (2) CV24 CV28 CV24 56 2719 BARIUM BROMATE 50 2720 CHROMIUM NITRATE CV24 50 2721 COPPER CHLORATE CV24 50 2722 LITHIUM NITRATE CV24 50 2723 MAGNESIUM CHLORATE CV24 50 2724 MANGANESE NITRATE VC1 VC2 AP6 AP7 CV24 50 2725 NICKEL NITRATE VC1 VC2 AP6 AP7 CV24 50 2726 NICKEL NITRITE 65 2727 THALLIUM NITRATE 50 2728 ZIRCONIUM NITRATE VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 VC1 VC2 AP6 AP7 V11 CV13 CV28 CV24 S9 S19 CV13 CV28 S9 60 2729 HEXACHLOROBENZENE V12 CV13 CV28 S9 60 2730 NITROANISOLES, LIQUID V12 CV13 CV28 S9 60 2732 NITROBROMOBENZENES, LIQUID 1 (C/E) S2 S20 338 FL 2 (D/E) S2 S20 338 FL 3 (D/E) S2 38 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. VC1 VC2 AP6 AP7 VC1 VC2 AP7 V12 - 431 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. 2.2 (3a) 8 2.2 (3b) CF1 2.1.1.3 (4) I 5.2.2 (5) 8 +3 3.3 (6) 274 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P001 8 CF1 II 8 +3 274 1L E2 8 C7 I 8 274 0 8 C7 II 8 274 8 C7 III 8 274 2738 N-BUTYLANILINE 6.1 T1 II 2739 BUTYRIC ANHYDRIDE 8 C3 2740 n-PROPYL CHLOROFORMATE 6.1 2741 BARIUM HYPOCHLORITE with more than 22% available chlorine 2742 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 2743 n-BUTYL CHLOROFORMATE 5.1 4.1.10 (9b) MP8 MP17 4.2.5.2 (10) T14 4.2.5.3 (11) TP2 TP27 P001 IBC02 MP15 T11 TP2 TP27 E0 P001 MP8 MP17 T14 TP2 TP27 1L E2 P001 IBC02 MP15 T11 TP1 TP27 5L E1 MP19 T7 TP1 TP28 6.1 100 ml E4 MP15 T7 TP2 III 8 5L E1 MP19 T4 TP1 TFC I 0 E0 MP8 MP17 T20 TP2 OT2 II 6.1 +3 +8 5.1 +6.1 6.1 +3 +8 6.1 +3 +8 6.1 +3 +8 6.1 +8 6.1 +8 6.1 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P602 1 kg E2 MP2 T3 TP33 6.1 TFC II 6.1 TFC II 2744 CYCLOBUTYL CHLOROFORMATE 6.1 TFC II 2745 CHLOROMETHYL CHLOROFORMATE 2746 PHENYL CHLOROFORMATE 6.1 TC1 II 6.1 TC1 II 2747 tert-BUTYLCYCLOHEXYL CHLOROFORMATE 6.1 T1 III 2748 2-ETHYLHEXYL CHLOROFORMATE 2749 TETRAMETHYLSILANE 6.1 TC1 II 3 F1 2750 1,3-DICHLOROPROPANOL-2 6.1 2751 DIETHYLTHIO-PHOSPHORYL CHLORIDE 2752 1,2-EPOXY-3-ETHOXYPROPANE B4 100 ml E4 100 ml E0 P001 MP15 T20 TP2 100 ml E4 P001 IBC01 MP15 T7 TP2 100 ml E4 MP15 T7 TP2 100 ml E4 MP15 T7 TP2 5L E1 MP19 T4 TP1 100 ml E4 MP15 T7 TP2 I 6.1 +8 3 0 E0 P001 IBC02 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 T14 TP2 T1 II 6.1 100 ml E4 MP7 MP17 MP15 T7 TP2 8 C3 II 8 1L E2 MP15 T7 TP2 3 F1 III 3 5L E1 MP19 T2 TP1 2753 N-ETHYLBENZYL-TOLUIDINES, LIQUID 6.1 T1 III 6.1 5L E1 MP19 T7 TP1 2754 N-ETHYLTOLUIDINES 6.1 T1 II 6.1 100 ml E4 MP15 T7 TP2 2757 CARBAMATE PESTICIDE, SOLID, TOXIC 6.1 T7 I 6.1 0 E5 MP18 T6 TP33 2757 CARBAMATE PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 500 g E4 MP10 T3 TP33 2757 CARBAMATE PESTICIDE, SOLID, TOXIC 6.1 MP10 T1 TP33 T7 III 6.1 274 561 P002 IBC08 P001 IBC01 4.1.4 (9a) 61 274 648 61 274 648 61 274 648 - 432 - 5 kg E1 MP15 P001 IBC02 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 B4 B3 ADR tank Tank code Special provisions 4.3 (12) L10BH 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 1 (D/E) L4BN FL L10BH Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation 8.5 (19) S2 S14 5.3.2.3 (20) 883 2 (D/E) S2 83 AT 1 (E) S20 88 L4BN AT 2 (E) L4BN AT 3 (E) AT 2 (D/E) 3 (E) L4BH TU15 TE19 L4BN AT L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) SGAN TU3 AT L4BH TU15 TE19 FL 2 (E) 2 (D/E) L4BH TU15 TE19 FL 2 (D/E) L4BH TU15 TE19 FL L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BN L4BH FL TU15 TE19 AT L4BN AT LGBF FL 80 V12 80 CV13 CV28 S9 S19 V12 CV1 CV13 CV28 CV24 CV28 CV13 CV28 V11 S2 S9 S14 Name and description 3.1.2 (1) (2) 2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. 60 2738 N-BUTYLANILINE 80 2739 BUTYRIC ANHYDRIDE 668 2740 n-PROPYL CHLOROFORMATE 56 2741 BARIUM HYPOCHLORITE with more than 22% available chlorine 2742 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 2743 n-BUTYL CHLOROFORMATE S2 S9 S19 638 CV13 CV28 S2 S9 S19 638 2 (D/E) CV13 CV28 S2 S9 S19 638 2744 CYCLOBUTYL CHLOROFORMATE 2 (D/E) 2 (D/E) 2 (E) CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 68 S9 S19 68 2745 CHLOROMETHYL CHLOROFORMATE 2746 PHENYL CHLOROFORMATE S9 60 2747 tert-BUTYLCYCLOHEXYL CHLOROFORMATE CV13 CV28 S9 S19 68 S2 S20 33 2748 2-ETHYLHEXYL CHLOROFORMATE 2749 TETRAMETHYLSILANE S9 S19 60 2750 1,3-DICHLOROPROPANOL-2 80 2751 DIETHYLTHIO-PHOSPHORYL CHLORIDE 2752 1,2-EPOXY-3-ETHOXYPROPANE 2 (D/E) 1 (D/E) 2 (D/E) 2 (E) 3 (D/E) L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT S10AH L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 1 (C/E) SGAH L4BH TU15 TE19 AT 2 (D/E) SGAH L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 V12 V12 V10 V11 VC1 VC2 AP7 S2 30 CV13 CV28 S9 60 2753 N-ETHYLBENZYL-TOLUIDINES, LIQUID CV13 CV28 CV1 CV13 CV28 CV13 CV28 S9 S19 60 2754 N-ETHYLTOLUIDINES S9 S14 66 2757 CARBAMATE PESTICIDE, SOLID, TOXIC S9 S19 60 2757 CARBAMATE PESTICIDE, SOLID, TOXIC S9 60 2757 CARBAMATE PESTICIDE, SOLID, TOXIC CV13 CV28 - 433 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2759 ARSENICAL PESTICIDE, SOLID, TOXIC 2.2 (3a) 3 2.2 (3b) FT2 2.1.1.3 (4) I 5.2.2 (5) 3 +6.1 3.3 (6) 61 274 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P001 3 FT2 II 3 +6.1 61 274 1L E2 6.1 T7 I 6.1 0 2759 ARSENICAL PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 500 g 2759 ARSENICAL PESTICIDE, SOLID, TOXIC 6.1 61 274 648 61 274 648 61 274 648 2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 3 FT2 I 3 +6.1 61 274 0 E0 3 FT2 II 3 +6.1 61 274 1L E2 6.1 T7 I 6.1 0 2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 500 g 2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 6.1 61 274 648 61 274 648 61 274 648 2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3 FT2 I 3 +6.1 61 274 0 E0 2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3 FT2 II 3 +6.1 61 274 1L E2 2763 TRIAZINE PESTICIDE, SOLID, TOXIC 6.1 T7 I 6.1 0 2763 TRIAZINE PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 500 g 2763 TRIAZINE PESTICIDE, SOLID, TOXIC 6.1 2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 3 FT2 I 3 +6.1 61 274 648 61 274 648 61 274 648 61 274 3 FT2 II 3 +6.1 6.1 T7 I 6.1 2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 6.1 2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3 FT2 I 3 +6.1 61 274 0 E0 3 FT2 II 3 +6.1 61 274 1L E2 T7 T7 T7 T7 III III III III 6.1 6.1 6.1 6.1 5 kg 5 kg 5 kg Portable tanks and bulk containers 4.1.10 (9b) MP7 MP17 4.2.5.2 (10) T14 4.2.5.3 (11) TP2 TP27 P001 IBC02 R001 MP19 T11 TP2 TP27 E5 P002 IBC07 MP18 T6 TP33 E4 P002 IBC08 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 P001 IBC02 R001 MP19 T11 TP2 TP27 E5 P002 IBC07 MP18 T6 TP33 E4 P002 IBC08 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 P001 IBC02 R001 MP19 T11 TP2 TP27 E5 P002 IBC07 MP18 T6 TP33 E4 P002 IBC08 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 E1 E1 E1 P002 IBC08 LP02 R001 P001 P002 IBC08 LP02 R001 P001 P002 IBC08 R001 P001 4.1.4 (9a) B4 B3 B4 B3 B4 B3 0 E0 61 274 1L E2 P001 IBC02 R001 MP19 T11 TP2 TP27 61 274 648 61 274 648 61 274 648 0 E5 P002 IBC07 MP18 T6 TP33 500 g E4 P002 IBC08 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 MP19 T11 TP2 TP27 - 434 - 5 kg E1 P002 IBC08 LP02 R001 P001 P001 IBC02 R001 B4 B3 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Tank code Special provisions 4.3 (12) L10CH 4.3.5, 6.8.4 (13) TU14 TU15 TE21 9.1.1.2 (14) FL 1.1.3.6 (15) 1 (C/E) L4BH TU15 FL 2 (D/E) S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 SGAH L4BH TU15 TE19 AT 2 (E) L10CH TU14 TU15 TE21 FL L4BH TU15 S10AH L10CH Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV13 CV28 8.5 (19) S2 S22 5.3.2.3 (20) 336 CV13 CV28 S2 S22 336 CV1 CV13 CV28 CV13 CV28 S9 S14 66 S9 S19 60 2759 ARSENICAL PESTICIDE, SOLID, TOXIC CV13 CV28 S9 60 2759 ARSENICAL PESTICIDE, SOLID, TOXIC 1 (C/E) CV13 CV28 S2 S22 336 FL 2 (D/E) CV13 CV28 S2 S22 336 TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC S9 S19 60 2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 2763 TRIAZINE PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 S9 S19 60 2763 TRIAZINE PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 2763 TRIAZINE PESTICIDE, SOLID, TOXIC L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC S9 S19 60 2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C VC1 VC2 AP7 VC1 VC2 AP7 VC1 VC2 AP7 VC1 VC2 AP7 - 435 - 3.1.2 (1) (2) 2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2759 ARSENICAL PESTICIDE, SOLID, TOXIC UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (1) (2) 2775 COPPER BASED PESTICIDE, SOLID, TOXIC 2.2 (3a) 6.1 2.2 (3b) T7 2.1.1.3 (4) I 5.2.2 (5) 6.1 2775 COPPER BASED PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 2775 COPPER BASED PESTICIDE, SOLID, TOXIC 6.1 2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2777 MERCURY BASED PESTICIDE, SOLID, TOXIC 3 FT2 I 3 +6.1 61 274 0 E0 3 FT2 II 3 +6.1 61 274 1L E2 6.1 T7 I 6.1 0 2777 MERCURY BASED PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 500 g 2777 MERCURY BASED PESTICIDE, SOLID, TOXIC 6.1 61 274 648 61 274 648 61 274 648 2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC 3 FT2 I 3 +6.1 61 274 0 E0 3 FT2 II 3 +6.1 61 274 1L E2 6.1 T7 I 6.1 0 E5 2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 500 g E4 2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC 6.1 61 274 648 61 274 648 61 274 648 2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 3 FT2 I 3 +6.1 61 274 0 E0 3 FT2 II 3 +6.1 61 274 1L E2 6.1 T7 I 6.1 0 2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 500 g 2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 6.1 61 274 648 61 274 648 61 274 648 2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 3 FT2 I 3 +6.1 61 274 0 E0 3 FT2 II 3 +6.1 61 274 1L E2 6.1 T7 I 6.1 0 6.1 T7 II 6.1 61 274 648 61 274 648 500 g 2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC T7 T7 T7 T7 III III III III 6.1 6.1 6.1 6.1 - 436 - 3.4 (7a) 0 3.5.1.2 (7b) E5 4.1.4 (8) P002 IBC07 500 g E4 P002 IBC08 5 kg 5 kg 5 kg 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.3 (6) 61 274 648 61 274 648 61 274 648 Packaging 4.1.10 (9b) MP18 4.2.5.2 (10) T6 4.2.5.3 (11) TP33 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 P001 IBC02 R001 MP19 T11 TP2 TP27 E5 P002 IBC07 MP18 T6 TP33 E4 P002 IBC08 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 MP19 T11 TP2 TP27 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 P001 IBC02 R001 MP19 T11 TP2 TP27 E5 P002 IBC07 MP18 T6 TP33 E4 P002 IBC08 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 P001 IBC02 R001 MP19 T11 TP2 TP27 E5 P002 IBC07 MP18 T6 TP33 E4 P002 IBC08 MP10 T3 TP33 E1 E1 E1 E1 P002 IBC08 LP02 R001 P001 P002 IBC08 LP02 R001 P001 4.1.4 (9a) B4 B3 B4 B3 P001 IBC02 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P001 P002 IBC08 LP02 R001 P001 B4 B3 B4 B3 B4 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) S10AH L10CH 4.3.5, 6.8.4 (13) TU14 TU15 TE19 TE21 9.1.1.2 (14) AT SGAH L4BH TU15 TE19 SGAH L4BH Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (C/E) 7.2.4 (16) V10 7.3.3 (17) AT 2 (D/E) V11 7.5.11 (18) CV1 CV13 CV28 CV13 CV28 TU15 TE19 AT 2 (E) L10CH TU14 TU15 TE21 FL L4BH TU15 S10AH L10CH Hazard UN No. identification No. Operation Name and description 8.5 (19) S9 S14 5.3.2.3 (20) 66 3.1.2 (1) (2) 2775 COPPER BASED PESTICIDE, SOLID, TOXIC S9 S19 60 2775 COPPER BASED PESTICIDE, SOLID, TOXIC CV13 CV28 S9 60 2775 COPPER BASED PESTICIDE, SOLID, TOXIC 1 (C/E) CV13 CV28 S2 S22 336 FL 2 (D/E) CV13 CV28 S2 S22 336 TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2777 MERCURY BASED PESTICIDE, SOLID, TOXIC S9 S19 60 2777 MERCURY BASED PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 2777 MERCURY BASED PESTICIDE, SOLID, TOXIC L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC S9 S19 60 2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC S9 S19 60 2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC S9 S19 60 VC1 VC2 AP7 VC1 VC2 AP7 VC1 VC2 AP7 VC1 VC2 AP7 - 437 - 2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) T7 3.3 (6) 61 274 648 3.4 (7a) 5 kg 4.1.10 (9b) MP10 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2785 4-THIAPENTANAL 3 FT2 I 3 +6.1 61 274 0 E0 MP7 MP17 T14 TP2 TP27 3 FT2 II 3 +6.1 61 274 1L E2 P001 IBC02 R001 MP19 T11 TP2 TP27 6.1 T1 III 6.1 5L E1 P001 IBC03 LP01 R001 P002 IBC07 MP19 T4 TP1 2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 6.1 T7 I 6.1 0 E5 MP18 T6 TP33 2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 500 g E4 MP10 T3 TP33 2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 6.1 MP10 T1 TP33 2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 3 FT2 I 3 +6.1 61 274 0 E0 MP7 MP17 T14 TP2 TP27 3 FT2 II 3 +6.1 61 274 1L E2 P001 IBC02 R001 MP19 T11 TP2 TP27 6.1 T3 I 6.1 43 274 0 E5 P001 MP8 MP17 T14 TP2 TP27 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 6.1 T3 II 6.1 6.1 T3 III 6.1 43 274 43 274 100 ml E4 MP15 T11 5L E1 MP19 T7 TP2 TP27 TP2 TP28 8 +3 1L E2 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 2789 ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, more than 80% acid, by mass 2790 ACETIC ACID SOLUTION, not less than 50% but not more than 80% acid, by mass 2790 ACETIC ACID SOLUTION, more than 10% and less than 50% acid, by mass 8 CF1 II MP15 T7 TP2 8 C3 II 8 1L E2 P001 IBC02 MP15 T7 TP2 8 C3 III 8 597 647 5L E1 MP19 T4 TP1 4.2 S4 III 4.2 592 0 E1 8 C11 8 1L E0 8 C11 8 295 598 295 598 1L E0 8 C1 II 8 1L E2 P001 IBC03 LP01 R001 P003 IBC08 LP02 R001 P801 P801a P801 P801a P001 IBC02 2793 FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to selfheating 2794 BATTERIES, WET, FILLED WITH ACID, electric storage 2795 BATTERIES, WET, FILLED WITH ALKALI, electric storage 2796 SULPHURIC ACID with not more than 51% acid or BATTERY FLUID, ACID 2797 BATTERY FLUID, ALKALI MP15 T8 TP2 8 C5 II 8 1L E2 MP15 T7 2798 PHENYLPHOSPHORUS DICHLORIDE 2799 PHENYLPHOSPHORUS THIODICHLORIDE 2800 BATTERIES, WET, NONSPILLABLE, electric storage 8 C3 II 8 1L E0 MP15 T7 TP2 TP28 TP2 8 C3 II 8 1L E0 MP15 T7 TP2 8 C11 1L E0 2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. 8 C9 0 E0 MP8 MP17 T14 TP2 TP27 T7 2.1.1.3 (4) III III 5.2.2 (5) 6.1 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC Packaging 6.1 8 I 8 61 274 648 61 274 648 61 274 648 238 295 598 274 - 438 - 5 kg 3.5.1.2 (7b) E1 E1 4.1.4 (8) P002 IBC08 LP02 R001 P001 P002 IBC08 P002 IBC08 LP02 R001 P001 P001 IBC02 P001 IBC02 P001 IBC02 P003 P801a P001 4.1.4 (9a) B3 B4 B3 PP20 B3 B6 MP14 PP16 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) SGAH L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT 1.1.3.6 (15) 2 (E) L10CH TU14 TU15 TE21 FL L4BH TU15 L4BH Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) CV13 CV28 8.5 (19) S9 5.3.2.3 (20) 60 3.1.2 (1) (2) 2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 1 (C/E) CV13 CV28 S2 S22 336 FL 2 (D/E) CV13 CV28 S2 S22 336 TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2785 4-THIAPENTANAL S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 2786 ORGANOTIN PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 S9 S19 60 2786 ORGANOTIN PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 2786 ORGANOTIN PESTICIDE, SOLID, TOXIC L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 L4BH TU15 TE19 AT S9 S19 60 L4BH TU15 TE19 AT 2 (D/E) 2 (E) CV1 CV13 CV28 CV13 CV28 CV13 CV28 2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. S9 60 S2 83 VC1 VC2 AP7 V12 L4BN FL 2 (D/E) L4BN AT 2 (E) L4BN AT 3 (E) V12 3 (E) V1 L4BN AT L4BN AT L4BN AT L4BN AT L10BH AT 3 (E) 3 (E) 2 (E) 2 (E) 2 (E) 2 (E) 3 (E) 80 80 VC1 VC2 AP1 40 VC1 VC2 AP8 VC1 VC2 AP8 80 80 80 80 80 80 VC1 VC2 AP8 80 1 (E) S20 - 439 - 88 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 2789 ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, more than 80% acid, by mass 2790 ACETIC ACID SOLUTION, not less than 50% but not more than 80% acid, by mass 2790 ACETIC ACID SOLUTION, more than 10% and less than 50% acid, by mass 2793 FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to selfheating 2794 BATTERIES, WET, FILLED WITH ACID, electric storage 2795 BATTERIES, WET, FILLED WITH ALKALI, electric storage 2796 SULPHURIC ACID with not more than 51% acid or BATTERY FLUID, ACID 2797 BATTERY FLUID, ALKALI 2798 PHENYLPHOSPHORUS DICHLORIDE 2799 PHENYLPHOSPHORUS THIODICHLORIDE 2800 BATTERIES, WET, NONSPILLABLE, electric storage 2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. 2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. 2.2 (3a) 8 2.2 (3b) C9 2.1.1.3 (4) II 5.2.2 (5) 8 3.3 (6) 274 3.4 (7a) 1L 3.5.1.2 (7b) E2 4.1.4 (8) P001 IBC02 8 C9 III 8 274 5L E1 2802 COPPER CHLORIDE 8 C2 III 8 5 kg E1 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P800 4.1.10 (9b) MP15 4.2.5.2 (10) T11 4.2.5.3 (11) TP2 TP27 MP19 T7 TP1 TP28 MP10 T1 TP33 PP41 MP10 T1 TP33 P410 PP40 IBC04 E0 P403 IBC04 NOT SUBJECT TO ADR E0 P800 MP14 T3 TP33 2803 GALLIUM 8 C10 III 8 5 kg E0 2805 LITHIUM HYDRIDE, FUSED SOLID 2806 LITHIUM NITRIDE 4.3 W2 II 4.3 500 g E2 4.3 W2 I 4.3 0 2807 Magnetized material 2809 MERCURY 9 8 M11 CT1 III 2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 T1 I 8 +6.1 6.1 2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 T1 II 6.1 2810 TOXIC LIQUID, ORGANIC, N.O.S. 6.1 T1 III 6.1 2811 TOXIC SOLID, ORGANIC, N.O.S. 6.1 T2 I 6.1 2811 TOXIC SOLID, ORGANIC, N.O.S. 6.1 T2 II 6.1 2811 TOXIC SOLID, ORGANIC, N.O.S. 6.1 T2 III 6.1 2812 Sodium aluminate, solid 2813 WATER-REACTIVE SOLID, N.O.S. 8 4.3 C6 W2 I 2813 WATER-REACTIVE SOLID, N.O.S. 4.3 W2 2813 WATER-REACTIVE SOLID, N.O.S. 4.3 W2 2814 INFECTIOUS SUBSTANCE, AFFECTING HUMANS 6.2 2814 INFECTIOUS SUBSTANCE, AFFECTING HUMANS, in refrigerated liquid nitrogen 4.1.4 (9a) B3 MP2 365 5 kg 274 315 614 274 614 274 614 0 E5 P001 MP8 MP17 T14 TP2 TP27 100 ml E4 MP15 T11 5L E1 MP19 T7 TP2 TP27 TP1 TP28 274 614 0 E5 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC07 MP18 T6 TP33 274 614 274 614 500 g E4 MP10 T3 TP33 MP10 T1 TP33 4.3 274 0 MP2 T9 TP7 TP33 II 4.3 274 500 g E2 PP83 MP14 T3 TP33 III 4.3 274 1 kg E1 PP83 B4 MP14 T1 TP33 I1 6.2 318 0 E0 P410 IBC07 P410 IBC08 R001 P620 6.2 I1 6.2 +2.2 318 0 E0 P620 MP5 2814 INFECTIOUS SUBSTANCE, AFFECTING HUMANS (animal material only) 6.2 I1 6.2 318 0 E0 P620 MP5 BK1 BK2 2815 N-AMINOETHYLPIPERAZINE 8 C7 III 8 5L E1 MP19 T4 TP1 2817 AMMONIUM HYDROGENDIFLUORIDE SOLUTION 2817 AMMONIUM HYDROGENDIFLUORIDE SOLUTION 2818 AMMONIUM POLYSULPHIDE SOLUTION 2818 AMMONIUM POLYSULPHIDE SOLUTION 8 CT1 II 8 +6.1 1L E2 P001 IBC03 LP01 R001 P001 IBC02 MP15 T8 TP2 8 CT1 III 8 +6.1 5L E1 MP19 T4 TP1 8 CT1 II 1L E2 MP15 T7 TP2 8 CT1 III 8 +6.1 8 +6.1 5L E1 MP19 T4 TP1 2819 AMYL ACID PHOSPHATE 8 C3 III 8 5L E1 P001 IBC03 R001 P001 IBC02 P001 IBC03 R001 P001 IBC03 LP01 R001 MP19 T4 TP1 - 440 - 5 kg P002 IBC08 B4 E1 P002 IBC08 B3 LP02 R001 NOT SUBJECT TO ADR E0 P403 PP83 IBC99 MP15 MP5 ADR tank Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation 9.1.1.2 (14) AT 1.1.3.6 (15) 2 (E) 7.2.4 (16) L4BN AT 3 (E) V12 SGAV AT 3 (E) VC1 VC2 AP7 80 2802 COPPER CHLORIDE SGAV L4BN SGAN AT 3 VC1 VC2 (E) AP7 2 V1 (D/E) 1 V1 (E) NOT SUBJECT TO ADR 3 (E) 1 (C/E) 80 2803 GALLIUM 423 2805 LITHIUM HYDRIDE, FUSED SOLID 2806 LITHIUM NITRIDE AT L4BN AT L10CH TU14 TU15 TE19 TE21 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT S10AH L10CH TU15 TE19 AT 1 (C/E) V10 SGAH L4BH SGAH L4BH TU15 TE19 AT V11 TU15 TE19 AT 2 (D/E) 2 (E) TU4 TU14 TU22 TE21 TM2 AT S10AN L10DH SGAN AT SGAN AT 2 (D/E) 2 (E) V12 VC1 VC2 AP7 V1 V1 0 (E) 0 (E) L4BN AT 3 (E) L4DH TU14 TE21 AT 2 (E) L4DH TU14 TE21 AT 3 (E) L4BN AT L4BN AT 2 (E) 3 (E) L4BN AT 3 (E) VC1 VC2 AP3 AP4 AP5 CV23 CV23 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 V12 86 2807 Magnetized material 2809 MERCURY S9 S14 66 2810 TOXIC LIQUID, ORGANIC, N.O.S. S9 S19 60 2810 TOXIC LIQUID, ORGANIC, N.O.S. S9 60 2810 TOXIC LIQUID, ORGANIC, N.O.S. S9 S14 66 2811 TOXIC SOLID, ORGANIC, N.O.S. S9 S19 60 2811 TOXIC SOLID, ORGANIC, N.O.S. S9 60 2811 TOXIC SOLID, ORGANIC, N.O.S. CV23 S20 X423 2812 Sodium aluminate, solid 2813 WATER-REACTIVE SOLID, N.O.S. CV23 423 2813 WATER-REACTIVE SOLID, N.O.S. CV23 423 2813 WATER-REACTIVE SOLID, N.O.S. S3 S9 S15 2814 INFECTIOUS SUBSTANCE, AFFECTING HUMANS S3 S9 S15 2814 INFECTIOUS SUBSTANCE, AFFECTING HUMANS, in refrigerated liquid nitrogen 606 2814 INFECTIOUS SUBSTANCE, AFFECTING HUMANS (animal material only) 80 2815 N-AMINOETHYLPIPERAZINE CV13 CV28 86 CV13 CV28 86 CV13 CV28 CV13 CV28 86 2817 AMMONIUM HYDROGENDIFLUORIDE SOLUTION 2817 AMMONIUM HYDROGENDIFLUORIDE SOLUTION 2818 AMMONIUM POLYSULPHIDE SOLUTION 2818 AMMONIUM POLYSULPHIDE SOLUTION V12 V12 S20 3.1.2 (1) (2) 2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. 2801 DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV25 CV26 CV28 CV13 CV25 CV26 CV28 CV13 CV25 CV26 CV28 0 (E) 5.3.2.3 (20) 80 80 NOT SUBJECT TO ADR 0 V1 (B/E) 0 (D/E) 0 (E) 8.5 (19) Name and description V12 S3 S9 S15 86 80 - 441 - 2819 AMYL ACID PHOSPHATE UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 8 2.2 (3b) C3 2.1.1.3 (4) III 5.2.2 (5) 8 2821 PHENOL SOLUTION 6.1 T1 II 2821 PHENOL SOLUTION 6.1 T1 2822 2-CHLOROPYRIDINE 6.1 2823 CROTONIC ACID, SOLID 8 3.4 (7a) 5L 3.5.1.2 (7b) E1 6.1 100 ml E4 III 6.1 5L E1 T1 II 6.1 100 ml E4 C4 III 8 5 kg E1 2826 ETHYL CHLOROTHIOFORMATE 8 CF1 II 2829 CAPROIC ACID 8 C3 2830 LITHIUM FERROSILICON 4.3 2831 1,1,1-TRICHLOROETHANE 2834 PHOSPHOROUS ACID 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2820 BUTYRIC ACID Packaging 0 E0 III 8 +3 8 5L E1 W2 II 4.3 500 g E2 6.1 T1 III 6.1 5L E1 8 C2 III 8 5 kg E1 4.1.4 (8) P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 LP02 R001 P001 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 MP15 T7 TP2 MP19 T4 TP1 MP15 T7 TP2 MP10 T1 TP33 MP15 T7 TP2 MP19 T4 TP1 MP14 T3 TP33 MP19 T4 TP1 MP10 T1 TP33 MP14 T3 TP33 MP15 T7 TP2 MP19 T4 TP1 MP19 T4 TP1 MP15 T7 TP2 MP19 T2 TP1 MP19 T4 TP1 MP19 T2 TP1 MP14 T1 TP33 MP2 T22 TP2 TP7 B3 4.2 S1 I 4.2 274 0 E0 P001 IBC03 LP01 R001 P410 IBC07 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P410 IBC04 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 R001 P001 IBC03 LP01 R001 P410 IBC08 R001 P400 4.2 S2 I 4.2 274 0 E0 P404 MP13 6.1 T1 III 6.1 5L E1 MP19 T4 TP1 2850 PROPYLENE TETRAMER 3 F1 III 3 5L E1 MP19 T2 TP1 2851 BORON TRIFLUORIDE DIHYDRATE 2852 DIPICRYL SULPHIDE, WETTED with not less than 10% water, by mass 8 C1 II 8 1L E2 MP15 T7 TP2 4.1 D I 4.1 0 E0 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P406 2835 SODIUM ALUMINIUM HYDRIDE 4.3 W2 II 4.3 500 g E0 2837 BISULPHATES, AQUEOUS SOLUTION 2837 BISULPHATES, AQUEOUS SOLUTION 8 C1 II 8 1L E2 8 C1 III 8 5L E1 2838 VINYL BUTYRATE, STABILIZED 3 F1 II 3 1L E2 2839 ALDOL 6.1 T1 II 6.1 100 ml E4 2840 BUTYRALDOXIME 3 F1 III 3 5L E1 2841 DI-n-AMYLAMINE 3 FT1 III 3 +6.1 5L E1 2842 NITROETHANE 3 F1 III 3 5L E1 2844 CALCIUM MANGANESE SILICON 4.3 W2 III 4.3 1 kg E1 2845 PYROPHORIC LIQUID, ORGANIC, N.O.S. 2846 PYROPHORIC SOLID, ORGANIC, N.O.S. 2849 3-CHLOROPROPANOL-1 545 - 442 - B3 B4 PP24 MP2 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) 9.1.1.2 (14) AT 1.1.3.6 (15) 3 (E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) L4BH TU15 TE19 AT SGAV L4BN AT L4BN FL L4BN AT SGAN AT L4BH TU15 TE19 AT 2 (D/E) 3 (E) 2 (D/E) 2 (E) AT 3 (E) SGAN AT L4BN AT L4BN AT 2 (D/E) 2 (E) 3 (E) LGBF FL 2 (D/E) AT 2 (D/E) 3 (D/E) TU15 TE19 LGBF L4BH FL Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) 8.5 (19) 5.3.2.3 (20) 80 3.1.2 (1) (2) 2820 BUTYRIC ACID CV13 CV28 CV13 CV28 S9 S19 60 2821 PHENOL SOLUTION S9 60 2821 PHENOL SOLUTION CV13 CV28 S9 S19 60 2822 2-CHLOROPYRIDINE 80 2823 CROTONIC ACID, SOLID 83 2826 ETHYL CHLOROTHIOFORMATE 80 2829 CAPROIC ACID 423 2830 LITHIUM FERROSILICON 60 2831 1,1,1-TRICHLOROETHANE 80 2834 PHOSPHOROUS ACID 423 2835 SODIUM ALUMINIUM HYDRIDE 80 2837 BISULPHATES, AQUEOUS SOLUTION 2837 BISULPHATES, AQUEOUS SOLUTION V12 VC1 VC2 AP7 S2 V12 V1 CV23 V12 CV13 CV28 S9 VC1 VC2 AP7 V1 CV23 V12 80 CV13 CV28 V12 339 2838 VINYL BUTYRATE, STABILIZED S9 S19 60 2839 ALDOL S2 30 2840 BUTYRALDOXIME S2 36 2841 DI-n-AMYLAMINE S2 30 2842 NITROETHANE 423 2844 CALCIUM MANGANESE SILICON 333 V12 LGBF FL 3 (D/E) V12 SGAN AT 3 (E) V1 AT 0 (B/E) 0 (E) 2 (E) V1 S20 V1 S20 L4BH TU15 TE19 AT LGBF FL 3 (D/E) L4BN AT 2 (E) 1 (B) V12 CV13 CV28 S2 S20 3 (D/E) TU14 TC1 TE21 TM1 Name and description Bulk FL L21DH TU15 Hazard UN No. identification No. Operation Packages 2 (D/E) 3 (E) SGAV L4BH Special provisions for carriage VC1 VC2 AP3 AP4 AP5 CV23 CV13 CV28 V12 S9 60 2845 PYROPHORIC LIQUID, ORGANIC, N.O.S. 2846 PYROPHORIC SOLID, ORGANIC, N.O.S. 2849 3-CHLOROPROPANOL-1 S2 30 2850 PROPYLENE TETRAMER 80 2851 BORON TRIFLUORIDE DIHYDRATE 2852 DIPICRYL SULPHIDE, WETTED with not less than 10% water, by mass S14 - 443 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2854 AMMONIUM FLUOROSILICATE 2855 ZINC FLUOROSILICATE 2856 FLUOROSILICATES, N.O.S. 2857 REFRIGERATING MACHINES containing non-flammable, non-toxic gases or ammonia solutions (UN 2672) 2858 ZIRCONIUM, DRY, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns) 2859 AMMONIUM METAVANADATE 2861 AMMONIUM POLYVANADATE 2.2 (3a) 6.1 6.1 6.1 6.1 T5 T5 T5 2 6A 4.1 F3 6.1 T5 6.1 2862 VANADIUM PENTOXIDE, nonfused form 6.1 2863 SODIUM AMMONIUM VANADATE 2864 POTASSIUM METAVANADATE 6.1 2865 HYDROXYLAMINE SULPHATE 2.2 (3b) T5 6.1 8 T5 T5 T5 T5 C2 III III III 3.3 (6) 6.1 5 kg 6.1 6.1 3.4 (7a) 5 kg 5 kg 274 5 kg 3.5.1.2 (7b) E1 E1 E1 E1 0 E0 III 4.1 546 5 kg E1 P002 LP02 R001 II 6.1 500 g E4 II III II II III 2870 ALUMINIUM BOROHYDRIDE 4.2 SW I 2870 ALUMINIUM BOROHYDRIDE IN DEVICES 2871 ANTIMONY POWDER 4.2 SW I 6.1 T5 III II III 6.1 6.1 0 E0 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 LP02 R001 P400 0 E0 P002 5 kg E1 P002 IBC08 LP02 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 500 g 600 6.1 5 kg 500 g 6.1 500 g 8 5 kg 8 1 kg 8 5 kg 4.2 +4.3 4.2 +4.3 6.1 E4 E1 E4 E4 E1 E2 E1 2872 DIBROMOCHLORO-PROPANES 6.1 T1 II 6.1 100 ml E4 2872 DIBROMOCHLORO-PROPANES 6.1 T1 III 6.1 5L E1 2873 DIBUTYLAMINOETHANOL 6.1 T1 III 6.1 5L E1 2874 FURFURYL ALCOHOL 6.1 T1 III 6.1 5L E1 2875 HEXACHLOROPHENE 6.1 T2 III 6.1 5 kg E1 2876 RESORCINOL 6.1 T2 4.1.4 (8) P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P003 119 8 C2 5.2.2 (5) 6.1 2.2 2869 TITANIUM TRICHLORIDE MIXTURE 2869 TITANIUM TRICHLORIDE MIXTURE 8 C2 2.1.1.3 (4) III III 6.1 5 kg - 444 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2853 MAGNESIUM FLUOROSILICATE Packaging E1 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP10 T1 TP33 MP10 T1 TP33 MP10 T1 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 MP10 T1 TP33 MP2 T21 TP7 TP33 MP10 T1 TP33 MP15 T7 TP2 MP19 T4 TP1 MP19 T4 TP1 MP19 T4 TP1 MP10 T1 TP33 MP10 T1 TP33 B3 B3 B3 B3 PP32 MP9 MP11 B4 B4 B3 B4 B4 B3 B4 B3 PP13 MP2 B3 B3 B3 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) SGAH L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT 1.1.3.6 (15) 2 (E) SGAH L4BH TU15 TE19 AT SGAH L4BH TU15 TE19 SGAH L4BH TU15 TE19 Special provisions for carriage Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) CV13 CV28 8.5 (19) S9 5.3.2.3 (20) 60 3.1.2 (1) (2) 2853 MAGNESIUM FLUOROSILICATE 2 (E) VC1 VC2 AP7 CV13 CV28 S9 60 2854 AMMONIUM FLUOROSILICATE AT 2 (E) VC1 VC2 AP7 CV13 CV28 S9 60 2855 ZINC FLUOROSILICATE AT 2 (E) VC1 VC2 AP7 CV13 CV28 S9 60 2856 FLUOROSILICATES, N.O.S. CV9 3 (E) SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAH TU15 TE19 AT SGAV AT SGAN AT SGAV AT TU14 TC1 TE21 TM1 Name and description Packages 3 (E) L21DH Hazard UN No. identification No. Operation AT 2 (D/E) 2 (D/E) 2 (E) 2 (D/E) 2 (D/E) 3 (E) VC1 VC2 V11 V11 VC1 VC2 AP7 V11 40 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 V11 S9 S19 60 2859 AMMONIUM METAVANADATE S9 S19 60 2861 AMMONIUM POLYVANADATE S9 60 2862 VANADIUM PENTOXIDE, nonfused form S9 S19 60 S9 S19 60 2863 SODIUM AMMONIUM VANADATE 2864 POTASSIUM METAVANADATE 80 2865 HYDROXYLAMINE SULPHATE 80 2869 TITANIUM TRICHLORIDE MIXTURE 2869 TITANIUM TRICHLORIDE MIXTURE VC1 VC2 AP7 2 (E) 3 (E) V11 0 (B/E) 0 (E) 2 (E) V1 S20 V1 S20 SGAH L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT 2 (E) SGAH L4BH TU15 TE19 AT 2 (E) SGAH L4BH TU15 TE19 AT 2 (E) 2 (D/E) 2 (E) 2857 REFRIGERATING MACHINES containing non-flammable, non-toxic gases or ammonia solutions (UN 2672) 2858 ZIRCONIUM, DRY, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns) VC1 VC2 AP7 80 X333 2870 ALUMINIUM BOROHYDRIDE CV13 CV28 S9 60 2870 ALUMINIUM BOROHYDRIDE IN DEVICES 2871 ANTIMONY POWDER CV13 CV28 CV13 CV28 S9 S19 60 2872 DIBROMOCHLORO-PROPANES S9 60 2872 DIBROMOCHLORO-PROPANES V12 CV13 CV28 S9 60 2873 DIBUTYLAMINOETHANOL V12 CV13 CV28 S9 60 2874 FURFURYL ALCOHOL VC1 VC2 AP7 CV13 CV28 S9 60 2875 HEXACHLOROPHENE VC1 VC2 AP7 CV13 CV28 S9 60 2876 RESORCINOL VC1 VC2 AP7 V12 - 445 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (1) (2) 2878 TITANIUM SPONGE GRANULES or TITANIUM SPONGE POWDERS 2.2 (3a) 4.1 2879 SELENIUM OXYCHLORIDE 8 CT1 I 2880 CALCIUM HYPOCHLORITE, HYDRATED, or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, with not less than 5.5% but not more than 16% water 5.1 O2 II 2880 CALCIUM HYPOCHLORITE, HYDRATED, or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, with not less than 5.5% but not more than 16% water 5.1 2881 METAL CATALYST, DRY 4.2 S4 I 4.2 274 0 E0 P404 2881 METAL CATALYST, DRY 4.2 S4 II 4.2 274 0 E0 2881 METAL CATALYST, DRY 4.2 S4 III 4.2 274 0 E1 O2 2.1.1.3 (4) III III 5.2.2 (5) 4.1 8 +6.1 5.1 5.1 3.3 (6) 3.4 (7a) 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 2.2 (3b) F3 Packaging 3.5.1.2 (7b) E1 0 E0 314 322 1 kg E2 314 5 kg E1 4.1.4 (8) P002 IBC08 LP02 R001 P001 P002 IBC08 P002 IBC08 R001 4.1.4 (9a) 4.1.10 (9b) MP11 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP8 MP17 MP10 T10 TP2 MP13 T21 MP14 T3 TP7 TP33 TP33 MP14 T1 TP33 B3 B4 B13 MP10 B4 B13 2900 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only 6.2 I2 6.2 318 0 E0 P410 IBC06 P002 IBC08 LP02 R001 P620 2900 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only, in refrigerated liquid nitrogen 6.2 I2 6.2 +2.2 318 0 E0 P620 MP5 2900 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only (animal material only) 6.2 I2 6.2 318 0 E0 P620 MP5 BK1 BK2 2901 BROMINE CHLORIDE 2 2TOC 0 E0 P200 MP9 (M) 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 T6 I 2.3 +5.1 +8 6.1 0 E5 P001 MP8 MP17 T14 TP2 TP27 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 T6 II 6.1 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 T6 III 6.1 5L E1 MP19 T7 TP2 TP28 2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-point not less than 23 °C 2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-point not less than 23 °C 2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-point not less than 23 °C 2904 CHLOROPHENOLATES, LIQUID or PHENOLATES, LIQUID 6.1 TF2 I 6.1 +3 61 274 0 E5 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 TP27 6.1 TF2 II 6.1 +3 61 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 6.1 TF2 III 6.1 +3 61 274 5L E1 MP19 T7 TP2 8 C9 III 8 5L E1 2905 CHLOROPHENOLATES, SOLID or PHENOLATES, SOLID 8 C10 III 8 5 kg E1 T1 TP33 2907 ISOSORBIDE DINITRATE MIXTURE with not less than 60% lactose, mannose, starch or calcium hydrogen phosphate 2908 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING 4.1 P001 IBC03 R001 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P406 D II 4.1 61 274 648 61 274 648 61 274 648 127 0 E0 IBC06 7 290 - 446 - 0 E0 See 1.7 B3 MP5 MP19 MP10 B3 PP26 PP80 B12 See 4.1.9.1.3 MP2 ADR tank Tank code Special provisions 4.3 (12) SGAV 4.3.5, 6.8.4 (13) L10BH Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) AT 1.1.3.6 (15) 3 (E) AT 1 (C/D) 2 (E) SGAN TU3 AT SGAV TU3 AT 3 (E) AT 0 (B/E) 2 (D/E) 3 (E) SGAN AT SGAN AT Special provisions for carriage Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) VC1 VC2 7.5.11 (18) 8.5 (19) 5.3.2.3 (20) 40 3.1.2 (1) (2) 2878 TITANIUM SPONGE GRANULES or TITANIUM SPONGE POWDERS CV13 CV28 CV24 CV35 S14 X886 2879 SELENIUM OXYCHLORIDE 50 2880 CALCIUM HYPOCHLORITE, HYDRATED, or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, with not less than 5.5% but not more than 16% water 50 2880 CALCIUM HYPOCHLORITE, HYDRATED, or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, with not less than 5.5% but not more than 16% water 43 2881 METAL CATALYST, DRY 40 2881 METAL CATALYST, DRY 40 2881 METAL CATALYST, DRY V11 VC1 VC2 AP6 AP7 CV24 CV35 V1 S20 V1 V1 VC1 VC2 AP1 CV13 CV25 CV26 CV28 CV13 CV25 CV26 CV28 CV13 CV25 CV26 CV28 CV9 CV10 CV36 CV1 CV13 CV28 CV13 CV28 0 (E) 0 (E) PxBH(M) TA4 TT9 AT 1 (C/D) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) L4BH TU15 TE19 FL 2 (D/E) L4BH TU15 TE19 FL 2 (D/E) V12 L4BN AT 3 (E) V12 SGAV L4BN AT 3 (E) 4 (E) Name and description Packages 0 (E) 2 (B) Hazard UN No. identification No. Operation V12 S3 S9 S15 2900 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only S3 S9 S15 2900 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only, in refrigerated liquid nitrogen S3 S9 S15 606 2900 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only (animal material only) S14 265 2901 BROMINE CHLORIDE S9 S14 66 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. S9 S19 60 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. CV13 CV28 S9 60 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. CV1 CV13 CV28 CV13 CV28 S2 S9 S14 663 S2 S9 S19 63 CV13 CV28 S2 S9 63 2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-point not less than 23 °C 2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-point not less than 23 °C 2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-point not less than 23 °C 2904 CHLOROPHENOLATES, LIQUID or PHENOLATES, LIQUID 80 VC1 VC2 AP7 80 V11 S14 CV33 (See 1.7.1.5.1) - 447 - S5 S21 2905 CHLOROPHENOLATES, SOLID or PHENOLATES, SOLID 2907 ISOSORBIDE DINITRATE MIXTURE with not less than 60% lactose, mannose, starch or calcium hydrogen phosphate 2908 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 7 3.3 (6) 290 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) See 1.7 4.1.4 (9a) See 4.1.9.1.3 7 290 368 0 E0 See 1.7 See 4.1.9.1.3 2911 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE INSTRUMENTS or ARTICLES 2912 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I), non fissile or fissile-excepted 7 290 0 E0 See 1.7 See 4.1.9.1.3 7 7X 172 317 325 0 E0 2913 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), non fissile or fissile-excepted 2915 RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissile-excepted 7 7X 172 317 336 0 7 7X 172 317 325 2916 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile or fissile-excepted 7 7X 2917 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, non fissile or fissile-excepted 7 7X 2919 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted 2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. 2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. 2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. 2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. 7 7X 172 317 325 337 172 317 325 337 172 317 325 2923 CORROSIVE SOLID, TOXIC, N.O.S. 2923 CORROSIVE SOLID, TOXIC, N.O.S. 2923 CORROSIVE SOLID, TOXIC, N.O.S. 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. 2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. 2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 2.2 (3b) 2.1.1.3 (4) 8 CF1 I 8 CF1 II 8 CF2 I 8 CF2 II 8 CT1 I 8 CT1 II 8 CT1 III 8 CT2 I 8 CT2 II 8 CT2 III 3 FC I 3 FC II 3 FC III 4.1 FC1 II 4.1 FC1 III 4.1 FT1 II 4.1 FT1 III 5.2.2 (5) 8 +3 8 +3 8 +4.1 8 +4.1 8 +6.1 8 +6.1 8 +6.1 8 +6.1 8 +6.1 8 +6.1 3 +8 3 +8 3 +8 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2909 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM 2910 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL Packaging 4.2.5.2 (10) 4.2.5.3 (11) See 2.2.7 See and 4.1.9 4.1.9.1.3 T5 see 4.1.9.2.4 TP4 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 see 4.1.9.2.4 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 274 0 E0 P001 274 1L E2 274 0 E0 274 1 kg E2 P001 IBC02 P002 IBC05 P002 IBC08 P001 274 0 E0 274 1L E2 274 5L E1 274 0 E0 274 1 kg E2 274 5 kg E1 274 0 E0 274 1L E2 274 5L E1 4.1 +8 4.1 +8 274 1 kg E2 274 5 kg E1 4.1 +6.1 4.1 +6.1 274 1 kg E2 274 5 kg E1 - 448 - P001 IBC02 P001 IBC03 R001 P002 IBC05 P002 IBC08 P002 IBC08 R001 P001 P001 IBC02 P001 IBC03 R001 P002 IBC06 P002 IBC06 R001 P002 IBC06 P002 IBC06 R001 4.1.10 (9b) MP8 MP17 MP15 T14 T11 MP18 T6 TP2 TP27 TP2 TP27 TP33 MP10 T3 TP33 MP8 MP17 MP15 T14 TP2 TP27 TP2 MP19 T7 TP1 TP28 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 MP19 T14 TP2 T11 MP19 T7 TP2 TP27 TP1 TP28 MP10 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 MP10 T1 TP33 B4 T7 B4 B3 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) S2.65AN(+) TU36 TT7 L2.65CN(+) TM7 Vehicle for tank carriage 9.1.1.2 (14) AT L10BH FL L4BN FL S10AN L10BH SGAN L4BN L10BH AT AT L4BN AT L4BN AT S10AN L10BH SGAN L4BN SGAV L4BN AT L10CH AT AT AT TU14 TE21 FL L4BH FL L4BN FL SGAN AT SGAN AT SGAN AT SGAN AT Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV33 (See 1.7.1.5.1) 8.5 (19) S5 S21 4 (E) CV33 (See 1.7.1.5.1) S5 S21 4 (E) CV33 (See 1.7.1.5.1) S5 S21 1.1.3.6 (15) 4 (E) 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 2909 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM 2910 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL 2911 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE INSTRUMENTS or ARTICLES 2912 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I), non fissile or fissile-excepted 0 (E) see 4.1.9.2.4 CV33 S6 S11 S21 70 0 (E) see 4.1.9.2.4 CV33 S6 S11 S21 70 0 (E) CV33 S6 S11 S12 S21 70 0 (E) CV33 S6 S11 S21 70 2916 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile or fissile-excepted 0 (E) CV33 S6 S11 S21 70 2917 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, non fissile or fissile-excepted 0 (-) CV33 S6 S11 S21 70 S2 S14 883 S2 83 S14 884 2919 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted 2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. 2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. 2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. 2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. 1 (D/E) 2 (D/E) 1 (E) 2 (E) 1 (C/D) 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) 1 (C/E) 2 (D/E) 3 (D/E) V10 V11 84 V12 V10 V11 VC1 VC2 AP7 CV13 CV28 CV13 CV28 CV13 CV28 S14 CV13 CV28 CV13 CV28 CV13 CV28 S14 V12 2 (E) 3 (E) V11 2 (E) 3 (E) V11 886 86 86 886 86 86 S2 S20 338 S2 S20 338 S2 38 48 48 CV28 46 CV28 46 - 449 - 2913 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), non fissile or fissile-excepted 2915 RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissile-excepted 2923 CORROSIVE SOLID, TOXIC, N.O.S. 2923 CORROSIVE SOLID, TOXIC, N.O.S. 2923 CORROSIVE SOLID, TOXIC, N.O.S. 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. 2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. 2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 2.2 (3a) 6.1 2.2 (3b) TC1 2.1.1.3 (4) I 5.2.2 (5) 6.1 +8 3.3 (6) 274 315 3.4 (7a) 0 3.5.1.2 (7b) E5 4.1.4 (8) P001 2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 6.1 TC1 II 274 100 ml E4 6.1 TC2 I 6.1 +8 6.1 +8 274 0 E5 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 6.1 TC2 II 274 500 g E4 6.1 TF1 I 6.1 +8 6.1 +3 274 315 0 E5 2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 6.1 TF1 II 274 100 ml E4 6.1 TF3 I 6.1 +3 6.1 +4.1 274 0 E5 2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 2931 VANADYL SULPHATE 6.1 TF3 II 6.1 +4.1 6.1 274 500 g E4 6.1 T5 II 500 g E4 2933 METHYL 2CHLOROPROPIONATE 3 F1 III 3 5L E1 2934 ISOPROPYL 2CHLOROPROPIONATE 3 F1 III 3 5L E1 2935 ETHYL 2-CHLOROPROPIONATE 3 F1 III 3 5L E1 2936 THIOLACTIC ACID 6.1 T1 II 6.1 100 ml E4 2937 alpha-METHYLBENZYL ALCOHOL, LIQUID 6.1 T1 III 6.1 5L E1 2940 9-PHOSPHABICYCLO-NONANES (CYCLOOCTADIENE PHOSPHINES) 2941 FLUOROANILINES 4.2 S2 II 4.2 0 E2 6.1 T1 III 6.1 5L E1 2942 2-TRIFLUOROMETHYL-ANILINE 6.1 T1 III 6.1 5L E1 2943 TETRAHYDROFURFURYLAMINE 3 F1 III 3 5L E1 2945 N-METHYLBUTYLAMINE 3 FC II 1L E2 2946 2-AMINO-5DIETHYLAMINOPENTANE 6.1 T1 III 3 +8 6.1 5L E1 2947 ISOPROPYL CHLOROACETATE 3 F1 III 3 5L E1 2948 3-TRIFLUOROMETHYL-ANILINE 6.1 T1 II 6.1 100 ml E4 2949 SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization 2950 MAGNESIUM GRANULES, COATED, particle size not less than 149 microns 2956 5-tert-BUTYL-2,4,6-TRINITRO-mXYLENE (MUSK XYLENE) 2965 BORON TRIFLUORIDE DIMETHYL ETHERATE 8 C6 II 8 1 kg E2 4.3 W2 III 523 4.3 4.1 SR1 III 4.1 4.3 WFC I 4.3 +3 +8 1 kg 638 - 450 - Portable tanks and bulk containers E1 4.1.10 (9b) MP8 MP17 4.2.5.2 (10) T14 4.2.5.3 (11) TP2 TP27 P001 IBC02 P002 IBC05 MP15 T11 MP18 T6 TP2 TP27 TP33 P002 IBC06 P001 MP10 T3 TP33 MP8 MP17 T14 TP2 TP27 P001 IBC02 P002 IBC05 MP15 T11 MP18 T6 TP2 TP27 TP33 MP10 T3 TP33 MP10 T3 TP33 MP19 T2 TP1 MP19 T2 TP1 MP19 T2 TP1 MP15 T7 TP2 MP19 T4 TP1 MP14 T3 TP33 MP19 T4 TP1 MP19 T2 TP1 MP19 T7 TP1 MP19 T4 TP1 MP19 T2 TP1 MP15 T7 TP2 MP10 T7 TP2 MP14 T1 BK2 TP33 T10 TP2 TP7 P002 IBC08 P002 IBC08 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P410 IBC06 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 5 kg E0 P410 IBC08 R001 P409 0 E0 P401 4.1.4 (9a) B4 B4 MP19 B4 B4 MP2 MP2 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) L10CH 4.3.5, 6.8.4 (13) TU14 TU15 TE19 TE21 9.1.1.2 (14) AT 1.1.3.6 (15) 1 (C/E) L4BH TU15 TE19 AT S10AH TU14 TU15 TE19 TE21 AT 2 (D/E) 1 (C/E) SGAH L4BH L10CH TU15 TE19 AT TU14 TU15 TE19 TE21 FL TU15 TE19 FL L4BH AT SGAH L4BH SGAH TU15 TE19 AT TU15 TE19 AT 2 (D/E) 1 (C/D) 2 (D/E) 1 (C/E) 2 (D/E) 2 (D/E) 3 (D/E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 Hazard UN No. identification No. Operation Name and description 8.5 (19) S9 S14 5.3.2.3 (20) 668 3.1.2 (1) (2) 2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. S9 S19 68 S9 S14 668 2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. S9 S19 68 S2 S9 S14 663 S2 S9 S19 63 S9 S14 664 S9 S19 64 S9 S19 60 V12 S2 30 2933 METHYL 2CHLOROPROPIONATE V10 V11 V10 V11 V11 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 2931 VANADYL SULPHATE LGBF FL LGBF FL 3 (D/E) V12 S2 30 2934 ISOPROPYL 2CHLOROPROPIONATE LGBF FL 3 (D/E) V12 S2 30 2935 ETHYL 2-CHLOROPROPIONATE 2 (D/E) 2 (E) S9 S19 60 2936 THIOLACTIC ACID S9 60 2937 alpha-METHYLBENZYL ALCOHOL, LIQUID 40 L4BH TU15 TE19 AT L4BH TU15 TE19 AT SGAN CV13 CV28 CV13 CV28 V12 L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2940 9-PHOSPHABICYCLO-NONANES (CYCLOOCTADIENE PHOSPHINES) 2941 FLUOROANILINES L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 2942 2-TRIFLUOROMETHYL-ANILINE LGBF FL 3 (D/E) V12 S2 30 2943 TETRAHYDROFURFURYLAMINE L4BH FL 2 (D/E) 2 (E) S2 S20 338 2945 N-METHYLBUTYLAMINE S9 60 2946 2-AMINO-5DIETHYLAMINOPENTANE S2 30 2947 ISOPROPYL CHLOROACETATE S9 S19 60 2948 3-TRIFLUOROMETHYL-ANILINE 80 2949 SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization 2950 MAGNESIUM GRANULES, COATED, particle size not less than 149 microns 2956 5-tert-BUTYL-2,4,6-TRINITRO-mXYLENE (MUSK XYLENE) 2965 BORON TRIFLUORIDE DIMETHYL ETHERATE L4BH TU15 TE19 LGBF L4BH TU15 TE19 AT 2 (D/E) V1 AT FL 3 (D/E) AT 2 (D/E) 2 (E) SGAN L4BN AT SGAN AT L10DH TU4 TU14 TU22 TE21 TM2 FL 3 (E) 3 (D) 0 (B/E) V12 CV13 CV28 V12 CV13 CV28 V11 V1 V1 VC2 AP4 AP5 CV23 423 CV14 S24 CV23 S2 S20 - 451 - 382 UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) T1 2.1.1.3 (4) II 5.2.2 (5) 6.1 2967 SULPHAMIC ACID 8 C2 III 8 2968 MANEB, STABILIZED or MANEB PREPARATION, STABILIZED against self-heating 4.3 2969 CASTOR BEANS or CASTOR MEAL or CASTOR POMACE or CASTOR FLAKE 2977 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE 9 7 7X +7E +8 2978 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non fissile or fissile-excepted 7 7X +8 2983 ETHYLENE OXIDE AND PROPYLENE OXIDE MIXTURE, not more than 30% ethylene oxide 3 FT1 I 3 +6.1 2984 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary) 5.1 O1 III 5.1 2985 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. 3 FC II 2986 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. 2987 CHLOROSILANES, CORROSIVE, N.O.S. 2988 CHLOROSILANES, WATERREACTIVE, FLAMMABLE, CORROSIVE, N.O.S. 2989 LEAD PHOSPHITE, DIBASIC 8 CF1 II 8 C3 II 4.3 WFC I 4.1 F3 II 2989 LEAD PHOSPHITE, DIBASIC W2 M11 III II 4.3 9 3.3 (6) 547 141 3.5.1.2 (7b) E4 5 kg E1 E1 4.1.4 (8) P001 IBC02 P002 IBC08 LP02 R001 P002 IBC08 R001 4.1.4 (9a) PP34 B4 4.1.10 (9b) MP15 4.2.5.2 (10) T7 4.2.5.3 (11) TP2 MP10 T1 TP33 MP14 T1 TP33 MP10 T3 BK1 BK2 TP33 MP7 MP17 T14 TP2 TP7 MP15 T4 TP1 TP6 TP24 B3 B4 5 kg E2 P002 IBC08 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 0 E0 P001 65 5L E1 P504 IBC02 R001 3 +8 548 0 E0 P010 MP19 T14 TP2 TP7 TP27 8 +3 8 548 0 E0 P010 MP15 T14 548 0 E0 P010 MP15 T14 4.3 +3 +8 4.1 549 0 E0 P401 MP2 T14 TP2 TP7 TP27 TP2 TP7 TP27 TP2 TP7 1 kg E2 MP11 T3 TP33 MP11 T1 TP33 317 PP10 B5 RR7 0 E0 P002 IBC08 P002 IBC08 LP02 R001 P905 0 E5 P001 MP8 MP17 T14 TP2 TP27 61 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 6.1 +3 61 274 5L E1 MP19 T7 TP2 TP28 I 6.1 0 E5 MP8 MP17 T14 TP2 TP27 T6 II 6.1 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 6.1 T6 III 6.1 61 274 648 61 274 648 61 274 648 P001 IBC03 R001 P001 5L E1 MP19 T7 TP2 TP28 6.1 TF2 I 6.1 +3 61 274 0 E5 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 TP27 6.1 TF2 II 6.1 +3 61 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 6.1 TF2 III 6.1 +3 61 274 5L E1 P001 IBC03 R001 MP19 T7 TP2 TP28 4.1 F3 III 4.1 9 5 kg 9 M5 6.1 TF2 I 6.1 +3 296 635 61 274 6.1 TF2 II 6.1 +3 6.1 TF2 III 6.1 T6 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2990 LIFE-SAVING APPLIANCES, SELFINFLATING 2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 3.4 (7a) 100 ml 1 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2966 THIOGLYCOL Packaging - 452 - E1 B4 B3 ADR tank Tank code Special provisions 4.3 (12) L4BH 4.3.5, 6.8.4 (13) TU15 TE19 Vehicle for tank carriage 9.1.1.2 (14) AT Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (D/E) 3 (E) 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV13 CV28 SGAV AT SGAN AT 0 (E) V1 VC1 VC2 AP3 AP4 AP5 SGAV AT 2 (E) V11 VC1 VC2 Hazard UN No. identification No. Operation 8.5 (19) S9 S19 VC1 VC2 AP7 CV23 Name and description 5.3.2.3 (20) 60 3.1.2 (1) (2) 2966 THIOGLYCOL 80 2967 SULPHAMIC ACID 423 2968 MANEB, STABILIZED or MANEB PREPARATION, STABILIZED against self-heating 90 2969 CASTOR BEANS or CASTOR MEAL or CASTOR POMACE or CASTOR FLAKE 2977 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE 0 (C) CV33 S6 S11 S21 78 0 (C) CV33 S6 S11 S21 78 2978 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non fissile or fissile-excepted S2 S22 336 2983 ETHYLENE OXIDE AND PROPYLENE OXIDE MIXTURE, not more than 30% ethylene oxide 50 2984 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary) L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 LGBV TU3 TC2 TE8 TE11 TT1 AT 3 (E) CV24 L4BH FL 2 (D/E) S2 S20 X338 2985 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. L4BN FL S2 X83 L4BN AT 2 (D/E) 2 (E) 0 (B/E) 40 2986 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. 2987 CHLOROSILANES, CORROSIVE, N.O.S. 2988 CHLOROSILANES, WATERREACTIVE, FLAMMABLE, CORROSIVE, N.O.S. 2989 LEAD PHOSPHITE, DIBASIC 40 2989 LEAD PHOSPHITE, DIBASIC L10DH TU14 TU26 TE21 TM2 TM3 FL SGAN AT SGAV AT 2 (E) 3 (E) X80 V1 TU14 TU15 TE19 TE21 FL L4BH TU15 TE19 FL 2 (D/E) L4BH TU15 TE19 FL 2 (D/E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) L4BH TU15 TE19 FL 2 (D/E) L4BH TU15 TE19 FL 2 (D/E) S2 S20 V11 VC1 VC2 3 (E) 1 (C/E) L10CH CV23 CV1 CV13 CV28 CV13 CV28 V12 V12 V12 X338 2990 LIFE-SAVING APPLIANCES, SELFINFLATING 2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC S2 S9 S14 663 S2 S9 S19 63 CV13 CV28 S2 S9 63 CV1 CV13 CV28 CV13 CV28 S9 S14 66 S9 S19 60 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC CV13 CV28 S9 60 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC CV1 CV13 CV28 CV13 CV28 S2 S9 S14 663 S2 S9 S19 63 CV13 CV28 S2 S9 63 2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C - 453 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 2.2 (3b) T6 2.1.1.3 (4) I 5.2.2 (5) 6.1 2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 T6 II 6.1 2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 TF2 I 6.1 +3 2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 TF2 II 2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 TF2 2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 3.3 (6) 61 274 648 61 274 648 61 274 648 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 2994 ARSENICAL PESTICIDE, LIQUID, TOXIC Packaging 3.4 (7a) 0 3.5.1.2 (7b) E5 4.1.4 (8) P001 100 ml E4 5L E1 61 274 0 E5 6.1 +3 61 274 100 ml III 6.1 +3 61 274 T6 I 6.1 6.1 T6 II 6.1 2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 61 274 648 61 274 648 61 274 648 2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 TF2 I 6.1 +3 6.1 TF2 II 6.1 TF2 6.1 2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 4.1.10 (9b) MP8 MP17 4.2.5.2 (10) T14 4.2.5.3 (11) TP2 TP27 P001 IBC02 MP15 T11 TP2 TP27 P001 IBC03 LP01 R001 P001 MP19 T7 TP2 TP28 MP8 MP17 T14 TP2 TP27 E4 P001 IBC02 MP15 T11 TP2 TP27 5L E1 P001 IBC03 R001 MP19 T7 TP2 TP28 0 E5 P001 MP8 MP17 T14 TP2 TP27 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 5L E1 MP19 T7 TP2 TP28 61 274 0 E5 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 TP27 6.1 +3 61 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 III 6.1 +3 61 274 5L E1 MP19 T7 TP2 TP28 T6 I 6.1 0 E5 MP8 MP17 T14 TP2 TP27 6.1 T6 II 6.1 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 61 274 648 61 274 648 61 274 648 P001 IBC03 R001 P001 5L E1 MP19 T7 TP2 TP28 3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 TF2 I 6.1 +3 61 274 0 E5 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 6.1 TF2 II 6.1 +3 61 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 6.1 TF2 III 6.1 +3 61 274 5L E1 MP19 T7 TP2 TP28 6.1 T6 I 6.1 0 E5 MP8 MP17 T14 TP2 3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 T6 II 6.1 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 61 274 648 61 274 648 61 274 648 P001 IBC03 R001 P001 5L E1 MP19 T7 TP2 TP28 3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 TF2 I 6.1 +3 61 274 0 E5 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 TP27 6.1 TF2 II 6.1 +3 61 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 - 454 - 4.1.4 (9a) ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) L10CH 4.3.5, 6.8.4 (13) TU14 TU15 TE19 TE21 9.1.1.2 (14) AT 1.1.3.6 (15) 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) L10CH TU14 TU15 TE19 TE21 FL L4BH TU15 TE19 L4BH Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV1 CV13 CV28 CV13 CV28 8.5 (19) S9 S14 5.3.2.3 (20) 66 3.1.2 (1) (2) 2994 ARSENICAL PESTICIDE, LIQUID, TOXIC S9 S19 60 2994 ARSENICAL PESTICIDE, LIQUID, TOXIC CV13 CV28 S9 60 2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 1 (C/E) CV1 CV13 CV28 S2 S9 S14 663 2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C FL 2 (D/E) CV13 CV28 S2 S9 S19 63 2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 63 2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC L4BH TU15 TE19 AT 2 (D/E) CV1 CV13 CV28 CV13 CV28 S9 S19 60 2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) S2 S9 S14 663 L4BH TU15 TE19 FL 2 (D/E) CV1 CV13 CV28 CV13 CV28 S2 S9 S19 63 L4BH TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 63 L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 L4BH TU15 TE19 AT 2 (D/E) CV1 CV13 CV28 CV13 CV28 2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2998 TRIAZINE PESTICIDE, LIQUID, TOXIC S9 S19 60 2998 TRIAZINE PESTICIDE, LIQUID, TOXIC L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 2998 TRIAZINE PESTICIDE, LIQUID, TOXIC L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) S2 S9 S14 663 L4BH TU15 TE19 FL 2 (D/E) CV1 CV13 CV28 CV13 CV28 S2 S9 S19 63 L4BH TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 63 L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 L4BH TU15 TE19 AT 2 (D/E) CV1 CV13 CV28 CV13 CV28 3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC S9 S19 60 3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) S2 S9 S14 663 L4BH TU15 TE19 FL 2 (D/E) CV1 CV13 CV28 CV13 CV28 S2 S9 S19 63 3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C V12 V12 V12 V12 V12 V12 V12 - 455 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 2.2 (3a) 6.1 2.2 (3b) TF2 2.1.1.3 (4) III 5.2.2 (5) 6.1 +3 3.3 (6) 61 274 3.4 (7a) 5L 3.5.1.2 (7b) E1 6.1 T6 I 6.1 0 E5 3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 6.1 T6 II 6.1 100 ml E4 3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 61 274 648 61 274 648 61 274 648 5L E1 3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 TF2 I 6.1 +3 61 274 0 E5 6.1 TF2 II 6.1 +3 61 274 100 ml E4 6.1 TF2 III 6.1 +3 61 274 5L E1 6.1 T6 I 6.1 0 E5 3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 T6 II 6.1 100 ml 3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 61 274 648 61 274 648 61 274 648 3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 6.1 TF2 I 6.1 +3 6.1 TF2 II 6.1 TF2 6.1 3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 4.1.10 (9b) MP19 4.2.5.2 (10) T7 4.2.5.3 (11) TP2 TP28 MP8 MP17 T14 TP2 TP27 P001 IBC02 MP15 T11 TP2 TP27 P001 IBC03 LP01 R001 P001 MP19 T7 TP2 TP28 MP8 MP17 T14 TP2 TP27 P001 IBC02 MP15 T11 TP2 TP27 P001 IBC03 R001 P001 MP19 T7 TP2 TP28 MP8 MP17 T14 TP2 TP27 E4 P001 IBC02 MP15 T11 TP2 TP27 5L E1 MP19 T7 TP2 TP28 61 274 0 E5 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 TP27 6.1 +3 61 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 III 6.1 +3 61 274 5L E1 P001 IBC03 R001 MP19 T7 TP2 TP28 T6 I 6.1 0 E5 P001 MP8 MP17 T14 TP2 TP27 6.1 T6 II 6.1 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 61 274 648 61 274 648 61 274 648 5L E1 MP19 T7 TP2 TP28 3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 TF2 I 6.1 +3 61 274 0 E5 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 TP27 6.1 TF2 II 6.1 +3 61 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 6.1 TF2 III 6.1 +3 61 274 5L E1 MP19 T7 TP2 TP28 6.1 T6 I 6.1 0 E5 MP8 MP17 T14 TP2 TP27 3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 T6 II 6.1 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 61 274 648 61 274 648 61 274 648 P001 IBC03 R001 P001 5L E1 MP19 T7 TP2 TP28 3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 TF2 I 6.1 +3 0 E5 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 TP27 61 274 - 456 - 4.1.4 (8) P001 IBC03 R001 P001 4.1.4 (9a) ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) FL 1.1.3.6 (15) 2 (D/E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) L4BH TU15 TE19 FL 2 (D/E) L4BH TU15 TE19 FL 2 (D/E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) L10CH TU14 TU15 TE19 TE21 FL L4BH TU15 TE19 L4BH Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) CV13 CV28 8.5 (19) S2 S9 5.3.2.3 (20) 63 CV1 CV13 CV28 CV13 CV28 S9 S14 66 S9 S19 60 3010 COPPER BASED PESTICIDE, LIQUID, TOXIC CV13 CV28 S9 60 3010 COPPER BASED PESTICIDE, LIQUID, TOXIC CV1 CV13 CV28 CV13 CV28 S2 S9 S14 663 S2 S9 S19 63 CV13 CV28 S2 S9 63 CV1 CV13 CV28 CV13 CV28 S9 S14 66 3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC S9 S19 60 3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC CV13 CV28 S9 60 3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC 1 (C/E) CV1 CV13 CV28 S2 S9 S14 663 FL 2 (D/E) CV13 CV28 S2 S9 S19 63 TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 63 L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 L4BH TU15 TE19 AT 2 (D/E) CV1 CV13 CV28 CV13 CV28 3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC S9 S19 60 3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) S2 S9 S14 663 L4BH TU15 TE19 FL 2 (D/E) CV1 CV13 CV28 CV13 CV28 S2 S9 S19 63 L4BH TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 63 L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 L4BH TU15 TE19 AT 2 (D/E) CV1 CV13 CV28 CV13 CV28 3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC S9 S19 60 3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) CV1 CV13 CV28 S2 S9 S14 663 3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C V12 V12 V12 V12 V12 V12 V12 - 457 - 3.1.2 (1) (2) 3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3010 COPPER BASED PESTICIDE, LIQUID, TOXIC UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 2.2 (3a) 6.1 2.2 (3b) TF2 2.1.1.3 (4) II 5.2.2 (5) 6.1 +3 3.3 (6) 61 274 3.4 (7a) 100 ml 3.5.1.2 (7b) E4 4.1.4 (8) P001 IBC02 6.1 TF2 III 6.1 +3 61 274 5L E1 6.1 T6 I 6.1 0 3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 6.1 T6 II 6.1 3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 61 274 648 61 274 648 61 274 648 3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 TF2 I 6.1 +3 6.1 TF2 II 6.1 TF2 6.1 3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 4.1.10 (9b) MP15 4.2.5.2 (10) T11 4.2.5.3 (11) TP2 TP27 P001 IBC03 R001 MP19 T7 TP2 TP28 E5 P001 MP8 MP17 T14 TP2 TP27 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 5L E1 MP19 T7 TP2 TP28 61 274 0 E5 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 TP27 6.1 +3 61 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 III 6.1 +3 61 274 5L E1 MP19 T7 TP2 TP28 T6 I 6.1 0 E5 MP8 MP17 T14 TP2 TP27 6.1 T6 II 6.1 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 61 274 648 61 274 648 61 274 648 P001 IBC03 R001 P001 5L E1 MP19 T7 TP2 TP28 3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash-point less than 23 °C 3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash-point less than 23 °C 3022 1,2-BUTYLENE OXIDE, STABILIZED 3 FT2 I 3 +6.1 61 274 0 E0 P001 IBC03 LP01 R001 P001 MP7 MP17 T14 TP2 TP27 3 FT2 II 3 +6.1 61 274 1L E2 P001 IBC02 R001 MP19 T11 TP2 TP27 3 F1 II 3 1L E2 MP19 T4 TP1 3023 2-METHYL-2-HEPTANETHIOL 6.1 TF1 I 6.1 +3 354 0 E0 P001 IBC02 R001 P602 MP8 MP17 T20 TP2 TP35 3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 3 FT2 I 3 +6.1 61 274 0 E0 P001 MP7 MP17 T14 TP2 TP27 3 FT2 II 3 +6.1 61 274 1L E2 P001 IBC02 R001 MP19 T11 TP2 TP27 6.1 TF2 I 6.1 +3 61 274 0 E5 P001 MP8 MP17 T14 TP2 TP27 6.1 TF2 II 6.1 +3 61 274 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 6.1 TF2 III 6.1 +3 61 274 5L E1 P001 IBC03 R001 MP19 T7 TP1 TP28 6.1 T6 I 6.1 0 E5 P001 MP8 MP17 T14 TP2 TP27 6.1 T6 II 6.1 61 274 648 61 274 648 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC - 458 - 4.1.4 (9a) ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) FL L4BH TU15 TE19 L10CH Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (D/E) 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV13 CV28 8.5 (19) S2 S9 S19 5.3.2.3 (20) 63 FL 2 (D/E) V12 CV13 CV28 S2 S9 63 TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 L4BH TU15 TE19 AT 2 (D/E) CV1 CV13 CV28 CV13 CV28 S9 S19 60 3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) S2 S9 S14 663 L4BH TU15 TE19 FL 2 (D/E) CV1 CV13 CV28 CV13 CV28 S2 S9 S19 63 L4BH TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 63 L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 L4BH TU15 TE19 AT 2 (D/E) CV1 CV13 CV28 CV13 CV28 3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC S9 S19 60 3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 FL 2 (D/E) S2 S20 339 3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash-point less than 23 °C 3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash-point less than 23 °C 3022 1,2-BUTYLENE OXIDE, STABILIZED S2 S9 S14 663 3023 2-METHYL-2-HEPTANETHIOL S2 S22 336 3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC LGBF V12 V12 V12 L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L10CH TU14 TU15 TE21 FL 1 (C/E) CV1 CV13 CV28 CV13 CV28 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) CV1 CV13 CV28 S2 S9 S14 663 L4BH TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 S19 63 L4BH TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 63 L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 L4BH TU15 TE19 AT 2 (D/E) CV1 CV13 CV28 CV13 CV28 S9 S19 60 V12 - 459 - 3.1.2 (1) (2) 3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (1) (2) 3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 2.2 (3a) 6.1 2.2 (3b) T6 2.1.1.3 (4) III 5.2.2 (5) 6.1 3.3 (6) 61 274 648 3.4 (7a) 5L 3.5.1.2 (7b) E1 3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 T7 I 6.1 0 E5 3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 500 g E4 3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 61 274 648 61 274 648 61 274 648 3028 BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE SOLID, electric storage 8 C11 3048 ALUMINIUM PHOSPHIDE PESTICIDE 6.1 T7 3054 CYCLOHEXYL MERCAPTAN 3 3055 2-(2-AMINOETHOXY) ETHANOL III 6.1 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities T7 Packaging E1 4.1.4 (8) P001 IBC03 LP01 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P801 P801a 4.1.4 (9a) 4.1.10 (9b) MP19 4.2.5.2 (10) T7 4.2.5.3 (11) TP1 TP28 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 B4 B3 8 295 304 598 2 kg E0 I 6.1 153 648 0 E0 P002 IBC07 MP18 T6 TP33 F1 III 3 5L E1 MP19 T2 TP1 8 C7 III 8 5L E1 MP19 T4 TP1 3056 n-HEPTALDEHYDE 3 F1 III 3 5L E1 MP19 T2 TP1 3057 TRIFLUOROACETYL CHLORIDE 2 2TC 2.3 +8 0 E0 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P200 MP9 T50 TP21 3064 NITROGLYCERIN, SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin 3 D II 3 0 E0 P300 MP2 3065 ALCOHOLIC BEVERAGES, with more than 70% alcohol by volume 3 F1 II 3 5L E2 3065 ALCOHOLIC BEVERAGES, with more than 24% but not more than 70% alcohol by volume 3066 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) 3 F1 III 3 5L E1 8 C9 II 8 1L E2 P001 IBC02 R001 P001 IBC03 R001 P001 IBC02 3066 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) 8 C9 III 8 163 367 5L E1 3070 ETHYLENE OXIDE AND DICHLORODIFLUOROMETHANE MIXTURE with not more than 12.5% ethylene oxide 3071 MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. 2 2A 2.2 662 120 ml 6.1 TF1 6.1 +3 274 3072 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment 9 M5 9 296 635 3073 VINYLPYRIDINES, STABILIZED 6.1 TFC II II 359 144 145 247 163 367 6.1 +3 +8 - 460 - PP2 MP19 T4 TP1 PP2 MP19 T2 TP1 MP15 T7 TP2 TP28 P001 IBC03 R001 MP19 T4 TP1 TP29 E1 P200 MP9 (M) T50 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 0 E0 P905 100 ml E4 P001 IBC01 MP15 T7 TP2 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT S10AH L10CH TU14 TU15 TE19 TE21 SGAH L4BH SGAH L4BH S10AH Transport category (Tunnel restriction code) Special provisions for carriage Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (E) 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) CV13 CV28 8.5 (19) S9 5.3.2.3 (20) 60 3.1.2 (1) (2) 3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC AT 1 (C/E) V10 S9 S14 66 3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 S9 S19 60 3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC TU15 TE19 AT 2 (E) VC1 VC2 AP7 S9 60 3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 3 (E) VC1 VC2 AP8 80 3028 BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE SOLID, electric storage S9 S14 642 3048 ALUMINIUM PHOSPHIDE PESTICIDE S2 30 3054 CYCLOHEXYL MERCAPTAN 80 3055 2-(2-AMINOETHOXY) ETHANOL S2 30 3056 n-HEPTALDEHYDE S14 268 3057 TRIFLUOROACETYL CHLORIDE 1 (C/E) V10 LGBF FL 3 (D/E) V12 L4BN AT 3 (E) V12 LGBF FL 3 (D/E) V12 AT 1 (C/D) TU15 TE19 TA4 TT9 CV13 CV28 CV1 CV13 CV28 CV9 CV10 CV36 2 (B) S2 S14 S2 S20 33 3065 ALCOHOLIC BEVERAGES, with more than 70% alcohol by volume S2 30 3065 ALCOHOLIC BEVERAGES, with more than 24% but not more than 70% alcohol by volume 3066 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) LGBF FL 2 (D/E) LGBF FL 3 (D/E) L4BN AT 2 (E) L4BN AT 3 (E) V12 3064 NITROGLYCERIN, SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin 80 V12 PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 L4BH TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 S19 80 3066 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning and reducing compound) 20 3070 ETHYLENE OXIDE AND DICHLORODIFLUOROMETHANE MIXTURE with not more than 12.5% ethylene oxide 3071 MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. 63 3 (E) L4BH Name and description Packages AT PxBH(M) Hazard UN No. identification No. Operation TU15 TE19 FL 2 (D/E) 3072 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment CV13 CV28 - 461 - S2 S9 S19 638 3073 VINYLPYRIDINES, STABILIZED UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 9 2.2 (3b) M7 2.1.1.3 (4) III 5.2.2 (5) 9 3078 CERIUM, turnings or gritty powder 4.3 W2 II 4.3 3079 METHACRYLONITRILE, STABILIZED 6.1 TF1 I 3080 ISOCYANATES, TOXIC, 6.1 FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. 3082 ENVIRONMENTALLY 9 HAZARDOUS SUBSTANCE, LIQUID, N.O.S. TF1 M6 3083 PERCHLORYL FLUORIDE 2 2TO 3.3 (6) 274 335 375 601 550 3.4 (7a) 5 kg 3.5.1.2 (7b) E1 500 g E2 6.1 +3 354 0 E0 II 6.1 +3 274 551 100 ml E4 P001 IBC02 III 9 274 335 375 601 5L E1 0 E0 P001 IBC03 LP01 R001 P200 3084 CORROSIVE SOLID, OXIDIZING, N.O.S. 3084 CORROSIVE SOLID, OXIDIZING, N.O.S. 3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 8 CO2 I 274 0 E0 8 CO2 II 274 1 kg E2 5.1 OC2 I 274 0 E0 5.1 OC2 II 274 1 kg E2 5.1 OC2 III 274 5 kg E1 2.3 +5.1 8 +5.1 8 +5.1 5.1 +8 5.1 +8 5.1 +8 3086 TOXIC SOLID, OXIDIZING, N.O.S. 6.1 TO2 I 6.1 +5.1 274 0 E5 3086 TOXIC SOLID, OXIDIZING, N.O.S. 6.1 TO2 II 274 500 g E4 3087 OXIDIZING SOLID, TOXIC, N.O.S. 5.1 OT2 I 274 0 E0 3087 OXIDIZING SOLID, TOXIC, N.O.S. 5.1 OT2 II 274 1 kg E2 3087 OXIDIZING SOLID, TOXIC, N.O.S. 5.1 OT2 III 6.1 +5.1 5.1 +6.1 5.1 +6.1 5.1 +6.1 274 5 kg E1 3088 SELF-HEATING SOLID, ORGANIC, N.O.S. 3088 SELF-HEATING SOLID, ORGANIC, N.O.S. 4.2 S2 II 4.2 274 0 E2 4.2 S2 III 4.2 274 0 E1 3089 METAL POWDER, FLAMMABLE, N.O.S. 3089 METAL POWDER, FLAMMABLE, N.O.S. 4.1 3090 LITHIUM METAL BATTERIES (including lithium alloy batteries) 9 M4 9 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT or LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries) 3092 1-METHOXY-2-PROPANOL 9 M4 9 3 F1 III 3 8 CO1 I 8 CO1 II 8 CW1 I 8 CW1 II 8 CS2 I 8 +5.1 8 +5.1 8 +4.3 8 +4.3 8 +4.2 3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. 3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. 3094 CORROSIVE LIQUID, WATERREACTIVE, N.O.S. 3094 CORROSIVE LIQUID, WATERREACTIVE, N.O.S. 3095 CORROSIVE SOLID, SELFHEATING, N.O.S. 4.1 F3 F3 II III 4.1 4.1 552 552 188 230 376 377 636 188 230 376 377 636 1 kg 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. Packaging E2 E1 4.1.4 (8) P002 IBC08 LP02 R001 P410 IBC07 P602 4.1.4 (9a) PP12 B3 4.1.10 (9b) MP10 4.2.5.2 (10) T1 BK1 BK2 4.2.5.3 (11) TP33 MP14 T3 TP33 MP8 MP17 T20 TP2 TP37 MP15 T11 TP2 TP27 MP19 T4 TP1 TP29 MP9 (M) P002 MP18 T6 TP33 P002 IBC06 P503 MP10 T3 TP33 P002 IBC06 P002 IBC08 R001 P002 MP2 T3 TP33 MP2 T1 TP33 MP18 T6 TP33 P002 IBC06 P503 MP10 T3 TP33 P002 IBC06 P002 IBC08 R001 P410 IBC06 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 R001 P903 P908 P909 LP903 LP904 P903 P908 P909 LP903 LP904 P001 IBC03 LP01 R001 P001 MP2 T3 TP33 MP2 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP11 T3 TP33 MP11 T1 TP33 MP19 T2 TP1 T6 TP33 PP1 MP2 B3 MP2 B3 B3 B4 B4 0 E0 0 E0 5L E1 274 0 E0 274 1L E2 274 0 E0 P001 IBC02 P001 274 1L E2 P001 MP8 MP17 MP15 274 0 E0 P002 MP18 - 462 - MP8 MP17 MP15 ADR tank Tank code Special provisions 4.3 (12) SGAV LGBV 4.3.5, 6.8.4 (13) SGAN Vehicle for tank carriage Transport category (Tunnel restriction code) 7.3.3 (17) VC1 VC2 7.5.11 (18) CV13 AT 2 (D/E) 1 (C/D) V1 L4BH TU15 TE19 FL 2 (D/E) AT 3 (E) AT 1 (C/D) AT 1 (E) 2 (E) 1 (E) 2 (E) 3 (E) S10AN L10BH SGAN L4BN Loading, unloading and handling 7.2.4 (16) V13 FL TA4 TT9 Bulk 1.1.3.6 (15) 3 (E) TU14 TU15 TE19 TE21 PxBH(M) Packages 9.1.1.2 (14) AT L10CH LGBV Special provisions for carriage AT SGAN TU3 AT SGAN TU3 AT S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) SGAH L4BH TU15 TE19 AT 2 (D/E) 1 (E) 2 (E) 3 (E) SGAN TU3 AT SGAN TU3 AT SGAV AT SGAV AT SGAN AT SGAV AT Hazard UN No. identification No. Operation 8.5 (19) 5.3.2.3 (20) 90 3.1.2 (1) (2) 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 423 3078 CERIUM, turnings or gritty powder S2 S9 S14 663 3079 METHACRYLONITRILE, STABILIZED S2 S9 S19 63 3080 ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. CV23 CV1 CV13 CV28 CV13 CV28 V12 CV13 CV9 CV10 CV36 CV24 V11 90 S14 265 3083 PERCHLORYL FLUORIDE S14 885 3084 CORROSIVE SOLID, OXIDIZING, N.O.S. 3084 CORROSIVE SOLID, OXIDIZING, N.O.S. 3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 3085 OXIDIZING SOLID, CORROSIVE, N.O.S. 3085 OXIDIZING SOLID, CORROSIVE, N.O.S. CV24 CV24 V11 V11 V11 85 S20 CV24 58 CV24 58 CV1 CV13 CV28 CV13 CV28 CV24 CV28 CV24 CV28 CV24 CV28 S9 S14 665 3086 TOXIC SOLID, OXIDIZING, N.O.S. S9 S19 65 3086 TOXIC SOLID, OXIDIZING, N.O.S. S20 3087 OXIDIZING SOLID, TOXIC, N.O.S. 56 3087 OXIDIZING SOLID, TOXIC, N.O.S. 56 3087 OXIDIZING SOLID, TOXIC, N.O.S. 3088 SELF-HEATING SOLID, ORGANIC, N.O.S. 3088 SELF-HEATING SOLID, ORGANIC, N.O.S. 2 (D/E) 3 (E) V1 40 V1 40 2 (E) 3 (E) V11 40 V11 Name and description VC1 VC2 40 3089 METAL POWDER, FLAMMABLE, N.O.S. 3089 METAL POWDER, FLAMMABLE, N.O.S. 2 (E) 3090 LITHIUM METAL BATTERIES (including lithium alloy batteries) 2 (E) 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT or LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries) 3092 1-METHOXY-2-PROPANOL LGBF FL 3 (D/E) L10BH AT L4BN AT L10BH AT L4BN AT S10AN AT 1 (E) 2 (E) 1 (D/E) 2 (E) 1 (E) V12 CV24 S2 30 S14 885 CV24 85 S14 823 823 S14 - 463 - 884 3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. 3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. 3094 CORROSIVE LIQUID, WATERREACTIVE, N.O.S. 3094 CORROSIVE LIQUID, WATERREACTIVE, N.O.S. 3095 CORROSIVE SOLID, SELFHEATING, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 8 2.2 (3b) CS2 2.1.1.3 (4) II 8 CW2 I 8 CW2 II 4.1 FO 5.1 OC1 I 5.1 OC1 II 5.1 OC1 III 3099 OXIDIZING LIQUID, TOXIC, N.O.S. 3099 OXIDIZING LIQUID, TOXIC, N.O.S. 3099 OXIDIZING LIQUID, TOXIC, N.O.S. 5.1 OT1 I 5.1 OT1 II 5.1 OT1 III 3100 OXIDIZING SOLID, SELFHEATING, N.O.S. 3101 ORGANIC PEROXIDE TYPE B, LIQUID 5.1 OS 5.2 P1 3102 ORGANIC PEROXIDE TYPE B, SOLID 5.2 3103 ORGANIC PEROXIDE TYPE C, LIQUID Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3095 CORROSIVE SOLID, SELFHEATING, N.O.S. 3096 CORROSIVE SOLID, WATERREACTIVE, N.O.S. 3096 CORROSIVE SOLID, WATERREACTIVE, N.O.S. 3097 FLAMMABLE SOLID, OXIDIZING, N.O.S. 3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. Packaging 5.2.2 (5) 8 +4.2 8 +4.3 8 +4.3 3.3 (6) 274 3.4 (7a) 1 kg 3.5.1.2 (7b) E2 274 0 E0 274 1 kg E2 5.1 +8 5.1 +8 5.1 +8 274 0 E0 P502 MP2 274 1L E2 MP2 274 5L E1 274 0 E0 P504 IBC01 P504 IBC02 R001 P502 274 1L E2 274 5L 5.2 +1 122 181 274 25 ml E0 P520 MP4 P1 5.2 +1 122 181 274 100 g E0 P520 MP4 5.2 P1 5.2 122 274 25 ml E0 P520 MP4 3104 ORGANIC PEROXIDE TYPE C, SOLID 5.2 P1 5.2 122 274 100 g E0 P520 MP4 3105 ORGANIC PEROXIDE TYPE D, LIQUID 5.2 P1 5.2 122 274 125 ml E0 P520 MP4 3106 ORGANIC PEROXIDE TYPE D, SOLID 5.2 P1 5.2 122 274 500 g E0 P520 MP4 3107 ORGANIC PEROXIDE TYPE E, LIQUID 5.2 P1 5.2 122 274 125 ml E0 P520 MP4 3108 ORGANIC PEROXIDE TYPE E, SOLID 5.2 P1 5.2 122 274 500 g E0 P520 MP4 3109 ORGANIC PEROXIDE TYPE F, LIQUID 5.2 P1 5.2 122 274 125 ml E0 P520 IBC520 MP4 T23 3110 ORGANIC PEROXIDE TYPE F, SOLID 5.2 P1 5.2 122 274 500 g E0 P520 IBC520 MP4 T23 3111 ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED 5.2 P2 5.2 +1 122 181 274 0 E0 P520 MP4 3112 ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED 5.2 P2 5.2 +1 122 181 274 0 E0 P520 MP4 3113 ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED 5.2 P2 5.2 122 274 0 E0 P520 MP4 3114 ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED 5.2 P2 5.2 122 274 0 E0 P520 MP4 5.1 +6.1 5.1 +6.1 5.1 +6.1 - 464 - 4.1.4 (8) P002 IBC06 P002 4.1.4 (9a) P002 IBC06 CARRIAGE PROHIBITED P504 IBC01 E1 P504 IBC02 R001 CARRIAGE PROHIBITED 4.1.10 (9b) MP10 4.2.5.2 (10) T3 4.2.5.3 (11) TP33 MP18 T6 TP33 MP10 T3 TP33 MP2 MP2 MP2 MP2 TP33 ADR tank Tank code Special provisions 4.3 (12) SGAN 4.3.5, 6.8.4 (13) S10AN L10BH SGAN L4BN Vehicle for tank carriage 9.1.1.2 (14) AT AT AT Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk 1.1.3.6 7.2.4 7.3.3 (15) (16) (17) 2 V11 (E) 1 (E) 2 V11 (E) CARRIAGE PROHIBITED Loading, unloading and handling 7.5.11 (18) Hazard UN No. identification No. Operation 8.5 (19) 5.3.2.3 (20) 84 S14 842 842 1 (E) 2 (E) 3 (E) CV24 1 (E) 2 (E) 3 (E) CV24 CV28 CV24 CV28 CV24 CV28 S20 CV24 CV24 S20 L4BN(+) S4AN(+) TU3 TU13 TU30 TE12 TA2 TM4 TU3 TU13 TU30 TE12 TA2 TM4 V1 V5 1 (B) V1 V5 1 (D) V1 1 (D) V1 2 (D) V1 2 (D) V1 2 (D) V1 2 (D) V1 AT 2 (D) V1 AT 2 (D) V1 1 (B) V8 1 (B) V8 1 (D) V8 1 (D) V8 CV15 CV20 CV22 CV24 CV15 CV20 CV22 CV24 CV15 CV20 CV22 CV24 CV15 CV20 CV22 CV24 CV15 CV22 CV24 CV15 CV22 CV24 CV15 CV22 CV24 CV15 CV22 CV24 CV15 CV22 CV24 CV15 CV22 CV24 CV15 CV20 CV21 CV22 CV24 CV15 CV20 CV21 CV22 CV24 CV15 CV20 CV21 CV22 CV24 CV15 CV20 CV21 CV22 CV24 - 465 - 3.1.2 (1) (2) 3095 CORROSIVE SOLID, SELFHEATING, N.O.S. 3096 CORROSIVE SOLID, WATERREACTIVE, N.O.S. 3096 CORROSIVE SOLID, WATERREACTIVE, N.O.S. 3097 FLAMMABLE SOLID, OXIDIZING, N.O.S. 3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 3098 OXIDIZING LIQUID, CORROSIVE, N.O.S. 3099 OXIDIZING LIQUID, TOXIC, N.O.S. 3099 OXIDIZING LIQUID, TOXIC, N.O.S. 3099 OXIDIZING LIQUID, TOXIC, N.O.S. CARRIAGE PROHIBITED 1 (B) Name and description 3100 OXIDIZING SOLID, SELFHEATING, N.O.S. 3101 ORGANIC PEROXIDE TYPE B, LIQUID S9 S17 S9 S17 3102 ORGANIC PEROXIDE TYPE B, SOLID S8 S18 3103 ORGANIC PEROXIDE TYPE C, LIQUID S8 S18 3104 ORGANIC PEROXIDE TYPE C, SOLID S19 3105 ORGANIC PEROXIDE TYPE D, LIQUID S19 3106 ORGANIC PEROXIDE TYPE D, SOLID 3107 ORGANIC PEROXIDE TYPE E, LIQUID 3108 ORGANIC PEROXIDE TYPE E, SOLID 539 3109 ORGANIC PEROXIDE TYPE F, LIQUID 539 3110 ORGANIC PEROXIDE TYPE F, SOLID S4 S9 S16 3111 ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED S4 S9 S16 3112 ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED S4 S8 S17 3113 ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED S4 S8 S17 3114 ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 5.2 2.2 (3b) P2 3116 ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED 5.2 3117 ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED 5.2.2 (5) 5.2 3.3 (6) 122 274 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P520 P2 5.2 122 274 0 E0 P520 MP4 5.2 P2 5.2 122 274 0 E0 P520 MP4 3118 ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED 5.2 P2 5.2 122 274 0 E0 P520 MP4 3119 ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED 5.2 P2 5.2 122 274 0 E0 P520 IBC520 MP4 T23 3120 ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED 5.2 P2 5.2 122 274 0 E0 P520 IBC520 MP4 T23 TP33 3121 OXIDIZING SOLID, WATERREACTIVE, N.O.S. 3122 TOXIC LIQUID, OXIDIZING, N.O.S. 5.1 OW 6.1 TO1 I 6.1 +5.1 274 315 0 E0 P001 MP8 MP17 3122 TOXIC LIQUID, OXIDIZING, N.O.S. 3123 TOXIC LIQUID, WATERREACTIVE, N.O.S. 6.1 TO1 II 274 100 ml E4 TW1 I 274 315 0 E0 P001 IBC02 P099 MP15 6.1 6.1 +5.1 6.1 +4.3 3123 TOXIC LIQUID, WATERREACTIVE, N.O.S. 3124 TOXIC SOLID, SELF-HEATING, N.O.S. 6.1 TW1 II 274 100 ml E4 TS I 274 0 E5 P001 IBC02 P002 MP15 6.1 6.1 +4.3 6.1 +4.2 MP18 T6 TP33 3124 TOXIC SOLID, SELF-HEATING, N.O.S. 3125 TOXIC SOLID, WATERREACTIVE, N.O.S. 6.1 TS II 274 0 E4 MP10 T3 TP33 6.1 TW2 I 6.1 +4.2 6.1 +4.3 274 0 E5 MP18 T6 TP33 6.1 TW2 II 274 500 g E4 MP10 T3 TP33 4.2 SC2 II 274 0 MP14 T3 TP33 4.2 SC2 III 6.1 +4.3 4.2 +8 4.2 +8 274 0 MP14 T1 TP33 3127 SELF-HEATING SOLID, OXIDIZING, N.O.S 3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 4.2 SO 4.2 ST2 II 274 0 E2 MP14 T3 TP33 4.2 ST2 III 4.2 +6.1 4.2 +6.1 274 0 E1 MP14 T1 TP33 3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 4.3 WC1 I 274 0 E0 RR7 RR8 MP2 T14 4.3 WC1 II 274 500 ml E0 RR7 RR8 MP15 T11 4.3 WC1 III 4.3 +8 4.3 +8 4.3 +8 274 1L E1 MP15 T7 TP2 TP7 TP2 TP7 TP2 TP7 3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 4.3 WT1 I 274 0 E0 4.3 WT1 II 274 500 ml E0 4.3 WT1 III 4.3 +6.1 4.3 +6.1 4.3 +6.1 274 1L E1 3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 4.3 WC2 I 4.3 +8 274 0 E0 3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 4.3 WC2 II 4.3 +8 274 500 g E2 3125 TOXIC SOLID, WATERREACTIVE, N.O.S. 3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. 3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3115 ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED Packaging 4.1.4 (9a) 4.1.10 (9b) MP4 4.2.5.2 (10) 4.2.5.3 (11) CARRIAGE PROHIBITED - 466 - MP8 MP17 P002 IBC06 P099 P002 IBC06 E2 P410 IBC05 E1 P002 IBC08 B3 R001 CARRIAGE PROHIBITED P410 IBC05 P002 IBC08 R001 P402 P402 IBC01 P001 IBC02 R001 P402 P402 IBC01 P001 IBC02 R001 P403 P410 IBC06 B3 RR4 RR8 MP2 RR4 RR8 BB1 MP15 MP15 MP2 T9 TP7 TP33 MP14 T3 TP33 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (D) 7.2.4 (16) V8 7.3.3 (17) 1 (D) V8 1 (D) V8 1 (D) V8 7.5.11 (18) CV15 CV21 CV22 CV24 CV15 CV21 CV22 CV24 CV15 CV21 CV22 CV24 CV15 CV21 CV22 CV24 CV15 CV21 CV22 CV24 CV15 CV21 CV22 CV24 L4BN(+) TU3 TU13 TU30 TE12 TA2 TM4 AT 1 (D) V8 S4AN(+) TU3 TU13 TU30 TE12 TA2 TM4 AT 1 (D) V8 Hazard UN No. identification No. Operation 8.5 (19) S4 S18 5.3.2.3 (20) TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT 2 (D/E) 1 (C/E) L4BH TU15 TE19 AT S10AH L10CH TU14 TU15 TE19 TE21 AT SGAH L4BH S10AH L10CH TU15 TE19 AT TU14 TU15 TE19 TE21 AT TU15 TE19 AT SGAH L4BH SGAN AT SGAN AT 2 (D/E) 1 (C/E) 2 (D/E) 1 (C/E) V11 2 (D/E) 2 (D/E) 3 (E) V11 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 3116 ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED S4 S19 3117 ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED S4 S19 3118 ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED S4 539 3119 ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED S4 539 3120 ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED S9 S14 665 S9 S19 65 S9 S14 623 S9 S19 623 S9 S14 664 S9 S19 64 S9 S14 642 S9 S19 642 V1 48 V1 48 CARRIAGE PROHIBITED SGAN AT SGAN AT L10DH L4DH L4DH L10DH L4DH L4DH S10AN L10DH SGAN TU14 TE21 TM2 TU14 TE21 TM2 TU14 TE21 TM2 TU14 TE21 TM2 TU14 TE21 TM2 TU14 TE21 TM2 TU4 TU14 TU22 TE21 TM2 AT AT AT AT AT AT 2 (D/E) 3 (E) V1 CV28 46 V1 CV28 46 0 (B/E) 0 (D/E) 0 (E) V1 CV23 V1 CV23 382 V1 CV23 382 V1 CV23 CV28 CV23 CV28 CV23 CV28 S20 S20 0 (B/E) 0 (D/E) 0 (E) V1 V1 AT 0 (B/E) V1 CV23 AT 0 (D/E) V1 CV23 - 467 - 3.1.2 (1) (2) 3115 ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED S4 S18 CARRIAGE PROHIBITED L10CH Name and description S20 X382 X362 362 362 3121 OXIDIZING SOLID, WATERREACTIVE, N.O.S. 3122 TOXIC LIQUID, OXIDIZING, N.O.S. 3122 TOXIC LIQUID, OXIDIZING, N.O.S. 3123 TOXIC LIQUID, WATERREACTIVE, N.O.S. 3123 TOXIC LIQUID, WATERREACTIVE, N.O.S. 3124 TOXIC SOLID, SELF-HEATING, N.O.S. 3124 TOXIC SOLID, SELF-HEATING, N.O.S. 3125 TOXIC SOLID, WATERREACTIVE, N.O.S. 3125 TOXIC SOLID, WATERREACTIVE, N.O.S. 3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. 3126 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. 3127 SELF-HEATING SOLID, OXIDIZING, N.O.S 3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 3128 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 3129 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 3130 WATER-REACTIVE LIQUID, TOXIC, N.O.S. X482 3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 482 3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 2.2 (3a) 4.3 2.2 (3b) WC2 2.1.1.3 (4) III 5.2.2 (5) 4.3 +8 3.3 (6) 274 3.4 (7a) 1 kg 3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 3133 WATER-REACTIVE SOLID, OXIDIZING, N.O.S. 3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 4.3 WF2 I 274 0 4.3 WF2 II 274 500 g 4.3 WF2 III 4.3 +4.1 4.3 +4.1 4.3 +4.1 274 1 kg 4.3 WO 4.3 WT2 I 274 0 E0 P403 MP2 4.3 WT2 II 274 500 g E2 4.3 WT2 III 4.3 +6.1 4.3 +6.1 4.3 +6.1 274 1 kg E1 4.3 +4.2 4.3 +4.2 4.3 +4.2 2.2 274 0 E0 P410 IBC05 P410 IBC08 R001 P403 274 0 E2 274 0 E1 3135 WATER-REACTIVE SOLID, SELFHEATING, N.O.S. 3135 WATER-REACTIVE SOLID, SELFHEATING, N.O.S. 3135 WATER-REACTIVE SOLID, SELFHEATING, N.O.S. 3136 TRIFLUOROMETHANE, REFRIGERATED LIQUID 4.3 WS I 4.3 WS II 4.3 WS III 2 3A 3137 OXIDIZING SOLID, FLAMMABLE, 5.1 N.O.S. 3138 ETHYLENE, ACETYLENE AND 2 PROPYLENE MIXTURE, REFRIGERATED LIQUID containing at least 71.5% ethylene with not more than 22.5% acetylene and not more than 6% propylene OF 3139 OXIDIZING LIQUID, N.O.S. 5.1 O1 I 5.1 3139 OXIDIZING LIQUID, N.O.S. 5.1 O1 II 3139 OXIDIZING LIQUID, N.O.S. 5.1 O1 3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. 3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. 3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. 6.1 593 120 ml 3.5.1.2 (7b) E1 4.1.4 4.1.4 (8) (9a) P410 IBC08 B4 R001 E0 P403 IBC99 E2 P410 IBC04 E1 P410 IBC06 CARRIAGE PROHIBITED E1 P410 IBC05 P410 IBC08 P203 4.1.10 (9b) MP14 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP14 T3 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP9 T75 TP5 T75 TP5 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP2 B4 MP2 B4 CARRIAGE PROHIBITED 0 E0 P203 MP9 274 0 E0 P502 MP2 5.1 274 1L E2 MP2 III 5.1 274 5L E1 T1 I 6.1 43 274 0 E5 P504 IBC02 P504 IBC02 R001 P001 6.1 T1 II 6.1 43 274 100 ml E4 P001 IBC02 MP15 6.1 T1 III 6.1 43 274 5L E1 MP19 3141 ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. 6.1 T4 III 6.1 45 274 512 5L E1 3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 6.1 T1 I 6.1 274 0 E5 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 6.1 T1 II 6.1 274 100 ml E4 6.1 T1 III 6.1 274 5L E1 3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 6.1 T2 I 6.1 274 0 E5 6.1 T2 II 6.1 274 500 g E4 6.1 3F T2 2.1 III 6.1 274 - 468 - 5 kg E1 MP2 MP8 MP17 MP19 MP8 MP17 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 MP15 MP19 B4 B3 ADR tank Tank code Special provisions 4.3 (12) SGAN 4.3.5, 6.8.4 (13) SGAN L4DH SGAN L4DH TU14 TE21 TM2 TU14 TE21 TM2 Vehicle for tank carriage 9.1.1.2 (14) AT AT AT SGAN AT SGAN AT SGAN L4DH SGAN L4DH RxBN TU14 TE21 TM2 TU14 TE21 TM2 TU19 TA4 TT9 AT AT AT Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 7.2.4 (16) V1 7.3.3 (17) 7.5.11 (18) CV23 8.5 (19) 0 V1 (B/E) 0 V1 (D/E) 0 V1 (E) CARRIAGE PROHIBITED CV23 S20 1.1.3.6 (15) 0 (E) 0 (E) 0 (D/E) 0 (E) 1 (B/E) 2 (D/E) 3 (E) 3 (C/E) V1 5.3.2.3 (20) 482 CV23 423 CV23 423 CV23 CV28 CV23 CV28 CV23 CV28 S20 V1 CV23 S20 V1 CV23 423 V1 CV23 423 V5 CV9 CV11 CV36 V1 V1 462 462 S20 22 CARRIAGE PROHIBITED RxBN TU18 TA4 TT9 FL 2 (B/D) V5 CV9 CV11 CV36 S2 S17 1 (E) 2 (E) 3 (E) CV24 S20 CV1 CV13 CV28 CV13 CV28 L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) V12 L4BH TU15 TE19 AT 2 (E) V12 L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) S10AH L10CH TU15 TE19 AT 1 (C/E) V10 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 SGAH L4BH TU15 TE19 AT 2 (E) V12 3.1.2 (1) (2) 3131 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 3132 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 3133 WATER-REACTIVE SOLID, OXIDIZING, N.O.S. 3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 3134 WATER-REACTIVE SOLID, TOXIC, N.O.S. 3135 WATER-REACTIVE SOLID, SELFHEATING, N.O.S. 3135 WATER-REACTIVE SOLID, SELFHEATING, N.O.S. 3135 WATER-REACTIVE SOLID, SELFHEATING, N.O.S. 3136 TRIFLUOROMETHANE, REFRIGERATED LIQUID 3137 OXIDIZING SOLID, FLAMMABLE, N.O.S. 3138 ETHYLENE, ACETYLENE AND PROPYLENE MIXTURE, REFRIGERATED LIQUID containing at least 71.5% ethylene with not more than 22.5% acetylene and not more than 6% propylene 3139 OXIDIZING LIQUID, N.O.S. CV24 3139 OXIDIZING LIQUID, N.O.S. CV24 3139 OXIDIZING LIQUID, N.O.S. S9 S14 66 S9 S19 60 CV13 CV28 S9 60 CV13 CV28 S9 60 3141 ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 S14 66 3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. S9 S19 60 S9 60 3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. S9 S14 66 S9 S19 60 S9 60 CV1 CV13 CV28 CV13 CV28 VC1 VC2 AP7 223 Name and description CV13 CV28 - 469 - 3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. 3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. 3140 ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. 3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 3143 DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3144 NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. 3144 NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. 3144 NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. 2.2 (3a) 6.1 2.2 (3b) T1 2.1.1.3 (4) I 5.2.2 (5) 6.1 3.3 (6) 43 274 3.4 (7a) 0 3.5.1.2 (7b) E5 4.1.4 (8) P001 6.1 T1 II 6.1 43 274 100 ml E4 P001 IBC02 MP15 6.1 T1 III 6.1 43 274 5L E1 MP19 3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) 8 C3 I 8 0 E0 P001 IBC03 LP01 R001 P001 3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) 8 C3 II 8 1L E2 3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) 8 C3 III 8 5L E1 3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 6.1 T3 I 6.1 43 274 0 E5 3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 6.1 T3 II 6.1 43 274 43 274 500 g E4 3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 8 C10 I 8 274 0 E0 8 C10 II 8 274 1 kg E2 3148 WATER-REACTIVE LIQUID, N.O.S. 4.3 W1 I 4.3 274 0 E0 3148 WATER-REACTIVE LIQUID, N.O.S. 3148 WATER-REACTIVE LIQUID, N.O.S. 4.3 W1 II 4.3 274 500 ml E2 4.3 W1 III 4.3 274 1L E1 3149 HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE with acid(s), water and not more than 5% peroxyacetic acid, STABILIZED 5.1 OC1 II 5.1 +8 196 553 1L E2 3150 DEVICES, SMALL, HYDROCARBON GAS POWERED or HYDROCARBON GAS REFILLS FOR SMALL DEVICES with release device 3151 POLYHALOGENATED BIPHENYLS, LIQUID or POLYHALOGENATED TERPHENYLS, LIQUID 3152 POLYHALOGENATED BIPHENYLS, SOLID or POLYHALOGENATED TERPHENYLS, SOLID 3153 PERFLUORO(METHYL VINYL ETHER) 2 6F 0 E0 P209 MP9 9 M2 II 9 203 305 1L E2 P906 IBC02 MP15 9 M2 II 9 203 305 1 kg E2 P906 IBC08 6.1 8 T3 C10 III III 6.1 8 274 2.1 5 kg 5 kg E1 E1 4.2.5.2 (10) 4.2.5.3 (11) MP8 MP17 T14 TP2 P001 IBC02 MP15 T11 TP2 TP27 P001 IBC03 LP01 R001 P002 IBC07 MP19 T7 TP1 TP28 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 RR8 MP2 T13 RR8 MP15 T7 MP15 T7 TP2 TP7 TP38 TP2 TP7 TP2 TP7 MP15 T7 TP2 TP6 TP24 MP10 T3 TP33 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P402 P402 IBC01 P001 IBC02 R001 P504 IBC02 4.1.4 (9a) 4.1.10 (9b) MP8 MP17 B4 B3 B4 B3 PP10 B5 B4 2 2F 2.1 662 0 E0 P200 MP9 (M) T50 3154 PERFLUORO(ETHYL VINYL ETHER) 2 2F 2.1 662 0 E0 P200 MP9 (M) 3155 PENTACHLOROPHENOL 6.1 T2 6.1 43 500 g E4 P002 IBC08 P200 MP10 T3 MP9 (M) 3156 COMPRESSED GAS, OXIDIZING, N.O.S. 2 1O II 2.2 +5.1 274 655 662 - 470 - 0 E0 B4 TP33 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Tank code Special provisions 4.3 (12) L10CH 4.3.5, 6.8.4 (13) TU14 TU15 TE19 TE21 9.1.1.2 (14) AT 1.1.3.6 (15) 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) L10BH AT 1 (E) L4BN AT 2 (E) L4BN AT 3 (E) V12 Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV1 CV13 CV28 CV13 CV28 8.5 (19) S9 S14 5.3.2.3 (20) 66 S9 S19 60 CV13 CV28 S9 60 S20 88 3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) 80 3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) 80 3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) S9 S14 66 3146 ORGANOTIN COMPOUND, SOLID, N.O.S. S9 S19 60 S9 60 3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 3146 ORGANOTIN COMPOUND, SOLID, N.O.S. S20 88 V12 TU14 TU15 TE19 TE21 AT 1 (C/E) V10 SGAH L4BH SGAH L4BH TU15 TE19 AT V11 TU15 TE19 AT 2 (D/E) 2 (E) VC1 VC2 AP7 S10AN L10BH AT 1 (E) V10 SGAN L4BN AT 2 (E) V11 SGAV L4BN AT 3 (E) CV1 CV13 CV28 CV13 CV28 CV13 CV28 80 VC1 VC2 AP7 80 L10DH TU14 TE21 TM2 AT 0 (B/E) V1 CV23 L4DH TU14 TE21 TM2 TU14 TE21 TM2 AT 0 (D/E) 0 (E) V1 V1 TU3 TC2 TE8 TE11 TT1 AT L4BV(+) AT Name and description Packages S10AH L10CH L4DH Hazard UN No. identification No. Operation 3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 3147 DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. X323 3148 WATER-REACTIVE LIQUID, N.O.S. CV23 323 CV23 323 3148 WATER-REACTIVE LIQUID, N.O.S. 3148 WATER-REACTIVE LIQUID, N.O.S. 2 (E) CV24 58 2 (D) CV9 S2 VC1 VC2 AP9 CV1 CV13 CV28 S19 90 VC1 VC2 AP9 CV1 CV13 CV28 S19 90 CV9 CV10 CV36 CV9 CV10 CV36 CV13 CV28 CV9 CV10 CV36 S2 S20 23 S2 S20 23 3154 PERFLUORO(ETHYL VINYL ETHER) S9 S19 60 3155 PENTACHLOROPHENOL 25 3156 COMPRESSED GAS, OXIDIZING, N.O.S. L4BH TU15 AT 0 (D/E) S4AH L4BH TU15 AT 0 (D/E) PxBN(M) TA4 TT9 FL 2 (B/D) PxBN(M) TA4 TT9 FL 2 (B/D) SGAH TU15 TE19 AT CxBN(M) TA4 TT9 AT 2 (D/E) 3 (E) V11 V11 - 471 - S20 3.1.2 (1) (2) 3144 NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. 3144 NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. 3144 NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, N.O.S. 3149 HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE with acid(s), water and not more than 5% peroxyacetic acid, STABILIZED 3150 DEVICES, SMALL, HYDROCARBON GAS POWERED or HYDROCARBON GAS REFILLS FOR SMALL DEVICES with release device 3151 POLYHALOGENATED BIPHENYLS, LIQUID or POLYHALOGENATED TERPHENYLS, LIQUID 3152 POLYHALOGENATED BIPHENYLS, SOLID or POLYHALOGENATED TERPHENYLS, SOLID 3153 PERFLUORO(METHYL VINYL ETHER) UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 2O 3158 GAS, REFRIGERATED LIQUID, N.O.S. 2 3159 1,1,1,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 134a) 3160 LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. 5.2.2 (5) 2.2 +5.1 3.3 (6) 274 662 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P200 4.1.10 (9b) MP9 4.2.5.2 (10) (M) 4.2.5.3 (11) 3A 2.2 274 593 120 ml E1 P203 MP9 T75 TP5 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 2 2TF 2.3 +2.1 274 0 E0 P200 MP9 (M) 3161 LIQUEFIED GAS, FLAMMABLE, N.O.S. 2 2F 2.1 274 662 0 E0 P200 MP9 (M) T50 3162 LIQUEFIED GAS, TOXIC, N.O.S. 2 2T 2.3 274 0 E0 P200 MP9 (M) 3163 LIQUEFIED GAS, N.O.S. 2 2A 2.2 274 662 120 ml E1 P200 MP9 (M) T50 3164 ARTICLES, PRESSURIZED, PNEUMATIC or HYDRAULIC (containing non-flammable gas) 3165 AIRCRAFT HYDRAULIC POWER UNIT FUEL TANK (containing a mixture of anhydrous hydrazine and methylhydrazine) (M86 fuel) 2 6A 2.2 283 371 594 120 ml E0 P003 MP9 3 FTC 0 E0 P301 MP7 3166 Engine, internal combustion or vehicle, flammable gas powered or vehicle, flammable liquid powered or engine, fuel cell, flammable gas powered or engine, fuel cell, flammable liquid powered or vehicle, fuel cell, flammable gas powered or vehicle, fuel cell, flammable liquid powered 9 M11 3167 GAS SAMPLE, NONPRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid 3168 GAS SAMPLE, NONPRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid 3169 GAS SAMPLE, NONPRESSURIZED, TOXIC, N.O.S., not refrigerated liquid 3170 ALUMINIUM SMELTING BYPRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS 3170 ALUMINIUM SMELTING BYPRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS 3171 Battery-powered vehicle or Batterypowered equipment 3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 2 7F 2.1 0 E0 P201 MP9 2 7TF 2.3 +2.1 0 E0 P201 MP9 2 7T 2.3 0 E0 P201 MP9 4.3 W2 II 4.3 244 500 g E2 P410 IBC07 MP14 4.3 W2 III 4.3 244 1 kg E1 9 M11 P002 MP14 IBC08 B4 R001 NOT SUBJECT TO ADR, see also special provision 240 in Chapter 3.3. 6.1 T1 I 6.1 210 274 0 E5 P001 MP8 MP17 3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 6.1 T1 II 6.1 210 274 100 ml E4 P001 IBC02 MP15 3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 6.1 T1 III 6.1 210 274 5L E1 MP19 3174 TITANIUM DISULPHIDE 4.2 S4 III 4.2 0 E1 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P002 IBC06 R001 3175 SOLIDS or mixtures of solids (such as preparations and wastes) CONTAINING FLAMMABLE LIQUID, N.O.S. having a flash-point up to 60 °C 3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3157 LIQUEFIED GAS, OXIDIZING, N.O.S. Packaging I 3 +6.1 +8 4.1.4 (9a) NOT SUBJECT TO ADR 4.1 F1 II 4.1 216 274 601 1 kg E2 4.1 F2 II 4.1 274 0 E0 - 472 - T3 BK1 BK2 T1 BK1 BK2 TP33 MP14 T1 TP33 MP11 T3 BK1 BK2 TP33 T3 TP3 TP26 TP33 B3 PP9 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) PxBN(M) 4.3.5, 6.8.4 (13) TA4 TT9 9.1.1.2 (14) AT RxBN TU19 TA4 TT9 TA4 TT9 PxBN(M) PxBH(M) PxBN(M) PxBH(M) PxBN(M) Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 3 (C/E) 7.2.4 (16) 7.3.3 (17) AT 3 (C/E) V5 AT 3 (C/E) TU6 TA4 TT9 TA4 TT9 FL 1 (B/D) FL 2 (B/D) TU6 TA4 TT9 TA4 TT9 AT 1 (C/D) AT 3 (C/E) 7.5.11 (18) CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 3 (E) 1 (E) CV13 CV28 Hazard UN No. identification No. Operation 8.5 (19) 5.3.2.3 (20) 25 3.1.2 (1) (2) 3157 LIQUEFIED GAS, OXIDIZING, N.O.S. S20 22 3158 GAS, REFRIGERATED LIQUID, N.O.S. 20 3159 1,1,1,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 134a) 3160 LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. S2 S14 263 S2 S20 23 3161 LIQUEFIED GAS, FLAMMABLE, N.O.S. S14 26 3162 LIQUEFIED GAS, TOXIC, N.O.S. 20 3163 LIQUEFIED GAS, N.O.S. 3164 ARTICLES, PRESSURIZED, PNEUMATIC or HYDRAULIC (containing non-flammable gas) 3165 AIRCRAFT HYDRAULIC POWER UNIT FUEL TANK (containing a mixture of anhydrous hydrazine and methylhydrazine) (M86 fuel) S2 S19 NOT SUBJECT TO ADR 3166 Engine, internal combustion or vehicle, flammable gas powered or vehicle, flammable liquid powered or engine, fuel cell, flammable gas powered or engine, fuel cell, flammable liquid powered or vehicle, fuel cell, flammable gas powered or vehicle, fuel cell, flammable liquid powered 2 (D) CV9 S2 1 (D) CV9 S2 1 (D) CV9 SGAN AT 2 (D/E) V1 VC1 VC2 AP2 CV23 CV37 423 SGAN AT 3 (E) V1 VC1 VC2 AP2 CV23 CV37 423 NOT SUBJECT TO ADR, see also special provision 240 in Chapter 3.3. L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) V12 AT 3 (E) V1 AT 2 (E) V11 AT 2 (E) SGAN LGBV TU27 TE4 TE6 Name and description 3167 GAS SAMPLE, NONPRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid 3168 GAS SAMPLE, NONPRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid 3169 GAS SAMPLE, NONPRESSURIZED, TOXIC, N.O.S., not refrigerated liquid 3170 ALUMINIUM SMELTING BYPRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS 3170 ALUMINIUM SMELTING BYPRODUCTS or ALUMINIUM REMELTING BY-PRODUCTS 3171 Battery-powered vehicle or Batterypowered equipment 3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. CV1 CV13 CV28 CV13 CV28 S9 S14 66 S9 S19 60 3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. CV13 CV28 S9 60 3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 40 3174 TITANIUM DISULPHIDE 40 3175 SOLIDS or mixtures of solids (such as preparations and wastes) CONTAINING FLAMMABLE LIQUID, N.O.S. having a flash-point up to 60 °C 3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. VC1 VC2 AP2 44 - 473 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 3178 FLAMMABLE SOLID, INORGANIC, N.O.S. 3178 FLAMMABLE SOLID, INORGANIC, N.O.S. 2.2 (3a) 4.1 2.2 (3b) F2 2.1.1.3 (4) III 5.2.2 (5) 4.1 3.3 (6) 274 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) 4.1 F3 II 4.1 274 1 kg E2 3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 4.1 FT2 II 4.1 FT2 III 3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. 4.1 FC2 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC06 R001 P002 IBC06 3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. 4.1 3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. 3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. 4.1 3182 METAL HYDRIDES, FLAMMABLE, N.O.S. 3182 METAL HYDRIDES, FLAMMABLE, N.O.S. 4.1 F3 II 4.1 4.1 F3 III 4.1 3183 SELF-HEATING LIQUID, ORGANIC, N.O.S. 3183 SELF-HEATING LIQUID, ORGANIC, N.O.S. 4.2 S1 II 4.2 4.2 S1 III 3184 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 3184 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 4.2 ST1 II 4.2 ST1 III 3185 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. 3185 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. 4.2 SC1 II 4.2 SC1 III 3186 SELF-HEATING LIQUID, INORGANIC, N.O.S. 3186 SELF-HEATING LIQUID, INORGANIC, N.O.S. 4.2 S3 4.2 3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 4.1 4.1 F3 III 4.1 274 5 kg E1 4.1 +6.1 4.1 +6.1 274 1 kg E2 274 5 kg E1 II 4.1 +8 274 1 kg E2 FC2 III 4.1 +8 274 5 kg E1 F3 II 4.1 274 1 kg E2 F3 III 4.1 274 274 554 274 554 5 kg E1 1 kg E2 5 kg E1 274 0 E2 4.2 274 0 E1 4.2 +6.1 4.2 +6.1 274 0 E2 274 0 E1 4.2 +8 4.2 +8 274 0 E2 274 0 E1 II 4.2 274 0 E2 S3 III 4.2 274 0 E1 4.2 ST3 II 274 0 E2 4.2 ST3 III 4.2 +6.1 4.2 +6.1 274 0 E1 3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. 4.2 SC3 II 4.2 +8 274 0 E2 3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. 4.2 SC3 III 4.2 +8 274 0 E1 3189 METAL POWDER, SELFHEATING, N.O.S. 3189 METAL POWDER, SELFHEATING, N.O.S. 4.2 S4 II 4.2 0 E2 4.2 S4 III 4.2 274 555 274 555 0 E1 3190 SELF-HEATING SOLID, INORGANIC, N.O.S. 3190 SELF-HEATING SOLID, INORGANIC, N.O.S. 4.2 S4 II 4.2 274 0 E2 4.2 S4 III 4.2 274 0 E1 3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. 4.2 ST4 II 4.2 +6.1 274 - 474 - 0 Portable tanks and bulk containers E2 P002 IBC06 R001 P002 IBC08 P002 IBC08 LP02 R001 P410 IBC04 P002 IBC04 R001 P001 IBC02 P001 IBC02 R001 P402 IBC02 P001 IBC02 R001 P402 IBC02 P001 IBC02 R001 P001 IBC02 P001 IBC02 R001 P402 IBC02 P001 IBC02 R001 P402 IBC02 P001 IBC02 R001 P410 IBC06 P002 IBC08 LP02 R001 P410 IBC06 P002 IBC08 LP02 R001 P410 IBC05 4.1.4 (9a) 4.1.10 (9b) 4.2.5.2 (10) T1 4.2.5.3 (11) TP3 TP26 MP11 T3 TP33 MP11 T1 TP33 MP10 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 MP10 T1 TP33 MP11 T3 TP33 MP11 T1 TP33 MP11 T3 TP33 MP11 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP14 T3 TP33 B4 B3 B4 B3 PP40 MP15 MP15 MP15 MP15 MP15 MP15 MP15 MP15 MP15 MP15 MP15 MP15 B3 B3 ADR tank Tank code Special provisions 4.3 (12) LGBV 4.3.5, 6.8.4 (13) TU27 TE4 TE6 Vehicle for tank carriage 9.1.1.2 (14) AT Transport category (Tunnel restriction code) Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 3 (E) 2 (E) 3 (E) 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) 2 (E) 3 (E) V11 V11 SGAN AT SGAV AT SGAN AT SGAN AT SGAN AT 2 (E) SGAN AT 3 (E) SGAN AT 2 (E) SGAV AT 3 (E) SGAN AT SGAV AT 2 (E) 3 (E) L4DH TU14 TE21 AT L4DH TU14 TE21 AT L4DH TU14 TE21 AT L4DH TU14 TE21 AT L4DH TU14 TE21 AT L4DH TU14 TE21 AT L4DH TU14 TE21 AT L4DH TU14 TE21 AT L4DH TU14 TE21 AT L4DH TU14 TE21 AT L4DH TU14 TE21 L4DH TU14 TE21 Special provisions for carriage V11 Hazard UN No. identification No. Operation 8.5 (19) 5.3.2.3 (20) 44 40 VC1 VC2 40 CV28 46 CV28 46 V11 VC1 VC2 3.1.2 (1) (2) 3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 3178 FLAMMABLE SOLID, INORGANIC, N.O.S. 3178 FLAMMABLE SOLID, INORGANIC, N.O.S. 3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 48 3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. 48 3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. 40 3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. 3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. 40 40 VC1 VC2 Name and description 40 3182 METAL HYDRIDES, FLAMMABLE, N.O.S. 3182 METAL HYDRIDES, FLAMMABLE, N.O.S. 2 (D/E) 3 (E) V1 30 V1 30 2 (D/E) 3 (E) V1 CV28 36 V1 CV28 36 2 (D/E) 3 (E) V1 38 V1 38 2 (D/E) 3 (E) V1 30 V1 30 2 (D/E) 3 (E) V1 CV28 36 V1 CV28 36 AT 2 (D/E) V1 38 3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. AT 3 (E) V1 38 3188 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. SGAN AT V1 40 SGAN AT 2 (D/E) 3 (E) 3189 METAL POWDER, SELFHEATING, N.O.S. 3189 METAL POWDER, SELFHEATING, N.O.S. SGAN AT V1 SGAN AT 2 (D/E) 3 (E) SGAN AT 2 (D/E) V1 V1 V1 40 VC1 VC2 AP1 40 VC1 VC2 AP1 40 CV28 - 475 - 46 3183 SELF-HEATING LIQUID, ORGANIC, N.O.S. 3183 SELF-HEATING LIQUID, ORGANIC, N.O.S. 3184 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 3184 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 3185 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. 3185 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. 3186 SELF-HEATING LIQUID, INORGANIC, N.O.S. 3186 SELF-HEATING LIQUID, INORGANIC, N.O.S. 3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 3187 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 3190 SELF-HEATING SOLID, INORGANIC, N.O.S. 3190 SELF-HEATING SOLID, INORGANIC, N.O.S. 3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 4.2 3192 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. 4.2 SC4 3192 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. 4.2 SC4 3194 PYROPHORIC LIQUID, INORGANIC, N.O.S. 3200 PYROPHORIC SOLID, INORGANIC, N.O.S. 3205 ALKALINE EARTH METAL ALCOHOLATES, N.O.S. 3205 ALKALINE EARTH METAL ALCOHOLATES, N.O.S. 4.2 S3 4.2 3206 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. 3206 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. 3208 METALLIC SUBSTANCE, WATERREACTIVE, N.O.S. 3208 METALLIC SUBSTANCE, WATERREACTIVE, N.O.S. 3208 METALLIC SUBSTANCE, WATERREACTIVE, N.O.S. 4.2 SC4 II 4.2 SC4 III 3209 METALLIC SUBSTANCE, WATERREACTIVE, SELF-HEATING, N.O.S. 3209 METALLIC SUBSTANCE, WATERREACTIVE, SELF-HEATING, N.O.S. 3209 METALLIC SUBSTANCE, WATERREACTIVE, SELF-HEATING, N.O.S. 3210 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3210 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 2.2 (3b) ST4 2.1.1.3 (4) III 5.2.2 (5) 4.2 +6.1 3.3 (6) 274 II 4.2 +8 274 0 E2 III 4.2 +8 274 0 E1 I 4.2 274 0 E0 P002 IBC08 R001 P400 S4 I 4.2 274 0 E0 P404 4.2 S4 II 4.2 0 E2 4.2 S4 III 4.2 183 274 183 274 0 E1 4.2 +8 182 274 0 E2 P410 IBC06 P002 IBC08 LP02 R001 P410 IBC05 4.2 +8 182 274 0 E1 274 557 274 557 274 557 0 E0 500 g E0 1 kg E1 4.3 W2 I 4.3 4.3 W2 II 4.3 4.3 W2 III 4.3 3.4 (7a) 0 3.5.1.2 (7b) E1 4.1.4 (8) P002 IBC08 R001 P410 IBC05 P002 IBC08 R001 P403 IBC99 P410 IBC07 P410 IBC08 R001 P403 4.3 WS I 4.3 +4.2 274 558 0 E0 4.3 WS II 4.3 +4.2 274 558 0 E2 P410 IBC05 4.3 WS III 4.3 +4.2 274 558 0 E1 274 351 274 351 1L E2 5L E1 P410 IBC08 R001 P504 IBC02 P504 IBC02 R001 P504 IBC02 P504 IBC02 R001 P002 IBC08 P504 IBC02 P504 IBC02 R001 P504 IBC02 5.1 O1 II 5.1 5.1 O1 III 5.1 3211 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3211 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 O1 II 5.1 1L E2 5.1 O1 III 5.1 5L E1 3212 HYPOCHLORITES, INORGANIC, N.O.S. 3213 BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3213 BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 O2 II 5.1 274 349 274 350 274 350 1 kg E2 274 353 5.1 O1 II 5.1 5.1 O1 III 5.1 3214 PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 O1 II 5.1 3215 PERSULPHATES, INORGANIC, N.O.S. 5.1 O2 III 5.1 3216 PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 O1 III 5.1 3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 O1 II 5.1 5.1 O1 III 5.1 3219 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3219 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 O1 II 5.1 5.1 O1 III 5.1 1L E2 5L E1 1L E2 5 kg E1 5L E1 270 511 270 511 1L E2 5L E1 103 274 103 274 1L E2 5L E1 - 476 - Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. Packaging P002 IBC08 LP02 R001 P504 IBC02 R001 P504 IBC02 P504 IBC02 R001 P504 IBC01 P504 IBC02 R001 4.1.4 (9a) 4.1.10 (9b) MP14 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP14 T3 TP33 MP14 T1 TP33 MP13 T21 MP14 T3 TP7 TP33 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 MP2 T4 TP1 MP2 T4 TP1 MP2 T4 TP1 MP2 T4 TP1 MP10 T3 TP33 MP2 T4 TP1 MP15 T4 TP1 MP2 T4 TP1 MP10 T1 TP33 MP15 T4 TP1 TP29 MP15 T4 TP1 MP15 T4 TP1 MP15 T4 TP1 MP15 T4 TP1 B3 B3 MP2 B3 B3 MP2 B4 MP2 B4 B4 B3 ADR tank Tank code Special provisions 4.3 (12) SGAN 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.3.3 (17) 7.5.11 (18) CV28 9.1.1.2 (14) AT 1.1.3.6 (15) 3 (E) 7.2.4 (16) V1 SGAN AT 2 (D/E) SGAN AT AT L21DH TU14 TC1 TE21 TM1 AT SGAN AT SGAN AT SGAN AT SGAN AT SGAN AT SGAN AT Hazard UN No. identification No. Operation 8.5 (19) Name and description 5.3.2.3 (20) 46 3.1.2 (1) (2) 3191 SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. V1 48 3192 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. 3 (E) V1 48 3192 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. 0 (B/E) 0 (B/E) 2 (D/E) 3 (E) V1 S20 333 V1 S20 43 3194 PYROPHORIC LIQUID, INORGANIC, N.O.S. 3200 PYROPHORIC SOLID, INORGANIC, N.O.S. 3205 ALKALINE EARTH METAL ALCOHOLATES, N.O.S. 3205 ALKALINE EARTH METAL ALCOHOLATES, N.O.S. V1 40 V1 40 2 (D/E) V1 48 3 (E) V1 48 1 (E) 2 (D/E) 3 (E) V1 CV23 V1 CV23 423 CV23 423 V1 VC1 VC2 AP3 AP4 AP5 S20 1 (E) V1 CV23 S20 CV23 423 CV23 423 3206 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. 3206 ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S. 3208 METALLIC SUBSTANCE, WATERREACTIVE, N.O.S. 3208 METALLIC SUBSTANCE, WATERREACTIVE, N.O.S. 3208 METALLIC SUBSTANCE, WATERREACTIVE, N.O.S. 3209 METALLIC SUBSTANCE, WATERREACTIVE, SELF-HEATING, N.O.S. 3209 METALLIC SUBSTANCE, WATERREACTIVE, SELF-HEATING, N.O.S. 3209 METALLIC SUBSTANCE, WATERREACTIVE, SELF-HEATING, N.O.S. 3210 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3210 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. SGAN AT 2 (D/E) V1 SGAN AT 3 (E) V1 2 (E) 3 (E) CV24 50 CV24 50 2 (E) 3 (E) CV24 50 CV24 50 CV24 50 CV24 50 CV24 50 CV24 50 3214 PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. CV24 50 3215 PERSULPHATES, INORGANIC, N.O.S. VC1 VC2 AP3 AP4 AP5 L4BN TU3 AT LGBV TU3 AT L4BN TU3 AT LGBV TU3 AT SGAN TU3 AT L4BN TU3 AT LGBV TU3 AT L4BN TU3 AT 2 (E) SGAV TU3 AT 3 (E) LGBV TU3 AT 3 (E) CV24 50 3216 PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. L4BN TU3 AT CV24 50 LGBV TU3 AT 2 (E) 3 (E) CV24 50 3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3218 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. L4BN TU3 AT CV24 50 LGBV TU3 AT 2 (E) 3 (E) CV24 50 2 (E) 2 (E) 3 (E) V11 VC1 VC2 AP6 AP7 - 477 - 3211 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3211 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3212 HYPOCHLORITES, INORGANIC, N.O.S. 3213 BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3213 BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3219 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3219 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 2A 3221 SELF-REACTIVE LIQUID TYPE B 4.1 3222 SELF-REACTIVE SOLID TYPE B 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3220 PENTAFLUOROETHANE (REFRIGERANT GAS R 125) Packaging 5.2.2 (5) 2.2 3.3 (6) 662 3.4 (7a) 120 ml 3.5.1.2 (7b) E1 4.1.4 (8) P200 4.1.4 (9a) 4.1.10 (9b) MP9 SR1 4.1 +1 25 ml E0 P520 PP21 MP2 4.1 SR1 4.1 +1 100 g E0 P520 PP21 MP2 3223 SELF-REACTIVE LIQUID TYPE C 4.1 SR1 4.1 181 194 274 181 194 274 194 274 25 ml E0 P520 PP21 MP2 3224 SELF-REACTIVE SOLID TYPE C 4.1 SR1 4.1 194 274 100 g E0 P520 PP21 MP2 3225 SELF-REACTIVE LIQUID TYPE D 3226 SELF-REACTIVE SOLID TYPE D 3227 SELF-REACTIVE LIQUID TYPE E 3228 SELF-REACTIVE SOLID TYPE E 3229 SELF-REACTIVE LIQUID TYPE F 3230 SELF-REACTIVE SOLID TYPE F 3231 SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED 4.1 SR1 4.1 125 ml E0 P520 MP2 4.1 SR1 4.1 500 g E0 P520 MP2 4.1 SR1 4.1 125 ml E0 P520 MP2 4.1 SR1 4.1 500 g E0 P520 MP2 4.1 SR1 4.1 125 ml E0 T23 SR1 4.1 500 g E0 MP2 T23 4.1 SR2 4.1 +1 0 E0 P520 IBC99 P520 IBC99 P520 MP2 4.1 194 274 194 274 194 274 194 274 194 274 194 274 181 194 274 PP21 MP2 3232 SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED 4.1 SR2 4.1 +1 181 194 274 0 E0 P520 PP21 MP2 3233 SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED 4.1 SR2 4.1 194 274 0 E0 P520 PP21 MP2 3234 SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED 4.1 SR2 4.1 194 274 0 E0 P520 PP21 MP2 3235 SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED 3236 SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED 3237 SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED 3238 SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED 3239 SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED 3240 SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED 3241 2-BROMO-2-NITROPROPANE-1,3DIOL 3242 AZODICARBONAMIDE 4.1 SR2 4.1 194 274 0 E0 P520 MP2 4.1 SR2 4.1 194 274 0 E0 P520 MP2 4.1 SR2 4.1 194 274 0 E0 P520 MP2 4.1 SR2 4.1 194 274 0 E0 P520 MP2 4.1 SR2 4.1 194 274 0 E0 P520 MP2 T23 4.1 SR2 4.1 194 274 0 E0 P520 MP2 T23 4.1 SR1 III 4.1 638 5 kg E1 PP22 B3 4.1 SR1 II 4.1 1 kg E0 3243 SOLIDS CONTAINING TOXIC LIQUID, N.O.S. 6.1 T9 II 6.1 500 g E4 P002 IBC02 3244 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. 8 C10 II 8 215 638 217 274 601 218 274 P520 IBC08 P409 1 kg E2 P002 IBC05 3245 GENETICALLY MODIFIED MICROORGANISMS or GENETICALLY MODIFIED ORGANISMS 9 M8 0 E0 P904 IBC08 9 219 637 - 478 - 4.2.5.2 (10) (M) T50 4.2.5.3 (11) MP2 MP2 T3 TP33 PP9 MP10 TP33 PP9 MP10 T3 BK1 BK2 T3 BK1 BK2 MP6 TP33 ADR tank Tank code Special provisions 4.3 (12) PxBN(M) 4.3.5, 6.8.4 (13) TA4 TT9 Vehicle for tank carriage Bulk Loading, unloading and handling 1.1.3.6 (15) 3 (C/E) 7.2.4 (16) 7.3.3 (17) 1 (B) V1 1 (B) V1 1 (D) V1 1 (D) V1 2 (D) 2 (D) 2 (D) 2 (D) 2 (D) 2 (D) 1 (B) V1 1 (B) V8 1 (D) V8 1 (D) V8 1 (D) V8 1 (D) V8 1 (D) V8 1 (D) V8 AT 1 (D) V8 AT 1 (D) V8 7.5.11 (18) CV9 CV10 CV36 CV15 CV20 CV22 CV15 CV20 CV22 CV15 CV20 CV22 CV15 CV20 CV22 CV15 CV22 CV15 CV22 CV15 CV22 CV15 CV22 CV15 CV22 CV15 CV22 CV15 CV20 CV21 CV22 CV15 CV20 CV21 CV22 CV15 CV20 CV21 CV22 CV15 CV20 CV21 CV22 CV15 CV21 CV22 CV15 CV21 CV22 CV15 CV21 CV22 CV15 CV21 CV22 CV15 CV21 CV22 CV15 CV21 CV22 CV14 9.1.1.2 (14) AT AT AT SGAV TU15 TE19 Special provisions for carriage Packages AT SGAH Transport category (Tunnel restriction code) AT AT V1 V1 V1 V1 V1 V8 3 (D) 2 (D) 2 (D/E) VC1 VC2 AP7 2 (E) VC1 VC2 AP7 2 (E) Hazard UN No. identification No. Operation 8.5 (19) 5.3.2.3 (20) 20 Name and description 3.1.2 (1) (2) 3220 PENTAFLUOROETHANE (REFRIGERANT GAS R 125) S9 S17 3221 SELF-REACTIVE LIQUID TYPE B S9 S17 3222 SELF-REACTIVE SOLID TYPE B S8 S18 3223 SELF-REACTIVE LIQUID TYPE C S8 S18 3224 SELF-REACTIVE SOLID TYPE C S19 3225 SELF-REACTIVE LIQUID TYPE D 3226 SELF-REACTIVE SOLID TYPE D 3227 SELF-REACTIVE LIQUID TYPE E 3228 SELF-REACTIVE SOLID TYPE E 3229 SELF-REACTIVE LIQUID TYPE F 3230 SELF-REACTIVE SOLID TYPE F 3231 SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED S19 40 40 S4 S9 S16 S4 S9 S16 3232 SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED S4 S8 S17 3233 SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED S4 S8 S17 3234 SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED S4 S18 3235 SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED 3236 SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED 3237 SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED 3238 SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED 3239 SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED 3240 SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED 3241 2-BROMO-2-NITROPROPANE-1,3DIOL 3242 AZODICARBONAMIDE S4 S18 S4 S19 S4 S19 S4 40 S4 40 S24 CV14 S24 40 CV13 CV28 S9 S19 60 3243 SOLIDS CONTAINING TOXIC LIQUID, N.O.S. 80 3244 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. CV1 CV13 CV26 CV27 CV28 - 479 - S17 3245 GENETICALLY MODIFIED MICROORGANISMS or GENETICALLY MODIFIED ORGANISMS UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3245 GENETICALLY MODIFIED MICROORGANISMS or GENETICALLY MODIFIED ORGANISMS, in refrigerated liquid nitrogen 3246 METHANESULPHONYL CHLORIDE 2.2 (3a) 9 2.2 (3b) M8 2.1.1.3 (4) 5.2.2 (5) 9 +2.2 3.3 (6) 219 637 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P904 IBC08 6.1 TC1 I 6.1 +8 354 0 E0 P602 3247 SODIUM PEROXOBORATE, ANHYDROUS 3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 5.1 O2 II 5.1 1 kg E2 3 FT1 II 3 +6.1 P002 IBC08 P001 3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3 FT1 III 3 +6.1 3249 MEDICINE, SOLID, TOXIC, N.O.S. 6.1 T2 II 6.1 3249 MEDICINE, SOLID, TOXIC, N.O.S. 6.1 T2 III 6.1 3250 CHLOROACETIC ACID, MOLTEN 6.1 TC1 II 3251 ISOSORBIDE-5-MONONITRATE 4.1 SR1 III 6.1 +8 4.1 3252 DIFLUOROMETHANE (REFRIGERANT GAS R 32) 2 2F 3253 DISODIUM TRIOXOSILICATE 8 C6 2.1 III 220 221 601 220 221 601 221 601 221 601 226 638 662 8 Portable tanks and bulk containers 4.1.4 (9a) 4.1.10 (9b) MP6 4.2.5.2 (10) 4.2.5.3 (11) MP8 MP17 T20 TP2 TP37 MP2 T3 TP33 B4 1L E2 5L E1 P001 R001 MP19 500 g E4 P002 MP10 T3 TP33 5 kg E1 P002 LP02 R001 MP10 T1 TP33 0 E0 T7 TP3 TP28 5 kg E0 P409 MP2 0 E0 P200 MP9 (M) T50 5 kg E1 P002 IBC08 LP02 R001 P400 MP10 T1 TP33 MP2 T21 TP2 TP7 MP2 T3 TP3 TP29 MP2 T3 TP3 TP29 4.2 S1 I 4.2 3255 tert-BUTYL HYPOCHLORITE 3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flashpoint above 60° C, at or above its flashpoint and below 100° C 4.2 3 SC1 F2 III 3 274 560 0 3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flashpoint above 60° C, at or above its flashpoint and at or above 100° C 3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash-point (including molten metals, molten salts, etc.), filled at a temperature higher than 190 °C 3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash-point (including molten metals, molten salts, etc.), filled at or below 190 °C 3 F2 III 3 274 560 0 E0 P099 IBC99 9 M9 III 9 274 643 0 E0 P099 IBC99 T3 TP3 TP29 9 M9 III 9 274 643 0 E0 P099 IBC99 T3 TP3 TP29 3258 ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 °C 3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. 3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. 3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. 9 M10 III 9 274 643 0 E0 P099 IBC99 8 C8 I 8 274 0 E0 P002 IBC07 MP18 T6 TP33 8 C8 II 8 274 1 kg E2 P002 IBC08 MP10 T3 TP33 MP10 T1 TP33 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 8 C2 I 8 274 0 E0 MP18 T6 TP33 8 C2 II 8 274 1 kg E2 MP10 T3 TP33 MP10 T1 TP33 8 C8 C2 III III 8 8 274 274 - 480 - 5 kg 5 kg E0 B3 3254 TRIBUTYLPHOSPHANE 8 0 MP19 CARRIAGE PROHIBITED E0 P099 IBC99 E1 E1 P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 B4 B3 B4 B3 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) 9.1.1.2 (14) 1.1.3.6 (15) 2 (E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/D) SGAN TU3 AT L4BH TU15 FL 2 (E) 2 (D/E) L4BH TU15 FL SGAH L4BH SGAH L4BH TU15 TE19 AT TU15 TE19 AT L4BH TU15 TC4 TE19 AT PxBN(M) TA4 TT9 SGAV FL Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV1 CV13 CV26 CV27 CV28 CV1 CV13 CV28 CV24 V11 Hazard UN No. identification No. Operation 8.5 (19) S17 5.3.2.3 (20) S9 S14 668 50 Name and description 3.1.2 (1) (2) 3245 GENETICALLY MODIFIED MICROORGANISMS or GENETICALLY MODIFIED ORGANISMS, in refrigerated liquid nitrogen 3246 METHANESULPHONYL CHLORIDE 3247 SODIUM PEROXOBORATE, ANHYDROUS 3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. CV13 CV28 S2 S19 336 3 (D/E) CV13 CV28 S2 36 3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 2 (D/E) 2 (E) CV13 CV28 CV13 CV28 S9 S19 60 3249 MEDICINE, SOLID, TOXIC, N.O.S. S9 60 3249 MEDICINE, SOLID, TOXIC, N.O.S. CV13 S9 S19 68 3250 CHLOROACETIC ACID, MOLTEN CV14 S24 CV9 CV10 CV36 S2 S20 VC1 VC2 AP7 0 (D/E) 3 (D) 2 (B/D) VC1 VC2 AP7 3251 ISOSORBIDE-5-MONONITRATE 23 3252 DIFLUOROMETHANE (REFRIGERANT GAS R 32) 80 3253 DISODIUM TRIOXOSILICATE 3254 TRIBUTYLPHOSPHANE AT 3 (E) AT 0 V1 (B/E) CARRIAGE PROHIBITED 3 (D/E) S20 333 S2 30 S2 30 LGAV TU35 TE24 FL LGAV TU35 TE24 FL 3 (D/E) LGAV TU35 TC7 TE6 TE14 TE18 TE24 AT 3 (D) VC3 99 LGAV TU35 TC7 TE6 TE14 TE24 AT 3 (D) VC3 99 3 (D) VC3 99 S10AN L10BH AT 1 (E) V10 SGAN L4BN AT 2 (E) V11 SGAV L4BN AT 3 (E) S10AN AT SGAN AT SGAV AT 1 (E) 2 (E) 3 (E) S20 88 80 VC1 VC2 AP7 80 V10 S20 V11 88 80 VC1 VC2 AP7 80 - 481 - 3255 tert-BUTYL HYPOCHLORITE 3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flashpoint above 60° C, at or above its flashpoint and below 100° C 3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flashpoint above 60° C, at or above its flashpoint and at or above 100° C 3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash-point (including molten metals, molten salts, etc.), filled at a temperature higher than 190 °C 3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash-point (including molten metals, molten salts, etc.), filled at or below 190 °C 3258 ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 °C 3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. 3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. 3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (1) (2) 3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 2.2 (3a) 8 2.2 (3b) C4 2.1.1.3 (4) I 5.2.2 (5) 8 3.3 (6) 274 3.4 (7a) 0 3.5.1.2 (7b) E0 8 C4 II 8 274 1 kg E2 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 8 C6 I 8 274 0 E0 8 C6 II 8 274 1 kg E2 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 8 C8 I 8 274 0 E0 8 C8 II 8 274 1 kg E2 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 8 C1 I 8 274 0 E0 8 C1 II 8 274 1L E2 8 C1 III 8 274 5L E1 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 8 C3 I 8 274 0 E0 8 C3 II 8 274 1L E2 8 C3 III 8 274 5L E1 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 8 C5 I 8 274 0 E0 8 C5 II 8 274 1L E2 8 C5 III 8 274 5L E1 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 8 C7 I 8 274 0 E0 8 C7 II 8 274 1L E2 8 C7 III 8 274 5L E1 3268 SAFETY DEVICES, electrically initiated 3269 POLYESTER RESIN KIT 9 M5 9 0 E0 3 F3 II 3 5L E0 3269 POLYESTER RESIN KIT 3 F3 III 3 5L E0 3270 NITROCELLULOSE MEMBRANE FILTERS, with not more than 12.6% nitrogen, by dry mass 4.1 F1 II 4.1 280 289 236 340 236 340 237 286 1 kg E2 3271 ETHERS, N.O.S. 3 F1 II 3 274 1L E2 3271 ETHERS, N.O.S. 3 F1 III 3 274 5L E1 3272 ESTERS, N.O.S. 3 F1 II 3 274 601 1L E2 8 8 C4 C6 C8 III III III 8 8 8 274 274 274 - 482 - 5 kg 5 kg 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 8 Packaging E1 E1 E1 4.1.4 (8) P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P001 P001 IBC02 P001 IBC03 LP01 R001 P001 P001 IBC02 P001 IBC03 LP01 R001 P001 P001 IBC02 P001 IBC03 LP01 R001 P001 P001 IBC02 P001 IBC03 LP01 R001 P902 LP902 P302 R001 P302 R001 P411 P001 IBC02 R001 P001 IBC03 LP01 R001 P001 IBC02 R001 4.1.4 (9a) 4.1.10 (9b) MP18 4.2.5.2 (10) T6 4.2.5.3 (11) TP33 MP10 T3 TP33 MP10 T1 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP8 MP17 MP15 T14 T11 MP19 T7 TP2 TP27 TP2 TP27 TP1 TP28 MP8 MP17 MP15 T14 T11 MP19 T7 MP8 MP17 MP15 T14 T11 MP19 T7 MP8 MP17 MP15 T14 T11 MP19 T7 B4 B3 B4 B3 B4 B3 TP2 TP27 TP2 TP27 TP1 TP28 TP2 TP27 TP2 TP27 TP1 TP28 TP2 TP27 TP2 TP27 TP1 TP28 MP11 MP19 T7 MP19 T4 MP19 T7 TP1 TP8 TP28 TP1 TP29 TP1 TP8 TP28 ADR tank Tank code Special provisions 4.3 (12) S10AN L10BH SGAN L4BN SGAV L4BN 4.3.5, 6.8.4 (13) S10AN L10BH SGAN L4BN SGAV L4BN S10AN L10BH SGAN L4BN SGAV L4BN Vehicle for tank carriage 9.1.1.2 (14) AT AT AT AT AT AT AT AT AT L10BH AT L4BN AT L4BN AT L10BH AT L4BN AT L4BN AT L10BH AT L4BN AT L4BN AT L10BH AT L4BN AT L4BN AT Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (E) 2 (E) 3 (E) 7.2.4 (16) V10 7.3.3 (17) 7.5.11 (18) 1 (E) 2 (E) 3 (E) V10 1 (E) 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) 1 (E) 2 (E) 3 (E) FL 2 (D/E) LGBF FL 3 (D/E) LGBF FL 2 (D/E) 8.5 (19) S20 V11 5.3.2.3 (20) 88 80 VC1 VC2 AP7 80 S20 V11 88 80 VC1 VC2 AP7 80 V10 S20 V11 88 80 VC1 VC2 AP7 80 S20 88 80 V12 80 S20 88 80 V12 80 S20 88 80 V12 80 S20 88 80 V12 80 4 (E) 2 (E) 3 (E) 2 (E) LGBF Hazard UN No. identification No. Operation Name and description 3.1.2 (1) (2) 3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 3268 SAFETY DEVICES, electrically initiated 3269 POLYESTER RESIN KIT S2 S20 S2 3269 POLYESTER RESIN KIT 3270 NITROCELLULOSE MEMBRANE FILTERS, with not more than 12.6% nitrogen, by dry mass V12 - 483 - S2 S20 33 3271 ETHERS, N.O.S. S2 30 3271 ETHERS, N.O.S. S2 S20 33 3272 ESTERS, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3272 ESTERS, N.O.S. 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) III 5.2.2 (5) 3 3.3 (6) 274 601 3.4 (7a) 5L 3.5.1.2 (7b) E1 3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 3274 ALCOHOLATES SOLUTION, N.O.S., in alcohol 3275 NITRILES, TOXIC, FLAMMABLE, N.O.S. 3 FT1 I 274 0 E0 3 FT1 II 274 1L E2 3 FC II 274 1L E2 6.1 TF1 I 3 +6.1 3 +6.1 3 +8 6.1 +3 274 315 0 E5 274 100 ml E4 274 315 0 E5 4.1.4 (8) P001 IBC03 LP01 R001 P001 4.1.4 (9a) P001 IBC02 P001 IBC02 P001 4.1.10 (9b) MP19 4.2.5.2 (10) T4 4.2.5.3 (11) TP1 TP29 MP7 MP17 MP19 T14 TP2 TP27 TP2 TP27 T11 MP19 MP8 MP17 T14 TP2 TP27 P001 IBC02 P001 MP15 T11 MP8 MP17 T14 TP2 TP27 TP2 TP27 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC02 P001 MP15 T11 MP19 T7 MP15 T8 MP8 MP17 T14 3275 NITRILES, TOXIC, FLAMMABLE, N.O.S. 3276 NITRILES, LIQUID, TOXIC, N.O.S. 6.1 TF1 II 6.1 T1 I 6.1 +3 6.1 3276 NITRILES, LIQUID, TOXIC, N.O.S. 6.1 T1 II 6.1 274 100 ml E4 3276 NITRILES, LIQUID, TOXIC, N.O.S. 6.1 T1 III 6.1 274 5L E1 3277 CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. 3278 ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. 3278 ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. 3278 ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. 6.1 TC1 II E4 T1 I 0 E5 6.1 T1 II 6.1 274 561 43 274 315 43 274 100 ml 6.1 6.1 +8 6.1 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 6.1 T1 III 6.1 43 274 5L E1 MP19 T7 TP1 TP28 6.1 TF1 I 6.1 +3 0 E5 MP8 MP17 T14 TP2 TP27 6.1 TF1 II 6.1 +3 43 274 315 43 274 P001 IBC03 LP01 R001 P001 100 ml E4 P001 MP15 T11 TP2 TP27 6.1 T3 I 6.1 274 315 0 E5 P001 MP8 MP17 T14 TP2 TP27 3280 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. 3280 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. 6.1 T3 II 6.1 274 100 ml E4 MP15 T11 6.1 T3 III 6.1 274 5L E1 MP19 T7 TP2 TP27 TP1 TP28 3281 METAL CARBONYLS, LIQUID, N.O.S. 6.1 T3 I 6.1 0 E5 MP8 MP17 T14 TP2 TP27 3281 METAL CARBONYLS, LIQUID, N.O.S. 3281 METAL CARBONYLS, LIQUID, N.O.S. 6.1 T3 II 6.1 100 ml E4 T11 T3 III 6.1 5L E1 MP19 T7 TP2 TP27 TP1 TP28 3282 ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. 3282 ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. 3282 ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. 6.1 T3 I 6.1 274 562 0 E5 P001 IBC02 P001 IBC03 LP01 R001 P001 MP15 6.1 274 315 562 274 562 274 562 P001 IBC02 P001 IBC03 LP01 R001 P601 MP8 MP17 T14 TP2 TP27 6.1 T3 II 6.1 274 562 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 6.1 T3 III 6.1 274 562 5L E1 MP19 T7 TP1 TP28 3283 SELENIUM COMPOUND, SOLID, N.O.S. 6.1 T5 I 6.1 274 563 0 E5 P001 IBC03 LP01 R001 P002 IBC07 MP18 T6 TP33 3283 SELENIUM COMPOUND, SOLID, N.O.S. 6.1 T5 II 6.1 274 563 500 g E4 MP10 T3 TP33 3279 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. 3279 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. 3280 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. - 484 - P002 IBC08 B4 TP2 TP27 TP1 TP28 TP2 TP28 TP2 TP27 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) LGBF 4.3.5, 6.8.4 (13) 9.1.1.2 (14) FL 1.1.3.6 (15) 3 (D/E) L10CH TU14 TU15 TE21 TU15 FL 1 (C/E) 2 (D/E) 2 (D/E) 1 (C/D) L4BH L4BH FL FL Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) V12 7.3.3 (17) 7.5.11 (18) 8.5 (19) S2 5.3.2.3 (20) 30 3.1.2 (1) (2) 3272 ESTERS, N.O.S. CV13 CV28 CV13 CV28 S2 S22 336 S2 S22 336 S2 S20 338 S2 S9 S14 663 3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 3274 ALCOHOLATES SOLUTION, N.O.S., in alcohol 3275 NITRILES, TOXIC, FLAMMABLE, N.O.S. S2 S9 S19 63 S9 S14 66 3275 NITRILES, TOXIC, FLAMMABLE, N.O.S. 3276 NITRILES, LIQUID, TOXIC, N.O.S. S9 S19 60 3276 NITRILES, LIQUID, TOXIC, N.O.S. S9 60 3276 NITRILES, LIQUID, TOXIC, N.O.S. S9 S19 68 S9 S14 66 S9 S19 60 CV13 CV28 S9 60 3277 CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. 3278 ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. 3278 ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. 3278 ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. CV1 CV13 CV28 CV13 CV28 S2 S9 S14 663 S2 S9 S19 63 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 S14 66 S9 S19 60 S9 60 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 S14 66 3281 METAL CARBONYLS, LIQUID, N.O.S. S9 S19 60 S9 60 3281 METAL CARBONYLS, LIQUID, N.O.S. 3281 METAL CARBONYLS, LIQUID, N.O.S. CV1 CV13 CV28 CV13 CV28 S9 S14 66 S9 S19 60 L10CH TU14 TU15 TE19 TE21 FL L4BH TU15 TE19 FL L10CH TU14 TU15 TE19 TE21 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L10CH TU14 TU15 TE19 TE21 AT L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L4BH TU15 TE19 FL 2 (D/E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 3283 SELENIUM COMPOUND, SOLID, N.O.S. SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 S9 S19 60 3283 SELENIUM COMPOUND, SOLID, N.O.S. 2 (D/E) 1 (C/E) 2 (D/E) 2 (E) V12 2 (D/E) 1 (C/E) CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 V12 V12 V12 - 485 - 3279 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. 3279 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. 3280 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. 3280 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. 3280 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. 3282 ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. 3282 ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. 3282 ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 6.1 3284 TELLURIUM COMPOUND, N.O.S. 6.1 T5 I 3284 TELLURIUM COMPOUND, N.O.S. 6.1 T5 II 3284 TELLURIUM COMPOUND, N.O.S. 6.1 2.2 (3b) T5 T5 2.1.1.3 (4) III III 5.2.2 (5) 6.1 3.3 (6) 274 563 3.4 (7a) 5 kg 6.1 274 0 E5 6.1 274 500 g E4 6.1 274 5 kg 3.5.1.2 (7b) E1 E1 3285 VANADIUM COMPOUND, N.O.S. 6.1 T5 I 6.1 274 564 0 E5 3285 VANADIUM COMPOUND, N.O.S. 6.1 T5 II 6.1 274 564 274 564 500 g E4 3285 VANADIUM COMPOUND, N.O.S. 6.1 T5 III 3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. 3 FTC I 3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. 3 FTC II 3287 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 T4 3287 TOXIC LIQUID, INORGANIC, N.O.S. 3287 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 6.1 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3283 SELENIUM COMPOUND, SOLID, N.O.S. Packaging E1 4.1.4 (8) P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P001 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 B3 B4 B3 B4 B3 274 0 E0 274 1L E2 P001 IBC02 MP19 T11 TP2 TP27 I 3 +6.1 +8 3 +6.1 +8 6.1 274 315 0 E5 P001 MP8 MP17 T14 TP2 TP27 T4 II 6.1 274 100 ml E4 MP15 T11 6.1 T4 III 6.1 274 5L E1 MP19 T7 TP2 TP27 TP1 TP28 3288 TOXIC SOLID, INORGANIC, N.O.S. 6.1 T5 I 6.1 274 0 E5 P001 IBC02 P001 IBC03 LP01 R001 P002 IBC07 MP18 T6 TP33 3288 TOXIC SOLID, INORGANIC, N.O.S. 3288 TOXIC SOLID, INORGANIC, N.O.S. 6.1 T5 II 6.1 274 500 g E4 MP10 T3 TP33 MP10 T1 TP33 3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 6.1 TC3 I 6.1 +8 274 315 0 E5 MP8 MP17 T14 TP2 TP27 3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 6.1 TC3 II 274 100 ml E4 T11 TC4 I 274 0 E5 P001 IBC02 P002 IBC05 MP15 6.1 6.1 +8 6.1 +8 MP18 T6 TP2 TP27 TP33 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 3291 CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S. 3291 CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S., in refrigerated liquid nitrogen 6.1 TC4 II 274 500 g E4 T3 TP33 I3 II 565 0 E0 P002 IBC06 P621 IBC620 LP621 MP10 6.2 6.1 +8 6.2 MP6 BK2 6.2 I3 II 6.2 +2.2 565 0 E0 P621 IBC620 LP621 MP6 3292 BATTERIES, CONTAINING SODIUM, or CELLS, CONTAINING SODIUM 3293 HYDRAZINE, AQUEOUS SOLUTION with not more than 37% hydrazine, by mass 4.3 W3 4.3 239 295 0 E0 P408 6.1 T4 III 6.1 566 5L E1 6.1 TF1 I 6.1 +3 610 0 E0 P001 IBC03 LP01 R001 P601 3294 HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45% hydrogen cyanide 6.1 T5 III 6.1 274 - 486 - 5 kg E1 P002 IBC08 P002 IBC08 LP02 R001 P001 B4 B3 MP19 T4 TP1 MP8 MP17 T14 TP2 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) SGAH L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT S10AH L10CH TU14 TU15 TE19 TE21 SGAH L4BH SGAH L4BH Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (E) 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) CV13 CV28 8.5 (19) S9 5.3.2.3 (20) 60 3.1.2 (1) (2) 3283 SELENIUM COMPOUND, SOLID, N.O.S. AT 1 (C/E) V10 S9 S14 66 3284 TELLURIUM COMPOUND, N.O.S. TU15 TE19 AT V11 S9 S19 60 3284 TELLURIUM COMPOUND, N.O.S. TU15 TE19 AT 2 (D/E) 2 (E) VC1 VC2 AP7 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 60 3284 TELLURIUM COMPOUND, N.O.S. S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 3285 VANADIUM COMPOUND, N.O.S. SGAH L4BH SGAH L4BH TU15 TE19 AT V11 S9 S19 60 3285 VANADIUM COMPOUND, N.O.S. TU15 TE19 AT 2 (D/E) 2 (E) VC1 VC2 AP7 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 60 3285 VANADIUM COMPOUND, N.O.S. L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 368 3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 368 3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 3287 TOXIC LIQUID, INORGANIC, N.O.S. L4BH TU15 TE19 AT S9 S19 60 L4BH TU15 TE19 AT 2 (D/E) 2 (E) CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 60 3287 TOXIC LIQUID, INORGANIC, N.O.S. 3287 TOXIC LIQUID, INORGANIC, N.O.S. S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 3288 TOXIC SOLID, INORGANIC, N.O.S. SGAH L4BH SGAH L4BH TU15 TE19 AT V11 S9 S19 60 TU15 TE19 AT 2 (D/E) 2 (E) CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 60 3288 TOXIC SOLID, INORGANIC, N.O.S. 3288 TOXIC SOLID, INORGANIC, N.O.S. L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 668 3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. L4BH TU15 TE19 AT S9 S19 68 S10AH L10CH TU15 TE19 AT 2 (D/E) 1 (C/E) S9 S14 668 3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. SGAH L4BH S4AH L4BH TU15 TE19 AT S9 S19 68 TU15 TE19 AT S3 606 V12 VC1 VC2 AP7 V10 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV25 CV28 2 (D/E) 2 (-) V11 2 (-) V1 CV13 CV25 CV28 2 (E) V1 CV23 V12 CV13 CV28 S9 60 CV1 CV13 CV28 S2 S9 S14 663 L4BH TU15 TE19 AT 2 (E) L15DH(+) TU14 TU15 TE19 TE21 FL 0 (C/D) V1 VC3 - 487 - S3 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 3291 CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S. 3291 CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S., in refrigerated liquid nitrogen 3292 BATTERIES, CONTAINING SODIUM, or CELLS, CONTAINING SODIUM 3293 HYDRAZINE, AQUEOUS SOLUTION with not more than 37% hydrazine, by mass 3294 HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45% hydrogen cyanide UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3295 HYDROCARBONS, LIQUID, N.O.S. 2.2 (3a) 3 2.2 (3b) F1 2.1.1.3 (4) I 5.2.2 (5) 3 3.3 (6) 3.4 (7a) 500 ml 3.5.1.2 (7b) E3 4.1.4 (8) P001 3295 HYDROCARBONS, LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 3295 HYDROCARBONS, LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 3295 HYDROCARBONS, LIQUID, N.O.S. 3 F1 II 3 640C 1L E2 3 F1 II 3 640D 1L E2 3 F1 III 3 5L E1 3296 HEPTAFLUOROPROPANE (REFRIGERANT GAS R 227) 2 2A 2.2 662 120 ml 3297 ETHYLENE OXIDE AND CHLOROTETRAFLUOROETHANE MIXTURE with not more than 8.8% ethylene oxide 3298 ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than 7.9% ethylene oxide 3299 ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more than 5.6% ethylene oxide 3300 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxide 2 2A 2.2 662 2 2A 2.2 2 2A 2.2 2 2TF 2.3 +2.1 3301 CORROSIVE LIQUID, SELFHEATING, N.O.S. 3301 CORROSIVE LIQUID, SELFHEATING, N.O.S. 3302 2-DIMETHYLAMINOETHYL ACRYLATE 3303 COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. 8 CS1 I 8 CS1 II 6.1 T1 II 2 3304 COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. 4.1.4 (9a) 4.1.10 (9b) MP7 MP17 4.2.5.2 (10) T11 P001 MP19 T7 MP19 T7 MP19 T4 E1 P001 IBC02 R001 P001 IBC03 LP01 R001 P200 MP9 (M) T50 120 ml E1 P200 MP9 (M) T50 662 120 ml E1 P200 MP9 (M) T50 662 120 ml E1 P200 MP9 (M) T50 0 E0 P200 MP9 (M) MP8 MP17 MP15 4.2.5.3 (11) TP1 TP8 TP28 TP1 TP8 TP28 TP1 TP8 TP28 TP1 TP29 8 +4.2 8 +4.2 6.1 274 0 E0 P001 274 0 E2 P001 100 ml E4 MP15 T7 1TO 2.3 +5.1 274 0 E0 P001 IBC02 P200 MP9 (M) 2 1TC 2.3 +8 274 0 E0 P200 MP9 (M) 3305 COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 3306 COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2 1TFC 274 0 E0 P200 MP9 (M) 2 1TOC 274 0 E0 P200 MP9 (M) 3307 LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. 2 2TO 2.3 +2.1 +8 2.3 +5.1 +8 2.3 +5.1 274 0 E0 P200 MP9 (M) 3308 LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. 2 2TC 2.3 +8 274 0 E0 P200 MP9 (M) 3309 LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 3310 LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2 2TFC 274 0 E0 P200 MP9 (M) 2 2TOC 274 0 E0 P200 MP9 (M) 3311 GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. 2 3O 2.3 +2.1 +8 2.3 +5.1 +8 2.2 +5.1 274 0 E0 P203 MP9 T75 TP5 TP22 3312 GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. 2 3F 2.1 274 0 E0 P203 MP9 T75 TP5 3313 ORGANIC PIGMENTS, SELFHEATING 3313 ORGANIC PIGMENTS, SELFHEATING 4.2 S2 0 E2 MP14 T3 TP33 MP14 T1 TP33 3314 PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour 9 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 R001 4.2 S2 M3 II III III 4.2 4.2 None 0 207 633 - 488 - 5 kg E1 E1 TP2 B4 B3 PP14 B3 B6 MP10 ADR tank Tank code Special provisions 4.3 (12) L4BN 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) FL 1.1.3.6 (15) 1 (D/E) L1.5BN FL LGBF LGBF Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation 8.5 (19) S2 S20 5.3.2.3 (20) 33 3.1.2 (1) (2) 3295 HYDROCARBONS, LIQUID, N.O.S. 2 (D/E) S2 S20 33 FL 2 (D/E) S2 S20 33 FL 3 (D/E) S2 30 3295 HYDROCARBONS, LIQUID, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 3295 HYDROCARBONS, LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 3295 HYDROCARBONS, LIQUID, N.O.S. V12 PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 AT 3 (C/E) PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 20 PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 20 PxBH(M) TA4 TT9 FL 1 (B/D) CV9 CV10 CV36 L10BH AT L4BN AT 1 (E) 2 (E) 2 (D/E) 1 (C/D) L4BH TU15 TE19 AT CxBH(M) TU6 TA4 TT9 TU6 TA4 TT9 TU6 TA4 TT9 TU6 TA4 TT9 TU6 TA4 TT9 TU6 TA4 TT9 TU6 TA4 TT9 TU6 TA4 TT9 TU7 TU19 TA4 TT9 TU18 TA4 TT9 AT CxBH(M) CV9 CV10 CV36 CV9 CV10 CV36 20 3296 HEPTAFLUOROPROPANE (REFRIGERANT GAS R 227) 20 3297 ETHYLENE OXIDE AND CHLOROTETRAFLUOROETHANE MIXTURE with not more than 8.8% ethylene oxide 3298 ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than 7.9% ethylene oxide 3299 ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more than 5.6% ethylene oxide 3300 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxide S2 S14 263 S14 884 84 CV13 CV28 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV10 CV36 CV9 CV11 CV36 CV9 CV11 CV36 60 S14 265 S14 268 3304 COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. S2 S14 263 S14 265 3305 COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 3306 COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. S14 265 3307 LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. S14 268 3308 LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. S2 S14 263 S14 265 3309 LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 3310 LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. S20 225 3311 GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. S2 S17 223 3312 GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. 3313 ORGANIC PIGMENTS, SELFHEATING 3313 ORGANIC PIGMENTS, SELFHEATING 1 (C/D) FL 1 (B/D) AT 1 (C/D) AT 1 (C/D) AT 1 (C/D) FL 1 (B/D) AT 1 (C/D) AT 3 (C/E) V5 FL 2 (B/D) V5 SGAV AT V1 40 SGAV AT 2 (D/E) 3 (E) V1 40 CxBH(M) PxBH(M) PxBH(M) PxBH(M) PxBH(M) RxBN RxBN 3 (D/E) VC1 VC2 AP2 90 - 489 - 3301 CORROSIVE LIQUID, SELFHEATING, N.O.S. 3301 CORROSIVE LIQUID, SELFHEATING, N.O.S. 3302 2-DIMETHYLAMINOETHYL ACRYLATE 3303 COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. S9 S19 AT CxBH(M) Name and description 3314 PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3315 CHEMICAL SAMPLE, TOXIC 2.2 (3a) 6.1 2.2 (3b) T8 2.1.1.3 (4) I 5.2.2 (5) 6.1 3.3 (6) 250 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P099 3316 CHEMICAL KIT or FIRST AID KIT 9 M11 II 9 See SP 251 See SP 340 P901 3316 CHEMICAL KIT or FIRST AID KIT 9 M11 III 9 251 340 251 340 See SP 251 See SP 340 P901 3317 2-AMINO-4,6-DINITROPHENOL, WETTED with not less than 20% water, by mass 4.1 D I 4.1 0 E0 P406 3318 AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia 2 4TC 3319 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin, by mass 3320 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION, with not more than 12% sodium borohydride and not more than 40% sodium hydroxide by mass 4.1 D 8 3320 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION, with not more than 12% sodium borohydride and not more than 40% sodium hydroxide by mass 8 3321 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), non fissile or fissile-excepted 7 7X 3322 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-III), non fissile or fissile-excepted 7 7X 3323 RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissileexcepted 7 7X 3324 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), FISSILE 7 7X +7E 3325 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (LSA-III), FISSILE 7 3326 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSILE 3327 RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non-special form 4.1.4 (9a) 4.1.10 (9b) MP8 MP17 PP26 MP2 4.2.5.2 (10) 4.2.5.3 (11) 2.3 +8 23 0 E0 P200 MP9 II 4.1 272 274 0 E0 P099 IBC99 MP2 C5 II 8 1L E2 P001 IBC02 MP15 T7 TP2 C5 III 8 5L E1 P001 IBC03 LP01 R001 MP19 T4 TP2 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 T5 TP4 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 T5 TP4 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 172 326 336 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 7X +7E 172 326 336 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 7 7X +7E 172 336 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 7 7X +7E 172 326 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 3328 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE 7 7X +7E 172 326 337 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 3329 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE 7 7X +7E 172 326 337 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 3330 RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE 7 7X +7E 172 326 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 3331 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE 7 7X +7E 172 326 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 172 317 325 336 172 317 325 336 172 317 325 - 490 - (M) T50 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) 1.1.3.6 (15) 1 (C/E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV1 CV13 CV28 2 (E) 3 (E) 1 (B) PxBH(M) TA4 TT9 AT Hazard UN No. identification No. Operation 8.5 (19) S9 S14 5.3.2.3 (20) Name and description 3.1.2 (1) (2) 3315 CHEMICAL SAMPLE, TOXIC 3316 CHEMICAL KIT or FIRST AID KIT 3316 CHEMICAL KIT or FIRST AID KIT S14 1 (C/D) CV9 CV10 2 (B) S14 3317 2-AMINO-4,6-DINITROPHENOL, WETTED with not less than 20% water, by mass 268 S14 L4BN AT 2 (E) 80 L4BN AT 3 (E) S2.65AN(+) TU36 TT7 L2.65CN(+) TM7 AT 0 (E) CV33 S2.65AN(+) TU36 TT7 L2.65CN(+) TM7 AT 0 (E) V12 3318 AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia 3319 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin, by mass 3320 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION, with not more than 12% sodium borohydride and not more than 40% sodium hydroxide by mass 80 3320 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION, with not more than 12% sodium borohydride and not more than 40% sodium hydroxide by mass S6 S11 S21 70 3321 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), non fissile or fissile-excepted CV33 S6 S11 S21 70 3322 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-III), non fissile or fissile-excepted 0 (E) CV33 S6 S11 S21 70 3323 RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissileexcepted 0 (E) CV33 S6 S11 S21 70 3324 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), FISSILE 0 (E) CV33 S6 S11 S21 70 3325 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (LSA-III), FISSILE 0 (E) CV33 S6 S11 S21 70 0 (E) CV33 S6 S11 S21 70 3326 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSILE 3327 RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non-special form 0 (E) CV33 S6 S11 S21 70 3328 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE 0 (E) CV33 S6 S11 S21 70 3329 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE 0 (E) CV33 S6 S11 S21 70 3330 RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE 0 (-) CV33 S6 S11 S21 70 3331 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE - 491 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3b) 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 2.2 (1) (2) (3a) 3332 RADIOACTIVE MATERIAL, TYPE 7 A PACKAGE, SPECIAL FORM, non fissile or fissile-excepted Packaging 5.2.2 (5) 7X 3.3 (6) 172 317 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 4.1.4 (8) (9a) See 2.2.7 See and 4.1.9 4.1.9.1.3 7X +7E 172 0 E0 See 2.2.7 See and 4.1.9 4.1.9.1.3 4.1.10 (9b) 4.2.5.2 (10) 4.2.5.3 (11) MP7 MP17 T11 TP2 3333 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE 7 3334 Aviation regulated liquid, n.o.s. 3335 Aviation regulated solid, n.o.s. 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. 3337 REFRIGERANT GAS R 404A (Pentafluoroethane, 1,1,1trifluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 44% pentafluoroethane and 52% 1,1,1trifluoroethane) 3338 REFRIGERANT GAS R 407A (Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 20% difluoromethane and 40% pentafluoroethane) 9 9 3 M11 M11 F1 I 3 274 0 3 F1 II 3 274 640C 1L E2 P001 MP19 T7 TP1 TP8 TP28 3 F1 II 3 274 640D 1L E2 P001 IBC02 R001 MP19 T7 TP1 TP8 TP28 3 F1 III 3 274 5L E1 MP19 T4 TP1 TP29 2 2A 2.2 662 120 ml E1 P001 IBC03 LP01 R001 P200 MP9 (M) T50 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 3339 REFRIGERANT GAS R 407B (Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 10% difluoromethane and 70% pentafluoroethane) 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 3340 REFRIGERANT GAS R 407C (Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 23%difluoromethane and 25% pentafluoroethane) 2 2A 2.2 662 120 ml E1 P200 MP9 (M) T50 3341 THIOUREA DIOXIDE 4.2 S2 II 4.2 0 E2 MP14 T3 TP33 3341 THIOUREA DIOXIDE 4.2 S2 III 4.2 0 E1 P002 IBC06 P002 IBC08 LP02 R001 P002 IBC06 P002 IBC08 LP02 R001 P099 MP14 T1 TP33 MP14 T3 TP33 MP14 T1 TP33 NOT SUBJECT TO ADR NOT SUBJECT TO ADR E0 P001 3342 XANTHATES 4.2 S2 II 4.2 0 E2 3342 XANTHATES 4.2 S2 III 4.2 0 E1 3343 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass 3 D 3 274 278 - 492 - 0 E0 B3 B3 MP2 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) 1.1.3.6 (15) 0 (E) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV33 8.5 (19) S6 S11 S12 S21 5.3.2.3 (20) 70 3.1.2 (1) (2) 3332 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, non fissile or fissile-excepted CV33 S6 S11 S21 70 3333 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE 0 (E) NOT SUBJECT TO ADR NOT SUBJECT TO ADR L4BN FL 1 (D/E) S2 S20 33 L1.5BN FL 2 (D/E) S2 S20 33 LGBF FL 2 (D/E) S2 S20 33 LGBF FL 3 (D/E) S2 30 V12 3334 Aviation regulated liquid, n.o.s. 3335 Aviation regulated solid, n.o.s. 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (vapour pressure at 50 °C more than 110 kPa) 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. 3337 REFRIGERANT GAS R 404A (Pentafluoroethane, 1,1,1trifluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 44% pentafluoroethane and 52% 1,1,1trifluoroethane) 3338 REFRIGERANT GAS R 407A (Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 20% difluoromethane and 40% pentafluoroethane) PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 20 PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 20 PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 20 3339 REFRIGERANT GAS R 407B (Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 10% difluoromethane and 70% pentafluoroethane) PxBN(M) TA4 TT9 AT 3 (C/E) CV9 CV10 CV36 20 3340 REFRIGERANT GAS R 407C (Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 23%difluoromethane and 25% pentafluoroethane) SGAV AT V1 40 3341 THIOUREA DIOXIDE SGAV AT 2 (D/E) 3 (E) V1 40 3341 THIOUREA DIOXIDE SGAV AT V1 40 3342 XANTHATES SGAV AT 2 (D/E) 3 (E) V1 40 3342 XANTHATES 0 (B) S2 S14 - 493 - 3343 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3344 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN, by mass 3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 2.2 (3a) 4.1 2.2 (3b) D 2.1.1.3 (4) II 5.2.2 (5) 4.1 3.3 (6) 272 274 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P099 6.1 T7 I 6.1 0 E5 P002 IBC07 6.1 T7 II 6.1 61 274 648 61 274 648 61 274 648 500 g E4 P002 IBC08 3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 3 FT2 I 3 +6.1 61 274 0 E0 3 FT2 II 3 +6.1 61 274 1L E2 6.1 TF2 I 6.1 +3 61 274 0 6.1 TF2 II 6.1 +3 61 274 6.1 TF2 III 6.1 +3 6.1 T6 I 6.1 6.1 T6 II 6.1 6.1 T6 III 6.1 3349 PYRETHROID PESTICIDE, SOLID, TOXIC 6.1 T7 I 6.1 3349 PYRETHROID PESTICIDE, SOLID, TOXIC 6.1 T7 II 6.1 3349 PYRETHROID PESTICIDE, SOLID, TOXIC 6.1 3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3 FT2 I 3 +6.1 61 274 0 E0 3 FT2 II 3 +6.1 61 274 1L E2 6.1 TF2 I 6.1 +3 61 274 0 6.1 TF2 II 6.1 +3 61 274 6.1 TF2 III 6.1 +3 61 274 6.1 T7 T7 III III 6.1 6.1 Portable tanks and bulk containers 4.1.10 (9b) MP2 4.2.5.2 (10) 4.2.5.3 (11) MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 P001 IBC02 R001 MP19 T11 TP2 TP27 E5 P001 MP8 MP17 T14 TP2 TP27 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 61 274 5L E1 P001 IBC03 R001 MP19 T7 TP2 TP28 61 274 648 61 274 648 61 274 648 0 E5 P001 MP8 MP17 T14 TP2 TP27 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 5L E1 MP19 T7 TP2 TP28 0 E5 P001 IBC03 LP01 R001 P002 IBC07 MP18 T6 TP33 500 g E4 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T14 TP2 TP27 P001 IBC02 R001 MP19 T11 TP2 TP27 E5 P001 MP8 MP17 T14 TP2 TP27 100 ml E4 P001 IBC02 MP15 T11 TP2 TP27 5L E1 P001 IBC03 R001 MP19 T7 TP2 TP28 61 274 648 61 274 648 61 274 648 - 494 - 5 kg 5 kg E1 E1 P002 IBC08 LP02 R001 P001 P002 IBC08 P002 IBC08 LP02 R001 P001 4.1.4 (9a) B4 B3 B4 B3 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) 9.1.1.2 (14) S10AH L10CH TU14 TU15 TE19 TE21 SGAH L4BH Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (B) 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) 8.5 (19) S14 5.3.2.3 (20) AT 1 (C/E) V10 S9 S14 66 TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 S9 S19 60 SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) CV1 CV13 CV28 S2 S9 S14 663 L4BH TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 S19 63 L4BH TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 63 L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) S9 S14 66 L4BH TU15 TE19 AT 2 (D/E) CV1 CV13 CV28 CV13 CV28 S9 S19 60 L4BH TU15 TE19 AT 2 (E) V12 CV13 CV28 S9 60 S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 3349 PYRETHROID PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 S9 S19 60 3349 PYRETHROID PESTICIDE, SOLID, TOXIC SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 3349 PYRETHROID PESTICIDE, SOLID, TOXIC L10CH TU14 TU15 TE21 FL 1 (C/E) CV13 CV28 S2 S22 336 L4BH TU15 FL 2 (D/E) CV13 CV28 S2 S22 336 L10CH TU14 TU15 TE19 TE21 FL 1 (C/E) S2 S9 S14 663 L4BH TU15 TE19 FL 2 (D/E) CV1 CV13 CV28 CV13 CV28 S2 S9 S19 63 L4BH TU15 TE19 FL 2 (D/E) CV13 CV28 S2 S9 63 3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C VC1 VC2 AP7 V12 VC1 VC2 AP7 V12 - 495 - 3.1.2 (1) (2) 3344 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE; PETN) MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN, by mass 3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 2.2 (3a) 6.1 2.2 (3b) T6 2.1.1.3 (4) I 5.2.2 (5) 6.1 3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 T6 II 6.1 3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 T6 III 6.1 3354 INSECTICIDE GAS, FLAMMABLE, N.O.S. 2 2F 2.1 3355 INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. 2 2TF 3356 OXYGEN GENERATOR, CHEMICAL 3357 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin, by mass 3358 REFRIGERATING MACHINES containing flammable, non-toxic, liquefied gas 3359 FUMIGATED CARGO TRANSPORT UNIT 3360 Fibres, vegetable, dry 3361 CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. 3362 CHLOROSILANES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 3363 Dangerous goods in machinery or dangerous goods in apparatus 3364 TRINITROPHENOL (PICRIC ACID), WETTED with not less than 10% water, by mass 3365 TRINITROCHLOROBENZENE (PICRYL CHLORIDE), WETTED with not less than 10% water, by mass 3366 TRINITROTOLUENE (TNT), WETTED with not less than 10% water, by mass 3367 TRINITROBENZENE, WETTED with not less than 10% water, by mass 3368 TRINITROBENZOIC ACID, WETTED with not less than 10% water, by mass 3369 SODIUM DINITRO-oCRESOLATE, WETTED with not less than 10% water, by mass 3370 UREA NITRATE, WETTED with not less than 10% water, by mass 3371 2 –METHYLBUTANAL 5.1 O3 3 D 2 6F 9 M11 4.1 6.1 F1 TC1 II 6.1 TFC II 9 M11 4.1 D I 4.1 0 E0 P406 PP24 MP2 4.1 D I 4.1 0 E0 P406 PP24 MP2 4.1 D I 4.1 0 E0 P406 PP24 MP2 4.1 D I 4.1 0 E0 P406 PP24 MP2 4.1 D I 4.1 0 E0 P406 PP24 MP2 4.1 DT I 4.1 +6.1 0 E0 P406 PP24 MP2 4.1 D I 4.1 0 E0 P406 PP78 MP2 3 F1 II 3 1L E2 3373 BIOLOGICAL SUBSTANCE, CATEGORY B 3373 BIOLOGICAL SUBSTANCE, CATEGORY B (animal material only) 3374 ACETYLENE, SOLVENT FREE 6.2 I4 6.2 319 0 E0 P001 IBC02 R001 P650 6.2 I4 6.2 319 0 E0 P650 2 2F 2.1 662 0 E0 P200 3375 AMMONIUM NITRATE EMULSION or SUSPENSION or GEL, intermediate for blasting explosives, liquid 3375 AMMONIUM NITRATE EMULSION or SUSPENSION or GEL, intermediate for blasting explosives, solid 3376 4-NITROPHENYL-HYDRAZINE, with not less than 30% water, by mass 5.1 O1 5.1 309 0 E2 P505 IBC02 B16 P505 IBC02 B16 P406 PP26 5.1 4.1 O2 D II 3.3 (6) 61 274 648 61 274 648 61 274 648 Packaging 3.4 (7a) 0 3.5.1.2 (7b) E5 4.1.4 (8) P001 100 ml E4 5L E1 274 662 0 2.3 +2.1 274 5.1 4.1.4 (9a) 4.1.10 (9b) MP8 MP17 4.2.5.2 (10) T14 4.2.5.3 (11) TP2 TP27 P001 IBC02 MP15 T11 TP2 TP27 MP19 T7 TP2 TP28 E0 P001 IBC03 LP01 R001 P200 MP9 (M) 0 E0 P200 MP9 (M) 284 0 E0 P500 MP2 3 274 288 0 E0 P099 MP2 2.1 291 0 E0 P003 PP32 MP9 302 6.1 +8 6.1 +3 +8 274 0 274 0 NOT SUBJECT TO ADR E0 P010 E0 P010 MP15 T14 MP15 T14 TP2 TP7 TP27 TP2 TP7 TP27 NOT SUBJECT TO ADR [see also 1.1.3.1 (b)] II II I 5.1 309 4.1 0 0 - 496 - E2 E0 MP19 T4 TP1 T1 TP1 T1 BK1 BK2 TP1 MP2 T1 MP2 T1 TP1 TP9 TP17 TP32 TP1 TP9 TP17 TP32 MP9 MP2 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) L10CH 4.3.5, 6.8.4 (13) TU14 TU15 TE19 TE21 9.1.1.2 (14) AT 1.1.3.6 (15) 1 (C/E) L4BH TU15 TE19 AT 2 (D/E) L4BH TU15 TE19 AT 2 (E) PxBN(M) TA4 TT9 FL 2 (B/D) PxBH(M) TU6 TA4 TT9 FL 1 (B/D) Special provisions for carriage Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV1 CV13 CV28 CV13 CV28 8.5 (19) S9 S14 5.3.2.3 (20) 66 3.1.2 (1) (2) 3352 PYRETHROID PESTICIDE, LIQUID, TOXIC S9 S19 60 3352 PYRETHROID PESTICIDE, LIQUID, TOXIC CV13 CV28 S9 60 3352 PYRETHROID PESTICIDE, LIQUID, TOXIC CV9 CV10 CV36 CV9 CV10 CV36 CV24 S2 S20 23 3354 INSECTICIDE GAS, FLAMMABLE, N.O.S. S2 S14 263 3355 INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. V12 S2 S14 2 (D) TU15 TE19 AT L4BH TU15 TE19 FL (-) NOT SUBJECT TO ADR 2 (D/E) 2 (D/E) CV9 S2 CV13 CV28 CV13 CV28 S9 S19 68 S2 S9 S19 638 NOT SUBJECT TO ADR [see also 1.1.3.1 (b)] 1 (B) S14 1 (B) S14 1 (B) S14 1 (B) S14 1 (B) S14 1 (B) LGBF L4BH L4BH FL TU15 TU37 TE19 TU15 TU37 TE19 CV13 CV28 1 (B) 2 (D/E) (-) _ (-) 2 (D) LGAV(+) SGAV(+) TU3 TU12 TU39 TE10 TE23 TA1 TA3 TU3 TU12 TU39 TE10 TE23 TA1 TA3 AT 2 (E) AT 2 (E) 1 (B) S14 S14 AT AT Name and description Packages 2 (E) 2 (B) L4BH Hazard UN No. identification No. Operation S2 S20 33 S3 606 S3 606 CV9 CV10 CV36 CV24 S9 S23 50 CV24 S9 S23 50 V1 S2 S20 S14 - 497 - 3356 OXYGEN GENERATOR, CHEMICAL 3357 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin, by mass 3358 REFRIGERATING MACHINES containing flammable, non-toxic, liquefied gas 3359 FUMIGATED CARGO TRANSPORT UNIT 3360 Fibres, vegetable, dry 3361 CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. 3362 CHLOROSILANES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 3363 Dangerous goods in machinery or dangerous goods in apparatus 3364 TRINITROPHENOL (PICRIC ACID), WETTED with not less than 10% water, by mass 3365 TRINITROCHLOROBENZENE (PICRYL CHLORIDE), WETTED with not less than 10% water, by mass 3366 TRINITROTOLUENE (TNT), WETTED with not less than 10% water, by mass 3367 TRINITROBENZENE, WETTED with not less than 10% water, by mass 3368 TRINITROBENZOIC ACID, WETTED with not less than 10% water, by mass 3369 SODIUM DINITRO-oCRESOLATE, WETTED with not less than 10% water, by mass 3370 UREA NITRATE, WETTED with not less than 10% water, by mass 3371 2 –METHYLBUTANAL 3373 BIOLOGICAL SUBSTANCE, CATEGORY B 3373 BIOLOGICAL SUBSTANCE, CATEGORY B (animal material only) 3374 ACETYLENE, SOLVENT FREE 3375 AMMONIUM NITRATE EMULSION or SUSPENSION or GEL, intermediate for blasting explosives, liquid 3375 AMMONIUM NITRATE EMULSION or SUSPENSION or GEL, intermediate for blasting explosives, solid 3376 4-NITROPHENYL-HYDRAZINE, with not less than 30% water, by mass UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 5.1 2.2 (3b) O2 3378 SODIUM CARBONATE PEROXYHYDRATE 5.1 3378 SODIUM CARBONATE PEROXYHYDRATE 5.1 3379 DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. 3380 DESENSITIZED EXPLOSIVE, SOLID, N.O.S. 3381 TOXIC BY INHALATION LIQUID, N.O.S. with an LC50 lower than or 3 D I 3 4.1 D I 4.1 6.1 T1 or T4 I 6.1 T1 or T4 6.1 O2 O2 2.1.1.3 (4) III II III 5.2.2 (5) 5.1 3.3 (6) 5.1 3.4 (7a) 5 kg 1 kg 5.1 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3377 SODIUM PERBORATE MONOHYDRATE Packaging 3.5.1.2 (7b) E1 E2 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T1 BK1 BK2 4.2.5.3 (11) TP33 MP10 T3 BK1 BK2 T1 BK1 BK2 TP33 B3 B4 0 E0 P002 IBC08 LP02 R001 P099 0 E0 P099 MP2 0 E0 P601 MP8 MP17 T22 TP2 274 0 E0 P602 MP8 MP17 T20 TP2 6.1 +3 274 0 E0 P601 MP8 MP17 T22 TP2 I 6.1 +3 274 0 E0 P602 MP8 MP17 T20 TP2 TW1 I 6.1 +4.3 274 0 E0 P601 MP8 MP17 T22 TP2 6.1 TW1 I 6.1 +4.3 274 0 E0 P602 MP8 MP17 T20 TP2 3387 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S.with an LC50 lower than or equal to 3 200 ml/m and saturated vapour concentration greater than or equal to 500 LC50 6.1 TO1 I 6.1 +5.1 274 0 E0 P601 MP8 MP17 T22 TP2 3388 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an LC50 lower than or equal to 3 1000 ml/m and saturated vapour concentration greater than or equal to 10 LC50 6.1 TO1 I 6.1 +5.1 274 0 E0 P602 MP8 MP17 T20 TP2 3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC50 lower than or equal to 3 200 ml/m and saturated vapour concentration greater than or equal to 500 LC50 6.1 TC1 or TC3 I 6.1 +8 274 0 E0 P601 MP8 MP17 T22 TP2 6.1 274 311 274 311 274 I 6.1 TF1 I 6.1 TF1 6.1 E1 4.1.4 (8) P002 IBC08 LP02 R001 P002 IBC08 MP10 B3 TP33 MP2 3 equal to 200 ml/m and saturated vapour concentration greater than or equal to 500 LC50 3382 TOXIC BY INHALATION LIQUID, N.O.S. with an LC50 lower than or 3 equal to 1000 ml/m and saturated vapour concentration greater than or equal to 10 LC50 3383 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3384 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with with an LC50 lower than or equal to 1000 3 ml/m and saturated vapour concentration greater than or equal to 10 LC50 3385 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an LC50 lower than or equal to 200 3 ml/m and saturated vapour concentration greater than or equal to 500 LC50 3386 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an LC50 lower than or equal to 1000 3 ml/m and saturated vapour concentration greater than or equal to 10 LC50 - 498 - ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) SGAV 4.3.5, 6.8.4 (13) TU3 9.1.1.2 (14) AT SGAV TU3 SGAV TU3 L15CH L10CH L15CH L10CH TU14 TU15 TE19 TE21 TU14 TU15 TE19 TE21 TU14 TU15 TE19 TE21 TU14 TU15 TE19 TE21 Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 3 (E) 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP6 AP7 7.5.11 (18) CV24 AT 2 (E) V11 VC1 VC2 AP6 AP7 AT 3 (E) VC1 VC2 AP6 AP7 AT AT FL FL 1 (B) 1 (B) 1 (C/D) 1 (C/D) 1 (C/D) 1 (C/D) Hazard UN No. identification No. Operation 8.5 (19) Name and description 5.3.2.3 (20) 50 3.1.2 (1) (2) 3377 SODIUM PERBORATE MONOHYDRATE CV24 50 3378 SODIUM CARBONATE PEROXYHYDRATE CV24 50 3378 SODIUM CARBONATE PEROXYHYDRATE S2 S14 S14 CV1 CV13 CV28 S9 S14 CV1 CV13 CV28 S9 S14 CV1 CV13 CV28 S2 S9 S14 CV1 CV13 CV28 S2 S9 S14 66 3379 DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. 3380 DESENSITIZED EXPLOSIVE, SOLID, N.O.S. 3381 TOXIC BY INHALATION LIQUID, N.O.S. with an LC50 lower than or 3 equal to 200 ml/m and saturated vapour concentration greater than or equal to 500 LC50 66 3382 TOXIC BY INHALATION LIQUID, N.O.S. with an LC50 lower than or 3 equal to 1000 ml/m and saturated vapour concentration greater than or equal to 10 LC50 663 3383 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 663 3384 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with with an LC50 lower than or equal to 1000 3 ml/m and saturated vapour concentration greater than or equal to 10 LC50 L15CH TU14 TU15 TE19 TE21 AT 1 (C/D) CV1 CV13 CV28 S9 S14 623 3385 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an LC50 lower than or equal to 200 3 ml/m and saturated vapour concentration greater than or equal to 500 LC50 L10CH TU14 TU15 TE19 TE21 AT 1 (C/D) CV1 CV13 CV28 S9 S14 623 3386 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an LC50 lower than or equal to 1000 3 ml/m and saturated vapour concentration greater than or equal to 10 LC50 L15CH TU14 TU15 TE19 TE21 AT 1 (C/D) CV1 CV13 CV28 S9 S14 665 3387 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S.with an LC50 lower than or equal to 3 200 ml/m and saturated vapour concentration greater than or equal to 500 LC50 L10CH TU14 TU15 TE19 TE21 AT 1 (C/D) CV1 CV13 CV28 S9 S14 665 3388 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an LC50 lower than or equal to 3 1000 ml/m and saturated vapour concentration greater than or equal to 10 LC50 L15CH TU14 TU15 TE19 TE21 AT 1 (C/D) CV1 CV13 CV28 S9 S14 668 3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC50 lower than or equal to 3 200 ml/m and saturated vapour concentration greater than or equal to 500 LC50 - 499 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC50 lower than or equal to 3 1000 ml/m and saturated vapour concentration greater than or equal to 10 LC50 2.2 (3a) 6.1 2.2 (3b) TC1 or TC3 2.1.1.3 (4) I 5.2.2 (5) 6.1 +8 3.3 (6) 274 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P602 4.1.4 (9a) 4.1.10 (9b) MP8 MP17 4.2.5.2 (10) T20 4.2.5.3 (11) TP2 3391 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC 3392 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC 3393 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATERREACTIVE 4.2 S5 I 4.2 274 0 E0 P404 PP86 MP2 T21 4.2 S5 I 4.2 274 0 E0 P400 PP86 MP2 T21 4.2 SW I 4.2 +4.3 274 0 E0 P404 PP86 MP2 T21 TP7 TP33 TP36 TP2 TP7 TP36 TP7 TP33 TP36 TP41 3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATERREACTIVE 3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE 4.2 SW I 4.2 +4.3 274 0 E0 P400 PP86 MP2 T21 4.3 W2 I 4.3 274 0 E0 P403 MP2 T9 3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE 3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE 3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, FLAMMABLE 4.3 W2 II 4.3 274 500 g E2 P410 IBC04 MP14 T3 4.3 W2 III 4.3 274 1 kg E1 P410 IBC06 MP14 T1 4.3 WF2 I 4.3 +4.1 274 0 E0 P403 MP2 T9 3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, FLAMMABLE 3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, FLAMMABLE 3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, SELF-HEATING 4.3 WF2 II 4.3 +4.1 274 500 g E2 P410 IBC04 MP14 T3 4.3 WF2 III 4.3 +4.1 274 1 kg E1 P410 IBC06 MP14 T1 4.3 WS I 4.3 +4.2 274 0 E0 P403 MP2 T9 3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, SELF-HEATING 3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, SELF-HEATING 3398 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE 4.3 WS II 4.3 +4.2 274 500 g E2 P410 IBC04 MP14 T3 4.3 WS III 4.3 +4.2 274 1 kg E1 P410 IBC06 MP14 T1 4.3 W1 I 4.3 274 0 E0 P402 MP2 T13 3398 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE 4.3 W1 II 4.3 274 500 ml E2 P001 IBC01 MP15 T7 3398 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE 4.3 W1 III 4.3 274 1L E1 P001 IBC02 MP15 T7 3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE, FLAMMABLE 4.3 WF1 I 4.3 +3 274 0 E0 P402 MP2 T13 3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE, FLAMMABLE 4.3 WF1 II 4.3 +3 274 500 ml E2 P001 IBC01 MP15 T7 3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE, FLAMMABLE 4.3 WF1 III 4.3 +3 274 1L E1 P001 IBC02 R001 MP15 T7 - 500 - TP2 TP7 TP36 TP41 TP7 TP33 TP36 TP41 TP33 TP36 TP41 TP33 TP36 TP41 TP7 TP33 TP36 TP41 TP33 TP36 TP41 TP33 TP36 TP41 TP7 TP33 TP36 TP41 TP33 TP36 TP41 TP33 TP36 TP41 TP2 TP7 TP36 TP41 TP2 TP7 TP36 TP41 TP2 TP7 TP36 TP41 TP2 TP7 TP36 TP41 TP2 TP7 TP36 TP41 TP2 TP7 TP36 TP41 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) L10CH 4.3.5, 6.8.4 (13) TU14 TU15 TE19 TE21 9.1.1.2 (14) AT L21DH TU4 TU14 TU22 TC1 TE21 TM1 TU4 TU14 TU22 TC1 TE21 TM1 TU4 TU14 TU22 TC1 TE21 TM1 L21DH Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 1 (C/D) 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV1 CV13 CV28 AT 0 (B/E) AT Hazard UN No. identification No. Operation 8.5 (19) S9 S14 5.3.2.3 (20) 668 V1 S20 43 0 (B/E) V1 S20 333 AT 0 (B/E) V1 S20 X432 TU4 TU14 TU22 TC1 TE21 TM1 AT 0 (B/E) V1 S20 X333 S10AN L10DH TU4 TU14 TU22 TE21 TM2 AT 1 (B/E) V1 CV23 S20 X423 SGAN L4DH TU14 TE21 TM2 AT 2 (D/E) V1 CV23 423 SGAN L4DH TU14 TE21 TM2 AT 3 (E) V1 CV23 423 S10AN L10DH TU4 TU14 TU22 TE21 TM2 AT 0 (B/E) V1 CV23 SGAN L4DH TU14 TE21 TM2 AT 0 (D/E) V1 CV23 423 SGAN L4DH TU14 TE21 TM2 AT 0 (E) V1 CV23 423 S10AN L10DH TU14 TE21 TM2 AT 1 (B/E) V1 CV23 SGAN L4DH AT 2 (D/E) V1 CV23 423 SGAN L4DH AT 3 (E) V1 CV23 423 L21DH L21DH S20 S20 X423 X323 3.1.2 (1) (2) 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an LC50 lower than or equal to 3 1000 ml/m and saturated vapour concentration greater than or equal to 10 LC50 3391 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC 3392 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC 3393 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATERREACTIVE 3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATERREACTIVE 3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE 3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE 3395 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE 3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, FLAMMABLE 3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, FLAMMABLE 3396 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, FLAMMABLE 3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, SELF-HEATING 3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, SELF-HEATING 3397 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, SELF-HEATING 3398 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE L10DH TU4 TU14 TU22 TE21 TM2 AT 0 (B/E) V1 CV23 L4DH TU14 TE21 TM2 AT 0 (D/E) V1 CV23 323 3398 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE L4DH TU14 TE21 TM2 AT 0 (E) V1 CV23 323 3398 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE L10DH TU4 TU14 TU22 TE21 TM2 FL 0 (B/E) V1 CV23 S2 S20 X323 3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE, FLAMMABLE L4DH TU4 TU14 TU22 TE21 TM2 FL 0 (D/E) V1 CV23 S2 323 3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE, FLAMMABLE L4DH TU14 TE21 TM2 FL 0 (E) V1 CV23 S2 323 3399 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE, FLAMMABLE - 501 - S20 X423 Name and description UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted Packaging Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3400 ORGANOMETALLIC SUBSTANCE, SOLID, SELFHEATING 3400 ORGANOMETALLIC SUBSTANCE, SOLID, SELFHEATING 3401 ALKALI METAL AMALGAM, SOLID 3402 ALKALINE EARTH METAL AMALGAM, SOLID 3403 POTASSIUM METAL ALLOYS, SOLID 3404 POTASSIUM SODIUM ALLOYS, SOLID 3405 BARIUM CHLORATE SOLUTION 2.2 (3a) 4.2 2.2 (3b) S5 2.1.1.3 (4) II 5.2.2 (5) 4.2 3.3 (6) 274 3.4 (7a) 500 g 3.5.1.2 (7b) E2 4.1.4 (8) P410 IBC06 4.2 S5 III 4.2 274 1 kg E1 4.3 W2 I 4.3 182 0 4.3 W2 I 4.3 183 506 4.3 W2 I 4.3 W2 5.1 3405 BARIUM CHLORATE SOLUTION 4.1.10 (9b) MP14 4.2.5.2 (10) T3 4.2.5.3 (11) TP33 TP36 P002 IBC08 MP14 T1 TP33 TP36 E0 P403 MP2 T9 0 E0 P403 MP2 T9 4.3 0 E0 P403 MP2 T9 I 4.3 0 E0 P403 MP2 T9 OT1 II 1L E2 T4 OT1 III 5L E1 MP2 T4 TP1 3406 BARIUM PERCHLORATE SOLUTION 3406 BARIUM PERCHLORATE SOLUTION 3407 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION 5.1 OT1 II 1L E2 MP2 T4 TP1 5.1 OT1 III 5L E1 MP2 T4 TP1 5.1 O1 II 1L E2 P504 IBC02 P001 IBC02 P504 IBC02 P001 IBC02 P504 IBC02 MP2 5.1 5.1 +6.1 5.1 +6.1 5.1 +6.1 5.1 +6.1 5.1 TP7 TP33 TP7 TP33 TP7 TP33 TP7 TP33 TP1 MP2 T4 TP1 3407 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION 5.1 O1 III 5.1 5L E1 P504 IBC02 MP2 T4 TP1 3408 LEAD PERCHLORATE SOLUTION 5.1 OT1 II 1L E2 T4 TP1 5.1 OT1 III 5L E1 MP2 T4 TP1 3409 CHLORONITROBENZENES, LIQUID 3410 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE SOLUTION 6.1 T1 II 100 ml E4 MP15 T7 TP2 6.1 T1 III 6.1 5L E1 MP19 T4 TP1 3411 beta-NAPHTHYLAMINE SOLUTION 3411 beta-NAPHTHYLAMINE SOLUTION 3412 FORMIC ACID with not less than 10% but not more than 85% acid by mass 3412 FORMIC ACID with not less than 5% but less than 10% acid by mass 6.1 T1 II 6.1 100 ml E4 MP15 T7 TP2 6.1 T1 III 6.1 5L E1 MP19 T7 TP2 8 C3 II 8 1L E2 P504 IBC02 P001 IBC02 P001 IBC02 P001 IBC03 R001 P001 IBC02 P001 IBC02 P001 IBC02 MP2 3408 LEAD PERCHLORATE SOLUTION 5.1 +6.1 5.1 +6.1 6.1 MP15 T7 TP2 8 C3 III 8 5L E1 MP19 T4 TP1 3413 POTASSIUM CYANIDE SOLUTION 6.1 T4 I 6.1 0 E5 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 3413 POTASSIUM CYANIDE SOLUTION 3413 POTASSIUM CYANIDE SOLUTION 6.1 T4 II 6.1 100 ml E4 MP15 T11 6.1 T4 III 6.1 5L E1 MP19 T7 TP2 TP27 TP2 TP28 3414 SODIUM CYANIDE SOLUTION 6.1 T4 I 6.1 0 E5 P001 IBC02 P001 IBC03 LP01 R001 P001 MP8 MP17 T14 TP2 3414 SODIUM CYANIDE SOLUTION 6.1 T4 II 6.1 100 ml E4 MP15 T11 3414 SODIUM CYANIDE SOLUTION 6.1 T4 III 6.1 5L E1 MP19 T7 TP2 TP27 TP2 TP28 3415 SODIUM FLUORIDE SOLUTION 6.1 T4 III 6.1 5L E1 MP19 T4 TP1 3416 CHLOROACETO-PHENONE, LIQUID 3417 XYLYL BROMIDE, SOLID 6.1 T1 II 6.1 0 E0 MP15 T7 TP2 6.1 T2 II 6.1 0 E4 P001 IBC02 P001 IBC03 LP01 R001 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 P001 IBC03 LP01 R001 MP10 T3 TP33 MP19 T4 TP1 3418 2,4-TOLUYLENEDIAMINE SOLUTION 6.1 T1 III 279 6.1 5L - 502 - E1 4.1.4 (9a) B4 ADR tank Tank code Special provisions 4.3 (12) SGAN L4BN 4.3.5, 6.8.4 (13) SGAN L4BN L10BN(+) Vehicle for tank carriage Bulk Loading, unloading and handling 7.3.3 (17) 7.5.11 (18) 7.2.4 (16) V1 AT 3 (E) V1 AT 1 (B/E) 1 (B/E) 1 (B/E) 1 (B/E) 2 (E) 3 (E) 2 (E) 3 (E) 2 (E) V1 CV23 S20 X423 V1 CV23 S20 X423 V1 CV23 S20 X423 V1 CV23 S20 X423 AT LGBV TU3 AT L4BN TU3 AT LGBV TU3 AT L4BN TU3 AT LGBV TU3 AT L4BN TU3 AT LGBV TU3 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L4BH TU15 TE19 AT L10BN(+) Packages Hazard UN No. identification No. Operation 1.1.3.6 (15) 2 (D/E) L4BN L10BN(+) Special provisions for carriage 9.1.1.2 (14) AT TU1 TE5 TT3 TM2 TU1 TE5 TT3 TM2 TU1 TE5 TT3 TM2 TU1 TE5 TT3 TM2 TU3 L10BN(+) Transport category (Tunnel restriction code) AT AT AT 8.5 (19) 5.3.2.3 (20) 40 Name and description 56 3.1.2 (1) (2) 3400 ORGANOMETALLIC SUBSTANCE, SOLID, SELFHEATING 3400 ORGANOMETALLIC SUBSTANCE, SOLID, SELFHEATING 3401 ALKALI METAL AMALGAM, SOLID 3402 ALKALINE EARTH METAL AMALGAM, SOLID 3403 POTASSIUM METAL ALLOYS, SOLID 3404 POTASSIUM SODIUM ALLOYS, SOLID 3405 BARIUM CHLORATE SOLUTION 56 3405 BARIUM CHLORATE SOLUTION 56 3406 BARIUM PERCHLORATE SOLUTION 3406 BARIUM PERCHLORATE SOLUTION 3407 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION 40 CV24 CV28 CV24 CV28 CV24 CV28 CV24 CV28 CV24 50 3 (E) CV24 50 3407 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE SOLUTION 2 (E) 3 (E) 2 (D/E) 2 (E) CV24 CV28 CV24 CV28 CV13 CV28 CV13 CV28 56 3408 LEAD PERCHLORATE SOLUTION 56 3408 LEAD PERCHLORATE SOLUTION S9 S19 60 S9 60 3409 CHLORONITROBENZENES, LIQUID 3410 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE SOLUTION S9 S19 60 S9 60 V12 2 (D/E) 2 (E) 2 (E) L4BN AT L4BN AT 3 (E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) L4BH TU15 TE19 AT 2 (E) L4BH TU15 TE19 AT SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (E) CV13 CV28 CV13 CV28 56 80 V12 V12 V12 V12 V11 V12 80 CV1 CV13 CV28 CV13 CV28 CV13 CV28 3411 beta-NAPHTHYLAMINE SOLUTION 3411 beta-NAPHTHYLAMINE SOLUTION 3412 FORMIC ACID with not less than 10% but not more than 85% acid by mass 3412 FORMIC ACID with not less than 5% but less than 10% acid by mass S9 S14 66 3413 POTASSIUM CYANIDE SOLUTION S9 S19 60 S9 60 3413 POTASSIUM CYANIDE SOLUTION 3413 POTASSIUM CYANIDE SOLUTION CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 S14 66 3414 SODIUM CYANIDE SOLUTION S9 S19 60 3414 SODIUM CYANIDE SOLUTION S9 60 3414 SODIUM CYANIDE SOLUTION CV13 CV28 S9 60 3415 SODIUM FLUORIDE SOLUTION CV13 CV28 CV13 CV28 CV13 CV28 S9 S19 60 S9 S19 60 3416 CHLOROACETO-PHENONE, LIQUID 3417 XYLYL BROMIDE, SOLID S9 60 - 503 - 3418 2,4-TOLUYLENEDIAMINE SOLUTION UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 8 2.2 (3b) C4 2.1.1.3 (4) II 5.2.2 (5) 8 8 C4 II 8 3423 TETRAMETHYL-AMMONIUM HYDROXIDE, SOLID 3424 AMMONIUM DINITRO-oCRESOLATE SOLUTION 3424 AMMONIUM DINITRO-oCRESOLATE SOLUTION 3425 BROMOACETIC ACID, SOLID 3.3 (6) 3.4 (7a) 1 kg 3.5.1.2 (7b) E2 1 kg E2 4.1.4 (8) P002 IBC08 P002 IBC08 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T3 4.2.5.3 (11) TP33 MP10 T3 TP33 B4 B4 8 CT1 II 8 +6.1 1L E2 P001 IBC02 MP15 T7 TP2 8 CT1 III 8 +6.1 5L E1 MP19 T4 TP1 6.1 T4 III 6.1 5L E1 MP19 T4 TP1 8 C8 II 8 1 kg E2 P001 IBC03 R001 P001 IBC03 LP01 R001 P002 IBC08 P001 IBC02 P001 IBC02 P002 IBC08 P001 IBC03 LP01 R001 P002 IBC08 LP02 R001 P002 IBC08 P001 IBC03 LP01 R001 P001 IBC02 P002 IBC08 P906 IBC08 MP10 T3 TP33 MP15 T7 TP2 MP19 T7 TP2 MP10 T3 TP33 MP19 T4 TP1 MP10 T1 TP33 MP10 T3 TP33 MP19 T4 TP1 MP15 T7 TP2 MP10 T3 TP33 MP10 T3 TP33 MP19 T4 TP1 MP10 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP8 MP17 T14 TP2 TP27 MP15 T11 MP19 T7 TP2 TP27 TP1 TP28 MP10 T3 TP33 MP10 T3 TP33 6.1 T1 II 6.1 100 ml E4 6.1 T1 III 6.1 5L E1 8 C4 II 8 1 kg E2 3426 ACRYLAMIDE SOLUTION 6.1 T1 III 6.1 5L E1 3427 CHLOROBENZYL CHLORIDES, SOLID 6.1 T2 III 6.1 5 kg E1 3428 3-CHLORO-4-METHYLPHENYL ISOCYANATE, SOLID 3429 CHLOROTOLUIDINES, LIQUID 6.1 6.1 T1 III 6.1 5L E1 3430 XYLENOLS, LIQUID 6.1 T1 II 6.1 100 ml E4 3431 NITROBENZO-TRIFLUORIDES, SOLID 3432 POLYCHLORINATED BIPHENYLS, SOLID 6.1 T2 II 6.1 500 g E4 3434 NITROCRESOLS, LIQUID 6.1 T1 III 6.1 5L E1 3436 HEXAFLUOROACETONE HYDRATE, SOLID 3437 CHLOROCRESOLS, SOLID 6.1 T2 II 6.1 500 g E4 9 6.1 T2 M2 T2 II II 9 500 g 305 6.1 1 kg 500 g E4 T2 I 6.1 274 0 E5 3439 NITRILES, SOLID, TOXIC, N.O.S. 6.1 T2 II 6.1 274 500 g E4 6.1 5 kg E2 6.1 III 6.1 E4 3439 NITRILES, SOLID, TOXIC, N.O.S. T2 III 6.1 6.1 6.1 T2 II 3438 alpha-METHYLBENZYL ALCOHOL, SOLID 3439 NITRILES, SOLID, TOXIC, N.O.S. Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3419 BORON TRIFLUORIDE ACETIC ACID COMPLEX, SOLID 3420 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, SOLID 3421 POTASSIUM HYDROGENDIFLUORIDE SOLUTION 3421 POTASSIUM HYDROGENDIFLUORIDE SOLUTION 3422 POTASSIUM FLUORIDE SOLUTION Packaging 274 5 kg E1 E1 3440 SELENIUM COMPOUND, LIQUID, N.O.S. 6.1 T4 I 6.1 274 563 0 E5 3440 SELENIUM COMPOUND, LIQUID, N.O.S. 3440 SELENIUM COMPOUND, LIQUID, N.O.S. 6.1 T4 II 6.1 100 ml E4 6.1 T4 III 6.1 274 563 274 563 5L E1 3441 CHLORODINITROBENZENES, SOLID 3442 DICHLOROANILINES, SOLID 6.1 T2 II 6.1 279 500 g E4 6.1 T2 II 6.1 279 - 504 - 500 g E4 P001 IBC03 LP01 R001 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P001 P001 IBC02 P001 IBC03 R001 P002 IBC08 P002 IBC08 B4 B4 B3 B4 B4 B4 B4 B4 B3 B4 B3 B4 B4 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Tank code Special provisions 4.3 (12) SGAN L4BN SGAN L4BN 4.3.5, 6.8.4 (13) L4DH TU14 TE21 AT 2 (E) L4DH TU14 TE21 AT 3 (E) L4BH TU15 TE19 AT AT 9.1.1.2 (14) AT AT SGAN L4BN L4BH TU15 TE19 AT L4BH TU15 TE19 AT SGAN L4BN L4BH AT 1.1.3.6 (15) 2 (E) 2 (E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) V11 7.3.3 (17) 7.5.11 (18) Hazard UN No. identification No. Operation 8.5 (19) V11 5.3.2.3 (20) 80 80 CV13 CV28 86 V12 CV13 CV28 86 2 (E) V12 CV13 CV28 2 (E) 2 (D/E) 2 (E) 2 (E) 2 (E) V11 SGAH L4BH TU15 TE19 AT 2 (E) SGAH L4BH L4BH TU15 TE19 AT TU15 TE19 AT 2 (D/E) 2 (E) L4BH TU15 TE19 AT SGAH L4BH S4AH L4BH TU15 TE19 AT TU15 AT L4BH TU15 TE19 AT 2 (E) V12 SGAH L4BH SGAH L4BH SGAH L4BH TU15 TE19 AT V11 TU15 TE19 AT TU15 TE19 AT 2 (D/E) 2 (D/E) 2 (E) S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 SGAH L4BH SGAH L4BH TU15 TE19 AT V11 TU15 TE19 AT 2 (D/E) 2 (E) L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) L4BH TU15 TE19 AT L4BH TU15 TE19 AT 2 (D/E) 2 (E) SGAH L4BH SGAH L4BH TU15 TE19 AT TU15 TE19 AT 2 (D/E) 2 (D/E) V12 VC1 VC2 AP7 V11 V12 V11 V11 VC1 VC2 AP9 V12 V11 V11 80 60 S9 60 CV13 CV28 S9 60 3426 ACRYLAMIDE SOLUTION CV13 CV28 S9 60 3427 CHLOROBENZYL CHLORIDES, SOLID CV13 CV28 CV13 CV28 S9 S19 60 S9 60 3428 3-CHLORO-4-METHYLPHENYL ISOCYANATE, SOLID 3429 CHLOROTOLUIDINES, LIQUID CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 S9 S19 60 3430 XYLENOLS, LIQUID S9 S19 60 S19 90 3431 NITROBENZO-TRIFLUORIDES, SOLID 3432 POLYCHLORINATED BIPHENYLS, SOLID S9 60 3434 NITROCRESOLS, LIQUID S9 S19 60 S9 S19 60 3436 HEXAFLUOROACETONE HYDRATE, SOLID 3437 CHLOROCRESOLS, SOLID S9 60 3438 alpha-METHYLBENZYL ALCOHOL, SOLID S9 S14 66 3439 NITRILES, SOLID, TOXIC, N.O.S. S9 S19 60 3439 NITRILES, SOLID, TOXIC, N.O.S. S9 60 3439 NITRILES, SOLID, TOXIC, N.O.S. S9 S14 66 3440 SELENIUM COMPOUND, LIQUID, N.O.S. S9 S19 60 S9 60 3440 SELENIUM COMPOUND, LIQUID, N.O.S. 3440 SELENIUM COMPOUND, LIQUID, N.O.S. S9 S19 60 S9 S19 60 VC1 VC2 AP7 CV13 CV28 CV13 CV28 CV13 CV28 VC1 VC2 AP7 CV1 CV13 CV28 CV13 CV28 CV13 CV28 V11 3.1.2 (1) (2) 3419 BORON TRIFLUORIDE ACETIC ACID COMPLEX, SOLID 3420 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, SOLID 3421 POTASSIUM HYDROGENDIFLUORIDE SOLUTION 3421 POTASSIUM HYDROGENDIFLUORIDE SOLUTION 3422 POTASSIUM FLUORIDE SOLUTION 3423 TETRAMETHYL-AMMONIUM HYDROXIDE, SOLID 3424 AMMONIUM DINITRO-oCRESOLATE SOLUTION 3424 AMMONIUM DINITRO-oCRESOLATE SOLUTION 3425 BROMOACETIC ACID, SOLID S9 S19 V11 AT 60 80 CV13 CV28 CV13 CV28 TU15 TE19 2 (D/E) 2 (D/E) 0 (D/E) S9 Name and description CV1 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 - 505 - 3441 CHLORODINITROBENZENES, SOLID 3442 DICHLOROANILINES, SOLID UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (1) (2) 3443 DINITROBENZENES, SOLID 2.2 (3a) 6.1 2.2 (3b) T2 2.1.1.3 (4) II 5.2.2 (5) 6.1 3.3 (6) 3.4 (7a) 500 g 3.5.1.2 (7b) E4 3444 NICOTINE HYDROCHLORIDE, SOLID 3445 NICOTINE SULPHATE, SOLID 6.1 T2 II 6.1 43 500 g E4 3446 NITROTOLUENES, SOLID 3447 NITROXYLENES, SOLID 6.1 6.1 T2 T2 T2 II II II 6.1 500 g 6.1 500 g 6.1 500 g E4 E4 E4 3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. 6.1 T2 I 6.1 274 0 E0 3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. 3449 BROMOBENZYL CYANIDES, SOLID 6.1 T2 II 6.1 274 0 E0 6.1 T2 I 6.1 3450 DIPHENYLCHLORO-ARSINE, SOLID 6.1 T3 I 6.1 3451 TOLUIDINES, SOLID 6.1 T2 II 6.1 3452 XYLIDINES, SOLID 3453 PHOSPHORIC ACID, SOLID 3454 DINITROTOLUENES, SOLID 3455 CRESOLS, SOLID 3456 NITROSYLSULPHURIC ACID, SOLID 3457 CHLORONITROTOLUENES, SOLID 3458 NITROANISOLES, SOLID 3459 NITROBROMOBENZENES, SOLID 6.1 8 6.1 6.1 8 6.1 6.1 6.1 T2 C2 T2 TC2 C2 T2 T2 T2 III II II II III III III 6.1 E0 P002 IBC07 500 g E4 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC08 LP02 R001 P002 IBC07 5 kg 6.1 500 g 6.1 +8 8 500 g 1 kg 6.1 6.1 0 500 g 8 5 kg 279 6.1 5 kg 5 kg E1 E4 E4 E2 E1 E1 E1 6.1 T2 I 6.1 210 274 0 E5 3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. 6.1 T2 II 6.1 210 274 500 g E4 3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. 6.1 210 274 5 kg 3463 PROPIONIC ACID with not less than 90% acid by mass 3464 ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. 3464 ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. 3464 ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. 8 CF1 II 6.1 T2 I 8 +3 6.1 6.1 T2 II 6.1 T2 III 6.1 6.1 5 kg E4 3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. III 6.1 E1 E1 1L E2 43 274 0 E5 43 274 500 g E4 43 274 5 kg E1 3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 6.1 T3 I 6.1 274 0 E5 3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 6.1 T3 II 6.1 274 500 g E4 - 506 - P002 IBC08 P002 E5 6.1 T2 III 279 4.1.4 (8) P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 IBC08 P002 0 3460 N-ETHYLBENZYL-TOLUIDINES, SOLID 6.1 T2 II 138 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 6.1 Packaging P002 IBC08 P002 IBC08 R001 P001 IBC02 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 4.1.4 (9a) 4.1.10 (9b) MP10 4.2.5.2 (10) T3 4.2.5.3 (11) TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP18 T6 TP33 MP10 T3 TP33 MP18 T6 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T3 TP33 MP10 T1 TP33 MP10 T1 TP33 MP10 T1 TP33 MP10 T1 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP15 T7 TP2 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP18 T6 TP33 MP10 T3 TP33 B4 B4 B4 B4 B4 B4 B4 B4 B3 B4 B4 B4 B3 B3 B3 B3 B4 B3 B4 B3 B4 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) SGAH L4BH SGAH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT TU15 TE19 AT SGAH TU15 TE19 AT SGAH L4BH SGAH L4BH S10AH L10CH TU15 TE19 AT TU15 TE19 AT TU14 TU15 TE19 TE21 AT TU15 TE19 AT TU15 TE19 AT S10AH L10CH TU15 TE19 SGAH L4BH SGAH L4BH SGAV L4BN SGAH L4BH S10AH L10CH SGAH L4BH SGAH L4BH SGAN L4BN SGAH L4BH Transport category (Tunnel restriction code) Special provisions for carriage Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 2 (D/E) 1 (C/E) 7.2.4 (16) V11 7.3.3 (17) 2 (D/E) 1 (C/E) V11 AT 1 (C/E) V10 TU15 TE19 AT V11 TU15 TE19 AT 2 (D/E) 2 (D/E) 3 (E) 7.5.11 (18) CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV1 CV13 CV28 CV1 CV13 CV28 CV13 CV28 CV13 CV28 AT TU15 TE19 AT TU15 TE19 AT AT TU15 TE19 AT SGAH L4BH TU15 TE19 AT SGAH L4BH TU15 TE19 SGAH L4BH 2 (D/E) 2 (D/E) 2 (E) 2 (E) V11 V11 V11 V11 V11 Hazard UN No. identification No. Operation 8.5 (19) S9 S19 5.3.2.3 (20) 60 3.1.2 (1) (2) 3443 DINITROBENZENES, SOLID S9 S19 60 S9 S19 60 3444 NICOTINE HYDROCHLORIDE, SOLID 3445 NICOTINE SULPHATE, SOLID S9 S19 60 3446 NITROTOLUENES, SOLID S9 S19 60 3447 NITROXYLENES, SOLID S9 S14 66 3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. S9 S19 60 S9 S14 66 3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. 3449 BROMOBENZYL CYANIDES, SOLID S9 S14 66 3450 DIPHENYLCHLORO-ARSINE, SOLID S9 S19 60 3451 TOLUIDINES, SOLID S9 S19 60 3452 XYLIDINES, SOLID 80 3453 PHOSPHORIC ACID, SOLID S9 S19 60 3454 DINITROTOLUENES, SOLID S9 S19 68 3455 CRESOLS, SOLID X80 3456 NITROSYLSULPHURIC ACID, SOLID 3457 CHLORONITROTOLUENES, SOLID VC1 VC2 AP7 V11 CV13 CV28 CV13 CV28 V11 Name and description V11 VC1 VC2 AP7 CV13 CV28 S9 60 2 (E) VC1 VC2 AP7 CV13 CV28 S9 60 3458 NITROANISOLES, SOLID AT 2 (E) VC1 VC2 AP7 CV13 CV28 S9 60 3459 NITROBROMOBENZENES, SOLID TU15 TE19 AT 2 (E) VC1 VC2 AP7 CV13 CV28 S9 60 3460 N-ETHYLBENZYL-TOLUIDINES, SOLID S10AH L10CH TU15 TE19 AT 1 (C/E) V10 S9 S14 66 3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV1 CV13 CV28 CV13 CV28 S9 S19 60 3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. SGAH L4BH TU15 TE19 AT 2 (E) S9 60 3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. FL 2 (D/E) 1 (C/E) S2 83 S9 S14 66 S9 S19 60 CV13 CV28 S9 60 3463 PROPIONIC ACID with not less than 90% acid by mass 3464 ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. 3464 ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. 3464 ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. CV1 CV13 CV28 CV13 CV28 S9 S14 66 3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. S9 S19 60 3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. L4BN VC1 VC2 AP7 S10AH L10CH TU14 TU15 TE19 TE21 AT V10 SGAH L4BH TU15 TE19 AT 2 (D/E) SGAH L4BH TU15 TE19 AT 2 (E) S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 CV13 CV28 CV1 CV13 CV28 CV13 CV28 V11 VC1 VC2 AP7 - 507 - UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 3.1.2 (1) (2) 3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 2.2 (3a) 6.1 3466 METAL CARBONYLS, SOLID, N.O.S. 6.1 T3 I 6.1 274 562 0 E5 3466 METAL CARBONYLS, SOLID, N.O.S. 3466 METAL CARBONYLS, SOLID, N.O.S. 6.1 T3 II 6.1 274 562 274 562 500 g E4 3467 ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. 3467 ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. 3467 ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. 6.1 T3 I 6.1 274 562 0 E5 6.1 T3 II 6.1 274 562 500 g E4 274 562 5 kg 3468 HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT 3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning and reducing compound) 2 1F 2.1 321 356 0 E0 P002 IBC08 LP02 R001 P205 3 FC I 3 +8 163 367 0 E0 P001 3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning and reducing compound) 3 FC II 3 +8 163 367 1L E2 3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning and reducing compound) 3 FC III 3 +8 163 367 5L 3470 PAINT, CORROSIVE, FLAMMABLE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE (including paint thinning and reducing compound) 8 CF1 II 8 +3 163 367 3471 HYDROGENDIFLUORIDES SOLUTION, N.O.S. 3471 HYDROGENDIFLUORIDES SOLUTION, N.O.S. 8 CT1 II 8 CT1 III 3472 CROTONIC ACID, LIQUID 8 C3 III 6.1 6.1 T3 T3 2.1.1.3 (4) III III III 5.2.2 (5) 6.1 4.1.10 (9b) MP10 4.2.5.2 (10) T1 4.2.5.3 (11) TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP18 T6 TP33 MP10 T3 TP33 MP10 T1 TP33 MP7 MP17 T11 TP2 TP27 P001 IBC02 MP19 T7 TP2 TP8 TP28 E1 P001 IBC03 R001 MP19 T4 TP1 TP29 1L E2 P001 IBC02 MP15 T7 TP2 TP8 TP28 8 +6.1 8 +6.1 1L E2 MP15 T7 TP2 5L E1 MP19 T4 TP1 8 5L E1 P001 IBC02 P001 IBC03 R001 P001 IBC03 LP01 R001 MP19 T4 TP1 6.1 6.1 3.3 (6) 274 - 508 - 3.4 (7a) 5 kg Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 2.2 (3b) T3 Packaging 5 kg 3.5.1.2 (7b) E1 E1 E1 4.1.4 (8) P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 P002 IBC08 LP02 R001 P002 IBC07 P002 IBC08 4.1.4 (9a) B3 B4 B3 B4 B3 MP9 ADR tank Vehicle for tank carriage Tank code Special provisions 4.3 (12) SGAH L4BH 4.3.5, 6.8.4 (13) TU15 TE19 9.1.1.2 (14) AT S10AH L10CH TU14 TU15 TE19 TE21 SGAH L4BH SGAH L4BH Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 1.1.3.6 (15) 2 (E) 7.2.4 (16) 7.3.3 (17) VC1 VC2 AP7 7.5.11 (18) CV13 CV28 8.5 (19) S9 5.3.2.3 (20) 60 3.1.2 (1) (2) 3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. AT 1 (C/E) V10 S9 S14 66 3466 METAL CARBONYLS, SOLID, N.O.S. TU15 TE19 AT V11 S9 S19 60 TU15 TE19 AT 2 (D/E) 2 (E) VC1 VC2 AP7 CV1 CV13 CV28 CV13 CV28 CV13 CV28 S9 60 3466 METAL CARBONYLS, SOLID, N.O.S. 3466 METAL CARBONYLS, SOLID, N.O.S. S10AH L10CH TU14 TU15 TE19 TE21 AT 1 (C/E) V10 S9 S14 66 SGAH L4BH TU15 TE19 AT 2 (D/E) V11 S9 S19 60 SGAH L4BH TU15 TE19 AT 2 (E) CV13 CV28 S9 60 CV9 CV10 CV36 S2 S20 VC1 VC2 AP7 2 (D) L10CH TU14 TE21 CV1 CV13 CV28 CV13 CV28 3467 ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. 3467 ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. 3467 ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. 3468 HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT 3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning and reducing compound) FL 1 (C/E) S2 S20 338 L4BH FL 2 (D/E) S2 S20 338 3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning and reducing compound) L4BN FL 3 (D/E) S2 38 3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning and reducing compound) L4BN FL 2 (D/E) S2 83 3470 PAINT, CORROSIVE, FLAMMABLE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL, CORROSIVE, FLAMMABLE (including paint thinning and reducing compound) 2 (E) 3 (E) 86 3471 HYDROGENDIFLUORIDES SOLUTION, N.O.S. 3471 HYDROGENDIFLUORIDES SOLUTION, N.O.S. L4DH TU14 TE21 AT L4DH TU14 TE21 AT L4BN AT 3 (E) V12 V12 CV13 CV28 CV13 CV28 V12 86 80 - 509 - 3472 CROTONIC ACID, LIQUID UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 3 2.2 (3b) F3 2.1.1.3 (4) 5.2.2 (5) 3 4.1 D I 4.1 3 F1 II 3 4.3 W3 3477 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing corrosive substances 3478 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing liquefied flammable gas 8 3.4 (7a) 1L 3.5.1.2 (7b) E0 4.1.4 (8) P004 4.1.4 (9a) 4.1.10 (9b) 0 E0 P406 PP48 MP2 333 363 664 1L E2 P001 IBC02 4.3 328 334 500 ml or 500 g E0 P004 C11 8 328 334 1 L or 1 kg E0 P004 2 6F 2.1 328 338 120 ml E0 P004 3479 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing hydrogen in metal hydride 2 6F 2.1 328 339 120 ml E0 P004 3480 LITHIUM ION BATTERIES (including lithium ion polymer batteries) 9 M4 9 188 230 310 348 376 377 636 0 E0 P903 P908 P909 LP903 LP904 3481 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT or LITHIUM ION BATTERIES PACKED WITH EQUIPMENT (including lithium ion polymer batteries) 9 M4 9 188 230 348 376 377 360 636 0 E0 P903 P908 P909 LP903 LP904 3482 ALKALI METAL DISPERSION, FLAMMABLE or ALKALINE EARTH METAL DISPERSION, FLAMMABLE 3483 MOTOR FUEL ANTI-KNOCK MIXTURE, FLAMMABLE 4.3 WF1 I 4.3 +3 182 183 506 0 E0 P402 6.1 TF1 I 6.1 +3 0 E0 P602 3484 HYDRAZINE AQUEOUS SOLUTION, FLAMMABLE with more than 37% hydrazine, by mass 8 CFT I 8 +3 +6.1 530 0 E0 P001 3485 CALCIUM HYPOCHLORITE, DRY, CORROSIVE or CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 39% available chlorine (8.8% available oxygen) 3486 CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 10% but not more than 39% available chlorine 5.1 OC2 II 5.1 +8 314 1 kg E2 P002 IBC08 5.1 +8 314 5.1 OC2 III 3.3 (6) 328 Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3473 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT containing flammable liquids 3474 1‑HYDROXYBENZOTRIAZOLE MONOHYDRATE 3475 ETHANOL AND GASOLINE MIXTURE or ETHANOL AND MOTOR SPIRIT MIXTURE or ETHANOL AND PETROL MIXTURE, with more than 10% ethanol 3476 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing water-reactive substances Packaging - 510 - 5 kg E1 P002 IBC08 LP02 R001 4.2.5.2 (10) 4.2.5.3 (11) T4 TP1 MP8 MP17 T14 TP2 MP8 MP17 T10 TP2 MP19 RR8 MP2 MP2 B4 B13 MP2 B3 B13 L3 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) LGBF Vehicle for tank carriage 9.1.1.2 (14) FL Transport category (Tunnel restriction code) 1.1.3.6 (15) 3 (E) Special provisions for carriage Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) 1 (B) 2 (D/E) 3 (E) Hazard UN No. identification No. Operation 8.5 (19) S2 5.3.2.3 (20) S17 S2 S20 V1 33 CV23 3 (E) 2 (D) CV9 CV12 S2 2 (D) CV9 CV12 S2 3.1.2 (1) (2) 3473 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT containing flammable liquids 3474 1‑HYDROXYBENZOTRIAZOLE MONOHYDRATE 3475 ETHANOL AND GASOLINE MIXTURE or ETHANOL AND MOTOR SPIRIT MIXTURE or ETHANOL AND PETROL MIXTURE, with more than 10% ethanol 3476 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing water-reactive substances 3477 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing corrosive substances 3478 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing liquefied flammable gas 3479 FUEL CELL CARTRIDGES or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing hydrogen in metal hydride 2 (E) 3480 LITHIUM ION BATTERIES (including lithium ion polymer batteries) 2 (E) 3481 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT or LITHIUM ION BATTERIES PACKED WITH EQUIPMENT (including lithium ion polymer batteries) L10BN (+) TU1 TE5 TT3 TM2 FL 1 (B/E) L10CH TU14 TU15 TE19 TE21 TT6 FL 1 (C/D) FL 1 (C/D) L10BH Name and description SGAN TU3 AT 2 (E) SGAN TU3 AT 3 (E) V1 V11 CV23 S2 S20 X323 CV1 CV13 CV28 CV13 CV28 S2 S9 S14 663 S2 S14 886 3484 HYDRAZINE AQUEOUS SOLUTION, FLAMMABLE with more than 37% hydrazine, by mass CV24 CV35 58 CV24 CV35 58 3485 CALCIUM HYPOCHLORITE, DRY, CORROSIVE or CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 39% available chlorine (8.8% available oxygen) 3486 CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 10% but not more than 39% available chlorine - 511 - 3482 ALKALI METAL DISPERSION, FLAMMABLE or ALKALINE EARTH METAL DISPERSION, FLAMMABLE 3483 MOTOR FUEL ANTI-KNOCK MIXTURE, FLAMMABLE UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3b) OC2 3487 CALCIUM HYPOCHLORITE, HYDRATED, CORROSIVE or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water 5.1 OC2 3488 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC50 lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 6.1 TFC 3489 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC50 lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 6.1 3490 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 2.1.1.3 (4) II Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 2.2 (1) (2) (3a) 3487 CALCIUM HYPOCHLORITE, 5.1 HYDRATED, CORROSIVE or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water Packaging 5.2.2 (5) 5.1 +8 3.3 (6) 314 322 3.4 (7a) 1 kg 4.2.5.2 (10) 4.2.5.3 (11) 5.1 +8 314 5 kg I 6.1 +3 +8 274 0 E0 P601 MP8 MP17 T22 TP2 TFC I 6.1 +3 +8 274 0 E0 P602 MP8 MP17 T20 TP2 6.1 TFW I 6.1 +3 +4.3 274 0 E0 P601 MP8 MP17 T22 TP2 3491 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 6.1 TFW I 6.1 +3 +4.3 274 0 E0 P602 MP8 MP17 T20 TP2 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC 3 FT1 I 3 FT1 II 3 FT1 III 3 +6.1 3 +6.1 3 +6.1 343 0 E0 P001 T14 TP2 343 1L E2 MP7 MP17 MP19 T7 TP2 343 5L MP19 T4 TP1 3495 IODINE 8 CT2 III 8 +6.1 279 5 kg MP10 T1 TP33 3496 Batteries, nickel-metal hydride 3497 KRILL MEAL 9 4.2 M11 S2 II 4.2 300 0 MP14 T3 TP33 3497 KRILL MEAL 4.2 S2 III 4.2 300 0 MP14 T1 TP33 3498 IODINE MONOCHLORIDE, LIQUID 3499 CAPACITOR, ELECTRIC DOUBLE LAYER (with an energy storage capacity greater than 0.3Wh) 8 C1 II 8 MP15 T7 TP2 9 M11 9 361 0 3500 CHEMICAL UNDER PRESSURE, N.O.S. 2 8A 2.2 274 659 0 E0 P206 MP9 T50 TP4 TP40 3501 CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S. 2 8F 2.1 274 659 0 E0 P206 MP9 T50 TP4 TP40 III 1L - 512 - 3.5.1.2 (7b) E2 E1 4.1.4 (8) P002 IBC08 P002 IBC08 R001 4.1.4 (9a) 4.1.10 (9b) MP2 B4 B13 MP2 B4 B13 P001 IBC02 E1 P001 IBC03 R001 E1 P002 IBC08 B3 R001 NOT SUBJECT TO ADR E2 P410 IBC06 E1 P002 IBC08 B3 LP02 R001 E0 P001 IBC02 E0 P003 PP89 ADR tank Vehicle for tank carriage Transport category (Tunnel restriction code) Special provisions for carriage Tank code Special provisions Packages Bulk Loading, unloading and handling 4.3 (12) SGAN 4.3.5, 6.8.4 (13) TU3 9.1.1.2 (14) AT 1.1.3.6 (15) 2 (E) 7.2.4 (16) V11 7.3.3 (17) 7.5.11 (18) CV24 CV35 SGAN TU3 AT 3 (E) CV24 CV35 L15CH TU14 TU15 TE19 TE21 FL 1 (C/D) CV1 CV13 CV28 L10CH TU14 TU15 TE19 TE21 FL 1 (C/D) L15CH TU14 TU15 TE19 TE21 FL L10CH TU14 TU15 TE19 TE21 L10CH Hazard UN No. identification No. Operation 5.3.2.3 (20) 58 3.1.2 (1) (2) 3487 CALCIUM HYPOCHLORITE, HYDRATED, CORROSIVE or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water 58 3487 CALCIUM HYPOCHLORITE, HYDRATED, CORROSIVE or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water S2 S9 S14 663 3488 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC50 lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 CV1 CV13 CV28 S2 S9 S14 663 3489 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an LC50 lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 1 (C/D) CV1 CV13 CV28 S2 S9 S14 623 3490 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 FL 1 (C/D) CV1 CV13 CV28 S2 S9 S14 623 3491 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 FL S2 S19 336 TU15 FL CV13 CV28 CV13 CV28 CV13 CV28 336 L4BH 1 (C/E) 2 (D/E) 3 (D/E) S2 S22 L4BH TU14 TU15 TE21 TU15 S2 36 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC FL SGAV L4BN AT 3 (E) SGAN AT SGAV AT L4BN AT 2 (E) 4 (E) AT 3 (C/E) FL 2 (B/D) V12 VC1 VC2 AP7 8.5 (19) Name and description CV13 CV28 NOT SUBJECT TO ADR 2 V1 (D/E) 3 V1 VC1 VC2 (E) AP1 CV9 CV10 CV12 CV36 CV9 CV10 CV12 CV36 - 513 - S2 86 3495 IODINE 40 3496 Batteries, nickel-metal hydride 3497 KRILL MEAL 40 3497 KRILL MEAL 80 3498 IODINE MONOCHLORIDE, LIQUID 3499 CAPACITOR, ELECTRIC DOUBLE LAYER (with an energy storage capacity greater than 0.3Wh) 20 3500 CHEMICAL UNDER PRESSURE, N.O.S. 23 3501 CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 8T 3503 CHEMICAL UNDER PRESSURE, CORROSIVE, N.O.S. 2 3504 CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S. 2.1.1.3 (4) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3502 CHEMICAL UNDER PRESSURE, TOXIC, N.O.S. Packaging 5.2.2 (5) 2.2 +6.1 3.3 (6) 274 659 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P206 4.1.4 (9a) PP89 4.1.10 (9b) MP9 4.2.5.2 (10) T50 4.2.5.3 (11) TP4 TP40 8C 2.2 +8 274 659 0 E0 P206 PP89 MP9 T50 TP4 TP40 2 8TF 2.1 +6.1 274 659 0 E0 P206 PP89 MP9 T50 TP4 TP40 3505 CHEMICAL UNDER PRESSURE, FLAMMABLE, CORROSIVE, N.O.S. 2 8FC 2.1 +8 274 659 0 E0 P206 PP89 MP9 T50 TP4 TP40 3506 MERCURY CONTAINED IN MANUFACTURED ARTICLES 8 CT3 8 +6.1 366 5 kg E0 P003 PP90 MP15 3507 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE, less than 0.1 kg per package, non-fissile or fissile-excepted 3508 CAPACITOR, ASYMMETRIC (with an energy storage capacity greater than 0.3Wh) 3509 PACKAGINGS, DISCARDED, EMPTY, UNCLEANED 8 8 317 369 0 E0 P805 I 9 M11 9 372 0 E0 P003 9 M11 9 663 0 E0 3510 ADSORBED GAS, FLAMMABLE, N.O.S. 2 9F 2.1 274 0 E0 P003 IBC08 LP02 P208 3511 ADSORBED GAS, N.O.S. 2 9A 2.2 274 0 E0 P208 MP9 3512 ADSORBED GAS, TOXIC, N.O.S. 2 9T 2.3 274 0 E0 P208 MP9 3513 ADSORBED GAS, OXIDIZING, N.O.S. 2 9O 2.2 +5.5 274 0 E0 P208 MP9 3514 ADSORBED GAS, TOXIC, FLAMMABLE, N.O.S. 2 9TF 2.3 +2.1 274 0 E0 P208 MP9 3515 ADSORBED GAS, TOXIC, OXIDIZING, N.O.S. 2 9TO 2.3 +5.1 274 0 E0 P208 MP9 3516 ADSORBED GAS, TOXIC, CORROSIVE, N.O.S. 2 9TC 2.3 +8 274 0 E0 P208 MP9 3517 ADSORBED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 2 9TFC 2.3 +2.1 +8 274 0 E0 P208 MP9 3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2 9TOC 2.3 +5.1 +8 274 0 E0 P208 MP9 3519 BORON TRIFLUORIDE, ADSORBED 2 9TC 2.3 +8 0 E0 P208 MP9 3520 CHLORINE, ADSORBED 2 9TOC 2.3 +5.1 +8 0 E0 P208 MP9 - 514 - RR9 BB3 LL1 BK2 MP9 ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage Transport category (Tunnel restriction code) 9.1.1.2 (14) AT 1.1.3.6 (15) 1 (C/D) AT 1 (C/D) FL 1 (B/D) FL 1 (B/D) Special provisions for carriage Hazard UN No. identification No. Operation Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV9 CV10 CV12 CV28 CV36 CV9 CV10 CV12 CV36 CV9 CV10 CV12 CV28 CV36 CV9 CV10 CV12 CV36 CV13 CV28 8.5 (19) See SP 369 S21 3 (E) 1 (D) 5.3.2.3 (20) 26 3.1.2 (1) (2) 3502 CHEMICAL UNDER PRESSURE, TOXIC, N.O.S. 28 3503 CHEMICAL UNDER PRESSURE, CORROSIVE, N.O.S. S2 263 3504 CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S. S2 238 3505 CHEMICAL UNDER PRESSURE, FLAMMABLE, CORROSIVE, N.O.S. 3506 MERCURY CONTAINED IN MANUFACTURED ARTICLES 4 (E) 4 (E) Name and description VC2 AP10 90 3507 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE, less than 0.1 kg per package, non-fissile or fissile-excepted 3508 CAPACITOR, ASYMMETRIC (with an energy storage capacity greater than 0.3Wh) 3509 PACKAGINGS, DISCARDED, EMPTY, UNCLEANED 2 (D) CV9 CV10 CV36 3 (E) CV9 CV10 CV36 1 (D) CV9 CV10 CV36 3 (E) CV9 CV10 CV36 1 (D) CV9 CV10 CV36 S2 S14 3514 ADSORBED GAS, TOXIC, FLAMMABLE, N.O.S. 1 (D) CV9 CV10 CV36 S14 3515 ADSORBED GAS, TOXIC, OXIDIZING, N.O.S. 1 (D) CV9 CV10 CV36 S14 3516 ADSORBED GAS, TOXIC, CORROSIVE, N.O.S. 1 (D) CV9 CV10 CV36 S2 S14 3517 ADSORBED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 1 (D) CV9 CV10 CV36 S14 3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 1 (D) CV9 CV10 CV36 S14 3519 BORON TRIFLUORIDE, ADSORBED 1 (D) CV9 CV10 CV36 S14 3520 CHLORINE, ADSORBED - 515 - S2 3510 ADSORBED GAS, FLAMMABLE, N.O.S. 3511 ADSORBED GAS, N.O.S. S14 3512 ADSORBED GAS, TOXIC, N.O.S. 3513 ADSORBED GAS, OXIDIZING, N.O.S. UN No. Name and description Class Classifi- Packing Labels Special provication group sions code Limited and excepted 2.2 (3a) 2 2.2 (3b) 9TC 3522 ARSINE, ADSORBED 2 9TF 3523 GERMANE, ADSORBED 2 3524 PHOSPHORUS PENTAFLUORIDE, ADSORBED 2.1.1.3 (4) 5.2.2 (5) 2.3 +8 3.3 (6) Portable tanks and bulk containers Packing Special Mixed Instruc- Special instruc- packing packing tions provisions tions provisions provisions quantities 3.1.2 (1) (2) 3521 SILICON TETRAFLUORIDE, ADSORBED Packaging 3.4 (7a) 0 3.5.1.2 (7b) E0 4.1.4 (8) P208 2.3 +2.1 0 E0 P208 MP9 9TF 2.3 +2.1 0 E0 P208 MP9 2 9TC 2.3 +8 0 E0 P208 MP9 3525 PHOSPHINE, ADSORBED 2 9TF 2.3 +2.1 0 E0 P208 MP9 3526 HYDROGEN SELENIDE, ADSORBED 2 9TF 2.3 +2.1 0 E0 P208 MP9 - 516 - 4.1.4 (9a) 4.1.10 (9b) MP9 4.2.5.2 (10) 4.2.5.3 (11) ADR tank Tank code Special provisions 4.3 (12) 4.3.5, 6.8.4 (13) Vehicle for tank carriage 9.1.1.2 (14) Transport category (Tunnel restriction code) Special provisions for carriage Hazard UN No. identification No. Operation Name and description Packages Bulk Loading, unloading and handling 7.2.4 (16) 7.3.3 (17) 7.5.11 (18) CV9 CV10 CV36 8.5 (19) S14 1 (D) CV9 CV10 CV36 S2 S14 3522 ARSINE, ADSORBED 1 (D) CV9 CV10 CV36 S2 S14 3523 GERMANE, ADSORBED 1 (D) CV9 CV10 CV36 S14 3524 PHOSPHORUS PENTAFLUORIDE, ADSORBED 1 (D) CV9 CV10 CV36 S2 S14 3525 PHOSPHINE, ADSORBED 1 (D) CV9 CV10 CV36 S2 S14 3526 HYDROGEN SELENIDE, ADSORBED 1.1.3.6 (15) 1 (D) - 517 - 5.3.2.3 (20) 3.1.2 (1) (2) 3521 SILICON TETRAFLUORIDE, ADSORBED 3.2.2 Table B: Alphabetic index of substances and articles of ADR This index is an alphabetical list of the substances and articles which are listed in the UN numerical order in Table A of 3.2.1. It does not form an integral part of ADR. It has been submitted neither to the Working Party on the Transport of Dangerous Goods of the Inland Transport Committee for checking and approval nor to the Contracting Parties to ADR for formal acceptance. It has been prepared, with all necessary care by the Secretariat of the United Nations Economic Commission for Europe, in order to facilitate the consultation of Annexes A and B, but it cannot be relied upon as a substitute for the careful study and observance of the actual provisions of those annexes which, in case of conflict, are deemed to be authoritative. NOTE 1: For the purpose of determining the alphabetical order the following information has been ignored, even when it forms part of the proper shipping name: numbers; Greek letters; the abbreviations "sec" and "tert"; and the letters "N" (nitrogen), "n" (normal), "o" (ortho), "m" (meta), "p" (para) and "N.O.S." (not otherwise specified). NOTE 2: The name of a substance or article in block capital letters indicates a proper shipping name (see 3.1.2). NOTE 3: The name of a substance or article in block capital letters followed by the word "see" indicates an alternative proper shipping name or part of a proper shipping name (except for PCBs) (see 3.1.2.1). NOTE 4: An entry in lower case letters followed by the word "see" indicates that the entry is not a proper shipping name; it is a synonym. NOTE 5: Where an entry is partly in block capital letters and partly in lower case letters, the latter part is considered not to be part of the proper shipping name (see 3.1.2.1). NOTE 6: A proper shipping name may be used in the singular or plural, as appropriate, for the purposes of documentation and package marking (see 3.1.2.3). NOTE 7: For the exact determination of a proper shipping name, see 3.1.2. - 518 - ADHESIVES containing flammable liquid 1133 3 ADIPONITRILE 2205 6.1 ADSORBED GAS, FLAMMABLE, N.O.S. 3510 ADSORBED GAS, N.O.S. 3511 ADSORBED GAS, OXIDIZING, N.O.S. 3513 ADSORBED GAS, TOXIC, CORROSIVE, N.O.S. 3516 ADSORBED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 3517 8 ADSORBED GAS, TOXIC, FLAMMABLE, N.O.S. 3514 1715 8 ADSORBED GAS, TOXIC, N.O.S. 3512 Acetoin, see 2621 3 3518 ACETONE 1090 3 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. ACETONE CYANOHYDRIN, STABILIZED 1541 6.1 ADSORBED GAS, TOXIC, OXIDIZING, N.O.S. 3515 ACETONE OILS 1091 3 ACETONITRILE 1648 3 ACETYL BROMIDE 1716 8 ACETYL CHLORIDE 1717 ACETYLENE, DISSOLVED Accumulators, electric, see 2794 2795 2800 3028 3292 8 8 8 8 4.3 ACETAL 1088 3 ACETALDEHYDE 1089 3 ACETALDEHYDE AMMONIA 1841 9 ACETALDEHYDE OXIME 2332 3 ACETIC ACID, GLACIAL 2789 8 ACETIC ACID SOLUTION, more than 10% but not more than 80% acid, by mass 2790 8 ACETIC ACID SOLUTION, more than 80% acid, by mass 2789 ACETIC ANHYDRIDE 2 2 2 2 2 2 2 2 2 Aeroplane flares, see 0093 0403 0404 0420 0421 1 1 1 1 1 3 AEROSOLS 1950 2 1001 2 AGENT, BLASTING, TYPE B 0331 1 ACETYLENE, SOLVENT FREE 3374 2 AGENT, BLASTING, TYPE E 0332 1 Acetylene tetrabromide, see 2504 6.1 Air bag inflators, see Acetylene tetrachloride, see 1702 6.1 0503 3268 1 9 ACETYL IODIDE 1898 8 Air bag modules, see 0503 3268 1 9 ACETYL METHYL CARBINOL 2621 3 AIR, COMPRESSED 1002 2 Acid butyl phosphate, see 1718 8 Aircraft evacuation slides, see 2990 9 Acid mixture, hydrofluoric and sulphuric, see 1786 8 3165 3 Acid mixture, nitrating acid, see 1796 8 Acid mixture, spent, nitrating acid, see 1826 8 AIRCRAFT HYDRAULIC POWER UNIT FUEL TANK (containing a mixture of anhydrous hydrazine and methylhydrazine) (M86 fuel) Aircraft survival kits, see 2990 9 Acraldehyde, inhibited, see 1092 6.1 AIR, REFRIGERATED LIQUID 1003 2 ACRIDINE 2713 6.1 3274 3 ACROLEIN DIMER, STABILIZED 2607 3 ALCOHOLATES SOLUTION, N.O.S., in alcohol ACROLEIN, STABILIZED 1092 6.1 Alcohol, denaturated, see 1986 1987 3 3 ACRYLAMIDE, SOLID 2074 6.1 Alcohol, industrial, see ACRYLAMIDE, SOLUTION 3426 6.1 1986 1987 3 3 ACRYLIC ACID, STABILIZED 2218 8 ALCOHOLS, N.O.S. 1987 3 ACRYLONITRILE, STABILIZED 1093 3 1986 3 Actinolite, see 2212 9 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. Activated carbon, see 1362 4.2 3065 3 Activated charcoal, see 1362 4.2 ALCOHOLIC BEVERAGES, with more than 24% but not more than 70% alcohol by volume - 519 - ALCOHOLIC BEVERAGES, with more than 70% alcohol by volume 3065 3 ALKYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid 2583 8 Aldehyde, see 1989 3 ALDEHYDES, N.O.S. 1989 3 ALKYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid 2585 8 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 1988 3 ALDOL 2839 6.1 ALKYLSULPHURIC ACIDS 2571 8 ALKALI METAL ALCOHOLATES, SELFHEATING, CORROSIVE, N.O.S. 3206 4.2 Allene, see 2200 2 ALLYL ACETATE 2333 3 ALLYL ALCOHOL 1098 6.1 ALKALI METAL ALLOY, LIQUID, N.O.S. 1421 4.3 ALLYLAMINE 2334 6.1 ALKALI METAL AMALGAM, LIQUID 1389 4.3 ALLYL BROMIDE 1099 3 ALLYL CHLORIDE 1100 3 ALKALI METAL AMALGAM, SOLID 3401 4.3 Allyl chlorocarbonate, see 1722 6.1 ALLYL CHLOROFORMATE 1722 6.1 ALKALI METAL AMIDES 1390 4.3 ALLYL ETHYL ETHER 2335 3 ALKALI METAL DISPERSION 1391 4.3 ALLYL FORMATE 2336 3 ALKALI METAL DISPERSION, FLAMMABLE 3482 4.3 ALLYL GLYCIDYL ETHER 2219 3 ALLYL IODIDE 1723 3 Alkaline corrosive battery fluid, see 2797 8 6.1 3205 4.2 ALLYL ISOTHIOCYANATE, STABILIZED 1545 ALKALINE EARTH METAL ALCOHOLATES, N.O.S. 8 1393 4.3 ALLYLTRICHLOROSILANE, STABILIZED 1724 ALKALINE EARTH METAL ALLOY, N.O.S. Aluminium alkyls, see 3394 4.2 ALKALINE EARTH METAL AMALGAM, LIQUID 1392 4.3 Aluminium alkyl halides, liquid, see 3394 4.2 ALKALINE EARTH METAL AMALGAM, SOLID 3402 4.3 Aluminium alkyl halides, solid, see 3393 4.2 Aluminium alkyl hydrides, see 3394 4.2 ALKALINE EARTH METAL DISPERSION 1391 4.3 ALUMINIUM BOROHYDRIDE 2870 4.2 4.2 1391 4.3 ALUMINIUM BOROHYDRIDE IN DEVICES 2870 ALKALINE EARTH METAL DISPERSION, FLAMMABLE 8 3140 6.1 ALUMINIUM BROMIDE, ANHYDROUS 1725 ALKALOIDS, LIQUID, N.O.S. ALKALOIDS, SOLID, N.O.S. 1544 6.1 8 3140 6.1 ALUMINIUM BROMIDE SOLUTION 2580 ALKALOID SALTS, LIQUID, N.O.S. ALUMINIUM CARBIDE 1394 4.3 ALKALOID SALTS, SOLID, N.O.S. 1544 6.1 ALUMINIUM CHLORIDE, ANHYDROUS 1726 8 Alkyl aluminium halides, see 3394 4.2 8 8 ALUMINIUM CHLORIDE SOLUTION 2581 ALKYLPHENOLS, LIQUID, N.O.S. 3145 (including C2-C12 homologues) Aluminium dross, see 3170 4.3 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) 2430 8 ALUMINIUM FERROSILICON POWDER 1395 4.3 ALKYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid 2584 8 ALUMINIUM HYDRIDE 2463 4.3 ALUMINIUM NITRATE 1438 5.1 ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid 2586 ALUMINIUM PHOSPHIDE 1397 4.3 ALUMINIUM PHOSPHIDE PESTICIDE 3048 6.1 ALUMINIUM POWDER, COATED 1309 4.1 8 - 520 - ALUMINIUM POWDER, UNCOATED 1396 4.3 Ammonium bichromate, see 1439 5.1 ALUMINIUM REMELTING BYPRODUCTS 3170 4.3 Ammonium bifluoride solid, see 1727 8 Ammonium bifluoride solution, see 2817 8 ALUMINIUM RESINATE 2715 4.1 Ammonium bisulphate, see 2506 8 ALUMINIUM SILICON POWDER, UNCOATED 1398 4.3 Ammonium bisulphite solution, see 2693 8 AMMONIUM DICHROMATE 1439 5.1 ALUMINIUM SMELTING BYPRODUCTS 3170 4.3 AMMONIUM DINITRO-oCRESOLATE, SOLID 1843 6.1 Amatols, see 0082 1 3424 6.1 AMINES, FLAMMABLE, CORROSIVE, N.O.S. 2733 3 AMMONIUM DINITRO-oCRESOLATE, SOLUTION AMMONIUM FLUORIDE 2505 6.1 AMINES, LIQUID, CORROSIVE, N.O.S. 2735 8 AMMONIUM FLUORO-SILICATE 2854 6.1 Ammonium hexafluorosilicate, see 2854 6.1 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 2734 8 1727 8 AMINES, SOLID, CORROSIVE, N.O.S. 3259 8 AMMONIUM HYDROGENDIFLUORIDE, SOLID 8 1547 6.1 2-Aminobenzotrifluoruride, see 2942 6.1 AMMONIUM HYDROGENDIFLUORIDE SOLUTION 2817 Aminobenzene, see 3-Aminobenzotrifluoruride, see 2948 6.1 AMMONIUM HYDROGEN SULPHATE 2506 8 Aminobutane, see 1125 3 8 2673 6.1 2-AMINO-5-DIETHYLAMINOPENTANE 2946 6.1 Ammonium hydrosulphide solution (treat as ammonium sulphide solution), see 2683 2-AMINO-4-CHLOROPHENOL AMMONIUM METAVANADATE 2859 6.1 2-AMINO-4,6-DINITROPHENOL, WETTED with not less than 20% water, by mass 3317 AMMONIUM NITRATE 0222 1 1942 5.1 2-(2-AMINOETHOXY) ETHANOL 3055 8 N-AMINOETHYLPIPERAZINE 2815 8 AMMONIUM NITRATE with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance 1-Amino-2-nitrobenzene, see 1661 6.1 5.1 1661 6.1 1-Amino-4-nitrobenzene, see 1661 6.1 AMMONIUM NITRATE EMULSION, intermediate for blasting explosives, liquid 3375 1-Amino-3-nitrobenzene, see AMINOPHENOLS (o-, m-, p-) 2512 6.1 AMMONIUM NITRATE EMULSION, intermediate for blasting explosives, solid 3375 5.1 AMINOPYRIDINES (o-, m-, p-) 2671 6.1 Ammonium nitrate explosive, see 0082 0331 1 1 AMMONIA, ANHYDROUS 1005 2 5.1 2672 8 AMMONIUM NITRATE BASED FERTILIZER 2067 AMMONIA SOLUTION relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia 2071 9 AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 35% but not more than 50% ammonia 2073 2 AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia 3318 2 Ammonium nitrate based fertilizer, uniform mixtures of the nitrogen/phosphate, nitrogen/potash or nitrogen/phosphate/potash type, containing not more than 70% ammonium nitrate and not more than 0.4% total combustible/organic material calculated as carbon or with not more than 45% ammonium nitrate and unrestricted combustible material AMMONIUM ARSENATE 1546 6.1 4.1 - 521 - Not subject to ADR AMMONIUM NITRATE GEL, 3375 intermediate for blasting explosives, liquid 5.1 AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 0243 0244 1 1 AMMONIUM NITRATE GEL, 3375 intermediate for blasting explosives, solid 5.1 Ammunition, industrial, see 0275 0276 0277 0278 0323 0381 1 1 1 1 1 1 AMMONIUM NITRATE, LIQUID hot concentrated solution, in a concentration of more than 80% but not more than 93% 2426 5.1 AMMONIUM NITRATE SUSPENSION, intermediate for blasting explosives, liquid 3375 5.1 Ammunition, lachrymatory, see 0018 0019 0301 2017 1 1 1 1 AMMONIUM NITRATE SUSPENSION, intermediate for blasting explosives, solid 3375 5.1 AMMUNITION, PRACTICE 0362 0488 1 1 AMMONIUM PERCHLORATE 0402 1442 1 5.1 AMMUNITION, PROOF 0363 1 AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge 0015 0016 0303 1 1 1 Ammonium permanganate, see 1482 5.1 AMMONIUM PERSULPHATE 1444 5.1 AMMONIUM PICRATE dry or wetted with less than 10% water, by mass 0004 1 Ammunition, smoke (water-activated contrivances), white phosphorus with burster, expelling charge or propelling charge, see 0248 1 AMMONIUM PICRATE, WETTED with not less than 10% water, by mass 1310 4.1 Ammunition, smoke (water-activated contrivances), without white phosphorus or phosphides with burster, expelling charge or propelling charge, see 0249 1 AMMONIUM POLYSULPHIDE SOLUTION 2818 8 AMMONIUM POLYVANADATE 2861 6.1 AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge 0245 0246 1 1 Ammonium silicofluoride, see 2854 6.1 AMMONIUM SULPHIDE SOLUTION 2683 8 Ammunition, sporting, see 0012 0328 0339 0417 1 1 1 1 Ammunition, blank, see 0014 0326 0327 0338 0413 1 1 1 1 1 AMMUNITION, TEARPRODUCING, NON-EXPLOSIVE without burster or expelling charge, non-fuzed 2017 6.1 Ammunition, fixed Ammunition, semi-fixed Ammunition, separate loading, see 0005 0006 0007 0321 0348 0412 1 1 1 1 1 1 AMMUNITION, TEARPRODUCING with burster, expelling charge or propelling charge 0018 0019 0301 1 1 1 AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge 0171 0254 0297 1 1 1 AMMUNITION, TOXIC with burster, expelling charge or propelling charge 0020 1 Carriage prohibited AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge 0247 1 AMMUNITION, TOXIC with burster, expelling charge or propelling charge 0021 1 Carriage prohibited AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge 0009 0010 0300 1 1 1 0248 0249 1 1 Ammunition, incendiary (water0248 activated contrivances) with burster, 0249 expelling charge or propelling charge, see 1 1 Ammunition, toxic (water-activated contrivances) with burster, expelling charge or propelling charge, see AMMUNITION, TOXIC, NONEXPLOSIVE without burster or expelling charge, non-fuzed 2016 6.1 - 522 - Amosite, see 2212 9 ARGON, REFRIGERATED LIQUID 1951 2 Amphibole asbestos, see 2212 9 AMYL ACETATES 1104 3 Arsenates, n.o.s., see 1556 1557 6.1 6.1 AMYL ACID PHOSPHATE 2819 8 Amyl aldehyde, see 2058 3 ARSENIC 1558 6.1 AMYLAMINE 1106 3 ARSENIC ACID, LIQUID 1553 6.1 AMYL BUTYRATES 2620 3 ARSENIC ACID, SOLID 1554 6.1 AMYL CHLORIDE 1107 3 ARSENICAL DUST 1562 6.1 n-AMYLENE, see 1108 3 Arsenical flue dust, see 1562 6.1 AMYL FORMATES 1109 3 ARSENICAL PESTICIDE, LIQUID, 2760 FLAMMABLE, TOXIC, flashpoint less than 23 °C 3 AMYL MERCAPTAN 1111 3 n-AMYL METHYL KETONE 1110 3 ARSENICAL PESTICIDE, LIQUID, 2994 TOXIC 6.1 AMYL NITRATE 1112 3 AMYL NITRITE 1113 3 ARSENICAL PESTICIDE, LIQUID, 2993 TOXIC, FLAMMABLE, flashpoint not less than 23 °C 6.1 AMYLTRICHLOROSILANE 1728 8 Anaesthetic ether, see 1155 3 ARSENICAL PESTICIDE, SOLID, TOXIC 2759 6.1 ANILINE 1547 6.1 ARSENIC BROMIDE 1555 6.1 Aniline chloride, see 1548 6.1 Arsenic (III) bromide, see 1555 6.1 ANILINE HYDROCHLORIDE 1548 6.1 Arsenic chloride, see 1560 6.1 Aniline oil, see 1547 6.1 6.1 1548 6.1 ANISIDINES 2431 6.1 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1556 Aniline salt, see ANISOLE 2222 3 1557 6.1 ANISOYL CHLORIDE 1729 8 Anthophyllite, see 2212 9 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. Antimonous chloride, see 1733 8 Arsenic (III) oxide, see 1561 6.1 ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. 3141 6.1 Arsenic (V) oxide, see 1559 6.1 ARSENIC PENTOXIDE 1559 6.1 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. 1549 6.1 Arsenic sulphides, see 1556 1557 6.1 6.1 Antimony hydride, see 2676 2 ARSENIC TRICHLORIDE 1560 6.1 ANTIMONY LACTATE 1550 6.1 ARSENIC TRIOXIDE 1561 6.1 Antimony (III) lactate, see 1550 6.1 Arsenious chloride, see 1560 6.1 ANTIMONY PENTACHLORIDE, LIQUID 1730 8 Arsenites, n.o.s., see 1556 1557 6.1 6.1 ANTIMONY PENTACHLORIDE SOLUTION 1731 8 Arsenous chloride, see 1560 6.1 ANTIMONY PENTAFLUORIDE 1732 8 ARSINE 2188 2 Antimony perchloride, liquid, see 1730 8 ARSINE, ADSORBED 3522 2 ANTIMONY POTASSIUM TARTRATE 1551 6.1 ARTICLES, EEI, see 0486 1 0486 1 ANTIMONY POWDER 2871 6.1 ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE ANTIMONY TRICHLORIDE 1733 8 A.n.t.u., see 1651 6.1 ARGON, COMPRESSED 1006 2 - 523 - ARTICLES, EXPLOSIVE, N.O.S. 0349 0350 0351 0352 0353 0354 0355 0356 0462 0463 0464 0465 0466 0467 0468 0469 0470 0471 0472 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Ballistite, see 0160 0161 1 1 Bangalore torpedoes, see 0136 0137 0138 0294 1 1 1 1 BARIUM 1400 4.3 BARIUM ALLOYS, PYROPHORIC 1854 4.2 BARIUM AZIDE, dry or wetted with 0224 less than 50% water, by mass 1 BARIUM AZIDE, WETTED with not less than 50% water, by mass 1571 4.1 Barium binoxide, see 1449 5.1 BARIUM BROMATE 2719 5.1 BARIUM CHLORATE, SOLID 1445 5.1 ARTICLES, PRESSURIZED, HYDRAULIC (containing nonflammable gas) 3164 2 BARIUM CHLORATE, SOLUTION 3405 5.1 BARIUM COMPOUND, N.O.S. 1564 6.1 ARTICLES, PRESSURIZED, PNEUMATIC (containing nonflammable gas) 3164 BARIUM CYANIDE 1565 6.1 Barium dioxide, see 1449 5.1 ARTICLES, PYROPHORIC 0380 1 BARIUM HYPOCHLORITE with more than 22% available chlorine 2741 5.1 ARTICLES, PYROTECHNIC for technical purposes 0428 0429 0430 0431 0432 1 1 1 1 1 BARIUM NITRATE 1446 5.1 BARIUM OXIDE 1884 6.1 BARIUM PERCHLORATE, SOLID 1447 5.1 ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid 2584 8 BARIUM PERCHLORATE, SOLUTION 3406 5.1 BARIUM PERMANGANATE 1448 5.1 ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid 2586 8 BARIUM PEROXIDE 1449 5.1 Barium selenate, see 2630 6.1 Barium selenite, see 2630 6.1 Barium superoxide, see 1449 5.1 2 ARYLSULPHONIC ACIDS, SOLID 2583 with more than 5% free sulphuric acid 8 4.3 8 BATTERIES, CONTAINING SODIUM 3292 ARYLSULPHONIC ACIDS, SOLID 2585 with not more than 5% free sulphuric acid 3028 8 ASBESTOS, AMPHIBOLE 2212 9 BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE SOLID, electric storage ASBESTOS, CHRYSOTILE 2590 9 Batteries, nickel-metal hydride 3496 9 Asphalt, with a flash-point above 60 °C, at or above its flash-point, see 3256 3 BATTERIES, WET, FILLED WITH ACID, electric storage 2794 8 Asphalt, at or above 100 °C and below its flash-point, see 3257 9 BATTERIES, WET, FILLED WITH ALKALI, electric storage 2795 8 Aviation regulated liquid, n.o.s. 3334 9 Not subject to ADR BATTERIES, WET, NONSPILLABLE, electric storage 2800 8 Aviation regulated solid, n.o.s. 3335 9 Not subject to ADR BATTERY FLUID, ACID 2796 8 AZODICARBONAMIDE 3242 4.1 BATTERY FLUID, ALKALI 2797 8 Bag charges, see 0242 0279 0414 1 1 1 - 524 - Not subject to ADR Battery-powered vehicle or Batterypowered equipment 3171 9 Not subject to ADR, see also special provision 240 of Chapter 3.3. BISULPHATES, AQUEOUS SOLUTION 2837 8 BISULPHITES, AQUEOUS SOLUTION, N.O.S. 2693 8 Bitumen, with a flash-point above 60 °C, at or above its flash-point, see 3256 3 Bitumen, at or above 100 °C and below its flash-point, see 3257 9 BLACK POWDER, COMPRESSED 0028 1 BENZALDEHYDE 1990 9 BENZENE 1114 3 BENZENESULPHONYL CHLORIDE 2225 8 Benzenethiol, see 2337 6.1 BENZIDINE 1885 6.1 BLACK POWDER, granular or as a meal 0027 1 Benzol, see 1114 3 BLACK POWDER, IN PELLETS 0028 1 Benzolene, see 1268 3 Blasting cap assemblies, see BENZONITRILE 2224 6.1 0360 0361 1 1 BENZOQUINONE 2587 6.1 Blasting caps, electric, see Benzosulphochloride, see 2225 8 0030 0255 0456 1 1 1 BENZOTRICHLORIDE 2226 8 Blasting caps, non electric, see BENZOTRIFLUORIDE 2338 3 0029 0267 0455 1 1 1 BENZOYL CHLORIDE 1736 8 Bleaching powder, see 2208 5.1 BENZYL BROMIDE 1737 6.1 BOMBS with bursting charge BENZYL CHLORIDE 1738 6.1 Benzyl chlorocarbonate, see 1739 8 0033 0034 0035 0291 1 1 1 1 BENZYL CHLOROFORMATE 1739 8 Bombs, illuminating, see 0254 1 Benzyl cyanide, see 2470 6.1 BOMBS, PHOTO-FLASH BENZYLDIMETHYLAMINE 2619 8 BENZYLIDENE CHLORIDE 1886 6.1 0037 0038 0039 0299 1 1 1 1 BENZYL IODIDE 2653 6.1 8 6.1 BERYLLIUM NITRATE 2464 5.1 BOMBS, SMOKE, NONEXPLOSIVE with corrosive liquid, without initiating device 2028 BERYLLIUM COMPOUND, N.O.S. 1566 BERYLLIUM POWDER 1567 6.1 Bombs, target identification, see Bhusa 1327 4.1 0171 0254 0297 1 1 1 BICYCLO[2.2.1]HEPTA-2,5DIENE, STABILIZED 2251 3 BOMBS WITH FLAMMABLE LIQUID with bursting charge 0399 0400 1 1 BOOSTERS WITH DETONATOR Bifluorides, n.o.s., see 1740 8 0225 0268 1 1 BIOLOGICAL SUBSTANCE, CATEGORY B 3373 6.2 BOOSTERS without detonator 0042 0283 1 1 (BIO) MEDICAL WASTE, N.O.S. 3291 6.2 Borate and chlorate mixture, see 1458 5.1 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2782 3 BORNEOL 1312 4.1 BORON TRIBROMIDE 2692 8 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 3016 6.1 BORON TRICHLORIDE 1741 2 8 3015 6.1 BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID 1742 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C BORON TRIFLUORIDE ACETIC ACID COMPLEX, SOLID 3419 8 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 2781 BORON TRIFLUORIDE 1008 2 Not subject to ADR 6.1 - 525 - BORON TRIFLUORIDE, ADSORBED 3519 2 3-BROMOPROPYNE 2345 3 BORON TRIFLUORIDE DIETHYL ETHERATE 2604 8 BROMOTRIFLUOROETHYLENE 2419 2 BROMOTRIFLUOROMETHANE 1009 2 BORON TRIFLUORIDE DIHYDRATE 2851 8 BRUCINE 1570 6.1 BURSTERS, explosive 0043 1 BORON TRIFLUORIDE DIMETHYL ETHERATE 2965 4.3 BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l 1010 2 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID 1743 8 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, SOLID 3420 8 BUTADIENES, STABILIZED, (1,2butadiene) 1010 2 BROMATES, INORGANIC, N.O.S. 1450 5.1 BUTADIENES, STABILIZED, (1,3butadiene) 1010 2 BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S 3213 5.1 BUTANE 1011 2 BROMINE 1744 8 BUTANEDIONE 2346 3 BROMINE CHLORIDE 2901 2 Butane-1-thiol, see 2347 3 BROMINE PENTAFLUORIDE 1745 5.1 BUTANOLS 1120 3 BROMINE SOLUTION 1744 8 1-Butanol, see 1120 3 BROMINE TRIFLUORIDE 1746 5.1 Butan-2-ol, see 1120 3 BROMOACETIC ACID, SOLID 3425 8 Butanol, secondary, see 1120 3 BROMOACETIC ACID, SOLUTION 1938 8 Butanol, tertiary, see 1120 3 Butanone, see 1193 3 BROMOACETONE 1569 6.1 2-Butenal, see 1143 6.1 omega-Bromoacetone, see 2645 6.4 Butene, see 1012 2 BROMOACETYL BROMIDE 2513 8 Bute-1-ene-3-one, see 1251 3 BROMOBENZENE 2514 3 1,2-Buteneoxide, see 3022 3 BROMOBENZYL CYANIDES, LIQUID 1694 6.1 2-Buten-1-ol, see 2614 3 BUTYL ACETATES 1123 3 BROMOBENZYL CYANIDES, SOLID 3449 6.1 Butyl acetate, secondary, see 1123 3 1-BROMOBUTANE 1126 3 BUTYL ACID PHOSPHATE 1718 8 2-BROMOBUTANE 2339 3 BUTYL ACRYLATES, STABILIZED 2348 3 BROMOCHLOROMETHANE 1887 6.1 Butyl alcohols, see 1120 3 1-BROMO-3-CHLOROPROPANE 2688 6.1 n-BUTYLAMINE 1125 3 1-Bromo-2,3-epoxypropane, see 2558 6.1 N-BUTYLANILINE 2738 6.1 Bromoethane, see 1891 6.1 sec-Butyl benzene, see 2709 3 2-BROMOETHYL ETHYL ETHER 2340 3 BUTYLBENZENES 2709 3 BROMOFORM 2515 6.1 n-Butyl bromide, see 1126 3 Bromomethane, see 1062 2 n-Butyl chloride, see 1127 3 1-BROMO-3-METHYLBUTANE 2341 3 n-BUTYL CHLOROFORMATE 2743 6.1 BROMOMETHYLPROPANES 2342 3 6.1 3241 4.1 tert-BUTYLCYCLOHEXYL CHLOROFORMATE 2747 2-BROMO-2-NITROPROPANE1,3-DIOL 2343 3 BROMOPROPANES 2344 3 BUTYLENES MIXTURE or 11012 BUTYLENE or CIS-2-BUTYLENE or TRANS-2-BUTYLENE 2 2-BROMOPENTANE - 526 - 1,2-BUTYLENE OXIDE, STABILIZED 3022 3 Caffeine, see 1544 6.1 Butyl ethers, see 1149 3 Cajeputene, see 2052 3 Butyl ethyl ether, see 1179 3 CALCIUM 1401 4.3 n-BUTYL FORMATE 1128 3 CALCIUM ALLOYS, PYROPHORIC 1855 4.2 tert-BUTYL HYPOCHLORITE 3255 4.2 CALCIUM ARSENATE 1573 6.1 N,n-BUTYLIMIDAZOLE 2690 6.1 1574 6.1 6.1 CALCIUM ARSENATE AND CALCIUM ARSENITE MIXTURE, SOLID N,n-Butyliminazole, see 2690 n-BUTYL ISOCYANATE 2485 6.1 Calcium bisulphite solution, see 2693 8 tert-BUTYL ISOCYANATE 2484 6.1 CALCIUM CARBIDE 1402 4.3 Butyl lithium, see 3394 4.2 CALCIUM CHLORATE 1452 5.1 BUTYL MERCAPTAN 2347 3 CALCIUM CHLORATE, AQUEOUS SOLUTION 2429 5.1 n-BUTYL METHACRYLATE, STABILIZED 2227 3 CALCIUM CHLORITE 1453 5.1 BUTYL METHYL ETHER 2350 3 CALCIUM CYANAMIDE with more than 0.1% calcium carbide 1403 4.3 BUTYL NITRITES 2351 3 CALCIUM CYANIDE 1575 6.1 Butylphenols, liquid, see 3145 8 CALCIUM DITHIONITE 1923 4.2 Butylphenols, solid, see 2430 8 CALCIUM HYDRIDE 1404 4.3 BUTYL PROPIONATES 1914 3 CALCIUM HYDROSULPHITE, see 1923 4.2 p-tert-Butyltoluene, see 2667 6.1 2667 6.1 BUTYLTRICHLOROSILANE 1747 8 CALCIUM HYPOCHLORITE, DRY 1748 with more than 39% available chlorine (8.8% available oxygen) 5.1 BUTYLTOLUENES 5-tert-BUTYL-2,4,6-TRINITRO-mXYLENE 2956 4.1 5.1 BUTYL VINYL ETHER, STABILIZED 2352 3 CALCIUM HYPOCHLORITE, 3485 DRY, CORROSIVE with more than 39% available chlorine (8.8% available oxygen) 5.1 2452 2 1,4-BUTYNEDIOL 2716 6.1 CALCIUM HYPOCHLORITE, HYDRATED with not less than 5.5% but not more than 16% water 2880 But-1-yne, see 2-Butyne-1,4-diol, see 2716 6.1 2880 5.1 BUTYRALDEHYDE 1129 3 BUTYRALDOXIME 2840 3 CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16% water BUTYRIC ACID 2820 8 3487 5.1 BUTYRIC ANHYDRIDE 2739 8 Butyrone, see 2710 3 CALCIUM HYPOCHLORITE, HYDRATED, CORROSIVE with not less than 5.5% but not more than 16% water BUTYRONITRILE 2411 3 3487 5.1 Butyroyl chloride, see 2353 3 CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water BUTYRYL CHLORIDE 2353 3 Cable cutters, explosive, see 0070 1 2208 5.1 CACODYLIC ACID 1572 6.1 CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 10% but not more than 39% available chlorine CADMIUM COMPOUND 2570 6.1 5.1 1407 4.3 CAESIUM HYDROXIDE 2682 8 CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) 1748 CAESIUM CAESIUM HYDROXIDE SOLUTION 2681 8 CAESIUM NITRATE 1451 5.1 Carriage prohibited - 527 - CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 10% but not more than 39% available chlorine 3486 CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 39% available chlorine (8.8% available oxygen) 3485 CALCIUM MANGANESE SILICON 2844 CALCIUM NITRATE 5.1 Carbon bisulphide, see 1131 3 Carbon black (animal or vegetable origin), see 1361 4.2 CARBON DIOXIDE 1013 2 Carbon dioxide and ethylene oxide mixture, see 1041 1952 3300 2 2 2 4.3 CARBON DIOXIDE, REFRIGERATED LIQUID 2187 2 1454 5.1 Carbon dioxide, solid 1845 9 Calcium oxide 1910 8 CALCIUM PERCHLORATE 1455 5.1 CALCIUM PERMANGANATE 1456 5.1 CARBON DISULPHIDE 1131 3 CALCIUM PEROXIDE 1457 5.1 Carbonic anhydride, see CALCIUM PHOSPHIDE 1360 4.3 1013 1845 2187 2 9 2 CALCIUM, PYROPHORIC 1855 4.2 2 1313 4.1 CARBON MONOXIDE, COMPRESSED 1016 CALCIUM RESINATE CALCIUM RESINATE, FUSED 1314 4.1 Carbon oxysulphide, see 2204 2.3 Calcium selenate, see 2630 6.1 CARBON TETRABROMIDE 2516 6.1 CALCIUM SILICIDE 1405 4.3 CARBON TETRACHLORIDE 1846 6.1 Calcium silicon, see 1405 4.3 Carbonyl chloride, see 1076 2 Calcium superoxide, see 1457 5.1 CARBONYL FLUORIDE 2417 2 CAPACITOR, ASYMMETRIC, (with an energy storage capacity greater than 0.3Wh) 3508 9 CARBONYL SULPHIDE 2204 2 Cartridge cases, empty, primed, see 0055 0379 1 1 CAPACITOR, ELECTRIC DOUBLE LAYER (with an energy storage capacity greater than 0.3 Wh) 3499 9 Cartridges, actuating, for fire extinguisher or apparatus valve, see 0275 0276 0323 0381 1 1 1 1 Camphanone, see 2717 4.1 Cartridges, explosive, see 0048 1 CAMPHOR OIL 1130 3 CARTRIDGES, FLASH CAMPHOR, synthetic 2717 4.1 0049 0050 1 1 CAPROIC ACID 2829 8 0014 1 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2758 3 CARTRIDGES FOR TOOLS, BLANK CARTRIDGES FOR WEAPONS with bursting charge CARBAMATE PESTICIDE, LIQUID, TOXIC 2992 6.1 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2991 6.1 0005 0006 0007 0321 0348 0412 1 1 1 1 1 1 CARTRIDGES FOR WEAPONS, BLANK CARBAMATE PESTICIDE, SOLID, TOXIC 2757 6.1 Carbolic acid, see 1671 2312 2821 6.1 6.1 6.1 0014 0326 0327 0338 0413 1 1 1 1 1 CARTRIDGES FOR WEAPONS, INERT PROJECTILE CARBON, animal or vegetable origin 1361 4.2 0012 0328 0339 0417 1 1 1 1 CARBON, ACTIVATED 1362 4.2 Cartridges, illuminating, see 0171 0254 0297 1 1 1 5.1 to ADR when used as a coolant, see 5.5.3 Not subject to ADR - 528 - Not subject CARTRIDGES, OIL WELL 0277 0278 1 1 Charges, expelling, explosive, for fire 0275 extinguishers, see 0276 0323 0381 1 1 1 1 CARTRIDGES, POWER DEVICE 0275 0276 0323 0381 1 1 1 1 CHARGES, EXPLOSIVE, COMMERCIAL without detonator 0442 0443 0444 0445 1 1 1 1 0054 0312 0405 1 1 1 CHARGES, PROPELLING 0271 0272 0415 0491 1 1 1 1 CARTRIDGES, SMALL ARMS 0012 0339 0417 1 1 1 CARTRIDGES, SMALL ARMS, BLANK 0014 0327 0338 1 1 1 CHARGES, PROPELLING, FOR CANNON 0242 0279 0414 1 1 1 Cartridges, starter, jet engine, see 0275 0276 0323 0381 1 1 1 1 CHARGES, SHAPED, FLEXIBLE, LINEAR 0237 0288 1 1 CHARGES, SHAPED, without detonator 0059 0439 0440 0441 1 1 1 1 CASES, CARTRIDGE, EMPTY, WITH PRIMER 0055 0379 1 1 CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER 0446 0447 1 1 CHARGES, SUPPLEMENTARY, EXPLOSIVE 0060 1 Casinghead gasoline, see 1203 3 CHEMICAL KIT 3316 9 CASTOR BEANS 2969 9 CHEMICAL SAMPLE, TOXIC 3315 6.1 CASTOR FLAKE 2969 9 CHEMICAL UNDER PRESSURE, N.O.S. 3500 2 CASTOR MEAL 2969 9 CASTOR POMACE 2969 9 CHEMICAL UNDER PRESSURE, CORROSIVE, N.O.S. 3503 2 CAUSTIC ALKALI LIQUID, N.O.S. 1719 8 CHEMICAL UNDER PRESSURE, FLAMMABLE, N.O.S. 3501 2 Caustic potash, see 1814 8 3505 2 Caustic soda, see 1824 8 CHEMICAL UNDER PRESSURE, FLAMMABLE, CORROSIVE, N.O.S. Caustic soda liquor, see 1824 8 2 3292 4.3 CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S. 3504 CELLS, CONTAINING SODIUM CELLULOID in block, rods, rolls, sheets, tubes, etc., except scrap 2000 4.1 CHEMICAL UNDER PRESSURE, TOXIC, N.O.S. 3502 2 CELLULOID, SCRAP 2002 4.2 Chile saltpetre, see 1498 5.1 Cement, see 1133 3 2075 6.1 CERIUM, slabs, ingots or rods 1333 4.1 CHLORAL, ANHYDROUS, STABILIZED CERIUM, turnings or gritty powder 3078 4.3 CHLORATE AND BORATE MIXTURE 1458 5.1 Cer mishmetall, see 1323 4.1 5.1 1362 4.1 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 1459 Charcoal, activated, see Charcoal, non-activated, see 1361 4.2 3407 5.1 CHARGES, BURSTING, PLASTICS BONDED 0457 0458 0459 0460 1 1 1 1 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLUTION CHLORATES, INORGANIC, N.O.S. 1461 5.1 CHARGES, DEMOLITION 0048 1 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3210 5.1 CHARGES, DEPTH 0056 1 CHLORIC ACID, AQUEOUS SOLUTION with not more than 10% chloric acid 2626 5.1 CARTRIDGES, SIGNAL - 529 - CHLORINE 1017 2 CHLORODINITROBENZENES, SOLID 3441 6.1 CHLORINE, ADSORBED 3520 2 CHLORINE PENTAFLUORIDE 2548 2 2-CHLOROETHANAL 2232 6.1 CHLORINE TRIFLUORIDE 1749 2 Chloroethane, see 1037 2 CHLORITES, INORGANIC, N.O.S. 1462 5.1 Chloroethane nitrile, see 2668 6.1 CHLORITE SOLUTION 1908 8 2-Chloroethanol, see 1135 6.1 Chloroacetaldehyde, see 2232 6.1 CHLOROFORM 1888 6.1 CHLOROACETIC ACID, MOLTEN 3250 6.1 CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. 3277 6.1 CHLOROACETIC ACID, SOLID 1751 6.1 CHLOROACETIC ACID SOLUTION 1750 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 2742 6.1 6.1 CHLOROACETONE, STABILIZED 1695 6.1 Chloromethane, see 1063 2 CHLOROACETONITRILE 2668 6.1 1-Chloro-3-methylbutane, see 1107 3 CHLOROACETOPHENONE, LIQUID 3416 6.1 2-Chloro-2-methylbutane, see 1107 3 6.1 1697 6.1 CHLOROMETHYL CHLOROFORMATE 2745 CHLOROACETOPHENONE, SOLID Chloromethyl cyanide, see 2668 6.1 CHLOROACETYL CHLORIDE 1752 6.1 3 2019 6.1 CHLOROMETHYL ETHYL ETHER 2354 CHLOROANILINES, LIQUID CHLOROANILINES, SOLID 2018 6.1 Chloromethyl methyl ether, see 1239 6.1 CHLOROANISIDINES 2233 6.1 2236 6.1 CHLOROBENZENE 1134 3 3-CHLORO-4-METHYLPHENYL ISOCYANATE, LIQUID CHLOROBENZO-TRIFLUORIDES 2234 3 3-CHLORO-4-METHYLPHENYL ISOCYANATE, SOLID 3428 6.1 CHLOROBENZYL CHLORIDES, LIQUID 2235 6.1 3-Chloro-2-methylprop-1-ene, see 2554 3 CHLOROBENZYL CHLORIDES, SOLID 3427 6.1 CHLORONITROANILINES 2237 6.1 3409 6.1 1-Chloro-3-bromopropane, see 2688 6.1 CHLORONITROBENZENES LIQUID 1-Chlorobutane, see 1127 3 CHLORONITROBENZENES SOLID 1578 6.1 2-Chlorobutane, see 1127 3 6.1 1127 3 CHLORONITROTOLUENES, LIQUID 2433 CHLOROBUTANES CHLOROCRESOLS, SOLUTION 2669 6.1 3457 6.1 CHLOROCRESOLS, SOLID 3437 6.1 CHLORONITROTOLUENES, SOLID CHLORODIFLUOROBROMOMETHANE 1974 2 CHLOROPENTAFLUOROETHANE 1020 2 1-CHLORO-1,1-DIFLUOROETHANE 2517 2 CHLOROPHENOLATES, LIQUID 2904 8 CHLOROPHENOLATES, SOLID 2905 8 CHLORODIFLUOROMETHANE 1018 2 CHLOROPHENOLS, LIQUID 2021 6.1 CHLORODIFLUOROMETHANE 1973 AND CHLOROPENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane 2 CHLOROPHENOLS, SOLID 2020 6.1 CHLOROPHENYLTRICHLOROSILANE 1753 8 CHLOROPICRIN 1580 6.1 3-Chloro-1,2-dihydroxypropane, see 2689 6.1 1581 2 Chlorodimethyl ether, see 1239 6.1 CHLOROPICRIN AND METHYL BROMIDE MIXTURE, with more than 2% chloropicrin CHLORODINITROBENZENES, LIQUID 1577 6.1 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE 1582 2 - 530 - CHLOROPICRIN MIXTURE, N.O.S. 1583 6.1 CHROMIC ACID SOLUTION 1755 8 CHLOROPLATINIC ACID, SOLID 2507 8 Chromic anhydride, solid, see 1463 5.1 CHLOROPRENE, STABILIZED 1991 3 CHROMIC FLUORIDE, SOLID 1756 8 1-CHLOROPROPANE 1278 3 CHROMIC FLUORIDE SOLUTION 1757 8 2-CHLOROPROPANE 2356 3 Chromic nitrate, see 2720 5.1 3-Chloro-propanediol-1,2, see 2689 Chromium (VI) dichloride dioxide, see 1758 8 6.1 3-CHLOROPROPANOL-1 2849 6.1 Chromium (III) fluoride, solid, see 1756 8 2-CHLOROPROPENE 2456 3 CHROMIUM NITRATE 2720 5.1 3-Chloropropene, see 1100 3 Chromium (III) nitrate, see 2720 5.1 3-Chloroprop-1-ene, see 1100 3 CHROMIUM OXYCHLORIDE 1758 8 CHROMIUM TRIOXIDE, ANHYDROUS 1463 5.1 CHROMOSULPHURIC ACID 2240 8 Chrysotile, see 2590 9 Cinene, see 2052 3 Cinnamene, see 2055 3 Cinnamol, see 2055 3 CLINICAL WASTE, UNSPECIFIED, N.O.S. 3291 6.2 COAL GAS, COMPRESSED 1023 2 COAL TAR DISTILLATES, FLAMMABLE 1136 3 Coal tar naphtha, see 1268 3 Coal tar oil, see 1136 3 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) 1139 3 2-CHLOROPROPIONIC ACID 2511 8 2-CHLOROPYRIDINE 2822 6.1 CHLOROSILANES, CORROSIVE, N.O.S. 2987 8 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. 2986 8 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. 2985 3 CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. 3361 6.1 CHLOROSILANES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 3362 6.1 CHLOROSILANES, WATERREACTIVE, FLAMMABLE, CORROSIVE, N.O.S. 2988 4.3 CHLOROSULPHONIC ACID (with or without sulphur trioxide) 1754 8 1-CHLORO-1,2,2,2-TETRAFLUOROETHANE 1021 2 COBALT NAPHTHENATES, POWDER 2001 4.1 CHLOROTOLUENES 2238 3 1318 4.1 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLID 1579 6.1 COBALT RESINATE, PRECIPITATED Cocculus, see 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLUTION 3410 3172 3462 6.1 6.1 Collodion cottons, see CHLOROTOLUIDINES LIQUID 3429 6.1 CHLOROTOLUIDINES SOLID 3429 6.1 1-CHLORO-2,2,2-TRIFLUOROETHANE 1983 2 0340 0341 0342 2059 2555 2556 2557 1 1 1 3 4.1 4.1 4.1 Chlorotrifluoroethylene, see 1082 2 CHLOROTRIFLUOROMETHANE 1022 2 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. CHLOROTRIFLUOROMETHANE AND TRIFLUOROMETHANE AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane 2599 2 0382 0383 0384 0461 1 1 1 1 Composition B, see 0118 1 COMPRESSED GAS, N.O.S. 1956 2 Chromic acid, solid, see 1463 COMPRESSED GAS, FLAMMABLE, N.O.S. 1954 2 6.1 5.1 - 531 - COMPRESSED GAS, OXIDIZING, N.O.S. 3156 2 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. 3265 8 COMPRESSED GAS, TOXIC, N.O.S. 1955 2 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. 3266 8 COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. 3304 2 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. 3267 8 COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. 1953 2 CORROSIVE LIQUID, FLAMMABLE, N.O.S. 2920 8 COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 3305 2 CORROSIVE LIQUID, OXIDIZING, N.O.S. 3093 8 8 3303 2 CORROSIVE LIQUID, SELFHEATING, N.O.S. 3301 COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. 8 2 CORROSIVE LIQUID, TOXIC, N.O.S. 2922 COMPRESSED GAS, TOXIC, 3306 OXIDIZING, CORROSIVE, N.O.S. 8 0248 0249 1 1 CORROSIVE LIQUID, WATERREACTIVE, N.O.S. 3094 CONTRIVANCES, WATERACTIVATED with burster, expelling charge or propelling charge CORROSIVE SOLID, N.O.S. 1759 8 8 1585 6.1 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 3260 COPPER ACETOARSENITE COPPER ARSENITE 1586 6.1 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 3261 8 Copper (II) arsenite, see 1586 6.1 8 2776 3 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. 3262 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 3263 8 COPPER BASED PESTICIDE, LIQUID, TOXIC 3010 6.1 CORROSIVE SOLID, FLAMMABLE, N.O.S. 2921 8 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3009 6.1 CORROSIVE SOLID, OXIDIZING, N.O.S. 3084 8 COPPER BASED PESTICIDE, SOLID, TOXIC 2775 6.1 CORROSIVE SOLID, SELFHEATING, N.O.S. 3095 8 COPPER CHLORATE 2721 5.1 CORROSIVE SOLID, TOXIC, N.O.S. 2923 8 Copper (II) chlorate, see 2721 5.1 8 2802 8 CORROSIVE SOLID, WATERREACTIVE, N.O.S. 3096 COPPER CHLORIDE COPPER CYANIDE 1587 6.1 COTTON WASTE, OILY 1364 4.2 Copper selenate, see 2630 6.1 COTTON, WET 1365 4.2 Copper selenite, see 2630 6.1 3024 3 COPRA 1363 4.2 CORD, DETONATING, flexible 0065 0289 1 1 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 °C 6.1 0102 0290 1 1 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 3026 CORD, DETONATING, metal clad 6.1 0104 1 CORD, IGNITER 0066 1 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3025 CORD, DETONATING, MILD EFFECT, metal clad Cordite, see 0160 0161 1 1 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 3027 6.1 CORROSIVE LIQUID, N.O.S. 1760 8 Creosote, see 2810 6.1 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. 3264 8 Creosote salts, see 1334 4.1 CRESOLS, LIQUID 2076 6.1 - 532 - CRESOLS, SOLID 3455 6.1 CYCLOHEXANE 1145 3 CRESYLIC ACID 2022 6.1 Cyclehexanethiol, see 3054 3 Crocidolite, see 2212 9 CYCLOHEXANONE 1915 3 CROTONALDEHYDE or CROTONALDEHYDE, STABILIZED 1143 6.1 CYCLOHEXENE 2256 3 CYCLOHEXENYLTRICHLOROSILANE 1762 8 CROTONIC ACID, LIQUID 3472 8 CYCLOHEXYL ACETATE 2243 3 CROTONIC ACID, SOLID 2823 8 CYCLOHEXYLAMINE 2357 8 Crotonic aldehyde / Crotonic aldehyde, stabilized, see 1143 6.1 CYCLOHEXYL ISOCYANATE 2488 6.1 CROTONYLENE 1144 3 CYCLOHEXYL MERCAPTAN 3054 3 Crude naphtha, see 1268 3 CYCLOHEXYLTRICHLOROSILANE 1763 8 Cumene, see 1918 3 2721 5.1 CUPRIETHYLENEDIAMINE SOLUTION 1761 8 Cutback bitumen, with a flash-point not greater than 60 °C, see 1999 3 CYCLONITE AND 0391 CYCLOTETRAMETHYLENETETRANITRAMINE MIXTURE, WETTED with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegmatiser by mass, see 1 Cupric chlorate, see Cutback bitumen, with a flash-point above 60 °C, at or above its flashpoint, see 3256 3 Cutback bitumen, at or above 100 °C and below its flash-point, see 3257 9 CYCLONITE, DESENSITIZED, see 0483 1 0072 1 CUTTERS, CABLE, EXPLOSIVE 0070 1 CYCLONITE, WETTED with not less than 15% water, by mass, see CYANIDE SOLUTION, N.O.S. 1935 6.1 CYCLOOCTADIENES 2520 3 CYANIDES, INORGANIC, SOLID, N.O.S. 1588 6.1 CYCLOOCTADIENE PHOSPHINES, see 2940 4.2 Cyanides, organic, flammable, toxic, n.o.s., see 3273 3 CYCLOOCTATETRAENE 2358 3 CYCLOPENTANE 1146 3 Cyanides, organic, toxic, n.o.s., see 3276 3439 6.1 CYCLOPENTANOL 2244 3 CYCLOPENTANONE 2245 3 Cyanides, organic, toxic, flammable, n.o.s., see 3275 6.1 CYCLOPENTENE 2246 3 Cyanoacetonitrile, see 2647 6.1 CYCLOPROPANE 1027 2 CYANOGEN 1026 2 0484 1 CYANOGEN BROMIDE 1889 6.1 CYCLOTETRAMETHYLENETETRANITRAMINE, DESENSITIZED CYANOGEN CHLORIDE, STABILIZED 1589 2 0226 1 CYANURIC CHLORIDE 2670 8 CYCLOTETRAMETHYLENETETRANITRAMINE, WETTED with not less than 15% water, by mass CYCLOBUTANE 2601 2 1 2744 6.1 1,5,9-CYCLODODECATRIENE 2518 6.1 CYCLOHEPTANE 2241 3 CYCLOTRIMETHYLENETRINITRAMINE AND CYCLOTETRAMETHYLENETETRANITRAMINE MIXTURE, DESENSITIZED with not less than 10% phlegmatiser by mass 0391 CYCLOBUTYL CHLOROFORMATE CYCLOHEPTATRIENE 2603 3 0391 1 1,3,5-Cycloheptatriene, see 2603 3 CYCLOHEPTENE 2242 3 1,4-Cyclohexadienedione, see 2587 6.1 CYCLOTRIMETHYLENETRINITRAMINE AND CYCLOTETRAMETHYLENETETRANITRAMINE MIXTURE, WETTED with not less than 15% water, by mass - 533 - CYCLOTRIMETHYLENETRINITRAMINE, DESENSITIZED 0483 1 CYCLOTRIMETHYLENETRINITRAMINE, WETTED with not less than 15% water, by mass 0072 CYMENES 2046 3 Cymol, see 2046 3 Deanol, see 2051 8 Dangerous goods in machinery or dangerous goods in apparatus 3363 9 1 Not subject to ADR [see also 1.1.3.1 (b)] 1,2-Diaminoethane, see 1604 8 Diaminopropylamine, see 2269 8 DI-n-AMYLAMINE 2841 3 DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass 0074 1 Dibenzopyridine, see 2713 6.1 DIBENZYLDICHLORO-SILANE 2434 8 DIBORANE 1911 2 1,2-DIBROMOBUTAN-3-ONE 2648 6.1 DIBROMOCHLOROPROPANES 2872 6.1 1,2-Dibromo-3-chloropropane, see 2872 6.1 DIBROMODIFLUOROMETHANE 1941 9 DIBROMOMETHANE 2664 6.1 DI-n-BUTYLAMINE 2248 8 DIBUTYLAMINOETHANOL 2873 6.1 2-Dibutylaminoethanol, see 2873 6.1 N,N-Di-n-butylaminoethanol, see 2873 6.1 DIBUTYL ETHERS 1149 3 DICHLOROACETIC ACID 1764 8 DECABORANE 1868 4.1 DECAHYDRONAPHTHALENE 1147 3 Decalin, see 1147 3 n-DECANE 2247 3 DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES, N.O.S. 0132 1 Depth charge, see 0056 1 DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. 3379 3 DESENSITIZED EXPLOSIVE, SOLID, N.O.S. 3380 4.1 1,3-DICHLOROACETONE 2649 6.1 Detonating relays, see 0029 0267 0360 0361 0455 0500 1 1 1 1 1 1 DICHLOROACETYL CHLORIDE 1765 8 DICHLOROANILINES, LIQUID 1590 6.1 DICHLOROANILINES, SOLID 3442 6.1 o-DICHLOROBENZENE 1591 6.1 DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting 0360 0361 0500 1 1 1 2,2'-DICHLORODIETHYL ETHER 1916 6.1 DICHLORODIFLUOROMETHANE 1028 2 DETONATORS FOR AMMUNITION 0073 0364 0365 0366 1 1 1 1 2602 2 DETONATORS, ELECTRIC for blasting 0030 0255 0456 1 1 1 DICHLORODIFLUOROMETHANE AND DIFLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane Dichlorodifluoromethane and ethylene oxide mixture, see 3070 2 DETONATORS, NON-ELECTRIC for blasting 0029 0267 0455 1 1 1 DICHLORODIMETHYL ETHER, SYMMETRICAL 2249 6.1 DEUTERIUM, COMPRESSED 1957 2 1,1-DICHLOROETHANE 2362 3 DEVICES, SMALL, HYDROCARBON GAS POWERED with release device 3150 2 1,2-Dichloroethane, see 1184 3 1,2-DICHLOROETHYLENE 1150 3 Di(2-chloroethyl) ether, see 1916 6.1 DIACETONE ALCOHOL 1148 3 DICHLOROFLUOROMETHANE 1029 2 DIALLYLAMINE 2359 3 alpha-Dichlorohydrin, see 2750 6.1 DIALLYL ETHER 2360 3 5.1 2651 6.1 DICHLOROISOCYANURIC ACID, DRY 2465 4,4'-DIAMINODIPHENYLMETHANE - 534 - Carriage prohibited DICHLOROISOCYANURIC ACID SALTS 2465 5.1 0075 1 6.1 DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile, water-insoluble phlegmatizer, by mass DICHLOROISOPROPYL ETHER 2490 6.1 DICHLOROMETHANE 1593 1,1-DICHLORO-1-NITROETHANE 2650 6.1 DIETHYLENETRIAMINE 2079 8 DICHLOROPENTANES 1152 3 N,N-Diethylethanolamine, see 2686 3 DIETHYL ETHER 1155 3 Dichlorophenol, see 2020 2021 6.1 6.1 N,N-DIETHYLETHYLENEDIAMINE 2685 8 DICHLOROPHENYL ISOCYANATES 2250 6.1 Di-(2-ethylhexyl) phosphoric acid, see 1902 8 DICHLOROPHENYLTRICHLOROSILANE 1766 8 DIETHYL KETONE 1156 3 1,2-DICHLOROPROPANE 1279 3 DIETHYL SULPHATE 1594 6.1 1,3-DICHLOROPROPANOL-2 2750 6.1 DIETHYL SULPHIDE 2375 3 1,3-Dichloro-2-propanone, see 2649 6.1 DIETHYLTHIOPHOSPHORYL CHLORIDE 2751 8 DICHLOROPROPENES 2047 3 Diethylzinc, see 3394 4.2 DICHLOROSILANE 2189 2 2,4-Difluoroaniline, see 2941 6.1 1,2-DICHLORO-1,1,2,2TETRAFLUOROETHANE 1958 2 Difluorochloroethane, see 2517 2 Dichloro-s-triazine-2,4,6-trione, see 2465 5.1 1,1-DIFLUOROETHANE 1030 2 1,4-Dicyanobutane, see 2205 6.1 1,1-DIFLUOROETHYLENE 1959 2 Dicycloheptadiene, see 2251 3 DIFLUOROMETHANE 3252 2 DICYCLOHEXYLAMINE 2565 8 3339 2 Dicyclohexylamine nitrite, see 2687 4.1 DICYCLOHEXYL-AMMONIUM NITRITE 2687 4.1 Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 10% difluoromethane and 70% pentafluoroethane, see DICYCLOPENTADIENE 2048 3 2 2372 3 DIDYMIUM NITRATE 1465 5.1 DIESEL FUEL 1202 3 Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 20% difluoromethane and 40% pentafluoroethane, see 3338 1,2-DI-(DIMETHYLAMINO) ETHANE 1,1-Diethoxyethane, see 1088 3 3340 2 1,2-Diethoxyethane, see 1153 3 DIETHOXYMETHANE 2373 3 Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 23%difluoromethane and 25% pentafluoroethane, see 3,3-DIETHOXYPROPENE 2374 3 8 1154 3 DIFLUOROPHOSPHORIC ACID, ANHYDROUS 1768 DIETHYLAMINE 2-DIETHYLAMINOETHANOL 2686 8 2,3-DIHYDROPYRAN 2376 3 3-DIETHYLAMINOPROPYLAMINE 2684 3 DIISOBUTYLAMINE 2361 3 3 2432 6.1 DIISOBUTYLENE, ISOMERIC COMPOUNDS 2050 N,N-DIETHYLANILINE DIETHYLBENZENE 2049 3 alpha-Diisobutylene, see 2050 3 Diethylcarbinol, see 1105 3 beta-Diisobutylene, see 2050 3 DIETHYL CARBONATE 2366 3 DIISOBUTYL KETONE 1157 3 DIETHYLDICHLOROSILANE 1767 8 DIISOOCTYL ACID PHOSPHATE 1902 8 Diethylenediamine, see 2579 8 DIISOPROPYLAMINE 1158 3 DIISOPROPYL ETHER 1159 3 - 535 - DIKETENE, STABILIZED 2521 6.1 DINITROANILINES 1596 6.1 1,1-DIMETHOXYETHANE 2377 3 DINITROBENZENES, LIQUID 1597 6.1 1,2-DIMETHOXYETHANE 2252 3 DINITROBENZENES, SOLID 3443 6.1 Dimethoxystrychnine, see 1570 6.1 Dinitrochlorobenzene, see DIMETHYLAMINE, ANHYDROUS 1032 2 1577 3441 6.1 6.1 DINITRO-o-CRESOL 1598 6.1 DIMETHYLAMINE AQUEOUS SOLUTION 1160 3 DINITROGEN TETROXIDE 1067 2 DINITROGLYCOLURIL 0489 1 2-DIMETHYLAMINOACETONITRILE 2378 3 DINITROPHENOL, dry or wetted with less than 15% water, by mass 0076 1 2-DIMETHYLAMINOETHANOL 2051 8 DINITROPHENOL SOLUTION 1599 6.1 2-DIMETHYLAMINOETHYL ACRYLATE 3302 6.1 DINITROPHENOL, WETTED with not less than 15% water, by mass 1320 4.1 2-DIMETHYLAMINOETHYL METHACRYLATE 2522 6.1 0077 1 N,N-DIMETHYLANILINE 2253 6.1 DINITROPHENOLATES, alkali metals, dry or wetted with less than 15% water, by mass Dimethylarsenic acid, see 1572 6.1 1321 4.1 N,N-Dimethylbenzylamine, see 2619 8 DINITROPHENOLATES, WETTED with not less than 15% water, by mass 2,3-DIMETHYLBUTANE 2457 3 1 2379 3 DIMETHYLCARBAMOYL CHLORIDE 2262 8 DINITRORESORCINOL, dry or wetted with less than 15% water, by mass 0078 1,3-DIMETHYLBUTYLAMINE 1322 4.1 DIMETHYL CARBONATE 1161 3 DINITRORESORCINOL, WETTED with not less than 15% water, by mass DIMETHYLCYCLOHEXANES 2263 3 DINITROSOBENZENE 0406 1 N,N-DIMETHYLCYCLOHEXYLAMINE 2264 8 Dinitrotoluene mixed with sodium chlorate, see 0083 1 DIMETHYLDICHLOROSILANE 1162 3 DINITROTOLUENES, LIQUID 2038 6.1 DIMETHYLDIETHOXYSILANE 2380 3 DINITROTOLUENES, MOLTEN 1600 6.1 DIMETHYLDIOXANES 2707 3 DINITROTOLUENES, SOLID 3454 6.1 DIMETHYL DISULPHIDE 2381 3 DIOXANE 1165 3 Dimethylethanolamine, see 2051 8 DIOXOLANE 1166 3 DIMETHYL ETHER 1033 2 DIPENTENE 2052 3 N,N-DIMETHYLFORMAMIDE 2265 3 6.1 2382 6.1 DIPHENYLAMINE CHLOROARSINE 1698 DIMETHYLHYDRAZINE, SYMMETRICAL 6.1 1163 6.1 DIPHENYLCHLOROARSINE, LIQUID 1699 DIMETHYLHYDRAZINE, UNSYMMETRICAL 6.1 1163 6.1 DIPHENYLCHLOROARSINE, SOLID 3450 1,1-Dimethylhydrazine, see N,N-Dimethyl-4-nitrosoaniline, see 1369 4.2 DIPHENYLDICHLOROSILANE 1769 8 2,2-DIMETHYLPROPANE 2044 2 DIPHENYLMETHYL BROMIDE 1770 8 DIMETHYL-N-PROPYLAMINE 2266 3 DIPICRYLAMINE, see 0079 1 DIMETHYL SULPHATE 1595 6.1 0401 1 DIMETHYL SULPHIDE 1164 3 DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass DIMETHYL THIOPHOSPHORYL CHLORIDE 2267 6.1 2852 4.1 Dimethylzinc, see 3394 4.2 DIPICRYL SULPHIDE, WETTED with not less than 10% water, by mass DINGU, see 0489 1 DIPROPYLAMINE 2383 3 - 536 - Dipropylene triamine, see 2269 8 DI-n-PROPYL ETHER 2384 3 DIPROPYL KETONE 2710 3 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 1903 8 DISINFECTANT, LIQUID, TOXIC, N.O.S. 3142 6.1 DISINFECTANT, SOLID, TOXIC, N.O.S. 1601 6.1 DISODIUM TRIOXOSILICATE 3253 8 DIVINYL ETHER, STABILIZED 1167 3 DODECYLTRICHLOROSILANE 1771 8 Dry ice, see 1845 9 DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. 2801 8 DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 1602 6.1 DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 3147 8 DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 3143 6.1 DYE, LIQUID, CORROSIVE, N.O.S. 2801 DYE, LIQUID, TOXIC, N.O.S. Empty IBC, uncleaned See 4.1.1.11, 5.1.3 and 5.4.1.1.6 Empty large packaging, uncleaned See 4.1.1.11, 5.1.3 and 5.4.1.1.6 Empty MEGC, uncleaned See 4.3.2.4, 5.1.3 and 5.4.1.1.6 Empty packaging, uncleaned See 4.1.1.11, 5.1.3 and 5.4.1.1.6 Empty receptacle, uncleaned See 5.1.3 and 5.4.1.1.6 Empty tank, uncleaned See 4.3.2.4, 5.1.3 and 5.4.1.1.6 Empty vehicle, uncleaned See 5.1.3 and 5.4.1.1.6 Not subject to ADR Enamel, see 1263 3066 3469 3470 3 8 3 8 8 Engine, fuel cell, flammable gas powered 3166 9 Not subject to ADR 1602 6.1 3166 9 DYE, SOLID, CORROSIVE, N.O.S. 3147 8 Engine, fuel cell, flammable liquid powered Not subject to ADR DYE, SOLID, TOXIC, N.O.S. 3143 6.1 Engine, internal combustion 3166 9 Not subject to ADR Dynamite, see 0081 1 Engines, rocket, see Electric storage batteries, see 2794 2795 2800 3028 8 8 8 8 0250 0322 1 1 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 3082 9 Electrolyte (acid or alkaline) for batteries, see 2796 2797 8 8 3077 9 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash-point (including molten metals, molten salts, etc.) 3257 9 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. EPIBROMOHYDRIN 2558 6.1 EPICHLOROHYDRIN 2023 6.1 1,2-Epoxybutane, stabilized, see 3022 3 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flashpoint above 60 °C, at or above its flashpoint and at or above 100 °C 3256 Epoxyethane, see 1040 2 1,2-EPOXY-3-ETHOXYPROPANE 2752 3 2,3-Epoxy-1-propanal, see 2622 3 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flashpoint above 60 °C, at or above its flashpoint and below 100 °C 3256 2,3-Epoxypropyl ethyl ether, see 2752 3 ESTERS, N.O.S. 3272 3 ETHANE 1035 2 ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 °C 3258 ETHANE, REFRIGERATED LIQUID 1961 2 Ethanethiol, see 2363 3 ETHANOL 1170 3 Empty battery-vehicle, uncleaned 3 3 9 See 4.3.2.4, 5.1.3 and 5.4.1.1.6 - 537 - ETHANOL AND GASOLINE MIXTURE or ETHANOL AND MOTOR SPIRIT MIXTURE or ETHANOL AND PETROL MIXTURE, with more than 10% ethanol 3475 ETHANOL SOLUTION 1170 ETHANOLAMINE 3 Ethyl-alpha-chloropropionate, see 2935 3 ETHYL CHLOROTHIOFORMATE 2826 8 ETHYL CROTONATE 1862 3 ETHYLDICHLOROARSINE 1892 6.1 3 ETHYLDICHLOROSILANE 1183 4.3 2491 8 3138 2 ETHANOLAMINE SOLUTION 2491 8 Ether, see 1155 3 ETHERS, N.O.S. 3271 3 ETHYLENE, ACETYLENE AND PROPYLENE MIXTURE, REFRIGERATED LIQUID containing at least 71.5% ethylene with not more than 22.5% acetylene and not more than 6% propylene 2-Ethoxyethanol, see 1171 3 ETHYLENE CHLOROHYDRIN 1135 6.1 2-Ethoxyethyl acetate, see 1172 3 ETHYLENE 1962 2 Ethoxy propane-1, see 2615 3 ETHYLENEDIAMINE 1604 8 ETHYL ACETATE 1173 3 ETHYLENE DIBROMIDE 1605 6.1 ETHYLACETYLENE, STABILIZED 2452 2 Ethylene dibromide and methyl bromide, liquid mixture, see 1647 6.1 ETHYL ACRYLATE, STABILIZED 1917 3 ETHYLENE DICHLORIDE 1184 3 ETHYL ALCOHOL, see 1170 3 1153 3 ETHYL ALCOHOL SOLUTION, see 1170 3 ETHYLENE GLYCOL DIETHYL ETHER 1171 3 ETHYLAMINE 1036 2 ETHYLENE GLYCOL MONOETHYL ETHER ETHYLAMINE, AQUEOUS SOLUTION with not less than 50% but not more than 70% ethylamine 2270 3 ETHYLENE GLYCOL 1172 MONOETHYL ETHER ACETATE 3 1188 3 ETHYL AMYL KETONE 2271 3 ETHYLENE GLYCOL MONOMETHYL ETHER N-ETHYLANILINE 2272 6.1 1189 3 2-ETHYLANILINE 2273 6.1 ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE ETHYLBENZENE 1175 3 ETHYLENEIMINE, STABILIZED 1185 6.1 N-ETHYL-N-BENZYLANILINE 2274 6.1 ETHYLENE OXIDE 1040 2 N-ETHYLBENZYLTOLUIDINES, LIQUID 2753 6.1 3300 2 N-ETHYLBENZYLTOLUIDINES, SOLID 3460 6.1 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxide 1041 2 ETHYL BORATE 1176 3 ETHYL BROMIDE 1891 6.1 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide ETHYL BROMOACETATE 1603 6.1 1952 2 2-ETHYLBUTANOL 2275 3 2-ETHYLBUTYL ACETATE 1177 3 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide ETHYL BUTYL ETHER 1179 3 3297 2 2-ETHYLBUTYRALDEHYDE 1178 3 ETHYL BUTYRATE 1180 3 ETHYLENE OXIDE AND CHLOROTETRAFLUOROETHANE MIXTURE with not more than 8.8% ethylene oxide ETHYL CHLORIDE 1037 2 3070 2 ETHYL CHLOROACETATE 1181 6.1 Ethyl chlorocarbonate, see 1182 6.1 ETHYLENE OXIDE AND DICHLORODIFLUOROMETHANE MIXTURE with not more than 12.5% ethylene oxide ETHYL CHLOROFORMATE 1182 6.1 3298 2 ETHYL 2-CHLOROPROPIONATE 2935 3 ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than 7.9% ethylene oxide - 538 - ETHYLENE OXIDE AND PROPYLENE OXIDE MIXTURE, not more than 30% ethylene oxide 2983 3 Explosive, seismic, see 0081 0082 0083 0331 1 1 1 1 ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more than 5.6% ethylene oxide 3299 2 Explosive, slurry, see 0241 0332 1 1 ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50 °C 1040 Explosive, water gel, see 0241 0332 1 1 EXTRACTS, AROMATIC, LIQUID 1169 3 ETHYLENE, REFRIGERATED LIQUID 1038 2 EXTRACTS, FLAVOURING, LIQUID 1197 3 ETHYL ETHER, see 1155 3 FABRICS, ANIMAL, N.O.S. with oil 1373 4.2 ETHYL FLUORIDE 2453 2 4.1 1190 3 2-ETHYLHEXYLAMINE 2276 3 FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 1353 ETHYL FORMATE 2-ETHYLHEXYL CHLOROFORMATE 2748 6.1 FABRICS, SYNTHETIC, N.O.S. with oil 1373 4.2 Ethylidene chloride, see 2362 3 FABRICS, VEGETABLE, N.O.S. with oil 1373 4.2 ETHYL ISOBUTYRATE 2385 3 FERRIC ARSENATE 1606 6.1 ETHYL ISOCYANATE 2481 6.1 FERRIC ARSENITE 1607 6.1 ETHYL LACTATE 1192 3 8 2363 3 FERRIC CHLORIDE, ANHYDROUS 1773 ETHYL MERCAPTAN ETHYL METHACRYLATE, STABILIZED 2277 3 FERRIC CHLORIDE SOLUTION 2582 8 FERRIC NITRATE 1466 5.1 ETHYL METHYL ETHER 1039 2 FERROCERIUM 1323 4.1 ETHYL METHYL KETONE 1193 3 4.3 1194 3 FERROSILICON with 30% or more but less than 90% silicon 1408 ETHYL NITRITE SOLUTION ETHYL ORTHOFORMATE 2524 3 FERROUS ARSENATE 1608 6.1 ETHYL OXALATE 2525 6.1 2793 4.2 ETHYLPHENYLDICHLOROSILANE 2435 8 FERROUS METAL BORINGS in a form liable to self-heating 4.2 1-ETHYLPIPERIDINE 2386 3 FERROUS METAL CUTTINGS in a 2793 form liable to self-heating ETHYL PROPIONATE 1195 3 FERROUS METAL SHAVINGS in a form liable to self-heating 2793 4.2 ETHYL PROPYL ETHER 2615 3 4.2 1292 3 FERROUS METAL TURNINGS in a form liable to self-heating 2793 Ethyl silicate, see Ethyl sulphate, see 1594 6.1 1043 2 N-ETHYLTOLUIDINES 2754 6.1 FERTILIZER AMMONIATING SOLUTION with free ammonia ETHYLTRICHLOROSILANE 1196 3 Fertilizer with ammonium nitrate, n.o.s., see 2067 5.1 EXPLOSIVE, BLASTING, TYPE A 0081 1 Fibres, animal, burnt wet or damp 1372 4.2 EXPLOSIVE, BLASTING, TYPE B 0082 0331 1 1 FIBRES, ANIMAL, N.O.S. with oil 1373 4.2 EXPLOSIVE, BLASTING, TYPE C 0083 1 1353 4.1 EXPLOSIVE, BLASTING, TYPE D 0084 1 FIBRES IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. EXPLOSIVE, BLASTING, TYPE E 0241 0332 1 1 FIBRES, SYNTHETIC, N.O.S. with oil 1373 4.2 Explosives, emulsion, see 0241 0332 1 1 Fibres, vegetable, burnt wet or damp 1372 4.2 2 - 539 - Not subject to ADR Not subject to ADR Fibres, vegetable, dry 3360 4.1 FIBRES, VEGETABLE, N.O.S. with 1373 oil Films, nitrocellulose base, from which gelatine has been removed; film scrap, see Not subject to ADR FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 3176 4.1 4.2 FLAMMABLE SOLID, OXIDIZING, N.O.S. 3097 4.1 2002 4.2 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 3179 4.1 FILMS, NITROCELLULOSE BASE, gelatin coated, except scrap 1324 4.1 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 2926 4.1 FLARES, AERIAL Filler, liquid, see 1263 3066 3469 3470 3 8 3 8 0093 0403 0404 0420 0421 1 1 1 1 1 FIRE EXTINGUISHER CHARGES, corrosive liquid 1774 8 Flares, aeroplane, see Fire extinguisher charges, expelling, explosive, see 0275 0276 0323 0381 1 1 1 1 0093 0403 0404 0420 0421 1 1 1 1 1 FIRE EXTINGUISHERS with compressed or liquefied gas 1044 2 Flares, highway, Flares, distress, small, Flares, railway or highway, see 0191 0373 1 1 FIRELIGHTERS, SOLID with flammable liquid 2623 4.1 FLARES, SURFACE 0092 0418 0419 1 1 1 FIREWORKS 0333 0334 0335 0336 0337 1 1 1 1 1 Flares, water-activated, see 0248 0249 1 1 FLASH POWDER 0094 0305 1 1 FIRST AID KIT 3316 9 Flue dusts, toxic, see 1562 6.1 Fish meal, stabilized 2216 9 Fluoric acid, see 1790 8 FLUORINE, COMPRESSED 1045 2 FLUOROACETIC ACID 2642 6.1 FLUOROANILINES 2941 6.1 2-Fluoroaniline, see 2941 6.1 FISH MEAL, UNSTABILIZED 1374 4.2 Fish scrap, stabilized, see 2216 9 See 2.2.1.1.7 Not subject to ADR Not subject to ADR FISH SCRAP, UNSTABILIZED, see 1374 4.2 4-Fluoroaniline, see 2941 6.1 Flammable gas in lighters, see 1057 2 o-Fluoroaniline, see 2941 6.1 FLAMMABLE LIQUID, N.O.S. 1993 3 p-Fluoroaniline, see 2941 6.1 FLAMMABLE LIQUID, CORROSIVE, N.O.S. 2924 3 FLUOROBENZENE 2387 3 FLUOROBORIC ACID 1775 8 FLAMMABLE LIQUID, TOXIC, N.O.S. 1992 3 Fluoroethane, see 2453 2 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. 3286 3 Fluoroform, see 1984 2 Fluoromethane, see 2454 2 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. 3180 4.1 FLUOROPHOSPHORIC ACID, ANHYDROUS 1776 8 FLUOROSILICATES, N.O.S. 2856 6.1 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. 2925 4.1 FLUOROSILICIC ACID 1778 8 FLAMMABLE SOLID, INORGANIC, N.O.S. 3178 4.1 FLUOROSULPHONIC ACID 1777 8 FLUOROTOLUENES 2388 3 FLAMMABLE SOLID, ORGANIC, N.O.S. 1325 FORMALDEHYDE SOLUTION with not less than 25% formaldehyde 2209 8 4.1 - 540 - Carriage prohibited FORMALDEHYDE SOLUTION, FLAMMABLE 1198 3 Fuze, combination, percussion or time, see 0106 0107 0257 0316 0317 0367 0368 1 1 1 1 1 1 1 Formalin, see 1198 2209 3 8 Formamidine sulphinic acid, see 3341 4.2 FORMIC ACID with more than 85% acid by mass 1779 8 FUZES, DETONATING 0106 0107 0257 0367 1 1 1 1 FORMIC ACID with not more than 85% acid by mass 3412 8 Formic aldehyde, see 1198 2209 3 8 FUZES, DETONATING with protective features 0408 0409 0410 1 1 1 2-Formyl-3,4-dihydro-2H-pyran, see 2607 3 FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells 0099 1 FUZES, IGNITING 0316 0317 0368 1 1 1 FUEL, AVIATION, TURBINE ENGINE 1863 3 GALLIUM 2803 8 FUEL CELL CARTRIDGES 2 2 2 3 4.3 8 GAS CARTRIDGES without a release device, non-refillable, see 2037 3478 3479 3473 3476 3477 Gas drips, hydrocarbon, see 3295 3 GAS OIL 1202 3 GASOLINE 1203 3 3478 3479 3473 3476 3477 2 2 3 4.3 8 Gasoline and ethanol mixture, with more than 10% ethanol, see 3475 3 Gasoline, casinghead, see 1203 3 2 2 2 3 4.3 8 GAS, REFRIGERATED LIQUID, N.O.S. 3158 3478 3479 3473 3476 3477 GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. 3312 2 3311 2 Fumaroyl dichloride, see 1780 3 GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. FUMARYL CHLORIDE 1780 8 3167 2 FUMIGATED CARGO TRANSPORT UNIT 3359 9 GAS SAMPLE, NONPRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid 2 1199 6.1 FURAN 2389 3 GAS SAMPLE, NONPRESSURIZED, TOXIC, N.O.S., not refrigerated liquid 3169 FURALDEHYDES FURFURYL ALCOHOL 2874 6.1 3168 2 FURFURYLAMINE 2526 3 Furyl carbinol, see 2874 6.1 GAS SAMPLE, NONPRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid FUSE, DETONATING, metal clad 0102 0290 1 1 Gelatin, blasting, see 0081 1 Gelatin, dynamites, see 0081 1 FUSE, DETONATING, MILD EFFECT, metal clad 0104 1 GENETICALLY MODIFIED MICROORGANISMS 3245 9 FUSE, IGNITER, tubular, metal clad 0103 1 3245 9 FUSE, NON-DETONATING 0101 1 GENETICALLY MODIFIED ORGANISMS FUSEL OIL 1201 3 GERMANE 2192 2 FUSE, SAFETY 0105 1 GERMANE, ADSORBED 3523 2 Germanium hydride, see 2192 2 Glycer-1,3-dichlorohydrin, see 2750 6.1 FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT - 541 - GLYCEROL alphaMONOCHLOROHYDRIN 2689 6.1 n-HEPTENE 2278 3 Glyceryl trinitrate, see 0143 0144 1204 3064 1 1 3 3 HEXACHLOROACETONE 2661 6.1 HEXACHLOROBENZENE 2729 6.1 HEXACHLOROBUTADIENE 2279 6.1 GLYCIDALDEHYDE 2622 3 Hexachloro-1,3-butadiene, see 2279 6.1 GRENADES, hand or rifle, with bursting charge 0284 0285 0292 0293 1 1 1 1 HEXACHLOROCYCLOPENTADIENE 2646 6.1 HEXACHLOROPHENE 2875 6.1 Hexachloro-2-propanone, see 2661 6.1 Grenades, illuminating, see 0171 0254 0297 1 1 1 HEXADECYLTRICHLOROSILANE 1781 8 GRENADES, PRACTICE, hand or rifle HEXADIENES 2458 3 0110 0318 0372 0452 1 1 1 1 HEXAETHYL TETRAPHOSPHATE 1611 6.1 Grenades, smoke, see 2 1 1 1 1 1 HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE 1612 0015 0016 0245 0246 0303 HEXAFLUOROACETONE 2420 2 2552 6.1 GUANIDINE NITRATE 1467 5.1 HEXAFLUOROACETONE HYDRATE, LIQUID GUANYLNITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass 0113 1 HEXAFLUOROACETONE HYDRATE, SOLID 3436 6.1 HEXAFLUOROETHANE 2193 2 HEXAFLUOROPHOSPHORIC ACID 1782 8 HEXAFLUOROPROPYLENE 1858 2 Hexahydrocresol, see 2617 3 Hexahydromethyl phenol, see 2617 3 HEXALDEHYDE 1207 3 GUANYLNITROSAMINO0114 GUANYLTETRAZENE, WETTED with not less than 30% water, or mixture of alcohol and water, by mass 1 GUNPOWDER, COMPRESSED, see 0028 1 GUNPOWDER, granular or as a meal, see 0027 1 HEXAMETHYLENEDIAMINE, SOLID 2280 8 GUNPOWDER, IN PELLETS, see 0028 1 HEXAMETHYLENEDIAMINE SOLUTION 1783 8 Gutta percha solution, see 1287 3 6.1 2545 4.2 HEXAMETHYLENE DIISOCYANATE 2281 HAFNIUM POWDER, DRY HAFNIUM POWDER, WETTED with not less than 25% water 1326 4.1 HEXAMETHYLENEIMINE 2493 3 HEXAMETHYLENETETRAMINE 1328 4.1 Hay 1327 4.1 Hexamine, see 1328 4.1 HEATING OIL, LIGHT 1202 3 HEXANES 1208 3 Heavy hydrogen, see 1957 2 HEXANITRODIPHENYLAMINE 0079 1 HELIUM, COMPRESSED 1046 2 HEXANITROSTILBENE 0392 1 HELIUM, REFRIGERATED LIQUID 1963 2 Hexanoic acid, see 2829 8 HEXANOLS 2282 3 HEPTAFLUOROPROPANE 3296 2 1-HEXENE 2370 3 n-HEPTALDEHYDE 3056 3 n-Heptanal, see 3056 3 HEPTANES 1206 3 4-Heptanone, see 2710 3 Not subject to ADR - 542 - HEXOGEN AND 0391 CYCLOTETRAMETHYLENETETRANITRAMINE MIXTURE, WETTED with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegmatiser by mass, see 1 HYDROFLUORIC ACID with more than 60% but not more than 85% hydrogen fluoride 1790 8 HYDROFLUORIC ACID with more than 85% hydrogen fluoride 1790 8 HEXOGEN, DESENSITIZED, see 0483 1 HYDROFLUORIC ACID with not more than 60% hydrogen fluoride 1790 8 HEXOGEN, WETTED with not less than 15% water, by mass, see 0072 1 HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE 1786 8 HEXOLITE, dry or wetted with less than 15% water, by mass 0118 1 Hydrofluoroboric acid, see 1775 8 Hydrofluorosilicic acid, see 1778 8 HEXOTOL, dry or wetted with less than 15% water, by mass, see 0118 1 HYDROGEN AND METHANE MIXTURE, COMPRESSED 2034 2 HEXOTONAL 0393 1 Hydrogen arsenide, see 2188 2 HEXOTONAL, cast, see 0393 1 1048 2 HEXYL, see 0079 1 HYDROGEN BROMIDE, ANHYDROUS HEXYLTRICHLOROSILANE 1784 8 Hydrogen bromide solution, see 1788 8 HMX, see 0391 1 HYDROGEN CHLORIDE, ANHYDROUS 1050 2 HMX, DESENSITIZED, see 0484 1 2 0226 1 HYDROGEN CHLORIDE, REFRIGERATED LIQUID 2186 HMX, WETTED with not less than 15% water, by mass, see HYDROGEN, COMPRESSED 1049 2 HYDRAZINE, ANHYDROUS 2029 8 6.1 2030 8 HYDROGEN CYANIDE, AQUEOUS SOLUTION with not more than 20% hydrogen cyanide, see 1613 HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass HYDRAZINE, AQUEOUS SOLUTION with not more than 37% hydrazine, by mass 3293 6.1 3294 6.1 HYDRAZINE AQUEOUS SOLUTION, FLAMMABLE with more than 37% hydrazine, by mass 3484 8 HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45% hydrogen cyanide 1051 6.1 Hydrides, metal, water-reactive, n.o.s., see 1409 HYDROGEN CYANIDE, STABILIZED containing less than 3% water 1614 6.1 Hydriodic acid, anhydrous, see 2197 2 HYDRIODIC ACID 1787 8 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water and absorbed in a porous inert material HYDROBROMIC ACID 1788 8 1740 8 HYDROCARBON GAS MIXTURE, 1964 COMPRESSED, N.O.S. 2 HYDROGENDIFLUORIDES, SOLID, N.O.S. 3471 8 HYDROCARBON GAS MIXTURE, 1965 LIQUEFIED, N.O.S. such as mixtures A, A01, A02, A0, A1, B1, B2, B or C 2 HYDROGENDIFLUORIDES SOLUTION, N.O.S. HYDROGEN FLUORIDE, ANHYDROUS 1052 8 Hydrogen fluoride solution, see 1790 8 HYDROCARBON GAS REFILLS FOR SMALL DEVICES with release device 3150 2 HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM 3468 2 HYDROCARBONS, LIQUID, N.O.S. 3295 3 HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT 3468 2 HYDROCHLORIC ACID 1789 8 2 1613 6.1 HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT 3468 HYDROCYANIC ACID, AQUEOUS SOLUTION with not more than 20% hydrogen cyanide HYDROGEN IODIDE, ANHYDROUS 2197 2 4.3 - 543 - Carriage prohibited Hydrogen iodide solution, see 1787 8 Indiarubber, see 1287 3 HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE with acid(s), water and not more than 5% peroxyacetic acid, STABILIZED 3149 5.1 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only 2900 6.2 INFECTIOUS SUBSTANCE, AFFECTING HUMANS 2814 6.2 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary) 2984 Ink, printer's, flammable, see 1210 3 INSECTICIDE GAS, N.O.S. 1968 2 INSECTICIDE GAS, FLAMMABLE, N.O.S. 3354 2 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) 2014 INSECTICIDE GAS, TOXIC, N.O.S. 1967 2 INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. 3355 2 IODINE 3495 8 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 60% hydrogen peroxide and not more than 70% hydrogen peroxide 2015 IODINE MONOCHLORIDE, LIQUID 3498 8 IODINE MONOCHLORIDE, SOLID 1792 8 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 70% hydrogen peroxide 2015 IODINE PENTAFLUORIDE 2495 5.1 2-IODOBUTANE 2390 3 Iodomethane, see 2644 6.1 HYDROGEN, REFRIGERATED LIQUID 1966 2 IODOMETHYLPROPANES 2391 3 HYDROGEN SELENIDE, ADSORBED 3526 2 IODOPROPANES 2392 3 alpha-Iodotoluene, see 2653 6.1 HYDROGEN SELENIDE, ANHYDROUS 2202 2 I.p.d.i., see 2290 6.1 Iron chloride, anhydrous, see 1773 8 Hydrogen silicide, see 2203 2 Iron (III) chloride, anhydrous, see 1773 8 HYDROGEN SULPHIDE 1053 2 Hydroselenic acid, see 2202 2 Iron chloride solution, see 2582 8 Hydrosilicofluoric acid, see 1778 8 1376 4.2 1-HYDROXYBENZOTRIAZOLE, ANHYDROUS, dry or wetted with less than 20% water, by mass 0508 1 IRON OXIDE, SPENT obtained from coal gas purification IRON PENTACARBONYL 1994 6.1 Iron perchloride, anhydrous, see 1773 8 1-HYDROXYBENZOTRIAZOLE MONOHYDRATE 3474 4.1 Iron powder, pyrophoric, see 1383 4.2 3-Hydroxybutan-2-one, see 2621 3 Iron sesquichloride, anhydrous, see 1773 8 HYDROXYLAMINE SULPHATE 2865 8 IRON SPONGE, SPENT obtained from coal gas purification 1376 4.2 1-Hydroxy-3-methyl-2-penten-4-yne, 2705 see 8 Iron swarf, see 2793 4.2 3-Hydroxyphenol, see 2876 6.1 ISOBUTANE 1969 2 HYPOCHLORITES, INORGANIC, N.O.S. 3212 5.1 ISOBUTANOL 1212 3 Isobutene, see 1055 2 HYPOCHLORITE SOLUTION 1791 8 ISOBUTYL ACETATE 1213 3 IGNITERS 0121 0314 0315 0325 0454 1 1 1 1 1 ISOBUTYL ACRYLATE, STABILIZED 2527 3 ISOBUTYL ALCOHOL, see 1212 3 ISOBUTYL ALDEHYDE, see 2045 3 2269 8 ISOBUTYLAMINE 1214 3 3,3'-IMINODIPROPYLAMINE 5.1 5.1 5.1 5.1 - 544 - ISOBUTYLENE 1055 2 ISOPROPYL BUTYRATE 2405 3 ISOBUTYL FORMATE 2393 3 Isopropyl chloride, see 2356 3 ISOBUTYL ISOBUTYRATE 2528 3 ISOPROPYL CHLOROACETATE 2947 3 ISOBUTYL ISOCYANATE 2486 6.1 ISOPROPYL CHLOROFORMATE 2407 6.1 ISOBUTYL METHACRYLATE, STABILIZED 2283 3 ISOPROPYL 2-CHLOROPROPIONATE 2934 3 ISOBUTYL PROPIONATE 2394 3 2934 3 ISOBUTYRALDEHYDE 2045 3 Isopropyl-alpha-chloropropionate, see ISOBUTYRIC ACID 2529 3 Isopropyl ether, see 1159 3 ISOBUTYRONITRILE 2284 3 Isopropylethylene, see 2561 3 ISOBUTYRYL CHLORIDE 2395 3 Isopropyl formate, see 1281 3 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. 2478 3 ISOPROPYL ISOBUTYRATE 2406 3 ISOPROPYL ISOCYANATE 2483 6.1 ISOCYANATES, TOXIC, N.O.S. 2206 6.1 Isopropyl mercaptan, see 2402 3 ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. 3080 6.1 ISOPROPYL NITRATE 1222 3 ISOPROPYL PROPIONATE 2409 3 ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. 2478 3 Isolpropyltoluene, see 2046 3 ISOCYANATE SOLUTION, TOXIC, N.O.S. 2206 6.1 Isopropyltoluol, see 2046 3 2907 4.1 ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. 3080 6.1 ISOSORBIDE DINITRATE MIXTURE with not less than 60% lactose, mannose, starch or calcium hydrogen phosphate ISOCYANATOBENZOTRIFLUORIDES 2285 6.1 ISOSORBIDE-5-MONONITRATE 3251 4.1 3-Isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate, see 2290 6.1 Isovaleraldehyde, see 2058 3 Isododecane, see 2286 3 JET PERFORATING GUNS, CHARGED, oil well, without detonator 0124 0494 1 1 ISOHEPTENE 2287 3 Jet tappers, without detonator, see 0059 1 ISOHEXENE 2288 3 KEROSENE 1223 3 Isooctane, see 1262 3 KETONES, LIQUID, N.O.S. 1224 3 ISOOCTENE 1216 3 KRILL MEAL 3497 4.2 Isopentane, see 1265 3 KRYPTON, COMPRESSED 1056 2 ISOPENTENES 2371 3 2 1106 3 KRYPTON, REFRIGERATED LIQUID 1970 Isopentylamine, see Isopentyl nitrite, see 1113 3 Lacquer, see ISOPHORONEDIAMINE 2289 8 ISOPHORONE DIISOCYANATE 2290 6.1 1263 3066 3469 3470 3 8 3 8 ISOPRENE, STABILIZED 1218 3 Lacquer base, liquid, see ISOPROPANOL 1219 3 ISOPROPENYL ACETATE 2403 3 1263 3066 3469 3470 3 8 3 8 ISOPROPENYLBENZENE 2303 3 2557 4.1 ISOPROPYL ACETATE 1220 3 Lacquer base or lacquer chips, nitrocellulose, dry, see ISOPROPYL ACID PHOSPHATE 1793 8 ISOPROPYL ALCOHOL, see 1219 3 Lacquer base or lacquer chips, plastic, wet with alcohol or solvent, see 1263 2059 2555 2556 3 3 4.1 4.1 ISOPROPYLAMINE 1221 3 LEAD ACETATE 1616 6.1 ISOPROPYLBENZENE 1918 3 Lead (II) acetate, see 1616 6.1 - 545 - LEAD ARSENATES 1617 6.1 LIQUEFIED GAS, TOXIC, N.O.S. 3162 2 LEAD ARSENITES 1618 6.1 2 0129 1 LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. 3308 LEAD AZIDE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. 3160 2 Lead chloride, solid, see 2291 6.1 2 2291 6.1 LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 3309 LEAD COMPOUND, SOLUBLE, N.O.S. LEAD CYANIDE 1620 6.1 3307 2 Lead (II) cyanide 1620 6.1 LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. LEAD DIOXIDE 1872 5.1 LIQUEFIED GAS, TOXIC, 3310 OXIDIZING, CORROSIVE, N.O.S. 2 LEAD NITRATE 1469 5.1 Liquefied petroleum gas, see 1075 2 Lead (II) nitrate 1469 5.1 Liquid filler, see LEAD PERCHLORATE, SOLID 1470 5.1 LEAD PERCHLORATE, SOLUTION 3408 5.1 1263 3066 3469 3470 3 8 3 8 Liquid lacquer base, see Lead (II) perchlorate 1470 3408 5.1 5.1 Lead peroxide, see 1872 5.1 1263 3066 3469 3470 3 8 3 8 LEAD PHOSPHITE, DIBASIC 2989 4.1 LITHIUM 1415 4.3 LEAD STYPHNATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0130 1 Lithium alkyls, liquid, see 3394 4.2 Lithium alkyls, solid, see 3393 4.2 LITHIUM ALUMINIUM HYDRIDE 1410 4.3 LEAD SULPHATE with more than 3% free acid 1794 8 LITHIUM ALUMINIUM HYDRIDE, ETHEREAL 1411 4.3 Lead tetraethyl, see 1649 6.1 LITHIUM BOROHYDRIDE 1413 4.3 Lead tetramethyl, see 1649 6.1 LITHIUM FERROSILICON 2830 4.3 LEAD TRINITRORESORCINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass, see 0130 1 LITHIUM HYDRIDE 1414 4.3 LITHIUM HYDRIDE, FUSED SOLID 2805 4.3 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment 3072 LITHIUM HYDROXIDE 2680 8 2679 8 LIFE-SAVING APPLIANCES, SELF-INFLATING 2990 LITHIUM HYDROXIDE SOLUTION LITHIUM HYPOCHLORITE, DRY 1471 5.1 LIGHTER REFILLS containing flammable gas 1057 2 LITHIUM HYPOCHLORITE MIXTURE 1471 5.1 LIGHTERS containing flammable gas 1057 2 Lithium in cartouches, see 1415 4.3 9 0131 1 Limonene, inactive, see 2052 3 LITHIUM ION BATTERIES (including lithium ion polymer batteries) 3480 LIGHTERS, FUSE LIQUEFIED GAS, N.O.S. 3163 2 3481 9 LIQUEFIED GAS, FLAMMABLE, N.O.S. 3161 2 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT (including lithium ion polymer batteries) LIQUEFIED GASES, nonflammable, charged with nitrogen, carbon dioxide or air 1058 2 LITHIUM ION BATTERIES PACKED WITH EQUIPMENT (including lithium ion polymer batteries) 3481 9 LIQUEFIED GAS, OXIDIZING, N.O.S. 3157 2 9 9 - 546 - LITHIUM METAL BATTERIES (including lithium alloy batteries) 3090 9 MAGNESIUM SILICIDE 2624 4.3 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT (including lithium alloy batteries) 3091 9 Magnesium silicofluoride, see 2853 6.1 Magnetized material 2807 9 LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries) 3091 9 MALEIC ANHYDRIDE 2215 8 MALEIC ANHYDRIDE, MOLTEN 2215 8 LITHIUM NITRATE 2722 5.1 Malonic dinitrile, see 2647 6.1 LITHIUM NITRIDE 2806 4.3 Malonodinitrile, see 2647 6.1 LITHIUM PEROXIDE 1472 5.1 MALONONITRILE 2647 6.1 Lithium silicide, see 1417 4.3 MANEB 2210 4.2 LITHIUM SILICON 1417 4.3 MANEB PREPARATION with not less than 60% maneb 2210 4.2 L.n.g., see 1972 2 MANEB PREPARATION, STABILIZED against self-heating 2968 4.3 LONDON PURPLE 1621 6.1 L.p.g., see 1075 2 MANEB, STABILIZED against selfheating 2968 4.3 Lye, see 1823 8 Lythene, see 1268 3 Manganese ethylene-didithiocarbamate, see 2210 4.2 MAGNESIUM in pellets, turnings or ribbons 1869 4.1 Manganese ethylene-1,2dithiocarbamate, see 2210 4.2 Magnesium alkyls, see 3394 4.2 MANGANESE NITRATE 2724 5.1 MAGNESIUM ALLOYS with more than 50% magnesium in pellets, turnings or ribbons 1869 4.1 Manganese (II) nitrate, see 2724 5.1 MANGANESE RESINATE 1330 4.1 MAGNESIUM ALLOYS POWDER 1418 4.3 Manganous nitrate, see 2724 5.1 MAGNESIUM ALUMINIUM PHOSPHIDE 1419 4.3 0133 1 MAGNESIUM ARSENATE 1622 6.1 MANNITOL HEXANITRATE, WETTED with not less than 40% water, or mixture of alcohol and water, by mass Magnesium bisulphite solution, see 2693 8 MATCHES, FUSEE 2254 4.1 4.1 1473 5.1 MATCHES, SAFETY (book, card or strike on box) 1944 MAGNESIUM BROMATE MAGNESIUM CHLORATE 2723 5.1 MATCHES, "STRIKE ANYWHERE" 1331 4.1 Magnesium chloride and chlorate mixture, see 1459 3407 5.1 5.1 MATCHES, WAX "VESTA" 1945 4.1 MAGNESIUM DIAMIDE 2004 4.2 MEDICAL WASTE, N.O.S. 3291 6.2 Magnesium diphenyl, see 3393 4.2 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3248 3 MAGNESIUM FLUOROSILICATE 2853 6.1 MEDICINE, LIQUID, TOXIC, N.O.S. 1851 6.1 MAGNESIUM GRANULES, 2950 COATED, particle size not less than 149 microns 4.3 MEDICINE, SOLID, TOXIC, N.O.S. 3249 6.1 p-Mentha-1,8-diene, see 2052 8 MAGNESIUM HYDRIDE 2010 4.3 3336 3 MAGNESIUM NITRATE 1474 5.1 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. MAGNESIUM PERCHLORATE 1475 5.1 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. 1228 3 MAGNESIUM PEROXIDE 1476 5.1 6.1 2011 4.3 MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. 3071 MAGNESIUM PHOSPHIDE MAGNESIUM POWDER 1418 4.3 3336 3 Magnesium scrap, see 1869 4.1 MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. - 547 - Not subject to ADR MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 1228 MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. 3071 2-Mercaptoethanol, see 2966 2-Mercaptopropionic acid, see 3 MERCURY IODIDE 1638 6.1 MERCURY NUCLEATE 1639 6.1 MERCURY OLEATE 1640 6.1 MERCURY OXIDE 1641 6.1 MERCURY OXYCYANIDE, DESENSITIZED 1642 6.1 6.1 2936 6.1 MERCURY POTASSIUM IODIDE 1643 6.1 5-MERCAPTOTETRAZOL-1ACETIC ACID 0448 1 MERCURY SALICYLATE 1644 6.1 MERCURY SULPHATE 1645 6.1 MERCURIC ARSENATE 1623 6.1 MERCURY THIOCYANATE 1646 6.1 MERCURIC CHLORIDE 1624 6.1 Mesitylene, see 2325 3 MERCURIC NITRATE 1625 6.1 MESITYL OXIDE 1229 3 MERCURIC POTASSIUM CYANIDE 1626 6.1 3394 4.2 Mercuric sulphate, see 1645 6.1 Metal alkyl halides, water-reactive, n.o.s. / Metal aryl halides, waterreactive, n.o.s., see Mercurol, see 1639 6.1 4.2 1645 6.1 Metal alkyl hydrides, water-reactive, n.o.s. / Metal aryl hydrides, waterreactive, n.o.s., see 3394 Mercurous bisulphate, see Mercurous chloride, see 2025 6.1 4.2 1627 6.1 Mercurous sulphate, see 1645 6.1 Metal alkyls, water-reactive, n.o.s. / Metal aryls, water-reactive, n.o.s., see 3393 MERCUROUS NITRATE MERCURY 2809 8 METAL CARBONYLS, LIQUID, N.O.S. 3281 6.1 MERCURY ACETATE 1629 6.1 6.1 1630 6.1 METAL CARBONYLS, SOLID, N.O.S. 3466 MERCURY AMMONIUM CHLORIDE METAL CATALYST, DRY 2881 4.2 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2778 3 METAL CATALYST, WETTED with a visible excess of liquid 1378 4.2 MERCURY BASED PESTICIDE, LIQUID, TOXIC 3012 6.1 METALDEHYDE 1332 4.1 3182 4.1 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3011 METAL HYDRIDES, FLAMMABLE, N.O.S. METAL HYDRIDES, WATERREACTIVE, N.O.S. 1409 4.3 MERCURY BASED PESTICIDE, SOLID, TOXIC 2777 6.1 METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. 3208 4.3 MERCURY BENZOATE 1631 6.1 3209 4.3 Mercury bichloride, see 1624 6.1 METALLIC SUBSTANCE, WATER-REACTIVE, SELFHEATING, N.O.S. MERCURY BROMIDES 6.1 6.1 1634 6.1 4.1 6.1 METAL POWDER, FLAMMABLE, N.O.S. 3089 MERCURY COMPOUND, LIQUID, 2024 N.O.S. 4.2 2025 6.1 METAL POWDER, SELFHEATING, N.O.S. 3189 MERCURY COMPOUND, SOLID, N.O.S. 4.1 3506 8 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. 3181 MERCURY CONTAINED IN MANUFACTURED ARTICLES MERCURY CYANIDE 1636 6.1 2396 3 MERCURY FULMINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0135 1 METHACRYLALDEHYDE, STABILIZED METHACRYLIC ACID, STABILIZED 2531 8 6.1 1637 METHACRYLONITRILE, STABILIZED 3079 MERCURY GLUCONATE 6.1 - 548 - METHALLYL ALCOHOL 2614 3 Methyl bromide and chloropicrin mixture, with more than 2% chloropicrin, see 1581 2 Methanal, see 1198 2209 3 8 Methane and hydrogen mixture, see 2034 2 1647 6.1 2 METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID METHANE, COMPRESSED 1971 METHANE, REFRIGERATED LIQUID 1972 2 METHYL BROMOACETATE 2643 6.1 2-METHYLBUTANAL 3371 3 METHANESULPHONYL CHLORIDE 3246 6.1 3-METHYLBUTAN-2-ONE 2397 3 METHANOL 1230 3 2-METHYL-1-BUTENE 2459 3 2-Methoxyethyl acetate, see 1189 3 2-METHYL-2-BUTENE 2460 3 METHOXYMETHYL ISOCYANATE 2605 6.1 3-METHYL-1-BUTENE 2561 3 N-METHYLBUTYLAMINE 2945 3 4-METHOXY-4METHYLPENTAN-2-ONE 2293 3 METHYL tert-BUTYL ETHER 2398 3 METHYL BUTYRATE 1237 3 1-Methoxy-2-nitrobenzene, see 2730 3458 6.1 6.1 METHYL CHLORIDE 1063 2 1-Methoxy-3-nitrobenzene, see 2730 3458 6.1 6.1 Methyl chloride and chloropicrin mixture, see 1582 2 1-Methoxy-4-nitrobenzene, see 2730 3458 6.1 6.1 METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE 1912 2 1-METHOXY-2-PROPANOL 3092 3 METHYL CHLOROACETATE 2295 6.1 METHYL ACETATE 1231 3 Methyl chlorocarbonate, see 1238 6.1 METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED such as mixture P1 or mixture P2 1060 2 Methyl chloroform, see 2831 6.1 METHYL CHLOROFORMATE 1238 6.1 6.1 1143 6.1 METHYL CHLOROMETHYL ETHER 1239 beta-Methyl acrolein, see METHYL ACRYLATE, STABILIZED 1919 3 METHYL 2-CHLOROPROPIONATE 2933 3 METHYLAL 1234 3 Methyl alpha-chloropropionate, see 2933 3 Methyl alcohol, see 1230 3 METHYLCHLOROSILANE 2534 2 Methyl allyl alcohol, see 2614 3 Methyl cyanide, see 1648 3 METHYLALLYL CHLORIDE 2554 3 METHYLCYCLOHEXANE 2296 3 METHYLAMINE, ANHYDROUS 1061 2 2617 3 METHYLAMINE, AQUEOUS SOLUTION 1235 3 METHYLCYCLOHEXANOLS, flammable METHYLCYCLOHEXANONE 2297 3 METHYLAMYL ACETATE 1233 3 METHYLCYCLOPENTANE 2298 3 Methyl amyl alcohol, see 2053 3 METHYL DICHLOROACETATE 2299 6.1 Methyl amyl ketone, see 1110 3 METHYLDICHLOROSILANE 1242 4.3 N-METHYLANILINE 2294 6.1 Methylene bromide, see 2664 6.1 Methylated spirit, see 1986 1987 3 3 Methylene chloride, see 1593 6.1 2 2937 6.1 Methylene chloride and methyl chloride mixture, see 1912 alpha-METHYLBENZYL ALCOHOL, LIQUID Methylene cyanide, see 2647 6.1 alpha-METHYLBENZYL ALCOHOL, SOLID 3438 6.1 p,p'-Methylene dianiline, see 2651 6.1 METHYL BROMIDE with not more than 2% chloropicrin 1062 2 Methylene dibromide, see 2664 6.1 2,2'-Methylene-di-(3,4,6trichlorophenol), see 2875 6.1 - 549 - Methyl ethyl ether, see 1039 2 alpha-Methylstyrene, see 2303 3 METHYL ETHYL KETONE, see 1193 3 Methyl sulphate, see 1595 6.1 2-METHYL-5-ETHYLPYRIDINE 2300 6.1 Methyl sulphide, see 1164 3 METHYL FLUORIDE 2454 2 METHYLTETRAHYDROFURAN 2536 3 METHYL FORMATE 1243 3 METHYL TRICHLOROACETATE 2533 6.1 2-METHYLFURAN 2301 3 METHYLTRICHLOROSILANE 1250 3 Methyl glycol, see 1188 3 2367 3 Methyl glycol acetate, see 1189 3 alpha-METHYLVALERALDEHYDE 2-METHYL-2-HEPTANETHIOL 3023 6.1 Methyl vinyl benzene, inhibited, see 2618 3 5-METHYLHEXAN-2-ONE 2302 3 METHYL VINYL KETONE, STABILIZED 1251 6.1 METHYLHYDRAZINE 1244 6.1 M.i.b.c., see 2053 3 METHYL IODIDE 2644 6.1 MINES with bursting charge METHYL ISOBUTYL CARBINOL 2053 3 METHYL ISOBUTYL KETONE 1245 3 0136 0137 0138 0294 1 1 1 1 METHYL ISOCYANATE 2480 6.1 Mirbane oil, see 1662 6.1 METHYL ISOPROPENYL KETONE, STABILIZED 1246 3 Missiles, guided, see METHYL ISOTHIOCYANATE 2477 6.1 METHYL ISOVALERATE 2400 3 METHYL MAGNESIUM BROMIDE IN ETHYL ETHER 1928 4.3 METHYL MERCAPTAN 1064 2 Methyl mercapto-propionaldehyde, see 2785 6.1 0180 0181 0182 0183 0295 0397 0398 0436 0437 0438 1 1 1 1 1 1 1 1 1 1 1965 2 METHYL METHACRYLATE MONOMER, STABILIZED 1247 3 Mixtures A, A01, A02, A0, A1, B1, B2, B or C, see 2 2535 3 Mixture F1, mixture F2 or mixture F3, see 1078 4-METHYLMORPHOLINE N-METHYLMORPHOLINE, see 2535 3 1010 2 METHYL NITRITE 2455 2 METHYL ORTHOSILICATE 2606 6.1 MIXTURES OF 1,3-BUTADIENE AND HYDROCARBONS, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l METHYLPENTADIENE 2461 3 Methylpentanes, see 1208 3 Mixture P1 or mixture P2, see 1060 2 2-METHYLPENTAN-2-OL 2560 3 MOLYBDENUM PENTACHLORIDE 2508 8 4-Methylpentan-2-ol, see 2053 3 Monochloroacetic acid, see 3-Methyl-2-penten-4ynol, see 2705 8 1750 1751 6.1 6.1 METHYLPHENYLDICHLOROSILANE 2437 8 Monochlorobenzene, see 1134 3 Monochlorodifluoromethane, see 1018 2 2-Methyl-2-phenylpropane, see 2709 3 2 2399 3 Monochlorodifluoromethane and monochloropentafluoroethane mixture, see 1973 1-METHYLPIPERIDINE METHYL PROPIONATE 1248 3 2 2046 3 Monochlorodifluoromonobromomethane, see 1974 Methylpropylbenzene, see METHYL PROPYL ETHER 2612 3 1973 2 METHYL PROPYL KETONE 1249 3 Monochloropentafluoroethane and monochlorodifluoromethane mixture, see Methyl pyridines, see 2313 3 Monoethylamine, see 1036 2 Methylstyrene, inhibited, see 2618 3 Carriage prohibited - 550 - MONONITROTOLUIDINES, see 2660 6.1 NICOTINE COMPOUND, LIQUID, N.O.S 3144 6.1 Monopropylamine, see 1277 3 MORPHOLINE 2054 8 NICOTINE COMPOUND, SOLID, N.O.S. 1655 6.1 MOTOR FUEL ANTI-KNOCK MIXTURE 1649 6.1 NICOTINE HYDROCHLORIDE, LIQUID 1656 6.1 MOTOR FUEL ANTI-KNOCK MIXTURE, FLAMMABLE 3483 6.1 NICOTINE HYDROCHLORIDE, SOLID 3444 6.1 MOTOR SPIRIT 1203 3 Motor spirit and ethanol mixture, with more than 10% ethanol, see 3475 NICOTINE HYDROCHLORIDE, SOLUTION 1656 6.1 3 Muriatic acid, see 6.1 8 NICOTINE PREPARATION, LIQUID, N.O.S. 3144 1789 MUSK XYLENE, see 2956 4.1 1655 6.1 Mysorite, see 2212 9 NICOTINE PREPARATION, SOLID, N.O.S. Naphta, see 1268 3 NICOTINE SALICYLATE 1657 6.1 Naphta, petroleum, see 1268 3 NICOTINE SULPHATE, SOLID 3445 6.1 Naphta, solvent, see 1268 3 NICOTINE SULPHATE, SOLUTION 1658 6.1 NAPHTHALENE, CRUDE 1334 4.1 NICOTINE TARTRATE 1659 6.1 NAPHTHALENE, MOLTEN 2304 4.1 NITRATES, INORGANIC, N.O.S. 1477 5.1 NAPHTHALENE, REFINED 1334 4.1 5.1 2077 6.1 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3218 alpha-NAPHTHYLAMINE beta-NAPHTHYLAMINE, SOLID 1650 6.1 1796 8 beta-NAPHTHYLAMINE, SOLUTION 3411 6.1 NITRATING ACID MIXTURE with more than 50% nitric acid 1796 8 NAPHTHYLTHIOUREA 1651 6.1 NITRATING ACID MIXTURE with not more than 50% nitric acid 1-Naphthylthiourea, see 1651 6.1 1826 8 NAPHTHYLUREA 1652 6.1 NITRATING ACID MIXTURE, SPENT, with more than 50% nitric acid NATURAL GAS, COMPRESSED with high methane content 1971 2 NITRATING ACID MIXTURE, SPENT, with not more than 50% nitric acid 1826 8 NATURAL GAS, REFRIGERATED 1972 LIQUID with high methane content 2 2031 8 Natural gasoline, see 1203 3 NITRIC ACID, other than red fuming, with at least 65% but not more than 70% nitric acid Neohexane, see 1208 3 8 1065 2 NITRIC ACID, other than red fuming, with less than 65% nitric acid 2031 NEON, COMPRESSED NEON, REFRIGERATED LIQUID 1913 2 8 2612 3 NICKEL CARBONYL 1259 6.1 NITRIC ACID, other than red fuming, with more than 70% nitric acid 2031 Neothyl, see NICKEL CYANIDE 1653 6.1 NITRIC ACID, RED FUMING 2032 8 Nickel (II) cyanide, see 1653 6.1 NITRIC OXIDE, COMPRESSED 1660 2 NICKEL NITRATE 2725 5.1 1975 2 Nickel (II) nitrate, see 2725 5.1 NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE NICKEL NITRITE 2726 5.1 1975 2 Nickel (II) nitrite, see 2726 5.1 NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE, see Nickelous nitrate, see 2725 5.1 NITRILES, FLAMMABLE, TOXIC, 3273 N.O.S. 3 Nickelous nitrite, see 2726 5.1 6.1 1259 6.1 NITRILES, LIQUID, TOXIC, N.O.S. 3276 Nickel tetracarbonyl, see NICOTINE 1654 6.1 NITRILES, SOLID, TOXIC, N.O.S. 3439 6.1 - 551 - NITRILES, TOXIC, FLAMMABLE, 3275 N.O.S. 6.1 NITRITES, INORGANIC, N.O.S. 2627 5.1 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3219 5.1 NITROANILINES (o-, m-, p-) 1661 6.1 NITROANISOLES, LIQUID 2730 6.1 NITROANISOLES, SOLID 3458 6.1 NITROBENZENE 1662 6.1 Nitrobenzene bromide, see 2732 6.1 NITROBENZENESULPHONIC ACID 2305 8 Nitrobenzol, see 1662 6.1 5-NITROBENZOTRIAZOL 0385 1 NITROBENZOTRIFLUORIDES, LIQUID 2306 6.1 NITROBENZOTRIFLUORIDES, SOLID 3431 6.1 NITROBROMOBENZENES, LIQUID 2732 6.1 NITROBROMOBENZENES, SOLID 3459 NITROCELLULOSE, dry or wetted with less than 25% water (or alcohol), by mass 0340 NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass 0341 NITROCELLULOSE MEMBRANE FILTERS, with not more than 12.6% nitrogen, by dry mass 3270 4.1 NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH PLASTICIZER, WITH PIGMENT 2557 4.1 NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH PLASTICIZER, WITHOUT PIGMENT 2557 4.1 NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITHOUT PLASTICIZER, WITH PIGMENT 2557 NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITHOUT PLASTICIZER, WITHOUT PIGMENT 2557 NITROCELLULOSE, 0343 PLASTICIZED with not less than 18% plasticizing substance, by mass NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose 2059 3 NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass 0342 1 NITROCELLULOSE WITH ALCOHOL (not less than 25% alcohol, by mass, and not more than 12.6% nitrogen, by dry mass) 2556 4.1 NITROCELLULOSE WITH WATER (not less than 25% water, by mass) 2555 4.1 Nitrochlorobenzenes, see 1578 3409 6.1 3-NITRO-4-CHLOROBENZOTRIFLUORIDE 2307 6.1 NITROCRESOLS, LIQUID 3434 6.1 NITROCRESOLS, SOLID 2446 6.1 NITROETHANE 2842 3 NITROGEN, COMPRESSED 1066 2 6.1 NITROGEN DIOXIDE, see 1067 2 NITROGEN, REFRIGERATED LIQUID 1977 2 1 NITROGEN TRIFLUORIDE 2451 2 NITROGEN TRIOXIDE 2421 2 NITROGLYCERIN, DESENSITIZED with not less than 40% non-volatile water-insoluble phlegmatizer, by mass 0143 1 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin, by mass 3357 3 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass 3343 3 4.1 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin, by mass 3319 4.1 4.1 NITROGLYCERIN, SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin 3064 3 NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 10% nitroglycerin 0144 1 NITROGLYCERIN SOLUTION IN ALCOHOL with not more than 1% nitroglycerin 1204 3 NITROGUANIDINE, dry or wetted with less than 20% water, by mass 0282 1 1 1 - 552 - Carriage prohibited NITROGUANIDINE, WETTED with not less than 20% water, by mass 1336 4.1 OCTANES 1262 3 OCTOGEN, see 0226 0391 0484 1 1 1 NITROHYDROCHLORIC ACID 1798 8 NITROMANNITE, WETTED, see 0133 1 OCTOL, dry or wetted with less than 15% water, by mass, see 0266 1 NITROMETHANE 1261 3 Nitromuriatic acid, see 1798 OCTOLITE, dry or wetted with less than 15% water, by mass 0266 1 8 NITRONAPHTHALENE 2538 4.1 OCTONAL 0496 1 NITROPHENOLS (o-, m-, p-) 1663 6.1 OCTYL ALDEHYDES 1191 3 4-NITROPHENYL-HYDRAZINE, with not less than 30% water, by mass 3376 4.1 tert-Octyl mercaptan, see 3023 6.1 OCTYLTRICHLOROSILANE 1801 8 NITROPROPANES 2608 3 Oenanthol, see 3056 3 p-NITROSODIMETHYLANILINE 1369 4.2 OIL GAS, COMPRESSED 1071 2 NITROSTARCH, dry or wetted with less than 20% water, by mass 0146 1 Oleum, see 1831 8 3101 5.2 NITROSTARCH, WETTED with not less than 20% water, by mass 1337 4.1 ORGANIC PEROXIDE TYPE B, LIQUID 3111 5.2 NITROSYL CHLORIDE 1069 2 ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED NITROSYLSULPHURIC ACID, LIQUID 2308 8 ORGANIC PEROXIDE TYPE B, SOLID 3102 5.2 NITROSYLSULPHURIC ACID, SOLID 3456 8 3112 5.2 NITROTOLUENES, LIQUID 1664 6.1 ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED NITROTOLUENES, SOLID 3446 6.1 ORGANIC PEROXIDE TYPE C, LIQUID 3103 5.2 NITROTOLUIDINES 2660 6.1 5.2 0490 1 NITRO UREA 0147 1 ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED 3113 NITROTRIAZOLONE NITROUS OXIDE 1070 2 ORGANIC PEROXIDE TYPE C, SOLID 3104 5.2 NITROUS OXIDE, REFRIGERATED LIQUID 2201 2 3114 5.2 NITROXYLENES, LIQUID 1665 6.1 ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED NITROXYLENES, SOLID 3447 6.1 3105 5.2 Non-activated carbon, see 1361 4.2 ORGANIC PEROXIDE TYPE D, LIQUID Non-activated charcoal, see 1361 4.2 3115 5.2 NONANES 1920 3 ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED NONYLTRICHLOROSILANE 1799 8 3106 5.2 2,5-NORBORNADIENE, STABILIZED, see 2251 3 ORGANIC PEROXIDE TYPE D, SOLID 3116 5.2 Normal propyl alcohol, see 1274 3 ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED NTO, see 0490 1 5.2 1800 8 ORGANIC PEROXIDE TYPE E, LIQUID 3107 OCTADECYLTRICHLOROSILANE 5.2 2309 3 OCTAFLUOROBUT-2-ENE 2422 2 ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED 3117 OCTADIENE OCTAFLUOROCYCLOBUTANE 1976 2 ORGANIC PEROXIDE TYPE E, SOLID 3108 5.2 OCTAFLUOROPROPANE 2424 2 Carriage prohibited - 553 - ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED 3118 5.2 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATERREACTIVE 3394 4.2 ORGANIC PEROXIDE TYPE F, LIQUID 3109 5.2 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATERREACTIVE 3393 4.2 ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED 3119 5.2 ORGANIC PEROXIDE TYPE F, SOLID 3110 5.2 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE 3398 4.3 ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED 3120 5.2 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE 3395 4.3 Organic peroxides, see 2.2.52.4 for an alphabetic list of currently assigned organic peroxides and see 3101 to 3120 5.2 ORGANOMETALLIC SUBSTANCE, LIQUID, WATERREACTIVE, FLAMMABLE 3399 4.3 ORGANIC PIGMENTS, SELFHEATING 3313 4.2 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, FLAMMABLE 3396 4.3 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. 3280 6.1 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 3465 6.1 ORGANOMETALLIC SUBSTANCE, SOLID, WATERREACTIVE, SELF-HEATING 3397 4.3 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2762 3 ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. 3278 6.1 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 2996 6.1 3464 6.1 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 2995 6.1 ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S. 3279 6.1 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 2761 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. 2784 3 ORGANOMETALLIC COMPOUND, LIQUID, TOXIC, N.O.S. 3282 6.1 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 °C ORGANOMETALLIC COMPOUND, SOLID, TOXIC, N.O.S. 3467 6.1 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 3018 6.1 3017 6.1 Organometallic compound, solid, water-reactive, flammable, n.o.s., see 3396 4.3 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C Organometallic compound or Organometallic compound solution or Organometallic compound dispersion, water-reactive, flammable, n.o.s., see 3399 4.3 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 2783 6.1 ORGANOTIN COMPOUND, LIQUID, N.O.S. 2788 6.1 6.1 3392 4.2 ORGANOTIN COMPOUND, SOLID, N.O.S. 3146 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC 2787 3 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC 3391 4.2 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C ORGANOTIN PESTICIDE, LIQUID, TOXIC 3020 6.1 ORGANOMETALLIC SUBSTANCE, SOLID, SELFHEATING 3400 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3019 6.1 6.1 4.2 - 554 - ORGANOTIN PESTICIDE, SOLID, TOXIC 2786 6.1 PENTACHLOROETHANE 1669 6.1 Orthophospohoric acid, see 1805 8 PENTACHLOROPHENOL 3155 6.1 OSMIUM TETROXIDE 2471 6.1 PENTAERYTHRITE TETRANITRATE with not less than 7% wax, by mass 0411 1 OXIDIZING LIQUID, N.O.S. 3139 5.1 OXIDIZING LIQUID, CORROSIVE, N.O.S. 3098 5.1 PENTAERYTHRITE TETRANITRATE, DESENSITIZED with not less than 15% phlegmatizer, by mass 0150 1 OXIDIZING LIQUID, TOXIC, N.O.S. 3099 5.1 OXIDIZING SOLID, N.O.S. 1479 5.1 PENTAERYTHRITE TETRANITRATE MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN, by mass 3344 4.1 OXIDIZING SOLID, CORROSIVE, N.O.S. 3085 5.1 OXIDIZING SOLID, FLAMMABLE, N.O.S. 3137 5.1 Carriage prohibited PENTAERYTHRITE TETRANITRATE, WETTED with not less than 25% water, by mass 0150 1 OXIDIZING SOLID, SELFHEATING, N.O.S. 3100 5.1 Carriage prohibited OXIDIZING SOLID, TOXIC, N.O.S. 3087 5.1 PENTAERYTHRITOL TETRANITRATE, see 0150 0411 3344 1 1 4.1 OXIDIZING SOLID, WATERREACTIVE, N.O.S. 3121 5.1 PENTAFLUOROETHANE 3220 2 Oxirane, see 1040 2 Pentafluoroethane, 1,1,1trifluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 44% pentafluoroethane and 52% 1,1,1trifluoroethane, see 3337 2 OXYGEN, COMPRESSED 1072 2 OXYGEN DIFLUORIDE, COMPRESSED 2190 2 OXYGEN GENERATOR, CHEMICAL 3356 5.1 PENTAMETHYLHEPTANE 2286 3 Pentanal, see 2058 3 OXYGEN, REFRIGERATED LIQUID 1073 2 PENTANE-2,4-DIONE 2310 3 1-Oxy-4-nitrobenzene, see 1663 6.1 PENTANES, liquid 1265 3 PACKAGINGS, DISCARDED, EMPTY, UNCLEANED 3509 9 n-Pentane, see 1265 3 PENTANOLS 1105 3 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) 1263 3066 3469 3470 3 8 3 8 3-Pentanol, see 1105 3 1-PENTENE 1108 3 1-PENTOL 2705 8 PAINT RELATED MATERIAL (including paint thinning and reducing compound) 1263 3066 3469 3470 3 8 3 8 PENTOLITE, dry or wetted with less than 15% water, by mass 0151 1 Pentyl nitrite, see 1113 3 Paint thinning and reducing compound, see 1263 3066 3469 3470 3 8 3 8 PERCHLORATES, INORGANIC, N.O.S. 1481 5.1 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3211 5.1 PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper) 1379 4.2 PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass 1873 5.1 Paraffin, see 1223 3 1802 8 PARAFORMALDEHYDE 2213 4.1 PERCHLORIC ACID with not more than 50% acid, by mass PARALDEHYDE 1264 3 Perchlorobenzene, see 2729 6.1 PCBs, see 2315 3432 9 9 Perchlorocyclopentadiene, see 2646 6.1 Perchloroethylene, see 1897 6.1 1380 4.2 PENTABORANE Carriage prohibited - 555 - PERCHLOROMETHYL MERCAPTAN 1670 6.1 Petroleum spirit, see 1268 3 PERCHLORYL FLUORIDE 3083 2 PHENACYL BROMIDE 2645 6.1 Perfluoroacetylchloride, see 3057 2 PHENETIDINES 2311 6.1 PERFLUORO (ETHYL VINYL ETHER) 3154 2 PHENOLATES, LIQUID 2904 8 PHENOLATES, SOLID 2905 8 PERFLUORO (METHYL VINYL ETHER) 3153 2 PHENOL, MOLTEN 2312 6.1 PHENOL, SOLID 1671 6.1 Perfluoropropane, see 2424 2 PHENOL SOLUTION 2821 6.1 PERFUMERY PRODUCTS with flammable solvents 1266 3 PHENOLSULPHONIC ACID, LIQUID 1803 8 PERMANGANATES, INORGANIC, N.O.S. 1482 5.1 3346 3 PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3214 5.1 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3348 6.1 PEROXIDES, INORGANIC, N.O.S. 1483 5.1 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC PERSULPHATES, INORGANIC, N.O.S. 3215 5.1 3347 6.1 PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 3216 5.1 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash-point less than 23 °C 3021 3 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 3345 6.1 PESTICIDE, LIQUID, TOXIC, N.O.S. 2902 6.1 PHENYLACETONITRILE, LIQUID 2470 6.1 PHENYLACETYL CHLORIDE 2577 8 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-point not less than 23 °C 2903 6.1 Phenylamine, see 1547 6.1 1-Phenylbutane, see 2709 3 PESTICIDE, SOLID, TOXIC, N.O.S. 2588 6.1 2-Phenylbutane, see 2709 3 6.1 1950 2 PHENYLCARBYLAMINE CHLORIDE 1672 Pesticide, toxic, under compressed gas, n.o.s, see PHENYL CHLOROFORMATE 2746 6.1 PETN, see 0150 0411 3344 1 1 4.1 Phenyl cyanide, see 2224 6.1 6.1 0151 1 PHENYLENEDIAMINES (o-, m-, p-) 1673 PETN/TNT, see PETROL 1203 3 Phenylethylene, see 2055 3 Petrol and ethanol mixture, with more than 10% ethanol, see 3475 3 PHENYLHYDRAZINE 2572 6.1 PHENYL ISOCYANATE 2487 6.1 PETROLEUM CRUDE OIL 1267 3 Phenylisocyanodichloride, see 1672 6.1 PETROLEUM DISTILLATES, N.O.S. 1268 3 PHENYL MERCAPTAN 2337 6.1 Petroleum ether, see 1268 3 PETROLEUM GASES, LIQUEFIED 1075 2 Petroleum naphtha, see 1268 3 Petroleum oil, see 1268 PETROLEUM PRODUCTS, N.O.S. PHENYLMERCURIC ACETATE 1674 6.1 PHENYLMERCURIC COMPOUND, N.O.S. 2026 6.1 1894 6.1 3 PHENYLMERCURIC HYDROXIDE 1268 3 PHENYLMERCURIC NITRATE 1895 6.1 Petroleum raffinate, see 1268 3 PHENYLPHOSPHORUS DICHLORIDE 2798 8 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC 3494 3 PHENYLPHOSPHORUS THIODICHLORIDE 2799 8 - 556 - 2-Phenylpropene, see 2303 3 PHOSPHORUS, YELLOW, DRY 1381 4.2 PHENYLTRICHLOROSILANE 1804 8 1381 4.2 PHOSGENE 1076 2 PHOSPHORUS, YELLOW, IN SOLUTION 9-PHOSPHABICYCLO-NONANES 2940 4.2 PHOSPHORUS, YELLOW, UNDER WATER 1381 4.2 PHOSPHINE 2199 2 Phosphoryl chloride, see 1810 6.1 PHOSPHINE, ADSORBED 3525 2 8 2199 2 PHOSPHORIC ACID, SOLUTION 1805 8 PHTHALIC ANHYDRIDE with more than 0.05% of maleic anhydride 2214 Phosphoretted hydrogen, see PHOSPHORIC ACID, SOLID 3453 8 PICOLINES 2313 3 Phosphoric acid, anhydrous, see 1807 8 PICRAMIDE, see 0153 1 PHOSPHOROUS ACID 2834 8 PICRIC ACID, WETTED, see 1344 3364 4.1 4.1 PHOSPHORUS, AMORPHOUS 1338 4.1 PICRITE, see 0282 1 Phosphorus bromide, see 1808 8 PICRITE, WETTED, see 1336 4.1 Phosphorus chloride, see 1809 6.1 Picrotoxin, see PHOSPHORUS HEPTASULPHIDE, 1339 free from yellow and white phosphorus 4.1 3172 3462 6.1 6.1 PICRYL CHLORIDE, see 0155 1 PHOSPHORUS OXYBROMIDE 1939 8 PICRYL CHLORIDE, WETTED, see 3365 4.1 PHOSPHORUS OXYBROMIDE, MOLTEN 2576 8 alpha-PINENE 2368 3 PHOSPHORUS OXYCHLORIDE 1810 6.1 PINE OIL 1272 3 PHOSPHORUS PENTABROMIDE 2691 8 PIPERAZINE 2579 8 PHOSPHORUS PENTACHLORIDE 1806 8 PIPERIDINE 2401 8 PHOSPHORUS PENTAFLUORIDE 2198 2 Pivaloyl chloride, see 2438 6.1 PHOSPHORUS PENTAFLUORIDE, 3524 ADSORBED 2 Plastic explosives, see 0084 1 3314 9 PHOSPHORUS PENTASULPHIDE, 1340 free from yellow and white phosphorus 4.3 PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour PHOSPHORUS PENTOXIDE 1807 8 PLASTICS, NITROCELLULOSEBASED, SELF-HEATING, N.O.S. 2006 4.2 PHOSPHORUS SESQUISULPHIDE, free from yellow and white phosphorus 1341 4.1 Polish, see Phosphorus (V) sulphide, free from yellow and white phosphorus, see 1340 4.3 1263 3066 3469 3470 3 8 3 8 3 1837 8 POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 2733 Phosphorus sulphochloride, see PHOSPHORUS TRIBROMIDE 1808 8 2735 8 PHOSPHORUS TRICHLORIDE 1809 6.1 POLYAMINES, LIQUID, CORROSIVE, N.O.S. PHOSPHORUS TRIOXIDE 2578 8 2734 8 PHOSPHORUS TRISULPHIDE, free from yellow and white phosphorus 1343 4.1 POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. POLYAMINES, SOLID, CORROSIVE, N.O.S. 3259 8 PHOSPHORUS, WHITE, DRY 1381 4.2 9 1381 4.2 POLYCHLORINATED BIPHENYLS, LIQUID 2315 PHOSPHORUS, WHITE IN SOLUTION 9 2447 4.2 POLYCHLORINATED BIPHENYLS, SOLID 3432 PHOSPHORUS, WHITE, MOLTEN PHOSPHORUS, WHITE, UNDER WATER 1381 4.2 POLYESTER RESIN KIT 3269 3 - 557 - POLYHALOGENATED BIPHENYLS, LIQUID 3151 9 POTASSIUM HYDROXIDE, SOLID 1813 8 POLYHALOGENATED BIPHENYLS, SOLID 3152 9 POTASSIUM HYDROXIDE SOLUTION 1814 8 POLYHALOGENATED TERPHENYLS, LIQUID 3151 9 POTASSIUM METAL ALLOYS, LIQUID 1420 4.3 POLYHALOGENATED TERPHENYLS, SOLID 3152 9 POTASSIUM METAL ALLOYS, SOLID 3403 4.3 POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour 2211 9 POTASSIUM METAVANADATE 2864 6.1 POTASSIUM MONOXIDE 2033 8 Polystyrene beads, expandable, see 2211 9 POTASSIUM NITRATE 1486 5.1 POTASSIUM 2257 4.3 Potassium nitrate and sodium nitrate mixture, see 1499 5.1 POTASSIUM ARSENATE 1677 6.1 5.1 1678 6.1 POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE 1487 POTASSIUM ARSENITE Potassium bifluoride, see 1811 8 POTASSIUM NITRITE 1488 5.1 Potassium bisulphate, see 2509 8 POTASSIUM PERCHLORATE 1489 5.1 Potassium bisulphite solution, see 2693 8 POTASSIUM PERMANGANATE 1490 5.1 POTASSIUM BOROHYDRIDE 1870 4.3 POTASSIUM PEROXIDE 1491 5.1 POTASSIUM BROMATE 1484 5.1 POTASSIUM PERSULPHATE 1492 5.1 POTASSIUM CHLORATE 1485 5.1 POTASSIUM PHOSPHIDE 2012 4.3 POTASSIUM CHLORATE, AQUEOUS SOLUTION 2427 5.1 Potassium selenate, see 2630 6.1 Potassium selenite, see 2630 6.1 Potassium chlorate mixed with mineral oil, see 0083 1 Potassium silicofluoride, see 2655 6.1 POTASSIUM CUPROCYANIDE 1679 6.1 POTASSIUM SODIUM ALLOYS, LIQUID 1422 4.3 POTASSIUM CYANIDE, SOLID 1680 6.1 4.3 3413 6.1 POTASSIUM SODIUM ALLOYS, SOLID 3404 POTASSIUM CYANIDE, SOLUTION 4.2 1679 6.1 POTASSIUM SULPHIDE with less than 30% water of crystallization 1382 Potassium dicyanocuprate (I), see POTASSIUM DITHIONITE 1929 4.2 1382 4.2 POTASSIUM FLUORIDE, SOLID 1812 6.1 POTASSIUM SULPHIDE, ANHYDROUS POTASSIUM FLUORIDE, SOLUTION 3422 6.1 POTASSIUM SULPHIDE, HYDRATED with not less than 30% water of crystallization 1847 8 POTASSIUM FLUOROACETATE 2628 6.1 POTASSIUM SUPEROXIDE 2466 5.1 POTASSIUM FLUOROSILICATE 2655 6.1 6.1 2655 6.1 Potassium tetracyanomercurate (II), see 1626 Potassium hexafluorosilicate, see Potassium hydrate, see 1814 8 0433 1 POTASSIUM HYDROGENDIFLUORIDE, SOLID 1811 8 POWDER CAKE, WETTED with not less than 17% alcohol, by mass POWDER CAKE, WETTED with not less than 25% water, by mass 0159 1 POTASSIUM HYDROGENDIFLUORIDE, SOLUTION 3421 8 POWDER PASTE, see 0159 0433 1 1 POWDER, SMOKELESS POTASSIUM HYDROGEN SULPHATE 2509 8 0160 0161 0509 1 1 1 POTASSIUM HYDROSULPHITE, see 1929 4.2 Power devices, explosive, see Potassium hydroxide, liquid, see 1814 8 0275 0276 0323 0381 1 1 1 1 - 558 - PRIMERS, CAP TYPE 0044 0377 0378 1 1 1 PROPYL ALCOHOL, NORMAL, see 1274 3 Primers, small arms, see 0044 1 PROPYLAMINE 1277 3 PRIMERS, TUBULAR 0319 0320 0376 1 1 1 n-PROPYLBENZENE 2364 3 Propyl chloride, see 1278 3 n-PROPYL CHLOROFORMATE 2740 6.1 PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 1210 3 PROPYLENE 1077 2 PROPYLENE CHLOROHYDRIN 2611 6.1 1,2-PROPYLENEDIAMINE 2258 8 Projectiles, illuminating, see 0171 0254 0297 1 1 1 Propylene dichloride, see 1279 3 PROPYLENEIMINE, STABILIZED 1921 3 PROPYLENE OXIDE 1280 3 0345 0424 0425 1 1 1 PROPYLENE TETRAMER 2850 3 Propylene trimer, see 2057 3 0346 0347 0426 0427 0434 0435 1 1 1 1 1 1 PROPYL FORMATES 1281 3 n-PROPYL ISOCYANATE 2482 6.1 Propyl mercaptan, see 2402 3 n-PROPYL NITRATE 1865 3 0167 0168 0169 0324 0344 1 1 1 1 1 PROPYLTRICHLOROSILANE 1816 8 Pyrazine hexahydride, see 2579 8 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 3350 3 PROPADIENE, STABILIZED 2200 2 6.1 1060 2 PYRETHROID PESTICIDE, LIQUID, TOXIC 3352 Propadiene and methyl acetylene mixture, stabilized, see 6.1 1978 2 PROPANETHIOLS 2402 3 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3351 PROPANE n-PROPANOL 1274 3 PYRETHROID PESTICIDE, SOLID, TOXIC 3349 6.1 PROPELLANT, LIQUID 0495 0497 1 1 PYRIDINE 1282 3 PROPELLANT, SOLID 0498 0499 0501 1 1 1 PYROPHORIC ALLOY, N.O.S. 1383 4.2 3394 4.2 Propellant with a single base, Propellant with a double base, Propellant with a triple base, see 0160 0161 1 1 Pyrophoric organometallic compound, water-reactive, n.o.s., liquid, see 3393 4.2 Propene, see 1077 2 Pyrophoric organometallic compound, water-reactive, n.o.s., solid, see PROPIONALDEHYDE 1275 3 PYROPHORIC LIQUID, INORGANIC, N.O.S. 3194 4.2 PROPIONIC ACID with not less than 10% and less than 90% acid by mass 1848 8 PYROPHORIC LIQUID, ORGANIC, N.O.S. 2845 4.2 PROPIONIC ACID with not less than 90% acid by mass 3463 8 PYROPHORIC METAL, N.O.S. 1383 4.2 4.2 2496 8 PYROPHORIC SOLID, INORGANIC, N.O.S. 3200 PROPIONIC ANHYDRIDE PROPIONITRILE 2404 3 PYROPHORIC SOLID, ORGANIC, N.O.S. 2846 4.2 PROPIONYL CHLORIDE 1815 3 PYROSULPHURYL CHLORIDE 1817 8 n-PROPYL ACETATE 1276 3 Pyroxylin solution, see 2059 3 PROJECTILES, inert with tracer PROJECTILES with burster or expelling charge PROJECTILES with bursting charge - 559 - PYRROLIDINE 1922 3 QUINOLINE 2656 6.1 Quinone, see 2587 6.1 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM 2909 7 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING 2908 7 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE INSTRUMENTS or ARTICLES 2911 7 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE LIMITED QUANTITY OF MATERIAL 2910 7 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE 3333 7 RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, non fissile or fissileexcepted 3332 7 RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE 3329 7 RADIOACTIVE MATERIAL, 2917 TYPE B(M) PACKAGE, non fissile or fissile-excepted 7 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE 3328 7 RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile or fissile-excepted 2916 7 RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE 3330 7 RADIOACTIVE MATERIAL, LOW 2912 SPECIFIC ACTIVITY (LSA-I), non fissile or fissile-excepted 7 RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissile-excepted 3323 7 RADIOACTIVE MATERIAL, LOW 3324 SPECIFIC ACTIVITY (LSA-II), FISSILE 7 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE 2977 7 RADIOACTIVE MATERIAL, LOW 3321 SPECIFIC ACTIVITY (LSA-II), non fissile or fissile-excepted 7 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non fissile or fissile-excepted 2978 7 RADIOACTIVE MATERIAL, LOW 3325 SPECIFIC ACTIVITY, (LSA-III), FISSILE 7 Rags, oily 1856 4.2 RDX, see RADIOACTIVE MATERIAL, LOW 3322 SPECIFIC ACTIVITY (LSA-III), non fissile or fissile-excepted 7 0072 0391 0483 1 1 1 2 3326 7 RECEPTACLES, SMALL, CONTAINING GAS without a release device, non-refillable 2037 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSILE Red phosphorus, see 1338 4.1 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), non fissile or fissile-excepted 2913 REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture P2 1078 2 REFRIGERANT GAS R 12, see 1028 2 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE 3331 REFRIGERANT GAS R 12B1, see 1974 2 REFRIGERANT GAS R 13, see 1022 2 REFRIGERANT GAS R 13B1, see 1009 2 RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted 2919 REFRIGERANT GAS R 14, see 1982 2 REFRIGERANT GAS R 21, see 1029 2 REFRIGERANT GAS R 22, see 1018 2 RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non-special form 3327 REFRIGERANT GAS R 23, see 1984 2 REFRIGERANT GAS R 32, see 3252 2 RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissile-excepted 2915 REFRIGERANT GAS R 40, see 1063 2 REFRIGERANT GAS R 41, see 2454 2 REFRIGERANT GAS R 114, see 1958 2 REFRIGERANT GAS R 115, see 1020 2 7 7 7 7 7 - 560 - Not subject to ADR REFRIGERANT GAS R 116, see 2193 2 ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge 0250 0322 1 1 REFRIGERANT GAS R 124, see 1021 2 REFRIGERANT GAS R 125, see 3220 2 REFRIGERANT GAS R 133a, see 1983 2 ROCKETS with bursting charge 0180 0181 0182 0295 1 1 1 1 REFRIGERANT GAS R 134a, see 3159 2 REFRIGERANT GAS R 142b, see 2517 2 REFRIGERANT GAS R 143a, see 2035 2 ROCKETS with expelling charge 0436 0437 0438 1 1 1 REFRIGERANT GASR 152a, see 1030 2 REFRIGERANT GAS R 161, see 2453 2 ROCKETS with inert head 0183 0502 1 1 REFRIGERANT GAS R 218, see 2424 2 REFRIGERANT GAS R 227, see 3296 2 ROCKETS, LINE-THROWING 0238 0240 0453 1 1 1 REFRIGERANT GAS R 404A 3337 2 REFRIGERANT GAS R 407A 3338 2 ROCKETS, LIQUID FUELLED with bursting charge 0397 0398 1 1 REFRIGERANT GAS R 407B 3339 2 ROSIN OIL 1286 3 REFRIGERANT GAS R 407C 3340 2 1345 4.1 REFRIGERANT GAS R 500, see 2602 2 RUBBER SCRAP, powdered or granulated REFRIGERANT GAS R 502, see 1973 2 RUBBER SHODDY, powdered or granulated 1345 4.1 REFRIGERANT GAS R 503, see 2599 2 RUBBER SOLUTION 1287 3 REFRIGERANT GAS R 1132a, see 1959 2 RUBIDIUM 1423 4.3 REFRIGERANT GAS R 1216, see 1858 2 RUBIDIUM HYDROXIDE 2678 8 REFRIGERANT GAS R 1318, see 2422 2 8 1976 2 RUBIDIUM HYDROXIDE SOLUTION 2677 REFRIGERANT GAS RC 318, see REFRIGERATING MACHINES containing flammable, non-toxic, liquefied gas 3358 2 Rubidium nitrate, see 1477 5.1 SAFETY DEVICES, electrically initiated 3268 9 REFRIGERATING MACHINES containing non-flammable, nontoxic, gases or ammonia solutions (UN 2672) 2857 SAFETY DEVICES, PYROTECHNIC 0503 1 Saltpetre, see 1486 5.1 REGULATED MEDICAL WASTE, N.O.S. 3291 6.2 SAMPLES, EXPLOSIVE, other than initiating explosive 0190 1 RELEASE DEVICES, EXPLOSIVE 0173 1 Sand acid, see 1778 8 RESIN SOLUTION, flammable 1866 3 Seat-belt pretensioners, see Resorcin, see 2876 6.1 0503 3268 1 9 RESORCINOL 2876 6.1 SEED CAKE with more than 1.5% oil and not more than 11% moisture 1386 4.2 RIVETS, EXPLOSIVE 0174 1 4.2 1999 3 SEED CAKE with not more than 1.5% oil and not more than 11% moisture 2217 Road oil, with a flash-point not greater than 60 °C, see Road oil, with a flash-point above 3256 60 °C, at or above its flash-point, see 3 Seed expellers, see 1386 2217 4.2 4.2 Road oil, at or above 100 °C and below its flash-point, see 3257 9 SELENATES 2630 6.1 SELENIC ACID 1905 8 ROCKET MOTORS 0186 0280 0281 1 1 1 SELENITES 2630 6.1 6.1 0395 0396 1 1 SELENIUM COMPOUND, LIQUID, N.O.S. 3440 ROCKET MOTORS, LIQUID FUELLED SELENIUM COMPOUND, SOLID, N.O.S. 3283 6.1 2 - 561 - SELENIUM DISULPHIDE 2657 6.1 SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED 3232 4.1 SELENIUM HEXAFLUORIDE 2194 2 SELENIUM OXYCHLORIDE 2879 8 SELF-REACTIVE SOLID TYPE C 3224 4.1 SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. 3188 4.2 SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED 3234 4.1 SELF-REACTIVE SOLID TYPE D 3226 4.1 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. 3185 4.2 SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED 3236 4.1 SELF-HEATING LIQUID, INORGANIC, N.O.S. 3186 4.2 SELF-REACTIVE SOLID TYPE E 3228 4.1 4.1 3183 4.2 SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED 3238 SELF-HEATING LIQUID, ORGANIC, N.O.S. SELF-REACTIVE SOLID TYPE F 3230 4.1 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 3187 4.2 SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED 3240 4.1 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 3184 4.2 SHALE OIL 1288 3 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. 3192 4.2 Shaped charges, see 0059 0439 0440 0441 1 1 1 1 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. 3126 4.2 Shellac, see SELF-HEATING SOLID, INORGANIC, N.O.S. 3190 4.2 1263 3066 3469 3470 3 8 3 8 SELF-HEATING SOLID, ORGANIC, N.O.S. 3088 4.2 SIGNAL DEVICES, HAND 0191 0373 1 1 SELF-HEATING SOLID, OXIDIZING, N.O.S 3127 4.2 SIGNALS, DISTRESS, ship SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. 3191 4.2 0194 0195 0505 0506 1 1 1 1 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 3128 4.2 Signals, distress, ship, wateractivated, see 0249 1 SELF-REACTIVE LIQUID TYPE B 3221 4.1 SIGNALS, RAILWAY TRACK, EXPLOSIVE SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED 3231 4.1 0192 0193 0492 0493 1 1 1 1 SIGNALS, SMOKE SELF-REACTIVE LIQUID TYPE C 3223 4.1 SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED 3233 4.1 0196 0197 0313 0487 0507 1 1 1 1 1 SELF-REACTIVE LIQUID TYPE D 3225 4.1 SILANE 2203 2 SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED 3235 4.1 Silicofluoric acid, see 1778 8 Silicofluorides, n.o.s., see 2856 6.1 Silicon chloride, see 1818 8 SELF-REACTIVE LIQUID TYPE E 3227 4.1 4.1 3237 4.1 SILICON POWDER, AMORPHOUS 1346 SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED SILICON TETRACHLORIDE 1818 8 SELF-REACTIVE LIQUID TYPE F 3229 4.1 SILICON TETRAFLUORIDE 1859 2 SELF-REACTIVE LIQUID TYPE F, 3239 TEMPERATURE CONTROLLED 4.1 SILICON TETRAFLUORIDE, ADSORBED 3521 2 SELF-REACTIVE SOLID TYPE B 4.1 SILVER ARSENITE 1683 6.1 SILVER CYANIDE 1684 6.1 3222 Carriage prohibited - 562 - SILVER NITRATE 1493 5.1 Sodium dimethylarsenate, see 1688 6.1 SILVER PICRATE, WETTED with not less than 30% water, by mass 1347 4.1 0234 1 SLUDGE ACID 1906 8 SODIUM DINITRO-oCRESOLATE, dry or wetted with less than 15% water, by mass SODA LIME with more than 4% sodium hydroxide 1907 8 SODIUM DINITRO-oCRESOLATE, WETTED with not less than 10% water, by mass 3369 4.1 SODIUM 1428 4.3 4.1 2812 8 SODIUM DINITRO-oCRESOLATE, WETTED with not less than 15% water, by mass 1348 Sodium aluminate, solid SODIUM ALUMINATE SOLUTION 1819 8 Sodium dioxide, see 1504 5.1 SODIUM DITHIONITE 1384 4.2 SODIUM ALUMINIUM HYDRIDE 2835 4.3 SODIUM FLUORIDE, SOLID 1690 6.1 SODIUM AMMONIUM VANADATE 2863 6.1 SODIUM FLUORIDE, SOLUTION 3415 6.1 SODIUM ARSANILATE 2473 6.1 SODIUM FLUOROACETATE 2629 6.1 SODIUM ARSENATE 1685 6.1 SODIUM FLUOROSILICATE 2674 6.1 SODIUM ARSENITE, AQUEOUS SOLUTION 1686 6.1 Sodium hexafluorosilicate, see 2674 6.1 Sodium hydrate, see 1824 8 SODIUM ARSENITE, SOLID 2027 6.1 SODIUM HYDRIDE 1427 4.3 SODIUM AZIDE 1687 6.1 2473 6.1 Sodium bifluoride, see 2439 8 Sodium hydrogen 4-aminophenylarsenate, see Sodium binoxide, see 1504 5.1 SODIUM HYDROGENDIFLUORIDE 2439 8 Sodium bisulphite solution, see 2693 8 4.2 1426 4.3 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION, with not more than 12% sodium borohydride and not more than 40% sodium hydroxide by mass 3320 8 SODIUM HYDROSULPHIDE with less than 25% water of crystallization 2318 SODIUM BOROHYDRIDE SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization 2949 8 SODIUM HYDROSULPHITE, see 1384 4.2 SODIUM BROMATE 1494 5.1 SODIUM HYDROXIDE, SOLID 1823 8 SODIUM CACODYLATE 1688 6.1 SODIUM HYDROXIDE SOLUTION 1824 8 SODIUM CARBONATE PEROXYHYDRATE 3378 5.1 Sodium metasilicate pentahydrate, see 3253 8 SODIUM CHLORATE 1495 5.1 SODIUM METHYLATE 1431 4.2 SODIUM CHLORATE, AQUEOUS SOLUTION 2428 5.1 SODIUM METHYLATE SOLUTION in alcohol 1289 3 Sodium chlorate mixed with dinitrotoluene, see 0083 1 SODIUM MONOXIDE 1825 8 SODIUM CHLORITE 1496 5.1 SODIUM NITRATE 1498 5.1 SODIUM CHLOROACETATE 2659 6.1 1499 5.1 SODIUM CUPROCYANIDE, SOLID 2316 6.1 SODIUM NITRATE AND POTASSIUM NITRATE MIXTURE SODIUM NITRITE 1500 5.1 SODIUM CUPROCYANIDE SOLUTION 2317 6.1 Sodium nitrite and potassium nitrate mixture, see 1487 5.1 SODIUM CYANIDE, SOLID 1689 6.1 6.1 3414 6.1 SODIUM PENTACHLOROHENATE 2567 SODIUM CYANIDE, SOLUTION Sodium dicyanocuprate (I), solid, see 2316 6.1 3377 5.1 Sodium dicyanocuprate (I) solution, see 2317 6.1 SODIUM PERBORATE MONOHYDRATE SODIUM PERCHLORATE 1502 5.1 Not subject to ADR - 563 - SODIUM PERMANGANATE 1503 5.1 Straw 1327 4.1 SODIUM PEROXIDE 1504 5.1 SODIUM PEROXOBORATE, ANHYDROUS 3247 5.1 Strontium alloys, pyrophoric, see 1383 4.2 STRONTIUM ARSENITE 1691 6.1 SODIUM PERSULPHATE 1505 5.1 STRONTIUM CHLORATE 1506 5.1 SODIUM PHOSPHIDE 1432 4.3 Strontium dioxide, see 1509 5.1 SODIUM PICRAMATE, dry or wetted with less than 20% water, by mass 0235 1 STRONTIUM NITRATE 1507 5.1 STRONTIUM PERCHLORATE 1508 5.1 SODIUM PICRAMATE, WETTED with not less than 20% water, by mass 1349 STRONTIUM PEROXIDE 1509 5.1 STRONTIUM PHOSPHIDE 2013 4.3 STRYCHNINE 1692 6.1 Sodium potassium alloys, liquid, see 1422 4.3 STRYCHNINE SALTS 1692 6.1 Sodium selenate, see 2630 6.1 STYPHNIC ACID, see Sodium selenite, see 2630 6.1 0219 0394 1 1 Sodium silicofluoride, see 2674 6.1 2055 3 SODIUM SULPHIDE, ANHYDROUS 1385 4.2 STYRENE MONOMER, STABILIZED SUBSTANCES, EVI, N.O.S., see 0482 1 SODIUM SULPHIDE with less than 30% water of crystallization 1385 4.2 SUBSTANCES, EXPLOSIVE, N.O.S. SODIUM SULPHIDE, HYDRATED 1849 with not less than 30% water 8 SODIUM SUPEROXIDE 2547 5.1 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. 3244 8 SOLIDS or mixtures of solids (such as preparations and wastes) CONTAINING FLAMMABLE LIQUID, N.O.S. having a flashpoint up to 60 °C 3175 4.1 0357 0358 0359 0473 0474 0475 0476 0477 0478 0479 0480 0481 0485 1 1 1 1 1 1 1 1 1 1 1 1 1 0482 1 SOLIDS CONTAINING TOXIC LIQUID, N.O.S. 3243 6.1 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE, N.O.S. Solvents, flammable, n.o.s., see 1993 3 Substances liable to spontaneous combustion, n.o.s., see Solvents, flammable, toxic, n.o.s., see 1992 3 2845 2846 3194 3200 4.2 4.2 4.2 4.2 SOUNDING DEVICES, EXPLOSIVE 0204 0296 0374 0375 1 1 1 1 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 °C 2780 3 Squibs, see 0325 0454 1 1 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 3014 6.1 Stain, see 1263 3066 3469 3470 3 8 3 8 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3013 6.1 STANNIC CHLORIDE, ANHYDROUS 1827 8 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC 2779 6.1 STANNIC CHLORIDE PENTAHYDRATE 2440 8 SULPHAMIC ACID 2967 8 SULPHUR 1350 4.1 STANNIC PHOSPHIDES 1433 4.3 SULPHUR CHLORIDES 1828 8 Steel swarf, see 2793 4.2 Sulphur dichloride, see 1828 8 STIBINE 2676 2 SULPHUR DIOXIDE 1079 2 4.1 - 564 - Not subject to ADR Sulphuretted hydrogen, see 1053 2 Tetrafluorodichloroethane, see 1958 2 SULPHUR HEXAFLUORIDE 1080 2 1,1,1,2-TETRAFLUOROETHANE 3159 2 SULPHURIC ACID with more than 51% acid 1830 8 TETRAFLUOROETHYLENE, STABILIZED 1081 2 SULPHURIC ACID with not more than 51% acid 2796 8 TETRAFLUOROMETHANE 1982 2 3 1831 8 1,2,3,6-TETRAHYDROBENZALDEHYDE 2498 SULPHURIC ACID, FUMING SULPHURIC ACID, SPENT 1832 8 TETRAHYDROFURAN 2056 3 Sulphuric and hydrofluoric acid mixture, see 1786 8 TETRAHYDROFURFURYLAMINE 2943 3 SULPHUR, MOLTEN 2448 4.1 Tetrahydro-1,4-oxazine, see 2054 3 Sulphur monochloride, see 1828 8 2698 8 SULPHUROUS ACID 1833 8 TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% of maleic anhydride SULPHUR TETRAFLUORIDE 2418 2 1,2,3,6-TETRAHYDROPYRIDINE 2410 3 SULPHUR TRIOXIDE, STABILIZED 1829 8 TETRAHYDROTHIOPHENE 2412 3 SULPHURYL CHLORIDE 1834 6.1 Tetramethoxysilane, see 2606 6.1 SULPHURYL FLUORIDE 2191 2 TETRAMETHYLAMMONIUM HYDROXIDE SOLID 3423 8 Talcum with tremolite and/or actinolite, see 2212 9 TETRAMETHYLAMMONIUM HYDROXIDE SOLUTION 1835 8 TARS, LIQUID, including road oils, and cutback bitumens, with a flashpoint not greater than 60 °C 1999 3 Tetramethylene, see 2601 2 Tetramethylene cyanide, see 2205 6.1 Tars, liquid, with a flash-point above 60 °C, at or above its flash-point, see 3256 Tetramethyl lead, see 1649 6.1 TETRAMETHYLSILANE 2749 3 Tars, liquid, at or above 100 °C and below its flash-point, see 3257 TETRANITROANILINE 0207 1 TETRANITROMETHANE 1510 6.1 Tartar emetic, see 1551 6.1 2413 3 TEAR GAS CANDLES 1700 6.1 TETRAPROPYL ORTHOTITANATE TEAR GAS SUBSTANCE, LIQUID, 1693 N.O.S. 6.1 TETRAZENE, WETTED with not less than 30% water, or mixture of alcohol and water, by mass, see 0114 1 TEAR GAS SUBSTANCE, SOLID, N.O.S. 3448 6.1 TETRAZOL-1-ACETIC ACID 0407 1 TELLURIUM COMPOUND, N.O.S. 3284 6.1 1H-TETRAZOLE 0504 1 TELLURIUM HEXAFLUORIDE 2195 2 TETRYL, see 0208 1 TERPENE HYDROCARBONS, N.O.S. 2319 3 Textile waste, wet 1857 4.2 TERPINOLENE 2541 3 THALLIUM CHLORATE 2573 5.1 TETRABROMOETHANE 2504 6.1 Thallium (I) chlorate, see 2573 5.1 1,1,2,2-TETRACHLOROETHANE 1702 6.1 THALLIUM COMPOUND, N.O.S. 1707 6.1 TETRACHLOROETHYLENE 1897 6.1 THALLIUM NITRATE 2727 6.1 TETRAETHYL DITHIOPYROPHOSPHATE 1704 6.1 Thallium (I) nitrate, see 2727 6.1 Thallous chlorate, see 2573 5.1 TETRAETHYLENEPENTAMINE 2320 8 4-THIAPENTANAL 2785 6.1 Tetraethyl lead, see 1649 6.1 Thia-4-pentanal, see 2785 6.1 TETRAETHYL SILICATE 1292 3 THIOACETIC ACID 2436 3 Tetraethyoxysilane, see 1292 3 3 9 - 565 - Not subject to ADR THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C 2772 3 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 3005 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 2771 6.1 THIOGLYCOL 2966 6.1 THIOGLYCOLIC ACID 1940 8 THIOLACTIC ACID 2936 6.1 THIONYL CHLORIDE 1836 8 THIOPHENE 2414 3 Thiophenol, see 2337 6.1 THIOPHOSGENE 2474 6.1 THIOPHOSPHORYL CHLORIDE 1837 8 THIOUREA DIOXIDE 3341 4.2 Tin (IV) chloride, anhydrous, see 1827 8 Tin (IV) chloride pentahydrate, see 2440 8 TINCTURES, MEDICINAL 1293 3 Tin tetrachloride, see 1827 8 TITANIUM DISULPHIDE 3174 4.2 TITANIUM HYDRIDE 1871 4.1 TITANIUM POWDER, DRY 2546 4.2 TITANIUM POWDER, WETTED with not less than 25% water 1352 4.1 TITANIUM SPONGE GRANULES 2878 4.1 TITANIUM SPONGE POWDERS 2878 4.1 TITANIUM TETRACHLORIDE 1838 6.1 TITANIUM TRICHLORIDE MIXTURE 2869 8 TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC 2441 4.2 TITANIUM TRICHLORIDE, PYROPHORIC 2441 4.2 TNT, see 0209 0388 0389 1 1 1 TNT mixed with aluminium, see 0390 1 TNT, WETTED with not less than 30% water, by mass, see 1356 4.1 TNT, WETTED with not less than 10% water, by mass, see 3366 4.1 Toe puffs, nitrocellulose base, see 1353 4.1 TOLUENE 1294 3 TOLUENE DIISOCYANATE 2078 6.1 6.1 6.1 - 566 - TOLUIDINES, LIQUID 1708 6.1 TOLUIDINES, SOLID 3451 6.1 Toluol, see 1294 3 2,4-TOLUYLENEDIAMINE, SOLID 1709 6.1 2,4-TOLUYLENEDIAMINE, SOLUTION 3418 6.1 Toluylene diisocyanate, see 2078 6.1 Tolylene diisocyanate, see 2078 6.1 Tolylethylene, inhibited, see 2618 3 TORPEDOES with bursting charge 0329 0330 0451 1 1 1 TORPEDOES, LIQUID FUELLED with inert head 0450 1 TORPEDOES, LIQUID FUELLED with or without bursting charge 0449 1 TOXIC BY INHALATION LIQUID, 3381 N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, 3382 N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, 3389 CORROSIVE, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, 3390 CORROSIVE, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, 3383 FLAMMABLE, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, 3384 FLAMMABLE, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, 3488 FLAMMABLE, CORROSIVE, N.O.S. with an LC50 lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, 3489 FLAMMABLE, CORROSIVE, N.O.S. with an LC50 lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, 3387 OXIDIZING, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, 3388 OXIDIZING, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, 3385 WATER-REACTIVE, N.O.S. with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, 3386 WATER-REACTIVE, N.O.S. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, 3490 WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, 3491 WATER-REACTIVE, FLAMMABLE, N.O.S. with an LC50 lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 3289 6.1 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 2927 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. TOXIC LIQUID, INORGANIC, N.O.S. TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 2930 6.1 TOXIC SOLID, INORGANIC, N.O.S. 3288 6.1 TOXIC SOLID, ORGANIC, N.O.S. 2811 6.1 TOXIC SOLID, OXIDIZING, N.O.S. 3086 6.1 TOXIC SOLID, SELF-HEATING, N.O.S. 3124 6.1 TOXIC SOLID, WATERREACTIVE, N.O.S. 3125 6.1 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 3172 6.1 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. 3462 6.1 TRACERS FOR AMMUNITION 0212 0306 1 1 Tremolite, see 2212 9 TRIALLYLAMINE 2610 3 TRIALLYL BORATE 2609 6.1 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 °C 2764 3 TRIAZINE PESTICIDE, LIQUID, TOXIC 2998 6.1 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 °C 2997 6.1 TRIAZINE PESTICIDE, SOLID, TOXIC 2763 6.1 Tribromoborane, see 2692 8 TRIBUTYLAMINE 2542 6.1 TRIBUTYLPHOSPHANE 3254 4.2 Trichloroacetaldehyde, see 2075 6.1 TRICHLOROACETIC ACID 1839 8 6.1 TRICHLOROACETIC ACID SOLUTION 2564 8 2929 6.1 Trichlororaceticaldehyde, see 2075 6.1 TRICHLOROACETYL CHLORIDE 2442 8 3287 6.1 TRICHLOROBENZENES, LIQUID 2321 6.1 TOXIC LIQUID, ORGANIC, N.O.S. 2810 6.1 TRICHLOROBUTENE 2322 6.1 TOXIC LIQUID, OXIDIZING, N.O.S. 3122 6.1 1,1,1-TRICHLOROETHANE 2831 6.1 TRICHLOROETHYLENE 1710 6.1 TOXIC LIQUID, WATERREACTIVE, N.O.S. 3123 6.1 TRICHLOROISOCYANURIC ACID, DRY 2468 5.1 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 3290 6.1 Trichloronitromethane, see 1580 6.1 TRICHLOROSILANE 1295 4.3 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 2928 6.1 - 567 - 1,3,5-Trichloro-s-triazine-2,4,6trione, see 2468 5.1 TRINITROBENZENE, dry or wetted 0214 with less than 30% water, by mass 1 2,4,6-Trichloro-1,3,5- triazine, see 2670 8 3367 4.1 TRICRESYL PHOSPHATE with more than 3% ortho isomer 2574 6.1 TRINITROBENZENE, WETTED with not less than 10% water, by mass TRIETHYLAMINE 1296 3 1354 4.1 Triethyl borate, see 1176 3 TRINITROBENZENE, WETTED with not less than 30% water, by mass TRIETHYLENETETRAMINE 2259 8 0386 1 Triethyl orthoformate, see 2524 3 TRINITROBENZENESULPHONIC ACID TRIETHYL PHOSPHITE 2323 3 0215 1 TRIFLUOROACETIC ACID 2699 8 TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass TRIFLUOROACETYL CHLORIDE 3057 2 3368 4.1 Trifluorobromomethane, see 1009 2 TRINITROBENZOIC ACID, WETTED with not less than 10% water, by mass Trifluorochloroethane, see 1983 2 4.1 1082 2 TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass 1355 TRIFLUOROCHLOROETHYLENE, STABILIZED, REFRIGERANT GAS R 1113 TRINITROCHLOROBENZENE 0155 1 Trifluorochloromethane, see 1022 2 4.1 2035 2 TRINITROCHLOROBENZENE WETTED with not less than 10% water, by mass 3365 1,1,1-TRIFLUOROETHANE TRIFLUOROMETHANE 1984 2 TRINITRO-m-CRESOL 0216 1 TRIFLUOROMETHANE, REFRIGERATED LIQUID 3136 2 TRINITROFLUORENONE 0387 1 2-TRIFLUOROMETHYLANILINE 2942 6.1 TRINITRONAPHTHALENE 0217 1 3-TRIFLUOROMETHYLANILINE 2948 6.1 TRINITROPHENETOLE 0218 1 TRIISOBUTYLENE 2324 3 TRINITROPHENOL, dry or wetted with less than 30% water, by mass 0154 1 TRIISOPROPYL BORATE 2616 3 4.1 6.1 TRIMETHYLAMINE, ANHYDROUS 1083 2 TRINITROPHENOL (PICRIC ACID), WETTED with not less than 30% water, by mass 1344 TRIMETHYLACETYL CHLORIDE 2438 4.1 1297 3 TRINITROPHENOL WETTED with not less than 10% water, by mass 3364 TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass TRINITROPHENYLMETHYLNITRAMINE 0208 1 1,3,5-TRIMETHYLBENZENE 2325 3 0219 1 TRIMETHYL BORATE 2416 3 TRIMETHYLCHLOROSILANE 1298 3 TRINITRORESORCINOL, dry or wetted with less than 20% water, or mixture of alcohol and water, by mass TRIMETHYLCYCLOHEXYLAMINE 2326 8 0394 1 Trimethylene chlorobromide, see 2688 6.1 TRINITRORESORCINOL, WETTED with not less than 20% water, or mixture of alcohol and water, by mass TRIMETHYLHEXAMETHYLENEDIAMINES 2327 8 1 TRIMETHYLHEXAMETHYLENE DIISOCYANATE 2328 6.1 TRINITROTOLUENE (TNT), dry or 0209 wetted with less than 30% water, by mass 1 2050 3 2,4,4-Trimethylpentene-2, see 2050 3 TRINITROTOLUENE AND HEXANITROSTILBENE MIXTURE 0388 2,4,4-Trimethylpentene-1, see TRIMETHYL PHOSPHITE 2329 3 0389 1 TRINITROANILINE 0153 1 TRINITROANISOLE 0213 1 TRINITROTOLUENE MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE - 568 - TRINITROTOLUENE AND TRINITROBENZENE MIXTURE 0388 1 Vehicle, flammable liquid powered 3166 9 Not subject to ADR TRINITROTOLUENE, WETTED with not less than 10% water, by mass 3366 4.1 Vehicle, fuel cell, flammable gas powered 3166 9 Not subject to ADR 3166 9 TRINITROTOLUENE, WETTED with not less than 30% water, by mass 1356 Vehicle, fuel cell, flammable liquid powered Not subject to ADR Villiaumite, see 1690 6.1 TRIPROPYLAMINE 2260 3 VINYL ACETATE, STABILIZED 1301 3 TRIPROPYLENE 2057 3 Vinylbenzene, see 2055 3 TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION 2501 6.1 VINYL BROMIDE, STABILIZED 1085 2 VINYL BUTYRATE, STABILIZED 2838 3 TRITONAL 0390 1 VINYL CHLORIDE, STABILIZED 1086 2 Tropilidene, see 2603 3 VINYL CHLOROACETATE 2589 6.1 TUNGSTEN HEXAFLUORIDE 2196 2 1302 3 TURPENTINE 1299 3 VINYL ETHYL ETHER, STABILIZED TURPENTINE SUBSTITUTE 1300 3 VINYL FLUORIDE, STABILIZED 1860 2 UNDECANE 2330 3 VINYLIDENE CHLORIDE, STABILIZED 1303 3 URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE, less than 0.1 kg per package, non-fissile or fissile-excepted 3507 8 VINYL ISOBUTYL ETHER, STABILIZED 1304 3 VINYL METHYL ETHER, STABILIZED 1087 2 UREA HYDROGEN PEROXIDE 1511 5.1 VINYLPYRIDINES, STABILIZED 3073 6.1 UREA NITRATE, dry or wetted with 0220 less than 20% water, by mass 1 VINYLTOLUENES, STABILIZED 2618 3 VINYLTRICHLOROSILANE 1305 3 UREA NITRATE, WETTED with not less than 10% water, by mass 3370 4.1 Warheads for guided missiles, see UREA NITRATE, WETTED with not less than 20% water, by mass 1357 4.1 0286 0287 0369 0370 0371 1 1 1 1 1 WARHEADS, ROCKET with burster or expelling charge 0370 0371 1 1 WARHEADS, ROCKET with bursting charge 0286 0287 0369 1 1 1 WARHEADS, TORPEDO with bursting charge 0221 1 WATER-REACTIVE LIQUID, N.O.S. 3148 4.3 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 3129 4.3 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 3130 4.3 WATER-REACTIVE SOLID, N.O.S. 2813 4.3 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 3131 4.3 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 3132 4.3 WATER-REACTIVE SOLID, OXIDIZING, N.O.S. 3133 4.3 4.1 Valeral, see 2058 3 VALERALDEHYDE 2058 3 n-Valeraldehyde, see 2058 3 Valeric aldehyde, see 2058 3 VALERYL CHLORIDE 2502 8 VANADIUM COMPOUND, N.O.S. 3285 6.1 Vanadium (IV) oxide sulphate, see 2931 6.1 Vanadium oxysulphate, see 2931 6.1 VANADIUM OXYTRICHLORIDE 2443 8 VANADIUM PENTOXIDE, nonfused form 2862 6.1 VANADIUM TETRACHLORIDE 2444 8 VANADIUM TRICHLORIDE 2475 8 VANADYL SULPHATE 2931 6.1 Varnish, see 1263 3066 3469 3470 3 8 3 8 3166 9 Vehicle, flammable gas powered Not subject to ADR - 569 - Carriage prohibited WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. 3135 4.3 WATER-REACTIVE SOLID, TOXIC, N.O.S. 3134 4.3 White arsenic, see 1561 6.1 White spirit, see 1300 3 WOOD PRESERVATIVES, LIQUID 1306 3 Not subject to ADR ZINC DUST 1436 4.3 ZINC FLUOROSILICATE 2855 6.1 Zinc hexafluorosilicate, see 2855 6.1 ZINC HYDROSULPHITE, see 1931 9 ZINC NITRATE 1514 5.1 ZINC PERMANGANATE 1515 5.1 ZINC PEROXIDE 1516 5.1 ZINC PHOSPHIDE 1714 4.3 ZINC POWDER 1436 4.3 ZINC RESINATE 2714 4.1 Zinc selenate, see 2630 4.1 Zinc selenite, see 2630 4.1 Wool waste, wet 1387 4.2 XANTHATES 3342 4.2 XENON 2036 2 XENON, REFRIGERATED LIQUID 2591 2 XYLENES 1307 3 Zinc silicofluoride, see 2855 6.1 XYLENOLS, LIQUID 3430 6.1 2858 4.1 XYLENOLS, SOLID 2261 6.1 XYLIDINES, LIQUID 1711 6.1 ZIRCONIUM, DRY, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns) XYLIDINES, SOLID 3452 6.1 2009 4.2 Xylols, see 1307 3 ZIRCONIUM, DRY, finished sheets, strip or coiled wire XYLYL BROMIDE, LIQUID 1701 6.1 ZIRCONIUM HYDRIDE 1437 4.1 XYLYL BROMIDE, SOLID 3417 6.1 ZIRCONIUM NITRATE 2728 5.1 ZINC AMMONIUM NITRITE 1512 5.1 0236 1 ZINC ARSENATE 1712 6.1 ZIRCONIUM PICRAMATE, dry or wetted with less than 20% water, by mass ZINC ARSENATE AND ZINC ARSENITE MIXTURE 1712 6.1 ZIRCONIUM PICRAMATE, WETTED with not less than 20% water, by mass 1517 4.1 ZINC ARSENITE 1712 6.1 ZIRCONIUM POWDER, DRY 2008 4.2 ZINC ASHES 1435 4.3 4.1 2693 8 ZIRCONIUM POWDER, WETTED with not less than 25% water 1358 Zinc bisulphite solution, see ZINC BROMATE 2469 5.1 ZIRCONIUM SCRAP 1932 4.2 ZINC CHLORATE 1513 5.1 1308 3 ZINC CHLORIDE, ANHYDROUS 2331 8 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID ZINC CHLORIDE SOLUTION 1840 8 ZIRCONIUM TETRACHLORIDE 2503 8 ZINC CYANIDE 1713 6.1 ZINC DITHIONITE 1931 9 - 570 - CHAPTER 3.3 SPECIAL PROVISIONS APPLICABLE TO CERTAIN ARTICLES OR SUBSTANCES 3.3.1 When Column (6) of Table A of Chapter 3.2 indicates that a special provision is relevant to a substance or article, the meaning and requirements of that special provision are as set forth below. 16 Samples of new or existing explosive substances or articles may be carried as directed by the competent authorities (see 2.2.1.1.3) for purposes including: testing, classification, research and development, quality control, or as a commercial sample. Explosive samples which are not wetted or desensitized shall be limited to 10 kg in small packages as specified by the competent authorities. Explosive samples which are wetted or desensitized shall be limited to 25 kg. 23 Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. 32 This substance is not subject to the requirements of ADR when in any other form. 37 This substance is not subject to the requirements of ADR when coated. 38 This substance is not subject to the requirements of ADR when it contains not more than 0.1% calcium carbide. 39 This substance is not subject to the requirements of ADR when it contains less than 30% or not less than 90% silicon. 43 When offered for carriage as pesticides, these substances shall be carried under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see 2.2.61.1.10 to 2.2.61.1.11.2). 45 Antimony sulphides and oxides which contain not more than 0.5% of arsenic calculated on the total mass are not subject to the requirements of ADR. 47 Ferricyanides and ferrocyanides are not subject to the requirements of ADR. 48 The carriage of this substance, when it contains more than 20% hydrocyanic acid, is prohibited. 59 These substances are not subject to the requirements of ADR when they contain not more than 50% magnesium. 60 If the concentration is more than 72%, the carriage of this substance is prohibited. 61 The technical name which shall supplement the proper shipping name shall be the ISO common name (see also ISO 1750:1981 "Pesticides and other agrochemicals - common names", as amended), other name listed in the WHO "Recommended Classification of Pesticides by Hazard and Guidelines to Classification" or the name of the active substance (see also 3.1.2.8.1 and 3.1.2.8.1.1). 62 This substance is not subject to the requirements of ADR when it contains not more than 4% sodium hydroxide. 65 Hydrogen peroxide aqueous solutions with less than 8% hydrogen peroxide are not subject to the requirements of ADR. 66 Cinnabar is not subject to the requirements of ADR. 103 The carriage of ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt is prohibited. - 571 - 105 Nitrocellulose meeting the descriptions of UN No. 2556 or UN No. 2557 may be classified in Class 4.1. 113 The carriage of chemically unstable mixtures is prohibited. 119 Refrigerating machines include machines or other appliances which have been designed for the specific purpose of keeping food or other items at a low temperature in an internal compartment, and air conditioning units. Refrigerating machines and refrigerating machine components are not subject to the provisions of ADR if they contain less than 12 kg of gas in Class 2, group A or O according to 2.2.2.1.3, or if they contain less than 12 litres ammonia solution (UN No. 2672). 122 The subsidiary risks, control and emergency temperatures if any, and the UN number (generic entry) for each of the currently assigned organic peroxide formulations are given in 2.2.52.4, 4.1.4.2 packing instruction IBC520 and 4.2.5.2.6 portable tank instruction T23. 123 (Reserved) 127 Other inert material or inert material mixture may be used, provided this inert material has identical phlegmatizing properties. 131 The phlegmatized substance shall be significantly less sensitive than dry PETN. 135 The dihydrated sodium salt of dichloroisocyanuric acid does not meet the criteria for inclusion in Class 5.1 and is not subject to ADR unless meeting the criteria for inclusion in another Class. 138 p-Bromobenzyl cyanide is not subject to the requirements of ADR. 141 Products which have undergone sufficient heat treatment so that they present no hazard during carriage are not subject to the requirements of ADR. 142 Solvent extracted soya bean meal containing not more than 1.5% oil and 11% moisture, which is substantially free of flammable solvent, is not subject to the requirements of ADR. 144 An aqueous solution containing not more than 24% alcohol by volume is not subject to the requirements of ADR. 145 Alcoholic beverages of packing group III, when carried in receptacles of 250 litres or less, are not subject to the requirements of ADR. 152 The classification of this substance will vary with particle size and packaging, but borderlines have not been experimentally determined. Appropriate classifications shall be made in accordance with 2.2.1. 153 This entry applies only if it is demonstrated, on the basis of tests, that the substances when in contact with water are not combustible nor show a tendency to auto-ignition and that the mixture of gases evolved is not flammable. 162 (Deleted) 163 A substance mentioned by name in Table A of Chapter 3.2 shall not be carried under this entry. Substances carried under this entry may contain 20% or less nitrocellulose provided the nitrocellulose contains not more than 12.6% nitrogen (by dry mass). 168 Asbestos which is immersed or fixed in a natural or artificial binder (such as cement, plastics, asphalt, resins or mineral ore) in such a way that no escape of hazardous quantities of respirable asbestos fibres can occur during carriage is not subject to the requirements of ADR. Manufactured articles containing asbestos and not meeting this provision are nevertheless not subject to the requirements of ADR when packed so that no escape of hazardous quantities of respirable asbestos fibres can occur during carriage. - 572 - 169 Phthalic anhydride in the solid state and tetrahydrophthalic anhydrides, with not more than 0.05% maleic anhydride, are not subject to the requirements of ADR. Phthalic anhydride molten at a temperature above its flash-point, with not more than 0.05% maleic anhydride, shall be classified under UN No. 3256. 172 Where a radioactive material has (a) subsidiary risk(s): (a) The substance shall be allocated to packing group I, II or III, if appropriate, by application of the packing group criteria provided in Part 2 corresponding to the nature of the predominant subsidiary risk; (b) Packages shall be labelled with subsidiary risk labels corresponding to each subsidiary risk exhibited by the material; corresponding placards shall be affixed to vehicles or containers in accordance with the relevant provisions of 5.3.1; (c) For the purposes of documentation and package marking, the proper shipping name shall be supplemented with the name of the constituents which most predominantly contribute to this (these) subsidiary risk(s) and which shall be enclosed in parenthesis; (d) The dangerous goods transport document shall indicate the label model number(s) corresponding to each subsidiary risk in parenthesis after the Class number "7" and, where assigned the packing group as required by 5.4.1.1.1 (d). For packing, see also 4.1.9.1.5. 177 Barium sulphate is not subject to the requirements of ADR. 178 This designation shall be used only when no other appropriate designation exists in Table A of Chapter 3.2, and only with the approval of the competent authority of the country of origin (see 2.2.1.1.3). 181 Packages containing this type of substance shall bear a label conforming to model No. 1 (see 5.2.2.2.2) unless the competent authority of the country of origin has permitted this label to be dispensed with for the specific packaging employed because test data have proved that the substance in this packaging does not exhibit explosive behaviour (see 5.2.2.1.9). 182 The group of alkali metals includes lithium, sodium, potassium, rubidium and caesium. 183 The group of alkaline earth metals includes magnesium, calcium, strontium and barium. 186 In determining the ammonium nitrate content, all nitrate ions for which a molecular equivalent of ammonium ions is present in the mixture shall be calculated as ammonium nitrate. 188 Cells and batteries offered for carriage are not subject to other provisions of ADR if they meet the following: (a) For a lithium metal or lithium alloy cell, the lithium content is not more than 1 g, and for a lithium ion cell, the Watt-hour rating is not more than 20 Wh; (b) For a lithium metal or lithium alloy battery the aggregate lithium content is not more than 2 g, and for a lithium ion battery, the Watt-hour rating is not more than 100 Wh. Lithium ion batteries subject to this provision shall be marked with the Watt-hour rating on the outside case, except those manufactured before 1 January 2009; (c) Each cell or battery meets the provisions of 2.2.9.1.7 (a) and (e); (d) Cells and batteries, except when installed in equipment, shall be packed in inner packagings that completely enclose the cell or battery. Cells and batteries shall be protected so as to prevent short circuits. This includes protection against contact with conductive materials within the same packaging that could lead to a short circuit. The inner packagings shall be packed in strong outer packagings which conform to the provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.5; - 573 - (e) Cells and batteries when installed in equipment shall be protected from damage and short circuit, and the equipment shall be equipped with an effective means of preventing accidental activation. This requirement does not apply to devices which are intentionally active in carriage (radio frequency identification (RFID) transmitters, watches, sensors, etc.) and which are not capable of generating a dangerous evolution of heat. When batteries are installed in equipment, the equipment shall be packed in strong outer packagings constructed of suitable material of adequate strength and design in relation to the packaging’s capacity and its intended use unless the battery is afforded equivalent protection by the equipment in which it is contained; (f) Except for packages containing button cell batteries installed in equipment (including circuit boards), or no more than four cells installed in equipment or no more than two batteries installed in equipment, each package shall be marked with the following: (g) (i) an indication that the package contains "lithium metal" or "lithium ion" cells or batteries, as appropriate; (ii) an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; (iii) an indication that special procedures shall be followed in the event the package is damaged, to include inspection and repacking if necessary; and (iv) a telephone number for additional information; Each consignment of one or more packages marked in accordance with paragraph (f) shall be accompanied with a document including the following: (i) an indication that the package contains "lithium metal" or "lithium ion" cells or batteries, as appropriate; (ii) an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; (iii) an indication that special procedures shall be followed in the event the package is damaged, to include inspection and repacking if necessary; and (iv) a telephone number for additional information; (h) Except when batteries are installed in equipment, each package shall be capable of withstanding a 1.2 m drop test in any orientation without damage to cells or batteries contained therein, without shifting of the contents so as to allow battery to battery (or cell to cell) contact and without release of contents; and (i) Except when batteries are installed in or packed with equipment, packages shall not exceed 30 kg gross mass. As used above and elsewhere in ADR, "lithium content" means the mass of lithium in the anode of a lithium metal or lithium alloy cell. Separate entries exist for lithium metal batteries and lithium ion batteries to facilitate the carriage of these batteries for specific modes of carriage and to enable the application of different emergency response actions. 190 Aerosol dispensers shall be provided with protection against inadvertent discharge. Aerosols with a capacity not exceeding 50 ml containing only non-toxic constituents are not subject to the requirements of ADR. 191 Receptacles, small, with a capacity not exceeding 50 ml, containing only non-toxic constituents are not subject to the requirements of ADR. 194 The control and emergency temperatures, if any, and the UN number (generic entry) for each of the currently assigned self-reactive substances are given in 2.2.41.4. - 574 - 196 Formulations which in laboratory testing neither detonate in the cavitated state nor deflagrate, which show no effect when heated under confinement and which exhibit no explosive power may be carried under this entry. The formulation must also be thermally stable (i.e. the SADT is 60 °C or higher for a 50 kg package). Formulations not meeting these criteria shall be carried under the provisions of Class 5.2, (see 2.2.52.4). 198 Nitrocellulose solutions containing not more than 20% nitrocellulose may be carried as paint, perfumery products or printing ink, as applicable (see UN Nos. 1210, 1263, 1266, 3066, 3469 and 3470). 199 Lead compounds which, when mixed in a ratio of 1:1000 with 0.07M hydrochloric acid and stirred for one hour at a temperature of 23 °C ± 2 °C, exhibit a solubility of 5% or less (see ISO 3711:1990 "Lead chromate pigments and lead chromate -molybdate pigments – Specifications and methods of test") are considered insoluble and are not subject to the requirements of ADR unless they meet the criteria for inclusion in another class. 201 Lighters and lighter refills shall comply with the provisions of the country in which they were filled. They shall be provided with protection against inadvertent discharge. The liquid portion of the gas shall not exceed 85% of the capacity of the receptacle at 15 °C. The receptacles, including the closures, shall be capable of withstanding an internal pressure of twice the pressure of the liquefied petroleum gas at 55 °C. The valve mechanisms and ignition devices shall be securely sealed, taped or otherwise fastened or designed to prevent operation or leakage of the contents during carriage. Lighters shall not contain more than 10 g of liquefied petroleum gas. Lighter refills shall not contain more than 65 g of liquefied petroleum gas. NOTE: For waste lighters collected separately see Chapter 3.3, special provision 654. 203 This entry shall not be used for polychlorinated biphenyls, liquid, UN No. 2315 and polychlorinated biphenyls, solid, UN No.3432. 204 (Deleted) 205 This entry shall not be used for UN No. 3155 PENTACHLOROPHENOL. 207 Polymeric beads and plastics moulding compounds may be made from polystyrene, poly(methyl methacrylate) or other polymeric material. 208 The commercial grade of calcium nitrate fertilizer, when consisting mainly of a double salt (calcium nitrate and ammonium nitrate) containing not more than 10% ammonium nitrate and at least 12% water of crystallization, is not subject to the requirements of ADR. 210 Toxins from plant, animal or bacterial sources which contain infectious substances, or toxins that are contained in infectious substances, shall be classified in Class 6.2. 215 This entry only applies to the technically pure substance or to formulations derived from it having an SADT higher than 75 °C and therefore does not apply to formulations which are self-reactive substances (for self-reactive substances, see 2.2.41.4). Homogeneous mixtures containing not more than 35% by mass of azodicarbonamide and at least 65% of inert substance are not subject to the requirements of ADR unless criteria of other classes are met. Mixtures of solids which are not subject to the requirements of ADR and flammable liquids may be carried under this entry without first applying the classification criteria of Class 4.1, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, vehicle or container is closed. Sealed packets and articles containing less than 10 ml of a packing group II or III flammable liquid absorbed into a solid material are not subject to ADR provided there is no free liquid in the packet or article. 216 217 Mixtures of solids which are not subject to the requirements of ADR and toxic liquids may be carried under this entry without first applying the classification criteria of Class 6.1, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, vehicle or container is closed. This entry shall not be used for solids containing a packing group I liquid. - 575 - 218 Mixtures of solids which are not subject to the requirements of ADR and corrosive liquids may be carried under this entry without first applying the classification criteria of Class 8, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, vehicle or container is closed. 219 Genetically modified microorganisms (GMMOs) and genetically modified organisms (GMOs) packed and marked in accordance with packing instruction P904 of 4.1.4.1 are not subject to any other requirements of ADR. If GMMOs or GMOs meet the criteria for inclusion in Class 6.1 or 6.2 (see 2.2.61.1 and 2.2.62.1) the requirements in ADR for the carriage of toxic substances or infectious substances apply. 220 Only the technical name of the flammable liquid component of this solution or mixture shall be shown in parentheses immediately following the proper shipping name. 221 Substances included under this entry shall not be of packing group I. 224 Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is no greater than in its liquid state, the substance shall remain liquid during normal transport conditions. It shall not freeze at temperatures above -15 °C. 225 Fire extinguishers under this entry may include installed actuating cartridges (cartridges, power device of classification code 1.4C or 1.4S), without changing the classification of Class 2, group A or O according to 2.2.2.1.3 provided the total quantity of deflagrating (propellant) explosives does not exceed 3.2 g per extinguishing unit. Fire extinguishers shall be manufactured, tested, approved and labelled according to the provisions applied in the country of manufacture. NOTE: "Provisions applied in the country of manufacture" means the provisions applicable in the country of manufacture or those applicable in the country of use. Fire extinguishers under this entry include: (a) portable fire extinguishers for manual handling and operation; (b) fire extinguishers for installation in aircraft; (c) fire extinguishers mounted on wheels for manual handling; (d) fire extinguishing equipment or machinery mounted on wheels or wheeled platforms or units carried similar to (small) trailers, and (e) fire extinguishers composed of a non-rollable pressure drum and equipment, and handled e.g. by fork lift or crane when loaded or unloaded. NOTE: Pressure receptacles which contain gases for use in the above-mentioned fire extinguishers or for use in stationary fire-fighting installations shall meet the requirements of Chapter 6.2 and all requirements applicable to the relevant gas when these pressure receptacles are carried separately. 226 Formulations of this substance containing not less than 30% non-volatile, non-flammable phlegmatizer are not subject to the requirements of ADR. 227 When phlegmatized with water and inorganic inert material the content of urea nitrate may not exceed 75% by mass and the mixture shall not be capable of being detonated by the Series 1, type (a), test in the Manual of Tests and Criteria, Part 1. 228 Mixtures not meeting the criteria for flammable gases (see 2.2.2.1.5) shall be carried under UN No. 3163. 230 Lithium cells and batteries may be carried under this entry if they meet the provisions of 2.2.9.1.7. - 576 - 235 This entry applies to articles which contain Class 1 explosive substances and which may also contain dangerous goods of other classes. These articles are used to enhance safety in vehicles, vessels or aircraft – e.g. air bag inflators, air bag modules, seat-belt pretensioners, and pyromechanical devices. 236 Polyester resin kits consist of two components: a base material (Class 3, packing group II or III) and an activator (organic peroxide). The organic peroxide shall be type D, E or F, not requiring temperature control. Packing group shall be II or III, according to the criteria for Class 3, applied to the base material. The quantity limit referred to in Column (7a) of Table A of Chapter 3.2 applies to the base material. 237 The membrane filters, including paper separators, coating or backing materials, etc., that are present in carriage, shall not be liable to propagate a detonation as tested by one of the tests described in the Manual of Tests and Criteria, Part I, Test series 1 (a). In addition the competent authority may determine, on the basis of the results of suitable burning rate tests taking account of the standard tests in the Manual of Tests and Criteria, Part III, sub-section 33.2.1, that nitrocellulose membrane filters in the form in which they are to be carried are not subject to the requirements applicable to flammable solids in Class 4.1. 238 (a) Batteries can be considered as non-spillable provided that they are capable of withstanding the vibration and pressure differential tests given below, without leakage of battery fluid. Vibration test: The battery is rigidly clamped to the platform of a vibration machine and a simple harmonic motion having an amplitude of 0.8 mm (1.6 mm maximum total excursion) is applied. The frequency is varied at the rate of 1 Hz/min between the limits of 10 Hz and 55 Hz. The entire range of frequencies and return is traversed in 95 ± 5 minutes for each mounting position (direction of vibration) of the battery. The battery is tested in three mutually perpendicular positions (to include testing with fill openings and vents, if any, in an inverted position) for equal time periods. Pressure differential test: Following the vibration test, the battery is stored for six hours at 24 °C ± 4 °C while subjected to a pressure differential of at least 88 kPa. The battery is tested in three mutually perpendicular positions (to include testing with fill openings and vents, if any, in an inverted position) for at least six hours in each position. (b) 239 Non-spillable batteries are not subject to the requirements of ADR if, at a temperature of 55 °C, the electrolyte will not flow from a ruptured or cracked case and there is no free liquid to flow and if, as packaged for carriage, the terminals are protected from short circuit. Batteries or cells shall not contain dangerous substances other than sodium, sulphur or sodium compounds (e.g. sodium polysulphides and sodium tetrachloroaluminate). Batteries or cells shall not be offered for carriage at a temperature such that liquid elemental sodium is present in the battery or cell unless approved and under the conditions established by the competent authority of the country of origin. If the country of origin is not a Contracting Party to ADR, the approval and conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. Cells shall consist of hermetically sealed metal casings which fully enclose the dangerous substances and which are so constructed and closed as to prevent the release of the dangerous substances under normal conditions of carriage. Batteries shall consist of cells secured within and fully enclosed by a metal casing so constructed and closed as to prevent the release of the dangerous substances under normal conditions of carriage. 240 See the last NOTE in 2.2.9.1.7. - 577 - 241 The formulation shall be prepared so that it remains homogeneous and does not separate during carriage. Formulations with low nitrocellulose contents and not showing dangerous properties when tested for their liability to detonate, deflagrate or explode when heated under defined confinement by tests of Test series 1 (a), 2 (b) and 2 (c) respectively in the Manual of Tests and Criteria, Part I and not being a flammable solid when tested in accordance with test No. 1 in the Manual of Tests and Criteria, Part III, sub-section 33.2.1.4 (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm) are not subject to the requirements of ADR. 242 Sulphur is not subject to the requirements of ADR when it has been formed to a specific shape (e.g. prills, granules, pellets, pastilles or flakes). 243 Gasoline, motor spirit and petrol for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) shall be assigned to this entry regardless of variations in volatility. 244 This entry includes e.g. aluminium dross, aluminium skimmings, spent cathodes, spent potliner, and aluminium salt slags. 247 Alcoholic beverages containing more than 24% alcohol but not more than 70% by volume, when carried as part of the manufacturing process, may be carried in wooden barrels with a capacity of more than 250 litres and not more than 500 litres meeting the general requirements of 4.1.1, as appropriate, on the following conditions: (a) The wooden barrels shall be checked and tightened before filling; (b) Sufficient ullage (not less than 3%) shall be left to allow for the expansion of the liquid; (c) The wooden barrels shall be carried with the bungholes pointing upwards; (d) The wooden barrels shall be carried in containers meeting the requirements of the CSC. Each wooden barrel shall be secured in custom-made cradles and be wedged by appropriate means to prevent it from being displaced in any way during carriage. 249 Ferrocerium, stabilized against corrosion, with a minimum iron content of 10% is not subject to the requirements of ADR. 250 This entry may only be used for samples of chemicals taken for analysis in connection with the implementation of the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction. The carriage of substances under this entry shall be in accordance with the chain of custody and security procedures specified by the Organisation for the Prohibition of Chemical Weapons. The chemical sample may only be carried providing prior approval has been granted by the competent authority or the Director General of the Organisation for the Prohibition of Chemical Weapons and providing the sample complies with the following provisions: 251 (a) It shall be packed according to packing instruction 623 in the ICAO Technical Instructions (see S-3-8 of the Supplement); and (b) During carriage, a copy of the document of approval for transport, showing the quantity limitations and the packing provisions shall be attached to the transport document. The entry CHEMICAL KIT or FIRST AID KIT is intended to apply to boxes, cases etc. containing small quantities of various dangerous goods which are used for example for medical, analytical or testing or repair purposes. Such kits may not contain dangerous goods for which the quantity "0"has been indicated in Column (7a) of Table A of Chapter 3.2. Components shall not react dangerously (see "dangerous reaction" in 1.2.1). The total quantity of dangerous goods in any one kit shall not exceed either 1 l or 1 kg. The packing group assigned to the kit as a whole shall be the most stringent packing group assigned to any individual substance in the kit. Where the kit contains only dangerous goods to which no packing group is assigned, no packing group need be indicated on the dangerous goods transport document. - 578 - Kits which are carried on board vehicles for first-aid or operating purposes are not subject to the requirements of ADR. Chemical kits and first aid kits containing dangerous goods in inner packagings which do not exceed the quantity limits for limited quantities applicable to individual substances as specified in Column (7a) of Table A of Chapter 3.2 may be carried in accordance with Chapter 3.4. 252 Provided the ammonium nitrate remains in solution under all conditions of carriage, aqueous solutions of ammonium nitrate, with not more than 0.2% combustible material, in a concentration not exceeding 80%, are not subject to the requirements of ADR. 266 This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be carried unless specifically authorized by the competent authority (see 2.2.1.1). 267 Any explosives, blasting, type C containing chlorates shall be segregated from explosives containing ammonium nitrate or other ammonium salts. 270 Aqueous solutions of Class 5.1 inorganic solid nitrate substances are considered as not meeting the criteria of Class 5.1 if the concentration of the substances in solution at the minimum temperature encountered during carriage is not greater than 80% of the saturation limit. 271 Lactose or glucose or similar materials, may be used as a phlegmatizer provided that the substance contains not less than 90%, by mass, of phlegmatizer. The competent authority may authorize these mixtures to be classified in Class 4.1 on the basis of a test Series 6(c) of Section 16 of Part I of the Manual of Tests and Criteria on at least three packages as prepared for carriage. Mixtures containing at least 98%, by mass, of phlegmatizer are not subject to the requirements of ADR. Packages containing mixtures with not less than 90%, by mass, of phlegmatizer need not bear a label conforming to model No. 6.1. 272 This substance shall not be carried under the provisions of Class 4.1 unless specifically authorized by the competent authority (see UN No. 0143 or UN No. 0150 as appropriate). 273 Maneb and maneb preparations stabilized against self-heating need not be classified in Class 4.2 when it can be demonstrated by testing that a cubic volume of 1 m3 of substance does not self-ignite and that the temperature at the centre of the sample does not exceed 200 °C, when the sample is maintained at a temperature of not less than 75 °C ± 2 °C for a period of 24 hours. 274 The provisions of 3.1.2.8 apply. 278 These substances shall not be classified and carried unless authorized by the competent authority on the basis of results from Series 2 tests and a Series 6(c) test of Part I of the Manual of Tests and Criteria on packages as prepared for carriage (see 2.2.1.1). The competent authority shall assign the packing group on the basis of 2.2.3 criteria and the package type used for the Series 6(c) test. 279 The substance is assigned to this classification or packing group based on human experience rather than the strict application of classification criteria set out in ADR. 280 This entry applies to safety devices for vehicles, vessels or aircraft, e.g. air bag inflators, air bag modules, seat-belt pretensioners, and pyromechanical devices, which contain dangerous goods of Class 1 or of other classes, when carried as component parts and if these articles as presented for carriage have been tested in accordance with Test Series 6(c) of Part 1 of the Manual of Tests and Criteria, with no explosion of the device, no fragmentation of device casing or pressure receptacle, and no projection hazard nor thermal effect which would significantly hinder fire-fighting or emergency response efforts in the immediate vicinity. This entry does not apply to life saving appliances described in special provision 296 (UN Nos. 2990 and 3072). 282 (Deleted) - 579 - 283 Articles, containing gas, intended to function as shock absorbers, including impact energyabsorbing devices, or pneumatic springs are not subject to the requirements of ADR provided: (a) Each article has a gas space capacity not exceeding 1.6 litres and a charge pressure not exceeding 280 bar where the product of the capacity (litres) and charge pressure (bars) does not exceed 80 (i.e. 0.5 litres gas space and 160 bar charge pressure, 1 litre gas space and 80 bar charge pressure, 1.6 litres gas space and 50 bar charge pressure, 0.28 litres gas space and 280 bar charge pressure); (b) Each article has a minimum burst pressure of 4 times the charge pressure at 20 °C for products not exceeding 0.5 litres gas space capacity and 5 times charge pressure for products greater than 0.5 litres gas space capacity; (c) Each article is manufactured from material which will not fragment upon rupture; (d) Each article is manufactured in accordance with a quality assurance standard acceptable to the competent authority; and (e) The design type has been subjected to a fire test demonstrating that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, such that the article will not fragment and that the article does not rocket. See also 1.1.3.2 (d) for equipment used for the operation of the vehicle. 284 An oxygen generator, chemical, containing oxidizing substances shall meet the following conditions: (a) The generator when containing an explosive actuating device shall only be carried under this entry when excluded from Class 1 in accordance with the NOTE under paragraph 2.2.1.1.1 (b); (b) The generator, without its packaging, shall be capable of withstanding a 1.8 m drop test onto a rigid, non-resilient, flat and horizontal surface, in the position most likely to cause damage, without loss of its contents and without actuation; (c) When a generator is equipped with an actuating device, it shall have at least two positive means of preventing unintentional actuation. 286 Nitrocellulose membrane filters covered by this entry, each with a mass not exceeding 0.5 g, are not subject to the requirements of ADR when contained individually in an article or a sealed packet. 288 These substances shall not be classified and carried unless authorized by the competent authority on the basis of results from Series 2 tests and a Series 6(c) test of Part I of the Manual of tests and Criteria on packages as prepared for carriage (see 2.2.1.1). 289 Safety devices, electrically initiated and safety devices, pyrotechnic installed in vehicles, wagons, vessels or aircraft or in completed components such as steering columns, door panels, seats, etc. are not subject to ADR. 290 When this radioactive material meets the definitions and criteria of other classes as defined in Part 2, it shall be classified in accordance with the following: (a) Where the substance meets the criteria for dangerous goods in excepted quantities as set out in Chapter 3.5, the packagings shall be in accordance with 3.5.2 and meet the testing requirements of 3.5.3. All other requirements applicable to radioactive material, excepted packages as set out in 1.7.1.5 shall apply without reference to the other class; (b) Where the quantity exceeds the limits specified in 3.5.1.2 the substance shall be classified in accordance with the predominant subsidiary risk. The transport document shall describe the substance with the UN number and proper shipping name applicable to the other class supplemented with the name applicable to the radioactive excepted package according to Column (2) of Table A of Chapter 3.2, and the substance shall be carried in accordance with the provisions applicable to that UN number. An example of the information shown on the transport document is: - 580 - "UN 1993, Flammable liquid, n.o.s. (ethanol and toluene mixture), Radioactive material, excepted package – limited quantity of material, 3, PG II". In addition, the requirements of 2.2.7.2.4.1 shall apply; (c) The provisions of Chapter 3.4 for the carriage of dangerous goods packed in limited quantities shall not apply to substances classified in accordance with sub-paragraph (b); (d) When the substance meets a special provision that exempts this substance from all dangerous goods provisions of the other classes it shall be classified in accordance with the applicable UN number of Class 7 and all requirements specified in 1.7.1.5 shall apply. 291 Flammable liquefied gases shall be contained within refrigerating machine components. These components shall be designed and tested to at least three times the working pressure of the machinery. The refrigerating machines shall be designed and constructed to contain the liquefied gas and preclude the risk of bursting or cracking of the pressure retaining components during normal conditions of carriage. Refrigerating machines and refrigerating-machine components are not subject to the requirements of ADR if they contain less than 12 kg of gas. 292 (Deleted) 293 The following definitions apply to matches: (a) (b) Fusee matches are matches the heads of which are prepared with a friction-sensitive igniter composition and a pyrotechnic composition which burns with little or no flame, but with intense heat; Safety matches are matches which are combined with or attached to the box, book or card that can be ignited by friction only on a prepared surface; (c) Strike anywhere matches are matches that can be ignited by friction on a solid surface; (d) Wax Vesta matches are matches that can be ignited by friction either on a prepared surface or on a solid surface. 295 Batteries need not be individually marked and labelled if the pallet bears the appropriate mark and label. 296 These entries apply to life-saving appliances such as life rafts, personal flotation devices and self-inflating slides. UN No. 2990 applies to self-inflating appliances and UN No. 3072 applies to life-saving appliances that are not self-inflating. Life-saving appliances may contain: (a) Signal devices (Class 1) which may include smoke and illumination signal flares packed in packagings that prevent them from being inadvertently activated; (b) For UN No. 2990 only, cartridges, power device of Division 1.4, compatibility group S, may be contained for purposes of the self-inflating mechanism and provided that the quantity of explosives per appliance does not exceed 3.2 g; (c) Class 2 compressed or liquefied gases, group A or O, according to 2.2.2.1.3; (d) Electric storage batteries (Class 8) and lithium batteries (Class 9); (e) First aid kits or repair kits containing small quantities of dangerous goods (e.g.: substances of Class 3, 4.1, 5.2, 8 or 9); or (f) "Strike anywhere" matches packed in packagings that prevent them from being inadvertently activated. Life-saving appliances packed in strong rigid outer packagings with a total maximum gross mass of 40 kg, containing no dangerous goods other than compressed or liquefied gases of Class 2, group A or group O, in receptacles with a capacity not exceeding 120 ml, installed solely for the purpose of the activation of the appliance, are not subject to the requirements of ADR. 298 (Deleted) - 581 - 300 Fish meal, fish scrap and krill meal shall not be loaded if the temperature at the time of loading exceeds 35 °C or 5 °C above the ambient temperature whichever is higher. 302 Fumigated cargo transport units containing no other dangerous goods are only subject to the provisions of 5.5.2. 303 Receptacles shall be assigned to the classification code of the gas or mixture of gases contained therein determined in accordance with the provisions of section 2.2.2. 304 This entry may only be used for the transport of non-activated batteries which contain dry potassium hydroxide and which are intended to be activated prior to use by addition of an appropriate amount of water to the individual cells. 305 These substances are not subject to the requirements of ADR when in concentrations of not more than 50 mg/kg. 306 This entry may only be used for substances that are too insensitive for acceptance into Class 1 when tested in accordance with Test Series 2 (see Manual of Tests and Criteria, Part I). 307 This entry may only be used for uniform mixtures containing ammonium nitrate as the main ingredient within the following composition limits: 309 (a) Not less than 90% ammonium nitrate with not more than 0.2% total combustible/organic material calculated as carbon and with added matter, if any, which is inorganic and inert towards ammonium nitrate; or (b) Less than 90% but more than 70% ammonium nitrate with other inorganic materials or more than 80% but less than 90% ammonium nitrate mixed with calcium carbonate and/or dolomite and/or mineral calcium sulphate and not more than 0.4% total combustible/organic material calculated as carbon; or (c) Nitrogen type ammonium nitrate based fertilizers containing mixtures of ammonium nitrate and ammonium sulphate with more than 45% but less than 70% ammonium nitrate and not more than 0.4% total combustible/organic material calculated as carbon such that the sum of the percentage compositions of ammonium nitrate and ammonium sulphate exceeds 70%. This entry applies to non sensitized emulsions, suspensions and gels consisting primarily of a mixture of ammonium nitrate and fuel, intended to produce a Type E blasting explosive only after further processing prior to use. The mixture for emulsions typically has the following composition: 60-85% ammonium nitrate, 5-30% water, 2-8% fuel, 0.5-4% emulsifier agent, 0-10% soluble flame suppressants, and trace additives. Other inorganic nitrate salts may replace part of the ammonium nitrate. The mixture for suspensions and gels typically has the following composition: 60-85% ammonium nitrate, 0-5% sodium or potassium perchlorate, 0-17% hexamine nitrate or monomethylamine nitrate, 5-30% water, 2-15% fuel, 0.5-4% thickening agent, 0-10% soluble flame suppressants, and trace additives. Other inorganic nitrate salts may replace part of the ammonium nitrate. Substances shall satisfactorily pass Tests 8 (a), (b) and (c) of Test Series 8 of the Manual of Tests and Criteria, Part I, Section 18 and be approved by the competent authority. 310 The testing requirements in sub-section 38.3 of the Manual of Tests and Criteria do not apply to production runs consisting of not more than 100 cells and batteries, or to pre-production prototypes of cells and batteries when these prototypes are carried for testing, if: (a) the cells and batteries are carried in an outer packaging that is a metal, plastics or plywood drum or a metal, plastics or wooden box and that meets the criteria for packing group I; and - 582 - (b) each cell and battery is individually packed in an inner packaging inside an outer packaging and is surrounded by cushioning material that is non-combustible, and nonconductive. 311 Substances shall not be carried under this entry unless approved by the competent authority on the basis of the results of appropriate tests according to Part I of the Manual of Tests and Criteria. Packaging shall ensure that the percentage of diluent does not fall below that stated in the competent authority approval, at any time during carriage. 312 (Reserved) 313 (Deleted) 314 (a) These substances are liable to exothermic decomposition at elevated temperatures. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds); (b) During the course of carriage, these substances shall be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas. 315 This entry shall not be used for Class 6.1 substances which meet the inhalation toxicity criteria for packing group I described in 2.2.61.1.8. 316 This entry applies only to calcium hypochlorite, dry, when carried in non friable tablet form. 317 "Fissile-excepted" applies only to those packages complying with 6.4.11.2. 318 For the purposes of documentation, the proper shipping name shall be supplemented with the technical name (see 3.1.2.8). When the infectious substances to be carried are unknown, but suspected of meeting the criteria for inclusion in Category A and assignment to UN No. 2814 or 2900, the words "suspected Category A infectious substance" shall be shown, in parentheses, following the proper shipping name on the transport document. 319 Substances packed and packages which are marked in accordance with packing instruction P650 are not subject to any other requirements of ADR. 320 (Deleted) 321 These storage systems shall always be considered as containing hydrogen. 322 When carried in non-friable tablet form, these goods are assigned to packing group III. 323 (Reserved) 324 This substance needs to be stabilized when in concentrations of not more than 99%. 325 In the case of non-fissile or fissile excepted uranium hexafluoride, the material shall be classified under UN No. 2978. 326 In the case of fissile uranium hexafluoride, the material shall be classified under UN No. 2977. 327 Waste aerosols consigned in accordance with 5.4.1.1.3 may be carried under this entry for the purposes of reprocessing or disposal. They need not be protected against inadvertent discharge provided that measures to prevent dangerous build up of pressure and dangerous atmospheres are addressed. Waste aerosols, other than those leaking or severely deformed, shall be packed in accordance with packing instruction P207 and special provision PP87, or packing instruction LP02 and special packing provision L2. Leaking or severely deformed aerosols shall be carried in salvage packagings provided appropriate measures are taken to ensure there is no dangerous build up of pressure. NOTE: For maritime carriage, waste aerosols shall not be carried in closed containers. - 583 - 328 This entry applies to fuel cell cartridges including when contained in equipment or packed with equipment. Fuel cell cartridges installed in or integral to a fuel cell system are regarded as contained in equipment. Fuel cell cartridge means an article that stores fuel for discharge into the fuel cell through (a) valve(s) that control(s) the discharge of fuel into the fuel cell. Fuel cell cartridges, including when contained in equipment, shall be designed and constructed to prevent fuel leakage under normal conditions of carriage. Fuel cell cartridge design types using liquids as fuels shall pass an internal pressure test at a pressure of 100 kPa (gauge) without leakage. Except for fuel cell cartridges containing hydrogen in metal hydride which shall be in compliance with special provision 339, each fuel cell cartridge design type shall be shown to pass a 1.2 meter drop test onto an unyielding surface in the orientation most likely to result in failure of the containment system with no loss of contents. When lithium metal or lithium ion batteries are contained in the fuel cell system, the consignment shall be consigned under this entry and under the appropriate entries for UN 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT or UN 3481 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT. 329 (Reserved) 330 (Deleted) 331 (Reserved) 332 Magnesium nitrate hexahydrate is not subject to the requirements of ADR. 333 Ethanol and gasoline, motor spirit or petrol mixtures for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) shall be assigned to this entry regardless of variations in volatility. 334 A fuel cell cartridge may contain an activator provided it is fitted with two independent means of preventing unintended mixing with the fuel during carriage. 335 Mixtures of solids which are not subject to the requirements of ADR and environmentally hazardous liquids or solids shall be classified as UN 3077 and may be carried under this entry provided there is no free liquid visible at the time the substance is loaded or at the time the packaging or vehicle or container is closed. Each vehicle or container shall be leakproof when used for carriage in bulk. If free liquid is visible at the time the mixture is loaded or at the time the packaging or vehicle or container is closed, the mixture shall be classified as UN 3082. Sealed packets and articles containing less than 10 ml of an environmentally hazardous liquid, absorbed into a solid material but with no free liquid in the packet or article, or containing less than 10 g of an environmentally hazardous solid, are not subject to the requirements of ADR. 336 A single package of non-combustible solid LSA-II or LSA-III material, if carried by air, shall not contain an activity greater than 3 000 A2. 337 Type B(U) and Type B(M) packages, if carried by air, shall not contain activities greater than the following: (a) For low dispersible radioactive material: as authorized for the package design as specified in the certificate of approval; (b) For special form radioactive material: 3 000 A1 or 100 000 A2, whichever is the lower; or (c) For all other radioactive material: 3 000 A2. - 584 - 338 339 Each fuel cell cartridge carried under this entry and designed to contain a liquefied flammable gas shall: (a) Be capable of withstanding, without leakage or bursting, a pressure of at least two times the equilibrium pressure of the contents at 55 ºC; (b) Not contain more than 200 ml liquefied flammable gas, the vapour pressure of which shall not exceed 1 000 kPa at 55 °C; and (c) Pass the hot water bath test prescribed in 6.2.6.3.1. Fuel cell cartridges containing hydrogen in a metal hydride carried under this entry shall have a water capacity less than or equal to 120 ml. The pressure in the fuel cell cartridge shall not exceed 5 MPa at 55 °C. The design type shall withstand, without leaking or bursting, a pressure of twice the design pressure of the cartridge at 55 °C or 200 kPa more than the design pressure of the cartridge at 55 °C, whichever is greater. The pressure at which this test is conducted is referred to in the drop test and the hydrogen cycling test as the "minimum shell burst pressure". Fuel cell cartridges shall be filled in accordance with procedures provided by the manufacturer. The manufacturer shall provide the following information with each fuel cell cartridge: (a) Inspection procedures to be carried out before initial filling and before refilling of the fuel cell cartridge; (b) Safety precautions and potential hazards to be aware of; (c) Method for determining when the rated capacity has been achieved; (d) Minimum and maximum pressure range; (e) Minimum and maximum temperature range; and (f) Any other requirements to be met for initial filling and refilling including the type of equipment to be used for initial filling and refilling. The fuel cell cartridges shall be designed and constructed to prevent fuel leakage under normal conditions of carriage. Each cartridge design type, including cartridges integral to a fuel cell, shall be subjected to and shall pass the following tests: Drop test A 1.8 metre drop test onto an unyielding surface in four different orientations: (a) Vertically, on the end containing the shut-off valve assembly; (b) Vertically, on the end opposite to the shut-off valve assembly; (c) Horizontally, onto a steel apex with a diameter of 38 mm, with the steel apex in the upward position; and (d) At a 45° angle on the end containing the shut-off valve assembly. There shall be no leakage, determined by using a soap bubble solution or other equivalent means on all possible leak locations, when the cartridge is charged to its rated charging pressure. The fuel cell cartridge shall then be hydrostatically pressurized to destruction. The recorded burst pressure shall exceed 85% of the minimum shell burst pressure. - 585 - Fire test A fuel cell cartridge filled to rated capacity with hydrogen shall be subjected to a fire engulfment test. The cartridge design, which may include a vent feature integral to it, is deemed to have passed the fire test if: (a) The internal pressure vents to zero gauge pressure without rupture of the cartridge; or (b) The cartridge withstands the fire for a minimum of 20 minutes without rupture. Hydrogen cycling test This test is intended to ensure that a fuel cell cartridge design stress limits are not exceeded during use. The fuel cell cartridge shall be cycled from not more than 5% rated hydrogen capacity to not less than 95% rated hydrogen capacity and back to not more than 5% rated hydrogen capacity. The rated charging pressure shall be used for charging and temperatures shall be held within the operating temperature range. The cycling shall be continued for at least 100 cycles. Following the cycling test, the fuel cell cartridge shall be charged and the water volume displaced by the cartridge shall be measured. The cartridge design is deemed to have passed the hydrogen cycling test if the water volume displaced by the cycled cartridge does not exceed the water volume displaced by an uncycled cartridge charged to 95% rated capacity and pressurized to 75% of its minimum shell burst pressure. Production leak test Each fuel cell cartridge shall be tested for leaks at 15 °C ± 5 °C, while pressurized to its rated charging pressure. There shall be no leakage, determined by using a soap bubble solution or other equivalent means on all possible leak locations. Each fuel cell cartridge shall be permanently marked with the following information: (a) The rated charging pressure in MPa; (b) The manufacturer's serial number of the fuel cell cartridges or unique identification number; and (c) The date of expiry based on the maximum service life (year in four digits; month in two digits). 340 Chemical kits, first aid kits and polyester resin kits containing dangerous substances in inner packagings which do not exceed the quantity limits for excepted quantities applicable to individual substances as specified in column (7b) of Table A of Chapter 3.2, may be carried in accordance with Chapter 3.5. Class 5.2 substances, although not individually authorized as excepted quantities in column (7b) of Table A of Chapter 3.2, are authorized in such kits and are assigned Code E2 (see 3.5.1.2). 341 (Reserved) 342 Glass inner receptacles (such as ampoules or capsules) intended only for use in sterilization devices, when containing less than 30 ml of ethylene oxide per inner packaging with not more than 300 ml per outer packaging, may be carried in accordance with the provisions in Chapter 3.5, irrespective of the indication of "E0" in column (7b) of Table A of Chapter 3.2 provided that: (a) After filling, each glass inner receptacle has been determined to be leak-tight by placing the glass inner receptacle in a hot water bath at a temperature, and for a period of time, sufficient to ensure that an internal pressure equal to the vapour pressure of ethylene oxide at 55 °C is achieved. Any glass inner receptacle showing evidence of leakage, distortion or other defect under this test shall not be carried under the terms of this special provision; - 586 - (b) In addition to the packaging required by 3.5.2, each glass inner receptacle is placed in a sealed plastics bag compatible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner receptacle; and (c) Each glass inner receptacle is protected by a means of preventing puncture of the plastics bag (e.g. sleeves or cushioning) in the event of damage to the packaging (e.g. by crushing). 343 This entry applies to crude oil containing hydrogen sulphide in sufficient concentration that vapours evolved from the crude oil can present an inhalation hazard. The packing group assigned shall be determined by the flammability hazard and inhalation hazard, in accordance with the degree of danger presented. 344 The provisions of 6.2.6 shall be met. 345 This gas contained in open cryogenic receptacles with a maximum capacity of 1 litre constructed with glass double walls having the space between the inner and outer wall evacuated (vacuum insulated) is not subject to ADR provided each receptacle is carried in an outer packaging with suitable cushioning or absorbent materials to protect it from impact damage. 346 Open cryogenic receptacles conforming to the requirements of packing instruction P203 of 4.1.4.1 and containing no dangerous goods except for UN No. 1977 nitrogen, refrigerated liquid, which is fully absorbed in a porous material are not subject to any other requirements of ADR. 347 This entry shall only be used if the results of Test series 6 (d) of Part I of the Manual of Tests and Criteria have demonstrated that any hazardous effects arising from functioning are confined within the package. 348 Batteries manufactured after 31 December 2011 shall be marked with the Watt-hour rating on the outside case. 349 Mixtures of a hypochlorite with an ammonium salt are not to be accepted for carriage. UN No. 1791 hypochlorite solution is a substance of Class 8. 350 Ammonium bromate and its aqueous solutions and mixtures of a bromate with an ammonium salt are not to be accepted for carriage. 351 Ammonium chlorate and its aqueous solutions and mixtures of a chlorate with an ammonium salt are not to be accepted for carriage. 352 Ammonium chlorite and its aqueous solutions and mixtures of a chlorite with an ammonium salt are not to be accepted for carriage. 353 Ammonium permanganate and its aqueous solutions and mixtures of a permanganate with an ammonium salt are not to be accepted for carriage. 354 This substance is toxic by inhalation. 355 Oxygen cylinders for emergency use carried under this entry may include installed actuating cartridges (cartridges, power device of Division 1.4, Compatibility Group C or S), without changing the classification in Class 2 provided the total quantity of deflagrating (propellant) explosives does not exceed 3.2 g per oxygen cylinder. The cylinders with the installed actuating cartridges as prepared for carriage shall have an effective means of preventing inadvertent activation. 356 Metal hydride storage systems installed in vehicles, wagons, vessels or aircraft or in completed components or intended to be installed in vehicles, wagons, vessels or aircraft shall be approved by the competent authority of the country of manufacture1 before acceptance for 1 If the country of manufacture is not a Contracting Party to ADR, the approval shall be recognized by the competent authority of a Contracting Party to ADR. - 587 - carriage. The transport document shall include an indication that the package was approved by the competent authority of the country of manufacture1 or a copy of the competent authority of the country of manufacture1 approval shall accompany each consignment. 357 Petroleum crude oil containing hydrogen sulphide in sufficient concentration that vapours evolved from the crude oil can present an inhalation hazard shall be consigned under the entry UN 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC. 358 Nitroglycerin solution in alcohol with more than 1% but not more than 5% nitroglycerin may be classified in Class 3 and assigned to UN No. 3064 provided all the requirements of packing instruction P300 of 4.1.4.1 are complied with. 359 Nitroglycerin solution in alcohol with more than 1% but not more than 5% nitroglycerin shall be classified in Class 1 and assigned to UN No. 0144 if not all the requirements of packing instruction P300 of 4.1.4.1 are complied with. 360 Vehicles only powered by lithium metal batteries or lithium ion batteries shall be classified under the entry UN 3171 battery-powered vehicle. 361 This entry applies to electric double layer capacitors with an energy storage capacity greater than 0.3 Wh. Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to ADR. Energy storage capacity means the energy held by a capacitor, as calculated using the nominal voltage and capacitance. All capacitors to which this entry applies, including capacitors containing an electrolyte that does not meet the classification criteria of any class of dangerous goods, shall meet the following conditions: (a) Capacitors not installed in equipment shall be carried in an uncharged state. Capacitors installed in equipment shall be carried either in an uncharged state or protected against short circuit; (b) Each capacitor shall be protected against a potential short circuit hazard in carriage as follows: (i) When a capacitor’s energy storage capacity is less than or equal to 10Wh or when the energy storage capacity of each capacitor in a module is less than or equal to 10 Wh , the capacitor or module shall be protected against short circuit or be fitted with a metal strap connecting the terminals; and (ii) When the energy storage capacity of a capacitor or a capacitor in a module is more than 10 Wh, the capacitor or module shall be fitted with a metal strap connecting the terminals; (c) Capacitors containing dangerous goods shall be designed to withstand a 95 kPa pressure differential; (d) Capacitors shall be designed and constructed to safely relieve pressure that may build up in use, through a vent or a weak point in the capacitor casing. Any liquid which is released upon venting shall be contained by the packaging or by the equipment in which a capacitor is installed; and (e) Capacitors shall be marked with the energy storage capacity in Wh. Capacitors containing an electrolyte not meeting the classification criteria of any class of dangerous goods, including when installed in equipment, are not subject to other provisions of ADR. Capacitors containing an electrolyte meeting the classification criteria of any class of dangerous goods, with an energy storage capacity of 10 Wh or less are not subject to other provisions of ADR when they are capable of withstanding a 1.2 metre drop test unpackaged on an unyielding surface without loss of contents. Capacitors containing an electrolyte meeting the classification criteria of any class of dangerous goods that are not installed in equipment and with an energy storage capacity of more than 10 Wh are subject to ADR. - 588 - Capacitors installed in equipment and containing an electrolyte meeting the classification criteria of any class of dangerous goods, are not subject to other provisions of ADR provided the equipment is packaged in a strong outer packaging constructed of suitable material, and of adequate strength and design in relation to the packaging’s intended use and in such a manner as to prevent accidental functioning of capacitors during carriage. Large robust equipment containing capacitors may be offered for carriage unpackaged or on pallets when capacitors are afforded equivalent protection by the equipment in which they are contained. NOTE: Capacitors which by design maintain a terminal voltage (e.g. asymmetrical capacitors) do not belong to this entry. 362 (Reserved) 363 This entry also applies to liquid fuels, other than those exempted according to 1.1.3.3, above the quantity specified in column (7a) of Table A of Chapter 3.2, in means of containment integral to equipment or machinery (e.g. generators, compressors, heating units, etc) as part of their original design type. They are not subject to other provisions of ADR if they meet the following: (a) The means of containment are in compliance with the construction requirements of the competent authority of the country of manufacture2; (b) Any valves or openings (e.g. venting devices) in the means of containment containing dangerous goods are closed during carriage; (c) The machinery or equipment is oriented to prevent inadvertent leakage of dangerous goods and secured by means capable of restraining the machinery or equipment to prevent any movement during carriage which would change the orientation or cause it to be damaged; (d) Where the means of containment has a capacity of more than 60 litres but not more than 450 litres, the machinery or equipment is labelled on one external side in accordance with 5.2.2 and where the capacity is greater than 450 litres but not more than 1 500 litres the machinery or equipment is labelled on all four external sides in accordance with 5.2.2; and (e) Where the means of containment has a capacity greater than 1500 litres, the machinery or equipment is placarded on all four external sides in accordance with 5.3.1.1.1, the requirement of 5.4.1 applies and the transport document includes the following additional statement: "Carriage in accordance with Special Provision 363". 364 This article may only be carried under the provisions of Chapter 3.4 if, as presented for carriage, the package is capable of passing the test in accordance with Test Series 6(d) of Part I of the Manual of Tests and Criteria as determined by the competent authority. 365 For manufactured instruments and articles containing mercury, see UN No. 3506. 366 Manufactured instruments and articles containing not more than 1 kg of mercury are not subject to ADR. 367 For the purposes of documentation: The proper shipping name "Paint related material" may be used for consignments of packages containing "Paint" and "Paint related material" in the same package; The proper shipping name "Paint related material, corrosive, flammable" may be used for consignments of packages containing "Paint, corrosive, flammable" and "Paint related material, corrosive, flammable" in the same package; 2 For example, compliance with the relevant provisions of Directive 2006/42/EC of the European Parliament and of the Council of 17 May 2006 on machinery, and amending Directive 95/16/EC (Official Journal of the European Union No. L 157 of 9 June 2006, pp. 0024-0086). - 589 - The proper shipping name "Paint related material, flammable, corrosive" may be used for consignments of packages containing "Paint, flammable, corrosive" and "Paint related material, flammable, corrosive" in the same package; and The proper shipping name "Printing ink related material" may be used for consignments of packages containing "Printing ink" and "Printing ink related material" in the same package. 368 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material shall be classified under UN No. 3507 or UN No. 2978. 369 In accordance with 2.1.3.5.3 (a), this radioactive material in an excepted package possessing corrosive properties is classified in Class 8 with a radioactive material subsidiary risk. Uranium hexafluoride may be classified under this entry only if the conditions of 2.2.7.2.4.1.2, 2.2.7.2.4.1.5, 2.2.7.2.4.5.2 and, for fissile-excepted material, of 2.2.7.2.3.6 are met. In addition to the provisions applicable to the carriage of Class 8 substances, the provisions of 5.1.3.2, 5.1.5.2.2, 5.1.5.4.1 (b), 7.5.11 CV33 (3.1), (5.1) to (5.4) and (6) apply. No Class 7 label is required to be displayed. 370 This entry applies to: - ammonium nitrate with more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any added substance; and - ammonium nitrate with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any added substance, that is not too sensitive for acceptance into Class 1 when tested in accordance with Test Series 2 (see Manual of Tests and Criteria, Part I). See also UN No. 1942. 371 (1) This entry also applies to articles, containing a small pressure receptacle with a release device. Such articles shall comply with the following requirements: (a) The water capacity of the pressure receptacle shall not exceed 0.5 litres and the working pressure shall not exceed 25 bar at 15 °C; (b) The minimum burst pressure of the pressure receptacle shall be at least four times the pressure of the gas at 15 °C; (c) Each article shall be manufactured in such a way that unintentional firing or release is avoided under normal conditions of handling, packing, carriage and use. This may be fulfilled by an additional locking device linked to the activator; (d) Each article shall be manufactured in such a way as to prevent hazardous projections of the pressure receptacle or parts of the pressure receptacle; (e) Each pressure receptacle shall be manufactured from material which will not fragment upon rupture; (f) The design type of the article shall be subjected to a fire test. For this test, the provisions of paragraphs 16.6.1.2 except letter g, 16.6.1.3.1 to 16.6.1.3.6, 16.6.1.3.7 (b) and 16.6.1.3.8 of the Manual of Tests and Criteria shall be applied. It shall be demonstrated that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, in such a way that the pressure receptacle will not fragment and that the article or fragments of the article do not rocket more than 10 metres; (g) The design type of the article shall be subjected to the following test. A stimulating mechanism shall be used to initiate one article in the middle of the packaging. There shall be no hazardous effects outside the package such as disruption of the package, metal fragments or a receptacle which passes through the packaging. - 590 - (2) The manufacturer shall produce technical documentation of the design type, manufacture as well as the tests and their results. The manufacturer shall apply procedures to ensure that articles produced in series are made of good quality, conform to the design type and are able to meet the requirements in (1). The manufacturer shall provide such information to the competent authority on request. 372 This entry applies to asymmetric capacitors with an energy storage capacity greater than 0.3 Wh. Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to ADR. Energy storage capacity means the energy stored in a capacitor, as calculated according to the following equation, Wh = 1/2CN(UR2-UL2) × (1/3600), using the nominal capacitance (CN), rated voltage (UR) and rated lower limit voltage (UL). All asymmetric capacitors to which this entry applies shall meet the following conditions: (a) Capacitors or modules shall be protected against short circuit; (b) Capacitors shall be designed and constructed to safely relieve pressure that may build up in use, through a vent or a weak point in the capacitor casing. Any liquid which is released upon venting shall be contained by packaging or by equipment in which a capacitor is installed; (c) Capacitors shall be marked with the energy storage capacity in Wh; and (d) Capacitors containing an electrolyte meeting the classification criteria of any class of dangerous goods shall be designed to withstand a 95 kPa pressure differential; Capacitors containing an electrolyte not meeting the classification criteria of any class of dangerous goods, including when configured in a module or when installed in equipment are not subject to other provisions of ADR. Capacitors containing an electrolyte meeting the classification criteria of any class of dangerous goods, with an energy storage capacity of 20 Wh or less, including when configured in a module, are not subject to other provisions of ADR when the capacitors are capable of withstanding a 1.2 metre drop test unpackaged on an unyielding surface without loss of contents. Capacitors containing an electrolyte meeting the classification criteria of any class of dangerous goods that are not installed in equipment and with an energy storage capacity of more than 20 Wh are subject to ADR. Capacitors installed in equipment and containing an electrolyte meeting the classification criteria of any class of dangerous goods, are not subject to other provisions of ADR provided that the equipment is packaged in a strong outer packaging constructed of suitable material, and of adequate strength and design, in relation to the packaging’s intended use and in such a manner as to prevent accidental functioning of capacitors during carriage. Large robust equipment containing capacitors may be offered for carriage unpackaged or on pallets when capacitors are afforded equivalent protection by the equipment in which they are contained. NOTE: Notwithstanding the provisions of this special provision, nickel-carbon asymmetric capacitors containing Class 8 alkaline electrolytes shall be carried as UN 2795 BATTERIES, WET, FILLED WITH ALKALI, electric storage. 373 Neutron radiation detectors containing non-pressurized boron trifluoride gas may be carried under this entry provided that the following conditions are met: (a) Each radiation detector shall meet the following conditions. (i) The pressure in each detector shall not exceed 105 kPa absolute at 20 °C; - 591 - (ii) The amount of gas shall not exceed 13 g per detector; (iii) Each detector shall be manufactured under a registered quality assurance programme; NOTE: ISO 9001:2008 may be used for this purpose. (b) (c) (iv) Each neutron radiation detector shall be of welded metal construction with brazed metal to ceramic feed through assemblies. These detectors shall have a minimum burst pressure of 1800 kPa as demonstrated by design type qualification testing; and (v) Each detector shall be tested to a 1 x 10-10 cm3/s leaktightness standard before filling. Radiation detectors carried as individual components shall be carried as follows: (i) Detectors shall be packed in a sealed intermediate plastics liner with sufficient absorbent material to absorb the entire gas contents; (ii) They shall be packed in strong outer packaging. The completed package shall be capable of withstanding a 1.8 m drop test without leakage of gas contents from detectors; (iii) The total amount of gas from all detectors per outer packaging shall not exceed 52 g. Completed neutron radiation detection systems containing detectors meeting the conditions of paragraph (a) shall be carried as follows: (i) The detectors shall be contained in a strong sealed outer casing; (ii) The casing shall contain sufficient absorbent material to absorb the entire gas contents; (iii) The completed systems shall be packed in strong outer packagings capable of withstanding a 1.8 m drop test without leakage unless a system’s outer casing affords equivalent protection. Packing instruction P200 of 4.1.4.1 is not applicable. The transport document shall include the following statement "Carriage in accordance with special provision 373". Neutron radiation detectors containing not more than 1 g of boron trifluoride, including those with solder glass joints, are not subject to ADR provided they meet the requirements in paragraph (a) and are packed in accordance with paragraph (b). Radiation detection systems containing such detectors are not subject to ADR provided they are packed in accordance with paragraph (c). 374 (Reserved) 375 These substances when carried in single or combination packagings containing a net quantity per single or inner packaging of 5 l or less for liquids or having a net mass per single or inner packaging of 5 kg or less for solids, are not subject to any other provisions of ADR provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8. 376 Lithium ion cells or batteries and lithium metal cells or batteries identified as being damaged or defective such that they do not conform to the type tested according to the applicable provisions of the Manual of Tests and Criteria shall comply with the requirements of this special provision. - 592 - For the purposes of this special provision, these may include, but are not limited to: - Cells or batteries identified as being defective for safety reasons; - Cells or batteries that have leaked or vented; - Cells or batteries that cannot be diagnosed prior to carriage; or - Cells or batteries that have sustained physical or mechanical damage. NOTE: In assessing a battery as damaged or defective, the type of battery and its previous use and misuse shall be taken into account. Cells and batteries shall be carried according to the provisions applicable to UN No. 3090, UN No. 3091, UN No. 3480 and No. UN 3481, except special provision 230 and as otherwise stated in this special provision. Packages shall be marked "DAMAGED/DEFECTIVE LITHIUM-ION BATTERIES" or "DAMAGED/DEFECTIVE LITHIUM METAL BATTERIES", as applicable. Cells and batteries shall be packed in accordance with packing instructions P908 of 4.1.4.1 or LP904 of 4.1.4.3, as applicable. Cells and batteries liable to rapidly disassemble, dangerously react, produce a flame or a dangerous evolution of heat or a dangerous emission of toxic, corrosive or flammable gases or vapours under normal conditions of carriage shall not be carried except under conditions specified by the competent authority. 377 Lithium ion and lithium metal cells and batteries and equipment containing such cells and batteries carried for disposal or recycling, either packed together with or packed without nonlithium batteries, may be packaged in accordance with packing instruction P909 of 4.1.4.1. These cells and batteries are not subject to the requirements of 2.2.9.1.7 (a) to (e). Packages shall be marked "LITHIUM BATTERIES FOR DISPOSAL" or "LITHIUM BATTERIES FOR RECYCLING". Identified damaged or defective batteries shall be carried in accordance with special provision 376 and packaged in accordance with P908 of 4.1.4.1 or LP904 of 4.1.4.3, as applicable. 378-499 (Reserved) 500 (Deleted) 501 For naphthalene, molten, see UN No. 2304. 502 UN No. 2006 plastics, nitrocellulose-based, self-heating, n.o.s., and 2002 celluloid scrap are substances of Class 4.2. 503 For phosphorus, white, molten, see UN No. 2447. 504 UN No. 1847 potassium sulphide, hydrated with not less than 30% water of crystallization, UN No. 1849 sodium sulphide, hydrated with not less than 30% water of crystallization and UN No. 2949 sodium hydrosulphide hydrated with not less than 25% water of crystallization are substances of Class 8. 505 UN No. 2004 magnesium diamide is a substance of Class 4.2. - 593 - 506 Alkaline earth metals and alkaline earth metal alloys in pyrophoric form are substances of Class 4.2. UN No. 1869 magnesium or magnesium alloys containing more than 50% magnesium as pellets, turnings or ribbons, are substances of Class 4.1. 507 UN No. 3048 aluminium phosphide pesticides, with additives inhibiting the emission of toxic flammable gases are substances of Class 6.1. 508 UN No. 1871 titanium hydride and UN No. 1437 zirconium hydride are substances of Class 4.1. UN No. 2870 aluminium borohydride is a substance of Class 4.2. 509 UN No. 1908 chlorite solution is a substance of Class 8. 510 UN No. 1755 chromic acid solution is a substance of Class 8. 511 UN No. 1625 mercuric nitrate, UN No. 1627 mercurous nitrate and UN No. 2727 thallium nitrate are substances of Class 6.1. Thorium nitrate, solid, uranyl nitrate hexahydrate solution and uranyl nitrate, solid are substances of Class 7. 512 UN No. 1730 antimony pentachloride, liquid, UN No. 1731 antimony pentachloride solution, UN No. 1732 antimony pentafluoride and UN No. 1733 antimony trichloride are substances of Class 8. 513 UN No. 0224 barium azide, dry or wetted with less than 50% water, by mass, is a substance of Class 1. UN No. 1571 barium azide, wetted with not less than 50% water, by mass, is a substance of Class 4.1. UN No. 1854 barium alloys, pyrophoric, are substances of Class 4.2. UN No. 1445 barium chlorate, solid, UN No. 1446 barium nitrate, UN No. 1447 barium perchlorate, solid, UN No. 1448 barium permanganate, UN No. 1449 barium peroxide, UN No. 2719 barium bromate, UN No. 2741 barium hypochlorite with more than 22% available chlorine, UN No. 3405 barium chlorate, solution and UN No. 3406 barium perchlorate, solution, are substances of Class 5.1. UN No. 1565 barium cyanide and UN No. 1884 barium oxide are substances of Class 6.1. 514 UN No. 2464 beryllium nitrate is a substance of Class 5.1. 515 UN No. 1581 chloropicrin and methyl bromide mixture and UN No. 1582 chloropicrin and methyl chloride mixture are substances of Class 2. 516 UN No. 1912 methyl chloride and methylene chloride mixture is a substance of Class 2. 517 UN No. 1690 sodium fluoride, solid, UN No. 1812 potassium fluoride, solid, UN No. 2505 ammonium fluoride, UN No. 2674 sodium fluorosilicate, UN No. 2856 fluorosilicates, n.o.s., UN No. 3415 sodium fluoride, solution and UN No. 3422 potassium fluoride, solution, are substances of Class 6.1. 518 UN No. 1463 chromium trioxide, anhydrous (chromic acid, solid) is a substance of Class 5.1. 519 UN No. 1048 hydrogen bromide, anhydrous, is a substance of Class 2. 520 UN No. 1050 hydrogen chloride, anhydrous, is a substance of Class 2. 521 Solid chlorites and hypochlorites are substances of Class 5.1. 522 UN No. 1873 perchloric acid aqueous solution with more than 50% but not more than 72% pure acid, by mass are substances of Class 5.1. Perchloric acid solutions containing more than 72% pure acid, by mass, or mixtures of perchloric acid with any liquid other than water, are not to be accepted for carriage. 523 UN No. 1382 anhydrous potassium sulphide and UN No. 1385 anhydrous sodium sulphide and their hydrates with less than 30% water of crystallization, and UN No. 2318 sodium hydrosulphide with less than 25% water of crystallization are substances of Class 4.2. - 594 - 524 UN No. 2858 finished zirconium products of a thickness of 18 m or more are substances of Class 4.1. 525 Solutions of inorganic cyanides with a total cyanide ion content of more than 30% shall be classified in packing group I, solutions with a total cyanide ion content of more than 3% and not more than 30% in packing group II and solutions with a cyanide ion content of more than 0.3% and not more than 3% in packing group III. 526 UN No. 2000 celluloid is assigned to Class 4.1. 528 UN No. 1353 fibres or fabrics impregnated with weakly nitrated cellulose, non-self heating are articles of Class 4.1. 529 UN No. 0135 mercury fulminate, wetted with not less than 20% water, or mixture of alcohol and water, by mass, is a substance of Class 1. Mercurous chloride (calomel) is a substance of Class 9 (UN No. 3077). 530 UN No. 3293 hydrazine, aqueous solution with not more than 37% hydrazine, by mass, is a substance of Class 6.1. 531 Mixtures having a flash-point below 23 °C and containing more than 55% nitrocellulose, whatever its nitrogen content or containing not more than 55% nitrocellulose with a nitrogen content above 12.6% (by dry mass), are substances of Class 1 (see UN Nos. 0340 or 0342) or of Class 4.1. 532 UN No. 2672 ammonia solution containing not less than 10% but not more than 35% ammonia is a substance of Class 8. 533 UN No. 1198 formaldehyde solutions, flammable are substances of Class 3. Formaldehyde solutions, non-flammable, with less than 25% formaldehyde are not subject to the requirements of ADR. 534 While in some climatic conditions, petrol (gasoline) may have a vapour pressure at 50 °C of more than 110 kPa (1.10 bar) but not more than 150 kPa (1.50 bar) it is to continue to be considered as a substance having a vapour pressure at 50 °C of not more than 110 kPa (1.10 bar). 535 UN No. 1469 lead nitrate, UN No. 1470 lead perchlorate, solid and UN No. 3408 lead perchlorate, solution, are substances of Class 5.1. 536 For naphthalene, solid, see UN No. 1334. 537 UN No. 2869 titanium trichloride mixture, not pyrophoric, is a substance of Class 8. 538 For sulphur (in the solid state), see UN No. 1350. 539 Solutions of isocyanates having a flash-point of not less than 23 °C are substances of Class 6.1. 540 UN No. 1326 hafnium powder, wetted, UN No. 1352 titanium powder, wetted or UN No. 1358 zirconium powder, wetted, with not less than 25% water, are substances of Class 4.1. 541 Nitrocellulose mixtures with a water content, alcohol content or plasticizer content lower than the stated limits are substances of Class 1. 542 Talc containing tremolite and/or actinolite is covered by this entry. 543 UN No. 1005 ammonia, anhydrous, UN No. 3318 ammonia solution with more than 50% ammonia and UN No. 2073 ammonia solution, with more than 35% but not more than 50% ammonia, are substances of Class 2. Ammonia solutions with not more than 10% ammonia are not subject to the requirements of ADR. - 595 - 544 UN No. 1032 dimethylamine, anhydrous, UN No. 1036 ethylamine, UN No. 1061 methylamine, anhydrous and UN No. 1083 trimethylamine, anhydrous, are substances of Class 2. 545 UN No. 0401 dipicryl sulphide, wetted with less than 10% water by mass is a substance of Class 1. 546 UN No. 2009 zirconium, dry, finished sheets, strip or coiled wire, in thicknesses of less than 18 m, is a substance of Class 4.2. Zirconium, dry, finished sheets, strip or coiled wire, in thicknesses of 254 m or more, is not subject to the requirements of ADR. 547 UN No. 2210 maneb or UN No. 2210 maneb preparations in self-heating form are substances of Class 4.2. 548 Chlorosilanes which, in contact with water, emit flammable gases, are substances of Class 4.3. 549 Chlorosilanes having a flash-point of less than 23 °C and which, in contact with water, do not emit flammable gases are substances of Class 3. Chlorosilanes having a flash-point equal to or greater than 23 °C and which, in contact with water, do not emit flammable gases are substances of Class 8. 550 UN No. 1333 cerium in slabs, rods or ingots is a substance of Class 4.1. 551 Solutions of these isocyanates having a flash-point below 23 °C are substances of Class 3. 552 Metals and metal alloys in powdered or other flammable form, liable to spontaneous combustion, are substances of Class 4.2. Metals and metal alloys in powdered or other flammable form which, in contact with water, emit flammable gases are substances of Class 4.3. 553 This mixture of hydrogen peroxide and peroxyacetic acid shall, in laboratory testing (see Manual of Tests and Criteria, Part II, section 20), neither detonate in the cavitated state nor deflagrate at all and shall show no effect when heated under confinement nor any explosive power. The formulation shall be thermally stable (self-accelerating decomposition temperature 60 °C or higher for a 50 kg package), and a liquid compatible with peroxyacetic acid shall be used for desensitization. Formulations not meeting these criteria are to be regarded as substances of Class 5.2 (see Manual of Tests and Criteria, Part II, paragraph 20.4.3(g)). 554 Metal hydrides which, in contact with water, emit flammable gases are substances of Class 4.3. UN No. 2870 aluminium borohydride or UN No. 2870 aluminium borohydride in devices is a substance of Class 4.2. 555 Dust and powder of metals in non-spontaneously combustible form, non-toxic which nevertheless, in contact with water, emit flammable gases, are substances of Class 4.3. 556 Organometallic compounds and their solutions which ignite spontaneously are substances of Class 4.2. Flammable solutions with organometallic compounds in concentrations which, in contact with water, neither emit flammable gases in dangerous quantities nor ignite spontaneously are substances of Class 3. 557 Dust and powder of metals in pyrophoric form are substances of Class 4.2. 558 Metals and metal alloys in pyrophoric form are substances of Class 4.2. Metals and metal alloys which, in contact with water, do not emit flammable gases and are not pyrophoric or self-heating, but which are easily ignited, are substances of Class 4.1. 559 (Deleted) 560 An elevated temperature liquid, n.o.s. at or above 100 °C (including molten metals and molten salts) and, for a substance having a flashpoint, at a temperature below its flashpoint, is a substance of Class 9 (UN No. 3257). 561 Chloroformates having predominantly corrosive properties are substances of Class 8. - 596 - 562 Spontaneously combustible organometallic compounds are substances of Class 4.2. Waterreactive organometallic compounds, flammable, are substances of Class 4.3. 563 UN No. 1905 selenic acid is a substance of Class 8. 564 UN No. 2443 vanadium oxytrichloride, UN No. 2444 vanadium UN No. 2475 vanadium trichloride are substances of Class 8. 565 Unspecified wastes resulting from medical/veterinary treatment of humans/animals or from biological research, and which are unlikely to contain substances of Class 6.2 shall be assigned to this entry. Decontaminated clinical wastes or wastes resulting from biological research which previously contained infectious substances are not subject to the requirements of Class 6.2. 566 UN No. 2030 hydrazine aqueous solution, with more than 37% hydrazine, by mass, is a substance of Class 8. 567 (Deleted) 568 Barium azide with a water content lower than the stated limit is a substance of Class 1, UN No. 0224. tetrachloride and 569-579 (Reserved) 580 (Deleted) 581 This entry covers mixtures of methylacetylene and propadiene with hydrocarbons, which as Mixture P1, contain not more than 63% methylacetylene and propadiene by volume and not more than 24% propane and propylene by volume, the percentage of C4-saturated hydrocarbons being not less than 14% by volume; and as Mixture P2, contain not more than 48% methylacetylene and propadiene by volume and not more than 50% propane and propylene by volume, the percentage of C4-saturated hydrocarbons being not less than 5% by volume, as well as mixtures of propadiene with 1 to 4% methylacetylene. When relevant, in order to meet the requirements for the transport document (5.4.1.1), the term "Mixture P1" or "Mixture P2" may be used as technical name. 582 This entry covers, inter alia, mixtures of gases indicated by the letter R ..., with the following properties: Mixture Maximum vapour pressure at 70 °C (MPa) Minimum density at 50 °C (kg/l) Permitted technical name for purposes of 5.4.1.1 F1 1.3 1.30 "Mixture F1" F2 1.9 1.21 "Mixture F2" F3 3.0 1.09 "Mixture F3" NOTE 1: Trichlorofluoromethane (refrigerant R 11), 1,1,2-trichloro-1,2,2-trifluoroethane (refrigerant R 113), 1,1,1-trichloro-2,2,2-trifluoroethane (refrigerant R 113a), 1-chloro-1,2,2trifluoroethane (refrigerant R 133) and 1-chloro-1,1,2-trifluoroethane (refrigerant R 133b) are not substances of Class 2. They may, however, enter into the composition of mixtures F1 to F3. NOTE 2: The reference densities correspond to the densities of dichlorofluoromethane (1.30 kg/l), dichlorodifluoromethane (1.21 kg/l) and chlorodifluoromethane (1.09 kg/l). - 597 - 583 This entry covers, inter alia, mixtures of gases with the following properties: Maximun vapour pressure at 70 °C (MPa) Mixture a Minimun density at 50 °C (kg/l) Permitted technical namea for purposes of 5.4.1.1 A 1.1 0.525 "Mixture A" or "Butane" A01 1.6 0.516 "Mixture A01" or "Butane" A02 1.6 0.505 "Mixture A02" or "Butane" A0 1.6 0.495 "Mixture A0" or "Butane" A1 2.1 0.485 "Mixture A1" B1 2.6 0.474 "Mixture B1" B2 2.6 0.463 "Mixture B2" B 2.6 0.450 "Mixture B" C 3.1 0.440 "Mixture C" or "Propane" For carriage in tanks, the trade names "Butane" or "Propane" may be used only as a complement 584 This gas is not subject to the requirements of ADR when: - it contains not more than 0.5% air in the gaseous state; - it is contained in metal capsules (sodors, sparklets) free from defects which may impair their strength; - the leakproofness of the closure of the capsule is ensured; - a capsule contains not more than 25 g of this gas; - a capsule contains not more than 0.75 g of this gas per cm3 of capacity. 585 (Deleted) 586 Hafnium, titanium and zirconium powders shall contain a visible excess of water. Hafnium, titanium and zirconium powders, wetted, mechanically produced, of a particle size of 53 m and over, or chemically produced, of a particle size of 840 m and over, are not subject to the requirements of ADR. 587 Barium stearate and barium titanate are not subject to the requirements of ADR. 588 Solid hydrated forms of aluminium bromide and aluminium chloride are not subject to the requirements of ADR. 589 (Deleted) 590 Ferric chloride hexahydrate is not subject to the requirements of ADR. 591 Lead sulphate with not more than 3% free acid is not subject to the requirements of ADR. 592 Uncleaned empty packagings (including empty IBCs and large packagings), empty tankvehicles, empty demountable tanks, empty portable tanks, empty tank-containers and empty small containers which have contained this substance are not subject to the requirements of ADR. 593 This gas, intended for the cooling of e.g. medical or biological specimens, if contained in double wall receptacles which comply with the provisions of packing instruction P203, paragraph (6) for open cryogenic receptacles of 4.1.4.1 is not subject to the requirements of ADR except as specified in 5.5.3. - 598 - 594 The following articles, manufactured and filled according to the provisions applied in the country of manufacture, are not subject to the requirements of ADR: (a) (b) UN No. 1044 fire extinguishers provided with protection against inadvertent discharge, when: – they are packaged in a strong outer packaging; or – they are large fire extinguishers which meet the requirements of special packing provision PP91 of packing instruction P003 in 4.1.4.1; UN No. 3164 articles, pressurized pneumatic or hydraulic, designed to withstand stresses greater than the internal gas pressure by virtue of transmission of force, intrinsic strength or construction, when they are packaged in a strong outer packaging. NOTE: "Provisions applied in the country of manufacture" means the provisions applicable in the country of manufacture or those applicable in the country of use. 596 Cadmium pigments, such as cadmium sulphides, cadmium sulphoselenides and cadmium salts of higher fatty acids (e.g. cadmium stearate), are not subject to the requirements of ADR. 597 Acetic acid solutions with not more than 10% pure acid by mass, are not subject to the requirements of ADR. 598 The following are not subject to the requirements of ADR: (a) New storage batteries when: - (b) they are secured in such a way that they cannot slip, fall or be damaged; they are provided with carrying devices, unless they are suitably stacked, e.g. on pallets; there are no dangerous traces of alkalis or acids on the outside; they are protected against short circuits; Used storage batteries when: - their cases are undamaged; they are secured in such a way that they cannot leak, slip, fall or be damaged, e.g. by stacking on pallets; there are no dangerous traces of alkalis or acids on the outside of the articles; they are protected against short circuits. "Used storage batteries" means storage batteries carried for recycling at the end of their normal service life. 599 (Deleted) 600 Vanadium pentoxide, fused and solidified, is not subject to the requirements of ADR. 601 Pharmaceutical products (medicines) ready for use, which are substances manufactured and packaged for retail sale or distribution for personal or household consumption are not subject to the requirements of ADR. 602 Phosphorus sulphides which are not free from yellow and white phosphorus are not to be accepted for carriage. 603 Anhydrous hydrogen cyanide not meeting the description for UN No. 1051 or UN No. 1614 is not to be accepted for carriage. Hydrogen cyanide (hydrocyanic acid) containing less than 3% water is stable, if the pH-value is 2.5 ± 0.5 and the liquid is clear and colourless. 604-606 (Deleted) - 599 - 607 Mixtures of potassium nitrate and sodium nitrite with an ammonium salt are not to be accepted for carriage. 608 (Deleted) 609 Tetranitromethane not free from combustible impurities is not to be accepted for carriage. 610 The carriage of this substance, when it contains more than 45% hydrogen cyanide is prohibited. 611 Ammonium nitrate containing more than 0.2% combustible substances (including any organic substance calculated as carbon) is not to be accepted for carriage unless it is a constituent of a substance or article of Class 1. 612 (Reserved) 613 Chloric acid solution containing more than 10% chloric acid and mixtures of chloric acid with any liquid other than water is not to be accepted for carriage. 614 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in concentrations considered highly toxic according to the criteria in 2.2.61.1 is not to be accepted for carriage. 615 (Reserved) 616 Substances containing more than 40% liquid nitric esters shall satisfy the exudation test specified in 2.3.1. 617 In addition to the type of explosive, the commercial name of the particular explosive shall be marked on the package. 618 In receptacles containing 1,2-butadiene, the oxygen concentration in the gaseous phase shall not exceed 50 ml/m3. 619-622 (Reserved) 623 UN No. 1829 sulphur trioxide shall be inhibited. Sulphur trioxide, 99.95% pure or above, may be carried without inhibitor in tanks provided that its temperature is maintained at or above 32.5 °C. For the carriage of this substance without inhibitor in tanks at a minimum temperature of 32.5 °C, the specification "Transport under minimum temperature of the product of 32.5 °C" shall appear in the transport document. 625 Packages containing these articles shall be clearly marked as follows: "UN 1950 AEROSOLS" 626-627 (Reserved) 632 Considered to be spontaneously flammable (pyrophoric). 633 Packages and small containers containing this substance shall bear the following marking: "Keep away from any source of ignition". This marking shall be in an official language of the forwarding country, and also, if that language is not English, French or German, in English, French or German, unless any agreements concluded between the countries concerned in the transport operation provide otherwise. 634 (Deleted) 635 Packages containing these articles need not bear a label conforming to model No. 9 unless the article is fully enclosed by packaging, crates or other means that prevent the ready identification of the article. 636 (a) Cells contained in equipment shall not be capable of being discharged during carriage to the extent that the open circuit voltage falls below 2 volts or two thirds of the voltage of the undischarged cell, whichever is the lower. - 600 - (b) Up to the intermediate processing facility, lithium cells and batteries with a gross mass of not more than 500 g each or lithium ion cells with a Watt-hour rating of not more than 20 Wh, lithium ion batteries with a Watt-hour rating of not more than 100 Wh, lithium metal cells with a lithium content of not more than 1 g and lithium metal batteries with an aggregate lithium content of not more than 2 g, whether or not contained in equipment, collected and handed over for carriage for disposal or recycling, together with or without other non-lithium cells or batteries, are not subject to the other provisions of ADR including special provision 376 and paragraph 2.2.9.1.7, if they meet the following conditions: (i) The provisions of packing instruction P909 of 4.1.4.1 apply except for the additional requirements 1 and 2; (ii) A quality assurance system is in place to ensure that the total amount of lithium cells or batteries per transport unit does not exceed 333 kg; NOTE: The total quantity of lithium cells and batteries in the mix may be assessed by means of a statistical method included in the quality assurance system. A copy of the quality assurance records shall be made available to the competent authority upon request. (iii) 637 Packages are marked "LITHIUM BATTERIES FOR DISPOSAL" or "LITHIUM BATTERIES FOR RECYCLING" as appropriate. Genetically modified microorganisms and genetically modified organisms are those which are not dangerous for humans and animals, but which could alter animals, plants, microbiological substances and ecosystems in such a way as cannot occur naturally. Genetically modified microorganisms and genetically modified organisms are not subject to the requirements of ADR when authorized for use by the competent authorities of the countries of origin, transit and destination3. Live vertebrate or invertebrate animals shall not be used to carry these substances classified under this UN number unless the substance can be carried in no other way. For the carriage of easily perishable substances under this UN number appropriate information shall be given, e.g.: "Cool at +2 °/+4 °C" or "Carry in frozen state" or "Do not freeze". 638 Substances related to self-reactive substances (see 2.2.41.1.19). 639 See 2.2.2.3, classification code 2F, UN No. 1965, Note 2. 640 The physical and technical characteristics mentioned in column (2) of Table A of Chapter 3.2 determine different tank codes for the carriage of substances of the same packing group in ADR tanks. In order to identify these physical and technical characteristics of the product carried in the tank, the following shall be added, to the particulars required in the transport document, only in case of carriage in ADR tanks: "Special provision 640X" where "X" is the applicable capital letter appearing after the reference to special provision 640 in column (6) of Table A of Chapter 3.2. These particulars may, however, be dispensed with in the case of carriage in the type of tank which, for substances of a specific packing group of a specific UN number, meets at least the most stringent requirements. 3 See in particular Part C of Directive 2001/18/EC of the European Parliament and of the Council on the deliberate release into the environment of genetically modified organisms and repealing Council Directive 90/220/EEC (Official Journal of the European Communities, No. L 106, of 17 April 2001, pp. 8-14), which sets out the authorization procedures for the European Community. - 601 - 642 Except as authorized under 1.1.4.2, this entry of the UN Model Regulations shall not be used for the carriage of fertilizer ammoniating solutions with free ammonia. 643 Stone or aggregate asphalt mixture is not subject to the requirements for Class 9. 644 This substance is admitted for carriage provided that: - The pH is between 5 and 7 measured in an aqueous solution of 10% of the substance carried; - The solution does not contain more than 0.2% combustible material or chlorine compounds in quantities such that the chlorine level exceeds 0.02%. 645 The classification code as mentioned in Column (3b) of Table A of Chapter 3.2 shall be used only with the approval of the competent authority of a Contracting Party to ADR prior to carriage. The approval shall be given in writing as a classification approval certificate (see 5.4.1.2.1 (g)) and shall be provided with a unique reference. When assignment to a division is made in accordance with the procedure in 2.2.1.1.7.2, the competent authority may require the default classification to be verified on the basis of test data derived from Test Series 6 of the Manual of Tests and Criteria, Part I, Section 16. 646 Carbon made by steam activation process is not subject to the requirements of ADR. 647 The carriage of vinegar and acetic acid food grade with not more than 25% pure acid by mass is subject only to the following requirements: (a) Packagings, including IBCs and large packagings, and tanks shall be manufactured from stainless steel or plastic material which is permanently resistant to corrosion of vinegar/acetic acid food grade; (b) Packagings, including IBCs and large packagings, and tanks shall be subjected to a visual inspection by the owner at least once a year. The results of the inspections shall be recorded and the records kept for at least one year. Damaged packagings, including IBCs and large packagings, and tanks shall not be filled; (c) Packagings, including IBCs and large packagings, and tanks shall be filled in a way that no product is spilled or adheres to the outer surface; (d) Seals and closures shall be resistant to vinegar/acetic acid food grade. Packagings, including IBCs and large packagings, and tanks shall be hermetically sealed by the packer or the filler so that under normal conditions of carriage there will be no leakage; (e) Combination packagings with inner packaging made of glass or plastic (see packing instruction P001 in 4.1.4.1) which fulfil the general packing requirements of 4.1.1.1, 4.1.1.2, 4.1.1.4, 4.1.1.5, 4.1.1.6, 4.1.1.7 and 4.1.1.8 may be used; The other provisions of ADR do not apply. 648 Articles impregnated with this pesticide, such as fibreboard plates, paper strips, cotton-wool balls, sheets of plastics material, in hermetically closed wrappings, are not subject to the provisions of ADR. 649 (Deleted) 650 Waste consisting of packaging residues, solidified residues and liquid residues of paint may be carried under the conditions of packing group II. In addition to the provisions of UN No. 1263 packing group II, the waste may also be packed and carried as follows: (a) The waste may be packed in accordance with packing instruction P002 of 4.1.4.1 or to packing instruction IBC06 of 4.1.4.2; (b) The waste may be packed in flexible IBCs of types 13H3, 13H4 and 13H5 in overpacks with complete walls; - 602 - (c) Testing of packagings and IBCs indicated under (a) or (b) may be carried out in accordance with the requirements of Chapters 6.1 or 6.5, as appropriate, in relation to solids, at the packing group II performance level. The tests shall be carried out on packagings and IBCs, filled with a representative sample of the waste, as prepared for carriage; (d) Carriage in bulk in sheeted vehicles, closed containers or sheeted large containers, all with complete walls is allowed. The body of vehicles or containers shall be leakproof or rendered leakproof, for example by means of a suitable and sufficiently stout inner lining; (e) If the waste is carried under the conditions of this special provision, the goods shall be declared in accordance with 5.4.1.1.3 in the transport document, as follows: "UN 1263 WASTE PAINT, 3, II, (D/E)", or "UN 1263 WASTE PAINT, 3, PG II, (D/E)". 651 Special provision V2 (1) does not apply if the net explosive mass per transport unit does not exceed 4 000 kg, provided that the net explosive mass per vehicle does not exceed 3 000 kg. 652 Austenitic stainless steel, ferritic and austenitic steel (Duplex steel) and welded titanium receptacles which do not meet the requirements of Chapter 6.2 but have been constructed and approved in accordance with national aviation provisions for use as hot air balloon or hot air airship fuel receptacles, brought into service (date of initial inspection) before 1 July 2004, may be carried by road provided they meet the following conditions: (a) The general provisions of 6.2.1 shall be complied with; (b) The design and construction of the receptacles shall have been approved for aviation use by a national air transport authority; (c) As an exemption from 6.2.3.1.2, the calculation pressure shall be derived from a reduced maximum ambient temperature of +40 °C; in this case: (i) as an exemption from 6.2.5.1, cylinders may be manufactured from rolled and annealed commercially pure titanium with the minimum requirements of Rm > 450 MPa, εA > 20% (εA = elongation after fracture); (ii) austenitic stainless steel and ferritic and austenitic steel (Duplex steel) cylinders may be used with a stress level up to 85% of the minimum guaranteed yield strength (Re) at a calculation pressure derived from a reduced maximum ambient temperature of +40 °C; (iii) the receptacles shall be equipped with a pressure relief device having a nominal set pressure of 26 bar; the test pressure of these receptacles shall be not less than 30 bar; (d) When the exemptions from (c) are not applied, the receptacles shall be designed for a reference temperature of 65 °C and shall be equipped with pressure relief devices with a nominal set pressure specified by the competent authority of the country of use; (e) The main body of the receptacles shall be covered by an outer, water-resistant protective layer at least 25 mm thick made from structural cellular foam or similar material; (f) During carriage, the receptacle shall be firmly secured in a crate or an additional safety device; (g) The receptacles shall be marked with a clear, visible label stating that the receptacles are for use only in hot air balloons and hot air airships; (h) The duration of service (from the date of initial inspection) shall not exceed 25 years. - 603 - 653 654 The carriage of this gas in cylinders having a test pressure capacity product of maximum 15.2 MPa.litre (152 bar.litre) is not subject to the other provisions of ADR if the following conditions are met: - The provisions for construction and testing of cylinders are observed; - The cylinders are contained in outer packagings which at least meet the requirements of Part 4 for combination packagings. The general provisions of packing of 4.1.1.1, 4.1.1.2 and 4.1.1.5 to 4.1.1.7 shall be observed; - The cylinders are not packed together with other dangerous goods; - The total gross mass of a package does not exceed 30 kg; and - Each package is clearly and durably marked with "UN 1006" for argon compressed, "UN 1013" for carbon dioxide, "UN 1046" for helium compressed or "UN 1066" for nitrogen compressed. This marking is displayed within a diamond-shaped area surrounded by a line that measures at least 100 mm by 100 mm. Waste lighters collected separately and consigned in accordance with 5.4.1.1.3 may be carried under this entry for the purposes of disposal. They need not be protected against inadvertent discharge provided that measures are taken to prevent the dangerous build up of pressure and dangerous atmospheres. Waste lighters, other than those leaking or severely deformed, shall be packed in accordance with packing instruction P003. In addition the following provisions shall apply: - only rigid packagings of a maximum capacity of 60 litres shall be used; - the packagings shall be filled with water or any other appropriate protection material to avoid any ignition; - under normal conditions of carriage all ignition devices of the lighters shall fully be covered by the protection material; - the packagings shall be adequately vented to prevent the creation of flammable atmosphere and the build up of pressure; - the packages shall only be carried in ventilated or open vehicles or containers. Leaking or severely deformed lighters shall be carried in salvage packagings, provided appropriate measures are taken to ensure there is no dangerous build up of pressure. NOTE: Special provision 201 and special packing provisions PP84 and RR5 of packing instruction P002 in 4.1.4.1 do not apply to waste lighters. 655 Cylinders and their closures designed, constructed, approved and marked in accordance with Directive 97/23/EC4 and used for breathing apparatus may be carried without conforming to Chapter 6.2, provided that they are subject to inspections and tests specified in 6.2.1.6.1 and the interval between tests specified in packing instruction P200 in 4.1.4.1 is not exceeded. The pressure used for the hydraulic pressure test is the pressure marked on the cylinder in accordance with Directive 97/23/EC4. 656 (Deleted) 657 This entry shall be used for the technically pure substance only; for mixtures of LPG components, see UN No. 1965 or see UN No. 1075 in conjunction with NOTE 2 in 2.2.2.3. 4 Directive 97/23/EC of the European Parliament and of the Council of 29 May 1997 on the approximation of the laws of the Member States concerning pressure equipment (PED) (Official Journal of the European Communities No. L 181 of 9 July 1997, p. 1 - 55). - 604 - 658 659 UN No. 1057 LIGHTERS complying with standard EN ISO 9994:2006 + A1:2008 "Lighters – Safety Specification" and UN No. 1057 LIGHTER REFILLS, may be carried subject only to the provisions of 3.4.1 (a) to (h), 3.4.2 (except for the total gross mass of 30 kg), 3.4.3 (except for the total gross mass of 20 kg), 3.4.11 and 3.4.12, provided the following conditions are met: (a) The total gross mass of each package is not more than 10 kg; (b) Not more than 100 kg gross mass of such packages is carried in a vehicle; and (c) Each outer packaging is clearly and durably marked with "UN 1057 LIGHTERS" or "UN 1057 LIGHTER REFILLS", as appropriate. Substances to which PP86 or TP7 are assigned in Column (9a) and Column (11) of Table A in Chapter 3.2 and therefore require air to be eliminated from the vapour space, shall not be used for carriage under this UN number but shall be carried under their respective UN numbers as listed in Table A of Chapter 3.2. NOTE: See also 2.2.2.1.7. 660 For the carriage of fuel gas containment systems designed to be fitted in motor vehicles containing this gas the provisions of sub-section 4.1.4.1, Chapter 5.2, Chapter 5.4 and Chapter 6.2 of ADR need not be applied, provided the following conditions are met: (a) The fuel gas containment systems shall meet the requirements of ECE Regulation No. 67 Revision 25, ECE Regulation No. 110 Revision 16 or ECE Regulation No. 1157 or Regulation (EC) No. 79/20098 in combination with Regulation (EU) No. 406/20109, as applicable. (b) The fuel gas containment systems shall be leakproof and shall not exhibit any signs of external damage which may affect their safety. NOTE 1: Criteria may be found in standard ISO 11623:2002 Transportable gas cylinders – Periodic inspection and testing of composite gas cylinders (or ISO DIS 19078 Gas cylinders – Inspection of the cylinder installation, and requalification of high pressure cylinders for the on-board storage of natural gas as a fuel for automotive vehicles). NOTE 2: If the fuel gas containment systems are not leakproof or overfilled or if they exhibit damage that could affect their safety, they shall only be carried in salvage pressure receptacles in conformity with ADR. (c) If the fuel gas containment system is equipped with two valves or more integrated in line, two valves shall be so closed as to be gastight under normal conditions of carriage. If only one valve exists or only one valve works properly all openings with the exception of the opening of the pressure relief device shall be so closed as to be gastight under normal conditions of carriage. 5 ECE Regulation No. 67 (Uniform provisions concerning: I. Approval of specific equipment of motor vehicles using liquefied petroleum gases in their propulsion system; II. Approval of a vehicle fitted with specific equipment for the use of liquefied petroleum gases in its propulsion system with regard to the installation of such equipment). 6 ECE Regulation No. 110 (Uniform provisions concerning the approval of: I. Specific components of motor vehicles using compressed natural gas (CNG) and/or liquefied natural gas (LNG) in their propulsion system; II. Vehicles with regard to the installation of specific components of an approved type for the use of compressed natural gas (CNG) and/or liquefied natural gas (LNG) in their propulsion system.) 7 ECE Regulation No. 115 (Uniform provisions concerning the approval of: I. Specific LPG (liquefied petroleum gases) retrofit systems to be installed in motor vehicles for the use of LPG in their propulsion system; II. Specific CNG (compressed natural gas) retrofit systems to be installed in motor vehicles for the use of CNG in their propulsion system). 8 Regulation (EC) No 79/2009 of the European Parliament and of the Council of 14 January 2009 on typeapproval of hydrogen-powered motor vehicles, and amending Directive 2007/46/EC. 9 Commission Regulation (EU) No 406/2010 of 26 April 2010 implementing Regulation (EC) No 79/2009 of the European Parliament and of the Council on type-approval of hydrogen-powered motor vehicles. - 605 - (d) Fuel gas containment systems shall be carried in such a way as to prevent obstruction of the pressure relief device or any damage to the valves and any other pressurised part of the fuel gas containment systems and unintentional release of the gas under normal conditions of carriage. The fuel gas containment system shall be secured so as to prevent slipping, rolling or vertical movement. (e) Fuel gas containment systems shall satisfy the provisions of 4.1.6.8 (a), (b), (c), (d) or (e). (f) The marking and labelling provisions of Chapter 5.2 shall be met, unless fuel gas containment systems are consigned in a handling device. If so, the markings and danger labels shall be affixed to the handling device. (g) Documentation Every consignment that is carried in accordance with this special provision shall be accompanied by a transport document, containing at least the following information: (i) The UN number of the gas contained in the fuel gas containment systems, preceded by the letters "UN"; (ii) The proper shipping name of the gas; (iii) The label model number; (iv) The number of fuel gas containment systems; (v) In the case of liquefied gases the net mass in kg of the gas of each fuel gas containment system and in the case of compressed gases the water capacity in litres of each fuel gas containment system followed by the nominal working pressure; (vi) The names and the addresses of the consignor and the consignee. (i) to (v) shall appear according to one of the following examples: Example 1: UN 1971 natural gas, compressed, 2.1, 1 fuel gas containment system of 50 l in total, 200 bar. Example 2: UN 1965 hydrocarbon gas mixture, liquefied, n.o.s., 2.1, 3 fuel gas containment systems, each of 15 kg net mass of gas. NOTE: All other provisions of ADR shall be applied. 661 (Deleted) 662 Cylinders not conforming to the provisions of Chapter 6.2 which are used exclusively on board a ship or aircraft, may be carried for the purpose of filling or inspection and subsequent return, provided the cylinders are designed and constructed in accordance with a standard recognized by the competent authority of the country of approval and all the other relevant requirements of ADR are met including: (a) The cylinders shall be carried with valve protection in conformity with 4.1.6.8; (b) The cylinders shall be marked and labelled in conformity with 5.2.1 and 5.2.2; and (c) All the relevant filling requirements of packing instruction P200 of 4.1.4.1 shall be complied with. The transport document shall include the following statement: "Carriage in accordance with special provision 662". - 606 - 663 This entry may only be used for packagings, large packagings or IBCs, or parts thereof, which have contained dangerous goods which are carried for disposal, recycling or recovery of their material, other than reconditioning, repair, routine maintenance, remanufacturing or reuse, and which have been emptied to the extent that only residues of dangerous goods adhering to the packaging parts are present when they are handed over for carriage. Scope: Residues present in the packagings, discarded, empty, uncleaned shall only be of dangerous goods of classes 3, 4.1, 5.1, 6.1, 8 or 9. In addition, they shall not be: - Substances assigned to packing group I or that have "0" assigned in Column (7a) of Table A of Chapter 3.2; nor - Substances classified as desensitized explosive substances of Class 3 or Class 4.1; nor - Substances classified as self-reactive substances of Class 4.1; nor - Radioactive material; nor - Asbestos (UN 2212 and UN 2590), polychlorinated biphenyls (UN 2315 and UN 3432) and polyhalogenated biphenyls or polyhalogenated terphenyls (UN 3151 and UN 3152). General provisions: Packagings, discarded, empty, uncleaned with residues presenting a risk or a subsidiary risk of Class 5.1 shall not be packed together with other packagings, discarded, empty, uncleaned, or loaded together with other packagings, discarded, empty, uncleaned in the same container, vehicle or bulk container. Documented sorting procedures shall be implemented on the loading site to ensure compliance with the provisions applicable to this entry. NOTE: 664 All the other provisions of ADR apply. When substances under this entry are carried in fixed tanks (tank-vehicles) or demountable tanks, these tanks may be equipped with additive devices. Additive devices: - are part of the service equipment for dispensing additives of UN 1202, UN 1993 packing group III, UN 3082 or non-dangerous substances during discharge of the tank; - consist of elements such as connecting pipes and hoses, closing devices, pumps and dosing devices which are permanently connected to the discharge device of the tank’s service equipment; - include means of containment which are an integral part of the shell, or permanently fixed to the exterior of the tank or tank-vehicle. Alternatively, additive devices may have connectors for connecting packagings. In this latter case, the packaging itself is not considered part of the additive device. The following requirements shall apply depending on the configuration: (a) Construction of the means of containment: (i) As an integral part of the shell (e.g. a tank compartment), they shall meet the relevant provisions of Chapter 6.8. (ii) When permanently fixed to the exterior of the tank or to the tank-vehicle, they are not subject to the construction provisions of ADR provided they comply with the following provisions: - 607 - They shall be made of a metallic material and comply with the following minimum wall thickness requirements: Material Minimum wall thicknessa Austenitic stainless steels 2.5 mm Other steels 3 mm Aluminium alloys 4 mm Pure aluminium of 99.80% 6 mm a For means of containment made with double walls, the aggregate thickness of the outer metal wall and the inner metal wall shall correspond to the wall thickness prescribed. Welding shall be carried out in accordance with 6.8.2.1.23. (iii) (b) Packagings which are connectable to the additive device shall be metal packagings and meet the relevant construction requirements of Chapter 6.1, as applicable for the additive concerned. Tank approval For tanks equipped or intended to be equipped with additive devices, where the additive device is not included in the original type approval of the tank, the provisions of 6.8.2.3.4 shall apply. (c) (d) Use of means of containment and additive devices (i) In case of (a) (i) above, no additional requirements. (ii) In case of (a) (ii) above, the total capacity of the means of containment shall not exceed 400 litres per vehicle. (iii) In case of (a) (iii) above, 7.5.7.5 and 8.3.3 shall not apply. The packagings may only be connected to the additive device during discharge of the tank. During carriage, the closures and connectors shall be closed so as to be leaktight. Testing for additive devices The provisions of 6.8.2.4 shall apply to the additive device. However, in case of (a) (ii) above, at the time of the initial, intermediate or periodic inspection of the tank, the means of containment of the additive device shall only be subject to an external visual inspection and a leakproofness test. The leakproofness test shall be carried out at a test pressure of at least 0.2 bar. NOTE: For the packagings described in (a) (iii) above, the relevant provisions of ADR shall apply. (e) Transport document Only the information required in accordance with 5.4.1.1.1 (a) to (d) needs to be added to the transport document for the additive concerned. The following shall also be entered in the transport document: "Carriage in accordance with special provision 664". (f) Training of drivers Drivers who have been trained in accordance with 8.2.1 for carriage of this substance in tanks need no additional training for the carriage of the additives; (g) Placarding or marking Placarding or marking of the fixed tank (tank-vehicle) or demountable tank for the carriage of substances under this entry in accordance with Chapter 5.3 is not affected by the presence of an additive device or the additives contained therein. - 608 - CHAPTER 3.4 DANGEROUS GOODS PACKED IN LIMITED QUANTITIES 3.4.1 This Chapter provides the provisions applicable to the carriage of dangerous goods of certain classes packed in limited quantities. The applicable quantity limit for the inner packaging or article is specified for each substance in Column (7a) of Table A of Chapter 3.2. In addition, the quantity "0" has been indicated in this column for each entry not permitted to be carried in accordance with this Chapter. Limited quantities of dangerous goods packed in such limited quantities, meeting the provisions of this Chapter are not subject to any other provisions of ADR except the relevant provisions of: (a) Part 1, Chapters 1.1, 1.2, 1.3, 1.4, 1.5, 1.6, 1.8, 1.9; (b) Part 2; (c) Part 3, Chapters 3.1, 3.2, 3.3 (except special provisions 61, 178, 181, 220, 274, 625, 633 and 650 (e)); (d) Part 4, paragraphs 4.1.1.1, 4.1.1.2, 4.1.1.4 to 4.1.1.8; (e) Part 5, 5.1.2.1(a) (i) and (b), 5.1.2.2, 5.1.2.3, 5.2.1.9, 5.4.2; (f) Part 6, construction requirements of 6.1.4 and paragraphs 6.2.5.1 and 6.2.6.1 to 6.2.6.3; (g) Part 7, Chapter 7.1 and 7.2.1, 7.2.2, 7.5.1 (except 7.5.1.4), 7.5.2.4, 7.5.7, 7.5.8 and 7.5.9; (h) 8.6.3.3 and 8.6.4. 3.4.2 Dangerous goods shall be packed only in inner packagings placed in suitable outer packagings. Intermediate packagings may be used. In addition, for articles of Division 1.4, Compatibility Group S, the provisions of section 4.1.5 shall be fully complied with. The use of inner packagings is not necessary for the carriage of articles such as aerosols or "receptacles, small, containing gas". The total gross mass of the package shall not exceed 30 kg. 3.4.3 Except for articles of Division 1.4, Compatibility Group S, shrink-wrapped or stretch-wrapped trays meeting the conditions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8 are acceptable as outer packagings for articles or inner packagings containing dangerous goods carried in accordance with this Chapter. Inner packagings that are liable to break or be easily punctured, such as those made of glass, porcelain, stoneware or certain plastics, shall be placed in suitable intermediate packagings meeting the provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8, and be so designed that they meet the construction requirements of 6.1.4. The total gross mass of the package shall not exceed 20 kg. 3.4.4 Liquid goods of Class 8, packing group II in glass, porcelain or stoneware inner packagings shall be enclosed in a compatible and rigid intermediate packaging. 3.4.5 and 3.4.6 (Reserved) 3.4.7 Marking for packages containing limited quantities 3.4.7.1 Except for air transport, packages containing dangerous goods in limited quantities shall bear the marking shown in Figure 3.4.7.1: - 609 - Figure 3.4.7.1 Marking for packages containing limited quantities The marking shall be readily visible, legible and able to withstand open weather exposure without a substantial reduction in effectiveness. The marking shall be in the form of a square set at an angle of 45° (diamond-shaped). The top and bottom portions and the surrounding line shall be black. The centre area shall be white or a suitable contrasting background. The minimum dimensions shall be 100 mm x 100 mm and the minimum width of the line forming the diamond shall be 2 mm. Where dimensions are not specified, all features shall be in approximate proportion to those shown. 3.4.7.2 If the size of the package so requires, the minimum outer dimensions shown in Figure 3.4.7.1 may be reduced to be not less than 50 mm x 50 mm provided the marking remains clearly visible. The minimum width of the line forming the diamond may be reduced to a minimum of 1 mm. 3.4.8 Marking for packages containing limited quantities conforming to Part 3, Chapter 4 of the ICAO Technical Instructions 3.4.8.1 Packages containing dangerous goods packed in conformity with the provisions of Part 3, Chapter 4 of the ICAO Technical Instructions may bear the marking shown in Figure 3.4.8.1 to certify conformity with these provisions: Figure 3.4.8.1 Marking for packages containing limited quantities conforming to Part 3, Chapter 4 of the ICAO Technical Instructions The marking shall be readily visible, legible and able to withstand open weather exposure without a substantial reduction in effectiveness. - 610 - The marking shall be in the form of a square set at an angle of 45° (diamond-shaped). The top and bottom portions and the surrounding line shall be black. The centre area shall be white or a suitable contrasting background. The minimum dimensions shall be 100 mm x 100 mm and the minimum width of the line forming the diamond shall be 2 mm. The symbol "Y" shall be placed in the centre of the mark and shall be clearly visible. Where dimensions are not specified, all features shall be in approximate proportion to those shown. 3.4.8.2 If the size of the package so requires, the minimum outer dimensions shown in Figure 3.4.8.1 may be reduced to be not less than 50 mm x 50 mm provided the marking remains clearly visible. The minimum width of the line forming the diamond may be reduced to a minimum of 1 mm. The symbol "Y" shall remain in approximate proportion to that shown in Figure 3.4.8.1. 3.4.9 Packages containing dangerous goods bearing the marking shown in 3.4.8 with or without the additional labels and markings for air transport shall be deemed to meet the provisions of section 3.4.1 as appropriate and of sections 3.4.2 to 3.4.4 and need not bear the marking shown in 3.4.7. 3.4.10 Packages containing dangerous goods in limited quantities bearing the marking shown in 3.4.7 and conforming with the provisions of the ICAO Technical Instructions, including all necessary marks and labels specified in Parts 5 and 6, shall be deemed to meet the provisions of section 3.4.1 as appropriate and of sections 3.4.2 to 3.4.4. 3.4.11 When packages containing dangerous goods packed in limited quantities are placed in an overpack, the provisions of 5.1.2 shall apply. In addition the overpack shall be marked with the markings required by this Chapter unless the markings representative of all dangerous goods in the overpack are visible. The provisions of 5.1.2.1 (a) (ii) and 5.1.2.4 apply only if other dangerous goods which are not packed in limited quantities are contained, and only in relation to these other dangerous goods. 3.4.12 In advance of carriage, consignors of dangerous goods packed in limited quantities shall inform the carrier in a traceable form of the total gross mass of such goods to be consigned. 3.4.13 (a) Transport units with a maximum mass exceeding 12 tonnes carrying dangerous goods packed in limited quantities shall be marked in accordance with 3.4.15 at the front and at the rear except when the transport unit contains other dangerous goods for which orange-coloured plate marking in accordance with 5.3.2 is required. In this latter case, the transport unit may display the required orange-coloured plate marking only, or both the orange-coloured plate marking in accordance with 5.3.2 and the marking in accordance with 3.4.15. (b) Containers carrying dangerous goods packed in limited quantities, on transport units with a maximum mass exceeding 12 tonnes, shall be marked in accordance with 3.4.15 on all four sides except when the container contains other dangerous goods for which placarding in accordance with 5.3.1 is required. In this latter case, the container may display the required placards only, or both the placards in accordance with 5.3.1 and the marking in accordance with 3.4.15. The carrying transport unit need not be marked, except when the marking affixed to the containers is not visible from outside this carrying transport unit. In this latter case, the same marking shall be affixed at the front and at the rear of the transport unit. 3.4.14 Markings specified in 3.4.13 may be dispensed with, if the total gross mass of the packages containing dangerous goods packed in limited quantities carried does not exceed 8 tonnes per transport unit. 3.4.15 The marking shall be that required in 3.4.7, except that the minimum dimensions shall be 250 mm  250 mm. - 611 - CHAPTER 3.5 DANGEROUS GOODS PACKED IN EXCEPTED QUANTITIES 3.5.1 Excepted quantities 3.5.1.1 Excepted quantities of dangerous goods of certain classes, other than articles, meeting the provisions of this Chapter are not subject to any other provisions of ADR except for: (a) The training requirements in Chapter 1.3; (b) The classification procedures and packing group criteria in Part 2; (c) The packaging requirements of 4.1.1.1, 4.1.1.2, 4.1.1.4 and 4.1.1.6. NOTE: In the case of radioactive material, the requirements for radioactive material in excepted packages in 1.7.1.5 apply. 3.5.1.2 Dangerous goods which may be carried as excepted quantities in accordance with the provisions of this Chapter are shown in column (7b) of Table A of Chapter 3.2 list by means of an alphanumeric code as follows: Code E0 E1 E2 E3 E4 E5 Maximum net quantity per outer packaging (in Maximum net quantity grams for solids and ml for liquids per inner packaging and gases, or sum of grams and ml (in grams for solids in the case of mixed packing) and ml for liquids and gases) Not permitted as Excepted Quantity 30 1000 30 500 30 300 1 500 1 300 For gases, the volume indicated for inner packagings refers to the water capacity of the inner receptacle and the volume indicated for outer packagings refers to the combined water capacity of all inner packagings within a single outer packaging. 3.5.1.3 Where dangerous goods in excepted quantities for which different codes are assigned are packaged together the total quantity per outer packaging shall be limited to that corresponding to the most restrictive code. 3.5.1.4 Excepted quantities of dangerous goods assigned to codes E1, E2, E4 and E5 with a maximum net quantity of dangerous goods per inner packaging limited to 1 ml for liquids and gases and 1 g for solids and a maximum net quantity of dangerous goods per outer packaging which does not exceed 100 g for solids or 100 ml for liquids and gases are only subject to: (a) The provisions of 3.5.2, except that an intermediate packaging is not required if the inner packagings are securely packed in an outer packaging with cushioning material in such a way that, under normal conditions of carriage, they cannot break, be punctured, or leak their contents; and for liquids, the outer packaging contains sufficient absorbent material to absorb the entire contents of the inner packagings; and (b) The provisions of 3.5.3. - 613 - 3.5.2 Packagings Packagings used for the carriage of dangerous goods in excepted quantities shall be in compliance with the following: (a) There shall be an inner packaging and each inner packaging shall be constructed of plastic (with a minimum thickness of 0.2 mm when used for liquids), or of glass, porcelain, stoneware, earthenware or metal (see also 4.1.1.2) and the closure of each inner packaging shall be held securely in place with wire, tape or other positive means; any receptacle having a neck with moulded screw threads shall have a leak proof threaded type cap. The closure shall be resistant to the contents; (b) Each inner packaging shall be securely packed in an intermediate packaging with cushioning material in such a way that, under normal conditions of carriage, they cannot break, be punctured or leak their contents. The intermediate packaging shall completely contain the contents in case of breakage or leakage, regardless of package orientation. For liquids, the intermediate packaging shall contain sufficient absorbent material to absorb the entire contents of the inner packaging. In such cases, the absorbent material may be the cushioning material. Dangerous goods shall not react dangerously with cushioning, absorbent material and packaging material or reduce the integrity or function of the materials; (c) The intermediate packaging shall be securely packed in a strong, rigid outer packaging (wooden, fibreboard or other equally strong material); (d) Each package type shall be in compliance with the provisions in 3.5.3; (e) Each package shall be of such a size that there is adequate space to apply all necessary markings; and (f) Overpacks may be used and may also contain packages of dangerous goods or goods not subject to the requirements of ADR. 3.5.3 Tests for packages 3.5.3.1 The complete package as prepared for carriage, with inner packagings filled to not less than 95% of their capacity for solids or 98% for liquids, shall be capable of withstanding, as demonstrated by testing which is appropriately documented, without breakage or leakage of any inner packaging and without significant reduction in effectiveness: (a) Drops onto a rigid, non-resilient flat and horizontal surface from a height of 1.8 m: (i) Where the sample is in the shape of a box, it shall be dropped in each of the following orientations: - flat on the base; - flat on the top; - flat on the longest side; - flat on the shortest side; - on a corner; - 614 - (ii) Where the sample is in the shape of a drum, it shall be dropped in each of the following orientations: - diagonally on the top chime, with the centre of gravity directly above the point of impact; - diagonally on the base chime; - flat on the side; NOTE: Each of the above drops may be performed on different but identical packages. (b) A force applied to the top surface for a duration of 24 hours, equivalent to the total weight of identical packages if stacked to a height of 3 m (including the sample). 3.5.3.2 For the purposes of testing, the substances to be carried in the packaging may be replaced by other substances except where this would invalidate the results of the tests. For solids, when another substance is used, it must have the same physical characteristics (mass, grain size, etc.) as the substance to be carried. In the drop tests for liquids, when another substance is used, its relative density (specific gravity) and viscosity should be similar to those of the substance to be carried. 3.5.4 Marking of packages 3.5.4.1 Packages containing excepted quantities of dangerous goods prepared in accordance with this Chapter shall be durably and legibly marked with the mark shown in 3.5.4.2. The first or only label number indicated in column (5) of Table A of Chapter 3.2 for each of the dangerous goods contained in the package shall be shown in the mark. Where the name of the consignor or consignee is not shown elsewhere on the package this information shall be included within the mark. 3.5.4.2 Excepted quantities mark Minimum dimension 100 mm Figure 3.5.4.2 Minimum dimension 100 mm Excepted quantities mark * The first or only label number indicated in column (5) of Table A of Chapter 3.2 shall be shown in this location. ** The name of the consignor or of the consignee shall be shown in this location if not shown elsewhere on the package. - 615 - The marking shall be in the form of a square. The hatching and symbol shall be of the same colour, black or red, on white or suitable contrasting background. The minimum dimensions shall be 100 mm x 100 mm. Where dimensions are not specified, all features shall be in approximate proportion to those shown. 3.5.4.3 An overpack containing dangerous goods in excepted quantities shall display the markings required by 3.5.4.1, unless such markings on packages within the overpack are clearly visible. 3.5.5 Maximum number of packages in any vehicle or container The number of packages in any vehicle or container shall not exceed 1 000. 3.5.6 Documentation If a document or documents (such as a bill of lading, air waybill or CMR/CIM consignment note) accompanies(y) dangerous goods in excepted quantities, at least one of these documents shall include the statement "Dangerous Goods in Excepted Quantities" and indicate the number of packages. - 616 - ECE/TRANS/242 (Vol.II) Economic Commission for Europe Committee on Inland Transport applicable as from 1 January 2015 European Agreement Concerning the International Carriage of Dangerous Goods by Road Volume II UNITED NATIONS New York and Geneva, 2014 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ECE/TRANS/242 (Vol.II) Copyright  United Nations, 2014 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS PUBLICATION Sales No.: 14.VIII.1 ISBN 978-92-1-139149-7 (complete set of 2 volumes) e-ISBN 978-92-1-056691-9 Volumes I and II not to be sold separately. United Nations Economic Commission for Europe (UNECE) The United Nations Economic Commission for Europe (UNECE) is one of the five United Nations regional commissions, administered by the Economic and Social Council (ECOSOC). It was established in 1947 with the mandate to help rebuild post-war Europe, develop economic activity and strengthen economic relations among European countries, and between Europe and the rest of the world. During the Cold War, UNECE served as a unique forum for economic dialogue and cooperation between East and West. Despite the complexity of this period, significant achievements were made, with consensus reached on numerous harmonization and standardization agreements. In the post-Cold War era, UNECE acquired not only many new member States, but also new functions. Since the early 1990s the organization has focused on analyses of the transition process, using its harmonization experience to facilitate the integration of central and eastern European countries into global markets. UNECE is the forum where the countries of western, central and eastern Europe, Central Asia and North America – 56 countries in all – come together to forge the tools of their economic cooperation. That cooperation concerns economics, statistics, environment, transport, trade, sustainable energy, timber and habitat. The Commission offers a regional framework for the elaboration and harmonization of conventions, norms and standards. The Commission's experts provide technical assistance to the countries of South-East Europe and the Commonwealth of Independent States. This assistance takes the form of advisory services, training seminars and workshops where countries can share their experiences and best practices. - iii - Transport in UNECE The UNECE Inland Transport Committee (ITC) facilitates the international movement of persons and goods by inland transport modes. It aims to improve competitiveness, safety, energy efficiency and security in the transport sector. At the same time it focuses on reducing the adverse effects of transport activities on the environment and contributing effectively to sustainable development. The ITC is a: - Centre for multilateral transport standards and agreements in Europe and beyond, e.g. regulations for dangerous goods transport and road vehicle construction at the global level - Gateway for technical assistance and exchange of best practices - Promoter of multi-country investment planning - Substantive partner for transport and trade facilitation initiatives - Historic centre for transport statistics. For more than six decades, ITC has provided a platform for intergovernmental cooperation to facilitate and develop international transport while improving its safety and environmental performance. The main results of this persevering and important work are reflected in more than 50 international agreements and conventions which provide an international legal framework and technical regulations for the development of international road, rail, inland water and intermodal transport, as well as dangerous goods transport and vehicle construction. Considering the needs of the transport sector and its regulators, UNECE offers a balanced approach to and treatment of facilitation and security issues alike. - iv - TABLE OF CONTENTS VOLUME II Page Annex A (cont’d) General provisions and provisions concerning dangerous substances and articles .............................................................................................................. 1 Part 4 Packing and tank provisions ........................................................................................... 3 Chapter 4.1 4.1.1 4.1.2 4.1.3 4.1.4 4.1.5 4.1.6 4.1.7 4.1.8 4.1.9 4.1.10 Chapter 4.2 4.2.1 4.2.2 4.2.3 4.2.4 4.2.5 Chapter 4.3 4.3.1 4.3.2 4.3.3 4.3.4 4.3.5 Chapter 4.4 4.4.1 4.4.2 Use of packagings, including intermediate bulk containers (IBCs) and large packagings .......................................... 5 General provisions for the packing of dangerous goods in packagings, including IBCs and large packagings .......................... Additional general provisions for the use of IBCs .............................. General provisions concerning packing instructions .......................... List of packing instructions ................................................................. Special packing provisions for goods of Class 1 ................................ Special packing provisions for goods of Class 2 and goods of other classes assigned to packing instruction P200 ......................... Special packing provisions for organic peroxides (Class 5.2) and self-reactive substances of Class 4.1 ............................................ Special packing provisions for infectious substances (Class 6.2) ........ Special packing provisions for radioactive material ........................... Special provisions for mixed packing ................................................. 139 140 141 144 Use of portable tanks and UN multiple-element gas containers (MEGCs) ..................................... 151 5 33 34 37 135 136 General provisions for the use of portable tanks for the carriage of substances of Class 1 and Classes 3 to 9 ..................... General provisions for the use of portable tanks for the carriage of non-refrigerated liquefied gases and chemicals ........... under presure General provisions for the use of portable tanks for the carriage of refrigerated liquefied gases ......................................... General provisions for the use of UN multiple-element gas containers (MEGCs) ................................... Portable tank instructions and special provisions ............................... 158 159 Use of fixed tanks (tank-vehicles), demountable tanks, tank-containers and tank swap bodies with shells made of metallic materials, and battery-vehicles and multiple-element gas containers (MEGCs) ..................................... 175 Scope ................................................................................................... Provisions applicable to all classes ..................................................... Special provisions applicable to Class 2 ............................................. Special provisions applicable to Classes 1 and 3 to 9 ......................... Special provisions ............................................................................... 175 175 179 188 195 Use of fibre-reinforced plastics (FRP) tanks, fixed-tanks (tank-vehicles), demountable tanks, tank containers and tank swap bodies ............................................ 199 General ................................................................................................ Operation ............................................................................................. 199 199 -v- 151 155 156 Table of contents (cont'd) Page Chapter 4.5 Use of vacuum operated waste tanks ............................................... 201 Use ...................................................................................................... Operation ............................................................................................. 201 201 Chapter 4.6 (Reserved) ........................................................................................... 203 Chapter 4.7 Use of mobile explosives manufacturing units (MEMUs) ............. 205 Use ...................................................................................................... Operation ............................................................................................. 205 205 Consignment procedures ................................................................................................. 207 Chapter 5.1 General provisions ............................................................................ 209 Application and general provisions ..................................................... Use of overpacks ................................................................................. Empty uncleaned packagings (including IBCs and large packagings), tanks, MEMUs, vehicles and containers for carriage in bulk ............. Mixed packing ..................................................................................... General provisions for Class 7 ............................................................ 209 209 209 210 210 Marking and labelling ...................................................................... 217 Marking of packages ........................................................................... Labelling of packages ......................................................................... 217 221 Placarding and marking of containers, MEGCs, MEMUs, tank-containers, portable tanks and vehicles ................................. 229 Placarding ............................................................................................ Orange-coloured plate marking ........................................................... Elevated temperature substance mark ................................................. (Reserved) ........................................................................................... (Reserved) ........................................................................................... Environmentally hazardous substance mark ........................................ 229 232 237 238 238 238 Documentation .................................................................................. 239 General ................................................................................................. Dangerous goods transport document and related information ........... Large container or vehicle packing certificate .................................... Instructions in writing ......................................................................... Retention of dangerous goods transport information ........................... Example of a multimodal dangerous goods form ............................... 239 239 248 249 255 255 Special provisions .............................................................................. 259 4.5.1 4.5.2 4.7.1 4.7.2 Part 5 5.1.1 5.1.2 5.1.3 5.1.4 5.1.5 Chapter 5.2 5.2.1 5.2.2 Chapter 5.3 5.3.1 5.3.2 5.3.3 5.3.4 5.3.5 5.3.6 Chapter 5.4 5.4.0 5.4.1 5.4.2 5.4.3 5.4.4 5.4.5 Chapter 5.5 5.5.1 5.5.2 5.5.3 (Deleted)............................................................................................... 259 Special provisions applicable to fumigated cargo transport units (UN 3359) ............................................................................................ 259 Special provisions applicable to packages and vehicles and containers containing substances presenting a risk of asphyxiation when used for cooling or conditioning purposes (such as dry ice (UN 1845) or nitrogen, refrigerated liquid (UN 1977) or argon, refrigerated liquid (UN 1951)).............................................. 261 - vi - Table of contents (cont'd) Page Part 6 Requirements for the construction and testing of packagings, intermediate bulk containers (IBCs), large packagings, tanks and bulk containers ......................... Chapter 6.1 6.1.1 6.1.2 6.1.3 6.1.4 6.1.5 6.1.6 Chapter 6.2 6.2.1 6.2.2 6.2.3 6.2.4 6.2.5 6.2.6 Chapter 6.3 6.3.1 6.3.2 6.3.3 6.3.4 6.3.5 Chapter 6.4 6.4.1 6.4.2 6.4.3 6.4.4 6.4.5 6.4.6 6.4.7 6.4.8 6.4.9 6.4.10 6.4.11 6.4.12 Requirements for the construction and testing of packagings .......................................................................................... General ................................................................................................ Code for designating types of packagings .......................................... Marking ............................................................................................... Requirements for packagings .............................................................. Test requirements for packagings ....................................................... Standard liquids for verifying the chemical compatibility testing of polyethylene packagings, including IBCs, in accordance with 6.1.5.2.6 and 6.5.6.3.5, respectively .................... Requirements for the construction and testing of pressure receptacles, aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas ..................................................................................... General requirements .......................................................................... Requirements for UN pressure receptacles ......................................... General requirements for non-UN pressure receptacles....................... Requirements for non-UN pressure receptacles designed, constructed and tested according to referenced standards ................... Requirements for non-UN pressure receptacles not designed, constructed and tested according to referenced standards ................... General requirements for aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas..................................... 265 267 267 268 270 274 285 294 297 297 302 319 323 329 333 Requirements for the construction and testing of packagings for Class 6.2 infectious substances of Category A ........................... 337 General ................................................................................................ Requirements for packagings .............................................................. Code for designating types of packagings .......................................... Marking ............................................................................................... Test requirements for packagings ....................................................... 337 337 337 337 338 Requirements for the construction, testing and approval of packages for radioactive material and for the approval of such material............................................................ 343 (Reserved) ........................................................................................... General requirements .......................................................................... (Reserved) ........................................................................................... Requirements for excepted packages .................................................. Requirements for Industrial packages ................................................. Requirements for packages containing uranium hexafluoride ............ Requirements for Type A packages .................................................... Requirements for Type B(U) packages ............................................... Requirements for Type B(M) packages .............................................. Requirements for Type C packages ..................................................... Requirements for packages containing fissile material ....................... Test procedures and demonstration of compliance ............................. 343 343 344 344 344 345 346 347 349 349 350 353 - vii - Table of contents (cont'd) Page 6.4.13 6.4.14 6.4.15 6.4.16 6.4.17 6.4.18 6.4.19 6.4.20 6.4.21 6.4.22 6.4.23 Chapter 6.5 6.5.1 6.5.2 6.5.3 6.5.4 6.5.5 6.5.6 Chapter 6.6 6.6.1 6.6.2 6.6.3 6.6.4 6.6.5 Chapter 6.7 6.7.1 6.7.2 6.7.3 6.7.4 6.7.5 Testing the integrity of the containment system and shielding and evaluating criticality safety .......................................................... Target for drop tests ............................................................................ Tests for demonstrating ability to withstand normal conditions of carriage .......................................................................... Additional tests for Type A packages designed for liquids and gases.............................................................. Tests for demonstrating ability to withstand accident conditions in carriage .......................................................................... Enhanced water immersion test for Type B(U) and Type B(M) packages containing more than 105 A2 and Type C packages ........................................................................... Water leakage test for packages containing fissile material ................ Tests for Type C packages ................................................................... Inspections for packagings designed to contain 0.1 kg or more of uranium hexafluoride ...................................................................... Approvals of package designs and materials ...................................... Applications and approvals for radioactive material carriage ............. 354 354 355 356 356 357 357 357 358 359 360 Requirements for the construction and testing of intermediate bulk containers (IBCs) ........................................... 369 General requirements ........................................................................... Marking ............................................................................................... Construction requirements ................................................................... Testing, certification and inspection ................................................... Specific requirements for IBCs ........................................................... Test requirements for IBCs ................................................................. 369 371 374 375 376 383 Requirements for the construction and testing of large packagings ................................................................................ 393 General ................................................................................................ Code for designating types of large packagings ................................. Marking ............................................................................................... Specific requirements for large packagings ........................................ Test requirements for large packagings .............................................. 393 393 394 395 397 Requirements for the design, construction, inspection and testing of portable tanks and UN multiple-element gas containers (MEGCs) ............................... 403 Application and general requirements ................................................. Requirements for the design, construction, inspection and testing of portable tanks intended for the carriage of substances of Class 1 and Classes 3 to 9 ......................................... Requirements for the design, construction, inspection and testing of portable tanks intended for the carriage of non-refrigerated liquefied gases ...................................................... Requirements for the design, construction, inspection and testing of portable tanks intended for the carriage of refrigerated liquefied gases ............................................................. Requirements for the design, construction, inspection and testing of UN multiple-element gas containers (MEGCs) intended for the carriage of non–refrigerated gases ............................. - viii - 403 403 420 434 446 Table of contents (cont'd) Page Chapter 6.8 6.8.1 6.8.2 6.8.3 6.8.4 6.8.5 Requirements for the construction, equipment, type approval, inspections and tests, and marking of fixed tanks (tank-vehicles), demountable tanks and tank-containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple element gas containers (MEGCs) ..................................... 455 Scope ................................................................................................... Requirements applicable to all classes ................................................ Special requirements applicable to Class 2 ......................................... Special provisions ............................................................................... Requirements concerning the materials and construction of fixed welded tanks, demountable welded tanks, and welded shells of tank-containers for which a test pressure of not less than 1 MPa (10 bar) is required, and of fixed welded tanks, demountable welded tanks and welded shells of tank-containers intended for the carriage of refrigerated liquefied gases of Class 2 .................................................................... 492 Requirements for the design, construction, equipment, type approval, testing and marking of fibre-reinforced plastics (FRP) fixed tanks (tank-vehicles), demountable tanks, tank-containers and tank swap bodies ............................................ 497 6.9.1 6.9.2 6.9.3 6.9.4 6.9.5 6.9.6 General ................................................................................................ Construction ........................................................................................ Items of equipment .............................................................................. Type testing and approval ................................................................... Inspections .......................................................................................... Marking ............................................................................................... 497 497 501 501 503 503 Chapter 6.10 Requirements for the construction, equipment, type approval, inspection and marking of vacuum-operated waste tanks ......................................................................................... 505 General ................................................................................................ Construction ........................................................................................ Items of equipment .............................................................................. Inspection ............................................................................................ 505 505 506 507 Requirements for the design, construction, inspection and testing of bulk containers ........................................................... 509 Chapter 6.9 6.10.1 6.10.2 6.10.3 6.10.4 Chapter 6.11 6.11.1 6.11.2 6.11.3 6.11.4 (Reserved) ............................................................................................ Application and general requirements ................................................. Requirements for the design, construction, inspection and testing of containers conforming to the CSC used as BK1 or BK2 bulk containers .......................................................... Requirements for the design, construction and approval of BK1 or BK2 bulk containers other than containers conforming to the CSC ............................................................................................ - ix - 455 455 475 485 509 509 509 510 Table of contents (cont'd) Page Chapter 6.12 Requirements for the construction, equipment, type approval, inspections and tests, and marking of tanks, bulk containers and special compartments for explosives of mobile explosives manufacturing units (MEMUs) ....................................................... 511 Scope .................................................................................................... General provisions .............................................................................. Tanks ................................................................................................... Items of equipment ............................................................................... Special compartments for explosives ................................................... 511 511 511 513 513 Provisions concerning the conditions of carriage, loading, unloading and handling .............................................................................................................. 515 Chapter 7.1 General provisions ............................................................................ 517 Chapter 7.2 Provisions concerning carriage in packages ................................... 519 Chapter 7.3 Provisions concerning carriage in bulk ........................................... 523 General provisions ............................................................................... Additional provisions for the carriage in bulk when the provisions of 7.3.1.1 (a) are applied ..................................................................... Special provisions for the carriage in bulk when the provisions of 7.3.1.1 (b) are applied .................................................... 523 526 Chapter 7.4 Provisions concerning carriage in tanks ......................................... 529 Chapter 7.5 Provisions concerning loading, unloading and handling ...................................................................................... 531 6.12.1 6.12.2 6.12.3 6.12.4 6.12.5 Part 7 7.3.1 7.3.2 7.3.3 7.5.1 7.5.2 7.5.3 7.5.4 7.5.5 7.5.6 7.5.7 7.5.8 7.5.9 7.5.10 7.5.11 General provisions concerning loading, unloading and handling ........................................................................................ Mixed loading prohibition .................................................................. (Reserved) ........................................................................................... Precautions with respect to foodstuffs, other articles of consumption and animal feeds ............................................................ Limitation of the quantities carried ..................................................... (Reserved) ........................................................................................... Handling and stowage ......................................................................... Cleaning after unloading ..................................................................... Prohibition of smoking ........................................................................ Precautions against electrostatic charges ............................................ Additional provisions applicable to certain classes or specific goods ...................................................................................... -x- 524 531 531 534 534 534 535 536 537 537 537 537 Table of contents (cont'd) Page Annex B Part 8 Provisions concerning transport equipment and transport operations ........................................................................................................ 545 Requirements for vehicle crews, equipment, operation and documentation .............................................................................................................. 547 Chapter 8.1 8.1.1 8.1.2 8.1.3 8.1.4 8.1.5 Chapter 8.2 8.2.1 8.2.2 8.2.3 General requirements concerning transport units and equipment on board ................................................................... 549 Transport units .................................................................................... Documents to be carried on the transport unit .................................... Placarding and marking ....................................................................... Fire-fighting equipment ...................................................................... Miscellaneous equipment and equipment for personal protection ...... 549 549 549 549 550 Requirements concerning the training of the vehicle crew ............................................................................. 553 Scope and general requirements concerning the training of drivers ... Special requirements concerning the training of drivers ..................... Training of persons, other than the drivers holding a certificate in accordance with 8.2.1, involved in the carriage of dangerous goods by road .................................................. 558 Miscellaneous requirements to be complied with by the vehicle crew ................................................................................. 559 Passengers ........................................................................................... Use of fire-fighting appliances ............................................................ Prohibition on opening packages ........................................................ Portable lighting apparatus .................................................................. Prohibition on smoking ....................................................................... Running the engine during loading or unloading ................................ Use of the parking brakes and wheel chocks ....................................... Use of cables ........................................................................................ 559 559 559 559 559 559 559 559 Chapter 8.4 Requirements concerning the supervision of vehicles..................... 561 Chapter 8.5 Additional requirements relating to particular classes or substances ...................................................................................... 563 Road tunnel restrictions for the passage of vehicles carrying dangerous goods ................................................................................. 567 Chapter 8.3 8.3.1 8.3.2 8.3.3 8.3.4 8.3.5 8.3.6 8.3.7 8.3.8 Chapter 8.6 8.6.1 8.6.2 8.6.3 8.6.4 General provisions .............................................................................. Road signs or signals governing the passage of vehicles carrying dangerous goods .................................................................................. Tunnel restriction codes ...................................................................... Restrictions for the passage of transport units carrying dangerous goods through tunnels ......................................................................... - xi - 553 553 567 567 567 567 Table of contents (cont'd) Page Part 9 Requirements concerning the construction and approval of vehicles ......................... Chapter 9.1 9.1.1 9.1.2 9.1.3 Chapter 9.2 9.2.1 9.2.2 9.2.3 9.2.4 9.2.5 9.2.6 Chapter 9.3 9.3.1 9.3.2 9.3.3 9.3.4 9.3.5 9.3.6 9.3.7 Chapter 9.4 Chapter 9.5 Chapter 9.6 Chapter 9.7 9.7.1 9.7.2 9.7.3 9.7.4 9.7.5 569 Scope, definitions and requirements for the approval of vehicles .............................................................. 571 Scope and definitions .......................................................................... Approval of EX/II, EX/III, FL, OX and AT vehicles and MEMUs..... Certificate of approval.......................................................................... 571 572 573 Requirements concerning the construction of vehicles ............................................................................................... 577 Compliance with the requirements of this Chapter .............................. Electrical equipment ............................................................................ Braking equipment .............................................................................. Prevention of fire risks ........................................................................ Speed limitation device ....................................................................... Coupling devices of trailers ................................................................ 577 580 583 583 584 585 Additional requirements concerning complete or completed EX/II or EX/III vehicles intended for the carriage of explosive substances and articles (Class 1) in packages ................. 587 Materials to be used in the construction of vehicle bodies ................. Combustion heaters ............................................................................. EX/II vehicles ..................................................................................... EX/III vehicles .................................................................................... Engine and load compartment .............................................................. External heat sources and load compartment ...................................... Electrical equipment ............................................................................ 587 587 587 587 588 588 588 Additional requirements concerning the construction of the bodies of complete or completed vehicles intended for the carriage of dangerous goods in packages (other than EX/II and EX/III vehicles) ........................................... 589 Additional requirements concerning the construction of the bodies of complete or completed vehicles intended for the carriage of dangerous solids in bulk ................................... 591 Additional requirements concerning complete or completed vehicles intended for the carriage of temperature controlled substances ................................................... 593 Additional requirements concerning fixed tanks (tank-vehicles), battery-vehicles and complete or completed vehicles used for the carriage of dangerous goods in demountable tanks with a capacity greater than 1 m3 or in tank-containers, portable tanks or MEGCs of a capacity greater than 3 m3 (FX/III, FL, OX and AT vehicles) ..................... 595 General provisions .............................................................................. Requirements concerning tanks .......................................................... Fastenings ............................................................................................ Earthing of FL vehicles ....................................................................... Stability of tank-vehicles .................................................................... 595 595 595 595 595 - xii - Table of contents (cont'd) Page 9.7.6 9.7.7 9.7.8 9.7.9 Chapter 9.8 9.8.1 9.8.2 9.8.3 9.8.4 9.8.5 9.8.6 9.8.7 9.8.8 Rear protection of vehicles .................................................................. Combustion heaters ............................................................................. Electrical equipment ............................................................................ Additional safety requirements concerning EX/III vehicles ................ 596 596 596 597 Additional requirements concerning complete and completed MEMUs ............................................................................ 599 General provisions .............................................................................. Requirements concerning tanks and bulk containers ........................... Earthing of MEMUs............................................................................. Stability of MEMUs ............................................................................. Rear protection of MEMUs .................................................................. Combustion heaters .............................................................................. Additional safety requirements ............................................................ Additional security requirements ......................................................... 599 599 599 599 599 599 600 600 - xiii - ANNEX A GENERAL PROVISIONS AND PROVISIONS CONCERNING DANGEROUS SUBSTANCES AND ARTICLES (cont'd) PART 4 Packing and tank provisions CHAPTER 4.1 USE OF PACKAGINGS, INCLUDING INTERMEDIATE BULK CONTAINERS (IBCs) AND LARGE PACKAGINGS 4.1.1 General provisions for the packing of dangerous goods in packagings, including IBCs and large packagings NOTE: For the packing of goods of Classes 2, 6.2 and 7, the general provisions of this section only apply as indicated in 4.1.8.2 (Class 6.2), 4.1.9.1.5 (Class 7) and in the applicable packing instructions of 4.1.4 (P201 and LP02 for Class 2 and P620, P621, IBC620 and LP621 for Class 6.2). 4.1.1.1 Dangerous goods shall be packed in good quality packagings, including IBCs and large packagings, which shall be strong enough to withstand the shocks and loadings normally encountered during carriage, including trans-shipment between transport units and between transport units and warehouses as well as any removal from a pallet or overpack for subsequent manual or mechanical handling. Packagings, including IBCs and large packagings, shall be constructed and closed so as to prevent any loss of contents when prepared for transport which might be caused under normal conditions of transport, by vibration, or by changes in temperature, humidity or pressure (resulting from altitude, for example). Packagings, including IBCs and large packagings, shall be closed in accordance with the information provided by the manufacturer. No dangerous residue shall adhere to the outside of packagings, IBCs and large packagings during carriage. These provisions apply, as appropriate, to new, reused, reconditioned or remanufactured packagings and to new, reused, repaired or remanufactured IBCs, and to new, reused or remanufactured large packagings. 4.1.1.2 Parts of packagings, including IBCs and large packagings, which are in direct contact with dangerous goods: (a) shall not be affected or significantly weakened by those dangerous goods; (b) shall not cause a dangerous effect e.g. catalysing a reaction or reacting with the dangerous goods; and (c) shall not allow permeation of the dangerous goods that could constitute a danger under normal conditions of carriage. Where necessary, they shall be provided with a suitable inner coating or treatment. NOTE: For chemical compatibility of plastics packagings, including IBCs, made from polyethylene see 4.1.1.21. 4.1.1.3 Unless otherwise provided elsewhere in ADR, each packaging, including IBCs and large packagings, except inner packagings, shall conform to a design type successfully tested in accordance with the requirements of 6.1.5, 6.3.5, 6.5.6 or 6.6.5, as applicable. The packagings for which the test is not required are mentioned under 6.1.1.3. 4.1.1.4 When filling packagings, including IBCs and large packagings, with liquids, sufficient ullage (outage) shall be left to ensure that neither leakage nor permanent distortion of the packaging occurs as a result of an expansion of the liquid caused by temperatures likely to occur during transport. Unless specific requirements are prescribed, liquids shall not completely fill a packaging at a temperature of 55 °C. However, sufficient ullage shall be left in an IBC to ensure that at the mean bulk temperature of 50 °C it is not filled to more than 98% of its water capacity. For a filling temperature of 15 °C, the maximum degree of filling shall be determined as follows, unless otherwise provided, either: (a) Boiling point (initial boiling point) of the substance in °C < 60 Degree of filling as a percentage of the capacity of the packaging 90 or -5-  60 < 100 92  100 < 200 94  200 < 300 96  300 98 (b) degree of filling  98 % of the capacity of the packaging. 1   (50 - t f ) In this formula  represents the mean coefficient of cubic expansion of the liquid substance between 15 °C and 50 °C; that is to say, for a maximum rise in temperature of 35 °C,  is calculated according to the formula :   d15  d 50 35  d 50 d15 and d50 being the relative densities1 of the liquid at 15 °C and 50 °C and tf the mean temperature of the liquid at the time of filling. 4.1.1.5 Inner packagings shall be packed in an outer packaging in such a way that, under normal conditions of carriage, they cannot break, be punctured or leak their contents into the outer packaging. Inner packagings containing liquids shall be packed with their closures upward and placed within outer packagings consistent with the orientation markings prescribed in 5.2.1.9. Inner packagings that are liable to break or be punctured easily, such as those made of glass, porcelain or stoneware or of certain plastics materials, etc., shall be secured in outer packagings with suitable cushioning material. Any leakage of the contents shall not substantially impair the protective properties of the cushioning material or of the outer packaging. 4.1.1.5.1 Where an outer packaging of a combination packaging or a large packaging has been successfully tested with different types of inner packagings, a variety of such different inner packagings may also be assembled in this outer packaging or large packaging. In addition, provided an equivalent level of performance is maintained, the following variations in inner packagings are allowed without further testing of the package: (a) Inner packagings of equivalent or smaller size may be used provided: (i) the inner packagings are of similar design to the tested inner packagings (e.g. shape round, rectangular, etc.); (ii) the material of construction of the inner packagings (glass, plastics, metal, etc.) offers resistance to impact and stacking forces equal to or greater than that of the originally tested inner packaging; (iii) the inner packagings have the same or smaller openings and the closure is of similar design (e.g. screw cap, friction lid, etc.); (iv) sufficient additional cushioning material is used to take up void spaces and to prevent significant movement of the inner packagings; and inner packagings are oriented within the outer packaging in the same manner as in the tested package. (v) (b) A lesser number of the tested inner packagings, or of the alternative types of inner packagings identified in (a) above, may be used provided sufficient cushioning is added to fill the void space(s) and to prevent significant movement of the inner packagings. 4.1.1.5.2 Use of supplementary packagings within an outer packaging (e.g. an intermediate packaging or a receptacle inside a required inner packaging) additional to what is required by the packing instructions is authorized provided all relevant requirements are met, including those of 4.1.1.3, and, if appropriate, suitable cushioning is used to prevent movement within the packaging. 4.1.1.6 Dangerous goods shall not be packed together in the same outer packaging or in large packagings, with dangerous or other goods if they react dangerously with each other and cause: (a) combustion or evolution of considerable heat; (b) evolution of flammable, asphyxiant, oxidizing or toxic gases; 1 Relative density (d) is considered to be synonymous with specific gravity (SG) and will be used throughout this Chapter. -6- (c) the formation of corrosive substances; or (d) the formation of unstable substances. NOTE: For mixed packing special provisions, see 4.1.10. 4.1.1.7 The closures of packagings containing wetted or diluted substances shall be such that the percentage of liquid (water, solvent or phlegmatizer) does not fall below the prescribed limits during transport. 4.1.1.7.1 Where two or more closure systems are fitted in series on an IBC, that nearest to the substance being carried shall be closed first. 4.1.1.8 Where pressure may develop in a package by the emission of gas from the contents (as a result of temperature increase or other causes), the packaging or IBC may be fitted with a vent provided that the gas emitted will not cause danger on account of its toxicity, its flammability or the quantity released, for example. A venting device shall be fitted if dangerous overpressure may develop due to normal decomposition of substances. The vent shall be so designed that, when the packaging or IBC is in the attitude in which it is intended to be carried, leakages of liquid and the penetration of foreign substances are prevented under normal conditions of carriage. NOTE: Venting of the package is not permitted for air carriage. 4.1.1.8.1 Liquids may only be filled into inner packagings which have an appropriate resistance to internal pressure that may be developed under normal conditions of carriage. 4.1.1.9 New, remanufactured or reused packagings, including IBCs and large packagings, or reconditioned packagings and repaired or routinely maintained IBCs shall be capable of passing the tests prescribed in 6.1.5, 6.3.5, 6.5.6 or 6.6.5, as applicable. Before being filled and handed over for carriage, every packaging, including IBCs and large packagings, shall be inspected to ensure that it is free from corrosion, contamination or other damage and every IBC shall be inspected with regard to the proper functioning of any service equipment. Any packaging which shows signs of reduced strength as compared with the approved design type shall no longer be used or shall be so reconditioned, that it is able to withstand the design type tests. Any IBC which shows signs of reduced strength as compared with the tested design type shall no longer be used or shall be so repaired or routinely maintained that it is able to withstand the design type tests. 4.1.1.10 Liquids shall be filled only into packagings, including IBCs, which have an appropriate resistance to the internal pressure that may develop under normal conditions of carriage. Packagings and IBCs marked with the hydraulic test pressure prescribed in 6.1.3.1 (d) and 6.5.2.2.1, respectively shall be filled only with a liquid having a vapour pressure: (a) such that the total gauge pressure in the packaging or IBC (i.e. the vapour pressure of the filling substance plus the partial pressure of air or other inert gases, less 100 kPa) at 55 °C, determined on the basis of a maximum degree of filling in accordance with 4.1.1.4 and a filling temperature of 15 °C, will not exceed two-thirds of the marked test pressure; or (b) at 50 °C less than four-sevenths of the sum of the marked test pressure plus 100 kPa; or (c) at 55 °C less than two-thirds of the sum of the marked test pressure plus 100 kPa. IBCs intended for the carriage of liquids shall not be used to carry liquids having a vapour pressure of more than 110kPa (1.1 bar) at 50 °C or 130kPa (1.3 bar) at 55 °C. -7- Examples of required marked test pressures for packagings, including IBCs, calculated as in 4.1.1.10 (c) UN No Name Class Packing Vp55 Vp55 × 1.5 (Vp55 × 1.5) group (kPa) (kPa) minus 100 (kPa) 2056 Tetrahydrofuran 3 II 70 105 5 Required minimum test pressure gauge under 6.1.5.5.4(c) (kPa) 100 Minimum test pressure (gauge) to be marked on the packaging (kPa) 2247 n-Decane 3 III 1.4 2.1 -97.9 100 100 1593 Dichloromethane 6.1 III 164 246 146 146 150 1155 Diethyl ether 3 I 199 299 199 199 250 100 NOTE 1: For pure liquids the vapour pressure at 55 °C (Vp55) can often be obtained from scientific tables. NOTE 2: The table refers to the use of 4.1.1.10 (c) only, which means that the marked test pressure shall exceed 1.5 times the vapour pressure at 55 °C less 100 kPa. When, for example, the test pressure for n-decane is determined according to 6.1.5.5.4 (a), the minimum marked test pressure may be lower. NOTE 3: For diethyl ether the required minimum test pressure under 6.1.5.5.5 is 250 kPa. 4.1.1.11 Empty packagings, including IBCs and large packagings, that have contained a dangerous substance are subject to the same requirements as those for a filled packaging, unless adequate measures have been taken to nullify any hazard. NOTE: When such packagings are carried for disposal, recycling or recovery of their material, they may also be carried under UN 3509 provided the conditions of special provision 663 of Chapter 3.3 are met. 4.1.1.12 Every packagings as specified in Chapter 6.1 intended to contain liquids shall successfully undergo a suitable leakproofness test, and be capable of meeting the appropriate test level indicated in 6.1.5.4.3: (a) before it is first used for carriage; (b) after remanufacturing or reconditioning of any packaging, before it is re-used for carriage. For this test the packaging need not have its closures fitted. The inner receptacle of a composite packaging may be tested without the outer packaging, provided the test results are not affected. This test is not required for: - inner packagings of combination packagings or large packagings; - inner receptacles of composite packagings (glass, porcelain or stoneware) marked with the symbol "RID/ADR" in accordance with 6.1.3.1 (a) (ii); - light gauge metal packagings marked with the symbol "RID/ADR" in accordance with 6.1.3.1 (a) (ii). 4.1.1.13 Packagings, including IBCs, used for solids which may become liquid at temperatures likely to be encountered during carriage shall also be capable of containing the substance in the liquid state. 4.1.1.14 Packagings, including IBCs, used for powdery or granular substances shall be sift-proof or shall be provided with a liner. 4.1.1.15 For plastics drums and jerricans, rigid plastics IBCs and composite IBCs with plastics inner receptacles, unless otherwise approved by the competent authority, the period of use permitted for the carriage of dangerous substances shall be five years from the date of manufacture of the receptacles, except where a shorter period of use is prescribed because of the nature of the substance to be carried. 4.1.1.16 Where ice is used as a coolant it shall not affect the integrity of the packaging. -8- 4.1.1.17 Packagings, including IBCs and large packagings, marked in accordance with 6.1.3, 6.2.2.7, 6.2.2.8, 6.3.1, 6.5.2 or 6.6.3 but which were approved in a State which is not a Contracting Party to ADR may nevertheless be used for carriage under ADR. 4.1.1.18 Explosives, self-reactive substances and organic peroxides Unless specific provision to the contrary is made in ADR, the packagings, including IBCs and large packagings, used for goods of Class 1, self-reactive substances of Class 4.1 and organic peroxides of Class 5.2 shall comply with the provisions for the medium danger group (packing group II). 4.1.1.19 Use of salvage packagings and large salvage packagings 4.1.1.19.1 Damaged, defective, leaking or non-conforming packages, or dangerous goods that have spilled or leaked may be carried in salvage packagings mentioned in 6.1.5.1.11 and in large salvage packagings mentioned in 6.6.5.1.9. This does not prevent the use of a bigger size packaging, including intermediate bulk container (IBC) and large packaging, of appropriate type and performance level under the conditions of 4.1.1.19.2 and 4.1.1.19.3. 4.1.1.19.2 Appropriate measures shall be taken to prevent excessive movement of the damaged or leaking packages within a salvage packaging or large salvage packaging. When the salvage packaging or large salvage packaging contains liquids, sufficient inert absorbent material shall be added to eliminate the presence of free liquid. 4.1.1.19.3 Appropriate measures shall be taken to ensure that there is no dangerous build up of pressure. 4.1.1.20 Use of salvage pressure receptacles 4.1.1.20.1 In the case of damaged, defective, leaking or non-conforming pressure receptacles, salvage pressure receptacles according to 6.2.3.11 may be used. NOTE: A salvage pressure receptacle may be used as an overpack in accordance with 5.1.2. When used as an overpack, markings shall be in accordance with 5.1.2.1 instead of 5.2.1.3. 4.1.1.20.2 Pressure receptacles shall be placed in salvage pressure receptacles of suitable size. More than one pressure receptacle may be placed in the same salvage pressure receptacle only if the contents are known and do not react dangerously with each other (see 4.1.1.6). Appropriate measures shall be taken to prevent movement of the pressure receptacles within the salvage pressure receptacle e.g. by partitioning, securing or cushioning. 4.1.1.20.3 A pressure receptacle may only be placed in a salvage pressure receptacle if: (a) The salvage pressure receptacle is in accordance with 6.2.3.11 and a copy of the approval certificate is available; (b) Parts of the salvage pressure receptacle which are, or are likely to be in direct contact with the dangerous goods will not be affected or weakened by those dangerous goods and will not cause a dangerous effect (e.g. catalyzing reaction or reacting with the dangerous goods); and (c) The contents of the contained pressure receptacle(s) are limited in pressure and volume so that if totally discharged into the salvage pressure receptacle, the pressure in the salvage pressure receptacle at 65 °C will not exceed the test pressure of the salvage pressure receptacle (for gases, see packing instruction in P200 (3) in 4.1.4.1). The reduction of the useable water capacity of the salvage pressure receptacle, e.g. by any contained equipment and cushioning, shall be taken into account. 4.1.1.20.4 The proper shipping name, the UN number preceded by the letters "UN" and label(s) as required for packages in Chapter 5.2 applicable to the dangerous goods inside the contained pressure receptacle(s) shall be applied to the salvage pressure receptacle for carriage. 4.1.1.20.5 Salvage pressure receptacles shall be cleaned, purged and visually inspected internally and externally after each use. They shall be periodically inspected and tested in accordance with 6.2.3.5 at least once every five years. -9- 4.1.1.21 Verification of the chemical compatibility of plastics packagings, including IBCs, by assimilation of filling substances to standard liquids 4.1.1.21.1 Scope For polyethylene packagings as specified in 6.1.5.2.6, and for polyethylene IBCs as specified in 6.5.6.3.5, the chemical compatibility with filling substances may be verified by assimilation to standard liquids following the procedures, as set out in 4.1.1.21.3 to 4.1.1.21.5 and using the list in table 4.1.1.21.6, provided that the particular design types have been tested with these standard liquids in accordance with 6.1.5 or 6.5.6, taking into account 6.1.6 and that the conditions in 4.1.1.21.2 are met. When assimilation in accordance with this sub-section is not possible, the chemical compatibility needs to be verified by design type testing in accordance with 6.1.5.2.5 or by laboratory tests in accordance with 6.1.5.2.7 for packagings, and in accordance with 6.5.6.3.3 or 6.5.6.3.6 for IBCs, respectively. NOTE: Irrespective of the provisions of this sub-section, the use of packagings, including IBCs, for a specific filling substance is subject to the limitations of Table A of Chapter 3.2, and the packing instructions in Chapter 4.1. 4.1.1.21.2 Conditions The relative densities of the filling substances shall not exceed that used to determine the height for the drop test performed successfully according to 6.1.5.3.5 or 6.5.6.9.4 and the mass for the stacking test performed successfully according to 6.1.5.6 or where necessary according to 6.5.6.6 with the assimilated standard liquid(s). The vapour pressures of the filling substances at 50 °C or 55 °C shall not exceed that used to determine the pressure for the internal pressure (hydraulic) test performed successfully according to 6.1.5.5.4 or 6.5.6.8.4.2 with the assimilated standard liquid(s). In case that filling substances are assimilated to a combination of standard liquids, the corresponding values of the filling substances shall not exceed the minimum values derived from the applied drop heights, stacking masses and internal test pressures. Example: UN 1736 Benzoyl chloride is assimilated to the combination of standard liquids "Mixture of hydrocarbons and wetting solution". It has a vapour pressure of 0.34 kPa at 50 °C and a relative density of approximately 1.2. Design type tests for plastics drums and jerricans were frequently performed at minimum required test levels. In practice this means that the stacking test is commonly performed with stacking loads considering only a relative density of 1.0 for the "Mixture of hydrocarbons" and a relative density of 1.2 for the "Wetting solution" (see definition of standard liquids in 6.1.6). As a consequence chemical compatibility of such tested design types would not be verified for benzoyl chloride by reason of the inadequate test level of the design type with the standard liquid "mixture of hydrocarbons". (Due to the fact that in the majority of cases the applied internal hydraulic test pressure is not less than 100 kPa, the vapour pressure of benzoyl chloride would be covered by such test level according to 4.1.1.10). All components of a filling substance, which may be a solution, mixture or preparation, such as wetting agents in detergents and disinfectants, irrespective whether dangerous or non-dangerous, shall be included in the assimilation procedure. 4.1.1.21.3 Assimilation procedure The following steps shall be taken to assign filling substances to listed substances or groups of substances in table 4.1.1.21.6 (see also scheme in Figure 4.1.1.21.1): (a) Classify the filling substance in accordance with the procedures and criteria of Part 2 (determination of the UN number and packing group); (b) If it is included there, go to the UN number in column (1) of table 4.1.1.21.6; (c) Select the line that corresponds in terms of packing group, concentration, flashpoint, the presence of non-dangerous components etc. by means of the information given in columns (2a), (2b) and (4), if there is more than one entry for this UN number. - 10 - If this is not possible, the chemical compatibility shall be verified in accordance with 6.1.5.2.5 or 6.1.5.2.7 for packagings, and in accordance with 6.5.6.3.3 or 6.5.6.3.6 for IBCs (however, in the case of aqueous solutions, see 4.1.1.21.4); (d) If the UN number and packing group of the filling substance determined in accordance with (a) is not included in the assimilation list, the chemical compatibility shall be proved in accordance with 6.1.5.2.5 or 6.1.5.2.7 for packagings, and in accordance with 6.5.6.3.3 or 6.5.6.3.6 for IBCs; (e) Apply the "Rule for collective entries", as described in 4.1.1.21.5, if this is indicated in column (5) of the selected line; (f) The chemical compatibility of the filling substance may be regarded as verified taking into account 4.1.1.21.1 and 4.1.1.21.2, if a standard liquid or a combination of standard liquids is assimilated in column (5) and the design type is approved for that/those standard liquid(s). Figure 4.1.1.21.1: Scheme for the assimilation of filling substances to standard liquids Classification of the substance according to Part 2 to determine UN number and packing group Are the UN number and packing group included in the assimilation list? No Further tests required (see 4.1.1.21.1) Yes Is the substance or group of substances mentioned by name in the assimilation list? Yes Does the assimilation list indicate standard liquid or combination of standard liquids? No No to be continued with "Rule for collective entries" - 11 - Yes Chemical compatibility may be regarded as verified, if packaging/IBC design type has been tested with indicated standard liquid(s); may be also valid for aqueous solutions 4.1.1.21.4 Aqueous solutions Aqueous solutions of substances and groups of substances assimilated to specific standard liquid(s) in accordance with 4.1.1.21.3 may also be assimilated to that (those) standard liquid(s) provided the following conditions are met: (a) the aqueous solution can be assigned to the same UN number as the listed substance in accordance with the criteria of 2.1.3.3, and (b) the aqueous solution is not specifically mentioned by name otherwise in the assimilation list in 4.1.1.21.6, and (c) no chemical reaction is taking place between the dangerous substance and the solvent water. Example: Aqueous solutions of UN 1120 tert-Butanol: - Pure tert-Butanol itself is assigned to the standard liquid "acetic acid" in the assimilation list. - Aqueous solutions of tert-Butanol can be classified under the entry UN 1120 BUTANOLS in accordance with 2.1.3.3, because the aqueous solution of tert-Butanol does not differ from the entries of the pure substances relating to the class, the packing group(s) and the physical state. Furthermore, the entry "1120 BUTANOLS" is not explicitly limited to the pure substances, and aqueous solutions of these substances are not specifically mentioned by name otherwise in Table A of chapter 3.2 as well as in the assimilation list. - UN 1120 BUTANOLS do not react with water under normal conditions of carriage. As a consequence, aqueous solutions of UN 1120 tert-Butanol may be assigned to the standard liquid "acetic acid". 4.1.1.21.5 Rule for collective entries For the assimilation of filling substances for which "Rule for collective entries" is indicated in column (5), the following steps shall be taken and conditions be met (see also scheme in Figure 4.1.1.21.2): (a) Perform the assimilation procedure for each dangerous component of the solution, mixture or preparation in accordance with 4.1.1.21.3 taking into account the conditions in 4.1.1.21.2. In the case of generic entries, components may be neglected, that are known to have no damaging effect on high density polyethylene (e.g. solid pigments in UN 1263 PAINT or PAINT RELATED MATERIAL); (b) A solution, mixture or preparation cannot be assimilated to a standard liquid, if: (c) (i) the UN number and packing group of one or more of the dangerous components does not appear in the assimilation list; or (ii) "Rule for collective entries" is indicated in column (5) of the assimilation list for one or more of the components; or (iii) (with the exception of UN 2059 NITROCELLULOSE SOLUTION, FLAMMABLE) the classification code of one or more of its dangerous components differs from that of the solution, mixture or preparation. If all dangerous components are listed in the assimilation list, and its classification codes are in accordance with the classification code of the solution, mixture or preparation itself, and all dangerous components are assimilated to the same standard liquid or combination of standard liquids in column (5), the chemical compatibility of the solution, mixture or preparation may be regarded as verified taking into account 4.1.1.21.1 and 4.1.1.21.2; - 12 - (d) (e) If all dangerous components are listed in the assimilation list and its classification codes are in accordance with the classification code of the solution, mixture or preparation itself, but different standard liquids are indicated in column (5), the chemical compatibility may only be regarded as verified for the following combinations of standard liquids taking into account 4.1.1.21.1 and 4.1.1.21.2: (i) water/nitric acid 55%; with the exception of inorganic acids with the classification code C1, which are assigned to standard liquid "water"; (ii) water/wetting solution; (iii) water/acetic acid; (iv) water/mixture of hydrocarbons; (v) water/n-butyl acetate – n-butyl acetate-saturated wetting solution; In the scope of this rule, chemical compatibility is not regarded as verified for other combinations of standard liquids than those specified in (d) and for all cases specified in (b). In such cases the chemical compatibility shall be verified by other means (see 4.1.1.21.3 (d)). Example 1: Mixture of UN 1940 THIOGLYCOLIC ACID (50%) and UN 2531 METHACRYLIC ACID, STABILIZED (50%); classification of the mixture: UN 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. - Both the UN numbers of the components and the UN number of the mixture are included in the assimilation list; - Both the components and the mixture have the same classification code: C3; - UN 1940 THIOGLYCOLIC ACID is assimilated to standard liquid "acetic acid", and UN 2531 METHACRYLIC ACID, STABILIZED is assimilated to standard liquid "n-butyl acetate/n-butyl acetate-saturated wetting solution". According to paragraph (d) this is not an acceptable combination of standard liquids. The chemical compatibility of the mixture has to be verified by other means. Example 2: Mixture of UN 1793 ISOPROPYL ACID PHOSPHATE (50%) and UN 1803 PHENOLSULPHONIC ACID, LIQUID (50%); classification of the mixture: UN 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. - Both the UN numbers of the components and the UN number of the mixture are included in the assimilation list; - Both the components and the mixture have the same classification code: C3; - UN 1793 ISOPROPYL ACID PHOSPHATE is assimilated to standard liquid "wetting solution", and UN 1803 PHENOLSULPHONIC ACID, LIQUID is assimilated to standard liquid "water". According to paragraph (d) this is one of the acceptable combinations of standard liquids. As a consequence the chemical compatibility may be regarded as verified for this mixture, provided the packaging design type is approved for the standard liquids "wetting solution" and "water". - 13 - Figure 4.1.1.21.2: Scheme "Rules for collective entries" Single entries, collective entries, solutions, mixtures, preparations with indication "Rule for collective entries" in assimilation list Are entries included in the assimilation list for all components of solution, mixture or preparation? No Yes Have all components the same classification code as the solution, mixture or preparation? No Yes Are all components assimilated to the same standard liquid or combination of standard liquids? No Are all components separately or together, assimilated to one of the combinations of standard liquids below? No Further testing required Yes Yes Chemical compatibility may be regarded as proven, if packaging/ IBC design type has been tested with indicated standard liquid(s) Acceptable combinations of standard liquids: - water/nitric acid (55%), with the exception of inorganic acids of classification code C1 which are assigned to standard liquid "water"; - water/wetting solution; - water/acetic acid; - water/mixture of hydrocarbons; - water/n-butyl acetate – n-butyl acetate saturated wetting solution - 14 - 4.1.1.21.6 Assimilation list In the following table (assimilation list) dangerous substances are listed in the numerical order of their UN numbers. As a rule, each line deals with a dangerous substance, single entry or collective entry covered by a specific UN number. However, several consecutive lines may be used for the same UN number, if substances belonging to the same UN number have different names (e.g. individual isomers of a group of substances), different chemical properties, different physical properties and/or different transport conditions. In such cases the single entry or collective entry within the particular packing group is the last one of such consecutive lines. Columns (1) to (4) of table 4.1.1.21.6, following a structure similar to that of Table A of Chapter 3.2, are used to identify the substance for the purpose of this sub-section. The last column indicates the standard liquid(s) to which the substance can be assimilated. Explanatory notes for each column: Column (1) UN No. Contains the UN number: - of the dangerous substance, if the substance has been assigned its own specific UN number, or - of the collective entry to which dangerous substances not listed by name have been assigned in accordance with the criteria ("decision trees") of Part 2. Column (2a) Proper shipping name or technical name Contains the name of the substance, the name of the single entry, which may cover various isomers, or the name of the collective entry itself. The indicated name can deviate from the applicable proper shipping name. Column (2b) Description Contains a descriptive text to clarify the scope of the entry in those cases when the classification, the transport conditions and/or the chemical compatibility of the substance may be variable. Column (3a) Class Contains the number of the class, whose heading covers the dangerous substance. This class number is assigned in accordance with the procedures and criteria of Part 2. Column (3b) Classification code Contains the classification code of the dangerous substance in accordance with the procedures and criteria of Part 2. Column (4) Packing group Contains the packing group number(s) (I, II or III) assigned to the dangerous substance in accordance with the procedures and criteria of Part 2. Certain substances are not assigned to packing groups. Column (5) Standard liquid This column indicates, as definite information, either a standard liquid or a combination of standard liquids to which the substance can be assimilated, or a reference to the rule for collective entries in 4.1.1.21.5. - 15 - Table 4.1.1.21.6: Assimilation list Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) 1090 Acetone 1093 Acrylonitrile, stabilized Class Classifi- Packing group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 F1 II 3 FT1 I Mixture of hydrocarbons Remark: applicable only, if it is proved that the permeability of the substance out of the package intended for carriage has an acceptable level n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Acetic acid 1104 Amyl acetates pure isomers and isomeric mixture 3 F1 III 1105 Pentanols pure isomers and isomeric mixture 3 F1 II/III 1106 Amylamines pure isomers and isomeric mixture 3 FC II/III 1109 Amyl formates pure isomers and isomeric mixture 3 F1 III 1120 Butanols pure isomers and isomeric mixture pure isomers and isomeric mixture 3 F1 II/III 3 F1 II/III 1125 n-Butylamine 3 FC II 1128 n-Butyl formate 3 F1 II 3 3 3 F1 F1 F1 II I/II/III I/II/III 1145 Cyclohexane 1146 Cyclopentane 1153 Ethylene glycol diethyl ether 3 3 3 F1 F1 F1 II II III 1154 Diethylamine 3 FC II 1158 Diisopropylamine 3 FC II 1123 Butyl acetates 1129 Butyraldehyde 1133 Adhesives 1139 Coating solution containing flammable liquid includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining - 16 - Standard liquid cation Code n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons Rule for collective entries Rule for collective entries Mixture of hydrocarbons Mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons and wetting solution Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) 1160 Dimethylamine aqueous solution Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 FC II 1165 Dioxane 1169 Extracts, aromatic, liquid 3 3 F1 F1 II II/III Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons Rule for collective entries 1170 Ethanol or Ethanol aqueous solution solution 1171 Ethylene glycol monoethyl ether 3 F1 II/III Acetic acid 3 F1 III 1172 Ethylene glycol monoethyl ether acetate 3 F1 III 1173 Ethyl acetate 3 F1 II 1177 2-Ethylbutyl acetate 3 F1 III 1178 2-Ethylbutyraldehyde 1180 Ethyl butyrate 3 3 F1 F1 II III 1188 Ethylene glycol monomethyl ether 3 F1 III 1189 Ethylene glycol monomethyl ether acetate 3 F1 III 1190 Ethyl formate 3 F1 II 3 F1 III n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons 1192 Ethyl lactate 3 F1 III 1195 Ethyl propionate 3 F1 II 1197 Extracts, flavouring, liquid 1198 Formaldehyde solution, flammable 3 F1 II/III n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Rule for collective entries 3 FC III Acetic acid 3 F1 III Mixture of hydrocarbons 1191 Octyl aldehydes 1202 Diesel fuel pure isomers and isomeric mixture aqueous solution, flashpoint between 23 °C and 60 °C complying with EN 590:2009 + A1:2010 or with a flashpoint not more than 100 °C - 17 - Description UN No. Proper shipping name or technical name Class Classifi- Packing 3.1.2 3.1.2 (1) (2a) (2b) flashpoint not more than 100 °C extra light complying with EN 590:2009 + A1:2010 or with a flashpoint not more than 100 °C Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 F1 III Mixture of hydrocarbons 3 3 F1 F1 III III Mixture of hydrocarbons Mixture of hydrocarbons 3 F1 II Mixture of hydrocarbons 3 F1 II Mixture of hydrocarbons 3 3 F1 F1 III II Mixture of hydrocarbons Mixture of hydrocarbons 3 F1 I/II/III Rule for collective entries 3 3 F1 F1 III II 3 FC II 3 F1 II Acetic acid n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons 1219 Isopropanol 1220 Isopropyl acetate 3 3 F1 F1 II II 1221 Isopropylamine 3 FC I 1223 Kerosene 1224 3,3-Dimethyl-2-butanone 1224 Ketones, liquid, n.o.s. 3 3 3 F1 F1 F1 III II II/III 1230 Methanol 1231 Methyl acetate 3 3 FT1 F1 II II 1233 Methylamyl acetate 3 F1 III 1235 Methylamine, aqueous solution 3 FC II 1237 Methyl butyrate 3 F1 II 1247 Methyl methacrylate monomer, stabilized 3 F1 II 1248 Methyl propionate 3 F1 II 1202 Gas oil 1202 Heating oil, light 1202 Heating oil, light 1203 Motor spirit, or gasoline, or petrol 1206 Heptanes 1207 Hexaldehyde 1208 Hexanes 1210 Printing ink or Printing ink related material 1212 Isobutanol 1213 Isobutyl acetate pure isomers and isomeric mixture n-Hexaldehyde pure isomers and isomeric mixture flammable, including printing ink thinning or reducing compound 1214 Isobutylamine 1216 Isooctenes pure isomers and isomeric mixture - 18 - Acetic acid n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons Mixture of hydrocarbons Rule for collective entries Acetic acid n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) pure isomers and isomeric mixture including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base or including paint thinning and reducing compound n-Pentane with flammable solvents vapour pressure at 50 °C not more than 110 kPa 1262 Octanes 1263 Paint or Paint related material 1265 Pentanes 1266 Perfumery products 1268 Coal tar naphtha Class Classifi- Packing 1268 Petroleum distillates, n.o.s. or Petroleum products, n.o.s. 1274 n-Propanol 1275 Propionaldehyde 1276 n-Propyl acetate Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 F1 II Mixture of hydrocarbons 3 F1 I/II/III Rule for collective entries 3 3 3 F1 F1 F1 II II/III II Mixture of hydrocarbons Rule for collective entries Mixture of hydrocarbons 3 F1 I/II/III Rule for collective entries 3 3 3 F1 F1 F1 II/III II II 1277 Propylamine n-Propylamine 3 FC II 1281 Propyl formates pure isomers and isomeric mixture 3 F1 II 1282 Pyridine 1286 Rosin oil 3 3 F1 F1 II II/III Acetic acid Mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons Rule for collective entries 1287 Rubber solution 3 F1 II/III Rule for collective entries 1296 Triethylamine 3 FC II 1297 Trimethylamine, aqueous not more than 50% trimethylamine, by mass solution 3 FC I/II/III 1301 Vinyl acetate, stabilized 3 F1 II 1306 Wood preservatives, liquid 1547 Aniline 1590 Dichloroanilines, liquid 3 F1 II/III Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Rule for collective entries 6.1 6.1 T1 T1 II II Acetic acid Acetic acid 1602 Dye, liquid, toxic, n.o.s. or Dye intermediate, liquid, toxic, n.o.s. 1604 Ethylenediamine 6.1 T1 I/II/III Rule for collective entries 8 CF1 II 1715 Acetic anhydride 8 CF1 II Mixture of hydrocarbons and wetting solution Acetic acid pure isomers and isomeric mixture - 19 - Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) 1717 Acetyl chloride 1718 1719 1719 1730 Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 FC II Butyl acid phosphate Hydrogen sulphide aqueous solution Caustic alkali liquid, n.o.s. inorganic Antimony pentachloride, pure liquid 1736 Benzoyl chloride 8 8 8 8 C3 C5 C5 C1 III III II/III II n-Butyl acetate/ n-butyl acetate-saturated wetting solution Wetting solution Acetic acid Rule for collective entries Water 8 C3 II 1750 Chloroacetic acid solution aqueous solution 1750 Chloroacetic acid solution mixtures of mono- and dichloroacetic acid 1752 Chloroacetyl chloride 6.1 6.1 TC1 TC1 II II 6.1 TC1 I 1755 Chromic acid solution 8 C1 II/III n-Butyl acetate/ n-butyl acetate-saturated wetting solution Nitric acid 8 C9 II Water 1760 O,O-Diethyldithiophosphoric acid 8 C9 II 1760 O,O-Diisopropyldithiophosphoric acid 8 C9 II 1760 O,O-Di-n-propyldithiophosphoric acid 8 C9 II 8 8 C9 CT1 I/II/III II/III 8 8 C3 C1 II II n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Rule for collective entries Mixture of hydrocarbons and wetting solution Acetic acid Water 8 8 C1 C3 II II Water Acetic acid 8 C7 II/III aqueous solution aqueous solution not more than 38% aqueous solution with not more than 60% hydrofluoric acid 8 8 8 C1 C1 C1 II/III II/III II/III Mixture of hydrocarbons and wetting solution Water Water Water 8 CT1 II aqueous solution, containing wetting agents as customary in trade 8 C9 II/III 1760 Cyanamide 1760 Corrosive liquid, n.o.s. 1761 Cupriethylenediamine solution 1764 Dichloroacetic acid 1775 Fluoroboric acid 1778 Fluorosilicic acid 1779 Formic acid 1783 Hexamethylenediamine solution 1787 Hydriodic acid 1788 Hydrobromic acid 1789 Hydrochloric acid 1790 Hydrofluoric acid 1791 Hypochlorite solution aqueous solution with not more than 30% chromic acid aqueous solution with not more than 50% cyanamide flashpoint more than 60 °C aqueous solution aqueous solution with not more than 50% fluoroboric acid with more than 85% acid by mass aqueous solution - 20 - Mixture of hydrocarbons and wetting solution Acetic acid Acetic acid Water the permissible period of use: not more than 2 years Nitric acid and wetting solution * Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) Class Classifi- Packing cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) Standard liquid (5) 1791 Hypochlorite solution aqueous solution 8 C9 II/III Nitric acid * * For UN 1791: Test to be carried out only with vent. If the test is carried out with nitric acid as the standard liquid, an acid-resistant vent and gasket shall be used. If the test is carried out with hypochlorite solutions themselves, vents and gaskets of the same design type, resistant to hypochlorite (e.g. of silicone rubber) but not resistant to nitric acid, are also permitted. 1793 Isopropyl acid phosphate 8 C3 III Wetting solution 1802 Perchloric acid 8 CO1 II Water aqueous solution with not more than 50% acid, by mass 1803 Phenolsulphonic acid, isomeric mixture 8 C3 II Water liquid 1805 Phosphoric acid, solution 8 C1 III Water 1814 Potassium hydroxide aqueous solution 8 C5 II/III Water solution 1824 Sodium hydroxide aqueous solution 8 C5 II/III Water solution 1830 Sulphuric acid 8 C1 II Water with more than 51% pure acid 1832 Sulphuric acid, spent chemical stable 8 C1 II Water 1833 Sulphurous acid 8 C1 II Water 1835 Tetramethylammonium 8 C7 II Water aqueous solution, flashpoint more than 60 °C hydroxide, solution 1840 Zinc chloride solution aqueous solution 8 C1 III Water 1848 Propionic acid 8 C3 III with not less than 10% and n-Butyl acetate/ less than 90% acid by mass n-butyl acetate-saturated wetting solution 1862 Ethyl crotonate 3 F1 II n-Butyl acetate/ n-butyl acetate-saturated wetting solution 1863 Fuel, aviation, turbine 3 F1 I/II/III Mixture of hydrocarbons engine 1866 Resin solution flammable 3 F1 I/II/III Rule for collective entries 1902 Diisooctyl acid phosphate 8 C3 III Wetting solution 1906 Sludge acid 8 C1 II Nitric acid 1908 Chlorite solution aqueous solution 8 C9 II/III Acetic acid 1914 Butyl propionates 3 F1 III n-Butyl acetate/ n-butyl acetate-saturated wetting solution 1915 Cyclohexanone 3 F1 III Mixture of hydrocarbons 1917 Ethyl acrylate, stabilized 3 F1 II n-Butyl acetate/ n-butyl acetate-saturated wetting solution 1919 Methyl acrylate, stabilized 3 F1 II n-Butyl acetate/ n-butyl acetate-saturated wetting solution 1920 Nonanes 3 F1 III Mixture of hydrocarbons pure isomers and isomeric mixture, flashpoint between 23 °C and 60 °C 1935 Cyanide solution, n.o.s. inorganic 6.1 T4 I/II/III Water 1940 Thioglycolic acid 8 C3 II Acetic acid 1986 Alcohols, flammable, 3 FT1 I/II/III Rule for collective entries toxic, n.o.s. 1987 Cyclohexanol technical pure 3 F1 III Acetic acid 1987 Alcohols, n.o.s. 3 F1 II/III Rule for collective entries 1988 Aldehydes, flammable, 3 FT1 I/II/III Rule for collective entries toxic, n.o.s. - 21 - Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) 1989 Aldehydes, n.o.s. 1992 2,6-cis-Dimethylmorpholine 1992 Flammable liquid, toxic, n.o.s. 1993 Propionic acid vinyl ester 1993 (1-Methoxy-2-propyl) acetate Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 3 F1 FT1 I/II/III III Rule for collective entries Mixture of hydrocarbons 3 FT1 I/II/III Rule for collective entries 3 F1 II 3 F1 III 3 5.1 F1 OC1 I/II/III II n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Rule for collective entries Nitric acid 6.1 TC1 II Acetic acid 8 CT1 II Water 8 CT1 II Water 8 CO1 II Nitric acid 3 3 F1 F1 II II Mixture of hydrocarbons Mixture of hydrocarbons 3 8 3 3 F1 CF1 F1 F1 III I II/III II Acetic acid Mixture of hydrocarbons Mixture of hydrocarbons Mixture of hydrocarbons 2059 Nitrocellulose solution, flammable 3 D I/II/III 2075 Chloral, anhydrous, stabilized 2076 Cresols, liquid 6.1 T1 II Rule for collective entries: Deviating from the general procedure this rule may be applied to solvents of classification code F1 Wetting solution 6.1 TC1 II Acetic acid 6.1 T1 II 8 8 C7 C9 II III n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons Acetic acid 8 C9 III Water 8 CF1 II n-Butyl acetate/ n-butyl acetate-saturated wetting solution 1993 Flammable liquid, n.o.s. 2014 Hydrogen peroxide, aqueous solution 2022 Cresylic acid 2030 Hydrazine aqueous solution 2030 Hydrazine hydrate 2031 Nitric acid 2045 Isobutyraldehyde 2050 Diisobutylene isomeric compounds 2053 Methyl isobutyl carbinol 2054 Morpholine 2057 Tripropylene 2058 Valeraldehyde 2078 Toluene diisocyanate 2079 Diethylenetriamine 2209 Formaldehyde solution 2209 Formaldehyde solution with not less than 20% but not more than 60% hydrogen peroxide, stabilized as necessary liquid mixture containing cresols, xylenols and methyl phenols with not less than 37% but not more than 64% hydrazine, by mass aqueous solution with 64% hydrazine other than red fuming, with not more than 55% pure acid pure isomers and isomeric mixture pure isomers and isomeric mixture liquid aqueous solution with 37% Form-aldehyde, methanol content: 8-10% aqueous solution, with not less than 25% formaldehyde 2218 Acrylic acid, stabilized - 22 - Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 F1 III 6.1 T2 III n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons 3 3 3 F1 F1 F1 II II III Cyclopentanol Cyclopentanone n-Decane Di-n-butylamine 1,2-Propylenediamine 3 3 3 8 8 F1 F1 F1 CF1 CF1 III III III II II 2259 Triethylenetetramine 2260 Tripropylamine 8 3 C7 FC II III 3 F1 II 2264 N,N-Dimethylcyclohexylamine 8 CF1 II 2265 N,N-Dimethyl-formamide 3 F1 III 2266 Dimethyl-N-propylamine 3 FC II 2269 3,3'-Imino-dipropylamine 8 C7 III 3 FC II 2275 2-Ethylbutanol 3 F1 III 2276 2-Ethylhexylamine 3 FC III 2277 Ethyl methacrylate, stabilized 3 F1 II 3 F1 II 3 F1 III n-Butyl acetate/ n-butyl acetate-saturated wetting solution 3 F1 III n-Butyl acetate/ n-butyl acetate-saturated wetting solution 2227 n-Butyl methacrylate, stabilized 2235 Chlorobenzyl chlorides, liquid 2241 Cycloheptane 2242 Cycloheptene 2243 Cyclohexyl acetate 2244 2245 2247 2248 2258 2263 Dimethylcyclohexanes 2270 Ethylamine, aqueous solution 2278 n-Heptene 2282 Hexanols para-Chlorobenzyl chloride pure isomers and isomeric mixture with not less than 50% but not more than 70% ethylamine, flashpoint below 23 °C, corrosive or slightly corrosive pure isomers and isomeric mixture 2283 Isobutyl methacrylate, stabilized - 23 - Mixture of hydrocarbons Mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution Acetic acid Mixture of hydrocarbons Mixture of hydrocarbons Mixture of hydrocarbons Mixture of hydrocarbons and wetting solution Water Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) Pentamethylheptane Isoheptenes Isohexenes Isophoronediamine 2293 4-Methoxy-4-methylpentan-2-one 2296 Methylcyclohexane 2297 Methylcyclohexanone Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 3 3 8 F1 F1 F1 C7 III II II III 3 F1 III Mixture of hydrocarbons Mixture of hydrocarbons Mixture of hydrocarbons Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons 3 3 F1 F1 II III Mixture of hydrocarbons Mixture of hydrocarbons 3 3 8 F1 F1 C1 II III II Mixture of hydrocarbons Mixture of hydrocarbons Water 3 3 F1 F1 II III Mixture of hydrocarbons Mixture of hydrocarbons 6.1 T4 I Water 8 C7 III 3 F1 III Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons 2326 Trimethylcyclohexylamine 8 C7 III 2327 Trimethylhexamethylene- pure isomers and isomeric mixture diamines 8 C7 III 2330 Undecane 2336 Allyl formate 3 3 F1 FT1 III I 2348 Butyl acrylates, stabilized pure isomers and isomeric mixture 3 F1 III 2357 Cyclohexylamine 8 CF1 II 2361 Diisobutylamine 3 FC III 2366 Diethyl carbonate 3 F1 III 2367 alpha-Methylvaleraldehyde 2370 1-Hexene 2372 1,2-Di-(dimethylamino)ethane 3 F1 II 3 3 F1 F1 II II 2286 2287 2288 2289 2298 Methylcyclopentane 2302 5-Methylhexan-2-one 2308 Nitrosylsulphuric acid, liquid 2309 Octadienes 2313 Picolines 2317 Sodium cuprocyanide solution 2320 Tetraethylenepentamine 2324 Triisobutylene pure isomers and isomeric mixture pure isomers and isomeric mixture aqueous solution mixture of C12-monoolefines, flashpoint between 23 °C and 60 °C flashpoint between 23 °C and 60 °C - 24 - Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons Mixture of hydrocarbons Mixture of hydrocarbons and wetting solution Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) 2379 1,3-Dimethylbutylamine Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 FC II 2383 Dipropylamine 3 FC II 2385 Ethyl isobutyrate 3 F1 II 2393 Isobutyl formate 3 F1 II 3 F1 III 2396 Methacrylaldehyde, stabilized 2400 Methyl isovalerate 3 FT1 II Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons 3 F1 II 2401 Piperidine 8 CF1 I 2403 Isopropenyl acetate 3 F1 II 2405 Isopropyl butyrate 3 F1 III 2406 Isopropyl isobutyrate 3 F1 II 2409 Isopropyl propionate 3 F1 II 2410 1,2,3,6-Tetrahydropyridine 2427 Potassium chlorate, aqueous solution 2428 Sodium chlorate, aqueous solution 2429 Calcium chlorate, aqueous solution 2436 Thioacetic acid 2457 2,3-Dimethylbutane 2491 Ethanolamine 2491 Ethanolamine solution aqueous solution 2496 Propionic anhydride 3 F1 II n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons 5.1 O1 II/III Water 5.1 O1 II/III Water 5.1 O1 II/III Water 3 3 8 8 8 F1 F1 C7 C7 C3 II II III III III 2524 Ethyl orthoformate 3 F1 III 2526 Furfurylamine 3 FC III Acetic acid Mixture of hydrocarbons Wetting solution Wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution 2394 Isobutyl propionate flashpoint between 23 °C and 60 °C - 25 - Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) 2527 Isobutyl acrylate, stabilized Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 F1 III 2528 Isobutyl isobutyrate 3 F1 III 2529 Isobutyric acid 3 FC III 2531 Methacrylic acid, stabilized 8 C3 II 2542 Tributylamine 2560 2-Methylpentan-2-ol 6.1 3 T1 F1 II III 8 C3 II/III n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution Acetic acid 8 C7 III 8 C3 II aqueous solution 8 8 C3 C1 II III Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Rule for collective entries Water aqueous solution 8 C1 III Water aqueous solution with more than 5% free sulphuric acid with more than 5% free sulphuric acid 8 8 C1 C1 III II Water Water 8 C1 II with more than 5% free sulphuric acid with more than 5% free sulphuric acid with more than 5% free sulphuric acid 8 C1 II n-Butyl acetate/ n-butyl acetate-saturated wetting solution Water 8 C1 II Water 8 C1 II with not more than 5% free sulphuric acid with not more than 5% free sulphuric acid 8 C1 III n-Butyl acetate/ n-butyl acetate-saturated wetting solution Water 8 C1 III with not more than 5% free sulphuric acid with not more than 5% free sulphuric acid with not more than 5% free sulphuric acid 8 C1 III n-Butyl acetate/ n-butyl acetate-saturated wetting solution Water 8 C1 III Water 8 C1 III 3 FC III n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution 2564 Trichloroacetic acid solution 2565 Dicyclohexylamine aqueous solution 2571 Ethylsulphuric acid 2571 Alkylsulphuric acids 2580 Aluminium bromide solution 2581 Aluminium chloride solution 2582 Ferric chloride solution 2584 Methane sulphonic acid 2584 Alkylsulphonic acids, liquid 2584 Benzene sulphonic acid 2584 Toluene sulphonic acids 2584 Arylsulphonic acids, liquid 2586 Methane sulfonic acid 2586 Alkylsulphonic acids, liquid 2586 Benzene sulphonic acid 2586 Toluene sulphonic acids 2586 Arylsulphonic acids, liquid 2610 Triallylamine - 26 - Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) 2614 Methallyl alcohol 2617 Methylcyclohexanols Class Classifi- Packing group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3 3 F1 F1 III III Acetic acid Acetic acid 8 CF1 II 3 F1 III 3 5.1 FT1 O1 II II Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons Nitric acid 6.1 8 T1 C5 III III Water Water 8 CFT II Acetic acid 3 FC III 8 CF1 II inorganic 8 C1 III Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons and wetting solution Water pure isomers and isomeric mixture 3 F1 II/III Mixture of hydrocarbons 3 FC I/II/III Mixture of hydrocarbons and wetting solution 8 8 CF1 CF1 II I/II Mixture of hydrocarbons Mixture of hydrocarbons and wetting solution 8 C7 I/II/III Mixture of hydrocarbons and wetting solution 8 C3 III aqueous solution, more than 80% acid, by mass 8 CF1 II n-Butyl acetate/ n-butyl acetate-saturated wetting solution Acetic acid aqueous solution, more than 10% but not more than 80% acid, by mass 8 C3 II/III Acetic acid pure isomers and isomeric mixture, flashpoint between 23 °C and 60 °C 2619 Benzyldimethylamine 2620 Amyl butyrates 2622 Glycidaldehyde 2626 Chloric acid, aqueous solution 2656 Quinoline 2672 Ammonia solution 2683 Ammonium sulphide solution 2684 3-Diethylaminopropylamine pure isomers and isomeric mixture, flashpoint between 23 °C and 60 °C flashpoint below 23 °C with not more than 10% chloric acid flashpoint more than 60 °C relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia aqueous solution, flashpoint between 23 °C and 60 °C 2685 N,N-Diethylethylenediamine 2693 Bisulphites, aqueous solution, n.o.s. 2707 Dimethyldioxanes 2733 Amines, flammable, corrosive , n.o.s. or Polyamines, flammable, corrosive, n.o.s. 2734 Di-sec-butylamine 2734 Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s. 2735 Amines, liquid, corrosive, n.o.s. or Polyamines, liquid, corrosive, n.o.s. 2739 Butyric anhydride 2789 Acetic acid, glacial or Acetic acid solution 2790 Acetic acid solution Standard liquid cation Code - 27 - Description UN No. Proper shipping name or technical name Class Classifi- Packing 3.1.2 3.1.2 (1) (2a) (2b) with not more than 51% pure acid Potassium/Sodium hydroxide, aqueous solution stabilized Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 8 C1 II Water 8 C5 II Water 6.1 T1 III Mixture of hydrocarbons 6.1 6.1 T1 T1 III III Acetic acid Acetic acid 6.1 T1 I/II/III Rule for collective entries 8 C7 III 2818 Ammonium polysulphide aqueous solution solution 2819 Amyl acid phosphate 2820 Butyric acid n-Butyric acid 8 CT1 II/III Mixture of hydrocarbons and wetting solution Acetic acid 8 8 C3 C3 III III 2821 Phenol solution 6.1 T1 II/III 8 C3 III 2837 Bisulphates, aqueous solution 2838 Vinyl butyrate, stabilized 8 C1 II/III 3 F1 II 2841 Di-n-amylamine 3 FT1 III 3 F1 III n-Butyl acetate/ n-butyl acetate-saturated wetting solution Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons 6.1 T1 III Acetic acid 6.1 8 T1 CF1 III II 8 CF1 II Acetic acid n-Butylacetate/ n-Butylacetate-saturated wetting solution Wetting solution 8 CF1 II Wetting solution 8 CF1 II Water 8 CF1 I/II Rule for collective entries 8 CT1 II Water 8 CT1 II Acetic acid 2796 Sulphuric acid 2797 Battery fluid, alkali 2810 2-Chloro-6-fluorobenzyl chloride 2810 2-Phenylethanol 2810 Ethylene glycol monohexyl ether 2810 Toxic liquid, organic, n.o.s. 2815 N-Aminoethylpiperazine 2829 Caproic acid 2850 Propylene tetramer 2873 Dibutylaminoethanol 2874 Furfuryl alcohol 2920 O,O-Diethyldithiophosphoric acid 2920 O,O-Dimethyldithiophosphoric acid 2920 Hydrogen bromide 2920 Tetramethylammonium hydroxide 2920 Corrosive liquid, flammable, n.o.s. 2922 Ammonium sulphide 2922 Cresols aqueous solution, toxic, nonalkaline n-Caproic acid mixture of C12monoolefines, flashpoint between 23 °C and 60 °C N,N-Di-nbutylaminoethanol flashpoint between 23 °C and 60 °C flashpoint between 23 °C and 60 °C 33% solution in glacial acetic acid aqueous solution, flashpoint between 23 °C and 60 °C aqueous solution, flashpoint more than 60 °C aqueous alkaline solution, mixture of sodium and potassium cresolate, - 28 - Wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Acetic acid n-Butyl acetate/ n-butyl acetate-saturated wetting solution Water Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) 2922 Phenol 2922 2922 Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 8 CT1 II Acetic acid 8 8 CT1 CT1 III I/II/III Water Rule for collective entries 3 FC I/II/III Rule for collective entries 6.1 TC1 I/II Rule for collective entries 3 F1 III n-Butyl acetate/ n-butyl acetate-saturated wetting solution 2934 Isopropyl 2-chloropropionate 3 F1 III 2935 Ethyl 2-chloropropionate 3 F1 III 2936 Thiolactic acid 2941 Fluoroanilines 6.1 6.1 T1 T1 II III n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Acetic acid Acetic acid 2943 Tetrahydrofurfurylamine 2945 N-Methylbutylamine 3 3 F1 FC III II 2946 2-Amino-5-diethylaminopentane 6.1 T1 III 2947 Isopropyl chloroacetate 3 F1 III 5.1 O1 III Mixture of hydrocarbons Mixture of hydrocarbons and wetting solution Mixture of hydrocarbons and wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Nitric acid 3 F1 III Mixture of hydrocarbons 3 F1 II/III Acetic acid 8 C9 II/III Rule for collective entries 3079 Methacrylonitrile, stabilized 6.1 TF1 I 3082 sec-Alcohol C6-C17 poly (3-6) ethoxylate 9 M6 III n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons 2924 2927 2933 aqueous alkaline solution, mixture of sodium and potassium phenolate Sodium hydrogen difluoride aqueous solution Corrosive liquid, toxic, n.o.s. slightly corrosive Flammable liquid, corrosive, n.o.s. Toxic liquid, corrosive, organic, n.o.s. Methyl 2-chloropropionate 2984 Hydrogen peroxide, aqueous solution pure isomers and isomeric mixture with not less than 8% but less than 20% hydrogen peroxide, stabilized as necessary 3056 n-Heptaldehyde 3065 Alcoholic beverages 3066 Paint or Paint related material with more than 24% alcohol by volume including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base or including paint thinning and reducing compound - 29 - Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) 3082 Alcohol C12-C15 poly (1-3) ethoxylate Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 9 M6 III 3082 Alcohol C13-C15 poly (1-6) ethoxylate 9 M6 III 3082 3082 3082 3082 3082 Aviation turbine fuel JP-5 flashpoint more than 60 °C Aviation turbine fuel JP-7 flashpoint more than 60 °C Coal tar flashpoint more than 60 °C Coal tar naphtha flashpoint more than 60 °C Creosote produced of coal flashpoint more than 60 °C tar 3082 Creosote produced of wood flashpoint more than 60 °C tar 3082 Cresyl diphenyl phosphate 3082 Decyl acrylate 9 9 9 9 9 M6 M6 M6 M6 M6 III III III III III n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons Mixture of hydrocarbons Mixture of hydrocarbons Mixture of hydrocarbons Mixture of hydrocarbons Mixture of hydrocarbons 9 M6 III Mixture of hydrocarbons 9 9 M6 M6 III III 3082 Diisobutyl phthalate 9 M6 III 3082 Di-n-butyl phthalate 9 M6 III 9 M6 III Wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons n-Butyl acetate/ n-butyl acetate-saturated wetting solution and mixture of hydrocarbons Rule for collective entries 9 M6 III Wetting solution 9 9 9 M6 M6 M6 III III III Mixture of hydrocarbons Wetting solution Wetting solution 9 9 9 9 M6 M6 M6 M6 III III III III Wetting solution Wetting solution Wetting solution Rule for collective entries 5.1 OT1 I/II/III Rule for collective entries 3082 Hydrocarbons 3082 Isodecyl diphenyl phosphate 3082 Methylnaphthalenes 3082 Triaryl phosphates 3082 Tricresyl phosphate 3082 3082 3082 3082 Trixylenyl phosphate Zinc alkyl dithiophosphate Zinc aryl dithiophosphate Environmentally hazardous substance, liquid, n.o.s. 3099 Oxidizing liquid, toxic, n.o.s. liquid, flashpoint more than 60 °C, environmentally hazardous isomeric mixture, liquid n.o.s. with not more than 3% ortho-isomer C3-C14 C7-C16 - 30 - Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) Class Classifi- Packing cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) Standard liquid (5) 3101 Organic Peroxide, Type B, 5.2 P1 n-Butyl acetate/ n-butyl acetate-saturated 3103 C, D, E or F, liquid wetting solution 3105 or Organic Peroxide, Type B, and 3107 C, D, E or F, liquid, mixture of hydrocarbons 3109 temperature controlled and 3111 nitric acid** 3113 3115 3117 3119 ** For UN Nos. 3101, 3103, 3105, 3107, 3109, 3111, 3113, 3115, 3117, 3119 (tert-butyl hydroperoxide with more than 40% peroxide content and peroxyacetic acids are excluded): All organic peroxides in a technically pure form or in solution in solvents which, as far as their compatibility is concerned, are covered by the standard liquid "mixture of hydrocarbons" in this list. Compatibility of vents and gaskets with organic peroxides may be verified, also independently of the design type test, by laboratory tests with nitric acid. 3145 Butylphenols liquid, n.o.s. 8 C3 I/II/III Acetic acid 3145 Alkylphenols, liquid, n.o.s. including C2 to C12 8 C3 I/II/III n-Butyl acetate/ homologues n-butyl acetate-saturated wetting solution 3149 Hydrogen peroxide and 5.1 OC1 II with UN 2790 acetic acid, Wetting solution peroxyacetic acid mixture, UN 2796 sulphuric acid and stabilized and/or UN 1805 phosphoric nitric acid acid, water and not more than 5% peroxyacetic acid 3210 Chlorates, inorganic, 5.1 O1 II/III Water aqueous solution, n.o.s. 3211 Perchlorates, inorganic, 5.1 O1 II/III Water aqueous solution, n.o.s. 3213 Bromates, inorganic, 5.1 O1 II/III Water aqueous solution, n.o.s. 3214 Permanganates, 5.1 O1 II Water inorganic, aqueous solution, n.o.s. 3216 Persulphates, inorganic, 5.1 O1 III Wetting solution aqueous solution, n.o.s. 3218 Nitrates, inorganic, 5.1 O1 II/III Water aqueous solution, n.o.s. 3219 Nitrites, inorganic, 5.1 O1 II/III Water aqueous solution, n.o.s. 3264 Cupric chloride 8 C1 III Water aqueous solution, slightly corrosive 3264 Hydroxylamine sulphate 25% aqueous solution 8 C1 III Water 3264 Phosphorous acid aqueous solution 8 C1 III Water 3264 Corrosive liquid, acidic, flashpoint more than 60 °C 8 C1 I/II/III Rule for collective entries; not applicable to mixtures inorganic, n.o.s. having components of UN Nos.: 1830, 1832, 1906 and 2308 3265 Methoxyacetic acid 8 C3 I n-Butyl acetate/ n-butyl acetate-saturated wetting solution 3265 Allyl succinic acid 8 C3 II n-Butyl acetate/ anhydride n-butyl acetate-saturated wetting solution 3265 Dithioglycolic acid 8 C3 II n-Butyl acetate/ n-butyl acetate-saturated wetting solution - 31 - Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 8 C3 III Wetting solution 3265 Caprylic acid 8 C3 III 3265 Isovaleric acid 8 C3 III 3265 Pelargonic acid 8 C3 III 3265 Pyruvic acid 8 C3 III 3265 Valeric acid 3265 Corrosive liquid, acidic, organic, n.o.s. 3266 Sodium hydrosulphide 3266 Sodium sulphide 8 8 C3 C3 III I/II/III n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Acetic acid Rule for collective entries 8 8 C5 C5 II III Acetic acid Acetic acid 8 C5 I/II/III Rule for collective entries 8 C7 II 3267 Corrosive liquid, basic, flashpoint more than 60 °C organic, n.o.s. 3271 Ethylene glycol monobutyl flashpoint 60 °C ether 3271 Ether, n.o.s. 3272 Acrylic acid tert-butyl ester 8 C7 I/II/III Mixture of hydrocarbons and wetting solution Rule for collective entries 3 F1 III Acetic acid 3 3 F1 F1 II/III II 3272 Isobutyl propionate 3 F1 II 3272 Methyl valerate 3 F1 II 3272 Trimethyl ortho-formate 3 F1 II 3272 Ethyl valerate 3 F1 III 3272 Isobutyl isovalerate 3 F1 III 3272 n-Amyl propionate 3 F1 III 3272 n-Butylbutyrate 3 F1 III 3272 Methyl lactate 3 F1 III 3272 Ester, n.o.s. 3 F1 II/III Rule for collective entries n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution n-Butyl acetate/ n-butyl acetate-saturated wetting solution Rule for collective entries 3265 Butyl phosphate 3266 Corrosive liquid, basic, inorganic, n.o.s. 3267 2,2'-(Butylimino)bisethanol mixture of mono- and dibutyl phosphate flashpoint more than 60 °C aqueous solution aqueous solution, slightly corrosive flashpoint more than 60 °C flashpoint below 23 °C - 32 - Description UN No. Proper shipping name or technical name 3.1.2 3.1.2 (1) (2a) (2b) Class Classifi- Packing Standard liquid cation Code group 2.2 2.2 2.1.1.3 (3a) (3b) (4) (5) 3287 Sodium nitrite 3287 Toxic liquid, inorganic, n.o.s. 3291 Clinical waste, unspecified, n.o.s. 3293 Hydrazine, aqueous solution 3295 Heptenes 3295 Nonanes 40% aqueous solution 6.1 6.1 T4 T4 III I/II/III Water Rule for collective entries liquid 6.2 I3 II Water with not more than 37% hydrazine, by mass n.o.s flashpoint below 23 °C 6.1 T4 III Water 3 3 F1 F1 II II Mixture of hydrocarbons Mixture of hydrocarbons 3295 Decanes n.o.s 3 F1 III Mixture of hydrocarbons 3 3 F1 F1 III I/II/III Mixture of hydrocarbons Rule for collective entries 5.1 5.1 OT1 OT1 II/III II/III Water Water 5.1 6.1 OT1 T4 II/III I/II/III Water Water 6.1 6.1 6.1 T4 T4 T4 I/II/III III III Water Water Water 3295 1,2,3-Trimethylbenzene 3295 Hydrocarbons, liquid, n.o.s. 3405 Barium chlorate, solution aqueous solution 3406 Barium perchlorate, aqueous solution solution 3408 Lead perchlorate, solution aqueous solution 3413 Potassium cyanide, aqueous solution solution 3414 Sodium cyanide, solution aqueous solution 3415 Sodium fluoride, solution aqueous solution 3422 Potassium fluoride, aqueous solution solution 4.1.2 Additional general provisions for the use of IBCs 4.1.2.1 When IBCs are used for the carriage of liquids with a flash-point of 60 °C (closed cup) or lower, or of powders liable to dust explosion, measures shall be taken to prevent a dangerous electrostatic discharge. 4.1.2.2 Every metal, rigid plastics and composite IBC, shall be inspected and tested, as relevant, in accordance with 6.5.4.4 or 6.5.4.5: - before it is put into service; - thereafter at intervals not exceeding two and a half and five years, as appropriate; - after the repair or remanufacture, before it is re-used for carriage. An IBC shall not be filled and offered for carriage after the date of expiry of the last periodic test or inspection. However, an IBC filled prior to the date of expiry of the last periodic test or inspection may be carried for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection. In addition, an IBC may be carried after the date of expiry of the last periodic test or inspection: (a) after emptying but before cleaning, for purposes of performing the required test or inspection prior to refilling; and (b) unless otherwise approved by the competent authority, for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection in order to allow the return of dangerous goods or residues for proper disposal or recycling. NOTE: For the particulars in the transport document, see 5.4.1.1.11. 4.1.2.3 IBCs of type 31HZ2 shall be filled to at least 80% of the volume of the outer casing. - 33 - 4.1.2.4 Except for routine maintenance of metal, rigid plastics, composite and flexible IBCs performed by the owner of the IBC, whose State and name or authorized symbol is durably marked on the IBC, the party performing routine maintenance shall durably mark the IBC near the manufacturer's UN design type marking to show: (a) The State in which the routine maintenance was carried out; and (b) The name or authorized symbol of the party performing the routine maintenance. 4.1.3 General provisions concerning packing instructions 4.1.3.1 Packing instructions applicable to dangerous goods of Classes 1 to 9 are specified in Section 4.1.4. They are subdivided in three sub-sections depending on the type of packagings to which they apply: Sub-section 4.1.4.1 for packagings other than IBCs and large packagings; these packing instructions are designated by an alphanumeric code starting with the letter "P" or "R" for packagings specific to RID and ADR; Sub-section 4.1.4.2 for IBCs; these are designated by an alphanumeric code starting with the letters "IBCs"; Sub-section 4.1.4.3 for large packagings; these are designated by an alphanumeric code starting with the letters "LP". Generally, packing instructions specify that the general provisions of 4.1.1, 4.1.2 or 4.1.3, as appropriate, are applicable. They may also require compliance with the special provisions of Sections 4.1.5, 4.1.6, 4.1.7, 4.1.8 or 4.1.9 when appropriate. Special packing provisions may also be specified in the packing instruction for individual substances or articles. They are also designated by an alphanumeric code comprising the letters: "PP" for packagings other than IBCs and large packagings, or "RR" for special provisions specific to RID and ADR; "B" for IBCs or "BB" for special packing provisions specific to RID and ADR; "L" for large packagings or "LL" for special packing provisions specific to ADR. Unless otherwise specified, each packaging shall conform to the applicable requirements of Part 6. Generally packing instructions do not provide guidance on compatibility and the user shall not select a packaging without checking that the substance is compatible with the packaging material selected (e.g. glass receptacles are unsuitable for most fluorides). Where glass receptacles are permitted in the packing instructions porcelain, earthenware and stoneware packagings are also allowed. 4.1.3.2 Column (8) of Table A of Chapter 3.2 shows for each article or substance the packing instruction(s) that shall be used. Columns (9a) and (9b) indicate the special packing provisions and the mixed packing provisions (see 4.1.10) applicable to specific substances or articles. 4.1.3.3 Each packing instruction shows, where applicable, the acceptable single and combination packagings. For combination packagings, the acceptable outer packagings, inner packagings and when applicable the maximum quantity permitted in each inner or outer packaging, are shown. Maximum net mass and maximum capacity are as defined in 1.2.1. 4.1.3.4 The following packagings shall not be used when the substances being carried are liable to become liquid during carriage: Packagings Drums: Boxes: Bags: Composite packagings: 1D and 1G 4A, 4B, 4C1, 4C2, 4D, 4F, 4G, 4H1 and 4H2 5L1, 5L2, 5L3, 5H1, 5H2, 5H3, 5H4, 5M1 and 5M2 6HC, 6HD2, 6HG1, 6HG2, 6HD1, 6PC, 6PD1, 6PD2, 6PG1, 6PG2 and 6PH1 - 34 - Large packagings Flexible plastics: 51H (outer packaging) IBCs For substances of packing group I: All types of IBC For substances of packing groups II and III: Wooden: Fibreboard: Flexible: Composite: 11C, 11D and 11F 11G 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2 11HZ2 and 21HZ2 For the purposes of this paragraph, substances and mixtures of substances having a melting point equal to or less than 45 °C shall be treated as solids liable to become liquid during carriage. 4.1.3.5 Where the packing instructions in this Chapter authorize the use of a particular type of packaging (e.g. 4G; 1A2), packagings bearing the same packaging identification code followed by the letters "V", "U" or "W" marked in accordance with the requirements of Part 6 (e.g. 4GV, 4GU or 4GW; 1A2V, 1A2U or 1A2W) may also be used under the same conditions and limitations applicable to the use of that type of packaging according to the relevant packing instructions. For example, a combination packaging marked with the packaging code "4GV" may be used whenever a combination packaging marked "4G" is authorized, provided the requirements in the relevant packing instruction regarding types of inner packagings and quantity limitations are respected. 4.1.3.6 Pressure receptacles for liquids and solids 4.1.3.6.1 Unless otherwise indicated in ADR, pressure receptacles conforming to: (a) the applicable requirements of Chapter 6.2; or (b) the national or international standards on the design, construction, testing, manufacturing and inspection, as applied by the country in which the pressure receptacles are manufactured, provided that the provisions of 4.1.3.6 are met, and that, for metallic cylinders, tubes, pressure drums, bundles of cylinders and salvage pressure receptacles, the construction is such that the minimum burst ratio (burst pressure divided by test pressure) is: (i) 1.50 for refillable pressure receptacles; (ii) 2.00 for non-refillable pressure receptacles, are authorized for the carriage of any liquid or solid substance other than explosives, thermally unstable substances, organic peroxides, self-reactive substances, substances where significant pressure may develop by evolution of chemical reaction and radioactive material (unless permitted in 4.1.9). This sub-section is not applicable to the substances mentioned in 4.1.4.1, packing instruction P200, table 3. 4.1.3.6.2 Every design type of pressure receptacle shall be approved by the competent authority of the country of manufacture or as indicated in Chapter 6.2. 4.1.3.6.3 Unless otherwise indicated, pressure receptacles having a minimum test pressure of 0.6 MPa shall be used. 4.1.3.6.4 Unless otherwise indicated, pressure receptacles may be provided with an emergency pressure relief device designed to avoid bursting in case of overfill or fire accidents. - 35 - Pressure receptacle valves shall be designed and constructed in such a way that they are inherently able to withstand damage without release of the contents or shall be protected from damage which could cause inadvertent release of the contents of the pressure receptacle, by one of the methods as given in 4.1.6.8 (a) to (e). 4.1.3.6.5 The level of filling shall not exceed 95% of the capacity of the pressure receptacle at 50 °C. Sufficient ullage (outage) shall be left to ensure that the pressure receptacle will not be liquid full at a temperature of 55 °C. 4.1.3.6.6 Unless otherwise indicated pressure receptacles shall be subjected to a periodic inspection and test every 5 years. The periodic inspection shall include an external examination, an internal examination or alternative method as approved by the competent authority, a pressure test or equivalent effective non-destructive testing with the agreement of the competent authority including an inspection of all accessories (e.g. tightness of valves, emergency relief valves or fusible elements). Pressure receptacles shall not be filled after they become due for periodic inspection and test but may be carried after the expiry of the time limit. Pressure receptacle repairs shall meet the requirements of 4.1.6.11. 4.1.3.6.7 Prior to filling, the packer shall perform an inspection of the pressure receptacle and ensure that the pressure receptacle is authorized for the substances to be carried and that the requirements of ADR have been met. Shut-off valves shall be closed after filling and remain closed during carriage. The consignor shall verify that the closures and equipment are not leaking. 4.1.3.6.8 Refillable pressure receptacles shall not be filled with a substance different from that previously contained unless the necessary operations for change of service have been performed. 4.1.3.6.9 Marking of pressure receptacles for liquids and solids according to 4.1.3.6 (not conforming to the requirements of Chapter 6.2) shall be in accordance with the requirements of the competent authority of the country of manufacturing. 4.1.3.7 Packagings or IBCs not specifically authorized in the applicable packing instruction shall not be used for the carriage of a substance or article unless specifically allowed under a temporary derogation agreed between Contracting Parties in accordance with 1.5.1. 4.1.3.8 Unpackaged articles other than Class 1 articles 4.1.3.8.1 Where large and robust articles cannot be packaged in accordance with the requirements of Chapters 6.1 or 6.6 and they have to be carried empty, uncleaned and unpackaged, the competent authority of the country of origin2 may approve such carriage. In doing so the competent authority shall take into account that: (a) Large and robust articles shall be strong enough to withstand the shocks and loadings normally encountered during carriage including trans-shipment between transport units and between transport units and warehouses, as well as any removal from a pallet for subsequent manual or mechanical handling; (b) All closures and openings shall be sealed so that there can be no loss of contents which might be caused under normal conditions of carriage, by vibration, or by changes in temperature, humidity or pressure (resulting from altitude, for example). No dangerous residue shall adhere to the outside of the large and robust articles; (c) Parts of large and robust articles, which are in direct contact with dangerous goods: (i) shall not be affected or significantly weakened by those dangerous goods; and (ii) shall not cause a dangerous effect e.g. catalysing a reaction or reacting with the dangerous goods; 2 If the country of origin is not a contracting party to ADR, the competent authority of the first country contracting party to the ADR reached by the consignment. - 36 - 4.1.3.8.2 (d) Large and robust articles containing liquids shall be stowed and secured to ensure that neither leakage nor permanent distortion of the article occurs during carriage; (e) They shall be fixed in cradles or crates or other handling devices or to the transport unit or container in such a way that they will not become loose during normal conditions of carriage. Unpackaged articles approved by the competent authority in accordance with the provisions of 4.1.3.8.1 shall be subject to the consignment procedures of Part 5. In addition the consignor of such articles shall ensure that a copy of any such approval is attached to the transport document. NOTE: A large and robust article may include flexible fuel containment systems, military equipment, machinery or equipment containing dangerous goods above the limited quantities according to 3.4.1. 4.1.4 List of packing instructions NOTE: Although the following packing instructions use the same numbering system as used in the IMDG Code and the UN Model Regulations, readers should be aware that some of the details may be different in the case of ADR. - 37 - 4.1.4.1 Packing instructions concerning the use of packagings (except IBCs and large packagings) P001 PACKING INSTRUCTION (LIQUIDS) P001 The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met: Combination packagings: Maximum capacity/Net mass (see 4.1.3.3) Inner packagings Outer packagings Packing group I Packing group II Packing group III Drums Glass 10 l steel (1A1, 1A2) 250 kg 400 kg 400 kg Plastics 30 l aluminium (1B1, 1B2) 250 kg 400 kg 400 kg Metal 40 l other metal (1N1, 1N2) 250 kg 400 kg 400 kg plastics (1H1, 1H2) 250 kg 400 kg 400 kg plywood (1D) 150 kg 400 kg 400 kg fibre (1G) 75 kg 400 kg 400 kg Boxes steel (4A) aluminium (4B) other metal (4N) natural wood (4C1, 4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) expanded plastics (4H1) solid plastics (4H2) 250 kg 250 kg 250 kg 150 kg 150 kg 75 kg 75 kg 60 kg 150 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 60 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 60 kg 400 kg Jerricans steel (3A1, 3A2) aluminium (3B1, 3B2) plastics (3H1, 3H2) 120 kg 120 kg 120 kg 120 kg 120 kg 120 kg 120 kg 120 kg 120 kg 450 l 450 l 450 l 450 l 450 l 450 l 450 l 450 l 450 l 450 l 450 l 450 l 450 l 450 l 450 l 450 l 60 l 60 l 60 l 60 l 60 l 60 l 60 l 60 l 60 l 60 l 60 l 60 l Single packagings: Drums steel, non-removable head (1A1) 250 l steel, removable head (1A2) 250 l a aluminium, non-removable head (1B1) 250 l aluminium, removable head (1B2) 250 l a metal other than steel or aluminium, non250 l removable head (1N1) metal other than steel or aluminium, removable 250 l a head (1N2) plastics, non-removable head (1H1) 250 l plastics, removable head (1H2) 250 l a Jerricans steel, non-removable head (3A1) 60 l steel, removable head (3A2) 60 l a aluminium, non-removable head (3B1) 60 l aluminium, removable head (3B2) 60 l a plastics, non-removable head (3H1) 60 l plastics, removable head (3H2) 60 l a a Only substances with a viscosity of more than 2 680 mm2/s are authorized. (Cont'd on next page) - 38 - P001 PACKING INSTRUCTION (LIQUIDS) (cont’d) P001 Single packagings (cont’d) Maximum capacity/Net mass (see 4.1.3.3) Composite packagings Packing group I Packing group II Packing group III plastics receptacle with outer steel or aluminium 250 l 250 l 250 l drum (6HA1, 6HB1) plastics receptacle with outer fibre, plastics or 120 l 250 l 250 l plywood drum (6HG1, 6HH1, 6HD1) plastics receptacle with outer steel or aluminium 60 l 60 l 60 l crate or box or plastics receptacle with outer wooden, plywood, fibreboard or solid plastics box (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2) glass receptacle with outer steel, aluminium, 60 l 60 l 60 l fibreboard, plywood, solid plastics or expanded plastics drum (6PA1, 6PB1, 6PG1, 6PD1, 6PH1 or 6PH2) or with outer steel or aluminium crate or box or with outer wooden or fibreboard box or with outer wickerwork hamper (6PA2, 6PB2, 6PC, 6PG2 or 6PD2) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. Additional requirement: For substances of Class 3, packing group III, which give off small quantities of carbon dioxide or nitrogen, the packagings shall be vented. Special packing provisions: PP1 For UN Nos. 1133, 1210, 1263 and 1866 and for adhesives, printing inks, printing ink related materials, paints, paint related materials and resin solutions which are assigned to UN 3082, metal or plastics packagings for substances of packing groups II and III in quantities of 5 litres or less per packaging are not required to meet the performance tests in Chapter 6.1 when carried: (a) in palletized loads, a pallet box or unit load device, e.g. individual packagings placed or stacked and secured by strapping, shrink or stretch-wrapping or other suitable means to a pallet; or (b) as inner packagings of combination packagings with a maximum net mass of 40 kg. PP2 For UN 3065, wooden barrels with a maximum capacity of 250 litres and which do not meet the provisions of Chapter 6.1 may be used. PP4 For UN No. 1774, packagings shall meet the packing group II performance level. PP5 For UN No. 1204, packagings shall be so constructed that explosion is not possible by reason of increased internal pressure. Cylinders, tubes and pressure drums shall not be used for these substances. PP6 (Deleted) PP10 For UN No. 1791, packing group II, the packaging shall be vented. PP31 For UN No. 1131, packagings shall be hermetically sealed. PP33 For UN No. 1308, packing groups I and II, only combination packagings with a maximum gross mass of 75 kg allowed. PP81 For UN No. 1790 with more than 60% but not more than 85% hydrogen fluoride and UN No. 2031 with more than 55% nitric acid, the permitted use of plastics drums and jerricans as single packagings shall be two years from their date of manufacture. Special packing provisions specific to RID and ADR: RR2 For UN No. 1261, removable head packagings are not permitted. - 39 - P002 PACKING INSTRUCTION (SOLIDS) The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met: Combination packagings: Inner packagings Glass Plastics a Metal Paper a, b, c Fibre a, b, c 10 kg 50 kg 50 kg 50 kg 50 kg Outer packagings Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plastics (1H1, 1H2) plywood (1D) fibre (1G) Boxes steel (4A) aluminium (4B) other metal (4N) natural wood (4C1) natural wood with sift proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) expanded plastics (4H1) solid plastics (4H2) Jerricans steel (3A1, 3A2) aluminium (3B1, 3B2) plastics (3H1, 3H2) P002 Maximum net mass (see 4.1.3.3) Packing group I Packing group II Packing group III 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 250 kg 250 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 250 kg 125 kg 125 kg 60 kg 250 kg 400 kg 400 kg 400 kg 60 kg 400 kg 400 kg 400 kg 400 kg 60 kg 400 kg 120 kg 120 kg 120 kg 120 kg 120 kg 120 kg 120 kg 120 kg 120 kg Single packagings: Drums steel (1A1 or 1A2 d) 400 kg 400 kg 400 kg d aluminium (1B1 or 1B2 ) 400 kg 400 kg 400 kg metal, other than steel or aluminium (1N1 or 1N2 d) 400 kg 400 kg 400 kg plastics (1H1 or 1H2 d) 400 kg 400 kg 400 kg fibre (1G) e 400 kg 400 kg 400 kg plywood (1D) e 400 kg 400 kg 400 kg Jerricans steel (3A1 or 3A2 d) 120 kg 120 kg 120 kg aluminium (3B1 or 3B2 d ) 120 kg 120 kg 120 kg plastics (3H1 or 3H2 d) 120 kg 120 kg 120 kg a These inner packagings shall be sift-proof. b These inner packagings shall not be used when the substances being carried may become liquid during carriage (see 4.1.3.4). c These inner packagings shall not be used for substances of packing group I. d These packagings shall not be used for substances of packing group I that may become liquid during carriage (see 4.1.3.4). e These packagings shall not be used when substances being carried may become liquid during carriage (see 4.1.3.4). (Cont'd on next page) - 40 - P002 PACKING INSTRUCTION (SOLIDS) (cont’d) P002 Maximum net mass (see 4.1.3.3) Packing group I Packing group II Packing group III Single packagings (cont’d): Boxes steel (4A) e aluminium (4B) e other metal (4N) e natural wood (4C1) e plywood (4D) e reconstituted wood (4F) e natural wood with sift-proof walls (4C2) e fibreboard (4G) e solid plastics (4H2) e Bags bags (5H3, 5H4, 5L3, 5M2) e Not allowed Not allowed Not allowed Not allowed Not allowed Not allowed Not allowed Not allowed Not allowed 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg Not allowed 50 kg 50 kg Composite packagings plastics receptacle with outer steel, aluminium, 400 kg 400 kg 400 kg plywood, fibre or plastics drum (6HA1, 6HB1, 6HG1 e , 6HD1 e, or 6HH1) plastics receptacle with outer steel or aluminium 75 kg 75 kg 75 kg crate or box, wooden box, plywood box, fibreboard box or solid plastics box (6HA2, 6HB2, 6HC, 6HD2 e, 6HG2 e or 6HH2) 75 kg 75 kg 75 kg glass receptacle with outer steel, aluminium plywood or fibre drum (6PA1, 6PB1, 6PD1 e or 6PG1 e ) or with outer steel or aluminium crate or box or with outer wooden, or fibreboard box or with outer wickerwork hamper (6PA2, 6PB2, 6PC, 6PD2 e, or 6PG2e) or with outer solid plastics or expanded plastics packaging (6PH2 or 6PH1 e) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. e These packagings shall not be used when the substances being carried may become liquid during carriage (see 4.1.3.4). (Cont'd on next page) - 41 - P002 Special packing provisions: PACKING INSTRUCTION (SOLIDS) (cont’d) P002 PP6 (Deleted) PP7 For UN No. 2000, celluloid may also be transported unpacked on pallets, wrapped in plastic film and secured by appropriate means, such as steel bands as a full load in closed vehicles or containers. Each pallet shall not exceed 1 000 kg. PP8 For UN No. 2002, packagings shall be so constructed that explosion is not possible by reason of increased internal pressure. Cylinders, tubes and pressure drums shall not be used for these substances. PP9 For UN Nos. 3175, 3243 and 3244, packagings shall conform to a design type that has passed a leakproofness test at the packing group II performance level. For UN No. 3175, the leakproofness test is not required when the liquids are fully absorbed in solid material contained in sealed bags. PP11 For UN No. 1309, packing group III, and UN No. 1362, 5H1, 5L1 and 5M1 bags are allowed if they are overpacked in plastic bags and are wrapped in shrink or stretch wrap on pallets. PP12 For UN Nos. 1361, 2213 and UN No. 3077, 5H1, 5L1 and 5M1 bags are allowed when carried in closed vehicles or containers. PP13 For articles classified under UN No. 2870, only combination packagings meeting the packing group I performance level are authorized. PP14 For UN Nos. 2211, 2698 and 3314, packagings are not required to meet the performance tests in Chapter 6.1. PP15 For UN Nos. 1324 and 2623, packagings shall meet the packing group III performance level. PP20 For UN No. 2217, any sift-proof, tearproof receptacle may be used. PP30 For UN No. 2471, paper or fibre inner packagings are not permitted. PP34 For UN No. 2969 (as whole beans), 5H1, 5L1 and 5M1 bags are permitted. PP37 For UN Nos. 2590 and 2212, 5M1 bags are permitted. All bags of any type shall be carried in closed vehicles or containers or be placed in closed rigid overpacks. PP38 For UN No. 1309, packing group II, bags are permitted only in closed vehicles or containers. PP84 For UN No. 1057, rigid outer packagings meeting the packing group II performance level shall be used. The packagings shall be designed and constructed and arranged to prevent movement, inadvertent ignition of the devices or inadvertent release of flammable gas or liquid. NOTE: For waste lighters collected separately see Chapter 3.3, special provision 654. Special packing provision specific to RID and ADR: RR5 Notwithstanding special packing provision PP84, only the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.5 to 4.1.1.7 need be complied with if the gross mass of the package is not more than 10 kg. NOTE: For waste lighters collected separately see Chapter 3.3, special provision 654. - 42 - P003 PACKING INSTRUCTION P003 Dangerous goods shall be placed in suitable outer packagings. The packagings shall meet the provisions of 4.1.1.1, 4.1.1.2, 4.1.1.4, 4.1.1.8 and 4.1.3 and be so designed that they meet the construction requirements of 6.1.4. Outer packagings constructed of suitable material, and of adequate strength and design in relation to the packaging capacity and its intended use, shall be used. Where this packing instruction is used for the transport of articles or inner packagings of combination packagings, the packaging shall be designed and constructed to prevent inadvertent discharge of articles during normal conditions of carriage. Special packing provisions: PP16 For UN No. 2800, batteries shall be protected from short circuits and shall be securely packed in strong outer packagings. NOTE 1: Non-spillable batteries which are an integral part of, and necessary for, the operation of mechanical or electronic equipment shall be securely fastened in the battery holder on the equipment and protected in such a manner as to prevent damage and short circuits. NOTE 2: For used batteries (UN 2800), see P801a. PP17 For UN No. 2037, packages shall not exceed 55 kg net mass for fibreboard packagings or 125 kg net mass for other packagings. PP19 For UN Nos. 1364 and 1365, carriage as bales is authorized. PP20 For UN Nos. 1363, 1386, 1408 and 2793 any sift-proof, tearproof receptacle may be used. PP32 UN Nos. 2857 and 3358 may be carried unpackaged, in crates or in appropriate overpacks. PP87 (Deleted) PP88 (Deleted) PP90 For UN No. 3506, sealed inner liners or bags of strong leakproof and puncture resistant material impervious to mercury which will prevent escape of the substance from the package irrespective of the position or the orientation of the package shall be used. PP91 For UN 1044, large fire extinguishers may also be carried unpackaged provided that the requirements of 4.1.3.8.1 (a) to (e) are met, the valves are protected by one of the methods in accordance with 4.1.6.8 (a) to (d) and other equipment mounted on the fire extinguisher is protected to prevent accidental activation. For the purpose of this special packing provision, "large fire extinguishers" means fire extinguishers as described in indents (c) to (e) of special provision 225 of Chapter 3.3. Special packing provisions specific to RID and ADR: RR6 For UN No. 2037 in the case of carriage by full load, metal articles may also be packed as follows: the articles shall be grouped together in units on trays and held in position with an appropriate plastics cover; these units shall be stacked and suitably secured on pallets. RR9 For UN 3509, packagings are not required to meet the requirements of 4.1.1.3. Packagings meeting the requirements of 6.1.4, made leak tight or fitted with a leak tight and puncture resistant sealed liner or bag, shall be used. When the only residues contained are solids which are not liable to become liquid at temperatures likely to be encountered during carriage, flexible packagings may be used. When liquid residues are present, rigid packagings that provide a means of retention (e.g. absorbent material) shall be used. Before being filled and handed over for carriage, every packaging shall be inspected to ensure that it is free from corrosion, contamination or other damage. Any packaging showing signs of reduced strength shall no longer be used (minor dents and scratches are not considered as reducing the strength of the packaging). Packagings intended for the carriage of packagings, discarded, empty, uncleaned with residues of Class 5.1 shall be so constructed or adapted that the goods cannot come into contact with wood or any other combustible material. - 43 - P004 PACKING INSTRUCTION P004 This instruction applies to UN Nos. 3473, 3476, 3477, 3478 and 3479. The following packagings are authorized: (1) (2) For fuel cell cartridges, provided that the general provisions of 4.1.1.1, 4.1.1.2, 4.1.1.3, 4.1.1.6 and 4.1.3 are met: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). Packagings shall conform to the packing group II performance level. For fuel cell cartridges packed with equipment: strong outer packagings which meet the general provisions of 4.1.1.1, 4.1.1.2, 4.1.1.6 and 4.1.3. When fuel cell cartridges are packed with equipment, they shall be packed in inner packagings or placed in the outer packaging with cushioning material or divider(s) so that the fuel cell cartridges are protected against damage that may be caused by the movement or placement of the contents within the outer packaging. The equipment shall be secured against movement within the outer packaging. For the purpose of this packing instruction, "equipment" means apparatus requiring the fuel cell cartridges with which it is packed for its operation. (3) For fuel cell cartridges contained in equipment: strong outer packagings which meet the general provisions of 4.1.1.1, 4.1.1.2, 4.1.1.6 and 4.1.3. Large robust equipment (see 4.1.3.8) containing fuel cell cartridges may be carried unpackaged. For fuel cell cartridges contained in equipment, the entire system shall be protected against short circuit and inadvertent operation. P010 PACKING INSTRUCTION The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: Combination packagings Inner packagings Outer packagings Maximum net mass (see 4.1.3.3) Glass 1 l Drums Steel 40 l steel (1A1, 1A2) 400 kg plastics (1H1, 1H2) 400 kg plywood (1D) 400 kg fibre (1G) 400 kg Boxes steel (4A) 400 kg natural wood (4C1, 4C2) 400 kg plywood (4D) 400 kg reconstituted wood (4F) 400 kg fibreboard (4G) 400 kg expanded plastics (4H1) 60 kg solid plastics (4H2) 400 kg Single packagings Maximum capacity (see 4.1.3.3) Drums steel, non-removable head (1A1) 450 l Jerricans steel, non-removable head (3A1) 60 l Composite packagings plastics receptacle in steel drums (6HA1) 250 l Steel pressure receptacles, provided that the general provisions of 4.1.3.6 are met. P010 P099 PACKING INSTRUCTION P099 Only packagings which are approved for these goods by the competent authority may be used. A copy of the competent authority approval shall accompany each consignment or the transport document shall include an indication that the packaging was approved by the competent authority. - 44 - P101 PACKING INSTRUCTION P101 Only packagings which are approved by the competent authority of the country of origin may be used. If the country of origin is not a Contracting Party to the ADR, the packaging shall be approved by the competent authority of the first country Contracting Party to ADR reached by the consignment. The State’s distinguishing sign for motor vehicles in international traffic of the country for which the authority acts, shall be marked on the transport documents as follows: "Packaging approved by the competent authority of..." (see 5.4.1.2.1 (e)) P110(a) PACKING INSTRUCTION (Reserved) P110(a) NOTE: This packing instruction in the UN Model Regulations is not admitted for carriage under ADR. P110(b) PACKING INSTRUCTION P110(b) The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Receptacles metal wood rubber, conductive plastics, conductive Dividing partitions metal wood plastics fibreboard Boxes natural wood, sift-proof wall (4C2) plywood (4D) reconstituted wood (4F) Bags rubber, conductive plastics, conductive Special packing provision: PP42 For UN Nos. 0074, 0113, 0114, 0129, 0130, 0135 and 0224, the following conditions shall be met: (a) Inner packagings shall not contain more than 50 g of explosive substance (quantity corresponding to dry substance); (b) Compartments between dividing partitions shall not contain more than one inner packaging, firmly fitted; and (c) The outer packaging may be partitioned into up to 25 compartments. - 45 - P111 PACKING INSTRUCTION P111 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Bags paper, waterproofed plastics textile, rubberized Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, expanded (4H1) plastics, solid (4H2) Receptacles wood Sheets plastics textile, rubberized Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Special packing provision: PP43 For UN 0159, inner packagings are not required when metal (1A1, 1A2, 1B1, 1B2, 1N1 or 1N2) or plastics (1H1 or 1H2) drums are used as outer packagings. P112(a) PACKING INSTRUCTION P112(a) (Solid wetted, 1.1D) The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Bags paper, multiwall, water resistant plastics textile textile, rubberized woven plastics Receptacles metal plastics wood Bags plastics textile, plastic coated or lined Receptacles metal plastics wood Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, expanded (4H1) plastics, solid (4H2) Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Additional requirement: Intermediate packagings are not required if leakproof removable head drums are used as the outer packaging. Special packing provisions: PP26 For UN Nos. 0004, 0076, 0078, 0154, 0219 and 0394, packagings shall be lead free. PP45 For UN Nos. 0072 and 0226, intermediate packagings are not required. - 46 - P112(b) PACKING INSTRUCTION P112(b) (Solid dry, other than powder 1.1D) The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Bags paper, kraft paper, multiwall, water resistant plastics textile textile, rubberized woven plastics Bags (for UN No. 0150 only) plastics textile, plastic coated or lined Bags woven plastics, sift-proof (5H2) woven plastics, water-resistant (5H3) plastics, film (5H4) textile, sift-proof (5L2) textile, water resistant (5L3) paper, multiwall, water resistant (5M2) Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, expanded (4H1) plastics, solid (4H2) Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Special packing provisions: PP26 For UN Nos. 0004, 0076, 0078, 0154, 0216, 0219 and 0386, packagings shall be lead free. PP46 For UN Nos. 0209, bags, sift-proof (5H2) are recommended for flake or prilled TNT in the dry state and a maximum net mass of 30 kg. PP47 For UN No. 0222, inner packagings are not required when the outer packaging is a bag. - 47 - P112(c) PACKING INSTRUCTION P112(c) (Solid dry powder 1.1D) The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Bags paper, multiwall, water resistant plastics woven plastics Receptacles fibreboard metal plastics wood Bags paper, multiwall, water resistant with inner lining plastics Receptacles metal plastics wood Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Additional requirements: 1. Inner packagings are not required if drums are used as the outer packaging. 2. The packaging shall be sift-proof. Special packing provisions: PP26 For UN Nos. 0004, 0076, 0078, 0154, 0216, 0219 and 0386, packagings shall be lead free. PP46 For UN No. 0209, bags, sift-proof (5H2) are recommended for flake or prilled TNT in the dry state and a maximum net mass of 30 kg. PP48 For UN No. 0504, metal packagings shall not be used. - 48 - P113 PACKING INSTRUCTION P113 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Bags paper plastics textile, rubberized Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Receptacles fibreboard metal plastics wood Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Additional requirement: The packaging shall be sift-proof. Special packing provisions: PP49 For UN Nos. 0094 and 0305, no more than 50 g of substance shall be packed in an inner packaging. PP50 For UN No. 0027, inner packagings are not necessary when drums are used as outer packagings. PP51 For UN No. 0028, paper kraft or waxed paper sheets may be used as inner packagings. - 49 - P114(a) PACKING INSTRUCTION P114(a) (Solid wetted) The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Bags Boxes Bags plastics steel (4A) plastics textile, plastic coated metal, other than steel or aluminium (4N) textile or lined natural wood, ordinary (4C1) woven plastics natural wood, sift-proof walls (4C2) Receptacles Receptacles plywood (4D) metal metal reconstituted wood (4F) plastics plastics fibreboard (4G) wood plastics, solid (4H2) Dividing partitions wood Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) Plywood (1D) fibre (1G) plastics (1H1, 1H2) Additional requirement: Intermediate packagings are not required if leakproof removable head drums are used as outer packagings. Special packing provisions: PP26 For UN Nos. 0077, 0132, 0234, 0235 and 0236, packagings shall be lead free. PP43 For UN 0342, inner packagings are not required when metal (1A1, 1A2, 1B1, 1B2, 1N1 or 1N2) or plastics (1H1 or 1H2) drums are used as outer packagings. P114(b) PACKING INSTRUCTION P114(b) (Solid dry) The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Not necessary Boxes Bags natural wood, ordinary (4C1) paper, kraft natural wood, sift-proof walls (4C2) plastics plywood (4D) textile, sift-proof reconstituted wood (4F) woven plastics, sift-proof fibreboard (4G) Receptacles fibreboard Drums metal steel (1A1, 1A2) paper aluminium (1B1, 1B2) plastics other metal (1N1, 1N2) woven plastics, sift-proof plywood (1D) wood fibre (1G) plastics (1H1, 1H2) Special packing provisions: PP26 For UN Nos. 0077, 0132, 0234, 0235 and 0236, packagings shall be lead free. PP48 For UN Nos. 0508 and 0509, metal packagings shall not be used. PP50 For UN Nos. 0160, 0161 and 0508, inner packagings are not necessary if drums are used as outer packagings. PP52 For UN Nos. 0160 and 0161, when metal drums (1A1, 1A2, 1B1, 1B2, 1N1 or 1N2) are used as outer packagings, metal packagings shall be so constructed that the risk of explosion, by reason of increased internal pressure from internal or external causes is prevented. - 50 - P115 PACKING INSTRUCTION P115 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Receptacles plastics wood Boxes natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) Bags plastics in metal receptacles Drums metal Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Receptacles wood Special packing provisions: PP45 For UN No. 0144, intermediate packagings are not required. PP53 For UN Nos. 0075, 0143, 0495 and 0497, when boxes are used as outer packagings, inner packagings shall have taped screw cap closures and be not more than 5 litres capacity each. Inner packagings shall be surrounded with non-combustible absorbent cushioning materials. The amount of absorbent cushioning material shall be sufficient to absorb the liquid contents. Metal receptacles shall be cushioned from each other. Net mass of propellant is limited to 30 kg for each package when outer packagings are boxes. PP54 For UN Nos. 0075, 0143, 0495 and 0497, when drums are used as outer packagings and when intermediate packagings are drums, they shall be surrounded with non-combustible cushioning material in a quantity sufficient to absorb the liquid contents. A composite packaging consisting of a plastics receptacle in a metal drum may be used instead of the inner and intermediate packagings. The net volume of propellant in each package shall not exceed 120 litres. PP55 For UN No. 0144, absorbent cushioning material shall be inserted. PP56 For UN No. 0144, metal receptacles may be used as inner packagings. PP57 For UN Nos. 0075, 0143, 0495 and 0497, bags shall be used as intermediate packagings when boxes are used as outer packagings. PP58 For UN Nos. 0075, 0143, 0495 and 0497, drums shall be used as intermediate packagings when drums are used as outer packagings. PP59 For UN No. 0144, fibreboard boxes (4G) may be used as outer packagings. PP60 For UN No. 0144, aluminium drums (1B1 and 1B2) and metal, other than steel or aluminium, drums (1N1 and 1N2) shall not be used. - 51 - P116 PACKING INSTRUCTION P116 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Bags paper, water and oil resistant plastics textile, plastic coated or lined woven plastics, sift-proof Not necessary Bags woven plastics (5H1, 5H2, 5H3) paper, multiwall, water resistant (5M2) plastics, film (5H4) textile, sift-proof (5L2) textile, water resistant (5L3) Receptacles fibreboard, water resistant metal plastics wood, sift-proof Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Sheets paper, water resistant paper, waxed plastics Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Jerricans steel (3A1, 3A2) plastics (3H1, 3H2) Special packing provisions: PP61 For UN Nos. 0082, 0241, 0331 and 0332, inner packagings are not required if leakproof removable head drums are used as outer packagings. PP62 For UN Nos. 0082, 0241, 0331 and 0332, inner packagings are not required when the explosive is contained in a material impervious to liquid. PP63 For UN No. 0081, inner packagings are not required when contained in rigid plastic which is impervious to nitric esters. PP64 For UN No. 0331, inner packagings are not required when bags (5H2), (5H3) or (5H4) are used as outer packagings. PP65 (Deleted) PP66 For UN No. 0081, bags shall not be used as outer packagings. - 52 - P130 PACKING INSTRUCTION P130 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Not necessary Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, expanded (4H1) plastics, solid (4H2) Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Special packing provision: PP67 The following applies to UN Nos. 0006, 0009, 0010, 0015, 0016, 0018, 0019, 0034, 0035, 0038, 0039, 0048, 0056, 0137, 0138, 0168, 0169, 0171, 0181, 0182, 0183, 0186, 0221, 0243, 0244, 0245, 0246, 0254, 0280, 0281, 0286, 0287, 0297, 0299, 0300, 0301, 0303, 0321, 0328, 0329, 0344, 0345, 0346, 0347, 0362, 0363, 0370, 0412, 0424, 0425, 0434, 0435, 0436, 0437, 0438, 0451, 0488 and 0502: Large and robust explosives articles, normally intended for military use, without their means of initiation or with their means of initiation containing at least two effective protective features, may be carried unpackaged. When such articles have propelling charges or are self-propelled, their ignition systems shall be protected against stimuli encountered during normal conditions of carriage. A negative result in Test Series 4 on an unpackaged article indicates that the article can be considered for carriage unpackaged. Such unpackaged articles may be fixed to cradles or contained in crates or other suitable handling devices. - 53 - P131 PACKING INSTRUCTION P131 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Intermediate packagings Outer packagings Inner packagings Bags paper plastics Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plastics, solid (4H2) plywood (4D) reconstituted wood (4F) fibreboard (4G) Receptacles fibreboard metal plastics wood Reels Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Special packing provision: PP68 For UN Nos. 0029, 0267 and 0455, bags and reels shall not be used as inner packagings. P132(a) PACKING INSTRUCTION P132(a) (Articles consisting of closed metal, plastics or fibreboard casings that contain a detonating explosive, or consisting of plastics-bonded detonating explosives) The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Not necessary Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) wood, natural, ordinary (4C1) wood, natural, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) - 54 - P132(b) PACKING INSTRUCTION P132(b) (Articles without closed casings) The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Intermediate packagings Outer packagings Inner packagings Receptacles fibreboard metal plastics wood Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Sheets paper plastics P133 PACKING INSTRUCTION P133 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Intermediate packagings Outer packagings Inner packagings Receptacles fibreboard metal plastics wood Receptacles fibreboard metal plastics wood Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Trays, fitted with dividing partitions fibreboard plastics wood Additional requirement: Receptacles are only required as intermediate packagings when the inner packagings are trays. Special packing provision: PP69 For UN Nos. 0043, 0212, 0225, 0268 and 0306, trays shall not be used as inner packagings. - 55 - P134 PACKING INSTRUCTION P134 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Intermediate packagings Outer packagings Inner packagings Bags water resistant Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, expanded (4H1) plastics, solid (4H2) Receptacles fibreboard metal plastics wood Sheets fibreboard, corrugated Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Tubes fibreboard P135 PACKING INSTRUCTION P135 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Intermediate packagings Outer packagings Inner packagings Bags paper plastics Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, expanded (4H1) plastics, solid (4H2) Receptacles fibreboard metal plastics wood Sheets paper plastics Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) - 56 - P136 PACKING INSTRUCTION P136 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Intermediate packagings Outer packagings Inner packagings Bags plastics textile Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Boxes fibreboard plastics wood Dividing partitions in the outer packagings Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) P137 PACKING INSTRUCTION P137 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Outer packagings Intermediate packagings Inner packagings Bags plastics Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plastics, solid (4H2) plywood (4D) reconstituted wood (4F) fibreboard (4G) Boxes Fibreboard wood Tubes fibreboard metal plastics Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Dividing partitions in the outer packagings Special packing provision: PP70 For UN Nos. 0059, 0439, 0440 and 0441, when the shaped charges are packed singly, the conical cavity shall face downwards and the package marked "THIS SIDE UP". When the shaped charges are packed in pairs, the conical cavities shall face inwards to minimize the jetting effect in the event of accidental initiation. - 57 - P138 PACKING INSTRUCTION P138 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Bags plastics Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Additional requirement: If the ends of the articles are sealed, inner packagings are not necessary. P139 PACKING INSTRUCTION P139 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Intermediate packagings Outer packagings Inner packagings Bags plastics Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Receptacles fibreboard metal plastics wood Reels Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Sheets paper plastics Special packing provisions: PP71 For UN Nos. 0065, 0102, 0104, 0289 and 0290, the ends of the detonating cord shall be sealed, for example, by a plug firmly fixed so that the explosive cannot escape. The ends of flexible detonating cord shall be fastened securely. PP72 For UN Nos. 0065 and 0289, inner packagings are not required when they are in coils. - 58 - P140 PACKING INSTRUCTION P140 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Intermediate packagings Outer packagings Inner packagings Bags Plastics Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Receptacles wood Reels Sheets paper, kraft plastics Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Special packing provisions: PP73 For UN No. 0105, no inner packagings are required if the ends are sealed. PP74 For UN No. 0101, the packaging shall be sift-proof except when the fuse is covered by a paper tube and both ends of the tube are covered with removable caps. PP75 For UN No. 0101, steel, aluminium or other metal boxes or drums shall not be used. P141 PACKING INSTRUCTION P141 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Outer packagings Intermediate packagings Inner packagings Receptacles fibreboard metal plastics wood Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Trays, fitted with dividing partitions plastics wood Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Dividing partitions in the outer packagings - 59 - P142 PACKING INSTRUCTION P142 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Intermediate packagings Outer packagings Inner packagings Bags paper plastics Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Receptacles fibreboard metal plastics wood Sheets paper Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Trays, fitted with dividing partitions plastics P143 PACKING INSTRUCTION P143 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Intermediate packagings Outer packagings Inner packagings Bags paper, kraft plastics textile textile, rubberized Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2) Receptacles fibreboard metal Plastics wood Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2) Trays, fitted with dividing partitions plastics wood Additional requirement: Instead of the above inner and outer packagings, composite packagings (6HH2) (plastics receptacle with outer solid plastics box) may be used. Special packing provision: PP76 For UN Nos. 0271, 0272, 0415 and 0491, when metal packagings are used, metal packagings shall be so constructed that the risk of explosion, by reason of increase in internal pressure from internal or external causes is prevented. - 60 - P144 PACKING INSTRUCTION P144 The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Receptacles fibreboard metal Plastics wood Not necessary Boxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary with metal liner (4C1) plywood (4D) with metal liner reconstituted wood (4F) with metal liner plastics, expanded (4H1) plastics, solid (4H2) Dividing partitions in the outer packagings Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plastics (1H1, 1H2) Special packing provision: PP77 For UN Nos. 0248 and 0249, packagings shall be protected against the ingress of water. When water-activated contrivances are transported unpackaged, they shall be provided with at least two independent protective features which prevent the ingress of water. - 61 - P200 PACKING INSTRUCTION P200 Type of packagings: Cylinders, tubes, pressure drums and bundles of cylinders Cylinders, tubes, pressure drums and bundles of cylinders are authorised provided the special packing provisions of 4.1.6, the provisions listed below under (1) to (9) and, when referred to in the column "Special packing provisions" of tables 1, 2 or 3, the relevant special packing provisions listed below under (10), are met. General (1) Pressure receptacles shall be so closed and leakproof as to prevent escape of the gases; (2) Pressure receptacles containing toxic substances with an LC50 less than or equal to 200 ml/m3 (ppm) as specified in the table shall not be equipped with any pressure relief device. Pressure relief devices shall be fitted on UN pressure receptacles used for the carriage of UN No. 1013 carbon dioxide and UN No. 1070 nitrous oxide; (3) The following three tables cover compressed gases (Table 1), liquefied and dissolved gases (Table 2) and substances not in Class 2 (Table 3). They provide: (a) the UN number, name and description, and the classification code of the substance; (b) the LC50 for toxic substances; (c) the types of pressure receptacles authorised for the substance, shown by the letter "X"; (d) the maximum test period for periodic inspection of the pressure receptacles; NOTE: For pressure receptacles which make use of composite materials, the periodic inspection frequencies shall be as determined by the competent authority or body designated by this authority which issued the type approval. (e) the minimum test pressure of the pressure receptacles; (f) the maximum working pressure of the pressure receptacles for compressed gases or the maximum filling ratio(s) for liquefied and dissolved gases; (g) special packing provisions that are specific to a substance. Test pressure, filling ratios and filling requirements (4) The minimum test pressure required for is 1 MPa (10 bar); (5) In no case shall pressure receptacles be filled in excess of the limit permitted in the following requirements: (a) For compressed gases, the working pressure shall be not more than two thirds of the test pressure of the pressure receptacles. Restrictions to this upper limit on working pressure are imposed by special packing provision "o". In no case shall the internal pressure at 65 °C exceed the test pressure. (b) For high pressure liquefied gases, the filling ratio shall be such that the settled pressure at 65 °C does not exceed the test pressure of the pressure receptacles. The use of test pressures and filling ratios other than those in the table is permitted, except where special packing provision "o" applies, provided that: (i) (ii) the criterion of special packing provision "r" is met when applicable; or the above criterion is met in all other cases. For high pressure liquefied gases and gas mixtures for which relevant data are not available, the maximum filling ratio (FR) shall be determined as follows: FR = 8.5 10-4  dg  Ph where FR dg Ph = = = maximum filling ratio gas density (at 15 °C, 1 bar)(in kg/m3) minimum test pressure (in bar). (Cont'd on next page) - 62 - P200 PACKING INSTRUCTION (cont'd) P200 If the density of the gas is unknown, the maximum filling ratio shall be determined as follows: FR  where Ph  MM  10 3 R  338 FR = maximum filling ratio Ph = minimum test pressure (in bar) MM = molecular mass (in g/mol) R = 8.31451  10-2 bar.l.mol-1.K-1 (gas constant). For gas mixtures, the average molecular mass is to be taken, taking into account the volumetric concentrations of the various components. (c) For low pressure liquefied gases, the maximum mass of contents per litre of water capacity shall equal 0.95 times the density of the liquid phase at 50 °C; in addition, the liquid phase shall not fill the pressure receptacle at any temperature up to 60 °C. The test pressure of the pressure receptacle shall be at least equal to the vapour pressure (absolute) of the liquid at 65 °C, minus 100 kPa (1 bar). For low pressure liquefied gases and gas mixtures for which relevant data are not available, the maximum filling ratio shall be determined as follows: FR = (0.0032  BP – 0.24)  d1 where (d) FR = maximum filling ratio BP = boiling point (in Kelvin) d1 = density of the liquid at boiling point (in kg/l). For UN No. 1001 acetylene, dissolved, and UN No. 3374 acetylene, solvent free, see (10), special packing provision "p". (6) Other test pressure and filling ratio may be used provided they satisfy the general requirements outlined in paragraphs (4) and (5) above; (7) (a) The filling of pressure receptacles may only be carried out by specially-equipped centres, with qualified staff using appropriate procedures. The procedures should include checks: (b) – of the conformity to regulations of receptacles and accessories; – of their compatibility with the product to be carried; – of the absence of damage which might affect safety; – of compliance with the degree or pressure of filling, as appropriate; – of regulation markings and identification. LPG to be filled in cylinders shall be of high quality; this is deemed to be fulfilled if the LPG to be filled is in compliance with the limitations on corrosiveness as specified in ISO 9162:1989. Periodic inspections (8) Refillable pressure receptacles shall be subjected to periodic inspections in accordance with the requirements of 6.2.1.6 and 6.2.3.5 respectively. (9) If special provisions for certain substances do not appear in the tables below, periodic inspections shall be carried out: (a) Every 5 years in the case of pressure receptacles intended for the carriage of gases of classification codes 1T, 1TF, 1TO, 1TC, 1TFC, 1TOC, 2T, 2TO, 2TF, 2TC, 2TFC, 2TOC, 4A, 4F and 4TC; (b) Every 5 years in the case of pressure receptacles intended for the carriage of substances from other classes; (Cont'd on next page) - 63 - P200 PACKING INSTRUCTION (cont'd) P200 (c) Every 10 years in the case of pressure receptacles intended for the carriage of gases of classification codes 1A, 1O, 1F, 2A, 2O and 2F. By derogation from this paragraph, the periodic inspection of pressure receptacles which make use of composite materials (composite pressure receptacles) shall be carried out at intervals determined by the competent authority or body designated by this authority which issued the type approval. Special packing provisions (10) Material compatibility a: Aluminium alloy pressure receptacles shall not be used. b: Copper valves shall not be used. c: Metal parts in contact with the contents shall not contain more than 65% copper. d: When steel pressure receptacles are used, only those bearing the "H" mark in accordance with 6.2.2.7.4 (p) are permitted. Requirements for toxic substances with an LC50 less than or equal to 200 ml/m3 (ppm) k: Valve outlets shall be fitted with pressure retaining gas-tight plugs or caps having threads that match those of the valve outlets and made of material not liable to attack by the contents of the pressure receptacle. Each cylinder within a bundle shall be fitted with an individual valve that shall be closed during carriage. After filling, the manifold shall be evacuated, purged and plugged. Bundles containing UN 1045 Fluorine, compressed, may be constructed with isolation valves on groups of cylinders not exceeding 150 litres total water capacity instead of isolation valves on every cylinder. Cylinders and individual cylinders within a bundle shall have a test pressure greater than or equal to 200 bar and a minimum wall thickness of 3.5 mm for aluminium alloy or 2 mm for steel. Individual cylinders not complying with this requirement shall be carried in a rigid outer packaging that will adequately protect the cylinder and its fittings and meeting the packing group I performance level. Pressure drums shall have a minimum wall thickness as specified by the competent authority. Pressure receptacles shall not be fitted with a pressure relief device. Cylinders and individual cylinders in a bundle shall be limited to a maximum water capacity of 85 litres. Each valve shall be capable of withstanding the test pressure of the pressure receptacle and be connected directly to the pressure receptacle by either a taper thread or other means which meets the requirements of ISO 10692-2:2001. Each valve shall either be of the packless type with non-perforated diaphragm, or be of a type which prevents leakage through or past the packing. Carriage in capsules is not allowed. Each pressure receptacle shall be tested for leakage after filling. (Cont'd on next page) - 64 - P200 PACKING INSTRUCTION (cont'd) P200 Gas specific provisions l: UN No. 1040 ethylene oxide may also be packed in hermetically sealed glass or metal inner packagings suitably cushioned in fibreboard, wooden or metal boxes meeting the packing group I performance level. The maximum quantity permitted in any glass inner packaging is 30 g, and the maximum quantity permitted in any metal inner packaging is 200 g. After filling, each inner packaging shall be determined to be leak-tight by placing the inner packaging in a hot water bath at a temperature, and for a period of time, sufficient to ensure that an internal pressure equal to the vapour pressure of ethylene oxide at 55 °C is achieved. The maximum net mass in any outer packaging shall not exceed 2.5 kg. m: Pressure receptacles shall be filled to a working pressure not exceeding 5 bar. n: Cylinders and individual cylinders in a bundle shall contain not more than 5 kg of the gas. When bundles containing UN 1045 Fluorine, compressed are divided into groups of cylinders in accordance with special packing provision "k" each group shall contain not more than 5 kg of the gas. o: In no case shall the working pressure or filling ratio shown in the tables be exceeded. p: For UN No. 1001 acetylene, dissolved, and UN No. 3374 acetylene, solvent free: cylinders shall be filled with a homogeneous monolithic porous material; the working pressure and the quantity of acetylene shall not exceed the values prescribed in the approval or in ISO 3807-1:2000 or ISO 3807-2:2000, as applicable. For UN No. 1001 acetylene, dissolved: cylinders shall contain a quantity of acetone or suitable solvent as specified in the approval (see ISO 3807-1:2000 or ISO 3807-2:2000, as applicable); cylinders fitted with pressure relief devices or manifolded together shall be carried vertically. Alternatively, for UN No. 1001 acetylene, dissolved: cylinders which are not UN pressure receptacles may be filled with a non monolithic porous material; the working pressure, the quantity of acetylene and the quantity of solvent shall not exceed the values prescribed in the approval. The maximum test period for periodic inspection of the cylinders shall not exceed five years. A test pressure of 52 bar shall be applied only to cylinders conforming to ISO 3807-2:2000. q: Valve outlets of pressure receptacles for pyrophoric gases or flammable mixtures of gases containing more than 1% of pyrophoric compounds shall be fitted with gas-tight plugs or caps which shall be made of material not liable to attack by the contents of the pressure receptacle. When these pressure receptacles are manifolded in a bundle, each of the pressure receptacles shall be fitted with an individual valve that shall be closed during carriage, and the outlet of the manifold valve shall be fitted with a pressure retaining gas-tight plug or cap. Gas-tight plugs or caps shall have threads that match those of the valve outlets. Carriage in capsules is not allowed. r: The filling ratio of this gas shall be limited such that, if complete decomposition occurs, the pressure does not exceed two thirds of the test pressure of the pressure receptacle. ra: This gas may also be packed in capsules under the following conditions: (a) The mass of gas shall not exceed 150 g per capsule; (b) The capsules shall be free from faults liable to impair the strength; (c) The leakproofness of the closure shall be ensured by an additional device (cap, crown, seal, binding, etc.) capable of preventing any leakage of the closure during carriage; (d) The capsules shall be placed in an outer packaging of sufficient strength. A package shall not weigh more than 75 kg. (Cont'd on next page) - 65 - P200 PACKING INSTRUCTION (cont'd) s: P200 Aluminium alloy pressure receptacles shall be: - Equipped only with brass or stainless steel valves; and - Cleaned for hydrocarbons contamination and not contaminated with oil. UN pressure receptacles shall be cleaned in accordance with ISO 11621:1997. ta: Other criteria may be used for filling of welded steel cylinders intended for the carriage of substances of UN No. 1965: (a) with the agreement of the competent authorities of the countries where the carriage is carried out; and (b) in compliance with the provisions of a national code or standard recognised by the competent authorities. When the criteria for filling are different from those in P200(5), the transport document shall include the statement "Carriage in accordance with packing instruction P200, special packing provision ta" and the indication of the reference temperature used for the calculation of the filling ratio. Periodic inspection u: The interval between periodic tests may be extended to 10 years for aluminium alloy pressure receptacles. This derogation may only be applied to UN pressure receptacles when the alloy of the pressure receptacle has been subjected to stress corrosion testing as specified in ISO 7866:2012. ua: The interval between periodic tests may be extended to 15 years for aluminium alloy cylinders and bundles of such cylinders if the provisions of paragraph (13) of this packing instruction are applied. This shall not apply to cylinders made from aluminium alloy AA 6351. For mixtures, this provision "ua" may be applied provided all the individual gases in the mixture have been allocated "ua" in Table 1 or Table 2. v: (1) (2) va: The interval between inspections for steel cylinders, other than refillable welded steel cylinders for UN Nos. 1011, 1075, 1965, 1969 or 1978, may be extended to 15 years: (a) with the agreement of the competent authority (authorities) of the country (countries) where the periodic inspection and the carriage take place; and (b) in accordance with the requirements of a technical code or a standard recognised by the competent authority For refillable welded steel cylinders for UN Nos. 1011, 1075, 1965, 1969 or 1978, the interval may be extended to 15 years, if the provisions of paragraph (12) of this packing instruction are applied. For seamless steel cylinders which are equipped with residual pressure valves (RPVs) (see note below) that have been designed and tested in accordance with EN ISO 15996:2005 + A1:2007 and for bundles of seamless steel cylinders equipped with main valve(s) with a residual pressure device, tested in accordance with EN ISO 15996:2005 + A1:2007, the interval between periodic tests may be extended to 15 years if the provisions of paragraph (13) of this packing instruction are applied. For mixtures, this provision "va" may be applied provided all the individual gases in the mixture have been allocated "va" in Table 1 or Table 2. NOTE: "Residual Pressure Valve" (RPV) means a closure which incorporates a residual pressure device that prevents ingress of contaminants by maintaining a positive differential between the pressure within the cylinder and the valve outlet. In order to prevent back-flow of fluids into the cylinder from a higher pressure source a "Non-Return Valve" (NRV) function shall either be incorporated into the residual pressure device or be a discrete additional device in the cylinder valve, e.g. a regulator. Requirements for N.O.S. entries and for mixtures z: The construction materials of the pressure receptacles and their accessories shall be compatible with the contents and shall not react to form harmful or dangerous compounds therewith. The test pressure and filling ratio shall be calculated in accordance with the relevant requirements of (5). Toxic substances with an LC50 less than or equal to 200 ml/m3 shall not be carried in tubes, pressure drums or MEGCs and shall meet the requirements of special packing provision "k". However, UN 1975 Nitric oxide and dinitrogen tetroxide mixture may be carried in pressure drums. (Cont'd on next page) - 66 - P200 PACKING INSTRUCTION (cont'd) P200 For pressure receptacles containing pyrophoric gases or flammable mixtures of gases containing more than 1% pyrophoric compounds, the requirements of special packing provision "q" shall be met. The necessary steps shall be taken to prevent dangerous reactions (i.e. polymerisation or decomposition) during carriage. If necessary, stabilisation or addition of an inhibitor shall be required. Mixtures containing UN No. 1911 diborane, shall be filled to a pressure such that, if complete decomposition of the diborane occurs, two thirds of the test pressure of the pressure receptacle shall not be exceeded. Mixtures containing UN 2192 germane, other than mixtures of up to 35% germane in hydrogen or nitrogen or up to 28% germane in helium or argon, shall be filled to a pressure such that, if complete decomposition of the germane occurs, two thirds of the test pressure of the pressure receptacle shall not be exceeded. Requirements for substances not in Class 2 ab: Pressure receptacles shall satisfy the following conditions: (i) (ii) (iii) ac: ad: The pressure test shall include an inspection of the inside of the pressure receptacles and check of accessories; In addition resistance to corrosion shall be checked every two years by means of suitable instruments (e.g. ultrasound) and the condition of the accessories verified; Wall thickness shall not be less than 3 mm. Tests and inspections shall be carried out under the supervision of an expert approved by the competent authority. Pressure receptacles shall satisfy the following conditions: (i) (ii) Pressure receptacles shall be designed for a design pressure of not less than 2.1 MPa (21 bar) (gauge pressure); In addition to the marks for refillable receptacles, the pressure receptacles shall bear the following particulars in clearly legible and durable characters: - The UN number and the proper shipping name of the substance according to 3.1.2; - The maximum permitted mass when filled and the tare of the pressure receptacle, including accessories fitted during filling, or the gross mass. (11) The applicable requirements of this packing instruction are considered to have been complied with if the following standards, as relevant, are applied: Applicable requirements (7) Reference Title of document EN 1919:2000 (7) EN 1920:2000 (7) EN 13365:2002 +A1:2005 (7) and (10) ta (b) EN 1439:2008 (except 3.5 and Annex G) EN 14794:2005 Transportable gas cylinders. Cylinders for gases (excluding acetylene and LPG). Inspection at time of filling Transportable gas cylinders. Cylinders for compressed gases (excluding acetylene). Inspection at time of filling Transportable gas cylinders – Cylinder bundles for permanent and liquefied gases (excluding acetylene) – Inspection at the time of filling LPG equipment and accessories – Procedures for checking LPG cylinders before, during and after filling (7) and (10) ta (b) (10) p EN 12755:2000 (10) p EN ISO 11372:2011 EN ISO 13088:2012 (10) p LPG equipment and accessories - Transportable refillable aluminium cylinders for liquefied petroleum gas (LPG) - Procedure for checking before, during and after filling Transportable gas cylinders – Filling conditions for acetylene bundles Gas cylinders – Acetylene cylinders – Filling conditions and filling inspection (ISO 11372:2011) Gas cylinders - Acetylene cylinder bundles - Filling conditions and filling inspection (ISO 13088:2011) (Cont'd on next page) - 67 - P200 PACKING INSTRUCTION (cont'd) (12) An interval of 15 years for the periodic inspection of refillable welded steel cylinders may be granted in accordance with special packing provision v (2) of paragraph (10), if the following provisions are applied. 1. General provisions 1.1 For the application of this section, the competent authority shall not delegate its tasks and duties to Xb bodies (inspection bodies of type B) or IS bodies (in-house inspection services). 1.2 The owner of the cylinders shall apply to the competent authority for granting the 15 year interval, and shall demonstrate that the requirements of sub-paragraphs 2, 3 and 4 are met. 1.3 Cylinders manufactured since 1 January 1999 shall have been manufactured in conformity with the following standards: EN 1442; or EN 13322-1; or Annex I, parts 1 to 3 to Council Directive 84/527/EECa as applicable according to the table in 6.2.4. Other cylinders manufactured before 1 January 2009 in conformity with ADR in accordance with a technical code accepted by the national competent authority may be accepted for a 15 year interval, if they are of equivalent safety to the provisions of ADR as applicable at the time of application. 1.4 The owner shall submit documentary evidence to the competent authority demonstrating that the cylinders comply with the provisions of sub-paragraph 1.3. The competent authority shall verify that these conditions are met. 1.5 The competent authority shall check whether the provisions of sub-paragraphs 2 and 3 are fulfilled and correctly applied. If all provisions are fulfilled, it shall authorise the 15-year interval for the cylinders. In this authorisation, the type of cylinder (as specified in the type approval) or a group of cylinders (see Note) covered shall be clearly identified. The authorisation shall be delivered to the owner; the competent authority shall keep a copy. The owner shall keep the documents for as long as the cylinders are authorised for a 15 year interval. NOTE: A group of cylinders is defined by the production dates of identical cylinders for a period, during which the applicable provisions of ADR and of the technical code accepted by the competent authority have not changed in their technical content. Example: Cylinders of identical design and volume having been manufactured according to the provisions of ADR as applicable between 1 January 1985 and 31 December 1988 in combination with a technical code accepted by the competent authority applicable for the same period, form one group in terms of the provisions of this paragraph. 1.6 The competent authority shall monitor the owner of the cylinders for compliance with the provisions of ADR and the authorisation given as appropriate, but at least every three years or when changes to the procedures are introduced. 2. Operational provisions 2.1 Cylinders having been granted a 15 year interval for periodic inspection shall only be filled in filling centres applying a documented quality system to ensure that all the provisions of paragraph (7) of this packing instruction and the requirements and responsibilities of EN 1439:2008 are fulfilled and correctly applied. 2.2 The competent authority shall verify that these requirements are fulfilled and check this as appropriate, but at least every three years or when changes to the procedures are introduced. 2.3 The owner shall provide documentary evidence to the competent authority that the filling centre complies with the provisions of sub-paragraph 2.1. 2.4 If a filling centre is situated in a different Contracting Party to ADR, the owner shall provide additional documentary evidence that the filling centre is monitored accordingly by the competent authority of that Contracting Party to ADR. 2.5 To prevent internal corrosion, only gases of high quality with very low potential contamination shall be filled into the cylinders. This is deemed to be fulfilled, if the gases conform to the limitations on corrosiveness as specified in ISO 9162:1989. (Cont'd on next page) a P200 Council directive on the approximation of the laws of the Member States relating to welded unalloyed steel gas cylinders, published in the Official Journal of the European Communities No. L 300 of 19.11.1984. - 68 - P200 3. 4. (13) PACKING INSTRUCTION (cont'd) P200 Provisions for qualification and periodic inspection 3.1 Cylinders of a type or group already in use, for which a 15 year interval has been granted and to which the 15 year interval has been applied, shall be subject to a periodic inspection according to 6.2.3.5. NOTE: For the definition of a group of cylinders, see Note to sub-paragraph 1.5. 3.2 If a cylinder with a 15-year interval fails the hydraulic pressure test during a periodic inspection e.g. by bursting or leakage, the owner shall investigate and produce a report on the cause of the failure and if other cylinders (e.g. of the same type or group) are affected. In the latter case, the owner shall inform the competent authority. The competent authority shall then decide on appropriate measures and inform the competent authorities of all other Contracting Parties to ADR accordingly. 3.3 If internal corrosion as defined in the standard applied (see sub-paragraph 1.3) has been detected, the cylinder shall be withdrawn from use and shall not be granted any further period for filling and carriage. 3.4 Cylinders having been granted a 15 year interval shall only be fitted with valves designed and manufactured for a minimum 15 year period of use according to EN 13152:2001 + A1:2003, EN 13153:2001 + A1:2003, EN ISO 14245:2010 or EN ISO 15995:2010. After a periodic inspection, a new valve shall be fitted to the cylinder, except that manually operated valves, which have been refurbished or inspected according to EN 14912:2005 may be re-fitted, if they are suitable for another 15 year period of use. Refurbishment or inspection shall only be carried out by the manufacturer of the valves or according to his technical instruction by an enterprise qualified for such work and operating under a documented quality system. Marking Cylinders having been granted a 15 year interval for periodic inspection in accordance with this paragraph shall additionally be marked clearly and legibly with "P15Y". This marking shall be removed if the cylinder is no longer authorised for a 15 year interval. NOTE: This marking shall not apply to cylinders subject to the transitional provision in 1.6.2.9, 1.6.2.10 or the provisions of special packing provision v (1) of paragraph (10) of this packing instruction. An interval of 15 years for the periodic inspection of seamless steel and aluminium alloy cylinders and bundles of such cylinders may be granted in accordance with special packing provisions ua or va of paragraph (10), if the following provisions are applied: 1. General provisions 1.1 For the application of this paragraph, the competent authority shall not delegate its tasks and duties to Xb bodies (inspection bodies of type B) or IS bodies (in-house inspection services). 1.2 The owner of the cylinders or bundles of cylinders shall apply to the competent authority for granting the 15 year interval, and shall demonstrate that the requirements of sub-paragraphs 2, 3 and 4 are met. 1.3 Cylinders manufactured since 1 January 1999 shall have been manufactured in conformity with one of the following standards: - EN 1964-1 or EN 1964-2; or - EN 1975; or - EN ISO 9809-1 or EN ISO 9809-2; or - EN ISO 7866; or - Annex I, parts 1 to 3 to Council Directive 84/525/EECb and 84/526/EECc as applicable at the time of manufacture (see also the table in 6.2.4.1). (Cont'd on next page) b Council Directive on the approximation of the laws of the Member States relating to seamless, steel gas cylinders, published in the Official Journal of the European Communities No. L 300 of 19.11.1984. c Council Directive on the approximation of the laws of the Member States relating to seamless, unalloyed aluminium and aluminium alloy gas cylinders, published in the Official Journal of the European Communities No. L 300 of 19.11.1984. - 69 - P200 PACKING INSTRUCTION (cont'd) P200 Other cylinders manufactured before 1 January 2009 in conformity with ADR in accordance with a technical code accepted by the national competent authority may be accepted for a 15 year interval for periodic inspection, if they are of equivalent safety to the provisions of ADR as applicable at the time of application. NOTE: This provision is considered to be fulfilled if the cylinder has been reassessed according to the procedure for the reassessment of conformity described in Annex III of Directive 2010/35/EU of 16 June 2010 or Annex IV, Part II, of Directive 1999/36/EC of 29 April 1999. Cylinders and bundles of cylinders marked with the United Nations packaging symbol specified in 6.2.2.7.2 (a) shall not be granted a 15 year interval for periodic inspection. 1.4 Bundles of cylinders shall be constructed such that contact between cylinders along the longitudinal axis of the cylinders does not result in external corrosion. The supports and restraining straps shall be such as to minimise the risk of corrosion to the cylinders. Shock absorbent materials used in supports shall only be allowed if they have been treated to eliminate water absorption. Examples of suitable materials are water resistant belting and rubber. 1.5 The owner shall submit documentary evidence to the competent authority demonstrating that the cylinders comply with the provisions of sub-paragraph 1.3. The competent authority shall verify that these conditions are met. 1.6 The competent authority shall check whether the provisions of sub-paragraphs 2 and 3 are fulfilled and correctly applied. If all provisions are fulfilled, it shall authorise the 15 year interval for periodic inspection for the cylinders or bundles of cylinders. In this authorisation a group of cylinders (see NOTE below) covered shall be clearly identified. The authorisation shall be delivered to the owner; the competent authority shall keep a copy. The owner shall keep the documents for as long as the cylinders are authorised for a 15 year interval. 2. NOTE: A group of cylinders is defined by the production dates of identical cylinders for a period, during which the applicable provisions of ADR and of the technical code accepted by the competent authority have not changed in their technical content. Example: Cylinders of identical design and volume having been manufactured according to the provisions of ADR applicable between 1 January 1985 and 31 December 1988 in combination with a technical code accepted by the competent authority applicable for the same period form one group in terms of the provisions of this paragraph. 1.7 The owner shall ensure compliance with the provisions of ADR and the authorisation given as appropriate and shall demonstrate this to the competent authority on request but at least every three years or when significant changes to the procedures are introduced. Operational provisions 2.1 Cylinders or bundles of cylinders having been granted a 15 year interval for periodic inspection shall only be filled in filling centres applying a documented and certified quality system to ensure that all the provisions of paragraph (7) of this packing instruction and the requirements and responsibilities of EN 1919:2000, EN 1920:2000 or EN 13365:2002 as applicable are fulfilled and correctly applied. The quality system, according to the ISO 9000 (series) or equivalent, shall be certified by an accredited independent body recognized by the competent authority. This includes procedures for pre- and postfill inspections and the filling process for cylinders, bundles of cylinders and valves. 2.2 Aluminium alloy cylinders and bundles of such cylinders without RPVs having been granted a 15 year interval for periodic inspection shall be checked prior to every fill in accordance with a documented procedure which shall at least include the following:  Open the cylinder valve or the main valve of the bundle of cylinders to check for residual pressure;  If gas is emitted, the cylinder or bundle of cylinders may be filled;  If no gas is emitted, the internal condition of the cylinder or bundle of cylinders shall be checked for contamination;  If no contamination is detected, the cylinder or bundle of cylinders may be filled. If contamination is detected corrective action is to be carried out. (Cont'd on next page) - 70 - P200 3. 4. PACKING INSTRUCTION (cont'd) P200 2.3 Seamless steel cylinders fitted with RPVs and bundles of seamless steel cylinders equipped with main valve(s) with a residual pressure device having been granted a 15 year interval for periodic inspection shall be checked prior to every fill in accordance with a documented procedure which shall at least include the following:  Open the cylinder valve or bundle of cylinders main valve to check for residual pressure;  If gas is emitted, the cylinder or bundle of cylinders may be filled;  If no gas is emitted the functioning of the residual pressure device shall be checked;  If the check shows that the residual pressure device has retained pressure the cylinder or bundle of cylinders may be filled;  If the check shows that the residual pressure device has not retained pressure, the internal condition of the cylinder or bundle of cylinders shall be checked for contamination: If no contamination is detected, the cylinder or bundle of cylinders may be filled following repair or replacement of the residual pressure device; If contamination is detected, a corrective action shall be carried out. 2.4 To prevent internal corrosion, only gases of high quality with very low potential contamination shall be filled into cylinders or bundles of cylinders. This is deemed to be fulfilled, if the compatibility of gases/material is acceptable in accordance with EN ISO 11114-1:2012 and EN 11114-2:2013, and the gas quality meets the specifications in EN ISO 14175:2008 or, for gases not covered in the standard, a minimum purity of 99.5% by volume and a maximum moisture content of 40 ml/m3(ppm). For nitrous oxide the values shall be a minimum purity of 98% by volume and a maximum moisture content of 70 ml/m3 (ppm). 2.5 The owner shall ensure that the requirements of 2.1 to 2.4 are fulfilled and provide documentary evidence of this to the competent authority on request, but at least every three years or when significant changes to the procedures are introduced. 2.6 If a filling centre is situated in a different Contracting Party to ADR, the owner shall provide to the competent authority, on request, additional documentary evidence that the filling centre is monitored accordingly by the competent authority of that Contracting Party to ADR. See also 1.2. Provisions for qualification and periodic inspection 3.1 Cylinders and bundles of cylinders already in use, for which the conditions of sub-paragraph 2 have been met from the date of the last periodic inspection to the satisfaction of the competent authority, may have their inspection period extended to 15 years from the date of the last periodic inspection. Otherwise the change of test period from ten to fifteen years shall be made at the time of periodic inspection. The periodic inspection report shall indicate that this cylinder or bundle of cylinders shall be fitted with a residual pressure device as appropriate. Other documentary evidence may be accepted by the competent authority. 3.2 If a cylinder with a 15 year interval fails the pressure test by bursting or leakage or if a severe defect is detected by a non-destructive test (NDT) during a periodic inspection the owner shall investigate and produce a report on the cause of the failure and if other cylinders (e.g. of the same type or group) are affected. In the latter case, the owner shall inform the competent authority. The competent authority shall then decide on appropriate measures and inform the competent authorities of all other Contracting Parties to ADR accordingly. 3.3 If internal corrosion and other defects as defined in the periodic inspection standards referenced in 6.2.4 have been detected, the cylinder shall be withdrawn from use and shall not be granted any further period for filling and carriage. 3.4 Cylinders or bundles of cylinders having been granted a 15 year interval for periodic inspection shall only be fitted with valves designed and tested according to EN 849 or EN ISO 10297 as applicable at the time of manufacture (see also the table in 6.2.4.1). After a periodic inspection a new valve shall be fitted, except that valves which have been refurbished or inspected according to EN ISO 22434:2011 may be re-fitted. Marking Cylinders and bundles of cylinders having been granted a 15 year interval for periodic inspection in accordance with this paragraph shall have the date (year) of the next periodic inspection as required in section 5.2.1.6 (c) and at the same time additionally be marked clearly and legibly with "P15Y". This marking shall be removed if the cylinder or bundle of cylinders is no longer authorised for a 15 year interval for periodic inspection. (Cont'd on next page) - 71 - P200 PACKING INSTRUCTION (cont'd) P200 Bundles of cylinders Test period, years a 1A X X X X 10 ua, va 1006 ARGON, COMPRESSED 1A X X X X 10 ua, va 1016 CARBON MONOXIDE, COMPRESSED 1TF X X X X 5 u 1023 COAL GAS, COMPRESSED 1TF X X X X 5 1045 FLUORINE, COMPRESSED 1TOC X 5 1046 HELIUM, COMPRESSED 1A X X X X 10 ua, va 1049 HYDROGEN, COMPRESSED 1F X X X X 10 d, ua, va 1056 KRYPTON, COMPRESSED 1A X X X X 10 ua, va 1065 NEON, COMPRESSED 1A X X X X 10 ua, va 1066 NITROGEN, COMPRESSED 1A X X X X 10 ua, va 1071 OIL GAS, COMPRESSED 1TF X X X X 5 1072 OXYGEN, COMPRESSED 1O X X X X 10 s, ua, va 1612 HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE 1T X X X X 5 z 1660 NITRIC OXIDE, COMPRESSED 1TOC 115 X X 5 1953 COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. 1TF  5000 X X X X 5 z 1954 COMPRESSED GAS, FLAMMABLE, N.O.S 1F X X X X 10 z, ua, va 1955 COMPRESSED GAS, TOXIC, N.O.S. 1T X X X X 5 z 1956 COMPRESSED GAS, N.O.S. 1A X X X X 10 z, ua, va 1957 DEUTERIUM, COMPRESSED 1F X X X X 10 d, ua, va 1964 HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. 1F X X X X 10 z, ua, va 1971 METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content 1F X X X X 10 ua, va 2034 HYDROGEN AND METHANE MIXTURE, COMPRESSED 1F X X X X 10 d, ua, va 2190 OXYGEN DIFLUORIDE, COMPRESSED 1TOC X 5 3156 COMPRESSED GAS, OXIDIZING, N.O.S. 1O X 10 LC50 ml/m3 3760 185  5000 2.6 X X X - 72 - X X 200 225 200 30 33 30 Special packing provisions Pressure drums AIR, COMPRESSED Maximum working pressure, bar b Tubes 1002 Test pressure, bar b Name and description Classification code UN No. Cylinders Table 1: COMPRESSED GASES a, k, n, o k, o a, k, n, o z, ua, va P200 PACKING INSTRUCTION (cont'd) P200 Tubes Pressure drums Bundles of cylinders Test period, years a 1TO  5000 X X X X 5 z 3304 COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. 1TC  5000 X X X X 5 z 3305 COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 1TFC  5000 X X X X 5 z 3306 COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 1TOC  5000 X X X X 5 z a Not applicable for pressure receptacles made of composite materials. b Where the entries are blank, the working pressure shall not exceed two thirds of the test pressure. - 73 - Special packing provisions Cylinders COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. Name and description Maximum working pressure, bar b LC50 ml/m3 3303 UN No. Test pressure, bar b Classification code Table 1: COMPRESSED GASES P200 P200 PACKING INSTRUCTION (cont'd) Pressure drums Bundles of cylinders X X X X X X X 2A X X X X 10 2F X X X X 2F X X X 2F X X 2F 2F 2F 2F 2F 2A X X X X X X 10 60 29 225 300 42 120 250 10 0.54 0.715 0.86 1.13 1.44 1.60 0.59 X 10 10 0.55 ra X X 10 10 0.50 ra, v, z X X X X X X X X X X X X X X X X X X 10 10 10 10 10 10 X X X X X X 5 10 0.52 0.50 0.53 0.55 0.54 0.68 0.76 1.25 1.03 ra, v ra, z X X 10 10 10 10 10 190 250 22 27 ra, ua, va ra, ua, va a, ra ra 2A X X X X 10 25 1.05 ra 2A X X X X 10 11 1.20 ra 2A X X X X 10 X X X X X X X X X X X X 5 10 10 100 120 190 250 100 18 16 0.83 0.90 1.04 1.11 0.70 0.55 1.15 ra ra ra ra ra, u ra ra 2A X X X X 10 10 1.23 ra 2F X X X X 10 16 0.79 ra Name and description 1001 1005 1008 ACETYLENE, DISSOLVED AMMONIA, ANHYDROUS BORON TRIFLUORIDE 4F 2TC 2TC 1009 BROMOTRIFLUOROMETHANE (REFRIGERANT GAS R 13B1) 1010 BUTADIENES, STABILIZED (1,2-butadiene) or BUTADIENES, STABILIZED (1,3-butadiene) or BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED BUTANE BUTYLENES MIXTURES or 1-BUTYLENE or CIS-2-BUTYLENE or TRANS-2 BUTYLENE CARBON DIOXIDE 1010 1010 1011 1012 1012 1012 1012 1013 1017 1018 1020 1021 1022 1026 1027 1028 1029 1030 CHLORINE CHLORODIFLUOROMETHANE (REFRIGERANT GAS R 22) CHLOROPENTAFLUOROETHANE (REFRIGERANT GAS R 115) 1-CHLORO-1,2,2,2TETRAFLUOROETHANE (REFRIGERANT GAS R 124) CHLOROTRIFLUOROMETHANE (REFRIGERANT GAS R 13) 2TOC 2A CYANOGEN CYCLOPROPANE DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) DICHLOROFLUOROMETHANE (REFRIGERANT GAS R 21) 1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152a) 2TF 2F 2A 293 350 - 74 - Special packing provisions 10 5 5 UN No. Classification code Filling ratio Tubes X X X Test pressure, bar Cylinders 4000 387 Test period, years a LC50 ml/m3 Table 2: LIQUEFIED GASES AND DISSOLVED GASES c, p b, ra a ra ra ra ra P200 P200 PACKING INSTRUCTION (cont'd) 1048 Filling ratio Special packing provisions 2F X X X X 10 10 0.59 b, ra 2F 2F X X X X X X X X 10 10 2F 2F 2F 2TF X X X X X X X X X X X X X X X X 10 10 10 5 18 95 120 300 10 10 10 15 0.58 0.25 0.30 0.40 0.61 0.80 0.64 0.78 ra ra ra ra b, ra a, ra ra l, ra 2F X X X X 10 190 250 0.66 0.75 ra ra 4A X X X 5 LC50 ml/m3 Test pressure, bar 1043 Test period, years a 1041 ETHYLAMINE ETHYL CHLORIDE ETHYL METHYL ETHER ETHYLENE OXIDE, or ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1MPa (10 bar) at 50 °C ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide FERTILIZER AMMONIATING SOLUTION with free ammonia HYDROGEN BROMIDE, ANHYDROUS Bundles of cylinders 1036 1037 1039 1040 Pressure drums 1033 1035 DIMETHYLAMINE, ANHYDROUS DIMETHYL ETHER ETHANE Tubes 1032 Name and description Classification code UN No. Cylinders Table 2: LIQUEFIED GASES AND DISSOLVED GASES 2900 b, z 2TC 2860 X X X X 5 60 1.51 a, d, ra 100 120 150 200 48 10 0.30 0.56 0.67 0.74 0.67 0.52 a, d, ra a, d, ra a, d, ra a, d, ra d, ra, u ra ra 1050 HYDROGEN CHLORIDE, ANHYDROUS 2TC 2810 X X X X 5 1053 1055 1058 HYDROGEN SULPHIDE ISOBUTYLENE LIQUEFIED GASES, nonflammable, charged with nitrogen, carbon dioxide or air METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED Propadiene with 1% to 4% methylacetylene Mixture P1 Mixture P2 METHYLAMINE, ANHYDROUS METHYL BROMIDE with not more than 2% chloropicrin METHYL CHLORIDE (REFRIGERANT GAS R 40) 2TF 2F 2A 712 X X X X X X X X X X X X 5 10 10 2F X X X X 10 2F X X X X 10 22 0.52 c, ra 2F 2F 2F X X X X X X X X X X X X 10 10 10 30 24 13 0.49 0.47 0.58 c, ra c, ra b, ra X X X X 5 10 1.51 a X X X X 10 17 0.81 a, ra 1060 1061 1062 1063 2T 850 2F - 75 - c, ra, z P200 P200 PACKING INSTRUCTION (cont'd) 1083 1085 1086 1087 1581 1582 1589 1741 1749 1858 5 5 10 10 0.78 1.30 d, ra, u k X X X X 5 10 13 180 225 250 1.10 0.68 0.74 0.75 X X X X 10 k, ra ua, va ua, va ua, va v, z X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X 5 10 10 10 10 10 5 10 20 27 1.23 0.43 a, k, ra ra ra, z 1.23 1.15 1.03 1.23 1.06 1.34 1.38 X X X X 10 12 18 29 12 70 140 160 200 X X X X 5 19 1.13 ra, u 2F X X X X 10 10 0.56 b, ra 2F X X X X 10 10 1.37 a, ra 2F X X X X 10 12 0.81 a, ra 2F X X X X 10 10 0.67 ra METHYL MERCAPTAN DINITROGEN TETROXIDE (NITROGEN DIOXIDE) NITROSYL CHLORIDE NITROUS OXIDE 2TF 2TOC 1350 115 X X 2TC 2O 35 X X PETROLEUM GASES, LIQUEFIED PHOSGENE PROPYLENE REFRIGERANT GAS, N.O.S. Mixture F1 Mixture F2 Mixture F3 SULPHUR DIOXIDE SULPHUR HEXAFLUORIDE 2F Name and description TETRAFLUOROETHYLENE, STABILIZED TRIFLUOROCHLOROETHYLENE, STABILIZED (REFRIGERANT GAS R1113) TRIMETHYLAMINE, ANHYDROUS VINYL BROMIDE, STABILIZED VINYL CHLORIDE, STABILIZED VINYL METHYL ETHER, STABILIZED CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more than 2% chloropicrin CHLOROPICRIN AND METHYL CHLORIDE MIXTURE CYANOGEN CHLORIDE, STABILIZED BORON TRICHLORIDE CHLORINE TRIFLUORIDE HEXAFLUOROPROPYLENE (REFRIGERANT GAS R 1216) 2TC 2F 2A 2A 2A 2A 2TC 2A 5 2520 2F 2TF 2000 Tubes Special packing provisions 1082 Filling ratio 1081 Test pressure, bar 1079 1080 Test period, years a 1076 1077 1078 Bundles of cylinders 1075 X X Cylinders 1069 1070 X X LC50 ml/m3 1064 1067 Classification code UN No. Pressure drums Table 2: LIQUEFIED GASES AND DISSOLVED GASES X ra ra, ua, va ra, ua, va ra, ua, va m, o, ra 2T 850 X X X X 5 10 1.51 a 2T d X X X X 5 17 0.81 a 2TC 80 X X 5 20 1.03 k 2TC 2TOC 2A 2541 299 X X X X X X 5 5 10 10 30 22 1.19 1.40 1.11 a, ra a ra - 76 - X X X X X X P200 P200 PACKING INSTRUCTION (cont'd) Pressure drums Bundles of cylinders X X X X X X X X X X X 2A X X 2A X 2F 10 200 300 250 0.74 1.10 0.64 a, ra X X 5 10 250 17 0.07 0.81 d, k, o a, ra X X 10 190 250 0.66 0.75 ra ra X X X 10 10 1.30 ra X X X X 10 250 0.77 ra 2F X X X X 10 225 300 0.34 0.38 2F X X X X 10 Name and description 1859 SILICON TETRAFLUORIDE 2TC 1860 VINYL FLUORIDE, STABILIZED DIBORANE METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide 1,2-DICHLORO-1,1,2,2TETRAFLUOROETHANE (REFRIGERANT GAS R 114) 1,1-DIFLUOROETHYLENE (REFRIGERANT GAS R 1132a) ETHYLENE 2F 1911 1912 1952 1958 1959 1962 1965 1967 1968 1969 1973 1974 HYDROCARBON GAS MIXTURE, LIQUEFIED,N.O.S Mixture A Mixture A01 Mixture A02 Mixture A0 Mixture A1 Mixture B1 Mixture B2 Mixture B Mixture C INSECTICIDE GAS, TOXIC, N.O.S. INSECTICIDE GAS, N.O.S. ISOBUTANE CHLORODIFLUOROMETHANE AND CHLOROPENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502) CHLORODIFLUOROBROMOMETHANE (REFRIGERANT GAS R 12B1) 2TF 2F 80 b a ra, ta, v, z 2F 2F 2F 2F 2F 2F 2F 2F 2F 2T X X X X 10 10 10 10 10 10 10 10 10 5 2A 2F 2A X X X X X X X X X X X X 10 10 10 10 31 0.49 1.01 ra, z ra, v ra 2A X X X X 10 10 1.61 ra - 77 - 10 15 15 15 20 25 25 25 30 Special packing provisions 5 UN No. Classification code Filling ratio Tubes X Test pressure, bar Cylinders 450 Test period, years a LC50 ml/m3 Table 2: LIQUEFIED GASES AND DISSOLVED GASES 0.50 0.49 0.48 0.47 0.46 0.45 0.44 0.43 0.42 z P200 P200 PACKING INSTRUCTION (cont'd) 1976 1978 1982 1983 1984 2035 2036 2044 2073 2188 2189 2191 2192 2193 2199 SULPHURYL FLUORIDE GERMANE c HEXAFLUOROETHANE (REFRIGERANT GAS R 116) SELENIUM HEXAFLUORIDE TELLURIUM HEXAFLUORIDE TUNGSTEN HEXAFLUORIDE HYDROGEN IODIDE, ANHYDROUS PHOSPHORUS PENTAFLUORIDE PHOSPHINE c 2200 PROPADIENE, STABILIZED 2194 2195 2196 2197 2198 5 Special packing provisions X Filling ratio X Test pressure, bar Test period, years a X Bundles of cylinders 115 Tubes 2TOC Pressure drums NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE (NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE) OCTAFLUOROCYCLOBUTANE (REFRIGERANT GAS RC 318) PROPANE TETRAFLUOROMETHANE (REFRIGERANT GAS R 14) 1-CHLORO-2,2,2TRIFLUOROETHANE (REFRIGERANT GAS R 133a) TRIFLUOROMETHANE (REFRIGERANT GAS R 23) 1,1,1-TRIFLUOROETHANE (REFRIGERANT GAS R 143a) XENON 2,2-DIMETHYLPROPANE AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 35% but not more than 40% ammonia with more than 40% but not more than 50% ammonia ARSINE DICHLOROSILANE Cylinders 1975 Name and description LC50 ml/m3 UN No. Classification code Table 2: LIQUEFIED GASES AND DISSOLVED GASES k, z 2.A X X X X 10 11 1.32 ra 2F 2A X X X X X X X X 10 10 X X X X 10 0.43 0.71 0.90 1.18 ra, v 2A 23 200 300 10 2A X X X X 10 2F X X X X 10 190 250 35 0.88 0.96 0.73 ra ra ra 2A 2F 4A X X X X X X X X 10 10 130 10 1.28 0.53 ra 4A X X X X 5 10 0.80 b 4A X X X X 5 12 0.77 b 1.10 0.90 1.08 1.10 0.064 1.13 d, k a ra 2TF 2TFC 20 314 X X X X X X 5 5 2T 2TF 2A 3020 620 X X X X X X X X X X X X 5 5 10 42 10 200 50 250 200 2TC 50 X X 5 36 1.46 k, ra 2TC 25 X X 5 20 1.00 k, ra 2TC 160 X X 5 10 3.08 a, k, ra 2TC 2860 X X 5 23 2.25 a, d, ra 2TC 190 X X 5 2TF 20 X X 5 X 10 200 300 225 250 22 0.90 1.25 0.30 0.45 0.50 k k d, k, q, ra d, k, q, ra ra 2F X - 78 - X X X X u d, ra, r, q P200 P200 PACKING INSTRUCTION (cont'd) 2418 2419 2676 SULPHUR TETRAFLUORIDE BROMOTRIFLUOROETHYLENE HEXAFLUOROACETONE NITROGEN TRIOXIDE OCTAFLUOROBUT-2-ENE (REFRIGERANT GAS R 1318) OCTAFLUOROPROPANE (REFRIGERANT GAS R 218) NITROGEN TRIFLUORIDE ETHYLACETYLENE, STABILIZED ETHYL FLUORIDE (REFRIGERANT GAS R 161) METHYL FLUORIDE (REFRIGERANT GAS R 41) METHYL NITRITE 1-CHLORO-1,1DIFLUOROETHANE (REFRIGERANT GAS R 142b) METHYLCHLOROSILANE CHLORINE PENTAFLUORIDE CHLOROTRIFLUOROMETHANE AND TRIFLUOROMETHANE AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane (REFRIGERANT GAS R 503) CYCLOBUTANE DICHLORODIFLUOROMETHANE AND DIFLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane (REFRIGERANT GAS R 500) STIBINE 2901 BROMINE CHLORIDE 2420 2421 2422 2424 2451 2452 2453 2454 2455 2517 2534 2548 2599 2601 2602 Special packing provisions 2TF 2TC Filling ratio CARBONYL SULPHIDE CARBONYL FLUORIDE Test pressure, bar 2204 2417 2F Test period, years a X Bundles of cylinders Cylinders 2 2202 Name and description Pressure drums LC50 ml/m3 2TF 2203 HYDROGEN SELENIDE, ANHYDROUS SILANE c UN No. Tubes Classification code Table 2: LIQUEFIED GASES AND DISSOLVED GASES X 5 31 1.60 k 225 250 30 200 300 30 10 0.32 0.36 0.87 0.47 0.70 0.91 1.19 q q ra, u X X X X 10 1700 360 X X X X X X X X 5 5 2TC 2F 40 X X X X X X 5 10 2TC 2TOC 2A 470 X X a, k, ra ra X X X 5 22 1.08 CARRIAGE PROHIBITED X X X 10 12 1.34 ra 2A X X X X 10 25 1.04 ra 2O 2F X X X X X X X X 10 10 200 10 0.50 0.57 c, ra 2F X X X X 10 30 0.57 ra 2F X X X X 10 300 0.63 ra 2A 2F X X CARRIAGE PROHIBITED X X 10 10 0.99 ra X X X X X 2TFC 2TOC 600 122 2A 2F 2A X X 2TF 20 X 2TOC 290 X - 79 - X X X X X X X X ra X X 5 5 13 1.49 ra, z a, k X 10 31 0.12 ra 42 0.17 ra 100 0.64 ra X X 10 10 10 22 0.63 1.01 ra ra X 5 200 0.49 X 5 10 1.50 k, ra, r a P200 P200 PACKING INSTRUCTION (cont'd) 3070 3083 3153 3154 3157 3159 3160 3161 3162 3163 3220 3252 3296 3297 3298 3299 3300 3307 2A Test period, years a Test pressure, bar Filling ratio Special packing provisions X Bundles of cylinders 10 Tubes 2TC Pressure drums TRIFLUOROACETYL CHLORIDE ETHYLENE OXIDE AND DICHLORODIFLUOROMETHANE MIXTURE with not more than 12,5% ethylene oxide PERCHLORYL FLUORIDE PERFLUORO(METHYL VINYL ETHER) PERFLUORO(ETHYL VINYL ETHER) LIQUEFIED GAS, OXIDIZING, N.O.S. 1,1,1,2TETRAFLUOROETHANE (REFRIGERANT GAS R 134a) LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. LIQUEFIED GAS, FLAMMABLE, N.O.S. LIQUEFIED GAS, TOXIC, N.O.S. LIQUEFIED GAS, N.O.S. PENTAFLUOROETHANE (REFRIGERANT GAS R 125) DIFLUOROMETHANE (REFRIGERANT GAS R 32) HEPTAFLUOROPROPANE (REFRIGERANT GAS R 227) ETHYLENE OXIDE AND CHLOROTETRAFLUOROETHANE MIXTURE with not more than 8.8% ethylene oxide ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than 7.9% ethylene oxide ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more than 5.6% ethylene oxide ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxide LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. Cylinders 3057 Name and description LC50 ml/m3 UN No. Classification code Table 2: LIQUEFIED GASES AND DISSOLVED GASES X X 5 17 1.17 k, ra X X X X 10 18 1.09 ra X X X X X X X X 5 10 33 20 1.21 0.75 u ra 2F X X X X 10 10 0.98 ra 2O X X X X 10 2A X X X X 10 X X X X 5 ra, z X X X X 10 ra, z X X X X 5 z 2A 2A X X X X X X X X 10 10 2F X X X X 2A X X X 2A X X 2A X 2A 2TO 2F 2TF 770  5000 2F 2T  5000 18 1.05 ra 10 49 35 48 0.95 0.87 0.78 ra, z ra ra ra X 10 13 1.21 ra X X 10 10 1.16 ra X X X 10 26 1.02 ra X X X X 10 17 1.03 ra 28 0.73 ra 2TF More than 2900 X X X X 5 2TO  5000 X X X X 5 - 80 - z z P200 P200 PACKING INSTRUCTION (cont'd) 3338 3339 3340 3354 3355 3374 a X X X X 5 ra, z 2TFC  5000 X X X X 5 ra, z 2TOC  5000 X X X X 5 z 4TC X X X X 5 b 2A X X X X 10 36 0.82 ra 2A X X X X 10 32 0.94 ra 2A X X X X 10 33 0.93 ra 2A X X X X 10 30 0.95 ra 2F X X X X 10 ra, z 2TF X X X X 5 ra, z 2F X X 5 Not applicable for pressure receptacles made of composite materials. - 81 - 60 Special packing provisions  5000 Filling ratio 2TC Test pressure, bar Test period, years a 3337 Bundles of cylinders 3318 Pressure drums 3310 Tubes 3309 LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia REFRIGERANT GAS R 404A (Pentafluoroethane, 1,1,1trifluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 44% pentafluoroethane and 52% 1,1,1-trifluoroethane) REFRIGERANT GAS R 407A (Difluoromethane, pentafluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 20% difluoromethane and 40% pentafluoroethane) REFRIGERANT GAS R 407B (Difluoromethane, pentafluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 10% difluoromethane and 70% pentafluoroethane REFRIGERANT GAS R 407C (Difluoromethane, pentafluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 23% difluoromethane and 25% pentafluoroethane) INSECTICIDE GAS, FLAMMABLE, N.O.S INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. ACETYLENE, SOLVENT FREE Cylinders 3308 Name and description LC50 ml/m3 UN No. Classification code Table 2: LIQUEFIED GASES AND DISSOLVED GASES c, p b For mixtures of UN No. 1965, the maximum permissible filling mass per litre of capacity is as follows: Commercial propane Commercial butane Maximum permissible mass of contents per litre of capacity 0.50 A 0.49 A01 0.48 A02 0.47 A0 0.46 A1 0.45 B1 0.44 B2 0.43 0.42 B C 0.440 0.450 0.463 0.474 0.485 0.495 0.505 0.516 0.525 Density at 50 °C in kg/l c Considered as pyrophoric. d Considered to be toxic. The LC50 value still to be determined. - 82 - P200 P200 PACKING INSTRUCTION (cont'd) Test period, years a Test pressure, bar Filling ratio Special packing provisions X X 5 10 0.84 X X X 5 10 b 50 X X X 5 10 b CT1 966 X X X 5 10 0.84 a, ab, ac k, ab, ad k, ab, ad ab, ac OTC 120 X X X 5 10 b 6.1 TF1 40 X 8 CT1 966 X BROMINE PENTAFLUORIDE BROMINE TRIFLUORIDE 5.1 OTC 25 5.1 OTC 1790 HYDROFLUORIC ACID, solution, with more than 85% hydrofluoric acid 8 2495 IODINE PENTAFLUORIDE 5.1 Name and description 1051 1052 1745 1746 a Not applicable for pressure receptacles made of composite materials. b A minimum ullage of 8% by volume is required. PACKING INSTRUCTION P201 This instruction applies to UN Nos. 3167, 3168 and 3169. The following packagings are authorized: (1) (2) Pressure drums k HYDROGEN CYANIDE, STABILIZED containing less than 3% water HYDROGEN FLUORIDE, ANHYDROUS UN No. Tubes 0.55 Cylinders 100 LC50 ml/m3 5 Classification Code X Class Bundles of cylinders Table 3: SUBSTANCES NOT IN CLASS 2 k, ab, ad P201 Cylinders and gas receptacles conforming to the construction, testing and filling requirements approved by the competent authority. The following combination packagings provided that the general provisions of 4.1.1 and 4.1.3 are met: Outer packagings: Drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A1, 3A2, 3B1, 3B2, 3H1, 3H2). Inner packagings: (a) For non-toxic gases, hermetically sealed inner packagings of glass or metal with a maximum capacity of 5 litres per package; (b) For toxic gases, hermetically sealed inner packagings of glass or metal with a maximum capacity of 1 litre per package. Packagings shall conform to the packing group III performance level. - 83 - P202 PACKING INSTRUCTION P202 (Reserved) P203 PACKING INSTRUCTION P203 This instruction applies to Class 2 refrigerated liquefied gases. Requirements for closed cryogenic receptacles: (1) The special packing provisions of 4.1.6 shall be met. (2) The requirements of Chapter 6.2 shall be met. (3) The closed cryogenic receptacles shall be so insulated that they do not become coated with frost. (4) Test pressure Refrigerated liquids shall be filled in closed cryogenic receptacles with the following minimum test pressures: (a) For closed cryogenic receptacles with vacuum insulation, the test pressure shall not be less than 1.3 times the sum of the maximum internal pressure of the filled receptacle, including during filling and discharge, plus 100 kPa (1 bar); (b) For other closed cryogenic receptacles, the test pressure shall be not less than 1.3 times the maximum internal pressure of the filled receptacle, taking into account the pressure developed during filling and discharge. (5) Degree of filling For non-flammable, non-toxic refrigerated liquefied gases (classification codes 3A and 3O) the volume of liquid phase at the filling temperature and at a pressure of 100 kPa (1 bar) shall not exceed 98% of the water capacity of the pressure receptacle. For flammable refrigerated liquefied gases (classification code 3F) the degree of filling shall remain below the level at which, if the contents were raised to the temperature at which the vapour pressure equalled the opening pressure of the relief valve, the volume of the liquid phase would reach 98% of the water capacity at that temperature. (6) Pressure-relief devices Closed cryogenic receptacles shall be fitted with at least one pressure-relief device. (7) Compatibility Materials used to ensure the leakproofness of the joints or for the maintenance of the closures shall be compatible with the contents. In the case of receptacles intended for the carriage of oxidizing gases (classification code 3O), these materials shall not react with these gases in a dangerous manner. (8) Periodic inspection (a) The periodic inspection and test frequencies of pressure relief valves in accordance with 6.2.1.6.3 shall not exceed five years. (b) The periodic inspection and test frequencies of non-UN closed cryogenic receptacles in accordance with 6.2.3.5.2 shall not exceed 10 years. (Cont'd on next page) - 84 - P203 PACKING INSTRUCTION (cont'd) P203 Requirements for open cryogenic receptacles: Only the following non oxidizing refrigerated liquefied gases of classification code 3A may be carried in open cryogenic receptacles: UN Nos. 1913, 1951, 1963, 1970, 1977, 2591, 3136 and 3158. Open cryogenic receptacles shall be constructed to meet the following requirements: (1) The receptacles shall be designed, manufactured, tested and equipped in such a way as to withstand all conditions, including fatigue, to which they will be subjected during their normal use and during normal conditions of carriage. (2) The capacity shall be not more than 450 litres. (3) The receptacle shall have a double wall construction with the space between the inner and outer wall being evacuated (vacuum insulation). The insulation shall prevent the formation of hoar frost on the exterior of the receptacle. (4) The materials of construction shall have suitable mechanical properties at the service temperature. (5) Materials which are in direct contact with the dangerous goods shall not be affected or weakened by the dangerous goods intended to be carried and shall not cause a dangerous effect, e.g. catalysing a reaction or reacting with the dangerous goods. (6) Receptacles of glass double wall construction shall have an outer packaging with suitable cushioning or absorbent materials which withstand the pressures and impacts liable to occur under normal conditions of carriage. (7) The receptacle shall be designed to remain in an upright position during carriage, e.g. have a base whose smaller horizontal dimension is greater than the height of the centre of gravity when filled to capacity or be mounted on gimbals. (8) The openings of the receptacles shall be fitted with devices allowing gases to escape, preventing any splashing out of liquid, and so configured that they remain in place during carriage. (9) Open cryogenic receptacles shall bear the following marks permanently affixed e.g. by stamping, engraving or etching: The manufacturer’s name and address; The model number or name; The serial or batch number; The UN number and proper shipping name of gases for which the receptacle is intended; The capacity of the receptacle in litres. P204 PACKING INSTRUCTION (Deleted) - 85 - P204 P205 PACKING INSTRUCTION P205 This instruction applies to UN No. 3468. (1) For metal hydride storage systems, the special packing provisions of 4.1.6 shall be met. (2) Only pressure receptacles not exceeding 150 litres in water capacity and having a maximum developed pressure not exceeding 25 MPa are covered by this packing instruction. (3) Metal hydride storage systems meeting the applicable requirements for the construction and testing of pressure receptacles containing gas of Chapter 6.2 are authorised for the carriage of hydrogen only. (4) When steel pressure receptacles or composite pressure receptacles with steel liners are used, only those bearing the "H" mark, in accordance with 6.2.2.9.2 (j) shall be used. (5) Metal hydride storage systems shall meet the service conditions, design criteria, rated capacity, type tests, batch tests, routine tests, test pressure, rated charging pressure and provisions for pressure relief devices for transportable metal hydride storage systems specified in ISO 16111:2008 (Transportable gas storage devices – Hydrogen absorbed in reversible metal hydride) and their conformity and approval shall be assessed in accordance with 6.2.2.5. (6) Metal hydride storage systems shall be filled with hydrogen at a pressure not exceeding the rated charging pressure shown in the permanent markings on the system as specified by ISO 16111:2008. (7) The periodic test requirements for a metal hydride storage system shall be in accordance with ISO 16111:2008 and carried out in accordance with 6.2.2.6, and the interval between periodic inspections shall not exceed five years. P206 PACKING INSTRUCTION P206 This instruction applies to UN Nos. 3500, 3501, 3502, 3503, 3504 and 3505. Unless otherwise indicated in ADR, cylinders and pressure drums conforming to the applicable requirements of Chapter 6.2 are authorized. (1) The special packing provisions of 4.1.6 shall be met. (2) The maximum test period for periodic inspection shall be 5 years. (3) Cylinders and pressure drums shall be so filled that at 50 °C the non-gaseous phase does not exceed 95% of their water capacity and they are not completely filled at 60 °C. When filled, the internal pressure at 65 °C shall not exceed the test pressure of the cylinders and pressure drums. The vapour pressures and volumetric expansion of all substances in the cylinders and pressure drums shall be taken into account. (4) The minimum test pressure shall be in accordance with packing instruction P200 for the propellant but shall not be less than 20 bar. Additional requirement: Cylinders and pressure drums shall not be offered for carriage when connected with spray application equipment such as a hose and wand assembly. Special packing provision: PP89 For UN Nos. 3501, 3502, 3503, 3504 and 3505, notwithstanding 4.1.6.9 (b), non-refillable cylinders used may have a water capacity in litres not exceeding 1 000 litres divided by the test pressure expressed in bars provided capacity and pressure restrictions of the construction standard comply with ISO 11118:1999, which limits the maximum capacity to 50 litres. - 86 - P207 PACKING INSTRUCTION P207 This instruction applies to UN No. 1950. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (a) Drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2). Packagings shall conform to the packing group II performance level. (b) Rigid outer packagings with a maximum net mass as follows: Fibreboard 55 kg Other than fibreboard 125 kg The provisions of 4.1.1.3 need not be met. The packagings shall be designed and constructed to prevent movement of the aerosols and inadvertent discharge during normal conditions of carriage. Special packing provision: PP87 For UN 1950 waste aerosols carried in accordance with special provision 327, the packagings shall have a means of retaining any free liquid that might escape during carriage, e.g. absorbent material. The packagings shall be adequately ventilated to prevent the creation of flammable atmosphere and the build-up of pressure. Special packing provision specific to RID and ADR RR6 For UN 1950 in the case of carriage by full load, metal articles may also be packed as follows: The articles shall be grouped together in units on trays and held in position with an appropriate plastics cover; these units shall be stacked and suitably secured on pallets. - 87 - P208 PACKING INSTRUCTION This instruction applies to Class 2 adsorbed gases. (1) P208 The following packagings are authorized provided the general packing requirements of 4.1.6.1 are met: Cylinders specified in Chapter 6.2 and in accordance with ISO 11513:2011 or ISO 9809-1:2010. (2) The pressure of each filled cylinder shall be less than 101.3 kPa at 20 C and less than 300 kPa at 50 C. (3) The minimum test pressure of the cylinder shall be 21 bar. (4) The minimum burst pressure of the cylinder shall be 94.5 bar. (5) The internal pressure at 65 C of the filled cylinder shall not exceed the test pressure of the cylinder. (6) The adsorbent material shall be compatible with the cylinder and shall not form harmful or dangerous compounds with the gas to be adsorbed. The gas in combination with the adsorbent material shall not affect or weaken the cylinder or cause a dangerous reaction (e.g. a catalyzing reaction). (7) The quality of the adsorbent material shall be verified at the time of each fill to ensure that the pressure and chemical stability requirements of this packing instruction are met each time an adsorbed gas package is offered for carriage. (8) The adsorbent material shall not meet the criteria of any of the classes in ADR. (9) Requirements for cylinders and closures containing toxic gases with an LC50 less than or equal to 200 ml/m3 (ppm) (see Table 1) shall be as follows: (a) Valve outlets shall be fitted with pressure retaining gas-tight plugs or caps having threads matching those of the valve outlets. (b) Each valve shall either be of the packless type with non-perforated diaphragm, or be of a type which prevents leakage through or past the packing. (c) Each cylinder and closure shall be tested for leakage after filling. (d) Each valve shall be capable of withstanding the test pressure of the cylinder and be directly connected to the cylinder by either a taper-thread or other means which meets the requirements of ISO 10692-2:2001. (e) Cylinders and valves shall not be fitted with a pressure relief device. (10) Valve outlets for cylinders containing pyrophoric gases shall be fitted with gas-tight plugs or caps having threads matching those of the valve outlets. (11) The filling procedure shall be in accordance with Annex A of ISO 11513:2011. (12) (13) The maximum period for periodic inspections shall be 5 years. Special packing provisions that are specific to a substance (see Table 1). Material compatibility a: Aluminium alloy cylinders shall not be used. d: When steel cylinders are used, only those bearing the "H" mark in accordance with 6.2.2.7.4 (p) are permitted. Gas specific provisions r: The filling of this gas shall be limited such that, if complete decomposition occurs, the pressure does not exceed two thirds of the test pressure of the cylinder. Material compatibility for n.o.s. adsorbed gas entries z: The construction materials of the cylinders and their accessories shall be compatible with the contents and shall not react to form harmful or dangerous compounds therewith. (Cont'd on next page) - 88 - P208 PACKING INSTRUCTION (cont'd) Table 1: ADSORBED GASES UN No. Name and description P208 Classification code LC50 ml/m3 Special packing provisions 3510 ADSORBED GAS, FLAMMABLE, N.O.S. 9F z 3511 ADSORBED GAS, N.O.S. 9A z 3512 ADSORBED GAS, TOXIC, N.O.S. 9T 3513 ADSORBED GAS, OXIDIZING, N.O.S. 9O 3514 ADSORBED GAS, TOXIC, FLAMMABLE, N.O.S. 9TF ≤ 5000 z 3515 ADSORBED GAS, TOXIC, OXIDIZING, N.O.S. 9TO ≤ 5000 z 3516 ADSORBED GAS, TOXIC, CORROSIVE, N.O.S. ADSORBED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 9TC ≤ 5000 z 9TFC ≤ 5000 z 9TOC ≤ 5000 z 3517 3518 ≤ 5000 z z 3519 BORON TRIFLUORIDE, ADSORBED 9TC 387 a 3520 CHLORINE, ADSORBED 9TOC 293 a 3521 SILICON TETRAFLUORIDE, ADSORBED 9TC 450 a 3522 ARSINE, ADSORBED 9TF 20 d 3523 GERMANE, ADSORBED 9TF 620 d, r 3524 PHOSPHORUS PENTAFLUORIDE, ADSORBED 9TC 190 3525 PHOSPHINE, ADSORBED 9TF 20 3526 HYDROGEN SELENIDE, ADSORBED 9TF 2 d P209 PACKING INSTRUCTION P209 This packing instruction applies to UN No. 3150 devices, small, hydrocarbon gas powered or hydrocarbon gas refills for small devices (1) The special packing provisions of 4.1.6 when applicable shall be met. (2) The articles shall comply with the provisions of the country in which they were filled. (3) The devices and refills shall be packed in outer packagings conforming to 6.1.4 tested and approved in accordance with Chapter 6.1 for packing group II. P300 PACKING INSTRUCTION This instruction applies to UN No. 3064. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: P300 Combination packagings consisting of inner metal cans of not more than 1 litre capacity each and outer wooden boxes (4C1, 4C2, 4D or 4F) containing not more than 5 litres of solution. Additional requirements: 1. Metal cans shall be completely surrounded with absorbent cushioning material. 2. Wooden boxes shall be completely lined with suitable material impervious to water and nitroglycerin. - 89 - P301 PACKING INSTRUCTION This instruction applies to UN No. 3165. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: P301 (1) Aluminium pressure receptacle made from tubing and having welded heads. Primary containment of the fuel within this receptacle shall consist of a welded aluminium bladder having a maximum internal volume of 46 litres. The outer receptacle shall have a minimum design gauge pressure of 1 275 kPa and a minimum burst gauge pressure of 2 755 kPa. Each receptacle shall be leak checked during manufacture and before dispatch and shall be found leakproof. The complete inner unit shall be securely packed in non-combustible cushioning material, such as vermiculite, in a strong outer tightly closed metal packaging which will adequately protect all fittings. Maximum quantity of fuel per unit and package is 42 litres. (2) Aluminium pressure receptacle. Primary containment of the fuel within this receptacle shall consist of a welded vapour tight fuel compartment with an elastomeric bladder having a maximum internal volume of 46 litres. The pressure receptacle shall have a minimum design gauge pressure of 2 860 kPa and a minimum burst gauge pressure of 5 170 kPa. Each receptacle shall be leak-checked during manufacture and before dispatch and shall be securely packed in non-combustible cushioning material such as vermiculite, in a strong outer tightly closed metal packaging which will adequately protect all fittings. Maximum quantity of fuel per unit and package is 42 litres. P302 PACKING INSTRUCTION P302 This instruction applies to UN No. 3269. The following combination packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: Outer packagings: Drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A1, 3A2, 3B1, 3B2, 3H1, 3H2); Inner packagings: The activator (organic peroxide) shall have a maximum quantity of 125 ml per inner packaging if liquid, and 500 g per inner packaging if solid. The base material and the activator shall be each separately packed in inner packagings. The components may be placed in the same outer packaging provided that they will not interact dangerously in the event of a leakage. Packagings shall conform to the packing group II or III performance level according to the criteria for Class 3 applied to the base material. - 90 - P400 PACKING INSTRUCTION P400 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. They shall be made of steel and shall be subjected to an initial test and periodic tests every 10 years at a pressure of not less than 1 MPa (10 bar, gauge pressure). During carriage, the liquid shall be under a layer of inert gas with a gauge pressure of not less than 20 kPa (0.2 bar); (2) Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F or 4G), drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1D or 1G) or jerricans (3A1, 3A2, 3B1 or 3B2) enclosing hermetically sealed metal cans with inner packagings of glass or metal, with a capacity of not more than 1 litre each, having threaded closures with gaskets. Inner packagings shall be cushioned on all sides with dry, absorbent, non-combustible material in a quantity sufficient to absorb the entire contents. Inner packagings shall not be filled to more than 90% of their capacity. Outer packagings shall have a maximum net mass of 125 kg; (3) Steel, aluminium or metal drums (1A1, 1A2, 1B1, 1B2, 1N1 or 1N2), jerricans (3A1, 3A2, 3B1 or 3B2) or boxes (4A, 4B or 4N) with a maximum net mass of 150 kg each with hermetically sealed inner metal cans not more than 4 litre capacity each, with threaded closures fitted with gaskets. Inner packagings shall be cushioned on all sides with dry, absorbent, non-combustible material in a quantity sufficient to absorb the entire contents. Each layer of inner packagings shall be separated by a dividing partition in addition to cushioning material. Inner packagings shall not be filled to more than 90% of their capacity. Special packing provision: PP86 For UN Nos. 3392 and 3394, air shall be eliminated from the vapour space by nitrogen or other means. P401 PACKING INSTRUCTION P401 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. They shall be made of steel and subjected to an initial test and periodic tests every 10 years at a pressure of not less than 0.6 MPa (6 bar, gauge pressure). During carriage, the liquid shall be under a layer of inert gas with a gauge pressure of not less than 20 kPa (0.2 bar); (2) Combination packagings: Outer packagings: Drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A1, 3A2, 3B1, 3B2, 3H1, 3H2). Inner packagings: Glass, metal or plastics which have threaded closures with a maximum capacity of 1 litre. Each inner packaging shall be surrounded by inert cushioning and absorbent material in a quantity sufficient to absorb the entire contents. The maximum net mass per outer packaging shall not exceed 30 kg. Special packing provision specific to RID and ADR: RR7 For UN Nos. 1183, 1242, 1295 and 2988, the pressure receptacles shall however be subjected to the tests every five years. - 91 - P402 PACKING INSTRUCTION P402 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. They shall be made of steel and subjected to an initial test and periodic tests every 10 years at a pressure of not less than 0.6 MPa (6 bar, gauge pressure). During carriage, the liquid shall be under a layer of inert gas with a gauge pressure of not less than 20 kPa (0.2 bar); (2) Combination packagings: Outer packagings: Drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A1, 3A2, 3B1, 3B2, 3H1, 3H2). Inner packagings with a maximum net mass as follows: Glass 10 kg Metal or plastics 15 kg Each inner packaging shall be fitted with threaded closures. Each inner packaging shall be surrounded by inert cushioning and absorbent material in a quantity sufficient to absorb the entire contents. The maximum net mass per outer packaging shall not exceed 125 kg. (3) (4) Steel drums (1A1) with a maximum capacity of 250 litres; Composite packagings consisting of a plastics receptacle with outer steel drum or aluminium (6HA1 or 6HB1) with a maximum capacity of 250 litres. Special packing provisions specific to RID and ADR: RR4 For UN No. 3130, the openings of receptacles shall be tightly closed by means of two devices in series, one of which shall be screwed or secured in an equivalent manner. RR7 For UN No. 3129, the pressure receptacles shall however be subjected to the tests every five years. RR8 For UN Nos. 1389, 1391, 1411, 1421, 1928, 3129, 3130, 3148 and 3482, the pressure receptacles shall however be subjected to an initial test and to periodic tests at a pressure of not less than 1 MPa (10 bar). - 92 - P403 P403 PACKING INSTRUCTION The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: Maximum net Combination packagings: mass Inner packagings Outer packagings Drums Glass 2 kg Plastics 15 kg steel (1A1, 1A2) 400 kg Metal 20 kg aluminium (1B1, 1B2) 400 kg other metal (1N1, 1N2) 400 kg Inner packagings shall be plastics (1H1, 1H2) 400 kg hermetically sealed (e.g. plywood (1D) 400 kg by taping or by threaded fibre (1G) 400 kg closures). Boxes steel (4A) 400 kg aluminium (4B) 400 kg other metal (4N) 400 kg natural wood (4C1) 250 kg natural wood with sift proof walls (4C2) 250 kg plywood (4D) 250 kg reconstituted wood (4F) 125 kg fibreboard (4G) 125 kg expanded plastics (4H1) 60 kg solid plastics (4H2) 250 kg Jerricans steel (3A1, 3A2) 120 kg aluminium (3B1, 3B2) 120 kg plastics (3H1, 3H2) 120 kg Single packagings: Drums steel (1A1, 1A2) 250 kg aluminium (1B1, 1B2) 250 kg metal other than steel or aluminium (1N1, 1N2) 250 kg plastics (1H1, 1H2) 250 kg Jerricans steel (3A1, 3A2) 120 kg aluminium (3B1, 3B2) 120 kg plastics (3H1, 3H2) 120 kg Composite packagings plastics receptacle with outer steel or aluminium drums (6HA1 or 6HB1) 250 kg plastics receptacle with outer fibre, plastics or plywood drums (6HG1, 6HH1 or 6HD1) 75 kg plastics receptacle with outer steel or aluminium crate or box or with outer wooden, plywood, 75 kg fibreboard or solid plastics boxes (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. Additional requirement: Packagings shall be hermetically sealed. Special packing provision: PP83 For UN No. 2813, waterproof bags containing not more than 20 g of substance for the purposes of heat formation may be packaged for carriage. Each waterproof bag shall be sealed in a plastics bag and placed within an intermediate packaging. No outer packaging shall contain more than 400 g of substance. Water or liquid which may react with the water reactive substance shall not be included in the packaging. - 93 - P404 PACKING INSTRUCTION P404 This instruction applies to pyrophoric solids: UN Nos.: 1383, 1854, 1855, 2008, 2441, 2545, 2546, 2846, 2881, 3200, 3391 and 3393. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) Combination packagings Outer packagings: (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2) Inner packagings: Metal receptacles with a maximum net mass of 15 kg each. Inner packagings shall be hermetically sealed and have threaded closures; Glass receptacles, with a maximum net mass of 1 kg each, having threaded closures with gaskets, cushioned on all sides and contained in hermetically sealed metal cans. Outer packagings shall have a maximum net mass of 125 kg. (2) Metal packagings: (1A1, 1A2, 1B1, 1N1, 1N2, 3A1, 3A2, 3B1 and 3B2) Maximum gross mass: 150 kg; (3) Composite packagings: Plastics receptacle with outer steel or aluminium drum (6HA1 or 6HB1) Maximum gross mass: 150 kg. Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. Special packing provision: For UN Nos. 3391 and 3393, air shall be eliminated from the vapour space by nitrogen or other means. PP86 P405 PACKING INSTRUCTION This instruction applies to UN No. 1381. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) P405 For UN No. 1381, phosphorus, wet: (a) Combination packagings Outer packagings: (4A, 4B, 4N, 4C1, 4C2, 4D or 4F) Maximum net mass: 75 kg Inner packagings: (b) (i) hermetically sealed metal cans, with a maximum net mass of 15 kg; or (ii) glass inner packagings cushioned on all sides with dry, absorbent, non-combustible material in a quantity sufficient to absorb the entire contents with a maximum net mass of 2 kg; or Drums (1A1, 1A2, 1B1, 1B2, 1N1 or 1N2); maximum net mass: 400 kg Jerricans (3A1 or 3B1); maximum net mass: 120 kg. These packagings shall be capable of passing the leakproofness test specified in 6.1.5.4 at the packing group II performance level; (2) For UN No. 1381, dry phosphorus: (a) When fused, drums (1A2, 1B2 or 1N2) with a maximum net mass of 400 kg; or (b) In projectiles or hard cased articles when carried without Class 1 components: as specified by the competent authority. - 94 - P406 PACKING INSTRUCTION The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) Combination packagings (2) outer packagings: (4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2, 1G, 1D, 1H1, 1H2, 3H1 or 3H2) inner packagings: water-resistant packagings; P406 Plastics, plywood or fibreboard drums (1H2, 1D or 1G) or boxes (4A, 4B, 4N, 4C1, 4D, 4F, 4C2, 4G and 4H2) with a water resistant inner bag, plastics film lining or water resistant coating; (3) Metal drums (1A1, 1A2, 1B1, 1B2, 1N1 or 1N2), plastics drums (1H1 or 1H2), metal jerricans (3A1, 3A2, 3B1 or 3B2), plastics jerricans (3H1 or 3H2), plastics receptacle with outer steel or aluminium drums (6HA1 or 6HB1), plastics receptacle with outer fibre, plastics or plywood drums (6HG1, 6HH1 or 6HD1), plastics receptacle with outer steel or aluminium crate or box or with outer wooden, plywood, fibreboard or solid plastics boxes (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2). Additional requirements: 1. Packagings shall be designed and constructed to prevent the loss of water or alcohol content or the content of the phlegmatizer. 2. Packagings shall be so constructed and closed so as to avoid an explosive overpressure or pressure build-up of more than 300 kPa (3 bar). Special packing provisions: PP24 UN Nos. 2852, 3364, 3365, 3366, 3367, 3368 and 3369 shall not be carried in quantities of more than 500 g per package. PP25 For UN No. 1347, the quantity carried shall not exceed 15 kg per package. PP26 For UN Nos. 1310, 1320, 1321, 1322, 1344, 1347, 1348, 1349, 1517, 2907, 3317 and 3376 packagings shall be lead free. PP48 For UN No. 3474, metal packagings shall not be used. PP78 UN No. 3370 shall not be carried in quantities of more than 11.5 kg per package. PP80 For UN No. 2907, packagings shall meet the packing group II performance level. Packagings meeting the test criteria of packing group I shall not be used. P407 PACKING INSTRUCTION This instruction applies to UN Nos. 1331, 1944, 1945 and 2254. P407 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: Outer packagings: Drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A1, 3A2, 3B1, 3B2, 3H1, 3H2). Inner packagings: Matches shall be tightly packed in securely closed inner packagings to prevent accidental ignition under normal conditions of carriage. The maximum gross mass of the package shall not exceed 45 kg except for fibreboard boxes which shall not exceed 30 kg. Packagings shall conform to the packing group III performance level. Special packing provision: PP27 UN No. 1331, Strike-anywhere matches shall not be packed in the same outer packaging with any other dangerous goods other than safety matches or wax Vesta matches, which shall be packed in separate inner packagings. Inner packagings shall not contain more than 700 strike-anywhere matches. - 95 - P408 PACKING INSTRUCTION This instruction applies to UN No. 3292. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) P408 For cells: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). There shall be sufficient cushioning material to prevent contact between cells and between cells and the internal surfaces of the outer packaging and to ensure that no dangerous movement of the cells within the outer packaging occurs in carriage. Packagings shall conform to the packing group II performance level. (2) Batteries may be carried unpacked or in protective enclosures (e.g. fully enclosed or wooden slatted crates). The terminals shall not support the weight of other batteries or materials packed with the batteries. Packagings need not meet the requirements of 4.1.1.3. Additional requirement: Cells and batteries shall be protected against short circuit and shall be isolated in such a manner as to prevent short circuits. P409 PACKING INSTRUCTION This instruction applies to UN Nos. 2956, 3242 and 3251. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) Fibre drum (1G) which may be fitted with a liner or coating; maximum net mass: 50 kg; (2) Combination packagings: Fibreboard box (4G) with a single inner plastic bag; P409 maximum net mass: 50 kg; (3) Combination packagings: Fibreboard box (4G) or fibre drum (1G) with plastics inner packagings each containing a maximum of 5 kg; maximum net mass: 25 kg. - 96 - P410 PACKING INSTRUCTION P410 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: Combination packagings: Maximum net mass Inner packagings Outer packagings Packing group Packing group III II Glass 10 kg Drums Plastics a 30 kg steel (1A1, 1A2) 400 kg 400 kg Metal 40 kg aluminium (1B1, 1B2) 400 kg 400 kg Paper a, b 10 kg other metal (1N1, 1N2) 400 kg 400 kg plastics (1H1, 1H2) Fibre a, b 10 kg plywood (1D) 400 kg 400 kg fibre (1G)a 400 kg 400 kg Boxes steel (4A) 400 kg 400 kg aluminium (4B) 400 kg 400 kg other metal (4N) 400 kg 400 kg natural wood (4C1) 400 kg 400 kg natural wood with sift-proof 400 kg 400 kg walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) a expanded plastics (4H1) solid plastics (4H2) Jerricans steel (3A1, 3A2) aluminium (3B1, 3B2) plastics (3H1, 3H2) 400 kg 400 kg 400 kg 60 kg 400 kg 400 kg 400 kg 400 kg 60 kg 400 kg 120 kg 120 kg 120 kg 120 kg 120 kg 120 kg Single packagings: Drums steel (1A1 or 1A2) 400 kg 400 kg aluminium (1B1 or 1B2) 400 kg 400 kg metal other than steel or aluminium (1N1 or 1N2) 400 kg 400 kg plastics (1H1 or 1H2) 400 kg 400 kg Jerricans steel (3A1 or 3A2) 120 kg 120 kg aluminium (3B1 or 3B2) 120 kg 120 kg plastics (3H1 or 3H2) 120 kg 120 kg Boxes steel (4A) c 400 kg 400 kg aluminium (4B) c 400 kg 400 kg other metal (4N) c 400 kg 400 kg natural wood (4C1) c 400 kg 400 kg plywood (4D) c 400 kg 400 kg reconstituted wood (4F) c 400 kg 400 kg natural wood with sift-proof walls (4C2) c 400 kg 400 kg fibreboard (4G) c 400 kg 400 kg solid plastics (4H2) c 400 kg 400 kg Bags Bags (5H3, 5H4, 5L3, 5M2) c, d 50 kg 50 kg a These packagings shall be sift-proof. b These inner packagings shall not be used when the substances being carried may become liquid during carriage. c These packagings shall not be used when the substances being carried may become liquid during carriage. d These packagings shall only be used for packing group II substances when carried in a closed vehicle or container. (Cont'd on next page) - 97 - P410 PACKING INSTRUCTION (cont’d) P410 Maximum net mass Packing group Packing group II III 400 kg 400 kg Composite packagings plastics receptacle with outer steel, aluminium, plywood, fibre or plastics drum (6HA1, 6HB1, 6HG1, 6HD1, or 6HH1) 75 kg 75 kg plastics receptacle with outer steel or aluminium crate or box, or outer wooden, plywood, fibreboard or solid plastics box (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2) 75 kg 75 kg glass receptacle with outer steel, aluminium, plywood or fibre drum (6PA1, 6PB1, 6PD1 or 6PG1) or outer steel or aluminium crate or box or with outer wooden or fibreboard box or with outer wickerwork hamper (6PA2, 6PB2, 6PC, 6PD2, or 6PG2) or with outer solid or expanded plastics packaging (6PH1 or 6PH2) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. Special packing provisions: PP39 For UN No. 1378, for metal packagings a venting device is required. PP40 For UN Nos. 1326, 1352, 1358, 1395, 1396, 1436, 1437, 1871, 2805 and 3182, packing group II, bags are not allowed. PP83 For UN No. 2813, waterproof bags containing not more than 20 g of substance for the purposes of heat formation may be packaged for carriage. Each waterproof bag shall be sealed in a plastics bag and placed within an intermediate packaging. No outer packaging shall contain more than 400 g of substance. Water or liquid which may react with the water reactive substance shall not be included in the packaging. P411 PACKING INSTRUCTION This instruction applies to UN No. 3270. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: P411 Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2); provided that explosion is not possible by reason of increased internal pressure. The maximum net mass shall not exceed 30 kg. P500 PACKING INSTRUCTION This instruction applies to UN No. 3356. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); P500 Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). Packagings shall conform to the packing group II performance level. The generator(s) shall be carried in a package which meets the following requirements when one generator in the package is actuated: (a) Other generators in the package will not be actuated; (b) (c) Packaging material will not ignite; and The outside surface temperature of the completed package shall not exceed 100 °C. - 98 - P501 PACKING INSTRUCTION This instruction applies to UN No. 2015. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: 5l Outer packaging maximum net mass 125 kg 2l 50 kg Inner packaging maximum capacity Combination packagings: (1) Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4H2) or drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D) or jerricans (3A1, 3A2, 3B1, 3B2, 3H1, 3H2) with glass, plastics or metal inner packagings (2) Fibreboard box (4G) or fibre drum (1G), with plastics or metal inner packagings each in a plastics bag Single packagings: Drums steel (1A1) aluminium (1B1) metal other than steel or aluminium (1N1) plastics (1H1) Jerricans steel (3A1) aluminium (3B1) plastics (3H1) Composite packagings plastics receptacle with outer steel or aluminium drum (6HA1, 6HB1) plastics receptacle with outer fibre, plastics or plywood drum (6HG1, 6HH1, 6HD1) plastics receptacle with outer steel or aluminium crate or box or plastics receptacle with outer wooden, plywood, fibreboard or solid plastics box (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2) glass receptacle with outer steel, aluminium, fibre or plywood drum (6PA1, 6PB1, 6PD1 or 6PG1) or with outer steel, aluminium, wooden or fibreboard box or with outer wickerwork hamper (6PA2, 6PB2, 6PC, 6PG2 or 6PD2) or with outer solid or expanded plastics packaging (6PH1 or 6PH2). Additional requirements: 1. Packagings shall have a maximum filling degree of 90%. 2. Packagings shall be vented. - 99 - P501 Maximum capacity 250 l 60 l 250 l 250 l 60 l 60 l P502 PACKING INSTRUCTION P502 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: Combination packagings: Maximum net mass Inner packagings Outer packagings Glass 5l Drums Metal 5l steel (1A1, 1A2) 125 kg Plastics 5l aluminium (1B1, 1B2) 125 kg other metal (1N1, 1N2) 125 kg plywood (1D) 125 kg fibre (1G) 125 kg plastics (1H1, 1H2) 125 kg Boxes steel (4A) 125 kg aluminium (4B) 125 kg other metal (4N) 125 kg natural wood (4C1) 125 kg natural wood with sift-proof walls (4C2) 125 kg plywood (4D) 125 kg reconstituted wood (4F) 125 kg fibreboard (4G) 125 kg expanded plastics (4H1) 60 kg solid plastics (4H2) 125 kg Single packagings: Maximum capacity Drums steel (1A1) 250 l aluminium (1B1) plastics (1H1) Jerricans steel (3A1) 60 l aluminium (3B1) plastics (3H1) Composite packagings: plastics receptacle with outer steel or aluminium drum (6HA1, 6HB1) 250 l plastics receptacle with outer fibre, plastics or plywood drum (6HG1, 6HH1, 6HD1) 250 l 60 l plastics receptacle with outer steel or aluminium crate or box or plastics receptacle with outer wooden, plywood, fibreboard or solid plastics box (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2) 60 l glass receptacle with outer steel, aluminium, fibre or plywood drum (6PA1, 6PB1, 6PD1 or 6PG1) or with outer steel, aluminium, wooden or fibreboard box or with outer wickerwork hamper (6PA2, 6PB2, 6PC, 6PG2 or 6PD2) or with outer solid or expanded plastics packaging (6PH1 or 6PH2). Special packing provision: PP28 For UN No. 1873, only glass inner packagings and glass inner receptacles are authorized respectively for combination packagings and composite packagings. - 100 - P503 PACKING INSTRUCTION P503 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: Combination packagings: Inner packagings Outer packagings Maximum net mass Glass 5 kg Drums Metal 5 kg steel (1A1, 1A2) 125 kg Plastics 5 kg aluminium (1B1, 1B2) 125 kg other metal (1N1, 1N2) 125 kg plywood (1D) 125 kg fibre (1G) 125 kg plastics (1H1, 1H2) 125 kg Boxes steel (4A) 125 kg aluminium (4B) 125 kg other metal (4N) 125 kg natural wood (4C1) 125 kg natural wood with sift-proof walls (4C2) 125 kg plywood (4D) 125 kg reconstituted wood (4F) 125 kg fibreboard (4G) 40 kg expanded plastics (4H1) 60 kg solid plastics (4H2) 125 kg Single packagings: Metal drums (1A1, 1A2, 1B1, 1B2, 1N1 or 1N2) with a maximum net mass of 250 kg. Fibreboard (1G) or plywood drums (1D) fitted with inner liners with a maximum net mass of 200 kg. - 101 - P504 PACKING INSTRUCTION P504 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: Combination packagings: Maximum net mass (1) Glass receptacles with a maximum capacity of 5 litres in 1A1, 1A2, 1B1, 1B2, 1N1, 75 kg 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H2 outer packagings (2) Plastics receptacles with a maximum capacity of 30 litres in 1A1, 1A2, 1B1, 1B2, 75 kg 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H2 outer packagings (3) Metal receptacles with a maximum capacity of 40 litres in 1G, 4F or 4G outer 125 kg packagings (4) Metal receptacles with a maximum capacity of 40 litres in 1A1, 1A2, 1B1, 1B2, 1N1, 225 kg 1N2, 1H1, 1H2, 1D, 4A, 4B, 4N, 4C1, 4C2, 4D, 4H2 outer packagings Single packagings: Maximum capacity Drums steel, non-removable head (1A1) 250 l steel, removable head (1A2) 250 l aluminium, non-removable head (1B1) 250 l aluminium, removable head (1B2) 250 l metal other than steel or aluminium, non-removable head (1N1) 250 l metal other than steel or aluminium, removable head (1N2) 250 l plastics, non-removable head (1H1) 250 l plastics, removable head (1H2) 250 l Jerricans steel, non-removable head (3A1) 60 l steel, removable head (3A2) 60 l aluminium, non-removable head (3B1) 60 l aluminium, removable head (3B2) 60 l plastics, non-removable head (3H1) 60 l plastics, removable head (3H2) 60 l Composite packagings plastics receptacle with outer steel or aluminium drum (6HA1, 6HB1) 250 l plastics receptacle with outer fibre, plastics or plywood drum (6HG1, 6HH1, 6HD1) 120 l plastics receptacle with outer steel or aluminium crate or box or plastics receptacle with 60 l outer wooden, plywood, fibreboard or solid plastics box (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2) glass receptacle with outer steel, aluminium, fibre or plywood drum (6PA1, 6PB1, 6PD1 or 60 l 6PG1) or with outer steel, aluminium, wooden or fibreboard box or with outer wickerwork hamper (6PA2, 6PB2, 6PC, 6PG2 or 6PD2) or with outer solid or expanded plastics packaging (6PH1 or 6PH2). Special packing provisions: PP10 For UN No. 2014, 2984 and 3149, the packaging shall be vented. - 102 - P505 PACKING INSTRUCTION This instruction applies to UN No. 3375. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: Inner packaging maximum capacity Combination packagings: P505 Outer packaging maximum net mass 125 kg Boxes (4B, 4C1, 4C2, 4D, 4G, 4H2) or drums (1B2, 1G, 1N2, 1H2, 1D) or jerricans (3B2, 3H2) with glass, plastics or metal inner packagings 5l Single packagings: Drums aluminium (1B1, 1B2) plastics (1H1, 1H2) Jerricans: aluminium (3B1, 3B2) plastics (3H1, 3H2) Composite packagings: plastics receptacle with outer aluminium drum (6HB1) plastics receptacle with outer fibre, plastics or plywood drum (6HG1, 6HH1, 6HD1) plastics receptacle with outer aluminium crate or box or plastics receptacle with outer wooden, plywood, fibreboard or solid plastics box (6HB2, 6HC, 6HD2, 6HG2 or 6HH2) glass receptacle with outer aluminium, fibre or plywood drum (6PB1, 6PG1, 6PD1) or with outer expanded or solid plastics plastics receptacles (6PH1 or 6PH2) or with outer aluminium crate or box or with outer wooden or fibreboard box or with outer wickerwork hamper (6PB2, 6PC, 6PG2 or 6PD2) Maximum capacity - 103 - 250 l 250 l 60 l 60 l 250 l 250 l 60 l 60 l P520 PACKING INSTRUCTION P520 This instruction applies to organic peroxides of Class 5.2 and self-reactive substances of Class 4.1 The packagings listed below are authorized provided the general provisions of 4.1.1 and 4.1.3 and special provisions of 4.1.7.1 are met. The packing methods are designated OP1 to OP8. The packing methods appropriate for the individual currently assigned organic peroxides and self-reactive substances are listed in 2.2.41.4 and 2.2.52.4. The quantities specified for each packing method are the maximum quantities authorized per package. The following packagings are authorized: (1) Combination packagings with outer packagings comprising boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1 and 4H2), drums (1A1, 1A2, 1B1, 1B2, 1G, 1H1, 1H2 and 1D), jerricans (3A1, 3A2, 3B1, 3B2, 3H1 and 3H2); (2) Single packagings consisting of drums (1A1, 1A2, 1B1, 1B2, 1G, 1H1, 1H2 and 1D) and jerricans (3A1, 3A2, 3B1, 3B2, 3H1 and 3H2); (3) Composite packagings with plastics inner receptacles (6HA1, 6HA2, 6HB1, 6HB2, 6HC, 6HD1, 6HD2, 6HG1, 6HG2, 6HH1 and 6HH2). Maximum quantity per packaging/package a for packing methods OP1 to OP8 Packing Method OP1 OP2 a OP3 OP4 a OP5 OP6 OP7 OP8 Maximum Quantity Maximum mass (kg) for 0.5 0.5/10 5 5/25 25 50 50 400 b solids and for combination packagings (liquid and solid) Maximum contents in 0.5 5 30 60 60 225 d litres for liquids c a If two values are given, the first applies to the maximum net mass per inner packaging and the second to the maximum net mass of the complete package. b 60 kg for jerricans / 200 kg for boxes and, for solids, 400 kg in combination packagings with outer packagings comprising boxes (4C1, 4C2, 4D, 4F, 4G, 4H1 and 4H2) and with inner packagings of plastics or fibre with a maximum net mass of 25 kg. c Viscous substances shall be treated as solids when they do not meet the criteria provided in the definition for "liquids" presented in 1.2.1. d 60 litres for jerricans. Additional requirements: 1. Metal packagings, including inner packagings of combination packagings and outer packagings of combination or composite packagings may only be used for packing methods OP7 and OP8. 2. In combination packagings, glass receptacles may only be used as inner packagings with maximum contents of 0.5 kg for solids or 0.5 litre for liquids. 3. In combination packagings, cushioning materials shall not be readily combustible. 4. The packaging of an organic peroxide or self-reactive substance required to bear an "EXPLOSIVE" subsidiary risk label (model No.1, see 5.2.2.2.2) shall also comply with the provisions given in 4.1.5.10 and 4.1.5.11. Special packing provisions: PP21 For certain self-reactive substances of types B or C, UN Nos. 3221, 3222, 3223, 3224, 3231, 3232, 3233 and 3234, a smaller packaging than that allowed by packing methods OP5 or OP6 respectively shall be used (see 4.1.7 and 2.2.41.4). PP22 UN No. 3241, 2-Bromo-2-nitropropane-1, 3-diol, shall be packed in accordance with packing method OP6. - 104 - P600 PACKING INSTRUCTION This instruction applies to UN Nos. 1700, 2016 and 2017. The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 are met: P600 Outer packagings (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H2) meeting the packing group II performance level. The articles shall be individually packaged and separated from each other using partitions, dividers, inner packagings or cushioning material to prevent inadvertent discharge during normal conditions of carriage. Maximum net mass: 75 kg P601 PACKING INSTRUCTION P601 The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met and the packagings are hermetically sealed: (1) Combination packagings with a maximum gross mass of 15 kg, consisting of  one or more glass inner packaging(s) with a maximum quantity of 1 litre each and filled to not more than 90% of their capacity; the closure(s) of which shall be physically held in place by any means capable of preventing back-off or loosening by impact or vibration during carriage, individually placed in  metal receptacles together with cushioning and absorbent material sufficient to absorb the entire contents of the glass inner packaging(s), further packed in  1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings; (2) Combination packagings consisting of metal or plastics inner packagings not exceeding 5 litres in capacity individually packed with absorbent material sufficient to absorb the contents and inert cushioning material in 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings with a maximum gross mass of 75 kg. Inner packagings shall not be filled to more than 90% of their capacity. The closure of each inner packaging shall be physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during carriage; (3) Packagings consisting of: Outer packagings: Steel or plastics drums (1A1, 1A2, 1H1 or 1H2), tested in accordance with the test requirements in 6.1.5 at a mass corresponding to the mass of the assembled package either as a packaging intended to contain inner packagings, or as a single packaging intended to contain solids or liquids, and marked accordingly; Inner packagings: Drums and composite packagings (1A1, 1B1, 1N1, 1H1 or 6HA1) meeting the requirements of Chapter 6.1 for single packagings, subject to the following conditions: (a) The hydraulic pressure test shall be conducted at a pressure of at least 0.3 MPa (gauge pressure); (b) The design and production leakproofness tests shall be conducted at a test pressure of 30 kPa; (c) They shall be isolated from the outer drum by the use of inert shock-mitigating cushioning material which surrounds the inner packaging on all sides; (d) Their capacity shall not exceed 125 litres; (Cont'd on next page) - 105 - P601 (3) PACKING INSTRUCTION (cont'd) Packagings consisting of: (cont'd) (e) (f) P601 Closures shall be of a screw cap type that are: (i) physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during carriage; and (ii) provided with a cap seal; The outer and inner packagings shall be subjected periodically to a leakproofness test according to (b) at intervals of not more than two and a half years; (g) The complete packaging shall be visually inspected to the satisfaction of the competent authority at least every 3 years; and (h) The outer and inner packaging shall bear in clearly legible and durable characters: (4) (i) the date (month, year) of the initial test and the latest periodic test and inspection; (ii) the stamp of the expert who carried out the test and inspection; Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. They shall be subjected to an initial test and periodic tests every 10 years at a pressure of not less than 1 MPa (10 bar) (gauge pressure). Pressure receptacles may not be equipped with any pressure relief device. Each pressure receptacle containing a toxic by inhalation liquid with an LC50 less than or equal to 200 ml/m3 (ppm) shall be closed with a plug or valve conforming to the following: (a) Each plug or valve shall have a taper-threaded connection directly to the pressure receptacle and be capable of withstanding the test pressure of the pressure receptacle without damage or leakage; (b) Each valve shall be of the packless type with non-perforated diaphragm, except that, for corrosive substances, a valve may be of the packed type with an assembly made gas-tight by means of a seal cap with gasket joint attached to the valve body or the pressure receptacle to prevent loss of substance through or past the packing; (c) Each valve outlet shall be sealed by a threaded cap or threaded solid plug and inert gasket material; (d) The materials of construction for the pressure receptacle, valves, plugs, outlet caps, luting and gaskets shall be compatible with each other and with the contents. Each pressure receptacle with a wall thickness at any point of less than 2.0 mm and each pressure receptacle which does not have fitted valve protection shall be carried in an outer packaging. Pressure receptacles shall not be manifolded or interconnected. Special packing provision: PP82 (Deleted) Special packing provisions specific to RID and ADR: RR3 (Deleted) RR7 For UN No. 1251, the pressure receptacles shall however be subjected to the tests every five years. RR10 UN No. 1614, when completely absorbed by an inert porous material, shall be packed in metal receptacles of a capacity of not more than 7.5 litres, placed in wooden cases in such a manner that they cannot come into contact with one another. The receptacles shall be entirely filled with the porous material which shall not shake down or form dangerous spaces even after prolonged use or under impact, even at temperatures of up to 50 °C. - 106 - P602 PACKING INSTRUCTION P602 The following packagings are authorised provided the general provisions of 4.1.1 and 4.1.3 are met and the packagings are hermetically sealed: (1) Combination packagings with a maximum gross mass of 15 kg, consisting of  one or more glass inner packaging(s) with a maximum quantity of 1 litre each and filled to not more than 90% of their capacity; the closure(s) of which shall be physically held in place by any means capable of preventing back-off or loosening by impact or vibration during carriage, individually placed in  metal receptacles together with cushioning and absorbent material sufficient to absorb the entire contents of the glass inner packaging(s), further packed in  1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings; (2) Combination packagings consisting of metal or plastics inner packagings individually packed with absorbent material sufficient to absorb the entire contents and inert cushioning material in 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings with a maximum gross mass of 75 kg. Inner packagings shall not be filled to more than 90% of their capacity. The closure of each inner packaging shall be physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during carriage. Inner packagings shall not exceed 5 litres in capacity; (3) Drums and composite packagings (1A1, 1B1, 1N1, 1H1, 6HA1 or 6HH1), subject to the following conditions: (a) The hydraulic pressure test shall be conducted at a pressure of at least 0.3 MPa (gauge pressure); (b) The design and production leakproofness tests shall be conducted at a test pressure of 30 kPa; and (c) Closures shall be of a screw cap type that are: (i) physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during carriage; and (ii) provided with a cap seal; (4) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. They shall be subjected to an initial test and periodic tests every 10 years at a pressure of not less than 1 MPa (10 bar) (gauge pressure). Pressure receptacles may not be equipped with any pressure relief device. Each pressure receptacle containing a toxic by inhalation liquid with an LC50 less than or equal to 200 ml/m3 (ppm) shall be closed with a plug or valve conforming to the following: (a) Each plug or valve shall have a taper-threaded connection directly to the pressure receptacle and be capable of withstanding the test pressure of the pressure receptacle without damage or leakage; (b) Each valve shall be of the packless type with non-perforated diaphragm, except that, for corrosive substances, a valve may be of the packed type with an assembly made gas-tight by means of a seal cap with gasket joint attached to the valve body or the pressure receptacle to prevent loss of substance through or past the packing; (c) Each valve outlet shall be sealed by a threaded cap or threaded solid plug and inert gasket material; (d) The materials of construction for the pressure receptacle, valves, plugs, outlet caps, luting and gaskets shall be compatible with each other and with the contents. Each pressure receptacle with a wall thickness at any point of less than 2.0 mm and each pressure receptacle which does not have fitted valve protection shall be carried in an outer packaging. Pressure receptacles shall not be manifolded or interconnected. - 107 - P620 PACKING INSTRUCTION This instruction applies to UN Nos. 2814 and 2900. P620 The following packagings are authorized provided the special packing provisions of 4.1.8 are met: Packagings meeting the requirements of Chapter 6.3 and approved accordingly consisting of: (a) (b) Inner packagings comprising: (i) leakproof primary receptacle(s); (ii) a leakproof secondary packaging; (iii) other than for solid infectious substances, an absorbent material in sufficient quantity to absorb the entire contents placed between the primary receptacle(s) and the secondary packaging; if multiple primary receptacles are placed in a single secondary packaging, they shall be either individually wrapped or separated so as to prevent contact between them; A rigid outer packaging: Drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A1, 3A2, 3B1, 3B2, 3H1, 3H2). The smallest external dimension shall be not less than 100 mm. Additional requirements: 1. 2. 3. 4. 5. a Inner packagings containing infectious substances shall not be consolidated with inner packagings containing unrelated types of goods. Complete packages may be overpacked in accordance with the provisions of 1.2.1 and 5.1.2; such an overpack may contain dry ice. Other than for exceptional consignments, e.g. whole organs which require special packaging, the following additional requirements shall apply: (a) Substances consigned at ambient temperatures or at a higher temperature: Primary receptacles shall be of glass, metal or plastics. Positive means of ensuring a leakproof seal shall be provided, e.g. a heat seal, a skirted stopper or a metal crimp seal. If screw caps are used, they shall be secured by positive means, e.g., tape, paraffin sealing tape or manufactured locking closure; (b) Substances consigned refrigerated or frozen: Ice, dry ice or other refrigerant shall be placed around the secondary packaging(s) or alternatively in an overpack with one or more complete packages marked in accordance with 6.3.3. Interior supports shall be provided to secure secondary packaging(s) or packages in position after the ice or dry ice has dissipated. If ice is used, the outer packaging or overpack shall be leakproof. If dry ice is used, the outer packaging or overpack shall permit the release of carbon dioxide gas. The primary receptacle and the secondary packaging shall maintain their integrity at the temperature of the refrigerant used; (c) Substances consigned in liquid nitrogen: Plastics primary receptacles capable of withstanding very low temperature shall be used. The secondary packaging shall also be capable of withstanding very low temperatures, and in most cases will need to be fitted over the primary receptacle individually. Provisions for the consignment of liquid nitrogen shall also be fulfilled. The primary receptacle and the secondary packaging shall maintain their integrity at the temperature of the liquid nitrogen; (d) Lyophilised substances may also be carried in primary receptacles that are flame-sealed glass ampoules or rubber-stoppered glass vials fitted with metal seals. Whatever the intended temperature of the consignment, the primary receptacle or the secondary packaging shall be capable of withstanding without leakage an internal pressure producing a pressure differential of not less than 95 kPa and temperatures in the range -40 °C to +55 °C. Other dangerous goods shall not be packed in the same packaging as Class 6.2 infectious substances unless they are necessary for maintaining the viability, stabilizing or preventing degradation or neutralizing the hazards of the infectious substances. A quantity of 30 ml or less of dangerous goods included in Classes 3, 8 or 9 may be packed in each primary receptacle containing infectious substances. These small quantities of dangerous goods of Classes 3, 8 or 9 are not subject to any additional requirements of ADR when packed in accordance with this packing instruction. Alternative packagings for the carriage of animal material may be authorized by the competent authority of the country of origin a in accordance with the provisions of 4.1.8.7. If the country of origin is not a Contracting Party to ADR, the competent authority of the first Contracting Party to the ADR reached by the consignment. - 108 - P621 PACKING INSTRUCTION P621 This instruction applies to UN No. 3291. The following packagings are authorized provided that the general provisions of 4.1.1 except 4.1.1.15 and 4.1.3 are met: (1) Provided that there is sufficient absorbent material to absorb the entire amount of liquid present and the packaging is capable of retaining liquids: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). Packagings shall conform to the packing group II performance level for solids. (2) For packages containing larger quantities of liquid: Drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G); Jerricans (3A1, 3A2, 3B1, 3B2, 3H1, 3H2); Composites (6HA1, 6HB1, 6HG1, 6HH1, 6HD1, 6HA2, 6HB2, 6HC, 6HD2, 6HG2, 6HH2, 6PA1, 6PB1, 6PG1, 6PD1, 6PH1, 6PH2, 6PA2, 6PB2, 6PC, 6PG2 or 6PD2). Packagings shall conform to the packing group II performance level for liquids. Additional requirement: Packagings intended to contain sharp objects such as broken glass and needles shall be resistant to puncture and retain liquids under the performance test conditions in Chapter 6.1. - 109 - P650 PACKING INSTRUCTION P650 This packing instruction applies to UN No. 3373. (1) (2) The packaging shall be of good quality, strong enough to withstand the shocks and loadings normally encountered during carriage, including transhipment between vehicles or containers and between vehicles or containers and warehouses as well as any removal from a pallet or overpack for subsequent manual or mechanical handling. Packagings shall be constructed and closed to prevent any loss of contents that might be caused under normal conditions of carriage by vibration or by changes in temperature, humidity or pressure. The packaging shall consist of at least three components: (a) a primary receptacle; (b) a secondary packaging; and (c) an outer packaging (4) of which either the secondary or the outer packaging shall be rigid. Primary receptacles shall be packed in secondary packagings in such a way that, under normal conditions of carriage, they cannot break, be punctured or leak their contents into the secondary packaging. Secondary packagings shall be secured in outer packagings with suitable cushioning material. Any leakage of the contents shall not compromise the integrity of the cushioning material or of the outer packaging. For carriage, the mark illustrated below shall be displayed on the external surface of the outer packaging on a background of a contrasting colour and shall be clearly visible and legible. The mark shall be in the form of a square set at an angle of 45° (diamond-shaped) with minimum dimensions of 50 mm by 50 mm; the width of the line shall be at least 2 mm and the letters and numbers shall be at least 6 mm high. The proper shipping name "BIOLOGICAL SUBSTANCE, CATEGORY B" in letters at least 6 mm high shall be marked on the outer packaging adjacent to the diamond-shaped mark. (5) At least one surface of the outer packaging shall have a minimum dimension of 100 mm  100 mm. (6) The completed package shall be capable of successfully passing the drop test in 6.3.5.3 as specified in 6.3.5.2 at a height of 1.2 m. Following the appropriate drop sequence, there shall be no leakage from the primary receptacle(s) which shall remain protected by absorbent material, when required, in the secondary packaging. (Cont'd on next page) (3) - 110 - P650 (7) (8) (9) PACKING INSTRUCTION (cont'd) P650 For liquid substances: (a) The primary receptacle(s) shall be leakproof; (b) The secondary packaging shall be leakproof; (c) If multiple fragile primary receptacles are placed in a single secondary packaging, they shall be either individually wrapped or separated to prevent contact between them; (d) Absorbent material shall be placed between the primary receptacle(s) and the secondary packaging. The absorbent material shall be in quantity sufficient to absorb the entire contents of the primary receptacle(s) so that any release of the liquid substance will not compromise the integrity of the cushioning material or of the outer packaging; (e) The primary receptacle or the secondary packaging shall be capable of withstanding, without leakage, an internal pressure of 95 kPa (0.95 bar). For solid substances: (a) The primary receptacle(s) shall be siftproof; (b) The secondary packaging shall be siftproof; (c) If multiple fragile primary receptacles are placed in a single secondary packaging, they shall be either individually wrapped or separated to prevent contact between them; (d) If there is any doubt as to whether or not residual liquid may be present in the primary receptacle during carriage then a packaging suitable for liquids, including absorbent materials, shall be used. Refrigerated or frozen specimens: Ice, dry ice and liquid nitrogen: (a) When dry ice or liquid nitrogen is used as a coolant, the requirements of 5.5.3 shall apply. When used, ice shall be placed outside the secondary packagings or in the outer packaging or an overpack. Interior supports shall be provided to secure the secondary packagings in the original position. If ice is used, the outside packaging or overpack shall be leakproof. (b) The primary receptacle and the secondary packaging shall maintain their integrity at the temperature of the refrigerant used as well as the temperatures and the pressures which could result if refrigeration were lost. (10) When packages are placed in an overpack, the package markings required by this packing instruction shall either be clearly visible or be reproduced on the outside of the overpack. (11) Infectious substances assigned to UN No. 3373 which are packed and packages which are marked in accordance with this packing instruction are not subject to any other requirement in ADR. (12) Clear instructions on filling and closing such packages shall be provided by packaging manufacturers and subsequent distributors to the consignor or to the person who prepares the package (e.g. patient) to enable the package to be correctly prepared for carriage. (13) Other dangerous goods shall not be packed in the same packaging as Class 6.2 infectious substances unless they are necessary for maintaining the viability, stabilizing or preventing degradation or neutralizing the hazards of the infectious substances. A quantity of 30 ml or less of dangerous goods included in Classes 3, 8 or 9 may be packed in each primary receptacle containing infectious substances. When these small quantities of dangerous goods are packed with infectious substances in accordance with this packing instruction no other requirements of ADR need be met. (14) If any substance has leaked and has been spilled in a vehicle or container, it may not be reused until after it has been thoroughly cleaned and, if necessary, disinfected or decontaminated. Any other goods and articles carried in the same vehicle or container shall be examined for possible contamination. Additional requirement: Alternative packagings for the carriage of animal material may be authorized by the competent authority of the country of origin a in accordance with the provisions of 4.1.8.7. a If the country of origin is not a Contracting Party to ADR, the competent authority of the first Contracting Party to the ADR reached by the consignment. - 111 - P800 PACKING INSTRUCTION This instruction applies to UN Nos. 2803 and 2809. The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 are met: (1) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. (2) Steel flasks or bottles with threaded closures with a capacity not exceeding 3 l; or (3) Combination packagings which conform to the following requirements: P800 (a) Inner packagings shall comprise glass, metal or rigid plastics intended to contain liquids with a maximum net mass of 15 kg each; (b) The inner packagings shall be packed with sufficient cushioning material to prevent breakage; (c) Either the inner packagings or the outer packagings shall have inner liners or bags of strong leakproof and puncture-resistant material impervious to the contents and completely surrounding the contents to prevent it from escaping from the package irrespective of its position or orientation; (d) The following outer packagings and maximum net masses are authorized: Outer packaging: Drums steel (1A1, 1A2) metal, other than steel or aluminium (1N1, 1N2) plastics (1H1, 1H2) plywood (1D) fibre (1G) Boxes steel (4A) metal, other than steel or aluminium (4N) natural wood (4C1) natural wood with sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) expanded plastics (4H1) solid plastics (4H2) Special packing provision: Maximum net mass 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 400 kg 250 kg 250 kg 250 kg 125 kg 125 kg 60 kg 125 kg PP41 For UN No. 2803, when it is necessary to carry gallium at low temperatures in order to maintain it in a completely solid state, the above packagings may be overpack ed in a strong, water-resistant outer packaging which contains dry ice or other means of refrigeration. If a refrigerant is used, all of the above materials used in the packaging of gallium shall be chemically and physically resistant to the refrigerant and shall have impact resistance at the low temperatures of the refrigerant employed. If dry ice is used, the outer packaging shall permit the release of carbon dioxide gas. - 112 - P801 PACKING INSTRUCTION P801 This instruction applies to new and used batteries assigned to UN Nos. 2794, 2795 or 3028. The following packagings are authorized, provided the general provisions of 4.1.1, except 4.1.1.3, and 4.1.3 are met: (1) Rigid outer packagings; (2) Wooden slatted crates; (3) Pallets. Additional requirements: 1. Batteries shall be protected against short circuits. 2. Batteries stacked shall be adequately secured in tiers separated by a layer of non conductive material. 3. Battery terminals shall not support the weight of other superimposed elements. 4. Batteries shall be packaged or secured to prevent inadvertent movement. Any cushioning material used shall be inert. P801a PACKING INSTRUCTION P801a This instruction applies to used batteries of UN Nos. 2794, 2795, 2800 and 3028. Stainless steel or solid plastics battery boxes of a capacity of up to 1 m3 are authorized provided the following provisions are met: (1) The battery boxes shall be resistant to the corrosive substances contained in the storage batteries; (2) Under normal conditions of carriage, no corrosive substance shall leak from the battery boxes and no other substance (e.g. water) shall enter the battery boxes. No dangerous residues of corrosive substances contained in the storage batteries shall adhere to the outside of the battery boxes; (3) The battery boxes shall not be loaded with storage batteries to a height greater than the height of their sides; (4) No storage battery containing substances or other dangerous goods which may react dangerously with one another shall be placed in a battery box; (5) The battery boxes shall be either: (a) covered; or (b) carried in closed or sheeted vehicles or containers. - 113 - P802 PACKING INSTRUCTION The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 are met: P802 (1) Combination packagings: Outer packagings: 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2; maximum net mass: 75 kg. Inner packagings: glass or plastics; maximum capacity: 10 litres; (2) Combination packagings: Outer packagings: 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2; maximum net mass: 125 kg. Inner packagings: metal; maximum capacity: 40 litres; (3) Composite packagings: Glass receptacle with outer steel, aluminium or plywood drum (6PA1, 6PB1 or 6PD1) or with outer steel, aluminium or wooden box or with outer wickerwork hamper (6PA2, 6PB2, 6PC or 6PD2) or with outer solid plastics packaging (6PH2); maximum capacity: 60 litres. (4) Steel drums (1A1) with a maximum capacity of 250 litres; (5) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. P803 PACKING INSTRUCTION This instruction applies to UN No. 2028. The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 are met: (1) Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); (2) Boxes ( 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H2). P803 Maximum net mass: 75 kg. The articles shall be individually packaged and separated from each other using partitions, dividers, inner packagings or cushioning material to prevent inadvertent discharge during normal conditions of carriage. - 114 - P804 PACKING INSTRUCTION P804 This instruction applies to UN No. 1744. The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met and the packagings are hermetically sealed: (1) Combination packagings with a maximum gross mass of 25 kg, consisting of one or more glass inner packaging(s) with a maximum capacity of 1.3 litres each and filled to not more than 90% of their capacity; the closure(s) of which shall be physically held in place by any means capable of preventing back-off or loosening by impact or vibration during carriage, individually placed in metal or rigid plastics receptacles together with cushioning and absorbent material sufficient to absorb the entire contents of the glass inner packaging(s), further packed in 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings. (2) Combination packagings consisting of metal or polyvinylidene fluoride (PVDF) inner packagings, not exceeding 5 litres in capacity individually packed with absorbent material sufficient to absorb the contents and inert cushioning material in 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings with a maximum gross mass of 75 kg. Inner packagings shall not be filled to more than 90% of their capacity. The closure of each inner packaging shall be physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during carriage; (3) Packagings consisting of: Outer packagings: Steel or plastics drums (1A1, 1A2, 1H1 or 1H2) tested in accordance with the test requirements in 6.1.5 at a mass corresponding to the mass of the assembled package either as a packaging intended to contain inner packagings, or as a single packaging intended to contain solids or liquids, and marked accordingly; Inner packagings: Drums and composite packagings (1A1, 1B1, 1N1, 1H1 or 6HA1) meeting the requirements of Chapter 6.1 for single packagings, subject to the following conditions: (a) The hydraulic pressure test shall be conducted at a pressure of at least 300 kPa (3 bar) (gauge pressure); (b) The design and production leakproofness tests shall be conducted at a test pressure of 30 kPa (0.3 bar); (c) They shall be isolated from the outer drum by the use of inert shock-mitigating cushioning material which surrounds the inner packaging on all sides; (d) Their capacity shall not exceed 125 litres; (e) Closures shall be of a screw type that are: (i) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during carriage; (ii) Provided with a cap seal; (f) The outer and inner packagings shall be subjected periodically to an internal inspection and leakproofness test according to (b) at intervals of not more than two and a half years; and (g) The outer and inner packagings shall bear in clearly legible and durable characters: (i) the date (month, year) of the initial test and the latest periodic test and inspection of the inner packaging; and (ii) the name or authorized symbol of the expert who carried out the tests and inspections; (4) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. (a) They shall be subjected to an initial test and periodic tests every 10 years at a pressure of not less than 1 MPa (10 bar) (gauge pressure); (b) They shall be subjected periodically to an internal inspection and leakproofness test at intervals of not more than two and a half years; (c) They may not be equipped with any pressure relief device; (d) Each pressure receptacle shall be closed with a plug or valve(s) fitted with a secondary closure device; and (e) The materials of construction for the pressure receptacle, valves, plugs, outlet caps, luting and gaskets shall be compatible with each other and with the contents. - 115 - P805 This instruction applies to UN 3507. PACKING INSTRUCTION P805 The following packagings are authorized provided that the general provisions of 4.1.1 and 4.1.3 and the special packing provisions of 4.1.9.1.2, 4.1.9.1.4 and 4.1.9.1.7 are met: Packagings consisting of: (a) Metal or plastics primary receptacle(s); in (b) Leakproof rigid secondary packaging(s); in (c) A rigid outer packaging: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). Additional requirements: 1. Primary inner receptacles shall be packed in secondary packagings in a way that, under normal conditions of carriage, they cannot break, be punctured or leak their contents into the secondary packaging. Secondary packagings shall be secured in outer packagings with suitable cushioning material to prevent movement. If multiple primary receptacles are placed in a single secondary packaging, they shall be either individually wrapped or separated so as to prevent contact between them. 2. The contents shall comply with the provisions of 2.2.7.2.4.5.2. 3. The provisions of 6.4.4 shall be met. Special packing provision: In the case of fissile-excepted material, limits specified in 2.2.7.2.3.5 and 6.4.11.2 shall be met. P900 PACKING INSTRUCTION P900 (Reserved) P901 PACKING INSTRUCTION P901 This instruction applies to UN No. 3316. The following combination packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met: Drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A1, 3A2, 3B1, 3B2, 3H1, 3H2). Packagings shall conform to the performance level consistent with the packing group assigned to the kit as a whole (see special provision 251 of Chapter 3.3). Where the kit contains only dangerous goods to which no packing group is assigned, packagings shall meet the packing group II performance level. Maximum quantity of dangerous goods per outer packaging: 10 kg excluding the mass of any carbon dioxide, solid (dry ice) used as a refrigerant. Additional requirements: Dangerous goods in kits shall be packed in inner packagings which shall not exceed either 250 ml or 250 g and shall be protected from other materials in the kit. - 116 - P902 This instruction applies to UN No. 3268. Packaged articles: PACKING INSTRUCTION P902 The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). Packagings shall conform to the packing group III performance level. The packagings shall be designed and constructed so as to prevent movement of the articles and inadvertent operation during normal conditions of carriage. Unpackaged articles: The articles may also be carried unpackaged in dedicated handling devices, vehicles or containers when moved from where they are manufactured to an assembly plant. Additional requirement: Any pressure receptacle shall be in accordance with the requirements of the competent authority for the substance(s) contained therein. - 117 - P903 PACKING INSTRUCTION This instruction applies to UN Nos. 3090 , 3091, 3480 and 3481. The following packagings are authorized provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) P903 For cells and batteries: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). Cells or batteries shall be packed in packagings so that the cells or batteries are protected against damage that may be caused by the movement or placement of the cells or batteries within the packaging. Packagings shall conform to the packing group II performance level. (2) In addition for cells or batteries with a gross mass of 12 kg or more employing a strong, impact resistant outer casing, and assemblies of such cells or batteries: (a) Strong outer packagings; (b) Protective enclosures (e.g., fully enclosed or wooden slatted crates); or (c) Pallets or other handling devices. Cells or batteries shall be secured to prevent inadvertent movement, and the terminals shall not support the weight of other superimposed elements. Packagings need not meet the requirements of 4.1.1.3. (3) For cells or batteries packed with equipment: Packagings conforming to the requirements in paragraph (1) of this packing instruction, then placed with the equipment in an outer packaging; or Packagings that completely enclose the cells or batteries, then placed with equipment in a packaging conforming to the requirements in paragraph (1) of this packing instruction. The equipment shall be secured against movement within the outer packaging. For the purpose of this packing instruction, "equipment" means apparatus requiring the lithium metal or lithium ion cells or batteries with which it is packed for its operation. (4) For cells or batteries contained in equipment: Strong outer packagings constructed of suitable material, and of adequate strength and design in relation to the packaging capacity and its intended use. They shall be constructed in such a manner as to prevent accidental operation during carriage. Packagings need not meet the requirements of 4.1.1.3. Large equipment can be offered for carriage unpackaged or on pallets when the cells or batteries are afforded equivalent protection by the equipment in which they are contained. Devices such as radio frequency identification (RFID) tags, watches and temperature loggers, which are not capable of generating a dangerous evolution of heat, may be carried when intentionally active in strong outer packagings. Additional requirement: Cells or batteries shall be protected against short circuit. - 118 - P903a PACKING INSTRUCTION P903a (Deleted) P903b PACKING INSTRUCTION P903b (Deleted) P904 PACKING INSTRUCTION P904 This instruction applies to UN No. 3245. The following packagings are authorized: (1) Packagings meeting the provisions of 4.1.1.1, 4.1.1.2, 4.1.1.4, 4.1.1.8 and 4.1.3 and so designed that they meet the construction requirements of 6.1.4. Outer packagings constructed of suitable material, and of adequate strength and design in relation to the packaging capacity and its intended use, shall be used. Where this packing instruction is used for the carriage of inner packagings of combination packagings the packaging shall be designed and constructed to prevent inadvertent discharge during normal conditions of carriage. (2) Packagings, which need not conform to the packaging test requirements of Part 6, but conforming to the following: (a) An inner packaging comprising: (i) primary receptacle(s) and a secondary packaging, the primary receptacle(s) or the secondary packaging shall be leakproof for liquids or siftproof for solids; (ii) for liquids, absorbent material placed between the primary receptacle(s) and the secondary packaging. The absorbent material shall be in a quantity sufficient to absorb the entire contents of the primary receptacle(s) so that any release of the liquid substance will not compromise the integrity of the cushioning material or of the outer packaging; (iii) if multiple fragile primary receptacles are placed in a single secondary packaging they shall be individually wrapped or separated to prevent contact between them; (b) An outer packaging shall be strong enough for its capacity, mass and intended use, and with a smallest external dimension of at least 100 mm. For carriage, the mark illustrated below shall be displayed on the external surface of the outer packaging on a background of a contrasting colour and shall be clearly visible and legible. The mark shall be in the form of a square set at an angle of 45° (diamond-shaped) with each side having a length of at least 50 mm; the width of the line shall be at least 2 mm and the letters and numbers shall be at least 6 mm high. Additional requirement: Ice, dry ice and liquid nitrogen When dry ice or liquid nitrogen is used as a coolant, the requirements of 5.5.3 shall apply. When used, ice shall be placed outside the secondary packagings or in the outer packaging or an overpack. Interior supports shall be provided to secure the secondary packaging in the original position. If ice is used, the outside packaging or overpack shall be leakproof. - 119 - P905 PACKING INSTRUCTION P905 This instruction applies to UN Nos. 2990 and 3072. Any suitable packaging is authorized, provided the general provisions of 4.1.1 and 4.1.3 are met, except that packagings need not conform to the requirements of Part 6. When the life saving appliances are constructed to incorporate or are contained in rigid outer weatherproof casings (such as for lifeboats), they may be carried unpackaged. Additional requirements: 1. 2. All dangerous substances and articles contained as equipment within the appliances shall be secured to prevent inadvertent movement and in addition: (a) Signal devices of Class 1 shall be packed in plastics or fibreboard inner packagings; (b) Non-flammable, non-toxic gases shall be contained in cylinders as specified by the competent authority, which may be connected to the appliance; (c) Electric storage batteries (Class 8) and lithium batteries (Class 9) shall be disconnected or electrically isolated and secured to prevent any spillage of liquid; and (d) Small quantities of other dangerous substances (for example in Classes 3, 4.1 and 5.2) shall be packed in strong inner packagings. Preparation for transport and packaging shall include provisions to prevent any accidental inflation of the appliance. P906 PACKING INSTRUCTION This instruction applies to UN Nos. 2315, 3151, 3152 and 3432. The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 are met: P906 (1) For liquids and solids containing or contaminated with PCBs or polyhalogenated biphenyls or terphenyls: Packagings in accordance with P001 or P002, as appropriate; (2) For transformers and condensers and other devices: (a) Packagings in accordance with packing instructions P001 or P002. The articles shall be secured with suitable cushioning material to prevent inadvertent movement during normal conditions of carriage; or (b) Leakproof packagings which are capable of containing, in addition to the devices, at least 1.25 times the volume of the liquid PCBs, polyhalogenated biphenyls or terphenyls present in them. There shall be sufficient absorbent material in the packagings to absorb at least 1.1 times the volume of liquid which is contained in the devices. In general, transformers and condensers shall be carried in leakproof metal packagings which are capable of holding, in addition to the transformers and condensers, at least 1.25 times the volume of the liquid present in them. Notwithstanding the above, liquids and solids not packaged in accordance with P001 and P002 and unpackaged transformers and condensers may be carried in cargo transport units fitted with a leakproof metal tray to a height of at least 800 mm, containing sufficient inert absorbent material to absorb at least 1.1 times the volume of any free liquid. Additional requirement: Adequate provisions shall be taken to seal the transformers and condensers to prevent leakage during normal conditions of carriage. - 120 - P908 PACKING INSTRUCTION P908 This instruction applies to damaged or defective lithium ion cells and batteries and damaged or defective lithium metal cells and batteries, including those contained in equipment, of UN Nos. 3090, 3091, 3480 and 3481. The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met: For cells and batteries and equipment containing cells and batteries: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G) Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2) Jerricans (3A2, 3B2, 3H2) Packagings shall conform to the packing group II performance level. 1. Each damaged or defective cell or battery or equipment containing such cells or batteries shall be individually packed in inner packaging and placed inside an outer packaging. The inner packaging or outer packaging shall be leak-proof to prevent the potential release of electrolyte. 2. Each inner packaging shall be surrounded by sufficient non-combustible and non-conductive thermal insulation material to protect against a dangerous evolution of heat. 3. Sealed packagings shall be fitted with a venting device when appropriate. 4. Appropriate measures shall be taken to minimize the effects of vibrations and shocks, prevent movement of the cells or batteries within the package that may lead to further damage and a dangerous condition during carriage. Cushioning material that is non-combustible and non-conductive may also be used to meet this requirement. 5. Non combustibility shall be assessed according to a standard recognized in the country where the packaging is designed or manufactured. For leaking cells or batteries, sufficient inert absorbent material shall be added to the inner or outer packaging to absorb any release of electrolyte. A cell or battery with a net mass of more than 30 kg shall be limited to one cell or battery per outer packaging. Additional requirement: Cells or batteries shall be protected against short circuit. - 121 - P909 PACKING INSTRUCTION P909 This instruction applies to UN Nos. 3090, 3091, 3480 and 3481 carried for disposal or recycling, either packed together with or packed without non-lithium batteries. (1) Cells and batteries shall be packed in accordance with the following: (a) The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3, are met: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H2); and Jerricans (3A2, 3B2, 3H2). (b) Packagings shall conform to the packing group II performance level. (c) Metal packagings shall be fitted with a non-conductive lining material (e.g. plastics) of adequate strength for the intended use. (2) However, lithium ion cells with a Watt-hour rating of not more than 20 Wh, lithium ion batteries with a Watthour rating of not more than 100 Wh, lithium metal cells with a lithium content of not more than 1 g and lithium metal batteries with an aggregate lithium content of not more than 2 g may be packed in accordance with the following: (a) In strong outer packaging up to 30 kg gross mass meeting the general provisions of 4.1.1, except 4.1.1.3, and 4.1.3. (b) Metal packagings shall be fitted with a non-conductive lining material (e.g. plastics) of adequate strength for the intended use. (3) For cells or batteries contained in equipment, strong outer packagings constructed of suitable material, and of adequate strength and design in relation to the packaging capacity and its intended use, may be used. Packagings need not meet the requirements of 4.1.1.3. Large equipment may be offered for carriage unpackaged or on pallets when the cells or batteries are afforded equivalent protection by the equipment in which they are contained. (4) In addition, for cells or batteries with a gross mass of 12 kg or more employing a strong, impact resistant outer casing, strong outer packagings constructed of suitable material and of adequate strength and design in relation to the packaging’s capacity and its intended use, may be used. Packagings need not meet the requirements of 4.1.1.3. Additional requirements: 1. Cells and batteries shall be designed or packed to prevent short circuits and the dangerous evolution of heat. 2. Protection against short circuits and the dangerous evolution of heat includes, but is not limited to: -individual protection of the battery terminals, -inner packaging to prevent contact between cells and batteries, -batteries with recessed terminals designed to protect against short circuits, or -the use of a non-conductive and non-combustible cushioning material to fill empty space between the cells or batteries in the packaging. 3. Cells and batteries shall be secured within the outer packaging to prevent excessive movement during carriage (e.g. by using a non-combustible and non-conductive cushioning material or through the use of a tightly closed plastics bag). - 122 - R001 PACKING INSTRUCTION R001 The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met: Maximum capacity/maximum net mass Light gauge metal packagings Packing group I Packing group II Packing group III steel, non-removable head (0A1) Not allowed 40 l / 50 kg 40 l / 50 kg steel, removable head (0A2) a Not allowed 40 l / 50 kg 40 l / 50 kg a Not allowed for UN No. 1261 NITROMETHANE. NOTE 1: This instruction applies to solids and liquids (provided the design type is tested and marked appropriately). NOTE 2: For Class 3, packing group II, these packagings may be used only for substances with no subsidiary risk and a vapour pressure of not more than 110 kPa at 50 °C and for slightly toxic pesticides. - 123 - 4.1.4.2 Packing instructions concerning the use of IBCs IBC01 PACKING INSTRUCTION IBC01 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: Metal (31A, 31B and 31N). Special packing provision specific to RID and ADR: BB1 For UN No. 3130, the openings of receptacles for this substance shall be tightly closed by means of two devices in series, one of which shall be screwed or secured in an equivalent manner. IBC02 PACKING INSTRUCTION IBC02 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: (1) Metal (31A, 31B and 31N); (2) Rigid plastics (31H1 and 31H2); (3) Composite (31HZ1). Special packing provisions: B5 For UN Nos. 1791, 2014, 2984 and 3149, IBCs shall be provided with a device to allow venting during carriage. The inlet to the venting device shall be sited in the vapour space of the IBC under maximum filling conditions during carriage. B7 For UN Nos. 1222 and 1865, IBCs with a capacity greater than 450 litres are not permitted due to the substance’s potential for explosion when carried in large volumes. B8 The pure form of this substance shall not be transported in IBCs since it is known to have a vapour pressure of more than 110 kPa at 50 °C or 130 kPa at 55 °C. B15 For UN No. 2031 with more than 55% nitric acid, the permitted use of rigid plastics IBCs and of composite IBCs with a rigid plastics inner receptacle shall be two years from their date of manufacture. B16 For UN No. 3375, IBCs of type 31A and 31N are not allowed without competent authority approval. Special packing provisions specific to RID and ADR: BB2 For UN No.1203, notwithstanding special provision 534 (see 3.3.1), IBCs shall only be used when the actual vapour pressure is not more than 110 kPa at 50 ºC, or 130 kPa at 55 ºC. BB4 For UN Nos. 1133, 1139, 1169, 1197, 1210, 1263, 1266, 1286, 1287, 1306, 1866, 1993 and 1999, assigned to packing group III in accordance with 2.2.3.1.4, IBCs with a capacity greater than 450 litres are not permitted. IBC03 PACKING INSTRUCTION IBC03 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: (1) Metal (31A, 31B and 31N); (2) Rigid plastics (31H1 and 31H2); (3) Composite (31HZ1, 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Special packing provision: B8 The pure form of this substance shall not be carried in IBCs since it is known to have a vapour pressure of more than 110 kPa at 50 °C or 130 kPa at 55 °C. - 124 - IBC04 PACKING INSTRUCTION IBC04 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N). IBC05 PACKING INSTRUCTION IBC05 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: (1) Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N).); (2) Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); (3) Composite (11HZ1, 21HZ1 and 31HZ1). IBC06 PACKING INSTRUCTION IBC06 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: (1) Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); (2) Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); (3) Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1). Additional requirement: Where the solid may become liquid during carriage see 4.1.3.4. Special packing provisions: B12 For UN No. 2907, IBCs shall meet the packing group II performance level. IBCs meeting the test criteria of packing group I shall not be used. IBC07 PACKING INSTRUCTION The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: (1) Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); (2) Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); (3) Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); (4) Wooden (11C, 11D and 11F). Additional requirements: 1. Where the solid may become liquid during carriage see 4.1.3.4. 2. Liners of wooden IBCs shall be siftproof. - 125 - IBC07 IBC08 PACKING INSTRUCTION IBC08 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: (1) Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); (2) Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); (3) Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); (4) Fibreboard (11G); (5) Wooden (11C, 11D and 11F); (6) Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2). Additional requirement: Where the solid may become liquid during carriage see 4.1.3.4. Special packing provisions: B3 Flexible IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-restistant liner. B4 Flexible, fibreboard or wooden IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. B6 For UN Nos. 1363, 1364, 1365, 1386, 1408, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC testing requirements of Chapter 6.5. B13 Note: For UN Nos. 1748, 2208, 2880, 3485, 3486 and 3487, carriage by sea in IBCs is prohibited according to the IMDG Code. Special packing provision specific to RID and ADR BB3 For UN 3509, IBCs are not required to meet the requirements of 4.1.1.3. IBCs meeting the requirements of 6.5.5, made leak tight or fitted with a leak tight and puncture resistant sealed liner or bag, shall be used. When the only residues are solids which are not liable to become liquid at temperatures likely to be encountered during carriage, flexible IBCs may be used. When liquid residues are present, rigid IBCs that provide a means of retention (e.g. absorbent material) shall be used. Before being filled and handed over for carriage, every IBC shall be inspected to ensure that it is free from corrosion, contamination or other damage. Any IBC showing signs of reduced strength, shall no longer be used (minor dents and scratches are not considered as reducing the strength of the IBC). IBCs intended for the carriage of packagings, discarded, empty, uncleaned with residues of Class 5.1 shall be so constructed or adapted that the goods cannot come into contact with wood or any other combustible material. IBC99 PACKING INSTRUCTION IBC99 Only IBCs which are approved for these goods by the competent authority may be used. A copy of the competent authority approval shall accompany each consignment or the transport document shall include an indication that the packaging was approved by the competent authority. - 126 - IBC100 PACKING INSTRUCTION IBC100 This instruction applies to UN Nos. 0082, 0222, 0241, 0331 and 0332. The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 and special provisions of 4.1.5 are met: (1) Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); (2) Flexible (13H2, 13H3, 13H4, 13L2, 13L3, 13L4 and 13M2); (3) Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); (4) Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2). Additional requirements: 1. IBCs shall only be used for free flowing substances. 2. Flexible IBCs shall only be used for solids. Special packing provisions: B3 For UN No. 0222, flexible IBCs shall be sift-proof and water resistant or shall be fitted with a sift-proof and water resistant liner. B9 For UN No. 0082, this packing instruction may only be used when the substances are mixtures of ammonium nitrate or other inorganic nitrates with other combustible substances which are not explosive ingredients. Such explosives shall not contain nitroglycerin, similar liquid organic nitrates, or chlorates. Metal IBCs are not authorized. B10 For UN No. 0241, this packing instruction may only be used for substances which consist of water as an essential ingredient and high proportions of ammonium nitrate or other oxidizing substances some or all of which are in solution. The other constituents may include hydrocarbons or aluminium powder, but shall not include nitro-derivatives such as trinitrotoluene. Metal IBCs are not authorized. B17 For UN No. 0222, metal IBCs are not authorized. - 127 - IBC520 PACKING INSTRUCTION IBC520 This instruction applies to organic peroxides and self-reactive substances of type F. The IBCs listed below are authorized for the formulations listed, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 and special provisions of 4.1.7.2 are met. For formulations not listed below, only IBCs which are approved by the competent authority may be used (see 4.1.7.2.2). UN No. Organic peroxide Type of Maximum Control Emer-gency IBC quantity Tempe- Tempera(litres/kg) rature ture 3109 3110 3119 ORGANIC PEROXIDE, TYPE F, LIQUID tert-Butyl hydroperoxide, not more than 72% with water tert-Butyl peroxyacetate, not more than 32% in diluent type A tert-Butyl peroxybenzoate, not more than 32% in diluent type A tert-Butyl peroxy-3,5,5-trimethylhexanoate, not more than 37% in diluent type A Cumyl hydroperoxide, not more than 90% in diluent type A Dibenzoyl peroxide, not more than 42% as a stable dispersion in water Di-tert-butyl peroxide, not more than 52% in diluent type A 1,1-Di-(tert-butylperoxy) cyclohexane, not more than 42% in diluent type A 1,1-Di-(tert-butylperoxy) cyclohexane, not more than 37% in diluent type A Dilauroyl peroxide, not more than 42%, stable dispersion, in water Isopropyl cumyl hydroperoxide, not more than 72% in diluent type A p-Menthyl hydroperoxide, not more than 72% in diluent type A Peroxyacetic acid, stabilized, not more than 17% ORGANIC PEROXIDE, TYPE F, SOLID Dicumyl peroxide ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED tert-Amyl peroxypivalate, not more than 32% in diluent type A tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent type B tert-Butyl peroxyneodecanoate, not more than 32% in diluent type A tert-Butyl peroxyneodecanoate, not more than 52%, stable dispersion, in water tert-Butyl peroxypivalate, not more than 27% in diluent type B Cumyl peroxyneodecanoate, not more than 52%, stable dispersion, in water 31A 31A 31HA1 31A 1 250 1 250 1 000 1 250 31A 31HA1 31HA1 1 250 1 000 1 250 31H1 1 000 31A 31HA1 31H1 1 250 1 000 1 000 31A 1 250 31HA1 1 000 31HA1 1 250 31HA1 1 250 31A 31H1 31H2 31HA1 1 500 1 500 1 500 1 500 31A 31H1 31HA1 2 000 31A 1 250 +10 °C +15 °C 31HA1 31A 31A 1 000 1 250 1 250 +30 °C +30 °C 0 °C +35 °C +35 °C +10 °C 31A 1 250 -5 °C +5 °C 31HA1 31A 31A 1 000 1 250 1 250 +10 °C +10 °C -15 °C +15 °C +15 °C - 5 °C (Cont'd on next page) - 128 - IBC520 PACKING INSTRUCTION (cont’d) UN No. Organic peroxide 3119 (cont'd) tert-Butyl peroxyneodecanoate, not more than 42% stable dispersion, in water Di-(4-tert-butylcyclohexyl) peroxydicarbonate, not more than 42%, stable dispersion, in water Dicetyl peroxydicarbonate, not more than 42%, stable dispersion, in water Di-(2-neodecanoylperoxyisopropyl)benzene, not more than 42%, stable dispersion, in water 3-Hydroxy-1,1-dimethylbutyl peroxyneodecanoate, not more than 52%, stable dispersion, in water Di-(2-ethylhexyl) peroxydicarbonate, not more than 62%, stable dispersion, in water Dimyristyl peroxydicarbonate, not more than 42%, stable dispersion, in water Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 52% in diluent type A Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 52%, stable dispersion, in water 1,1,3,3-Tetramethylbutyl peroxyneodecanoate, not more than 52%, stable dispersion, in water Dicyclohexylperoxydicarbonate, not more than 42% as a stable dispersion, in water Diisobutyryl peroxide, not more than 28% as a stable dispersion in water Diisobutyryl peroxide, not more than 42% as a stable dispersion in water IBC520 Type of IBC Maximum quantity (litres) Control Emer-gency Tempe- Temperarature ture 31A 1 250 - 5 °C + 5 °C 31HA1 1 000 +30 °C +35 °C 31HA1 1 000 +30 °C +35 °C 31A 1 250 -15 °C -5 °C 31A 1 250 -15 °C -5 °C 31A 1 250 -20 °C -10 °C 31HA1 1 000 +15 °C +20 °C 31HA1 31A 31A 1 000 1 250 1 250 +10 °C +10 °C +10 °C +15 °C +15 °C +15 °C 31A 31HA1 31A 1 250 1 000 1 250 - 5 °C -5 °C +10 °C + 5 °C +5 °C +15 °C 31HA1 31A 31HA1 31A 1 000 1 250 1 000 1 250 -20 ºC -20 ºC -25 ºC -25 ºC -10 ºC -10 ºC -15 ºC -15 ºC 3120 ORGANIC PEROXIDE, TYPE F, SOLID, TEMPERATURE CONTROLLED No formulation listed Additional requirements: 1. IBCs shall be provided with a device to allow venting during carriage. The inlet to the pressure-relief device shall be sited in the vapour space of the IBC under maximum filling conditions during carriage. 2. To prevent explosive rupture of metal IBCs or composite IBCs with complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapours evolved during self-accelerating decomposition or during a period of not less than one hour of fire-engulfment as calculated by the formula in 4.2.1.13.8. The control and emergency temperatures specified in this packing instruction are based on a non-insulated IBC. When consigning an organic peroxide in an IBC in accordance with this instruction, it is the responsibility of the consignor to ensure that: (a) (b) the pressure and emergency relief devices installed on the IBC are designed to take appropriate account of the self-accelerating decomposition of the organic peroxide and of fire-engulfment; and when applicable, the control and emergency temperatures indicated are appropriate, taking into account the design (e.g. insulation) of the IBC to be used. - 129 - IBC620 PACKING INSTRUCTION IBC620 This instruction applies to UN No. 3291. The following IBCs are authorized, provided the general provisions of 4.1.1, except 4.1.1.15, 4.1.2 and 4.1.3 are met: Rigid, leakproof IBCs conforming to the packing group II performance level. Additional requirements: 1. 2. 3. There shall be sufficient absorbent material to absorb the entire amount of liquid present in the IBC. IBCs shall be capable of retaining liquids. IBCs intended to contain sharp objects such as broken glass and needles shall be resistant to puncture. - 130 - 4.1.4.3 Packing instructions concerning the use of large packagings LP01 PACKING INSTRUCTION (LIQUIDS) The following large packagings are authorized provided the general provision of 4.1.1 and 4.1.3 are met: Inner packagings Glass 10 litres Plastics 30 litres Metal 40 litres Large outer packagings Steel (50A) Aluminium (50B) Metal other than steel or aluminium (50N) Rigid plastics (50H) Natural wood (50C) Plywood (50D) Reconstituted wood (50F) Fibreboard (50G) Packing group I Packing group II Packing group III Not allowed Not allowed Maximum capacity: 3 m3 LP02 PACKING INSTRUCTION (SOLIDS) The following large packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met: Inner packagings Glass 10 kg b Plastics 50 kg Metal 50 kg Paper a, b 50 kg Fibre a, b 50 kg Large outer packagings Steel (50A) Aluminium (50B) Metal other than steel or aluminium (50N) Rigid plastics (50H) Natural wood (50C) Plywood (50D) Reconstituted wood (50F) Fibreboard (50G) Flexible plastics (51H) c LP01 LP02 Packing group I Packing group II Packing group III Not allowed Not allowed Maximum capacity: 3 m3 a These inner packagings shall not be used when the substances being carried may become liquid during carriage. b These inner packagings shall be sift-proof. c To be used with flexible inner packagings only. Special packing provisions: L2 For UN 1950 aerosols, the large packaging shall meet the packing group III performance level. Large packagings for waste aerosols carried in accordance with special provision 327 shall have in addition a means of retaining any free liquid that might escape during carriage e.g. absorbent material. L3 Note: For UN Nos. 2208 and 3486, carriage by sea in large packagings is prohibited. (Cont'd on next page) - 131 - LP02 PACKING INSTRUCTION (SOLIDS) (cont'd) LP02 Special packing provision specific to RID and ADR: LL1 For UN 3509, large packagings are not required to meet the requirements of 4.1.1.3. Large packagings meeting the requirements of 6.6.4, made leak tight or fitted with a leak tight and puncture resistant sealed liner or bag, shall be used. When the only residues are solids which are not liable to become liquid at temperatures likely to be encountered during carriage, flexible large packagings may be used. When liquid residues are present, rigid large packagings that provide a means of retention (e.g. absorbent material) shall be used. Before being filled and handed over for carriage, every large packaging shall be inspected to ensure that it is free from corrosion, contamination or other damage. Any large packaging showing signs of reduced strength, shall no longer be used (minor dents and scratches are not considered as reducing the strength of the large packaging). Large packagings intended for the carriage of packagings, discarded, empty, uncleaned with residues of Class 5.1 shall be so constructed or adapted that the goods cannot come into contact with wood or any other combustible material. LP99 PACKING INSTRUCTION LP99 Only large packagings which are approved for these goods by the competent authority may be used. A copy of the competent authority approval shall accompany each consignment or the transport document shall include an indication that the packaging was approved by the competent authority. LP101 PACKING INSTRUCTION LP101 The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 and special provisions of 4.1.5 are met: Inner packagings Intermediate packagings Large packagings Not necessary Steel (50A) Aluminium (50B) Metal other than steel or aluminium (50N) Rigid plastics (50H) Natural wood (50C) Plywood (50D) Reconstituted wood (50F) Fibreboard (50G) Not necessary Special packing provision: L1 For UN Nos. 0006, 0009, 0010, 0015, 0016, 0018, 0019, 0034, 0035, 0038, 0039, 0048, 0056, 0137, 0138, 0168, 0169, 0171, 0181, 0182, 0183, 0186, 0221, 0243, 0244, 0245, 0246, 0254, 0280, 0281, 0286, 0287, 0297, 0299, 0300, 0301, 0303, 0321, 0328, 0329, 0344, 0345, 0346, 0347, 0362, 0363, 0370, 0412, 0424, 0425, 0434, 0435, 0436, 0437, 0438, 0451, 0488 and 0502: Large and robust explosives articles, normally intended for military use, without their means of initiation or with their means of initiation containing at least two effective protective features, may be carried unpackaged. When such articles have propelling charges or are self-propelled, their ignition systems shall be protected against stimuli encountered during normal conditions of carriage. A negative result in Test Series 4 on an unpackaged article indicates that the article can be considered for carriage unpackaged. Such unpackaged articles may be fixed to cradles or contained in crates or other suitable handling devices. - 132 - LP102 PACKING INSTRUCTION LP102 The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 and special provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Bags water resistant Receptacles fibreboard metal plastics wood Steel (50A) Aluminium (50B) Metal other than steel or aluminium (50N) Rigid plastics (50H) Natural wood (50C) Plywood (50D) Reconstituted wood (50F) Fibreboard (50G) Not necessary Sheets fibreboard, corrugated Tubes fibreboard LP621 PACKING INSTRUCTION LP621 This instruction applies to UN No. 3291. The following large packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 are met: (1) For clinical waste placed in inner packagings: Rigid, leakproof large packagings conforming to the requirements of Chapter 6.6 for solids, at the packing group II performance level, provided there is sufficient absorbent material to absorb the entire amount of liquid present and the large packaging is capable of retaining liquids; (2) For packages containing larger quantities of liquid: Large rigid packagings conforming to the requirements of Chapter 6.6, at the packing group II performance level, for liquids. Additional requirement: Large packagings intended to contain sharp objects such as broken glass and needles shall be resistant to puncture and retain liquids under the performance test conditions in Chapter 6.6. LP902 PACKING INSTRUCTION LP902 This instruction applies to UN No. 3268. Packaged articles: The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 are met: Packagings conforming to the packing group III performance level. The packagings shall be designed and constructed to prevent movement of the articles and inadvertent operation during normal conditions of carriage. Unpackaged articles: The articles may also be carried unpackaged in dedicated handling devices, vehicles, or containers when moved from where they are manufactured to an assembly plant. Additional requirement: Any pressure receptacle shall be in accordance with the requirements of the competent authority for the substance(s) contained in the pressure receptacle(s). - 133 - LP903 PACKING INSTRUCTION LP903 This instruction applies to UN Nos. 3090, 3091, 3480 and 3481. The following large packagings are authorized for a single battery, including for a battery contained in equipment, provided that the general provisions of 4.1.1 and 4.1.3 are met: Rigid large packagings conforming to the packing group II performance level, made of: steel (50A); aluminium (50B); metal other than steel or aluminium (50N); rigid plastics (50H); natural wood (50C); plywood (50D); reconstituted wood (50F); rigid fibreboard (50G). The battery shall be packed so that the battery is protected against damage that may be caused by its movement or placement within the large packaging. Additional requirement: Batteries shall be protected against short circuit. LP904 PACKING INSTRUCTION LP904 This instruction applies to single damaged or defective batteries of UN Nos. 3090, 3091, 3480 and 3481, including those contained in equipment. The following large packagings are authorized for a single damaged or defective battery and for a single damaged or defective battery contained in equipment, provided the general provisions of 4.1.1 and 4.1.3 are met For batteries and equipment containing batteries, large packagings made of: steel (50A) aluminium (50B) metal other than steel or aluminium (50N) rigid plastics (50H) plywood (50D) Packagings shall conform to the packing group II performance level. 1. Each damaged or defective battery or equipment containing such a battery shall be individually packed in an inner packaging and placed inside an outer packaging. The inner packaging or outer packaging shall be leakproof to prevent the potential release of electrolyte. 2. Each inner packaging shall be surrounded by sufficient non-combustible and non-conductive thermal insulation material to protect against a dangerous evolution of heat. 3. Sealed packagings shall be fitted with a venting device when appropriate. 4. Appropriate measures shall be taken to minimize the effects of vibrations and shocks, prevent movement of the battery within the package that may lead to further damage and a dangerous condition during carriage. Cushioning material that is non-combustible and non-conductive may also be used to meet this requirement. 5. Non combustibility shall be assessed according to a standard recognized in the country where the packaging is designed or manufactured. For leaking batteries, sufficient inert absorbent material shall be added to the inner or outer packaging to absorb any release of electrolyte. Additional requirement: Batteries shall be protected against short circuit. 4.1.4.4 (Deleted) - 134 - 4.1.5 Special packing provisions for goods of Class 1 4.1.5.1 The general provisions of Section 4.1.1 shall be met. 4.1.5.2 All packagings for Class 1 goods shall be so designed and constructed that: (a) They will protect the explosives, prevent them escaping and cause no increase in the risk of unintended ignition or initiation when subjected to normal conditions of carriage including foreseeable changes in temperature, humidity and pressure; (b) The complete package can be handled safely in normal conditions of carriage; and (c) The packages will withstand any loading imposed on them by foreseeable stacking to which they will be subject during carriage so that they do not add to the risk presented by the explosives, the containment function of the packagings is not harmed, and they are not distorted in a way or to an extent which will reduce their strength or cause instability of a stack. 4.1.5.3 All explosive substances and articles, as prepared for carriage, shall have been classified in accordance with the procedures detailed in 2.2.1. 4.1.5.4 Class 1 goods shall be packed in accordance with the appropriate packing instruction shown in Column (8) of Table A of Chapter 3.2, as detailed in 4.1.4. 4.1.5.5 Unless otherwise specified in ADR, packagings, including IBCs and large packagings, shall conform to the requirements of chapters 6.1, 6.5 or 6.6, as appropriate, and shall meet their test requirements for packing group II. 4.1.5.6 The closure device of packagings containing liquid explosives shall ensure a double protection against leakage. 4.1.5.7 The closure device of metal drums shall include a suitable gasket; if a closure device includes a screwthread, the ingress of explosive substances into the screw-thread shall be prevented. 4.1.5.8 Packagings for water soluble substances shall be water resistant. Packagings for desensitized or phlegmatized substances shall be closed to prevent changes in concentration during carriage. 4.1.5.9 When the packaging includes a double envelope filled with water which may freeze during transport, a sufficient quantity of an anti-freeze agent shall be added to the water to prevent freezing. Anti-freeze that could create a fire hazard because of its inherent flammability shall not be used. 4.1.5.10 Nails, staples and other closure devices made of metal without protective covering shall not penetrate to the inside of the outer packaging unless the inner packaging adequately protects the explosives against contact with the metal. 4.1.5.11 Inner packagings, fittings and cushioning materials and the placing of explosive substances or articles in packages shall be accomplished in a manner which prevents the explosive substances or articles from becoming loose in the outer packaging under normal conditions of carriage. Metallic components of articles shall be prevented from making contact with metal packagings. Articles containing explosive substances not enclosed in an outer casing shall be separated from each other in order to prevent friction and impact. Padding, trays, partitioning in the inner or outer packaging, mouldings or receptacles may be used for this purpose. 4.1.5.12 Packagings shall be made of materials compatible with, and impermeable to, the explosives contained in the package, so that neither interaction between the explosives and the packaging materials, nor leakage, causes the explosive to become unsafe to carriage, or the hazard division or compatibility group to change. 4.1.5.13 The ingress of explosive substances into the recesses of seamed metal packagings shall be prevented. 4.1.5.14 Plastics packagings shall not be liable to generate or accumulate sufficient static electricity so that a discharge could cause the packaged explosive substances or articles to initiate, ignite or function. - 135 - 4.1.5.15 Large and robust explosives articles, normally intended for military use, without their means of initiation or with their means of initiation containing at least two effective protective features, may be carried unpackaged. When such articles have propelling charges or are self-propelled, their ignition systems shall be protected against stimuli encountered during normal conditions of carriage. A negative result in Test Series 4 on an unpackaged article indicates that the article can be considered for carriage unpackaged. Such unpackaged articles may be fixed to cradles or contained in crates or other suitable handling, storage or launching devices in such a way that they will not become loose during normal conditions of carriage. Where such large explosive articles are as part of their operational safety and suitability tests subjected to test regimes that meet the intentions of ADR and such tests have been successfully undertaken, the competent authority may approve such articles to be carried in accordance with ADR. 4.1.5.16 Explosive substances shall not be packed in inner or outer packagings where the differences in internal and external pressures, due to thermal or other effects, could cause an explosion or rupture of the package. 4.1.5.17 Whenever loose explosive substances or the explosive substance of an uncased or partly cased article may come into contact with the inner surface of metal packagings (1A1, 1A2, 1B1, 1B2, 4A, 4B and metal receptacles), the metal packaging shall be provided with an inner liner or coating (see 4.1.1.2). 4.1.5.18 Packing instruction P101 may be used for any explosive provided the packaging has been approved by a competent authority regardless of whether the packaging complies with the packing instruction assignment in Column (8) of Table A of Chapter 3.2. 4.1.6 Special packing provisions for goods of Class 2 and goods of other classes assigned to packing instruction P200 4.1.6.1 This section provides general requirements applicable to the use of pressure receptacles and open cryogenic receptacles for the carriage of Class 2 substances and goods of other classes assigned to packing instruction P200 (e.g. UN 1051 hydrogen cyanide, stabilized). Pressure receptacles shall be constructed and closed so as to prevent any loss of contents which might be caused under normal conditions of carriage, including by vibration, or by changes in temperature, humidity or pressure (resulting from change in altitude, for example). 4.1.6.2 Parts of pressure receptacles and open cryogenic receptacles which are in direct contact with dangerous goods shall not be affected or weakened by those dangerous goods and shall not cause a dangerous effect (e.g. catalysing a reaction or reacting with the dangerous goods) (see also table of standards at the end of this section). 4.1.6.3 Pressure receptacles, including their closures and open cryogenic receptacles, shall be selected to contain a gas or a mixture of gases according to the requirements of 6.2.1.2 and the requirements of the relevant packing instructions of 4.1.4.1. This sub-section also applies to pressure receptacles which are elements of MEGCs and battery-vehicles. 4.1.6.4 A change of use of a refillable pressure receptacle shall include emptying, purging and evacuation operations to the extent necessary for safe operation (see also table of standards at the end of this section). In addition, a pressure receptacle that previously contained a Class 8 corrosive substance or a substance of another class with a corrosive subsidiary risk shall not be authorized for the carriage of a Class 2 substance unless the necessary inspection and testing as specified in 6.2.1.6 and 6.2.3.5 respectively have been performed. 4.1.6.5 Prior to filling, the packer shall perform an inspection of the pressure receptacle or open cryogenic receptacle and ensure that the pressure receptacle or open cryogenic receptacle is authorized for the substance and, in case of a chemical under pressure, for the propellant to be carried and that the requirements have been met. Shut-off valves shall be closed after filling and remain closed during carriage. The consignor shall verify that the closures and equipment are not leaking. NOTE: Shut-off valves fitted to individual cylinders in bundles may be open during carriage, unless the substance carried is subject to special packing provision ‘k’ or ‘q’ in packing provision P200. - 136 - 4.1.6.6 Pressure receptacles and open cryogenic receptacles shall be filled according to the working pressures, filling ratios and provisions specified in the appropriate packing instruction for the specific substance being filled. Reactive gases and gas mixtures shall be filled to a pressure such that if complete decomposition of the gas occurs, the working pressure of the pressure receptacle shall not be exceeded. Bundles of cylinders shall not be filled in excess of the lowest working pressure of any given cylinder in the bundle. 4.1.6.7 Pressure receptacles, including their closures, shall conform to the design, construction, inspection and testing requirements detailed in Chapter 6.2. When outer packagings are prescribed, the pressure receptacles and open cryogenic receptacles shall be firmly secured therein. Unless otherwise specified in the detailed packing instructions, one or more inner packagings may be enclosed in one outer packaging. 4.1.6.8 Valves shall be designed and constructed in such a way that they are inherently able to withstand damage without release of the contents or shall be protected from damage which could cause inadvertent release of the contents of the pressure receptacle, by one of the following methods (see also table of standards at the end of this section): 4.1.6.9 (a) Valves are placed inside the neck of the pressure receptacle and protected by a threaded plug or cap; (b) Valves are protected by caps. Caps shall possess vent-holes of sufficient cross-sectional area to evacuate the gas if leakage occurs at the valves; (c) Valves are protected by shrouds or guards; (d) Pressure receptacles are carried in frames, (e.g. cylinders in bundles); or (e) Pressure receptacles are carried in protective boxes. For UN pressure receptacles the packaging as prepared for carriage shall be capable of meeting the drop test specified in 6.1.5.3 at the packing group I performance level. Non-refillable pressure receptacles shall: (a) be carried in an outer packaging, such as a box or crate, or in shrink-wrapped or stretchwrapped trays; (b) be of a water capacity less than or equal to 1.25 litres when filled with flammable or toxic gas; (c) not be used for toxic gases with an LC50 less than or equal to 200 ml/m3; and (d) not be repaired after being put into service. 4.1.6.10 Refillable pressure receptacles, other than cryogenic receptacles, shall be periodically inspected according to the provisions of 6.2.1.6, or 6.2.3.5.1 for non UN receptacles, and packing instruction P200, P205 or P206 as applicable. Pressure relief valves for closed cryogenic receptacles shall be subject to periodic inspections and tests according to the provisions of 6.2.1.6.3 and packing instruction P203. Pressure receptacles shall not be filled after they become due for periodic inspection but may be carried after the expiry of the time-limit for purposes of performing inspection or disposal, including the intermediate carriage operations. 4.1.6.11 Repairs shall be consistent with the fabrication and testing requirements of the applicable design and construction standards and are only permitted as indicated in the relevant periodic inspection standards specified in chapter 6.2. Pressure receptacles, other than the jacket of closed cryogenic receptacles, shall not be subjected to repairs of any of the following: (a) weld cracks or other weld defects; (b) cracks in walls; (c) leaks or defects in the material of the wall, head or bottom. - 137 - 4.1.6.12 4.1.6.13 Receptacles shall not be offered for filling: (a) when damaged to such an extent that the integrity of the receptacle or its service equipment may be affected; (b) unless the receptacle and its service equipment has been examined and found to be in good working order; and (c) unless the required certification, retest, and filling markings are legible. Filled receptacles shall not be offered for carriage: (a) when leaking; (b) when damaged to such an extent that the integrity of the receptacle or its service equipment may be affected; (c) unless the receptacle and its service equipment has been examined and found to be in good working order; and (d) unless the required certification, retest, and filling markings are legible. 4.1.6.14 Owners shall, on the basis of a reasoned request from the competent authority, provide it with all the information necessary to demonstrate the conformity of the pressure receptacle in a language easily understood by the competent authority. They shall cooperate with that authority, at its request, on any action taken to eliminate non-conformity of the pressure receptacles which they own. 4.1.6.15 For UN pressure receptacles, the ISO standards listed below shall be applied. For other pressure receptacles, the requirements of section 4.1.6 are considered to have been complied with if the following standards, as relevant, are applied: Applicable paragraphs 4.1.6.2 Reference Title of document ISO 11114-1:2012 Gas cylinders – Compatibility of cylinder and valve materials with gas contents – Part 1: Metallic Materials ISO 11114-2:2000 Transportable gas cylinders – Compatibility of cylinder and valve materials with gas contents – Part 2: Non-metallic Materials 4.1.6.4 ISO 11621:1997 4.1.6.8 Valves with inherent protection Annex A of ISO 10297:2006 Gas cylinders – Procedures for change of gas service NOTE: The EN version of this ISO standard fulfils the requirements and may also be used. Gas cylinder – Refillable gas cylinder valves – Specification and type testing NOTE: The EN version of this ISO standard fulfils the requirements and may also be used Testing and specifications of LPG cylinder valves – self closing EN 13152:2001 + A1:2003 EN 13153:2001 + A1:2003 4.1.6.8 (b) and (c) Testing and specifications of LPG cylinder valves – manually operated EN ISO 14245:2010 Gas cylinders – Specifications and testing of LPG cylinder valves – Self closing (ISO 14245:2006) EN ISO 15995:2010 Gas cylinders – Specifications and testing of LPG cylinder valves – Manually operated (ISO 15995:2006) either ISO 11117:1998 or ISO 11117:2008 + Cor 1:2009 EN 962:1996 + A2:2000 Gas Cylinders – Valve Protection caps and valve guards for industrial and medical gas cylinders – Design construction and tests ISO 16111:2008 Valve protection caps and valve guards for industrial and medical gas cylinders – Design, construction and tests Transportable gas storage devices – Hydrogen absorbed in reversible metal hydride - 138 - 4.1.7 Special packing provisions for organic peroxides (Class 5.2) and self-reactive substances of Class 4.1 4.1.7.0.1 For organic peroxides, all receptacles shall be "effectively closed". Where significant internal pressure may develop in a package by the evolution of a gas, a vent may be fitted, provided the gas emitted will not cause danger, otherwise the degree of filling shall be limited. Any venting device shall be so constructed that liquid will not escape when the package is in an upright position and it shall be able to prevent ingress of impurities. The outer packaging, if any, shall be so designed as not to interfere with the operation of the venting device. 4.1.7.1 Use of packagings (except IBCs) 4.1.7.1.1 Packagings for organic peroxides and self-reactive substances shall conform to the requirements of Chapter 6.1 and shall meet its test requirements for packing group II. 4.1.7.1.2 The packing methods for organic peroxides and self-reactive substances are listed in packing instruction 520 and are designated OP1 to OP8. The quantities specified for each packing method are the maximum quantities authorized per package. 4.1.7.1.3 The packing methods appropriate for the individual currently assigned organic peroxides and selfreactive substances are listed in 2.2.41.4 and 2.2.52.4. 4.1.7.1.4 For new organic peroxides, new self-reactive substances or new formulations of currently assigned organic peroxides or self-reactive substances, the following procedure shall be used to assign the appropriate packing method: (a) ORGANIC PEROXIDE, TYPE B or SELF-REACTIVE SUBSTANCE, TYPE B: Packing method OP5 shall be assigned, provided that the organic peroxide (or self-reactive substance) satisfies the criteria of 20.4.3 (b) (resp. 20.4.2 (b)) of the Manual of Tests and Criteria in a packaging authorized by the packing method. If the organic peroxide (or selfreactive substance) can only satisfy these criteria in a smaller packaging than those authorized by packing method OP5 (viz. one of the packagings listed for OP1 to OP4), then the corresponding packing method with the lower OP number is assigned; (b) ORGANIC PEROXIDE, TYPE C or SELF-REACTIVE SUBSTANCE, TYPE C: Packing method OP6 shall be assigned, provided that the organic peroxide (or self-reactive substance) satisfies the criteria of 20.4.3 (c) (resp. 20.4.2 (c)) of the Manual of Tests and Criteria in a packaging authorized by the packing method. If the organic peroxide (or selfreactive substance) can only satisfy these criteria in a smaller packaging than those authorized by packing method OP6 then the corresponding packing method with the lower OP number is assigned; (c) ORGANIC PEROXIDE, TYPE D or SELF-REACTIVE SUBSTANCE, TYPE D: Packing method OP7 shall be assigned to this type of organic peroxide or self-reactive substance; (d) ORGANIC PEROXIDE, TYPE E or SELF-REACTIVE SUBSTANCE, TYPE E: Packing method OP8 shall be assigned to this type of organic peroxide or self-reactive substance; (e) ORGANIC PEROXIDE, TYPE F or SELF-REACTIVE SUBSTANCE, TYPE F: Packing method OP8 shall be assigned to this type of organic peroxide or self-reactive substance. - 139 - 4.1.7.2 Use of intermediate bulk containers 4.1.7.2.1 The currently assigned organic peroxides specifically listed in packing instruction IBC520 may be carried in IBCs in accordance with this packing instruction. IBCs shall conform to the requirements of Chapter 6.5 and shall meet its test requirements for packing group II. 4.1.7.2.2 Other organic peroxides and self-reactive substances of type F may be carried in IBCs under conditions established by the competent authority of the country of origin when, on the basis of the appropriate tests, that competent authority is satisfied that such carriage may be safely conducted. The tests undertaken shall include those necessary: (a) To prove that the organic peroxide (or self-reactive substance) complies with the principles for classification given in 20.4.3 (f) [resp. 20.4.2 (f)] of the Manual of Tests and Criteria, exit box F of Figure 20.1 (b) of the Manual; (b) To prove the compatibility of all materials normally in contact with the substance during carriage; (c) To determine, when applicable, the control and emergency temperatures associated with the carriage of the product in the IBC concerned as derived from the SADT; (d) To design, when applicable, pressure and emergency relief devices; and (e) To determine if any special provisions are necessary for safe carriage of the substance. If the country of origin is not a Contracting Party to ADR, the classification and transport conditions shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. 4.1.7.2.3 Emergencies to be taken into account are self-accelerating decomposition and fire engulfment. To prevent explosive rupture of metal or composite IBCs with a complete metal casing, the emergencyrelief devices shall be designed to vent all the decomposition products and vapours evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire engulfment calculated by the equations given in 4.2.1.13.8. 4.1.8 Special packing provisions for infectious substances (Class 6.2) 4.1.8.1 Consignors of infectious substances shall ensure that packages are prepared in such a manner that they arrive at their destination in good condition and present no hazard to persons or animals during carriage. 4.1.8.2 The definitions in 1.2.1 and the general packing provisions of 4.1.1.1 to 4.1.1.17, except 4.1.1.3, 4.1.1.9 to 4.1.1.12 and 4.1.1.15 apply to infectious substances packages. However, liquids shall only be filled into packagings which have an appropriate resistance to the internal pressure that may develop under normal conditions of carriage. 4.1.8.3 An itemized list of contents shall be enclosed between the secondary packaging and the outer packaging. When the infectious substances to be carried are unknown, but suspected of meeting the criteria for inclusion in Category A, the words "suspected Category A infectious substance" shall be shown, in parenthesis, following the proper shipping name on the document inside the outer packaging. 4.1.8.4 Before an empty packaging is returned to the consignor, or sent elsewhere, it shall be disinfected or sterilized to nullify any hazard and any label or marking indicating that it had contained an infectious substance shall be removed or obliterated. 4.1.8.5 Provided an equivalent level of performance is maintained, the following variations in the primary receptacles placed within a secondary packaging are allowed without the need for further testing of the completed packaging: - 140 - (a) (b) Primary receptacles of equivalent or smaller size as compared to the tested primary receptacles may be used provided: (i) the primary receptacles are of similar design to the primary receptacle tested (e.g. shape: round, rectangular, etc.); (ii) the material of construction of the primary receptacles (e.g. glass, plastics, metal) offers resistance to impact and stacking forces equivalent to or better than that of the primary receptacles originally tested; (iii) the primary receptacles have the same or smaller openings and the closure is of equivalent design (e.g. screw cap, friction lid, etc.); (iv) sufficient additional cushioning material is used to take up empty spaces and to prevent significant movement of the primary receptacles; and (v) primary receptacles are oriented within the secondary packagings in the same manner as in the tested package; A lesser number of the tested primary receptacles, or of the alternative types of primary receptacles identified in (a) above, may be used provided sufficient cushioning is added to fill the void space(s) and to prevent significant movement of the primary receptacles. 4.1.8.6 Paragraphs 4.1.8.1 to 4.1.8.5 only apply to infectious substances of Category A (UN Nos. 2814 and 2900). They do not apply to UN No. 3373 BIOLOGICAL SUBSTANCE, CATEGORY B (see packing instruction P650 of 4.1.4.1), nor to UN No. 3291 CLINICAL WASTE, UNSPECIFIED, N.O.S. or (BIO) MEDICAL WASTE, N.O.S. or REGULATED MEDICAL WASTE, N.O.S. 4.1.8.7 For the carriage of animal material, packagings or IBCs not specifically authorized in the applicable packing instruction shall not be used for the carriage of a substance or article unless specifically approved by the competent authority of the country of origin2 and provided: (a) The alternative packaging complies with the general requirements of this Part; (b) When the packing instruction indicated in Column (8) of Table A of Chapter 3.2 so specifies, the alternative packaging meets the requirements of Part 6; (c) The competent authority of the country of origin2 determines that the alternative packaging provides at least the same level of safety as if the substance were packed in accordance with a method specified in the particular packing instruction indicated in Column (8) of Table A of Chapter 3.2; and (d) A copy of the competent authority approval accompanies each consignment or the transport document includes an indication that alternative packaging was approved by the competent authority. 4.1.9 Special packing provisions for radioactive material 4.1.9.1 General 4.1.9.1.1 Radioactive material, packagings and packages shall meet the requirements of Chapter 6.4. The quantity of radioactive material in a package shall not exceed the limits specified in 2.2.7.2.2, 2.2.7.2.4.1, 2.2.7.2.4.4, 2.2.7.2.4.5, 2.2.7.2.4.6, special provision 336 of Chapter 3.3 and 4.1.9.3. 2 If the country of origin is not a Contracting Party to ADR, the competent authority of the first Contracting Party to the ADR reached by the consignment. - 141 - The types of packages for radioactive materials covered by ADR, are: (a) (b) (c) (d) (e) (f) (g) (h) Excepted package (see 1.7.1.5); Industrial package Type 1 (Type IP-1 package); Industrial package Type 2 (Type IP-2 package); Industrial package Type 3 (Type IP-3 package); Type A package; Type B(U) package; Type B(M) package; Type C package. Packages containing fissile material or uranium hexafluoride are subject to additional requirements. 4.1.9.1.2 The non-fixed contamination on the external surfaces of any package shall be kept as low as practicable and, under routine conditions of transport, shall not exceed the following limits: (a) 4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters; and (b) 0.4 Bq/cm2 for all other alpha emitters. These limits are applicable when averaged over any area of 300 cm2 of any part of the surface. 4.1.9.1.3 A package shall not contain any items other than those that are necessary for the use of the radioactive material. The interaction between these items and the package under the conditions of carriage applicable to the design, shall not reduce the safety of the package. 4.1.9.1.4 Except as provided in 7.5.11, CV33, the level of non-fixed contamination on the external and internal surfaces of overpacks, containers, tanks, IBCs and vehicles shall not exceed the limits specified in 4.1.9.1.2. 4.1.9.1.5 For radioactive material having other dangerous properties the package design shall take into account those properties. Radioactive material with a subsidiary risk, packaged in packages that do not require competent authority approval, shall be carried in packagings, IBCs, tanks or bulk containers fully complying with the requirements of the relevant chapters of Part 6 as appropriate, as well as applicable requirements of chapters 4.1, 4.2 or 4.3 for that subsidiary risk. 4.1.9.1.6 Before a packaging is first used to carry radioactive material, it shall be confirmed that it has been manufactured in conformity with the design specifications to ensure compliance with the relevant provisions of ADR and any applicable certificate of approval. The following requirements shall also be fulfilled, if applicable: 4.1.9.1.7 (a) If the design pressure of the containment system exceeds 35 kPa (gauge), it shall be ensured that the containment system of each packaging conforms to the approved design requirements relating to the capability of that system to maintain its integrity under that pressure; (b) For each packaging intended for use as a Type B(U), Type B(M) or Type C package and for each packaging intended to contain fissile material, it shall be ensured that the effectiveness of its shielding and containment and, where necessary, the heat transfer characteristics and the effectiveness of the confinement system, are within the limits applicable to or specified for the approved design; (c) For each packaging intended to contain fissile material, it shall be ensured that the effectiveness of the criticality safety features is within the limits applicable to or specified for the design and in particular where, in order to comply with the requirements of 6.4.11.1 neutron poisons are specifically included, checks shall be performed to confirm the presence and distribution of those neutron poisons. Before each shipment of any package, it shall be ensured that the package contains neither: (a) Radionuclides different from those specified for the package design; nor (b) Contents in a form, or physical or chemical state different from those specified for the package design. - 142 - 4.1.9.1.8 Before each shipment of any package, it shall be ensured that all the requirements specified in the relevant provisions of ADR and in the applicable certificates of approval have been fulfilled. The following requirements shall also be fulfilled, if applicable: (a) It shall be ensured that lifting attachments which do not meet the requirements of 6.4.2.2 have been removed or otherwise rendered incapable of being used for lifting the package, in accordance with 6.4.2.3; (b) Each Type B(U), Type B(M) and Type C package shall be held until equilibrium conditions have been approached closely enough to demonstrate compliance with the requirements for temperature and pressure unless an exemption from these requirements has received unilateral approval; (c) For each Type B(U), Type B(M) and Type C package, it shall be ensured by inspection and/or appropriate tests that all closures, valves and other openings of the containment system through which the radioactive contents might escape are properly closed and, where appropriate, sealed in the manner for which the demonstrations of compliance with the requirements of 6.4.8.8 and 6.4.10.3 were made; (d) For packages containing fissile material the measurement specified in 6.4.11.5 (b) and the tests to demonstrate closure of each package as specified in 6.4.11.8 shall be performed. 4.1.9.1.9 The consignor shall also have a copy of any instructions with regard to the proper closing of the package and any preparation for shipment before making any shipment under the terms of the certificates. 4.1.9.1.10 Except for consignments under exclusive use, the transport index of any package or overpack shall not exceed 10, nor shall the criticality safety index of any package or overpack exceed 50. 4.1.9.1.11 Except for packages or overpacks carried under exclusive use under the conditions specified in 7.5.11, CV33 (3.5)(a), the maximum radiation level at any point on any external surface of a package or overpack shall not exceed 2 mSv/h. 4.1.9.1.12 The maximum radiation level at any point on any external surface of a package or overpack under exclusive use shall not exceed 10 mSv/h. 4.1.9.2 Requirements and controls for carriage of LSA material and SCO 4.1.9.2.1 The quantity of LSA material or SCO in a single Type IP-1 package , Type IP-2 package, Type IP-3 package , or object or collection of objects, whichever is appropriate, shall be so restricted that the external radiation level at 3 m from the unshielded material or object or collection of objects does not exceed 10 mSv/h. 4.1.9.2.2 For LSA material and SCO which are or contain fissile material, which is not excepted under 2.2.7.2.3.5, the applicable requirements of 7.5.11, CV33 (4.1) and (4.2) shall be met. 4.1.9.2.3 For LSA material and SCO which are or contain fissile material, the applicable requirements of 6.4.11.1 shall be met. 4.1.9.2.4 LSA material and SCO in groups LSA-I and SCO-I may be carried unpackaged under the following conditions: (a) All unpackaged material other than ores containing only naturally occurring radionuclides shall be carried in such a manner that under routine conditions of carriage there will be no escape of the radioactive contents from the vehicle nor will there be any loss of shielding; (b) Each vehicle shall be under exclusive use, except when only carrying SCO-I on which the contamination on the accessible and the inaccessible surfaces is not greater than ten times the corresponding level according to the definition of "contamination" in 2.2.7.1.2; - 143 - 4.1.9.2.5 (c) For SCO-I where it is suspected that non-fixed contamination exists on inaccessible surfaces in excess of the values specified in 2.2.7.2.3.2 (a)(i), measures shall be taken to ensure that the radioactive material is not released into the vehicle; (d) Unpackaged fissile material shall meet the requirements of 2.2.7.2.3.5 (e). LSA material and SCO, except as otherwise specified in 4.1.9.2.4, shall be packaged in accordance with the table below: Table 4.1.9.2.5: Industrial package requirements for LSA material and SCO Industrial package type Exclusive use Not under exclusive use Radioactive contents LSA-I Solid a Liquid Type IP-1 Type IP-1 Type IP-1 Type IP-2 Solid Liquid and gas Type IP-2 Type IP-2 Type IP-2 Type IP-1 Type IP-2 Type IP-2 Type IP-3 Type IP-3 Type IP-1 Type IP-2 LSA-II LSA-III SCO-I a SCO-II a Under the conditions specified in 4.1.9.2.4, LSA-I material and SCO-I may be carried unpackaged. 4.1.9.3 Packages containing fissile material The contents of packages containing fissile material shall be as specified for the package design either directly in ADR or in the certificate of approval. 4.1.10 Special provisions for mixed packing 4.1.10.1 When mixed packing is permitted in accordance with the provisions of this section, different dangerous goods or dangerous goods and other goods may be packed together in combination packagings conforming to 6.1.4.21, provided that they do not react dangerously with one another and that all other relevant provisions of this Chapter are complied with. NOTE 1: See also 4.1.1.5 and 4.1.1.6. NOTE 2: For radioactive material, see 4.1.9. 4.1.10.2 Except for packages containing Class 1 goods only or Class 7 goods only, if wooden or fibreboard boxes are used as outer packagings, a package containing different goods packed together shall not weigh more than 100 kg. 4.1.10.3 Unless otherwise prescribed by a special provision applicable according to 4.1.10.4, dangerous goods of the same class and the same classification code may be packed together. 4.1.10.4 When indicated for a given entry in Column (9b) of Table A of Chapter 3.2, the following special provisions shall apply to the mixed packing of the goods assigned to that entry with other goods in the same package. MP 1 May only be packed together with goods of the same type within the same compatibility group. MP 2 Shall not be packed together with other goods. MP 3 Mixed packing of UN No. 1873 with UN No. 1802 is permitted. - 144 - MP 4 Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of ADR. However, if this organic peroxide is a hardener or compound system for Class 3 substances, mixed packing is permitted with these substances of Class 3. MP 5 UN No. 2814 and UN No. 2900 may be packed together in a combination packaging in conformity with P620. They shall not be packed together with other goods; this does not apply to UN No. 3373 Biological substance, Category B packed in accordance with P650 or to substances added as coolants, e.g. ice, dry ice or refrigerated liquid nitrogen. MP 6 Shall not be packed together with other goods. This does not apply to substances added as coolants, e.g. ice, dry ice or refrigerated liquid nitrogen. MP 7 May - in quantities not exceeding 5 litres per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of the same class covered by other classification codes when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. MP 8 May - in quantities not exceeding 3 litres per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of the same class covered by other classification codes when mixed packing is also permitted for these; or with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. MP 9 May be packed together in an outer packaging for combination packagings in accordance with 6.1.4.21: - with other goods of Class 2; - with goods of other classes, when the mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. MP 10 May - in quantities not exceeding 5 kg per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. MP 11 May - in quantities not exceeding 5 kg per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21: - 145 - - with goods of the same class covered by other classification codes or with goods of other classes (except substances of packing group I or II of Class 5.1) when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. MP 12 May - in quantities not exceeding 5 kg per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of the same class covered by other classification codes or with goods of other classes (except substances of packing group I or II of Class 5.1) when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. Packagings shall not weigh more than 45 kg. If fibreboard boxes are used as outer packagings however, a package shall not weigh more than 27 kg. MP 13 May - in quantities not exceeding 3 kg per inner packaging and per package - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. MP 14 May - in quantities not exceeding 6 kg per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. MP 15 May - in quantities not exceeding 3 litres per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. MP 16 May - in quantities not exceeding 3 litres per inner packaging and per package - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. - 146 - MP 17 May - in quantities not exceeding 0.5 litre per inner packaging and 1 litre per package be packed together in a combination packaging conforming to 6.1.4.21: - with goods of other classes, except Class 7, when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. MP 18 May - in quantities not exceeding 0.5 kg per inner packaging and 1 kg per package - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of other classes, except Class 7, when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. MP 19 MP 20 May - in quantities not exceeding 5 litres per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of ADR, provided they do not react dangerously with one another. May be packed together with substances covered by the same UN number. Shall not be packed together with goods of Class 1 having different UN numbers, except if provided for by special provision MP 24. Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of ADR. MP 21 May be packed together with articles covered by the same UN number. Shall not be packed together with goods of Class 1 having different UN numbers, except for: (a) (b) their own means of initiation, provided that (i) the means of initiation will not function under normal conditions of carriage; or (ii) such means have at least two effective protective features which prevent explosion of an article in the event of accidental functioning of the means of initiation; or (iii) when such means do not have two effective protective features (i.e. means of initiation assigned to compatibility group B), in the opinion of the competent authority of the country of origin3, the accidental functioning of the means of initiation does not cause the explosion of an article under normal conditions of carriage; articles of compatibility groups C, D and E. 3 If the country of origin is not a Contracting Party to ADR, the approval shall require validation by the competent authority of the first country Contracting Party to ADR reached by the consignment. - 147 - Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of ADR. When goods are packed together in accordance with this special provision, account shall be taken of a possible amendment of the classification of packages in accordance with 2.2.1.1. For the description of the goods in the transport document, see 5.4.1.2.1 (b). MP 22 May be packed together with articles covered by the same UN number. Shall not be packed together with goods of Class 1 having different UN numbers, except (a) With their own means of initiation, provided that the means of initiation will not function under normal conditions of carriage; or (b) With articles of compatibility groups C, D and E; or (c) If provided for by special provision MP 24. Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of ADR. When goods are packed together in accordance with this special provision, account shall be taken of a possible amendment of the classification of packages in accordance with 2.2.1.1. For the description of the goods in the transport document, see 5.4.1.2.1 (b). MP 23 May be packed together with articles covered by the same UN number. Shall not be packed together with goods of Class 1 having different UN numbers, except (a) With their own means of initiation, provided that the means of initiation will not function under normal conditions of carriage; or (b) If provided for by special provision MP 24. Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of ADR. When goods are packed together in accordance with this special provision, account shall be taken of a possible amendment of the classification of packages in accordance with 2.2.1.1. For the description of the goods in the transport document, see 5.4.1.2.1 (b). MP 24 May be packed together with goods with the UN numbers shown in the table below, under the following conditions: - if a letter A is indicated in the table, the goods with those UN numbers may be included in the same package without any special limitation of mass; - if a letter B is indicated in the table, the goods with those UN numbers may be included in the same package up to a total mass of 50 kg of explosive substances. When goods are packed together in accordance with this special provision, account shall be taken of a possible amendment of the classification of packages in accordance with 2.2.1.1. For the description of the goods in the transport document, see 5.4.1.2.1 (b). - 148 - - 149 - UN 0012 0014 0027 0028 0044 0054 0160 0161 0186 0191 0194 0195 0197 0238 0240 0312 0333 0334 0335 0336 0337 0373 0405 0428 0429 0430 0431 0432 0505 0506 0507 No. 0012 A 0014 A 0027 B B B B 0028 B B B B 0044 B B B B 0054 B B B B B B B B B B B B B B B B B B 0160 B B B B 0161 B B B B 0186 B B B B B B B B B B B B B B B B B B 0191 B B B B B B B B B B B B B B B B B B 0194 B B B B B B B B B B B B B B B B B B 0195 B B B B B B B B B B B B B B B B B B 0197 B B B B B B B B B B B B B B B B B B 0238 B B B B B B B B B B B B B B B B B B 0240 B B B B B B B B B B B B B B B B B B 0312 B B B B B B B B B B B B B B B B B B 0333 A A A A 0334 A A A A 0335 A A A A 0336 A A A A 0337 A A A A 0373 B B B B B B B B B B B B B B B B B B 0405 B B B B B B B B B B B B B B B B B B 0428 B B B B B B B B B B B B B B B B B B 0429 B B B B B B B B B B B B B B B B B B 0430 B B B B B B B B B B B B B B B B B B 0431 B B B B B B B B B B B B B B B B B B 0432 B B B B B B B B B B B B B B B B B B 0505 B B B B B B B B B B B B B B B B B B 0506 B B B B B B B B B B B B B B B B B B 0507 B B B B B B B B B B B B B B B B B B CHAPTER 4.2 USE OF PORTABLE TANKS AND UN MULTIPLE-ELEMENT GAS CONTAINERS (MEGCs) NOTE 1: For fixed tanks (tank-vehicles), demountable tanks and tank-containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple element gas containers (MEGCs), see Chapter 4.3; for fibre-reinforced plastics tanks, see Chapter 4.4; for vacuum operated waste tanks, see Chapter 4.5. NOTE 2: Portable tanks and UN MEGCs marked in accordance with the applicable provisions of Chapter 6.7 but which were approved in a State which is not a Contracting Party to ADR may nevertheless be used for carriage under ADR. 4.2.1 General provisions for the use of portable tanks for the carriage of substances of Class 1 and Classes 3 to 9 4.2.1.1 This section provides general provisions applicable to the use of portable tanks for the carriage of substances of Classes 1, 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 7, 8 and 9. In addition to these general provisions, portable tanks shall conform to the design, construction, inspection and testing requirements detailed in 6.7.2. Substances shall be carried in portable tanks conforming to the applicable portable tank instruction identified in Column (10) of the Table A of Chapter 3.2 and described in 4.2.5.2.6 (T1 to T23) and the portable tank special provisions assigned to each substance in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3. 4.2.1.2 During carriage, portable tanks shall be adequately protected against damage to the shell and service equipment resulting from lateral and longitudinal impact and overturning. If the shell and service equipment are so constructed as to withstand impact or overturning it need not be protected in this way. Examples of such protection are given in 6.7.2.17.5. 4.2.1.3 Certain substances are chemically unstable. They are accepted for carriage only when the necessary steps have been taken to prevent their dangerous decomposition, transformation or polymerization during carriage. To this end, care shall in particular be taken to ensure that shells do not contain any substances liable to promote these reactions. 4.2.1.4 The temperature of the outer surface of the shell excluding openings and their closures or of the thermal insulation shall not exceed 70 °C during carriage. When necessary, the shell shall be thermally insulated. 4.2.1.5 Empty portable tanks not cleaned and not gas-free shall comply with the same provisions as portable tanks filled with the previous substance. 4.2.1.6 Substances shall not be carried in the same or in adjoining compartments of shells when they may react dangerously with each other (see definition for "dangerous reaction" in 1.2.1). 4.2.1.7 The design approval certificate, the test report and the certificate showing the results of the initial inspection and test for each portable tank issued by the competent authority or its authorized body shall be retained by the authority or body and the owner. Owners shall be able to provide this documentation upon the request of any competent authority. 4.2.1.8 Unless the name of the substance(s) being carried appears on the metal plate described in 6.7.2.20.2 a copy of the certificate specified in 6.7.2.18.1 shall be made available upon the request of a competent authority or its authorized body and readily provided by the consignor, consignee or agent, as appropriate. - 151 - 4.2.1.9 Degree of filling 4.2.1.9.1 Prior to filling, the consignor shall ensure that the appropriate portable tank is used and that the portable tank is not filled with substances which in contact with the materials of the shell, gaskets, service equipment and any protective linings, are likely to react dangerously with them to form dangerous products or appreciably weaken these materials. The consignor may need to consult the manufacturer of the substance in conjunction with the competent authority for guidance on the compatibility of the substance with the portable tank materials. 4.2.1.9.1.1 Portable tanks shall not be filled above the extent provided in 4.2.1.9.2 to 4.2.1.9.6. The applicability of 4.2.1.9.2, 4.2.1.9.3 or 4.2.1.9.5.1 to individual substances is specified in the applicable portable tank instruction or special provisions in 4.2.5.2.6 or 4.2.5.3 and Column (10) or (11) of Table A of Chapter 3.2. 4.2.1.9.2 The maximum degree of filling (in %) for general use is determined by the formula: Degree of filling  4.2.1.9.3 The maximum degree of filling (in %) for liquids of Class 6.1 and Class 8, in packing groups I and II, and liquids with an absolute vapour pressure of more than 175 kPa (1.75 bar) at 65 °C, is determined by the formula: Degree of filling  4.2.1.9.4 97 1   (t r - t f ) 95 1   (t r - t f ) In these formulae,  is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during carriage (tr) (both in °C). For liquids carried under ambient conditions  could be calculated by the formula:  d 15 - d 50 35d 50 in which d15 and d50 are the densities of the liquid at 15 °C and 50 °C, respectively. 4.2.1.9.4.1 The maximum mean bulk temperature (tr) shall be taken as 50 °C except that, for journeys under temperate or extreme climatic conditions, the competent authorities concerned may agree to a lower or require a higher temperature, as appropriate. 4.2.1.9.5 The provisions of 4.2.1.9.2 to 4.2.1.9.4.1 do not apply to portable tanks which contain substances maintained at a temperature above 50 °C during carriage (e.g. by means of a heating device). For portable tanks equipped with a heating device, a temperature regulator shall be used to ensure the maximum degree of filling is not more than 95% full at any time during carriage. 4.2.1.9.5.1 The maximum degree of filling (in %) for solids carried above their melting point and for elevated temperature liquids shall be determined by the following formula: Degree of filling  95 dr df in which df and dr are the densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during carriage respectively. 4.2.1.9.6 Portable tanks shall not be offered for carriage: (a) With a degree of filling, for liquids having a viscosity less than 2 680 mm2/s at 20 °C or maximum temperature of the substance during carriage in the case of the heated substance, of more than 20% but less than 80% unless the shells of portable tanks are divided, by partitions or surge plates, into sections of not more than 7 500 litres capacity; (b) With residue of substances previously carried adhering to the outside of the shell or service equipment; - 152 - (c) When leaking or damaged to such an extent that the integrity of the portable tank or its lifting or securing arrangements may be affected; and (d) Unless the service equipment has been examined and found to be in good working order. 4.2.1.9.7 Forklift pockets of portable tanks shall be closed off when the tank is filled. This provision does not apply to portable tanks which according to 6.7.2.17.4 need not be provided with a means of closing off the forklift pockets. 4.2.1.10 Additional provisions applicable to the carriage of Class 3 substances in portable tanks 4.2.1.10.1 All portable tanks intended for the carriage of flammable liquids shall be closed and be fitted with relief devices in accordance with 6.7.2.8 to 6.7.2.15. 4.2.1.10.1.1 For portable tanks intended for use only on land, open venting systems may be used if allowed according to Chapter 4.3. 4.2.1.11 Additional provisions applicable to the carriage of Classes 4.1, 4.2 or 4.3 substances (other than Class 4.1 self-reactive substances) in portable tanks (Reserved) NOTE: For Class 4.1 self-reactive substances, see 4.2.1.13.1. 4.2.1.12 Additional provisions applicable to the carriage of Class 5.1 substances in portable tanks (Reserved) 4.2.1.13 Additional provisions applicable to the carriage of Class 5.2 substances and Class 4.1 self-reactive substances in portable tanks 4.2.1.13.1 Each substance shall have been tested and a report submitted to the competent authority of the country of origin for approval. Notification thereof shall be sent to the competent authority of the country of destination. The notification shall contain relevant transport information and the report with test results. The tests undertaken shall include those necessary: (a) To prove the compatibility of all materials normally in contact with the substance during carriage; (b) To provide data for the design of the pressure and emergency relief devices taking into account the design characteristics of the portable tank. Any additional provision necessary for safe carriage of the substance shall be clearly described in the report. 4.2.1.13.2 The following provisions apply to portable tanks intended for the carriage of Type F organic peroxides or Type F self-reactive substances with a Self-Accelerating Decomposition Temperature (SADT) of 55 °C or more. In case of conflict these provisions prevail over those specified in Section 6.7.2. Emergencies to be taken into account are self-accelerating decomposition of the substance and fire-engulfment as described in 4.2.1.13.8. 4.2.1.13.3 The additional provisions for carriage of organic peroxides or self-reactive substances with a SADT less than 55 °C in portable tanks shall be specified by the competent authority of the country of origin. Notification thereof shall be sent to the competent authority of the country of destination. 4.2.1.13.4 The portable tank shall be designed for a test pressure of at least 0.4 MPa (4 bar). 4.2.1.13.5 Portable tanks shall be fitted with temperature sensing devices. 4.2.1.13.6 Portable tanks shall be fitted with pressure-relief devices and emergency-relief devices. Vacuum-relief devices may also be used. Pressure-relief devices shall operate at pressures determined according to both the properties of the substance and the construction characteristics of the portable tank. Fusible elements are not allowed in the shell. - 153 - 4.2.1.13.7 The pressure-relief devices shall consist of spring-loaded valves fitted to prevent significant build-up within the portable tank of the decomposition products and vapours released at a temperature of 50 °C. The capacity and start-to-discharge pressure of the relief valves shall be based on the results of the tests specified in 4.2.1.13.1. The start-to-discharge pressure shall, however, in no case be such that liquid would escape from the valve(s) if the portable tank were overturned. 4.2.1.13.8 The emergency-relief devices may be of the spring-loaded or frangible types, or a combination of the two, designed to vent all the decomposition products and vapours evolved during a period of not less than one hour of complete fire-engulfment as calculated by the following formula: q  70961  F  A 0.82 where: q = heat absorption [W] A = wetted area [m2 ] F = = insulation factor 1 for non-insulated shells, or F U (923 - T) for insulated shells 47032 where: K = heat conductivity of insulation layer L = thickness of insulation layer [W. m-1. K-1] [m] U = K/L = heat transfer coefficient of the insulation T = temperature of the substance at relieving conditions -2 [W. m . K-1] [K] The start-to-discharge pressure of the emergency-relief device(s) shall be higher than that specified in 4.2.1.13.7 and based on the results of the tests referred to in 4.2.1.13.1. The emergency-relief devices shall be dimensioned in such a way that the maximum pressure in the portable tank never exceeds the test pressure of the tank. NOTE: An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the "Manual of Tests and Criteria". 4.2.1.13.9 For insulated portable tanks the capacity and setting of emergency-relief device(s) shall be determined assuming a loss of insulation from 1% of the surface area. 4.2.1.13.10 Vacuum-relief devices and spring-loaded valves shall be provided with flame arresters. Due attention shall be paid to the reduction of the relief capacity caused by the flame arrester. 4.2.1.13.11 Service equipment such as valves and external piping shall be so arranged that no substance remains in them after filling the portable tank. 4.2.1.13.12 Portable tanks may be either insulated or protected by a sun-shield. If the SADT of the substance in the portable tank is 55 °C or less, or the portable tank is constructed of aluminium, the portable tank shall be completely insulated. The outer surface shall be finished in white or bright metal. 4.2.1.13.13 The degree of filling shall not exceed 90% at 15 C. 4.2.1.13.14 The marking as required in 6.7.2.20.2 shall include the UN number and the technical name with the approved concentration of the substance concerned. 4.2.1.13.15 Organic peroxides and self-reactive substances specifically listed in portable tank instruction T23 in 4.2.5.2.6 may be carried in portable tanks. - 154 - 4.2.1.14 Additional provisions applicable to the carriage of Class 6.1 substances in portable tanks (Reserved) 4.2.1.15 Additional provisions applicable to the carriage of Class 6.2 substances in portable tanks (Reserved) 4.2.1.16 Additional provisions applicable to the carriage of Class 7 substances in portable tanks 4.2.1.16.1 Portable tanks used for the carriage of radioactive material shall not be used for the carriage of other goods. 4.2.1.16.2 The degree of filling for portable tanks shall not exceed 90% or, alternatively, any other value approved by the competent authority. 4.2.1.17 Additional provisions applicable to the carriage of Class 8 substances in portable tanks 4.2.1.17.1 Pressure-relief devices of portable tanks used for the carriage of Class 8 substances shall be inspected at intervals not exceeding one year. 4.2.1.18 Additional provisions applicable to the carriage of Class 9 substances in portable tanks (Reserved) 4.2.1.19 Additional provisions applicable to the carriage of solid substances carried above their melting point 4.2.1.19.1 Solid substances carried or offered for carriage above their melting point which are not assigned a portable tank instruction in column (10) of the Table A of Chapter 3.2 or when the assigned portable tank instruction does not apply to carriage at temperatures above their melting point may be carried in portable tanks provided that the solid substances are classified in Classes 4.1, 4.2, 4.3, 5.1, 6.1, 8 or 9 and have no subsidiary risk other than that of Class 6.1 or Class 8 and are in packing group II or III. 4.2.1.19.2 Unless otherwise indicated in the Table A of Chapter 3.2, portable tanks used for the carriage of these solid substances above their melting point shall conform to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II. A portable tank which affords an equivalent or greater level of safety may be selected according to 4.2.5.2.5. The maximum degree of filling (in %) shall be determined according to 4.2.1.9.5 (TP3). 4.2.2 General provisions for the use of portable tanks for the carriage of non-refrigerated liquefied gases and chemicals under pressure 4.2.2.1 This section provides general provisions applicable to the use of portable tanks for the carriage of nonrefrigerated liquefied gases and chemicals under pressure. 4.2.2.2 Portable tanks shall conform to the design, construction, inspection and testing requirements detailed in 6.7.3. Non-refrigerated liquefied gases and chemicals under pressure shall be carried in portable tanks conforming to portable tank instruction T50 as described in 4.2.5.2.6 and any portable tank special provisions assigned to specific non-refrigerated liquefied gases in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3. 4.2.2.3 During carriage, portable tanks shall be adequately protected against damage to the shell and service equipment resulting from lateral and longitudinal impact and overturning. If the shell and service equipment are so constructed as to withstand impact or overturning it need not be protected in this way. Examples of such protection are given in 6.7.3.13.5. 4.2.2.4 Certain non-refrigerated liquefied gases are chemically unstable. They are accepted for carriage only when the necessary steps have been taken to prevent their dangerous decomposition, transformation or polymerization during carriage. To this end, care shall in particular be taken to ensure that portable tanks do not contain any non-refrigerated liquefied gases liable to promote these reactions. - 155 - 4.2.2.5 Unless the name of the gas(es) being carried appears on the metal plate described in 6.7.3.16.2, a copy of the certificate specified in 6.7.3.14.1 shall be made available upon a competent authority request and readily provided by the consignor, consignee or agent, as appropriate. 4.2.2.6 Empty portable tanks not cleaned and not gas-free shall comply with the same provisions as portable tanks filled with the previous non-refrigerated liquefied gas. 4.2.2.7 Filling 4.2.2.7.1 Prior to filling the portable tank shall be inspected to ensure that it is authorized for the nonrefrigerated liquefied gas or the propellant of the chemical under pressure to be carried and that the portable tank is not loaded with non-refrigerated liquefied gases, or with chemicals under pressure which in contact with the materials of the shell, gaskets, service equipment and any protective linings, are likely to react dangerously with them to form dangerous products or appreciably weaken these materials. During filling, the temperature of the non-refrigerated liquefied gas or propellant of chemicals under pressure shall fall within the limits of the design temperature range. 4.2.2.7.2 The maximum mass of non-refrigerated liquefied gas per litre of shell capacity (kg/l) shall not exceed the density of the non-refrigerated liquefied gas at 50 °C multiplied by 0.95. Furthermore, the shell shall not be liquid-full at 60 °C. 4.2.2.7.3 Portable tanks shall not be filled above their maximum permissible gross mass and the maximum permissible load mass specified for each gas to be carried. 4.2.2.8 Portable tanks shall not be offered for carriage: (a) In an ullage condition liable to produce an unacceptable hydraulic force due to surge within the shell; (b) When leaking; (c) When damaged to such an extent that the integrity of the tank or its lifting or securing arrangements may be affected; and (d) Unless the service equipment has been examined and found to be in good working order. 4.2.2.9 Forklift pockets of portable tanks shall be closed off when the tank is filled. This provision does not apply to portable tanks which according to 6.7.3.13.4 need not be provided with a means of closing off the forklift pockets. 4.2.3 General provisions for the use of portable tanks for the carriage of refrigerated liquefied gases 4.2.3.1 This section provides general provisions applicable to the use of portable tanks for the carriage of refrigerated liquefied gases. 4.2.3.2 Portable tanks shall conform to the design, construction, inspection and testing requirements detailed in 6.7.4. Refrigerated liquefied gases shall be carried in portable tanks conforming to portable tank instruction T75 as described in 4.2.5.2.6 and the portable tank special provisions assigned to each substance in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3. 4.2.3.3 During carriage, portable tanks shall be adequately protected against damage to the shell and service equipment resulting from lateral and longitudinal impact and overturning. If the shell and service equipment are so constructed as to withstand impact or overturning it need not be protected in this way. Examples of such protection are provided in 6.7.4.12.5. 4.2.3.4 Unless the name of the gas(es) being carried appears on the metal plate described in 6.7.4.15.2, a copy of the certificate specified in 6.7.4.13.1 shall be made available upon a competent authority request and readily provided by the consignor, consignee or agent, as appropriate. 4.2.3.5 Empty portable tanks not cleaned and not gas-free shall comply with the same provisions as portable tanks filled with the previous substance. - 156 - 4.2.3.6 Filling 4.2.3.6.1 Prior to filling the portable tank shall be inspected to ensure that it is authorized for the refrigerated liquefied gas to be carried and that the portable tank is not loaded with refrigerated liquefied gases which in contact with the materials of the shell, gaskets, service equipment and any protective linings, are likely to react dangerously with them to form dangerous products or appreciably weaken these materials. During filling, the temperature of the refrigerated liquefied gas shall be within the limits of the design temperature range. 4.2.3.6.2 In estimating the initial degree of filling the necessary holding time for the intended journey including any delays which might be encountered shall be taken into consideration. The initial degree of filling of the shell, except as provided for in 4.2.3.6.3 and 4.2.3.6.4, shall be such that if the contents, except helium, were to be raised to a temperature at which the vapour pressure is equal to the maximum allowable working pressure (MAWP) the volume occupied by liquid would not exceed 98%. 4.2.3.6.3 Shells intended for the carriage of helium can be filled up to but not above the inlet of the pressure-relief device. 4.2.3.6.4 A higher initial degree of filling may be allowed, subject to approval by the competent authority, when the intended duration of carriage is considerably shorter than the holding time. 4.2.3.7 Actual holding time 4.2.3.7.1 The actual holding time shall be calculated for each journey in accordance with a procedure recognized by the competent authority, on the basis of the following: (a) The reference holding time for the refrigerated liquefied gas to be carried (see 6.7.4.2.8.1) (as indicated on the plate referred to in 6.7.4.15.1); (b) The actual filling density; (c) The actual filling pressure; (d) The lowest set pressure of the pressure limiting device(s). 4.2.3.7.2 The actual holding time shall be marked either on the portable tank itself or on a metal plate firmly secured to the portable tank, in accordance with 6.7.4.15.2. 4.2.3.8 Portable tanks shall not be offered for carriage: 4.2.3.9 (a) In an ullage condition liable to produce an unacceptable hydraulic force due to surge within the shell; (b) When leaking; (c) When damaged to such an extent that the integrity of the portable tank or its lifting or securing arrangements may be affected; (d) Unless the service equipment has been examined and found to be in good working order; (e) Unless the actual holding time for the refrigerated liquefied gas being carried has been determined in accordance with 4.2.3.7 and the portable tank is marked in accordance with 6.7.4.15.2; and (f) Unless the duration of carriage, after taking into consideration any delays which might be encountered, does not exceed the actual holding time. Forklift pockets of portable tanks shall be closed off when the tank is filled. This provision does not apply to portable tanks which according to 6.7.4.12.4, need not be provided with a means of closing off the forklift pockets. - 157 - 4.2.4 General provisions for the use of UN multiple-element gas containers (MEGCs) 4.2.4.1 This section provides general requirements applicable to the use of multiple-element gas containers (MEGCs) for the carriage of non-refrigerated gases referred to in 6.7.5. 4.2.4.2 MEGCs shall conform to the design, construction, inspection and testing requirements detailed in 6.7.5. The elements of MEGCs shall be periodically inspected according to the provisions set out in packing instruction P200 of 4.1.4.1 and in 6.2.1.6. 4.2.4.3 During carriage, MEGCs shall be protected against damage to the elements and service equipment resulting from lateral and longitudinal impact and overturning. If the elements and service equipment are so constructed as to withstand impact or overturning, they need not be protected in this way. Examples of such protection are given in 6.7.5.10.4. 4.2.4.4 The periodic testing and inspection requirements for MEGCs are specified in 6.7.5.12. MEGCs or their elements shall not be charged or filled after they become due for periodic inspection but may be carried after the expiry of the time limit. 4.2.4.5 Filling 4.2.4.5.1 Prior to filling, the MEGC shall be inspected to ensure that it is authorized for the gas to be carried and that the applicable provisions of ADR have been met. 4.2.4.5.2 Elements of MEGCs shall be filled according to the working pressures, filling ratios and filling provisions specified in packing instruction P200 of 4.1.4.1 for the specific gas being filled into each element. In no case shall an MEGC or group of elements be filled as a unit in excess of the lowest working pressure of any given element. 4.2.4.5.3 MEGCs shall not be filled above their maximum permissible gross mass. 4.2.4.5.4 Isolation valves shall be closed after filling and remain closed during carriage. Toxic gases (gases of groups T, TF, TC, TO, TFC and TOC) shall only be carried in MEGCs where each element is equipped with an isolation valve. 4.2.4.5.5 The opening(s) for filling shall be closed by caps or plugs. The leakproofness of the closures and equipment shall be verified by the filler after filling. 4.2.4.5.6 MEGCs shall not be offered for filling: 4.2.4.6 (a) when damaged to such an extent that the integrity of the pressure receptacles or its structural or service equipment may be affected; (b) unless the pressure receptacles and its structural and service equipment has been examined and found to be in good working order; and (c) unless the required certification, retest, and filling markings are legible. Charged MEGCs shall not be offered for carriage; (a) when leaking; (b) when damaged to such an extent that the integrity of the pressure receptacles or its structural or service equipment may be affected; unless the pressure receptacles and its structural and service equipment have been examined and found to be in good working order; and (c) (d) 4.2.4.7 unless the required certification, retest, and filling markings are legible. Empty MEGCs that have not been cleaned and purged shall comply with the same requirements as MEGCs filled with the previous substance. - 158 - 4.2.5 Portable tank instructions and special provisions 4.2.5.1 General 4.2.5.1.1 This section includes the portable tank instructions and special provisions applicable to dangerous goods authorized to be carried in portable tanks. Each portable tank instruction is identified by an alpha-numeric code (e.g. T1). Column (10) of Table A of Chapter 3.2 indicates the portable tank instruction that shall be used for each substance permitted for carriage in a portable tank. When no portable tank instruction appears in Column (10) for a specific dangerous goods entry then carriage of the substance in portable tanks is not permitted unless a competent authority approval is granted as detailed in 6.7.1.3. Portable tank special provisions are assigned to specific dangerous goods in Column (11) of Table A of Chapter 3.2. Each portable tank special provision is identified by an alphanumeric code (e.g. TP1). A listing of the portable tank special provisions is provided in 4.2.5.3. NOTE: The gases authorized for carriage in MEGCs are indicated with the letter "(M)" in Column (10) of Table A of Chapter 3.2. 4.2.5.2 Portable tank instructions 4.2.5.2.1 Portable tank instructions apply to dangerous goods of Classes 1 to 9. Portable tank instructions provide specific information relevant to portable tanks provisions applicable to specific substances. These provisions shall be met in addition to the general provisions in this Chapter and the general requirements in Chapter 6.7. 4.2.5.2.2 For substances of Class 1 and Classes 3 to 9, the portable tank instructions indicate the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure relief requirements. In portable tank instruction T23, self-reactive substances of Class 4.1 and Class 5.2 organic peroxides permitted to be carried in portable tanks are listed along with the applicable control and emergency temperatures. 4.2.5.2.3 Non-refrigerated liquefied gases are assigned to portable tank instruction T50. T50 provides the maximum allowable working pressures, the requirements for the openings below liquid level, pressure-relief requirements and maximum filling density requirements for non-refrigerated liquefied gases permitted for carriage in portable tanks. 4.2.5.2.4 Refrigerated liquefied gases are assigned to portable tank instruction T75. 4.2.5.2.5 Determination of the appropriate portable tank instructions When a specific portable tank instruction is specified in Column (10) of Table A of Chapter 3.2 for a specific dangerous goods entry additional portable tanks which possess higher minimum test pressures, greater shell thicknesses, more stringent bottom opening and pressure-relief device arrangements may be used. The following guidelines apply to determining the appropriate portable tanks which may be used for carriage of particular substances: - 159 - Portable tank instruction specified T1 T2 T3 T4 T5 T6 T7 T8 T9 T10 T11 T12 T13 T14 T15 T16 T17 T18 T19 T20 T21 T22 T23 4.2.5.2.6 Portable tank instructions also permitted T2, T3, T4, T5, T6, T7, T8, T9, T10, T11, T12, T13, T14, T15, T16, T17, T18, T19, T20, T21, T22 T4, T5, T7, T8, T9, T10, T11, T12, T13, T14, T15, T16, T17, T18, T19, T20, T21, T22 T4, T5, T6, T7, T8, T9, T10, T11, T12, T13, T14, T15, T16, T17, T18, T19, T20, T21, T22 T5, T7, T8, T9, T10, T11, T12, T13, T14, T15, T16, T17, T18, T19, T20, T21, T22 T10, T14, T19, T20, T22 T7, T8, T9, T10, T11, T12, T13, T14, T15, T16, T17, T18, T19, T20, T21, T22 T8, T9, T10, T11, T12, T13, T14, T15, T16, T17, T18, T19, T20, T21, T22 T9, T10, T13, T14, T19, T20, T21, T22 T10, T13, T14, T19, T20, T21, T22 T14, T19, T20, T22 T12, T13, T14, T15, T16, T17, T18, T19, T20, T21, T22 T14, T16, T18, T19, T20, T22 T14, T19, T20, T21, T22 T19, T20, T22 T16, T17, T18, T19, T20, T21, T22 T18, T19, T20, T22 T18, T19, T20, T21, T22 T19, T20, T22 T20, T22 T22 T22 None None Portable tank instructions Portable tank instructions specify the requirements applicable to a portable tank when used for the carriage of specific substances. Portable tank instructions T1 to T22 specify the applicable minimum test pressure, the minimum shell thickness (in mm reference steel), and the pressure-relief and bottomopening requirements. - 160 - T1 - T22 PORTABLE TANK INSTRUCTIONS T1 - T22 These portable tank instructions apply to liquid and solid substances of Class 1 and Classes 3 to 9. The general provisions of Section 4.2.1 and the requirements of Section 6.7.2 shall be met. Portable tank Minimum test Minimum shell thickness Pressure-relief Bottom opening instruction pressure (bar) (in mm-reference steel) requirementsa requirementsb (see 6.7.2.4) (see 6.7.2.8) (see 6.7.2.6) T1 1.5 See 6.7.2.4.2 Normal See 6.7.2.6.2 T2 1.5 See 6.7.2.4.2 Normal See 6.7.2.6.3 T3 2.65 See 6.7.2.4.2 Normal See 6.7.2.6.2 T4 2.65 See 6.7.2.4.2 Normal See 6.7.2.6.3 T5 2.65 See 6.7.2.4.2 See 6.7.2.8.3 Not allowed T6 4 See 6.7.2.4.2 Normal See 6.7.2.6.2 T7 4 See 6.7.2.4.2 Normal See 6.7.2.6.3 T8 4 See 6.7.2.4.2 Normal Not allowed T9 4 6mm Normal Not allowed T10 4 6mm See 6.7.2.8.3 Not allowed T11 6 See 6.7.2.4.2 Normal See 6.7.2.6.3 T12 6 See 6.7.2.4.2 See 6.7.2.8.3 See 6.7.2.6.3 T13 6 6mm Normal Not allowed T14 6 6mm See 6.7.2.8.3 Not allowed T15 10 See 6.7.2.4.2 Normal See 6.7.2.6.3 T16 10 See 6.7.2.4.2 See 6.7.2.8.3 See 6.7.2.6.3 T17 10 6mm Normal See 6.7.2.6.3 T18 10 6mm See 6.7.2.8.3 See 6.7.2.6.3 T19 10 6mm See 6.7.2.8.3 Not allowed T20 10 8mm See 6.7.2.8.3 Not allowed T21 10 10mm Normal Not allowed T22 10 10mm See 6.7.2.8.3 Not allowed a When the word "Normal" is indicated, all the requirements of 6.7.2.8 apply except for 6.7.2.8.3. When this column indicates "Not allowed", bottom openings are not permitted when the substance to be carried is a liquid (see 6.7.2.6.1). When the substance to be carried is a solid at all temperatures encountered under normal conditions of carriage, bottom openings conforming to the requirements of 6.7.2.6.2 are authorized. b - 161 - T23 PORTABLE TANK INSTRUCTION T23 This portable tank instruction applies to self-reactive substances of Class 4.1 and organic peroxides of Class 5.2. The general provisions of Section 4.2.1 and the requirements of Section 6.7.2 shall be met. The additional provisions specific to self-reactive substances of Class 4.1 and organic peroxides of Class 5.2 in 4.2.1.13 shall also be met. UN Substance Minimum Minimum Bottom Pressure- Degree of Control Emergency No. test shell opening relief filling tempe- temperature pressure thickness requirequirature (bar) (mmrements rements reference steel) 4 See See See 6.7.2.8.2 See 3109 ORGANIC PEROXIDE, 6.7.2.4.2 6.7.2.6.3 4.2.1.13.6 4.2.1.13.13 TYPE F, LIQUID 4.2.1.13.7 tert-Butyl hydro4.2.1.13.8 peroxidea, not more than 72% with water Cumyl hydro-peroxide, not more than 90% in diluent type A Di-tert-butyl peroxide, not more than 32% in diluent type A Isopropyl cumyl hydroperoxide, not more than 72% in diluent type A p-Menthyl hydroperoxide, not more than 72% in diluent type A Pinanyl hydroperoxide, not more than 56% in diluent type A 3110 ORGANIC PEROXIDE TYPE F, SOLID Dicumyl peroxide b 4 See 6.7.2.4.2 3119 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED 4 See 6.7.2.4.2 See See 6.7.2.8.2 See 6.7.2.6.3 4.2.1.13.6 4.2.1.13.13 4.2.1.13.7 4.2.1.13.8 See See See 6.7.2.8.2 6.7.2.6.3 4.2.1.13.6 4.2.1.13.13 4.2.1.13.7 4.2.1.13.8 tert-Amyl peroxyneodecanoate, not more than 47% in diluent type A tert-Butyl peroxyacetate, not more than 32% in diluent type B tert-Butyl peroxy-2ethylhexanoate, not more than 32% in diluent type B a c c -10 °C -5 °C +30 °C +35 °C +15 °C +20 °C Provided that steps have been taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water. b c Maximum quantity per portable tank: 2000 kg. As approved by the competent authority. - 162 - T23 PORTABLE TANK INSTRUCTION (cont'd) T23 This portable tank instruction applies to self-reactive substances of Class 4.1 and organic peroxides of Class 5.2. The general provisions of Section 4.2.1 and the requirements of Section 6.7.2 shall be met. The additional provisions specific to self-reactive substances of Class 4.1 and organic peroxides of Class 5.2 in 4.2.1.13 shall also be met. UN Substance Minimum Minimum Bottom PressureDegree of Control Emergency No. test shell opening relief filling tempe- temperature pressure thickness requirequirature (bar) (mmrements rements reference steel) c 3119 tert-Butyl +5 °C +10 °C (Cont'd) peroxypivalate, not more than 27% in diluent type B tert-Butyl peroxy+35 °C +40 °C 3,5,5-trimethylhexanoate, not more than 32% in diluent type B Di-(3,5,5-trimethyl0 °C +5 °C hexanoyl) peroxide, not more than 38% in diluent type A or type B Peroxyacetic acid, +30 C +35 C distilled, type F, d stabilized c c 3120 ORGANIC 4 See See See 6.7.2.8.2 See PEROXIDE, TYPE F, 6.7.2.4.2 6.7.2.6.3 4.2.1.13.6 4.2.1.13.13 SOLID, 4.2.1.13.7 TEMPERATURE 4.2.1.13.8 CONTROLLED 3229 SELF-REACTIVE 4 See See See See LIQUID TYPE F 6.7.2.4.2 6.7.2.6.3 6.7.2.8.2 4.2.1.13.13 4.2.1.13.6 4.2.1.13.7 4.2.1.13.8 3230 SELF-REACTIVE SOLID TYPE F 4 See 6.7.2.4.2 See 6.7.2.6.3 See 6.7.2.8.2 4.2.1.13.6 4.2.1.13.7 4.2.1.13.8 See 4.2.1.13.13 3239 SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED 4 See 6.7.2.4.2 See 6.7.2.6.3 See 6.7.2.8.2 4.2.1.13.6 4.2.1.13.7 4.2.1.13.8 See 4.2.1.13.13 c c 3240 SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED 4 See 6.7.2.4.2 See 6.7.2.6.3 See 6.7.2.8.2 4.2.1.13.6 4.2.1.13.7 4.2.1.13.8 See 4.2.1.13.13 c c c d As approved by the competent authority. Formulation derived from distillation of peroxyacetic acid originating from peroxyacetic acid in concentration of not more than 41% with water, total active oxygen (Peroxyacetic acid+H2O2)  9.5%, which fulfils the criteria of the Manual of Tests and Criteria, paragraph 20.4.3 (f). "CORROSIVE" subsidiary risk placard required (Model No 8, see 5.2.2.2.2). - 163 - T50 PORTABLE TANK INSTRUCTION T50 This portable tank instruction applies to non-refrigerated liquefied gases and chemicals under pressure (UN Nos. 3500, 3501, 3502, 3503, 3504 and 3505). The general provisions of Section 4.2.2 and the requirements of Section 6.7.3 shall be met. UN Non-refrigerated Max. allowable working Openings Pressure- relief Maximum filling No. liquefied gases pressure (bar): Small; below liquid requirementsb ratio Bare; Sunshield; level (see 6.7.3.7) Insulated; respectivelya 1005 Ammonia, anhydrous 29.0 Allowed See 6.7.3.7.3 0.53 25.7 22.0 19.7 1009 Bromotrifluoromethane 38.0 Allowed Normal 1.13 (Refrigerant gas R 13B1) 34.0 30.0 27.5 1010 Butadienes, stabilized 7.5 Allowed Normal 0.55 7.0 7.0 7.0 1010 Butadienes and hydrocarbon See MAWP definition in Allowed Normal See 4.2.2.7 mixture, stabilized 6.7.3.1 1011 Butane 7.0 Allowed Normal 0.51 7.0 7.0 7.0 1012 Butylene 8.0 Allowed Normal 0.53 7.0 7.0 7.0 1017 Chlorine 19.0 Not Allowed See 6.7.3.7.3 1.25 17.0 15.0 13.5 1018 Chlorodifluoromethane 26.0 Allowed Normal 1.03 (Refrigerant gas R 22) 24.0 21.0 19.0 1020 Chloropentafluoroethane 23.0 Allowed Normal 1.06 (Refrigerant gas R 115) 20.0 18.0 16.0 1021 1-Chloro10.3 Allowed Normal 1.20 1,2,2,2-tetrafluoroethane 9.8 (Refrigerant gas R 124) 7.9 7.0 1027 Cyclopropane 18.0 Allowed Normal 0.53 16.0 14.5 13.0 a "Small" means tanks having a shell with a diameter of 1.5 m or less; "Bare" means tanks having a shell with a diameter of more than 1.5 m without insulation or sun shield (see 6.7.3.2.12); "Sunshield" means tanks having a shell with a diameter of more than 1.5 m with sun shield (see 6.7.3.2.12); "Insulated" means tanks having a shell with a diameter of more than 1.5 m with insulation (see 6.7.3.2.12); (See definition of "Design reference temperature" in 6.7.3.1). b The word "Normal" in the pressure relief requirements column indicates that a frangible disc as specified in 6.7.3.7.3 is not required. - 164 - T50 PORTABLE TANK INSTRUCTION (cont'd) T50 This portable tank instruction applies to non-refrigerated liquefied gases and chemicals under pressure (UN Nos. 3500, 3501, 3502, 3503, 3504 and 3505). The general provisions of Section 4.2.2 and the requirements of Section 6.7.3 shall be met. UN Non-refrigerated Max. allowable working Openings Pressure- relief Maximum filling No. liquefied gases pressure (bar): Small; below liquid requirementsb ratio Bare; Sunshield; level (see 6.7.3.7) Insulated; respectivelya 1028 Dichlorodifluoromethane 16.0 Allowed Normal 1.15 (Refrigerant gas R 12) 15.0 13.0 11.5 1029 Dichlorofluoromethane 7.0 Allowed Normal 1.23 (Refrigerant gas R 21) 7.0 7.0 7.0 1030 1,1-Difluoroethane 16.0 Allowed Normal 0.79 (Refrigerant gas R 152a) 14.0 12.4 11.0 1032 Dimethylamine, anhydrous 7.0 Allowed Normal 0.59 7.0 7.0 7.0 1033 Dimethyl ether 15.5 Allowed Normal 0.58 13.8 12.0 10.6 1036 Ethylamine 7.0 Allowed Normal 0.61 7.0 7.0 7.0 1037 Ethyl chloride 7.0 Allowed Normal 0.80 7.0 7.0 7.0 1040 Ethylene oxide with nitrogen up Not Allowed See 6.7.3.7.3 0.78 to a total pressure of 1MPa (10 bar) at 50 °C 10.0 1041 Ethylene oxide and carbon See MAWP definition in Allowed Normal See 4.2.2.7 dioxide mixture with more than 6.7.3.1 9% but not more than 87% ethylene oxide 1055 Isobutylene 8.1 Allowed Normal 0.52 7.0 7.0 7.0 a "Small" means tanks having a shell with a diameter of 1.5 m or less; "Bare" means tanks having a shell with a diameter of more than 1.5 m without insulation or sun shield (see 6.7.3.2.12); "Sunshield" means tanks having a shell with a diameter of more than 1.5 m with sun shield (see 6.7.3.2.12); "Insulated" means tanks having a shell with a diameter of more than 1.5 m with insulation (see 6.7.3.2.12); (See definition of "Design reference temperature" in 6.7.3.1). b The word "Normal" in the pressure relief requirements column indicates that a frangible disc as specified in 6.7.3.7.3 is not required. - 165 - T50 PORTABLE TANK INSTRUCTION (cont'd) T50 This portable tank instruction applies to non-refrigerated liquefied gases and chemicals under pressure (UN Nos. 3500, 3501, 3502, 3503, 3504 and 3505). The general provisions of Section 4.2.2 and the requirements of Section 6.7.3 shall be met. UN Non-refrigerated Max. allowable working Openings Pressure- relief Maximum filling No. liquefied gases pressure (bar): Small; below liquid requirementsb ratio Bare; Sunshield; (see 6.7.3.7) level Insulated respectivelya 1060 Methyllacetylene and 28.0 Allowed Normal 0.43 propadiene mixture, stabilized 24.5 22.0 20.0 1061 Methylamine, anhydrous 10.8 Allowed Normal 0.58 9.6 7.8 7.0 1062 Methyl bromide with not more 7.0 Not Allowed See 6.7.3.7.3 1.51 than 2% chloropicrin 7.0 7.0 7.0 1063 Methyl chloride 14.5 Allowed Normal 0.81 (Refrigerant gas R 40) 12.7 11.3 10.0 1064 Methyl mercaptan 7.0 Not Allowed See 6.7.3.7.3 0.78 7.0 7.0 7.0 1067 Dinitrogen tetroxide 7.0 Not Allowed See 6.7.3.7.3 1.30 7.0 7.0 7.0 1075 Petroleum gases, liquefied See MAWP definition in Allowed Normal See 4.2.2.7 6.7.3.1 1077 Propylene 28.0 Allowed Normal 0.43 24.5 22.0 20.0 1078 Refrigerant gas, n.o.s. See MAWP definition in Allowed Normal See 4.2.2.7 6.7.3.1 1079 Sulphur dioxide 11.6 Not Allowed See 6.7.3.7.3 1.23 10.3 8.5 7.6 1082 Trifluorochloroethylene, 17.0 Not Allowed See 6.7.3.7.3 1.13 stabilized 15.0 (Refrigerant gas R 1113) 13.1 11.6 a "Small" means tanks having a shell with a diameter of 1.5 m or less; "Bare" means tanks having a shell with a diameter of more than 1.5 m without insulation or sun shield (see 6.7.3.2.12); "Sunshield" means tanks having a shell with a diameter of more than 1.5 m with sun shield (see 6.7.3.2.12); "Insulated" means tanks having a shell with a diameter of more than 1.5 m with insulation (see 6.7.3.2.12); (See definition of "Design reference temperature" in 6.7.3.1). b The word "Normal" in the pressure relief requirements column indicates that a frangible disc as specified in 6.7.3.7.3 is not required. - 166 - T50 PORTABLE TANK INSTRUCTION (cont'd) T50 This portable tank instruction applies to non-refrigerated liquefied gases and chemicals under pressure (UN Nos. 3500, 3501, 3502, 3503, 3504 and 3505). The general provisions of Section 4.2.2 and the requirements of Section 6.7.3 shall be met. UN Non-refrigerated Max. allowable working Openings Pressure- relief Maximum filling No. liquefied gases pressure (bar): Small; below liquid requirementsb ratio Bare; Sunshield; (see 6.7.3.7) level Insulated respectivelya 1083 Trimethylamine, anhydrous 7.0 Allowed Normal 0.56 7.0 7.0 7.0 1085 Vinyl bromide, stabilized 7.0 Allowed Normal 1.37 7.0 7.0 7.0 1086 Vinyl chloride, stabilized 10.6 Allowed Normal 0.81 9.3 8.0 7.0 1087 Vinyl methyl ether, stabilized 7.0 Allowed Normal 0.67 7.0 7.0 7.0 1581 Chloropicrin and methyl 7.0 Not Allowed See 6.7.3.7.3 1.51 bromide mixture with more than 7.0 2% chloropicrin 7.0 7.0 1582 Chloropicrin and methyl 19.2 Not Allowed See 6.7.3.7.3 0.81 chloride mixture 16.9 15.1 13.1 1858 Hexafluoropropylene 19.2 Allowed Normal 1.11 (Refrigerant gas R 1216) 16.9 15.1 13.1 1912 Methyl chloride and methylene 15.2 Allowed Normal 0.81 chloride mixture 13.0 11.6 10.1 1958 1,2-Dichloro-1,1,2,27.0 Allowed Normal 1.30 tetrafluoroethane 7.0 (Refrigerant gas R 114) 7.0 7.0 1965 Hydrocarbon gas, mixture See MAWP definition in Allowed Normal See 4.2.2.7 liquefied, n.o.s. 6.7.3.1 1969 Isobutane 8.5 Allowed Normal 0.49 7.5 7.0 7.0 a "Small" means tanks having a shell with a diameter of 1.5 m or less; "Bare" means tanks having a shell with a diameter of more than 1.5 m without insulation or sun shield (see 6.7.3.2.12); "Sunshield" means tanks having a shell with a diameter of more than 1.5 m with sun shield (see 6.7.3.2.12); "Insulated" means tanks having a shell with a diameter of more than 1.5 m with insulation (see 6.7.3.2.12); (See definition of "Design reference temperature" in 6.7.3.1). b The word "Normal" in the pressure relief requirements column indicates that a frangible disc as specified in 6.7.3.7.3 is not required. - 167 - T50 PORTABLE TANK INSTRUCTION (cont'd) T50 This portable tank instruction applies to non-refrigerated liquefied gases and chemicals under pressure (UN Nos. 3500, 3501, 3502, 3503, 3504 and 3505). The general provisions of Section 4.2.2 and the requirements of Section 6.7.3 shall be met. UN Non-refrigerated Max. allowable working Openings Pressure- relief Maximum filling No. liquefied gases pressure (bar): Small; below liquid requirementsb ratio Bare; Sunshield; (see 6.7.3.7) level Insulated respectivelya 1973 Chlorodifluoromethane and 28.3 Allowed Normal 1.05 chloropentafluoroethane 25.3 mixture with fixed boiling point, 22.8 with approximately 49% 20.3 chlorodifluoromethane (Refrigerant gas R 502) 1974 Chlorodifluorobromomethane 7.4 Allowed Normal 1.61 (Refrigerant gas R 12B1) 7.0 7.0 7.0 1976 Octafluorocyclobutane 8.8 Allowed Normal 1.34 (Refrigerant gas RC 318) 7.8 7.0 7.0 1978 Propane 22.5 Allowed Normal 0.42 20.4 18.0 16.5 1983 1-Chloro-2,2,2-trifluoroethane 7.0 Allowed Normal 1.18 (Refrigerant gas R 133a) 7.0 7.0 7.0 2035 1,1,1-Trifluoroethane 31.0 Allowed Normal 0.76 (Refrigerant gas R 143a) 27.5 24.2 21.8 2424 Octafluoropropane (Refrigerant gas R 218) 2517 1-Chloro-1,1-difluoroethane (Refrigerant gas R 142b) 2602 Dichlorodifluoromethane and 1,1-difluoroethane azeotropic mixture with approximately 74% dichlorodifluoromethane (Refrigerant gas R 500) 23.1 20.8 18.6 16.6 8.9 7.8 7.0 7.0 20.0 18.0 16.0 14.5 a Allowed Normal 1.07 Allowed Normal 0.99 Allowed Normal 1.01 "Small" means tanks having a shell with a diameter of 1.5 m or less; "Bare" means tanks having a shell with a diameter of more than 1.5 m without insulation or sun shield (see 6.7.3.2.12); "Sunshield" means tanks having a shell with a diameter of more than 1.5 m with sun shield (see 6.7.3.2.12); "Insulated" means tanks having a shell with a diameter of more than 1.5 m with insulation (see 6.7.3.2.12); (See definition of "Design reference temperature" in 6.7.3.1). b The word "Normal" in the pressure relief requirements column indicates that a frangible disc as specified in 6.7.3.7.3 is not required. - 168 - T50 PORTABLE TANK INSTRUCTION (cont'd) T50 This portable tank instruction applies to non-refrigerated liquefied gases and chemicals under pressure (UN Nos. 3500, 3501, 3502, 3503, 3504 and 3505). The general provisions of Section 4.2.2 and the requirements of Section 6.7.3 shall be met. UN Non-refrigerated Max. allowable working Openings Pressure- relief Maximum filling No. liquefied gases pressure (bar): Small; below liquid requirementsb ratio Bare; Sunshield; level (see 6.7.3.7) Insulated; respectivelya 3057 Trifluoroacetyl chloride 14.6 Not allowed See 6.7.3.7.3 1.17 12.9 11.3 9.9 3070 Ethylene oxide and dichlorodifluoromethane mixture with not more than 12.5% ethylene oxide 14.0 12.0 11.0 9.0 Allowed See 6.7.3.7.3 1.09 3153 Perfluoro (methyl vinyl ether) 14.3 13.4 11.2 10.2 17.7 15.7 13.8 12.1 See MAWP definition in 6.7.3.1 Allowed Normal 1.14 Allowed Normal 1.04 Allowed Normal See 4.2.2.7 3163 Liquefied gas, n.o.s. See MAWP definition in 6.7.3.1 Allowed Normal See 4.2.2.7 3220 Pentafluoroethane (Refrigerant gas R 125) 34.4 30.8 27.5 24.5 43.0 39.0 34.4 30.5 16.0 14.0 12.5 11.0 8.1 7.0 7.0 7.0 Allowed Normal 0.87 Allowed Normal 0.78 Allowed Normal 1.20 Allowed Normal 1.16 3159 1,1,1,2-Tetrafluoroethane (Refrigerant gas R 134a) 3161 Liquefied gas, flammable, n.o.s. 3252 Difluoromethane (Refrigerant gas R 32) 3296 Heptafluoropropane (Refrigerant gas R 227) 3297 Ethylene oxide and chlorotetrafluoroethane mixture, with not more than 8.8% ethylene oxide a "Small" means tanks having a shell with a diameter of 1.5 m or less; "Bare" means tanks having a shell with a diameter of more than 1.5 m without insulation or sun shield (see 6.7.3.2.12); "Sunshield" means tanks having a shell with a diameter of more than 1.5 m with sun shield (see 6.7.3.2.12); "Insulated" means tanks having a shell with a diameter of more than 1.5 m with insulation (see 6.7.3.2.12); (See definition of "Design reference temperature" in 6.7.3.1). b The word "Normal" in the pressure relief requirements column indicates that a frangible disc as specified in 6.7.3.7.3 is not required. - 169 - T50 PORTABLE TANK INSTRUCTION (cont'd) T50 This portable tank instruction applies to non-refrigerated liquefied gases and chemicals under pressure (UN Nos. 3500, 3501, 3502, 3503, 3504 and 3505). The general provisions of Section 4.2.2 and the requirements of Section 6.7.3 shall be met. UN Non-refrigerated Max. allowable working Openings Pressure- relief Maximum filling No. liquefied gases pressure (bar): Small; below liquid requirementsb ratio Bare; Sunshield; level (see 6.7.3.7) Insulated; respectivelya 3298 Ethylene oxide and 25.9 Allowed Normal 1.02 pentafluoroethane mixture, with 23.4 not more than 7.9% ethylene 20.9 oxide 18.6 3299 Ethylene oxide and 16.7 Allowed Normal 1.03 tetrafluoroethane mixture, with 14.7 not more than 5.6% ethylene 12.9 oxide 11.2 3318 Ammonia solution, relative See MAWP definition in Allowed See 6.7.3.7.3 See 4.2.2.7 density less than 0.880 at 15 °C 6.7.3.1 in water, with more than 50% ammonia 3337 Refrigerant gas R 404A 31.6 Allowed Normal 0.84 28.3 25.3 22.5 3338 Refrigerant gas R 407A 31.3 Allowed Normal 0.95 28.1 25.1 22.4 3339 Refrigerant gas R 407B 33.0 Allowed Normal 0.95 29.6 26.5 23.6 3340 Refrigerant gas R 407C 29.9 Allowed Normal 0.95 26.8 23.9 21.3 3500 Chemical under pressure, n.o.s. See MAWP definition in Allowed See 6.7.3.7.3 TP4c 6.7.3.1 3501 Chemical under pressure, See MAWP definition in Allowed See 6.7.3.7.3 TP4c flammable, n.o.s. 6.7.3.1 Chemical under pressure, toxic, See MAWP definition in Allowed See 6.7.3.7.3 TP4c 3502 n.o.s. 6.7.3.1 Chemical under pressure, See MAWP definition in Allowed See 6.7.3.7.3 TP4c 3503 corrosive, n.o.s. 6.7.3.1 Chemical under pressure, See MAWP definition in Allowed See 6.7.3.7.3 TP4c 3504 flammable, toxic, n.o.s. 6.7.3.1 Chemical under pressure, See MAWP definition in Allowed See 6.7.3.7.3 TP4c 3505 flammable, corrosive, n.o.s. 6.7.3.1 a "Small" means tanks having a shell with a diameter of 1.5 m or less; "Bare" means tanks having a shell with a diameter of more than 1.5 m without insulation or sun shield (see 6.7.3.2.12); "Sunshield" means tanks having a shell with a diameter of more than 1.5 m with sun shield (see 6.7.3.2.12); "Insulated" means tanks having a shell with a diameter of more than 1.5 m with insulation (see 6.7.3.2.12); (See definition of "Design reference temperature" in 6.7.3.1). b The word "Normal" in the pressure relief requirements column indicates that a frangible disc as specified in 6.7.3.7.3 is not required. c For UN Nos. 3500, 3501, 3502, 3503, 3504 and 3505, the degree of filling shall be considered instead of the maximum filling ratio. - 170 - T75 PORTABLE TANK INSTRUCTION T75 This portable tank instruction applies to refrigerated liquefied gases. The general provisions of Section 4.2.3 and the requirements of Section 6.7.4 shall be met. 4.2.5.3 Portable tank special provisions Portable tank special provisions are assigned to certain substances to indicate provisions which are in addition to or in lieu of those provided by the portable tank instructions or the requirements in Chapter 6.7. Portable tank special provisions are identified by an alpha numeric code beginning with the letters "TP" (tank provision) and are assigned to specific substances in Column (11) of Table A of Chapter 3.2. The following is a list of the portable tank special provisions: TP1 The degree of filling prescribed in 4.2.1.9.2 shall not be exceeded. ( Degree of filling  TP2 97 ) 1   (t r  t f ) The degree of filling prescribed in 4.2.1.9.3 shall not be exceeded. ( Degree of filling  95 ) 1   (t r  t f ) TP3 The maximum degree of filling (in %) for solids carried above their melting point and for elevated temperature liquids shall be determined in accordance with 4.2.1.9.5. d ( Degree of filling  95 r ) df TP4 The degree of filling shall not exceed 90% or, alternatively, any other value approved by the competent authority (see 4.2.1.16.2). TP5 The degree of filling prescribed in 4.2.3.6 shall be met. TP6 To prevent the tank bursting in any event, including fire engulfment, it shall be provided with pressure-relief devices which are adequate in relation to the capacity of the tank and to the nature of the substance carried. The device shall also be compatible with the substance. TP7 Air shall be eliminated from the vapour space by nitrogen or other means. TP8 The test pressure may be reduced to 1.5 bar when the flash point of the substances carried is greater than 0 °C. TP9 A substance under this description shall only be carried in a portable tank under an approval granted by the competent authority. TP10 A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority is required. TP12 (Deleted) TP13 (Reserved) TP16 The tank shall be fitted with a special device to prevent under-pressure and excess pressure during normal carriage conditions. This device shall be approved by the competent authority. Pressure-relief requirements are as indicated in 6.7.2.8.3 to prevent crystallization of the product in the pressure-relief valve. - 171 - TP17 Only inorganic non-combustible materials shall be used for thermal insulation of the tank. TP18 Temperature shall be maintained between 18 °C and 40 °C. Portable tanks containing solidified methacrylic acid shall not be reheated during carriage. TP19 The calculated shell thickness shall be increased by 3 mm. Shell thickness shall be verified ultrasonically at intervals midway between periodic hydraulic tests. TP20 This substance shall only be carried in insulated tanks under a nitrogen blanket. TP21 The shell thickness shall be not less than 8 mm. Tanks shall be hydraulically tested and internally inspected at intervals not exceeding 2.5 years. TP22 Lubricant for joints or other devices shall be oxygen compatible. TP23 Carriage permitted under special conditions prescribed by the competent authorities. TP24 The portable tank may be fitted with a device located under maximum filling conditions in the vapour space of the shell to prevent the build up of excess pressure due to the slow decomposition of the substance carried. This device shall also prevent an unacceptable amount of leakage of liquid in the case of overturning or entry of foreign matter into the tank. This device shall be approved by the competent authority or its authorized body. TP25 Sulphur trioxide 99.95% pure and above may be carried in tanks without an inhibitor provided that it is maintained at a temperature equal to or above 32.5 °C. TP26 When carried under heated conditions, the heating device shall be fitted outside the shell. For UN 3176 this requirement only applies when the substance reacts dangerously with water. TP27 A portable tank having a minimum test pressure of 4 bar may be used if it is shown that a test pressure of 4 bar or less is acceptable according to the test pressure definition in 6.7.2.1. TP28 A portable tank having a minimum test pressure of 2.65 bar may be used if it is shown that a test pressure of 2.65 bar or less is acceptable according to the test pressure definition in 6.7.2.1. TP29 A portable tank having a minimum test pressure of 1.5 bar may be used if it is shown that a test pressure of 1.5 bar or less is acceptable according to the test pressure definition in 6.7.2.1. TP30 This substance shall be carried in insulated tanks. TP31 This substance may only be carried in tanks in the solid state. TP32 For UN Nos. 0331, 0332 and 3375, portable tanks may be used subject to the following conditions: (a) To avoid unnecessary confinement, each portable tank constructed of metal shall be fitted with a pressure-relief device that may be of the reclosing spring-loaded type, a frangible disc or a fusible element. The set to discharge or burst pressure, as applicable, shall not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar. (b) For UN 3375 only, the suitability for carriage in tanks shall be demonstrated. One method to evaluate this suitability is test 8 (d) in Test Series 8 (see Manual of Tests and Criteria, Part 1, Sub-section 18.7). - 172 - (c) TP33 TP34 Substances shall not be allowed to remain in the portable tank for any period that could result in caking. Appropriate measures shall be taken to avoid accumulation and packing of substances in the tank (e.g. cleaning, etc). The portable tank instruction assigned for this substance applies to granular and powdered solids and to solids which are filled and discharged at temperatures above their melting point which are cooled and carried as a solid mass. For solids which are carried above their melting point, see 4.2.1.19. Portable tanks need not be subjected to the impact test in 6.7.4.14.1 if the portable tank is marked "NOT FOR RAIL TRANSPORT" on the plate specified in 6.7.4.15.1 and also in letters of at least 10 cm high on both sides of the outer jacket. TP35 Portable tank instruction T14 prescribed in ADR applicable up to 31 December 2008 may continue to be applied until 31 December 2014. TP36 Fusible elements in the vapour space may be used on portable tanks. TP37 Portable tank instruction T14 may continue to be applied until 31 December 2016 except that until that date: (a) For UN Nos. 1810, 2474 and 2668, T7 may be applied; (b) For UN No. 2486, T8 may be applied; and (c) For UN No. 1838, T10 may be applied. TP38 Portable tank instruction T9 prescribed in ADR applicable up to 31 December 2012 may continue to be applied until 31 December 2018. TP39 Portable tank instruction T4 prescribed in ADR applicable up to 31 December 2012 may continue to be applied until 31 December 2018. TP40 Portable tanks shall not be carried when connected with spray application equipment. TP41 With the agreement of the competent authority, the 2.5 year internal examination may be waived or substituted by other test methods or inspection procedures, provided that the portable tank is dedicated to the carriage of the organometallic substances to which this tank special provision is assigned. However this examination is required when the conditions of 6.7.2.19.7 are met. - 173 - CHAPTER 4.3 USE OF FIXED TANKS (TANK-VEHICLES), DEMOUNTABLE TANKS, TANK-CONTAINERS AND TANK SWAP BODIES WITH SHELLS MADE OF METALLIC MATERIALS, AND BATTERY-VEHICLES AND MULTIPLE-ELEMENT GAS CONTAINERS (MEGCs) NOTE: For portable tanks and UN multiple-element gas containers (MEGCs) see Chapter 4.2; for fibrereinforced plastics tanks, see Chapter 4.4; for vacuum operated waste tanks, see Chapter 4.5. 4.3.1 Scope 4.3.1.1 Provisions which take up the whole width of the page apply both to fixed tanks (tank-vehicles), demountable tanks and battery-vehicles, and to tank-containers, tank swap bodies and MEGCs. Provisions contained in a single column apply only to: 4.3.1.2 - fixed tanks (tank-vehicles), demountable tanks and battery-vehicles (left-hand column); - tank-containers, tank swap bodies and MEGCs (right-hand column). These provisions apply to: fixed tanks (tank-vehicles), demountable tanks tank-containers, tank swap bodies and MEGCs and battery-vehicles used for the carriage of gaseous, liquid, powdery or granular substances. 4.3.1.3 Section 4.3.2 lists the provisions applicable to fixed tanks (tank-vehicles), demountable tanks, tankcontainers and tank swap bodies, intended for the carriage of substances of all classes, and to batteryvehicles and MEGCs intended for the carriage of gases of Class 2. Sections 4.3.3 and 4.3.4 contain special provisions adding to or amending the provisions of Section 4.3.2. 4.3.1.4 For requirements concerning the construction, equipment, type approval, tests and marking, see Chapter 6.8. 4.3.1.5 For transitional measures concerning the application of this Chapter, see: 1.6.3. 1.6.4. 4.3.2 Provisions applicable to all classes 4.3.2.1 Use 4.3.2.1.1 A substance subject to ADR may be carried in fixed tanks (tank-vehicles), demountable tanks, batteryvehicles, tank-containers, tank swap bodies and MEGCs only when provision is made for a tank code according to 4.3.3.1.1 and 4.3.4.1.1 in Column (12) of Table A in Chapter 3.2. 4.3.2.1.2 The required type of tank, battery-vehicle and MEGC is given in code form in Column (12) of Table A in Chapter 3.2. The explanations for reading the four parts of the code are given in 4.3.3.1.1 (when the substance to be carried belongs to Class 2) and in 4.3.4.1.1 (when the substance to be carried belongs to Classes 1 and 3 to 9)1. 1 An exception is made for tanks intended for the carriage of substances of classes 1, 5.2 or 7 (see 4.3.4.1.3). - 175 - 4.3.2.1.3 The required type according to 4.3.2.1.2 corresponds to the least stringent construction requirements which are acceptable for the dangerous substance in question unless otherwise prescribed in this Chapter or in Chapter 6.8. It is possible to use tanks corresponding to codes prescribing a higher minimum calculation pressure, or more stringent requirements for filling or discharge openings or for safety valves/devices (see 4.3.3.1.1 for Class 2 and 4.3.4.1.1 for Classes 3 to 9). 4.3.2.1.4 For certain substances, tanks, battery-vehicles or MEGCs are subject to additional provisions which are included as special provisions in Column (13) of Table A in Chapter 3.2. 4.3.2.1.5 Tanks, battery-vehicles and MEGCs shall not be loaded with any dangerous substances other than those for the carriage of which they have been approved according to 6.8.2.3.1 and which, in contact with the materials of the shell, gaskets, equipment and protective linings, are not liable to react dangerously with them (see "dangerous reaction" in 1.2.1), to form dangerous products or appreciably to weaken these materials2. 4.3.2.1.6 Foodstuffs shall not be carried in tanks used for dangerous substances unless the necessary steps have been taken to prevent any harm to public health. 4.3.2.1.7 The tank record shall be retained by the owner or the operator who shall be able to provide this documentation at the request of the competent authority. The tank record shall be maintained throughout the life of the tank and retained for 15 months after the tank is taken out of service. Should a change of owner or operator occur during the life of the tank the tank record shall be transferred to the new owner or operator. Copies of the tank record or all necessary documents shall be made available to the expert for tests, inspections and checks on tanks in accordance with 6.8.2.4.5 or 6.8.3.4.16, on the occasion of periodic inspections or exceptional checks. 4.3.2.2 Degree of filling 4.3.2.2.1 The following degrees of filling shall not be exceeded in tanks intended for the carriage of liquids at ambient temperatures: (a) for flammable substances, environmentally hazardous substances and flammable environmentally hazardous substances, without additional risks (e.g. toxicity or corrosivity), in tanks with a breather device or with safety valves (even where preceded by a bursting disc): Degree of filling  (b) for toxic or corrosive substances (whether flammable or environmentally hazardous or not) in tanks with a breather device or with safety valves (even where preceded by a bursting disc): Degree of filling  (c) 100 % of capacity 1   (50 - t F ) 98 % of capacity 1   (50 - t F ) for flammable substances, environmentally hazardous substances and slightly toxic or corrosive substances (whether flammable or environmentally hazardous or not) in hermetically closed tanks without a safety device: Degree of filling  2 97 % of capacity 1   (50 - t F ) It may be necessary to consult the manufacturer of the substance and the competent authority for guidance on the compatibility of the substance with the materials of the tank, battery-vehicle or MEGC. - 176 - (d) for highly toxic, toxic, highly corrosive or corrosive substances (whether flammable or environmentally hazardous or not) in hermetically closed tanks without a safety device: Degree of filling  4.3.2.2.2 95 % of capacity 1   (50 - t F ) In these formulae,  is the mean coefficient of cubical expansion of the liquid between 15 °C and 50 °C, i.e. for a maximum variation in temperature of 35 °C.  is calculated by the formula:  d15  d 50 35d 50 where d15 and d50 are the relative densities of the liquid at 15 °C and 50 °C respectively. tF is the mean temperature of the liquid during filling. 4.3.2.2.3 The provisions of 4.3.2.2.1 (a) to (d) above shall not apply to tanks whose contents are, by means of a heating device, maintained at a temperature above 50 °C during carriage. In this case the degree of filling at the outset shall be such, and the temperature so regulated, that the tank is not full to more than 95% of its capacity and that the filling temperature is not exceeded, at any time during carriage. 4.3.2.2.4 Shells intended for the carriage of substances in the liquid state or liquefied gases or refrigerated liquefied gases, which are not divided by partitions or surge plates into sections of not more than 7 500 litres capacity, shall be filled to not less than 80% or not more than 20% of their capacity. This provision is not applicable to: - liquids with a kinematic viscosity at 20 °C of at least 2 680 mm2/s; molten substances with a kinematic viscosity at the temperature of filling of at least 2 680 mm2/s; UN 1963 HELIUM, REFRIGERATED, LIQUID and UN 1966 HYDROGEN, REFRIGERATED, LIQUID. 4.3.2.3 Operation 4.3.2.3.1 The thickness of the walls of the shell shall not, throughout its use, fall below the minimum figure prescribed in: 6.8.2.1.17 to 6.8.2.1.21. 6.8.2.1.17 to 6.8.1.20. 4.3.2.3.2 During carriage tank-containers/MEGCs shall be loaded on the carrying vehicle in such a way as to be adequately protected by the fittings of the carrying vehicle or of the tank-container/MEGC itself against lateral and longitudinal impact and against overturning3. If the tankcontainers/MEGCs, including the service equipment, are so constructed as to withstand impact or overturning they need not be protected in this way. 3 Examples of protection of shells: protection against lateral impact may, for example, consist of longitudinal bars protecting the shell on both sides at the level of the median line; protection against overturning may, for example, consist of reinforcing rings or bars fixed transversally in relation to the frame; protection against rear impact, may, for example, consist of a bumper or frame. - 177 - 4.3.2.3.3 During filling and discharge of tanks, battery-vehicles and MEGCs, appropriate measures shall be taken to prevent the release of dangerous quantities of gases and vapours. Tanks, battery-vehicles and MEGCs shall be closed so that the contents cannot spill out uncontrolled. The openings of bottomdischarge tanks shall be closed by means of screw-threaded plugs, blank flanges or other equally effective devices. After filling, the filler shall ensure that all the closures of the tanks, battery-vehicles and MEGCs are in the closed position and there is no leakage. This also applies to the upper part of the dip tube. 4.3.2.3.4 Where several closure systems are fitted in series, that nearest to the substance being carried shall be closed first. 4.3.2.3.5 No dangerous residue of the filling substance shall adhere to the outside of the tank during carriage. 4.3.2.3.6 Substances which may react dangerously with each other shall not be carried in adjoining compartments of tanks. Substances which may react dangerously with each other may be carried in adjoining compartments of tanks, when these compartments are separated by a partition with a wall thickness equal to or greater than that of the tank itself. They may also be carried separated by an empty space or an empty compartment between loaded compartments. 4.3.2.4 Empty tanks, battery-vehicles and MEGCs, uncleaned NOTE: For empty tanks, battery-vehicles and MEGCs, uncleaned, special provisions TU1, TU2, TU4, TU16 and TU35 of 4.3.5 may apply. 4.3.2.4.1 No dangerous residue of the filling substance shall adhere to the outside of the tank during carriage. 4.3.2.4.2 To be accepted for carriage, empty tanks, battery-vehicles and MEGCs, uncleaned, shall be closed in the same manner and be leakproof to the same degree as if they were full. 4.3.2.4.3 Where empty tanks, battery-vehicles and MEGCs, uncleaned, are not closed in the same manner and are not leakproof to the same degree as if they were full and where the provisions of ADR cannot be complied with, they shall be carried, with due regard to adequate safety, to the nearest suitable place where cleaning or repair can be carried out. Carriage is adequately safe if suitable measures have been taken to ensure equivalent safety commensurate with the provisions of ADR and to prevent the uncontrolled release of the dangerous goods. 4.3.2.4.4 Empty fixed tanks (tank-vehicles), demountable tanks, battery-vehicles, tank-containers, tank swap bodies and MEGCs, uncleaned, may also be carried after the expiry of the periods established in 6.8.2.4.2 and 6.8.2.4.3 for undergoing the inspection. - 178 - 4.3.3 Special provisions applicable to Class 2 4.3.3.1 Coding and hierarchy of tanks 4.3.3.1.1 Coding of tanks, battery-vehicles and MEGCs The four parts of the codes (tank codes) given in Column (12) of Table A in Chapter 3.2 have the following meanings: Part 1 Description Types of tank, battery-vehicle or MEGC 2 Calculation pressure 3 Openings (see 6.8.2.2 and 6.8.3.2) 4 Safety valves/devices Tank Code = tank, battery-vehicle or MEGC for compressed gases; = tank, battery-vehicle or MEGC for liquefied gases or dissolved gases; R = tank for refrigerated liquefied gases. X = value of the minimum relevant test pressure according to the table in 4.3.3.2.5; or 22 = minimum calculation pressure in bar. B = tank with bottom filling or discharge openings with 3 closures; or battery-vehicle or MEGC with openings below the surface of the liquid or for compressed gases; C = tank with top filling or discharge openings with 3 closures with only cleaning openings below the surface of the liquid; D = tank with top filling or discharge openings with 3 closures; or battery-vehicle or MEGC with no openings below the surface of the liquid. N = tank, battery-vehicle or MEGC with safety valve according to 6.8.3.2.9 or 6.8.3.2.10 which is not hermetically closed; H = hermetically closed tank, battery-vehicle or MEGC (see 1.2.1); C P NOTE 1: The special provision TU17 indicated in Column (13) of Table A in Chapter 3.2 for certain gases means that the gas may only be carried in a battery-vehicle or MEGC the elements of which are composed of receptacles. NOTE 2: The special provision TU40 indicated in Column (13) of Table A in Chapter 3.2 for certain gases means that the gas may only be carried in a battery-vehicle or MEGC, the elements of which are composed of seamless receptacles. NOTE 3: The pressures indicated on the tank itself or on the panel shall be not less than the value of "X" or the minimum calculation pressure. - 179 - 4.3.3.1.2 Hierarchy of tanks Tank code Other tank code(s) permitted for the substances under this code C*BN C*BH C*CN C*CH C*DN C*DH P*BN P*BH P*CN P*CH P*DN P*DH R*BN R*CN R*DN C#BN, C#CN, C#DN, C#BH, C#CH, C#DH C#BH, C#CH, C#DH C#CN, C#DN, C#CH, C#DH C#CH, C#DH C#DN, C#DH C#DH P#BN, P#CN, P#DN, P#BH, P#CH, P#DH P#BH, P#CH, P#DH P#CN, P#DN, P#CH, P#DH P#CH, P#DH P#DN, P#DH P#DH R#BN, R#CN, R#DN R#CN, R#DN R#DN The figure represented by "#" shall be equal to or greater than the figure represented by "*". NOTE: This hierarchy does not take any special provisions into account (see 4.3.5 and 6.8.4) for each entry. 4.3.3.2 Filling conditions and test pressures 4.3.3.2.1 The test pressure for tanks intended for the carriage of compressed gases shall be at least 1.5 times the working pressure as defined in 1.2.1 for pressure receptacles. 4.3.3.2.2 The test pressure for tanks intended for the carriage of: - high pressure liquefied gases; and - dissolved gases shall be such that, when the shell is filled to the maximum filling ratio, the pressure reached in the shell by the substance at 55 °C for tanks with thermal insulation or 65 °C for tanks without thermal insulation does not exceed the test pressure. 4.3.3.2.3 The test pressure for tanks intended for the carriage of low pressure liquefied gases will be: (a) If the tank is equipped with thermal insulation, at least equal to the vapour pressure, reduced by 0.1 MPa (1 bar) of the liquid at 60 °C, but not less than 1 MPa (10 bar); (b) If the tank is not equipped with thermal insulation, at least equal to the vapour pressure, reduced by 0.1 MPa (1 bar), of the liquid at 65 °C, but not less than 1 MPa (10 bar). The maximum permissible mass of contents per litre of capacity is calculated as follows: Maximum permissible mass of contents per litre of capacity = 0.95  density of the liquid phase at 50 °C (in kg/l) Moreover the vapour phase shall not disappear below 60 °C. If the shells are not more than 1.5 m in diameter, the values of the test pressure and maximum filling ratio conforming to packing instruction P200 in 4.1.4.1 shall be applicable. 4.3.3.2.4 The test pressure for tanks intended for the carriage of refrigerated liquefied gases shall be not less than 1.3 times the maximum allowable working pressure and indicated on the tank but not less - 180 - than 300 kPa (3 bar) (gauge pressure); for tanks with vacuum insulation the test pressure shall be not less than 1.3 times the maximum allowable working pressure increased by 100 kPa (1 bar). 4.3.3.2.5 Table of gases and gas mixtures which may be carried in fixed tanks (tank-vehicles), battery-vehicles, demountable tanks, tank-containers or MEGCs indicating the minimum test pressure for tanks and as far as applicable the filling ratio In the case of gases and gas mixtures classified under n.o.s. entries, the values of the test pressure and the filling ratio shall be prescribed by the expert approved by the competent authority. When tanks for compressed or high pressure liquefied gases have been subjected to a test pressure lower than shown in the table, and the tanks are fitted with thermal insulation, a lower maximum load may be prescribed by the expert approved by the competent authority, provided that the pressure reached in the tank by the substance at 55 °C does not exceed the test pressure stamped on the tank. UN No. Name Classification code 1001 Acetylene, dissolved 4F 1002 1003 1005 1006 1008 Air, compressed Air, refrigerated liquid Ammonia, anhydrous Argon, compressed Boron trifluoride 1A 3O 2 TC 1A 2 TC 1009 Bromotrifluoromethane (Refrigerant gas R13B1) 2A 1010 BUTADIENES, STABILIZED (1,2butadiene) or BUTADIENES, STABILIZED (1,3butadiene) or BUTADIENES AND HYDROCARBON, MIXTURE, STABILIZED Butane 1-butylene or trans-2-butylene or cis-2-butylene or butylenes mixture Carbon dioxide 1010 1010 1011 1012 1012 1012 1012 1013 1016 1017 1018 1020 1021 1022 Carbon monoxide, compressed Chlorine Chlorodifluoromethane (Refrigerant gas R22) Chloropentafluoroethane (Refrigerant gas R115) 1-chloro-1,2,2,2- tetrafluoroethane (Refrigerant gas R124) Chlorotrifluoromethane (Refrigerant gas R13) Minimum test pressure for tanks Maximum permissible mass With thermal Without of contents per insulation thermal litre of capacity insulation MPa bar MPa bar kg only in battery-vehicles and MEGCs composed of receptacles see 4.3.3.2.1 see 4.3.3.2.4 2.6 26 2.9 29 0.53 see 4.3.3.2.1 22.5 225 22.5 225 0.715 30 300 30 300 0.86 12 120 1.50 4.2 42 1.13 12 120 1.44 25 250 1.60 2F 1 10 1 10 0.59 2F 1 10 1 10 0.55 2F 1 10 1 10 0.50 2F 2F 2F 2F 2F 2A 1 1 1 1 1 19 22.5 10 10 10 10 10 190 225 1 1 1 1 1 10 10 10 10 10 19 25 190 250 0.51 0.53 0.54 0.55 0.50 0.73 0.78 0.66 0.75 1.9 2.6 19 26 1.25 1.03 1 TF 2 TOC 2A see 4.3.3.2.1 1.7 17 2.4 24 2A 2 20 2.3 23 1.08 2A 1 10 1.1 11 1.2 2A 12 22.5 120 225 100 120 190 250 0.96 1.12 0.83 0.90 1.04 1.10 10 12 19 25 - 181 - UN No. Name Classification code 1023 1026 1027 1028 Coal gas, compressed Cyanogen Cyclopropane Dichlorodifluoromethane (Refrigerant gas R12) Dichlorofluoromethane (Refrigerant gas R21) 1,1-difluoroethane (Refrigerant gas R152a) Dimethylamine, anhydrous Dimethyl ether Ethane TF 2 TF 2F 2A 1029 1030 1032 1033 1035 1036 1037 1038 1039 1040 1041 1046 1048 1049 1050 1053 1055 1056 1058 Ethylamine Ethyl chloride Ethylene, refrigerated liquid Ethyl methyl ether Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 °C Ethylene oxide and carbon dioxide mixture, with more than 9% but not more than 87% ethylene oxide Helium, compressed Hydrogen bromide, anhydrous Hydrogen, compressed Hydrogen chloride, anhydrous 0.70 0.53 1.15 10 1 10 1.23 2F 1.4 14 1.6 16 0.79 2F 2F 2F 1 1.4 12 10 14 120 1 1.6 10 16 9.5 12 30 1 1 95 120 300 10 10 0.59 0.58 0.32 0.25 0.29 0.39 0.61 0.8 1 1.5 10 15 0.64 0.78 2.6 26 0.73 5.5 55 1.54 10 12 15 20 5 1 100 120 150 200 50 10 0.69 0.30 0.56 0.67 0.74 0.67 0.52 2F 2F 3F 2F 2 TF 2F 1A 2 TC 1F 2 TC 2 TF 1A 1A 2 TOC 1070 Nitrous oxide 2O 1063 kg 1 1064 1065 1066 1067 1061 1062 Maximum permissible mass of contents per litre of capacity 2A Hydrogen sulphide Isobutylene Krypton, compressed Liquefied gases, non flammable, charged with nitrogen, carbon dioxide or air Methylacetylene and propadiene mixture, stabilized: mixture P1 mixture P2 propadiene with 1% to 4% methylacetylene Methylamine, anhydrous Methyl bromide with not more than 2% chloropicrin Methyl chloride (Refrigerant gas R40) Methyl mercaptan Neon, compressed Nitrogen, compressed Dinitrogen tetroxide (nitrogen dioxide) 1060 Minimum test pressure for tanks With thermal Without insulation thermal insulation MPa bar MPa bar see 4.3.3.2.1 10 100 10 100 1.6 16 1.8 18 1.5 15 1.6 16 1 10 1 10 see 4.3.3.2.4 1 10 1.5 15 2.4 24 see 4.3.3.2.1 5 50 see 4.3.3.2.1 12 120 2 TF 2F 1A 2A 4.5 45 1 10 see 4.3.3.2.1 2F see 4.3.3.2.2 or 4.3.3.2.3 1.5  filling pressure see 4.3.3.2.2 or 4.3.3.2.3 2F 2F 2F 2.5 2.2 2.2 25 22 22 2.8 2.3 2.2 28 23 22 0.49 0.47 0.50 2F 2T 1 1 10 10 1.1 1 11 10 0.58 1.51 2F 1.3 13 1.5 15 0.81 - 182 - 1 10 1 10 0.78 see 4.3.3.2.1 see 4.3.3.2.1 only in battery-vehicles and MEGCs composed of receptacles 22.5 225 0.78 18 180 0.68 22.5 225 0.74 UN No. Classification code 1071 1072 1073 1075 1076 Oil gas, compressed Oxygen, compressed Oxygen, refrigerated liquid Petroleum gases, liquefied Phosgene 1 TF 1O 3O 2F 2 TC 1081 Tetrafluoroethylene, stabilized 2F 1077 1078 Propylene Refrigerant gases, n.o.s. such as: mixture F1 mixture F2 mixture F3 2F 2A 2A 2A 2A other mixtures Sulphur dioxide Sulphur hexafluoride 2A 2 TC 2A 1079 1080 1082 Minimum test pressure for tanks Maximum permissible mass With thermal Without of contents per insulation thermal litre of capacity insulation MPa bar MPa bar kg 25 250 0.75 see 4.3.3.2.1 see 4.3.3.2.1 see 4.3.3.2.4 See 4.3.3.2.2 or 4.3.3.2.3 only in battery-vehicles and MEGCs composed of receptacles only in battery-vehicles and MEGCs composed of seamless receptacles 2.5 25 2.7 27 0.43 1 1.5 2.4 10 15 24 1.1 1.6 2.7 see 4.3.3.2.2 or 4.3.3.2.3 1 10 1.2 12 120 7 14 16 1.5 15 1.7 11 16 27 1.23 1.15 1.03 12 70 140 160 17 1.23 1.34 1.04 1.33 1.37 1.13 Trifluorochloroethylene, stabilized (Refrigerant gas R1113) Trimethylamine, anhydrous Vinyl bromide, stabilized Vinyl chloride, stabilized Vinyl methyl ether, stabilized Chloropicrin and methyl bromide mixture with more than 2% chloropicrin 2 TF 2F 2F 2F 2F 2T 1 1 1 1 1 10 10 10 10 10 1 1 1.1 1 1 10 10 11 10 10 0.56 1.37 0.81 0.67 1.51 1582 Chloropicrin and methyl chloride mixture 2T 1.3 13 1.5 15 0.81 1612 1T 1859 Hexaethyl tetraphosphate and compressed gas mixture Chlorine trifluoride Hexafluoropropylene (Refrigerant gas R 1216) Silicon tetrafluoride 1860 Vinyl fluoride, stabilized 2F 1912 Methyl chloride and methylene chloride mixture Neon, refrigerated liquid Argon, refrigerated liquid Ethylene oxide and carbon dioxide mixture, with not more than 9% ethylene oxide Compressed gas, toxic, flammable, n.o.s.a Compressed gas, flammable n.o.s. Compressed gas, toxic, n.o.s.a Compressed gas, n.o.s. Deuterium, compressed 2F 1083 1085 1086 1087 1581 1749 1858 1913 1951 1952 1953 1954 1955 1956 1957 a Name see 4.3.3.2.1 2 TOC 2A 3 1.7 30 17 3 1.9 30 19 1.40 1.11 2 TC 20 30 12 22.5 200 300 120 225 20 30 200 300 1.3 13 25 1.5 250 15 0.74 1.10 0.58 0.65 0.64 0.81 3A 3A 2A see 4.3.3.2.4 see 4.3.3.2.4 19 190 25 250 19 25 190 250 0.66 0.75 1 TF see 4.3.3.2.1 or 4.3.3.2.2 1F 1T 1A 1F see 4.3.3.2.1 or 4.3.3.2.2 see 4.3.3.2.1 or 4.3.3.2.2 see 4.3.3.2.1 or 4.3.3.2.2 see 4.3.3.2.1 Allowed if LC50 equal to or greater than 200 ppm. - 183 - UN No. Name Classification code 1958 1,2-dichloro-1,1,2,2-tetrafluoroethane (Refrigerant gas R114) 1,1-difluoroethylene (Refrigerant gas R1132a) 2A 2F 12 22.5 Ethane, refrigerated liquid Ethylene 3F 2F see 4.3.3.2.4 12 120 22.5 225 1959 Minimum test pressure for tanks With thermal Without insulation thermal insulation MPa bar MPa bar 1 10 1 10 120 225 25 1961 1962 22.5 30 1963 1964 1965 1966 1967 1968 1969 1970 1971 1972 1973 1974 1976 1977 1978 1982 1983 1984 Helium, refrigerated liquid Hydrocarbon gas mixture, compressed, n.o.s. Hydrocarbon gas mixture, liquefied, n.o.s.: 3A 1F Mixture A Mixture A01 Mixture A02 Mixture A0 Mixture A1 Mixture B1 Mixture B2 Mixture B Mixture C Other mixtures Hydrogen, refrigerated liquid Insecticide gas, toxic, n.o.s.a Insecticide gas, n.o.s. Isobutane Krypton, refrigerated liquid Methane, compressed or natural gas, compressed with high methane content Methane, refrigerated liquid or natural gas, refrigerated liquid with high methane content Chlorodifluoromethane and chloropentafluoroethane mixture with fixed boiling point, with approximately 49% chlorodifluoromethane (Refrigerant gas R502) Chlorodifluorobromomethane (Refrigerant gas R12B1) Octafluorocyclobutane (Refrigerant gas RC318) Nitrogen, refrigerated liquid Propane Tetrafluoromethane (Refrigerant gas R14) 2F 2F 2F 2F 2F 2F 2F 2F 2F 2F 3F 2T 2A 2F 3A 1F 1 10 1 1.2 12 1.4 1.2 12 1.4 1.2 12 1.4 1.6 16 1.8 2 20 2.3 2 20 2.3 2 20 2.3 2.5 25 2.7 see 4.3.3.2.2 or 4.3.3.2.3 see 4.3.3.2.4 see 4.3.3.2.2 or 4.3.3.2.3 see 4.3.3.2.2 or 4.3.3.2.3 1 10 1 see 4.3.3.2.4 see 4.3.3.2.1 3F see 4.3.3.2.4 1-chloro-2,2,2-trifluoroethane (Refrigerant gas R133a) Trifluoromethane (Refrigerant gas R23) 2A Hydrogen and methane mixture, compressed kg 1.3 250 0.66 0.78 0.77 225 300 0.25 0.36 0.34 0.37 10 14 14 14 18 23 23 23 27 0.50 0.49 0.48 0.47 0.46 0.45 0.44 0.43 0.42 10 0.49 see 4.3.3.2.4 see 4.3.3.2.1 or 4.3.3.2.2 2F 2A 2.5 25 2.8 28 1.05 2A 1 10 1 10 1.61 2A 1 10 1 10 1.34 see 4.3.3.2.4 2.1 21 20 200 30 300 1 10 2.3 20 30 1 23 200 300 10 0.42 0.62 0.94 1.18 190 250 0.92 0.99 0.87 0.95 3A 2F 2A 2A 19 25 190 250 19 25 2034 Maximum permissible mass of contents per litre of capacity 1F - 184 - see 4.3.3.2.1 UN No. Name 2035 1,1,1-trifluoroethane (Refrigerant gas R143a) Xenon 2036 2044 2073 2187 2189 2191 2193 2F 2A 1 10 1 10 0.80 4A 1.2 12 1.2 12 0.77 1 5 10 50 20 2.1 2.0 200 21 20 0.90 1.1 1.28 1.34 1.10 2.25 0.50 22.5 25 3.0 20 30 1 1.8 1 225 250 30 200 300 10 18 10 0.32 0.36 0.84 0.47 0.70 1.19 1.08 1.34 3A 2 TFC 2T 2A see 4.3.3.2.4 1 10 5 50 16 160 20 200 1.9 19 1.8 18 see 4.3.3.2.4 22.5 225 25 250 2.7 27 20 200 30 300 1 10 1.6 16 1 10 2 TF 2 TC 2419 2420 2422 Bromotrifluoroethylene Hexafluoroacetone Octafluorobut-2-ene (Refrigerant gas R1318) Octafluoropropane (Refrigerant gas R218) Nitrogen trifluoride 2F 2 TC 2A Ethylacetylene, stabilized Ethyl fluoride (Refrigerant gas R161) Methyl fluoride (Refrigerant gas R41) 1-chloro-1,1-difluoroethane (Refrigerant gas R142b) Xenon, refrigerated liquid Chlorotrifluoromethane and trifluoromethane, azeotropic mixture with approximately 60% chlorotrifluoromethane (Refrigerant gas R503) 2591 2599 2601 2602 2901 3057 Cyclobutane Dichlorodifluoromethane and difluoro-1,1 ethane, azeotropic mixture with approximately 74% dichlorodifluoromethane (Refrigerant gas R500) Bromine chloride Trifluoroacetyl chloride 1.30 1.24 0.53 4A Carbonyl sulphide Carbonyl fluoride 2517 130 10 10 2204 2417 2454 120 kg 0.79 1 2 TC 2F 3O 2F 2452 2453 12 Maximum permissible mass of contents per litre of capacity 2F 4A Hydrogen iodide, anhydrous Propadiene, stabilized Nitrous oxide, refrigerated liquid Silane b 2451 Minimum test pressure for tanks With thermal Without insulation thermal insulation MPa bar MPa bar 2.8 28 3.2 32 13 1 2197 2200 2201 2203 2424 b 2,2-dimethylpropane Ammonia solutions, relative density less than 0.880 at 15 °C in water: with more than 35% and not more than 40% ammonia with more than 40% and not more than 50% ammonia Carbon dioxide, refrigerated liquid Dichlorosilane Sulfuryl fluoride Hexafluoroethane (Refrigerant gas R116) Classification code 2A 2.1 21 2.3 23 1.07 2O 2F 2F 20 30 1 2.1 200 300 10 21 20 30 1 2.5 200 300 10 25 0.50 0.75 0.57 0.57 2F 30 300 30 300 0.36 2F 1 10 1 10 0.99 3.1 31 42 100 10 20 0.11 0.21 0.76 0.20 0.66 0.63 1.01 10 15 1.50 1.17 3A 2A see 4.3.3.2.4 3.1 31 4.2 42 10 100 2F 2A 1 1.8 10 18 4.2 10 1 2 2 TOC 2 TC 1 1.3 10 13 1 1.5 Considered as pyrophoric. - 185 - UN No. Name Classification code 3070 Ethylene oxide and dichlorodifluoromethane mixture with not more than 12.5% ethylene oxide Perchloryl fluoride Trifluoromethane, refigerated liquid Ethylene, acetylene propylene in mixture, refrigerated liquid, containing at least 71.5% ethylene with not more than 22.5% acetylene and not more than 6% propylene Perfluoro(methyl vinyl ether) Perfluoro(ethyl vinyl ether) Compressed gas, oxidizing, n.o.s. Liquefied gas, oxidizing, n.o.s. Gas, refrigerated liquid, n.o.s. 1,1,1,2-tetrafluoroethane (Refrigerant gas R134a) Liquefied gas, toxic, flammable, n.o.s. a 2A Minimum test pressure for tanks With thermal Without insulation thermal insulation MPa bar MPa bar 1.5 15 1.6 16 2 TO 3A 3F 2.7 27 See 4.3.3.2.4 see 4.3.3.2.4 3.0 30 1.21 2F 2F 1O 2O 3A 2A 1.4 14 1.5 1 10 1 see 4.3.3.2.1 or 4.3.3.2.2 see 4.3.3.2.2 or 4.3.3.2.3 see 4.3.3.2.4 1.6 16 1.8 15 10 1.14 0.98 18 1.04 2 TF see 4.3.3.2.2 or 4.3.3.2.3 2F 2T 2A 2A see 4.3.3.2.2 or 4.3.3.2.3 see 4.3.3.2.2 or 4.3.3.2.3 see 4.3.3.2.2 or 4.3.3.2.3 4.1 41 4.9 49 0.95 3083 3136 3138 3153 3154 3156 3157 3158 3159 3160 3161 3162 3163 3220 3252 3296 3297 3298 3299 3300 3303 3304 3305 3306 3307 3308 3309 3310 3311 3312 a Liquefied gas, flammable, n.o.s. Liquefied gas, toxic, n.o.s. a Liquefied gas, n.o.s. Pentafluoroethane (Refrigerant gas R125) Difluoromethane (Refrigerant gas R32) Heptafluoropropane (Refrigerant gas R227) Ethylene oxide and chlorotetrafluoroethane mixture, with not more than 8.8% ethylene oxide Ethylene oxide and pentafluoroethane mixture, with not more than 7.9% ethylene oxide Ethylene oxide and tetrafluoroethane mixture, with not more than 5.6% ethylene oxide Ethylene oxide and carbon dioxide mixture, with more than 87% ethylene oxide Compressed gas, toxic, oxidizing, n.o.s.a Compressed gas, toxic, corrosive, n.o.s.a Compressed gas, toxic, flammable, corrosive, n.o.s. a Compressed gas, toxic, oxidizing, corrosive, n.o.s. a Liquefied gas, toxic, oxidizing, n.o.s. a Liquefied gas, toxic, corrosive, n.o.s. a Liquefied gas, toxic, flammable, corrosive, n.o.s. a Liquefied gas, toxic, oxidizing, corrosive, n.o.s. a Gas, refrigerated liquid, oxidizing, n.o.s. Gas, refrigerated liquid, flammable, n.o.s. Maximum permissible mass of contents per litre of capacity kg 1.09 2F 3.9 39 4.3 43 0.78 2A 1.4 14 1.6 16 1.20 2A 1 10 1 10 1.16 2A 2.4 24 2.6 26 1.02 2A 1.5 15 1.7 17 1.03 2 TF 2.8 28 2.8 28 0.73 1 TO 1 TC 1 TFC see 4.3.3.2.1 or 4.3.3.2.2 see 4.3.3.2.1 or 4.3.3.2.2 see 4.3.3.2.1 or 4.3.3.2.2 1 TOC see 4.3.3.2.1 or 4.3.3.2.2 2 TO 2 TC 2 TFC see 4.3.3.2.2 or 4.3.3.2.3 see 4.3.3.2.2 or 4.3.3.2.3 see 4.3.3.2.2 or 4.3.3.2.3 2 TOC see 4.3.3.2.2 or 4.3.3.2.3 3O 3F see 4.3.3.2.4 see 4.3.3.2.4 Allowed if LC50 equal to or greater than 200 ppm. - 186 - UN No. Name Classification code 3318 Ammonia solutions, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia Refrigerant gas R404A Refrigerant gas R407A Refrigerant gas R407B Refrigerant gas R407C Insecticide gas, flammable, n.o.s. Insecticide gas, toxic, flammable, n.o.s.a 4 TC Minimum test pressure for tanks With thermal Without insulation thermal insulation MPa bar MPa bar see 4.3.3.2.2 2A 2A 2A 2A 2F 2 TF 2.9 29 3.2 2.8 28 3.2 3.0 30 3.3 2.7 27 3.0 see 4.3.3.2.2 or 4.3.3.2.3 see 4.3.3.2.2 or 4.3.3.2.3 3337 3338 3339 3340 3354 3355 a Maximum permissible mass of contents per litre of capacity 32 32 33 30 kg 0.84 0.95 0.95 0.95 Allowed if LC50 equal to or greater than 200 ppm. 4.3.3.3 Operation 4.3.3.3.1 When tanks, battery-vehicles or MEGCs are approved for different gases, the change of use shall include emptying, purging and evacuation operations to the extent necessary for safe operation. 4.3.3.3.2 When tanks, battery-vehicles or MEGCs are handed over for carriage, only the particulars specified in 6.8.3.5.6 applicable to the gas loaded or just discharged shall be visible; all particulars concerning other gases shall be covered up. 4.3.3.3.3 All the elements of a battery-vehicle or MEGC shall contain only one and the same gas. 4.3.3.3.4 When the external overpressure could be greater than the tank resistance to external pressure (e.g. due to low ambient temperatures), adequate measures shall be taken to protect tanks carrying low pressure liquefied gases against the risk of deformation, e.g. by filling them with nitrogen or another inert gas in order to maintain sufficient pressure inside the tank. 4.3.3.4 (Reserved) - 187 - 4.3.4 Special provisions applicable to Classes 1 and 3 to 9 4.3.4.1 Coding, rationalized approach and hierarchy of tanks 4.3.4.1.1 Coding of tanks The four parts of the codes (tank codes) given in Column (12) of Table A in Chapter 3.2 have the following meanings: Part 1 2 3 4 Description Types of tank L= Tank code tank for substances in the liquid state (liquids or solids handed over for carriage in the molten state); S= tank for substances in the solid state (powdery or granular). Calculation pressure G= minimum calculation pressure according to the general requirements of 6.8.2.1.14; or Openings (see 6.8.2.2.2) 1.5; 2.65; 4; 10; 15 or 21= minimum calculation pressure in bar (see 6.8.2.1.14). A = tank with bottom-filling or bottom-discharge openings with 2 closures; Safety valves/devices B = tank with bottom-filling or bottom-discharge openings with 3 closures; C = tank with top-filling and discharge openings with only cleaning openings below the surface of the liquid; D = tank with top-filling and discharge openings with no openings below the surface of the liquid. = tank with a breather device, according to 6.8.2.2.6, but no device protecting against the propagation of a flame; or non-explosion pressure shock resistant tank ; V F = tank with a breather device, according to 6.8.2.2.6, fitted with a device protecting against the propagation of a flame; or explosion pressure shock resistant tank ; N = tank without a breather device according to 6.8.2.2.6 and not hermetically closed; H = hermetically closed tank (see 1.2.1). - 188 - 4.3.4.1.2 Rationalized approach for assignment of ADR tank codes to groups of substances and hierarchy of tanks NOTE: Certain substances and groups of substances are not included in the rationalized approach, see 4.3.4.1.3. Tank code LIQUIDS LGAV LGBV LGBF L1.5BN L4BN Rationalized approach Group of permitted substances Class Classification code Packing group 3 F2 III 9 M9 III 4.1 F2 II, III 5.1 O1 III 9 M6 III M11 III and groups of permitted substances for tank code LGAV 3 F1 II vapour pressure at 50 °C ≤ 1.1 bar F1 III D II vapour pressure at 50 °C ≤ 1.1 bar D III and groups of permitted substances for tank codes LGAV and LGBV 3 F1 II vapour pressure at 50 °C > 1.1 bar F1 III flash-point < 23 °C, viscous, vapour pressure at 50 °C > 1.1 bar boiling point > 35 °C D II vapour pressure at 50 °C > 1.1 bar and groups of permitted substances for tank codes LGAV, LGBV and LGBF 3 F1 I, III boiling point ≤ 35 °C FC III D I 5.1 O1 I, II OT1 I 8 C1 II, III C3 II, III C4 II, III C5 II, III C7 II, III C8 II, III C9 II, III C10 II, III CF1 II CF2 II CS1 II CW1 II CW2 II CO1 II CO2 II CT1 II, III CT2 II, III CFT II 9 M11 III and groups of permitted substances for tank codes LGAV, LGBV, LGBF and L1.5BN - 189 - Tank code L4BH L4DH L10BH Rationalized approach Group of permitted substances Class Classification code Packing group 3 FT1 II, III FT2 II FC II FTC II 6.1 T1 II, III T2 II, III T3 II, III T4 II, III T5 II, III T6 II, III T7 II, III TF1 II TF2 II, III TF3 II TS II TW1 II TW2 II TO1 II TO2 II TC1 II TC2 II TC3 II TC4 II TFC II 6.2 I3 II I4 9 M2 II and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN and L4BN 4.2 S1 II, III S3 II, III ST1 II, III ST3 II, III SC1 II, III SC3 II, III 4.3 W1 II, III WF1 II, III WT1 II, III WC1 II, III 8 CT1 II, III and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN and L4BH 8 C1 I C3 I C4 I C5 I C7 I C8 I C9 I C10 I CF1 I СF2 I CS1 I СW1 I СW2 I CO1 I CO2 I CT1 I CT2 I COT I and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN, and L4BH - 190 - Tank code L10CH L10DH L15CH L21DH Rationalized approach Group of permitted substances Class Classification code Packing group 3 FT1 I FT2 I FC I FTC I 6.1* T1 I T2 I T3 I T4 I T5 I T6 I T7 I TF1 I TF2 I TF3 I TS I TW1 I TO1 I TC1 I TC2 I TC3 I TC4 I TFC I TFW I and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN, L4BH, and L10BH * Substances with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 shall be assigned to tank code L15CH. 4.3 W1 I WF1 I WT1 I WC1 I WFC I 5.1 OTC I 8 CT1 I and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN, L4BH, L4DH, L10BH and L10CH 3 FT1 I 6.1** T1 I T4 I TF1 I TW1 I TO1 I TC1 I TC3 I TFC I TFW I and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN, L4BH, L10BH and L10CH ** Substances with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 shall be assigned to this tank code. 4.2 S1 I S3 I SW I ST3 I and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN, L4BH, L4DH, L10BH, L10CH, L10DH and L15CH - 191 - Tank code SOLIDS SGAV SGAN SGAH Rationalized approach Group of permitted substances Class Classification code Packing group 4.1 F1 III F3 III 4.2 S2 II, III S4 III 5.1 O2 II, III 8 C2 II, III C4 III C6 III C8 III C10 II, III СT2 III 9 M7 III M11 II, III 4.1 F1 II F3 II FT1 II, III FT2 II, III FC1 II, III FC2 II, III 4.2 S2 II S4 II, III ST2 II, III ST4 II, III SC2 II, III SC4 II, III 4.3 W2 II, III WF2 II WS II, III WT2 II, III WC2 II, III 5.1 O2 II, III OT2 II, III OC2 II, III 8 C2 II С4 II С6 II С8 II С10 II CF2 II CS2 II CW2 II CO2 II CT2 II 9 M3 III and groups of permitted substances for tank codes SGAV 6.1 T2 II, III T3 II, III T5 II, III T7 II, III T9 II TF3 II TS II TW2 II TO2 II TC2 II TC4 II 9 M1 II, III and groups of permitted substances for tanks codes SGAV and SGAN - 192 - Tank code S4AH S10AN S10AH Rationalized approach Group of permitted substances Class Classification code Packing group 6.2 I3 II 9 M2 II and groups of permitted substances for tanks codes SGAV, SGAN and SGAH 8 C2 I C4 I C6 I C8 I C10 I CF2 I CS2 I CW2 I CO2 I CT2 I and groups of permitted substances for tank codes SGAV and SGAN 6.1 T2 I T3 I T5 I T7 I TS I TW2 I TO2 I TC2 I TC4 I and groups of permitted substances for tank codes SGAV, SGAN, SGAH and S10AN Hierarchy of tanks Tanks with tank codes different from those indicated in this table or in Table A of Chapter 3.2 may also be used provided that any element (number or letter) of parts 1 to 4 of these tank codes correspond to a level of safety at least equivalent to the corresponding element of the tank code indicated in Table A of Chapter 3.2, according to the following increasing order: Part 1: Types of tanks SL Part 2: Calculation pressure G  1.5  2.65  4  10  15  21 bar Part 3: Openings ABCD Part 4: Safety valves/devices VFNH For example: - A tank with the tank code L10CN is authorized for the carriage of a substance to which the tank code L4BN has been assigned; - A tank with the tank code L4BN is authorized for the carriage of a substance to which the tank code SGAN has been assigned. NOTE: The hierarchy does not take account of any special provisions for each entry (see 4.3.5 and 6.8.4). 4.3.4.1.3 The following substances and groups of substances in respect of which a "(+)" is given after the tank code in Column (12) of Table A in Chapter 3.2 are subject to special provisions. In that case the alternate use of the tanks for other substances and groups of substances is permitted only where this is specified in the certificate of type approval. Higher value tanks according to the provisions at the end of the table in 4.3.4.1.2 may be used with due regard to the special provisions indicated in Column (13) of Table A in Chapter 3.2. - 193 - (a) Class 1 Division 1.5, UN No 0331 explosive, blasting, type B: code S2.65AN; (b) Class 4.1: UN No. 2448 sulphur, molten: code LGBV; (c) Class 4.2: UN No. 1381 phosphorus, white or yellow, dry, or under water or in solution and UN No. 2447 phosphorus, white molten: code L10DH; (d) Class 4.3: UN No. 1389 alkali metal amalgam, liquid, UN No. 1391 alkali metal dispersion or alkaline earth metal dispersion, UN No. 1392 alkaline earth metal amalgam, liquid, UN No. 1415 lithium, UN No. 1420 potassium metal alloys, liquid, UN No. 1421 alkali metal alloy, liquid, n.o.s, UN No. 1422 potassium sodium alloys, liquid, UN No. 1428 sodium, UN No. 2257 potassium, UN No. 3401 alkali metal amalgam, solid, UN No. 3402 alkaline earth metal amalgam, solid, 3403 potassium metal alloys, solid, UN No. 3404 potassium sodium alloys, solid and UN No. 3482 alkali metal dispersion, flammable or UN No. 3482 alkaline earth metal dispersion, flammable: code L10BN; UN No. 1407 caesium and UN No. 1423 rubidium: code L10CH; UN No. 1402 calcium carbide, packing group I: code S2.65AN; (e) Class 5.1: UN No. 1873 perchloric acid 50-72%: code L4DN; UN No. 2015 hydrogen peroxide, aqueous solution, stabilized with more than 70% hydrogen peroxide: code L4DV; UN No. 2014 hydrogen peroxide, aqueous solution with 20-60% hydrogen peroxide, UN No. 2015 hydrogen peroxide, aqueous solution, stabilized with 60-70% hydrogen peroxide, UN No. 2426 ammonium nitrate, liquid, hot concentrated solution with more than 80% but not more than 93% and UN No. 3149 hydrogen peroxide and peroxyacetic acid mixture, stabilized: code L4BV; UN No. 3375 ammonium nitrate emulsion, suspension or gel, liquid: code LGAV; UN No. 3375 ammonium nitrate emulsion, suspension or gel, solid: code SGAV; (f) Class 5.2: UN No. 3109 organic peroxide type F, liquid and UN No. 3119 organic peroxide, type F, liquid temperature controlled: code L4BN; UN No. 3110 organic peroxide, type F, solid and UN No. 3120 organic peroxide, type F, solid, temperature controlled: code S4AN; (g) Class 6.1: UN No. 1613 hydrogen cyanide, aqueous solution and UN No. 3294 hydrogen cyanide solution in alcohol: code L15DH; (h) Class 7: All substances: special tanks; Minimum requirements for liquids: code L2.65CN; for solids: code S2.65AN Notwithstanding the general requirements of this paragraph, tanks used for radioactive material may also be used for the carriage of other goods provided the requirements of 5.1.3.2 are complied with. - 194 - (i) Class 8: UN No. 1052 hydrogen fluoride, anhydrous, UN No. 1744 bromine or bromine solution and UN No. 1790 hydrofluoric acid, solution, with more than 85% hydrofluoric acid: code L21DH; UN No. 1791 hypochlorite solution and UN No. 1908 chlorite solution: code L4BV. 4.3.4.1.4 Tanks intended for the carriage of liquid wastes complying with the requirements of Chapter 6.10 and equipped with two closures in accordance with 6.10.3.2, shall be assigned to tank code L4AH. If the tanks concerned are equipped for the alternate carriage of liquid and solid substances, they shall be assigned to the combined codes L4AH+S4AH. 4.3.4.2 General provisions 4.3.4.2.1 Where hot substances are loaded, the temperature of the outer surface of the tank or of the thermal insulation shall not exceed 70 °C during carriage. 4.3.4.2.2 The connecting pipes between independent but interconnected tanks of a transport unit shall be empty during carriage. Flexible filling and discharge pipes which are not permanently connected to the shells shall be empty during carriage. 4.3.4.2.3 (Reserved) 4.3.5 Special provisions When they are shown under an entry in Column (13) of Table of A in Chapter 3.2, the following special provisions apply: TU1 The tanks shall not be handed over for carriage until the substance has solidified completely and been covered by an inert gas. Uncleaned empty tanks which have contained these substances shall be filled with an inert gas. TU2 The substance shall be covered by an inert gas. Uncleaned empty tanks which have contained these substances shall be filled with an inert gas. TU3 The inside of the shell and all parts liable to come into contact with the substance shall be kept clean. No lubricant capable of combining dangerously with the substance shall be used for pumps, valves or other devices. TU4 During carriage, these substances shall be under a layer of inert gas, the gauge pressure of which shall not be less than 50 kPa (0.5 bar). Uncleaned empty tanks which have contained these substances shall when handed over for carriage be filled with an inert gas at a gauge pressure of at least 50 kPa (0.5 bar). TU5 (Reserved) TU6 Not authorized for carriage in tanks, battery-vehicles and MEGCs when having a LC50 lower than 200 ppm. The materials used to ensure leakproofness of the joints or for the maintenance of the closures shall be compatible with the contents. TU7 TU8 An aluminium-alloy tank shall not be used for carriage unless the tank is reserved solely for such carriage and the acetaldehyde is free from acid. TU9 UN No.1203 petrol (gasoline) with a vapour pressure at 50 °C of more than 110 kPa (1.1 bar) but not above 150 kPa (1.5 bar) may also be carried in tanks designed according to 6.8.2.1.14 (a) and having equipment conforming to 6.8.2.2.6. TU10 (Reserved) - 195 - TU11 During filling, the temperature of this substance shall not exceed 60 °C. A maximum filling temperature of 80 °C is allowed provided that smoulder spots are prevented and that the following conditions are met. After filling, the tanks shall be pressurized (e.g. with compressed air) to check tightness. It shall be ensured that no depressurization takes place during carriage. Before discharge, it shall be checked if pressure in the tanks is still above atmospheric. If this is not the case, an inert gas shall be introduced into the tanks prior to discharge. TU12 In the event of a change of use, shells and equipment shall be thoroughly cleansed of all residues before and after the carriage of this substance. TU13 Tanks shall be free from impurities at the time of filling. Service equipment such as valves and external piping shall be emptied after filling or discharging. TU14 The protective caps of closures shall be locked during carriage. TU15 Tanks shall not be used for the carriage of foodstuffs, articles of consumption or animal feeds. TU16 Uncleaned empty tanks, shall, when handed over for carriage, either: - be filled with nitrogen; or - be filled with water to not less than 96% and not more than 98% of their capacity; between 1 October and 31 March, this water shall contain sufficient anti-freeze agent to make it impossible for the water to freeze during carriage; the anti-freeze agent shall be free from corrosive action and not liable to react with phosphorus. TU17 Only to be carried in battery-vehicles or MEGCs the elements of which are composed of receptacles. TU18 The degree of filling shall remain below the level at which, if the contents were raised to a temperature at which the vapour pressure equalled the opening pressure of the safety valve, the volume of the liquid would reach 95% of the tank’s capacity at that temperature. The provision in 4.3.2.3.4 shall not apply. TU19 Tanks may be filled to 98% at the filling temperature and pressure. The provision in 4.3.2.3.4 shall not apply. TU20 (Reserved) TU21 The substance shall, if water is used as a protective agent, be covered with a depth of not less than 12 cm of water at the time of filling; the degree of filling at a temperature of 60 °C shall not exceed 98%. If nitrogen is used as a protective agent, the degree of filling at a temperature of 60 °C shall not exceed 96%. The remaining space shall be filled with nitrogen in such a way that, even after cooling, the pressure at no time falls below atmospheric pressure. The tank shall be closed in such a way that no leakage of gas occurs. TU22 Tanks shall be filled to not more than 90% of their capacity; for liquids, a space of 5% shall remain empty when the liquid is at an average temperature of 50 °C. TU23 The degree of filling shall not exceed 0.93 kg per litre of capacity, if filling is by mass. If filling is by volume, the degree of filling shall not exceed 85%. TU24 The degree of filling shall not exceed 0.95 kg per litre of capacity, if filling is by mass. If filling is by volume, the degree of filling shall not exceed 85%. TU25 The degree of filling shall not exceed 1.14 kg per litre of capacity, if filling is by mass. If filling is by volume, the degree of filling shall not exceed 85%. TU26 The degree of filling shall not exceed 85%. TU27 Tanks shall not be filled to more than 98% of their capacity. - 196 - TU28 Tanks shall be filled to not more than 95% of their capacity at a reference temperature of 15 °C. TU29 Tanks shall be filled to not more than 97% of their capacity and the maximum temperature after filling shall not exceed 140 °C. TU30 Tanks shall be filled as set out in the test report for the type approval of the tank but shall be filled to not more than 90% of their capacity. TU31 Tanks shall not be filled to more than 1 kg per litre of capacity. TU32 Tanks shall not be filled to more than 88% of their capacity. TU33 Tanks shall be filled to not less than 88% and not more than 92% of their capacity or to 2.86 kg per litre of capacity. TU34 Tanks shall not be filled to more than 0.84 kg per litre of capacity. TU35 Empty fixed tanks (tank-vehicles), empty demountable tanks and empty tank-containers, uncleaned, which have contained these substances are not subject to the requirements of ADR if adequate measures have been taken to nullify any hazard. TU36 The degree of filling according to 4.3.2.2, at the reference temperature of 15 °C, shall not exceed 93% of the capacity. TU37 Carriage in tanks is limited to substances containing pathogens which are unlikely to be a serious hazard, and for which, while capable of causing serious infection on exposure, effective treatment and preventive measures are available and the risk of spread of infection is limited (i.e. moderate individual risk and low community risk). TU38 (Reserved) TU39 The suitability of the substance for carriage in tanks shall be demonstrated. The method to evaluate this suitability shall be approved by the competent authority. One method is test 8(d) in Test Series 8 (see Manual of Tests and Criteria, Part 1, sub-section 18.7). Substances shall not be allowed to remain in the tank for any period that could result in caking. Appropriate measures shall be taken to avoid accumulation and packing of substances in the tank (e.g. cleaning etc.). TU40 Only to be carried in battery-vehicles or MEGCs, the elements of which are composed of seamless receptacles. TU41 The suitability of the substance for carriage in tanks shall be demonstrated to the satisfaction of the competent authority of every country through or into which the carriage is performed. The method to evaluate this suitability shall be approved by the competent authority of any ADR Contracting Party who may also recognize an approval granted by the competent authority of a country which is not an ADR Contracting Party provided that this approval has been granted in accordance with the procedures applicable according to ADR, RID, ADN or the IMDG Code. Substances shall not be allowed to remain in the tank for any period that could result in caking. Appropriate measures shall be taken to avoid accumulation and packing of substances in the tank (e.g. cleaning etc.). - 197 - CHAPTER 4.4 USE OF FIBRE-REINFORCED PLASTICS (FRP) TANKS, FIXED TANKS (TANK-VEHICLES), DEMOUNTABLE TANKS, TANK-CONTAINERS AND TANK SWAP BODIES NOTE: For portable tanks and UN multiple-element gas containers (MEGCs), see Chapter 4.2; for fixed tanks (tank-vehicles), demountable tanks, tank-containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple elements gas containers (MEGCs) other than UN MEGCs, see Chapter 4.3; for vacuum operated waste containers, see Chapter 4.5. 4.4.1 General The carriage of dangerous substances in fibre-reinforced plastics (FRP) tanks is permitted only when the following conditions are met: (a) The substance is classified in Class 3, 5.1, 6.1, 6.2, 8 or 9; (b) The maximum vapour pressure (absolute pressure) at 50 °C of the substance does not exceed 110 kPa (1.1 bar); (c) The carriage of the substance in metallic tanks is authorized according to 4.3.2.1.1; (d) The calculation pressure specified for that substance in part 2 of the tank code given in Column (12) of Table A in Chapter 3.2 does not exceed 4 bar (see also 4.3.4.1.1); and (e) The tank complies with the provisions of Chapter 6.9 applicable for the carriage of the substance. 4.4.2 Operation 4.4.2.1 The provisions of 4.3.2.1.5 to 4.3.2.2.4, 4.3.2.3.3 to 4.3.2.3.6, 4.3.2.4.1, 4.3.2.4.2, 4.3.4.1 and 4.3.4.2 shall apply. 4.4.2.2 The temperature of the substance carried shall not exceed, at the time of filling, the maximum service temperature indicated on the tank plate referred to in 6.9.6. 4.4.2.3 When applicable to carriage in metallic tanks, the special provisions (TU) of 4.3.5 shall also apply, as indicated in Column (13) of Table A in Chapter 3.2. - 199 - CHAPTER 4.5 USE OF VACUUM OPERATED WASTE TANKS NOTE: For portable tanks and UN multiple-element gas containers (MEGCs), see Chapter 4.2; for fixed tanks (tank-vehicles), demountable tanks, tank-containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple elements gas containers (MEGCs) other than UN MEGCs, see Chapter 4.3; for fibre reinforced plastics tanks, see Chapter 4.4. 4.5.1 Use 4.5.1.1 Wastes consisting of substances in Classes 3, 4.1, 5.1, 6.1, 6.2, 8 and 9 may be carried in vacuumoperated waste tanks conforming to Chapter 6.10 if their carriage in fixed tanks, demountable tanks, tank-containers or tank swap bodies is permitted according to Chapter 4.3. Wastes consisting of substances assigned to tank code L4BH in Column (12) of Table A of Chapter 3.2 or to another tank code permitted under the hierarchy in 4.3.4.1.2 may be carried in vacuum operated waste tanks with the letter "A" or "B" in part 3 of the tank code, as indicated in No. 9.5 of the vehicle approval certificate conforming to 9.1.3.5. 4.5.1.2 Non waste substances may be carried in vacuum-operated waste tanks under the same conditions as mentioned under 4.5.1.1. 4.5.2 Operation 4.5.2.1 The provisions of Chapter 4.3 except those of 4.3.2.2.4 and 4.3.2.3.3 apply to the carriage in vacuum operated waste tanks and are supplemented by the provisions of 4.5.2.2 to 4.5.2.6 below. 4.5.2.2 For carriage of liquids meeting the flash point criteria of Class 3, vacuum-operated waste tanks shall be filled through filling devices which discharge into the tank at a low level. Measures shall be taken to minimize the production of spray. 4.5.2.3 When discharging flammable liquids with a flash-point below 23 °C by using air pressure, the maximum allowed pressure is 100 kPa (1 bar). 4.5.2.4 The use of tanks fitted with an internal piston operating as a compartment wall is allowed only when the substances on either side of the wall (piston) do not react dangerously with each other (see 4.3.2.3.6). 4.5.2.5 (Reserved) 4.5.2.6 When a vacuum pump/exhauster unit which may provide a source of ignition is used to fill or discharge flammable liquids, precautions shall be taken to avoid ignition of the substance or to avoid the propagation of the effects of the ignition outside the tank itself. - 201 - CHAPTER 4.6 (Reserved) - 203 - CHAPTER 4.7 USE OF MOBILE EXPLOSIVES MANUFACTURING UNITS (MEMUs) NOTE 1: For packagings, see Chapter 4.1; for portable tanks, see Chapter 4.2; for fixed tanks (tank vehicles), demountable tanks, tank-containers and tank swap bodies with shells made of metallic materials, see Chapter 4.3; for fibre-reinforced plastics (FRP) tanks, see Chapter 4.4; for vacuum operated waste tanks, see Chapter 4.5. NOTE 2: For requirements concerning construction, equipment, type approval, tests and marking, see Chapters 6.7, 6.8, 6.9, 6.11 and 6.12. 4.7.1 Use 4.7.1.1 Substances of Classes 3, 5.1, 6.1 and 8 may be carried on MEMUs conforming to Chapter 6.12, in portable tanks if their carriage is permitted according to Chapter 4.2; or in fixed tanks, demountable tanks, tank containers or tank swap bodies if their carriage is permitted according to Chapter 4.3; or in fibre-reinforced plastics (FRP) tanks if their carriage is permitted according to Chapter 4.4; or in bulk containers, if their carriage is permitted according to Chapter 7.3. 4.7.1.2 Subject to the approval of the competent authority (see 7.5.5.2.3) explosive substances or articles of Class 1 may be carried in packages, in special compartments conforming to section 6.12.5, if their packaging is permitted according to Chapter 4.1 and their carriage is permitted according to Chapter 7.2 and 7.5. 4.7.2 Operation 4.7.2.1 The following provisions apply for operation of tanks according to Chapter 6.12: (a) For tanks with a capacity of 1 000 litres or more, the provisions of Chapter 4.2, Chapter 4.3, except 4.3.1.4, 4.3.2.3.1, 4.3.3 and 4.3.4, or Chapter 4.4 apply to the carriage on MEMUs, and are supplemented by the provisions of 4.7.2.2 , 4.7.2.3 and 4.7.2.4 below. (b) For tanks with a capacity of less than 1 000 litres, the provisions of Chapter 4.2, Chapter 4.3, except 4.3.1.4, 4.3.2.1, 4.3.2.3.1, 4.3.3 and 4.3.4, or Chapter 4.4 apply to the carriage on MEMUs, and are supplemented by the provisions of 4.7.2.2, 4.7.2.3 and 4.7.2.4 below. 4.7.2.2 The thickness of the walls of the shell shall not, throughout its use, fall below the minimum figure prescribed in the appropriate construction requirements. 4.7.2.3 Flexible discharge pipes, whether permanently connected or not, and hoppers shall be empty of mixed or sensitised explosive substances during carriage. 4.7.2.4 When applicable to carriage in tanks, the special provisions (TU) of 4.3.5 shall also apply as indicated in Column (13) of Table A in Chapter 3.2. 4.7.2.5 Operators shall ensure that the locks specified in 9.8.8 are used during carriage. - 205 - PART 5 Consignment procedures CHAPTER 5.1 GENERAL PROVISIONS 5.1.1 Application and general provisions This Part sets forth the provisions for dangerous goods consignments relative to marking, labelling, and documentation, and, where appropriate, authorization of consignments and advance notifications. 5.1.2 Use of overpacks 5.1.2.1 (a) An overpack shall be: (i) marked with the word "OVERPACK"; and (ii) marked with the UN number preceded by the letters "UN" as required for packages in 5.2.1.1 and 5.2.1.2, labelled as required for packages in 5.2.2 and marked with the environmentally hazardous substance mark if required for packages in 5.2.1.8, for each item of dangerous goods contained in the overpack; unless the UN numbers, the labels and the environmentally hazardous substance mark representative of all dangerous goods contained in the overpack are visible, except as required in 5.2.2.1.11. If the same UN number, the same label or the environmentally hazardous substance mark is required for different packages, it only needs to be applied once. The lettering of the "OVERPACK" marking shall be at least 12 mm high. The marking of the word "OVERPACK", which shall be readily visible and legible, shall be in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise. (b) Orientation arrows illustrated in 5.2.1.9 shall be displayed on two opposite sides of overpacks containing packages which shall be marked in accordance with 5.2.1.9.1, unless the marking remains visible. 5.1.2.2 Each package of dangerous goods contained in an overpack shall comply with all applicable provisions of ADR. The intended function of each package shall not be impaired by the overpack. 5.1.2.3 Each package bearing package orientation markings as prescribed in 5.2.1.9 and which is overpacked or placed in a large packaging shall be oriented in accordance with such markings. 5.1.2.4 The prohibitions on mixed loading also apply to these overpacks. 5.1.3 Empty uncleaned packagings (including IBCs and large packagings), tanks, MEMUs, vehicles and containers for carriage in bulk 5.1.3.1 Empty uncleaned packagings (including IBCs and large packagings), tanks (including tank-vehicles, battery-vehicles, demountable tanks, portable tanks, tank-containers, MEGCs), MEMUs, vehicles and containers for carriage in bulk having contained dangerous goods of the different classes other than Class 7, shall be marked and labelled as if they were full. NOTE: For documentation, see Chapter 5.4. 5.1.3.2 Containers, tanks, IBCs, as well as other packagings and overpacks, used for the carriage of radioactive material shall not be used for the storage or carriage of other goods unless decontaminated below the level of 0.4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters and 0.04 Bq/cm2 for all other alpha emitters. - 209 - 5.1.4 Mixed packing When two or more dangerous goods are packed within the same outer packaging, the package shall be labelled and marked as required for each substance or article. If the same label is required for different goods, it only needs to be applied once. 5.1.5 General provisions for Class 7 5.1.5.1 Approval of shipments and notification 5.1.5.1.1 General In addition to the approval of package designs described in Chapter 6.4, multilateral shipment approval is also required in certain circumstances (5.1.5.1.2 and 5.1.5.1.3). In some circumstances it is also necessary to notify competent authorities of a shipment (5.1.5.1.4). 5.1.5.1.2 Shipment approvals Multilateral approval shall be required for: (a) the shipment of Type B(M) packages not conforming with the requirements of 6.4.7.5 or designed to allow controlled intermittent venting; (b) the shipment of Type B(M) packages containing radioactive material with an activity greater than 3 000 A1 or 3 000 A2, as appropriate, or 1 000 TBq, whichever is the lower; and (c) The shipment of packages containing fissile materials if the sum of the criticality safety indexes of the packages in a single vehicle or container exceeds 50; except that a competent authority may authorize carriage into or through its country without shipment approval, by a specific provision in its design approval (see 5.1.5.2.1). 5.1.5.1.3 Shipment approval by special arrangement Provisions may be approved by a competent authority under which a consignment, which does not satisfy all of the applicable requirements of ADR may be carried under special arrangement (see 1.7.4). 5.1.5.1.4 Notifications Notification to competent authorities is required as follows: (a) Before the first shipment of any package requiring competent authority approval, the consignor shall ensure that copies of each applicable competent authority certificate applying to that package design have been submitted to the competent authority of the country of origin of the shipment and to the competent authority of each country through or into which the consignment is to be carried. The consignor is not required to await an acknowledgement from the competent authority, nor is the competent authority required to make such acknowledgement of receipt of the certificate; (b) For each of the following types of shipments: (i) Type C packages containing radioactive material with an activity greater than 3 000 A1 or 3 000 A2, as appropriate, or 1 000 TBq, whichever is the lower; (ii) Type B(U) packages containing radioactive material with an activity greater than 3 000 A1 or 3 000 A2, as appropriate, or 1 000 TBq, whichever is the lower; (iii) Type B(M) packages; (iv) Shipment under special arrangement; - 210 - The consignor shall notify the competent authority of the country of origin of the shipment and the competent authority of each country through or into which the consignment is to be carried. This notification shall be in the hands of each competent authority prior to the commencement of the shipment, and preferably at least 7 days in advance; (c) The consignor is not required to send a separate notification if the required information has been included in the application for approval of shipment (see 6.4.23.2); (d) The consignment notification shall include: (i) sufficient information to enable the identification of the package or packages including all applicable certificate numbers and identification marks; (ii) information on the date of shipment, the expected date of arrival and proposed routeing; (iii) the name(s) of the radioactive material(s) or nuclide(s); (iv) descriptions of the physical and chemical forms of the radioactive material, or whether it is special form radioactive material or low dispersible radioactive material; and (v) the maximum activity of the radioactive contents during carriage expressed in becquerels (Bq) with an appropriate SI prefix symbol (see 1.2.2.1). For fissile material, the mass of fissile material (or of each fissile nuclide for mixtures when appropriate) in grams (g), or multiples thereof, may be used in place of activity. 5.1.5.2 Certificates issued by the competent authority 5.1.5.2.1 Certificates issued by the competent authority are required for the following: (a) Designs for: (i) special form radioactive material; (ii) low dispersible radioactive material; (iii) fissile material excepted under 2.2.7.2.3.5 (f); (iv) packages containing 0.1 kg or more of uranium hexafluoride; (v) packages containing fissile material unless excepted by 2.2.7.2.3.5, 6.4.11.2 or 6.4.11.3; (vi) Type B(U) packages and Type B(M) packages; (vii) Type C packages; (b) Special arrangements; (c) Certain shipments (see 5.1.5.1.2); (d) Determination of the basic radionuclide values referred to in 2.2.7.2.2.1 for individual radionuclides which are not listed in Table 2.2.7.2.2.1 (see 2.2.7.2.2.2 (a)); (e) Alternative activity limits for an exempt consignment of instruments or articles (see 2.2.7.2.2.2 (b)). The certificates shall confirm that the applicable requirements are met, and for design approvals shall attribute to the design an identification mark. The certificates of approval for the package design and the shipment may be combined into a single certificate. Certificates and applications for these certificates shall be in accordance with the requirements in 6.4.23. - 211 - 5.1.5.2.2 The consignor shall be in possession of a copy of each applicable certificate. 5.1.5.2.3 For package designs where it is not required that a competent authority issue a certificate of approval, the consignor shall, on request, make available for inspection by the competent authority, documentary evidence of the compliance of the package design with all the applicable requirements. 5.1.5.3 Determination of transport index (TI) and criticality safety index (CSI) 5.1.5.3.1 The transport index (TI) for a package, overpack or container, or for unpackaged LSA-I or SCO-I, shall be the number derived in accordance with the following procedure: (a) Determine the maximum radiation level in units of millisieverts per hour (mSv/h) at a distance of 1 m from the external surfaces of the package, overpack, container, or unpackaged LSA-I and SCO-I. The value determined shall be multiplied by 100 and the resulting number is the transport index. For uranium and thorium ores and their concentrates, the maximum radiation level at any point 1 m from the external surface of the load may be taken as: 0.4 mSv/h for ores and physical concentrates of uranium and thorium; 0.3 mSv/h for chemical concentrates of thorium; 0.02 mSv/h for chemical concentrates of uranium, other than uranium hexafluoride; (b) (c) For tanks, containers and unpackaged LSA-I and SCO-I, the value determined in step (a) above shall be multiplied by the appropriate factor from Table 5.1.5.3.1; The value obtained in steps (a) and (b) above shall be rounded up to the first decimal place (e.g. 1.13 becomes 1.2), except that a value of 0.05 or less may be considered as zero. Table 5.1.5.3.1: Multiplication factors for tanks, containers and unpackaged LSA-I and SCO-I Size of load a Multiplication factor 1 size of load  1 m2 2 1 m2 < size of load  5 m2 3 5 m2 < size of load  20 m2 10 20 m2 < size of load a Largest cross-sectional area of the load being measured. 5.1.5.3.2 The transport index for each overpack, container or vehicle shall be determined as either the sum of the TIs of all the packages contained, or by direct measurement of radiation level, except in the case of non-rigid overpacks for which the transport index shall be determined only as the sum of the TIs of all the packages. 5.1.5.3.3 The criticality safety index for each overpack or container shall be determined as the sum of the CSIs of all the packages contained. The same procedure shall be followed for determining the total sum of the CSIs in a consignment or aboard a vehicle. 5.1.5.3.4 Packages, overpacks and containers shall be assigned to either category I-WHITE, II-YELLOW or III-YELLOW in accordance with the conditions specified in Table 5.1.5.3.4 and with the following requirements: (a) For a package, overpack or container, both the transport index and the surface radiation level conditions shall be taken into account in determining which is the appropriate category. Where the transport index satisfies the condition for one category but the surface radiation level satisfies the condition for a different category, the package, overpack or container shall be assigned to the higher category. For this purpose, category I-WHITE shall be regarded as the lowest category; (b) The transport index shall be determined following the procedures specified in 5.1.5.3.1 and 5.1.5.3.2; (c) If the surface radiation level is greater than 2 mSv/h, the package or overpack shall be carried under exclusive use and under the provisions of 7.5.11, CV33 (1.3) and (3.5) (a); - 212 - (d) A package carried under a special arrangement shall be assigned to category III-YELLOW except under the provisions of 5.1.5.3.5; (e) An overpack or container which contains packages carried under special arrangement shall be assigned to category III-YELLOW except under the provisions of 5.1.5.3.5. Table 5.1.5.3.4: Categories of packages, overpacks and containers Transport index a Conditions Maximum radiation level at any point on external surface Not more than 0.005 mSv/h 0 More than 0 but not More than 0.005 mSv/h but not more than 0.5 mSv/h more than 1a More than 1 but not More than 0.5 mSv/h but not more than 2 mSv/h more than 10 More than 10 More than 2 mSv/h but not more than 10 mSv/h Category I-WHITE II-YELLOW III-YELLOW III-YELLOW b If the measured TI is not greater than 0.05, the value quoted may be zero in accordance with 5.1.5.3.1 (c). b Shall also be carried under exclusive use except for containers (see Table D in 7.5.11 CV33 (3.3)). a 5.1.5.3.5 In all cases of international carriage of packages requiring competent authority approval of design or shipment, for which different approval types apply in the different countries concerned by the shipment, the categorization shall be in accordance with the certificate of the country of origin of design. 5.1.5.4 Specific provisions for excepted packages of radioactive material of Class 7 5.1.5.4.1 Excepted packages of radioactive material of Class 7 shall be legibly and durably marked on the outside of the packaging with: 5.1.5.4.2 5.1.5.4.3 (a) The UN number preceded by the letters "UN"; (b) An identification of either the consignor or consignee, or both; and (c) The permissible gross mass if this exceeds 50 kg. The documentation requirements of Chapter 5.4 do not apply to excepted packages of radioactive material of Class 7, except that: (a) The UN number preceded by the letters "UN" and the name and address of the consignor and the consignee and, if relevant, the identification mark for each competent authority certificate of approval (see 5.4.1.2.5.1 (g)) shall be shown on a transport document such as a bill of lading, air waybill or CMR or CIM consignment note; (b) If relevant, the requirements of 5.4.1.2.5.1 (g), 5.4.1.2.5.3 and 5.4.1.2.5.4 shall apply; (c) The requirements of 5.4.2 and 5.4.4 shall apply. The requirements of 5.2.1.7.8 and 5.2.2.1.11.5 shall apply if relevant. - 213 - 5.1.5.5 Summary of approval and prior notification requirements NOTE 1: Before first shipment of any package requiring competent authority approval of the design, the consignor shall ensure that a copy of the approval certificate for that design has been submitted to the competent authority of each country en route (see 5.1.5.1.4 (a)). NOTE 2: Notification required if contents exceed 3 × 103 A1, or 3 × 103 A2, or 1 000 TBq; (see 5.1.5.1.4 (b)). NOTE 3: Multilateral approval of shipment required if contents exceed 3 × 103 A1, or 3 × 103 A2, or 1 000 TBq, or if controlled intermittent venting is allowed (see 5.1.5.1). NOTE 4: See approval and prior notification provisions for the applicable package for carrying this material. Subject UN Number Calculation of unlisted A1 and A2 values Excepted packages - package design - shipment LSA material b and SCO b Industrial packages types 1, 2 or 3, non fissile and fissile excepted - package design - shipment Type A packages b, non fissile and fissile excepted - package design - shipment Type B(U) packages b , non fissile and fissile excepted - package design - shipment Type B(M) packages b, non fissile and fissile excepted - package design - shipment - a 2908, 2909, 2910, 2911 Competent Authority approval required Country Countries of origin en route a Yes Yes Consignor required to notify the competent authorities of the country of origin and of the countries en route a before each shipment No No No No No No No Reference ----- --- 2912, 2913, 3321, 3322 No No No No No No 2915, 3332 -No No No No No No 2916 Yes No No No See Note 1 See Note 2 2917 Yes See Note 3 Yes See Note 3 No Yes 5.1.5.1.4 (b), 5.1.5.2.1 (a), 6.4.22.2 5.1.5.1.4 (b), 5.1.5.2.1 (a), 5.1.5.1.2, 6.4.22.3 Countries from, through or into which the consignment is carried. If the radioactive contents are fissile material which is not excepted from the provisions for packages containing fissile material, then the provisions for fissile material packages apply (see 6.4.11). b - 214 - Subject UN Number Type C packages b, non fissile and fissile excepted - package design - shipment Packages for fissile material - package design - shipment : - sum of criticality safety indexes not more than 50 - sum of criticality safety indexes greater than 50 3323 Special form radioactive material - design - shipment Low dispersable radioactive material - design - shipment Packages containing 0.1 kg or more of uranium hexafluoride - design - shipment Special Arrangement - shipment Approved packages designs subjected to transitional measures 2977, 3324, 3325, 3326, 3327, 3328, 3329, 3330, 3331, 3333 See Note 4 Competent Authority approval required Country Countries of origin en route a Consignor required to notify the competent authorities of the country of origin and of the countries en route a before each shipment Yes No No No See Note 1 See Note 2 Yes c Yes c No No d No d See Note 2 Yes Yes See Note 2 Yes See Note 4 No See Note 4 No See Note 4 Reference 5.1.5.1.4 (b), 5.1.5.2.1 (a), 6.4.22.2 5.1.5.2.1 (a), 5.1.5.1.2, 6.4.22.4, 6.4.22.5 1.6.6.4, 5.1.5.2.1 (a) 6.4.22.5 5.1.5.2.1 (a), 6.4.22.3 See Note 4 Yes See Note 4 No See Note 4 No See Note 4 5.1.5.2.1 (a), 6.4.22.1 See Note 4 2919, 3331 - Yes See Note 4 No See Note 4 No See Note 4 Yes Yes Yes See 1.6.6 See 1.6.6 See Note 1 1.7.4.2, 5.1.5.2.1 (b), 5.1.5.1.4 (b) 1.6.6.1, 1.6.6.2, 5.1.5.1.4 (b), 5.1.5.2.1 (a), 5.1.5.1.2. Designs of packages for fissile material may also require approval in respect of one of the other items in the table. c d Shipments may, however, require approval in respect of one of the other items in the table. - 215 - CHAPTER 5.2 MARKING AND LABELLING 5.2.1 Marking of packages NOTE: For markings related to the construction, testing and approval of packagings, large packagings, gas receptacles and IBCs, see Part 6. 5.2.1.1 Unless provided otherwise in ADR, the UN number corresponding to the dangerous goods contained, preceded by the letters "UN" shall be clearly and durably marked on each package. The UN number and the letters "UN" shall be at least 12 mm high, except for packages of 30 litres capacity or less or of 30 kg maximum net mass and for cylinders of 60 litres water capacity or less, when they shall be at least 6 mm in height and except for packages of 5 litres or 5 kg or less when they shall be of an appropriate size. In the case of unpackaged articles the marking shall be displayed on the article, on its cradle or on its handling, storage or launching device. 5.2.1.2 All package markings required by this Chapter: (a) (b) shall be readily visible and legible; shall be able to withstand open weather exposure without a substantial reduction in effectiveness. 5.2.1.3 Salvage packagings and salvage pressure receptacles shall additionally be marked with the word "SALVAGE". The lettering of the "SALVAGE" marking shall be at least 12 mm high. 5.2.1.4 Intermediate bulk containers of more than 450 litres capacity and large packagings shall be marked on two opposite sides. 5.2.1.5 Additional provisions for goods of Class 1 For goods of Class 1, packages shall, in addition, bear the proper shipping name as determined in accordance with 3.1.2. The marking, which shall be clearly legible and indelible, shall be in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German unless any agreements concluded between the countries concerned in the transport operation provide otherwise. 5.2.1.6 Additional provisions for goods of Class 2 Refillable receptacles shall bear the following particulars in clearly legible and durable characters: (a) 1 the UN number and the proper shipping name of the gas or mixture of gases, as determined in accordance with 3.1.2. In the case of gases classified under an N.O.S. entry, only the technical name1 of the gas has to be indicated in addition to the UN number. In the case of mixtures, not more than the two constituents which most predominantly contribute to the hazards have to be indicated; Instead of the technical name the use of one of the following names is permitted: - for UN No. 1078 refrigerant gas, n.o.s: mixture F1, mixture F2, mixture F3; for UN No. 1060 methylacetylene and propadiene mixtures, stabilized: mixture P1, mixture P2; for UN No. 1965 hydrocarbon gas mixture, liquefied, n.o.s.: mixture A or butane, mixture A01 or butane, mixture A02 or butane, mixture A0 or butane, mixture A1, mixture B1, mixture B2, mixture B, mixture C or propane; for UN No. 1010 Butadienes, stabilized: 1,2-Butadiene, stabilized, 1,3-Butadiene, stabilized. - 217 - (b) for compressed gases filled by mass and for liquefied gases, either the maximum filling mass and the tare of the receptacle with fittings and accessories as fitted at the time of filling, or the gross mass; (c) the date (year) of the next periodic inspection. These marks can either be engraved or indicated on a durable information disk or label attached on the receptacle or indicated by an adherent and clearly visible marking such as by printing or by any equivalent process. NOTE 1: See also 6.2.2.7. NOTE 2: For non refillable receptacles, see 6.2.2.8. 5.2.1.7 Special marking provisions for radioactive material 5.2.1.7.1 Each package shall be legibly and durably marked on the outside of the packaging with an identification of either the consignor or consignee, or both. Each overpack shall be legibly and durably marked on the outside of the overpack with an identification of either the consignor or consignee, or both unless these markings of all packages within the overpack are clearly visible. 5.2.1.7.2 For each package, other than excepted packages, the UN number preceded by the letters "UN" and the proper shipping name shall be legibly and durably marked on the outside of the packaging. The marking of excepted packages shall be as required by 5.1.5.4.1. 5.2.1.7.3 Each package of gross mass exceeding 50 kg shall have its permissible gross mass legibly and durably marked on the outside of the packaging. 5.2.1.7.4 Each package which conforms to: 5.2.1.7.5 5.2.1.7.6 (a) a Type IP-1 package, a Type IP-2 package or a Type IP-3 package design shall be legibly and durably marked on the outside of the packaging with "TYPE IP-1", "TYPE IP-2" or "TYPE IP3" as appropriate; (b) a Type A package design shall be legibly and durably marked on the outside of the packaging with "TYPE A"; (c) a Type IP-2 package, a Type IP-3 package or a Type A package design shall be legibly and durably marked on the outside of the packaging with the international vehicle registration code (VRI Code)2 of the country of origin of design and either the name of the manufacturer or other identification of the packaging specified by the competent authority of the country of origin of design. Each package which conforms to a design approved under one or more of paragraphs 5.1.5.2.1, 6.4.22.1 to 6.4.22.4, 6.4.23.4 to 6.4.23.7 and 6.4.24.2 shall be legibly and durably marked on the outside of the package with the following information: (a) the identification mark allocated to that design by the competent authority; (b) a serial number to uniquely identify each packaging which conforms to that design; (c) "Type B(U)", "Type B(M)" or "Type C", in the case of a Type B(U), Type B(M) or Type C package design. Each package which conforms to a Type B(U), Type B(M) or Type C package design shall have the outside of the outermost receptacle which is resistant to the effects of fire and water plainly marked by embossing, stamping or other means resistant to the effects of fire and water with the trefoil symbol shown in the figure below. Distinguishing sign for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). 2 - 218 - Basic trefoil symbol with proportions based on a central circle of radius X. The minimum allowable size of X shall be 4 mm. 5.2.1.7.7 Where LSA-I or SCO-I material is contained in receptacles or wrapping materials and is carried under exclusive use as permitted by 4.1.9.2.4, the outer surface of these receptacles or wrapping materials may bear the marking "RADIOACTIVE LSA-I" or "RADIOACTIVE SCO-I", as appropriate. 5.2.1.7.8 In all cases of international carriage of packages requiring competent authority approval of design or shipment, for which different approval types apply in the different countries concerned by the shipment, marking shall be in accordance with the certificate of the country of origin of the design. 5.2.1.8 Special marking provisions for environmentally hazardous substances 5.2.1.8.1 Packages containing environmentally hazardous substances meeting the criteria of 2.2.9.1.10 shall be durably marked with the environmentally hazardous substance mark shown in 5.2.1.8.3 with the exception of single packagings and combination packagings where such single packagings or inner packagings of such combination packagings have: - a quantity of 5 l or less for liquids; or - a net mass of 5 kg or less for solids. 5.2.1.8.2 The environmentally hazardous substance mark shall be located adjacent to the markings required by 5.2.1.1. The requirements of 5.2.1.2 and 5.2.1.4 shall be met. 5.2.1.8.3 The environmentally hazardous substance mark shall be as shown in Figure 5.2.1.8.3. Figure 5.2.1.8.3 Environmentally hazardous substance mark - 219 - The marking shall be in the form of a square set at an angle of 45° (diamond-shaped). The symbol (fish and tree) shall be black on white or suitable contrasting background. The minimum dimensions shall be 100 mm x 100 mm and the minimum width of the line forming the diamond shall be 2 mm. If the size of the package so requires, the dimensions/line thickness may be reduced, provided the marking remains clearly visible. Where dimensions are not specified, all features shall be in approximate proportion to those shown. NOTE: The labelling provisions of 5.2.2 apply in addition to any requirement for packages to bear the environmentally hazardous substance mark. 5.2.1.9 Orientation arrows 5.2.1.9.1 Except as provided in 5.2.1.9.2: - Combination packagings having inner packagings containing liquids; - Single packagings fitted with vents; and - Cryogenic receptacles intended for the carriage of refrigerated liquefied gases, shall be legibly marked with package orientation arrows which are similar to the illustration shown below or with those meeting the specifications of ISO 780:1997. The orientation arrows shall appear on two opposite vertical sides of the package with the arrows pointing in the correct upright direction. They shall be rectangular and of a size that is clearly visible commensurate with the size of the package. Depicting a rectangular border around the arrows is optional. Figure 5.2.1.9.1.1 Figure 5.2.1.9.1.2 or Two black or red arrows on white or suitable contrasting background. The rectangular border is optional. All features shall be in approximate proportion to those shown. 5.2.1.9.2 Orientation arrows are not required on: (a) Outer packagings containing pressure receptacles except cryogenic receptacles; (b) Outer packagings containing dangerous goods in inner packagings each containing not more than 120 ml, with sufficient absorbent material between the inner and outer packagings to completely absorb the liquid contents; (c) Outer packagings containing Class 6.2 infectious substances in primary receptacles each containing not more than 50 ml; (d) Type IP-2, type IP-3, type A, type B(U), type B(M) or type C packages containing Class 7 radioactive material; (e) Outer packagings containing articles which are leak-tight in all orientations (e.g. alcohol or mercury in thermometers, aerosols, etc.); or (f) Outer packagings containing dangerous goods in hermetically sealed inner packagings each containing not more than 500 ml. - 220 - 5.2.1.9.3 Arrows for purposes other than indicating proper package orientation shall not be displayed on a package marked in accordance with this sub-section. 5.2.2 Labelling of packages 5.2.2.1 Labelling provisions 5.2.2.1.1 For each article or substance listed in Table A of Chapter 3.2, the labels shown in Column (5) shall be affixed unless otherwise provided for by a special provision in Column (6). 5.2.2.1.2 Indelible danger markings corresponding exactly to the prescribed models may be used instead of labels. (Reserved) 5.2.2.1.3 to 5.2.2.1.5 5.2.2.1.6 Except as provided in 5.2.2.2.1.2, each label shall: (a) be affixed to the same surface of the package, if the dimensions of the package allow; for packages of Class1 and 7, near the mark indicating the proper shipping name; (b) be so placed on the package that it is not covered or obscured by any part or attachment to the packaging or any other label or marking; and (c) be displayed next to each other when more than one label is required. Where a package is of such an irregular shape or small size that a label cannot be satisfactorily affixed, the label may be attached to the package by a securely affixed tag or other suitable means. 5.2.2.1.7 Intermediate bulk containers of more than 450 litres capacity and large packagings shall be labelled on two opposite sides. 5.2.2.1.8 (Reserved) 5.2.2.1.9 Special provisions for the labelling of self-reactive substances and organic peroxides (a) The label conforming to model No. 4.1 also implies that the product may be flammable and hence no label conforming to model No. 3 is required. In addition, a label conforming to model No. 1 shall be applied for self-reactive substances Type B, unless the competent authority has permitted this label to be dispensed with for a specific packaging because test data have proven that the self-reactive substance in such a packaging does not exhibit explosive behaviour. (b) The label conforming to model No. 5.2 also implies that the product may be flammable and hence no label conforming to model No. 3 is required. In addition, the following labels shall be applied: (i) A label conforming to model No. 1 for organic peroxides type B, unless the competent authority has permitted this label to be dispensed with for a specific packaging because test data have proven that the organic peroxide in such a packaging does not exhibit explosive behaviour; (ii) A label conforming to model No. 8 is required when Packing Group I or II criteria of Class 8 are met. For self-reactive substances and organic peroxides mentioned by name, the labels to be affixed are indicated in the list found in 2.2.41.4 and 2.2.52.4 respectively. 5.2.2.1.10 Special provisions for the labelling of infectious substances packages In addition to the label conforming to model No. 6.2, infectious substances packages shall bear any other label required by the nature of the contents. - 221 - 5.2.2.1.11 Special provisions for the labelling of radioactive material 5.2.2.1.11.1 Except when enlarged labels are used in accordance with 5.3.1.1.3, each package, overpack and container containing radioactive material shall bear the labels conforming to the applicable models Nos. 7A, 7B or 7C, according to the appropriate category. Labels shall be affixed to two opposite sides on the outside of the package or overpack or on the outside of all four sides of a container or tank. In addition, each package, overpack and container containing fissile material, other than fissile material excepted under the provisions of 2.2.7.2.3.5 shall bear labels conforming to model No.7E; such labels, where applicable, shall be affixed adjacent to the labels conforming to the applicable model Nos. 7A, 7B or 7C.. Labels shall not cover the markings specified in 5.2.1. Any labels which do not relate to the contents shall be removed or covered. 5.2.2.1.11.2 Each label conforming to the applicable model No. 7A, 7B or 7C shall be completed with the following information. (a) Contents: (i) except for LSA-I material, the name(s) of the radionuclide(s) as taken from Table 2.2.7.2.2.1, using the symbols prescribed therein. For mixtures of radionuclides, the most restrictive nuclides shall be listed to the extent the space on the line permits. The group of LSA or SCO shall be shown following the name(s) of the radionuclide(s). The terms "LSA-II","LSA-III", "SCO-I" and "SCO-II" shall be used for this purpose; (ii) for LSA-I material, only the term "LSA-I" is necessary; the name of the radionuclide is not necessary; (b) Activity: The maximum activity of the radioactive contents during carriage expressed in becquerels (Bq) with the appropriate SI prefix symbol (see 1.2.2.1). For fissile material, the total mass of fissile nuclides in units of grams (g), or multiples thereof, may be used in place of activity; (c) For overpacks and containers the "contents" and "activity" entries on the label shall bear the information required in (a) and (b) above, respectively, totalled together for the entire contents of the overpack or container except that on labels for overpacks or containers containing mixed loads of packages containing different radionuclides, such entries may read "See Transport Documents"; (d) Transport index: The number determined in accordance with 5.1.5.3.1 and 5.1.5.3.2 (no transport index entry is required for category I-WHITE). 5.2.2.1.11.3 Each label conforming to the model No. 7E shall be completed with the criticality safety index (CSI) as stated in the certificate of approval applicable in the countries through or into which the consignment is carried and issued by the competent authority or as specified in 6.4.11.2 or 6.4.11.3. 5.2.2.1.11.4 For overpacks and containers, the label conforming to model No. 7E shall bear the sum of the criticality safety indexes of all the packages contained therein. 5.2.2.1.11.5 In all cases of international carriage of packages requiring competent authority approval of design or shipment, for which different approval types apply in the different countries concerned by the shipment, labelling shall be in accordance with the certificate of the country of origin of design. 5.2.2.2 Provisions for labels 5.2.2.2.1 Labels shall satisfy the provisions below and conform, in terms of colour, symbols and general format, to the models shown in 5.2.2.2.2. Corresponding models required for other modes of transport, with minor variations which do not affect the obvious meaning of the label, are also acceptable. NOTE: Where appropriate, labels in 5.2.2.2.2 are shown with a dotted outer boundary as provided for in 5.2.2.2.1.1. This is not required when the label is applied on a background of contrasting colour. - 222 - 5.2.2.2.1.1 Labels shall be configured as shown in Figure 5.2.2.2.1.1. Figure 5.2.2.2.1.1       Class/division label * The class or for Classes 4.1, 4.2 and 4.3, the figure "4" or for Classes 6.1 and 6.2, the figure "6", shall be shown in the bottom corner. ** Additional text/numbers/letters shall (if mandatory) or may (if optional) be shown in this bottom half. *** The class symbol or, for divisions 1.4, 1.5 and 1.6, the division number and for Model No 7E the word "FISSILE" shall be shown in this top half. 5.2.2.2.1.1.1 Labels shall be displayed on a background of contrasting colour, or shall have either a dotted or solid outer boundary line. 5.2.2.2.1.1.2 The label shall be in the form of a square set at an angle of 45° (diamond-shaped). The minimum dimensions shall be 100 mm x 100 mm and the minimum width of the line inside the edge forming the diamond shall be 2 mm. The line inside the edge shall be parallel and 5 mm from the outside of that line to the edge of the label. The line inside the edge on the upper half of the label shall be the same colour as the symbol and the line inside the edge on the lower half of the label shall be the same colour as the class or division number in the bottom corner. Where dimensions are not specified, all features shall be in approximate proportion to those shown. 5.2.2.2.1.1.3 If the size of the package so requires the dimensions may be reduced, provided the symbols and other elements of the label remain clearly visible. The line inside the edge shall remain 5 mm to the edge of the label. The minimum width of the line inside the edge shall remain 2 mm. Dimensions for cylinders shall comply with 5.2.2.2.1.2. 5.2.2.2.1.2 Cylinders for Class 2 may, on account of their shape, orientation and securing mechanisms for carriage, bear labels representative of those specified in this section and the environmentally hazardous substance mark when appropriate, which have been reduced in size, according to the dimensions outlined in ISO 7225:2005, "Gas cylinders - Precautionary labels", for display on the non-cylindrical part (shoulder) of such cylinders. Notwithstanding the provisions of 5.2.2.1.6, labels and the environmentally hazardous substance mark (see 5.2.1.8.3) may overlap to the extent provided for by ISO 7225:2005. However, in all cases, the primary risk label and the figures appearing on any label shall remain fully visible and the symbols recognizable. Empty uncleaned pressure receptacles for gases of Class 2 may be carried with obsolete or damaged labels for the purposes of refilling or inspection as appropriate and the application of a new label in conformity with current regulations or for the disposal of the pressure receptacle. - 223 - 5.2.2.2.1.3 With the exception of labels for Divisions 1.4, 1.5 and 1.6 of Class 1, the upper half of the label shall contain the pictorial symbol and the lower half shall contain: (a) For Classes 1, 2, 3, 5.1, 5.2, 7, 8 and 9, the class number; (b) For Classes 4.1, 4.2 and 4.3, the figure "4"; (c) For Classes 6.1 and 6.2, the figure "6". The labels may include text such as the UN number or words describing the hazard (e.g. "flammable") in accordance with 5.2.2.2.1.5 provided the text does not obscure or detract from the other required label elements. 5.2.2.2.1.4 In addition, except for Divisions 1.4, 1.5 and 1.6, labels for Class 1 shall show in the lower half, above the class number, the division number and the compatibility group letter for the substance or article. Labels for Divisions 1.4, 1.5 and 1.6 shall show in the upper half the division number, and in the lower half the class number and the compatibility group letter. 5.2.2.2.1.5 On labels other than those for material of Class 7, the optional insertion of any text (other than the class number) in the space below the symbol shall be confined to particulars indicating the nature of the risk and precautions to be taken in handling. 5.2.2.2.1.6 The symbols, text and numbers shall be clearly legible and indelible and shall be shown in black on all labels except for: 5.2.2.2.1.7 (a) the Class 8 label, where the text (if any) and class number shall appear in white; (b) labels with entirely green, red or blue backgrounds where they may be shown in white; (c) the Class 5.2 label, where the symbol may be shown in white; and (d) labels conforming to model No. 2.1 displayed on cylinders and gas cartridges for gases of UN Nos. 1011, 1075, 1965 and 1978, where they may be shown in the background colour of the receptacle if adequate contrast is provided. All labels shall be able to withstand open weather exposure without a substantial reduction in effectiveness. - 224 - 5.2.2.2.2 Specimen labels CLASS 1 HAZARD Explosive substances or articles (No. 1) Divisions 1.1, 1.2 and 1.3 Symbol (exploding bomb): black; Background: orange; Figure '1' in bottom corner (No. 1.4) (No. 1.5) (No. 1.6) Division 1.4 Division 1.5 Division 1.6 Background: orange; Figures: black; Numerals shall be about 30 mm in height and be about 5 mm thick (for a label measuring 100 mm x 100 mm); Figure '1' in bottom corner Place for division - to be left blank if explosive is the subsidiary risk Place for compatibility group - to be left blank if explosive is the subsidiary risk CLASS 2 HAZARD Gases (No. 2.1) Flammable gases Symbol (flame): black or white; (except as provided for in 5.2.2.2.1.6 (d)) Background: red; Figure '2' in bottom corner (No. 2.2) Non flammable, non-toxic gases Symbol (gas cylinder): black or white; Background: green; Figure '2' in bottom corner CLASS 3 HAZARD Flammable liquids 3 3 (No. 3) Symbol (flame): black or white; Background: red; Figure '3' in bottom corner (No.2.3) Toxic gases Symbol (skull and crossbones): black; Background: white; Figure '2' in bottom corner - 225 - - 226 - CLASS 7 HAZARD Radioactive material (No. 7C) (No. 7B) (No. 7A) Category III - Yellow Category II - Yellow Category I - White Symbol (trefoil): black; Symbol (trefoil): black; Background: upper half yellow with white border, lower half white; Background: white; Text (mandatory): black in lower half of label: Text (mandatory): black in lower half of label: 'RADIOACTIVE' 'RADIOACTIVE' 'CONTENTS .......' 'CONTENTS .......' 'ACTIVITY ......' 'ACTIVITY ......' In a black outlined box: 'TRANSPORT INDEX'; One red bar shall Two red vertical bars shall Three red vertical bars shall follow the word 'RADIOACTIVE'; follow the word 'RADIOACTIVE' ; follow the word 'RADIOACTIVE'; Figure '7' in bottom corner. Figure '7' in bottom corner. (No. 7E) Class 7 fissile material Background: white; Text (mandatory): black in upper half of label: 'FISSILE'; In a black outlined box in the lower half of the label: 'CRITICALITY SAFETY INDEX' Figure '7' in bottom corner. CLASS 8 HAZARD Corrosive substances CLASS 9 HAZARD Miscellaneous dangerous substances and articles (No. 9) Symbol (seven vertical stripes in upper half): black; Background: white; Figure '9' underlined in bottom corner (No. 8) Symbol (liquids, spilling from two glass vessels and attacking a hand and a metal): black; Background: upper half white; lower half black with white border; Figure '8' in bottom corner - 227 - CHAPTER 5.3 PLACARDING AND MARKING OF CONTAINERS, MEGCs, MEMUs, TANKCONTAINERS, PORTABLE TANKS AND VEHICLES NOTE: For marking and placarding of containers, MEGCs, tank-containers and portable tanks for carriage in a transport chain including a maritime journey, see also 1.1.4.2.1. If the provisions of 1.1.4.2.1 (c) are applied, only 5.3.1.3 and 5.3.2.1.1 of this Chapter are applicable. 5.3.1 Placarding 5.3.1.1 General provisions 5.3.1.1.1 As and when required in this section, placards shall be affixed to the exterior surface of containers, MEGCs, MEMUs, tank-containers, portable tanks and vehicles. Placards shall correspond to the labels required in Column (5) and, where appropriate, Column (6) of Table A of Chapter 3.2 for the dangerous goods contained in the container, MEGC, MEMU, tank-container, portable tank or vehicle and shall conform to the specifications given in 5.3.1.7. Placards shall be displayed on a background of contrasting colour, or shall have either a dotted or solid outer boundary line. 5.3.1.1.2 For Class 1, compatibility groups shall not be indicated on placards if the vehicle, container or special compartments of MEMUs are carrying substances or articles belonging to two or more compatibility groups. Vehicles, containers or special compartments of MEMUs carrying substances or articles of different divisions shall bear only placards conforming to the model of the most dangerous division in the order: 1.1 (most dangerous), 1.5, 1.2, 1.3, 1.6, 1.4 (least dangerous). When 1.5 D substances are carried with substances or articles of Division 1.2, the vehicle or container shall be placarded as Division 1.1. Placards are not required for the carriage of explosives of Division 1.4, compatibility group S. 5.3.1.1.3 For Class 7, the primary risk placard shall conform to model No. 7D as specified in 5.3.1.7.2. This placard is not required for vehicles or containers carrying excepted packages and for small containers. Where both Class 7 labels and placards would be required to be affixed to vehicles, containers, MEGCs, tank-containers or portable tanks, an enlarged label corresponding to the required label of model No. 7A, 7B or 7C may be displayed instead of placard No.7D to serve both purposes. In that case, the dimensions shall be not less than 250 mm by 250 mm. 5.3.1.1.4 Containers, MEGCs, MEMUs, tank-containers, portable tanks or vehicles containing goods of more than one class need not bear a subsidiary risk placard if the hazard represented by that placard is already indicated by a primary or subsidiary risk placard. 5.3.1.1.5 Placards which do not relate to the dangerous goods being carried, or residues thereof, shall be removed or covered. 5.3.1.1.6 When the placarding is affixed to folding panels, they shall be designed and secured so that they cannot unfold or come loose from the holder during carriage (especially as a result of impacts or unintentional actions). 5.3.1.2 Placarding of containers, MEGCs, tank-containers and portable tanks NOTE: This sub-section does not apply to swap bodies, except tank swap bodies or swap bodies carried in combined road/rail transport. The placards shall be affixed to both sides and at each end of the container, MEGC, tank-container or portable tank. - 229 - When the tank-container or portable tank has multiple compartments and carries two or more dangerous goods, the appropriate placards shall be displayed along each side at the position of the relevant compartments and one placard of each model shown on each side at both ends. 5.3.1.3 Placarding of vehicles carrying containers, MEGCs, tank-containers or portable tanks NOTE: This sub-section does not apply to the placarding of vehicles carrying swap bodies other than tank swap bodies or than swap bodies carried in combined road/rail transport; for such vehicles, see 5.3.1.5. If the placards affixed to the containers, MEGCs, tank-containers or portable tanks are not visible from outside the carrying vehicles, the same placards shall also be affixed to both sides and at the rear of the vehicle. Otherwise, no placard need be affixed on the carrying vehicle. 5.3.1.4 Placarding of vehicles for carriage in bulk, tank-vehicles, battery-vehicles, MEMUs and vehicles with demountable tanks 5.3.1.4.1 Placards shall be affixed to both sides and at the rear of the vehicle. When the tank-vehicle or the demountable tank carried on the vehicle has multiple compartments and carries two or more dangerous goods, the appropriate placards shall be displayed along each side at the position of the relevant compartments and one placard of each model shown on each side at the rear of the vehicle. However, in such case, if all compartments have to bear the same placards, these placards need be displayed only once along each side and at the rear of the vehicle. Where more than one placard is required for the same compartment, these placards shall be displayed adjacent to each other. NOTE: When, in the course of an ADR journey or at the end of an ADR journey, a tank semi-trailer is separated from its tractor to be loaded on board a ship or an inland navigation vessel, placards shall also be displayed at the front of the semi-trailer. 5.3.1.4.2 MEMUs with tanks and bulk containers shall be placarded in accordance with 5.3.1.4.1 for the substances contained therein. For tanks with a capacity of less than 1 000 litres placards may be replaced by labels conforming to 5.2.2.2. 5.3.1.4.3 For MEMUs carrying packages containing substances or articles of Class 1 (other than of Division 1.4, Compatibility group S), placards shall be affixed to both sides and at the rear of the MEMU. Special compartments for explosives shall be placarded in accordance with the provisions of 5.3.1.1.2. The last sentence of 5.3.1.1.2 does not apply. 5.3.1.5 Placarding of vehicles carrying packages only NOTE: This sub-section applies also to vehicles carrying swap bodies loaded with packages, except for combined road/rail transport; for combined road/rail transport, see 5.3.1.2 and 5.3.1.3. 5.3.1.5.1 For vehicles carrying packages containing substances or articles of Class 1 (other than of Division 1.4, compatibility group S), placards shall be affixed to both sides and at the rear of the vehicle. 5.3.1.5.2 For vehicles carrying radioactive material of Class 7 in packagings or IBCs (other than excepted packages), placards shall be affixed to both sides and at the rear of the vehicle. 5.3.1.6 Placarding of empty tank-vehicles, battery-vehicles, MEGCs, MEMUs, tank-containers, portable tanks and empty vehicles and containers for carriage in bulk 5.3.1.6.1 Empty tank-vehicles, vehicles with demountable tanks, battery-vehicles, MEGCs, MEMUs, tank-containers and portable tanks uncleaned and not degassed, and empty vehicles and containers for carriage in bulk, uncleaned, shall continue to display the placards required for the previous load. - 230 - 5.3.1.7 Specifications for placards 5.3.1.7.1 Except as provided in 5.3.1.7.2 for the Class 7 placard, and in 5.3.6.2 for the environmentally hazardous substance mark, a placard shall be configured as shown in Figure 5.3.1.7.1. Figure 5.3.1.7.1 Placard (except for Class 7) The placard shall be in the form of a square set at an angle of 45° (diamond-shaped). The minimum dimensions shall be 250 mm x 250 mm (to the edge of the placard). The line inside the edge shall be parallel and 12.5 mm from the outside of that line to the edge of the placard. The symbol and line inside the edge shall correspond in colour to the label for the class or division of the dangerous goods in question. The class or division symbol/numeral shall be positioned and sized in proportion to those prescribed in 5.2.2.2 for the corresponding class or division of the dangerous goods in question. The placard shall display the number of the class or division (and for goods in Class 1, the compatibility group letter) of the dangerous goods in question in the manner prescribed in 5.2.2.2 for the corresponding label, in digits not less than 25 mm high. Where dimensions are not specified, all features shall be in approximate proportion to those shown. 5.3.1.7.2 The Class 7 placard shall be not less than 250 mm by 250 mm with a black line running 5 mm inside the edge and parallel with it and is otherwise as shown below (Model No. 7D). The number "7" shall not be less than 25 mm high. The background colour of the upper half of the placard shall be yellow and of the lower half white, the colour of the trefoil and the printing shall be black. The use of the word "RADIOACTIVE" in the bottom half is optional to allow the use of this placard to display the appropriate UN number for the consignment. - 231 - Placard for radioactive material of Class 7 5 m m 10 mm MINIMUM N IN M O SI EN IM D m M 0m 25 7 IM U U M 25 D 0 IM m E m NS IO IM IN M N RADIOACTIVE (No.7D) Symbol (trefoil): black; Background: upper half yellow with white border, lower half white; The lower half shall show the word "RADIOACTIVE" or alternatively, the appropriate UN Number, and the figure "7" in the bottom corner. 5.3.1.7.3 For tanks with a capacity of not more than 3 m3 and for small containers, placards may be replaced by labels conforming to 5.2.2.2. If these labels are not visible from outside the carrying vehicle, placards according to 5.3.1.7.1 shall also be affixed to both sides and at the rear of the vehicle. 5.3.1.7.4 For Classes 1 and 7, if the size and construction of the vehicle are such that the available surface area is insufficient to affix the prescribed placards, their dimensions may be reduced to 100 mm on each side. 5.3.2 Orange-coloured plate marking 5.3.2.1 General orange-coloured plate marking provisions 5.3.2.1.1 Transport units carrying dangerous goods shall display two rectangular orange-coloured plates conforming to 5.3.2.2.1, set in a vertical plane. They shall be affixed one at the front and the other at the rear of the transport unit, both perpendicular to the longitudinal axis of the transport unit. They shall be clearly visible. If a trailer containing dangerous goods is detached from its motor vehicle during carriage of dangerous goods, an orange-coloured plate shall remain affixed to the rear of the trailer. When tanks are marked in accordance with 5.3.2.1.3, this plate shall correspond to the most hazardous substance carried in the tank. 5.3.2.1.2 When a hazard identification number is indicated in Column (20) of table A of Chapter 3.2, tankvehicles, battery vehicles or transport units having one or more tanks carrying dangerous goods shall in addition display on the sides of each tank, each tank compartment or each element of battery vehicles, clearly visible and parallel to the longitudinal axis of the vehicle, orange-coloured plates identical with those prescribed in 5.3.2.1.1. These orange-coloured plates shall bear the hazard identification number and the UN number prescribed respectively in Columns (20) and (1) of table A of Chapter 3.2 for each of the substances carried in the tank, in a compartment of the tank or in an element of a battery vehicle. For MEMUs these requirements shall only apply to tanks with a capacity of 1 000 litres or more and bulk containers. - 232 - 5.3.2.1.3 For tank-vehicles or transport units having one or more tanks carrying substances with UN Nos. 1202, 1203 or 1223, or aviation fuel classified under UN Nos. 1268 or 1863, but no other dangerous substance, the orange-coloured plates prescribed in 5.3.2.1.2 need not be affixed if the plates affixed to the front and rear in accordance with 5.3.2.1.1 bear the hazard identification number and the UN number prescribed for the most hazardous substance carried, i.e. the substance with the lowest flashpoint. 5.3.2.1.4 When a hazard identification number is indicated in Column (20) of Table A of Chapter 3.2, transport units and containers carrying unpackaged solids or articles or packaged radioactive material with a single UN number required to be carried under exclusive use and no other dangerous goods shall in addition display on the sides of each transport unit or container, clearly visible and parallel to the longitudinal axis of the vehicle, orange-coloured plates identical with those prescribed in 5.3.2.1.1. These orange-coloured plates shall bear the hazard identification number and the UN number prescribed respectively in Columns (20) and (1) of table A of Chapter 3.2 for each of the substances carried in bulk in the transport unit or in the container or for the packaged radioactive material when required to be carried under exclusive use in the transport unit or in the container. 5.3.2.1.5 If the orange-coloured plates prescribed in 5.3.2.1.2 and 5.3.2.1.4 affixed to the containers, tank-containers, MEGCs or portable tanks are not clearly visible from outside the carrying vehicle, the same plates shall also be affixed to both sides of the vehicle. NOTE: This paragraph need not be applied to the marking with orange coloured plates of closed and sheeted vehicles, carrying tanks with a maximum capacity of 3 000 litres. 5.3.2.1.6 For transport units carrying only one dangerous substance and no non-dangerous substance, the orange-coloured plates prescribed in 5.3.2.1.2, 5.3.2.1.4 and 5.3.2.1.5 shall not be necessary provided that those displayed at the front and rear in accordance with 5.3.2.1.1 bear the hazard identification number and the UN number for that substance prescribed respectively in Columns (20) and (1) of Table A of Chapter 3.2. 5.3.2.1.7 The requirements of 5.3.2.1.1 to 5.3.2.1.5 are also applicable to empty fixed or demountable tanks, battery-vehicles, tank-containers, portable tanks and MEGCs, uncleaned, not degassed or not decontaminated, MEMUs, uncleaned as well as to empty vehicles and containers for carriage in bulk, uncleaned or not decontaminated. 5.3.2.1.8 Orange-coloured marking which does not relate to dangerous goods carried, or residues thereof, shall be removed or covered. If plates are covered, the covering shall be total and remain effective after 15 minutes’ engulfment in fire. 5.3.2.2 Specifications for the orange-coloured plates 5.3.2.2.1 The orange-coloured plates shall be reflectorized and shall be of 40 cm base and of 30 cm high; they shall have a black border of 15 mm wide. The material used shall be weather-resistant and ensure durable marking. The plate shall not become detached from its mount in the event of 15 minutes’ engulfment in fire. It shall remain affixed irrespective of the orientation of the vehicle. The orangecoloured plates may be separated in their middle with a black horizontal line of 15 mm thickness. If the size and construction of the vehicle are such that the available surface area is insufficient to affix these orange-coloured plates, their dimensions may be reduced to a minimum of 300 mm for the base, 120 mm for the height and 10 mm for the black border. In this case, a different set of dimensions within the specified range may be used for the two orange-coloured plates specified in 5.3.2.1.1. When reduced dimensions of orange-coloured plates are used for a packaged radioactive material carried under exclusive use, only the UN number is required and the size of the digits stipulated in 5.3.2.2.2 may be reduced to 65 mm in height and 10 mm in stroke thickness. For containers carrying dangerous solid substances in bulk and for tank-containers, MEGCs and portable tanks, the plates prescribed in 5.3.2.1.2, 5.3.2.1.4 and 5.3.2.1.5 may be replaced by a selfadhesive sheet, by paint or by any other equivalent process. This alternative marking shall conform to the specifications set in this sub-section except for the provisions concerning resistance to fire mentioned in 5.3.2.2.1 and 5.3.2.2.2. - 233 - NOTE: The colour of the orange plates in conditions of normal use should have chromaticity coordinates lying within the area on the chromaticity diagram formed by joining the following coordinates: Chromaticity co-ordinates of points at the corners of the area on the chromaticity diagram x 0.52 0.52 0.578 0.618 y 0.38 0.40 0.422 0.38 Luminance factor of reflectorized colour: β > 0.12. Reference centre E, standard illuminant C, normal incidence 45°, viewed at 0°. Co-efficient of reflex luminous intensity at an angle of illumination of 5°, viewed at 0.2°: not less than 20 candelas per lux per m2. 5.3.2.2.2 The hazard identification number and the UN number shall consist of black digits 100 mm high and of 15 mm stroke thickness. The hazard-identification number shall be inscribed in the upper part of the plate and the UN number in the lower part; they shall be separated by a horizontal black line, 15 mm in stroke width, extending from side to side of the plate at mid-height (see 5.3.2.2.3).The hazard identification number and the UN number shall be indelible and shall remain legible after 15 minute’ engulfment in fire. Interchangeable numbers and letters on plates presenting the hazard identification number and the UN number shall remain in place during carriage and irrespective of the orientation of the vehicle. 5.3.2.2.3 Example of orange-coloured plate with hazard identification number and UN number 10 cm 30 cm 10 cm 33 1088 Hazard Identification number (2 or 3 figures preceded where appropriate by the letter X, see 5.3.2.3) UN number (4 figures) 40 cm Background orange. Border, horizontal line and figures black, 15 mm thickness. 5.3.2.2.4 The permitted tolerances for dimensions specified in this sub-section are ± 10%. 5.3.2.2.5 When the orange-coloured plate is affixed to folding panels, they shall be designed and secured so that they cannot unfold or come loose from the holder during carriage (especially as a result of impacts or unintentional actions). 5.3.2.3 Meaning of hazard identification numbers 5.3.2.3.1 The hazard identification number consists of two or three figures. In general, the figures indicate the following hazards: 2 3 4 Emission of gas due to pressure or to chemical reaction Flammability of liquids (vapours) and gases or self-heating liquid Flammability of solids or self-heating solid - 234 - 5 6 7 8 9 Oxidizing (fire-intensifying) effect Toxicity or risk of infection Radioactivity Corrosivity Risk of spontaneous violent reaction NOTE: The risk of spontaneous violent reaction within the meaning of figure 9 include the possibility following from the nature of a substance of a risk of explosion, disintegration and polymerization reaction following the release of considerable heat or flammable and/or toxic gases. Doubling of a figure indicates an intensification of that particular hazard. Where the hazard associated with a substance can be adequately indicated by a single figure, this is followed by zero. The following combinations of figures, however, have a special meaning: 22, 323, 333, 362, 382, 423, 44, 446, 462, 482, 539, 606, 623, 642, 823, 842, 90 and 99, see 5.3.2.3.2 below. If a hazard identification number is prefixed by the letter "X", this indicates that the substance will react dangerously with water. For such substances, water may only be used by approval of experts. For substances of Class 1, the classification code in accordance with Column (3 b) of Table A of Chapter 3.2, shall be used as the hazard identification number. The classification code consists of:  the division number in accordance with 2.2.1.1.5; and  the compatibility group letter in accordance with 2.2.1.1.6. 5.3.2.3.2 The hazard identification numbers listed in Column (20) of table A of Chapter 3.2 have the following meanings: 20 22 223 225 23 238 239 25 26 263 265 268 28 asphyxiant gas or gas with no subsidiary risk refrigerated liquefied gas, asphyxiant refrigerated liquefied gas, flammable refrigerated liquefied gas, oxidizing (fire-intensifying) flammable gas gas, flammable corrosive flammable gas, which can spontaneously lead to violent reaction oxidizing (fire-intensifying) gas toxic gas toxic gas, flammable toxic gas, oxidizing (fire-intensifying) toxic gas, corrosive gas, corrosive 30 flammable liquid (flash-point between 23 °C and 60 °C, inclusive) or flammable liquid or solid in the molten state with a flash-point above 60 °C, heated to a temperature equal to or above its flash-point, or self-heating liquid flammable liquid which reacts with water, emitting flammable gases flammable liquid which reacts dangerously with water, emitting flammable gases1 highly flammable liquid (flash-point below 23 °C) pyrophoric liquid pyrophoric liquid which reacts dangerously with water1 highly flammable liquid, toxic highly flammable liquid, corrosive highly flammable liquid, corrosive, which reacts dangerously with water1 highly flammable liquid which can spontaneously lead to violent reaction flammable liquid (flash-point between 23 °C and 60 °C, inclusive), slightly toxic, or self-heating liquid, toxic flammable liquid, toxic, which reacts with water, emitting flammable gases flammable liquid toxic, which reacts dangerously with water, emitting flammable gases1 323 X323 33 333 X333 336 338 X338 339 36 362 X362 1 Water not to be used except by approval of experts. - 235 - 368 38 382 X382 39 40 423 X423 43 X432 44 446 46 462 X462 48 482 X482 50 539 55 556 558 559 56 568 58 59 60 606 623 63 638 639 1 flammable liquid, toxic, corrosive flammable liquid (flash-point between 23 °C and 60 °C, inclusive), slightly corrosive or self-heating liquid, corrosive flammable liquid, corrosive, which reacts with water, emitting flammable gases flammable liquid, corrosive, which reacts dangerously with water, emitting flammable gases1 flammable liquid, which can spontaneously lead to violent reaction flammable solid, or self-reactive substance, or self-heating substance solid which reacts with water, emitting flammable gases, or flammable solid which reacts with water, emitting flammable gases or self-heating solid which reacts with water, emitting flammable gases solid which reacts dangerously with water, emitting flammable gases, or flammable solid which reacts dangerously with water, emitting flammable gases, or self-heating solid which reacts dangerously with water, emitting flammable gases1 spontaneously flammable (pyrophoric) solid spontaneously flammable (pyrophoric) solid which reacts dangerously with water, emitting flammable gases1 flammable solid, in the molten state at an elevated temperature flammable solid, toxic, in the molten state, at an elevated temperature flammable or self-heating solid, toxic toxic solid which reacts with water, emitting flammable gases solid which reacts dangerously with water, emitting toxic gases1 flammable or self-heating solid, corrosive corrosive solid which reacts with water, emitting flammable gases solid which reacts dangerously with water, emitting corrosive gases1 oxidizing (fire-intensifying) substance flammable organic peroxide strongly oxidizing (fire-intensifying) substance strongly oxidizing (fire-intensifying) substance, toxic strongly oxidizing (fire-intensifying) substance, corrosive strongly oxidizing (fire-intensifying) substance, which can spontaneously lead to violent reaction oxidizing substance (fire-intensifying), toxic oxidizing substance (fire-intensifying), toxic, corrosive oxidizing substance (fire-intensifying), corrosive oxidizing substance (fire-intensifying) which can spontaneously lead to violent reaction 64 642 65 66 663 664 665 668 X668 669 68 69 toxic or slightly toxic substance infectious substance toxic liquid, which reacts with water, emitting flammable gases toxic substance, flammable (flash-point between 23 °C and 60 °C, inclusive) toxic substance, flammable (flash-point between 23 °C and 60 °C, inclusive), corrosive toxic substance, flammable (flash-point not above 60 °C) which can spontaneously lead to violent reaction toxic solid, flammable or self-heating toxic solid, which reacts with water, emitting flammable gases toxic substance, oxidizing (fire-intensifying) highly toxic substance highly toxic substance, flammable (flash-point not above 60 °C) highly toxic solid, flammable or self-heating highly toxic substance, oxidizing (fire-intensifying) highly toxic substance, corrosive highly toxic substance, corrosive, which reacts dangerously with water1 highly toxic substance which can spontaneously lead to violent reaction toxic substance, corrosive toxic or slightly toxic substance, which can spontaneously lead to violent reaction 70 78 radioactive material radioactive material, corrosive Water not to be used except by approval of experts. - 236 - 80 X80 823 83 X83 839 X839 84 842 85 856 86 88 X88 883 884 885 886 X886 89 90 99 5.3.3 corrosive or slightly corrosive substance corrosive or slightly corrosive substance, which reacts dangerously with water1 corrosive liquid which reacts with water, emitting flammable gases corrosive or slightly corrosive substance, flammable (flash-point between 23 °C and 60 °C, inclusive) corrosive or slightly corrosive substance, flammable, (flash-point between 23 °C and 60 °C, inclusive), which reacts dangerously with water1 corrosive or slightly corrosive substance, flammable (flash-point between 23 °C and 60 °C inclusive) which can spontaneously lead to violent reaction corrosive or slightly corrosive substance, flammable (flash-point between 23 °C and 60 °C inclusive), which can spontaneously lead to violent reaction and which reacts dangerously with water1 corrosive solid, flammable or self-heating corrosive solid which reacts with water, emitting flammable gases corrosive or slightly corrosive substance, oxidizing (fire-intensifying) corrosive or slightly corrosive substance, oxidizing (fire-intensifying) and toxic corrosive or slightly corrosive substance, toxic highly corrosive substance highly corrosive substance, which reacts dangerously with water1 highly corrosive substance, flammable (flash-point between 23 °C and 60 °C inclusive) highly corrosive solid, flammable or self-heating highly corrosive substance, oxidizing (fire-intensifying) highly corrosive substance, toxic highly corrosive substance, toxic, which reacts dangerously with water1 corrosive or slightly corrosive substance, which can spontaneously lead to violent reaction environmentally hazardous substance; miscellaneous dangerous substances miscellaneous dangerous substance carried at an elevated temperature. Elevated temperature substance mark Tank-vehicles, tank-containers, portable tanks, special vehicles or containers or specially equipped vehicles or containers containing a substance that is carried or handed over for carriage in a liquid state at or above 100 °C or in a solid state at or above 240 °C shall bear on both sides and at the rear for vehicles, and on both sides and at each end for containers, tank-containers and portable tanks, the mark shown in Figure 5.3.3. Figure 5.3.3 Mark for carriage at elevated temperature 1 Water not to be used except by approval of experts. - 237 - The marking shall be an equilateral triangle. The colour of the mark shall be red. The minimum dimension of the sides shall be 250 mm. Where dimensions are not specified, all features shall be in approximate proportion to those shown. 5.3.4 (Reserved) 5.3.5 (Reserved) 5.3.6 Environmentally hazardous substance mark 5.3.6.1 When a placard is required to be displayed in accordance with the provisions of section 5.3.1, containers, MEGCs, tank-containers, portable tanks and vehicles containing environmentally hazardous substances meeting the criteria of 2.2.9.1.10 shall be marked with the environmentally hazardous substance mark shown in 5.2.1.8.3. 5.3.6.2 The environmentally hazardous substance mark for containers, MEGCs, tank-containers, portable tanks and vehicles shall be as described in 5.2.1.8.3 and Figure 5.2.1.8.3, except that the minimum dimensions shall be 250 mm x 250 mm. The other provisions of section 5.3.1 concerning placards shall apply mutatis mutandis to the mark. - 238 - CHAPTER 5.4 DOCUMENTATION 5.4.0 General 5.4.0.1 Unless otherwise specified, any carriage of goods governed by ADR shall be accompanied by the documentation prescribed in this Chapter, as appropriate. NOTE: For the list of documentation to be carried on board transport units, see 8.1.2. 5.4.0.2 The use of electronic data processing (EDP) or electronic data interchange (EDI) techniques as an aid to or instead of paper documentation is permitted, provided that the procedures used for the capture, storage and processing of electronics data meet the legal requirements as regards the evidential value and availability of data during transport in a manner at least equivalent to that of paper documentation. 5.4.0.3 When the dangerous goods transport information is given to the carrier by EDP or EDI techniques, the consignor shall be able to give the information to the carrier as a paper document, with the information in the sequence required by this Chapter. 5.4.1 Dangerous goods transport document and related information 5.4.1.1 General information required in the transport document 5.4.1.1.1 The transport document(s) shall contain the following information for each dangerous substance, material or article offered for carriage: (a) the UN number preceded by the letters "UN"; (b) the proper shipping name supplemented, when applicable (see 3.1.2.8.1) with the technical name in brackets (see 3.1.2.8.1.1), as determined in accordance with 3.1.2; (c) - for substances and articles of Class 1: the classification code given in Column (3b) of Table A in Chapter 3.2. When, in Column (5) of Table A in Chapter 3.2, label model numbers other than 1, 1.4, 1.5 and 1.6 are given, these label model numbers, in brackets, shall follow the classification code; - for radioactive material of Class 7: the Class number: "7"; NOTE: For radioactive material with a subsidiary risk, see also special provision 172 in Chapter 3.3. - (d) for substances and articles of other classes: the label model numbers given in Column (5) of Table A in Chapter 3.2 or applicable according to a special provision referred to in Column (6). When more than one label model numbers are given, the numbers following the first one shall be given in brackets. For substances and articles for which no label model is given in Column (5) of Table A in Chapter 3.2, their class according to Column (3a) shall be given instead; where assigned, the packing group for the substance which may be preceded by the letters "PG" (e.g. "PG II"), or the initials corresponding to the words "Packing Group" in the languages used according to 5.4.1.4.1; NOTE: For radioactive material of Class 7 with subsidiary risks, see special provision 172 (d) in Chapter 3.3. - 239 - (e) the number and a description of the packages when applicable. UN packaging codes may only be used to supplement the description of the kind of package (e.g. one box (4G)); NOTE: The number, type and capacity of each inner packaging within the outer packaging of a combination packaging is not required to be indicated. (f) the total quantity of each item of dangerous goods bearing a different UN number, proper shipping name or, when applicable, packing group (as a volume or as a gross mass, or as a net mass as appropriate); NOTE 1: In the case of intended application of 1.1.3.6, the total quantity of dangerous goods for each transport category shall be indicated in the transport document in accordance with 1.1.3.6.3. NOTE 2: For dangerous goods in machinery or equipment specified in this Annex, the quantity indicated shall be the total quantity of dangerous goods contained therein in kilograms or litres as appropriate. (g) the name and address of the consignor; (h) the name and address of the consignee(s). With the agreement of the competent authorities of the countries concerned by the carriage, when dangerous goods are carried to be delivered to multiple consignees who cannot be identified at the start of the carriage, the words "Delivery Sale" may be given instead; (i) a declaration as required by the terms of any special agreement; (j) (Reserved) (k) where assigned, the tunnel restriction code given in Column (15) of Table A of Chapter 3.2, in capitals within parenthesis. The tunnel restriction code need not be added in the transport document where the carriage is known beforehand not to pass through a tunnel with restrictions for carriage of dangerous goods. The location and order in which the elements of information required appear in the transport document is left optional, except that (a), (b), (c), (d) and (k) shall be shown in the order listed above (i.e. (a), (b), (c), (d), (k)) with no information interspersed, except as provided in ADR. Examples of such permitted dangerous goods descriptions are: "UN 1098 ALLYL ALCOHOL, 6.1 (3), I, (C/D)" or "UN 1098, ALLYL ALCOHOL, 6.1 (3), PG I, (C/D)" 5.4.1.1.2 The information required on a transport document shall be legible. Although upper case is used in Chapter 3.1 and in Table A in Chapter 3.2 to indicate the elements which shall be part of the proper shipping name, and although upper and lower case are used in this Chapter to indicate the information required in the transport document, except for the provisions in 5.4.1.1.1 (k), the use of upper or of lower case for entering the information in the transport document is left optional. 5.4.1.1.3 Special provisions for wastes If waste containing dangerous goods (other than radioactive wastes) is being carried, the proper shipping name shall be preceded by the word "WASTE", unless this term is part of the proper shipping name, e.g.: "UN 1230 WASTE METHANOL, 3 (6.1), II, (D/E)", or "UN 1230 WASTE METHANOL, 3 (6.1), PG II, (D/E)", or "UN 1993 WASTE FLAMMABLE LIQUID, N.O.S. (toluene and ethyl alcohol), 3, II, (D/E)", or "UN 1993 WASTE FLAMMABLE LIQUID, N.O.S. (toluene and ethyl alcohol), 3, PG II, (D/E)". - 240 - If the provision for waste as set out in 2.1.3.5.5 is applied, the following shall be added to the dangerous goods description required in 5.4.1.1.1 (a) to (d) and (k): "WASTE IN ACCORDANCE WITH 2.1.3.5.5" (e.g. "UN 3264, CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, II, (E), WASTE IN ACCORDANCE WITH 2.1.3.5.5"). The technical name, as prescribed in Chapter 3.3, special provision 274, need not be added. 5.4.1.1.4 (Deleted) 5.4.1.1.5 Special provisions for salvage packagings and salvage pressure receptacles When dangerous goods are carried in a salvage packaging or salvage pressure receptacle, the words "SALVAGE PACKAGING" or "SALVAGE PRESSURE RECEPTACLE" shall be added after the description of the goods in the transport document. 5.4.1.1.6 Special provision for empty means of containment, uncleaned 5.4.1.1.6.1 For empty means of containment, uncleaned, which contain the residue of dangerous goods of classes other than Class 7, the words "EMPTY, UNCLEANED" or "RESIDUE, LAST CONTAINED" shall be indicated before or after the dangerous goods description specified in 5.4.1.1.1 (a) to (d) and (k). Moreover, 5.4.1.1.1 (f) does not apply. 5.4.1.1.6.2 The special provision of 5.4.1.1.6.1 may be replaced with the provisions of 5.4.1.1.6.2.1, 5.4.1.1.6.2.2 or 5.4.1.1.6.2.3, as appropriate. 5.4.1.1.6.2.1 For empty packagings, uncleaned, which contain the residue of dangerous goods of classes other than Class 7, including empty uncleaned receptacles for gases with a capacity of not more than 1 000 litres, the particulars according to 5.4.1.1.1 (a), (b), (c), (d), (e) and (f) are replaced with "EMPTY PACKAGING", "EMPTY RECEPTACLE", "EMPTY IBC" or "EMPTY LARGE PACKAGING", as appropriate, followed by the information of the goods last loaded, as described in 5.4.1.1.1 (c). See example as follows: "EMPTY PACKAGING, 6.1 (3)". In addition, in such a case, if the dangerous goods last loaded are goods of Class 2, the information prescribed in 5.4.1.1.1 (c) may be replaced by the number of the class "2". 5.4.1.1.6.2.2 For empty means of containment other than packagings, uncleaned, which contain the residue of dangerous goods of classes other than Class 7 and for empty uncleaned receptacles for gases with a capacity of more than 1 000 litres, the particulars according to 5.4.1.1.1 (a) to (d) and (k) are preceded by "EMPTY TANK-VEHICLE", "EMPTY DEMOUNTABLE TANK", "EMPTY TANKCONTAINER", "EMPTY PORTABLE TANK", "EMPTY BATTERY-VEHICLE", "EMPTY MEGC", "EMPTY MEMU", "EMPTY VEHICLE", "EMPTY CONTAINER" or "EMPTY RECEPTACLE", as appropriate, followed by the words "LAST LOAD:". Moreover, paragraph 5.4.1.1.1 (f) does not apply. See examples as follows: "EMPTY TANK-VEHICLE, LAST LOAD: UN 1098 ALLYL ALCOHOL, 6.1 (3), I, (C/D)" or "EMPTY TANK-VEHICLE, LAST LOAD: UN 1098 ALLYL ALCOHOL, 6.1 (3), PG I, (C/D)". 5.4.1.1.6.2.3 When empty means of containment, uncleaned, which contain the residue of dangerous goods of classes other than Class 7, are returned to the consignor, the transport documents prepared for the full-capacity carriage of these goods may also be used. In such cases, the indication of the quantity is to be eliminated (by effacing it, striking it out or any other means) and replaced by the words "EMPTY, UNCLEANED RETURN". 5.4.1.1.6.3 (a) If empty tanks, battery- vehicles and MEGCs, uncleaned, are carried to the nearest place where cleaning or repair can be carried out in accordance with the provisions of 4.3.2.4.3, the following additional entry shall be made in the transport document: "Carriage in accordance with 4.3.2.4.3". - 241 - (b) If empty vehicles and containers, uncleaned, are carried to the nearest place where cleaning or repair can be carried out in accordance with the provisions of 7.5.8.1, the following additional entry shall be made in the transport document: "Carriage in accordance with 7.5.8.1". 5.4.1.1.6.4 For the carriage of fixed tanks (tank vehicles), demountable tanks, battery-vehicles, tank-containers and MEGCs under the conditions of 4.3.2.4.4, the following entry shall be included in the transport document: "Carriage in accordance with 4.3.2.4.4". 5.4.1.1.7 Special provisions for carriage in a transport chain including maritime or air carriage For carriage in accordance with 1.1.4.2.1, a statement shall be included in the transport document, as follows: "Carriage in accordance with 1.1.4.2.1". 5.4.1.1.8 and 5.4.1.1.9 (Reserved) 5.4.1.1.10 (Deleted) 5.4.1.1.11 Special provisions for the carriage of IBCs or portable tanks after the date of expiry of the last periodic test or inspection For carriage in accordance with 4.1.2.2 (b), 6.7.2.19.6 (b), 6.7.3.15.6 (b) or 6.7.4.14.6 (b), a statement to this effect shall be included in the transport document, as follows: "Carriage in accordance with 4.1.2.2 (b)", "Carriage in accordance with 6.7.2.19.6 (b)", "Carriage in accordance with 6.7.3.15.6 (b)" or "Carriage in accordance with 6.7.4.14.6 (b)" as appropriate. 5.4.1.1.12 (Reserved) 5.4.1.1.13 Special provisions for carriage in multi-compartment tank-vehicles or transport units with more than one tank When by derogation from 5.3.2.1.2 a multi-compartment tank-vehicle or a transport unit with more than one tank is marked in accordance with 5.3.2.1.3, the substances contained in each tank or in each compartment of a tank shall be specified in the transport document. 5.4.1.1.14 Special provisions for the carriage of substances carried under elevated temperature If the proper shipping name of a substance which is carried or offered for carriage in a liquid state at a temperature equal to or exceeding 100 °C, or in a solid state at a temperature equal to or exceeding 240 °C, does not convey the elevated temperature condition (for example, by using the term "MOLTEN" or "ELEVATED TEMPERATURE" as part of the proper shipping name), the word "HOT" shall immediately precede the proper shipping name. 5.4.1.1.15 Special provisions for the carriage of substances stabilized by temperature control If the word "STABILIZED" is part of the proper shipping name (see also 3.1.2.6), when stabilization is by means of temperature control, the control and emergency temperatures (see 2.2.41.1.17) shall be indicated in the transport document, as follows: "Control temperature: ....°C Emergency temperature: .... °C" 5.4.1.1.16 Information required in accordance with special provision 640 in Chapter 3.3 Where it is required by special provision 640 of Chapter 3.3, the transport document shall bear the inscription "Special provision 640X" where "X" is the capital letter appearing after the pertinent reference to special provision 640 in column (6) of Table A of Chapter 3.2. - 242 - 5.4.1.1.17 Special provisions for the carriage of solids in bulk containers conforming to 6.11.4 When solid substances are carried in bulk containers conforming to 6.11.4, the following statement shall be shown on the transport document (see NOTE at the beginning of 6.11.4): "Bulk container BK(x)1 approved by the competent authority of…" 5.4.1.1.18 Special provisions for carriage of environmentally hazardous substances (aquatic environment) When a substance belonging to one of classes 1 to 9 meets the classification criteria of 2.2.9.1.10, the transport document shall bear the additional inscription "ENVIRONMENTALLY HAZARDOUS" or "MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS". This additional requirement does not apply to UN Nos. 3077 and 3082 or for the exceptions listed in 5.2.1.8.1. The inscription "MARINE POLLUTANT" (according to 5.4.1.4.3 of the IMDG Code) is acceptable for carriage in a transport chain including maritime carriage. 5.4.1.1.19 Special provisions for carriage of packagings, discarded, empty, uncleaned (UN 3509) For packagings, discarded, empty, uncleaned, the proper shipping name specified in 5.4.1.1.1 (b) shall be complemented with the words "(WITH RESIDUES OF [...])" followed by the class(es) and subsidiary risk(s) corresponding to the residues, in the class numbering order. Moreover, 5.4.1.1.1 (f) does not apply. Example: Packagings, discarded, empty, uncleaned having contained goods of Class 4.1 packed together with packagings, discarded, empty, uncleaned having contained goods of Class 3 with a Class 6.1 subsidiary risk should be referred to in the transport document as: "UN 3509 PACKAGINGS, DISCARDED, EMPTY, UNCLEANED (WITH RESIDUES OF 3, 4.1, 6.1), 9". 5.4.1.2 Additional or special information required for certain classes 5.4.1.2.1 Special provisions for Class 1 (a) The transport document shall indicate, in addition to the requirements in 5.4.1.1.1 (f): - 1 2 the total net mass, in kg, of explosive contents2 for each substance or article bearing a different UN number; the total net mass, in kg, of explosive contents2 for all substances and articles covered by the transport document; (b) For mixed packing of two different goods, the description of the goods in the transport document shall include the UN numbers and names printed in capitals in Columns (1) and (2) of Table A of Chapter 3.2 of both substances or articles. If more than two different goods are contained in the same package in conformity with the mixed packing provisions given in 4.1.10 special provisions MP1, MP2 and MP20 to MP24, the transport document shall indicate under the description of the goods the UN numbers of all the substances and articles contained in the package, in the form, "Goods of UN Nos..."; (c) For the carriage of substances and articles assigned to an n.o.s. entry or the entry "0190 SAMPLES, EXPLOSIVE" or packed conforming to packing instruction P101 of 4.1.4.1, a copy of the competent authority approval with the conditions of carriage shall be attached to the transport document. It shall be drafted in an official language of the forwarding country and also, if that language is not English, French or German, in English, French or German unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise; (x) shall be replaced with "1" or "2" as appropriate. For articles, "explosive contents" means the explosive substance contained in the article. - 243 - (d) If packages containing substances and articles of compatibility groups B and D are loaded together in the same vehicle in accordance with the requirements of 7.5.2.2, a copy of the competent authority approval of the protective compartment or containment system in accordance with 7.5.2.2, note a under the table, shall be attached to the transport document. It shall be drafted in an official language of the forwarding country and also, if that language is not English, French or German, in English, French or German unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise; (e) When explosive substances or articles are carried in packagings conforming to packing instruction P101, the transport document shall bear the inscription "Packaging approved by the competent authority of ..." (see 4.1.4.1, packing instruction P101); (f) (Reserved) (g) When fireworks of UN Nos. 0333, 0334, 0335, 0336 and 0337 are carried, the transport document shall bear the inscription: "Classification of fireworks by the competent authority of XX with the firework reference XX/YYZZZZ". The classification approval certificate need not be carried with the consignment, but shall be made available by the consignor to the carrier or the competent authorities for control purposes. The classification approval certificate or a copy of it shall be in an official language of the forwarding country, and also, if that language is not German, English or French, in German, English or French. NOTE 1: The commercial or technical name of the goods may be entered additionally to the proper shipping name in the transport document. NOTE 2: The classification reference(s) shall consist of the ADR Contracting Party in which the classification code according to special provision 645 of 3.3.1 was approved, indicated by the distinguishing sign for motor vehicles in international traffic (XX)3, the competent authority identification (YY) and a unique serial reference (ZZZZ). Examples of such classification references are: GB/HSE123456 D/BAM1234. 5.4.1.2.2 Additional provisions for Class 2 (a) For the carriage of mixtures (see 2.2.2.1.1) in tanks (demountable tanks, fixed tanks, portable tanks, tank-containers or elements of battery-vehicles or of MEGCs), the composition of the mixture as a percentage of the volume or as a percentage of the mass shall be given. Constituents below 1% need not be indicated (see also 3.1.2.8.1.2). The composition of the mixture need not be given when the technical names authorized by special provisions 581, 582 or 583 are used to supplement the proper shipping name; (b) For the carriage of cylinders, tubes, pressure drums, cryogenic receptacles and bundles of cylinders under the conditions of 4.1.6.10, the following entry shall be included in the transport document: "Carriage in accordance with 4.1.6.10". 5.4.1.2.3 Additional provisions for self-reactive substances of Class 4.1 and organic peroxides of Class 5.2 5.4.1.2.3.1 For self-reactive substances of Class 4.1 and for organic peroxides of Class 5.2 that require temperature control during carriage (for self-reactive substances see 2.2.41.1.17; for organic peroxides, see 2.2.52.1.15 to 2.2.52.1.17), the control and emergency temperatures shall be indicated in the transport document, as follows: "Control temperature: ... °C Emergency temperature: ... °C". 3 Distinguishing sign for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 244 - 5.4.1.2.3.2 When for certain self-reactive substances of Class 4.1 and certain organic peroxides of Class 5.2 the competent authority has permitted the label conforming to model No.1 to be dispensed with for a specific packaging (see 5.2.2.1.9), a statement to this effect shall be included in the transport document, as follows: "The label conforming to model No. 1 is not required". 5.4.1.2.3.3 When organic peroxides and self-reactive substances are carried under conditions where approval is required (for organic peroxides see 2.2.52.1.8, 4.1.7.2.2 and special provision TA2 of 6.8.4; for self-reactive substances see 2.2.41.1.13 and 4.1.7.2.2, a statement to his effect shall be included in the transport document, e.g. "Carriage in accordance with 2.2.52.1.8". A copy of the competent authority approval with the conditions of carriage shall be attached to the transport document. It shall be drafted in an official language of the forwarding country and also, if that language is not English, French or German, in English, French or German unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise. 5.4.1.2.3.4 When a sample of an organic peroxide (see 2.2.52.1.9) or a self-reactive substance (see 2.2.41.1.15) is carried, a statement to this effect shall be included in the transport document, e.g. "Carriage in accordance with 2.2.52.1.9". 5.4.1.2.3.5 When self-reactive substances type G (see Manual of Tests and Criteria, Part II, paragraph 20.4.2 (g)) are carried, the following statement may be given in the transport document: "Not a self-reactive substance of Class 4.1". When organic peroxides type G (see Manual of Tests and Criteria, Part II, paragraph 20.4.3 (g)) are carried, the following statement may be given in the transport document: "Not a substance of Class 5.2". 5.4.1.2.4 Additional provisions for Class 6.2 In addition to the information concerning the consignee (see 5.4.1.1.1 (h)), the name and telephone number of a responsible person shall be indicated. 5.4.1.2.5 Additional provisions for Class 7 5.4.1.2.5.1 The following information shall be inserted in the transport document for each consignment of Class 7 material, as applicable, in the order given and immediately after the information required under 5.4.1.1.1 (a) to (c) and (k): (a) The name or symbol of each radionuclide or, for mixtures of radionuclides, an appropriate general description or a list of the most restrictive nuclides; (b) A description of the physical and chemical form of the material, or a notation that the material is special form radioactive material or low dispersible radioactive material. A generic chemical description is acceptable for chemical form. For radioactive material with a subsidiary risk, see sub-paragraph (c) of special provision 172 of Chapter 3.3; (c) The maximum activity of the radioactive contents during carriage expressed in becquerels (Bq) with an appropriate SI prefix symbol (see 1.2.2.1). For fissile material, the mass of fissile material (or mass of each fissile nuclide for mixtures when appropriate) in grams (g), or appropriate multiples thereof, may be used in place of activity; (d) The category of the package, i.e. I-WHITE, II-YELLOW, III-YELLOW; (e) The transport index (categories II-YELLOW and III-YELLOW only); - 245 - (f) 5.4.1.2.5.2 For fissile material: (i) Shipped under one exception of 2.2.7.2.3.5 (a) to (f), reference to that paragraph; (ii) Shipped under 2.2.7.2.3.5 (c) to (e), the total mass of fissile nuclides; (iii) Contained in a package for which one of 6.4.11.2 (a) to (c) or 6.4.11.3 is applied, reference to that paragraph; (iv) The criticality safety index, where applicable; (g) The identification mark for each competent authority certificate of approval (special form radioactive material, low dispersible radioactive material, fissile material excepted under 2.2.7.2.3.5 (f), special arrangement, package design, or shipment) applicable to the consignment; (h) For consignments of more than one package, the information required in 5.4.1.1.1 and in (a) to (g) above shall be given for each package. For packages in an overpack, container, or vehicle, a detailed statement of the contents of each package within the overpack, container, or vehicle and, where appropriate, of each overpack, container, or vehicle shall be included. If packages are to be removed from the overpack, container, or vehicle at a point of intermediate unloading, appropriate transport documents shall be made available; (i) Where a consignment is required to be shipped under exclusive use, the statement "EXCLUSIVE USE SHIPMENT"; and (j) For LSA-II and LSA-III substances, SCO-I and SCO-II, the total activity of the consignment as a multiple of A2. For radioactive material for which the A2 value is unlimited, the multiple of A2 shall be zero. The consignor shall provide in the transport documents a statement regarding actions, if any, that are required to be taken by the carrier. The statement shall be in the languages deemed necessary by the carrier or the authorities concerned, and shall include at least the following information: (a) Supplementary requirements for loading, stowage, carriage, handling and unloading of the package, overpack or container including any special stowage provisions for the safe dissipation of heat (see special provision CV33 (3.2) of 7.5.11), or a statement that no such requirements are necessary; (b) Restrictions on the mode of carriage or vehicle and any necessary routeing instructions; (c) Emergency arrangements appropriate to the consignment. 5.4.1.2.5.3 In all cases of international carriage of packages requiring competent authority approval of design or shipment, for which different approval types apply in the different countries concerned by the shipment, the UN number and proper shipping name required in 5.4.1.1.1 shall be in accordance with the certificate of the country of origin of design. 5.4.1.2.5.4 The applicable competent authority certificates need not necessarily accompany the consignment. The consignor shall make them available to the carrier(s) before loading and unloading. 5.4.1.3 (Reserved) 5.4.1.4 Format and language 5.4.1.4.1 The document containing the information in 5.4.1.1 and 5.4.1.2 may be that already required by other regulations in force for carriage by another mode of carriage. In case of multiple consignees, the name and address of the consignees and the quantities delivered enabling the nature and quantities carried to be evaluated at any time, may be entered in other documents which are to be used or in any other documents made mandatory according to other specific regulations and which shall be on board the vehicle. - 246 - The particulars to be entered in the document shall be drafted in an official language of the forwarding country, and also, if that language is not English, French, or German, in English, French or German, unless international road carriage tariffs, if any, or agreements concluded between the countries concerned in the transport operation, provide otherwise. 5.4.1.4.2 If by reason of the size of the load, a consignment cannot be loaded in its entirety on a single transport unit, at least as many separate documents, or copies of the single document, shall be made out as transport units loaded. Furthermore, in all cases, separate transport documents shall be made out for consignments or parts of consignments which may not be loaded together on the same vehicle by reason of the prohibitions set forth in 7.5.2. The information relative to the hazards of the goods to be carried (as indicated in 5.4.1.1) may be incorporated in, or combined with, an existing transport or cargo handling document. The layout of the information in the document (or the order of transmission of the corresponding data by electronic data processing (EDP) or electronic data interchange (EDI) techniques) shall be as provided in 5.4.1.1.1. When an existing transport document or cargo handling document cannot be used for the purposes of dangerous goods documentation for multimodal transport, the use of documents corresponding to the example shown in 5.4.5 is considered advisable4. 5.4.1.5 Non-dangerous goods When goods mentioned by name in Table A of Chapter 3.2, are not subject to ADR because they are considered as non-dangerous according to Part 2, the consignor may enter in the transport document a statement to that effect, e.g.: "Not goods of Class ..." NOTE: This provision may be used in particular when the consignor considers that, due to the chemical nature of the goods (e.g. solutions and mixtures) carried or to the fact that such goods are deemed dangerous for other regulatory purposes the consignment might be subject to control during the journey. If used, the relevant recommendations of the UNECE United Nations Centre for Trade Facilitation and Electronic Business (UN/CEFACT) may be consulted, in particular Recommendation No. 1 (United Nations Layout Key for Trade Documents) (ECE/TRADE/137, edition 81.3), UN Layout Key for Trade Documents - Guidelines for Applications (ECE/TRADE/270, edition 2002), Recommendation No. 11 (Documentary Aspects of the International Transport of Dangerous Goods) (ECE/TRADE/204, edition 96.1 – currently under revision) and Recommendation No. 22 (Layout Key for Standard Consignment Instructions) (ECE/TRADE/168, edition 1989). Refer also to the UN/CEFACT Summary of Trade Facilitation Recommendations (ECE/TRADE/346, edition 2006) and the United Nations Trade Data Elements Directory (UNTDED) (ECE/TRADE/362, edition 2005). 4 - 247 - 5.4.2 Large container or vehicle packing certificate If the carriage of dangerous goods in a large container precedes a voyage by sea, a container packing certificate conforming to section 5.4.2 of the IMDG Code5 shall be provided with the transport document6. The functions of the transport document required under 5.4.1 and of the container packing certificate as provided above may be incorporated into a single document; if not, these documents shall be attached one to the other. If these functions are incorporated into a single document, the inclusion in the transport document of a statement that the loading of the container has been carried out in accordance with the applicable modal regulations together with the identification of the person responsible for the container packing certificate shall be sufficient. NOTE: The container packing certificate is not required for portable tanks, tank-containers and MEGCs. 5 Guidelines for use in practice and in training for loading goods in transport units have also been drawn up by the International Maritime Organization (IMO), the International Labour Organization (ILO) and the United Nations Economic Commission for Europe (UNECE) and have been published by IMO ("IMO/ILO/UNECE Guidelines for Packing of Cargo Transport Units (CTUs)"). 6 Section 5.4.2 of the IMDG Code requires the following: "5.4.2 Container/vehicle packing certificate 5.4.2.1 When dangerous goods are packed or loaded into any container or vehicle, those responsible for packing the container or vehicle shall provide a “container/vehicle packing certificate” specifying the container/vehicle identification number(s) and certifying that the operation has been carried out in accordance with the following conditions: .1 The container/vehicle was clean, dry and apparently fit to receive the goods; .2 Packages, which need to be segregated in accordance with applicable segregation requirements, have not been packed together onto or in the container/vehicle [unless approved by the competent authority concerned in accordance with 7.2.2.3 (of the IMDG Code)]; .3 All packages have been externally inspected for damage, and only sound packages have been loaded; .4 Drums have been stowed in an upright position, unless otherwise authorized by the competent authority, and all goods have been properly loaded, and, where necessary, adequately braced with securing material to suit the mode(s) of transport for the intended journey; .5 Goods loaded in bulk have been evenly distributed within the container/vehicle; .6 For consignments including goods of class 1, other than division 1.4, the container/vehicle is structurally serviceable in conformity with 7.4.6 (of the IMDG Code); .7 The container/vehicle and packages are properly marked, labelled, and placarded, as appropriate; .8 When substances presenting a risk of asphyxiation are used for cooling or conditioning purposes (such as dry ice (UN 1845) or nitrogen, refrigerated liquid (UN 1977) or argon, refrigerated liquid (UN 1951)), the container/vehicle is externally marked in accordance with 5.5.3.6 (of the IMDG Code); and .9 A dangerous goods transport document, as indicated in 5.4.1 (of the IMDG Code) has been received for each dangerous goods consignment loaded in the container/vehicle. NOTE: The container/vehicle packing certificate is not required for tanks 5.4.2.2 The information required in the dangerous goods transport document and the container/vehicle packing certificate may be incorporated into a single document; if not, these documents shall be attached one to the other. If the information is incorporated into a single document, the document shall include a signed declaration such as “It is declared that the packing of the goods into the container/vehicle has been carried out in accordance with the applicable provisions”. This declaration shall be dated and the person signing this declaration shall be identified on the document. Facsimile signatures are acceptable where applicable laws and regulations recognize the legal validity of facsimile signatures. 5.4.2.3 If the container/vehicle packing certificate is presented to the carrier by means of EDP or EDI transmission techniques, the signature(s) may be electronic signature(s) or may be replaced by the name(s) (in capitals) of the person authorized to sign. 5.4.2.4 When the container/vehicle packing certificate is given to a carrier by EDP or EDI techniques and subsequently the dangerous goods are transferred to a carrier that requires a paper dangerous goods transport document, the carrier shall ensure that the paper document indicates "Original received electronically" and the name of the signatory shall be shown in capital letters. - 248 - 5.4.3 Instructions in writing 5.4.3.1 As an aid during an accident emergency situation that may occur or arise during carriage, instructions in writing in the form specified in 5.4.3.4 shall be carried in the vehicle crew’s cab and shall be readily available. 5.4.3.2 These instructions shall be provided by the carrier to the vehicle crew in language(s) that each member can read and understand before the commencement of the journey. The carrier shall ensure that each member of the vehicle crew concerned understands and is capable of carrying out the instructions properly. 5.4.3.3 Before the start of the journey, the members of the vehicle crew shall inform themselves of the dangerous goods loaded and consult the instructions in writing for details on actions to be taken in the event of an accident or emergency. 5.4.3.4 The instructions in writing shall correspond to the following four page model as regards its form and contents. - 249 - INSTRUCTIONS IN WRITING ACCORDING TO ADR Actions in the event of an accident or emergency In the event of an accident or emergency that may occur or arise during carriage, the members of the vehicle crew shall take the following actions where safe and practicable to do so: - Apply the braking system, stop the engine and isolate the battery by activating the master switch where available; - Avoid sources of ignition, in particular, do not smoke, use electronic cigarettes or similar devices or switch on any electrical equipment; - Inform the appropriate emergency services, giving as much information about the incident or accident and substances involved as possible; - Put on the warning vest and place the self-standing warning signs as appropriate; - Keep the transport documents readily available for responders on arrival; - Do not walk into or touch spilled substances and avoid inhalation of fumes, smoke, dusts and vapours by staying up wind; - Where appropriate and safe to do so, use the fire extinguishers to put out small/initial fires in tyres, brakes and engine compartments; - Fires in load compartments shall not be tackled by members of the vehicle crew; - Where appropriate and safe to do so, use on-board equipment to prevent leakages into the aquatic environment or the sewage system and to contain spillages; - Move away from the vicinity of the accident or emergency, advise other persons to move away and follow the advice of the emergency services; - Remove any contaminated clothing and used contaminated protective equipment and dispose of it safely. - 251 - Additional guidance to members of the vehicle crew on the hazard characteristics of dangerous goods by class and on actions subject to prevailing circumstances Danger labels and placards Hazard characteristics Additional guidance (1) (2) (3) Explosive substances and articles 1 1.5 1.6 May have a range of properties and effects such as mass detonation; projection of fragments; intense fire/heat flux; formation of bright light, loud noise or smoke. Take cover but stay away from windows. Sensitive to shocks and/or impacts and/or heat. Explosive substances and articles Slight risk of explosion and fire. Take cover. 1.4 Flammable gases Risk of fire. Risk of explosion. May be under pressure. Take cover. Risk of asphyxiation. Keep out of low areas. May cause burns and/or frostbite. 2.1 Containments may explode when heated. Non-flammable, non-toxic gases Risk of asphyxiation. May be under pressure. Take cover. May cause frostbite. Keep out of low areas. Containments may explode when heated. 2.2 Toxic gases Risk of intoxication. Use emergency escape mask. May be under pressure. May cause burns and/or frostbite. Containments may explode when heated. Take cover. Keep out of low areas. 2.3 Flammable liquids Risk of fire. Take cover. Risk of explosion. Containments may explode when heated. 3 3 Keep out of low areas. 3 Flammable solids, self-reactive substances and solid desensitized explosives 4 4.1 Risk of fire. Flammable or combustible, may be ignited by heat, sparks or flames. May contain self-reactive substances that are liable to exothermic decomposition in the case of heat supply, contact with other substances (such as acids, heavy-metal compounds or amines), friction or shock. This may result in the evolution of harmful and flammable gases or vapours or selfignition. Containments may explode when heated. Risk of explosion of desensitized explosives after loss of desensitizer. Substances liable to spontaneous combustion Risk of fire by spontaneous combustion if packages are damaged or contents are spilled. May react vigorously with water 4 4.2 Substances which, in contact with water, emit flammable gases Risk of fire and explosion in contact with water. 4 4 4.3 - 252 - Spilled substances should be kept dry by covering the spillages. Danger labels and placards (1) Hazard characteristics (2) Additional guidance (3) Oxidizing substances Risk of vigorous reaction, ignition and explosion Avoid mixing with flammable or combustible in contact with combustible or flammable substances (e.g. sawdust). substances. 5.1 5.1 Organic peroxides 5.2 5.2 5.2 Risk of exothermic decomposition at elevated temperatures, contact with other substances (such as acids, heavy-metal compounds or amines), Avoid mixing with flammable or combustible friction or shock. This may result in the evolution substances (e.g. sawdust). of harmful and flammable gases or vapours or self-ignition. Toxic substances Risk of intoxication by inhalation, skin contact or ingestion. Risk to the aquatic environment or the sewerage system. Use emergency escape mask. 6.1 Infectious substances Risk of infection. May cause serious disease in humans or animals. Risk to the aquatic environment or the sewerage system. 6.2 Radioactive material 7A 7B Risk of intake and external radiation. Limit time of exposure. RADIOACTIVE 7 7C 7D Fissile material Risk of nuclear chain reaction. 7E Corrosive substances Risk of burns by corrosion. May react vigorously with each other, with water and with other substances. Spilled substance may evolve corrosive vapours. 8 Miscellaneous dangerous substances and articles Risk to the aquatic environment or the sewerage system. Risk of burns. Risk of fire. Risk of explosion. Risk to the aquatic environment or the sewerage system. 9 NOTE 1: For dangerous goods with multiple risks and for mixed loads, each applicable entry shall be observed. NOTE 2: Additional guidance shown above may be adapted to reflect the classes of dangerous goods to be carried and their means of transport. - 253 - Mark (1) Additional guidance to members of the vehicle crew on the hazard characteristics of dangerous goods, indicated by marks, and on actions subject to prevailing circumstances Hazard characteristics Additional guidance (2) (3) Risk to the aquatic environment or the sewerage system Environmentally hazardous substances Avoid contact with hot parts of the transport unit and the spilled substance. Risk of burns by heat. Elevated temperature substances Equipment for personal and general protection to carry out general actions and hazard specific emergency actions to be carried on board the vehicle in accordance with section 8.1.5 of ADR The following equipment shall be carried on board the transport unit: - for each vehicle, a wheel chock of a size suited to the maximum mass of the vehicle and to the diameter of the wheel; two self-standing warning signs; eye rinsing liquida; and for each member of the vehicle crew - a warning vest; portable lighting apparatus; a pair of protective gloves; and eye protection. Additional equipment required for certain classes: - a b an emergency escape mask for each member of the vehicle crew shall be carried on board the vehicle for danger label numbers 2.3 or 6.1; a shovelb; a drain sealb; a collecting containerb. Not required for danger label numbers 1, 1.4, 1.5, 1.6, 2.1, 2.2 and 2.3. Only required for solids and liquids with danger label numbers 3, 4.1, 4.3, 8 or 9. - 254 - 5.4.4 Retention of dangerous goods transport information 5.4.4.1 The consignor and the carrier shall retain a copy of the dangerous goods transport document and additional information and documentation as specified in ADR, for a minimum period of three months. 5.4.4.2 When the documents are kept electronically or in a computer system, the consignor and the carrier shall be able to reproduce them in a printed form. 5.4.5 Example of a multimodal dangerous goods form Example of a form which may be used as a combined dangerous goods declaration and container packing certificate for multimodal carriage of dangerous goods. - 255 - 2. Transport document number 3. Page 1 of 4. Shipper's reference Pages 5. Freight Forwarder's reference 6. Consignee 7. Carrier (to be completed by the carrier) SHIPPER'S DECLARATION * FOR DANGEROUS GOODS: you must specify: UN no., proper shipping name, hazard class, packing group (where assigned) and any other element of information required under applicable national and international regulations I hereby declare that the contents of this consignment are fully and accurately described below by the proper shipping name, and are classified, packaged, marked and labeled /placarded and are in all respects in proper condition for transport according to the applicable international and national governmental regulations. 8. This shipment is within the limitations prescribed for: (Delete non-applicable) PASSENGER AND 9. Additional handling information CARGO AIRCRAFT ONLY CARGO AIRCRAFT 10. Vessel / flight no. and date 11. Port / place of loading 12. Port / place of discharge 13. Destination 14. Shipping marks * Number and kind of packages; description of goods 15. Container identification No./ vehicle registration No. 16. Seal number (s) CONTAINER/VEHICLE PACKING CERTIFICATE I hereby declare that the goods described above have been packed/loaded into the container/vehicle identified above in accordance with the applicable provisions ** Gross mass (kg) 17. Container/vehicle size & type Net mass 18. Tare (kg) Cube (m3) 19. Total gross mass (including tare) (kg) 21.RECEIVING ORGANISATION RECEIPT Received the above number of packages/containers/trailers in apparent good order and condition unless stated hereon: RECEIVING ORGANISATION REMARKS: MUST BE COMPLETED AND SIGNED FOR ALL CONTAINER/VEHICLE LOADS BY PERSON RESPONSIBLE FOR PACKING/LOADING 20. Name of company Haulier's name 22. Name of company (OF SHIPPER PREPARING THIS NOTE) Name / Status of declarant Vehicle reg. no. Name / Status of declarant Place and date Signature and date Place and date Signature of declarant DRIVER'S SIGNATURE Signature of declarant BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK MULTIMODAL DANGEROUS GOODS FORM 1. Shipper / Consignor /Sender ** See 5.4.2. - 1. Shipper / Consignor /Sender Continuation Sheet BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK HATCHINGS BLACK MULTIMODAL DANGEROUS GOODS FORM 2. Transport document number 3. Page 1 of 4. Shipper's reference Pages 5. Freight Forwarder's reference * Number and kind of packages; description of goods Gross mass (kg) Net mass Cube (m3) * FOR DANGEROUS GOODS: you must specify: UN no., proper shipping name, hazard class, packing group (where assigned) and any other element of information required under applicable national and international regulations 14. Shipping marks - CHAPTER 5.5 SPECIAL PROVISIONS 5.5.1 (Deleted) 5.5.2 Special provisions applicable to fumigated cargo transport units (UN 3359) 5.5.2.1 General 5.5.2.1.1 Fumigated cargo transport units (UN 3359) containing no other dangerous goods are not subject to any provisions of ADR other than those of this section. NOTE: For the purposes of this Chapter, cargo transport unit means a vehicle, a container, a tankcontainer, a portable tank or a MEGC. 5.5.2.1.2 When the fumigated cargo transport unit is loaded with dangerous goods in addition to the fumigant, any provision of ADR relevant to these goods (including placarding, marking and documentation) applies in addition to the provisions of this section. 5.5.2.1.3 Only cargo transport units that can be closed in such a way that the escape of gas is reduced to a minimum shall be used for the carriage of cargo under fumigation. 5.5.2.2 Training Persons engaged in the handling of fumigated cargo transport units shall be trained commensurate with their responsibilities. 5.5.2.3 Marking and placarding 5.5.2.3.1 A fumigated cargo transport unit shall be marked with a warning mark, as specified in 5.5.2.3.2, affixed at each access point in a location where it will be easily seen by persons opening or entering the cargo transport unit. This mark shall remain on the cargo transport unit until the following provisions are met: 5.5.2.3.2 (a) The fumigated cargo transport unit has been ventilated to remove harmful concentrations of fumigant gas; and (b) The fumigated goods or materials have been unloaded. The fumigation warning mark shall be as shown in Figure 5.5.2.3.2. - 259 - Figure 5.5.2.3.2 THIS UNIT IS UNDER FUMIGATION WITH ( fumigant name* ) APPLIED ON ( date* ) ( time* ) VENTILATED ON ( date* ) Minimum dimension 300 mm DANGER DO NOT ENTER * Insert details as appropriate Minimum dimension 400 mm Fumigation warning mark The marking shall be a rectangle. The minimum dimensions shall be 400 mm wide x 300 mm high and the minimum width of the outer line shall be 2 mm. The marking shall be in black print on a white background with lettering not less than 25 mm high. Where dimensions are not specified, all features shall be in approximate proportion to those shown. 5.5.2.3.3 If the fumigated cargo transport unit has been completely ventilated either by opening the doors of the unit or by mechanical ventilation after fumigation, the date of ventilation shall be marked on the fumigation warning mark. 5.5.2.3.4 When the fumigated cargo transport unit has been ventilated and unloaded, the fumigation warning mark shall be removed. 5.5.2.3.5 Placards conforming to model No. 9 (see 5.2.2.2.2) shall not be affixed to a fumigated cargo transport unit except as required for other Class 9 substances or articles packed therein. 5.5.2.4 Documentation 5.5.2.4.1 Documents associated with the carriage of cargo transport units that have been fumigated and have not been completely ventilated before carriage shall include the following information: - "UN 3359, fumigated cargo transport unit, 9", or "UN 3359, fumigated cargo transport unit, Class 9"; - The date and time of fumigation; and - The type and amount of the fumigant used. These particulars shall be drafted in an official language of the forwarding country and also, if the language is not English, French or German, in English, French or German, unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise. 5.5.2.4.2 The documents may be in any form, provided they contain the information required in 5.5.2.4.1. This information shall be easy to identify, legible and durable. 5.5.2.4.3 Instructions for disposal of any residual fumigant including fumigation devices (if used) shall be provided. 5.5.2.4.4 A document is not required when the fumigated cargo transport unit has been completely ventilated and the date of ventilation has been marked on the warning mark (see 5.5.2.3.3 and 5.5.2.3.4). - 260 - 5.5.3 Special provisions applicable to packages and vehicles and containers containing substances presenting a risk of asphyxiation when used for cooling or conditioning purposes (such as dry ice (UN 1845) or nitrogen, refrigerated liquid (UN 1977) or argon, refrigerated liquid (UN 1951)) 5.5.3.1 Scope 5.5.3.1.1 This section is not applicable to substances which may be used for cooling or conditioning purposes when carried as a consignment of dangerous goods. When they are carried as a consignment, these substances shall be carried under the relevant entry of Table A in Chapter 3.2 in accordance with the associated conditions of carriage. 5.5.3.1.2 This section is not applicable to gases in cooling cycles. 5.5.3.1.3 Dangerous goods used for cooling or conditioning tanks or MEGCs during carriage are not subject to this section. 5.5.3.1.4 Vehicles and containers containing substances used for cooling or conditioning purposes include vehicles and containers containing substances used for cooling or conditioning purposes inside packages as well as vehicles and containers with unpackaged substances used for cooling or conditioning purposes. 5.5.3.1.5 Sub-sections 5.5.3.6 and 5.5.3.7 only apply when there is an actual risk of asphyxiation in the vehicle or container. It is for the participants concerned to assess this risk, taking into consideration the hazards presented by the substances being used for cooling or conditioning, the amount of substance to be carried, the duration of the journey and the types of containment to be used. 5.5.3.2 General 5.5.3.2.1 Vehicles and containers containing substances used for cooling or conditioning purposes (other than fumigation) during carriage are not subject to any provisions of ADR other than those of this section. 5.5.3.2.2 When dangerous goods are loaded in vehicles or containers containing substances used for cooling or conditioning purposes any provisions of ADR relevant to these dangerous goods apply in addition to the provisions of this section. 5.5.3.2.3 (Reserved) 5.5.3.2.4 Persons engaged in the handling or carriage of vehicles and containers containing substances used for cooling or conditioning purposes shall be trained commensurate with their responsibilities. 5.5.3.3 Packages containing a coolant or conditioner 5.5.3.3.1 Packaged dangerous goods requiring cooling or conditioning assigned to packing instructions P203, P620, P650, P800, P901 or P904 of 4.1.4.1 shall meet the appropriate requirements of that packing instruction. 5.5.3.3.2 For packaged dangerous goods requiring cooling or conditioning assigned to other packing instructions, the packages shall be capable of withstanding very low temperatures and shall not be affected or significantly weakened by the coolant or conditioner. Packages shall be designed and constructed to permit the release of gas to prevent a build-up of pressure that could rupture the packaging. The dangerous goods shall be packed in such a way as to prevent movement after the dissipation of any coolant or conditioner. 5.5.3.3.3 Packages containing a coolant or conditioner shall be carried in well ventilated vehicles and containers. This provision does not apply when such packages are carried in insulated, refrigerated or mechanically refrigerated equipment, as defined in the Agreement on the International Carriage of Perishable Foodstuffs and on the Special Equipment to be Used for such Carriage (ATP). - 261 - 5.5.3.4 Marking of packages containing a coolant or conditioner 5.5.3.4.1 Packages containing dangerous goods used for cooling or conditioning shall be marked with the name indicated in Column (2) of Table A of Chapter 3.2 of these dangerous goods followed by the words "AS COOLANT" or "AS CONDITIONER" as appropriate in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements concluded between the countries concerned in the transport operation provide otherwise. 5.5.3.4.2 The markings shall be durable, legible and placed in such a location and of such a size relative to the package as to be readily visible. 5.5.3.5 Vehicles and containers containing unpackaged dry ice 5.5.3.5.1 If dry ice in unpackaged form is used, it shall not come into direct contact with the metal structure of a vehicle or container to avoid embrittlement of the metal. Measures shall be taken to provide adequate insulation between the dry ice and the vehicle or container by providing a minimum of 30 mm separation (e.g. by using suitable low heat conducting materials such as timber planks, pallets etc). 5.5.3.5.2 Where dry ice is placed around packages, measures shall be taken to ensure that packages remain in the original position during carriage after the dry ice has dissipated. 5.5.3.6 Marking of vehicles and containers 5.5.3.6.1 Vehicles and containers containing dangerous goods used for cooling or conditioning purposes shall be marked with a warning mark, as specified in 5.5.3.6.2 affixed at each access point in a location where it will be easily seen by persons opening or entering the vehicle or container. This mark shall remain on the vehicle or container until the following provisions are met: 5.5.3.6.2 (a) The vehicle or container has been ventilated to remove harmful concentrations of coolant or conditioner; and (b) The cooled or conditioned goods have been unloaded. The warning mark shall be as shown in Figure 5.5.3.6.2. - 262 - Figure 5.5.3.6.2 Coolant/conditioning warning mark for vehicles and containers * Insert the name indicated in Column (2) of Table A of Chapter 3.2 of the coolant/conditioner. The lettering shall be in capitals, all be on one line and shall be at least 25 mm high. If the length of the proper shipping name is too long to fit in the space provided, the lettering may be reduced to the maximum size possible to fit. For example: "CARBON DIOXIDE, SOLID". ** Insert "AS COOLANT" or "AS CONDITIONER" as appropriate. The lettering shall be in capitals, all be on one line and be at least 25 mm high. The marking shall be a rectangle. The minimum dimensions shall be 150 mm wide x 250 mm high. The word "WARNING" shall be in red or white and be at least 25 mm high. Where dimensions are not specified, all features shall be in approximate proportion to those shown. The word "WARNING" and the words "AS COOLANT" or "AS CONDITIONER", as appropriate, shall be in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements concluded between the countries concerned in the transport operation provide otherwise. - 263 - 5.5.3.7 Documentation 5.5.3.7.1 Documents (such as a bill of lading, cargo manifest or CMR/CIM consignment note) associated with the carriage of vehicles or containers containing or having contained substances used for cooling or conditioning purposes and have not been completely ventilated before carriage shall include the following information: (a) The UN number preceded by the letters "UN"; and (b) The name indicated in Column (2) of Table A of Chapter 3.2 followed by the words "AS COOLANT" or "AS CONDITIONER" as appropriate in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise. For example: UN 1845, CARBON DIOXIDE, SOLID, AS COOLANT. 5.5.3.7.2 The transport document may be in any form, provided it contains the information required in 5.5.3.7.1. This information shall be easy to identify, legible and durable. - 264 - PART 6 Requirements for the construction and testing of packagings, intermediate bulk containers (IBCs), large packagings, tanks and bulk containers CHAPTER 6.1 REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF PACKAGINGS 6.1.1 General 6.1.1.1 The requirements of this Chapter do not apply to: (a) Packages containing radioactive material of Class 7, unless otherwise provided (see 4.1.9); (b) Packages containing infectious substances of Class 6.2, unless otherwise provided (see Chapter 6.3, Note and packing instruction P621 of 4.1.4.1); (c) Pressure receptacles containing gases of Class 2; (d) Packages whose net mass exceeds 400 kg; (e) Packagings for liquids, other than combination packagings, with a capacity exceeding 450 litres. 6.1.1.2 The requirements for packagings in 6.1.4 are based on packagings currently used. In order to take into account progress in science and technology, there is no objection to the use of packagings having specifications different from those in 6.1.4, provided that they are equally effective, acceptable to the competent authority and able successfully to withstand the tests described in 6.1.1.3 and 6.1.5. Methods of testing other than those described in this Chapter are acceptable, provided they are equivalent, and are recognized by the competent authority. 6.1.1.3 Every packaging intended to contain liquids shall successfully undergo a suitable leakproofness test, and be capable of meeting the appropriate test level indicated in 6.1.5.4.3: (a) Before it is first used for carriage; (b) After remanufacturing or reconditioning, before it is re-used for carriage; For this test, packagings need not have their own closures fitted. The inner receptacle of composite packagings may be tested without the outer packaging provided the test results are not affected. This test is not necessary for: 6.1.1.4 - Inner packagings of combination packagings; - Inner receptacles of composite packagings (glass, porcelain or stoneware), marked with the symbol "RID/ADR" according to 6.1.3.1 (a) (ii); - Light gauge metal packagings, marked with the symbol "RID/ADR" according to 6.1.3.1 (a) (ii). Packagings shall be manufactured, reconditioned and tested under a quality assurance programme which satisfies the competent authority in order to ensure that each packaging meets the requirements of this Chapter. NOTE: ISO 16106:2006 "Packaging – Transport packages for dangerous goods – Dangerous goods packagings, intermediate bulk containers (IBCs) and large packagings – Guidelines for the application of ISO 9001" provides acceptable guidance on procedures which may be followed. - 267 - 6.1.1.5 Manufacturers and subsequent distributors of packagings shall provide information regarding procedures to be followed and a description of the types and dimensions of closures (including required gaskets) and any other components needed to ensure that packages as presented for carriage are capable of passing the applicable performance tests of this Chapter. 6.1.2 Code for designating types of packagings 6.1.2.1 The code consists of: (a) An Arabic numeral indicating the kind of packaging, e.g. drum, jerrican, etc., followed by; (b) A capital letter(s) in Latin characters indicating the nature of the material, e.g. steel, wood, etc., followed where necessary by; (c) An Arabic numeral indicating the category of packaging within the kind to which the packaging belongs. 6.1.2.2 In the case of composite packagings, two capital letters in Latin characters are used in sequence in the second position of the code. The first indicates the material of the inner receptacle and the second that of the outer packaging. 6.1.2.3 In the case of combination packagings only the code number for the outer packaging is used. 6.1.2.4 The letters "T", "V" or "W" may follow the packaging code. The letter "T" signifies a salvage packaging conforming to the requirements of 6.1.5.1.11. The letter "V" signifies a special packaging conforming to the requirements of 6.1.5.1.7. The letter "W" signifies that the packaging, although of the same type indicated by the code, is manufactured to a specification different to that in 6.1.4 and is considered equivalent under the requirements of 6.1.1.2. 6.1.2.5 The following numerals shall be used for the kinds of packaging: l. 2. 3. 4. 5. 6. 7. 0. 6.1.2.6 Drum (Reserved) Jerrican Box Bag Composite packaging (Reserved) Light gauge metal packagings The following capital letters shall be used for the types of material: A. B. C. D. F. G. H. L. M. N. P. Steel (all types and surface treatments) Aluminium Natural wood Plywood Reconstituted wood Fibreboard Plastics material Textile Paper, multiwall Metal (other than steel or aluminium) Glass, porcelain or stoneware NOTE: Plastics material is taken to include other polymeric materials such as rubber. 6.1.2.7 The following table indicates the codes to be used for designating types of packagings depending on the kind of packagings, the material used for their construction and their category; it also refers to the sub-sections to be consulted for the appropriate requirements: - 268 - Kind Material Category Code 1. A. Steel non-removable head removable head non-removable head removable head 1A1 1A2 1B1 1B2 1D 1G 1H1 1H2 1N1 1N2 Drums B. Aluminium D. Plywood G. Fibre H. Plastics N. Metal, other than steel or aluminium 2. (Reserved) 3. Jerricans A. Steel non-removable head removable head non-removable head removable head non-removable head removable head B. Aluminium H. Plastics 4. Boxes A. Steel B. Aluminium C. Natural wood ordinary with sift-proof walls D. Plywood F. Reconstituted wood G. Fibreboard H. Plastics 5. Bags expanded solid N. Metal, other than steel or aluminium H. Woven plastics H. Plastics film L. Textile M. Paper non-removable head removable head non-removable head removable head without inner liner or coating sift-proof water resistant without inner liner or coating sift-proof water resistant multiwall multiwall, water resistant - 269 - 3A1 3A2 3B1 3B2 3H1 3H2 4A 4B 4C1 4C2 4D 4F 4G 4H1 4H2 4N 5H1 5H2 5H3 5H4 5L1 5L2 5L3 5M1 5M2 Sub-section 6.1.4.1 6.1.4.2 6.1.4.5 6.1.4.7 6.1.4.8 6.1.4.3 6.1.4.4 6.1.4.4 6.1.4.8 6.1.4.14 6.1.4.14 6.1.4.9 6.1.4.10 6.1.4.11 6.1.4.12 6.1.4.13 6.1.4.14 6.1.4.16 6.1.4.17 6.1.4.15 6.1.4.18 Kind Material Category Code 6. Composite packagings H. Plastics receptacle with outer steel drum with outer steel crate or box with outer aluminium drum with outer aluminium crate or box with outer wooden box with outer plywood drum with outer plywood box with outer fibre drum with outer fibreboard box with outer plastics drum with outer solid plastics box with outer steel drum with outer steel crate or box with outer aluminium drum with outer aluminium crate or box with outer wooden box with outer plywood drum with outer wickerwork hamper with outer fibre drum with outer fibreboard box with outer expanded plastics packaging with outer solid plastics packaging 6HA1 6HA2 6HB1 6HB2 P. Glass, porcelain or stoneware receptacle 7. (Reserved) 0. Light gauge metal packagings 6.1.3 A. Steel non-removable head removable head 6HC 6HD1 6HD2 6HG1 6HG2 6HH1 6HH2 6PA1 6PA2 6PB1 6PB2 6PC 6PD1 6PD2 6PG1 6PG2 6PH1 Sub-section 6.1.4.19 6.1.4.20 6PH2 0A1 0A2 6.1.4.22 Marking NOTE 1: The marking indicates that the packaging which bears it corresponds to a successfully tested design type and that it complies with the requirements of this Chapter which are related to the manufacture, but not to the use, of the packaging. In itself, therefore, the mark does not necessarily confirm that the packaging may be used for any substance: generally the type of packaging (e.g. steel drum), its maximum capacity and/or mass, and any special requirements are specified for each substance in Table A of Chapter 3.2. NOTE 2: The marking is intended to be of assistance to packaging manufacturers, reconditioners, packaging users, carriers and regulatory authorities. In relation to the use of a new packaging, the original marking is a means for its manufacturer(s) to identify the type and to indicate those performance test regulations that have been met. - 270 - NOTE 3: The marking does not always provide full details of the test levels, etc., and these may need to be taken further into account, e.g. by reference to a test certificate, to test reports or to a register of successfully tested packagings. For example, a packaging having an X or Y marking may be used for substances to which a packing group having a lesser degree of danger has been assigned with the relevant maximum permissible value of the relative density1 determined by taking into account the factor 1.5 or 2.25 indicated in the packaging test requirements in 6.1.5 as appropriate, i.e. packing group I packaging tested for products of relative density 1.2 could be used as a packing group II packaging for products of relative density 1.8 or a packing group III packaging for products of relative density 2.7, provided of course that all the performance criteria can still be met with the higher relative density product. 6.1.3.1 Each packaging intended for use according to the ADR shall bear markings which are durable, legible and placed in a location and of such a size relative to the packaging as to be readily visible. For packages with a gross mass of more than 30 kg, the markings or a duplicate thereof shall appear on the top or on a side of the packaging. Letters, numerals and symbols shall be at least 12 mm high, except for packagings of 30 litres or 30 kg capacity or less, when they shall be at least 6 mm in height and for packagings of 5 litres or 5 kg or less when they shall be of an appropriate size. The marking shall show: (a) (i) The United Nations packaging symbol ; This symbol shall not be used for any purpose other than certifying that a packaging, a portable tank or a MEGC complies with the relevant requirements in Chapter 6.1, 6.2, 6.3, 6.5, 6.6 or 6.72. This symbol shall not be used for packagings which comply with the simplified conditions of 6.1.1.3, 6.1.5.3.1 (e), 6.1.5.3.5 (c), 6.1.5.4, 6.1.5.5.1 and 6.1.5.6 (see also (ii) below). For embossed metal packagings, the capital letters "UN" may be applied instead of the symbol; or (ii) The symbol "RID/ADR" for composite packagings (glass, porcelain or stoneware) and light gauge metal packagings conforming to simplified conditions (see 6.1.1.3, 6.1.5.3.1 (e), 6.1.5.3.5 (c), 6.1.5.4, 6.1.5.5.1 and 6.1.5.6); NOTE: Packagings bearing this symbol are approved for rail, road and inland waterways transport operations which are subject to the provisions of RID, ADR and ADN respectively. They are not necessarily accepted for carriage by other modes of transport or for transport operations by road, rail or inland waterways which are governed by other regulations. (b) The code designating the type of packaging according to 6.1.2; (c) A code in two parts: (i) a letter designating the packing group(s) for which the design type has been successfully tested: X for packing groups I, II and III; Y for packing groups II and III; Z for packing group III only; (ii) the relative density, rounded off to the first decimal, for which the design type has been tested for packagings without inner packagings intended to contain liquids; this may be omitted when the relative density does not exceed 1.2. For packagings intended to contain solids or inner packagings, the maximum gross mass in kilograms. 1 Relative density (d) is considered to be synonymous with Specific Gravity (SG) and is used throughout this text. This symbol is also used to certify that flexible bulk containers authorized for other modes of transport comply with the requirements in Chapter 6.8 of the UN Model Regulations. 2 - 271 - For light-gauge metal packagings, marked with the symbol "RID/ADR" according to 6.1.3.1 (a) (ii) intended to contain liquids having a viscosity at 23 °C exceeding 200 mm2/s, the maximum gross mass in kg; (d) Either the letter "S" denoting that the packaging is intended for the carriage of solids or inner packagings or, for packagings (other than combination packagings) intended to contain liquids, the hydraulic test pressure which the packaging was shown to withstand in kPa rounded down to the nearest 10 kPa. For light-gauge metal packagings, marked with the symbol "RID/ADR, according to 6.1.3.1(a) (ii) intended to contain liquids having a viscosity at 23 °C exceeding 200 mm2/s, the letter "S"; (e) The last two digits of the year during which the packaging was manufactured. Packagings of types 1H and 3H shall also be appropriately marked with the month of manufacture; this may be marked on the packaging in a different place from the remainder of the marking. An appropriate method is: 11 12 1 10 2 * 9 3 4 8 7 * 6 5 The last two digits of the year of manufacture may be displayed at that place. In such a case, the two digits of the year in the type approval marking and in the inner circle of the clock shall be identical. NOTE: Other methods that provide the minimum required information in a durable, visible and legible form are also acceptable. (f) The State authorizing the allocation of the mark, indicated by the distinguishing sign for motor vehicles in international traffic3; (g) The name of the manufacturer or other identification of the packaging specified by the competent authority. 6.1.3.2 In addition to the durable markings prescribed in 6.1.3.1, every new metal drum of a capacity greater than 100 litres shall bear the marks described in 6.1.3.1 (a) to (e) on the bottom, with an indication of the nominal thickness of at least the metal used in the body (in mm, to 0.1 mm), in permanent form (e.g. embossed). When the nominal thickness of either head of a metal drum is thinner than that of the body, the nominal thickness of the top head, body, and bottom head shall be marked on the bottom in permanent form (e.g. embossed), for example "1.0-1.2-1.0" or "0.9-1.0-1.0". Nominal thickness of metal shall be determined according to the appropriate ISO standard, for example ISO 3574:1999 for steel. The marks indicated in 6.1.3.1 (f) and (g) shall not be applied in a permanent form except as provided in 6.1.3.5. 6.1.3.3 Every packaging other than those referred to in 6.1.3.2 liable to undergo a reconditioning process shall bear the marks indicated in 6.1.3.1 (a) to (e) in a permanent form. Marks are permanent if they are able to withstand the reconditioning process (e.g. embossed). For packagings other than metal drums of a capacity greater than 100 litres, these permanent marks may replace the corresponding durable markings prescribed in 6.1.3.1. 3 Distinguishing sign for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 272 - 6.1.3.4 For remanufactured metal drums, if there is no change to the packaging type and no replacement or removal of integral structural components, the required markings need not be permanent. Every other remanufactured metal drum shall bear the markings in 6.1.3.1 (a) to (e) in a permanent form (e.g. embossed) on the top head or side. 6.1.3.5 Metal drums made from materials (e.g. stainless steel) designed to be reused repeatedly may bear the markings indicated in 6.1.3.1 (f) and (g) in a permanent form (e.g. embossed). 6.1.3.6 The marking in accordance with 6.1.3.1 is valid for only one design type or series of design types. Different surface treatments may fall within the same design type. A "series of design types" means packagings of the same structural design, wall thickness, material and cross-section, which differ only in their lesser design heights from the design type approved. The closures of receptacles shall be identifiable as those referred to in the test report. 6.1.3.7 Marking shall be applied in the sequence of the sub-paragraphs in 6.1.3.1; each element of the marking required in these sub-paragraphs and when appropriate sub-paragraphs (h) to (j) of 6.1.3.8 shall be clearly separated, e.g. by a slash or space, so as to be easily identifiable. For examples, see 6.1.3.11. Any additional markings authorized by a competent authority shall still enable the parts of the mark to be correctly identified with reference to 6.1.3.1. 6.1.3.8 After reconditioning a packaging, the reconditioner shall apply to it a durable marking showing, in the following sequence: (h) The State in which the reconditioning was carried out, indicated by the distinguishing sign for motor vehicles in international traffic3; (i) The name of the reconditioner or other identification of the packaging specified by the competent authority; (j) The year of reconditioning; the letter "R"; and, for every packaging successfully passing the leakproofness test in 6.1.1.3, the additional letter "L". 6.1.3.9 When, after reconditioning, the markings required by 6.1.3.1 (a) to (d) no longer appear on the top head or the side of a metal drum, the reconditioner also shall apply them in a durable form followed by 6.1.3.8 (h), (i) and (j). These markings shall not identify a greater performance capability than that for which the original design type had been tested and marked. 6.1.3.10 Packagings manufactured with recycled plastics material as defined in 1.2.1 shall be marked "REC". This mark shall be placed near the mark prescribed in 6.1.3.1. 3 Distinguishing sign for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 273 - 6.1.3.11 Examples of markings for NEW packagings 4G/Y145/S/02 NL/VL823 as in 6.1.3.1 (a) (i), (b), (c), (d) and (e) as in 6.1.3.1 (f) and (g) For a new fibreboard box 1A1/Y1.4/150/98 NL/VL824 as in 6.1.3.1 (a) (i), (b), (c), (d) and (e) as in 6.1.3.1 (f) and (g) For a new steel drum to contain liquids 1A2/Y150/S/01 NL/VL825 as in 6.1.3.1 (a) (i), (b), (c), (d) and (e) as in 6.1.3.1 (f) and (g) For a new steel drum to contain solids, or inner packagings 4HW/Y136/S/98 NL/VL826 as in 6.1.3.1 (a) (i), (b), (c), (d) and (e) as in 6.1.3.1 (f) and (g) For a new plastics box of equivalent specification 1A2/Y/100/01 USA/MM5 as in 6.1.3.1 (a) (i), (b), (c), (d) and (e) as in 6.1.3.1 (f) and (g) For a remanufactured steel drum to contain liquids RID/ADR/0A1/Y100/89 NL/VL123 as in 6.1.3.1 (a) (ii), (b), (c), (d) and (e) as in 6.1.3.1 (f) and (g) For a new light gauge metal packaging, non-removable head RID/ADR/0A2/Y20/S/04 NL/VL124 as in 6.1.3.1 (a) (ii), (b), (c), (d) and (e) as in 6.1.3.1 (f) and (g) For a new light gauge metal packaging, removable head, intended to contain solids, or liquids with a viscosity at 23 °C exceeding 200 mm2/s. 6.1.3.12 6.1.3.13 Examples of markings for RECONDITIONED packagings 1A1/Y1.4/150/97 NL/RB/01 RL as in 6.1.3.1 (a) (i), (b), (c), (d) and (e) as in 6.1.3.8 (h), (i) and (j) 1A2/Y150/S/99 USA/RB/00 R as in 6.1.3.1 (a) (i), (b), (c), (d) and (e) as in 6.1.3.8 (h), (i) and (j) Example of marking for SALVAGE packagings 1A2T/Y300/S/01 USA/abc as in 6.1.3.1 (a) (i), (b), (c), (d) and (e) as in 6.1.3.1 (f) and (g) NOTE: The markings, for which examples are given in 6.1.3.11, 6.1.3.12 and 6.1.3.13 may be applied in a single line or in multiple lines provided the correct sequence is respected. 6.1.3.14 Certification By affixing marking in accordance with 6.1.3.1, it is certified that mass-produced packagings correspond to the approved design type and that the requirements referred to in the approval have been met. 6.1.4 Requirements for packagings 6.1.4.0 General requirements Any permeation of the substance contained in the packaging shall not constitute a danger under normal conditions of carriage. - 274 - 6.1.4.1 Steel drums 1A1 1A2 6.1.4.1.1 non-removable head removable head Body and heads shall be constructed of steel sheet of a suitable type and of adequate thickness in relation to the capacity of the drum and to its intended use. NOTE: In the case of carbon steel drums, "suitable" steels are identified in ISO 3573:1999 "Hot rolled carbon steel sheet of commercial and drawing qualities" and ISO 3574:1999 "Cold-reduced carbon steel sheet of commercial and drawing qualities". For carbon steel drums below 100 litres "suitable" steels in addition to the above standards are also identified in ISO 11949:1995 "Cold-reduced electrolytic tinplate", ISO 11950:1995 "Cold-reduced electrolytic chromium/chromium oxide-coated steel" and ISO 11951:1995 "Cold-reduced blackplate in coil form for the production of tinplate or electrolytic chromium/chromium-oxide coated steel". 6.1.4.1.2 Body seams shall be welded on drums intended to contain more than 40 litres of liquid. Body seams shall be mechanically seamed or welded on drums intended to contain solids or 40 litres or less of liquids. 6.1.4.1.3 Chimes shall be mechanically seamed or welded. Separate reinforcing rings may be applied. 6.1.4.1.4 The body of a drum of a capacity greater than 60 litres shall, in general, have at least two expanded rolling hoops or, alternatively, at least two separate rolling hoops. If there are separate rolling hoops they shall be fitted tightly on the body and so secured that they cannot shift. Rolling hoops shall not be spot welded. 6.1.4.1.5 Openings for filling, emptying and venting in the bodies or heads of non-removable head (1A1) drums shall not exceed 7 cm in diameter. Drums with larger openings are considered to be of the removable head type (1A2). Closures for openings in the bodies and heads of drums shall be so designed and applied that they will remain secure and leakproof under normal conditions of carriage. Closure flanges may be mechanically seamed or welded in place. Gaskets or other sealing elements shall be used with closures, unless the closure is inherently leakproof. 6.1.4.1.6 Closure devices for removable head (1A2) drums shall be so designed and applied that they will remain secure and drums will remain leakproof under normal conditions of carriage. Gaskets or other sealing elements shall be used with all removable heads. 6.1.4.1.7 If materials used for body, heads, closures and fittings are not in themselves compatible with the contents to be carried, suitable internal protective coatings or treatments shall be applied. These coatings or treatments shall retain their protective properties under normal conditions of carriage. 6.1.4.1.8 Maximum capacity of drum: 450 litres. 6.1.4.1.9 Maximum net mass: 400 kg. 6.1.4.2 Aluminium drums 1B1 1B2 non-removable head removable head 6.1.4.2.1 Body and heads shall be constructed of aluminium at least 99% pure or of an aluminium base alloy. Material shall be of a suitable type and of adequate thickness in relation to the capacity of the drum and to its intended use. 6.1.4.2.2 All seams shall be welded. Chime seams, if any, shall be reinforced by the application of separate reinforcing rings. 6.1.4.2.3 The body of a drum of a capacity greater than 60 litres shall, in general, have at least two expanded rolling hoops or, alternatively, at least two separate rolling hoops. If there are separate rolling hoops they shall be fitted tightly on the body and so secured that they cannot shift. Rolling hoops shall not be spot welded. - 275 - 6.1.4.2.4 Openings for filling, emptying and venting in the bodies or heads of non-removable head (1B1) drums shall not exceed 7 cm in diameter. Drums with larger openings are considered to be of the removable head type (1B2). Closures for openings in the bodies and heads of drums shall be so designed and applied that they will remain secure and leakproof under normal conditions of carriage. Closure flanges shall be welded in place so that the weld provides a leakproof seam. Gaskets or other sealing elements shall be used with closures, unless the closure is inherently leakproof. 6.1.4.2.5 Closure devices for removable head (1B2) drums shall be so designed and applied that they will remain secure and drums will remain leakproof under normal conditions of carriage. Gaskets or other sealing elements shall be used with all removable heads. 6.1.4.2.6 Maximum capacity of drum: 450 litres. 6.1.4.2.7 Maximum net mass: 400 kg. 6.1.4.3 Drums of metal other than aluminium or steel 1N1 1N2 non-removable head removable head 6.1.4.3.1 The body and heads shall be constructed of a metal or of a metal alloy other than steel or aluminium. Material shall be of a suitable type and of adequate thickness in relation to the capacity of the drum and to its intended use. 6.1.4.3.2 Chime seams, if any, shall be reinforced by the application of separate reinforcing rings. All seams, if any, shall be joined (welded, solded, etc.) in accordance with the technical state of the art for the used metal or metal alloy. 6.1.4.3.3 The body of a drum of a capacity greater than 60 litres shall, in general, have at least two expanded rolling hoops or, alternatively, at least two separate rolling hoops. If there are separate rolling hoops they shall be fitted tightly on the body and so secured that they cannot shift. Rolling hoops shall not be spot welded. 6.1.4.3.4 Openings for filling, emptying and venting in the bodies or heads of non-removable head (1N1) drums shall not exceed 7 cm in diameter. Drums with larger openings are considered to be of the removable head type (1N2). Closures for openings in the bodies and heads of drums shall be so designed and applied that they will remain secure and leakproof under normal conditions of carriage. Closure flanges shall be joined in place (welded, solded, etc.) in accordance with the technical state of the art for the used metal or metal alloy so that the seam join is leakproof. Gaskets or other sealing elements shall be used with closures, unless the closure is inherently leakproof. 6.1.4.3.5 Closure devices for removable head (1N2) drums shall be so designed and applied that they will remain secure and drums will remain leakproof under normal conditions of carriage. Gaskets or other sealing elements shall be used with all removable heads. 6.1.4.3.6 Maximum capacity of drum: 450 litres. 6.1.4.3.7 Maximum net mass: 400 kg. 6.1.4.4 Steel or aluminium jerricans 3A1 3A2 3B1 3B2 steel, non-removable head steel, removable head aluminium, non-removable head aluminium, removable head 6.1.4.4.1 Body and heads shall be constructed of steel sheet, of aluminium at least 99% pure or of an aluminium base alloy. Material shall be of a suitable type and of adequate thickness in relation to the capacity of the jerrican and to its intended use. 6.1.4.4.2 Chimes of steel jerricans shall be mechanically seamed or welded. Body seams of steel jerricans intended to contain more than 40 litres of liquid shall be welded. Body seams of steel jerricans intended to contain 40 litres or less shall be mechanically seamed or welded. For aluminium jerricans, - 276 - all seams shall be welded. Chime seams, if any, shall be reinforced by the application of a separate reinforcing ring. 6.1.4.4.3 Openings in non-removable head jerricans (3A1 and 3B1) shall not exceed 7 cm in diameter. Jerricans with larger openings are considered to be of the removable head type (3A2 and 3B2). Closures shall be so designed that they will remain secure and leakproof under normal conditions of carriage. Gaskets or other sealing elements shall be used with closures, unless the closure is inherently leakproof. 6.1.4.4.4 If materials used for body, heads, closures and fittings are not in themselves compatible with the contents to be carried, suitable internal protective coatings or treatments shall be applied. These coatings or treatments shall retain their protective properties under normal conditions of carriage. 6.1.4.4.5 Maximum capacity of jerrican: 60 litres. 6.1.4.4.6 Maximum net mass: 120 kg. 6.1.4.5 Plywood drums 1D 6.1.4.5.1 The wood used shall be well seasoned, commercially dry and free from any defect likely to lessen the effectiveness of the drum for the purpose intended. If a material other than plywood is used for the manufacture of the heads, it shall be of a quality equivalent to the plywood. 6.1.4.5.2 At least two-ply plywood shall be used for the body and at least three-ply plywood for the heads; the plies shall be firmly glued together by a water resistant adhesive with their grain crosswise. 6.1.4.5.3 The body and heads of the drum and their joins shall be of a design appropriate to the capacity of the drum and to its intended use. 6.1.4.5.4 In order to prevent sifting of the contents, lids shall be lined with kraft paper or some other equivalent material which shall be securely fastened to the lid and extend to the outside along its full circumference. 6.1.4.5.5 6.1.4.5.6 Maximum capacity of drum: 250 litres. Maximum net mass: 400 kg. 6.1.4.6 (Deleted) 6.1.4.7 Fibre drums 1G 6.1.4.7.1 The body of the drum shall consist of multiple plies of heavy paper or fibreboard (without corrugations) firmly glued or laminated together and may include one or more protective layers of bitumen, waxed kraft paper, metal foil, plastics material, etc. 6.1.4.7.2 Heads shall be of natural wood, fibreboard, metal, plywood, plastics or other suitable material and may include one or more protective layers of bitumen, waxed kraft paper, metal foil, plastics material, etc. 6.1.4.7.3 The body and heads of the drum and their joins shall be of a design appropriate to the capacity of the drum and to its intended use. 6.1.4.7.4 The assembled packaging shall be sufficiently water resistant so as not to delaminate under normal conditions of carriage. 6.1.4.7.5 Maximum capacity of drum: 450 litres. 6.1.4.7.6 Maximum net mass: 400 kg. - 277 - 6.1.4.8 Plastics drums and jerricans 1H1 1H2 3H1 3H2 drums, non-removable head drums, removable head jerricans, non-removable head jerricans, removable head 6.1.4.8.1 The packaging shall be manufactured from suitable plastics material and be of adequate strength in relation to its capacity and intended use. Except for recycled plastics material as defined in 1.2.1, no used material other than production residues or regrind from the same manufacturing process may be used. The packaging shall be adequately resistant to ageing and to degradation caused either by the substance contained or by ultra-violet radiation. Any permeation of the substance contained in the package, or recycled plastics material used to produce new packaging, shall not constitute a danger under normal conditions of carriage. 6.1.4.8.2 If protection against ultra-violet radiation is required, it shall be provided by the addition of carbon black or other suitable pigments or inhibitors. These additives shall be compatible with the contents and remain effective throughout the life of the packaging. Where use is made of carbon black, pigments or inhibitors other than those used in the manufacture of the tested design type, retesting may be waived if the carbon black content does not exceed 2% by mass or if the pigment content does not exceed 3% by mass; the content of inhibitors of ultra-violet radiation is not limited. 6.1.4.8.3 Additives serving purposes other than protection against ultra-violet radiation may be included in the composition of the plastics material provided that they do not adversely affect the chemical and physical properties of the material of the packaging. In such circumstances, retesting may be waived. 6.1.4.8.4 The wall thickness at every point of the packaging shall be appropriate to its capacity and intended use, taking into account the stresses to which each point is liable to be exposed. 6.1.4.8.5 Openings for filling, emptying and venting in the bodies or heads of non-removable head drums (1H1) and jerricans (3H1) shall not exceed 7 cm in diameter. Drums and jerricans with larger openings are considered to be of the removable head type (1H2 and 3H2). Closures for openings in the bodies or heads of drums and jerricans shall be so designed and applied that they will remain secure and leakproof under normal conditions of carriage. Gaskets or other sealing elements shall be used with closures unless the closure is inherently leakproof. 6.1.4.8.6 Closure devices for removable head drums and jerricans (1H2 and 3H2) shall be so designed and applied that they will remain secure and leakproof under normal conditions of carriage. Gaskets shall be used with all removable heads unless the drum or jerrican design is such that, where the removable head is properly secured, the drum or jerrican is inherently leakproof. 6.1.4.8.7 The maximum permissible permeability for flammable liquids shall be 0.008 g/l.h at 23 °C (see 6.1.5.7). 6.1.4.8.8 Where recycled plastics material is used for production of new packaging, the specific properties of the recycled material shall be assured and documented regularly as part of a quality assurance programme recognised by the competent authority. The quality assurance programme shall include a record of proper pre-sorting and verification that each batch of recycled plastics material has the proper melt flow rate, density, and tensile yield strength, consistent with that of the design type manufactured from such recycled material. This necessarily includes knowledge about the packaging material from which the recycled plastics have been derived, as well as the awareness of the prior contents of those packagings if those prior contents might reduce the capability of new packaging produced using that material. In addition, the packaging manufacturer's quality assurance programme under 6.1.1.4 shall include performance of the mechanical design type test in 6.1.5 on packagings manufactured from each batch of recycled plastics material. In this testing, stacking performance may be verified by appropriate dynamic compression testing rather than static load testing. NOTE: ISO 16103:2005 – "Packaging – Transport packaging for dangerous goods - Recycled plastics material" provides additional guidance on procedures to be followed in approving the use of recycled plastics material. - 278 - 6.1.4.8.9 Maximum capacity of drums and jerricans: 6.1.4.8.10 Maximum net mass: 6.1.4.9 Boxes of natural wood 4C1 4C2 1H1, 1H2: 450 litres 3H1, 3H2: 60 litres. 1H1, 1H2: 400 kg 3H1, 3H2: 120 kg. ordinary with sift-proof walls 6.1.4.9.1 The wood used shall be well seasoned, commercially dry and free from defects that would materially lessen the strength of any part of the box. The strength of the material used and the method of construction shall be appropriate to the capacity and intended use of the box. The tops and bottoms may be made of water resistant reconstituted wood such as hardboard, particle board or other suitable type. 6.1.4.9.2 Fastenings shall be resistant to vibration experienced under normal conditions of carriage. End grain nailing shall be avoided whenever practicable. Joins which are likely to be highly stressed shall be made using clenched or annular ring nails or equivalent fastenings. 6.1.4.9.3 Box 4C2: each part shall consist of one piece or be equivalent thereto. Parts are considered equivalent to one piece when one of the following methods of glued assembly is used: Lindermann joint, tongue and groove joint, ship lap or rabbet joint or butt joint with at least two corrugated metal fasteners at each joint. 6.1.4.9.4 Maximum net mass: 400 kg. 6.1.4.10 Plywood boxes 4D 6.1.4.10.1 Plywood used shall be at least 3-ply. It shall be made from well seasoned rotary cut, sliced or sawn veneer, commercially dry and free from defects that would materially lessen the strength of the box. The strength of the material used and the method of construction shall be appropriate to the capacity and intended use of the box. All adjacent plies shall be glued with water resistant adhesive. Other suitable materials may be used together with plywood in the construction of boxes. Boxes shall be firmly nailed or secured to corner posts or ends or be assembled by equally suitable devices. 6.1.4.10.2 Maximum net mass: 400 kg. 6.1.4.11 Reconstituted wood boxes 4F 6.1.4.11.1 The walls of boxes shall be made of water resistant reconstituted wood such as hardboard, particle board or other suitable type. The strength of the material used and the method of construction shall be appropriate to the capacity of the boxes and to their intended use. 6.1.4.11.2 Other parts of the boxes may be made of other suitable material. 6.1.4.11.3 Boxes shall be securely assembled by means of suitable devices. 6.1.4.11.4 Maximum net mass: 400 kg. 6.1.4.12 Fibreboard boxes 4G - 279 - 6.1.4.12.1 Strong and good quality solid or double-faced corrugated fibreboard (single or multiwall) shall be used, appropriate to the capacity of the box and to its intended use. The water resistance of the outer surface shall be such that the increase in mass, as determined in a test carried out over a period of 30 minutes by the Cobb method of determining water absorption, is not greater than 155 g/m2 - see ISO 535:l991. It shall have proper bending qualities. Fibreboard shall be cut, creased without scoring, and slotted so as to permit assembly without cracking, surface breaks or undue bending. The fluting of corrugated fibreboard shall be firmly glued to the facings. 6.1.4.12.2 The ends of boxes may have a wooden frame or be entirely of wood or other suitable material. Reinforcements of wooden battens or other suitable material may be used. 6.1.4.12.3 Manufacturing joins in the body of boxes shall be taped, lapped and glued, or lapped and stitched with metal staples. Lapped joins shall have an appropriate overlap. 6.1.4.12.4 Where closing is effected by gluing or taping, a water resistant adhesive shall be used. 6.1.4.12.5 Boxes shall be designed so as to provide a good fit to the contents. 6.1.4.12.6 Maximum net mass: 400 kg. 6.1.4.13 Plastics boxes 4H1 4H2 expanded plastics boxes solid plastics boxes 6.1.4.13.1 The box shall be manufactured from suitable plastics material and be of adequate strength in relation to its capacity and intended use. The box shall be adequately resistant to ageing and to degradation caused either by the substance contained or by ultra-violet radiation. 6.1.4.13.2 An expanded plastics box shall comprise two parts made of a moulded expanded plastics material, a bottom section containing cavities for the inner packagings and a top section covering and interlocking with the bottom section. The top and bottom sections shall be designed so that the inner packagings fit snugly. The closure cap for any inner packaging shall not be in contact with the inside of the top section of this box. 6.1.4.13.3 For dispatch, an expanded plastics box shall be closed with a self-adhesive tape having sufficient tensile strength to prevent the box from opening. The adhesive tape shall be weather resistant and its adhesive compatible with the expanded plastics material of the box. Other closing devices at least equally effective may be used. 6.1.4.13.4 For solid plastics boxes, protection against ultra-violet radiation, if required, shall be provided by the addition of carbon black or other suitable pigments or inhibitors. These additives shall be compatible with the contents and remain effective throughout the life of the box. Where use is made of carbon black, pigments or inhibitors other than those used in the manufacture of the tested design type, retesting may be waived if the carbon black content does not exceed 2% by mass or if the pigment content does not exceed 3% by mass; the content of inhibitors of ultra-violet radiation is not limited. 6.1.4.13.5 Additives serving purposes other than protection against ultra-violet radiation may be included in the composition of the plastics material provided that they do not adversely affect the chemical or physical properties of the material of the box. In such circumstances, retesting may be waived. 6.1.4.13.6 Solid plastics boxes shall have closure devices made of a suitable material of adequate strength and so designed as to prevent the box from unintentional opening. - 280 - 6.1.4.13.7 Where recycled plastics material is used for production of new packaging, the specific properties of the recycled material shall be assured and documented regularly as part of a quality assurance programme recognised by the competent authority. The quality assurance programme shall include a record of proper pre-sorting and verification that each batch of recycled plastics material has the proper melt flow rate, density, and tensile yield strength, consistent with that of the design type manufactured from such recycled material. This necessarily includes knowledge about the packaging material from which the recycled plastics have been derived, as well as the awareness of the prior contents of those packagings if those prior contents might reduce the capability of new packaging produced using that material. In addition, the packaging manufacturer's quality assurance programme under 6.1.1.4 shall include performance of the mechanical design type test in 6.1.5 on packagings manufactured from each batch of recycled plastics material. In this testing, stacking performance may be verified by appropriate dynamic compression testing rather than static load testing. 6.1.4.13.8 Maximum net mass 6.1.4.14 Steel, aluminium or other metal boxes 4A 4B 4N 4H1: 60 kg 4H2: 400 kg. steel boxes aluminium boxes metal, other than steel or aluminium, boxes 6.1.4.14.l The strength of the metal and the construction of the box shall be appropriate to the capacity of the box and to its intended use. 6.1.4.14.2 Boxes shall be lined with fibreboard or felt packing pieces or shall have an inner liner or coating of suitable material, as required. If a double seamed metal liner is used, steps shall be taken to prevent the ingress of substances, particularly explosives, into the recesses of the seams. 6.1.4.14.3 Closures may be of any suitable type; they shall remain secured under normal conditions of carriage. 6.1.4.14.4 Maximum net mass: 400 kg. 6.1.4.15 Textile bags 5L1 5L2 5L3 without inner liner or coating sift-proof water resistant 6.1.4.15.1 The textiles used shall be of good quality. The strength of the fabric and the construction of the bag shall be appropriate to the capacity of the bag and to its intended use. 6.1.4.15.2 Bags, sift-proof, 5L2: the bag shall be made sift-proof, for example by the use of: 6.1.4.15.3 6.1.4.15.4 (a) paper bonded to the inner surface of the bag by a water resistant adhesive such as bitumen; or (b) plastics film bonded to the inner surface of the bag; or (c) one or more inner liners made of paper or plastics material. Bags, water resistant, 5L3: to prevent the entry of moisture the bag shall be made waterproof, for example by the use of: (a) separate inner liners of water resistant paper (e.g. waxed kraft paper, tarred paper or plastics-coated kraft paper); or (b) plastics film bonded to the inner surface of the bag; or (c) one or more inner liners made of plastics material. Maximum net mass: 50 kg. - 281 - 6.1.4.16 Woven plastics bags 5H1 5H2 5H3 without inner liner or coating sift-proof water resistant 6.1.4.16.1 Bags shall be made from stretched tapes or monofilaments of a suitable plastics material. The strength of the material used and the construction of the bag shall be appropriate to the capacity of the bag and to its intended use. 6.1.4.16.2 If the fabric is woven flat, the bags shall be made by sewing or some other method ensuring closure of the bottom and one side. If the fabric is tubular, the bag shall be closed by sewing, weaving or some other equally strong method of closure. 6.1.4.16.3 Bags, sift-proof, 5H2: the bag shall be made sift-proof, for example by means of: 6.1.4.16.4 (a) paper or a plastics film bonded to the inner surface of the bag; or (b) one or more separate inner liners made of paper or plastics material. Bags, water resistant, 5H3: to prevent the entry of moisture, the bag shall be made waterproof, for example by means of: (a) separate inner liners of water resistant paper (e.g. waxed kraft paper, double-tarred kraft paper or plastics-coated kraft paper); or (b) plastics film bonded to the inner or outer surface of the bag; or (c) one or more inner plastics liners. 6.1.4.16.5 Maximum net mass: 50 kg. 6.1.4.17 Plastics film bags 5H4 6.1.4.17.1 Bags shall be made of a suitable plastics material. The strength of the material used and the construction of the bag shall be appropriate to the capacity of the bag and to its intended use. Joins and closures shall withstand pressures and impacts liable to occur under normal conditions of carriage. 6.1.4.17.2 Maximum net mass: 50 kg. 6.1.4.18 Paper bags 5M1 multiwall 5M2 multiwall, water resistant 6.1.4.18.1 Bags shall be made of a suitable kraft paper or of an equivalent paper with at least three plies, the middle ply of which may be net-cloth and adhesive bonding to the outer paper plies. The strength of the paper and the construction of the bags shall be appropriate to the capacity of the bag and to its intended use. Joins and closures shall be sift-proof. 6.1.4.18.2 Bags 5M2: to prevent the entry of moisture, a bag of four plies or more shall be made waterproof by the use of either a water resistant ply as one of the two outermost plies or a water resistant barrier made of a suitable protective material between the two outermost plies; a bag of three plies shall be made waterproof by the use of a water resistant ply as the outermost ply. Where there is a danger of the substance contained reacting with moisture or where it is packed damp, a waterproof ply or barrier, such as double-tarred kraft paper, plastics-coated kraft paper, plastics film bonded to the inner surface of the bag, or one or more inner plastics liners, shall also be placed next to the substance. Joins and closures shall be waterproof. 6.1.4.18.3 Maximum net mass: 50 kg. - 282 - 6.1.4.19 Composite packagings (plastics material) 6HA1 6HA2 6HB1 6HB2 6HC 6HD1 6HD2 6HG1 6HG2 6HH1 6HH2 plastics receptacle with outer steel drum plastics receptacle with outer steel crate or box plastics receptacle with outer aluminium drum plastics receptacle with outer aluminium crate or box plastics receptacle with outer wooden box plastics receptacle with outer plywood drum plastics receptacle with outer plywood box plastics receptacle with outer fibre drum plastics receptacle with outer fibreboard box plastics receptacle with outer plastics drum plastics receptacle with outer solid plastics box 6.1.4.19.1 Inner receptacle 6.1.4.19.1.1 The requirements of 6.1.4.8.1 and 6.1.4.8.4 to 6.1.4.8.7 apply to plastics inner receptacles. 6.1.4.19.1.2 The plastics inner receptacle shall fit snugly inside the outer packaging, which shall be free of any projection that might abrade the plastics material. 6.1.4.19.1.3 Maximum capacity of inner receptacle: 6HA1, 6HB1, 6HD1, 6HG1, 6HH1: 6HA2, 6HB2, 6HC, 6HD2, 6HG2, 6HH2: 6.1.4.19.1.4 250 litres 60 litres. Maximum net mass: 6HA1, 6HB1, 6HD1, 6HG1, 6HH1: 6HA2, 6HB2, 6HC, 6HD2, 6HG2, 6HH2: 400 kg 75 kg. 6.1.4.19.2 Outer packaging 6.1.4.19.2.1 Plastics receptacle with outer steel or aluminium drum 6HA1 or 6HB1; the relevant requirements of 6.1.4.1 or 6.1.4.2, as appropriate, apply to the construction of the outer packaging. 6.1.4.19.2.2 Plastics receptacle with outer steel or aluminium crate or box 6HA2 or 6HB2; the relevant requirements of 6.1.4.14 apply to the construction of the outer packaging. 6.1.4.19.2.3 Plastics receptacle with outer wooden box 6HC; the relevant requirements of 6.1.4.9 apply to the construction of the outer packaging. 6.1.4.19.2.4 Plastics receptacle with outer plywood drum 6HD1; the relevant requirements of 6.1.4.5 apply to the construction of the outer packaging. 6.1.4.19.2.5 Plastics receptacle with outer plywood box 6HD2; the relevant requirements of 6.1.4.10 apply to the construction of the outer packaging. 6.1.4.19.2.6 Plastics receptacle with outer fibre drum 6HG1; the requirements of 6.1.4.7.1 to 6.1.4.7.4 apply to the construction of the outer packaging. 6.1.4.19.2.7 Plastics receptacle with outer fibreboard box 6HG2; the relevant requirements of 6.1.4.12 apply to the construction of the outer packaging. 6.1.4.19.2.8 Plastics receptacle with outer plastics drum 6HH1; the requirements of 6.1.4.8.1 to 6.1.4.8.6 apply to the construction of the outer packaging. 6.1.4.19.2.9 Plastics receptacles with outer solid plastics box (including corrugated plastics material) 6HH2; the requirements of 6.1.4.13.1 and 6.1.4.13.4 to 6.1.4.13.6 apply to the construction of the outer packaging. - 283 - 6.1.4.20 Composite packagings (glass, porcelain or stoneware) 6PA1 6PA2 6PB1 6PB2 6PC 6PD1 6PD2 6PG1 6PG2 6PH1 6PH2 receptacle with outer steel drum receptacle with outer steel crate or box receptacle with outer aluminium drum receptacle with outer aluminium crate or box receptacle with outer wooden box receptacle with outer plywood drum receptacle with outer wickerwork hamper receptacle with outer fibre drum receptacle with outer fibreboard box receptacle with outer expanded plastics packaging receptacle with outer solid plastics packaging 6.1.4.20.1 Inner receptacle 6.1.4.20.1.1 Receptacles shall be of a suitable form (cylindrical or pear-shaped) and be made of good quality material free from any defect that could impair their strength. The walls shall be sufficiently thick at every point and free from internal stresses. 6.1.4.20.1.2 Screw-threaded plastics closures, ground glass stoppers or closures at least equally effective shall be used as closures for receptacles. Any part of the closure likely to come into contact with the contents of the receptacle shall be resistant to those contents. Care shall be taken to ensure that the closures are so fitted as to be leakproof and are suitably secured to prevent any loosening during carriage. If vented closures are necessary, they shall comply with 4.1.1.8. 6.1.4.20.1.3 The receptacle shall be firmly secured in the outer packaging by means of cushioning and/or absorbent materials. 6.1.4.20.1.4 Maximum capacity of receptacle: 60 litres. 6.1.4.20.1.5 Maximum net mass: 75 kg. 6.1.4.20.2 Outer packaging 6.1.4.20.2.1 Receptacle with outer steel drum 6PA1; the relevant requirements of 6.1.4.1 apply to the construction of the outer packaging. The removable lid required for this type of packaging may nevertheless be in the form of a cap. 6.1.4.20.2.2 Receptacle with outer steel crate or box 6PA2; the relevant requirements of 6.1.4.14 apply to the construction of the outer packaging. For cylindrical receptacles the outer packaging shall, when upright, rise above the receptacle and its closure. If the crate surrounds a pear-shaped receptacle and is of matching shape, the outer packaging shall be fitted with a protective cover (cap). 6.1.4.20.2.3 Receptacle with outer aluminium drum 6PB1; the relevant requirements of 6.1.4.2 apply to the construction of the outer packaging. 6.1.4.20.2.4 Receptacle with outer aluminium crate or box 6PB2; the relevant requirements of 6.1.4.14 apply to the construction of the outer packaging. 6.1.4.20.2.5 Receptacle with outer wooden box 6PC; the relevant requirements of 6.1.4.9 apply to the construction of the outer packaging. 6.1.4.20.2.6 Receptacle with outer plywood drum 6PD1; the relevant requirements of 6.1.4.5 apply to the construction of the outer packaging. 6.1.4.20.2.7 Receptacle with outer wickerwork hamper 6PD2. The wickerwork hamper shall be properly made with material of good quality. It shall be fitted with a protective cover (cap) so as to prevent damage to the receptacle. 6.1.4.20.2.8 Receptacle with outer fibre drum 6PG1; the relevant requirements of 6.1.4.7.1 to 6.1.4.7.4 apply to the construction of the outer packaging. - 284 - 6.1.4.20.2.9 Receptacle with outer fibreboard box 6PG2; the relevant requirements of 6.1.4.12 apply to the construction of the outer packaging. 6.1.4.20.2.10 Receptacle with outer expanded plastics or solid plastics packaging (6PH1 or 6PH2); the materials of both outer packagings shall meet the relevant requirements of 6.1.4.13. Outer solid plastics packaging shall be manufactured from high density polyethylene or some other comparable plastics material. The removable lid for this type of packaging may nevertheless be in the form of a cap. 6.1.4.21 Combination packagings The relevant requirements of section 6.1.4 for the outer packagings to be used, are applicable. NOTE: For the inner and outer packagings to be used, see the relevant packing instructions in Chapter 4.1. 6.1.4.22 Light gauge metal packagings 0A1 0A2 non-removable-head removable-head 6.1.4.22.1 The sheet metal for the body and ends shall be of suitable steel, and of a gauge appropriate to the capacity and intended use of the packaging. 6.1.4.22.2 The joints shall be welded, at least double-seamed by welting or produced by a method ensuring a similar degree of strength and leakproofness. 6.1.4.22.3 Inner coatings of zinc, tin, lacquer, etc. shall be tough and shall adhere to the steel at every point, including the closures. 6.1.4.22.4 Openings for filling, emptying and venting in the bodies or heads of non-removable head (0A1) packagings shall not exceed 7 cm in diameter. Packagings with larger openings shall be considered to be of the removable-head type (0A2). 6.1.4.22.5 The closures of non-removable-head packagings (0A1) shall either be of the screw-threaded type or be capable of being secured by a screwable device or a device at least equally effective. The closures of removable-head packagings (0A2) shall be so designed and fitted that they stay firmly closed and the packagings remain leakproof in normal conditions of carriage. 6.1.4.22.6 Maximum capacity of packagings: 40 litres. 6.1.4.22.7 Maximum net mass: 50 kg. 6.1.5 Test requirements for packagings 6.1.5.1 Performance and frequency of tests 6.1.5.1.1 The design type of each packaging shall be tested as provided in 6.1.5 in accordance with procedures established by the competent authority allowing the allocation of the mark and shall be approved by this competent authority. 6.1.5.1.2 Each packaging design type shall successfully pass the tests prescribed in this Chapter before being used. A packaging design type is defined by the design, size, material and thickness, manner of construction and packing, but may include various surface treatments. It also includes packagings which differ from the design type only in their lesser design height. 6.1.5.1.3 Tests shall be repeated on production samples at intervals established by the competent authority. For such tests on paper or fibreboard packagings, preparation at ambient conditions is considered equivalent to the requirements of 6.1.5.2.3. 6.1.5.1.4 Tests shall also be repeated after each modification which alters the design, material or manner of construction of a packaging. - 285 - 6.1.5.1.5 The competent authority may permit the selective testing of packagings that differ only in minor respects from a tested type, e.g. smaller sizes of inner packagings or inner packagings of lower net mass; and packagings such as drums, bags and boxes which are produced with small reductions in external dimension(s). 6.1.5.1.6 (Reserved) NOTE: For the conditions for assembling different inner packagings in an outer packaging and permissible variations in inner packagings, see 4.1.1.5.1. 6.1.5.1.7 Articles or inner packagings of any type for solids or liquids may be assembled and carried without testing in an outer packaging under the following conditions: (a) The outer packaging shall have been successfully tested in accordance with 6.1.5.3 with fragile (e.g. glass) inner packagings containing liquids using the packing group I drop height; (b) The total combined gross mass of inner packagings shall not exceed one half the gross mass of inner packagings used for the drop test in (a) above; (c) The thickness of cushioning material between inner packagings and between inner packagings and the outside of the packaging shall not be reduced below the corresponding thicknesses in the originally tested packaging; and if a single inner packaging was used in the original test, the thicknesses of cushioning between inner packagings shall not be less than the thickness of cushioning between the outside of the packaging and the inner packaging in the original test. If either fewer or smaller inner packagings are used (as compared to the inner packagings used in the drop test), sufficient additional cushioning material shall be used to take up void spaces; (d) The outer packaging shall have passed successfully the stacking test in 6.1.5.6 while empty. The total mass of identical packages shall be based on the combined mass of inner packagings used for the drop test in (a) above; Inner packagings containing liquids shall be completely surrounded with a sufficient quantity of absorbent material to absorb the entire liquid contents of the inner packagings; (e) (f) If the outer packaging is intended to contain inner packagings for liquids and is not leakproof, or is intended to contain inner packagings for solids and is not siftproof, a means of containing any liquid or solid contents in the event of leakage shall be provided in the form of a leakproof liner, plastics bag or other equally efficient means of containment. For packagings containing liquids, the absorbent material required in (e) above shall be placed inside the means of containing the liquid contents; (g) Packagings shall be marked in accordance with 6.1.3 as having been tested to packing group I performance for combination packagings. The marked gross mass in kilograms shall be the sum of the mass of the outer packaging plus one half of the mass of the inner packaging(s) as used for the drop test referred to in (a) above. Such a package mark shall also contain a letter "V" as described in 6.1.2.4. 6.1.5.1.8 The competent authority may at any time require proof, by tests in accordance with this section, that serially-produced packagings meet the requirements of the design type tests. For verification purposes records of such tests shall be maintained. 6.1.5.1.9 If an inner treatment or coating is required for safety reasons, it shall retain its protective properties even after the tests. 6.1.5.1.10 Provided the validity of the test results is not affected and with the approval of the competent authority, several tests may be made on one sample. 6.1.5.1.11 Salvage packagings Salvage packagings (see 1.2.1) shall be tested and marked in accordance with the requirements applicable to packing group II packagings intended for the carriage of solids or inner packagings, except as follows: - 286 - (a) The test substance used in performing the tests shall be water, and the packagings shall be filled to not less than 98% of their maximum capacity. It is permissible to use additives, such as bags of lead shot, to achieve the requisite total package mass so long as they are placed so that the test results are not affected. Alternatively, in performing the drop test, the drop height may be varied in accordance with 6.1.5.3.5 (b); (b) Packagings shall, in addition, have been successfully subjected to the leakproofness test at 30 kPa, with the results of this test reflected in the test report required by 6.1.5.8; and (c) Packagings shall be marked with the letter "T" as described in 6.1.2.4. 6.1.5.2 Preparation of packagings for testing 6.1.5.2.1 Tests shall be carried out on packagings prepared as for carriage including, with respect to combination packagings, the inner packagings used. Inner or single receptacles or packagings other than bags shall be filled to not less than 98% of their maximum capacity for liquids or 95% for solids. Bags shall be filled to the maximum mass at which they may be used. For combination packagings where the inner packaging is designed to carry liquids and solids, separate testing is required for both liquid and solid contents. The substances or articles to be carried in the packagings may be replaced by other substances or articles except where this would invalidate the results of the tests. For solids, when another substance is used it shall have the same physical characteristics (mass, grain size, etc.) as the substance to be carried. It is permissible to use additives, such as bags of lead shot, to achieve the requisite total package mass, so long as they are placed so that the test results are not affected. 6.1.5.2.2 In the drop tests for liquids, when another substance is used, it shall be of similar relative density and viscosity to those of the substance being carried. Water may also be used for the liquid drop test under the conditions in 6.1.5.3.5. 6.1.5.2.3 Paper or fibreboard packagings shall be conditioned for at least 24 hours in an atmosphere having a controlled temperature and relative humidity (r.h.). There are three options, one of which shall be chosen. The preferred atmosphere is 23 ± 2 °C and 50% ± 2% r.h. The two other options are 20 ± 2 °C and 65% ± 2% r.h. or 27 ± 2 °C and 65% ± 2% r.h. NOTE: Average values shall fall within these limits. Short-term fluctuations and measurement limitations may cause individual measurements to vary by up to ± 5% relative humidity without significant impairment of test reproducibility. 6.1.5.2.4 (Reserved) 6.1.5.2.5 To check that their chemical compatibility with the liquids is sufficient, plastics drums and jerricans in accordance with 6.1.4.8 and if necessary composite packagings (plastics material) in accordance with 6.1.4.19 shall be subjected to storage at ambient temperature for six months, during which time the test samples shall be kept filled with the goods they are intended to carry. For the first and last 24 hours of storage, the test samples shall be placed with the closure downwards. However, packagings fitted with a vent shall be so placed on each occasion for five minutes only. After this storage the test samples shall undergo the tests prescribed in 6.1.5.3 to 6.1.5.6. When it is known that the strength properties of the plastics material of the inner receptacles of composite packagings (plastics material) are not significantly altered by the action of the filling substance, it shall not be necessary to check that the chemical compatibility is sufficient. A significant alteration in strength properties means: (a) distinct embrittlement; or (b) a considerable decrease in elasticity, unless related to a not less than proportionate increase in the elongation under load. Where the behaviour of the plastics material has been established by other means, the above compatibility test may be dispensed with. Such procedures shall be at least equivalent to the above compatibility test and be recognized by the competent authority. NOTE: For plastics drums and jerricans and composite packagings (plastics material) made of polyethylene, see also 6.1.5.2.6 below. - 287 - 6.1.5.2.6 For polyethylene drums and jerricans in accordance with 6.1.4.8 and if necessary, polyethylene composite packagings in accordance with 6.1.4.19, chemical compatibility with filling liquids assimilated in accordance with 4.1.1.21 may be verified as follows with standard liquids (see 6.1.6). The standard liquids are representative for the processes of deterioration on polyethylene, as there are softening through swelling, cracking under stress, molecular degradation and combinations thereof. The sufficient chemical compatibility of the packagings may be verified by storage of the required test samples for three weeks at 40 °C with the appropriate standard liquid(s); where this standard liquid is water, storage in accordance with this procedure is not required. Storage is not required either for test samples which are used for the stacking test in case of the standard liquids "wetting solution" and "acetic acid". For the first and last 24 hours of storage, the test samples shall be placed with the closure downwards. However, packagings fitted with a vent shall be so placed on each occasion for five minutes only. After this storage, the test samples shall undergo the tests prescribed in 6.1.5.3 to 6.1.5.6. The compatibility test for tert-Butyl hydroperoxide with more than 40% peroxide content and peroxyacetic acids of Class 5.2 shall not be carried out using standard liquids. For these substances, sufficient chemical compatibility of the test samples shall be verified during a storage period of six months at ambient temperature with the substances they are intended to carry. Results of the procedure in accordance with this paragraph from polyethylene packagings can be approved for an equal design type, the internal surface of which is fluorinated. 6.1.5.2.7 For packagings made of polyethylene, as specified in 6.1.5.2.6, which have passed the test in 6.1.5.2.6, filling substances other than those assimilated in accordance with 4.1.1.21 may also be approved. Such approval shall be based on laboratory tests verifying that the effect of such filling substances on the test specimens is less than that of the appropriate standard liquid(s) taking into account the relevant processes of deterioration. The same conditions as those set out in 4.1.1.21.2 shall apply with respect to relative density and vapour pressure. 6.1.5.2.8 Provided that the strength properties of the plastics inner packagings of a combination packaging are not significantly altered by the action of the filling substance, proof of chemical compatibility is not necessary. A significant alteration in strength properties means: (a) distinct embrittlement; (b) a considerable decrease in elasticity, unless related to a not less than proportionate increase in elastic elongation. 6.1.5.3 Drop test 4 6.1.5.3.1 Number of test samples (per design type and manufacturer) and drop orientation For other than flat drops the centre of gravity shall be vertically over the point of impact. Where more than one orientation is possible for a given drop test, the orientation most likely to result in failure of the packaging shall be used. 4 See ISO Standard 2248. - 288 - Packaging (a) Steel drums Aluminium drums Drums of metal other than steel or aluminium Steel jerricans Aluminium jerricans Plywood drums Fibre drums Plastics drums and jerricans Composite packagings which are in the shape of a drum Light gauge metal packagings No. of test samples Six (three for each drop) Drop orientation First drop (using three samples): the packaging shall strike the target diagonally on the chime or, if the packaging has no chime, on a circumferential seam or an edge. Second drop (using the other three samples): the packaging shall strike the target on the weakest part not tested by the first drop, for example a closure or, for some cylindrical drums, the welded longitudinal seam of the drum body (b) Boxes of natural wood Plywood boxes Reconstituted wood boxes Fibreboard boxes Five Plastics boxes (one for each drop) Steel or aluminium boxes Composite packagings which are in the shape of a box First drop: flat on the bottom Second drop: flat on the top Third drop: flat on the long side Fourth drop: flat on the short side Fifth drop: on a corner (c) Bags - single-ply with a side seam Three (three drops per bag) First drop: flat on a wide face Second drop: flat on a narrow face Third drop: on an end of the bag (d) Bags - single-ply without a side seam, or multi-ply Three (two drops per bag) First drop: flat on a wide face Second drop: on an end of the bag (e) Composite packagings (glass, stoneware or porcelain), marked with the symbol "RID/ADR" according to 6.1.3.1 (a) (ii) and which are in the shape of a drum or box Three (one for each drop) Diagonally on the bottom chime, or, if there is no chime, on a circumferential seam or the bottom edge 6.1.5.3.2 Special preparation of test samples for the drop test The temperature of the test sample and its contents shall be reduced to –18 °C or lower for the following packagings: (a) Plastics drums (see 6.1.4.8); (b) Plastics jerricans (see 6.1.4.8); (c) Plastics boxes other than expanded plastics boxes (see 6.1.4.13); (d) Composite packagings (plastics material) (see 6.1.4.19); and (e) Combination packagings with plastics inner packagings, other than plastics bags intended to contain solids or articles. Where test samples are prepared in this way, the conditioning in 6.1.5.2.3 may be waived. Test liquids shall be kept in the liquid state by the addition of anti-freeze if necessary. 6.1.5.3.3 Removable head packagings for liquids shall not be dropped until at least 24 hours after filling and closing to allow for any possible gasket relaxation. - 289 - 6.1.5.3.4 Target The target shall be a non-resilient and horizontal surface and shall be: 6.1.5.3.5 - Integral and massive enough to be immovable; - Flat with a surface kept free from local defects capable of influencing the test results; - Rigid enough to be non-deformable under test conditions and not liable to become damaged by the tests; and - Sufficiently large to ensure that the test package falls entirely upon the surface. Drop height For solids and liquids, if the test is performed with the solid or liquid to be carried or with another substance having essentially the same physical characteristics: Packing Group I 1.8 m Packing Group II 1.2 m Packing Group III 0.8 m For liquids in single packagings and for inner packagings of combination packagings, if the test is performed with water: NOTE: The term water includes water/antifreeze solutions with a minimum specific gravity of 0.95 for testing at - 18 °C. (a) where the substances to be carried have a relative density not exceeding 1.2: Packing Group I 1.8 m (b) Packing Group II 1.2 m where the substances to be carried have a relative density exceeding 1.2, the drop height shall be calculated on the basis of the relative density (d) of the substance to be carried, rounded up to the first decimal, as follows: Packing Group I d × 1.5 (m) (c) Packing Group III 0.8 m Packing Group II d × 1.0 (m) Packing Group III d × 0.67 (m) for light-gauge metal packagings, marked with symbol "RID/ADR" according to 6.1.3.1(a) (ii) intended for the carriage of substances having a viscosity at 23 °C greater than 200 mm2/s (corresponding to a flow time of 30 seconds with an ISO flow cup having a jet orifice of 6 mm diameter in accordance with ISO Standard 2431:1993) (i) if the relative density does not exceed 1.2: Packing group II 0.6 m (ii) Packing group III 0.4 m where the substances to be carried have a relative density (d) exceeding 1.2 the drop height shall be calculated on the basis of the relative density (d) of the substance to be carried, rounded up to the first decimal place, as follows: Packing group II d × 0.5 m - 290 - Packing group III d × 0.33 m 6.1.5.3.6 Criteria for passing the test 6.1.5.3.6.1 Each packaging containing liquid shall be leakproof when equilibrium has been reached between the internal and external pressures, however for inner packagings of combination packagings and except for inner receptacles of composite packagings (glass, porcelain or stoneware), marked with the symbol "RID/ADR" according to 6.1.3.1 (a) (ii) it is not necessary that the pressures be equalized. 6.1.5.3.6.2 Where a packaging for solids undergoes a drop test and its upper face strikes the target, the test sample passes the test if the entire contents are retained by an inner packaging or inner receptacle (e.g. a plastics bag), even if the closure while retaining its containment function, is no longer sift-proof. 6.1.5.3.6.3 The packaging or outer packaging of a composite or combination packaging shall not exhibit any damage liable to affect safety during carriage. Inner receptacles, inner packagings, or articles shall remain completely within the outer packaging and there shall be no leakage of the filling substance from the inner receptacle(s) or inner packaging(s). 6.1.5.3.6.4 Neither the outermost ply of a bag nor an outer packaging may exhibit any damage liable to affect safety during carriage. 6.1.5.3.6.5 A slight discharge from the closure(s) upon impact is not considered to be a failure of the packaging provided that no further leakage occurs. 6.1.5.3.6.6 No rupture is permitted in packagings for goods of Class 1 which would permit the spillage of loose explosive substances or articles from the outer packaging. 6.1.5.4 Leakproofness test The leakproofness test shall be performed on all design types of packagings intended to contain liquids; however, this test is not required for - inner packagings of combination packagings; - inner receptacles of composite packagings (glass, porcelain or stoneware), marked with the symbol "RID/ADR" according to 6.1.3.1 (a) (ii); - light gauge metal packagings, marked with the symbol "RID/ADR" according to 6.1.3.1 (a) (ii) intended for substances with a viscosity at 23 °C exceeding 200 mm2/s. 6.1.5.4.1 Number of test samples: three test samples per design type and manufacturer. 6.1.5.4.2 Special preparation of test samples for the test: either vented closures shall be replaced by similar non-vented closures or the vent shall be sealed. 6.1.5.4.3 Test method and pressure to be applied: the packagings including their closures shall be restrained under water for 5 minutes while an internal air pressure is applied, the method of restraint shall not affect the results of the test. The air pressure (gauge) to be applied shall be: Packing Group I Not less than 30 kPa (0.3 bar) Packing Group II Not less than 20 kPa (0.2 bar) Other methods at least equally effective may be used. 6.1.5.4.4 Criterion for passing the test: there shall be no leakage. - 291 - Packing Group III Not less than 20 kPa (0.2 bar) 6.1.5.5 Internal pressure (hydraulic) test 6.1.5.5.1 Packagings to be tested The internal pressure (hydraulic) test shall be carried out on all design types of metal, plastics and composite packagings intended to contain liquids. This test is not required for: - Inner packagings of combination packagings; - Inner receptacles of composite packagings (glass, porcelain or stoneware), marked with the symbol "RID/ADR" according to 6.1.3.1 (a) (ii); - Light gauge metal packagings, marked with the symbol "RID/ADR" according to 6.1.3.1 (a) (ii) intended for substances with a viscosity at 23 °C exceeding 200 mm2/s. 6.1.5.5.2 Number of test samples: three test samples per design type and manufacturer. 6.1.5.5.3 Special preparation of packagings for testing: either vented closures shall be replaced by similar non-vented closures or the vent shall be sealed. 6.1.5.5.4 Test method and pressure to be applied: metal packagings and composite packagings (glass, porcelain or stoneware), including their closures, shall be subjected to the test pressure for 5 minutes. Plastics packagings and composite packagings (plastics material) including their closures shall be subjected to the test pressure for 30 minutes. This pressure is the one to be included in the marking required by 6.1.3.1 (d). The manner in which the packagings are supported shall not invalidate the test. The test pressure shall be applied continuously and evenly; it shall be kept constant throughout the test period. The hydraulic pressure (gauge) applied, as determined by any one of the following methods, shall be: (a) not less than the total gauge pressure measured in the packaging (i.e. the vapour pressure of the filling liquid and the partial pressure of the air or other inert gases, minus 100 kPa) at 55 °C, multiplied by a safety factor of 1.5; this total gauge pressure shall be determined on the basis of a maximum degree of filling in accordance with 4.1.1.4 and a filling temperature of l5 °C; or (b) not less than 1.75 times the vapour pressure at 50 °C of the liquid to be carried, minus 100 kPa but with a minimum test pressure of 100 kPa; or (c) not less than 1.5 times the vapour pressure at 55 °C of the liquid to be carried, minus 100 kPa but with a minimum test pressure of 100 kPa. 6.1.5.5.5 In addition, packagings intended to contain liquids of packing group I shall be tested to a minimum test pressure of 250 kPa (gauge) for a test period of 5 or 30 minutes depending upon the material of construction of the packaging. 6.1.5.5.6 Criterion for passing the test: no packaging may leak. 6.1.5.6 Stacking test All design types of packagings other than bags, and other than non-stackable composite packagings (glass, porcelain, or stoneware) marked with the symbol "RID/ADR" according to 6.1.3.1 (a) (ii), shall be subjected to a stacking test. 6.1.5.6.1 Number of test samples: three test samples per design type and manufacturer. 6.1.5.6.2 Test method: the test sample shall be subjected to a force applied to the top surface of the test sample equivalent to the total weight of identical packages which might be stacked on it during carriage; where the contents of the test sample are liquids with relative density different from that of the liquid to be carried, the force shall be calculated in relation to the latter. The minimum height of the stack including the test sample shall be 3 metres. The duration of the test shall be 24 hours except that plastics drums, jerricans, and composite packagings 6HH1 and 6HH2 intended for liquids shall be subjected to the stacking test for a period of 28 days at a temperature of not less than 40 °C. For the test in accordance with 6.1.5.2.5, the original filling substance shall be used. For the test in accordance with 6.1.5.2.6, a stacking test shall be carried out with a standard liquid. - 292 - 6.1.5.6.3 Criteria for passing the test: no test sample shall leak. In composite packagings or combination packagings, there shall be no leakage of the filling substance from the inner receptacle or inner packaging. No test sample shall show any deterioration which could adversely affect transport safety or any distortion liable to reduce its strength or cause instability in stacks of packages. Plastics packagings shall be cooled to ambient temperature before the assessment. 6.1.5.7 Supplementary permeability test for plastics drums and jerricans in accordance with 6.1.4.8 and for composite packagings (plastics material) in accordance with 6.1.4.19 intended for the carriage of liquids having a flash-point  60 °C, other than 6HA1 packagings Polyethylene packagings need be subjected to this test only if they are to be approved for the carriage of benzene, toluene, xylene or mixtures and preparations containing those substances. 6.1.5.7.1 Number of test samples: three packagings per design type and manufacturer. 6.1.5.7.2 Special preparation of the test sample for the test: the test samples are to be pre-stored with the original filling substance in accordance with 6.1.5.2.5, or, for polyethylene packagings, with the standard liquid mixture of hydrocarbons (white spirit) in accordance with 6.1.5.2.6. 6.1.5.7.3 Test method: the test samples filled with the substance for which the packaging is to be approved shall be weighed before and after storage for 28 days at 23 °C and 50% relative atmospheric humidity. For polyethylene packagings, the test may be carried out with the standard liquid mixture of hydrocarbons (white spirit) in place of benzene, toluene or xylene. 6.1.5.7.4 Criterion for passing the test: permeability shall not exceed 0.008 g/l.h. 6.1.5.8 Test Report 6.1.5.8.1 A test report containing at least the following particulars shall be drawn up and shall be available to the users of the packaging: 1. Name and address of the test facility; 2. Name and address of applicant (where appropriate); 3. A unique test report identification; 4. Date of the test report; 5. Manufacturer of the packaging; 6. Description of the packaging design type (e.g. dimensions, materials, closures, thickness, etc.), including method of manufacture (e.g. blow moulding) and which may include drawing(s) and/or photograph(s); 7. Maximum capacity; 8. Characteristics of test contents, e.g. viscosity and relative density for liquids and particle size for solids; 9. Test descriptions and results; 10. The test report shall be signed with the name and status of the signatory. 6.1.5.8.2 The test report shall contain statements that the packaging prepared as for carriage was tested in accordance with the appropriate requirements of this section and that the use of other packaging methods or components may render it invalid. A copy of the test report shall be available to the competent authority. - 293 - 6.1.6 Standard liquids for verifying the chemical compatibility testing of polyethylene packagings, including IBCs, in accordance with 6.1.5.2.6 and 6.5.6.3.5, respectively 6.1.6.1 The following standard liquids shall be used for this plastics material. (a) Wetting Solution for substances causing severe cracking in polyethylene under stress, in particular for all solutions and preparations containing wetting agents. An aqueous solution of 1% of alkyl benzene sulphonate, or an aqueous solution of 5% nonylphenol ethoxylate which has been preliminary stored for at least 14 days at a temperature of 40 °C before being used for the first time for the tests, shall be used. The surface tension of this solution shall be 31 to 35 mN/m at 23 °C. The stacking test shall be carried out on the basis of a relative density of not less than 1.20. A compatibility test with acetic acid is not required if adequate chemical compatibility is proved with a wetting solution. For filling substances causing cracking in polyethylene under stress which is resistant to the wetting solution, adequate chemical compatibility may be proved after preliminary storing for three weeks at 40 °C in accordance with 6.1.5.2.6, but with the original filling matter; (b) Acetic acid for substances and preparations causing cracking in polyethylene under stress, in particular for monocarboxylic acids and monovalent alcohols. Acetic acid in 98 to 100% concentration shall be used. Relative density = 1.05. The stacking test shall be carried out on the basis of a relative density not less than 1.1. In the case of filling substances causing polyethylene to swell more than acetic acid and to such an extent that the polyethylene mass is increased by up to 4%, adequate chemical compatibility may be proved after preliminary storing for three weeks at 40 °C, in accordance with 6.1.5.2.6 but with the original filling matter; (c) Normal butyl acetate/normal butyl acetate-saturated wetting solution for substances and preparations causing polyethylene to swell to such an extent that the polyethylene mass is increased by about 4% and at the same time causing cracking under stress, in particular for phyto-sanitary products, liquid paints and esters. Normal butyl acetate in 98 to 100% concentration shall be used for preliminary storage in accordance with 6.1.5.2.6. For the stacking test in accordance with 6.1.5.6, a test liquid consisting of a 1 to 10% aqueous wetting solution mixed with 2% normal butyl acetate conforming to (a) above shall be used. The stacking test shall be carried out on the basis of a relative density not less than 1.0. In the case of filling substances causing polyethylene to swell more than normal butyl acetate and to such an extent that the polyethylene mass is increased by up to 7.5%, adequate chemical compatibility may be proved after preliminary storing for three weeks at 40 °C, in accordance with 6.1.5.2.6 but with the original filling matter; (d) Mixture of hydrocarbons (white spirit) for substances and preparations causing polyethylene to swell, in particular for hydrocarbons, esters and ketones. A mixture of hydrocarbons having a boiling range 160 °C to 220 °C, relative density 0.78-0.80, flash-point > 50 °C and an aromatic content 16% to 21% shall be used. The stacking test shall be carried out on the basis of a relative density not less than 1.0. In the case of filling substances causing polyethylene to swell to such an extent that the polyethylene mass is increased by more than 7.5%, adequate chemical compatibility may be proved after preliminary storing for three weeks at 40 °C, in accordance with 6.1.5.2.6 but with the original filling matter; - 294 - (e) Nitric acid for all substances and preparations having an oxidizing effect on polyethylene and causing molecular degradation identical to or less than 55% nitric acid. Nitric acid in a concentration of not less than 55% shall be used. The stacking test shall be carried out on the basis of a relative density of not less than 1.4. In the case of filling substances more strongly oxidizing than 55% nitric acid or causing degradation of the molecular mass proceed in accordance with 6.1.5.2.5. The period of use shall be determined in such cases by observing the degree of damage (e.g. two years for nitric acid in not less than 55% concentration); (f) Water for substances which do not attack polyethylene in any of the cases referred to under (a) to (e), in particular for inorganic acids and lyes, aqueous saline solutions, polyvalent alcohols and organic substances in aqueous solution. The stacking test shall be carried out on the basis of a relative density of not less than 1.2. A design type test with water is not required if adequate chemical compatibility is proved with wetting solution or nitric acid. - 295 - CHAPTER 6.2 REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF PRESSURE RECEPTACLES, AEROSOL DISPENSERS, SMALL RECEPTACLES CONTAINING GAS (GAS CARTRIDGES) AND FUEL CELL CARTRIDGES CONTAINING LIQUEFIED FLAMMABLE GAS NOTE: Aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas are not subject to the requirements of 6.2.1 to 6.2.5. 6.2.1 General requirements 6.2.1.1 Design and construction 6.2.1.1.1 Pressure receptacles and their closures shall be designed, manufactured, tested and equipped in such a way as to withstand all conditions, including fatigue, to which they will be subjected during normal conditions of carriage and use. 6.2.1.1.2 (Reserved) 6.2.1.1.3 In no case shall the minimum wall thickness be less than that specified in the design and construction technical standards. 6.2.1.1.4 For welded pressure receptacles, only metals of weldable quality shall be used. 6.2.1.1.5 The test pressure of cylinders, tubes, pressure drums and bundles of cylinders shall be in accordance with packing instruction P200 of 4.1.4.1, or, for a chemical under pressure, with packing instruction P206 of 4.1.4.1. The test pressure for closed cryogenic receptacles shall be in accordance with packing instruction P203 of 4.1.4.1. The test pressure of a metal hydride storage system shall be in accordance with packing instruction P205 of 4.1.4.1. The test pressure of a cylinder for an adsorbed gas shall be in accordance with packing instruction P208 of 4.1.4.1. 6.2.1.1.6 Pressure receptacles assembled in bundles shall be structurally supported and held together as a unit. Pressure receptacles shall be secured in a manner that prevents movement in relation to the structural assembly and movement that would result in the concentration of harmful local stresses. Manifold assemblies (e.g. manifold, valves, and pressure gauges) shall be designed and constructed such that they are protected from impact damage and forces normally encountered in carriage. Manifolds shall have at least the same test pressure as the cylinders. For toxic liquefied gases, each pressure receptacle shall have an isolation valve to ensure that each pressure receptacle can be filled separately and that no interchange of pressure receptacle contents can occur during carriage. NOTE: Toxic liquefied gases have the classification codes 2T, 2TF, 2TC, 2TO, 2TFC or 2TOC. 6.2.1.1.7 Contact between dissimilar metals which could result in damage by galvanic action shall be avoided. 6.2.1.1.8 Additional requirements for the construction of closed cryogenic receptacles for refrigerated liquefied gases 6.2.1.1.8.1 The mechanical properties of the metal used shall be established for each pressure receptacle, including the impact strength and the bending coefficient. NOTE: With regard to the impact strength, sub-section 6.8.5.3 gives details of test requirements which may be used. 6.2.1.1.8.2 The pressure receptacles shall be thermally insulated. The thermal insulation shall be protected against impact by means of a jacket. If the space between the pressure receptacle and the jacket is evacuated of air (vacuum-insulation), the jacket shall be designed to withstand without permanent deformation an external pressure of at least 100 kPa (1 bar) calculated in accordance with a recognised technical code or a calculated critical collapsing pressure of not less than 200 kPa (2 bar) gauge pressure. If the jacket is so closed as to be gas-tight (e.g. in the case of vacuum-insulation), a device shall be provided - 297 - to prevent any dangerous pressure from developing in the insulating layer in the event of inadequate gas-tightness of the pressure receptacle or its fittings. The device shall prevent moisture from penetrating into the insulation. 6.2.1.1.8.3 Closed cryogenic receptacles intended for the carriage of refrigerated liquefied gases having a boiling point below –182 °C at atmospheric pressure shall not include materials which may react with oxygen or oxygen enriched atmospheres in a dangerous manner, when located in parts of the thermal insulation where there is a risk of contact with oxygen or with oxygen enriched liquid. 6.2.1.1.8.4 Closed cryogenic receptacles shall be designed and constructed with suitable lifting and securing arrangements. 6.2.1.1.9 Additional requirements for the construction of pressure receptacles for acetylene Pressure receptacles for UN 1001 acetylene, dissolved, and UN 3374 acetylene, solvent free, shall be filled with a porous material, uniformly distributed, of a type that conforms to the requirements and testing specified by the competent authority and which: (a) Is compatible with the pressure receptacle and does not form harmful or dangerous compounds either with the acetylene or with the solvent in the case of UN 1001; and (b) Is capable of preventing the spread of decomposition of the acetylene in the porous material. In the case of UN 1001, the solvent shall be compatible with the pressure receptacle. 6.2.1.2 Materials 6.2.1.2.1 Construction materials of pressure receptacles and their closures which are in direct contact with dangerous goods shall not be affected or weakened by the dangerous goods intended to be carried and shall not cause a dangerous effect e.g. catalysing a reaction or reacting with the dangerous goods. 6.2.1.2.2 Pressure receptacles and their closures shall be made of the materials specified in the design and construction technical standards and the applicable packing instruction for the substances intended for carriage in the pressure receptacle. The materials shall be resistant to brittle fracture and to stress corrosion cracking as indicated in the design and construction technical standards. 6.2.1.3 Service equipment 6.2.1.3.1 Valves, piping and other fittings subjected to pressure, excluding pressure relief devices, shall be designed and constructed so that the burst pressure is at least 1.5 times the test pressure of the pressure receptacle. 6.2.1.3.2 Service equipment shall be configured or designed to prevent damage that could result in the release of the pressure receptacle contents during normal conditions of handling and carriage. Manifold piping leading to shut-off valves shall be sufficiently flexible to protect the valves and the piping from shearing or releasing the pressure receptacle contents. The filling and discharge valves and any protective caps shall be capable of being secured against unintended opening. Valves shall be protected as specified in 4.1.6.8. 6.2.1.3.3 Pressure receptacles which are not capable of being handled manually or rolled, shall be fitted with devices (skids, rings, straps) ensuring that they can be safely handled by mechanical means and so arranged as not to impair the strength of, nor cause undue stresses in, the pressure receptacle. 6.2.1.3.4 Individual pressure receptacles shall be equipped with pressure relief devices as specified in packing provision P200 (2) or P205 of 4.1.4.1 or in 6.2.1.3.6.4 and 6.2.1.3.6.5. Pressure-relief devices shall be designed to prevent the entry of foreign matter, the leakage of gas and the development of any dangerous excess pressure. When fitted, pressure relief devices on manifolded horizontal pressure receptacles filled with flammable gas shall be arranged to discharge freely to the open air in such a manner as to prevent any impingement of escaping gas upon the pressure receptacle itself under normal conditions of carriage. 6.2.1.3.5 Pressure receptacles whose filling is measured by volume shall be provided with a level indicator. - 298 - 6.2.1.3.6 Additional requirements for closed cryogenic receptacles 6.2.1.3.6.1 Each filling and discharge opening in a closed cryogenic receptacle used for the carriage of flammable refrigerated liquefied gases shall be fitted with at least two mutually independent shut-off devices in series, the first being a stop-valve, the second being a cap or equivalent device. 6.2.1.3.6.2 For sections of piping which can be closed at both ends and where liquid product can be trapped, a method of automatic pressure-relief shall be provided to prevent excess pressure build-up within the piping. 6.2.1.3.6.3 Each connection on a closed cryogenic receptacle shall be clearly marked to indicate its function (e.g. vapour or liquid phase). 6.2.1.3.6.4 Pressure-relief devices 6.2.1.3.6.4.1 Every closed cryogenic receptacle shall be provided with at least one pressure-relief device. The pressure-relief device shall be of the type that will resist dynamic forces including surge. 6.2.1.3.6.4.2 Closed cryogenic receptacles may, in addition, have a frangible disc in parallel with the spring loaded device(s) in order to meet the requirements of 6.2.1.3.6.5. 6.2.1.3.6.4.3 Connections to pressure-relief devices shall be of sufficient size to enable the required discharge to pass unrestricted to the pressure-relief device. 6.2.1.3.6.4.4 All pressure-relief device inlets shall under maximum filling conditions be situated in the vapour space of the closed cryogenic receptacle and the devices shall be so arranged as to ensure that the escaping vapour is discharged unrestrictedly. Capacity and setting of pressure-relief devices 6.2.1.3.6.5 NOTE: In relation to pressure-relief devices of closed cryogenic receptacles, maximum allowable working pressure (MAWP) means the maximum effective gauge pressure permissible at the top of a loaded closed cryogenic receptacle in its operating position including the highest effective pressure during filling and discharge. 6.2.1.3.6.5.1 The pressure-relief device shall open automatically at a pressure not less than the MAWP and be fully open at a pressure equal to 110% of the MAWP. It shall, after discharge, close at a pressure not lower than 10% below the pressure at which discharge starts and shall remain closed at all lower pressures. 6.2.1.3.6.5.2 Frangible discs shall be set to rupture at a nominal pressure which is the lower of either the test pressure or 150% of the MAWP. 6.2.1.3.6.5.3 In the case of the loss of vacuum in a vacuum-insulated closed cryogenic receptacle the combined capacity of all pressure-relief devices installed shall be sufficient so that the pressure (including accumulation) inside the closed cryogenic receptacle does not exceed 120% of the MAWP. 6.2.1.3.6.5.4 The required capacity of the pressure-relief devices shall be calculated in accordance with an established technical code recognized by the competent authority1. 6.2.1.4 Approval of pressure receptacles 6.2.1.4.1 The conformity of pressure receptacles shall be assessed at time of manufacture as required by the competent authority. Pressure receptacles shall be inspected, tested and approved by an inspection body. The technical documentation shall include full specifications on design and construction, and full documentation on the manufacturing and testing. 6.2.1.4.2 Quality assurance systems shall conform to the requirements of the competent authority. 1 See for example CGA Publications S-1.2-2003 "Pressure Relief Device Standards-Part 2-Cargo and Portable Tanks for Compressed Gases" and S-1.1-2003 "Pressure Relief Device Standards-Part 1-Cylinders for Compressed Gases". - 299 - 6.2.1.5 Initial inspection and test 6.2.1.5.1 New pressure receptacles, other than closed cryogenic receptacles and metal hydride storage systems, shall be subjected to testing and inspection during and after manufacture in accordance with the applicable design standards including the following: On an adequate sample of pressure receptacles: (a) Testing of the mechanical characteristics of the material of construction; (b) Verification of the minimum wall thickness; (c) Verification of the homogeneity of the material for each manufacturing batch; (d) Inspection of the external and internal conditions of the pressure receptacles; (e) Inspection of the neck threads; (f) Verification of the conformance with the design standard; For all pressure receptacles: (g) A hydraulic pressure test. Pressure receptacles shall withstand the test pressure without expansion greater than that allowed in the design specification; NOTE: With the agreement of the competent authority, the hydraulic pressure test may be replaced by a test using a gas, where such an operation does not entail any danger. 6.2.1.5.2 (h) Inspection and assessment of manufacturing defects and either repairing them or rendering the pressure receptacles unserviceable. In the case of welded pressure receptacles, particular attention shall be paid to the quality of the welds; (i) An inspection of the markings on the pressure receptacles; (j) In addition, pressure receptacles intended for the carriage of UN No. 1001 acetylene, dissolved, and UN No. 3374 acetylene, solvent free, shall be inspected to ensure proper installation and condition of the porous material and, if applicable, the quantity of solvent. On an adequate sample of closed cryogenic receptacles, the inspections and tests specified in 6.2.1.5.1 (a), (b), (d) and (f) shall be performed. In addition, welds shall be inspected by radiographic, ultrasonic or another suitable non-destructive test method on a sample of closed cryogenic receptacles according to the applicable design and construction standard. This weld inspection does not apply to the jacket. Additionally, all closed cryogenic receptacles shall undergo the initial inspections and tests specified in 6.2.1.5.1 (g), (h) and (i), as well as a leakproofness test and a test of the satisfactory operation of the service equipment after assembly. 6.2.1.5.3 For metal hydride storage systems, it shall be verified that the inspections and tests specified in 6.2.1.5.1 (a), (b), (c), (d), (e) if applicable, (f), (g), (h) and (i) have been performed on an adequate sample of the receptacles used in the metal hydride storage system. In addition, on an adequate sample of metal hydride storage systems, the inspections and tests specified in 6.2.1.5.1 (c) and (f) shall be performed, as well as 6.2.1.5.1 (e), if applicable, and inspection of the external conditions of the metal hydride storage system. Additionally, all metal hydride storage systems shall undergo the initial inspections and tests specified in 6.2.1.5.1 (h) and (i), as well as a leakproofness test and a test of the satisfactory operation of the service equipment. - 300 - 6.2.1.6 Periodic inspection and test 6.2.1.6.1 Refillable pressure receptacles, other than cryogenic receptacles, shall be subjected to periodic inspections and tests by a body authorised by the competent authority, in accordance with the following: (a) Check of the external conditions of the pressure receptacle and verification of the equipment and the external markings; (b) Check of the internal conditions of the pressure receptacle (e.g. internal inspection, verification of minimum wall thickness); (c) Checking of the threads if there is evidence of corrosion or if the fittings are removed; (d) A hydraulic pressure test and, if necessary, verification of the characteristics of the material by suitable tests; Check of service equipment, other accessories and pressure-relief devices, if to be reintroduced into service. (e) NOTE 1: With the agreement of the competent authority, the hydraulic pressure test may be replaced by a test using a gas, where such an operation does not entail any danger. NOTE 2: With the agreement of the competent authority, the hydraulic pressure test of cylinders or tubes may be replaced by an equivalent method based on acoustic emission testing or a combination of acoustic emission testing and ultrasonic examination. ISO 16148:2006 may be used as a guide for acoustic emission testing procedures. NOTE 3: The hydraulic pressure test may be replaced by ultrasonic examination carried out in accordance with ISO 10461:2005+A1:2006 for seamless aluminium alloy gas cylinders and in accordance with ISO 6406:2005 for seamless steel gas cylinders. NOTE 4: For the periodic inspection and test frequencies, see packing instruction P200 of 4.1.4.1 or, for a chemical under pressure, packing instruction P206 of 4.1.4.1. 6.2.1.6.2 Pressure receptacles intended for the carriage of UN No. 1001 acetylene, dissolved and UN No. 3374 acetylene, solvent free, shall be examined only as specified in 6.2.1.6.1 (a), (c) and (e). In addition the condition of the porous material (e.g. cracks, top clearance, loosening, settlement) shall be examined. 6.2.1.6.3 Pressure relief valves for closed cryogenic receptacles shall be subject to periodic inspections and tests. 6.2.1.7 Requirements for manufacturers 6.2.1.7.1 The manufacturer shall be technically able and shall possess all resources required for the satisfactory manufacture of pressure receptacles; this relates in particular to qualified personnel: (a) To supervise the entire manufacturing process; (b) To carry out joining of materials; and (c) To carry out the relevant tests. 6.2.1.7.2 The proficiency test of a manufacturer shall in all instances be carried out by an inspection body approved by the competent authority of the country of approval. 6.2.1.8 Requirements for inspection bodies 6.2.1.8.1 Inspection bodies shall be independent from manufacturing enterprises and competent to perform the tests, inspections and approvals required. - 301 - 6.2.2 Requirements for UN pressure receptacles In addition to the general requirements of section 6.2.1, UN pressure receptacles shall comply with the requirements of this section, including the standards, as applicable. Manufacture of new pressure receptacles or service equipment according to any particular standard in 6.2.2.1 and 6.2.2.3 is not permitted after the date shown in the right hand column of the tables. NOTE: UN pressure receptacles and service equipment constructed according to standards applicable at the date of manufacture may continue in use subject to the periodic inspection provisions of ADR. 6.2.2.1 Design, construction and initial inspection and test 6.2.2.1.1 The following standards apply for the design, construction, and initial inspection and test of UN cylinders, except that inspection requirements related to the conformity assessment system and approval shall be in accordance with 6.2.2.5: Reference Title ISO 9809-1:1999 Gas cylinders – Refillable seamless steel gas cylinders – Design, construction and testing – Part 1: Quenched and tempered steel cylinders with tensile strength less than 1 100 MPa NOTE: The note concerning the F factor in section 7.3 of this standard shall not be applied for UN cylinders. Gas cylinders -- Refillable seamless steel gas cylinders -- Design, construction and testing -- Part 1: Quenched and tempered steel cylinders with tensile strength less than 1 100 MPa Gas cylinders – Refillable seamless steel gas cylinders – Design, construction and testing – Part 2: Quenched and tempered steel cylinders with tensile strength greater than or equal to 1 100 MPa Gas cylinders – Refillable seamless steel gas cylinders – Design, construction and testing – Part 2: Quenched and tempered steel cylinders with tensile strength greater than or equal to 1 100 MPa Gas cylinders – Refillable seamless steel gas cylinders – Design, construction and testing – Part 3: Normalized steel cylinders Gas cylinders -- Refillable seamless steel gas cylinders -- Design, construction and testing -- Part 3: Normalized steel cylinders Gas cylinders – Refillable seamless aluminium alloy gas cylinders – Design, construction and testing NOTE: The note concerning the F factor in section 7.2 of this standard shall not be applied for UN cylinders. Aluminium alloy 6351A – T6 or equivalent shall not be authorised. Gas cylinders – Refillable seamless aluminium alloy gas cylinders – Design, construction and testing NOTE: Aluminium alloy 6351A or equivalent shall not be used. Gas cylinders – Refillable welded steel cylinders – Test pressure 60 bar and below Gas cylinders – Refillable welded stainless steel cylinders – Part 1: Test pressure 6 MPa and below Gas cylinders – Refillable welded aluminium-alloy cylinders – Design, construction and testing Gas cylinders – Non-refillable metallic gas cylinders – Specification and test methods ISO 9809-1:2010 ISO 9809-2:2000 ISO 9809-2:2010 ISO 9809-3:2000 ISO 9809-3:2010 ISO 7866:1999 ISO 7866: 2012 ISO 4706:2008 ISO 18172-1:2007 ISO 20703:2006 ISO 11118:1999 - 302 - Applicable for manufacture Until 31 December 2018 Until further notice Until 31 December 2018 Until further notice Until 31 December 2018 Until further notice Until 31 December 2020 Until further notice Until further notice Until further notice Until further notice Until further notice Reference Title ISO 11119-1:2002 Gas cylinders of composite construction – Specification and test methods – Part 1: Hoop wrapped composite gas cylinders Gas cylinders of composite construction – Specification and test methods – Part 2: Fully wrapped fibre reinforced composite gas cylinders with loadsharing metal liners Gas cylinders of composite construction – Specification and test methods – Part 3: Fully wrapped fibre reinforced composite gas cylinders with non-loadsharing metallic or non-metallic liners ISO 11119-2:2002 ISO 11119-3:2002 NOTE 1: service life. Applicable for manufacture Until further notice Until further notice Until further notice In the above referenced standards composite cylinders shall be designed for unlimited NOTE 2: After the first 15 years of service, composite cylinders manufactured according to these standards, may be approved for extended service by the competent authority which was responsible for the original approval of the cylinders and which will base its decision on the test information supplied by the manufacturer or owner or user. 6.2.2.1.2 The following standard apply for the design, construction, and initial inspection and test of UN tubes, except that inspection requirements related to the conformity assessment system and approval shall be in accordance with 6.2.2.5: Reference ISO 11120:1999 6.2.2.1.3 Title Gas cylinders – Refillable seamless steel tubes for compressed gas transport, of water capacity between 150 l and 3 000 l – Design, construction and testing NOTE: The note concerning the F factor in section 7.1 of this standard shall not be applied for UN tubes. Applicable for manufacture Until further notice The following standards apply for the design, construction and initial inspection and test of UN acetylene cylinders, except that inspection requirements related to the conformity assessment system and approval shall be in accordance with 6.2.2.5: For the cylinder shell: Reference Title ISO 9809-1:1999 Gas cylinders – Refillable seamless steel gas cylinders – Design, construction and testing – Part 1: Quenched and tempered steel cylinders with tensile strength less than 1 100 MPa NOTE: The note concerning the F factor in section 7.3 of this standard shall not be applied for UN cylinders. Gas cylinders – Refillable seamless steel gas cylinders – Design, construction and testing – Part 1: Quenched and tempered steel cylinders with tensile strength less than 1 100 MPa Gas cylinders – Refillable seamless steel gas cylinders – Design, construction and testing – Part 3: Normalized steel cylinders Gas cylinders – Refillable seamless steel gas cylinders – Design, construction and testing – Part 3: Normalized steel cylinders ISO 9809-1:2010 ISO 9809-3:2000 ISO 9809-3:2010 - 303 - Applicable for manufacture Until 31 December 2018 Until further notice Until 31 December 2018 Until further notice For the porous material in the cylinder: Reference Title ISO 3807-1:2000 Cylinders for acetylene – Basic requirements – Part 1: Cylinders without fusible plugs Cylinders for acetylene – Basic requirements – Part 2: Cylinders with fusible plugs ISO 3807-2:2000 6.2.2.1.4 6.2.2.1.5 The following standard apply for the design, construction, and initial inspection and test of UN cryogenic receptacles, except that inspection requirements related to the conformity assessment system and approval shall be in accordance with 6.2.2.5: Reference Title ISO 21029-1:2004 Cryogenic vessels – Transportable vacuum insulated vessels of not more than 1 000 l volume – Part 1: Design, fabrication, inspection and tests Applicable for manufacture Until further notice The following standard applies for the design, construction, and initial inspection and test of UN metal hydride storage systems, except that inspection requirements related to the conformity assessment system and approval shall be in accordance with 6.2.2.5: Reference ISO 16111:2008 6.2.2.1.6 Applicable for manufacture Until further notice Until further notice Applicable for manufacture Transportable gas storage devices – Hydrogen absorbed Until further notice in reversible metal hydride Title The standard shown below applies to the design, construction and initial inspection and test of UN bundles of cylinders. Each cylinder in a UN bundle of cylinders shall be a UN cylinder complying with the requirements of 6.2.2. The inspection requirements related to the conformity assessment system and approval for UN bundles of cylinders shall be in accordance with 6.2.2.5. Reference ISO 10961:2010 Title Gas cylinders – Cylinder bundles manufacture, testing and inspection – Design, Applicable for manufacture Until further notice NOTE: Changing one or more cylinders of the same design type, including the same test pressure, in an existing UN bundle of cylinders does not require re-certification of the existing bundle. 6.2.2.1.7 The following standards apply to the design, construction and initial inspection and test of UN cylinders for adsorbed gases except that the inspection requirements related to the conformity assessment system and approval shall be in accordance with 6.2.2.5. Reference ISO 11513:2011 ISO 9809-1:2010 Title Gas cylinders – Refillable welded steel cylinders containing materials for sub-atmospheric gas packaging (excluding acetylene) – Design, construction, testing, use and periodic inspection Gas cylinders – Refillable seamless steel gas cylinders – Design, construction and testing – Part 1: Quenched and tempered steel cylinders with tensile strength less than 1 100 MPa - 304 - Applicable for manufacture Until further notice Until further notice 6.2.2.2 Materials In addition to the material requirements specified in the pressure receptacle design and construction standards, and any restrictions specified in the applicable packing instruction for the gas(es) to be carried (e.g. packing instruction P200 or P205 of 4.1.4.1), the following standards apply to material compatibility: ISO 11114-1:2012 ISO 11114-2:2000 6.2.2.3 Gas cylinders – Compatibility of cylinder and valve materials with gas contents – Part 1: Metallic materials Transportable gas cylinders – Compatibility of cylinder and valve materials with gas contents – Part 2: Non-metallic materials Service equipment The following standards apply to closures and their protection: Reference ISO 11117:1998 ISO 11117:2008 + Cor 1:2009 ISO 10297:1999 ISO 10297:2006 ISO 13340:2001 Title Gas cylinders – Valve protection caps and valve guards for industrial and medical gas cylinders – Design, construction and tests Gas cylinders − Valve protection caps and valve guards − Design, construction and tests Gas cylinders – Refillable gas cylinder valves – Specification and type testing Gas cylinders – Refillable gas cylinder valves – Specification and type testing NOTE: The EN version of this ISO standard fulfils the requirements and may also be used. Transportable gas cylinders – Cylinder valves for nonrefillable cylinders – Specification and prototype testing Applicable for manufacture Until 31 December 2014 Until further notice Until 31 December 2008 Until further notice Until further notice For UN metal hydride storage systems, the requirements specified in the following standard apply to closures and their protection: Reference ISO 16111:2008 6.2.2.4 Applicable for manufacture Transportable gas storage devices – Hydrogen absorbed Until further notice in reversible metal hydride Title Periodic inspection and test The following standards apply to the periodic inspection and testing of UN cylinders and UN metal hydride storage systems: Reference ISO 6406:2005 ISO 10460:2005 ISO 10461:2005 + A1:2006 ISO 10462:2005 Title Periodic inspection and testing of seamless steel gas cylinders Gas cylinders – Welded carbon-steel gas cylinders – Periodic inspection and testing NOTE: The repair of welds described in clause 12.1 of this standard shall not be permitted. Repairs described in clause 12.2 require the approval of the competent authority which approved the periodic inspection and test body in accordance with 6.2.2.6. Seamless aluminium-alloy gas cylinders – Periodic inspection and testing Gas cylinders – Transportable cylinders for dissolved acetylene – Periodic inspection and maintenance - 305 - Applicable for manufacture Until further notice Until further notice Until further notice Until further notice Reference ISO 11513:2011 ISO 11623:2002 ISO 16111:2008 Title Gas cylinders – Refillable welded steel cylinders containing materials for sub-atmospheric gas packaging (excluding acetylene) – Design, construction, testing, use and periodic inspection Transportable gas cylinders – Periodic inspection and testing of composite gas cylinders Transportable gas storage devices – Hydrogen absorbed in reversible metal hydride Applicable for manufacture Until further notice Until further notice Until further notice 6.2.2.5 Conformity assessment system and approval for manufacture of pressure receptacles 6.2.2.5.1 Definitions For the purposes of this sub-section: Conformity assessment system means a system for competent authority approval of a manufacturer, by pressure receptacle design type approval, approval of manufacturer's quality system and approval of inspection bodies; Design type means a pressure receptacle design as specified by a particular pressure receptacle standard; Verify means confirm by examination or provision of objective evidence that specified requirements have been fulfilled. 6.2.2.5.2 General requirements Competent authority 6.2.2.5.2.1 The competent authority that approves the pressure receptacle shall approve the conformity assessment system for the purpose of ensuring that pressure receptacles conform to the requirements of ADR. In instances where the competent authority that approves a pressure receptacle is not the competent authority in the country of manufacture, the marks of the approval country and the country of manufacture shall be indicated in the pressure receptacle marking (see 6.2.2.7 and 6.2.2.8). The competent authority of the country of approval shall supply, upon request, evidence demonstrating compliance to this conformity assessment system to its counterpart in a country of use. 6.2.2.5.2.2 The competent authority may delegate its functions in this conformity assessment system in whole or in part. 6.2.2.5.2.3 The competent authority shall ensure that a current list of approved inspection bodies and their identity marks and approved manufacturers and their identity marks is available. Inspection body 6.2.2.5.2.4 The inspection body shall be approved by the competent authority for the inspection of pressure receptacles and shall: (a) Have a staff with an organizational structure, capable, trained, competent, and skilled, to satisfactorily perform its technical functions; (b) Have access to suitable and adequate facilities and equipment; (c) Operate in an impartial manner and be free from any influence which could prevent it from doing so; (d) Ensure commercial confidentiality of the commercial and proprietary activities of the manufacturer and other bodies; - 306 - 6.2.2.5.2.5 (e) Maintain clear demarcation between actual inspection body functions and unrelated functions; (f) Operate a documented quality system; (g) Ensure that the tests and inspections specified in the relevant pressure receptacle standard and ADR are performed; and (h) Maintain an effective and appropriate report and record system in accordance with 6.2.2.5.6. The inspection body shall perform design type approval, pressure receptacle production testing and inspection, and certification to verify conformity with the relevant pressure receptacle standard (see 6.2.2.5.4 and 6.2.2.5.5). Manufacturer 6.2.2.5.2.6 The manufacturer shall: (a) Operate a documented quality system in accordance with 6.2.2.5.3; (b) Apply for design type approvals in accordance with 6.2.2.5.4; (c) Select an inspection body from the list of approved inspection bodies maintained by the competent authority in the country of approval; and (d) Maintain records in accordance with 6.2.2.5.6. Testing laboratory 6.2.2.5.2.7 The testing laboratory shall have: (a) Staff with an organizational structure, sufficient in number, competence, and skill; and (b) Suitable and adequate facilities and equipment to perform the tests required by the manufacturing standard to the satisfaction of the inspection body. 6.2.2.5.3 Manufacturer's quality system 6.2.2.5.3.1 The quality system shall contain all the elements, requirements, and provisions adopted by the manufacturer. It shall be documented in a systematic and orderly manner in the form of written policies, procedures and instructions. The contents shall in particular include adequate descriptions of: (a) The organizational structure and responsibilities of personnel with regard to design and product quality; (b) The design control and design verification techniques, processes, and procedures that will be used when designing the pressure receptacles; (c) The relevant pressure receptacle manufacturing, quality control, quality assurance and process operation instructions that will be used; (d) Quality records, such as inspection reports, test data and calibration data; (e) Management reviews to ensure the effective operation of the quality system arising from the audits in accordance with 6.2.2.5.3.2; (f) The process describing how customer requirements are met; (g) The process for control of documents and their revision; - 307 - 6.2.2.5.3.2 (h) The means for control of non-conforming pressure receptacles, purchased components, inprocess and final materials; and (i) Training programmes and qualification procedures for relevant personnel. Audit of the quality system The quality system shall be initially assessed to determine whether it meets the requirements in 6.2.2.5.3.1 to the satisfaction of the competent authority. The manufacturer shall be notified of the results of the audit. The notification shall contain the conclusions of the audit and any corrective actions required. Periodic audits shall be carried out, to the satisfaction of the competent authority, to ensure that the manufacturer maintains and applies the quality system. Reports of the periodic audits shall be provided to the manufacturer. 6.2.2.5.3.3 Maintenance of the quality system The manufacturer shall maintain the quality system as approved in order that it remains adequate and efficient. The manufacturer shall notify the competent authority that approved the quality system, of any intended changes. The proposed changes shall be evaluated in order to determine whether the amended quality system will still satisfy the requirements in 6.2.2.5.3.1. 6.2.2.5.4 Approval process Initial design type approval 6.2.2.5.4.1 The initial design type approval shall consist of approval of the manufacturer's quality system and approval of the pressure receptacle design to be produced. An application for an initial design type approval shall meet the requirements of 6.2.2.5.4.2 to 6.2.2.5.4.6 and 6.2.2.5.4.9. 6.2.2.5.4.2 A manufacturer desiring to produce pressure receptacles in accordance with a pressure receptacle standard and ADR shall apply for, obtain, and retain a design type approval certificate issued by the competent authority in the country of approval for at least one pressure receptacle design type in accordance with the procedure given in 6.2.2.5.4.9. This certificate shall, on request, be submitted to the competent authority of the country of use. 6.2.2.5.4.3 An application shall be made for each manufacturing facility and shall include: (a) The name and registered address of the manufacturer and in addition, if the application is submitted by an authorised representative, its name and address; (b) The address of the manufacturing facility (if different from the above); (c) The name and title of the person(s) responsible for the quality system; (d) The designation of the pressure receptacle and the relevant pressure receptacle standard; (e) Details of any refusal of approval of a similar application by any other competent authority; (f) The identity of the inspection body for design type approval; (g) Documentation on the manufacturing facility as specified under 6.2.2.5.3.1; and (h) The technical documentation required for design type approval, which shall enable verification of the conformity of the pressure receptacles with the requirements of the relevant pressure receptacle design standard. The technical documentation shall cover the design and method of manufacture and shall contain, as far as is relevant for assessment, at least the following: - 308 - (i) pressure receptacle design standard, design and manufacturing drawings, showing components and subassemblies, if any; (ii) descriptions and explanations necessary for the understanding of the drawings and intended use of the pressure receptacles; (iii) a list of the standards necessary to fully define the manufacturing process; (iv) design calculations and material specifications; and (v) design type approval test reports, describing the results of examinations and tests carried out in accordance with 6.2.2.5.4.9. 6.2.2.5.4.4 An initial audit in accordance with 6.2.2.5.3.2 shall be performed to the satisfaction of the competent authority. 6.2.2.5.4.5 If the manufacturer is denied approval, the competent authority shall provide written detailed reasons for such denial. 6.2.2.5.4.6 Following approval, changes to the information submitted under 6.2.2.5.4.3 relating to the initial approval shall be provided to the competent authority. Subsequent design type approvals 6.2.2.5.4.7 An application for a subsequent design type approval shall meet the requirements of 6.2.2.5.4.8 and 6.2.2.5.4.9, provided a manufacturer is in the possession of an initial design type approval. In such a case, the manufacturer's quality system according to 6.2.2.5.3 shall have been approved during the initial design type approval and shall be applicable for the new design. 6.2.2.5.4.8 The application shall include: (a) The name and address of the manufacturer and in addition, if the application is submitted by an authorised representative, its name and address; (b) Details of any refusal of approval of a similar application by any other competent authority; (c) Evidence that initial design type approval has been granted; and (d) The technical documentation, as described in 6.2.2.5.4.3 (h). Procedure for design type approval 6.2.2.5.4.9 The inspection body shall: (a) Examine the technical documentation to verify that: (i) the design is in accordance with the relevant provisions of the standard, and (ii) the prototype lot has been manufactured in conformity with the technical documentation and is representative of the design; (b) Verify that the production inspections have been carried out as required in accordance with 6.2.2.5.5; (c) Select pressure receptacles from a prototype production lot and supervise the tests of these pressure receptacles as required for design type approval; - 309 - (d) (e) Perform or have performed the examinations and tests specified in the pressure receptacle standard to determine that: (i) the standard has been applied and fulfilled, and (ii) the procedures adopted by the manufacturer meet the requirements of the standard; and Ensure that the various type approval examinations and tests are correctly and competently carried out. After prototype testing has been carried out with satisfactory results and all applicable requirements of 6.2.2.5.4 have been satisfied, a design type approval certificate shall be issued, which shall include the name and address of the manufacturer, results and conclusions of the examination, and the necessary data for identification of the design type. If the manufacturer is denied a design type approval, the competent authority shall provide written detailed reasons for such denial. 6.2.2.5.4.10 Modifications to approved design types The manufacturer shall either: (a) Inform the issuing competent authority of modifications to the approved design type, where such modifications do not constitute a new design, as specified in the pressure receptacle standard; or (b) Request a subsequent design type approval where such modifications constitute a new design according to the relevant pressure receptacle standard. This additional approval shall be given in the form of an amendment to the original design type approval certificate. 6.2.2.5.4.11 Upon request, the competent authority shall communicate to any other competent authority, information concerning design type approval, modifications of approvals and withdrawn approvals. 6.2.2.5.5 Production inspection and certification General requirements An inspection body, or its delegate, shall carry out the inspection and certification of each pressure receptacle. The inspection body selected by the manufacturer for inspection and testing during production may be different from the inspection body used for the design type approval testing. Where it can be demonstrated to the satisfaction of the inspection body that the manufacturer has trained competent inspectors, independent of the manufacturing operations, inspection may be performed by those inspectors. In such a case, the manufacturer shall maintain training records of the inspectors. The inspection body shall verify that the inspections by the manufacturer, and tests performed on those pressure receptacles, fully conform to the standard and the requirements of ADR. Should nonconformance in conjunction with this inspection and testing be determined, the permission to have inspection performed by the manufacturer's inspectors may be withdrawn. The manufacturer shall, after approval by the inspection body, make a declaration of conformity with the certified design type. The application of the pressure receptacle certification marking shall be considered a declaration that the pressure receptacle complies with the applicable pressure receptacle standards and the requirements of this conformity assessment system and ADR. The inspection body shall affix or delegate the manufacturer to affix the pressure receptacle certification marking and the registered mark of the inspection body to each approved pressure receptacle. A certificate of compliance, signed by the inspection body and the manufacturer, shall be issued before the pressure receptacles are filled. - 310 - 6.2.2.5.6 Records Design type approval and certificate of compliance records shall be retained by the manufacturer and the inspection body for not less than 20 years. 6.2.2.6 Approval system for periodic inspection and test of pressure receptacles 6.2.2.6.1 Definition For the purposes of this section: Approval system means a system for competent authority approval of a body performing periodic inspection and test of pressure receptacles (hereinafter referred to as "periodic inspection and test body"), including approval of that body’s quality system. 6.2.2.6.2 General requirements Competent authority 6.2.2.6.2.1 The competent authority shall establish an approval system for the purpose of ensuring that the periodic inspection and test of pressure receptacles conform to the requirements of ADR. In instances where the competent authority that approves a body performing periodic inspection and test of a pressure receptacle is not the competent authority of the country approving the manufacture of the pressure receptacle, the marks of the approval country of periodic inspection and test shall be indicated in the pressure receptacle marking (see 6.2.2.7). The competent authority of the country of approval for the periodic inspection and test shall supply, upon request, evidence demonstrating compliance to this approval system including the records of the periodic inspection and test to its counterpart in a country of use. The competent authority of the country of approval may terminate the approval certificate referred to in 6.2.2.6.4.1, upon evidence demonstrating non-compliance with the approval system. 6.2.2.6.2.2 The competent authority may delegate its functions in this approval system, in whole or in part. 6.2.2.6.2.3 The competent authority shall ensure that a current list of approved periodic inspection and test bodies and their identity marks is available. Periodic inspection and test body 6.2.2.6.2.4 The periodic inspection and test body shall be approved by the competent authority and shall: (a) Have a staff with an organizational structure, capable, trained, competent, and skilled, to satisfactorily perform its technical functions; (b) Have access to suitable and adequate facilities and equipment; (c) Operate in an impartial manner and be free from any influence which could prevent it from doing so; (d) Ensure commercial confidentiality; (e) Maintain clear demarcation between actual periodic inspection and test body functions and unrelated functions; (f) Operate a documented quality system accordance with 6.2.2.6.3; (g) Apply for approval in accordance with 6.2.2.6.4; (h) Ensure that the periodic inspections and tests are performed in accordance with 6.2.2.6.5; and (i) Maintain an effective and appropriate report and record system in accordance with 6.2.2.6.6. - 311 - 6.2.2.6.3 Quality system and audit of the periodic inspection and test body 6.2.2.6.3.1 Quality system The quality system shall contain all the elements, requirements, and provisions adopted by the periodic inspection and test body. It shall be documented in a systematic and orderly manner in the form of written policies, procedures, and instructions. The quality system shall include: 6.2.2.6.3.2 (a) A description of the organizational structure and responsibilities; (b) The relevant inspection and test, quality control, quality assurance, and process operation instructions that will be used; (c) Quality records, such as inspection reports, test data, calibration data and certificates; (d) Management reviews to ensure the effective operation of the quality system arising from the audits performed in accordance with 6.2.2.6.3.2; (e) A process for control of documents and their revision; (f) A means for control of non-conforming pressure receptacles; and (g) Training programmes and qualification procedures for relevant personnel. Audit The periodic inspection and test body and its quality system shall be audited in order to determine whether it meets the requirements of ADR to the satisfaction of the competent authority. An audit shall be conducted as part of the initial approval process (see 6.2.2.6.4.3). An audit may be required as part of the process to modify an approval (see 6.2.2.6.4.6). Periodic audits shall be conducted, to the satisfaction of the competent authority, to ensure that the periodic inspection and test body continues to meet the requirements of ADR. The periodic inspection and test body shall be notified of the results of any audit. The notification shall contain the conclusions of the audit and any corrective actions required. 6.2.2.6.3.3 Maintenance of the quality system The periodic inspection and test body shall maintain the quality system as approved in order that it remains adequate and efficient. The periodic inspection and test body shall notify the competent authority that approved the quality system, of any intended changes, in accordance with the process for modification of an approval in 6.2.2.6.4.6. 6.2.2.6.4 Approval process for periodic inspection and test bodies Initial approval 6.2.2.6.4.1 A body desiring to perform periodic inspection and test of pressure receptacles in accordance with a pressure receptacle standard and ADR shall apply for, obtain, and retain an approval certificate issued by the competent authority. This written approval shall, on request, be submitted to the competent authority of a country of use. 6.2.2.6.4.2 An application shall be made for each periodic inspection and test body and shall include: (a) The name and address of the periodic inspection and test body and, if the application is submitted by an authorised representative, its name and address; - 312 - 6.2.2.6.4.3 (b) The address of each facility performing periodic inspection and test; (c) The name and title of the person(s) responsible for the quality system; (d) The designation of the pressure receptacles, the periodic inspection and test methods, and the relevant pressure receptacle standards met by the quality system; (e) Documentation on each facility, the equipment, and the quality system as specified under 6.2.2.6.3.1; (f) The qualifications and training records of the periodic inspection and test personnel; and (g) Details of any refusal of approval of a similar application by any other competent authority. The competent authority shall: (a) Examine the documentation to verify that the procedures are in accordance with the requirements of the relevant pressure receptacle standards and ADR; and (b) Conduct an audit in accordance with 6.2.2.6.3.2 to verify that the inspections and tests are carried out as required by the relevant pressure receptacle standards and ADR, to the satisfaction of the competent authority. 6.2.2.6.4.4 After the audit has been carried out with satisfactory results and all applicable requirements of 6.2.2.6.4 have been satisfied, an approval certificate shall be issued. It shall include the name of the periodic inspection and test body, the registered mark, the address of each facility, and the necessary data for identification of its approved activities (e.g. designation of pressure receptacles, periodic inspection and test method and pressure receptacle standards). 6.2.2.6.4.5 If the periodic inspection and test body is denied approval, the competent authority shall provide written detailed reasons for such denial. Modifications to periodic inspection and test body approvals 6.2.2.6.4.6 Following approval, the periodic inspection and test body shall notify the issuing competent authority of any modifications to the information submitted under 6.2.2.6.4.2 relating to the initial approval. The modifications shall be evaluated in order to determine whether the requirements of the relevant pressure receptacle standards and ADR will be satisfied. An audit in accordance with 6.2.2.6.3.2 may be required. The competent authority shall accept or reject these modifications in writing, and an amended approval certificate shall be issued as necessary. 6.2.2.6.4.7 Upon request, the competent authority shall communicate to any other competent authority, information concerning initial approvals, modifications of approvals, and withdrawn approvals. 6.2.2.6.5 Periodic inspection and test and certification The application of the periodic inspection and test marking to a pressure receptacle shall be considered a declaration that the pressure receptacle complies with the applicable pressure receptacle standards and the requirements of ADR. The periodic inspection and test body shall affix the periodic inspection and test marking, including its registered mark, to each approved pressure receptacle (see 6.2.2.7.7). A record certifying that a pressure receptacle has passed the periodic inspection and test shall be issued by the periodic inspection and test body, before the pressure receptacle is filled. 6.2.2.6.6 Records The periodic inspection and test body shall retain records of pressure receptacle periodic inspection and tests (both passed and failed) including the location of the test facility, for not less than 15 years. The owner of the pressure receptacle shall retain an identical record until the next periodic inspection and test unless the pressure receptacle is permanently removed from service. - 313 - 6.2.2.7 Marking of refillable UN pressure receptacles NOTE: Marking requirements for UN metal hydride storage systems are given in 6.2.2.9 and marking requirements for UN bundles of cylinders are given in 6.2.2.10. 6.2.2.7.1 Refillable UN pressure receptacles shall be marked clearly and legibly with certification, operational and manufacturing marks. These marks shall be permanently affixed (e.g. stamped, engraved, or etched) on the pressure receptacle. The marks shall be on the shoulder, top end or neck of the pressure receptacle or on a permanently affixed component of the pressure receptacle (e.g. welded collar or corrosion resistant plate welded on the outer jacket of a closed cryogenic receptacle). Except for the UN packaging symbol, the minimum size of the marks shall be 5 mm for pressure receptacles with a diameter greater than or equal to 140 mm and 2.5 mm for pressure receptacles with a diameter less than 140 mm. The minimum size of the UN packaging symbol shall be 10 mm for pressure receptacles with a diameter greater than or equal to 140 mm and 5 mm for pressure receptacles with a diameter less than 140 mm. 6.2.2.7.2 The following certification marks shall be applied: (a) The United Nations packaging symbol ; This symbol shall not be used for any purpose other than certifying that a packaging, a portable tank or a MEGC complies with the relevant requirements in Chapter 6.1, 6.2, 6.3, 6.5, 6.6 or 6.72. This symbol shall not be used for pressure receptacles which only conform to the requirements of 6.2.3 to 6.2.5 (see 6.2.3.9). (b) The technical standard (e.g. ISO 9809-1) used for design, manufacture and testing; (c) The character(s) identifying the country of approval as indicated by the distinguishing signs for motor vehicles in international traffic3; NOTE: The country of approval shall be understood to be the country that approved the body which inspected the individual receptacle at time of manufacture. 6.2.2.7.3 (d) The identity mark or stamp of the inspection body that is registered with the competent authority of the country authorizing the marking; (e) The date of the initial inspection, the year (four digits) followed by the month (two digits) separated by a slash (i.e. "/"); The following operational marks shall be applied: (f) The test pressure in bar, preceded by the letters "PH" and followed by the letters "BAR"; (g) The mass of the empty pressure receptacle including all permanently attached integral parts (e.g. neck ring, foot ring, etc.) in kilograms, followed by the letters "KG". This mass shall not include the mass of valve, valve cap or valve guard, any coating or porous material for acetylene. The mass shall be expressed to three significant figures rounded up to the last digit. For cylinders of less than 1 kg, the mass shall be expressed to two significant figures rounded up to the last digit. In the case of pressure receptacles for UN No. 1001 acetylene, dissolved and UN No. 3374 acetylene, solvent free, at least one decimal shall be shown after the decimal point and two digits for pressure receptacles of less than 1 kg; 2 This symbol is also used to certify that flexible bulk containers authorized for other modes of transport comply with the requirements in Chapter 6.8 of the UN Model Regulations. 3 Distinguishing signs for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 314 - 6.2.2.7.4 6.2.2.7.5 (h) The minimum guaranteed wall thickness of the pressure receptacle in millimetres followed by the letters "MM". This mark is not required for pressure receptacles with a water capacity less than or equal to 1 litre or for composite cylinders or for closed cryogenic receptacles; (i) In the case of pressure receptacles for compressed gases, UN No. 1001 acetylene, dissolved, and UN No. 3374 acetylene, solvent free, the working pressure in bar, preceded by the letters "PW". In the case of closed cryogenic receptacles, the maximum allowable working pressure preceded by the letters "MAWP"; (j) In the case of pressure receptacles for liquefied gases and refrigerated liquefied gases, the water capacity in litres expressed to three significant figures rounded down to the last digit, followed by the letter "L". If the value of the minimum or nominal water capacity is an integer, the figures after the decimal point may be neglected; (k) In the case of pressure receptacles for UN No. 1001 acetylene, dissolved, the total of the mass of the empty receptacle, the fittings and accessories not removed during filling, any coating, the porous material, the solvent and the saturation gas expressed to three significant figures rounded down to the last digit followed by the letters "KG". At least one decimal shall be shown after the decimal point. For pressure receptacles of less than 1 kg, the mass shall be expressed to two significant figures rounded down to the last digit; (l) In the case of pressure receptacles for UN No. 3374 acetylene, solvent free, the total of the mass of the empty receptacle, the fittings and accessories not removed during filling, any coating and the porous material expressed to three significant figures rounded down to the last digit followed by the letters "KG". At least one decimal shall be shown after the decimal point. For pressure receptacles of less than 1 kg, the mass shall be expressed to two significant figures rounded down to the last digit; The following manufacturing marks shall be applied: (m) Identification of the cylinder thread (e.g. 25E). This mark is not required for closed cryogenic receptacles; (n) The manufacturer's mark registered by the competent authority. When the country of manufacture is not the same as the country of approval, then the manufacturer's mark shall be preceded by the character(s) identifying the country of manufacture as indicated by the distinguishing signs for motor vehicles in international traffic3. The country mark and the manufacturer’s mark shall be separated by a space or slash; (o) The serial number assigned by the manufacturer; (p) In the case of steel pressure receptacles and composite pressure receptacles with steel liner intended for the carriage of gases with a risk of hydrogen embrittlement, the letter "H" showing compatibility of the steel (see ISO 11114-1:2012). The above marks shall be placed in three groups: - Manufacturing marks shall be the top grouping and shall appear consecutively in the sequence given in 6.2.2.7.4. - The operational marks in 6.2.2.7.3 shall be the middle grouping and the test pressure (f) shall be immediately preceded by the working pressure (i) when the latter is required. - Certification marks shall be the bottom grouping and shall appear in the sequence given in 6.2.2.7.2. 3 Distinguishing signs for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 315 - The following is an example of the markings applied to a cylinder. (m) 25E D (n) MF (o) 765432 (p) H (i) PW200 (f) PH300BAR (g) 62.1KG (j) 50L (h) 5.8MM (a) (b) (c) (d) (e) ISO 9809-1 F IB 2000/12 6.2.2.7.6 Other marks are allowed in areas other than the side wall, provided they are made in low stress areas and are not of a size and depth that will create harmful stress concentrations. In the case of closed cryogenic receptacles, such marks may be on a separate plate attached to the outer jacket. Such marks shall not conflict with required marks. 6.2.2.7.7 In addition to the preceding marks, each refillable pressure receptacle that meets the periodic inspection and test requirements of 6.2.2.4 shall be marked indicating: (a) The character(s) identifying the country authorizing the body performing the periodic inspection and test as indicated by the distinguishing signs of motor vehicles in international traffic3. This marking is not required if this body is approved by the competent authority of the country approving manufacture; (b) The registered mark of the body authorised by the competent authority for performing periodic inspection and test; (c) The date of the periodic inspection and test, the year (two digits) followed by the month (two digits) separated by a slash (i.e. "/" ). Four digits may be used to indicate the year. The above marks shall appear consecutively in the sequence given. 6.2.2.7.8 For acetylene cylinders, with the agreement of the competent authority, the date of the most recent periodic inspection and the stamp of the body performing the periodic inspection and test may be engraved on a ring held on the cylinder by the valve. The ring shall be configured so that it can only be removed by disconnecting the valve from the cylinder. 6.2.2.7.9 (Deleted) 6.2.2.8 Marking of non-refillable UN pressure receptacles 6.2.2.8.1 Non-refillable UN pressure receptacles shall be marked clearly and legibly with certification and gas or pressure receptacle specific marks. These marks shall be permanently affixed (e.g. stencilled, stamped, engraved, or etched) on the pressure receptacle. Except when stencilled, the marks shall be on the shoulder, top end or neck of the pressure receptacle or on a permanently affixed component of the pressure receptacle (e.g. welded collar). Except for the UN packaging symbol and the "DO NOT REFILL" mark, the minimum size of the marks shall be 5 mm for pressure receptacles with a diameter greater than or equal to 140 mm and 2.5 mm for pressure receptacles with a diameter less than 140 mm. The minimum size of the UN packaging symbol shall be 10 mm for pressure receptacles with a diameter greater than or equal to 140 mm and 5 mm for pressure receptacles with a diameter less than 140 mm. The minimum size of the "DO NOT REFILL" mark shall be 5 mm. 3 Distinguishing signs for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 316 - 6.2.2.8.2 The marks listed in 6.2.2.7.2 to 6.2.2.7.4 shall be applied with the exception of (g), (h) and (m). The serial number (o) may be replaced by the batch number. In addition, the words "DO NOT REFILL" in letters of at least 5 mm in height are required. 6.2.2.8.3 The requirements of 6.2.2.7.5 shall apply. NOTE: Non-refillable pressure receptacles may, on account of their size, substitute this marking by a label. 6.2.2.8.4 Other marks are allowed provided they are made in low stress areas other than the side wall and are not of a size and depth that will create harmful stress concentrations. Such marks shall not conflict with required marks. 6.2.2.9 Marking of UN metal hydride storage systems 6.2.2.9.1 UN metal hydride storage systems shall be marked clearly and legibly with the marks listed below. These marks shall be permanently affixed (e.g. stamped, engraved, or etched) on the metal hydride storage system. The marks shall be on the shoulder, top end or neck of the metal hydride storage system or on a permanently affixed component of the metal hydride storage system. Except for the United Nations packaging symbol, the minimum size of the marks shall be 5 mm for metal hydride storage systems with a smallest overall dimension greater than or equal to 140 mm and 2.5 mm for metal hydride storage systems with a smallest overall dimension less than 140 mm. The minimum size of the United Nations packaging symbol shall be 10 mm for metal hydride storage systems with a smallest overall dimension greater than or equal to 140 mm and 5 mm for metal hydride storage systems with a smallest overall dimension less than 140 mm. 6.2.2.9.2 The following marks shall be applied: (a) The United Nations packaging symbol ; This symbol shall not be used for any purpose other than certifying that a packaging, a portable tank or a MEGC complies with the relevant requirements in Chapter 6.1, 6.2, 6.3, 6.5, 6.6 or 6.72; (b) "ISO 16111" (the technical standard used for design, manufacture and testing); (c) The character(s) identifying the country of approval as indicated by the distinguishing signs of motor vehicles in international traffic3; NOTE: The country of approval shall be understood to be the country that approved the body which inspected the individual receptacle at the time of manufacture. (d) The identity mark or stamp of the inspection body that is registered with the competent authority of the country authorizing the marking; (e) The date of the initial inspection, the year (four digits) followed by the month (two digits) separated by a slash (i.e. "/"); (f) The test pressure of the receptacle in bar, preceded by the letters "PH" and followed by the letters "BAR"; (g) The rated charging pressure of the metal hydride storage system in bar, preceded by the letters "RCP" and followed by the letters "BAR"; 2 This symbol is also used to certify that flexible bulk containers authorized for other modes of transport comply with the requirements in Chapter 6.8 of the UN Model Regulations. 3 Distinguishing signs for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 317 - (h) The manufacturer's mark registered by the competent authority. When the country of manufacture is not the same as the country of approval, then the manufacturer's mark shall be preceded by the character(s) identifying the country of manufacture as indicated by the distinguishing signs of motor vehicles in international traffic3. The country mark and the manufacturer’s mark shall be separated by a space or slash; (i) The serial number assigned by the manufacturer; (j) In the case of steel receptacles and composite receptacles with steel liner, the letter "H" showing compatibility of the steel (see ISO 11114-1:2012); and, (k) In the case of metal hydride storage systems having limited life, the date of expiry, denoted by the letters "FINAL" followed by the year (four digits) followed by the month (two digits) separated by a slash (i.e. "/"). The certification marks specified in (a) to (e) above shall appear consecutively in the sequence given. The test pressure (f) shall be immediately preceded by the rated charging pressure (g). The manufacturing marks specified in (h) to (k) above shall appear consecutively in the sequence given. 6.2.2.9.3 Other marks are allowed in areas other than the side wall, provided they are made in low stress areas and are not of a size and depth that will create harmful stress concentrations. Such marks shall not conflict with required marks. 6.2.2.9.4 In addition to the preceding marks, each metal hydride storage system that meets the periodic inspection and test requirements of 6.2.2.4 shall be marked indicating: (a) The character(s) identifying the country authorizing the body performing the periodic inspection and test, as indicated by the distinguishing sign of motor vehicles in international traffic3. This marking is not required if this body is approved by the competent authority of the country approving manufacture; (b) The registered mark of the body authorised by the competent authority for performing periodic inspection and test; (c) The date of the periodic inspection and test, the year (two digits) followed by the month (two digits) separated by a slash (i.e. "/" ). Four digits may be used to indicate the year. The above marks shall appear consecutively in the sequence given. 6.2.2.10 Marking of UN bundles of cylinders 6.2.2.10.1 Individual cylinders in a bundle of cylinders shall be marked in accordance with 6.2.2.7. 6.2.2.10.2 Refillable UN bundles of cylinders shall be marked clearly and legibly with certification, operational, and manufacturing marks. These marks shall be permanently affixed (e.g. stamped, engraved, or etched) on a plate permanently attached to the frame of the bundle of cylinders. Except for the UN packaging symbol, the minimum size of the marks shall be 5 mm. The minimum size of the UN packaging symbol shall be 10 mm. 6.2.2.10.3 The following marks shall be applied: (a) The certification marks specified in 6.2.2.7.2 (a), (b), (c), (d) and (e); (b) The operational marks specified in 6.2.2.7.3 (f), (i), (j) and the total of the mass of the frame of the bundle and all permanently attached parts (cylinders, manifold, fittings and valves). Bundles intended for the carriage of UN 1001 acetylene, dissolved and UN 3374 acetylene, solvent free shall bear the tare mass as specified in clause B.4.2 of ISO 10961:2010; and (c) The manufacturing marks specified in 6.2.2.7.4 (n), (o) and, where applicable, (p). 3 Distinguishing signs for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 318 - 6.2.2.10.4 The marks shall be placed in three groups: (a) The manufacturing marks shall be the top grouping and shall appear consecutively in the sequence given in 6.2.2.10.3 (c); (b) The operational marks in 6.2.2.10.3 (b) shall be the middle grouping and the operational mark specified in 6.2.2.7.3 (f) shall be immediately preceded by the operational mark specified in 6.2.2.7.3 (i) when the latter is required; (c) 6.2.2.11 Certification marks shall be the bottom grouping and shall appear in the sequence given in 6.2.2.10.3 (a). Equivalent procedures for conformity assessment and periodic inspection and test For UN pressure receptacles the requirements of 6.2.2.5 and 6.2.2.6 are considered to have been complied with when the following procedures are applied: Procedure Relevant body Type approval (1.8.7.2) Xa Supervision of manufacture (1.8.7.3) Xa or IS Initial inspection and tests (1.8.7.4) Xa or IS Periodic inspection (1.8.7.5) Xa or Xb or IS Xa means the competent authority, its delegate or inspection body conforming to 1.8.6.2, 1.8.6.4, 1.8.6.5 and 1.8.6.8 and accredited according to EN ISO/IEC 17020:2012 (except clause 8.1.3) type A. Xb means inspection body conforming to 1.8.6.2, 1.8.6.4, 1.8.6.5 and 1.8.6.8 and accredited according to EN ISO/IEC 17020:2012 (except clause 8.1.3) type B. IS means an in-house inspection service of the applicant under the surveillance of an inspection body conforming to 1.8.6.2, 1.8.6.4, 1.8.6.5 and 1.8.6.8 and accredited according to EN ISO/IEC 17020:2012 (except clause 8.1.3) type A. The in-house inspection service shall be independent from design process, manufacturing operations, repair and maintenance. 6.2.3 General requirements for non-UN pressure receptacles 6.2.3.1 Design and construction 6.2.3.1.1 Pressure receptacles and their closures not designed, constructed, inspected, tested and approved according to the requirements of 6.2.2 shall be designed, constructed, inspected, tested and approved in accordance with the general requirements of 6.2.1 as supplemented or modified by the requirements of this section and those of 6.2.4 or 6.2.5. 6.2.3.1.2 Whenever possible the wall thickness shall be determined by calculation, accompanied, if needed, by experimental stress analysis. Otherwise the wall thickness may be determined by experimental means. Appropriate design calculations for the pressure envelope and supporting components shall be used to ensure the safety of the pressure receptacles concerned. The minimum wall thickness to withstand pressure shall be calculated in particular with regard to: - The calculation pressures, which shall not be less than the test pressure; - The calculation temperatures allowing for appropriate safety margins; - The maximum stresses and peak stress concentrations where necessary; - Factors inherent to the properties of the material. - 319 - 6.2.3.1.3 For welded pressure receptacles, only metals of weldable quality whose adequate impact strength at an ambient temperature of –20 °C can be guaranteed shall be used. 6.2.3.1.4 For closed cryogenic receptacles, the impact strength to be established as required by 6.2.1.1.8.1 shall be tested as laid down in 6.8.5.3. 6.2.3.1.5 Acetylene cylinders shall not be fitted with fusible plugs. 6.2.3.2 (Reserved) 6.2.3.3 Service equipment 6.2.3.3.1 Service equipment shall comply with 6.2.1.3. 6.2.3.3.2 Openings Pressure drums may be provided with openings for filling and discharge and with other openings intended for level gauges, pressure gauges or relief devices. The number of openings shall be kept to a minimum consistent with safe operations. Pressure drums may also be provided with an inspection opening, which shall be closed by an effective closure. 6.2.3.3.3 Fittings (a) If cylinders are fitted with a device to prevent rolling, this device shall not be integral with the valve cap; (b) Pressure drums which are capable of being rolled shall be equipped with rolling hoops or be otherwise protected against damage due to rolling (e.g. by corrosion resistant metal sprayed on to the pressure receptacle surface); (c) Bundles of cylinders shall be fitted with appropriate devices ensuring that they can be handled and carried safely; (d) If level gauges, pressure gauges or relief devices are installed, they shall be protected in the same way as is required for valves in 4.1.6.8. 6.2.3.4 Initial inspection and test 6.2.3.4.1 New pressure receptacles shall be subjected to testing and inspection during and after manufacture in accordance with the requirements of 6.2.1.5. 6.2.3.4.2 Specific provisions applying to aluminium alloy pressure receptacles (a) In addition to the initial inspection required by 6.2.1.5.1, it is necessary to test for possible intercrystalline corrosion of the inside wall of the pressure receptacles where use is made of an aluminium alloy containing copper, or where use is made of an aluminium alloy containing magnesium and manganese and the magnesium content is greater than 3.5% or the manganese content lower than 0.5%; (b) In the case of an aluminium/copper alloy the test shall be carried out by the manufacturer at the time of approval of a new alloy by the competent authority; it shall thereafter be repeated in the course of production, for each pour of the alloy; (c) In the case of an aluminium/magnesium alloy the test shall be carried out by the manufacturer at the time of approval of a new alloy and of the manufacturing process by the competent authority. The test shall be repeated whenever a change is made in the composition of the alloy or in the manufacturing process. - 320 - 6.2.3.5 Periodic inspection and test 6.2.3.5.1 Periodic inspection and test shall be in accordance with 6.2.1.6. NOTE: With the agreement of the competent authority of the country that issued the type approval, the hydraulic pressure test of each welded steel cylinder intended for the carriage of gases of UN No. 1965, hydrocarbon gas mixture liquefied, n.o.s., with a capacity below 6.5 l may be replaced by another test ensuring an equivalent level of safety. 6.2.3.5.2 Closed cryogenic receptacles shall be subject to periodic inspections and tests in accordance with the periodicity defined in packing instruction P203 (8) (b) of 4.1.4.1, in accordance with the following: (a) Check of the external condition of the receptacle and verification of the equipment and the external markings; (b) The leakproofness test. 6.2.3.6 Approval of pressure receptacles 6.2.3.6.1 The procedures for conformity assessment and periodic inspection of section 1.8.7 shall be performed by the relevant body according to the following table. Procedure Relevant body Type approval (1.8.7.2) Xa Supervision of manufacture (1.8.7.3) Xa or IS Initial inspection and tests (1.8.7.4) Xa or IS Periodic inspection (1.8.7.5) Xa or Xb or IS For refillable pressure receptacles, the conformity assessment of valves and other demountable accessories having a direct safety function may be carried out separately from the receptacles and the conformity assessment procedure shall be at least as stringent as that undergone by the pressure receptacle to which they are fitted. Xa means the competent authority, its delegate or inspection body conforming to 1.8.6.2, 1.8.6.4, 1.8.6.5 and 1.8.6.8 and accredited according to EN ISO/IEC 17020:2012 (except clause 8.1.3) type A. Xb means inspection body conforming to 1.8.6.2, 1.8.6.4, 1.8.6.5 and 1.8.6.8 and accredited according to EN ISO/IEC 17020:2012 (except clause 8.1.3) type B. IS means an in-house inspection service of the applicant under the surveillance of an inspection body conforming to 1.8.6.2, 1.8.6.4, 1.8.6.5 and 1.8.6.8 and accredited according to EN ISO/IEC 17020:2012 (except clause 8.1.3) type A. The in-house inspection service shall be independent from design process, manufacturing operations, repair and maintenance. 6.2.3.6.2 If the country of approval is not a Contracting Party to ADR, the competent authority mentioned in 6.2.1.7.2 shall be the competent authority of a Contracting Party to ADR. 6.2.3.7 Requirements for manufacturers 6.2.3.7.1 The relevant requirements of 1.8.7 shall be met. 6.2.3.8 Requirements for inspection bodies The requirements of 1.8.6 shall be met. 6.2.3.9 Marking of refillable pressure receptacles 6.2.3.9.1 Markings shall be in accordance with sub-section 6.2.2.7 with the following variations. - 321 - 6.2.3.9.2 The United Nations packaging symbol specified in 6.2.2.7.2 (a) shall not be applied. 6.2.3.9.3 The requirements of 6.2.2.7.3 (j) shall be replaced by the following: (j) The water capacity of the pressure receptacle in litres followed by the letter "L". In the case of pressure receptacles for liquefied gases the water capacity in litres shall be expressed to three significant figures rounded down to the last digit. If the value of the minimum or nominal water capacity is an integer, the figures after the decimal point may be neglected. 6.2.3.9.4 The marks specified in 6.2.2.7.3 (g) and (h) and 6.2.2.7.4 (m) are not required for pressure receptacles for UN No. 1965 hydrocarbon gas mixture, liquefied, n.o.s. 6.2.3.9.5 When marking the date required by 6.2.2.7.7 (c), the month need not be indicated for gases for which the interval between periodic inspections is 10 years or more (see packing instructions P200 and P203 of 4.1.4.1). 6.2.3.9.6 The marks in accordance with 6.2.2.7.7 may be engraved on a ring of an appropriate material affixed to the cylinder when the valve is installed and which is removable only by disconnecting the valve from the cylinder. 6.2.3.9.7 Marking of bundles of cylinders 6.2.3.9.7.1 Individual cylinders in a bundle of cylinders shall be marked in accordance with 6.2.3.9.1 to 6.2.3.9.6. 6.2.3.9.7.2 Marking of bundles of cylinders shall be in accordance with 6.2.2.10.2 and 6.2.2.10.3, except that the United Nations packaging symbol specified in 6.2.2.7.2 (a) shall not be applied. 6.2.3.9.7.3 In addition to the preceding marks, each bundle of cylinders that meets the periodic inspection and test requirements of 6.2.4.2 shall be marked indicating: (a) The character(s) identifying the country authorizing the body performing the periodic inspection and test, as indicated by the distinguishing sign of motor vehicles in international traffic3. This marking is not required if this body is approved by the competent authority of the country approving manufacture; (b) The registered mark of the body authorised by the competent authority for performing periodic inspection and test; (c) The date of the periodic inspection and test, the year (two digits) followed by the month (two digits) separated by a slash (i.e. "/"). Four digits may be used to indicate the year. The above marks shall appear consecutively in the sequence given either on the plate specified in 6.2.2.10.2 or on a separate plate permanently attached to the frame of the bundle of cylinders. 6.2.3.10 Marking of non-refillable pressure receptacles 6.2.3.10.1 Markings shall be in accordance with 6.2.2.8, except that the United Nations packaging symbol specified in 6.2.2.7.2 (a) shall not be applied. 6.2.3.11 Salvage pressure receptacles 6.2.3.11.1 To permit the safe handling and disposal of the pressure receptacles carried within the salvage pressure receptacle, the design may include equipment not otherwise used for cylinders or pressure drums such as flat heads, quick opening devices and openings in the cylindrical part. 3 Distinguishing signs for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 322 - 6.2.3.11.2 Instructions on the safe handling and use of the salvage pressure receptacle shall be clearly shown in the documentation for the application to the competent authority of the country of approval and shall form part of the approval certificate. In the approval certificate, the pressure receptacles authorized to be carried in a salvage pressure receptacle shall be indicated. A list of the materials of construction of all parts likely to be in contact with the dangerous goods shall also be included. 6.2.3.11.3 A copy of the approval certificate shall be delivered by the manufacturer to the owner of a salvage pressure receptacle. 6.2.3.11.4 The marking of salvage pressure receptacles according to 6.2.3 shall be determined by the competent authority of the country of approval taking into account suitable marking provisions of 6.2.3.9 as appropriate. The marking shall include the water capacity and test pressure of the salvage pressure receptacle. 6.2.4 Requirements for non-UN pressure receptacles designed, constructed and tested according to referenced standards NOTE: Persons or bodies identified in standards as having responsibilities in accordance with ADR shall meet the requirements of ADR. 6.2.4.1 Design, construction and initial inspection and test The standards referenced in the table below shall be applied for the issue of type approvals as indicated in column (4) to meet the requirements of Chapter 6.2 referred to in column (3). The requirements of Chapter 6.2 referred to in column (3) shall prevail in all cases. Column (5) gives the latest date when existing type approvals shall be withdrawn according to 1.8.7.2.4; if no date is shown the type approval remains valid until it expires. Since 1 January 2009 the use of the referenced standards has been mandatory. Exceptions are dealt with in 6.2.5. If more than one standard is referenced for the application of the same requirements, only one of them shall be applied, but in full unless otherwise specified in the table below. The scope of application of each standard is defined in the scope clause of the standard unless otherwise specified in the Table below. Reference Applicable subsections and paragraphs Title of document (1) (2) for design and construction Annex I, Parts 1 to 3 to Council directive on the approximation 84/525/EEC of the laws of the Member States relating to seamless steel gas cylinders, published in the Official Journal of the European Communities No. L300 of 19.11.1984 Annex I, Parts 1 to 3 to Council directive on the approximation 84/526/EEC of the laws of the Member States relating to seamless, unalloyed aluminium and aluminium alloy gas cylinders, published in the Official Journal of the European Communities No. L300 of 19.11.1984 Annex I, Parts 1 to 3 to Council directive on the approximation 84/527/EEC of the laws of the Member States relating to welded unalloyed steel gas cylinders, published in the Official Journal of the European Communities No. L300 of 19.11.1984 (3) Applicable for new type approvals or for renewals (4) 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until further notice - 323 - Latest date for withdrawal of existing type approvals (5) Reference Applicable for new type approvals or for renewals (3) (4) Between 1 July 6.2.3.1 and 6.2.3.4 2001 and 30 June 2007 Between 1 January 2007 and 6.2.3.1 and 6.2.3.4 31 December 2010 Applicable subsections and paragraphs Title of document (1) (2) EN 1442:1998 + AC:1999 Transportable refillable welded steel cylinders for liquefied petroleum gas (LPG) - Design and construction EN 1442:1998 + A2:2005 Transportable refillable welded steel cylinders for liquefied petroleum gas (LPG) - Design and construction EN 1442:2006 + A1:2008 Transportable refillable welded steel 6.2.3.1 and 6.2.3.4 cylinders for liquefied petroleum gas (LPG) - Design and construction EN 1800:1998 + AC:1999 Transportable gas cylinders - Acetylene cylinders - Basic requirements and 6.2.1.1.9 definitions EN 1800:2006 Transportable gas cylinders - Acetylene cylinders - Basic requirements, definitions and type testing Gas cylinders – Acetylene cylinders – Basic requirements and type testing EN ISO 3807:2013 NOTE: Fusible plugs shall not be fitted. EN 1964-1:1999 Transportable gas cylinders – Specifications for the design and construction of refillable transportable seamless steel gas cylinders of capacity from 0.5 litres up to 150 litres – Part 1: Cylinders made of seamless steel with a Rm value of less than 1 100 MPa EN 1975:1999 (except Transportable gas cylinders – Annex G) Specifications for the design and construction of refillable transportable seamless aluminium and aluminium alloy gas cylinders of capacity from 0.5 litres up to 150 litres EN 1975:1999 + A1:2003 Transportable gas cylinders – Specifications for the design and construction of refillable transportable seamless aluminium and aluminium alloy gas cylinders of capacity from 0.5 litres up to 150 litres EN ISO 7866:2012 Gas cylinders – Refillable seamless + AC:2014 aluminium alloy gas cylinders – Design, construction and testing (ISO 7866:2012) EN ISO 11120:1999 Gas cylinders – Refillable seamless steel tubes for compressed gas transport of water capacity between 150 litres and 3 000 litres – Design, construction and testing EN ISO 11120:1999 Gas cylinders – Refillable seamless + A1:2013 steel tubes for compressed gas transport of water capacity between 150 litres and 3 000 litres – Design, construction and testing 6.2.1.1.9 Between 1 July 2001 and 31 December 2010 Between 1 January 2009 and 31 December 2016 Until further notice 6.2.3.1 and 6.2.3.4 Until 31 December 2014 6.2.3.1 and 6.2.3.4 Until 30 June 2005 6.2.3.1 and 6.2.3.4 Between 1 January 2009 and 31 December 2016 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Between 1 July 2001 and 30 June 2015 - 324 - 31 December 2012 Until further notice 6.2.1.1.9 6.2.3.1 and 6.2.3.4 Latest date for withdrawal of existing type approvals (5) Until further notice 31 December 2015 for tubes marked with the letter "H" in accordance with 6.2.2.7.4 (p) Reference (1) EN 1964-3:2000 EN 12862:2000 EN 1251-2:2000 EN 12257:2002 EN 12807:2001 (except Annex A) EN 12807:2008 EN 1964-2:2001 EN ISO 9809-1:2010 EN ISO 9809-2:2010 EN ISO 9809-3:2010 EN 13293:2002 EN 13322-1:2003 Applicable subsections and paragraphs Title of document (2) Transportable gas cylinders – Specifications for the design and construction of refillable transportable seamless steel gas cylinders of capacity from 0.5 litre up to 150 litres – Part 3: Cylinders made of seamless stainless steel with an Rm value of less than 1 100 MPa Transportable gas cylindersSpecifications for the design and construction of refillable transportable welded aluminium alloy gas cylinders Cryogenic vessels – Transportable, vacuum insulated, of not more than 1 000 litres volume – Part 2: Design, fabrication, inspection and testing Transportable gas cylinders – Seamless, hoop wrapped composite cylinders Transportable refillable brazed steel cylinders for liquefied petroleum gas (LPG) – Design and construction Transportable refillable brazed steel cylinders for liquefied petroleum gas (LPG) – Design and construction Transportable gas cylinders – Specification for the design and construction of refillable transportable seamless steel gas cylinders of water capacities from 0.5 litre up to and including 150 litre – Part 2: Cylinders made of seamless steel with an Rm value of 1 100 MPa and above Gas cylinders — Refillable seamless steel gas cylinders — Design, construction and testing – Part 1: Quenched and tempered steel cylinders with tensile strength less than 1100 MPa (ISO 9809-1:2010) Gas cylinders — Refillable seamless steel gas cylinders — Design, construction and testing – Part 2: Quenched and tempered steel cylinders with tensile strength greater than or equal to 1100 MPa (ISO 9809-2:2010) Gas cylinders — Refillable seamless steel gas cylinders — Design, construction and testing – Part 3: Normalized steel cylinders (ISO 9809-3:2010) Transportable gas cylinders – Specification for the design and construction of refillable transportable seamless normalised carbon manganese steel gas cylinders of water capacity up to 0.5 litre for compressed, liquefied and dissolved gases and up to 1 litre for carbon dioxide Transportable gas cylinders – Refillable welded steel gas cylinders – Design and construction – Part 1: Welded steel (3) Applicable for new type approvals or for renewals (4) 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until further notice Until further notice Between 1 January 6.2.3.1 and 6.2.3.4 2005 and 31 December 2010 Latest date for withdrawal of existing type approvals (5) 6.2.3.1 and 6.2.3.4 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until 31 December 2014 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until 30 June 2007 - 325 - 31 December 2012 Reference (1) EN 13322-1:2003 + A1:2006 EN 13322-2:2003 EN 13322-2:2003 + A1:2006 EN 12245:2002 EN 12245:2009 +A1:2011 EN 12205:2001 EN 13110:2002 EN 13110:2012 EN 14427:2004 EN 14427:2004 + A1:2005 EN 14427:2013 EN 14208:2004 EN 14140:2003 Applicable subsections and paragraphs Title of document (2) Transportable gas cylinders – Refillable welded steel gas cylinders – Design and construction – Part 1: Welded steel Transportable gas cylinders – Refillable welded stainless steel gas cylinders – Design and construction – Part 2: Welded stainless steel Transportable gas cylinders – Refillable welded stainless steel gas cylinders – Design and construction – Part 2: Welded stainless steel Transportable gas cylinders – Fully wrapped composite cylinders Transportable gas cylinders – Fully wrapped composite cylinders Transportable gas cylinders – Non refillable metallic gas cylinders Transportable refillable welded aluminium cylinders for liquefied petroleum gas (LPG) – Design and construction Transportable refillable welded aluminium cylinders for liquefied petroleum gas (LPG) – Design and construction Transportable refillable fully wrapped composite cylinders for liquefied petroleum gases - Design and construction NOTE: This standard applies only to cylinders equipped with pressure relief valves. Transportable refillable fully wrapped composite cylinders for liquefied petroleum gases - Design and construction NOTE 1: This standard applies only to cylinders equipped with pressure relief valves. NOTE 2: In 5.2.9.2.1 and 5.2.9.3.1, both cylinders shall be subject to a burst test when they show damage equal to or worse than the rejection criteria. LPG Equipment and accessories – Transportable refillable fully wrapped composite cylinders for LPG – Design and construction Transportable gas cylinders – Specification for welded pressure drums up to 1000 litres capacity for the transport of gases – Design and construction Transportable refillable welded steel cylinders for Liquefied Petroleum Gas (LPG) – Alternative design and construction (3) Applicable for new type approvals or for renewals (4) 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until 30 June 2007 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 6.2.3.1 and 6.2.3.4 6.2.3.1 and 6.2.3.4 6.2.3.1 and 6.2.3.4 6.2.3.1 and 6.2.3.4 Until 31 December 2014 Until further notice Until further notice Until 31 December 2014 Until further notice 6.2.3.1 and 6.2.3.4 Between 1 January 2005 and 30 June 2007 6.2.3.1 and 6.2.3.4 Between 1 January 2007 and 31 December 2016 6.2.3.1 and 6.2.3.4 6.2.3.1 and 6.2.3.4 Until further notice Until further notice Between 1 January 2005 and 6.2.3.1 and 6.2.3.4 31 December 2010 - 326 - Latest date for withdrawal of existing type approvals (5) Reference (1) EN 14140:2003 + A1:2006 EN 13769:2003 EN 13769:2003 + A1:2005 EN ISO 10961:2012 EN 14638-1:2006 EN 14893:2006 + AC:2007 EN 14893:2014 EN 14638-3:2010 + AC:2012 for closures EN 849:1996 (except Annex A) EN 849:1996 + A2:2001 EN ISO 10297:2006 EN ISO 14245:2010 EN 13152:2001 Applicable subsections and paragraphs Title of document (2) LPG equipment and accessories – Transportable refillable welded steel cylinders for LPG – Alternative design and construction Transportable gas cylinders – Cylinder bundles – Design, manufacture, identification and testing Transportable gas cylinders – Cylinder bundles – Design, manufacture, identification and testing Gas cylinders – Cylinder bundles – Design, manufacture, testing and inspection Transportable gas cylinders – Refillable welded receptacles of a capacity not exceeding 150 litres – Part 1 Welded austenitic stainless steel cylinders made to a design justified by experimental methods LPG equipment and accessories – Transportable LPG welded steel pressure drums with a capacity between 150 and 1 000 litres LPG equipment and accessories – Transportable LPG welded steel pressure drums with a capacity between 150 and 1 000 litres Transportable gas cylinders — Refillable welded receptacles of a capacity not exceeding 150 litres — Part 3: Welded carbon steel cylinders made to a design justified by experimental methods Transportable gas cylinders – Cylinder valves – Specification and type testing Transportable gas cylinders – Cylinder valves – Specification and type testing Transportable gas cylinders – Cylinder valves – Specification and type testing Gas cylinders – Specifications and testing of LPG cylinder valves – Selfclosing (ISO 14245:2006) Specifications and testing of LPG – Cylinder valves – Self closing EN 13152:2001 + A1:2003 Specifications and testing of LPG – Cylinder valves – Self closing EN ISO 15995:2010 Gas cylinders – Specifications and testing of LPG cylinder valves – Manually operated (ISO 15995:2006) Specifications and testing of LPG – Cylinder valves – Manually operated EN 13153:2001 (3) Applicable for new type approvals or for renewals (4) 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until 30 June 2007 6.2.3.1 and 6.2.3.4 6.2.3.1 and 6.2.3.4 Latest date for withdrawal of existing type approvals (5) Until 31 December 2014 Until further notice 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Between 1 January 2009 and 31 December 2016 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.3 Until 30 June 2003 31 December 2014 6.2.3.1 and 6.2.3.3 Until 30 June 2003 31 December 2016 6.2.3.1 and 6.2.3.3 6.2.3.1 and 6.2.3.3 Until further notice Until further notice Between 1 January 2005 and 6.2.3.1 and 6.2.3.3 31 December 2010 Between 1 January 2009 and 6.2.3.1 and 6.2.3.3 31 December 2014 6.2.3.1 and 6.2.3.3 Until further notice Between 1 January 2005 and 6.2.3.1 and 6.2.3.3 31 December 2010 - 327 - Reference Title of document (1) EN 13153:2001 + A1:2003 (2) Specifications and testing of LPG – Cylinder valves – Manually operated EN ISO 13340:2001 Transportable gas cylinders – Cylinder valves for non-refillable cylinders – Specification and prototype testing Cryogenic vessels – Safety devices for protection against excessive pressure – Part 1: Safety valves for cryogenic service Cryogenic vessels – Valves for cryogenic service EN 13648-1:2008 EN 1626:2008 (except valve category B) 6.2.4.2 Applicable for new type approvals or for renewals (3) (4) Between 1 January 2009 and 6.2.3.1 and 6.2.3.3 31 December 2014 6.2.3.1 and 6.2.3.3 Until further notice Applicable subsections and paragraphs 6.2.3.1 and 6.2.3.4 Until further notice 6.2.3.1 and 6.2.3.4 Until further notice Latest date for withdrawal of existing type approvals (5) Periodic inspection and test The standards referenced in the table below shall be applied for the periodic inspection and test of pressure receptacles as indicated in column (3) to meet the requirements of 6.2.3.5 which shall prevail in all cases. The use of a referenced standard is mandatory. When a pressure receptacle is constructed in accordance with the provisions of 6.2.5 the procedure for periodic inspection if specified in the type approval shall be followed. If more than one standard is referenced for the application of the same requirements, only one of them shall be applied, but in full unless otherwise specified in the table below. The scope of application of each standard is defined in the scope clause of the standard unless otherwise specified in the Table below. Reference Title of document Applicable (1) (2) (3) for periodic inspection and test EN 1251-3:2000 Cryogenic vessels – Transportable, vacuum insulated, of not more than Until further notice 1 000 litres volume – Part 3: Operational requirements EN 1968:2002 + A1:2005 Transportable gas cylinders – Periodic inspection and testing of Until further notice (except Annex B) seamless steel gas cylinders EN 1802:2002 (except Transportable gas cylinders – Periodic inspection and testing of Until further notice Annex B) seamless aluminium alloy gas cylinders EN 12863:2002 + A1:2005 Transportable gas cylinders – Periodic inspection and maintenance of dissolved acetylene cylinders NOTE: In this standard "initial inspection" is to be understood as Until 31 December 2016 the "first periodic inspection" after final approval of a new acetylene cylinder. EN ISO 10462:2013 Gas cylinders – Acetylene cylinders – Periodic inspection and Mandatorily from maintenance (ISO 10462:2013) 1 January 2017 EN 1803:2002 (except Transportable gas cylinders – Periodic inspection and testing of welded Until further notice Annex B) steel gas cylinders EN ISO 11623:2002 (except Transportable gas cylinders – Periodic inspection and testing of Until further notice clause 4) composite gas cylinders Transportable gas cylinders – Inspection and maintenance of cylinder EN ISO 22434:2011 Until further notice valves (ISO 22434:2006) EN 14876:2007 Transportable gas cylinders – Periodic inspection and testing of welded Until further notice steel pressure drums EN 14912:2005 LPG equipment and accessories – Inspection and maintenance of LPG Until further notice cylinder valves at time of periodic inspection of cylinders - 328 - Reference (1) EN 1440:2008 + A1:2012 (except Annexes G and H) EN 15888: 2014 6.2.5 Title of document (2) LPG equipment and accessories – Periodic inspection of transportable refillable LPG cylinders Transportable gas cylinders - Cylinder bundles - Periodic inspection and testing Applicable (3) Until further notice Until further notice Requirements for non-UN pressure receptacles not designed, constructed and tested according to referenced standards To reflect scientific and technical progress or where no standard is referenced in 6.2.2 or 6.2.4, or to deal with specific aspects not addressed in a standard referenced in 6.2.2 or 6.2.4, the competent authority may recognize the use of a technical code providing the same level of safety. In the type approval the issuing body shall specify the procedure for periodic inspections if the standards referenced in 6.2.2 or 6.2.4 are not applicable or shall not be applied. The competent authority shall transmit to the secretariat of UNECE a list of the technical codes that it recognises. The list should include the following details: name and date of the code, purpose of the code and details of where it may be obtained. The secretariat shall make this information publicly available on its website. A standard which has been adopted for reference in a future edition of the ADR may be approved by the competent authority for use without notifying the secretariat of UNECE. The requirements of 6.2.1, 6.2.3 and the following requirements however shall be met. NOTE: For this section, the references to technical standards in 6.2.1 shall be considered as references to technical codes. 6.2.5.1 Materials The following provisions contain examples of materials that may be used to comply with the requirements for materials in 6.2.1.2: (a) Carbon steel for compressed, liquefied, refrigerated liquefied gases and dissolved gases as well as for substances not in Class 2 listed in Table 3 of packing instruction P200 of 4.1.4.1; (b) Alloy steel (special steels), nickel, nickel alloy (such as monel) for compressed, liquefied, refrigerated liquefied gases and dissolved gases as well as for substances not in Class 2 listed in Table 3 of packing instruction P200 of 4.1.4.1; (c) Copper for: (i) gases of classification codes 1A, 1O, 1F and 1TF, whose filling pressure referred to a temperature of 15 °C does not exceed 2 MPa (20 bar); (ii) gases of classification code 2A and also UN No. 1033 dimethyl ether; UN No. 1037 ethyl chloride; UN No. 1063 methyl chloride; UN No. 1079 sulphur dioxide; UN No. 1085 vinyl bromide; UN No. 1086 vinyl chloride; and UN No. 3300 ethylene oxide and carbon dioxide mixture with more than 87% ethylene oxide; (iii) gases of classification codes 3A, 3O and 3F; (d) Aluminium alloy: see special requirement "a" of packing instruction P200 (10) of 4.1.4.1; (e) Composite material for compressed, liquefied, refrigerated liquefied gases and dissolved gases; - 329 - 6.2.5.2 (f) Synthetic materials for refrigerated liquefied gases; and (g) Glass for the refrigerated liquefied gases of classification code 3A other than UN No. 2187 carbon dioxide, refrigerated, liquid or mixtures thereof, and gases of classification code 3O. Service equipment (Reserved) 6.2.5.3 Metal cylinders, tubes, pressure drums and bundles of cylinders At the test pressure, the stress in the metal at the most severely stressed point of the pressure receptacle shall not exceed 77% of the guaranteed minimum yield stress (Re). "Yield stress" means the stress at which a permanent elongation of 2 per thousand (i.e. 0.2%) or, for austenitic steels, 1% of the gauge length on the test-piece, has been produced. NOTE: In the case of sheet-metal the axis of the tensile test-piece shall be at right angles to the direction of rolling. The permanent elongation at fracture, shall be measured on a test-piece of circular cross-section in which the gauge length "l" is equal to five times the diameter "d" (l = 5d); if test pieces of rectangular cross-section are used, the gauge length "l" shall be calculated by the formula: l  5.65 Fo where F0 indicates the initial cross-sectional area of the test-piece. Pressure receptacles and their closures shall be made of suitable materials which shall be resistant to brittle fracture and to stress corrosion cracking between –20 °C and +50 °C. Welds shall be skilfully made and shall afford the fullest safety. 6.2.5.4 Additional provisions relating to aluminium-alloy pressure receptacles for compressed gases, liquefied gases, dissolved gases and non pressurized gases subject to special requirements (gas samples) as well as articles containing gas under pressure other than aerosol dispensers and small receptacles containing gas (gas cartridges) 6.2.5.4.1 The materials of aluminium-alloy pressure receptacles which are to be accepted shall satisfy the following requirements: Tensile strength, Rm, in MPa (= N/mm2) Yield stress, Re, in MPa (= N/mm2) (permanent set  = 0.2%) Permanent elongation at fracture (l = 5d) in per cent Bend test (diameter of former d = n  e, where e is the thickness of the test piece) Aluminium Association Series Number a A B C D 49 to 186 196 to 372 196 to 372 343 to 490 10 to 167 59 to 314 137 to 334 206 to 412 12 to 40 12 to 30 12 to 30 11 to 16 n=5(Rm  98) n=6(Rm > 98) n=6(Rm  325) n=7(Rm > 325) n=6(Rm  325) n=7(Rm > 325) n=7(Rm  392) n=8(Rm > 392) 1 000 5 000 6 000 2 000 a See "Aluminium Standards and Data", Fifth edition, January 1976, published by the Aluminium Association, 750 Third Avenue, New York. - 330 - The actual properties will depend on the composition of the alloy concerned and on the final treatment of the pressure receptacle, but whatever alloy is used the thickness of the pressure receptacle shall be calculated by one of the following formulae: e where e PMPa Pbar D Re = = = = = Pbar D PMPa D or e  20Re 2Re  PMPa  Pbar 1.3 1.3 minimum thickness of pressure receptacle wall, in mm test pressure, in MPa test pressure, in bar nominal external diameter of the pressure receptacle, in mm and guaranteed minimum proof stress with 0.2% proof stress, in MPa (= N/mm2) In addition, the value of the minimum guaranteed proof stress (Re) introduced into the formula is in no case to be greater than 0.85 times the guaranteed minimum tensile strength (Rm), whatever the type of alloy used. NOTE 1: The above characteristics are based on previous experience with the following materials used for pressure receptacles: Column A: Aluminium, unalloyed, 99.5% pure; Column B: Alloys of aluminium and magnesium; Column C: Alloys of aluminium, silicon and magnesium, such as ISO/R209-Al-Si-Mg (Aluminium Association 6351); Column D: Alloys of aluminium, copper and magnesium. NOTE 2: The permanent elongation at fracture is measured by means of test-pieces of circular cross-section in which the gauge length "l" is equal to five times the diameter "d" (l = 5d); if test-pieces of rectangular section are used the gauge length shall be calculated by the formula: l  5.65 Fo where Fo is the initial cross-section area of the test-piece. NOTE 3: (a) The bend test (see diagram) shall be carried out on specimens obtained by cutting into two equal parts of width 3e, but in no case less than 25 mm, an annular section of a cylinder. The specimens shall not be machined elsewhere than on the edges; (b) The bend test shall be carried out between a mandrel of diameter (d) and two circular supports separated by a distance of (d + 3e). During the test the inner faces shall be separated by a distance not greater than the diameter of the mandrel; (c) The specimen shall not exhibit cracks when it has been bent inwards around the mandrel until the inner faces are separated by a distance not greater than the diameter of the mandrel; (d) The ratio (n) between the diameter of the mandrel and the thickness of the specimen shall conform to the values given in the table. - 331 - Diagram of bend test d e d+ 3 e approx. 6.2.5.4.2 A lower minimum elongation value is acceptable on condition that an additional test approved by the competent authority of the country in which the pressure receptacles are made proves that safety of carriage is ensured to the same extent as in the case of pressure receptacles constructed to comply with the characteristics given in the table in 6.2.5.4.1 (see also EN 1975:1999 + A1:2003). 6.2.5.4.3 The wall thickness of the pressure receptacles at the thinnest point shall be the following: - where the diameter of the pressure receptacle is less than 50 mm: not less than 1.5 mm; - where the diameter of the pressure receptacle is from 50 to 150 mm: not less than 2 mm; and - where the diameter of the pressure receptacle is more than 150 mm: not less than 3 mm. 6.2.5.4.4 The ends of the pressure receptacles shall have a semicircular, elliptical or "basket-handle" section; they shall afford the same degree of safety as the body of the pressure receptacle. 6.2.5.5 Pressure receptacles in composite materials For composite cylinders, tubes, pressure drums and bundles of cylinders which make use of composite materials, the construction shall be such that a minimum burst ratio (burst pressure divided by test pressure) is: 6.2.5.6 - 1.67 for hoop wrapped pressure receptacles; - 2.00 for fully wrapped pressure receptacles. Closed cryogenic receptacles The following requirements apply to the construction of closed cryogenic receptacles for refrigerated liquefied gases: 6.2.5.6.1 If non-metallic materials are used, they shall resist brittle fracture at the lowest working temperature of the pressure receptacle and its fittings. 6.2.5.6.2 The pressure relief devices shall be so constructed as to work perfectly even at their lowest working temperature. Their reliability of functioning at that temperature shall be established and checked by testing each device or a sample of devices of the same type of construction. The vents and pressure relief devices of pressure receptacles shall be so designed as to prevent the liquid from splashing out. 6.2.5.6.3 - 332 - 6.2.6 General requirements for aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas 6.2.6.1 Design and construction 6.2.6.1.1 Aerosol dispensers (UN No.1950 aerosols) containing only a gas or a mixture of gases, and small receptacles containing gas (gas cartridges) (UN No. 2037), shall be made of metal. This requirement shall not apply to aerosols and small receptacles containing gas (gas cartridges) with a maximum capacity of 100 ml for UN No. 1011 butane. Other aerosol dispensers (UN No.1950 aerosols) shall be made of metal, synthetic material or glass. Receptacles made of metal and having an outside diameter of not less than 40 mm shall have a concave bottom. 6.2.6.1.2 The capacity of receptacles made of metal shall not exceed 1 000 ml; that of receptacles made of synthetic material or of glass shall not exceed 500 ml. 6.2.6.1.3 Each model of receptacles (aerosol dispensers or cartridges) shall, before being put into service, satisfy a hydraulic pressure test carried out in conformity with 6.2.6.2. 6.2.6.1.4 The release valves and dispersal devices of aerosol dispensers (UN No.1950 aerosols) and the valves of UN No. 2037 small receptacles containing gas (gas cartridges) shall ensure that the receptacles are so closed as to be leakproof and shall be protected against accidental opening. Valves and dispersal devices which close only by the action of the internal pressure are not to be accepted. 6.2.6.1.5 The internal pressure of aerosol dispensers at 50 °C shall exceed neither two-thirds of the test pressure nor 1.32 MPa (13.2 bar). They shall be so filled that at 50 °C the liquid phase does not exceed 95% of their capacity. Small receptacles containing gas (gas cartridges) shall meet the test pressure and filling requirements of P200 of 4.1.4.1. 6.2.6.2 Hydraulic pressure test 6.2.6.2.1 The internal pressure to be applied (test pressure) shall be 1.5 times the internal pressure at 50 °C, with a minimum pressure of 1 MPa (10 bar). 6.2.6.2.2 The hydraulic pressure tests shall be carried out on at least five empty receptacles of each model: 6.2.6.3 (a) until the prescribed test pressure is reached, by which time no leakage or visible permanent deformation shall have occurred; and (b) until leakage or bursting occurs; the dished end, if any, shall yield first and the receptacle shall not leak or burst until a pressure 1.2 times the test pressure has been reached or passed. Tightness (leakproofness) test Each filled aerosol dispenser or gas cartridge or fuel cell cartridge shall be subjected to a test in a hot water bath in accordance with 6.2.6.3.1 or an approved water bath alternative in accordance with 6.2.6.3.2. 6.2.6.3.1 Hot water bath test 6.2.6.3.1.1 The temperature of the water bath and the duration of the test shall be such that the internal pressure reaches that which would be reached at 55 °C (50 °C if the liquid phase does not exceed 95% of the capacity of the aerosol dispenser, gas cartridge or the fuel cell cartridge at 50 °C). If the contents are sensitive to heat or if the aerosol dispensers, gas cartridges or the fuel cell cartridges are made of plastics material which softens at this test temperature, the temperature of the bath shall be set at between 20 °C and 30 °C but, in addition, one aerosol dispenser, gas cartridge or the fuel cell cartridge in 2 000 shall be tested at the higher temperature. 6.2.6.3.1.2 No leakage or permanent deformation of an aerosol dispenser, gas cartridge or the fuel cell cartridge may occur, except that a plastic aerosol dispenser, gas cartridge or the fuel cell cartridge may be deformed through softening provided that it does not leak. - 333 - 6.2.6.3.2 Alternative methods With the approval of the competent authority alternative methods that provide an equivalent level of safety may be used provided that the requirements of 6.2.6.3.2.1 and, as appropriate, 6.2.6.3.2.2 or 6.2.6.3.2.3 are met. 6.2.6.3.2.1 Quality system Aerosol dispenser, gas cartridge or the fuel cell cartridge fillers and component manufacturers shall have a quality system. The quality system shall implement procedures to ensure that all aerosol dispensers, gas cartridges or the fuel cell cartridges that leak or that are deformed are rejected and not offered for transport. The quality system shall include: (a) A description of the organizational structure and responsibilities; (b) The relevant inspection and test, quality control, quality assurance, and process operation instructions that will be used; (c) Quality records, such as inspection reports, test data, calibration data and certificates; (d) Management reviews to ensure the effective operation of the quality system; (e) A process for control of documents and their revision; (f) A means for control of non-conforming aerosol dispensers, gas cartridges or the fuel cell cartridges; (g) Training programmes and qualification procedures for relevant personnel; and (h) Procedures to ensure that there is no damage to the final product. An initial audit and periodic audits shall be conducted to the satisfaction of the competent authority. These audits shall ensure the approved system is and remains adequate and efficient. Any proposed changes to the approved system shall be notified to the competent authority in advance. 6.2.6.3.2.2 Aerosol dispensers 6.2.6.3.2.2.1 Pressure and leak testing of aerosol dispensers before filling Each empty aerosol dispenser shall be subjected to a pressure equal to or in excess of the maximum expected in the filled aerosol dispensers at 55 °C (50 °C if the liquid phase does not exceed 95% of the capacity of the receptacle at 50 °C). This shall be at least two-thirds of the design pressure of the aerosol dispenser. If any aerosol dispenser shows evidence of leakage at a rate equal to or greater than 3.3 × 10-2 mbar.l.s-1 at the test pressure, distortion or other defect, it shall be rejected. 6.2.6.3.2.2.2 Testing of the aerosol dispensers after filling Prior to filling the filler shall ensure that the crimping equipment is set appropriately and the specified propellant is used. Each filled aerosol dispenser shall be weighed and leak tested. The leak detection equipment shall be sufficiently sensitive to detect at least a leak rate of 2.0 × 10-3 mbar.l.s-1 at 20 °C. Any filled aerosol dispenser that shows evidence of leakage, deformation or excessive mass shall be rejected. 6.2.6.3.2.3 Gas cartridges and fuel cell cartridges 6.2.6.3.2.3.1 Pressure testing of gas cartridges and fuel cell cartridges - 334 - Each gas cartridge or fuel cell cartridge shall be subjected to a test pressure equal to or in excess of the maximum expected in the filled receptacle at 55 °C (50 °C if the liquid phase does not exceed 95% of the capacity of the receptacle at 50 °C). This test pressure shall be that specified for the gas cartridge or fuel cell cartridge and shall not be less than two thirds the design pressure of the gas cartridge or fuel cell cartridge. If any gas cartridge or fuel cell cartridge shows evidence of leakage at a rate equal to or greater than 3.3 × 10-2 mbar.l.s-1 at the test pressure or distortion or any other defect, it shall be rejected. 6.2.6.3.2.3.2 Leak testing gas cartridges and fuel cell cartridges Prior to filling and sealing, the filler shall ensure that the closures (if any), and the associated sealing equipment are closed appropriately and the specified gas is used. Each filled gas cartridge or fuel cell cartridge shall be checked for the correct mass of gas and shall be leak tested. The leak detection equipment shall be sufficiently sensitive to detect at least a leak rate of 2.0 × 10-3 mbar.l.s-1 at 20 °C. Any gas cartridge or fuel cell cartridge that has gas masses not in conformity with the declared mass limits or shows evidence of leakage or deformation, shall be rejected. 6.2.6.3.3 With the approval of the competent authority, aerosols and receptacles, small, are not subject to 6.2.6.3.1 and 6.2.6.3.2, if they are required to be sterile but may be adversely affected by water bath testing, provided: (a) They contain a non-flammable gas and either (i) contain other substances that are constituent parts of pharmaceutical products for medical, veterinary or similar purposes; 6.2.6.4 (ii) contain other substances used in the production process for pharmaceutical products; or (iii) are used in medical, veterinary or similar applications; (b) An equivalent level of safety is achieved by the manufacturer's use of alternative methods for leak detection and pressure resistance, such as helium detection and water bathing a statistical sample of at least 1 in 2000 from each production batch; and (c) For pharmaceutical products according to (a) (i) and (iii) above, they are manufactured under the authority of a national health administration. If required by the competent authority, the principles of Good Manufacturing Practice (GMP) established by the World Health Organization (WHO)4 shall be followed. Reference to standards The requirements of this section are deemed to be met if the following standards are complied with: - for aerosol dispensers (UN No. 1950 aerosols): Annex to Council Directive 75/324/EEC5 as amended and applicable at the date of manufacture; - for UN No. 2037, small receptacles containing gas (gas cartridges) containing UN No. 1965, hydrocarbon gas mixture n.o.s, liquefied: EN 417:2012 Non-refillable metallic gas cartridges for liquefied petroleum gases, with or without a valve, for use with portable appliances Construction, inspection, testing and marking. 4 WHO Publication: "Quality assurance of pharmaceuticals. A compendium of guidelines and related materials. Volume 2: Good manufacturing practices and inspection". 5 Council Directive 75/324/EEC of 20 May 1975 on the approximation of the laws of the Member States relating to aerosol dispensers, published in the Official Journal of the European Communities No. L 147 of 9.06.1975. - 335 - CHAPTER 6.3 REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF PACKAGINGS FOR CLASS 6.2 INFECTIOUS SUBSTANCES OF CATEGORY A NOTE: The requirements of this Chapter don't apply to packagings used for the carriage of Class 6.2 substances according to packing instruction P621 of 4.1.4.1. 6.3.1 General 6.3.1.1 The requirements of this Chapter apply to packagings intended for the carriage of infectious substances of Category A. 6.3.2 Requirements for packagings 6.3.2.1 The requirements for packagings in this section are based on packagings, as specified in 6.1.4, currently used. In order to take into account progress in science and technology, there is no objection to the use of packagings having specifications different from those in this Chapter provided that they are equally effective, acceptable to the competent authority and able successfully to withstand the tests described in 6.3.5. Methods of testing other than those described in ADR are acceptable provided they are equivalent, and are recognized by the competent authority. 6.3.2.2 Packagings shall be manufactured and tested under a quality assurance programme which satisfies the competent authority in order to ensure that each packaging meets the requirements of this Chapter. NOTE: ISO 16106:2006 "Packaging – Transport packages for dangerous goods – Dangerous goods packagings, intermediate bulk containers (IBCs) and large packagings – Guidelines for the application of ISO 9001" provides acceptable guidance on procedures which may be followed. 6.3.2.3 Manufacturers and subsequent distributors of packagings shall provide information regarding procedures to be followed and a description of the types and dimensions of closures (including required gaskets) and any other components needed to ensure that packages as presented for carriage are capable of passing the applicable performance tests of this Chapter. 6.3.3 Code for designating types of packagings 6.3.3.1 The codes for designating types of packagings are set out in 6.1.2.7. 6.3.3.2 The letters "U" or "W" may follow the packaging code. The letter "U" signifies a special packaging conforming to the requirements of 6.3.5.1.6. The letter "W" signifies that the packaging, although, of the same type indicated by the code is manufactured to a specification different from that in 6.1.4 and is considered equivalent under the requirements of 6.3.2.1. 6.3.4 Marking NOTE 1: The marking indicates that the packaging which bears it corresponds to a successfully tested design type and that it complies with the requirements of this Chapter which are related to the manufacture, but not to the use, of the packaging. NOTE 2: The marking is intended to be of assistance to packaging manufacturers, reconditioners, packaging users, carriers and regulatory authorities. NOTE 3: The marking does not always provide full details of the test levels, etc., and these may need to be taken further into account, e.g. by reference to a test certificate, to test reports or to a register of successfully tested packagings. - 337 - 6.3.4.1 Each packaging intended for use according to ADR shall bear markings which are durable, legible and placed in a location and of such a size relative to the packaging as to be readily visible. For packages with a gross mass of more than 30 kg, the markings or a duplicate thereof shall appear on the top or on a side of the packaging. Letters, numerals and symbols shall be at least 12 mm high, except for packagings of 30 litres or 30 kg capacity or less, when they shall be at least 6 mm in height and for packagings of 5 litres or 5 kg or less when they shall be of an appropriate size. 6.3.4.2 A packaging that meets the requirements of this section and of 6.3.5 shall be marked with: (a) The United Nations packaging symbol ; This symbol shall not be used for any purpose other than certifying that a packaging, a portable tank or a MEGC complies with the relevant requirements in Chapter 6.1, 6.2, 6.3, 6.5, 6.6 or 6.71; 6.3.4.3 (b) The code designating the type of packaging according to the requirements of 6.1.2; (c) The text "CLASS 6.2"; (d) The last two digits of the year of manufacture of the packaging; (e) The state authorizing the allocation of the mark, indicated by the distinguishing sign for motor vehicles in international traffic2; (f) The name of the manufacturer or other identification of the packaging specified by the competent authority; (g) For packagings meeting the requirements of 6.3.5.1.6, the letter "U", inserted immediately following the marking required in (b) above. Marking shall be applied in the sequence shown in 6.3.4.2 (a) to (g); each element of the marking required in these sub-paragraphs shall be clearly separated, e.g. by a slash or space, so as to be easily identifiable. For examples, see 6.3.4.4. Any additional markings authorized by a competent authority shall still enable the parts of the mark to be correctly identified with reference to 6.3.4.1. 6.3.4.4 Example of marking 4G/CLASS 6.2/06 S/SP-9989-ERIKSSON as in 6.3.4.2 (a), (b), (c) and (d) as in 6.3.4.2 (e) and (f) 6.3.5 Test requirements for packagings 6.3.5.1 Performance and frequency of tests 6.3.5.1.1 The design type of each packaging shall be tested as provided in this section in accordance with procedures established by the competent authority allowing the allocation of the mark and shall be approved by this competent authority. 1 This symbol is also used to certify that flexible bulk containers authorized for other modes of transport comply with the requirements in Chapter 6.8 of the UN Model Regulations. 2 Distinguishing sign for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 338 - 6.3.5.1.2 Each packaging design type shall successfully pass the tests prescribed in this Chapter before being used. A packaging design type is defined by the design, size, material and thickness, manner of construction and packing, but may include various surface treatments. It also includes packagings which differ from the design type only in their lesser design height. 6.3.5.1.3 Tests shall be repeated on production samples at intervals established by the competent authority. 6.3.5.1.4 Tests shall also be repeated after each modification which alters the design, material or manner of construction of a packaging. 6.3.5.1.5 The competent authority may permit the selective testing of packagings that differ only in minor respects from a tested type, e.g. smaller sizes or lower net mass of primary receptacles; and packagings such as drums and boxes which are produced with small reductions in external dimension(s). 6.3.5.1.6 Primary receptacles of any type may be assembled within a secondary packaging and carried without testing in the rigid outer packaging under the following conditions: (a) The rigid outer packaging shall have been successfully tested in accordance with 6.3.5.2.2 with fragile (e.g. glass) primary receptacles; (b) The total combined gross mass of primary receptacles shall not exceed one half the gross mass of primary receptacles used for the drop test in (a) above; (c) The thickness of cushioning between primary receptacles and between primary receptacles and the outside of the secondary packaging shall not be reduced below the corresponding thicknesses in the originally tested packaging; and if a single primary receptacle was used in the original test, the thickness of cushioning between primary receptacles shall not be less than the thickness of cushioning between the outside of the secondary packaging and the primary receptacle in the original test. When either fewer or smaller primary receptacles are used (as compared to the primary receptacles used in the drop test), sufficient additional cushioning material shall be used to take up the void spaces; (d) The rigid outer packaging shall have successfully passed the stacking test in 6.1.5.6 while empty. The total mass of identical packages shall be based on the combined mass of packagings used in the drop test in (a) above; (e) For primary receptacles containing liquids, an adequate quantity of absorbent material to absorb the entire liquid content of the primary receptacles shall be present; (f) If the rigid outer packaging is intended to contain primary receptacles for liquids and is not leakproof, or is intended to contain primary receptacles for solids and is not siftproof, a means of containing any liquid or solid contents in the event of leakage shall be provided in the form of a leakproof liner, plastics bag or other equally effective means of containment; (g) In addition to the markings prescribed in 6.3.4.2 (a) to (f), packagings shall be marked in accordance with 6.3.4.2 (g). 6.3.5.1.7 The competent authority may at any time require proof, by tests in accordance with this section, that serially-produced packagings meet the requirements of the design type tests. 6.3.5.1.8 Provided the validity of the test results is not affected and with the approval of the competent authority, several tests may be made on one sample. 6.3.5.2 Preparation of packagings for testing 6.3.5.2.1 Samples of each packaging shall be prepared as for carriage, except that a liquid or solid infectious substance shall be replaced by water or, where conditioning at –18 °C is specified, by water/antifreeze. Each primary receptacle shall be filled to not less than 98% of its capacity. NOTE: The term water includes water/antifreeze solution with a minimum specific gravity of 0.95 for testing at – 18 °C. - 339 - 6.3.5.2.2 Tests and number of samples required Tests required for packaging types Type of packaging a Rigid outer Primary Water packaging receptacle spray Plastics Other 6.3.5.3.6.1 Fibreboard box x Fibreboard drum x x x x Plastics box Cold conditioning 6.3.5.3.6.2 No. of samples 5 5 3 3 0 0 0 No. of samples 5 0 3 0 5 5 3 Tests required Drop Additional 6.3.5.3 drop 6.3.5.3.6.3 Puncture 6.3.5.4 Stack 6.1.5.6 No. of samples 10 5 6 3 5 5 3 No. of samples 2 2 2 2 2 2 2 No. of samples No. of samples Required on one sample when the packaging is intended to contain dry ice. Required on three samples when testing a "U"-marked packaging as defined in 6.3.5.1.6 for specific provisions. x Plastics x drum/ x 0 3 3 2 jerrican Boxes of x 0 5 5 2 other x 0 0 5 2 material Drums/ x 0 3 3 2 jerricans of other x 0 0 3 2 material a "Type of packaging" categorizes packagings for test purposes according to the kind of packaging and its material characteristics. NOTE 1: In instances where a primary receptacle is made of two or more materials, the material most liable to damage determines the appropriate test. NOTE 2: The material of the secondary packagings are not taken into consideration when selecting the test or conditioning for the test. Explanation for use of the table: If the packaging to be tested consists of a fibreboard outer box with a plastics primary receptacle, five samples must undergo the water spray test (see 6.3.5.3.6.1) prior to dropping and another five must be conditioned to – 18 °C (see 6.3.5.3.6.2) prior to dropping. If the packaging is to contain dry ice then one further single sample shall be dropped five times after conditioning in accordance with 6.3.5.3.6.3. Packagings prepared as for carriage shall be subjected to the tests in 6.3.5.3 and 6.3.5.4. For outer packagings, the headings in the table relate to fibreboard or similar materials whose performance may be rapidly affected by moisture; plastics which may embrittle at low temperature; and other materials such as metal whose performance is not affected by moisture or temperature. 6.3.5.3 Drop test 6.3.5.3.1 Samples shall be subjected to free-fall drops from a height of 9 m onto a non-resilient, horizontal, flat, massive and rigid surface in conformity with 6.1.5.3.4. 6.3.5.3.2 Where the samples are in the shape of a box, five shall be dropped one in each of the following orientations: (a) flat on the base; (b) flat on the top; (c) flat on the longest side; - 340 - 6.3.5.3.3 (d) flat on the shortest side; (e) on a corner. Where the samples are in the shape of a drum, three shall be dropped one in each of the following orientations: (a) diagonally on the top chime, with the centre of gravity directly above the point of impact; (b) diagonally on the base chime; (c) flat on the side. 6.3.5.3.4 While the sample shall be released in the required orientation, it is accepted that for aerodynamic reasons the impact may not take place in that orientation. 6.3.5.3.5 Following the appropriate drop sequence, there shall be no leakage from the primary receptacle(s) which shall remain protected by cushioning/absorbent material in the secondary packaging. 6.3.5.3.6 Special preparation of test sample for the drop test 6.3.5.3.6.1 Fibreboard - Water spray test Fibreboard outer packagings: The sample shall be subjected to a water spray that simulates exposure to rainfall of approximately 5 cm per hour for at least one hour. It shall then be subjected to the test described in 6.3.5.3.1. 6.3.5.3.6.2 Plastics material – Cold conditioning Plastics primary receptacles or outer packagings: The temperature of the test sample and its contents shall be reduced to – 18 °C or lower for a period of at least 24 hours and within 15 minutes of removal from that atmosphere the test sample shall be subjected to the test described in 6.3.5.3.1. Where the sample contains dry ice, the conditioning period shall be reduced to 4 hours. 6.3.5.3.6.3 Packagings intended to contain dry ice – Additional drop test Where the packaging is intended to contain dry ice, a test additional to that specified in 6.3.5.3.1 and, when appropriate, in 6.3.5.3.6.1 or 6.3.5.3.6.2 shall be carried out. One sample shall be stored so that all the dry ice dissipates and then that sample shall be dropped in one of the orientations described in 6.3.5.3.2 which shall be that most likely to result in failure of the packaging. 6.3.5.4 Puncture test 6.3.5.4.1 Packagings with a gross mass of 7 kg or less Samples shall be placed on a level hard surface. A cylindrical steel rod with a mass of at least 7 kg, a diameter of 38 mm and whose impact end edges have a radius not exceeding 6 mm (see Figure 6.3.5.4.2), shall be dropped in a vertical free fall from a height of 1 m, measured from the impact end to the impact surface of the sample. One sample shall be placed on its base. A second sample shall be placed in an orientation perpendicular to that used for the first. In each instance the steel rod shall be aimed to impact the primary receptacle. Following each impact, penetration of the secondary packaging is acceptable, provided that there is no leakage from the primary receptacle(s). - 341 - 6.3.5.4.2 Packagings with a gross mass exceeding 7 kg Samples shall be dropped on to the end of a cylindrical steel rod. The rod shall be set vertically in a level hard surface. It shall have a diameter of 38 mm and the edges of the upper end a radius not exceeding 6 mm (see Figure 6.3.5.4.2). The rod shall protrude from the surface a distance at least equal to that between the centre of the primary receptacle(s) and the outer surface of the outer packaging with a minimum of 200 mm. One sample shall be dropped with its top face lowermost in a vertical free fall from a height of 1 m, measured from the top of the steel rod. A second sample shall be dropped from the same height in an orientation perpendicular to that used for the first. In each instance, the packaging shall be so orientated that the steel rod would be capable of penetrating the primary receptacle(s). Following each impact, penetration of the secondary packaging is acceptable provided that there is no leakage from the primary receptacle(s). Figure 6.3.5.4.2 Radius  6mm Dimensions In millimetres 6.3.5.5 Test report 6.3.5.5.1 A written test report containing at least the following particulars shall be drawn up and shall be available to the users of the packaging: 6.3.5.5.2 1. Name and address of the test facility; 2. Name and address of applicant (where appropriate); 3. A unique test report identification; 4. Date of the test and of the report; 5. Manufacturer of the packaging; 6. Description of the packaging design type (e.g. dimensions, materials, closures, thickness, etc.), including method of manufacture (e.g. blow moulding) and which may include drawing(s) and/or photograph(s); 7. Maximum capacity; 8. Test contents; 9. Test descriptions and results; 10. The test report shall be signed with the name and status of the signatory. The test report shall contain statements that the packaging prepared as for carriage was tested in accordance with the appropriate requirements of this Chapter and that the use of other packaging methods or components may render it invalid. A copy of the test report shall be available to the competent authority. - 342 - CHAPTER 6.4 REQUIREMENTS FOR THE CONSTRUCTION, TESTING AND APPROVAL OF PACKAGES FOR RADIOACTIVE MATERIAL AND FOR THE APPROVAL OF SUCH MATERIAL 6.4.1 (Reserved) 6.4.2 General requirements 6.4.2.1 The package shall be so designed in relation to its mass, volume and shape that it can be easily and safely carried. In addition, the package shall be so designed that it can be properly secured in or on the vehicle during carriage. 6.4.2.2 The design shall be such that any lifting attachments on the package will not fail when used in the intended manner and that, if failure of the attachments should occur, the ability of the package to meet other requirements of this Annex would not be impaired. The design shall take account of appropriate safety factors to cover snatch lifting. 6.4.2.3 Attachments and any other features on the outer surface of the package which could be used to lift it shall be designed either to support its mass in accordance with the requirements of 6.4.2.2 or shall be removable or otherwise rendered incapable of being used during carriage. 6.4.2.4 As far as practicable, the packaging shall be so designed and finished that the external surfaces are free from protruding features and can be easily decontaminated. 6.4.2.5 As far as practicable, the outer layer of the package shall be so designed as to prevent the collection and the retention of water. 6.4.2.6 Any features added to the package at the time of carriage which are not part of the package shall not reduce its safety. 6.4.2.7 The package shall be capable of withstanding the effects of any acceleration, vibration or vibration resonance which may arise under routine conditions of carriage without any deterioration in the effectiveness of the closing devices on the various receptacles or in the integrity of the package as a whole. In particular, nuts, bolts and other securing devices shall be so designed as to prevent them from becoming loose or being released unintentionally, even after repeated use. 6.4.2.8 The materials of the packaging and any components or structures shall be physically and chemically compatible with each other and with the radioactive contents. Account shall be taken of their behaviour under irradiation. 6.4.2.9 All valves through which the radioactive contents could escape shall be protected against unauthorized operation. 6.4.2.10 The design of the package shall take into account ambient temperatures and pressures that are likely to be encountered in routine conditions of carriage. 6.4.2.11 A package shall be so designed that it provides sufficient shielding to ensure that, under routine conditions of carriage and with the maximum radioactive contents that the package is designed to contain, the radiation level at any point on the external surface of the package would not exceed the values specified in 2.2.7.2.4.1.2, 4.1.9.1.10 and 4.1.9.1.11, as applicable, with account taken of 7.5.11 CV33 (3.3) (b) and (3.5). 6.4.2.12 For radioactive material having other dangerous properties the package design shall take into account those properties; see 2.1.3.5.3 and 4.1.9.1.5. - 343 - 6.4.2.13 Manufacturers and subsequent distributors of packagings shall provide information regarding procedures to be followed and a description of the types and dimensions of closures (including required gaskets) and any other components needed to ensure that packages as presented for carriage are capable of passing the applicable performance tests of this Chapter. 6.4.3 (Reserved) 6.4.4 Requirements for excepted packages An excepted package shall be designed to meet the requirements specified in 6.4.2. 6.4.5 Requirements for Industrial packages 6.4.5.1 Types IP-1, IP-2, and IP-3 packages shall meet the requirements specified in 6.4.2 and 6.4.7.2. 6.4.5.2 A Type IP-2 package shall, if it were subjected to the tests specified in 6.4.15.4 and 6.4.15.5, prevent: (a) Loss or dispersal of the radioactive contents; and (b) More than a 20% increase in the maximum radiation level at any external surface of the package. 6.4.5.3 A Type IP-3 package shall meet all the requirements specified in 6.4.7.2 to 6.4.7.15. 6.4.5.4 Alternative requirements for Types IP-2 and IP-3 packages 6.4.5.4.1 Packages may be used as Type IP-2 package provided that: 6.4.5.4.2 6.4.5.4.3 (a) They satisfy the requirements of 6.4.5.1; (b) They are designed to satisfy the requirements prescribed for packing group I or II in Chapter 6.1; and (c) When subjected to the tests required for packing groups I or II in Chapter 6.1, they would prevent: (i) Loss or dispersal of the radioactive contents; and (ii) More than a 20% increase in the maximum radiation level at any external surface of the package. Portable tanks may also be used as Types IP-2 or IP-3 packages, provided that: (a) They satisfy the requirements of 6.4.5.1; (b) They are designed to satisfy the requirements prescribed in Chapter 6.7 and are capable of withstanding a test pressure of 265 kPa; and (c) They are designed so that any additional shielding which is provided shall be capable of withstanding the static and dynamic stresses resulting from handling and routine conditions of carriage and of preventing more than a 20% increase in the maximum radiation level at any external surface of the portable tanks. Tanks, other than portable tanks, may also be used as Types IP-2 or IP-3 packages for carrying LSA-I and LSA-II liquids and gases as prescribed in Table 4.1.9.2.5, provided that: (a) They satisfy the requirements of 6.4.5.1; (b) They are designed to satisfy the requirements prescribed in Chapter 6.8; and - 344 - (c) 6.4.5.4.4 6.4.5.4.5 They are designed so that any additional shielding which is provided shall be capable of withstanding the static and dynamic stresses resulting from handling and routine conditions of carriage and of preventing more than a 20% increase in the maximum radiation level at any external surface of the tanks. Containers with the characteristics of a permanent enclosure may also be used as Types IP-2 or IP-3 packages, provided that: (a) The radioactive contents are restricted to solid materials; (b) They satisfy the requirements of 6.4.5.1; and (c) They are designed to conform to ISO 1496-1:1990: "Series 1 Containers - Specifications and Testing - Part 1: General Cargo Containers" and subsequent amendments 1:1993, 2:1998, 3:2005, 4:2006 and 5:2006, excluding dimensions and ratings. They shall be designed such that if subjected to the tests prescribed in that document and the accelerations occurring during routine conditions of carriage they would prevent: (i) loss or dispersal of the radioactive contents; and (ii) more than a 20% increase in the maximum radiation level at any external surface of the containers. Metal intermediate bulk containers may also be used as Types IP-2 or IP-3 packages provided that: (a) They satisfy the requirements of 6.4.5.1; and (b) They are designed to satisfy the requirements prescribed in Chapter 6.5 for packing group I or II, and if they were subjected to the tests prescribed in that Chapter, but with the drop test conducted in the most damaging orientation, they would prevent: (i) loss or dispersal of the radioactive contents; and (ii) more than a 20% increase in the maximum radiation level at any external surface of the intermediate bulk container. 6.4.6 Requirements for packages containing uranium hexafluoride 6.4.6.1 Packages designed to contain uranium hexafluoride shall meet the requirements which pertain to the radioactive and fissile properties of the material prescribed elsewhere in ADR. Except as allowed in 6.4.6.4, uranium hexafluoride in quantities of 0.1 kg or more shall also be packaged and carried in accordance with the provisions of ISO 7195:2005 "Nuclear Energy – Packaging of uranium hexafluoride (UF6) for transport", and the requirements of 6.4.6.2 and 6.4.6.3. 6.4.6.2 Each package designed to contain 0.1 kg or more of uranium hexafluoride shall be designed so that it would meet the following requirements: (a) Withstand without leakage and without unacceptable stress, as specified in ISO 7195:2005, the structural test as specified in 6.4.21.5 except as allowed in 6.4.6.4; (b) Withstand without loss or dispersal of the uranium hexafluoride the free drop test specified in 6.4.15.4; and (c) Withstand without rupture of the containment system the thermal test specified in 6.4.17.3 except as allowed in 6.4.6.4. 6.4.6.3 Packages designed to contain 0.1 kg or more of uranium hexafluoride shall not be provided with pressure relief devices. 6.4.6.4 Subject to multilateral approval, packages designed to contain 0.1 kg or more of uranium hexafluoride may be carried if the packages are designed: (a) to international or national standards other than ISO 7195:2005 provided an equivalent level of safety is maintained; and/or - 345 - (b) to withstand without leakage and without unacceptable stress a test pressure of less than 2.76 MPa as specified in 6.4.21.5; and/or (c) to contain 9 000 kg or more of uranium hexafluoride and the packages do not meet the requirement of 6.4.6.2 (c). In all other respects the requirements specified in 6.4.6.1 to 6.4.6.3 shall be satisfied. 6.4.7 Requirements for Type A packages 6.4.7.1 Type A packages shall be designed to meet the general requirements of 6.4.2 and of 6.4.7.2 to 6.4.7.17. 6.4.7.2 The smallest overall external dimension of the package shall not be less than 10 cm. 6.4.7.3 The outside of the package shall incorporate a feature such as a seal, which is not readily breakable and which, while intact, will be evidence that it has not been opened. 6.4.7.4 Any tie-down attachments on the package shall be so designed that, under normal and accident conditions of carriage, the forces in those attachments shall not impair the ability of the package to meet the requirements of ADR. 6.4.7.5 The design of the package shall take into account temperatures ranging from -40C to +70C for the components of the packaging. Attention shall be given to freezing temperatures for liquids and to the potential degradation of packaging materials within the given temperature range. 6.4.7.6 The design and manufacturing techniques shall be in accordance with national or international standards, or other requirements, acceptable to the competent authority. 6.4.7.7 The design shall include a containment system securely closed by a positive fastening device which cannot be opened unintentionally or by a pressure which may arise within the package. 6.4.7.8 Special form radioactive material may be considered as a component of the containment system. 6.4.7.9 If the containment system forms a separate unit of the package, it shall be capable of being securely closed by a positive fastening device which is independent of any other part of the packaging. 6.4.7.10 The design of any component of the containment system shall take into account, where applicable, the radiolytic decomposition of liquids and other vulnerable materials and the generation of gas by chemical reaction and radiolysis. 6.4.7.11 The containment system shall retain its radioactive contents under a reduction of ambient pressure to 60 kPa. 6.4.7.12 All valves, other than pressure relief valves, shall be provided with an enclosure to retain any leakage from the valve. 6.4.7.13 A radiation shield which encloses a component of the package specified as a part of the containment system shall be so designed as to prevent the unintentional release of that component from the shield. Where the radiation shield and such component within it form a separate unit, the radiation shield shall be capable of being securely closed by a positive fastening device which is independent of any other packaging structure. 6.4.7.14 A package shall be so designed that if it were subjected to the tests specified in 6.4.15, it would prevent: (a) Loss or dispersal of the radioactive contents; and (b) More than a 20% increase in the maximum radiation level at any external surface of the package. - 346 - 6.4.7.15 The design of a package intended for liquid radioactive material shall make provision for ullage to accommodate variations in the temperature of the contents, dynamic effects and filling dynamics. Type A packages to contain liquids 6.4.7.16 A Type A package designed to contain liquid radioactive material shall, in addition: (a) Be adequate to meet the conditions specified in 6.4.7.14 (a) above if the package is subjected to the tests specified in 6.4.16; and (b) Either (i) be provided with sufficient absorbent material to absorb twice the volume of the liquid contents. Such absorbent material shall be suitably positioned so as to contact the liquid in the event of leakage; or (ii) be provided with a containment system composed of primary inner and secondary outer containment components designed to enclose the liquid contents completely and ensure their retention, within the secondary outer containment components, even if the primary inner components leak. Type A packages to contain gas 6.4.7.17 A package designed for gases shall prevent loss or dispersal of the radioactive contents if the package were subjected to the tests specified in 6.4.16. A Type A package designed for tritium gas or for noble gases shall be excepted from this requirement. 6.4.8 Requirements for Type B(U) packages 6.4.8.1 Type B(U) packages shall be designed to meet the requirements specified in 6.4.2, and of 6.4.7.2 to 6.4.7.15, except as specified in 6.4.7.14 (a), and, in addition, the requirements specified in 6.4.8.2 to 6.4.8.15. 6.4.8.2 A package shall be so designed that, under the ambient conditions specified in 6.4.8.5 and 6.4.8.6 heat generated within the package by the radioactive contents shall not, under normal conditions of carriage, as demonstrated by the tests in 6.4.15, adversely affect the package in such a way that it would fail to meet the applicable requirements for containment and shielding if left unattended for a period of one week. Particular attention shall be paid to the effects of heat, which may cause one or more of the following: (a) Alter the arrangement, the geometrical form or the physical state of the radioactive contents or, if the radioactive material is enclosed in a can or receptacle (for example, clad fuel elements), cause the can, receptacle or radioactive material to deform or melt; (b) Lessen the efficiency of the packaging through differential thermal expansion or cracking or melting of the radiation shielding material; (c) In combination with moisture, accelerate corrosion. 6.4.8.3 A package shall be so designed that, under the ambient condition specified in 6.4.8.5 and in the absence of insolation, the temperature of the accessible surfaces of a package shall not exceed 50 °C, unless the package is carried under exclusive use. 6.4.8.4 The maximum temperature of any surface readily accessible during carriage of a package under exclusive use shall not exceed 85 C in the absence of insolation under the ambient conditions specified in 6.4.8.5. Account may be taken of barriers or screens intended to give protection to persons without the need for the barriers or screens being subject to any test. 6.4.8.5 The ambient temperature shall be assumed to be 38 C. 6.4.8.6 The solar insolation conditions shall be assumed to be as specified in Table 6.4.8.6. - 347 - Table 6.4.8.6: Insolation data Case Form and location of surface 1 2 3 4 5 Flat surfaces carried horizontally-downward facing Flat surfaces carried horizontally-upward facing Surfaces carried vertically Other downward facing (not horizontal) surfaces All other surfaces Insolation for 12 hours per day (W/m2) 0 800 200a 200a 400a a Alternatively, a sine function may be used, with an absorption coefficient adopted and the effects of possible reflection from neighbouring objects neglected. 6.4.8.7 A package which includes thermal protection for the purpose of satisfying the requirements of the thermal test specified in 6.4.17.3 shall be so designed that such protection will remain effective if the package is subjected to the tests specified in 6.4.15 and 6.4.17.2 (a) and (b) or 6.4.17.2 (b) and (c), as appropriate. Any such protection on the exterior of the package shall not be rendered ineffective by ripping, cutting, skidding, abrasion or rough handling. 6.4.8.8 A package shall be so designed that, if it were subjected to: (a) The tests specified in 6.4.15, it would restrict the loss of radioactive contents to not more than 10-6 A2 per hour; and (b) The tests specified in 6.4.17.1, 6.4.17.2 (b), 6.4.17.3, and 6.4.17.4 and either the test in (i) 6.4.17.2 (c), when the package has a mass not greater than 500 kg, an overall density not greater than 1 000 kg/m3 based on the external dimensions, and radioactive contents greater than 1 000 A2 not as special form radioactive material, or (ii) 6.4.17.2 (a), for all other packages, it would meet the following requirements: - retain sufficient shielding to ensure that the radiation level at 1 m from the surface of the package would not exceed 10 mSv/h with the maximum radioactive contents which the package is designed to contain; and - restrict the accumulated loss of radioactive contents in a period of one week to not more than 10 A2 for krypton-85 and not more than A2 for all other radionuclides. Where mixtures of different radionuclides are present, the provisions of 2.2.7.2.2.4 to 2.2.7.2.2.6 shall apply except that for krypton-85 an effective A2(i) value equal to 10 A2 may be used. For case (a) above, the assessment shall take into account the external contamination limits of 4.1.9.1.2. 6.4.8.9 A package for radioactive contents with activity greater than 105 A2 shall be so designed that if it were subjected to the enhanced water immersion test specified in 6.4.18, there would be no rupture of the containment system. 6.4.8.10 Compliance with the permitted activity release limits shall depend neither upon filters nor upon a mechanical cooling system. 6.4.8.11 A package shall not include a pressure relief system from the containment system which would allow the release of radioactive material to the environment under the conditions of the tests specified in 6.4.15 and 6.4.17. 6.4.8.12 A package shall be so designed that if it were at the maximum normal operating pressure and it were subjected to the tests specified in 6.4.15 and 6.4.17, the level of strains in the containment system would not attain values which would adversely affect the package in such a way that it would fail to meet the applicable requirements. - 348 - 6.4.8.13 A package shall not have a maximum normal operating pressure in excess of a gauge pressure of 700 kPa. 6.4.8.14 A package containing low dispersible radioactive material shall be so designed that any features added to the low dispersible radioactive material that are not part of it, or any internal components of the packaging shall not adversely affect the performance of the low dispersible radioactive material. 6.4.8.15 A package shall be designed for an ambient temperature range from -40 C to +38 C. 6.4.9 Requirements for Type B(M) packages 6.4.9.1 Type B(M) packages shall meet the requirements for Type B(U) packages specified in 6.4.8.1, except that for packages to be carried solely within a specified country or solely between specified countries, conditions other than those given in 6.4.7.5, 6.4.8.4 to 6.4.8.6, and 6.4.8.9 to 6.4.8.15 above may be assumed with the approval of the competent authorities of these countries. Notwithstanding, the requirements for Type B(U) packages specified in 6.4.8.4 and 6.4.8.9 to 6.4.8.15 shall be met as far as practicable. 6.4.9.2 Intermittent venting of Type B(M) packages may be permitted during carriage, provided that the operational controls for venting are acceptable to the relevant competent authorities. 6.4.10 Requirements for Type C packages 6.4.10.1 Type C packages shall be designed to meet the requirements specified in 6.4.2 and of 6.4.7.2 to 6.4.7.15, except as specified in 6.4.7.14 (a), and of the requirements specified in 6.4.8.2 to 6.4.8.6, 6.4.8.10 to 6.4.8.15, and, in addition, of 6.4.10.2 to 6.4.10.4. 6.4.10.2 A package shall be capable of meeting the assessment criteria prescribed for tests in 6.4.8.8 (b) and 6.4.8.12 after burial in an environment defined by a thermal conductivity of 0.33 W.m-1.K-1 and a temperature of 38 °C in the steady state. Initial conditions for the assessment shall assume that any thermal insulation of the package remains intact, the package is at the maximum normal operating pressure and the ambient temperature is 38 °C. 6.4.10.3 A package shall be so designed that, if it were at the maximum normal operating pressure and subjected to: (a) The tests specified in 6.4.15, it would restrict the loss of radioactive contents to not more than 10-6 A2 per hour; and (b) The test sequences in 6.4.20.1, (i) it would retain sufficient shielding to ensure that the radiation level at 1 m from the surface of the package would not exceed 10 mSv/h with the maximum radioactive contents which the package is designed to contain; and (ii) it would restrict the accumulated loss of radioactive contents in a period of 1 week to not more than 10 A2 for krypton-85 and not more than A2 for all other radionuclides. Where mixtures of different radionuclides are present, the provisions of 2.2.7.2.2.4 to 2.2.7.2.2.6 shall apply except that for krypton-85 an effective A2(i) value equal to 10 A2 may be used. For case (a) above, the assessment shall take into account the external contamination limits of 4.1.9.1.2. 6.4.10.4 A package shall be so designed that there will be no rupture of the containment system following performance of the enhanced water immersion test specified in 6.4.18. - 349 - 6.4.11 Requirements for packages containing fissile material 6.4.11.1 Fissile material shall be carried so as to: (a) (b) 6.4.11.2 Maintain sub-criticality during routine, normal and accident conditions of carriage; in particular, the following contingencies shall be considered: (i) water leaking into or out of packages; (ii) the loss of efficiency of built-in neutron absorbers or moderators; (iii) rearrangement of the contents either within the package or as a result of loss from the package; (iv) reduction of spaces within or between packages; (v) packages becoming immersed in water or buried in snow; and (vi) temperature changes; and Meet the requirements: (i) of 6.4.7.2 except for unpackaged material when specifically allowed by 2.2.7.2.3.5 (e); (ii) prescribed elsewhere in ADR which pertain to the radioactive properties of the material; (iii) of 6.4.7.3 unless the material is excepted by 2.2.7.2.3.5; (iv) of 6.4.11.4 to 6.4.11.14, unless the material is excepted by 2.2.7.2.3.5, 6.4.11.2 or 6.4.11.3. Packages containing fissile material that meet the provisions of subparagraph (d) and one of the provisions of (a) to (c) below are excepted from the requirements of 6.4.11.4 to 6.4.11.14. (a) Packages containing fissile material in any form provided that: (i) The smallest external dimension of the package is not less than 10 cm; (ii) The criticality safety index of the package is calculated using the following formula:  Mass of U - 235 in package (g) Mass of other fissile nuclides * in package (g)  CSI  50  5     Z 280   * Plutonium may be of any isotopic composition provided that the amount of Pu-241 is less than that of Pu-240 in the package where the values of Z are taken from Table 6.4.11.2; (iii) (b) The CSI of any package does not exceed 10; Packages containing fissile material in any form provided that: (i) The smallest external dimension of the package is not less than 30 cm; - 350 - (ii) (iii) The package, after being subjected to the tests specified in 6.4.15.1 to 6.4.15.6: - Retains its fissile material contents; - Preserves the minimum overall outside dimensions of the package to at least 30 cm; - Prevents the entry of a 10 cm cube; The criticality safety index of the package is calculated using the following formula:  Mass of U - 235 in package (g) Mass of other fissile nuclides * in package (g)  CSI  50  2     Z 280   * Plutonium may be of any isotopic composition provided that the amount of Pu-241 is less than that of Pu-240 in the package where the values of Z are taken from Table 6.4.11.2; (iv) (c) The criticality safety index of any package does not exceed 10; Packages containing fissile material in any form provided that: (i) The smallest external dimension of the package is not less than 10 cm; (ii) The package, after being subjected to the tests specified in 6.4.15.1 to 6.4.15.6: (iii) - Retains its fissile material contents; - Preserves the minimum overall outside dimensions of the package to at least 10 cm; - Prevents the entry of a 10 cm cube; The CSI of the package is calculated using the following formula:  Mass of U - 235 in package (g) Mass of other fissile nuclides * in package (g)  CSI  50  2     450 280   * Plutonium may be of any isotopic composition provided that the amount of Pu-241 is less than that of Pu-240 in the package (iv) (d) The maximum mass of fissile nuclides in any package does not exceed 15 g; The total mass of beryllium, hydrogenous material enriched in deuterium, graphite and other allotropic forms of carbon in an individual package shall not be greater than the mass of fissile nuclides in the package except where their total concentration does not exceed 1 g in any 1 000 g of material. Beryllium incorporated in copper alloys up to 4% in weight of the alloy does not need to be considered. Table 6.4.11.2 Values of Z for calculation of criticality safety index in accordance with 6.4.11.2 Enrichementa a Z Uranium enriched up to 1.5% 2200 Uranium enriched up to 5% 850 Uranium enriched up to 10% 660 Uranium enriched up to 20% 580 Uranium enriched up to 100% 450 If a package contains uranium with varying enrichments of U-235, then the value corresponding to the highest enrichment shall be used for Z. - 351 - 6.4.11.3 Packages containing not more than 1 000 g of plutonium are excepted from the application of 6.4.11.4 to 6.4.11.14 provided that: (a) Not more than 20% of the plutonium by mass is fissile nuclides; (b) The criticality safety index of the package is calculated using the following formula: CSI  50  2  (c) mass of plutonium (g) 1000 If uranium is present with the plutonium, the mass of uranium shall be no more than 1% of the mass of the plutonium. 6.4.11.4 Where the chemical or physical form, isotopic composition, mass or concentration, moderation ratio or density, or geometric configuration is not known, the assessments of 6.4.11.8 to 6.4.11.13 shall be performed assuming that each parameter that is not known has the value which gives the maximum neutron multiplication consistent with the known conditions and parameters in these assessments. 6.4.11.5 For irradiated nuclear fuel the assessments of 6.4.11.8 to 6.4.11.13 shall be based on an isotopic composition demonstrated to provide either: 6.4.11.6 (a) The maximum neutron multiplication during the irradiation history; or (b) A conservative estimate of the neutron multiplication for the package assessments. After irradiation but prior to shipment, a measurement shall be performed to confirm the conservatism of the isotopic composition. The package, after being subjected to the tests specified in 6.4.15, shall: (a) Preserve the minimum overall outside dimensions of the package to at least 10 cm; and (b) Prevent the entry of a 10 cm cube. 6.4.11.7 The package shall be designed for an ambient temperature range of -40C to + 38C unless the competent authority specifies otherwise in the certificate of approval for the package design. 6.4.11.8 For a package in isolation, it shall be assumed that water can leak into or out of all void spaces of the package, including those within the containment system. However, if the design incorporates special features to prevent such leakage of water into or out of certain void spaces, even as a result of error, absence of leakage may be assumed in respect of those void spaces. Special features shall include either of the following: (a) Multiple high standard water barriers, not less than two of which would remain watertight if the package were subject to the tests prescribed in 6.4.11.13 (b), a high degree of quality control in the manufacture, maintenance and repair of packagings and tests to demonstrate the closure of each package before each shipment; or (b) For packages containing uranium hexafluoride only, with maximum enrichment of 5 mass percent uranium-235: (i) packages where, following the tests prescribed in 6.4.11.13 (b), there is no physical contact between the valve and any other component of the packaging other than at its original point of attachment and where, in addition, following the test prescribed in 6.4.17.3 the valves remain leaktight; and (ii) a high degree of quality control in the manufacture, maintenance and repair of packagings coupled with tests to demonstrate closure of each package before each shipment. - 352 - 6.4.11.9 It shall be assumed that the confinement system is closely reflected by at least 20 cm of water or such greater reflection as may additionally be provided by the surrounding material of the packaging. However, when it can be demonstrated that the confinement system remains within the packaging following the tests prescribed in 6.4.11.13 (b), close reflection of the package by at least 20 cm of water may be assumed in 6.4.11.10 (c). 6.4.11.10 The package shall be subcritical under the conditions of 6.4.11.8 and 6.4.11.9 with the package conditions that result in the maximum neutron multiplication consistent with: (a) Routine conditions of carriage (incident free); (b) The tests specified in 6.4.11.12 (b); (c) The tests specified in 6.4.11.13 (b). 6.4.11.11 (Reserved) 6.4.11.12 For normal conditions of carriage a number "N" shall be derived, such that five times "N" packages shall be subcritical for the arrangement and package conditions that provide the maximum neutron multiplication consistent with the following: 6.4.11.13 (a) There shall not be anything between the packages, and the package arrangement shall be reflected on all sides by at least 20 cm of water; and (b) The state of the packages shall be their assessed or demonstrated condition if they had been subjected to the tests specified in 6.4.15. For accident conditions of carriage a number "N" shall be derived, such that two times "N" packages shall be subcritical for the arrangement and package conditions that provide the maximum neutron multiplication consistent with the following: (a) Hydrogenous moderation between packages, and the package arrangement reflected on all sides by at least 20 cm of water; and (b) The tests specified in 6.4.15 followed by whichever of the following is the more limiting: (c) (i) the tests specified in 6.4.17.2 (b) and, either 6.4.17.2 (c) for packages having a mass not greater than 500 kg and an overall density not greater than 1 000 kg/m3 based on the external dimensions, or 6.4.17.2 (a) for all other packages; followed by the test specified in 6.4.17.3 and completed by the tests specified in 6.4.19.1 to 6.4.19.3; or (ii) the test specified in 6.4.17.4; and Where any part of the fissile material escapes from the containment system following the tests specified in 6.4.11.13 (b), it shall be assumed that fissile material escapes from each package in the array and all of the fissile material shall be arranged in the configuration and moderation that results in the maximum neutron multiplication with close reflection by at least 20 cm of water. 6.4.11.14 The criticality safety index (CSI) for packages containing fissile material shall be obtained by dividing the number 50 by the smaller of the two values of N derived in 6.4.11.12 and 6.4.11.13 (i.e. CSI = 50/N). The value of the criticality safety index may be zero, provided that an unlimited number of packages is subcritical (i.e. N is effectively equal to infinity in both cases). 6.4.12 Test procedures and demonstration of compliance 6.4.12.1 Demonstration of compliance with the performance standards required in 2.2.7.2.3.1.3, 2.2.7.2.3.1.4, 2.2.7.2.3.3.1, 2.2.7.2.3.3.2, 2.2.7.2.3.4.1, 2.2.7.2.3.4.2, and 6.4.2 to 6.4.11 must be accomplished by any of the methods listed below or by a combination thereof: - 353 - (a) Performance of tests with specimens representing LSA-III material, or special form radioactive material, or low dispersible radioactive material or with prototypes or samples of the packaging, where the contents of the specimen or the packaging for the tests shall simulate as closely as practicable the expected range of radioactive contents and the specimen or packaging to be tested shall be prepared as presented for carriage; (b) Reference to previous satisfactory demonstrations of a sufficiently similar nature; (c) Performance of tests with models of appropriate scale incorporating those features which are significant with respect to the item under investigation when engineering experience has shown results of such tests to be suitable for design purposes. When a scale model is used, the need for adjusting certain test parameters, such as penetrator diameter or compressive load, shall be taken into account; (d) Calculation, or reasoned argument, when the calculation procedures and parameters are generally agreed to be reliable or conservative. 6.4.12.2 After the specimen, prototype or sample has been subjected to the tests, appropriate methods of assessment shall be used to assure that the requirements for the test procedures have been fulfilled in compliance with the performance and acceptance standards prescribed in 2.2.7.2.3.1.3, 2.2.7.2.3.1.4, 2.2.7.2.3.3.1, 2.2.7.2.3.3.2, 2.2.7.2.3.4.1, 2.2.7.2.3.4.2, and 6.4.2 to 6.4.11. 6.4.12.3 All specimens shall be inspected before testing in order to identify and record faults or damage including the following: (a) Divergence from the design; (b) Defects in manufacture; (c) Corrosion or other deterioration; and (d) Distortion of features. The containment system of the package shall be clearly specified. The external features of the specimen shall be clearly identified so that reference may be made simply and clearly to any part of such specimen. 6.4.13 Testing the integrity of the containment system and shielding and evaluating criticality safety After each of the applicable tests specified in 6.4.15 to 6.4.21: 6.4.14 (a) Faults and damage shall be identified and recorded; (b) It shall be determined whether the integrity of the containment system and shielding has been retained to the extent required in 6.4.2 to 6.4.11 for the package under test; and (c) For packages containing fissile material, it shall be determined whether the assumptions and conditions used in the assessments required by 6.4.11.1 to 6.4.11.14 for one or more packages are valid. Target for drop tests The target for the drop tests specified in 2.2.7.2.3.3.5 (a), 6.4.15.4, 6.4.16 (a), 6.4.17.2 and 6.4.20.2 shall be a flat, horizontal surface of such a character that any increase in its resistance to displacement or deformation upon impact by the specimen would not significantly increase the damage to the specimen. - 354 - 6.4.15 Tests for demonstrating ability to withstand normal conditions of carriage 6.4.15.1 The tests are: the water spray test, the free drop test, the stacking test and the penetration test. Specimens of the package shall be subjected to the free drop test, the stacking test and the penetration test, preceded in each case by the water spray test. One specimen may be used for all the tests, provided that the requirements of 6.4.15.2 are fulfilled. 6.4.15.2 The time interval between the conclusion of the water spray test and the succeeding test shall be such that the water has soaked in to the maximum extent, without appreciable drying of the exterior of the specimen. In the absence of any evidence to the contrary, this interval shall be taken to be two hours if the water spray is applied from four directions simultaneously. No time interval shall elapse, however, if the water spray is applied from each of the four directions consecutively. 6.4.15.3 Water spray test: The specimen shall be subjected to a water spray test that simulates exposure to rainfall of approximately 5 cm per hour for at least one hour. 6.4.15.4 Free drop test: The specimen shall drop onto the target so as to suffer maximum damage in respect of the safety features to be tested. (a) The height of drop measured from the lowest point of the specimen to the upper surface of the target shall be not less than the distance specified in Table 6.4.15.4 for the applicable mass. The target shall be as defined in 6.4.14; (b) For rectangular fibreboard or wood packages not exceeding a mass of 50 kg, a separate specimen shall be subjected to a free drop onto each corner from a height of 0.3 m; (c) For cylindrical fibreboard packages not exceeding a mass of 100 kg, a separate specimen shall be subjected to a free drop onto each of the quarters of each rim from a height of 0.3 m. Table 6.4.15.4: 6.4.15.5 Free drop distance for testing packages to normal conditions of carriage Package mass (kg) Free drop distance (m) Package mass < 5 000 1.2 5 000  Package mass < 10 000 0.9 10 000  Package mass < 15 000 0.6 15 000  Package mass 0.3 Stacking test: Unless the shape of the packaging effectively prevents stacking, the specimen shall be subjected, for a period of 24 h, to a compressive load equal to the greater of the following: (a) The equivalent of 5 times the maximum weight of the package; and (b) The equivalent of 13 kPa multiplied by the vertically projected area of the package. The load shall be applied uniformly to two opposite sides of the specimen, one of which shall be the base on which the package would typically rest. 6.4.15.6 Penetration test: The specimen shall be placed on a rigid, flat, horizontal surface which will not move significantly while the test is being carried out. (a) A bar of 3.2 cm in diameter with a hemispherical end and a mass of 6 kg shall be dropped and directed to fall, with its longitudinal axis vertical, onto the centre of the weakest part of the specimen, so that, if it penetrates sufficiently far, it will hit the containment system. The bar shall not be significantly deformed by the test performance; (b) The height of drop of the bar measured from its lower end to the intended point of impact on the upper surface of the specimen shall be 1 m. - 355 - 6.4.16 Additional tests for Type A packages designed for liquids and gases A specimen or separate specimens shall be subjected to each of the following tests unless it can be demonstrated that one test is more severe for the specimen in question than the other, in which case one specimen shall be subjected to the more severe test. (a) Free drop test: The specimen shall drop onto the target so as to suffer the maximum damage in respect of containment. The height of the drop measured from the lowest part of the specimen to the upper surface of the target shall be 9 m. The target shall be as defined in 6.4.14; (b) Penetration test: The specimen shall be subjected to the test specified in 6.4.15.6 except that the height of drop shall be increased to 1.7 m from the 1 m specified in 6.4.15.6 (b). 6.4.17 Tests for demonstrating ability to withstand accident conditions in carriage 6.4.17.1 The specimen shall be subjected to the cumulative effects of the tests specified in 6.4.17.2 and 6.4.17.3, in that order. Following these tests, either this specimen or a separate specimen shall be subjected to the effect(s) of the water immersion test(s) as specified in 6.4.17.4 and, if applicable, 6.4.18. 6.4.17.2 Mechanical test: The mechanical test consists of three different drop tests. Each specimen shall be subjected to the applicable drops as specified in 6.4.8.8 or 6.4.11.13. The order in which the specimen is subjected to the drops shall be such that, on completion of the mechanical test, the specimen shall have suffered such damage as will lead to the maximum damage in the thermal test which follows. 6.4.17.3 (a) For drop I, the specimen shall drop onto the target so as to suffer the maximum damage, and the height of the drop measured from the lowest point of the specimen to the upper surface of the target shall be 9 m. The target shall be as defined in 6.4.14; (b) For drop II, the specimen shall drop onto a bar rigidly mounted perpendicularly on the target so as to suffer the maximum damage. The height of the drop measured from the intended point of impact of the specimen to the upper surface of the bar shall be 1 m. The bar shall be of solid mild steel of circular section, (15.0 cm ± 0.5 cm) in diameter and 20 cm long unless a longer bar would cause greater damage, in which case a bar of sufficient length to cause maximum damage shall be used. The upper end of the bar shall be flat and horizontal with its edge rounded off to a radius of not more than 6 mm. The target on which the bar is mounted shall be as described in 6.4.14; (c) For drop III, the specimen shall be subjected to a dynamic crush test by positioning the specimen on the target so as to suffer maximum damage by the drop of a 500 kg mass from 9 m onto the specimen. The mass shall consist of a solid mild steel plate 1 m by 1 m and shall fall in a horizontal attitude. The lower face of the steel plate shall have its edges and corners rounded off to a radius of not more than 6 mm. The height of the drop shall be measured from the underside of the plate to the highest point of the specimen. The target on which the specimen rests shall be as defined in 6.4.14. Thermal test: The specimen shall be in thermal equilibrium under conditions of an ambient temperature of 38 C, subject to the solar insolation conditions specified in Table 6.4.8.6 and subject to the design maximum rate of internal heat generation within the package from the radioactive contents. Alternatively, any of these parameters are allowed to have different values prior to and during the test, providing due account is taken of them in the subsequent assessment of package response. - 356 - The thermal test shall then consist of: (a) Exposure of a specimen for a period of 30 minutes to a thermal environment which provides a heat flux at least equivalent to that of a hydrocarbon fuel/air fire in sufficiently quiescent ambient conditions to give a minimum average flame emissivity coefficient of 0.9 and an average temperature of at least 800 C, fully engulfing the specimen, with a surface absorptivity coefficient of 0.8 or that value which the package may be demonstrated to possess if exposed to the fire specified, followed by; (b) Exposure of the specimen to an ambient temperature of 38 C, subject to the solar insolation conditions specified in Table 6.4.8.6 and subject to the design maximum rate of internal heat generation within the package by the radioactive contents for a sufficient period to ensure that temperatures in the specimen are everywhere decreasing and/or are approaching initial steady state conditions. Alternatively, any of these parameters are allowed to have different values following cessation of heating, providing due account is taken of them in the subsequent assessment of package response. During and following the test the specimen shall not be artificially cooled and any combustion of materials of the specimen shall be permitted to proceed naturally. 6.4.17.4 Water immersion test: The specimen shall be immersed under a head of water of at least 15 m for a period of not less than eight hours in the attitude which will lead to maximum damage. For demonstration purposes, an external gauge pressure of at least 150 kPa shall be considered to meet these conditions. 6.4.18 Enhanced water immersion test for Type B(U) and Type B(M) packages containing more than 105 A2 and Type C packages Enhanced water immersion test: The specimen shall be immersed under a head of water of at least 200 m for a period of not less than one hour. For demonstration purposes, an external gauge pressure of at least 2 MPa shall be considered to meet these conditions. 6.4.19 Water leakage test for packages containing fissile material 6.4.19.1 Packages for which water in-leakage or out-leakage to the extent which results in greatest reactivity has been assumed for purposes of assessment under 6.4.11.8 to 6.4.11.13 shall be excepted from the test. 6.4.19.2 Before the specimen is subjected to the water leakage test specified below, it shall be subjected to the tests in 6.4.17.2 (b), and either 6.4.17.2 (a) or (c) as required by 6.4.11.13, and the test specified in 6.4.17.3. 6.4.19.3 The specimen shall be immersed under a head of water of at least 0.9 m for a period of not less than 8 hours and in the attitude for which maximum leakage is expected. 6.4.20 Tests for Type C packages 6.4.20.1 Specimens shall be subjected to the effects of each of the following test sequences in the orders specified: (a) The tests specified in 6.4.17.2 (a), 6.4.17.2 (c), 6.4.20.2 and 6.4.20.3; and (b) The test specified in 6.4.20.4. Separate specimens are allowed to be used for each of the sequences (a) and (b). 6.4.20.2 Puncture/tearing test: The specimen shall be subjected to the damaging effects of a vertical solid probe made of mild steel. The orientation of the package specimen and the impact point on the package surface shall be such as to cause maximum damage at the conclusion of the test sequence specified in 6.4.20.1 (a). - 357 - (a) The specimen, representing a package having a mass less than 250 kg, shall be placed on a target and subjected to a probe having a mass of 250 kg falling from a height of 3 m above the intended impact point. For this test the probe shall be a 20 cm diameter cylindrical bar with the striking end forming a frustum of a right circular cone with the following dimensions: 30 cm height and 2.5 cm in diameter at the top with its edge rounded off to a radius of not more than 6 mm. The target on which the specimen is placed shall be as specified in 6.4.14; (b) For packages having a mass of 250 kg or more, the base of the probe shall be placed on a target and the specimen dropped onto the probe. The height of the drop, measured from the point of impact with the specimen to the upper surface of the probe shall be 3 m. For this test the probe shall have the same properties and dimensions as specified in (a) above, except that the length and mass of the probe shall be such as to incur maximum damage to the specimen. The target on which the base of the probe is placed shall be as specified in 6.4.14. 6.4.20.3 Enhanced thermal test: The conditions for this test shall be as specified in 6.4.17.3, except that the exposure to the thermal environment shall be for a period of 60 minutes. 6.4.20.4 Impact test: The specimen shall be subject to an impact on a target at a velocity of not less than 90 m/s, at such an orientation as to suffer maximum damage. The target shall be as defined in 6.4.14, except that the target surface may be at any orientation as long as the surface is normal to the specimen path. 6.4.21 Inspections for packagings designed to contain 0.1 kg or more of uranium hexafluoride 6.4.21.1 Every manufactured packaging and its service and structural equipment shall, either jointly or separately, undergo an inspection initially before being put into service and periodically thereafter. These inspections shall be performed and certified by agreement with the competent authority. 6.4.21.2 The initial inspection shall consist of a check of the design characteristics, a structural test, a leakproofness test, a water capacity test and a check of satisfactory operation of the service equipment. 6.4.21.3 The periodic inspections shall consist of a visual examination, a structural test, a leakproofness test and a check of satisfactory operation of the service equipment. The maximum intervals for periodic inspections shall be five years. Packagings which have not been inspected within this five-year period shall be examined before carriage in accordance with a programme approved by the competent authority. They shall not be refilled before completion of the full programme for periodic inspections. 6.4.21.4 The check of design characteristics shall demonstrate compliance with the design type specifications and the manufacturing programme. 6.4.21.5 For the initial structural test, packagings designed to contain 0.1 kg or more of uranium hexafluoride shall be tested hydraulically at an internal pressure of at least 1.38 MPa but, when the test pressure is less than 2.76 MPa, the design shall require multilateral approval. For retesting packagings, any other equivalent non-destructive testing may be applied subject to multilateral approval. 6.4.21.6 The leakproofness test shall be performed in accordance with a procedure which is capable of indicating leakages in the containment system with a sensitivity of 0.1 Pa.l/s (10-6 bar.l/s). 6.4.21.7 The water capacity of the packagings shall be established with an accuracy of  0.25% at a reference temperature of 15 °C. The volume shall be stated on the plate described in 6.4.21.8. 6.4.21.8 A plate made of non-corroding metal shall be durably attached to every packaging in a readily accessible place. The method of attaching the plate must not impair the strength of the packaging. The following particulars, at least, shall be marked on the plate by stamping or by any other equivalent method: - Approval number; - Manufacturer's serial number; - Maximum working pressure (gauge pressure); - 358 - - Test pressure (gauge pressure); - Contents: uranium hexafluoride; - Capacity in litres; - Maximum permissible filling mass of uranium hexafluoride; - Tare mass; - Date (month, year) of the initial test and the most recent periodic test; - Stamp of the expert who performed the tests. 6.4.22 Approvals of package designs and materials 6.4.22.1 The approval of designs for packages containing 0.1 kg or more of uranium hexafluoride requires that: 6.4.22.2 (a) Each design that meets the requirements of 6.4.6.4 shall require multilateral approval; (b) Each design that meets the requirements of 6.4.6.1 to 6.4.6.3 shall require unilateral approval by the competent authority of the country of origin of the design, unless multilateral approval is otherwise required by ADR. Each Type B(U) and Type C package design shall require unilateral approval, except that: (a) A package design for fissile material, which is also subject to 6.4.22.4, 6.4.23.7, and 5.1.5.2.1 shall require multilateral approval; and (b) A Type B(U) package design for low dispersible radioactive material shall require multilateral approval. 6.4.22.3 Each Type B(M) package design, including those for fissile material which are also subject to the requirements of 6.4.22.4, 6.4.23.7, and 5.1.5.2.1 and those for low dispersible radioactive material, shall require multilateral approval. 6.4.22.4 Each package design for fissile material which is not excepted by any of the paragraphs 2.2.7.2.3.5 (a) to (f), 6.4.11.2 and 6.4.11.3 shall require multilateral approval. 6.4.22.5 The design for special form radioactive material shall require unilateral approval. The design for low dispersible radioactive material shall require multilateral approval (see also 6.4.23.8). 6.4.22.6 The design for a fissile material excepted from "FISSILE" classification in accordance with 2.2.7.2.3.5 (f) shall require multilateral approval. 6.4.22.7 Alternative activity limits for an exempt consignment of instruments or articles in accordance with 2.2.7.2.2.2 (b) shall require multilateral approval. 6.4.22.8 Any design that requires unilateral approval originating in a country Contracting Party to ADR shall be approved by the competent authority of this country; if the country where the package has been designed is not a Contracting Party to ADR, carriage is possible on condition that: 6.4.22.9 (a) A certificate has been supplied by this country, proving that the package design satisfies the technical requirements of ADR, and that this certificate is countersigned by the competent authority of the first country Contracting Party to ADR reached by the consignment; (b) If no certificate and no existing package design approval by a country Contracting Party to ADR has been supplied, the package design is approved by the competent authority of the first country Contracting Party to ADR reached by the consignment. For designs approved under the transitional measures see 1.6.6. - 359 - 6.4.23 Applications and approvals for radioactive material carriage 6.4.23.1 (Reserved) 6.4.23.2 An application for approval of shipment shall include: 6.4.23.3 (a) The period of time, related to the shipment, for which the approval is sought; (b) The actual radioactive contents, the expected modes of carriage, the type of vehicle, and the probable or proposed route; and (c) The details of how the precautions and administrative or operational controls, referred to in the certificate of approval for the package design, if applicable, issued under 5.1.5.2.1 (a) (v), (vi) or (vii), are to be put into effect. An application for approval of shipments under special arrangement shall include all the information necessary to satisfy the competent authority that the overall level of safety in carriage is at least equivalent to that which would be provided if all the applicable requirements of ADR had been met. The application shall also include: 6.4.23.4 6.4.23.5 (a) A statement of the respects in which, and of the reasons why, the shipment cannot be made in full accordance with the applicable requirements of ADR; and (b) A statement of any special precautions or special administrative or operational controls which are to be employed during carriage to compensate for the failure to meet the applicable requirements of ADR. An application for approval of Type B(U) or Type C package design shall include: (a) A detailed description of the proposed radioactive contents with reference to their physical and chemical states and the nature of the radiation emitted; (b) A detailed statement of the design, including complete engineering drawings and schedules of materials and methods of manufacture; (c) A statement of the tests which have been done and their results, or evidence based on calculative methods or other evidence that the design is adequate to meet the applicable requirements; (d) The proposed operating and maintenance instructions for the use of the packaging; (e) If the package is designed to have a maximum normal operating pressure in excess of 100 kPa gauge, a specification of the materials of manufacture of the containment system, the samples to be taken, and the tests to be made; (f) Where the proposed radioactive contents are irradiated nuclear fuel, a statement and a justification of any assumption in the safety analysis relating to the characteristics of the fuel and a description of any pre-shipment measurement as required by 6.4.11.5 (b); (g) Any special stowage provisions necessary to ensure the safe dissipation of heat from the package considering the various modes of carriage to be used and type of vehicle or container; (h) A reproducible illustration, not larger than 21 cm by 30 cm, showing the make-up of the package; and (i) A specification of the applicable management system as required in 1.7.3. An application for approval of a Type B(M) package design shall include, in addition to the general information required in 6.4.23.4 for Type B(U) packages: (a) A list of the requirements specified in 6.4.7.5, 6.4.8.4 to 6.4.8.6 and 6.4.8.9 to 6.4.8.15 with which the package does not conform; - 360 - (b) Any proposed supplementary operational controls to be applied during carriage not regularly provided for in this Annex, but which are necessary to ensure the safety of the package or to compensate for the deficiencies listed in (a) above; (c) A statement relative to any restrictions on the mode of carriage and to any special loading, carriage, unloading or handling procedures; and (d) A statement of the range of ambient conditions (temperature, solar radiation) which are expected to be encountered during carriage and which have been taken into account in the design. 6.4.23.6 The application for approval of designs for packages containing 0.1 kg or more of uranium hexafluoride shall include all information necessary to satisfy the competent authority that the design meets the applicable requirements of 6.4.6.1, and a description of the applicable management system as required in 1.7.3. 6.4.23.7 An application for a fissile package approval shall include all information necessary to satisfy the competent authority that the design meets the applicable requirements of 6.4.11.1, and a specification of the applicable management system as required by 1.7.3. 6.4.23.8 An application for approval of design for special form radioactive material and design for low dispersible radioactive material shall include: 6.4.23.9 6.4.23.10 (a) A detailed description of the radioactive material or, if a capsule, the contents; particular reference shall be made to both physical and chemical states; (b) A detailed statement of the design of any capsule to be used; (c) A statement of the tests which have been done and their results, or evidence based on calculative methods to show that the radioactive material is capable of meeting the performance standards, or other evidence that the special form radioactive material or low dispersible radioactive material meets the applicable requirements of ADR; (d) A specification of the applicable management system as required in 1.7.3; and (e) Any proposed pre-shipment actions for use in the consignment of special form radioactive material or low dispersible radioactive material. An application for approval of design for fissile material excepted from "FISSILE" classification in accordance with Table 2.2.7.2.1.1, under 2.2.7.2.3.5 (f) shall include: (a) A detailed description of the material; particular reference shall be made to both physical and chemical states; (b) A statement of the tests that have been carried out and their results, or evidence based on calculation methods to show that the material is capable of meeting the requirements specified in 2.2.7.2.3.6; (c) A specification of the applicable management system as required in 1.7.3; (d) A statement of specific actions to be taken prior to shipment. An application for approval of alternative activity limits for an exempt consignment of instruments or articles shall include: (a) An identification and detailed description of the instrument or article, its intended uses and the radionuclide(s) incorporated; (b) The maximum activity of the radionuclide(s) in the instrument or article; (c) Maximum external radiation levels arising from the instrument or article; (d) The chemical and physical forms of the radionuclide(s) contained in the instrument or article; - 361 - 6.4.23.11 (e) Details of the construction and design of the instrument or article, particularly as related to the containment and shielding of the radionuclide in routine, normal and accident conditions of carriage; (f) The applicable management system, including the quality testing and verification procedures to be applied to radioactive sources, components and finished products to ensure that the maximum specified activity of radioactive material or the maximum radiation levels specified for the instrument or article are not exceeded, and that the instruments or articles are constructed according to the design specifications; (g) The maximum number of instruments or articles expected to be shipped per consignment and annually; (h) Dose assessments in accordance with the principles and methodologies set out in the International Basic Safety Standards for Protection against Ionizing Radiation and for the Safety of Radiation Sources, Safety Series No.115, IAEA, Vienna (1996), including individual doses to transport workers and members of the public and, if appropriate, collective doses arising from routine, normal and accident conditions of carriage, based on representative carriage scenarios the consignments are subject to. Each certificate of approval issued by a competent authority shall be assigned an identification mark. The identification mark shall be of the following generalized type: VRI/Number/Type Code (a) Except as provided in 6.4.23.12 (b), VRI represents the international vehicle registration identification code of the country issuing the certificate1; (b) The number shall be assigned by the competent authority, and shall be unique and specific with regard to the particular design or shipment or alternative activity limit for exempt consignment. The identification mark of the approval of shipment shall be clearly related to the identification mark of the approval of design; (c) The following type codes shall be used in the order listed to indicate the types of certificate of approval issued: AF B(U) B(M) C IF S LD FE T X AL Type A package design for fissile material Type B(U) package design [B(U) F if for fissile material] Type B(M) package design [B(M) F if for fissile material] Type C package design (CF if for fissile material) Industrial package design for fissile material Special form radioactive material Low dispersible radioactive material Fissile material complying with the requirements of 2.2.7.2.3.6 Shipment Special arrangement Alternative activity limits for an exempt consignment of instruments or articles In the case of package designs for non-fissile or fissile excepted uranium hexafluoride, where none of the above codes apply, then the following type codes shall be used: H(U) H(M) (d) 1 Unilateral approval Multilateral approval; For certificates of approval of package design and special form radioactive material, other than those issued under the transitional provisions of 1.6.6.2 to 1.6.6.4, and for low dispersible radioactive material, the symbols "-96" shall be added to the type code. See the Vienna Convention on Road Traffic (1968). - 362 - 6.4.23.12 These identification marks shall be applied as follows: (a) (b) Each certificate and each package shall bear the appropriate identification mark, comprising the symbols prescribed in 6.4.23.11 (a), (b), (c) and (d) above, except that, for packages, only the applicable design type codes including, if applicable, the symbols "-96", shall appear following the second stroke, that is, the "T" or "X" shall not appear in the identification marking on the package. Where the approval of design and the approval of shipment are combined, the applicable type codes do not need to be repeated. For example: A/132/B(M)F-96: A Type B(M) package design approved for fissile material, requiring multilateral approval, for which the competent authority of Austria has assigned the design number 132 (to be marked on both the package and on the certificate of approval for the package design); A/132/B(M)F-96T: The approval of shipment issued for a package bearing the identification mark elaborated above (to be marked on the certificate only); A/137/X: An approval of special arrangement issued by the competent authority of Austria, to which the number 137 has been assigned (to be marked on the certificate only); A/139/IF-96: An industrial package design for fissile material approved by the competent authority of Austria, to which package design number 139 has been assigned (to be marked on both the package and on the certificate of approval for the package design); and A/145/H(U)-96: A package design for fissile excepted uranium hexafluoride approved by the competent authority of Austria, to which package design number 145 has been assigned (to be marked on both the package and on the certificate of approval for the package design); Where multilateral approval is effected by validation in accordance with 6.4.23.20, only the identification mark issued by the country of origin of the design or shipment shall be used. Where multilateral approval is effected by issue of certificates by successive countries, each certificate shall bear the appropriate identification mark and the package whose design was so approved shall bear all appropriate identification marks. For example: A/132/B(M)F-96 CH/28/B(M)F-96 would be the identification mark of a package which was originally approved by Austria and was subsequently approved, by separate certificate, by Switzerland. Additional identification marks would be tabulated in a similar manner on the package; (c) The revision of a certificate shall be indicated by a parenthetical expression following the identification mark on the certificate. For example, A/132/B(M)F-96 (Rev.2) would indicate revision 2 of the Austrian certificate of approval for the package design; or A/132/B(M)F-96 (Rev.0) would indicate the original issuance of the Austrian certificate of approval for the package design. For original issuances, the parenthetical entry is optional and other words such as "original issuance" may also be used in place of "Rev.0". Certificate revision numbers may only be issued by the country issuing the original certificate of approval; (d) Additional symbols (as may be necessitated by national regulations) may be added in brackets to the end of the identification mark; for example, A/132/B(M)F-96(SP503); (e) It is not necessary to alter the identification mark on the packaging each time that a revision to the design certificate is made. Such re-marking shall be required only in those cases where the revision to the package design certificate involves a change in the letter type codes for the package design following the second stroke. - 363 - 6.4.23.13 6.4.23.14 Each certificate of approval issued by a competent authority for special form radioactive material or low dispersible radioactive material shall include the following information: (a) Type of certificate; (b) The competent authority identification mark; (c) The issue date and an expiry date; (d) List of applicable national and international regulations, including the edition of the IAEA Regulations for the Safe Transport of Radioactive Material under which the special form radioactive material or low dispersible radioactive material is approved; (e) The identification of the special form radioactive material or low dispersible radioactive material; (f) A description of the special form radioactive material or low dispersible radioactive material; (g) Design specifications for the special form radioactive material or low dispersible radioactive material which may include references to drawings; (h) A specification of the radioactive contents which includes the activities involved and which may include the physical and chemical form; (i) A specification of the applicable management system as required in 1.7.3; (j) Reference to information provided by the applicant relating to specific actions to be taken prior to shipment; (k) If deemed appropriate by the competent authority, reference to the identity of the applicant; (l) Signature and identification of the certifying official. Each certificate of approval issued by a competent authority for material excepted from classification as "FISSILE" shall include the following information: (a) Type of certificate; (b) The competent authority identification mark; (c) The issue date and an expiry date; (d) List of applicable national and international regulations, including the edition of the IAEA Regulations for the Safe Transport of Radioactive Material under which the exception is approved; (e) A description of the excepted material; (f) Limiting specifications for the excepted material; (g) A specification of the applicable management system as required in 1.7.3; (h) (i) Reference to information provided by the applicant relating to specific actions to be taken prior to shipment; If deemed appropriate by the competent authority, reference to the identity of the applicant; (j) Signature and identification of the certifying official; (k) Reference to documentation that demonstrates compliance with 2.2.7.2.3.6. - 364 - 6.4.23.15 Each certificate of approval issued by a competent authority for a special arrangement shall include the following information: (a) Type of certificate; (b) The competent authority identification mark; (c) The issue date and an expiry date; (d) Mode(s) of carriage; (e) Any restrictions on the modes of carriage, type of vehicle, container, and any necessary routeing instructions; (f) List of applicable national and international regulations, including the edition of the IAEA Regulations for the Safe Transport of Radioactive Material under which the special arrangement is approved; (g) The following statement: "This certificate does not relieve the consignor from compliance with any requirement of the government of any country through or into which the package will be carried."; (h) References to certificates for alternative radioactive contents, other competent authority validation, or additional technical data or information, as deemed appropriate by the competent authority; (i) Description of the packaging by a reference to the drawings or a specification of the design. If deemed appropriate by the competent authority, a reproducible illustration, not larger than 21 cm by 30 cm, showing the make-up of the package shall also be provided, accompanied by a brief description of the packaging, including materials of manufacture, gross mass, general outside dimensions and appearance; (j) A specification of the authorized radioactive contents, including any restrictions on the radioactive contents which might not be obvious from the nature of the packaging. This shall include the physical and chemical forms, the activities involved (including those of the various isotopes, if appropriate), mass in grams (for fissile material or for each fissile nuclide when appropriate), and whether special form radioactive material, low dispersible radioactive material or fissile material excepted under 2.2.7.2.3.5 (f) if applicable; (k) Additionally, for packages containing fissile material: (i) a detailed description of the authorized radioactive contents; (ii) the value of the criticality safety index; (iii) reference to the documentation that demonstrates the criticality safety of the contents; (iv) any special features, on the basis of which the absence of water from certain void spaces has been assumed in the criticality assessment; (v) any allowance (based on 6.4.11.5 (b)) for a change in neutron multiplication assumed in the criticality assessment as a result of actual irradiation experience; and (vi) the ambient temperature range for which the special arrangement has been approved; (l) A detailed listing of any supplementary operational controls required for preparation, loading, carriage, unloading and handling of the consignment, including any special stowage provisions for the safe dissipation of heat; (m) If deemed appropriate by the competent authority, reasons for the special arrangement; - 365 - 6.4.23.16 (n) Description of the compensatory measures to be applied as a result of the shipment being under special arrangement; (o) Reference to information provided by the applicant relating to the use of the packaging or specific actions to be taken prior to the shipment; (p) A statement regarding the ambient conditions assumed for purposes of design if these are not in accordance with those specified in 6.4.8.5, 6.4.8.6, and 6.4.8.15, as applicable; (q) Any emergency arrangements deemed necessary by the competent authority; (r) A specification of the applicable management system as required in 1.7.3; (s) If deemed appropriate by the competent authority, reference to the identity of the applicant and to the identity of the carrier; (t) Signature and identification of the certifying official. Each certificate of approval for a shipment issued by a competent authority shall include the following information: (a) Type of certificate; (b) The competent authority identification mark(s); (c) The issue date and an expiry date; (d) List of applicable national and international regulations, including the edition of the IAEA Regulations for the Safe Transport of Radioactive Material under which the shipment is approved; (e) Any restrictions on the modes of carriage, type of vehicle, container, and any necessary routeing instructions; (f) The following statement: "This certificate does not relieve the consignor from compliance with any requirement of the government of any country through or into which the package will be carried."; (g) A detailed listing of any supplementary operational controls required for preparation, loading, carriage, unloading and handling of the consignment, including any special stowage provisions for the safe dissipation of heat or maintenance of criticality safety; (h) Reference to information provided by the applicant relating to specific actions to be taken prior to shipment; (i) Reference to the applicable certificate(s) of approval of design; (j) A specification of the actual radioactive contents, including any restrictions on the radioactive contents which might not be obvious from the nature of the packaging. This shall include the physical and chemical forms, the total activities involved (including those of the various isotopes, if appropriate), mass in grams (for fissile material or for each fissile nuclide when appropriate), and whether special form radioactive material, low dispersible radioactive material or fissile material excepted under 2.2.7.2.3.5 (f) if applicable;; (k) Any emergency arrangements deemed necessary by the competent authority; (l) A specification of the applicable management system as required in 1.7.3; (m) If deemed appropriate by the competent authority, reference to the identity of the applicant; (n) Signature and identification of the certifying official. - 366 - 6.4.23.17 Each certificate of approval of the design of a package issued by a competent authority shall include the following information: (a) Type of certificate; (b) The competent authority identification mark; (c) The issue date and an expiry date; (d) Any restriction on the modes of carriage, if appropriate; (e) List of applicable national and international regulations, including the edition of the IAEA Regulations for the Safe Transport of Radioactive Material under which the design is approved; (f) The following statement; "This certificate does not relieve the consignor from compliance with any requirement of the government of any country through or into which the package will be carried."; (g) References to certificates for alternative radioactive contents, other competent authority validation, or additional technical data or information, as deemed appropriate by the competent authority; (h) A statement authorizing shipment where approval of shipment is required under 5.1.5.1.2, if deemed appropriate; (i) Identification of the packaging; (j) Description of the packaging by a reference to the drawings or specification of the design. If deemed appropriate by the competent authority, a reproducible illustration, not larger than 21 cm by 30 cm, showing the make-up of the package shall also be provided, accompanied by a brief description of the packaging, including materials of manufacture, gross mass, general outside dimensions and appearance; (k) Specification of the design by reference to the drawings; (l) A specification of the authorized radioactive content, including any restrictions on the radioactive contents which might not be obvious from the nature of the packaging. This shall include the physical and chemical forms, the activities involved (including those of the various isotopes, if appropriate), mass in grams (for fissile material the total mass of fissile nuclides or the mass for each fissile nuclide, when appropriate) and whether special form radioactive material, low dispersible radioactive material or fissile material excepted under 2.2.7.2.3.5 (f), if applicable; (m) A description of the containment system; (n) For package designs containing fissile material which require multilateral approval of the package design in accordance with 6.4.22.4: (i) a detailed description of the authorized radioactive contents; (ii) a description of the confinement system; (iii) the value of the criticality safety index; (iv) reference to the documentation that demonstrates the criticality safety of the contents; (v) any special features, on the basis of which the absence of water from certain void spaces has been assumed in the criticality assessment; (vi) any allowance (based on 6.4.11.5 (b)) for a change in neutron multiplication assumed in the criticality assessment as a result of actual irradiation experience; and (vii) the ambient temperature range for which the package design has been approved; - 367 - 6.4.23.18 (o) For Type B(M) packages, a statement specifying those requirements of 6.4.7.5, 6.4.8.4, 6.4.8.5, 6.4.8.6 and 6.4.8.9 to 6.4.8.15 with which the package does not conform and any amplifying information which may be useful to other competent authorities; (p) For packages containing more than 0.1 kg of uranium hexafluoride, a statement specifying those prescriptions of 6.4.6.4 which apply if any and any amplifying information which may be useful to other competent authorities; (q) A detailed listing of any supplementary operational controls required for preparation, loading, carriage, unloading and handling of the consignment, including any special stowage provisions for the safe dissipation of heat; (r) Reference to information provided by the applicant relating to the use of the packaging or specific actions to be taken prior to shipment; (s) A statement regarding the ambient conditions assumed for purposes of design if these are not in accordance with those specified in 6.4.8.5, 6.4.8.6 and 6.4.8.15, as applicable; (t) A specification of the applicable management system as required in 1.7.3; (u) Any emergency arrangements deemed necessary by the competent authority; (v) If deemed appropriate by the competent authority, reference to the identity of the applicant; (w) Signature and identification of the certifying official. Each certificate issued by a competent authority for alternative activity limits for an exempt consignment of instruments or articles according to 5.1.5.2.1 (d) shall include the following information: (a) Type of certificate; (b) The competent authority identification mark; (c) The issue date and an expiry date; (d) List of applicable national and international regulations, including the edition of the IAEA Regulations for the Safe Transport of Radioactive Material under which the exemption is approved; (e) The identification of the instrument or article; (f) A description of the instrument or article; (g) Design specifications for the instrument or article; (h) A specification of the radionuclide(s), the approved alternative activity limit(s) for the exempt consignment(s) of the instrument(s) or article(s); (i) Reference to documentation that demonstrates compliance with 2.2.7.2.2.2 (b); (j) If deemed appropriate by the competent authority, reference to the identity of the applicant; (k) Signature and identification of the certifying official. 6.4.23.19 The competent authority shall be informed of the serial number of each packaging manufactured to a design approved by them under 1.6.6.2.1, 1.6.6.2.2, 6.4.22.2, 6.4.22.3 and 6.4.22.4. 6.4.23.20 Multilateral approval may be by validation of the original certificate issued by the competent authority of the country of origin of the design or shipment. Such validation may take the form of an endorsement on the original certificate or the issuance of a separate endorsement, annex, supplement, etc., by the competent authority of the country through or into which the shipment is made. - 368 - CHAPTER 6.5 REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF INTERMEDIATE BULK CONTAINERS (IBCs) 6.5.1 General requirements 6.5.1.1 Scope 6.5.1.1.1 The requirements of this Chapter apply to intermediate bulk containers (IBCs) the use of which is expressly authorized for the carriage of certain dangerous goods according to the packing instructions indicated in Column (8) of Table A in Chapter 3.2. Portable tanks and tank-containers which meet the requirements of Chapter 6.7 or 6.8 respectively are not considered to be IBCs. IBCs which meet the requirements of this Chapter are not considered to be containers for the purposes of ADR. The letters IBC only will be used in the rest of the text to refer to intermediate bulk containers. 6.5.1.1.2 Exceptionally, IBCs and their service equipment not conforming strictly to the requirements herein, but having acceptable alternatives, may be considered by the competent authority for approval. In addition, in order to take into account progress in science and technology, the use of alternative arrangements which offer at least equivalent safety in use in respect of compatibility with the properties of the substances carried and equivalent or superior resistance to impact, loading and fire, may be considered by the competent authority. 6.5.1.1.3 The construction, equipment, testing, marking and operation of IBCs shall be subject to acceptance by the competent authority of the country in which the IBCs are approved. NOTE: Parties performing inspections and tests in other countries, after the IBC has been put into service, need not be accepted by the competent authority of the country in which the IBC has been approved, but the inspections and tests have to be performed according to the rules specified in the IBC’s approval. 6.5.1.1.4 Manufacturers and subsequent distributors of IBCs shall provide information regarding procedures to be followed and a description of the types and dimensions of closures (including required gaskets) and any other components needed to ensure that IBCs as presented for carriage are capable of passing the applicable performance tests of this Chapter. 6.5.1.2 (Reserved) 6.5.1.3 (Reserved) 6.5.1.4 Designatory code system for IBCs 6.5.1.4.1 The code shall consist of two Arabic numerals as specified in (a), followed by a capital letter(s) specified in (b), followed, when specified in an individual section, by an Arabic numeral indicating the category of IBC. (a) Type Rigid Flexible For solids, filled or discharged by gravity under pressure of more than 10 kPa (0.1 bar) 11 21 13 - - 369 - For liquids 31 - (b) Materials A. B. C. D. F. G. H. L. M. N. Steel (all types and surface treatments) Aluminium Natural wood Plywood Reconstituted wood Fibreboard Plastics material Textile Paper, multiwall Metal (other than steel or aluminium). 6.5.1.4.2 For composite IBCs, two capital letters in Latin characters shall be used in sequence in the second position of the code. The first shall indicate the material of the inner receptacle of the IBC and the second that of the outer packaging of the IBC. 6.5.1.4.3 The following types and codes of IBC are assigned: Material Category Metal A. Steel for solids, filled or discharged by gravity for solids, filled or discharged under pressure for liquids B. Aluminium for solids, filled or discharged by gravity for solids, filled or discharged under pressure for liquids N. Other than steel for solids, filled or discharged by gravity or aluminium for solids, filled or discharged under pressure for liquids Flexible H. Plastics woven plastics without coating or liner woven plastics, coated woven plastics with liner woven plastics, coated and with liner plastics film L. Textile without coating or liner coated with liner coated and with liner M. Paper multiwall multiwall, water resistant H. Rigid plastics for solids, filled or discharged by gravity, fitted with structural equipment for solids, filled or discharged by gravity, freestanding for solids, filled or discharged under pressure, fitted with structural equipment for solids, filled or discharged under pressure, freestanding for liquids, fitted with structural equipment for liquids, freestanding - 370 - Code 11A 21A 31A 11B 21B 31B 11N 21N 31N 13H1 13H2 13H3 13H4 13H5 13L1 13L2 13L3 13L4 13M1 13M2 11H1 11H2 21H1 21H2 31H1 31H2 Subsection 6.5.5.1 6.5.5.2 6.5.5.3 Material Category Code HZ. Composite with plastics inner receptacle a for solids, filled or discharged by gravity, with rigid plastics inner receptacle for solids, filled or discharged by gravity, with flexible plastics inner receptacle for solids, filled or discharged under pressure, with rigid plastics inner receptacle for solids, filled or discharged under pressure, with flexible plastics inner receptacle for liquids, with rigid plastics inner receptacle for liquids, with flexible plastics inner receptacle for solids, filled or discharged by gravity 11HZ1 for solids, filled or discharged by gravity with inner liner for solids, filled or discharged by gravity, with inner liner for solids, filled or discharged by gravity, with inner liner 11C G. Fibreboard Wooden C. Natural wood D. Plywood F. Reconstituted wood Subsection 11HZ2 21HZ1 6.5.5.4 21HZ2 31HZ1 31HZ2 11G 11D 6.5.5.5 6.5.5.6 11F a The code shall be completed by replacing the letter Z by a capital letter in accordance with 6.5.1.4.1 (b) to indicate the nature of the material used for the outer casing. 6.5.1.4.4 The letter "W" may follow the IBC code. The letter "W" signifies that the IBC, although of the same type indicated by the code, is manufactured to a specification different from those in 6.5.5 and is considered equivalent in accordance with the requirements in 6.5.1.1.2. 6.5.2 Marking 6.5.2.1 Primary marking 6.5.2.1.1 Each IBC manufactured and intended for use according to ADR shall bear markings which are durable, legible and placed in a location so as to be readily visible. Letters, numerals and symbols shall be at least 12 mm high and shall show: (a) The United Nations packaging symbol ; This symbol shall not be used for any purpose other than certifying that a packaging, a portable tank or a MEGC complies with the relevant requirements in Chapter 6.1, 6.2, 6.3, 6.5, 6.6 or 6.71. For metal IBCs on which the marking is stamped or embossed, the capital letters "UN" may be applied instead of the symbol; (b) The code designating the type of IBC according to 6.5.1.4; (c) A capital letter designating the packing group(s) for which the design type has been approved: (i) X for packing groups I, II and III (IBCs for solids only); (ii) Y for packing groups II and III; (iii) Z for packing group III only; 1 This symbol is also used to certify that flexible bulk containers authorized for other modes of transport comply with the requirements in Chapter 6.8 of the UN Model Regulations. - 371 - (d) The month and year (last two digits) of manufacture; (e) The State authorizing the allocation of the mark; indicated by the distinguishing sign for motor vehicles in international traffic2; (f) The name or symbol of the manufacturer and other identification of the IBC as specified by the competent authority; (g) The stacking test load in kg. For IBCs not designed for stacking, the figure "0" shall be shown; (h) The maximum permissible gross mass in kg. The primary marking required above shall be applied in the sequence of the subparagraphs below. The marking required by 6.5.2.2 and any further marking authorized by a competent authority shall still enable the parts of the mark to be correctly identified. Each element of the marking applied in accordance with (a) to (h) and with 6.5.2.2 shall be clearly separated, e.g. by a slash or space, so as to be easily identifiable. 6.5.2.1.2 Examples of markings for various types of IBC in accordance with 6.5.2.1.1 (a) to (h) above: 11A/Y/02 99 NL/Mulder 007 5500/1500 For a metal IBC for solids discharged by gravity and made from steel/for packing groups II and III/ manufactured in February 1999/authorized by the Netherlands/manufactured by Mulder and of a design type to which the competent authority has allocated serial number 007/the stacking test load in kg/the maximum permissible gross mass in kg. 13H3/Z/03 01 F/Meunier 1713 0/1500 For a flexible IBC for solids discharged for instance by gravity and made from woven plastics with a liner/not designed to be stacked. 31H1/Y/04 99 GB/9099 10800/1200 For a rigid plastics IBC for liquids made from plastics with structural equipment withstanding the stack load. 31HA1/Y/05 01 D/Muller 1683 10800/1200 For a composite IBC for liquids with a rigid plastics inner receptacle and a steel outer casing. 11C/X/01 02 S/Aurigny 9876 3000/910 For a wooden IBC for solids with an inner liner authorized for packing groups I, II and III solids. 2 Distinguishing sign for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 372 - 6.5.2.2 Additional marking 6.5.2.2.1 Each IBC shall bear the markings required in 6.5.2.1 and, in addition, the following information which may appear on a corrosion-resistant plate permanently attached in a place readily accessible for inspection: Additional marking Metal Rigid plastics X X X Category of IBC Composite Fibreboard Wooden Capacity in litres a at 20 °C X X a Tare mass in kg X X X X X Test (gauge) pressure, in kPa or bar a, if applicable Maximum filling / discharge X X X pressure in kPa or bar a , if applicable Body material and its X minimum thickness in mm Date of last leakproofness X X X test, if applicable (month and year) Date of last inspection (month X X X and year) Serial number of the X manufacturer Maximum permitted stacking X X X X X load b a The unit used shall be indicated. b See 6.5.2.2.2. This additional marking shall apply to all IBCs manufactured, repaired or remanufactured as from 1 January 2011 (see also 1.6.1.15). 6.5.2.2.2 The maximum permitted stacking load applicable when the IBC is in use shall be displayed on a symbol as shown in Figure 6.5.2.2.2.1 or Figure 6.5.2.2.2.2. The symbol shall be durable and clearly visible. Figure 6.5.2.2.2.1 IBCs capable of being stacked Figure 6.5.2.2.2.2 IBCs NOT capable of being stacked The minimum dimensions shall be 100 mm x 100 mm. The letters and numbers indicating the mass shall be at least 12 mm high. The area within the printer’s marks indicated by the dimensional arrows shall be square. Where dimensions are not specified, all features shall be in approximate proportion to those shown. The mass marked above the symbol shall not exceed the load imposed during the design type test (see 6.5.6.6.4) divided by 1.8. - 373 - 6.5.2.2.3 In addition to the markings required in 6.5.2.1, flexible IBCs may bear a pictogram indicating recommended lifting methods. 6.5.2.2.4 The inner receptacle of composite IBCs manufactured after 1 January 2011 shall bear the markings indicated in 6.5.2.1.1 (b), (c), (d) where this date is that of the manufacture of the plastics inner receptacle, (e) and (f). The UN packaging symbol shall not be applied. The marking shall be applied in the sequence shown in 6.5.2.1.1. It shall be durable, legible and placed in a location so as to be readily visible when the inner receptacle is placed in the outer casing. The date of the manufacture of the plastics inner receptacle may alternatively be marked on the inner receptacle adjacent to the remainder of the marking. In such a case, the two digits of the year in the marking and in the inner circle of the clock shall be identical. An example of an appropriate marking method is: NOTE: Other methods that provide the minimum required information in a durable, visible and legible form are also acceptable. 6.5.2.2.5 Where a composite IBCs is designed in such a manner that the outer casing is intended to be dismantled for carriage when empty (such as for return of the IBC for reuse to the original consignor), each of the parts intended to be detached when so dismantled shall be marked with the month and year of manufacture and the name or symbol of the manufacturer and other identification of the IBC as specified by the competent authority (see 6.5.2.1.1 (f)). 6.5.2.3 Conformity to design type The marking indicates that IBCs correspond to a successfully tested design type and that the requirements referred to in the certificate have been met. 6.5.2.4 Marking of remanufactured composite IBCs (31HZ1) The marking specified in 6.5.2.1.1 and 6.5.2.2 shall be removed from the original IBC or made permanently illegible and new markings shall be applied to an IBC remanufactured in accordance with ADR. 6.5.3 Construction requirements 6.5.3.1 General requirements 6.5.3.1.1 IBCs shall be resistant to or adequately protected from deterioration due to the external environment. 6.5.3.1.2 IBCs shall be so constructed and closed that none of the contents can escape under normal conditions of carriage including the effect of vibration, or by changes in temperature, humidity or pressure. 6.5.3.1.3 IBCs and their closures shall be constructed of materials compatible with their contents, or be protected internally, so that they are not liable: 6.5.3.1.4 (a) To be attacked by the contents so as to make their use dangerous; (b) To cause the contents to react or decompose, or form harmful or dangerous compounds with the IBCs. Gaskets, where used, shall be made of materials not subject to attack by the contents of the IBCs. - 374 - 6.5.3.1.5 All service equipment shall be so positioned or protected as to minimize the risk of escape of the contents owing to damage during handling and carriage. 6.5.3.1.6 IBCs, their attachments and their service and structural equipment shall be designed to withstand, without loss of contents, the internal pressure of the contents and the stresses of normal handling and carriage. IBCs intended for stacking shall be designed for stacking. Any lifting or securing features of IBCs shall be of sufficient strength to withstand the normal conditions of handling and carriage without gross distortion or failure and shall be so positioned that no undue stress is caused in any part of the IBC. 6.5.3.1.7 Where an IBC consists of a body within a framework it shall be so constructed that: (a) The body does not chafe or rub against the framework so as to cause material damage to the body; (b) The body is retained within the framework at all times; (c) The items of equipment are fixed in such a way that they cannot be damaged if the connections between body and frame allow relative expansion or movement. 6.5.3.1.8 Where a bottom discharge valve is fitted, it shall be capable of being made secure in the closed position and the whole discharge system shall be suitably protected from damage. Valves having lever closures shall be able to be secured against accidental opening and the open or closed position shall be readily apparent. For IBCs containing liquids, a secondary means of sealing the discharge aperture shall also be provided, e.g. a blank flange or equivalent device. 6.5.4 Testing, certification and inspection 6.5.4.1 Quality assurance: the IBCs shall be manufactured, remanufactured, repaired and tested under a quality assurance programme which satisfies the competent authority, in order to ensure that each manufactured, remanufactured or repaired IBC meets the requirements of this Chapter. NOTE: ISO 16106:2006 "Packaging – Transport packages for dangerous goods – Dangerous goods packagings, intermediate bulk containers (IBCs) and large packagings – Guidelines for the application of ISO 9001" provides acceptable guidance on procedures which may be followed. 6.5.4.2 Test requirements: IBCs shall be subject to design type tests and, if applicable, to initial and periodic inspections and tests in accordance with 6.5.4.4. 6.5.4.3 Certification: in respect of each design type of IBC a certificate and mark (as in 6.5.2) shall be issued attesting that the design type, including its equipment, meets the test requirements. 6.5.4.4 Inspection and testing NOTE: See also 6.5.4.5 for tests and inspections on repaired IBCs. 6.5.4.4.1 Every metal, rigid plastics and composite IBC shall be inspected to the satisfaction of the competent authority: (a) Before it is put into service (including after remanufactured), and thereafter at intervals not exceeding five years, with regard to: (i) conformity to design type including marking; (ii) internal and external condition; (iii) proper functioning of service equipment. Thermal insulation, if any, need be removed only to the extent necessary for a proper examination of the body of the IBC. - 375 - (b) At intervals of not more than two and a half years, with regard to: (i) external condition; (ii) proper functioning of service equipment. Thermal insulation, if any, need be removed only to the extent necessary for a proper examination of the body of the IBC. Each IBC shall correspond in all respects to its design type. 6.5.4.4.2 Every metal, rigid plastics and composite IBC for liquids, or for solids which are filled or discharged under pressure, shall undergo a suitable leakproofness test at least equally effective as the test prescribed in 6.5.6.7.3 and be capable of meeting the test level indicated in 6.5.6.7.3: (a) Before it is first used for carriage; (b) At intervals of not more than two and a half years. For this test the IBC shall be fitted with the primary bottom closure. The inner receptacle of a composite IBC may be tested without the outer casing, provided that the test results are not affected. 6.5.4.4.3 A report of each inspection and test shall be kept by the owner of the IBC at least until the next inspection or test. The report shall include the results of the inspection and test and shall identify the party performing the inspection and test (see also the marking requirements in 6.5.2.2.1). 6.5.4.4.4 The competent authority may at any time require proof, by tests in accordance with this Chapter, that IBCs meet the requirements of the design type tests. 6.5.4.5 Repaired IBCs 6.5.4.5.1 When an IBC is impaired as a result of impact (e.g. accident) or any other cause, it shall be repaired or otherwise maintained (see definition of "Routine maintenance of IBCs" in 1.2.1), so as to conform to the design type. The bodies of rigid plastics IBCs and the inner receptacles of composite IBCs that are impaired shall be replaced. 6.5.4.5.2 In addition to any other testing and inspection requirements in ADR, an IBC shall be subjected to the full testing and inspection requirements set out in 6.5.4.4, and the required reports shall be prepared, whenever it is repaired. 6.5.4.5.3 The Party performing the tests and inspections after the repair shall durably mark the IBC near the manufacturer's UN design type marking to show: (a) The State in which the tests and inspections were carried out; (b) The name or authorized symbol of the party performing the tests and inspections; and (c) The date (month, year) of the tests and inspections. 6.5.4.5.4 Test and inspections performed in accordance with 6.5.4.5.2 may be considered to satisfy the requirements for the two and a half and five year periodic tests and inspections. 6.5.5 Specific requirements for IBCs 6.5.5.1 Specific requirements for metal IBCs 6.5.5.1.1 These requirements apply to metal IBCs intended for the carriage of solids and liquids. There are three categories of metal IBCs: (a) Those for solids which are filled or discharged by gravity (11A, 11B, 11N); - 376 - (b) Those for solids which are filled or discharged at a gauge pressure greater than 10 kPa (0.1 bar) (21A, 21B, 21N); and (c) Those for liquids (31A, 31B, 31N). 6.5.5.1.2 Bodies shall be made of suitable ductile metal in which the weldability has been fully demonstrated. Welds shall be skilfully made and afford complete safety. Low-temperature performance of the material shall be taken into account when appropriate. 6.5.5.1.3 Care shall be taken to avoid damage by galvanic action due to the juxtaposition of dissimilar metals. 6.5.5.1.4 Aluminium IBCs intended for the carriage of flammable liquids shall have no movable parts, such as covers, closures, etc., made of unprotected steel liable to rust, which might cause a dangerous reaction by coming into frictional or percussive contact with the aluminium. 6.5.5.1.5 Metal IBCs shall be made of metals which meet the following requirements: (a) for steel the elongation at fracture, in %, shall not be less than 10000 with an absolute Rm minimum of 20%; where Rm = guaranteed minimum tensile strength of the steel to be used, in N/mm2; (b) for aluminium and its alloy the elongation at fracture, in %, shall not be less than 10000 with 6Rm an absolute minimum of 8%. Specimens used to determine the elongation at fracture shall be taken transversely to the direction of rolling and be so secured that: Lo = 5d or Lo = 5.65 A where: 6.5.5.1.6 Lo = gauge length of the specimen before the test d = diameter A = cross-sectional area of test specimen. Minimum wall thickness: (a) Capacity (C) in litres C  1000 for a reference steel having a product of Rm  Ao = 10 000, the wall thickness shall not be less than: Wall thickness (T) in mm Types 11A, 11B, 11N Types 21A, 21B, 21N, 31A, 31B, 31N Unprotected Protected Unprotected Protected 2.0 1.5 2.5 2.0 1000 < C  2000 T = C/2000 + 1.5 T = C/2000 + 1.0 T = C/2000 + 2.0 T = C/2000 + 1.5 2000 < C  3000 T = C/2000 + 1.5 T = C/2000 + 1.0 T = C/1000 + 1.0 T = C/2000 + 1.5 - 377 - where: (b) Ao = minimum elongation (as a percentage) of the reference steel to be used on fracture under tensile stress (see 6.5.5.1.5); for metals other than the reference steel described in (a), the minimum wall thickness is given by the following equivalence formula: e1  where: 21.4  e 0 3 Rm 1  A1 e1 = required equivalent wall thickness of the metal to be used (in mm); e0 = required minimum wall thickness for the reference steel (in mm); Rm1 = guaranteed minimum tensile strength of the metal to be used (in N/mm2) (see (c)); A1 minimum elongation (as a percentage) of the metal to be used on fracture under tensile stress (see 6.5.5.1.5). = However, in no case shall the wall thickness be less than 1.5 mm. (c) For purposes of the calculation described in (b), the guaranteed minimum tensile strength of the metal to be used (Rm1) shall be the minimum value according to national or international material standards. However, for austenitic steels, the specified value for Rm according to the material standards may be increased by up to 15% when a greater value is attested in the material inspection certificate. When no material standard exists for the material in question, the value of Rm shall be the minimum value attested in the material inspection certificate. 6.5.5.1.7 Pressure-relief requirements: IBCs for liquids shall be capable of releasing a sufficient amount of vapour in the event of fire engulfment to ensure that no rupture of the body will occur. This can be achieved by conventional pressure relief devices or by other constructional means. The start-todischarge pressure shall not be higher than 65 kPa (0.65 bar) and no lower than the total gauge pressure experienced in the IBC (i.e. the vapour pressure of the filling substance plus the partial pressure of the air or other inert gases, minus 100 kPa (1 bar)) at 55 °C, determined on the basis of a maximum degree of filling as defined in 4.1.1.4. The required relief devices shall be fitted in the vapour space. 6.5.5.2 Specific requirements for flexible IBCs 6.5.5.2.1 These requirements apply to flexible IBCs of the following types: 13H1 13H2 13H3 13H4 13H5 13L1 13L2 13L3 13L4 13M1 13M2 woven plastics without coating or liner woven plastics, coated woven plastics with liner woven plastics, coated and with liner plastics film textile without coating or liner textile, coated textile with liner textile, coated and with liner paper, multiwall paper, multiwall, water resistant Flexible IBCs are intended for the carriage of solids only. 6.5.5.2.2 Bodies shall be manufactured from suitable materials. The strength of the material and the construction of the flexible IBC shall be appropriate to its capacity and its intended use. 6.5.5.2.3 All materials used in the construction of flexible IBCs of types 13M1 and 13M2 shall, after complete immersion in water for not less than 24 hours, retain at least 85% of the tensile strength as measured originally on the material conditioned to equilibrium at 67% relative humidity or less. - 378 - 6.5.5.2.4 Seams shall be formed by stitching, heat sealing, gluing or any equivalent method. All stitched seamends shall be secured. 6.5.5.2.5 Flexible IBCs shall provide adequate resistance to ageing and to degradation caused by ultraviolet radiation or the climatic conditions, or by the substance contained, thereby rendering them appropriate to their intended use. 6.5.5.2.6 For flexible plastics IBCs where protection against ultraviolet radiation is required, it shall be provided by the addition of carbon black or other suitable pigments or inhibitors. These additives shall be compatible with the contents and remain effective throughout the life of the body. Where use is made of carbon black, pigments or inhibitors other than those used in the manufacture of the tested design type, re-testing may be waived if changes in the carbon black content, the pigment content or the inhibitor content do not adversely affect the physical properties of the material of construction. 6.5.5.2.7 Additives may be incorporated into the material of the body to improve the resistance to ageing or to serve other purposes, provided that these do not adversely affect the physical or chemical properties of the material. 6.5.5.2.8 No material recovered from used receptacles shall be used in the manufacture of IBC bodies. Production residues or scrap from the same manufacturing process may, however, be used. Component parts such as fittings and pallet bases may also be used provided such components have not in any way been damaged in previous use. 6.5.5.2.9 When filled, the ratio of height to width shall be not more than 2:1. 6.5.5.2.10 The liner shall be made of a suitable material. The strength of the material used and the construction of the liner shall be appropriate to the capacity of the IBC and the intended use. Joins and closures shall be siftproof and capable of withstanding pressures and impacts liable to occur under normal conditions of handling and carriage. 6.5.5.3 Specific requirements for rigid plastics IBCs 6.5.5.3.1 These requirements apply to rigid plastics IBCs for the carriage of solids or liquids. Rigid plastics IBCs are of the following types: 11H1 11H2 21H1 21H2 31H1 31H2 fitted with structural equipment designed to withstand the whole load when IBCs are stacked, for solids which are filled or discharged by gravity freestanding, for solids which are filled or discharged by gravity fitted with structural equipment designed to withstand the whole load when IBCs are stacked, for solids which are filled or discharged under pressure freestanding, for solids which are filled or discharged under pressure fitted with structural equipment designed to withstand the whole load when IBCs are stacked, for liquids freestanding, for liquids. 6.5.5.3.2 The body shall be manufactured from suitable plastics material of known specifications and be of adequate strength in relation to its capacity and its intended use. The material shall be adequately resistant to ageing and to degradation caused by the substance contained or, where relevant, by ultraviolet radiation. Low temperature performance shall be taken into account when appropriate. Any permeation of the substance contained shall not constitute a danger under normal conditions of carriage. 6.5.5.3.3 Where protection against ultraviolet radiation is required, it shall be provided by the addition of carbon black or other suitable pigments or inhibitors. These additives shall be compatible with the contents and remain effective throughout the life of the body. Where use is made of carbon black, pigments or inhibitors other than those used in the manufacture of the tested design type, re-testing may be waived if changes in the carbon black content, the pigment content or the inhibitor content do not adversely affect the physical properties of the material of construction. 6.5.5.3.4 Additives may be incorporated in the material of the body to improve the resistance to ageing or to serve other purposes, provided that these do not adversely affect the physical or chemical properties of the material. - 379 - 6.5.5.3.5 No used material other than production residues or regrind from the same manufacturing process may be used in the manufacture of rigid plastics IBCs. 6.5.5.4 Specific requirements for composite IBCs with plastics inner receptacles 6.5.5.4.1 These requirements apply to composite IBCs for the carriage of solids and liquids of the following types: 11HZ1 11HZ2 21HZ1 21HZ2 31HZ1 31HZ2 Composite IBCs with a rigid plastics inner receptacle, for solids filled or discharged by gravity Composite IBCs with a flexible plastics inner receptacle, for solids filled or discharged by gravity Composite IBCs with a rigid plastics inner receptacle, for solids filled or discharged under pressure Composite IBCs with a flexible plastics inner receptacle, for solids filled or discharged under pressure Composite IBCs with a rigid plastics inner receptacle, for liquids Composite IBCs with a flexible plastics inner receptacle, for liquids. This code shall be completed by replacing the letter Z by a capital letter in accordance with 6.5.1.4.1 (b) to indicate the nature of the material used for the outer casing. 6.5.5.4.2 The inner receptacle is not intended to perform a containment function without its outer casing. A "rigid" inner receptacle is a receptacle which retains its general shape when empty without closures in place and without benefit of the outer casing. Any inner receptacle that is not "rigid" is considered to be "flexible". 6.5.5.4.3 The outer casing normally consists of rigid material formed so as to protect the inner receptacle from physical damage during handling and carriage but is not intended to perform the containment function. It includes the base pallet where appropriate. 6.5.5.4.4 A composite IBC with a fully enclosing outer casing shall be so designed that the integrity of the inner receptacle may be readily assessed following the leakproofness and hydraulic pressure tests. 6.5.5.4.5 IBCs of type 31HZ2 shall be limited to a capacity of not more than 1 250 litres. 6.5.5.4.6 The inner receptacle shall be manufactured from suitable plastics material of known specifications and be of adequate strength in relation to its capacity and its intended use. The material shall be adequately resistant to ageing and to degradation caused by the substance contained or, where relevant, by ultraviolet radiation. Low temperature performance shall be taken into account when appropriate. Any permeation of the substance contained shall not constitute a danger under normal conditions of carriage. 6.5.5.4.7 Where protection against ultraviolet radiation is required, it shall be provided by the addition of carbon black or other suitable pigments or inhibitors. These additives shall be compatible with the contents and remain effective throughout the life of the inner receptacle. Where use is made of carbon black, pigments or inhibitors, other than those used in the manufacture of the tested design type, retesting may be waived if changes in carbon black content, the pigment content or the inhibitor content do not adversely affect the physical properties of the material of construction. 6.5.5.4.8 Additives may be incorporated in the material of the inner receptacle to improve the resistance to ageing or to serve other purposes, provided that these do not adversely affect the physical or chemical properties of the material. 6.5.5.4.9 No used material other than production residues or regrind from the same manufacturing process may be used in the manufacture of inner receptacles. 6.5.5.4.10 The inner receptacle of IBCs type 31HZ2 shall consist of at least three plies of film. 6.5.5.4.11 The strength of the material and the construction of the outer casing shall be appropriate to the capacity of the composite IBC and its intended use. 6.5.5.4.12 The outer casing shall be free of any projection that might damage the inner receptacle. - 380 - 6.5.5.4.13 Metal outer casings shall be constructed of a suitable metal of adequate thickness. 6.5.5.4.14 Outer casings of natural wood shall be of well seasoned wood, commercially dry and free from defects that would materially lessen the strength of any part of the casing. The tops and bottoms may be made of water resistant reconstituted wood such as hardboard, particle board or other suitable type. 6.5.5.4.15 Outer casings of plywood shall be made of well seasoned rotary cut, sliced or sawn veneer, commercially dry and free from defects that would materially lessen the strength of the casing. All adjacent plies shall be glued with water resistant adhesive. Other suitable materials may be used with plywood for the construction of casings. Casings shall be firmly nailed or secured to corner posts or ends or be assembled by equally suitable devices. 6.5.5.4.16 The walls of outer casings of reconstituted wood shall be made of water resistant reconstituted wood such as hardboard, particle board or other suitable type. Other parts of the casings may be made of other suitable material. 6.5.5.4.17 For fibreboard outer casings, strong and good quality solid or double-faced corrugated fibreboard (single or multiwall) shall be used appropriate to the capacity of the casing and to its intended use. The water resistance of the outer surface shall be such that the increase in mass, as determined in a test carried out over 30 minutes by the Cobb method of determining water absorption, is not greater than 155 g/m2 (see ISO 535:1991). It shall have proper bending qualities. Fibreboard shall be cut, creased without scoring, and slotted so as to permit assembly without cracking, surface breaks or undue bending. The fluting of corrugated fibreboard shall be firmly glued to the facings. 6.5.5.4.18 The ends of fibreboard outer casings may have a wooden frame or be entirely of wood. Reinforcements of wooden battens may be used. 6.5.5.4.19 Manufacturing joins in the fibreboard outer casing shall be taped, lapped and glued, or lapped and stitched with metal staples. Lapped joins shall have an appropriate overlap. Where closing is effected by gluing or taping, a water resistant adhesive shall be used. 6.5.5.4.20 Where the outer casing is of plastics material, the relevant requirements of 6.5.5.4.6 to 6.5.5.4.9 apply, on the understanding that, in this case, the requirements applicable to the inner receptacle are applicable to the outer casing of composite IBCs. 6.5.5.4.21 The outer casing of an IBC type 31HZ2 shall enclose the inner receptacle on all sides. 6.5.5.4.22 Any integral pallet base forming part of an IBC or any detachable pallet shall be suitable for mechanical handling with the IBC filled to its maximum permissible gross mass. 6.5.5.4.23 The pallet or integral base shall be designed so as to avoid any protrusion of the base of the IBC that might be liable to damage in handling. 6.5.5.4.24 The outer casing shall be secured to any detachable pallet to ensure stability in handling and carriage. Where a detachable pallet is used, its top surface shall be free from sharp protrusions that might damage the IBC. 6.5.5.4.25 Strengthening devices such as timber supports to increase stacking performance may be used but shall be external to the inner receptacle. 6.5.5.4.26 Where IBCs are intended for stacking, the bearing surface shall be such as to distribute the load in a safe manner. Such IBCs shall be designed so that the load is not supported by the inner receptacle. 6.5.5.5 Specific requirements for fibreboard IBCs 6.5.5.5.1 These requirements apply to fibreboard IBCs for the carriage of solids which are filled or discharged by gravity. Fibreboard IBCs are of the following type: 11G. 6.5.5.5.2 Fibreboard IBCs shall not incorporate top lifting devices. - 381 - 6.5.5.5.3 The body shall be made of strong and good quality solid or double-faced corrugated fibreboard (single or multiwall), appropriate to the capacity of the IBC and to its intended use. The water resistance of the outer surface shall be such that the increase in mass, as determined in a test carried out over a period of 30 minutes by the Cobb method of determining water absorption, is not greater than 155 g/m2 (see ISO 535:1991). It shall have proper bending qualities. Fibreboard shall be cut, creased without scoring, and slotted so as to permit assembly without cracking, surface breaks or undue bending. The fluting or corrugated fibreboard shall be firmly glued to the facings. 6.5.5.5.4 The walls, including top and bottom, shall have a minimum puncture resistance of 15 J measured according to ISO 3036:1975. 6.5.5.5.5 Manufacturing joins in the body of IBCs shall be made with an appropriate overlap and shall be taped, glued, stitched with metal staples or fastened by other means at least equally effective. Where joins are effected by gluing or taping, a water resistant adhesive shall be used. Metal staples shall pass completely through all pieces to be fastened and be formed or protected so that any inner liner cannot be abraded or punctured by them. 6.5.5.5.6 The liner shall be made of a suitable material. The strength of the material used and the construction of the liner shall be appropriate to the capacity of the IBC and the intended use. Joins and closures shall be siftproof and capable of withstanding pressures and impacts liable to occur under normal conditions of handling and carriage. 6.5.5.5.7 Any integral pallet base forming part of an IBC or any detachable pallet shall be suitable for mechanical handling with the IBC filled to its maximum permissible gross mass. 6.5.5.5.8 The pallet or integral base shall be designed so as to avoid any protrusion of the base of the IBC that might be liable to damage in handling. 6.5.5.5.9 The body shall be secured to any detachable pallet to ensure stability in handling and carriage. Where a detachable pallet is used, its top surface shall be free from sharp protrusions that might damage the IBC. 6.5.5.5.10 Strengthening devices such as timber supports to increase stacking performance may be used but shall be external to the liner. 6.5.5.5.11 Where IBCs are intended for stacking, the bearing surface shall be such as to distribute the load in a safe manner. 6.5.5.6 Specific requirements for wooden IBCs 6.5.5.6.1 These requirements apply to wooden IBCs for the carriage of solids which are filled or discharged by gravity. Wooden IBCs are of the following types: 11C 11D 11F Natural wood with inner liner Plywood with inner liner Reconstituted wood with inner liner. 6.5.5.6.2 Wooden IBCs shall not incorporate top lifting devices. 6.5.5.6.3 The strength of the materials used and the method of construction of the body shall be appropriate to the capacity and intended use of the IBC. 6.5.5.6.4 Natural wood shall be well seasoned, commercially dry and free from defects that would materially lessen the strength of any part of the IBC. Each part of the IBC shall consist of one piece or be equivalent thereto. Parts are considered equivalent to one piece when a suitable method of glued assembly is used (as for instance Lindermann joint, tongue and groove joint, ship lap or rabbet joint); or butt joint with at least two corrugated metal fasteners at each joint, or when other methods at least equally effective are used. - 382 - 6.5.5.6.5 Bodies of plywood shall be at least 3-ply. They shall be made of well seasoned rotary cut, sliced or sawn veneer, commercially dry and free from defects that would materially lessen the strength of the body. All adjacent plies shall be glued with water resistant adhesive. Other suitable materials may be used with plywood for the construction of the body. 6.5.5.6.6 Bodies of reconstituted wood shall be made of water resistant reconstituted wood such as hardboard, particle board or other suitable type. 6.5.5.6.7 IBCs shall be firmly nailed or secured to corner posts or ends or be assembled by equally suitable devices. 6.5.5.6.8 The liner shall be made of a suitable material. The strength of the material used and the construction of the liner shall be appropriate to the capacity of the IBC and the intended use. Joins and closures shall be siftproof and capable of withstanding pressures and impacts liable to occur under normal conditions of handling and carriage. 6.5.5.6.9 Any integral pallet base forming part of an IBC or any detachable pallet shall be suitable for mechanical handling with the IBC filled to its maximum permissible gross mass. 6.5.5.6.10 The pallet or integral base shall be designed so as to avoid any protrusion of the base of the IBC that might be liable to damage in handling. 6.5.5.6.11 The body shall be secured to any detachable pallet to ensure stability in handling and carriage. Where a detachable pallet is used, its top surface shall be free from sharp protrusions that might damage the IBC. 6.5.5.6.12 Strengthening devices such as timber supports to increase stacking performance may be used but shall be external to the liner. 6.5.5.6.13 Where IBCs are intended for stacking, the bearing surface shall be such as to distribute the load in a safe manner. 6.5.6 Test requirements for IBCs 6.5.6.1 Performance and frequency of tests 6.5.6.1.1 Each IBC design type shall successfully pass the tests prescribed in this Chapter before being used and being approved by the competent authority allowing the allocation of the mark. An IBC design type is defined by the design, size, material and thickness, manner of construction and means of filling and discharging but may include various surface treatments. It also includes IBCs which differ from the design type only in their lesser external dimensions. 6.5.6.1.2 Tests shall be carried out on IBCs prepared for carriage. IBCs shall be filled as indicated in the relevant sections. The substances to be carried in the IBCs may be replaced by other substances except where this would invalidate the results of the tests. For solids, when another substance is used it shall have the same physical characteristics (mass, grain size, etc.) as the substance to be carried. It is permissible to use additives, such as bags of lead shot, to achieve the requisite total package mass, so long as they are placed so that the test results are not affected. 6.5.6.2 Design type tests 6.5.6.2.1 One IBC of each design type, size, wall thickness and manner of construction shall be submitted to the tests listed in the order shown in 6.5.6.3.7 and as set out in 6.5.6.4 to 6.5.6.13. These design type tests shall be carried out as required by the competent authority. 6.5.6.2.2 To prove sufficient chemical compatibility with the contained goods or standard liquids in accordance with 6.5.6.3.3 or 6.5.6.3.5 for rigid plastics IBCs of type 31H2 and for composite IBCs of types 31HH1 and 31HH2, a second IBC can be used when the IBCs are designed to be stacked. In such case both IBCs shall be subjected to a preliminary storage. 6.5.6.2.3 The competent authority may permit the selective testing of IBCs which differ only in minor respects from a tested type, e.g. with small reductions in external dimensions. - 383 - 6.5.6.2.4 If detachable pallets are used in the tests, the test report issued in accordance with 6.5.6.14 shall include a technical description of the pallets used. 6.5.6.3 Preparation of IBCs for testing 6.5.6.3.1 Paper and fibreboard IBCs and composite IBCs with fibreboard outer casings shall be conditioned for at least 24 hours in an atmosphere having a controlled temperature and relative humidity (r.h.). There are three options, one of which shall be chosen. The preferred atmosphere is 23  2 °C and 50%  2% r.h. The two other options are 20  2 °C and 65%  2% r.h.; or 27  2 °C and 65%  2% r.h. NOTE: Average values shall fall within these limits. Short-term fluctuations and measurement limitations may cause individual measurements to vary by up to  5% relative humidity without significant impairment of test reproducibility. 6.5.6.3.2 Additional steps shall be taken to ascertain that the plastics material used in the manufacture of rigid plastics IBCs (types 31H1 and 31H2) and composite IBCs (types 31HZ1 and 31HZ2) complies respectively with the requirements in 6.5.5.3.2 to 6.5.5.3.4 and 6.5.5.4.6 to 6.5.5.4.9. 6.5.6.3.3 To prove there is sufficient chemical compatibility with the contained goods, the sample IBC shall be subjected to a preliminary storage for six months, during which the samples shall remain filled with the substances they are intended to contain or with substances which are known to have at least as severe a stress-cracking, weakening or molecular degradation influence on the plastics materials in question, and after which the samples shall be submitted to the applicable tests listed in the table in 6.5.6.3.7. 6.5.6.3.4 Where the satisfactory behaviour of the plastics material has been established by other means, the above compatibility test may be dispensed with. Such procedures shall be at least equivalent to the above compatibility test and recognized by the competent authority. 6.5.6.3.5 For polyethylene rigid plastics IBCs (types 31H1 and 31H2) in accordance with 6.5.5.3 and composite IBCs with polyethylene inner receptacle (types 31HZ1 and 31HZ2) in accordance with 6.5.5.4, chemical compatibility with filling liquids assimilated in accordance with 4.1.1.21 may be verified as follows with standard liquids (see 6.1.6). The standard liquids are representative for the processes of deterioration on polyethylene, as there are softening through swelling, cracking under stress, molecular degradation and combinations thereof. The sufficient chemical compatibility of the IBCs may be verified by storage of the required test samples for three weeks at 40 °C with the appropriate standard liquid(s); where this standard liquid is water, storage in accordance with this procedure is not required. Storage is not required either for test samples which are used for the stacking test in case of the standard liquids wetting solution and acetic acid. After this storage, the test samples shall undergo the tests prescribed in 6.5.6.4 to 6.5.6.9. The compatibility test for tert-Butyl hydroperoxide with more than 40% peroxide content and peroxyacetic acids of Class 5.2 shall not be carried out using standard liquids. For these substances, sufficient chemical compatibility of the test samples shall be verified during a storage period of six months at ambient temperature with the substances they are intended to carry. Results of the procedure in accordance with this paragraph from polyethylene IBCs can be approved for an equal design type, the internal surface of which is fluorinated. 6.5.6.3.6 For IBC design types, made of polyethylene, as specified in 6.5.6.3.5, which have passed the test in 6.5.6.3.5, the chemical compatibility with filling substances may also be verified by laboratory tests proving that the effect of such filling substances on the test specimens is less than that of the appropriate standard liquid(s) taking into account the relevant processes of deterioration. The same conditions as those set out in 4.1.1.21.2 shall apply with respect to relative density and vapour pressure. - 384 - 6.5.6.3.7 Type of IBC Metal: 11A, 11B, 11N 21A, 21B, 21N 31A, 31B, 31N Flexible d Rigid plastics: 11H1, 11H2 21H1, 21H2 31H1, 31H2 Composite: 11HZ1, 11HZ2 21HZ1, 21HZ2 31HZ1, 31HZ2 Fibreboard Wooden a b c d e f g Design type tests required and sequential order Vibration f Bottom lift Top lift a Stacking 1st - 1st a 1st a 2nd a - 2nd 2nd 3rd xc 3rd 3rd 4th x 4th 5th - 5th 6th - 4th e 6th e 7th e x x x x 1st 1st a 1st a 2nd a 2nd 2nd 3rd 3rd 3rd 4th g 4th 5th 5th 6th 4th 6th 7th - - - 1st - 1st a 1st a 2nd a 1st 1st 2nd 2nd 3rd - 3rd 3rd 4th g 2nd 2nd 4th 5th - 5th 6th - 4th e 6th e 7th e 3rd 3rd - - - b Leak- Hydraulic Drop Tear Topple Righting c proofness pressure When IBCs are designed for this method of handling. When IBCs are designed to be stacked. When IBCs are designed to be lifted from the top or the side. Required test indicated by x; an IBC which has passed one test may be used for other tests, in any order. Another IBC of the same design may be used for the drop test. Another IBC of the same design may be used for the vibration test. The second IBC in accordance with 6.5.6.2.2 can be used out of the sequential order direct after the preliminary storage. 6.5.6.4 Bottom lift test 6.5.6.4.1 Applicability For all fibreboard and wooden IBCs, and for all types of IBC which are fitted with means of lifting from the base, as a design type test. 6.5.6.4.2 Preparation of the IBC for test The IBC shall be filled. A load shall be added and evenly distributed. The mass of the filled IBC and the load shall be 1.25 times the maximum permissible gross mass. 6.5.6.4.3 Method of testing The IBC shall be raised and lowered twice by a lift truck with the forks centrally positioned and spaced at three quarters of the dimension of the side of entry (unless the points of entry are fixed). The forks shall penetrate to three quarters of the direction of entry. The test shall be repeated from each possible direction of entry. 6.5.6.4.4 Criteria for passing the test No permanent deformation which renders the IBC, including the base pallet, if any, unsafe for carriage and no loss of contents. 6.5.6.5 Top lift test 6.5.6.5.1 Applicability For all types of IBC which are designed to be lifted from the top and for flexible IBCs designed to be lifted from the top or the side, as a design type test. - 385 - 6.5.6.5.2 Preparation of the IBC for test Metal, rigid plastics and composite IBCs shall be filled. A load shall be added and evenly distributed. The mass of the filled IBC and the load shall be twice the maximum permissible gross mass. Flexible IBCs shall be filled with a representative material and then shall be loaded to six times their maximum permissible gross mass, the load being evenly distributed. 6.5.6.5.3 Methods of testing Metal and flexible IBCs shall be lifted in the manner for which they are designed until clear of the floor and maintained in that position for a period of five minutes. Rigid plastics and composite IBCs shall be lifted: (a) by each pair of diagonally opposite lifting devices, so that the hoisting forces are applied vertically, for a period of five minutes; and (b) by each pair of diagonally opposite lifting devices, so that the hoisting forces are applied toward the centre at 45º to the vertical, for a period of five minutes. 6.5.6.5.4 Other methods of top lift testing and preparation at least equally effective may be used for flexible IBCs. 6.5.6.5.5 Criteria for passing the test (a) Metal, rigid plastics and composite IBCs: the IBC remains safe for normal conditions of carriage, there is no observable permanent deformation of the IBC, including the base pallet, if any, and no loss of contents; (b) Flexible IBCs: no damage to the IBC or its lifting devices which renders the IBC unsafe for carriage or handling and no loss of contents. 6.5.6.6 Stacking test 6.5.6.6.1 Applicability For all types of IBC which are designed to be stacked on each other, as a design type test. 6.5.6.6.2 Preparation of the IBC for test The IBC shall be filled to its maximum permissible gross mass. If the specific gravity of the product being used for testing makes this impracticable, the IBC shall additionally be loaded so that it is tested at its maximum permissible gross mass the load being evenly distributed. 6.5.6.6.3 Method of testing (a) The IBC shall be placed on its base on level hard ground and subjected to a uniformly distributed superimposed test load (see 6.5.6.6.4). For rigid plastics IBCs of type 31H2 and composite IBCs of types 31HH1 and 31HH2, a stacking test shall be carried out with the original filling substance or a standard liquid (see 6.1.6) in accordance with 6.5.6.3.3 or 6.5.6.3.5 using the second IBC in accordance with 6.5.6.2.2 after the preliminary storage. IBCs shall be subjected to the test load for a period of at least: (i) 5 minutes, for metal IBCs; (ii) 28 days at 40 ºC, for rigid plastics IBCs of types 11H2, 21H2 and 31H2 and for composite IBCs with outer casings of plastics material which bear the stacking load (i.e., types 11HH1, 11HH2, 21HH1, 21HH2, 31HH1 and 31HH2); (iii) 24 hours, for all other types of IBCs; - 386 - (b) 6.5.6.6.4 The load shall be applied by one of the following methods: (i) one or more IBCs of the same type filled to the maximum permissible gross mass stacked on the test IBC; (ii) appropriate weights loaded on to either a flat plate or a reproduction of the base of the IBC, which is stacked on the test IBC. Calculation of superimposed test load The load to be placed on the IBC shall be 1.8 times the combined maximum permissible gross mass of the number of similar IBCs that may be stacked on top of the IBC during carriage. 6.5.6.6.5 Criteria for passing the test (a) All types of IBCs other than flexible IBCs: no permanent deformation which renders the IBC including the base pallet, if any, unsafe for carriage and no loss of contents; (b) Flexible IBCs: no deterioration of the body which renders the IBC unsafe for carriage and no loss of contents. 6.5.6.7 Leakproofness test 6.5.6.7.1 Applicability For those types of IBC used for liquids or for solids filled or discharged under pressure, as a design type test and periodic test. 6.5.6.7.2 Preparation of the IBC for test The test shall be carried out before the fitting of any thermal insulation equipment. Vented closures shall either be replaced by similar non-vented closures or the vent shall be sealed. 6.5.6.7.3 Method of testing and pressure to be applied The test shall be carried out for a period of at least 10 minutes using air at a gauge pressure of not less than 20 kPa (0.2 bar). The air tightness of the IBC shall be determined by a suitable method such as by air-pressure differential test or by immersing the IBC in water or, for metal IBCs, by coating the seams and joints with a soap solution. In the case of immersing a correction factor shall be applied for the hydrostatic pressure. 6.5.6.7.4 Criterion for passing the test No leakage of air. 6.5.6.8 Internal pressure (hydraulic) test 6.5.6.8.1 Applicability For those types of IBCs used for liquids or for solids filled or discharged under pressure, as a design type test. 6.5.6.8.2 Preparation of the IBC for test The test shall be carried out before the fitting of any thermal insulation equipment. Pressure-relief devices shall be removed and their apertures plugged, or shall be rendered inoperative. 6.5.6.8.3 Method of testing The test shall be carried out for a period of at least 10 minutes applying a hydraulic pressure not less than that indicated in 6.5.6.8.4. The IBCs shall not be mechanically restrained during the test. - 387 - 6.5.6.8.4 Pressures to be applied 6.5.6.8.4.1 Metal IBCs: 6.5.6.8.4.2 (a) For IBCs of types 21A, 21B and 21N, for packing group I solids, a 250 kPa (2.5 bar) gauge pressure; (b) For IBCs of types 21A, 21B, 21N, 31A, 31B and 31N, for packing groups II or III substances, a 200 kPa (2 bar) gauge pressure; (c) In addition, for IBCs of types 31A, 31B and 31N, a 65kPa (0.65 bar) gauge pressure. This test shall be performed before the 200 kPa (2 bar) test. Rigid plastics and composite IBCs: (a) For IBCs of types 21H1, 2lH2, 21HZ1 and 21HZ2: 75 kPa (0.75 bar) (gauge); (b) For IBCs of types 31H1, 31H2, 31HZ1 and 31HZ2: whichever is the greater of two values, the first as determined by one of the following methods: (i) the total gauge pressure measured in the IBC (i.e. the vapour pressure of the filling substance and the partial pressure of the air or other inert gases, minus 100 kPa) at 55 °C multiplied by a safety factor of 1.5; this total gauge pressure shall be determined on the basis of a maximum degree of filling in accordance with 4.1.1.4 and a filling temperature of 15 °C; (ii) 1.75 times the vapour pressure at 50 °C of the substance to be carried minus 100 kPa, but with a minimum test pressure of 100 kPa; (iii) 1.5 times the vapour pressure at 55 °C of the substance to be carried minus 100 kPa, but with a minimum test pressure of 100 kPa; and the second as determined by the following method: (iv) 6.5.6.8.5 twice the static pressure of the substance to be carried, with a minimum of twice the static pressure of water; Criteria for passing the test(s): (a) For IBCs of types 21A, 21B, 21N, 31A, 31B and 31N, when subjected to the test pressure specified in 6.5.6.8.4.1 (a) or (b): no leakage; (b) For IBCs of types 31A, 31B and 31N, when subjected to the test pressure specified in 6.5.6.8.4.1 (c): no permanent deformation which renders the IBC unsafe for carriage and no leakage; (c) For rigid plastics and composite IBCs: no permanent deformation which would render the IBC unsafe for carriage and no leakage. 6.5.6.9 Drop test 6.5.6.9.1 Applicability For all types of IBCs, as a design type test. 6.5.6.9.2 Preparation of the IBC for test (a) Metal IBCs: the IBC shall be filled to not less than 95% of its maximum capacity for solids or 98% of its maximum capacity for liquids. Pressure-relief devices shall be removed and their apertures plugged, or shall be rendered inoperative; (b) Flexible IBCs: the IBC shall be filled to the maximum permissible gross mass, the contents being evenly distributed; - 388 - 6.5.6.9.3 (c) Rigid plastics and composite IBCs: the IBC shall be filled to not less than 95% of its maximum capacity for solids or 98% of its maximum capacity for liquids. Arrangements provided for pressure relief may be removed and plugged or rendered inoperative. Testing of IBCs shall be carried out when the temperature of the test sample and its contents has been reduced to minus 18 °C or lower. Where test samples of composite IBCs are prepared in this way the conditioning specified in 6.5.6.3.1 may be waived. Test liquids shall be kept in the liquid state, if necessary by the addition of anti-freeze. This conditioning may be disregarded if the materials in question are of sufficient ductility and tensile strength at low temperatures; (d) Fibreboard and wooden IBCs: The IBC shall be filled to not less than 95% of its maximum capacity. Method of testing The IBC shall be dropped on its base onto a non-resilient, horizontal, flat, massive and rigid surface in conformity with the requirements of 6.1.5.3.4, in such a manner as to ensure that the point of impact is that part of the base of the IBC considered to be the most vulnerable. IBCs of 0.45 m3 or less capacity shall also be dropped: (a) Metal IBCs: on the most vulnerable part other than the part of the base tested in the first drop; (b) Flexible IBCs: on the most vulnerable side; (c) Rigid plastics, composite, fibreboard and wooden IBCs: flat on a side, flat on the top and on a corner. The same or different IBCs may be used for each drop. 6.5.6.9.4 Drop height For solids and liquids, if the test is performed with the solid or liquid to be carried or with another substance having essentially the same physical characteristics: Packing group I 1.8 m Packing group II 1.2 m Packing group III 0.8 m For liquids if the test is performed with water: (a) Where the substances to be carried have a relative density not exceeding 1.2: Packing group II 1.2 m (b) Where the substances to be carried have a relative density exceeding 1.2, the drop heights shall be calculated on the basis of the relative density (d) of the substance to be carried rounded up to the first decimal as follows: Packing group II d × 1.0 m 6.5.6.9.5 Packing group III 0.8 m Packing group III d × 0.67 m Criteria for passing the test(s): (a) Metal IBCs: no loss of contents; (b) Flexible IBCs: no loss of contents. A slight discharge, e.g. from closures or stitch holes, upon impact shall not be considered to be a failure of the IBC provided that no further leakage occurs after the IBC has been raised clear of the ground; (c) Rigid plastics, composite, fibreboard and wooden IBCs: no loss of contents. A slight discharge from a closure upon impact shall not be considered to be a failure of the IBC provided that no further leakage occurs; - 389 - (d) All IBCs: no damage which renders the IBC unsafe to be carried for salvage or for disposal, and no loss of contents. In addition, the IBC shall be capable of being lifted by an appropriate means until clear of the floor for five minutes. NOTE: The criteria in (d) apply to design types for IBCs manufactured as from 1 January 2011. 6.5.6.10 Tear test 6.5.6.10.1 Applicability For all types of flexible IBCs, as a design type test. 6.5.6.10.2 Preparation of the IBC for test The IBC shall be filled to not less than 95% of its capacity and to its maximum permissible gross mass, the contents being evenly distributed. 6.5.6.10.3 Method of testing Once the IBC is placed on the ground, a 100 mm knife score, completely penetrating the wall of a wide face, is made at a 45° angle to the principal axis of the IBC, halfway between the bottom surface and the top level of the contents. The IBC shall then be subjected to a uniformly distributed superimposed load equivalent to twice the maximum permissible gross mass. The load shall be applied for at least five minutes. An IBC which is designed to be lifted from the top or the side shall then, after removal of the superimposed load, be lifted clear of the floor and maintained in that position for a period of five minutes. 6.5.6.10.4 Criteria for passing the test The cut shall not propagate more than 25% of its original length. 6.5.6.11 Topple test 6.5.6.11.1 Applicability For all types of flexible IBC, as a design type test. 6.5.6.11.2 Preparation of the IBC for test The IBC shall be filled to not less than 95% of its capacity and to its maximum permissible gross mass, the contents being evenly distributed. 6.5.6.11.3 Method of testing The IBC shall be caused to topple on to any part of its top on to a rigid, non-resilient, smooth, flat and horizontal surface. 6.5.6.11.4 Topple height Packing group I 1.8 m 6.5.6.11.5 Packing group II 1.2 m Packing group III 0.8 m Criteria for passing the test No loss of contents. A slight discharge, e.g. from closures or stitch holes, upon impact shall not be considered to be a failure of the IBC provided that no further leakage occurs. - 390 - 6.5.6.12 Righting test 6.5.6.12.1 Applicability For all flexible IBCs designed to be lifted from the top or side, as a design type test. 6.5.6.12.2 Preparation of the IBC for test The IBC shall be filled to not less than 95% of its capacity and to its maximum permissible gross mass, the contents being evenly distributed. 6.5.6.12.3 Method of testing The IBC, lying on its side, shall be lifted at a speed of at least 0.1 m/s to upright position, clear of the floor, by one lifting device or by two lifting devices when four are provided. 6.5.6.12.4 Criteria for passing the test No damage to the IBC or its lifting devices which renders the IBC unsafe for carriage or handling. 6.5.6.13 Vibration test 6.5.6.13.1 Applicability For all IBCs used for liquids, as a design type test. NOTE: This test applies to design types for IBCs manufactured after 31 December 2010 (see also 1.6.1.14). 6.5.6.13.2 Preparation of the IBC for test A sample IBC shall be selected at random and shall be fitted and closed as for carriage. The IBC shall be filled with water to not less than 98% of its maximum capacity. 6.5.6.13.3 Test method and duration 6.5.6.13.3.1 The IBC shall be placed in the center of the test machine platform with a vertical sinusoidal, double amplitude (peak-to peak displacement) of 25 mm  5%. If necessary, restraining devices shall be attached to the platform to prevent the specimen from moving horizontally off the platform without restricting vertical movement. 6.5.6.13.3.2 The test shall be conducted for one hour at a frequency that causes part of the base of the IBC to be momentarily raised from the vibrating platform for part of each cycle to such a degree that a metal shim can be completely inserted intermittently at, at least, one point between the base of the IBC and the test platform. The frequency may need to be adjusted after the initial set point to prevent the packaging from going into resonance. Nevertheless, the test frequency shall continue to allow placement of the metal shim under the IBC as described in this paragraph. The continuing ability to insert the metal shim is essential to passing the test. The metal shim used for this test shall be at least 1.6 mm thick, 50 mm wide, and be of sufficient length to be inserted between the IBC and the test platform a minimum of 100 mm to perform the test. 6.5.6.13.4 Criteria for passing the test No leakage or rupture shall be observed. In addition, no breakage or failure of structural components, such as broken welds or failed fastenings, shall be observed. - 391 - 6.5.6.14 Test report 6.5.6.14.1 A test report containing at least the following particulars shall be drawn up and shall be made available to the users of the IBC: 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 6.5.6.14.2 Name and address of the test facility; Name and address of applicant (where appropriate); A unique test report identification; Date of the test report; Manufacturer of the IBC; Description of the IBC design type (e.g. dimensions, materials, closures, thickness, etc.) including method of manufacture (e.g. blow moulding) and which may include drawing(s) and/or photograph(s); Maximum capacity; Characteristics of test contents, e.g. viscosity and relative density for liquids and particle size for solids; Test descriptions and results; The test report shall be signed with the name and status of the signatory. The test report shall contain statements that the IBC prepared as for carriage was tested in accordance with the appropriate requirements of this Chapter and that the use of other packaging methods or components may render it invalid. A copy of the test report shall be available to the competent authority. - 392 - CHAPTER 6.6 REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF LARGE PACKAGINGS 6.6.1 General 6.6.1.1 The requirements of this Chapter do not apply to: 6.6.1.2 - packagings for Class 2, except large packagings for articles, including aerosols; - packagings for Class 6.2, except large packagings for clinical waste of UN No. 3291; - Class 7 packages containing radioactive material. Large packagings shall be manufactured, tested and remanufactured under a quality assurance programme which satisfies the competent authority in order to ensure that each manufactured or remanufactured large packaging meets the requirements of this Chapter. NOTE: ISO 16106:2006 "Packaging – Transport packages for dangerous goods – Dangerous goods packagings, intermediate bulk containers (IBCs) and large packagings – Guidelines for the application of ISO 9001" provides acceptable guidance on procedures which may be followed. 6.6.1.3 The specific requirements for large packagings in 6.6.4 are based on large packagings currently used. In order to take into account progress in science and technology, there is no objection to the use of large packagings having specifications different from those in 6.6.4 provided they are equally effective, acceptable to the competent authority and able successfully to withstand the tests described in 6.6.5. Methods of testing other than those described in ADR are acceptable provided they are equivalent and are recognized by the competent authority. 6.6.1.4 Manufacturers and subsequent distributors of packagings shall provide information regarding procedures to be followed and a description of the types and dimensions of closures (including required gaskets) and any other components needed to ensure that packages as presented for carriage are capable of passing the applicable performance tests of this Chapter. 6.6.2 Code for designating types of large packagings 6.6.2.1 The code used for large packagings consist of: (a) Two Arabic numerals: 50 for rigid large packagings; or 51 for flexible large packagings; and (b) 6.6.2.2 A capital letter in Latin character indicating the nature of the material, e.g. wood, steel etc. The capital letters used shall be those shown in 6.1.2.6. The letters "T" or "W" may follow the Large Packaging code. The letter "T" signifies a large salvage packaging conforming to the requirements of 6.6.5.1.9. The letter "W" signifies that the large packaging, although of the same type indicated by the code, is manufactured to a specification different from those in 6.6.4 and is considered equivalent in accordance with the requirements in 6.6.1.3. - 393 - 6.6.3 Marking 6.6.3.1 Primary marking Each large packaging manufactured and intended for use in accordance with the provisions of ADR shall bear markings which are durable, legible and placed in a location so as to be readily visible. Letters, numerals and symbols shall be at least 12 mm high and shall show: (a) The United Nations packaging symbol ; This symbol shall not be used for any purpose other than certifying that a packaging, a portable tank or a MEGC complies with the relevant requirements in Chapter 6.1, 6.2, 6.3, 6.5, 6.6 or 6.71. For metal large packagings on which the marking is stamped or embossed, the capital letters "UN" may be applied instead of the symbol; (b) The number "50" designating a large rigid packaging or "51" for flexible large packagings, followed by the material type in accordance with 6.5.1.4.1 (b); (c) A capital letter designating the packing group(s) for which the design type has been approved: X for packing groups I, II and III Y for packing groups II and III Z for packing group III only; (d) The month and year (last two digits) of manufacture; (e) The State authorizing the allocation of the mark; indicated by the distinguishing sign for motor vehicles in international traffic2; (f) The name or symbol of the manufacturer and other identification of the large packagings as specified by the competent authority; (g) The stacking test load in kg. For large packagings not designed for stacking the figure "0" shall be shown; (h) The maximum permissible gross mass in kilograms. The primary marking required above shall be applied in the sequence of the sub-paragraphs. Each element of the marking applied in accordance with (a) to (h) shall be clearly separated, e.g. by a slash or space, so as to be easily identifiable. 1 This symbol is also used to certify that flexible bulk containers authorized for other modes of transport comply with the requirements in Chapter 6.8 of the UN Model Regulations. 2 Distinguishing sign for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). - 394 - 6.6.3.2 6.6.3.3 Examples of the marking: 50A/X/05 01/N/PQRS 2500/1000 For a large steel packaging suitable for stacking; stacking load: 2 500 kg; maximum gross mass: 1 000 kg. 50H/Y/04 02/D/ABCD 987 0/800 For a large plastics packaging not suitable for stacking; maximum gross mass: 800 kg. 51H/Z/06 01/S/1999 0/500 For a large flexible packaging not suitable for stacking; maximum gross mass: 500 kg. 50AT/Y/05/01/B/PQRS 2500/1000 For a large steel salvage packaging suitable for stacking; stacking load: 2 500 kg; maximum gross mass: 1 000 kg. The maximum permitted stacking load applicable when the large packaging is in use shall be displayed on a symbol as shown in Figure 6.6.3.3.1 or Figure 6.6.3.3.2. The symbol shall be durable and clearly visible. Figure 6.6.3.3.1 Figure 6.6.3.3.2 Large packagings capable of being stacked Large packagings NOT capable of being stacked The minimum dimensions shall be 100 mm x 100 mm. The letters and numbers indicating the mass shall be at least 12 mm high. The area within the printer’s marks indicated by the dimensional arrows shall be square. Where dimensions are not specified, all features shall be in approximate proportion to those shown. The mass marked above the symbol shall not exceed the load imposed during the design type test (see 6.6.5.3.3.4) divided by 1.8. 6.6.4 Specific requirements for large packagings 6.6.4.1 Specific requirements for metal large packagings 50A 50B 50N steel aluminium metal (other than steel or aluminium) 6.6.4.1.1 The large packaging shall be made of suitable ductile metal in which the weldability has been fully demonstrated. Welds shall be skilfully made and afford complete safety. Low-temperature performance shall be taken into account when appropriate. 6.6.4.1.2 Care shall be taken to avoid damage by galvanic action due to the juxtaposition of dissimilar metals. 6.6.4.2 Specific requirements for flexible material large packagings 51H flexible plastics 51M flexible paper - 395 - 6.6.4.2.1 The large packaging shall be manufactured from suitable materials. The strength of the material and the construction of the flexible large packagings shall be appropriate to its capacity and its intended use. 6.6.4.2.2 All materials used in the construction of flexible large packagings of types 51M shall, after complete immersion in water for not less than 24 hours, retain at least 85% of the tensile strength as measured originally on the material conditioned to equilibrium at 67% relative humidity or less. 6.6.4.2.3 Seams shall be formed by stitching, heat sealing, glueing or any equivalent method. All stitched seam-ends shall be secured. 6.6.4.2.4 Flexible large packagings shall provide adequate resistance to ageing and to degradation caused by ultraviolet radiation or the climatic conditions, or by the substance contained, thereby rendering them appropriate to their intended use. 6.6.4.2.5 For plastics flexible large packagings where protection against ultraviolet radiation is required, it shall be provided by the addition of carbon black or other suitable pigments or inhibitors. These additives shall be compatible with the contents and remain effective throughout the life of the large packaging. Where use is made of carbon black, pigments or inhibitors other than those used in the manufacture of the tested design type, re-testing may be waived if changes in the carbon black content, the pigment content or the inhibitor content do not adversely affect the physical properties of the material of construction. 6.6.4.2.6 Additives may be incorporated into the material of the large packaging to improve the resistance to ageing or to serve other purposes, provided that these do not adversely affect the physical or chemical properties of the material. 6.6.4.2.7 When filled, the ratio of height to width shall be not more than 2:1. 6.6.4.3 Specific requirements for plastics large packagings 50H rigid plastics 6.6.4.3.1 The large packaging shall be manufactured from suitable plastics material of known specifications and be of adequate strength in relation to its capacity and its intended use. The material shall be adequately resistant to ageing and to degradation caused by the substance contained or, where relevant, by ultraviolet radiation. Low temperature performance shall be taken into account when appropriate. Any permeation of the substance contained shall not constitute a danger under normal conditions of carriage. 6.6.4.3.2 Where protection against ultraviolet radiation is required, it shall be provided by the addition of carbon black or other suitable pigments or inhibitors. These additives shall be compatible with the contents and remain effective throughout the life of the outer packaging. Where use is made of carbon black, pigments or inhibitors other than those used in the manufacture of the tested design type, re-testing may be waived if changes in the carbon black content, the pigment content or the inhibitor content do not adversely affect the physical properties of the material of construction. 6.6.4.3.3 Additives may be incorporated in the material of the large packaging to improve the resistance to ageing or to serve other purposes, provided that these do not adversely affect the physical or chemical properties of the material. 6.6.4.4 Specific requirements for fibreboard large packagings 50G 6.6.4 4.1 rigid fibreboard Strong and good quality solid or double-faced corrugated fibreboard (single or multiwall) shall be used, appropriate to the capacity of the large packagings and to their intended use. The water resistance of the outer surface shall be such that the increase in mass, as determined in a test carried out over a period of 30 minutes by the Cobb method of determining water absorption, is not greater than 155 g/m2 - see ISO 535:1991. It shall have proper bending qualities. Fibreboard shall be cut, creased without scoring, and slotted so as to permit assembly without cracking, surface breaks or undue bending. The fluting or corrugated fibreboard shall be firmly glued to the facings. - 396 - 6.6.4.4.2 The walls, including top and bottom, shall have a minimum puncture resistance of 15 J measured according to ISO 3036:1975. 6.6.4.4.3 Manufacturing joins in the outer packaging of large packagings shall be made with an appropriate overlap and shall be taped, glued, stitched with metal staples or fastened by other means at least equally effective. Where joins are effected by gluing or taping, a water resistant adhesive shall be used. Metal staples shall pass completely through all pieces to be fastened and be formed or protected so that any inner liner cannot be abraded or punctured by them. 6.6.4.4.4 Any integral pallet base forming part of a large packaging or any detachable pallet shall be suitable for mechanical handling with the large packaging filled to its maximum permissible gross mass. 6.6.4.4.5 The pallet or integral base shall be designed so as to avoid any protrusion of the base of the large packaging that might be liable to damage in handling. 6.6.4.4.6 The body shall be secured to any detachable pallet to ensure stability in handling and carriage. Where a detachable pallet is used, its top surface shall be free from sharp protrusions that might damage the large packaging. 6.6.4.4.7 Strengthening devices such as timber supports to increase stacking performance may be used but shall be external to the liner. 6.6.4.4.8 Where large packagings are intended for stacking, the bearing surface shall be such as to distribute the load in a safe manner. 6.6.4.5 Specific requirements for wooden large packagings 50C 50D 50F natural wood plywood reconstituted wood 6.6.4.5.1 The strength of the materials used and the method of construction shall be appropriate to the capacity and intended use of the large packagings. 6.6.4.5.2 Natural wood shall be well seasoned, commercially dry and free from defects that would materially lessen the strength of any part of the large packagings. Each part of the large packagings shall consist of one piece or be equivalent thereto. Parts are considered equivalent to one piece when a suitable method of glued assembly is used as for instance Lindermann joint, tongue and groove joint, ship lap or rabbet joint; or butt joint with at least two corrugated metal fasteners at each joint, or when other methods at least equally effective are used. 6.6.4.5.3 Large packagings of plywood shall be at least 3-ply. They shall be made of well seasoned rotary cut, sliced or sawn veneer, commercially dry and free from defects that would materially lessen the strength of the large packaging. All adjacent plies shall be glued with water resistant adhesive. Other suitable materials may be used with plywood for the construction of the large packaging. 6.6.4.5.4 Large packagings of reconstituted wood shall be made of water resistant reconstituted wood such as hardboard, particle board or other suitable type. 6.6.4.5.5 Large packagings shall be firmly nailed or secured to corner posts or ends or be assembled by equally suitable devices. 6.6.4.5.6 Any integral pallet base forming part of a large packaging or any detachable pallet shall be suitable for mechanical handling with the large packaging filled to its maximum permissible gross mass. 6.6.4.5.7 The pallet or integral base shall be designed so as to avoid any protrusion of the base of the large packaging that might be liable to damage in handling. 6.6.4.5.8 The body shall be secured to any detachable pallet to ensure stability in handling and carriage. Where a detachable pallet is used, its top surface shall be free from sharp protrusions that might damage the large packaging. - 397 - 6.6.4.5.9 Strengthening devices such as timber supports to increase stacking performance may be used but shall be external to the liner. 6.6.4.5.10 Where large packagings are intended for stacking, the bearing surface shall be such as to distribute the load in a safe manner. 6.6.5 Test requirements for large packagings 6.6.5.1 Performance and frequency of test 6.6.5.1.1 The design type of each large packaging shall be tested as provided in 6.6.5.3 in accordance with procedures established by the competent authority allowing the allocation of the mark and shall be approved by this competent authority. 6.6.5.1.2 Each large packaging design type shall successfully pass the tests prescribed in this Chapter before being used. A large packaging design type is defined by the design, size, material and thickness, manner of construction and packing, but may include various surface treatments. It also includes large packagings which differ from the design type only in their lesser design height. 6.6.5.1.3 Tests shall be repeated on production samples at intervals established by the competent authority. For such tests on fibreboard large packagings, preparation at ambient conditions is considered equivalent to the provisions of 6.6.5.2.4. 6.6.5.1.4 Tests shall also be repeated after each modification which alters the design, material or manner of construction of large packagings. 6.6.5.1.5 The competent authority may permit the selective testing of large packagings that differ only in minor respects from a tested type, e.g. smaller sizes of inner packagings or inner packagings of lower net mass; and large packagings which are produced with small reductions in external dimension(s). 6.6.5.1.6 (Reserved) NOTE: For the conditions for assembling different inner packagings in a large packaging and permissible variations in inner packagings, see 4.1.1.5.1. 6.6.5.1.7 The competent authority may at any time require proof, by tests in accordance with this section, that serially-produced large packagings meet the requirements of the design type tests. 6.6.5.1.8 Provided the validity of the test results is not affected and with the approval of the competent authority, several tests may be made on one sample. 6.6.5.1.9 Large salvage packagings Large salvage packagings shall be tested and marked in accordance with the provisions applicable to packing group II large packagings intended for the carriage of solids or inner packagings, except as follows: (a) The test substance used in performing the tests shall be water, and the large salvage packagings shall be filled to not less than 98% of their maximum capacity. It is permissible to use additives, such as bags of lead shot, to achieve the requisite total package mass so long as they are placed so that the test results are not affected. Alternatively, in performing the drop test, the drop height may be varied in accordance with 6.6.5.3.4.4.2 (b); (b) Large salvage packagings shall, in addition, have been successfully subjected to the leakproofness test at 30 kPa, with the results of this test reflected in the test report required by 6.6.5.4; and (c) Large salvage packagings shall be marked with the letter "T" as described in 6.6.2.2. - 398 - 6.6.5.2 Preparation for testing 6.6.5.2.1 Tests shall be carried out on large packagings prepared as for carriage including the inner packagings or articles used. Inner packagings shall be filled to not less than 98% of their maximum capacity for liquids or 95% for solids. For large packagings where the inner packagings are designed to carry liquids and solids, separate testing is required for both liquid and solid contents. The substances in the inner packagings or the articles to be carried in the large packagings may be replaced by other material or articles except where this would invalidate the results of the tests. When other inner packagings or articles are used they shall have the same physical characteristics (mass, etc) as the inner packagings or articles to be carried. It is permissible to use additives, such as bags of lead shot, to achieve the requisite total package mass, so long as they are placed so that the test results are not affected. 6.6.5.2.2 In the drop tests for liquids, when another substance is used, it shall be of similar relative density and viscosity to those of the substance being carried. Water may also be used for the liquid drop test under the conditions in 6.6.5.3.4.4. 6.6.5.2.3 Large packagings made of plastics materials and large packagings containing inner packagings of plastic materials - other than bags intended to contain solids or articles - shall be drop tested when the temperature of the test sample and its contents has been reduced to -18 °C or lower. This conditioning may be disregarded if the materials in question are of sufficient ductility and tensile strength at low temperatures. Where test sample are prepared in this way, the conditioning in 6.6.5.2.4 may be waived. Test liquids shall be kept in the liquid state by the addition of anti-freeze if necessary. 6.6.5.2.4 Large packagings of fibreboard shall be conditioned for at least 24 hours in an atmosphere having a controlled temperature and relative humidity (r.h.). There are three options, one of which shall be chosen. The preferred atmosphere is 23 °C ± 2 °C and 50% ± 2% r.h. The two other options are: 20 °C ± 2 °C and 65% ± 2% r.h.; or 27 °C ± 2 °C and 65% ± 2% r.h. NOTE: Average values shall fall within these limits. Short term fluctuations and measurement limitations may cause individual measurements to vary by up to ± 5% relative humidity without significant impairment of test reproducibility. 6.6.5.3 Test requirements 6.6.5.3.1 Bottom lift test 6.6.5.3.1.1 Applicability For all types of large packagings which are fitted with means of lifting from the base, as a design type test. 6.6.5.3.1.2 Preparation of large packaging for test The large packaging shall be loaded to 1.25 times its maximum permissible gross mass, the load being evenly distributed. 6.6.5.3.1.3 Method of testing The large packaging shall be raised and lowered twice by a lift truck with the forks centrally positioned and spaced at three quarters of the dimension of the side of entry (unless the points of entry are fixed). The forks shall penetrate to three quarters of the direction of entry. The test shall be repeated from each possible direction of entry. 6.6.5.3.1.4 Criteria for passing the test No permanent deformation which renders the large packaging unsafe for carriage and no loss of contents. - 399 - 6.6.5.3.2 Top lift test 6.6.5.3.2.1 Applicability For types of large packagings which are intended to be lifted from the top and fitted with means of lifting, as a design type test. 6.6.5.3.2.2 Preparation of large packaging for test The large packaging shall be loaded to twice its maximum permissible gross mass. A flexible large packaging shall be loaded to six times its maximum permissible gross mass, the load being evenly distributed. 6.6.5.3.2.3 Method of testing The large packaging shall be lifted in the manner for which it is designed until clear of the floor and maintained in that position for a period of five minutes. 6.6.5.3.2.4 Criteria for passing the test (a) Metal and rigid plastics large packagings: no permanent deformation which renders the large packaging, including the base pallet, if any, unsafe for carriage and no loss of contents; (b) Flexible large packagings: no damage to the large packaging or its lifting devices which renders the large packaging unsafe for carriage or handling and no loss of contents. 6.6.5.3.3 Stacking test 6.6.5.3.3.1 Applicability For all types of large packagings which are designed to be stacked on each other, as a design type test. 6.6.5.3.3.2 Preparation of large packaging for test The large packaging shall be filled to its maximum permissible gross mass. 6.6.5.3.3.3 Method of testing The large packaging shall be placed on its base on level hard ground and subjected to a uniformly distributed superimposed test load (see 6.6.5.3.3.4) for a period of at least five minutes, large packagings of wood, fibreboard and plastics materials for a period of 24 h. 6.6.5.3.3.4 Calculation of superimposed test load The load to be placed on the large packagings shall be 1.8 times the combined maximum permissible gross mass of the number of similar large packagings that may be stacked on top of the large packagings during carriage. 6.6.5.3.3.5 Criteria for passing the test (a) All types of large packagings other than flexible large packagings: no permanent deformation which renders the large packaging including the base pallet, if any, unsafe for carriage and no loss of contents; (b) Flexible large packagings: no deterioration of the body which renders the large packaging unsafe for carriage and no loss of contents. 6.6.5.3.4 Drop test 6.6.5.3.4.1 Applicability For all types of large packagings as a design type test. - 400 - 6.6.5.3.4.2 Preparation of large packaging for testing The large packaging shall be filled in accordance with 6.6.5.2.1 6.6.5.3.4.3 Method of testing The large packaging shall be dropped onto a non resilient, horizontal, flat, massive and rigid surface in conformity with the requirements of 6.1.5.3.4, in such a manner as to ensure that the point of impact is that part of the base of the large packaging considered to be the most vulnerable. 6.6.5.3.4.4 Drop height NOTE: Large packagings for substances and articles of Class 1 shall be tested at the packing group II performance level. 6.6.5.3.4.4.1 For inner packagings containing solid or liquid substances or articles, if the test is performed with the solid, liquid or articles to be carried, or with another substance or article having essentially the same characteristics: Packing group I 1.8 m 6.6.5.3.4.4.2 Packing group II 1.2 m Packing group III 0.8 m For inner packagings containing liquids if the test is performed with water: (a) Where the substances to be carried have a relative density not exceeding 1.2: Packing group I 1.8 m (b) Packing group II 1.2 m Packing group III 0.8 m Where the substances to be carried have a relative density exceeding 1.2, the drop height shall be calculated on the basis of the relative density (d) of the substance to be carried, rounded up to the first decimal, as follows: Packing group I Packing group II Packing group III d 1.5 (m) d  1.0 (m) d  0.67 (m) 6.6.5.3.4.5 Criteria for passing the test 6.6.5.3.4.5.1 The large packaging shall not exhibit any damage liable to affect safety during carriage. There shall be no leakage of the filling substance from inner packaging(s) or article(s). 6.6.5.3.4.5.2 No rupture is permitted in large packagings for articles of Class 1 which would permit the spillage of loose explosive substances or articles from the large packaging. 6.6.5.3.4.5.3 Where a large packaging undergoes a drop test, the sample passes the test if the entire contents are retained even if the closure is no longer sift-proof. 6.6.5.4 Certification and test report 6.6.5.4.1 In respect of each design type of large packaging a certificate and mark (as in 6.6.3) shall be issued attesting that the design type including its equipment meets the test requirements. - 401 - 6.6.5.4.2 6.6.5.4.3 A test report containing at least the following particulars shall be drawn up and shall be made available to the users of the large packaging: 1. Name and address of the test facility; 2. Name and address of applicant (where appropriate); 3. A unique test report identification; 4. Date of the test report; 5. Manufacturer of the large packaging; 6. Description of the large packaging design type (e.g. dimensions, materials, closures, thickness, etc) and/or photograph(s); 7. Maximum capacity/maximum permissible gross mass; 8. Characteristics of test contents, e.g. types and descriptions of inner packagings or articles used; 9. Test descriptions and results; 10. The test report shall be signed with the name and status of the signatory. The test report shall contain statements that the large packaging prepared as for carriage was tested in accordance with the appropriate provisions of this Chapter and that the use of other packaging methods or components may render it invalid. A copy of the test report shall be available to the competent authority. - 402 - CHAPTER 6.7 REQUIREMENTS FOR THE DESIGN, CONSTRUCTION, INSPECTION AND TESTING OF PORTABLE TANKS AND UN MULTIPLE-ELEMENT GAS CONTAINERS (MEGCs) NOTE: For fixed tanks (tank-vehicles), demountable tanks and tank-containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple element gas containers (MEGCs) other than UN MEGCs, see Chapter 6.8; for fibre-reinforced plastics tanks, see Chapter 6.9; for vacuum operated waste tanks, see Chapter 6.10. 6.7.1 Application and general requirements 6.7.1.1 The requirements of this Chapter apply to portable tanks intended for the carriage of dangerous goods, and to MEGCs intended for the carriage of non-refrigerated gases of Class 2, by all modes of carriage. In addition to the requirements of this Chapter, unless otherwise specified, the applicable requirements of the International Convention for Safe Containers (CSC) 1972, as amended, shall be fulfilled by any multimodal portable tank or MEGC which meets the definition of a "container" within the terms of that Convention. Additional requirements may apply to offshore portable tanks or MEGCs that are handled in open seas. 6.7.1.2 In recognition of scientific and technological advances, the technical requirements of this Chapter may be varied by alternative arrangements. These alternative arrangements shall offer a level of safety not less than that given by the requirements of this Chapter with respect to the compatibility with substances carried and the ability of the portable tank or MEGC to withstand impact, loading and fire conditions. For international carriage, alternative arrangement portable tanks or MEGCs shall be approved by the applicable competent authorities. 6.7.1.3 When a substance is not assigned a portable tank instruction (T1 to T23, T50 or T75) in Column (10) of Table A of in Chapter 3.2, interim approval for carriage may be issued by the competent authority of the country of origin. The approval shall be included in the documentation of the consignment and contain as a minimum the information normally provided in the portable tank instructions and the conditions under which the substance shall be carried. 6.7.2 Requirements for the design, construction, inspection and testing of portable tanks intended for the carriage of substances of Class 1 and Classes 3 to 9 6.7.2.1 Definitions For the purposes of this section: Alternative arrangement means an approval granted by the competent authority for a portable tank or MEGC that has been designed, constructed or tested to technical requirements or testing methods other than those specified in this Chapter: Portable tank means a multimodal tank used for the carriage of substances of Class 1 and Classes 3 to 9. The portable tank includes a shell fitted with service equipment and structural equipment necessary for the carriage of dangerous substances. The portable tank shall be capable of being filled and discharged without the removal of its structural equipment. It shall possess stabilizing members external to the shell, and shall be capable of being lifted when full. It shall be designed primarily to be loaded onto a vehicle, wagon or sea-going or inland navigation vessel and shall be equipped with skids, mountings or accessories to facilitate mechanical handling. Tank-vehicles, tank-wagons, non-metallic tanks and intermediate bulk containers (IBCs) are not considered to fall within the definition for portable tanks; Shell means the part of the portable tank which retains the substance intended for carriage (tank proper), including openings and their closures, but does not include service equipment or external structural equipment; - 403 - Service equipment means measuring instruments and filling, discharge, venting, safety, heating, cooling and insulating devices; Structural equipment means the reinforcing, fastening, protective and stabilizing members external to the shell; Maximum allowable working pressure (MAWP) means a pressure that shall be not less than the highest of the following pressures measured at the top of the shell while in operating position: (a) The maximum effective gauge pressure allowed in the shell during filling or discharge; or (b) The maximum effective gauge pressure to which the shell is designed which shall be not less than the sum of: (i) the absolute vapour pressure (in bar) of the substance at 65 °C, minus 1 bar; and (ii) the partial pressure (in bar) of air or other gases in the ullage space being determined by a maximum ullage temperature of 65 °C and a liquid expansion due to an increase in mean bulk temperature of tr - tf (tf = filling temperature, usually 15 °C; tr = maximum mean bulk temperature, 50 °C); Design pressure means the pressure to be used in calculations required by a recognized pressure vessel code. The design pressure shall be not less than the highest of the following pressures: (a) The maximum effective gauge pressure allowed in the shell during filling or discharge; or (b) The sum of: (c) (i) the absolute vapour pressure (in bar) of the substance at 65 °C, minus 1 bar; (ii) the partial pressure (in bar) of air or other gases in the ullage space being determined by a maximum ullage temperature of 65 °C and a liquid expansion due to an increase in mean bulk temperature of tr - tf (tf = filling temperature usually 15 °C; tr = maximum mean bulk temperature, 50 °C); and (iii) a head pressure determined on the basis of the static forces specified in 6.7.2.2.12, but not less than 0.35 bar; or Two thirds of the minimum test pressure specified in the applicable portable tank instruction in 4.2.5.2.6; Test pressure means the maximum gauge pressure at the top of the shell during the hydraulic pressure test equal to not less than 1.5 times the design pressure. The minimum test pressure for portable tanks intended for specific substances is specified in the applicable portable tank instruction in 4.2.5.2.6; Leakproofness test means a test using gas subjecting the shell and its service equipment to an effective internal pressure of not less than 25% of the MAWP; Maximum permissible gross mass (MPGM) means the sum of the tare mass of the portable tank and the heaviest load authorized for carriage; Reference steel means a steel with a tensile strength of 370 N/mm2 and an elongation at fracture of 27%; Mild steel means a steel with a guaranteed minimum tensile strength of 360 N/mm2 to 440 N/mm2 and a guaranteed minimum elongation at fracture conforming to 6.7.2.3.3.3; Design temperature range for the shell shall be -40 °C to 50 °C for substances carried under ambient conditions. For the other substances handled under elevated temperature conditions the design temperature shall be not less than the maximum temperature of the substance during filling, discharge or carriage. More severe design temperatures shall be considered for portable tanks subjected to severe climatic conditions; - 404 - Fine grain steel means steel which has a ferritic grain size of 6 or finer when determined in accordance with ASTM E 112-96 or as defined in EN 10028-3, Part 3; Fusible element means a non-reclosable pressure relief device that is thermally actuated; Offshore portable tank means a portable tank specially designed for repeated use for carriage to, from and between offshore facilities. An offshore portable tank is designed and constructed in accordance with the guidelines for the approval of containers handled in open seas specified by the International Maritime Organization in document MSC/Circ.860. 6.7.2.2 General design and construction requirements 6.7.2.2.1 Shells shall be designed and constructed in accordance with the requirements of a pressure vessel code recognized by the competent authority. Shells shall be made of metallic materials suitable for forming. The materials shall in principle conform to national or international material standards. For welded shells only a material whose weldability has been fully demonstrated shall be used. Welds shall be skilfully made and afford complete safety. When the manufacturing process or the materials make it necessary, the shells shall be suitably heat-treated to guarantee adequate toughness in the weld and in the heat affected zones. In choosing the material, the design temperature range shall be taken into account with respect to risk of brittle fracture, to stress corrosion cracking and to resistance to impact. When fine grain steel is used, the guaranteed value of the yield strength shall be not more than 460 N/mm2 and the guaranteed value of the upper limit of the tensile strength shall be not more than 725 N/mm2 according to the material specification. Aluminium may only be used as a construction material when indicated in a portable tank special provision assigned to a specific substance in Column (11) of Table A of Chapter 3.2 or when approved by the competent authority. When aluminium is authorized, it shall be insulated to prevent significant loss of physical properties when subjected to a heat load of 110 kW/m2 for a period of not less than 30 minutes. The insulation shall remain effective at all temperatures less than 649 °C and shall be jacketed with a material with a melting point of not less than 700 °C. Portable tank materials shall be suitable for the external environment in which they may be carried. 6.7.2.2.2 Portable tank shells, fittings, and pipework shall be constructed from materials which are: (a) Substantially immune to attack by the substance(s) intended to be carried; or (b) Properly passivated or neutralized by chemical reaction; or (c) Lined with corrosion-resistant material directly bonded to the shell or attached by equivalent means. 6.7.2.2.3 Gaskets shall be made of materials not subject to attack by the substance(s) intended to be carried. 6.7.2.2.4 When shells are lined, the lining shall be substantially immune to attack by the substance(s) intended to be carried, homogeneous, non porous, free from perforations, sufficiently elastic and compatible with the thermal expansion characteristics of the shell. The lining of every shell, shell fittings and piping shall be continuous, and shall extend around the face of any flange. Where external fittings are welded to the tank, the lining shall be continuous through the fitting and around the face of external flanges. 6.7.2.2.5 Joints and seams in the lining shall be made by fusing the material together or by other equally effective means. 6.7.2.2.6 Contact between dissimilar metals which could result in damage by galvanic action shall be avoided. 6.7.2.2.7 The materials of the portable tank, including any devices, gaskets, linings and accessories, shall not adversely affect the substance(s) intended to be carried in the portable tank. 6.7.2.2.8 Portable tanks shall be designed and constructed with supports to provide a secure base during carriage and with suitable lifting and tie-down attachments. - 405 - 6.7.2.2.9 Portable tanks shall be designed to withstand, without loss of contents, at least the internal pressure due to the contents, and the static, dynamic and thermal loads during normal conditions of handling and carriage. The design shall demonstrate that the effects of fatigue, caused by repeated application of these loads through the expected life of the portable tank, have been taken into account. 6.7.2.2.9.1 For portable tanks that are intended for use offshore, the dynamic stresses imposed by handling in open seas shall be taken into account. 6.7.2.2.10 A shell which is to be equipped with a vacuum-relief device shall be designed to withstand, without permanent deformation, an external pressure of not less than 0.21 bar above the internal pressure. The vacuum-relief device shall be set to relieve at a vacuum setting not greater than minus (-) 0.21 bar unless the shell is designed for a higher external over pressure, in which case the vacuum-relief pressure of the device to be fitted shall be not greater than the tank design vacuum pressure. A shell used for the carriage of solid substances (powdery or granular) of packing groups II or III only, which do not liquefy during carriage, may be designed for a lower external pressure, subject to the approval of the competent authority. In this case, the vacuum valve shall be set to relieve at this lower pressure. A shell that is not to be fitted with a vacuum-relief device shall be designed to withstand, without permanent deformation an external pressure of not less than 0.4 bar above the internal pressure. 6.7.2.2.11 Vacuum-relief devices used on portable tanks intended for the carriage of substances meeting the flash-point criteria of Class 3, including elevated temperature substances carried at or above their flash-point, shall prevent the immediate passage of flame into the shell, or the portable tank shall have a shell capable of withstanding, without leakage an internal explosion resulting from the passage of flame into the shell. 6.7.2.2.12 Portable tanks and their fastenings shall, under the maximum permissible load, be capable of absorbing the following separately applied static forces: 6.7.2.2.13 (a) In the direction of travel: twice the MPGM multiplied by the acceleration due to gravity (g)1; (b) Horizontally at right angles to the direction of travel: the MPGM (when the direction of travel is not clearly determined, the forces shall be equal to twice the MPGM) multiplied by the acceleration due to gravity (g)1; (c) Vertically upwards: the MPGM multiplied by the acceleration due to gravity (g) 1; and (d) Vertically downwards: twice the MPGM (total loading including the effect of gravity) multiplied by the acceleration due to gravity (g)1. Under each of the forces in 6.7.2.2.12, the safety factor to be observed shall be as follows: (a) For metals having a clearly defined yield point, a safety factor of 1.5 in relation to the guaranteed yield strength; or (b) For metals with no clearly defined yield point, a safety factor of 1.5 in relation to the guaranteed 0.2% proof strength and, for austenitic steels, the 1% proof strength. 6.7.2.2.14 The values of yield strength or proof strength shall be the values according to national or international material standards. When austenitic steels are used, the specified minimum values of yield strength or proof strength according to the material standards may be increased by up to 15% when these greater values are attested in the material inspection certificate. When no material standard exists for the metal in question, the value of yield strength or proof strength used shall be approved by the competent authority. 6.7.2.2.15 Portable tanks shall be capable of being electrically earthed when intended for the carriage of substances meeting the flash-point criteria of Class 3 including elevated temperature substances carried at or above their flash-point. Measures shall be taken to prevent dangerous electrostatic discharge. 1 For calculation purposes g = 9.81 m/s2. - 406 - 6.7.2.2.16 When required for certain substances by the applicable portable tank instruction indicated in Column (10) of Table A of Chapter 3.2 and described in 4.2.5.2.6 or by a portable tank special provision indicated in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3, portable tanks shall be provided with additional protection, which may take the form of additional shell thickness or a higher test pressure, the additional shell thickness or higher test pressure being determined in the light of the inherent risks associated with the carriage of the substances concerned. 6.7.2.2.17 Thermal insulation directly in contact with the shell intended for substances carried at elevated temperature shall have an ignition temperature at least 50 °C higher than the maximum design temperature of the tank. 6.7.2.3 Design criteria 6.7.2.3.1 Shells shall be of a design capable of being stress-analysed mathematically or experimentally by resistance strain gauges, or by other methods approved by the competent authority. 6.7.2.3.2 Shells shall be designed and constructed to withstand a hydraulic test pressure not less than 1.5 times the design pressure. Specific requirements are laid down for certain substances in the applicable portable tank instruction indicated in Column (10) of Table A of Chapter 3.2 and described in 4.2.5.2.6 or by a portable tank special provision indicated in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3. Attention is drawn to the minimum shell thickness requirements specified in 6.7.2.4.1 to 6.7.2.4.10. 6.7.2.3.3 For metals exhibiting a clearly defined yield point or characterized by a guaranteed proof strength (0.2% proof strength, generally, or 1% proof strength for austenitic steels) the primary membrane stress  (sigma) in the shell shall not exceed 0.75 Re or 0.50 Rm, whichever is lower, at the test pressure, where: Re = yield strength in N/mm2, or 0.2% proof strength or, for austenitic steels, 1% proof strength; Rm = minimum tensile strength in N/mm2. 6.7.2.3.3.1 The values of Re and Rm to be used shall be the specified minimum values according to national or international material standards. When austenitic steels are used, the specified minimum values for Re and Rm according to the material standards may be increased by up to 15% when greater values are attested in the material inspection certificate. When no material standard exists for the metal in question, the values of Re and Rm used shall be approved by the competent authority or its authorized body. 6.7.2.3.3.2 Steels which have a Re/Rm ratio of more than 0.85 are not allowed for the construction of welded shells. The values of Re and Rm to be used in determining this ratio shall be the values specified in the material inspection certificate. 6.7.2.3.3.3 Steels used in the construction of shells shall have an elongation at fracture, in %, of not less than 10 000/Rm with an absolute minimum of 16% for fine grain steels and 20% for other steels. Aluminium and aluminium alloys used in the construction of shells shall have an elongation at fracture, in %, of not less than 10 000/6Rm with an absolute minimum of 12%. 6.7.2.3.3.4 For the purpose of determining actual values for materials, it shall be noted that for sheet metal, the axis of the tensile test specimen shall be at right angles (transversely) to the direction of rolling. The permanent elongation at fracture shall be measured on test specimens of rectangular cross sections in accordance with ISO 6892:1998 using a 50 mm gauge length. 6.7.2.4 Minimum shell thickness 6.7.2.4.1 The minimum shell thickness shall be the greater thickness based on: (a) The minimum thickness determined in accordance with the requirements of 6.7.2.4.2 to 6.7.2.4.10; (b) The minimum thickness determined in accordance with the recognized pressure vessel code including the requirements in 6.7.2.3; and - 407 - (c) The minimum thickness specified in the applicable portable tank instruction indicated in Column (10) of Table A of Chapter 3.2 and described in 4.2.5.2.6 or by a portable tank special provision indicated in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3. 6.7.2.4.2 The cylindrical portions, ends (heads) and manhole covers of shells not more than 1.80 m in diameter shall be not less than 5 mm thick in the reference steel or of equivalent thickness in the metal to be used. Shells more than 1.80 m in diameter shall be not less than 6 mm thick in the reference steel or of equivalent thickness in the metal to be used, except that for powdered or granular solid substances of packing group II or III the minimum thickness requirement may be reduced to not less than 5 mm thick in the reference steel or of equivalent thickness in the metal to be used. 6.7.2.4.3 When additional protection against shell damage is provided, portable tanks with test pressures less than 2.65 bar may have the minimum shell thickness reduced, in proportion to the protection provided, as approved by the competent authority. However, shells not more than 1.80 m in diameter shall be not less than 3 mm thick in the reference steel or of equivalent thickness in the metal to be used. Shells more than 1.80 m in diameter shall be not less than 4 mm thick in the reference steel or of equivalent thickness in the metal to be used. 6.7.2.4.4 The cylindrical portions, ends (heads) and manhole covers of all shells shall be not less than 3 mm thick regardless of the material of construction. 6.7.2.4.5 The additional protection referred to in 6.7.2.4.3 may be provided by overall external structural protection, such as suitable "sandwich" construction with the outer sheathing (jacket) secured to the shell, double wall construction or by enclosing the shell in a complete framework with longitudinal and transverse structural members. 6.7.2.4.6 The equivalent thickness of a metal other than the thickness prescribed for the reference steel in 6.7.2.4.2 shall be determined using the following formula: e1  where: = e1 6.7.2.4.7 21.4e o 3 Rm 1  A1 required equivalent thickness (in mm) of the metal to be used; e0 = minimum thickness (in mm) of the reference steel specified in the applicable portable tank instruction indicated in Column (10) of Table A of Chapter 3.2 and described in 4.2.5.2.6 or by a portable tank special provision indicated in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3; Rm1 = guaranteed minimum tensile strength (in N/mm2) of the metal to be used (see 6.7.2.3.3); A1 = guaranteed minimum elongation at fracture (in %) of the metal to be used according to national or international standards. When in the applicable portable tank instruction in 4.2.5.2.6, a minimum thickness of 8 mm or 10 mm is specified, it shall be noted that these thicknesses are based on the properties of the reference steel and a shell diameter of 1.80 m. When a metal other than mild steel (see 6.7.2.1) is used or the shell has a diameter of more than 1.80 m, the thickness shall be determined using the following formula: e1  21.4e o d 1 1,8 3 Rm 1  A 1 where: e1 = required equivalent thickness (in mm) of the metal to be used; e0 = minimum thickness (in mm) of the reference steel specified in the applicable portable tank instruction indicated in Column (10) of Table A of Chapter 3.2 and described in 4.2.5.2.6 or by a portable tank special provision indicated in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3; d1 = diameter of the shell (in m), but not less than 1.80 m; Rm1 = guaranteed minimum tensile strength (in N/mm2) of the metal to be used (see 6.7.2.3.3); - 408 - A1 = guaranteed minimum elongation at fracture (in %) of the metal to be used according to national or international standards. 6.7.2.4.8 In no case shall the wall thickness be less than that prescribed in 6.7.2.4.2, 6.7.2.4.3 and 6.7.2.4.4. All parts of the shell shall have a minimum thickness as determined by 6.7.2.4.2 to 6.7.2.4.4. This thickness shall be exclusive of any corrosion allowance. 6.7.2.4.9 When mild steel is used (see 6.7.2.1), calculation using the formula in 6.7.2.4.6 is not required. 6.7.2.4.10 There shall be no sudden change of plate thickness at the attachment of the ends (heads) to the cylindrical portion of the shell. 6.7.2.5 Service equipment 6.7.2.5.1 Service equipment shall be so arranged as to be protected against the risk of being wrenched off or damaged during handling and carriage. When the connection between the frame and the shell allows relative movement between the sub-assemblies, the equipment shall be so fastened as to permit such movement without risk of damage to working parts. The external discharge fittings (pipe sockets, shut-off devices), the internal stop-valve and its seating shall be protected against the danger of being wrenched off by external forces (for example using shear sections). The filling and discharge devices (including flanges or threaded plugs) and any protective caps shall be capable of being secured against unintended opening. 6.7.2.5.2 All openings in the shell, intended for filling or discharging the portable tank shall be fitted with a manually operated stop-valve located as close to the shell as reasonably practicable. Other openings, except for openings leading to venting or pressure-relief devices, shall be equipped with either a stop-valve or another suitable means of closure located as close to the shell as reasonably practicable. 6.7.2.5.3 All portable tanks shall be fitted with a manhole or other inspection openings of a suitable size to allow for internal inspection and adequate access for maintenance and repair of the interior. Compartmented portable tanks shall have a manhole or other inspection openings for each compartment. 6.7.2.5.4 As far as reasonably practicable, external fittings shall be grouped together. For insulated portable tanks, top fittings shall be surrounded by a spill collection reservoir with suitable drains. 6.7.2.5.5 Each connection to a portable tank shall be clearly marked to indicate its function. 6.7.2.5.6 Each stop-valve or other means of closure shall be designed and constructed to a rated pressure not less than the MAWP of the shell taking into account the temperatures expected during carriage. All stop-valves with screwed spindles shall close by a clockwise motion of the handwheel. For other stop-valves the position (open and closed) and direction of closure shall be clearly indicated. All stop-valves shall be designed to prevent unintentional opening. 6.7.2.5.7 No moving parts, such as covers, components of closures, etc., shall be made of unprotected corrodible steel when they are liable to come into frictional or percussive contact with aluminium portable tanks intended for the carriage of substances meeting the flash-point criteria of Class 3 including elevated temperature substances carried at or above their flash-point. 6.7.2.5.8 Piping shall be designed, constructed and installed so as to avoid the risk of damage due to thermal expansion and contraction, mechanical shock and vibration. All piping shall be of a suitable metallic material. Welded pipe joints shall be used wherever possible. 6.7.2.5.9 Joints in copper tubing shall be brazed or have an equally strong metal union. The melting point of brazing materials shall be no lower than 525 °C. The joints shall not decrease the strength of the tubing as may happen when cutting threads. 6.7.2.5.10 The burst pressure of all piping and pipe fittings shall be not less than the highest of four times the MAWP of the shell or four times the pressure to which it may be subjected in service by the action of a pump or other device (except pressure-relief devices). 6.7.2.5.11 Ductile metals shall be used in the construction of valves and accessories. - 409 - 6.7.2.5.12 The heating system shall be designed or controlled so that a substance cannot reach a temperature at which the pressure in the tank exceeds its MAWP or causes other hazards (e.g. dangerous thermal decomposition). 6.7.2.5.13 The heating system shall be designed or controlled so that power for internal heating elements shall not be available unless the heating elements are completely submerged. The temperature at the surface of the heating elements for internal heating equipment, or the temperature at the shell for external heating equipment shall, in no case, exceed 80% of the autoignition temperature (in °C) of the substance carried. 6.7.2.5.14 If an electrical heating system is installed inside the tank, it shall be equipped with an earth leakage circuit breaker with a releasing current of less than 100 mA. 6.7.2.5.15 Electrical switch cabinets mounted to tanks shall not have a direct connection to the tank interior and shall provide protection of at least the equivalent of type IP56 according to IEC 144 or IEC 529. 6.7.2.6 Bottom openings 6.7.2.6.1 Certain substances shall not be carried in portable tanks with bottom openings. When the applicable portable tank instruction identified in Column (10) of Table A of Chapter 3.2 and described in 4.2.5.2.6 indicates that bottom openings are prohibited there shall be no openings below the liquid level of the shell when it is filled to its maximum permissible filling limit. When an existing opening is closed it shall be accomplished by internally and externally welding one plate to the shell. 6.7.2.6.2 Bottom discharge outlets for portable tanks carrying certain solid, crystallizable or highly viscous substances shall be equipped with not less than two serially fitted and mutually independent shut-off devices. The design of the equipment shall be to the satisfaction of the competent authority or its authorized body and shall include: 6.7.2.6.3 (a) An external stop-valve, fitted as close to the shell as reasonably practicable, and so designed as to prevent any unintended opening through impact or other inadvertent act; and (b) A liquid tight closure at the end of the discharge pipe, which may be a bolted blank flange or a screw cap. Every bottom discharge outlet, except as provided in 6.7.2.6.2, shall be equipped with three serially fitted and mutually independent shut-off devices. The design of the equipment shall be to the satisfaction of the competent authority or its authorized body and include: (a) 6.7.2.6.4 A self-closing internal stop-valve, that is a stop-valve within the shell or within a welded flange or its companion flange, such that: (i) The control devices for the operation of the valve are designed so as to prevent any unintended opening through impact or other inadvertent act; (ii) The valve may be operable from above or below; (iii) If possible, the setting of the valve (open or closed) shall be capable of being verified from the ground; (iv) Except for portable tanks having a capacity of not more than 1 000 litres, it shall be possible to close the valve from an accessible position of the portable tank that is remote from the valve itself; and (v) The valve shall continue to be effective in the event of damage to the external device for controlling the operation of the valve; (b) An external stop-valve fitted as close to the shell as reasonably practicable; and (c) A liquid tight closure at the end of the discharge pipe, which may be a bolted blank flange or a screw cap. For a lined shell, the internal stop-valve required by 6.7.2.6.3 (a) may be replaced by an additional external stop-valve. The manufacturer shall satisfy the requirements of the competent authority or its authorized body. - 410 - 6.7.2.7 Safety-relief devices 6.7.2.7.1 All portable tanks shall be fitted with at least one pressure-relief device. All relief devices shall be designed, constructed and marked to the satisfaction of the competent authority or its authorized body. 6.7.2.8 Pressure-relief devices 6.7.2.8.1 Every portable tank with a capacity not less than 1 900 litres and every independent compartment of a portable tank with a similar capacity, shall be provided with one or more pressure-relief devices of the spring-loaded type and may in addition have a frangible disc or fusible element in parallel with the spring-loaded devices except when prohibited by reference to 6.7.2.8.3 in the applicable portable tank instruction in 4.2.5.2.6. The pressure-relief devices shall have sufficient capacity to prevent rupture of the shell due to over pressurization or vacuum resulting from filling, discharging, or from heating of the contents. 6.7.2.8.2 Pressure-relief devices shall be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. 6.7.2.8.3 When required for certain substances by the applicable portable tank instruction indicated in Column (10) of Table A of Chapter 3.2 and described in 4.2.5.2.6, portable tanks shall have a pressure-relief device approved by the competent authority. Unless a portable tank in dedicated service is fitted with an approved relief device constructed of materials compatible with the substance carried, the relief device shall comprise a frangible disc preceding a spring-loaded pressure-relief device. When a frangible disc is inserted in series with the required pressure-relief device, the space between the frangible disc and the pressure-relief device shall be provided with a pressure gauge or suitable tell-tale indicator for the detection of disc rupture, pinholing, or leakage which could cause a malfunction of the pressure-relief system. The frangible disc shall rupture at a nominal pressure 10% above the start to discharge pressure of the relief device. 6.7.2.8.4 Every portable tank with a capacity less than 1 900 litres shall be fitted with a pressure-relief device which may be a frangible disc when this disc complies with the requirements of 6.7.2.11.1. When no spring-loaded pressure-relief device is used, the frangible disc shall be set to rupture at a nominal pressure equal to the test pressure. In addition, fusible elements conforming to 6.7.2.10.1 may also be used. 6.7.2.8.5 When the shell is fitted for pressure discharge, the inlet line shall be provided with a suitable pressure-relief device set to operate at a pressure not higher than the MAWP of the shell, and a stop-valve shall be fitted as close to the shell as reasonably practicable. 6.7.2.9 Setting of pressure-relief devices 6.7.2.9.1 It shall be noted that the pressure-relief devices shall operate only in conditions of excessive rise in temperature, since the shell shall not be subject to undue fluctuations of pressure during normal conditions of carriage (see 6.7.2.12.2). 6.7.2.9.2 The required pressure-relief device shall be set to start-to-discharge at a nominal pressure of five-sixths of the test pressure for shells having a test pressure of not more than 4.5 bar and 110% of two-thirds of the test pressure for shells having a test pressure of more than 4.5 bar. After discharge the device shall close at a pressure not more than 10% below the pressure at which the discharge starts. The device shall remain closed at all lower pressures. This requirement does not prevent the use of vacuum-relief or combination pressure-relief and vacuum-relief devices. 6.7.2.10 Fusible elements 6.7.2.10.1 Fusible elements shall operate at a temperature between 100 °C and 149 °C on condition that the pressure in the shell at the fusing temperature will be not more than the test pressure. They shall be placed at the top of the shell with their inlets in the vapour space and when used for transport safety purposes, they shall not be shielded from external heat. Fusible elements shall not be used on portable tanks with a test pressure which exceeds 2.65 bar unless specified by special provision TP36 in Column (11) of Table A of Chapter 3.2. Fusible elements used on portable tanks intended for the carriage of elevated temperature substances shall be designed to operate at a temperature higher than the maximum temperature that will be experienced during carriage and shall be to the satisfaction of the competent authority or its authorized body. - 411 - 6.7.2.11 Frangible discs 6.7.2.11.1 Except as specified in 6.7.2.8.3, frangible discs shall be set to rupture at a nominal pressure equal to the test pressure throughout the design temperature range. Particular attention shall be given to the requirements of 6.7.2.5.1 and 6.7.2.8.3 if frangible discs are used. 6.7.2.11.2 Frangible discs shall be appropriate for the vacuum pressures which may be produced in the portable tank. 6.7.2.12 Capacity of pressure-relief devices 6.7.2.12.1 The spring-loaded pressure-relief device required by 6.7.2.8.1 shall have a minimum cross sectional flow area equivalent to an orifice of 31.75 mm diameter. Vacuum-relief devices, when used, shall have a cross sectional flow area not less than 284 mm2. 6.7.2.12.2 The combined delivery capacity of the pressure relief system (taking into account the reduction of the flow when the portable tank is fitted with frangible-discs preceding spring-loaded pressure-relief devices or when the spring-loaded pressure-relief devices are provided with a device to prevent the passage of the flame), in condition of complete fire engulfment of the portable tank shall be sufficient to limit the pressure in the shell to 20% above the start-to-discharge pressure of the pressure limiting device. Emergency pressure-relief devices may be used to achieve the full relief capacity prescribed. These devices may be fusible, spring loaded or frangible disc components, or a combination of springloaded and frangible disc devices. The total required capacity of the relief devices may be determined using the formula in 6.7.2.12.2.1 or the table in 6.7.2.12.2.3. 6.7.2.12.2.1 To determine the total required capacity of the relief devices, which shall be regarded as being the sum of the individual capacities of all the contributing devices, the following formula shall be used: Q  12.4 where: Q = F = FA 0.82 LC ZT M minimum required rate of discharge in cubic metres of air per second (m3/s) at standard conditions: 1 bar and 0 °C (273 K); is a coefficient with the following value: for uninsulated shells: F = 1; for insulated shells: F = U(649 - t)/13.6 but in no case is less than 0.25 where: U = thermal conductance of the insulation, in kW.m-2. K-1, at 38 °C; t = actual temperature of the substance during filling (in °C); when this temperature is unknown, let t = 15 °C; The value of F given above for insulated shells may be taken provided that the insulation is in accordance with 6.7.2.12.2.4; A = total external surface area of shell in m2; Z = the gas compressibility factor in the accumulating condition (when this factor is unknown, let Z =1.0); T = absolute temperature in Kelvin (°C + 273) above the pressure-relief devices in the accumulating condition; L = the latent heat of vaporization of the liquid, in kJ/kg, in the accumulating condition; M = molecular mass of the discharged gas; C = a constant which is derived from one of the following formulae as a function of the ratio k of specific heats: k - 412 - cp cv where: cp cv is the specific heat at constant pressure; and is the specific heat at constant volume. When k>1: k 1  2  k 1 C  k   k  1 When k = 1 or k is unknown: C 1 e  0.607 where e is the mathematical constant 2.7183 C may also be taken from the following table: k 1.00 1.02 1.04 1.06 1.08 1.10 1.12 1.14 1.16 1.18 1.20 1.22 1.24 6.7.2.12.2.2 k 1.26 1.28 1.30 1.32 1.34 1.36 1.38 1.40 1.42 1.44 1.46 1.48 1.50 C 0.660 0.664 0.667 0.671 0.674 0.678 0.681 0.685 0.688 0.691 0.695 0.698 0.701 k 1.52 1.54 1.56 1.58 1.60 1.62 1.64 1.66 1.68 1.70 2.00 2.20 C 0.704 0.707 0.710 0.713 0.716 0.719 0.722 0.725 0.728 0.731 0.770 0.793 As an alternative to the formula above, shells designed for the carriage of liquids may have their relief devices sized in accordance with the table in 6.7.2.12.2.3. This table assumes an insulation value of F = 1 and shall be adjusted accordingly when the shell is insulated. Other values used in determining this table are: M L Z 6.7.2.12.2.3 C 0.607 0.611 0.615 0.620 0.624 0.628 0.633 0.637 0.641 0.645 0.649 0.652 0.656 = = = 86.7 334.94 kJ/kg 1 T C = = 394 K 0.607 Minimum required rate of discharge, Q, in cubic metres per air per second at 1 bar and 0 °C (273 K) A Exposed area (square metres) 2 3 4 5 6 7 8 9 10 Q (cubic metres of air per second) 0.230 0.320 0.405 0.487 0.565 0.641 0.715 0.788 0.859 - 413 - A Exposed area (square metres) 37.5 40 42.5 45 47.5 50 52.5 55 57.5 Q (cubic metres of air per second) 2.539 2.677 2.814 2.949 3.082 3.215 3.346 3.476 3.605 A Exposed area (square metres) 12 14 16 18 20 22.5 25 27.5 30 32.5 35 6.7.2.12.2.4 Q (cubic metres of air per second) 0.998 1.132 1.263 1.391 1.517 1.670 1.821 1.969 2.115 2.258 2.400 A Exposed area (square metres) 60 62.5 65 67.5 70 75 80 85 90 95 100 Q (cubic metres of air per second) 3.733 3.860 3.987 4.112 4.236 4.483 4.726 4.967 5.206 5.442 5.676 Insulation systems, used for the purpose of reducing venting capacity, shall be approved by the competent authority or its authorized body. In all cases, insulation systems approved for this purpose shall: (a) Remain effective at all temperatures up to 649 °C; and (b) Be jacketed with a material having a melting point of 700 °C or greater. 6.7.2.13 Marking of pressure-relief devices 6.7.2.13.1 Every pressure-relief device shall be clearly and permanently marked with the following particulars: (a) The pressure (in bar or kPa) or temperature (in °C) at which it is set to discharge; (b) The allowable tolerance at the discharge pressure for spring-loaded devices; (c) The reference temperature corresponding to the rated pressure for frangible discs; (d) The allowable temperature tolerance for fusible elements; and (e) The rated flow capacity of the spring-loaded pressure relief devices, frangible discs or fusible elements in standard cubic metres of air per second (m3/s); (f) The cross sectional flow areas of the spring loaded pressure-relief devices, frangible discs and fusible elements in mm2. When practicable, the following information shall also be shown: (g) The manufacturer’s name and relevant catalogue number of the device. 6.7.2.13.2 The rated flow capacity marked on the spring-loaded pressure-relief devices shall be determined according to ISO 4126-1:2004 and ISO 4126-7:2004. 6.7.2.14 Connections to pressure-relief devices 6.7.2.14.1 Connections to pressure-relief devices shall be of sufficient size to enable the required discharge to pass unrestricted to the safety device. No stop-valve shall be installed between the shell and the pressure-relief devices except where duplicate devices are provided for maintenance or other reasons and the stop-valves serving the devices actually in use are locked open or the stop-valves are interlocked so that at least one of the duplicate devices is always in use. There shall be no obstruction in an opening leading to a vent or pressure-relief device which might restrict or cut-off the flow from the shell to that device. Vents or pipes from the pressure-relief device outlets, when used, shall deliver the relieved vapour or liquid to the atmosphere in conditions of minimum back-pressure on the relieving devices. - 414 - 6.7.2.15 Siting of pressure-relief devices 6.7.2.15.1 Each pressure-relief device inlet shall be situated on top of the shell in a position as near the longitudinal and transverse centre of the shell as reasonably practicable. All pressure-relief device inlets shall under maximum filling conditions be situated in the vapour space of the shell and the devices shall be so arranged as to ensure the escaping vapour is discharged unrestrictedly. For flammable substances, the escaping vapour shall be directed away from the shell in such a manner that it cannot impinge upon the shell. Protective devices which deflect the flow of vapour are permissible provided the required relief-device capacity is not reduced. 6.7.2.15.2 Arrangements shall be made to prevent access to the pressure-relief devices by unauthorized persons and to protect the devices from damage caused by the portable tank overturning. 6.7.2.16 Gauging devices 6.7.2.16.1 Glass level-gauges and gauges made of other fragile material, which are in direct communication with the contents of the tank shall not be used. 6.7.2.17 Portable tank supports, frameworks, lifting and tie-down attachments 6.7.2.17.1 Portable tanks shall be designed and constructed with a support structure to provide a secure base during carriage. The forces specified in 6.7.2.2.12 and the safety factor specified in 6.7.2.2.13 shall be considered in this aspect of the design. Skids, frameworks, cradles or other similar structures are acceptable. 6.7.2.17.2 The combined stresses caused by portable tank mountings (e.g. cradles, framework, etc.) and portable tank lifting and tie-down attachments shall not cause excessive stress in any portion of the shell. Permanent lifting and tie-down attachments shall be fitted to all portable tanks. Preferably they shall be fitted to the portable tank supports but may be secured to reinforcing plates located on the shell at the points of support. 6.7.2.17.3 In the design of supports and frameworks the effects of environmental corrosion shall be taken into account. 6.7.2.17.4 Forklift pockets shall be capable of being closed off. The means of closing forklift pockets shall be a permanent part of the framework or permanently attached to the framework. Single compartment portable tanks with a length less than 3.65 m need not have closed off forklift pockets provided that: 6.7.2.17.5 (a) The shell including all the fittings are well protected from being hit by the forklift blades; and (b) The distance between the centres of the forklift pockets is at least half of the maximum length of the portable tank. When portable tanks are not protected during carriage, according to 4.2.1.2, the shells and service equipment shall be protected against damage to the shell and service equipment resulting from lateral or longitudinal impact or overturning. External fittings shall be protected so as to preclude the release of the shell contents upon impact or overturning of the portable tank on its fittings. Examples of protection include: (a) Protection against lateral impact which may consist of longitudinal bars protecting the shell on both sides at the level of the median line; (b) Protection of the portable tank against overturning which may consist of reinforcement rings or bars fixed across the frame; (c) Protection against rear impact which may consist of a bumper or frame; (d) Protection of the shell against damage from impact or overturning by use of an ISO frame in accordance with ISO 1496-3:1995. - 415 - 6.7.2.18 Design approval 6.7.2.18.1 The competent authority or its authorized body shall issue a design approval certificate for any new design of a portable tank. This certificate shall attest that a portable tank has been surveyed by that authority, is suitable for its intended purpose and meets the requirements of this Chapter and where appropriate, the provisions for substances provided in Chapter 4.2 and in Table A of Chapter 3.2. When a series of portable tanks are manufactured without change in the design, the certificate shall be valid for the entire series. The certificate shall refer to the prototype test report, the substances or group of substances allowed to be carried, the materials of construction of the shell and lining (when applicable) and an approval number. The approval number shall consist of the distinguishing sign or mark of the State in whose territory the approval was granted, i.e. the distinguishing sign for use in international traffic as prescribed by the Convention on Road Traffic, Vienna 1968, and a registration number. Any alternative arrangements according to 6.7.1.2 shall be indicated on the certificate. A design approval may serve for the approval of smaller portable tanks made of materials of the same kind and thickness, by the same fabrication techniques and with identical supports, equivalent closures and other appurtenances. 6.7.2.18.2 The prototype test report for the design approval shall include at least the following: (a) The results of the applicable framework test specified in ISO 1496-3:1995; (b) The results of the initial inspection and test according to 6.7.2.19.3; and (c) The results of the impact test in 6.7.2.19.1, when applicable. 6.7.2.19 Inspection and testing 6.7.2.19.1 Portable tanks meeting the definition of container in the International Convention for Safe Containers (CSC), 1972, as amended, shall not be used unless they are successfully qualified by subjecting a representative prototype of each design to the Dynamic, Longitudinal Impact Test prescribed in the Manual of Tests and Criteria, Part IV, Section 41. 6.7.2.19.2 The shell and items of equipment of each portable tank shall be inspected and tested before being put into service for the first time (initial inspection and test) and thereafter at not more than five-year intervals (5 year periodic inspection and test) with an intermediate periodic inspection and test (2.5 year periodic inspection and test) midway between the 5 year periodic inspections and tests. The 2.5 year inspection and test may be performed within 3 months of the specified date. An exceptional inspection and test shall be performed regardless of the date of the last periodic inspection and test when necessary according to 6.7.2.19.7. 6.7.2.19.3 The initial inspection and test of a portable tank shall include a check of the design characteristics, an internal and external examination of the portable tank and its fittings with due regard to the substances to be carried, and a pressure test. Before the portable tank is placed into service, a leakproofness test and a check of the satisfactory operation of all service equipment shall also be performed. When the shell and its fittings have been pressure-tested separately, they shall be subjected together after assembly to a leakproofness test. 6.7.2.19.4 The 5-year periodic inspection and test shall include an internal and external examination and, as a general rule, a hydraulic pressure test. For tanks only used for the carriage of solid substances, other than toxic or corrosive substances that do not liquefy during carriage, the hydraulic pressure test may be replaced by a suitable pressure test at 1.5 times the MAWP, subject to competent authority approval. Sheathing, thermal insulation and the like shall be removed only to the extent required for reliable appraisal of the condition of the portable tank. When the shell and equipment have been pressure-tested separately, they shall be subjected together after assembly to a leakproofness test. 6.7.2.19.5 The intermediate 2.5 year periodic inspection and test shall at least include an internal and external examination of the portable tank and its fittings with due regard to the substances intended to be carried, a leakproofness test and a check of the satisfactory operation of all service equipment. Sheathing, thermal insulation and the like shall be removed only to the extent required for reliable appraisal of the condition of the portable tank. For portable tanks intended for the carriage of a single substance, the 2.5 year internal examination may be waived or substituted by other test methods or inspection procedures specified by the competent authority or its authorized body. - 416 - 6.7.2.19.6 A portable tank may not be filled and offered for carriage after the date of expiry of the last 5 year or 2.5 year periodic inspection and test as required by 6.7.2.19.2. However, a portable tank filled prior to the date of expiry of the last periodic inspection and test may be carried for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection. In addition, a portable tank may be carried after the date of expiry of the last periodic test and inspection: (a) After emptying but before cleaning, for purposes of performing the next required test or inspection prior to refilling; and (b) Unless otherwise approved by the competent authority, for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection, in order to allow the return of dangerous goods for proper disposal or recycling. Reference to this exemption shall be mentioned in the transport document. 6.7.2.19.7 The exceptional inspection and test is necessary when the portable tank shows evidence of damaged or corroded areas, or leakage, or other conditions that indicate a deficiency that could affect the integrity of the portable tank. The extent of the exceptional inspection and test shall depend on the amount of damage or deterioration of the portable tank. It shall include at least the 2.5 year inspection and test according to 6.7.2.19.5. 6.7.2.19.8 The internal and external examinations shall ensure that: (a) The shell is inspected for pitting, corrosion, or abrasions, dents, distortions, defects in welds or any other conditions, including leakage, that might render the portable tank unsafe for carriage; (b) The piping, valves, heating/cooling system, and gaskets are inspected for corroded areas, defects, or any other conditions, including leakage, that might render the portable tank unsafe for filling, discharge or carriage; (c) Devices for tightening manhole covers are operative and there is no leakage at manhole covers or gaskets; (d) Missing or loose bolts or nuts on any flanged connection or blank flange are replaced or tightened; (e) All emergency devices and valves are free from corrosion, distortion and any damage or defect that could prevent their normal operation. Remote closure devices and self-closing stop-valves shall be operated to demonstrate proper operation; (f) Linings, if any, are inspected in accordance with criteria outlined by the lining manufacturer; (g) Required markings on the portable tank are legible and in accordance with the applicable requirements; and (h) The framework, supports and arrangements for lifting the portable tank are in a satisfactory condition. 6.7.2.19.9 The inspections and tests in 6.7.2.19.1, 6.7.2.19.3, 6.7.2.19.4, 6.7.2.19.5 and 6.7.2.19.7 shall be performed or witnessed by an expert approved by the competent authority or its authorized body. When the pressure test is a part of the inspection and test, the test pressure shall be the one indicated on the data plate of the portable tank. While under pressure, the portable tank shall be inspected for any leaks in the shell, piping or equipment. 6.7.2.19.10 In all cases when cutting, burning or welding operations on the shell have been effected, that work shall be to the approval of the competent authority or its authorized body taking into account the pressure vessel code used for the construction of the shell. A pressure test to the original test pressure shall be performed after the work is completed. 6.7.2.19.11 When evidence of any unsafe condition is discovered, the portable tank shall not be returned to service until it has been corrected and the test is repeated and passed. . - 417 - 6.7.2.20 Marking 6.7.2.20.1 Every portable tank shall be fitted with a corrosion resistant metal plate permanently attached to the portable tank in a conspicuous place readily accessible for inspection. When for reasons of portable tank arrangements the plate cannot be permanently attached to the shell, the shell shall be marked with at least the information required by the pressure vessel code. As a minimum, at least the following information shall be marked on the plate by stamping or by any other similar method: (a) Owner information (i) (b) (c) Owner’s registration number; Manufacturing information (i) Country of manufacture; (ii) Year of manufacture; (iii) Manufacturer’s name or mark; (iv) Manufacturer’s serial number; Approval information (i) The United Nations packaging symbol ; This symbol shall not be used for any purpose other than certifying that a packaging, a portable tank or a MEGC complies with the relevant requirements in Chapter 6.1, 6.2, 6.3, 6.5, 6.6 or 6.72; (d) (e) (ii) Approval country; (iii) Authorized body for the design approval; (iv) Design approval number; (v) Letters ‘AA’, if the design was approved under alternative arrangements (see 6.7.1.2); (vi) Pressure vessel code to which the shell is designed; Pressures (i) MAWP (in bar gauge or kPa gauge)3; (ii) Test pressure (in bar gauge or kPa gauge)3; (iii) Initial pressure test date (month and year); (iv) Identification mark of the initial pressure test witness; (v) External design pressure4 (in bar gauge or kPa gauge)3; (vi) MAWP for heating/cooling system (in bar gauge or kPa gauge)3 (when applicable); Temperatures (i) (f) (g) Design temperature range (in °C)3; Materials (i) Shell material(s) and material standard reference(s); (ii) Equivalent thickness in reference steel (in mm)3; (iii) Lining material (when applicable); Capacity 2 This symbol is also used to certify that flexible bulk containers authorized for other modes of transport comply with the requirements in Chapter 6.8 of the UN Model Regulations. 3 The unit used shall be indicated. 4 See 6.7.2.2.10. - 418 - (i) Tank water capacity at 20 °C (in litres)3; This indication is to be followed by the symbol "S" when the shell is divided by surge plates into sections of not more than 7 500 litres capacity; (ii) Water capacity of each compartment at 20 °C (in litres)3 (when applicable, for multicompartment tanks). This indication is to be followed by the symbol "S" when the compartment is divided by surge plates into sections of not more than 7 500 litres capacity; (h) Periodic inspections and tests (i) Type of the most recent periodic test (2.5-year, 5-year or exceptional); (ii) Date of the most recent periodic test (month and year); (iii) Test pressure (in bar gauge or kPa gauge)3 of the most recent periodic test (if applicable); (iv) Identification mark of the authorized body who performed or witnessed the most recent test. Figure 6.7.2.20.1: Example of identification plate marking Owner’s registration number MANUFACTURING INFORMATION Country of manufacture Year of manufacture Manufacturer Manufacturer’s serial number APPROVAL INFORMATION Approval country Authorized body for design approval Design approval number Shell design code (pressure vessel code) PRESSURES MAWP Test pressure Initial pressure test date: (mm/yyyy) External design pressure MAWP for heating/cooling system (when applicable) TEMPERATURES Design temperature range MATERIALS Shell material(s) and material standard reference(s) Equivalent thickness in reference steel Lining material (when applicable) CAPACITY Tank water capacity at 20 °C Water capacity of compartment at 20 °C (when applicable, for multi-compartment tanks) ‘AA’ (if applicable) bar or kPa bar or kPa Witness stamp: bar or kPa bar or kPa °C 3 °C mm litres ‘S’ (if applicable) litres ‘S’ (if applicable) PERIODIC INSPECTIONS / TESTS Witness stamp and Test type Test date Test type test pressurea (mm/yyyy) bar or kPa a to Test pressure if applicable. The unit used shall be indicated. - 419 - Test date (mm/yyyy) Witness stamp and test pressurea bar or kPa 6.7.2.20.2 The following particulars shall be durably marked either on the portable tank itself or on a metal plate firmly secured to the portable tank: Name of the operator Maximum permissible gross mass (MPGM) ___________ kg Unladen (tare) mass ___________ kg Portable tank instruction in accordance with 4.2.5.2.6 NOTE: For the identification of the substances being carried, see also Part 5. 6.7.2.20.3 If a portable tank is designed and approved for handling in open seas, the words "OFFSHORE PORTABLE TANK" shall be marked on the identification plate. 6.7.3 Requirements for the design, construction, inspection and testing of portable tanks intended for the carriage of non-refrigerated liquefied gases NOTE: These requirements also apply to portable tanks intended for the carriage of chemicals under pressure (UN Nos. 3500, 3501, 3502, 3503, 3504 and 3505). 6.7.3.1 Definitions For the purposes of this section: Alternative arrangement means an approval granted by the competent authority for a portable tank or MEGC that has been designed, constructed or tested to technical requirements or testing methods other than those specified in this Chapter; Portable tank means a multimodal tank having a capacity of more than 450 litres used for the carriage of non-refrigerated liquefied gases of Class 2. The portable tank includes a shell fitted with service equipment and structural equipment necessary for the carriage of gases. The portable tank shall be capable of being filled and discharged without the removal of its structural equipment. It shall possess stabilizing members external to the shell, and shall be capable of being lifted when full. It shall be designed primarily to be loaded onto a vehicle, wagon or sea-going or inland navigation vessel and shall be equipped with skids, mountings or accessories to facilitate mechanical handling. Tankvehicles, tank-wagons, non-metallic tanks, intermediate bulk containers (IBCs), gas cylinders and large receptacles are not considered to fall within the definition for portable tanks; Shell means the part of the portable tank which retains the non-refrigerated liquefied gas intended for carriage (tank proper), including openings and their closures, but does not include service equipment or external structural equipment; Service equipment means measuring instruments and filling, discharge, venting, safety and insulating devices; Structural equipment means the reinforcing, fastening, protective and stabilizing members external to the shell; Maximum allowable working pressure (MAWP) means a pressure that shall be not less than the highest of the following pressures measured at the top of the shell while in operating position, but in no case less than 7 bar: (a) The maximum effective gauge pressure allowed in the shell during filling or discharge; or (b) The maximum effective gauge pressure to which the shell is designed, which shall be: (i) for a non-refrigerated liquefied gas listed in the portable tank instruction T50 in 4.2.5.2.6, the MAWP (in bar) given in T50 portable tank instruction for that gas; - 420 - (ii) (iii) for other non-refrigerated liquefied gases, not less than the sum of: - the absolute vapour pressure (in bar) of the non-refrigerated liquefied gas at the design reference temperature minus 1 bar; and - the partial pressure (in bar) of air or other gases in the ullage space being determined by the design reference temperature and the liquid phase expansion due to an increase of the mean bulk temperature of tr -tf (tf = filling temperature, usually 15 °C, tr = maximum mean bulk temperature, 50 °C); for chemicals under pressure, the MAWP (in bar) given in T50 portable tank instruction for the liquefied gas portion of the propellants listed in T50 in 4.2.5.2.6; Design pressure means the pressure to be used in calculations required by a recognized pressure vessel code. The design pressure shall be not less than the highest of the following pressures: (a) The maximum effective gauge pressure allowed in the shell during filling or discharge; or (b) The sum of: (i) the maximum effective gauge pressure to which the shell is designed as defined in (b) of the MAWP definition (see above); and (ii) a head pressure determined on the basis of the static forces specified in 6.7.3.2.9, but not less than 0.35 bar; Test pressure means the maximum gauge pressure at the top of the shell during the pressure test; Leakproofness test means a test using gas subjecting the shell and its service equipment to an effective internal pressure of not less than 25% of the MAWP; Maximum permissible gross mass (MPGM) means the sum of the tare mass of the portable tank and the heaviest load authorized for carriage; Reference steel means a steel with a tensile strength of 370 N/mm2 and an elongation at fracture of 27%; Mild steel means a steel with a guaranteed minimum tensile strength of 360 N/mm2 to 440 N/mm2 and a guaranteed minimum elongation at fracture conforming to 6.7.3.3.3.3; Design temperature range for the shell shall be -40 °C to 50 °C for non-refrigerated liquefied gases carried under ambient conditions. More severe design temperatures shall be considered for portable tanks subjected to severe climatic conditions; Design reference temperature means the temperature at which the vapour pressure of the contents is determined for the purpose of calculating the MAWP. The design reference temperature shall be less than the critical temperature of the non-refrigerated liquefied gas or liquefied gas propellants of chemicals under pressure intended to be carried to ensure that the gas at all times is liquefied. This value for each portable tank type is as follows: (a) Shell with a diameter of 1.5 metres or less: 65 °C; (b) Shell with a diameter of more than 1.5 metres: (i) without insulation or sun shield: 60 °C; (ii) with sun shield (see 6.7.3.2.12): 55 °C; and (iii) with insulation (see 6.7.3.2.12) : 50 °C; Filling density means the average mass of non-refrigerated liquefied gas per litre of shell capacity (kg/l). The filling density is given in portable tank instruction T50 in 4.2.5.2.6. - 421 - 6.7.3.2 General design and construction requirements 6.7.3.2.1 Shells shall be designed and constructed in accordance with the requirements of a pressure vessel code recognized by the competent authority. Shells shall be made of steel suitable for forming. The materials shall in principle conform to national or international material standards. For welded shells, only a material whose weldability has been fully demonstrated shall be used. Welds shall be skilfully made and afford complete safety. When the manufacturing process or the materials make it necessary, the shells shall be suitability heat-treated to guarantee adequate toughness in the weld and in the heat affected zones. In choosing the material the design temperature range shall be taken into account with respect to risk of brittle fracture, to stress corrosion cracking and to resistance to impact. When fine grain steel is used, the guaranteed value of the yield strength shall be not more than 460 N/mm2 and the guaranteed value of the upper limit of the tensile strength shall be not more than 725 N/mm2 according to the material specification. Portable tank materials shall be suitable for the external environment in which they may be carried. 6.7.3.2.2 Portable tank shells, fittings and pipework shall be constructed of materials which are: (a) Substantially immune to attack by the non-refrigerated liquefied gas(es) intended to be carried; or (b) Properly passivated or neutralized by chemical reaction. 6.7.3.2.3 Gaskets shall be made of materials compatible with the non-refrigerated liquefied gas(es) intended to be carried. 6.7.3.2.4 Contact between dissimilar metals which could result in damage by galvanic action shall be avoided. 6.7.3.2.5 The materials of the portable tank, including any devices, gaskets, and accessories, shall not adversely affect the non-refrigerated liquefied gas(es) intended for carriage in the portable tank. 6.7.3.2.6 Portable tanks shall be designed and constructed with supports to provide a secure base during carriage and with suitable lifting and tie-down attachments. 6.7.3.2.7 Portable tanks shall be designed to withstand, without loss of contents, at least the internal pressure due to the contents, and the static, dynamic and thermal loads during normal conditions of handling and carriage. The design shall demonstrate that the effects of fatigue, caused by repeated application of these loads through the expected life of the portable tank, have been taken into account. 6.7.3.2.8 Shells shall be designed to withstand an external pressure of at least 0.4 bar (gauge pressure) above the internal pressure without permanent deformation. When the shell is to be subjected to a significant vacuum before filling or during discharge it shall be designed to withstand an external pressure of at least 0.9 bar (gauge pressure) above the internal pressure and shall be proven at that pressure. 6.7.3.2.9 Portable tanks and their fastenings shall, under the maximum permissible load, be capable of absorbing the following separately applied static forces: 1 (a) In the direction of travel: twice the MPGM multiplied by the acceleration due to gravity (g)1; (b) Horizontally at right angles to the direction of travel: the MPGM (when the direction of travel is not clearly determined, the forces shall be equal to twice the MPGM) multiplied by the acceleration due to gravity (g)1; (c) Vertically upwards: the MPGM multiplied by the acceleration due to gravity (g)1; and (d) Vertically downwards: twice the MPGM (total loading including the effect of gravity) multiplied by the acceleration due to gravity (g)1. For calculation purposes g = 9.81 m/s2. - 422 - 6.7.3.2.10 Under each of the forces in 6.7.3.2.9, the safety factor to be observed shall be as follows: (a) For steels having a clearly defined yield point, a safety factor of 1.5 in relation to the guaranteed yield strength; or (b) For steels with no clearly defined yield point, a safety factor of 1.5 in relation to the guaranteed 0.2% proof strength and, for austenitic steels, the 1% proof strength. 6.7.3.2.11 The values of yield strength or proof strength shall be the values according to national or international material standards. When austenitic steels are used, the specified minimum values of yield strength and proof strength according to the material standards may be increased by up to 15% when these greater values are attested in the material inspection certificate. When no material standard exists for the steel in question, the value of yield strength or proof strength used shall be approved by the competent authority. 6.7.3.2.12 When the shells intended for the carriage of non-refrigerated liquefied gases are equipped with thermal insulation, the thermal insulation systems shall satisfy the following requirements: (a) It shall consist of a shield covering not less than the upper third but not more than the upper half of the surface of the shell and separated from the shell by an air space about 40 mm across; (b) It shall consist of a complete cladding of adequate thickness of insulating materials protected so as to prevent the ingress of moisture and damage under normal conditions of carriage and so as to provide a thermal conductance of not more than 0.67 (W.m-2.K-1); (c) When the protective covering is so closed as to be gas-tight, a device shall be provided to prevent any dangerous pressure from developing in the insulating layer in the event of inadequate gas tightness of the shell or of its items of equipment; and (d) The thermal insulation shall not inhibit access to the fittings and discharge devices. 6.7.3.2.13 Portable tanks intended for the carriage of flammable non-refrigerated liquefied gases shall be capable of being electrically earthed. 6.7.3.3 Design criteria 6.7.3.3.1 Shells shall be of a circular cross-section. 6.7.3.3.2 Shells shall be designed and constructed to withstand a test pressure not less than 1.3 times the design pressure. The shell design shall take into account the minimum MAWP values provided in portable tank instruction T50 in 4.2.5.2.6 for each non-refrigerated liquefied gas intended for carriage. Attention is drawn to the minimum shell thickness requirements for these shells specified in 6.7.3.4. 6.7.3.3.3 For steels exhibiting a clearly defined yield point or characterized by a guaranteed proof strength (0.2% proof strength, generally, or 1% proof strength for austenitic steels) the primary membrane stress  (sigma) in the shell shall not exceed 0.75 Re or 0.50 Rm, whichever is lower, at the test pressure, where: Re = yield strength in N/mm2, or 0.2% proof strength or, for austenitic steels, 1% proof stress; Rm = minimum tensile strength in N/mm2. 6.7.3.3.3.1 The values of Re and Rm to be used shall be the specified minimum values according to national or international material standards. When austenitic steels are used, the specified minimum values for Re and Rm according to the material standards may be increased by up to 15% when these greater values are attested in the material inspection certificate. When no material standard exists for the steel in question, the values of Re and Rm used shall be approved by the competent authority or its authorized body. 6.7.3.3.3.2 Steels which have a Re/Rm ratio of more than 0.85 are not allowed for the construction of welded shells. The values of Re and Rm to be used in determining this ratio shall be the values specified in the material inspection certificate. - 423 - 6.7.3.3.3.3 Steels used in the construction of shells shall have an elongation at fracture, in %, of not less than 10 000/Rm with an absolute minimum of 16% for fine grain steels and 20% for other steels. 6.7.3.3.3.4 For the purpose of determining actual values for materials, it shall be noted that for sheet metal, the axis of the tensile test specimen shall be at right angles (transversely) to the direction of rolling. The permanent elongation at fracture shall be measured on test specimens of rectangular cross sections in accordance with ISO 6892:1998 using a 50 mm gauge length. 6.7.3.4 Minimum shell thickness 6.7.3.4.1 The minimum shell thickness shall be the greater thickness based on: (a) The minimum thickness determined in accordance with the requirements in 6.7.3.4; and (b) The minimum thickness determined in accordance with the recognized pressure vessel code including the requirements in 6.7.3.3. 6.7.3.4.2 The cylindrical portions, ends (heads) and manhole covers of shells of not more than 1.80 m in diameter shall be not less than 5 mm thick in the reference steel or of equivalent thickness in the steel to be used. Shells of more than 1.80 m in diameter shall be not less than 6 mm thick in the reference steel or of equivalent thickness in the steel to be used. 6.7.3.4.3 The cylindrical portions, ends (heads) and manhole covers of all shells shall be not less than 4 mm thick regardless of the material of construction. 6.7.3.4.4 The equivalent thickness of a steel other than the thickness prescribed for the reference steel in 6.7.3.4.2 shall be determined using the following formula: e1  21,4e o 3 Rm 1 A 1 where: e1 = required equivalent thickness (in mm) of the steel to be used; e0 = minimum thickness (in mm) for the reference steel specified in 6.7.3.4.2; Rm1 = guaranteed minimum tensile strength (in N/mm2) of the steel to be used (see 6.7.3.3.3); A1 = guaranteed minimum elongation at fracture (in %) of the steel to be used according to national or international standards. 6.7.3.4.5 In no case shall the wall thickness be less than that prescribed in 6.7.3.4.1 to 6.7.3.4.3. All parts of the shell shall have a minimum thickness as determined by 6.7.3.4.1 to 6.7.3.4.3. This thickness shall be exclusive of any corrosion allowance. 6.7.3.4.6 When mild steel is used (see 6.7.3.1), calculation using the formula in 6.7.3.4.4 is not required. 6.7.3.4.7 There shall be no sudden change of plate thickness at the attachment of the ends (heads) to the cylindrical portion of the shell. 6.7.3.5 Service equipment 6.7.3.5.1 Service equipment shall be so arranged as to be protected against the risk of being wrenched off or damaged during handling and carriage. When the connection between the frame and the shell allows relative movement between the sub-assemblies, the equipment shall be so fastened as to permit such movement without risk of damage to working parts. The external discharge fittings (pipe sockets, shut-off devices), the internal stop-valve and its seating shall be protected against the danger of being wrenched off by external forces (for example using shear sections). The filling and discharge devices (including flanges or threaded plugs) and any protective caps shall be capable of being secured against unintended opening. - 424 - 6.7.3.5.2 All openings with a diameter of more than 1.5 mm in shells of portable tanks, except openings for pressure-relief devices, inspection openings and closed bleed holes, shall be fitted with at least three mutually independent shut-off devices in series, the first being an internal stop-valve, excess flow valve or equivalent device, the second being an external stop-valve and the third being a blank flange or equivalent device. 6.7.3.5.2.1 When a portable tank is fitted with an excess flow valve, the excess flow valve shall be so fitted that its seating is inside the shell or inside a welded flange or, when fitted externally, its mountings shall be designed so that in the event of impact its effectiveness shall be maintained. The excess flow valves shall be selected and fitted so as to close automatically when the rated flow specified by the manufacturer is reached. Connections and accessories leading to or from such a valve shall have a capacity for a flow more than the rated flow of the excess flow valve. 6.7.3.5.3 For filling and discharge openings, the first shut-off device shall be an internal stop-valve and the second shall be a stop-valve placed in an accessible position on each discharge and filling pipe. 6.7.3.5.4 For filling and discharge bottom openings of portable tanks intended for the carriage of flammable and/or toxic non-refrigerated liquefied gases or chemicals under pressure the internal stop-valve shall be a quick closing safety device which closes automatically in the event of unintended movement of the portable tank during filling or discharge or fire engulfment. Except for portable tanks having a capacity of not more than 1 000 litres, it shall be possible to operate this device by remote control. 6.7.3.5.5 In addition to filling, discharge and gas pressure equalizing orifices, shells may have openings in which gauges, thermometers and manometers can be fitted. Connections for such instruments shall be made by suitable welded nozzles or pockets and not be screwed connections through the shell. 6.7.3.5.6 All portable tanks shall be fitted with manholes or other inspection openings of suitable size to allow for internal inspection and adequate access for maintenance and repair of the interior. 6.7.3.5.7 External fittings shall be grouped together so far as reasonably practicable. 6.7.3.5.8 Each connection on a portable tank shall be clearly marked to indicate its function. 6.7.3.5.9 Each stop-valve or other means of closure shall be designed and constructed to a rated pressure not less than the MAWP of the shell taking into account the temperatures expected during carriage. All stop-valves with a screwed spindle shall close by a clockwise motion of the handwheel. For other stop-valves the position (open and closed) and direction of closure shall be clearly indicated. All stop-valves shall be designed to prevent unintentional opening. 6.7.3.5.10 Piping shall be designed, constructed and installed so as to avoid the risk of damage due to thermal expansion and contraction, mechanical shock and vibration. All piping shall be of suitable metallic material. Welded pipe joints shall be used wherever possible. 6.7.3.5.11 Joints in copper tubing shall be brazed or have an equally strong metal union. The melting point of brazing materials shall be no lower than 525 °C. The joints shall not decrease the strength of tubing as may happen when cutting threads. 6.7.3.5.12 The burst pressure of all piping and pipe fittings shall be not less than the highest of four times the MAWP of the shell or four times the pressure to which it may be subjected in service by the action of a pump or other device (except pressure-relief devices). 6.7.3.5.13 Ductile metals shall be used in the construction of valves and accessories. 6.7.3.6 Bottom openings 6.7.3.6.1 Certain non-refrigerated liquefied gases shall not be carried in portable tanks with bottom openings when portable tank instruction T50 in 4.2.5.2.6 indicates that bottom openings are not allowed. There shall be no openings below the liquid level of the shell when it is filled to its maximum permissible filling limit. - 425 - 6.7.3.7 Pressure-relief devices 6.7.3.7.1 Portable tanks shall be provided with one or more spring-loaded pressure-relief devices. The pressurerelief devices shall open automatically at a pressure not less than the MAWP and be fully open at a pressure equal to 110% of the MAWP. These devices shall, after discharge, close at a pressure not lower than 10% below the pressure at which discharge starts and shall remain closed at all lower pressures. The pressure-relief devices shall be of a type that will resist dynamic forces including liquid surge. Frangible discs not in series with a spring-loaded pressure-relief device are not permitted. 6.7.3.7.2 Pressure-relief devices shall be designed to prevent the entry of foreign matter, the leakage of gas and the development of any dangerous excess pressure. 6.7.3.7.3 Portable tanks intended for the carriage of certain non-refrigerated liquefied gases identified in portable tank instruction T50 in 4.2.5.2.6 shall have a pressure-relief device approved by the competent authority. Unless a portable tank in dedicated service is fitted with an approved relief device constructed of materials compatible with the load, such device shall comprise a frangible disc preceding a spring-loaded device. The space between the frangible disc and the device shall be provided with a pressure gauge or a suitable tell-tale indicator. This arrangement permits the detection of disc rupture, pinholing or leakage which could cause a malfunction of the pressure-relief device. The frangible discs shall rupture at a nominal pressure 10% above the start-to-discharge pressure of the relief device. 6.7.3.7.4 In the case of multi-purpose portable tanks, the pressure-relief devices shall open at a pressure indicated in 6.7.3.7.1 for the gas having the highest maximum allowable pressure of the gases allowed to be carried in the portable tank. 6.7.3.8 Capacity of relief devices 6.7.3.8.1 The combined delivery capacity of the relief devices shall be sufficient that, in the event of total fire engulfment, the pressure (including accumulation) inside the shell does not exceed 120% of the MAWP. Spring-loaded relief devices shall be used to achieve the full relief capacity prescribed. In the case of multi-purpose tanks, the combined delivery capacity of the pressure-relief devices shall be taken for the gas which requires the highest delivery capacity of the gases allowed to be carried in portable tanks. 6.7.3.8.1.1 To determine the total required capacity of the relief devices, which shall be regarded as being the sum of the individual capacities of the several devices, the following formula5 shall be used: Q  12.4 FA 0.82 LC ZT M where: Q = minimum required rate of discharge in cubic metres of air per second (m3/s) at standard conditions: 1 bar and 0 °C (273 K); F = is a coefficient with the following value: for uninsulated shells: F = 1; for insulated shells: F = U(649-t)/13.6 but in no case is less than 0.25 where: U = thermal conductance of the insulation, in Kw.m-2.K-1, at 38 °C; 5 This formula applies only to non-refrigerated liquefied gases which have critical temperatures well above the temperature at the accumulating condition. For gases which have critical temperatures near or below the temperature at the accumulating condition, the calculation of the pressure-relief device delivery capacity shall consider further thermodynamic properties of the gas (see for example CGA S-1.2-2003 "Pressure Relief Device Standards - Part 2 Cargo and Portable Tanks for Compressed Gases"). - 426 - t = actual temperature of the non-refrigerated liquefied gas during filling (°C); when this temperature is unknown, let t=15 °C; The value of F given above for insulated shells may be taken provided that the insulation is in accordance with 6.7.3.8.1.2; where: A = total external surface area of shell in square metres; Z = the gas compressibility factor in the accumulating condition (when this factor is unknown, let Z =1.0); T = absolute temperature in Kelvin (°C + 273) above the pressure relief devices in the accumulating condition; L = the latent heat of vaporization of the liquid, in kJ/kg, in the accumulating condition; M = molecular mass of the discharged gas; C = a constant which is derived from one of the following formulae as a function of the ratio k of specific heats k cp cv where cp is the specific heat at constant pressure; and cv is the specific heat at constant volume. when k>1: k 1  2  k 1 C  k   k  1 when k = 1 or k is unknown: C 1 e  0.607 where e is the mathematical constant 2.7183 - 427 - C may also be taken from the following table: k 1.00 1.02 1.04 1.06 1.08 1.10 1.12 1.14 1.16 1.18 1.20 1.22 1.24 6.7.3.8.1.2 C 0.607 0.611 0.615 0.620 0.624 0.628 0.633 0.637 0.641 0.645 0.649 0.652 0.656 k 1.26 1.28 1.30 1.32 1.34 1.36 1.38 1.40 1.42 1.44 1.46 1.48 1.50 C 0.660 0.664 0.667 0.671 0.674 0.678 0.681 0.685 0.688 0.691 0.695 0.698 0.701 k 1.52 1.54 1.56 1.58 1.60 1.62 1.64 1.66 1.68 1.70 2.00 2.20 C 0.704 0.707 0.710 0.713 0.716 0.719 0.722 0.725 0.728 0.731 0.770 0.793 Insulation systems, used for the purpose of reducing the venting capacity, shall be approved by the competent authority or its authorized body. In all cases, insulation systems approved for this purpose shall: (a) Remain effective at all temperatures up to 649 °C; and (b) Be jacketed with a material having a melting point of 700 °C or greater. 6.7.3.9 Marking of pressure-relief devices 6.7.3.9.1 Every pressure-relief device shall be plainly and permanently marked with the following particulars: (a) The pressure (in bar or kPa) at which it is set to discharge; (b) The allowable tolerance at the discharge pressure for spring-loaded devices; (c) The reference temperature corresponding to the rated pressure for frangible discs; (d) The rated flow capacity of the device in standard cubic metres of air per second (m3/s); and (e) The cross sectional flow areas of the spring loaded pressure-relief devices and frangible discs in mm². When practicable, the following information shall also be shown: (f) The manufacturer's name and relevant catalogue number of the device. 6.7.3.9.2 The rated flow capacity marked on the pressure-relief devices shall be determined according to ISO 4126-1:2004 and ISO 4126-7:2004. 6.7.3.10 Connections to pressure-relief devices 6.7.3.10.1 Connections to pressure-relief devices shall be of sufficient size to enable the required discharge to pass unrestricted to the safety device. No stop-valve shall be installed between the shell and the pressure-relief devices except when duplicate devices are provided for maintenance or other reasons and the stop-valves serving the devices actually in use are locked open or the stop-valves are interlocked so that at least one of the duplicate devices is always operable and capable of meeting the requirements of 6.7.3.8. There shall be no obstruction in an opening leading to a vent or pressure-relief device which might restrict or cut-off the flow from the shell to that device. Vents from the pressure-relief devices, when used, shall deliver the relieved vapour or liquid to the atmosphere in conditions of minimum back-pressure on the relieving device. - 428 - 6.7.3.11 Siting of pressure-relief devices 6.7.3.11.1 Each pressure-relief device inlet shall be situated on top of the shell in a position as near the longitudinal and transverse centre of the shell as reasonably practicable. All pressure relief device inlets shall under maximum filling conditions be situated in the vapour space of the shell and the devices shall be so arranged as to ensure that the escaping vapour is discharged unrestrictedly. For flammable non-refrigerated liquefied gases, the escaping vapour shall be directed away from the shell in such a manner that it cannot impinge upon the shell. Protective devices which deflect the flow of vapour are permissible provided the required relief-device capacity is not reduced. 6.7.3.11.2 Arrangements shall be made to prevent access to the pressure-relief devices by unauthorized persons and to protect the devices from damage caused by the portable tank overturning. 6.7.3.12 Gauging devices 6.7.3.12.1 Unless a portable tank is intended to be filled by weight it shall be equipped with one or more gauging devices. Glass level-gauges and gauges made of other fragile material, which are in direct communication with the contents of the shell shall not be used. 6.7.3.13 Portable tank supports, frameworks, lifting and tie-down attachments 6.7.3.13.1 Portable tanks shall be designed and constructed with a support structure to provide a secure base during carriage. The forces specified in 6.7.3.2.9 and the safety factor specified in 6.7.3.2.10 shall be considered in this aspect of the design. Skids, frameworks, cradles or other similar structures are acceptable. 6.7.3.13.2 The combined stresses caused by portable tank mountings (e.g. cradles, frameworks, etc.) and portable tank lifting and tie-down attachments shall not cause excessive stress in any portion of the shell. Permanent lifting and tie-down attachments shall be fitted to all portable tanks. Preferably they shall be fitted to the portable tank supports but may be secured to reinforcing plates located on the shell at the points of support. 6.7.3.13.3 In the design of supports and frameworks the effects of environmental corrosion shall be taken into account. 6.7.3.13.4 Forklift pockets shall be capable of being closed off. The means of closing forklift pockets shall be a permanent part of the framework or permanently attached to the framework. Single compartment portable tanks with a length less than 3.65 m need not have closed off forklift pockets provided that: 6.7.3.13.5 (a) The shell and all the fittings are well protected from being hit by the forklift blades; and (b) The distance between the centres of the forklift pockets is at least half of the maximum length of the portable tank. When portable tanks are not protected during carriage, according to 4.2.2.3, the shells and service equipment shall be protected against damage to the shell and service equipment resulting from lateral or longitudinal impact or overturning. External fittings shall be protected so as to preclude the release of the shell contents upon impact or overturning of the portable tank on its fittings. Examples of protection include: (a) Protection against lateral impact which may consist of longitudinal bars protecting the shell on both sides at the level of the median line; (b) Protection of the portable tank against overturning which may consist of reinforcement rings or bars fixed across the frame; (c) Protection against rear impact which may consist of a bumper or frame; (d) Protection of the shell against damage from impact or overturning by use of an ISO frame in accordance with ISO 1496-3:1995. - 429 - 6.7.3.14 Design approval 6.7.3.14.1 The competent authority or its authorized body shall issue a design approval certificate for any new design of a portable tank. This certificate shall attest that a portable tank has been surveyed by that authority, is suitable for its intended purpose and meets the requirements of this Chapter and where appropriate the provisions for gases provided in portable tank instruction T50 in 4.2.5.2.6. When a series of portable tanks are manufactured without change in the design, the certificate shall be valid for the entire series. The certificate shall refer to the prototype test report, the gases allowed to be carried, the materials of construction of the shell and an approval number. The approval number shall consist of the distinguishing sign or mark of the State in whose territory the approval was granted, i.e. the distinguishing sign for use in international traffic, as prescribed by the Convention on Road Traffic, Vienna 1968, and a registration number. Any alternative arrangements according to 6.7.1.2 shall be indicated on the certificate. A design approval may serve for the approval of smaller portable tanks made of materials of the same kind and thickness, by the same fabrication techniques and with identical supports, equivalent closures and other appurtenances. 6.7.3.14.2 The prototype test report for the design approval shall include at least the following: (a) The results of the applicable framework test specified in ISO 1496-3:1995; (b) The results of the initial inspection and test in 6.7.3.15.3; and (c) The results of the impact test in 6.7.3.15.1, when applicable. 6.7.3.15 Inspection and testing 6.7.3.15.1 Portable tanks meeting the definition of container in the International Convention for Safe Containers (CSC), 1972, as amended, shall not be used unless they are successfully qualified by subjecting a representative prototype of each design to the Dynamic, Longitudinal Impact Test prescribed in the Manual of Tests and Criteria, Part IV, Section 41. 6.7.3.15.2 The shell and items of equipment of each portable tank shall be inspected and tested before being put into service for the first time (initial inspection and test) and thereafter at not more than five-year intervals (5 year periodic inspection and test) with an intermediate periodic inspection and test (2.5 year periodic inspection and test) midway between the 5 year periodic inspections and tests. The 2.5 year inspection and test may be performed within 3 months of the specified date. An exceptional inspection and test shall be performed regardless of the last periodic inspection and test when necessary according to 6.7.3.15.7. 6.7.3.15.3 The initial inspection and test of a portable tank shall include a check of the design characteristics, an internal and external examination of the portable tank and its fittings with due regard to the nonrefrigerated liquefied gases to be carried, and a pressure test referring to the test pressures according to 6.7.3.3.2. The pressure test may be performed as a hydraulic test or by using another liquid or gas with the agreement of the competent authority or its authorized body. Before the portable tank is placed into service, a leakproofness test and a test of the satisfactory operation of all service equipment shall also be performed. When the shell and its fittings have been pressure-tested separately, they shall be subjected together after assembly to a leakproofness test. All welds subject to full stress level in the shell shall be inspected during the initial test by radiographic, ultrasonic, or another suitable nondestructive test method. This does not apply to the jacket. 6.7.3.15.4 The 5 year periodic inspection and test shall include an internal and external examination and, as a general rule, a hydraulic pressure test. Sheathing, thermal insulation and the like shall be removed only to the extent required for reliable appraisal of the condition of the portable tank. When the shell and equipment have been pressure-tested separately, they shall be subjected together after assembly to a leakproofness test. - 430 - 6.7.3.15.5 The intermediate 2.5 year periodic inspection and test shall at least include an internal and external examination of the portable tank and its fittings with due regard to the non-refrigerated liquefied gases intended to be carried, a leakproofness test and a check of the satisfactory operation of all service equipment. Sheathing thermal insulation and the like shall be removed only to the extent required for reliable appraisal of the condition of the portable tank. For portable tanks intended for the carriage of a single non-refrigerated liquefied gas, the 2.5 year internal examination may be waived or substituted by other test methods or inspection procedures specified by the competent authority or its authorized body. 6.7.3.15.6 A portable tank may not be filled and offered for carriage after the date of expiry of the last 5 year or 2.5 year periodic inspection and test as required by 6.7.3.15.2. However a portable tank filled prior to the date of expiry of the last periodic inspection and test may be carried for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection. In addition, a portable tank may be carried after the date of expiry of the last periodic test and inspection: (a) After emptying but before cleaning, for purposes of performing the next required test or inspection prior to refilling; and (b) Unless otherwise approved by the competent authority, for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection, in order to allow the return of dangerous goods for proper disposal or recycling. Reference to this exemption shall be mentioned in the transport document. 6.7.3.15.7 The exceptional inspection and test is necessary when the portable tank shows evidence of damaged or corroded areas, or leakage, or other conditions that indicate a deficiency that could affect the integrity of the portable tank. The extent of the exceptional inspection and test shall depend on the amount of damage or deterioration of the portable tank. It shall include at least the 2.5 year inspection and test according to 6.7.3.15.5. 6.7.3.15.8 The internal and external examinations shall ensure that: 6.7.3.15.9 (a) The shell is inspected for pitting, corrosion, or abrasions, dents, distortions, defects in welds or any other conditions, including leakage, that might render the portable tank unsafe for carriage; (b) The piping, valves, and gaskets are inspected for corroded areas, defects, or any other conditions, including leakage, that might render the portable tank unsafe for filling, discharge or carriage; (c) Devices for tightening manhole covers are operative and there is no leakage at manhole covers or gaskets; (d) Missing or loose bolts or nuts on any flanged connection or blank flange are replaced or tightened; (e) All emergency devices and valves are free from corrosion, distortion and any damage or defect that could prevent their normal operation. Remote closure devices and self-closing stop-valves shall be operated to demonstrate proper operation; (f) Required markings on the portable tank are legible and in accordance with the applicable requirements; and (g) The framework, the supports and the arrangements for lifting the portable tank are in satisfactory condition. The inspections and tests in 6.7.3.15.1, 6.7.3.15.3, 6.7.3.15.4, 6.7.3.15.5 and 6.7.3.15.7 shall be performed or witnessed by an expert approved by the competent authority or its authorized body. When the pressure test is a part of the inspection and test, the test pressure shall be the one indicated on the data plate of the portable tank. While under pressure, the portable tank shall be inspected for any leaks in the shell, piping or equipment. - 431 - 6.7.3.15.10 In all cases when cutting, burning or welding operations on the shell have been effected, that work shall be to the approval of the competent authority or its authorized body taking into account the pressure vessel code used for the construction of the shell. A pressure test to the original test pressure shall be performed after the work is completed. 6.7.3.15.11 When evidence of any unsafe condition is discovered, the portable tank shall not be returned to service until it has been corrected and the pressure test is repeated and passed. 6.7.3.16 Marking 6.7.3.16.1 Every portable tank shall be fitted with a corrosion resistant metal plate permanently attached to the portable tank in a conspicuous place readily accessible for inspection. When for reasons of portable tank arrangements the plate cannot be permanently attached to the shell, the shell shall be marked with at least the information required by the pressure vessel code. As a minimum, at least the following information shall be marked on the plate by stamping or by any other similar method: (a) Owner information (i) Owner’s registration number; (b) Manufacturing information (i) Country of manufacture; (ii) Year of manufacture; (iii) Manufacturer’s name or mark; (iv) Manufacturer’s serial number; (c) Approval information (i) The United Nations packaging symbol ; This symbol shall not be used for any purpose other than certifying that a packaging, a portable tank or a MEGC complies with the relevant requirements in Chapter 6.1, 6.2, 6.3, 6.5, 6.6 or 6.72; (ii) Approval country; (iii) Authorized body for the design approval; (iv) Design approval number; (v) Letters ‘AA’, if the design was approved under alternative arrangements (see 6.7.1.2); (vi) Pressure vessel code to which the shell is designed; (d) Pressures (i) MAWP (in bar gauge or kPa gauge)3; (ii) Test pressure (in bar gauge or kPa gauge)3; (iii) Initial pressure test date (month and year); (iv) Identification mark of the initial pressure test witness; (v) External design pressure6 (in bar gauge or kPa gauge)3; (e) Temperatures (i) Design temperature range (in °C)3; (ii) Design reference temperature (in °C)3; 2 This symbol is also used to certify that flexible bulk containers authorized for other modes of transport comply with the requirements in Chapter 6.8 of the UN Model Regulations. 3 The unit used shall be indicated. 6 See 6.7.3.2.8. - 432 - (f) Materials (i) Shell material(s) and material standard reference(s); (ii) Equivalent thickness in reference steel (in mm)3; (g) Capacity (i) (h) Tank water capacity at 20 °C (in litres)3; Periodic inspections and tests (i) Type of the most recent periodic test (2.5-year, 5-year or exceptional); (ii) Date of the most recent periodic test (month and year); (iii) Test pressure (in bar gauge or kPa gauge)3 of the most recent periodic test (if applicable); (iv) Identification mark of the authorized body who performed or witnessed the most recent test. Figure 6.7.3.16.1: Example of identification plate marking Owner’s registration number MANUFACTURING INFORMATION Country of manufacture Year of manufacture Manufacturer Manufacturer’s serial number APPROVAL INFORMATION Approval country Authorized body for design approval Design approval number Shell design code (pressure vessel code) PRESSURES MAWP Test pressure Initial pressure test date: (mm/yyyy) Witness stamp: External design pressure TEMPERATURES Design temperature range °C Design reference temperature MATERIALS Shell material(s) and material standard reference(s) Equivalent thickness in reference steel CAPACITY Tank water capacity at 20 °C PERIODIC INSPECTIONS / TESTS Witness stamp and Test type Test date Test type Test date test pressurea (mm/yyyy) bar or kPa (mm/yyyy) a 3 Test pressure if applicable. The unit used shall be indicated. - 433 - ‘AA’ (if applicable) bar or kPa bar or kPa bar or kPa to °C °C mm litres Witness stamp and test pressurea bar or kPa 6.7.3.16.2 The following information shall be durably marked either on the portable tank itself or on a metal plate firmly secured to the portable tank: Name of the operator Name of non-refrigerated liquefied gas(es) permitted for carriage Maximum permissible load mass for each non-refrigerated liquefied gas permitted ________kg Maximum permissible gross mass (MPGM)__________kg Unladen (tare) mass_________kg Portable tank instruction in accordance with 4.2.5.2.6 NOTE: For the identification of the non-refrigerated liquefied gases being carried, see also Part 5. 6.7.3.16.3 If a portable tank is designed and approved for handling in open seas, the words "OFFSHORE PORTABLE TANK" shall be marked on the identification plate. 6.7.4 Requirements for the design, construction, inspection and testing of portable tanks intended for the carriage of refrigerated liquefied gases 6.7.4.1 Definitions For the purposes of this section: Alternative arrangement means an approval granted by the competent authority for a portable tank or MEGC that has been designed, constructed or tested to technical requirements or testing methods other than those specified in this Chapter; Portable tank means a thermally insulated multimodal tank having a capacity of more than 450 litres fitted with service equipment and structural equipment necessary for the carriage of refrigerated liquefied gases. The portable tank shall be capable of being filled and discharged without the removal of its structural equipment. It shall possess stabilizing members external to the tank, and shall be capable of being lifted when full. It shall be designed primarily to be loaded onto a vehicle, wagon or sea-going or inland navigation vessel and shall be equipped with skids, mountings or accessories to facilitate mechanical handling. Tank-vehicles, tank-wagons, non-metallic tanks, intermediate bulk containers (IBCs), gas cylinders and large receptacles are not considered to fall within the definition for portable tanks; Tank means a construction which normally consists of either : (a) A jacket and one or more inner shells where the space between the shell(s) and the jacket is exhausted of air (vacuum insulation) and may incorporate a thermal insulation system; or (b) A jacket and an inner shell with an intermediate layer of solid thermally insulating material (e.g. solid foam); Shell means the part of the portable tank which retains the refrigerated liquefied gas intended for carriage, including openings and their closures, but does not include service equipment or external structural equipment; Jacket means the outer insulation cover or cladding which may be part of the insulation system; Service equipment means measuring instruments and filling, discharge, venting, safety, pressurizing, cooling and thermal insulation devices; Structural equipment means the reinforcing, fastening, protective and stabilizing members external to the shell; Maximum allowable working pressure (MAWP) means the maximum effective gauge pressure permissible at the top of the shell of a loaded portable tank in its operating position including the highest effective pressure during filling and discharge; Test pressure means the maximum gauge pressure at the top of the shell during the pressure test; - 434 - Leakproofness test means a test using gas subjecting the shell and its service equipment, to an effective internal pressure not less than 90% of the MAWP; Maximum permissible gross mass (MPGM) means the sum of the tare mass of the portable tank and the heaviest load authorized for carriage; Holding time means the time that will elapse from the establishment of the initial filling condition until the pressure has risen due to heat influx to the lowest set pressure of the pressure limiting device(s); Reference steel means a steel with a tensile strength of 370 N/mm2 and an elongation at fracture of 27%; Minimum design temperature means the temperature which is used for the design and construction of the shell not higher than the lowest (coldest) temperature (service temperature) of the contents during normal conditions of filling, discharge and carriage. 6.7.4.2 General design and construction requirements 6.7.4.2.1 Shells shall be designed and constructed in accordance with the requirements of a pressure vessel code recognized by the competent authority. Shells and jackets shall be made of metallic materials suitable for forming. Jackets shall be made of steel. Non-metallic materials may be used for the attachments and supports between the shell and jacket, provided their material properties at the minimum design temperature are proven to be sufficient. The materials shall in principle conform to national or international material standards. For welded shells and jackets only materials whose weldability has been fully demonstrated shall be used. Welds shall be skilfully made and afford complete safety. When the manufacturing process or the materials make it necessary, the shell shall be suitably heat treated to guarantee adequate toughness in the weld and in the heat affected zones. In choosing the material, the minimum design temperature shall be taken into account with respect to risk of brittle fracture, to hydrogen embrittlement, to stress corrosion cracking and to resistance to impact. When fine grain steel is used, the guaranteed value of the yield strength shall be not more than 460 N/mm2 and the guaranteed value of the upper limit of the tensile strength shall be not more than 725 N/mm2 in accordance with the material specifications. Portable tank materials shall be suitable for the external environment in which they may be carried. 6.7.4.2.2 Any part of a portable tank, including fittings, gaskets and pipe-work, which can be expected normally to come into contact with the refrigerated liquefied gas carried shall be compatible with that refrigerated liquefied gas. 6.7.4.2.3 Contact between dissimilar metals which could result in damage by galvanic action shall be avoided. 6.7.4.2.4 The thermal insulation system shall include a complete covering of the shell(s) with effective insulating materials. External insulation shall be protected by a jacket so as to prevent the ingress of moisture and other damage under normal carriage conditions. When a jacket is so closed as to be gas-tight, a device shall be provided to prevent any dangerous pressure from developing in the insulation space. 6.7.4.2.5 6.7.4.2.6 Portable tanks intended for the carriage of refrigerated liquefied gases having a boiling point below minus (-) 182 °C at atmospheric pressure shall not include materials which may react with oxygen or oxygen enriched atmospheres in a dangerous manner, when located in parts of the thermal insulation when there is a risk of contact with oxygen or with oxygen enriched fluid. 6.7.4.2.7 Insulating materials shall not deteriorate unduly in service. 6.7.4.2.8 A reference holding time shall be determined for each refrigerated liquefied gas intended for carriage in a portable tank. 6.7.4.2.8.1 The reference holding time shall be determined by a method recognized by the competent authority on the basis of the following: (a) The effectiveness of the insulation system, determined in accordance with 6.7.4.2.8.2; (b) The lowest set pressure of the pressure limiting device(s); - 435 - 6.7.4.2.8.2 (c) The initial filling conditions; (d) An assumed ambient temperature of 30 °C; (e) The physical properties of the individual refrigerated liquefied gas intended to be carried. The effectiveness of the insulation system (heat influx in watts) shall be determined by type testing the portable tank in accordance with a procedure recognized by the competent authority. This test shall consist of either: (a) A constant pressure test (for example at atmospheric pressure) when the loss of refrigerated liquefied gas is measured over a period of time; or (b) A closed system test when the rise in pressure in the shell is measured over a period of time. When performing the constant pressure test, variations in atmospheric pressure shall be taken into account. When performing either tests corrections shall be made for any variation of the ambient temperature from the assumed ambient temperature reference value of 30 °C. NOTE: For the determination of the actual holding time before each journey, refer to 4.2.3.7. 6.7.4.2.9 The jacket of a vacuum-insulated double-wall tank shall have either an external design pressure not less than 100 kPa (1 bar) (gauge pressure) calculated in accordance with a recognized technical code or a calculated critical collapsing pressure of not less than 200 kPa (2 bar) (gauge pressure). Internal and external reinforcements may be included in calculating the ability of the jacket to resist the external pressure. 6.7.4.2.10 Portable tanks shall be designed and constructed with supports to provide a secure base during carriage and with suitable lifting and tie-down attachments. Portable tanks shall be designed to withstand, without loss of contents, at least the internal pressure due to the contents, and the static, dynamic and thermal loads during normal conditions of handling and carriage. The design shall demonstrate that the effects of fatigue, caused by repeated application of these loads through the expected life of the portable tank, have been taken into account. 6.7.4.2.11 6.7.4.2.12 6.7.4.2.13 1 Portable tanks and their fastenings under the maximum permissible load shall be capable of absorbing the following separately applied static forces: (a) In the direction of travel: twice the MPGM multiplied by the acceleration due to gravity (g) 1; (b) Horizontally at right angles to the direction of travel: the MPGM (when the direction of travel is not clearly determined, the forces shall be equal to twice the MPGM) multiplied by the acceleration due to gravity (g) 1; (c) Vertically upwards: the MPGM multiplied by the acceleration due to gravity (g) 1; and (d) Vertically downwards: twice the MPGM (total loading including the effect of gravity) multiplied by the acceleration due to gravity (g) 1. Under each of the forces in 6.7.4.2.12, the safety factor to be observed shall be as follows: (a) For materials having a clearly defined yield point, a safety factor of 1.5 in relation to the guaranteed yield strength; and (b) For materials with no clearly defined yield point, a safety factor of 1.5 in relation to the guaranteed 0.2% proof strength or, in case of austenitic steels, the 1% proof strength. For calculation purposes g = 9.81 m/s2. - 436 - 6.7.4.2.14 The values of yield strength or proof strength shall be the values according to national or international material standards. When austenitic steels are used, the specified minimum values according to the material standards may be increased by up to 15% when greater values are attested in the material inspection certificate. When no material standard exists for the metal in question, or when nonmetallic materials are used the values of yield strength or proof strength shall be approved by the competent authority. 6.7.4.2.15 Portable tanks intended for the carriage of flammable refrigerated liquefied gases shall be capable of being electrically earthed. 6.7.4.3 Design criteria 6.7.4.3.1 Shells shall be of a circular cross section. 6.7.4.3.2 Shells shall be designed and constructed to withstand a test pressure not less than 1.3 times the MAWP. For shells with vacuum insulation the test pressure shall not be less than 1.3 times the sum of the MAWP and 100 kPa (1 bar). In no case shall the test pressure be less than 300 kPa (3 bar) (gauge pressure). Attention is drawn to the minimum shell thickness requirements, specified in 6.7.4.4.2 to 6.7.4.4.7. 6.7.4.3.3 For metals exhibiting a clearly defined yield point or characterized by a guaranteed proof strength (0.2% proof strength, generally, or 1% proof strength for austenitic steels) the primary membrane stress  (sigma) in the shell shall not exceed 0.75 Re or 0.50 Rm, whichever is lower, at the test pressure, where: Re = yield strength in N/mm2, or 0.2% proof strength or, for austenitic steels, 1% proof strength; Rm = minimum tensile strength in N/mm2. 6.7.4.3.3.1 The values of Re and Rm to be used shall be the specified minimum values according to national or international material standards. When austenitic steels are used, the specified minimum values for Re and Rm according to the material standards may be increased by up to 15% when greater values are attested in the material inspection certificate. When no material standard exists for the metal in question, the values of Re and Rm used shall be approved by the competent authority or its authorized body. 6.7.4.3.3.2 Steels which have a Re/Rm ratio of more than 0.85 are not allowed for the construction of welded shells. The values of Re and Rm to be used in determining this ratio shall be the values specified in the material inspection certificate. 6.7.4.3.3.3 Steels used in the construction of shells shall have an elongation at fracture, in %, of not less than 10 000/Rm with an absolute minimum of 16% for fine grain steels and 20% for other steels. Aluminium and aluminium alloys used in the construction of shells shall have an elongation at fracture, in %, of not less than 10 000/6Rm with an absolute minimum of 12%. 6.7.4.3.3.4 For the purpose of determining actual values for materials, it shall be noted that for sheet metal, the axis of the tensile test specimen shall be at right angles (transversely) to the direction of rolling. The permanent elongation at fracture shall be measured on test specimens of rectangular cross sections in accordance with ISO 6892:1988 using a 50 mm gauge length. 6.7.4.4 Minimum shell thickness 6.7.4.4.1 The minimum shell thickness shall be the greater thickness based on: (a) The minimum thickness determined in accordance with the requirements in 6.7.4.4.2 to 6.7.4.4.7; or (b) The minimum thickness determined in accordance with the recognized pressure vessel code including the requirements in 6.7.4.3. - 437 - 6.7.4.4.2 Shells of not more than 1.80 m in diameter shall be not less than 5 mm thick in the reference steel or of equivalent thickness in the metal to be used. Shells of more than 1.80 m in diameter shall be not less than 6 mm thick in the reference steel or of equivalent thickness in the metal to be used. 6.7.4.4.3 Shells of vacuum-insulated tanks of not more than 1.80 m in diameter shall be not less than 3 mm thick in the reference steel or of equivalent thickness in the metal to be used. Such shells of more than 1.80 m in diameter shall be not less than 4 mm thick in the reference steel or of equivalent thickness in the metal to be used. 6.7.4.4.4 For vacuum-insulated tanks, the aggregate thickness of the jacket and the shell shall correspond to the minimum thickness prescribed in 6.7.4.4.2, the thickness of the shell itself being not less than the minimum thickness prescribed in 6.7.4.4.3. 6.7.4.4.5 Shells shall be not less than 3 mm thick regardless of the material of construction. 6.7.4.4.6 The equivalent thickness of a metal other than the thickness prescribed for the reference steel in 6.7.4.4.2 and 6.7.4.4.3 shall be determined using the following formula: e1  21.4e o 3 Rm 1  A1 where: e1 = required equivalent thickness (in mm) of the metal to be used; e0 = minimum thickness (in mm) of the reference steel specified in 6.7.4.4.2 and 6.7.4.4.3; Rm1 = guaranteed minimum tensile strength (in N/mm2) of the metal to be used (see 6.7.4.3.3); A1 = guaranteed minimum elongation at fracture (in %) of the metal to be used according to national or international standards. 6.7.4.4.7 In no case shall the wall thickness be less than that prescribed in 6.7.4.4.1 to 6.7.4.4.5. All parts of the shell shall have a minimum thickness as determined by 6.7.4.4.1 to 6.7.4.4.6. This thickness shall be exclusive of any corrosion allowance. 6.7.4.4.8 There shall be no sudden change of plate thickness at the attachment of the ends (heads) to the cylindrical portion of the shell. 6.7.4.5 Service equipment 6.7.4.5.1 Service equipment shall be so arranged as to be protected against the risk of being wrenched off or damaged during handling and carriage. When the connection between the frame and the tank or the jacket and the shell allows relative movement, the equipment shall be so fastened as to permit such movement without risk of damage to working parts. The external discharge fittings (pipe sockets, shut-off devices), the stop-valve and its seating shall be protected against the danger of being wrenched off by external forces (for example using shear sections). The filling and discharge devices (including flanges or threaded plugs) and any protective caps shall be capable of being secured against unintended opening. 6.7.4.5.2 Each filling and discharge opening in portable tanks used for the carriage of flammable refrigerated liquefied gases shall be fitted with at least three mutually independent shut-off devices in series, the first being a stop-valve situated as close as reasonably practicable to the jacket, the second being a stop-valve and the third being a blank flange or equivalent device. The shut-off device closest to the jacket shall be a quick closing device, which closes automatically in the event of unintended movement of the portable tank during filling or discharge or fire engulfment. This device shall also be possible to operate by remote control. 6.7.4.5.3 Each filling and discharge opening in portable tanks used for the carriage of non-flammable refrigerated liquefied gases shall be fitted with at least two mutually independent shut-off devices in series, the first being a stop-valve situated as close as reasonably practicable to the jacket, the second a blank flange or equivalent device. - 438 - 6.7.4.5.4 For sections of piping which can be closed at both ends and where liquid product can be trapped, a method of automatic pressure relief shall be provided to prevent excess pressure build-up within the piping. 6.7.4.5.5 Vacuum insulated tanks need not have an opening for inspection. 6.7.4.5.6 External fittings shall be grouped together so far as reasonably practicable. 6.7.4.5.7 Each connection on a portable tank shall be clearly marked to indicate its function. 6.7.4.5.8 Each stop-valve or other means of closure shall be designed and constructed to a rated pressure not less than the MAWP of the shell taking into account the temperature expected during carriage. All stop-valves with a screwed spindle shall be closed by a clockwise motion of the handwheel. In the case of other stop-valves the position (open and closed) and direction of closure shall be clearly indicated. All stop-valves shall be designed to prevent unintentional opening. 6.7.4.5.9 When pressure-building units are used, the liquid and vapour connections to that unit shall be provided with a valve as close to the jacket as reasonably practicable to prevent the loss of contents in case of damage to the pressure-building unit. 6.7.4.5.10 Piping shall be designed, constructed and installed so as to avoid the risk of damage due to thermal expansion and contraction, mechanical shock and vibration. All piping shall be of a suitable material. To prevent leakage due to fire, only steel piping and welded joints shall be used between the jacket and the connection to the first closure of any outlet. The method of attaching the closure to this connection shall be to the satisfaction of the competent authority or its authorized body. Elsewhere pipe joints shall be welded when necessary. 6.7.4.5.11 Joints in copper tubing shall be brazed or have an equally strong metal union. The melting point of brazing materials shall be no lower than 525 °C. The joints shall not decrease the strength of the tubing as may happen when cutting threads. 6.7.4.5.12 The materials of construction of valves and accessories shall have satisfactory properties at the lowest operating temperature of the portable tank. 6.7.4.5.13 The burst pressure of all piping and pipe fittings shall be not less than the highest of four times the MAWP of the shell or four times the pressure to which it may be subjected in service by the action of a pump or other device (except pressure-relief devices). 6.7.4.6 Pressure-relief devices 6.7.4.6.1 Every shell shall be provided with not less than two independent spring-loaded pressure-relief devices. The pressure-relief devices shall open automatically at a pressure not less than the MAWP and be fully open at a pressure equal to 110% of the MAWP. These devices shall, after discharge, close at a pressure not lower than 10% below the pressure at which discharge starts and shall remain closed at all lower pressures. The pressure-relief devices shall be of the type that will resist dynamic forces including surge. 6.7.4.6.2 Shells for non-flammable refrigerated liquefied gases and hydrogen may in addition have frangible discs in parallel with the spring-loaded devices as specified in 6.7.4.7.2 and 6.7.4.7.3. 6.7.4.6.3 Pressure-relief devices shall be designed to prevent the entry of foreign matter, the leakage of gas and the development of any dangerous excess pressure. 6.7.4.6.4 Pressure-relief devices shall be approved by the competent authority or its authorized body. 6.7.4.7 Capacity and setting of pressure-relief devices 6.7.4.7.1 In the case of the loss of vacuum in a vacuum-insulated tank or of loss of 20% of the insulation of a tank insulated with solid materials, the combined capacity of all pressure-relief devices installed shall be sufficient so that the pressure (including accumulation) inside the shell does not exceed 120% of the MAWP. - 439 - 6.7.4.7.2 For non-flammable refrigerated liquefied gases (except oxygen) and hydrogen, this capacity may be achieved by the use of frangible discs in parallel with the required safety-relief devices. Frangible discs shall rupture at nominal pressure equal to the test pressure of the shell. 6.7.4.7.3 Under the circumstances described in 6.7.4.7.1 and 6.7.4.7.2 together with complete fire engulfment the combined capacity of all pressure-relief devices installed shall be sufficient to limit the pressure in the shell to the test pressure. 6.7.4.7.4 The required capacity of the relief devices shall be calculated in accordance with a well-established technical code recognized by the competent authority7. 6.7.4.8 Marking of pressure-relief devices 6.7.4.8.1 Every pressure-relief device shall be plainly and permanently marked with the following particulars: (a) The pressure (in bar or kPa) at which it is set to discharge; (b) The allowable tolerance at the discharge pressure for spring-loaded devices; (c) The reference temperature corresponding to the rated pressure for frangible discs; (d) The rated flow capacity of the device in standard cubic meters of air per second (m3/s); and (e) The cross sectional flow areas of the spring loaded pressure-relief devices and frangible discs in mm². When practicable, the following information shall also be shown: (f) The manufacturer’s name and relevant catalogue number of the device. 6.7.4.8.2 The rated flow capacity marked on the pressure-relief devices shall be determined according to ISO 4126-1:2004 and ISO 4126-7:2004. 6.7.4.9 Connections to pressure-relief devices 6.7.4.9.1 Connections to pressure-relief devices shall be of sufficient size to enable the required discharge to pass unrestricted to the safety device. No stop-valve shall be installed between the shell and the pressure-relief devices except when duplicate devices are provided for maintenance or other reasons and the stop-valves serving the devices actually in use are locked open or the stop-valves are interlocked so that the requirements of 6.7.4.7 are always fulfilled. There shall be no obstruction in an opening leading to a vent or pressure-relief device which might restrict or cut-off the flow from the shell to that device. Pipework to vent the vapour or liquid from the outlet of the pressure-relief devices, when used, shall deliver the relieved vapour or liquid to the atmosphere in conditions of minimum back-pressure on the relieving device. 6.7.4.10 Siting of pressure-relief devices 6.7.4.10.1 Each pressure-relief device inlet shall be situated on top of the shell in a position as near the longitudinal and transverse centre of the shell as reasonably practicable. All pressure-relief device inlets shall under maximum filling conditions be situated in the vapour space of the shell and the devices shall be so arranged as to ensure that the escaping vapour is discharged unrestrictedly. For refrigerated liquefied gases, the escaping vapour shall be directed away from the tank and in such a manner that it cannot impinge upon the tank. Protective devices which deflect the flow of vapour are permissible provided the required relief-device capacity is not reduced. 6.7.4.10.2 Arrangements shall be made to prevent access to the devices by unauthorized persons and to protect the devices from damage caused by the portable tank overturning. 7 See for example CGA S-1.2-2003 "Pressure Relief Device Standards - Part 2 - Cargo and Portable Tanks for Compressed Gases". - 440 - 6.7.4.11 Gauging devices 6.7.4.11.1 Unless a portable tank is intended to be filled by weight, it shall be equipped with one or more gauging devices. Glass level-gauges and gauges made of other fragile material, which are in direct communication with the contents of the shell shall not be used. 6.7.4.11.2 A connection for a vacuum gauge shall be provided in the jacket of a vacuum-insulated portable tank. 6.7.4.12 Portable tank supports, frameworks, lifting and tie-down attachments 6.7.4.12.1 Portable tanks shall be designed and constructed with a support structure to provide a secure base during carriage. The forces specified in 6.7.4.2.12 and the safety factor specified in 6.7.4.2.13 shall be considered in this aspect of the design. Skids, frameworks, cradles or other similar structures are acceptable. 6.7.4.12.2 The combined stresses caused by portable tank mountings (e.g. cradles, frameworks, etc.) and portable tank lifting and tie-down attachments shall not cause excessive stress in any portion of the tank. Permanent lifting and tie-down attachments shall be fitted to all portable tanks. Preferably they shall be fitted to the portable tank supports but may be secured to reinforcing plates located on the tank at the points of support. 6.7.4.12.3 In the design of supports and frameworks the effects of environmental corrosion shall be taken into account. 6.7.4.12.4 Forklift pockets shall be capable of being closed off. The means of closing forklift pockets shall be a permanent part of the framework or permanently attached to the framework. Single compartment portable tanks with a length less than 3.65 m need not have closed off forklift pockets provided that: 6.7.4.12.5 (a) The tank and all the fittings are well protected from being hit by the forklift blades; and (b) The distance between the centres of the forklift pockets is at least half of the maximum length of the portable tank. When portable tanks are not protected during carriage, according to 4.2.3.3, the shells and service equipment shall be protected against damage to the shell and service equipment resulting from lateral or longitudinal impact or overturning. External fittings shall be protected so as to preclude the release of the shell contents upon impact or overturning of the portable tank on its fittings. Examples of protection include: (a) Protection against lateral impact which may consist of longitudinal bars protecting the shell on both sides at the level of the median line; (b) Protection of the portable tank against overturning which may consist of reinforcement rings or bars fixed across the frame; (c) Protection against rear impact which may consist of a bumper or frame; (d) Protection of the shell against damage from impact or overturning by use of an ISO frame in accordance with ISO 1496-3:1995; (e) Protection of the portable tank from impact or overturning by a vacuum insulation jacket. 6.7.4.13 Design approval 6.7.4.13.1 The competent authority or its authorized body shall issue a design approval certificate for any new design of a portable tank. This certificate shall attest that a portable tank has been surveyed by that authority, is suitable for its intended purpose and meets the requirements of this Chapter. When a series of portable tanks are manufactured without change in the design, the certificate shall be valid for the entire series. The certificate shall refer to the prototype test report, the refrigerated liquefied gases allowed to be carried, the materials of construction of the shell and jacket and an approval number. The approval number shall consist of the distinguishing sign or mark of the State in whose territory the approval was granted, i.e. the distinguishing sign for use in international traffic, as prescribed by the Convention on Road Traffic, Vienna 1968, and a registration number. Any - 441 - alternative arrangements according to 6.7.1.2 shall be indicated on the certificate. A design approval may serve for the approval of smaller portable tanks made of materials of the same kind and thickness, by the same fabrication techniques and with identical supports, equivalent closures and other appurtenances. 6.7.4.13.2 The prototype test report for the design approval shall include at least the following: (a) The results of the applicable frame-work test specified in ISO 1496-3:1995; (b) The results of the initial inspection and test in 6.7.4.14.3; and (c) The results of the impact test in 6.7.4.14.1, when applicable. 6.7.4.14 Inspection and testing 6.7.4.14.1 Portable tanks meeting the definition of container in the International Convention for Safe Containers (CSC), 1972, as amended, shall not be used unless they are successfully qualified by subjecting a representative prototype of each design to the Dynamic, Longitudinal Impact Test prescribed in the Manual of Tests and Criteria, Part IV, Section 41. 6.7.4.14.2 The tank and items of equipment of each portable tank shall be inspected and tested before being put into service for the first time (initial inspection and test) and thereafter at not more than five-year intervals (5 year periodic inspection and test) with an intermediate periodic inspection and test (2.5 year periodic inspection and test) midway between the 5 year periodic inspections and tests. The 2.5 year inspection and test may be performed within 3 months of the specified date. An exceptional inspection and test shall be performed regardless of the last periodic inspection and test when necessary according to 6.7.4.14.7. 6.7.4.14.3 The initial inspection and test of a portable tank shall include a check of the design characteristics, an internal and external examination of the portable tank shell and its fittings with due regard to the refrigerated liquefied gases to be carried, and a pressure test referring to the test pressures according to 6.7.4.3.2. The pressure test may be performed as a hydraulic test or by using another liquid or gas with the agreement of the competent authority or its authorized body. Before the portable tank is placed into service, a leakproofness test and a check of the satisfactory operation of all service equipment shall also be performed. When the shell and its fittings have been pressure-tested separately, they shall be subjected together after assembly to a leakproofness test. All welds subject to full stress level shall be inspected during the initial test by radiographic, ultrasonic, or another suitable non-destructive test method. This does not apply to the jacket. 6.7.4.14.4 The 5 and 2.5 year periodic inspections and tests shall include an external examination of the portable tank and its fittings with due regard to the refrigerated liquefied gases carried, a leakproofness test, a check of the satisfactory operation of all service equipment and a vacuum reading, when applicable. In the case of non-vacuum insulated tanks, the jacket and insulation shall be removed during the 2.5 year and the 5 year periodic inspections and tests but only to the extent necessary for a reliable appraisal. 6.7.4.14.5 (Deleted) 6.7.4.14.6 A portable tank may not be filled and offered for carriage after the date of expiry of the last 5 year or 2.5 year periodic inspection and test as required by 6.7.4.14.2. However a portable tank filled prior to the date of expiry of the last periodic inspection and test may be carried for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection. In addition, a portable tank may be carried after the date of expiry of the last periodic test and inspection: (a) After emptying but before cleaning, for purposes of performing the next required test or inspection prior to refilling; and (b) Unless otherwise approved by the competent authority, for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection, in order to allow the return of dangerous goods for proper disposal or recycling. Reference to this exemption shall be mentioned in the transport document. - 442 - 6.7.4.14.7 The exceptional inspection and test is necessary when the portable tank shows evidence of damaged or corroded areas, leakage, or any other conditions that indicate a deficiency that could affect the integrity of the portable tank. The extent of the exceptional inspection and test shall depend on the amount of damage or deterioration of the portable tank. It shall include at least the 2.5 year inspection and test according to 6.7.4.14.4. 6.7.4.14.8 The internal examination during the initial inspection and test shall ensure that the shell is inspected for pitting, corrosion, or abrasions, dents, distortions, defects in welds or any other conditions, that might render the portable tank unsafe for carriage. 6.7.4.14.9 The external examination shall ensure that: (a) The external piping, valves, pressurizing/cooling systems when applicable and gaskets are inspected for corroded areas, defects, or any other conditions, including leakage, that might render the portable tank unsafe for filling, discharge or carriage; (b) There is no leakage at any manhole covers or gaskets; (c) Missing or loose bolts or nuts on any flanged connection or blank flange are replaced or tightened; (d) All emergency devices and valves are free from corrosion, distortion and any damage or defect that could prevent their normal operation. Remote closure devices and self-closing stop-valves shall be operated to demonstrate proper operation; (e) Required markings on the portable tank are legible and in accordance with the applicable requirements; and (f) The framework, the supports and the arrangements for lifting the portable tank are in satisfactory condition. 6.7.4.14.10 The inspections and tests in 6.7.4.14.1, 6.7.4.14.3, 6.7.4.14.4, 6.7.4.14.5 and 6.7.4.14.7 shall be performed or witnessed by an expert approved by the competent authority or its authorized body. When the pressure test is a part of the inspection and test, the test pressure shall be the one indicated on the data plate of the portable tank. While under pressure, the portable tank shall be inspected for any leaks in the shell, piping or equipment. 6.7.4.14.11 In all cases when cutting, burning or welding operations on the shell of a portable tank have been effected, that work shall be to the approval of the competent authority or its authorized body taking into account the pressure vessel code used for the construction of the shell. A pressure test to the original test pressure shall be performed after the work is completed. 6.7.4.14.12 When evidence of any unsafe condition is discovered, the portable tank shall not be returned to service until it has been corrected and the test is repeated and passed. 6.7.4.15 Marking 6.7.4.15.1 Every portable tank shall be fitted with a corrosion resistant metal plate permanently attached to the portable tank in a conspicuous place readily accessible for inspection. When for reasons of portable tank arrangements the plate cannot be permanently attached to the shell, the shell shall be marked with at least the information required by the pressure vessel code. As a minimum, at least the following information shall be marked on the plate by stamping or by any other similar method: (a) Owner information (i) (b) Owner’s registration number; Manufacturing information (i) Country of manufacture; (ii) Year of manufacture; (iii) Manufacturer’s name or mark; (iv) Manufacturer’s serial number; - 443 - (c) Approval information (i) The United Nations packaging symbol ; This symbol shall not be used for any purpose other than certifying that a packaging, a portable tank or a MEGC complies with the relevant requirements in Chapter 6.1, 6.2, 6.3, 6.5, 6.6 or 6.7 2; (ii) Approval country; (iii) Authorized body for the design approval; (iv) Design approval number; (v) Letters ‘AA’, if the design was approved under alternative arrangements (see 6.7.1.2); (vi) Pressure vessel code to which the shell is designed; (d) Pressures (i) MAWP (in bar gauge or kPa gauge)3; (ii) Test pressure (in bar gauge or kPa gauge)3; (iii) Initial pressure test date (month and year); (iv) Identification mark of the initial pressure test witness; (e) Temperatures (i) (f) Minimum design temperature (in °C)3; Materials (i) Shell material(s) and material standard reference(s); (ii) Equivalent thickness in reference steel (in mm)3; (g) Capacity (i) (h) Tank water capacity at 20 °C (in litres)3; Insulation (i) Either "Thermally insulated" or "Vacuum insulated" (as applicable); (ii) Effectiveness of the insulation system (heat influx) (in Watts)3; (i) Holding times – for each refrigerated liquefied gas permitted to be carried in the portable tank (i) Name, in full, of the refrigerated liquefied gas; (ii) Reference holding time (in days or hours)3; (iii) Initial pressure (in bar gauge or kPa gauge)3; (iv) Degree of filling (in kg)3; (j) Periodic inspections and tests (i) Type of the most recent periodic test (2.5-year, 5-year or exceptional); (ii) Date of the most recent periodic test (month and year); (iii) Identification mark of the authorized body who performed or witnessed the most recent test. 2 This symbol is also used to certify that flexible bulk containers authorized for other modes of transport comply with the requirements in Chapter 6.8 of the UN Model Regulations. 3 The unit used shall be indicated. - 444 - Figure 6.7.4.15.1: Example of identification plate marking Owner’s registration number MANUFACTURING INFORMATION Country of manufacture Year of manufacture Manufacturer Manufacturer’s serial number APPROVAL INFORMATION Approval country Authorized body for design approval Design approval number Shell design code (pressure vessel code) PRESSURES MAWP Test pressure Initial pressure test date: (mm/yyyy) Witness stamp: TEMPERATURES Minimum design temperature MATERIALS Shell material(s) and material standard reference(s) Equivalent thickness in reference steel CAPACITY Tank water capacity at 20 °C INSULATION ‘Thermally insulated’ or ‘Vacuum insulated’ (as applicable) Heat influx HOLDING TIMES Refrigerated liquefied gas(es) Reference holding time permitted days or hours PERIODIC INSPECTIONS / TESTS Test type Test date Witness stamp (mm/yyyy) 6.7.4.15.2 Test type ‘AA’ (if applicable) bar or kPa bar or kPa °C mm litres Watts Degree of filling Initial pressure bar or kPa Test date (mm/yyyy) kg Witness stamp The following particulars shall be durably marked either on the portable tank itself or on a metal plate firmly secured to the portable tank. Name of the owner and the operator Name of the refrigerated liquefied gas being carried (and minimum mean bulk temperature) Maximum permissible gross mass (MPGM)________kg Unladen (tare) mass________kg Actual holding time for gas being carried ______days (or hours) Portable tank instruction in accordance with 4.2.5.2.6 NOTE: For the identification of the refrigerated liquefied gas(es) being carried, see also Part 5. 6.7.4.15.3 If a portable tank is designed and approved for handling in open seas, the words "OFFSHORE PORTABLE TANK" shall be marked on the identification plate. - 445 - 6.7.5 Requirements for the design, construction, inspection and testing of UN multiple-element gas containers (MEGCs) intended for the carriage of non-refrigerated gases 6.7.5.1 Definitions For the purposes of this section: Alternative arrangement means an approval granted by the competent authority for a portable tank or MEGC that has been designed, constructed or tested to technical requirements or testing methods other than those specified in this Chapter; Elements are cylinders, tubes or bundles of cylinders; Leakproofness test means a test using gas subjecting the elements and the service equipment of the MEGC to an effective internal pressure of not less than 20% of the test pressure; Manifold means an assembly of piping and valves connecting the filling and/or discharge openings of the elements; Maximum permissible gross mass (MPGM) means the sum of the tare mass of the MEGC and the heaviest load authorized for carriage; UN Multiple-element gas containers (MEGCs) are multimodal assemblies of cylinders, tubes and bundles of cylinders which are interconnected by a manifold and which are assembled within a framework. The MEGC includes service equipment and structural equipment necessary for the carriage of gases; Service equipment means measuring instruments and filling, discharge, venting and safety devices; Structural equipment means the reinforcing, fastening, protective and stabilizing members external to the elements. 6.7.5.2 General design and construction requirements 6.7.5.2.1 The MEGC shall be capable of being filled and discharged without the removal of its structural equipment. It shall possess stabilizing members external to the elements to provide structural integrity for handling and carriage. MEGCs shall be designed and constructed with supports to provide a secure base during carriage and with lifting and tie-down attachments which are adequate for lifting the MEGC including when filled to its maximum permissible gross mass. The MEGC shall be designed to be loaded onto a vehicle, wagon or sea-going or inland navigation vessel and shall be equipped with skids, mountings or accessories to facilitate mechanical handling. 6.7.5.2.2 MEGCs shall be designed, manufactured and equipped in such a way as to withstand all conditions to which they will be subjected during normal conditions of handling and carriage. The design shall take into account the effects of dynamic loading and fatigue. 6.7.5.2.3 Elements of an MEGC shall be made of seamless steel and be constructed and tested according to 6.2.1 and 6.2.2. All of the elements in an MEGC shall be of the same design type. 6.7.5.2.4 Elements of MEGCs, fittings and pipework shall be: (a) Compatible with the substances intended to be carried (see ISO 11114-1:2012 and ISO 111142:2000); or (b) Properly passivated or neutralized by chemical reaction. 6.7.5.2.5 Contact between dissimilar metals which could result in damage by galvanic action shall be avoided. 6.7.5.2.6 The materials of the MEGC, including any devices, gaskets, and accessories, shall not adversely affect the gas(es) intended for carriage in the MEGC. - 446 - 6.7.5.2.7 MEGCs shall be designed to withstand, without loss of contents, at least the internal pressure due to the contents, and the static, dynamic and thermal loads during normal conditions of handling and carriage. The design shall demonstrate that the effects of fatigue, caused by repeated application of these loads through the expected life of the multiple-element gas container, have been taken into account. 6.7.5.2.8 MEGCs and their fastenings shall, under the maximum permissible load, be capable of withstanding the following separately applied static forces: (a) In the direction of travel: twice the MPGM multiplied by the acceleration due to gravity (g) 1; (b) Horizontally at right angles to the direction of travel: the MPGM (when the direction of travel is not clearly determined, the forces shall be equal to twice the MPGM) multiplied by the acceleration due to gravity (g)1; (c) Vertically upwards: the MPGM multiplied by the acceleration due to gravity (g) 1; and (d) Vertically downwards: twice the MPGM (total loading including the effect of gravity) multiplied by the acceleration due to gravity (g)1. 6.7.5.2.9 Under the forces defined in 6.7.5.2.8, the stress at the most severely stressed point of the elements shall not exceed the values given in either the relevant standards of 6.2.2.1 or, if the elements are not designed, constructed and tested according to those standards, in the technical code or standard recognised or approved by the competent authority of the country of use (see 6.2.5). 6.7.5.2.10 Under each of the forces in 6.7.5.2.8, the safety factor for the framework and fastenings to be observed shall be as follows: (a) for steels having a clearly defined yield point, a safety factor of 1.5 in relation to the guaranteed yield strength; or (b) for steels with no clearly defined yield point, a safety factor of 1.5 in relation to the guaranteed 0.2% proof strength and, for austenitic steels, the 1% proof strength. 6.7.5.2.11 MEGCs intended for the carriage of flammable gases shall be capable of being electrically earthed. 6.7.5.2.12 The elements shall be secured in a manner that prevents undesired movement in relation to the structure and the concentration of harmful localized stresses. 6.7.5.3 Service equipment 6.7.5.3.1 Service equipment shall be configured or designed to prevent damage that could result in the release of the pressure receptacle contents during normal conditions of handling and carriage. When the connection between the frame and the elements allows relative movement between the subassemblies, the equipment shall be so fastened as to permit such movement without damage to working parts. The manifolds, the discharge fittings (pipe sockets, shut-off devices), and the stopvalves shall be protected from being wrenched off by external forces. Manifold piping leading to shutoff valves shall be sufficiently flexible to protect the valves and the piping from shearing, or releasing the pressure receptacle contents. The filling and discharge devices (including flanges or threaded plugs) and any protective caps shall be capable of being secured against unintended opening. 6.7.5.3.2 Each element intended for the carriage of toxic gases (gases of groups T, TF, TC, TO, TFC and TOC) shall be fitted with a valve. The manifold for liquefied toxic gases (gases of classification codes 2T, 2TF, 2TC, 2TO, 2TFC and 2TOC) shall be so designed that the elements can be filled separately and be kept isolated by a valve capable of being sealed. For the carriage of flammable gases (gases of group F), the elements shall be divided into groups of not more than 3 000 litres each isolated by a valve. 6.7.5.3.3 For filling and discharge openings of the MEGC, two valves in series shall be placed in an accessible position on each discharge and filling pipe. One of the valves may be a non-return valve. The filling 1 For calculation purposes g = 9.81 m/s2. - 447 - and discharge devices may be fitted to a manifold. For sections of piping which can be closed at both ends and where a liquid product can be trapped, a pressure-relief valve shall be provided to prevent excessive pressure build-up. The main isolation valves on an MEGC shall be clearly marked to indicate their directions of closure. Each stop-valve or other means of closure shall be designed and constructed to withstand a pressure equal to or greater than 1.5 times the test pressure of the MEGC. All stop-valves with screwed spindles shall close by a clockwise motion of the handwheel. For other stop-valves, the position (open and closed) and direction of closure shall be clearly indicated. All stopvalves shall be designed and positioned to prevent unintentional opening. Ductile metals shall be used in the construction of valves or accessories. 6.7.5.3.4 Piping shall be designed, constructed and installed so as to avoid damage due to expansion and contraction, mechanical shock and vibration. Joints in tubing shall be brazed or have an equally strong metal union. The melting point of brazing materials shall be no lower than 525 °C. The rated pressure of the service equipment and of the manifold shall be not less than two thirds of the test pressure of the elements. 6.7.5.4 Pressure-relief devices 6.7.5.4.1 The elements of MEGCs used for the carriage of UN No. 1013 carbon dioxide and UN No. 1070 nitrous oxide shall be divided into groups of not more than 3 000 litres each isolated by a valve. Each group shall be fitted with one or more pressure relief devices. If so required by the competent authority of the country of use, MEGCs for other gases shall be fitted with pressure relief devices as specified by that competent authority. 6.7.5.4.2 When pressure relief devices are fitted, every element or group of elements of an MEGC that can be isolated shall then be fitted with one or more pressure relief devices. Pressure relief devices shall be of a type that will resist dynamic forces including liquid surge and shall be designed to prevent the entry of foreign matter, the leakage of gas and the development of any dangerous excess pressure. 6.7.5.4.3 MEGCs used for the carriage of certain non-refrigerated gases identified in portable tank instruction T50 in 4.2.5.2.6 may have a pressure-relief device as required by the competent authority of the country of use. Unless an MEGC in dedicated service is fitted with an approved pressure relief device constructed of materials compatible with the gas carried, such a device shall comprise a frangible disc preceding a spring-loaded device. The space between the frangible disc and the spring-loaded device may be equipped with a pressure gauge or a suitable telltale indicator. This arrangement permits the detection of disc rupture, pinholing or leakage which could cause a malfunction of the pressure relief device. The frangible disc shall rupture at a nominal pressure 10% above the start-to-discharge pressure of the spring-loaded device. 6.7.5.4.4 In the case of multi-purpose MEGCs used for the carriage of low-pressure liquefied gases, the pressure-relief devices shall open at a pressure as specified in 6.7.3.7.1 for the gas having the highest maximum allowable working pressure of the gases allowed to be carried in the MEGC. 6.7.5.5 Capacity of pressure relief devices 6.7.5.5.1 The combined delivery capacity of the pressure relief devices when fitted shall be sufficient that, in the event of total fire engulfment of the MEGC, the pressure (including accumulation) inside the elements does not exceed 120% of the set pressure of the pressure relief device. The formula provided in CGA S-1.2-2003 "Pressure Relief Device Standards - Part 2 - Cargo and Portable Tanks for Compressed Gases" shall be used to determine the minimum total flow capacity for the system of pressure relief devices. CGA S-1.1-2003 "Pressure Relief Device Standards - Part 1 - Cylinders for Compressed Gases" may be used to determine the relief capacity of individual elements. Springloaded pressure relief devices may be used to achieve the full relief capacity prescribed in the case of low pressure liquefied gases. In the case of multi-purpose MEGCs, the combined delivery capacity of the pressure-relief devices shall be taken for the gas which requires the highest delivery capacity of the gases allowed to be carried in the MEGC. 6.7.5.5.2 To determine the total required capacity of the pressure relief devices installed on the elements for the carriage of liquefied gases, the thermodynamic properties of the gas shall be considered (see, for example, CGA S-1.2-2003 "Pressure Relief Device Standards - Part 2 - Cargo and Portable Tanks for Compressed Gases" for low pressure liquefied gases and CGA S-1.1-2003 "Pressure Relief Device Standards - Part 1 - Cylinders for Compressed Gases" for high pressure liquefied gases). - 448 - 6.7.5.6 Marking of pressure-relief devices 6.7.5.6.1 Pressure relief devices shall be clearly and permanently marked with the following: (a) The manufacturer's name and relevant catalogue number; (b) The set pressure and/or the set temperature; (c) The date of the last test. (d) The cross sectional flow areas of the spring loaded pressure-relief devices and frangible discs in mm². 6.7.5.6.2 The rated flow capacity marked on spring loaded pressure relief devices for low pressure liquefied gases shall be determined according to ISO 4126-1:2004 and ISO 4126-7:2004. 6.7.5.7 Connections to pressure-relief devices 6.7.5.7.1 Connections to pressure-relief devices shall be of sufficient size to enable the required discharge to pass unrestricted to the pressure relief device. No stop-valve shall be installed between the element and the pressure-relief devices, except when duplicate devices are provided for maintenance or other reasons, and the stop-valves serving the devices actually in use are locked open, or the stop-valves are interlocked so that at least one of the duplicate devices is always operable and capable of meeting the requirements of 6.7.5.5. There shall be no obstruction in an opening leading to or leaving from a vent or pressure-relief device which might restrict or cut-off the flow from the element to that device. The opening through all piping and fittings shall have at least the same flow area as the inlet of the pressure relief device to which it is connected. The nominal size of the discharge piping shall be at least as large as that of the pressure relief device outlet. Vents from the pressure-relief devices, when used, shall deliver the relieved vapour or liquid to the atmosphere in conditions of minimum backpressure on the relieving device. 6.7.5.8 Siting of pressure-relief devices 6.7.5.8.1 Each pressure relief device shall, under maximum filling conditions, be in communication with the vapour space of the elements for the carriage of liquefied gases. The devices, when fitted, shall be so arranged as to ensure that the escaping vapour is discharged upwards and unrestrictedly as to prevent any impingement of escaping gas or liquid upon the MEGC, its elements or personnel. For flammable, pyrophoric and oxidizing gases, the escaping gas shall be directed away from the element in such a manner that it cannot impinge upon the other elements. Heat resistant protective devices which deflect the flow of gas are permissible provided the required pressure relief device capacity is not reduced. 6.7.5.8.2 Arrangements shall be made to prevent access to the pressure-relief devices by unauthorized persons and to protect the devices from damage caused by the MEGC overturning. 6.7.5.9 Gauging devices 6.7.5.9.1 When an MEGC is intended to be filled by mass, it shall be equipped with one or more gauging devices. Level-gauges made of glass or other fragile material shall not be used. 6.7.5.10 MEGC supports, frameworks, lifting and tie-down attachments 6.7.5.10.1 MEGCs shall be designed and constructed with a support structure to provide a secure base during carriage. The forces specified in 6.7.5.2.8 and the safety factor specified in 6.7.5.2.10 shall be considered in this aspect of the design. Skids, frameworks, cradles or other similar structures are acceptable. 6.7.5.10.2 The combined stresses caused by element mountings (e.g. cradles, frameworks, etc.) and MEGC lifting and tie-down attachments shall not cause excessive stress in any element. Permanent lifting and tie-down attachments shall be fitted to all MEGCs. In no case shall mountings or attachments be welded onto the elements. 6.7.5.10.3 In the design of supports and frameworks, the effects of environmental corrosion shall be taken into account. - 449 - 6.7.5.10.4 When MEGCs are not protected during carriage, according to 4.2.4.3, the elements and service equipment shall be protected against damage resulting from lateral or longitudinal impact or overturning. External fittings shall be protected so as to preclude the release of the elements' contents upon impact or overturning of the MEGC on its fittings. Particular attention shall be paid to the protection of the manifold. Examples of protection include: (a) Protection against lateral impact which may consist of longitudinal bars; (b) Protection against overturning which may consist of reinforcement rings or bars fixed across the frame; (c) Protection against rear impact which may consist of a bumper or frame; (d) Protection of the elements and service equipment against damage from impact or overturning by use of an ISO frame in accordance with the relevant provisions of ISO 1496-3:1995. 6.7.5.11 Design approval 6.7.5.11.1 The competent authority or its authorized body shall issue a design approval certificate for any new design of an MEGC. This certificate shall attest that the MEGC has been surveyed by that authority, is suitable for its intended purpose and meets the requirements of this Chapter, the applicable provisions for gases of Chapter 4.1 and of packing instruction P200. When a series of MEGCs are manufactured without change in the design, the certificate shall be valid for the entire series. The certificate shall refer to the prototype test report, the materials of construction of the manifold, the standards to which the elements are made and an approval number. The approval number shall consist of the distinguishing sign or mark of the country granting the approval, i.e. the distinguishing sign for use in international traffic, as prescribed by the Convention on Road Traffic, Vienna 1968, and a registration number. Any alternative arrangements according to 6.7.1.2 shall be indicated on the certificate. A design approval may serve for the approval of smaller MEGCs made of materials of the same type and thickness, by the same fabrication techniques and with identical supports, equivalent closures and other appurtenances. 6.7.5.11.2 The prototype test report for the design approval shall include at least the following: (a) The results of the applicable framework test specified in ISO1496-3:1995; (b) The results of the initial inspection and test specified in 6.7.5.12.3; (c) The results of the impact test specified in 6.7.5.12.1; and (d) Certification documents verifying that the cylinders and tubes comply with the applicable standards. 6.7.5.12 Inspection and testing 6.7.5.12.1 MEGCs meeting the definition of container in the International Convention for Safe Containers (CSC), 1972, as amended, shall not be used unless they are successfully qualified by subjecting a representative prototype of each design to the Dynamic, Longitudinal Impact Test prescribed in the Manual of Tests and Criteria, Part IV, Section 41. 6.7.5.12.2 The elements and items of equipment of each MEGC shall be inspected and tested before being put into service for the first time (initial inspection and test). Thereafter, MEGCs shall be inspected at no more than five-year intervals (5 year periodic inspection). An exceptional inspection and test shall be performed, regardless of the last periodic inspection and test, when necessary according to 6.7.5.12.5. 6.7.5.12.3 The initial inspection and test of an MEGC shall include a check of the design characteristics, an external examination of the MEGC and its fittings with due regard to the gases to be carried, and a pressure test performed at the test pressures according to packing instruction P200 of 4.1.4.1. The pressure test of the manifold may be performed as a hydraulic test or by using another liquid or gas with the agreement of the competent authority or its authorized body. Before the MEGC is placed into service, a leakproofness test and a test of the satisfactory operation of all service equipment shall also be performed. When the elements and their fittings have been pressure-tested separately, they shall be subjected together after assembly to a leakproofness test. - 450 - 6.7.5.12.4 The 5-year periodic inspection and test shall include an external examination of the structure, the elements and the service equipment in accordance with 6.7.5.12.6. The elements and the piping shall be tested at the periodicity specified in packing instruction P200 and in accordance with the provisions described in 6.2.1.6. When the elements and equipment have been pressure-tested separately, they shall be subjected together after assembly to a leakproofness test. 6.7.5.12.5 An exceptional inspection and test is necessary when the MEGC shows evidence of damaged or corroded areas, leakage, or other conditions that indicate a deficiency that could affect the integrity of the MEGC. The extent of the exceptional inspection and test shall depend on the amount of damage or deterioration of the MEGC. It shall include at least the examinations required under 6.7.5.12.6. 6.7.5.12.6 The examinations shall ensure that: (a) The elements are inspected externally for pitting, corrosion, abrasions, dents, distortions, defects in welds or any other conditions, including leakage, that might render the MEGC unsafe for carriage; (b) The piping, valves, and gaskets are inspected for corroded areas, defects, and other conditions, including leakage, that might render the MEGC unsafe for filling, discharge or carriage; (c) Missing or loose bolts or nuts on any flanged connection or blank flange are replaced or tightened; (d) All emergency devices and valves are free from corrosion, distortion and any damage or defect that could prevent their normal operation. Remote closure devices and self-closing stop-valves shall be operated to demonstrate proper operation; (e) Required markings on the MEGC are legible and in accordance with the applicable requirements; and (f) The framework, the supports and the arrangements for lifting the MEGC are in satisfactory condition. 6.7.5.12.7 The inspections and tests in 6.7.5.12.1, 6.7.5.12.3, 6.7.5.12.4 and 6.7.5.12.5 shall be performed or witnessed by a body authorized by the competent authority. When the pressure test is a part of the inspection and test, the test pressure shall be the one indicated on the data plate of the MEGC. While under pressure, the MEGC shall be inspected for any leaks in the elements, piping or equipment. 6.7.5.12.8 When evidence of any unsafe condition is discovered, the MEGC shall not be returned to service until it has been corrected and the applicable tests and verifications are passed. 6.7.5.13 Marking 6.7.5.13.1 Every MEGC shall be fitted with a corrosion resistant metal plate permanently attached to the MEGC in a conspicuous place readily accessible for inspection. The metal plate shall not be affixed to the elements. The elements shall be marked in accordance with Chapter 6.2. As a minimum, at least the following information shall be marked on the plate by stamping or by any other similar method: (a) Owner information (i) (b) Owner’s registration number; Manufacturing information (i) Country of manufacture; (ii) Year of manufacture; (iii) Manufacturer’s name or mark; (iv) Manufacturer’s serial number; - 451 - (c) Approval information (i) The United Nations packaging symbol ; This symbol shall not be used for any purpose other than certifying that a packaging, a portable tank or a MEGC complies with the relevant requirements in Chapter 6.1, 6.2, 6.3, 6.5, 6.6 or 6.72; (d) (e) (ii) Approval country; (iii) Authorized body for the design approval; (iv) Design approval number; (v) Letters ‘AA’, if the design was approved under alternative arrangements (see 6.7.1.2); Pressures (i) Test pressure (in bar gauge)3; (ii) Initial pressure test date (month and year); (iii) Identification mark of the initial pressure test witness; Temperatures (i) (f) (g) Design temperature range (in °C)3; Elements / Capacity (i) Number of elements; (ii) Total water capacity (in litres)3; Periodic inspections and tests (i) Type of the most recent periodic test (5-year or exceptional); (ii) Date of the most recent periodic test (month and year); (iii) Identification mark of the authorized body who performed or witnessed the most recent test. 2 This symbol is also used to certify that flexible bulk containers authorized for other modes of transport comply with the requirements in Chapter 6.8 of the UN Model Regulations. 3 The unit used shall be indicated. - 452 - Figure 6.7.5.13.1: Example of identification plate marking Owner’s registration number MANUFACTURING INFORMATION Country of manufacture Year of manufacture Manufacturer Manufacturer’s serial number APPROVAL INFORMATION Approval country Authorized body for design approval Design approval number PRESSURES Test pressure Initial pressure test date: (mm/yyyy) TEMPERATURES Design temperature range ELEMENTS / CAPACITY Number of elements Total water capacity PERIODIC INSPECTIONS / TESTS Test type Test date Witness stamp (mm/yyyy) 6.7.5.13.2 ‘AA’ (if applicable) bar Witness stamp: °C to °C litres Test type Test date (mm/yyyy) Witness stamp The following information shall be durably marked on a metal plate firmly secured to the MEGC: Name of the operator Maximum permissible load mass ________ kg Working pressure at 15°C: ________ bar gauge Maximum permissible gross mass (MPGM) __________ kg Unladen (tare) mass _________ kg - 453 - CHAPTER 6.8 REQUIREMENTS FOR THE CONSTRUCTION, EQUIPMENT, TYPE APPROVAL, INSPECTIONS AND TESTS, AND MARKING OF FIXED TANKS (TANK-VEHICLES), DEMOUNTABLE TANKS AND TANK-CONTAINERS AND TANK SWAP BODIES, WITH SHELLS MADE OF METALLIC MATERIALS, AND BATTERY-VEHICLES AND MULTIPLE ELEMENT GAS CONTAINERS (MEGCs) NOTE 1: For portable tanks and UN multiple-element gas containers (MEGCs) see Chapter 6.7, for fibrereinforced plastics tanks see Chapter 6.9, for vacuum operated waste tanks see Chapter 6.10. NOTE 2: For fixed tanks (tank-vehicles) and demountable tanks with additive devices, see special provision 664 of Chapter 3.3. 6.8.1 Scope 6.8.1.1 The requirements across the whole width of the page apply both to fixed tanks (tank-vehicles), to demountable tanks and battery-vehicles, and to tank-containers, tank swap bodies and MEGCs. Those contained in a single column apply only: 6.8.1.2 - to fixed tanks (tank-vehicles), to demountable tanks and battery-vehicles (left hand column); - to tank-containers, tank swap bodies and MEGCs (right hand column). These requirements shall apply to fixed tanks (tank-vehicles), demountable tanks and battery-vehicles tank-containers, tank swap bodies and MEGCs used for the carriage of gaseous, liquid, powdery or granular substances. 6.8.1.3 Section 6.8.2 sets out the requirements applicable to fixed tanks (tank-vehicles), to demountable tanks, tank-containers, tank swap bodies intended for the carriage of substances of all classes and batteryvehicles and MEGCs for gases of Class 2. Sections 6.8.3 to 6.8.5 contain special requirements supplementing or modifying the requirements of section 6.8.2. 6.8.1.4 For provisions concerning use of these tanks, see Chapter 4.3. 6.8.2 Requirements applicable to all classes 6.8.2.1 Construction Basic principles 6.8.2.1.1 Shells, their attachments and their service and structural equipment shall be designed to withstand without loss of contents (other than quantities of gas escaping through any degassing vents): - static and dynamic stresses in normal conditions of carriage as defined in 6.8.2.1.2 and 6.8.2.1.13; - prescribed minimum stresses as defined in 6.8.2.1.15. - 455 - 6.8.2.1.2 6.8.2.1.3 The tanks and their fastenings shall be capable of Tank-containers and their fastenings shall, absorbing, under the maximum permissible load, under the maximum permissible load be the forces exerted by: capable of absorbing the forces equal to those exerted by: in the direction of travel: twice the total mass; in the direction of travel: twice the total mass; at right angles to the direction of travel: the total mass; horizontally at right angles to the direction of travel: the total mass; (where the vertically upwards: the total mass; direction of travel is not clearly determined, twice the total mass in each vertically downwards: twice the total mass. direction); - vertically upwards: the total mass; - vertically downwards: twice the total mass. The walls of the shells shall have at least the thickness specified in 6.8.2.1.17 to 6.8.2.1.21 6.8.2.1.17 to 6.8.2.1.20. 6.8.2.1.4 Shells shall be designed and constructed in accordance with the requirements of standards listed in 6.8.2.6 or of a technical code recognized by the competent authority, in accordance with 6.8.2.7, in which the material is chosen and the shell thickness determined taking into account maximum and minimum filling and working temperatures, but the following minimum requirements of 6.8.2.1.6 to 6.8.2.1.26 shall be met. 6.8.2.1.5 Tanks intended to contain certain dangerous substances shall be provided with additional protection. This may take the form of additional thickness of the shell (increased calculation pressure) determined in the light of the dangers inherent in the substances concerned or of a protective device (see the special provisions of 6.8.4). 6.8.2.1.6 Welds shall be skilfully made and shall afford the fullest safety. The execution and checking of welds shall comply with the requirements of 6.8.2.1.23. 6.8.2.1.7 Measures shall be taken to protect shells against the risk of deformation as a result of a negative internal pressure. Shells, other than shells according to 6.8.2.2.6, designed to be equipped with vacuum valves shall be able to withstand, without permanent deformation, an external pressure of not less than 21 kPa (0.21 bar) above the internal pressure. Shells used for the carriage of solid substances (powdery or granular) of packing groups II or III only, which do not liquefy during carriage, may be designed for a lower external pressure but not less than 5 kPa (0.05 bar). The vacuum valves shall be set to relieve at a vacuum setting not greater than the tank's design vacuum pressure. Shells, which are not designed to be equipped with a vacuum valve shall be able to withstand, without permanent deformation an external pressure of not less than 40 kPa (0.4 bar) above the internal pressure. Materials for shells 6.8.2.1.8 Shells shall be made of suitable metallic materials which, unless other temperature ranges are prescribed in the various classes, shall be resistant to brittle fracture and to stress corrosion cracking between -20 C and +50 C. 6.8.2.1.9 The materials of shells or of their protective linings which are in contact with the contents shall not contain substances liable to react dangerously (see "Dangerous reaction" in 1.2.1) with the contents, to form dangerous compounds, or substantially to weaken the material. If contact between the substance carried and the material used for the construction of the shell entails a progressive decrease in the shell thickness, this thickness shall be increased at manufacture by an appropriate amount. This additional thickness to allow for corrosion shall not be taken into consideration in calculating the shell thickness. - 456 - 6.8.2.1.10 For welded shells only materials of faultless weldability whose adequate impact strength at an ambient temperature of –20 ºC can be guaranteed, particularly in the weld seams and the zones adjacent thereto, shall be used. If fine-grained steel is used, the guaranteed value of the yield strength Re shall not exceed 460 N/mm2 and the guaranteed value of the upper limit of tensile strength Rm shall not exceed 725 N/mm2, in accordance with the specifications of the material. 6.8.2.1.11 Ratios of Re/Rm exceeding 0.85 are not allowed for steels used in the construction of welded tanks. Re = apparent yield strength for steels having a clearly-defined yield point or guaranteed 0.2% proof strength for steels with no clearly-defined yield point (1% for austenitic steels) Rm = tensile strength. The values specified in the inspection certificate for the material shall be taken as a basis in determining this ratio in each case. 6.8.2.1.12 For steel, the elongation at fracture, in % shall be not less than 10 000 determined tensile stenght in N/mm 2 but in any case for fine-grained steels it shall be not less than 16% and not less than 20% for other steels. For aluminium alloys the elongation at fracture shall be not less than 12%1. Calculation of the shell thickness 6.8.2.1.13 The pressure on which the shell thickness is based shall not be less than the calculation pressure, but the stresses referred to in 6.8.2.1.1 shall also be taken into account, and, if necessary, the following stresses: In the case of vehicles in which the tank constitutes a stressed self-supporting member, the shell shall be designed to withstand the stresses thus imposed in addition to stresses from other sources. Under these stresses, the stress at the most Under each of these stresses the safety factors to severely stressed point of the shell and its be observed shall be the following: fastenings shall not exceed the value  defined in for metals having a clearly-defined yield 6.8.2.1.16. point: a safety factor of 1.5 in relation to the apparent yield strength; or - 1 for metals with no clearly-defined yield point: a safety factor of 1.5 in relation to the guaranteed 0.2% proof strength (1% maximum elongation for austenitic steels). In the case of sheet metal the axis of the tensile test-piece shall be at right angles to the direction of rolling. The permanent elongation at fracture shall be measured on test-pieces of circular cross-section in which the gauge length l is equal to five times the diameter d (l = 5d); if test-pieces of rectangular section are used, the gauge length shall be calculated by the formula l  5,65 Fo , where Fo indicates the initial cross-section area of the test-piece. - 457 - 6.8.2.1.14 The calculation pressure is in the second part of the code (see 4.3.4.1) according to Column (12) of Table A of Chapter 3.2. When "G" appears, the following requirements shall apply: (a) Gravity-discharge shells intended for the carriage of substances having a vapour pressure not exceeding 110 kPa (1.1 bar) (absolute pressure) at 50 ºC shall be designed for a calculation pressure of twice the static pressure of the substance to be carried but not less than twice the static pressure of water; (b) Pressure-filled or pressure-discharge shells intended for the carriage of substances having a vapour pressure not exceeding 110 kPa (1.1 bar) (absolute pressure) at 50 ºC shall be designed for a calculation pressure equal to 1.3 times the filling or discharge pressure; When the numerical value of the minimum calculation pressure is given (gauge pressure) the shell shall be designed for this pressure which shall not be less than 1.3 times the filling or discharge pressure. The following minimum requirements shall apply in these cases: (c) Shells intended for the carriage of substances having a vapour pressure of more than 110 kPa (1.1 bar) at 50 °C and a boiling point of more than 35 °C shall, whatever their filling or discharge system, be designed for a calculation pressure of not less than 150 kPa (1.5 bar) gauge pressure or 1.3 times the filling or discharge pressure, whichever is the higher; (d) Shells intended for the carriage of substances having a boiling point of not more than 35 °C shall, whatever their filling or discharge system, be designed for a calculation pressure equal to 1.3 times the filling or discharge pressure but not less than 0.4 MPa (4 bar) (gauge pressure). 6.8.2.1.15 At the test pressure, the stress  at the most severely stressed point of the shell shall not exceed the material-dependent limits prescribed below. Allowance shall be made for any weakening due to the welds. 6.8.2.1.16 For all metals and alloys, the stress  at the test pressure shall be lower than the smaller of the values given by the following formulae:   0.75 Re or   0.5 Rm where Re = apparent yield strength for steels having a clearly-defined yield point; or guaranteed 0.2% proof strength for steels with no clearly-defined yield point (1% for austenitic steels) Rm = tensile strength. The values of Re and Rm to be used shall be specified minimum values according to material standards. If no material standard exists for the metal or alloy in question, the values of Re and Rm used shall be approved by the competent authority or by a body designated by that authority. When austenitic steels are used, the specified minimum values according to the material standards may be exceeded by up to 15% if these higher values are attested in the inspection certificate. The minimum values shall, however, not be exceeded when the formula given in 6.8.2.1.18 is applied. Minimum shell thickness 6.8.2.1.17 The shell thickness shall not be less than the greater of the values determined by the following formulae: e PT D 2 e - 458 - PC D 2 where: e = minimum shell thickness in mm PT = test pressure in MPa PC = calculation pressure in MPa as specified in 6.8.2.1.14 D = internal diameter of shell in mm  = permissible stress, as defined in 6.8.2.1.16, in N/mm2  = a coefficient not exceeding 1, allowing for any weakening due to welds, and linked to the inspection methods defined in 6.8.2.1.23. The thickness shall in no case be less than that defined in 6.8.2.1.18 to 6.8.2.1.21. 6.8.2.1.18 6.8.2.1.18 to 6.8.2.1.20. Shells of circular cross-section 2 not more than Shells shall be not less than 5 mm thick if of mild 1.80 m in diameter other than those referred to in steel3 (in conformity with the requirements of 6.8.2.1.21, shall not be less than 5 mm thick if of 6.8.2.1.11 and 6.8.2.1.12) or of equivalent mild steel3, or of equivalent thickness if of thickness if of another metal. another metal. Where the diameter is more than 1.80 m, this Where the diameter is more than 1.80 m, this thickness shall be increased to 6 mm except in thickness shall be increased to 6 mm except in the case of shells intended for the carriage of the case of tanks intended for the carriage of powdery or granular substances, if the shell is of powdery or granular substances, if the shell is of mild steel3, or to an equivalent thickness if of mild steel3 or to an equivalent thickness if of another metal. another metal. Whatever the metal used, the shell thickness shall in no case be less than 3 mm. "Equivalent thickness" means the thickness obtained by the following formula4: e1  464e 0 3 R m1 A1 2 2 For shells not of a circular cross-section, for example box-shaped or elliptical shells, the indicated diameters shall correspond to those calculated on the basis of a circular cross-section of the same area. For such shapes of cross-section the radius of convexity of the shell wall shall not exceed 2 000 mm at the sides or 3 000 mm at the top and bottom. 3 For the definitions of "mild steel" and "reference steel" see 1.2.1. "Mild steel" in this case also covers a steel referred to in EN material standards as "mild steel", with a minimum tensile strength between 360 N/mm² and 490 N/mm² and a minimum elongation at fracture conforming to 6.8.2.1.12. 4 This formula is derived from the general formula: e1  e 0  R m0 A 0   R A1   m1  2 3  where e1 = minimum shell thickness for the metal chosen, in mm; eo = minimum shell thickness for mild steel, in mm, according to 6.8.2.1.18 and 6.8.2.1.19; Rmo = 370 (tensile strength for reference steel, see definition 1.2.1, in N/mm2); Ao = 27 (elongation at fracture for reference steel, in %); Rm1 = minimum tensile strength of the metal chosen, in N/mm2; and A1 = minimum elongation at fracture of the metal chosen under tensile stress, in %. - 459 - 6.8.2.1.19 Where protection of the tank against damage through lateral impact or overturning is provided according to 6.8.2.1.20, the competent authority may allow the aforesaid minimum thicknesses to be reduced in proportion to the protection provided; however, the said thicknesses shall not be less than 3 mm in the case of mild steel3, or than an equivalent thickness in the case of other materials, for shells not more than 1.80 m in diameter. For shells with a diameter exceeding 1.80 m the aforesaid minimum thickness shall be increased to 4 mm in the case of mild steel3 and to an equivalent thickness in the case of other metals. Where protection of the tank against damage is provided according to 6.8.2.1.20, the competent authority may allow the aforesaid minimum thicknesses to be reduced in proportion to the protection provided; however, the said thicknesses shall be not less than 3 mm in the case of mild steel3, or than an equivalent thickness in the case of other materials, for shells not more than 1.80 m in diameter. For shells of a diameter exceeding 1.80 m this minimum thickness shall be increased to 4 mm in the case of mild steel3, and to an equivalent thickness in the case of other metals. Equivalent thickness means the thickness given Equivalent thickness means the thickness given by the formula in 6.8.2.1.18. by the formula in 6.8.2.1.18. Minimum thickness of shells Except in cases for which 6.8.2.1.21 provide, the The thickness of shells with protection against thickness of shells with protection against damage in accordance with 6.8.2.1.20 shall not damage in accordance with 6.8.2.1.20 (a) or (b) be less than the values given in the table below. shall not be less than the values given in the table below. 6.8.2.1.20 Diameter of shell Austenitic stainless steels Austenitic-ferritic stainless steels Other steels Aluminium alloys Pure aluminium of 99.80%  1.80 m 2.5 mm > 1.80 m 3 mm 3 mm 3.5 mm 3 mm 4 mm 6 mm 4 mm 5 mm 8 mm For tanks built after 1 January 1990, there is The protection referred to in 6.8.2.1.19 may protection against damage as referred to in consist of: 6.8.2.1.19 when the following measures or - overall external structural protection as in equivalent5 measures are adopted: "sandwich" construction where the sheathing is secured to the shell; or (a) For tanks intended for the carriage of - a structure in which the shell is supported by a powdery or granular substances, the complete skeleton including longitudinal and protection against damage shall satisfy the transverse structural members; or competent authority. - double-wall construction. (b) For tanks intended for the carriage of other substances, there is protection against damage when: 1. For shells with a circular or elliptical Where the tanks are made with double walls, the cross-section having a maximum radius space between being evacuated of air, the of curvature of 2 m, the shell is aggregate thickness of the outer metal wall and equipped with strengthening members the shell wall shall correspond to the minimum comprising partitions, surge-plates or wall thickness prescribed in 6.8.2.1.18, the external or internal rings, so placed that thickness of the wall of the shell itself being not at least one of the following conditions less than the minimum thickness prescribed in is met: 6.8.2.1.19. 3 For the definitions of "mild steel" and "reference steel" see 1.2.1. "Mild steel" in this case also covers a steel referred to in EN material standards as "mild steel", with a minimum tensile strength between 360 N/mm² and 490 N/mm² and a minimum elongation at fracture conforming to 6.8.2.1.12. 5 Equivalent measures means measures given in standards referenced in 6.8.2.6. - 460 - - Distance between two adjacent Where tanks are made with double walls with an strengthening elements of not more intermediate layer of solid materials at least than 1.75 m. 50 mm thick, the outer wall shall have a thickness of not less than 0.5 mm if it - Volume contained between two is made of mild steel3 or at least 2 mm if it is partitions or surge-plates of not made of a plastics material reinforced with glass more than 7 500 l. fibre. Solid foam with an impact absorption capacity such as that, for example, of The vertical cross-section of a ring, polyurethane foam, may be used as the with the associated coupling, shall have intermediate layer of solid material. 3 a section modulus of at least 10 cm . External rings shall not have projecting edges with a radius of less than 2.5 mm. Partitions and surge-plates shall conform to the requirements of 6.8.2.1.22. The thickness of the partitions and surge-plates shall in no case be less than that of the shell. 2. For tanks made with double walls, the space between being evacuated of air, the aggregate thickness of the outer metal wall and the shell wall corresponds to the wall thickness prescribed in 6.8.2.1.18, and the thickness of the wall of the shell itself is not less than the minimum thickness prescribed in 6.8.2.1.19. 3. For tanks made with double walls having an intermediate layer of solid materials at least 50 mm thick, the outer wall has a thickness of at least 0.5 mm of mild steel3 or at least 2 mm of a plastics material reinforced with glass fibre. Solid foam (with an impact absorption capacity like that, for example, of polyurethane foam) may be used as the intermediate layer of solid material. 4. Shells of forms other than in 1, especially box-shaped shells, are provided, all round the mid-point of their vertical height and over at least 30% of their height with a protection designed in such a way as to offer specific resilience at least equal to that of a shell constructed in mild steel3 of a thickness of 5 mm (for a shell diameter not exceeding 1.80 m) or 6 mm (for a shell diameter exceeding 1.80 m). The protection shall be applied in a durable manner to the shell. This requirement shall be considered to have been met without further proof of the specific resilience when the 3 For the definitions of "mild steel" and "reference steel" see 1.2.1. "Mild steel" in this case also covers a steel referred to in EN material standards as "mild steel", with a minimum tensile strength between 360 N/mm² and 490 N/mm² and a minimum elongation at fracture conforming to 6.8.2.1.12. - 461 - protection involves the welding of a plate of the same material as the shell to the area to be strengthened, so that the minimum wall thickness is in accordance with 6.8.2.1.18. This protection is dependent upon the possible stresses exerted on mild steel3 shells in the event of an accident, where the ends and walls have a thickness of at least 5 mm for a diameter not exceeding 1.80 m or at least 6 mm for a diameter exceeding 1.80 m. If another metal is used, the equivalent thickness shall be obtained in accordance with the formula in 6.8.2.1.18. For demountable tanks this protection is not required when they are protected on all sides by the drop sides of the carrying vehicle. 6.8.2.1.21 The thickness of shells designed in accordance with 6.8.2.1.14 (a) which either are of not more than 5 000 litres capacity or are divided into leakproof compartments of not more than 5 000 litres unit capacity may be adjusted to a level which, unless prescribed otherwise in 6.8.3 or 6.8.4, shall however not be less than the appropriate value shown in the following table: Maximum radius of curvature of shell (m) Capacity of shell or shell compartment (m3) 2  5.0 3 2-3  3.5 3 > 3.5 but  5.0 4 Minimum thickness (mm) Mild steel Where a metal other than mild steel3 is used, the thickness shall be determined by the equivalence formula given in 6.8.2.1.18 and shall not be less than the values given in the following table: 3 For the definitions of "mild steel" and "reference steel" see 1.2.1. "Mild steel" in this case also covers a steel referred to in EN material standards as "mild steel", with a minimum tensile strength between 360 N/mm² and 490 N/mm² and a minimum elongation at fracture conforming to 6.8.2.1.12. - 462 - Minimum thickness of shell 6.8.2.1.22 Maximum radius of curvature of shell (m) Capacity of shell or shell compartment (m3) Austenitic stainless steels Other steels Aluminium alloys Pure aluminium at 99.80% 2 2-3 2-3  5.0  3.5 > 3.5 but  5.0 2.5 mm 2.5 mm 3 mm 3 mm 3 mm 4 mm 4 mm 4 mm 5 mm 6 mm 6 mm 8 mm The thickness of the partitions and surge-plates shall in no case be less than that of the shell. Surge-plates and partitions shall be dished, with a depth of dish of not less than 10 cm, or shall be corrugated, profiled or otherwise reinforced to give equivalent strength. The area of the surge plate shall be at least 70% of the cross-sectional area of the tank in which the surge-plate is fitted. Welding and inspection of welds 6.8.2.1.23 The manufacturer's qualification for performing welding operations shall be one recognized by the competent authority. Welding shall be performed by skilled welders using a welding process whose effectiveness (including any heat treatments required) has been demonstrated by test. Nondestructive tests shall be carried out by radiography or by ultrasound and must confirm that the quality of the welding is appropriate to the stresses. The following checks shall be carried out in accordance with the value of the coefficient  used in determining the thickness of the shell in 6.8.2.1.17:  = 0.8: the weld beads shall so far as possible be inspected visually on both faces and shall be subjected to a non-destructive spot check. All weld "Tee" junctions with the total length of weld examined to be not less than 10% of the sum of the length of all longitudinal, circumferential and radial (in the tank ends) welds shall be tested;  = 0.9: all longitudinal beads throughout their length, all connections, 25% of circular beads, and welds for the assembly of large-diameter items of equipment shall be subjected to non-destructive checks. Beads shall be checked visually on both sides as far as possible;  = 1: all beads shall be subjected to non-destructive checks and shall so far as possible be inspected visually on both sides. A weld test-piece shall be taken. Where the competent authority has doubts regarding the quality of weld beads, it may require additional checks. Other construction requirements 6.8.2.1.24 The protective lining shall be so designed that its leakproofness remains intact, whatever the deformation liable to occur in normal conditions of carriage (see 6.8.2.1.2). 6.8.2.1.25 The thermal insulation shall be so designed as not to hinder access to, or the operation of, filling and discharge devices and safety valves. - 463 - 6.8.2.1.26 If shells intended for the carriage of flammable liquids having a flash-point of not more than 60 ºC are fitted with non-metallic protective linings (inner layers), the shells and the protective linings shall be so designed that no danger of ignition from electrostatic charges can occur. 6.8.2.1.27 Shells intended for the carriage of liquids having a flash-point of not more than 60 ºC or for the carriage of flammable gases, or of UN No.1361 carbon or UN No.1361 carbon black, packing group II, shall be linked to the chassis by means of at least one good electrical connection. Any metal contact capable of causing electrochemical corrosion shall be avoided. Shells shall be provided with at least one earth fitting clearly marked with the symbol " of being electrically connected. 6.8.2.1.28 All parts of a tank-container intended for the carriage of liquids having a flash-point of not more than 60 ºC, flammable gases, or UN No.1361 carbon or UN No.1361 carbon black, packing group II, shall be capable of being electrically earthed. Any metal contact capable of causing electrochemical corrosion shall be avoided. ", capable Protection of fittings mounted on the upper part of the tank The fittings and accessories mounted on the upper part of the tank shall be protected against damage caused by overturning. This protection may take the form of strengthening rings, protective canopies or transverse or longitudinal members so shaped that effective protection is given. 6.8.2.2 Items of equipment 6.8.2.2.1 Suitable non-metallic materials may be used to manufacture service and structural equipment. The items of equipment shall be so arranged as to be protected against the risk of being wrenched off or damaged during carriage or handling. They shall exhibit a suitable degree of safety comparable to that of the shells themselves, and shall in particular: - be compatible with the substances carried; and meet the requirements of 6.8.2.1.1. Piping shall be designed, constructed and installed so as to avoid the risk of damage due to thermal expansion and contraction, mechanical shock and vibration. As many operating parts as possible shall be The leakproofness of the service equipment shall served by the smallest possible number of be ensured even in the event of the overturning of openings in the shell. The leakproofness of the the tank-container. service equipment including the closure (cover) of the inspection openings shall be ensured even in the event of overturning of the tank, taking into account the forces generated by an impact (such as acceleration and dynamic pressure). Limited release of the tank contents due to a pressure peak during the impact is however allowed. The gaskets shall be made of a material compatible with the substance carried and shall be replaced as soon as their effectiveness is impaired, for example as a result of ageing. Gaskets ensuring the leakproofness of fittings requiring manipulation during normal use of tanks shall be so designed and arranged that manipulation of the fittings incorporating them does not damage them. - 464 - 6.8.2.2.2 Each bottom-filling or bottom-discharge opening in tanks which are referred to, in Column (12) of Table A of Chapter 3.2, with a tank code including the letter "A" in its third part (see 4.3.4.1.1) shall be equipped with at least two mutually independent closures, mounted in series, comprising - an external stop-valve with piping made of a malleable metal material and - a closing device at the end of each pipe which may be a screw-threaded plug, a blank flange or an equivalent device. This closing device shall be sufficiently tight so that the substance is contained without loss. Measures shall be taken to enable the safe release of pressure in the discharge pipe before the closing device is completely removed. Each bottom-filling or bottom-discharge opening in tanks which are referred to, in Column (12) of Table A of Chapter 3.2, with a tank code including the letter "B" in its third part (see 4.3.3.1.1 or 4.3.4.1.1) shall be equipped with at least three mutually independent closures, mounted in series, comprising - an internal stop-valve, i.e. a stop-valve mounted inside the shell or in a welded flange or companion flange; - an external stop-valve or an equivalent device6 one at the end of each pipe as near as possible to the shell and - a closing device at the end of each pipe which may be a screw-threaded plug, a blank flange or an equivalent device. This closing device shall be sufficiently tight so that the substance is contained without loss. Measures shall be taken to enable the safe release of pressure in the discharge pipe before the closing device is completely removed. However, in the case of tanks intended for the carriage of certain crystallizable or highly viscous substances and shells fitted with an ebonite or thermoplastic coating, the internal stop-valve may be replaced by an external stop-valve provided with additional protection. The internal stop-valve shall be operable either from above or from below. Its setting - open or closed - shall so far as possible in each case be capable of being verified from the ground. Internal stopvalve control devices shall be so designed as to prevent any unintended opening through impact or an inadvertent act. The internal shut-off device shall continue to be effective in the event of damage to the external control device. In order to avoid any loss of contents in the event of damage to the external fittings (pipes, lateral shut-off devices), the internal stop-valve and its seating shall be protected against the danger of being wrenched off by external stresses or shall be so designed as to resist them. The filling and discharge devices (including flanges or threaded plugs) and protective caps (if any) shall be capable of being secured against any unintended opening. The position and/or direction of closure of shut-off devices shall be clearly apparent. All openings of tanks which are referred to in Column (12) of Table A of Chapter 3.2, by a tank code including letter "C" or "D" in its third part (see 4.3.3.1.1 and 4.3.4.1.1) shall be situated above the surface level of the liquid. These tanks shall have no pipes or pipe connections below the surface level of the liquid. The cleaning openings (fist-holes) are, however, permitted in the lower part of the shell for tanks referred to by a tank code including letter "C" in its third part. This opening shall be capable of being sealed by a flange so closed as to be leakproof and whose design shall be approved by the competent authority or by a body designated by that authority. 6 In the case of tank-containers of less than 1 m3 capacity, the external stop-valve or other equivalent device may be replaced by a blank flange. - 465 - 6.8.2.2.3 Tanks that are not hermetically closed may be fitted with vacuum valves to avoid an unacceptable negative internal pressure; these vacuum-relief valves shall be set to relieve at a vacuum setting not greater than the vacuum pressure for which the tank has been designed (see 6.8.2.1.7). Hermetically closed tanks shall not be fitted with vacuum valves. However, tanks of the tank code SGAH, S4AH or L4BH, fitted with vacuum valves which open at a negative pressure of not less than 21 kPa (0.21 bar) shall be considered as being hermetically closed. For tanks intended for the carriage of solid substances (powdery or granular) of packing groups II or III only, which do not liquefy during transport, the negative pressure may be reduced to not less than 5 kPa (0.05 bar). Vacuum valves and breather devices (see 6.8.2.2.6) used on tanks intended for the carriage of substances meeting the flash-point criteria of Class 3, shall prevent the immediate passage of flame into the shell by means of a suitable protective device, or the shell of the tank shall be explosion pressure shock resistant, which means being capable of withstanding without leakage, but allowing deformation, an explosion resulting from the passage of the flame. If the protective device consists of a suitable flame trap or flame arrester, it shall be positioned as close as possible to the shell or the shell compartment. For multi-compartment tanks, each compartment shall be protected separately. 6.8.2.2.4 The shell or each of its compartments shall be provided with an opening large enough to permit inspection. 6.8.2.2.5 (Reserved) 6.8.2.2.6 Tanks intended for the carriage of liquids having a vapour pressure of not more than 110 kPa (1.1 bar) (absolute) at 50 oC shall have a breather device and a safety device to prevent the contents from spilling out if the tank overturns; otherwise they shall conform to 6.8.2.2.7 or 6.8.2.2.8. 6.8.2.2.7 Tanks intended for the carriage of liquids having a vapour pressure of more than 110 kPa (1.1 bar) at 50 °C and a boiling point of more than 35 °C shall have a safety valve set at not less than 150 kPa (1.5 bar) (gauge pressure) and which shall be fully open at a pressure not exceeding the test pressure; otherwise they shall conform to 6.8.2.2.8. 6.8.2.2.8 Tanks intended for the carriage of liquids having a boiling point of not more than 35 °C shall have a safety valve set at not less than 300 kPa (3 bar) gauge pressure and which shall be fully open at a pressure not exceeding the test pressure; otherwise they shall be hermetically closed7. 6.8.2.2.9 Movable parts such as covers, closures, etc., which are liable to come into frictional or percussive contact with aluminium shells intended for the carriage of flammable liquids having a flash-point of not more than 60 ºC or for the carriage of flammable gases shall not be made of unprotected corrodible steel. 6.8.2.2.10 If tanks required to be hermetically closed are equipped with safety valves, these shall be preceded by a bursting disc and the following conditions shall be observed: The arrangement of the bursting disc and safety valve shall be such as to satisfy the competent authority. A pressure gauge or another suitable indicator shall be provided in the space between the bursting disc and the safety valve, to enable detection of any rupture, perforation or leakage of the disc which may disrupt the action of the safety valve. 7 For the definition of "hermetically closed tank" see 1.2.1. - 466 - 6.8.2.3 Type approval 6.8.2.3.1 The competent authority or a body designated by that authority shall issue in respect of each new type of tank-vehicle, demountable tank, tank-container, tank swap body, battery-vehicle or MEGC a certificate attesting that the type, including fastenings, which it has inspected is suitable for the purpose for which it is intended and meets the construction requirements of 6.8.2.1, the equipment requirements of 6.8.2.2 and the special conditions for the classes of substances carried. The certificate shall show: - the results of the test; - an approval number for the type; The approval number shall consist of the distinguishing sign8 of the State in whose territory the approval was granted and a registration number. - the tank code in accordance with 4.3.3.1.1 or 4.3.4.1.1; - the alphanumerical codes of special provisions of construction (TC), equipment (TE) and type approval (TA) of 6.8.4 which are shown in column (13) of Table A of Chapter 3.2 for those substances for the carriage of which the tank has been approved; - if required, the substances and/or group of substances for the carriage of which the tank has been approved. These shall be shown with their chemical name or the corresponding collective entry (see 2.1.1.2), together with their classification (class, classification code and packing group). With the exception of substances of Class 2 and those listed in 4.3.4.1.3, the listing of approved substances may be dispensed with. In such cases, groups of substances permitted on the basis of the tank code shown in the rationalised approach in 4.3.4.1.2 shall be accepted for carriage taking into account any relevant special provision. The substances referred to in the certificate or the groups of substances approved according to the rationalised approach shall, in general, be compatible with the characteristics of the tank. A reservation shall be included in the certificate if it was not possible to investigate this compatibility exhaustively when the type approval was issued. A copy of the certificate shall be attached to the tank record of each tank, battery-vehicle or MEGC constructed (see 4.3.2.1.7). The competent authority or a body designated by that authority shall at the request of the applicant carry out a separate type approval of valves and other service equipment for which a standard is listed in the table in 6.8.2.6.1, in accordance with that standard. This separate type approval shall be taken into account when issuing the certificate for the tank, if the test results are presented and the valves and other service equipment are fit for the intended use. 6.8.2.3.2 If the tanks, battery-vehicles or MECGs are manufactured in series without modification this approval shall be valid for the tanks, battery-vehicles or MECGs manufactured in series or according to the prototype. A type approval may however serve for the approval of tanks with limited variations of the design that either reduce the loads and stresses on the tanks (e.g. reduced pressure, reduced mass, reduced volume) or increase the safety of the structure (e.g. increased shell thickness, more surge-plates, decreased diameter of openings). The limited variations shall be clearly described in the type approval certificate. 6.8.2.3.3 8 The following requirements apply to tanks for which special provision TA4 of 6.8.4 (and therefore 1.8.7.2.4) does not apply. Distinguishing sign for use in international traffic prescribed by the Convention on Road Traffic (Vienna, 1968). - 467 - The type approval shall be valid for a maximum of ten years. If within that period the relevant technical requirements of ADR (including referenced standards) have changed so that the approved type is no longer in conformity with them, the competent authority or the body designated by that authority which issued the type approval shall withdraw it and inform the holder of the type approval. NOTE: For the ultimate dates for withdrawal of existing type approvals, see column (5) of the tables in 6.8.2.6 or 6.8.3.6 as appropriate. If a type approval has expired or has been withdrawn, the manufacture of the tanks, battery-vehicles or MEGCs according to that type approval is no longer authorised. In such a case, the relevant provisions concerning the use, periodic inspection and intermediate inspection of tanks, battery-vehicles or MEGCs contained in the type approval which has expired or has been withdrawn shall continue to apply to these tanks, battery-vehicles or MEGCs constructed before the expiry or the withdrawal if they may continue to be used. They may continue to be used as long as they remain in conformity with the requirements of ADR. If they are no longer in conformity with the requirements of ADR they may continue to be used only if such use is permitted by relevant transitional measures in Chapter 1.6. Type approvals may be renewed by a complete review and assessment for conformity with the provisions of ADR applicable at the date of renewal. Renewal is not permitted after a type approval has been withdrawn. Interim amendments of an existing type approval not affecting conformity (see 6.8.2.3.2) do not extend or modify the original validity of the certificate. NOTE: The review and assessment of conformity can be done by a body other than the one which issued the original type approval. The issuing body shall keep all documents for the type approval for the whole period of validity including its renewals if granted. If the designation of the issuing body is revoked or restricted, or when the body has ceased activity, the competent authority shall take appropriate steps to ensure that the files are either processed by another body or kept available. 6.8.2.3.4 In the case of a modification of a tank with a valid, expired or withdrawn type approval, the testing, inspection and approval are limited to the parts of the tank that have been modified. The modification shall meet the provisions of ADR applicable at the time of the modification. For all parts of the tank not affected by the modification, the documentation of the initial type approval remains valid. A modification may apply to one or more tanks covered by a type approval. A certificate approving the modification shall be issued by the competent authority of any Contracting Party to ADR or by a body designated by this authority and shall be kept as part of the tank record. Each application for an approval certificate for a modification shall be lodged with a single competent authority or body designated by this authority. - 468 - 6.8.2.4 Inspections and tests 6.8.2.4.1 Shells and their equipment shall either together or separately undergo an initial inspection before being put into service. This inspection shall include: - a check of conformity to the approved type; - a check of the design characteristics9 - an examination of the internal and external conditions; - a hydraulic pressure test10 at the test pressure indicated on the plate prescribed in 6.8.2.5.1; and - a leakproofness test and a check of satisfactory operation of the equipment. Except in the case of Class 2, the test pressure for the hydraulic pressure test depends on the calculation pressure and shall be at least equal to the pressure indicated below: Calculation pressure (bar) G11 1.5 2.65 4 10 15 21 Test pressure (bar) G11 1.5 2.65 4 4 4 10 (412) The minimum test pressures for Class 2 are given in the table of gases and gas mixtures in 4.3.3.2.5. The hydraulic pressure test shall be carried out on the shell as a whole and separately on each compartment of compartmented shells. The test shall be carried out on each compartment at a pressure at least equal to 1.3 times the maximum working pressure. The hydraulic pressure test shall be carried out before the installation of a thermal insulation as may be necessary. If the shells and their equipment are tested separately, they shall be jointly subjected to a leakproofness test after assembly in accordance with 6.8.2.4.3. The leakproofness test shall be carried out separately on each compartment of compartmented shells. 6.8.2.4.2 Shells and their equipment shall undergo periodic inspections no later than every six years. five years. These periodic inspections shall include: - An external and internal examination; 9 The check of the design characteristics shall also include, for shells requiring a test pressure of 1 MPa (10 bar) or higher, the taking of weld test-pieces (work samples) in accordance with 6.8.2.1.23 and the tests prescribed in 6.8.5. 10 In special cases and with the agreement of the expert approved by the competent authority, the hydraulic pressure test may be replaced by a pressure test using another liquid or gas, where such an operation does not present any danger. 11 G = minimum calculation pressure according to the general requirements of 6.8.2.1.14 (see 4.3.4.1). 12 Minimum test pressure for UN No. 1744 bromine or UN No. 1744 bromine solution. - 469 - - A leakproofness test in accordance with 6.8.2.4.3 of the shell with its equipment and check of the satisfactory operation of all the equipment; - As a general rule, a hydraulic pressure test10 (for the test pressure for the shells and compartments if applicable, see 6.8.2.4.1). Sheathing for thermal or other insulation shall be removed only to the extent required for reliable appraisal of the characteristics of the shell. In the case of tanks intended for the carriage of powdery or granular substances, and with the agreement of the expert approved by the competent authority, the periodic hydraulic pressure tests may be omitted and replaced by leakproofness tests in accordance with 6.8.2.4.3, at an effective internal pressure at least equal to the maximum working pressure. 6.8.2.4.3 Shells and their equipment shall undergo intermediate inspections at least every three years two and a half years after the initial inspection and each periodic inspection. These intermediate inspections may be performed within three months before or after the specified date. However, the intermediate inspection may be performed at any time before the specified date. If an intermediate inspection is performed more than three months before the due date, another intermediate inspection shall be performed at the latest three years two and a half years after this date. These intermediate inspections shall include a leakproofness test of the shell with its equipment and check of the satisfactory operation of all the equipment. For this purpose the tank shall be subjected to an effective internal pressure at least equal to the maximum working pressure. For tanks intended for the carriage of liquids or solids in the granular or powdery state, when a gas is used for the leakproofness test it shall be carried out at a pressure at least equal to 25% of the maximum working pressure. In all cases, it shall not be less than 20 kPa (0.2 bar) (gauge pressure). For tanks equipped with breather devices and a safety device to prevent the contents spilling out if the tank overturns, the pressure test shall be equal to the static pressure of the filling substance. The leakproofness test shall be carried out separately on each compartment of compartmented shells. 6.8.2.4.4 When the safety of the tank or of its equipment may have been impaired as a result of repairs, alterations or accident, an exceptional check shall be carried out. If an exceptional check fulfilling the requirements of 6.8.2.4.2 has been performed, then the exceptional check may be considered to be a periodic inspection. If an exceptional check fulfilling the requirements of 6.8.2.4.3 has been performed then the exceptional check may be considered to be an intermediate inspection. 6.8.2.4.5 The tests, inspections and checks in accordance with 6.8.2.4.1 to 6.8.2.4.4 shall be carried out by the expert approved by the competent authority. Certificates shall be issued showing the results of these operations, even in the case of negative results. These certificates shall refer to the list of the substances permitted for carriage in this tank or to the tank code and the alphanumeric codes of special provisions in accordance with 6.8.2.3. A copy of these certificates shall be attached to the tank record of each tank, battery-vehicle or MEGC tested (see 4.3.2.1.7). 10 In special cases and with the agreement of the expert approved by the competent authority, the hydraulic pressure test may be replaced by a pressure test using another liquid or gas, where such an operation does not present any danger. - 470 - 6.8.2.5 Marking 6.8.2.5.1 Every tank shall be fitted with a corrosion-resistant metal plate permanently attached to the tank in a place readily accessible for inspection. The following particulars at least shall be marked on the plate by stamping or by any other similar method. These particulars may be engraved directly on the walls of the shell itself, if the walls are so reinforced that the strength of the shell is not impaired13: - approval number; - manufacturer’s name or mark; - manufacturer’s serial number; - year of manufacture; - test pressure (gauge pressure); - external design pressure (see 6.8.2.1.7); - capacity of the shell – in the case of multiple-compartment shells, the capacity of each compartment –, followed by the symbol "S" when the shells or the compartments of more than 7 500 litres are divided by surge plates into sections of not more than 7 500 litres capacity; - design temperature (only if above +50 ºC or below -20 ºC); - date and type of the most recent test: "month, year" followed by a "P" when the test is the initial test or a periodic test in accordance with 6.8.2.4.1 and 6.8.2.4.2, or "month, year" followed by an "L" when the test is an intermediate leakproofness test in accordance with 6.8.2.4.3; - stamp of the expert who carried out the tests; - material of the shell and reference to materials standards, if available and, where appropriate, the protective lining; - test pressure on the shell as a whole and test pressure by compartment in MPa or bar (gauge pressure) where the pressure by compartment is less than the pressure on the shell. In addition, the maximum working pressure allowed shall be inscribed on pressure-filled or pressure-discharge tanks. 6.8.2.5.2 The following particulars shall be inscribed on the The following particulars shall be inscribed on tank-vehicle (on the tank itself or on plates)13: the tank-container (on the tank itself or on plates)13: - name of owner or operator; - names of owner and of operator; - unladen mass of the tank-vehicle; and - capacity of the shell; - maximum permissible mass of the tank- tare; vehicle. The following particulars shall be inscribed on a demountable tank (on the tank itself or on plates)13: 13 - name of owner or operator; - "demountable tank"; - tare of the tank; - maximum permissible gross mass of the tank; - for the substances according to 4.3.4.1.3, the proper shipping name of the substance(s) Add the units of measurement after the numerical values. - 471 - maximum permissible gross mass; for the substances according to 4.3.4.1.3, the proper shipping name of the substance(s) accepted for carriage; - tank code according to 4.3.4.1.1; and - for substances other than those according to 4.3.4.1.3, the alphanumeric codes of all special provisions TC and TE which are shown in column (13) of Table A of Chapter 3.2 for the substances to be carried in the tank. accepted for carriage; - tank code according to 4.3.4.1.1; and - for substances other than those according to 4.3.4.1.3, the alphanumeric codes of all special provisions TC and TE which are shown in column (13) of Table A of Chapter 3.2 for the substances to be carried in the tank. 6.8.2.6 Requirements for tanks which are designed, constructed and tested according to referenced standards NOTE: Persons or bodies identified in standards as having responsibilities in accordance with ADR shall meet the requirements of ADR. 6.8.2.6.1 Design and construction The standards referenced in the table below shall be applied for the issue of type approvals as indicated in column (4) to meet the requirements of Chapter 6.8 referred to in column (3). The requirements of Chapter 6.8 referred to in column (3) shall prevail in all cases. Column (5) gives the latest date when existing type approvals shall be withdrawn according to 1.8.7.2.4 or 6.8.2.3.3; if no date is shown the type approval remains valid until it expires. Since 1 January 2009 the use of the referenced standards has been mandatory. Exceptions are dealt with in 6.8.2.7 and 6.8.3.7. If more than one standard is referenced for the application of the same requirements, only one of them shall be applied, but in full unless otherwise specified in the table below. The scope of application of each standard is defined in the scope clause of the standard unless otherwise specified in the Table below. Reference Title of document Applicable subsections and paragraphs (1) For all tanks EN 14025:2003 + AC:2005 (2) (3) EN 14025:2008 Tanks for the transport of dangerous goods – Metallic pressure tanks – Design and construction Tanks for the transport of dangerous goods – Metallic pressure tanks – Design and construction EN 14025:2013 6.8.2.1 6.8.2.1 and 6.8.3.1 Applicable for new type approvals or for renewals (4) Latest date for withdrawal of existing type approvals (5) Between 1 January 2005 and 30 June 2009 Between 1 July 2009 and 31 December 2016 Tanks for the transport of dangerous goods – 6.8.2.1 and 6.8.3.1 Until further Metallic pressure tanks – Design and notice construction EN 14432:2006 Tanks for the transport of dangerous goods – 6.8.2.2.1 Tank equipment for the transport of liquid Until further chemicals – Product discharge and air inlet notice valves EN 14433:2006 Tanks for the transport of dangerous goods – 6.8.2.2.1 Until further Tank equipment for the transport of liquid notice chemicals – Foot valves For tanks with a maximum working pressure not exceeding 50 kPa and intended for the carriage of substances for which a tank code with the letter "G" is given in column (12) of Table A of Chapter 3.2 EN 13094:2004 Tanks for the transport of dangerous goods – 6.8.2.1 Between 1 Metallic tanks with a working pressure not January 2005 and exceeding 0.5 bar – Design and construction 31 December 2009 EN 13094:2008 + Tanks for the transport of dangerous goods – 6.8.2.1 Until further AC:2008 Metallic tanks with a working pressure not notice exceeding 0.5 bar – Design and construction - 472 - Reference Applicable subsections and paragraphs Title of document (1) (2) For tanks for gases of Class 2 EN 12493:2001 Welded steel tanks for liquefied petroleum (except Annex C) gas (LPG) – Road tankers – Design and manufacture NOTE: Road tankers is to be understood in the meaning of "fixed tanks" and "demountable tanks" as per ADR. EN 12493:2008 (except Annex C) (3) Applicable for new type approvals or for renewals (4) 6.8.2.1 (with the exception of Between 6.8.2.1.17); 1 January 2005 6.8.2.4.1 (with the and 31 December exclusion of the 2010 leakproofness test); 6.8.2.5.1, 6.8.3.1 and 6.8.3.5.1 6.8.2.1 (with the exception of Between 6.8.2.1.17), 6.8.2.5, 1 January 2010 6.8.3.1, 6.8.3.5, and 31 December 6.8.5.1 to 6.8.5.3 2013 LPG equipment and accessories - Welded steel tanks for liquefied petroleum gas (LPG) – Road tankers – Design and manufacture NOTE: Road tankers is to be understood in the meaning of "fixed tanks" and "demountable tanks" as per ADR. LPG equipment and accessories –Welded 6.8.2.1 (with the Until 31 EN 12493:2008 + steel tanks for liquefied petroleum gas (LPG) exception of December 2013 A1:2012 (except 6.8.2.1.17), 6.8.2.5, Annex C) – Road tankers – Design and manufacture 6.8.3.1, 6.8.3.5, NOTE: Road tankers is to be understood in 6.8.5.1 to 6.8.5.3 the meaning of "fixed tanks" and "demountable tanks" as per ADR. LPG equipment and accessories – Welded 6.8.2.1, 6.8.2.5, EN 12493:2013 Until further steel tanks for liquefied petroleum gas (LPG) 6.8.3.1, 6.8.3.5, (except Annex C) notice 6.8.5.1 to 6.8.5.3 – Road tankers – Design and manufacture NOTE: Road tankers is to be understood in the meaning of "fixed tanks" and "demountable tanks" as per ADR. 6.8.3.2 (with the EN 12252:2000 Equipping of LPG road tankers Between exception of 1 January 2005 NOTE: Road tankers is to be understood in 6.8.3.2.3) and 31 December the meaning of "fixed tanks" and 2010 "demountable tanks" as per ADR. EN 12252:2005 + LPG equipment and accessories – Equipping 6.8.3.2 (with the A1:2008 of LPG road tankers exception of Until further 6.8.3.2.3) and NOTE: Road tankers is to be understood in notice 6.8.3.4.9 the meaning of "fixed tanks" and "demountable tanks" as per ADR. 6.8.2.1 (with the EN 13530-2:2002 Cryogenic vessels – Large transportable Between exception of vacuum insulated vessels – Part 2: Design, 1 January 2005 6.8.2.1.17), 6.8.2.4, fabrication, inspection and testing and 30 June 2007 6.8.3.1 and 6.8.3.4 6.8.2.1 (with the EN 13530-2:2002 + Cryogenic vessels – Large transportable Until further exception of A1:2004 vacuum insulated vessels – Part 2: Design, notice 6.8.2.1.17), 6.8.2.4, fabrication, inspection and testing 6.8.3.1 and 6.8.3.4 EN 14398-2:2003 Cryogenic vessels - Large transportable non- 6.8.2.1 (with the vacuum insulated vessels - Part 2: Design, exception of Between (except Table 1) fabrication, inspection and testing 6.8.2.1.17, 1 January 2005 and 31 December NOTE: This standard shall not be used for 6.8.2.1.19 and 2016 those gases which are carried at temperatures 6.8.2.1.20), 6.8.2.4, 6.8.3.1 and 6.8.3.4 below -100 ºC. Cryogenic vessels – Large transportable non- 6.8.2.1 (with the vacuum insulated vessels – Part 2: Design, exception of 6.8.2.1.17, Until further EN 14398-2:2003 + fabrication, inspection and testing notice A2:2008 NOTE: This standard shall not be used for 6.8.2.1.19 and those gases which are carried at temperatures 6.8.2.1.20), 6.8.2.4, 6.8.3.1 and 6.8.3.4 below -100 ºC. EN 14129:2014 LPG Equipment and accessories – Pressure 6.8.2.1.1 and Until further relief valves for LPG pressure vessels 6.8.3.2.9 notice EN 1626:2008 Cryogenic vessels – Valves for cryogenic Until further (except valve 6.8.2.4 and 6.8.3.4 notice service category B) - 473 - Latest date for withdrawal of existing type approvals (5) 31 December 2012 31 December 2014 31 December 2015 31 December 2012 Applicable for Latest date for new type withdrawal of Reference Title of document approvals or for existing type approvals renewals (1) (2) (3) (4) (5) For tanks intended for the carriage of liquid petroleum products and other dangerous substances of Class 3 which have a vapour pressure not exceeding 110 kPa at 50 °C and petrol, and which have no toxic or corrosive subsidiary hazard EN 13094:2004 Tanks for the transport of dangerous goods – 6.8.2.1 Between Metallic tanks with a working pressure not 1 January 2005 exceeding 0.5 bar – Design and construction and 31 December 2009 EN 13094:2008 + Tanks for the transport of dangerous goods – 6.8.2.1 Until further AC:2008 Metallic tanks with a working pressure not notice exceeding 0.5 bar – Design and construction EN 13082:2001 Tanks for transport of dangerous goods – 6.8.2.2 and Between Service equipment for tanks – Vapour transfer 6.8.2.4.1 1 January 2005 31 December 2014 valve and 30 June 2013 Tanks for transport of dangerous goods – EN 13082:2008 6.8.2.2 and Until further + A1:2012 notice Service equipment for tanks – Vapour transfer 6.8.2.4.1 valve EN 13308:2002 Tanks for transport of dangerous goods – 6.8.2.2 and Until further Service equipment for tanks – Non pressure 6.8.2.4.1 notice balanced footvalve EN 13314:2002 Tanks for transport of dangerous goods – 6.8.2.2 and Until further Service equipment for tanks – Fill hole cover 6.8.2.4.1 notice EN 13316:2002 Tanks for transport of dangerous goods – 6.8.2.2 and Until further Service equipment for tanks –Pressure 6.8.2.4.1 notice balanced footvalve Tanks for transport of dangerous goods – EN 13317:2002 6.8.2.2 and Service equipment for tanks – Manhole cover 6.8.2.4.1 (except for the figure and table B.2 assembly Between in Annex B) (The 1 January 2005 material shall meet 31 December 2012 and 31 December the requirements of 2010 standard EN 13094:2004, Clause 5.2) EN 13317:2002 + Tanks for transport of dangerous goods – 6.8.2.2 and Until further A1:2006 Service equipment for tanks – Manhole cover 6.8.2.4.1 notice assembly EN 14595:2005 Tanks for transport of dangerous goods 6.8.2.2 and Until further Service equipment for tanks - Pressure and 6.8.2.4.1 notice vacuum breather vent EN 16257:2012 Tanks for the transport of dangerous goods – 6.8.2.2.1 and Until further Service equipment – Footvalve sizes other 6.8.2.2.2 notice than 100 mm dia (nom) Applicable subsections and paragraphs 6.8.2.6.2 Inspection and test The standard referenced in the table below shall be applied for the inspection and test of tanks as indicated in column (4) to meet the requirements of Chapter 6.8 referred to in column (3) which shall prevail in all cases. The use of a referenced standard is mandatory. The scope of application of each standard is defined in the scope clause of the standard unless otherwise specified in the Table below. - 474 - Reference Title of document (1) EN 12972:2007 6.8.2.7 (2) Tanks for transport of dangerous goods – Testing, inspection and marking of metallic tanks Applicable subsections and paragraphs (3) 6.8.2.4 6.8.3.4 Applicable (4) Until further notice Requirements for tanks which are not designed, constructed and tested according to referenced standards To reflect scientific and technical progress or where no standard is referenced in 6.8.2.6 or to deal with specific aspects not addressed in a standard referenced in 6.8.2.6, the competent authority may recognize the use of a technical code providing the same level of safety. Tanks shall, however, comply with the minimum requirements of 6.8.2. The competent authority shall transmit to the secretariat of UNECE a list of the technical codes that it recognises. The list should include the following details: name and date of the code, purpose of the code and details of where it may be obtained. The secretariat shall make this information publicly available on its website. A standard which has been adopted for reference in a future edition of the ADR may be approved by the competent authority for use without notifying the UNECE secretariat. For testing, inspection and marking, the applicable standard referenced in 6.8.2.6 may also be used. 6.8.3 Special requirements applicable to Class 2 6.8.3.1 Construction of shells 6.8.3.1.1 Shells intended for the carriage of compressed or liquefied gases or dissolved gases shall be made of steel. In the case of weldless shells, by derogation from 6.8.2.1.12 a minimum elongation at fracture of 14% and also a stress  lower than or equal to limits hereafter given according to the material may be accepted: (a) When the ratio Re/Rm (of the minimum guaranteed characteristics after heat treatment) is higher than 0.66 without exceeding 0.85:   0.75 Re; (b) When the ratio Re/Rm (of the minimum guaranteed characteristics after heat treatment) is higher than 0.85:   0.5 Rm. 6.8.3.1.2 The requirements of 6.8.5 apply to the materials and construction of welded shells. 6.8.3.1.3 (Reserved) Construction of battery-vehicles and MEGCs 6.8.3.1.4 Cylinders, tubes, pressure drums and bundles of cylinders, as elements of a battery-vehicle or MEGC, shall be constructed in accordance with Chapter 6.2. NOTE 1: Bundles of cylinders which are not elements of a battery-vehicle or of a MEGC shall be subject to the requirements of Chapter 6.2. NOTE 2: Tanks as elements of battery-vehicles and MEGCs shall be constructed in accordance with 6.8.2.1 and 6.8.3.1. NOTE 3: Demountable tanks14 are not to be considered elements of battery-vehicles or MEGCs. 14 For the definition of "demountable tank" see 1.2.1. - 475 - 6.8.3.1.5 Elements and their fastenings shall be capable of absorbing under the maximum permissible load the forces defined in 6.8.2.1.2. Under each force the stress at the most severely stressed point of the element and its fastenings shall not exceed the value defined in 6.2.5.3 for cylinders, tubes, pressure drums and bundles of cylinders and for tanks the value of  defined in 6.8.2.1.16. 6.8.3.2 Items of equipment 6.8.3.2.1 The discharge pipes of tanks shall be capable of being closed by blank flanges or some other equally reliable device. For tanks intended for the carriage of refrigerated liquefied gases, these blank flanges or other equally reliable devices may be fitted with pressure-release openings of a maximum diameter of 1.5 mm. 6.8.3.2.2 Shells intended for the carriage of liquefied gases may be provided with, in addition to the openings prescribed in 6.8.2.2.2 and 6.8.2.2.4, openings for the fitting of gauges, thermometers, manometers and with bleed holes, as required for their operation and safety. 6.8.3.2.3 The internal stop-valve of all filling and all discharge openings of tanks with a capacity greater than 1 m3 intended for the carriage of liquefied flammable or toxic gases shall be instant-closing and shall close automatically in the event of an unintended movement of the tank or in the event of fire. It shall also be possible to operate the internal stop-valve by remote control. However on tanks intended for the carriage of liquefied non-toxic flammable gases, the internal stop-valve with remote control may be replaced by a non-return valve for filling openings into the vapour phase of the tank only. The non-return valve shall be positioned internally in the tank, be spring loaded so that the valve is closed if the pressure in the filling line is equal to or lower than the pressure in the tank and be equipped with appropriate sealing15. 6.8.3.2.4 All openings, other than those accommodating safety valves and closed bleed holes, of tanks intended for the carriage of liquefied flammable and/or toxic gases shall, if their nominal diameter is more than 1.5 mm, shall be equipped with an internal shut-off device. 6.8.3.2.5 Notwithstanding the requirements of 6.8.2.2.2, 6.8.3.2.3 and 6.8.3.2.4, tanks intended for the carriage of refrigerated liquefied gases may be equipped with external devices in place of internal devices if the external devices afford protection against external damage at least equivalent to that afforded by the wall of the shell. 6.8.3.2.6 If the tanks are equipped with gauges in direct contact with the substance carried, the gauges shall not be made of a transparent material. If there are thermometers, they shall not project directly into the gas or liquid through the shell. 6.8.3.2.7 Filling and discharge openings situated in the upper part of tanks shall be equipped with, in addition to what is prescribed in 6.8.3.2.3, a second, external, closing device. This device shall be capable of being closed by a blank flange or some other equally reliable device. 6.8.3.2.8 Safety valves shall meet the requirements of 6.8.3.2.9 to 6.8.3.2.12 below: 15 The use of metal to metal sealing is not permitted. - 476 - 6.8.3.2.9 Tanks intended for the carriage of compressed or liquefied gases or dissolved gases, may be fitted with spring-loaded safety valves. These valves shall be capable of opening automatically under a pressure between 0.9 and 1.0 times the test pressure of the tank to which they are fitted. They shall be of such a type as to resist dynamic stresses, including liquid surge. The use of dead weight or counter weight valves is prohibited. The required capacity of the safety valves shall be calculated in accordance with the formula contained in 6.7.3.8.1.1. 6.8.3.2.10 Where tanks are intended for carriage by sea, the requirements of 6.8.3.2.9 shall not prohibit the fitting of safety valves conforming to the IMDG Code. 6.8.3.2.11 Tanks intended for the carriage of refrigerated liquefied gases shall be equipped with two or more independent safety valves capable of opening at the maximum working pressure indicated on the tank. Two of these safety valves shall be individually sized to allow the gases formed by evaporation during normal operation to escape from the tank in such a way that the pressure does not at any time exceed by more than 10% the working pressure indicated on the tank. One of the safety valves may be replaced by a bursting disc which shall be such as to burst at the test pressure. In the event of loss of the vacuum in a double-walled tank, or of destruction of 20% of the insulation of a single-walled tank, the combination of the pressure relief devices shall permit an outflow such that the pressure in the shell cannot exceed the test pressure. The provisions of 6.8.2.1.7 shall not apply to vacuum-insulated tanks. 6.8.3.2.12 These pressure relief devices of tanks intended for the carriage of refrigerated liquefied gases shall be so designed as to function faultlessly even at their lowest working temperature. The reliability of their operation at that temperature shall be established and checked either by testing each device or by testing a specimen device of each design-type. 6.8.3.2.13 The valves of demountable tanks that can be rolled shall be provided with protective caps. Thermal insulation 6.8.3.2.14 If tanks intended for the carriage of liquefied gases are equipped with thermal insulation, such insulation shall consist of either: - a sun shield covering not less than the upper third but not more than the upper half of the tank surface and separated from the shell by an air space at least 4 cm across; or - a complete cladding, of adequate thickness, of insulating materials. 6.8.3.2.15 Tanks intended for the carriage of refrigerated liquefied gases shall be thermally insulated. Thermal insulation shall be ensured by means of a continuous sheathing. If the space between the shell and the sheathing is under vacuum (vacuum insulation), the protective sheathing shall be so designed as to withstand without deformation an external pressure of at least 100 kPa (1 bar) (gauge pressure). By derogation from the definition of "calculation pressure" in 1.2.1, external and internal reinforcing devices may be taken into account in the calculations. If the sheathing is so closed as to be gas-tight, a device shall be provided to prevent any dangerous pressure from developing in the insulating layer in the event of inadequate gas-tightness of the shell or of its items of equipment. The device shall prevent the infiltration of moisture into the heat-insulating sheath. 6.8.3.2.16 Tanks intended for the carriage of liquefied gases having a boiling point below -182 C at atmospheric pressure shall not include any combustible material either in the thermal insulation or in the means of attachment. The means of attachment for vacuum insulated tanks may, with the approval of the competent authority, contain plastics substances between the shell and the sheathing. 6.8.3.2.17 By derogation from the requirements of 6.8.2.2.4 shells intended for the carriage of refrigerated liquefied gases need not have an inspection opening. - 477 - Items of equipment for battery-vehicles and MEGCs 6.8.3.2.18 Service and structural equipment shall be configured or designed to prevent damage that could result in the release of the pressure receptacle contents during normal conditions of handling and carriage. When the connection between the frame of the battery-vehicle or MEGC and the elements allows relative movement between the sub-assemblies, the equipment shall be so fastened as to permit such movement without damage to working parts. Manifold piping leading to shut-off valves shall be sufficiently flexible to protect the valves and the piping from shearing, or releasing the pressure receptacle contents. The filling and discharge devices (including flanges or threaded plugs) and any protective caps shall be capable of being secured against unintended opening. 6.8.3.2.19 In order to avoid any loss of content in the event of damage, the manifolds, the discharge fittings (pipe sockets, shut-off devices), and the stop-valves shall be protected or arranged from being wrenched off by external forces or designed to withstand them. 6.8.3.2.20 The manifold shall be designed for service in a temperature range of -20 C to +50 C. The manifold shall be designed, constructed and installed so as to avoid the risk of damage due to thermal expansion and contraction, mechanical shock and vibration. All piping shall be of suitable metallic material. Welded pipe joints shall be used wherever possible. Joints in copper tubing shall be brazed or have an equally strong metal union. The melting point of brazing materials shall be no lower than 525ºC. The joints shall not decrease the strength of tubing as may happen when cutting threads. 6.8.3.2.21 Except for UN No.1001 acetylene, dissolved, the permissible maximum stress  of the manifolding arrangement at the test pressure of the receptacles shall not exceed 75% of the guaranteed yield strength of the material. The necessary wall thickness of the manifolding arrangement for the carriage of UN No.1001 acetylene, dissolved shall be calculated according to an approved code of practice. NOTE: For the yield strength, see 6.8.2.1.11. The basic requirements of this paragraph shall be deemed to have been complied with if the following standards are applied: (Reserved). 6.8.3.2.22 By derogation from the requirements of 6.8.3.2.3, 6.8.3.2.4 and 6.8.3.2.7, for cylinders, tubes, pressure drums and bundles of cylinders (frames) forming a battery-vehicle or MEGC, the required closing devices may be provided for within the manifolding arrangement. 6.8.3.2.23 If one of the elements is equipped with a safety valve and shut-off devices are provided between the elements, every element shall be so equipped. 6.8.3.2.24 The filling and discharge devices may be affixed to a manifold. 6.8.3.2.25 Each element, including each individual cylinder of a bundle, intended for the carriage of toxic gases, shall be capable of being isolated by a shut-off valve. 6.8.3.2.26 Battery-vehicles or MEGCs intended for the carriage of toxic gases shall not have safety valves, unless the safety valves are preceded by a bursting disc. In the latter case, the arrangement of the bursting disc and safety valve shall be satisfactory to the competent authority. 6.8.3.2.27 When battery-vehicles or MEGCs are intended for carriage by sea, the requirements of 6.8.3.2.26 shall not prohibit the fitting of safety valves conforming to the IMDG Code. 6.8.3.2.28 Receptacles which are elements of a battery-vehicle or MEGC intended for the carriage of flammable gases shall be combined in groups of not more than 5 000 litres which are capable of being isolated by a shut-off valve. Each element of a battery-vehicle or MEGC intended for the carriage of flammable gases, when consisting of tanks conforming to this Chapter, shall be capable of being isolated by a shut-off valve. - 478 - 6.8.3.3 Type approval No special requirements. 6.8.3.4 Inspections and tests 6.8.3.4.1 The materials of every welded shell with the exception of cylinders, tubes, pressure drums and cylinders as part of bundles of cylinders which are elements of a battery-vehicle or of a MEGC shall be tested according to the method described in 6.8.5. 6.8.3.4.2 The basic requirements for the test pressure are given in 4.3.3.2.1 to 4.3.3.2.4 and the minimum test pressures are given in the table of gases and gas mixtures in 4.3.3.2.5. 6.8.3.4.3 The first hydraulic pressure test shall be carried out before thermal insulation is placed in position. When the shell, its fittings, piping and items of equipment have been tested separately, the tank shall be subjected to a leakproofness test after assembly. 6.8.3.4.4 The capacity of each shell intended for the carriage of compressed gases filled by mass, liquefied gases or dissolved gases shall be determined, under the supervision of an expert approved by the competent authority, by weighing or volumetric measurement of the quantity of water which fills the shell; the measurement of shell capacity shall be accurate to within 1%. Determination by a calculation based on the dimensions of the shell is not permitted. The maximum filling masses allowed in accordance with packing instruction P200 or P203 in 4.1.4.1 as well as 4.3.3.2.2 and 4.3.3.2.3 shall be prescribed by an approved expert. 6.8.3.4.5 Checking of the welds shall be carried out in accordance with the =1 requirements of 6.8.2.1.23. 6.8.3.4.6 By derogation from the requirements of 6.8.2.4.2, the periodic inspections shall take place: at least after six years at least after eight years of service and thereafter at least every 12 years in the case of tanks intended for the carriage of refrigerated liquefied gases. The intermediate inspections according to 6.8.2.4.3 shall be carried out at least six years after each periodic inspection. A leakproofness test or an intermediate inspection according to 6.8.2.4.3 may be performed, at the request of the competent authority, between any two successive periodic inspections. 6.8.3.4.7 In the case of vacuum-insulated tanks, the hydraulic-pressure test and the check of the internal condition may, with the consent of the approved expert, be replaced by a leakproofness test and measurement of the vacuum. 6.8.3.4.8 If, at the time of periodic inspections, openings have been made in shells intended for the carriage of refrigerated liquefied gases, the method by which they are hermetically closed before the shells are returned to service shall be approved by the approved expert and shall ensure the integrity of the shell. 6.8.3.4.9 Leakproofness tests of tanks intended for the carriage of gases shall be performed at a pressure of not less than: - For compressed gases, liquefied gases and dissolved gases: 20% of the test pressure; - For refrigerated liquefied gases: 90% of the maximum working pressure. - 479 - Inspections and tests for battery-vehicles and MEGCs 6.8.3.4.10 The elements and items of equipment of each battery-vehicle or MEGC shall be inspected and tested either together or separately before being put into service for the first time (initial inspection and test). Thereafter battery-vehicles or MEGCs the elements of which are receptacles shall be inspected at not more than five-year intervals. Battery-vehicles and MEGCs the elements of which are tanks shall be inspected according to 6.8.3.4.6. An exceptional inspection and test shall be performed regardless of the last periodic inspection and test when necessary according to 6.8.3.4.14. 6.8.3.4.11 The initial inspection shall include: - a check of conformity to the approved type; - a check of the design characteristics; - an examination of the internal and external conditions; - a hydraulic pressure test10 at the test pressure indicated on the plate prescribed in 6.8.3.5.10; - a leakproofness test at the maximum working pressure; and - a check of satisfactory operation of the equipment. When the elements and their fittings have been pressure-tested separately, they shall be subjected together after assembly to a leakproofness test. 6.8.3.4.12 Cylinders, tubes and pressure drums and cylinders as part of bundles of cylinders shall be tested according to packing instruction P200 or P203 in 4.1.4.1. The test pressure of the manifold of the battery-vehicle or MEGC shall be the same as that of the elements of the battery-vehicle or MEGC. The pressure test of the manifold may be performed as a hydraulic test or by using another liquid or gas with the agreement of the competent authority or its authorised body. By derogation from this requirement, the test pressure for the manifold of batteryvehicle or MEGC shall not be less than 300 bar for UN No. 1001 acetylene, dissolved. 6.8.3.4.13 The periodic inspection shall include a leakproofness test at the maximum working pressure and an external examination of the structure, the elements and the service equipment without disassembling. The elements and the piping shall be tested at the periodicity defined in packing instruction P200 of 4.1.4.1 and in accordance with the requirements of 6.2.1.6 and 6.2.3.5 respectively. When the elements and equipment have been pressure-tested separately, they shall be subjected together after assembly to a leakproofness test. 6.8.3.4.14 An exceptional inspection and test is necessary when the battery-vehicle or MEGC shows evidence of damaged or corroded areas, or leakage, or any other conditions, that indicate a deficiency that could affect the integrity of the battery-vehicle or MEGC. The extent of the exceptional inspection and test and, if deemed necessary, the disassembling of elements shall depend on the amount of damage or deterioration of the battery-vehicle or MEGC. It shall include at least the examinations required under 6.8.3.4.15. 6.8.3.4.15 The examinations shall ensure that: (a) The elements are inspected externally for pitting, corrosion, or abrasions, dents, distortions, defects in welds or any other conditions, including leakage, that might render the batteryvehicles or MEGCs unsafe for transport; (b) The piping, valves, and gaskets are inspected for corroded areas, defects, and other conditions, including leakage, that might render battery-vehicles or MEGCs unsafe for filling, discharge or transport; 10 In special cases and with the agreement of the expert approved by the competent authority, the hydraulic pressure test may be replaced by a pressure test using another liquid or gas, where such an operation does not present any danger. - 480 - 6.8.3.4.16 (c) Missing or loose bolts or nuts on any flanged connection or blank flange are replaced or tightened; (d) All emergency devices and valves are free from corrosion, distortion and any damage or defect that could prevent their normal operation. Remote closure devices and self-closing stop-valves shall be operated to demonstrate proper operation; (e) Required markings on the battery-vehicles or MEGCs are legible and in accordance with the applicable requirements; and (f) Any framework, supports and arrangements for lifting the battery-vehicles or MEGCs are in satisfactory condition. The tests, inspections and checks in accordance with 6.8.3.4.10 to 6.8.3.4.15 shall be carried out by the expert approved by the competent authority. Certificates shall be issued showing the results of these operations, even in the case of negative results. These certificates shall refer to the list of the substances permitted for carriage in this battery-vehicle or MEGC in accordance with 6.8.2.3.1. A copy of these certificates shall be attached to the tank record of each tank, battery-vehicle or MEGC tested (see 4.3.2.1.7). 6.8.3.5 Marking 6.8.3.5.1 The following additional particulars shall be marked by stamping or by any other similar method on the plate prescribed in 6.8.2.5.1, or directly on the walls of the shell itself if the walls are so reinforced that the strength of the tank is not impaired. 6.8.3.5.2 On tanks intended for the carriage of only one substance: - the proper shipping name of the gas and, in addition for gases classified under an n.o.s. entry, the technical name16; This indication shall be supplemented: 6.8.3.5.3 - in the case of tanks intended for the carriage of compressed gases filled by volume (pressure), by an indication of the maximum filling pressure at 15 °C permitted for the tank; and - in the case of tanks intended for the carriage of compressed gases filled by mass, and of liquefied gases, refrigerated liquefied gases or dissolved gases by an indication of the maximum permissible load mass in kg and of the filling temperature if below –20 °C. On multipurpose tanks: - the proper shipping names of the gases and, in addition for gases classified under an n.o.s. entry, the technical name of the gases 16 for whose carriage the tank is approved. 16 Instead of the proper shipping name or, if applicable, of the proper shipping name of the n.o.s. entry followed by the technical name, the use of the following names is permitted: - for UN No. 1078 refrigerant gas, n.o.s: mixture F1, mixture F2, mixture F3; - for UN No. 1060 methylacetylene and propadiene mixtures, stabilized: mixture P1, mixture P2; - for UN No. 1965 hydrocarbon gas mixture, liquefied, n.o.s: mixture A, mixture A01, mixture A02, mixture A0, mixture A1, mixture B1, mixture B2, mixture B, mixture C. The names customary in the trade and mentioned in 2.2.2.3, Classification code 2F, UN No. 1965, Note 1 may be used only as a complement; - for UN No. 1010 Butadienes, stabilized: 1,2-Butadiene, stabilized, 1,3-Butadiene, stabilized. - 481 - These particulars shall be supplemented by an indication of the maximum permissible load mass in kg for each gas. 6.8.3.5.4 On tanks intended for the carriage of refrigerated liquefied gases: - 6.8.3.5.5 On tanks equipped with thermal insulation: - 6.8.3.5.6 the maximum working pressure allowed. the inscription "thermally insulated" or "thermally insulated by vacuum". In addition to the particulars prescribed in In addition to the particulars prescribed in 6.8.2.5.2, the following shall be inscribed on the 6.8.2.5.2, the following shall be inscribed on the tank-vehicle (on the tank itself or on plates)13: tank-container (on the tank itself or on plates)13: (a) (b) (c) - the tank code according to the certificate (see 6.8.2.3.1) with the actual test pressure of the tank; - the inscription: "minimum filling temperature allowed: …"; where the tank is intended for the carriage of one substance only: -2 the proper shipping name of the gas and, in addition for gases classified under an n.o.s. entry, the technical name16; - for compressed gases which are filled by mass, and for liquefied gases, refrigerated liquefied gases or dissolved gases, the maximum permissible load mass in kg; where the tank is a multipurpose tank: - (d) the proper shipping name of the gas and, for gases classified under an n.o.s. entry, the technical name16 of all gases to whose carriage the tank is assigned with an indication of the maximum permissible load mass in kg for each of them; where the shell is equipped with thermal insulation: - the inscription "thermally insulated" (or "thermally insulated by vacuum"), in an official language of the country of registration and also, if that language is not English, French or German, in English, French or German, unless any agreements concluded between the countries concerned in the transport operation provide otherwise. 6.8.3.5.7 (Reserved) 6.8.3.5.8 These particulars shall not be required in the case of a vehicle carrying demountable tanks. 6.8.3.5.9 (Reserved) 13 Add the units of measurement after the numerical values. Instead of the proper shipping name or, if applicable, of the proper shipping name of the n.o.s. entry followed by the technical name, the use of the following names is permitted: 16 - for UN No. 1078 refrigerant gas, n.o.s: mixture F1, mixture F2, mixture F3; - for UN No. 1060 methylacetylene and propadiene mixtures, stabilized: mixture P1, mixture P2; - for UN No. 1965 hydrocarbon gas mixture, liquefied, n.o.s: mixture A, mixture A01, mixture A02, mixture A0, mixture A1, mixture B1, mixture B2, mixture B, mixture C. The names customary in the trade and mentioned in 2.2.2.3, Classification code 2F, UN No. 1965, Note 1 may be used only as a complement; - for UN No. 1010 Butadienes, stabilized: 1,2-Butadiene, stabilized, 1,3-Butadiene, stabilized. - 482 - Marking of battery-vehicles and MEGCs 6.8.3.5.10 6.8.3.5.11 Every battery-vehicle and every MEGC shall be fitted with a corrosion-resistant metal plate permanently attached in a place readily accessible for inspection. The following particulars at least shall be marked on the plate by stamping or by any other similar method13 - approval number; - manufacturer’s name or mark; - manufacturer’s serial number; - year of manufacture; - test pressure (gauge pressure) - design temperature (only if above +50 °C or below -20 °C); - date (month and year) of initial test and most recent periodic test in accordance with 6.8.3.4.10 to 6.8.3.4.13; - stamp of the expert who carried out the tests. The following particulars shall be inscribed on The following particulars shall be inscribed the battery-vehicle itself or on a plate13: either on the MEGC itself or on a plate13: - names of owner or of operator; - names of owner and of operator; - number of elements; - number of elements; - total capacity of the elements; - total capacity of the elements; and for battery-vehicles filled by mass: - maximum permissible laden mass; - unladen mass; - - maximum permissible mass. the tank code according to the certificate of approval (see 6.8.2.3.1) with the actual test pressure of the MEGC; - the proper shipping name of the gases, and in addition, for gases classified under an n.o.s. entry, the technical name16 of the gases for whose carriage the MEGC is used; and for MEGCs filled by mass: - tare. 13 Add the units of measurement after the numerical values. Instead of the proper shipping name or, if applicable, of the proper shipping name of the n.o.s. entry followed by the technical name, the use of the following names is permitted: 16 - for UN No. 1078 refrigerant gas, n.o.s: mixture F1, mixture F2, mixture F3; - for UN No. 1060 methylacetylene and propadiene mixtures, stabilized: mixture P1, mixture P2; - for UN No. 1965 hydrocarbon gas mixture, liquefied, n.o.s: mixture A, mixture A01, mixture A02, mixture A0, mixture A1, mixture B1, mixture B2, mixture B, mixture C. The names customary in the trade and mentioned in 2.2.2.3, Classification code 2F, UN No. 1965, Note 1 may be used only as a complement; - for UN No. 1010 Butadienes, stabilized: 1,2-Butadiene, stabilized, 1,3-Butadiene, stabilized. - 483 - 6.8.3.5.12 The frame of a battery-vehicle or MEGC shall bear near the filling point a plate specifying: - the maximum filling pressure13 at 15 °C allowed for elements intended for compressed gases; - the proper shipping name of the gas in accordance with Chapter 3.2 and, in addition for gases classified under an n.o.s. entry, the technical name16; and, in addition, in the case of liquefied gases: 6.8.3.5.13 the permissible maximum load per element13. Cylinders, tubes and pressure drums, and cylinders as part of bundles of cylinders, shall be marked according to 6.2.2.7. These receptacles need not be labelled individually with the danger labels as required in Chapter 5.2. Battery-vehicles and MEGCs shall be placarded and marked according to Chapter 5.3. 6.8.3.6 Requirements for battery-vehicles and MEGCs which are designed, constructed and tested according to referenced standards NOTE: Persons or bodies identified in standards as having responsibilities in accordance with ADR shall meet the requirements of ADR. The standard referenced in the table below shall be applied for the issue of type approvals as indicated in column (4) to meet the requirements of Chapter 6.8 referred to in column (3). The requirements of Chapter 6.8 referred to in column (3) shall prevail in all cases. Column (5) gives the latest date when existing type approvals shall be withdrawn according to 1.8.7.2.4; if no date is shown the type approval remains valid until it expires. Since 1 January 2009 the use of the referenced standards has been mandatory. Exceptions are dealt with in 6.8.3.7 If more than one standard is referenced for the application of the same requirements, only one of them shall be applied, but in full unless otherwise specified in the table below. The scope of application of each standard is defined in the scope clause of the standard unless otherwise specified in the Table below. 13 Add the units of measurements after the numerical values. Instead of the proper shipping name or, if applicable, of the proper shipping name of the n.o.s. entry followed by the technical name, the use of the following names is permitted: 16 - for UN No. 1078 refrigerant gas, n.o.s: mixture F1, mixture F2, mixture F3; - for UN No. 1060 methylacetylene and propadiene mixtures, stabilized: mixture P1, mixture P2; - for UN No. 1965 hydrocarbon gas mixture, liquefied, n.o.s: mixture A, mixture A01, mixture A02, mixture A0, mixture A1, mixture B1, mixture B2, mixture B, mixture C. The names customary in the trade and mentioned in 2.2.2.3, Classification code 2F, UN No. 1965, Note 1 may be used only as a complement; - for UN No. 1010 Butadienes, stabilized: 1,2-Butadiene, stabilized, 1,3-Butadiene, stabilized. - 484 - Reference Title of document (2) (3) Transportable gas cylinders – Battery vehicles 6.8.3.1.4 and – Design, manufacture, identification and 6.8.3.1.5, testing 6.8.3.2.18 to 6.8.3.2.26, 6.8.3.4.10 to 6.8.3.4.12 and 6.8.3.5.10 to 6.8.3.5.13 (1) EN 13807:2003 6.8.3.7 Applicable subsections and paragraphs Applicable for new type approvals or for renewals (4) Latest date for withdrawal of existing type approvals (5) Until further notice Requirements for battery-vehicles and MEGCs which are not designed, constructed and tested according to referenced standards To reflect scientific and technical progress or where no standard is referenced in 6.8.3.6 or to deal with specific aspects not addressed in a standard referenced in 6.8.3.6, the competent authority may recognize the use of a technical code providing the same level of safety. Battery-vehicles and MEGCs shall, however, comply with the minimum requirements of 6.8.3. In the type approval the issuing body shall specify the procedure for periodic inspections if the standards referenced in 6.2.2, 6.2.4 or 6.8.2.6 are not applicable or shall not be applied. The competent authority shall transmit to the secretariat of UNECE a list of the technical codes that it recognises. The list should include the following details: name and date of the code, purpose of the code and details of where it may be obtained. The secretariat shall make this information publicly available on its website. A standard which has been adopted for reference in a future edition of the ADR may be approved by the competent authority for use without notifying the UNECE secretariat. 6.8.4 Special provisions NOTE 1: For liquids having a flash-point of not more than 60 °C and for flammable gases, see also 6.8.2.1.26, 6.8.2.1.27 and 6.8.2.2.9. NOTE 2: For requirements for tanks subjected to a pressure test of not less than 1 MPa (10 bar) or for tanks intended for the carriage of refrigerated liquefied gases, see 6.8.5. When they are shown under an entry in Column (13) of Table A of Chapter 3.2, the following special provisions apply: (a) Construction (TC) TC1 The requirements of 6.8.5 are applicable to the materials and construction of these shells. TC2 Shells, and their items of equipment, shall be made of aluminium not less than 99.5% pure or of suitable steel not liable to cause hydrogen peroxide to decompose. Where shells are made of aluminium not less than 99.5% pure, the wall thickness need not exceed 15 mm, even where calculation in accordance with 6.8.2.1.17 gives a higher value. TC3 The shells shall be made of austenitic steel. TC4 Shells shall be provided with an enamel or equivalent protective lining if the material of the shell is attacked by UN No. 3250 chloroacetic acid. TC5 Shells shall be provided with a lead lining not less than 5 mm thick or an equivalent lining. - 485 - TC6 Where the use of aluminium is necessary for tanks, such tanks shall be made of aluminium not less than 99.5% pure; the wall thickness need not exceed 15 mm even where calculation in accordance with 6.8.2.1.17 gives a higher value. TC7 The effective minimum thickness of the shell shall not be less than 3 mm. TC8 The shells shall be made of aluminium or aluminium alloy. (b) Items of equipment (TE) TE1 (Deleted) TE2 (Deleted) TE3 Tanks shall in addition meet the following requirements. The heating device shall not penetrate into, but shall be exterior to the shell. However, a pipe used for extracting the phosphorus may be equipped with a heating jacket. The device heating the jacket shall be so regulated as to prevent the temperature of the phosphorus from exceeding the filling temperature of the shell. Other piping shall enter the shell in its upper part; openings shall be situated above the highest permissible level of the phosphorus and be capable of being completely enclosed under lockable caps. The tank shall be equipped with a gauging system for verifying the level of the phosphorus and, if water is used as a protective agent, with a fixed gauge mark showing the highest permissible level of the water. TE4 Shells shall be equipped with thermal insulation made of materials which are not readily flammable. If shells are equipped with thermal insulation, such insulation shall be made of materials which are not readily flammable. TE5 TE6 Tanks may be equipped with a device of a design which precludes its obstruction by the substance carried and which prevents leakage and the build-up of excess overpressure or underpressure inside the shell. TE7 The shell-discharge system shall be equipped with two mutually independent shut-off devices mounted in series, the first taking the form of a quick-closing internal stop-valve of an approved type and the second that of an external stop-valve, one at each end of the discharge pipe. A blank flange, or another device providing the same measure of security, shall also be fitted at the outlet of each external stop-valve. The internal stop-valve shall be such that if the pipe is wrenched off the stop-valve will remain integral with the shell and in the closed position. TE8 The connections to the external pipe-sockets of tanks shall be made of materials not liable to cause decomposition of hydrogen peroxide. TE9 Tanks shall be fitted in their upper part with a shut-off device preventing any build-up of excess pressure inside the shell due to the decomposition of the substances carried, any leakage of liquid, and any entry of foreign matter into the shell. TE10 The shut-off devices of tanks shall be so designed as to preclude obstruction of the devices by the solidified substance during carriage. Where tanks are sheathed in thermally-insulating material, the material shall be of an inorganic nature and entirely free from combustible matter. TE11 Shells and their service equipment shall be so designed as to prevent the entry of foreign matter, leakage of liquid or any building up of dangerous excess pressure inside the shell due to the decomposition of the substances carried. A safety valve preventing the entry of foreign matter also fulfils this provision. TE12 Tanks shall be equipped with thermal insulation complying with the requirements of 6.8.3.2.14. If the SADT of the organic peroxide in the tank is 55 °C or less, or the tank is constructed of aluminium, the shell shall be completely insulated. The sun shield and any part of the tank not covered by it, or the outer sheathing of a complete lagging, shall be painted white or finished in bright metal. The paint shall be cleaned before each transport journey and - 486 - renewed in case of yellowing or deterioration. The thermal insulation shall be free from combustible matter. Tanks shall be fitted with temperature sensing devices. Tanks shall be fitted with safety valves and emergency pressure-relief devices. Vacuum-relief devices may also be used. Emergency pressure-relief devices shall operate at pressures determined according to both the properties of the organic peroxide and the construction characteristics of the tank. Fusible elements shall not be permitted in the body of the shell. Tanks shall be fitted with spring-loaded safety valves to prevent significant pressure build-up within the shell of the decomposition products and vapours released at a temperature of 50 °C. The capacity and start-to-discharge pressure of the safety-valve(s) shall be based on the results of the tests specified in special provision TA2. The start-to-discharge pressure shall however in no case be such that liquid could escape from the valve(s) if the tank were overturned. The emergency-relief devices may be of the spring-loaded or frangible types designed to vent all the decomposition products and vapours evolved during a period of not less than one hour of complete fire-engulfment as calculated by the following formula: q  70961  F  A 0.82 where: q = heat absorption [W] A = wetted area [m2] F = insulation factor F = l for non-insulated tanks, or F U (923 - TP0 ) for insulated tanks 47032 where: K = heat conductivity of insulation layer [W·m-1·K-1] L = thickness of insulation layer [m] U = K/L = heat transfer coefficient of the insulation [W·m-2·K-1] TPO = temperature of peroxide at relieving conditions [K] The start-to-discharge pressure of the emergency-relief device(s) shall be higher than that above specified and based on the results of the tests referred to in special provision TA2. The emergency-relief devices shall be dimensioned in such a way that the maximum pressure in the tank never exceeds the test pressure of the tank. NOTE: An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the Manual of Tests and Criteria. For tanks equipped with thermal insulation consisting of a complete cladding, the capacity and setting of the emergency-relief device(s) shall be determined assuming a loss of insulation from 1% of the surface area. Vacuum-relief devices and spring-loaded safety valves of tanks shall be provided with flame arresters unless the substances to be carried and their decomposition products are noncombustible. Due attention shall be paid to the reduction of the relief capacity caused by the flame arrester. TE13 Tanks shall be thermally insulated and fitted with a heating device on the outside. TE14 Tanks shall be equipped with thermal insulation. The thermal insulation directly in contact with the shell shall have an ignition temperature at least 50 °C higher than the maximum temperature for which the tank was designed. TE15 (Deleted) - 487 - TE16 (Reserved) TE17 (Reserved) TE18 Tanks intended for the carriage of substances filled at a temperature higher than 190 ºC shall be equipped with deflectors placed at right angles to the upper filling openings, so as to avoid a sudden localized increase in wall temperature during filling. TE19 Fittings and accessories mounted in the upper part of the tank shall be either: - inserted in a recessed housing; or - equipped with an internal safety valve; or - shielded by a cap, or by transverse and/or longitudinal members, or by other equally effective devices, so profiled that in the event of overturning the fittings and accessories will not be damaged. Fittings and accessories mounted in the lower part of the tank: Pipe-sockets, lateral shut-off devices, and all discharge devices shall either be recessed by at least 200 mm from the extreme outer edge of the tank or be protected by a rail having a coefficient of inertia of not less than 20 cm3 transversally to the direction of travel; their ground clearance shall be not less than 300 mm with the tank full. Fittings and accessories mounted on the rear face of the tank shall be protected by the bumper prescribed in 9.7.6. Their height above the ground shall be such that they are adequately protected by the bumper TE20 Notwithstanding the other tank-codes which are permitted in the hierarchy of tanks of the rationalized approach in 4.3.4.1.2, tanks shall be equipped with a safety valve. TE21 The closures shall be protected with lockable caps. TE22 (Reserved) TE23 Tanks shall be equipped with a device of a design which precludes its obstruction by the substance carried and which prevents leakage and the build-up of excess overpressure or underpressure inside the shell. TE24 If tanks, intended for the carriage and handling of bitumen, are equipped with a spray bar at the end of the discharge pipe, the closing device, as required by 6.8.2.2.2, may be replaced by a shut-off valve, situated on the discharge pipe and preceding the spray bar. TE25 (Reserved) - 488 - (c) Type approval (TA) TA1 Tanks shall not be approved for the carriage of organic substances. TA2 This substance may be carried in fixed or demountable tanks or tank-containers under the conditions laid down by the competent authority of the country of origin, if, on the basis of the tests mentioned below, the competent authority is satisfied that such a transport operation can be carried out safely. If the country of origin is not party to ADR, these conditions shall be recognized by the competent authority of the first ADR country reached by the consignment. For the type approval tests shall be undertaken: - to prove the compatibility of all materials normally in contact with the substance during carriage; - to provide data to facilitate the design of the emergency pressure-relief devices and safety valves taking into account the design characteristics of the tank; and - to establish any special requirements necessary for the safe carriage of the substance. The test results shall be included in the report for the type approval. TA3 This substance may be carried only in tanks with the tank code LGAV or SGAV; the hierarchy in 4.3.4.1.2 is not applicable. TA4 The conformity assessment procedures of section 1.8.7 shall be applied by the competent authority, its delegate or inspection body conforming to 1.8.6.2, 1.8.6.4, 1.8.6.5 and 1.8.6.8 and accredited to EN ISO/IEC 17020:2012 (except clause 8.1.3) type A. TA5 This substance may be carried only in tanks with the tank code S2.65AN(+); the hierarchy in 4.3.4.1.2 is not applicable. (d) Tests (TT) TT1 Tanks of pure aluminium need to be subjected to the initial and periodic hydraulic pressure tests at a pressure of only 250 kPa (2.5 bar) (gauge pressure). TT2 The condition of the lining of shells shall be inspected every year by an expert approved by the competent authority, who shall inspect the inside of the shell. TT3 By derogation from the requirements of 6.8.2.4.2,, periodic inspections shall take place at least every eight years and shall include a thickness check using suitable instruments. For such tanks, the leakproofness test and check for which provision is made in 6.8.2.4.3 shall be carried out at least every four years. TT4 (Reserved) TT5 The hydraulic pressure tests shall take place at least every 3 years. 2½ years. TT6 The periodic tests, including the hydraulic pressure test, shall be carried out at least every 3 years. TT7 Notwithstanding the requirements of 6.8.2.4.2, the periodic internal inspection may be replaced by a programme approved by the competent authority. TT8 Tanks on which the proper shipping name required for the entry UN 1005 AMMONIA, ANHYDROUS is marked in accordance with 6.8.3.5.1 to 6.8.3.5.3 and constructed of finegrained steel with a yield strength of more than 400 N/mm2 in accordance with the material standard, shall be subjected at each periodic test according to 6.8.2.4.2, to magnetic particle inspections to detect surface cracking. - 489 - For the lower part of each shell at least 20% of the length of each circumferential and longitudinal weld shall, together with all nozzle welds and any repair or ground areas, be inspected. If the marking of the substance on the tank or tank plate is removed, a magnetic particle inspection shall be carried out and these actions recorded in the inspection certificate attached to the tank record. Such magnetic particle inspections shall be carried out by a competent person qualified for this method according to EN ISO 9712:2012 (Non-destructive testing – Qualification and certification of NDT personnel – General principles). TT9 For inspections and tests (including supervision of the manufacture) the procedures of section 1.8.7 shall be applied by the competent authority, its delegate or inspection body conforming to 1.8.6.2, 1.8.6.4, 1.8.6.5 and 1.8.6.8 and accredited according to EN ISO/IEC 17020:2012 (except clause 8.1.3) type A. TT10 The periodic inspections according to 6.8.2.4.2 shall take place: at least every three years. TT11 | For fixed tanks (tank-vehicles) and demountable tanks used exclusively for the carriage of LPG, with carbon steel shells and service equipment, the hydraulic pressure test, may, at the time of the periodic inspection and at the request of the applicant, be replaced by the non-destructive testing (NDT) techniques listed below. These techniques may be used either singularly or in combination as deemed suitable by the competent authority, its delegate or inspection body (see special provision TT9): – EN ISO 17640:2010 – Nondestructive testing of welds – Ultrasonic testing – Techniques, testing levels and assessment, – EN ISO 17638:2009 – Nondestructive testing of welds – Magnetic particle testing, with indications acceptance in accordance with EN ISO 23278:2009 – Magnetic particle testing of welds. Acceptance levels, – EN 1711:2000 – Non-destructive testing of welds – Eddy current examination of welds by complex plane analysis, – EN 14127:2011 – Non-destructive testing – Ultrasonic thickness measurement, Personnel involved in NDT shall be qualified, certified and have the appropriate theoretical and practical - 490 - at least every two and a half years. knowledge of the non-destructive tests they perform, specify, supervise, monitor or evaluate in accordance with: – EN ISO 9712:2012 – Nondestructive testing – Qualification and certification of NDT personnel. After direct application of heat such as welding or cutting to the pressure containing elements of the tank a hydraulic test shall be carried out in addition to any prescribed NDT. NDT shall be performed on the areas of the shell and equipment listed in the table below: Area of shell and equipment NDT Shell longitudinal butt welds Shell circumferential butt welds 100% NDT, using Attachments, manway, nozzles and one or more of the opening welds (internal) direct to following the shell techniques: High stress areas of fastening ultrasonic, magnetic doubling plates (over the end of the particle or eddy saddle horn, plus 400 mm down current testing each side) Piping and other equipment welds Shell, areas that cannot be visually Ultrasonic thickness inspected from the outside survey, from inside, on a 150 mm (maximum) spaced grid Irrespective of the original design and construction standard or technical code used for the tank, the defect acceptance levels shall be in accordance with the requirements of the relevant parts of EN 14025:2013 (Tanks for the transport of dangerous goods – metallic pressure tanks – design and construction), EN 12493:2013 (LPG equipment and accessories – welded steel tanks for liquefied petroleum gas (LPG) – road tankers – design and manufacture), EN ISO 23278:2009 (Non-destructive testing of welds – magnetic particle testing of welds – acceptance levels) or the acceptance standard referenced in the applicable NDT standard. If an unacceptable defect is found in the tank by NDT methods it shall be repaired and retested. It is not permitted to hydraulic test the tank without undertaking the required repairs. - 491 - The results of the NDT shall be recorded and retained for the lifetime of the tank. (e) Marking (TM) NOTE: These particulars shall be in an official language of the country of approval, and also, if that language is not English, French or German, in English, French or German, unless any agreements concluded between the countries concerned in the transport operation provide otherwise. TM1 Tanks shall bear in addition to the particulars prescribed in 6.8.2.5.2, the words: "Do not open during carriage. Liable to spontaneous combustion" (see also the Note above). TM2 Tanks shall bear in addition to the particulars prescribed in 6.8.2.5.2, the words: "Do not open during carriage. Gives off flammable gases on contact with water" (see also the Note above). TM3 Tanks shall also bear, on the plate prescribed in 6.8.2.5.1, the proper shipping name and the maximum permissible load mass in kg for this substance. TM4 For tanks the following additional particulars shall be marked by stamping or by any other similar method on the plate prescribed in 6.8.2.5.2 or directly on the shell itself, if the walls are so reinforced that the strength of the tank is not impaired: the chemical name with the approved concentration of the substance concerned. TM5 Tanks shall bear, in addition to the particulars referred to in 6.8.2.5.1 the date (month, year) of the most recent inspection of the internal condition of the shell. TM6 (Reserved) TM7 The trefoil symbol, as described in 5.2.1.7.6, shall be marked by stamping or any other equivalent method on the plate described in 6.8.2.5.1. This trefoil may be engraved directly on the walls of the shell itself, if the walls are so reinforced that the strength of the shell is not impaired. 6.8.5 Requirements concerning the materials and construction of fixed welded tanks, demountable welded tanks, and welded shells of tank-containers for which a test pressure of not less than 1 MPa (10 bar) is required, and of fixed welded tanks, demountable welded tanks and welded shells of tank-containers intended for the carriage of refrigerated liquefied gases of Class 2 6.8.5.1 Materials and shells 6.8.5.1.1 (a) Shells intended for the carriage of : - compressed, liquefied gases or dissolved gases of Class 2; - UN Nos. 1380, 2845, 2870, 3194 and 3391 to 3394 of Class 4.2; and - UN No. 1052 hydrogen fluoride, anhydrous and UN No.1790 hydrofluoric acid with more than 85% hydrogen fluoride of Class 8 shall be made of steel; (b) Shells constructed of fine-grained steels for the carriage of: - corrosive gases of Class 2 and UN No. 2073 ammonia solution; and - UN No. 1052 hydrogen fluoride, anhydrous and UN No.1790 hydrofluoric acid with more than 85% hydrogen fluoride of Class 8 shall be heat-treated for thermal stress relief; - 492 - 6.8.5.1.2 (c) Shells intended for the carriage of refrigerated liquefied gases of Class 2, shall be made of steel, aluminium, aluminium alloy, copper or copper alloy (e.g. brass). However, shells made of copper or copper alloy shall be allowed only for gases containing no acetylene; ethylene, however, may contain not more than 0.005% acetylene; (d) Only materials appropriate to the lowest and highest working temperatures of the shells and of their fittings and accessories may be used. The following materials shall be allowed for the manufacture of shells: (a) 6.8.5.1.3 6.8.5.1.4 Steels not subject to brittle fracture at the lowest working temperature (see 6.8.5.2.1): - mild steels (except for refrigerated liquefied gases of Class 2); - fine-grained steels, down to a temperature of -60 ºC; - nickel steels (with a nickel content of 0.5 to 9%), down to a temperature of –196 ºC, depending on the nickel content; - austenitic chrome-nickel steels, down to a temperature of -270 ºC; (b) Aluminium not less than 99.5% pure or aluminium alloys (see 6.8.5.2.2); (c) Deoxidized copper not less than 99.9% pure, or copper alloys having a copper content of over 56% (see 6.8.5.2.3). (a) Shells made of steel, aluminium or aluminium alloys shall be either seamless or welded; (b) Shells made of austenitic steel, copper or copper alloy may be hard-soldered. The fittings and accessories may either be screwed to the shells or be secured thereto as follows: (a) Shells made of steel, aluminium or aluminium alloy: by welding; (b) Shells made of austenitic steel, of copper or of copper alloy: by welding or hard-soldering. 6.8.5.1.5 The construction of shells and their attachment to the vehicle, to the underframe or in the container frame shall be such as to preclude with certainty any such reduction in the temperature of the loadbearing components as would be likely to render them brittle. The means of attachment of shells shall themselves be so designed that even when the shell is at its lowest working temperature they still possess the necessary mechanical properties. 6.8.5.2 Test requirements 6.8.5.2.1 Steel shells The materials used for the manufacture of shells and the weld beads shall, at their lowest working temperature, but at least at -20 ºC, meet at least the following requirements as to impact strength: - The tests shall be carried out with test-pieces having a V-shaped notch; - The minimum impact strength (see 6.8.5.3.1 to 6.8.5.3.3) for test-pieces with the longitudinal axis at right angles to the direction of rolling and a V-shaped notch (conforming to ISO R 148) perpendicular to the plate surface, shall be 34 J/cm2 for mild steel (which, because of existing ISO standards, may be tested with test-pieces having the longitudinal axis in the direction of rolling); fine-grained steel; ferritic alloy steel Ni < 5%, ferritic alloy steel 5%  Ni  9%; or austenitic Cr - Ni steel; - In the case of austenitic steels, only the weld bead need be subjected to an impact-strength test; - For working temperatures below -196ºC the impact-strength test is not performed at the lowest working temperature, but at -196 ºC. - 493 - 6.8.5.2.2 Shells made of aluminium or aluminium alloy The seams of shells shall meet the requirements laid down by the competent authority. 6.8.5.2.3 Shells made of copper or copper alloy It is not necessary to carry out tests to determine whether the impact strength is adequate. 6.8.5.3 Impact-strength tests 6.8.5.3.1 For sheets less than 10 mm but not less than 5 mm thick, test-pieces having a cross-section of 10 mm × e mm, where "e" represents the thickness of the sheet, shall be used. Machining to 7.5 mm or 5 mm is permitted if it is necessary. The minimum value of 34 J/cm2 shall be required in every case. NOTE: No impact-strength test shall be carried out on sheets less than 5 mm thick, or on their weld seams. 6.8.5.3.2 (a) For the purpose of testing sheets, the impact strength shall be determined on three test-pieces. Test-pieces shall be taken at right angles to the direction of rolling; however, for mild steel they may be taken in the direction of rolling. (b) For testing weld seams the test-pieces shall be taken as follows: when e  10 mm: three test-pieces with the notch at the centre of the weld; three test-pieces with the notch in the centre of the heat affected zone (the V-notch to cross the fusion boundary at the centre of the specimen); Center of the weld Heat affected zone - 494 - when 10 mm < e  20 mm: three test-pieces from the centre of the weld; e 2 e e 2 three test-pieces from the heat affected zone (the V-notch to cross the fusion boundary at the centre of the specimen); Center of the weld Heat affected zone when e > 20 mm e two sets of three test-pieces, one set on the upper face, one set on the lower face at each of the points indicated below (the V-notch to cross the fusion boundary at the centre of the specimen for those taken from the heat affected zone) Center of the weld Heat affected zone 6.8.5.3.3 (a) For sheets, the average of the three tests shall meet the minimum value of 34 J/cm2 indicated in 6.8.5.2.1; not more than one of the individual values may be below the minimum value and then not below 24 J/cm2; (b) For welds, the average value obtained from the three test-pieces taken at the centre of the weld shall not be below the minimum value of 34 J/cm2; not more than one of the individual values may be below the minimum value and then not below 24 J/cm2; - 495 - (c) 6.8.5.3.4 6.8.5.3.5 For the heat affected zone (the V-notch to cross the fusion boundary at the centre of the specimen) the value obtained from not more than one of the three test-pieces may be below the minimum value of 34 J/cm2, though not below 24 J/cm2. If the requirements prescribed in 6.8.5.3.3 are not met, one retest only may be done if: (a) the average value of the first three tests is below the minimum value of 34 J/cm2; or (b) more than one of the individual values is less than the minimum value of 34 J/cm2 but not below 24 J/cm2. In a repeated impact test on sheets or welds, none of the individual values may be below 34 J/cm2. The average value of all the results of the original test and of the retest should be equal to or more than the minimum of 34 J/cm2. On a repeated impact strength test on the heat-affected zone, none of the individual values may be below 34 J/cm2. 6.8.5.4 Reference to standards The requirements of 6.8.5.2 and 6.8.5.3 shall be deemed to have been complied with if the following relevant standards have been applied: EN 1252-1:1998 Cryogenic vessels - Materials - Part 1: Toughness requirements for temperature below - 80 °C. EN 1252-2:2001 Cryogenic vessels - Materials - Part 2: Toughness requirements for temperature between - 80 °C and - 20 °C. - 496 - CHAPTER 6.9 REQUIREMENTS FOR THE DESIGN, CONSTRUCTION, EQUIPMENT, TYPE APPROVAL, TESTING AND MARKING OF FIBRE-REINFORCED PLASTICS (FRP) FIXED TANKS (TANK-VEHICLES), DEMOUNTABLE TANKS, TANK-CONTAINERS AND TANK SWAP BODIES NOTE: For portable tanks and UN multiple-element gas containers (MEGCs) see Chapter 6.7; for fixed tanks (tank-vehicles), demountable tanks and tank-containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple element gas containers (MEGCs) other than UN MEGCs see Chapter 6.8; for vacuum operated waste tanks see Chapter 6.10. 6.9.1 General 6.9.1.1 FRP tanks shall be designed, manufactured and tested in accordance with a quality assurance programme recognized by the competent authority; in particular, lamination work and welding of thermoplastic liners shall only be carried out by qualified personnel in accordance with a procedure recognized by the competent authority. 6.9.1.2 For the design and testing of FRP tanks, the provisions of 6.8.2.1.1, 6.8.2.1.7, 6.8.2.1.13, 6.8.2.1.14 (a) and (b), 6.8.2.1.25, 6.8.2.1.27, 6.8.2.1.28 and 6.8.2.2.3 shall also apply. 6.9.1.3 Heating elements shall not be used for FRP tanks. 6.9.1.4 For the stability of tank-vehicles, the requirements of 9.7.5.1 shall apply. 6.9.2 Construction 6.9.2.1 Shells shall be made of suitable materials, which shall be compatible with the substances to be carried in a service temperature range of between -40°C and +50°C, unless temperature ranges are specified for specific climatic conditions by the competent authority of the country where the transport operation is performed. 6.9.2.2 Shells shall consist of the following three elements : 6.9.2.2.1 - internal liner, - structural layer, - external layer. The internal liner is the inner shell wall zone designed as the primary barrier to provide for the longterm chemical resistance in relation to the substances to be carried, to prevent any dangerous reaction with the contents or the formation of dangerous compounds and any substantial weakening of the structural layer owing to the diffusion of products through the internal liner. The internal liner may either be a FRP liner or a thermoplastic liner. 6.9.2.2.2 FRP liners shall consist of: (a) surface layer ("gel-coat"): adequate resin rich surface layer, reinforced with a veil, compatible with the resin and contents. This layer shall have a fibre mass content of not more than 30% and have a thickness between 0.25 and 0.60 mm; (b) strengthening layer(s): layer or several layers with a minimum thickness of 2 mm, containing a minimum of 900 g/m² of glass mat or chopped fibres with a mass content in glass of not less than 30% unless equivalent safety is demonstrated for a lower glass content. - 497 - 6.9.2.2.3 Thermoplastic liners shall consist of thermoplastic sheet material as referred to in 6.9.2.3.4, welded together in the required shape, to which the structural layers are bonded. Durable bonding between liners and the structural layer shall be achieved by the use of an appropriate adhesive. NOTE: For the carriage of flammable liquids the internal layer may require additional measures in accordance with 6.9.2.14, in order to prevent the accumulation of electrical charges. 6.9.2.2.4 The structural layer of the shell is the zone specially designed according to 6.9.2.4 to 6.9.2.6 to withstand the mechanical stresses. This part normally consists of several fibre reinforced layers in determined orientations. 6.9.2.2.5 The external layer is the part of the shell which is directly exposed to the atmosphere. It shall consist of a resin rich layer with a thickness of at least 0.2 mm. For a thickness larger than 0.5 mm, a mat shall be used. This layer shall have a mass content in glass of less than 30% and shall be capable of withstanding exterior conditions, in particular the occasional contact with the substance to be carried. The resin shall contain fillers or additives to provide protection against deterioration of the structural layer of the shell by ultra-violet radiation. 6.9.2.3 Raw materials 6.9.2.3.1 All materials used for the manufacture of FRP tanks shall be of known origin and specifications. 6.9.2.3.2 Resins The processing of the resin mixture shall be carried out in strict compliance with the recommendations of the supplier. This concerns mainly the use of hardeners, initiators and accelerators. These resins can be: - unsaturated polyester resins; - vinyl ester resins; - epoxy resins; - phenolic resins. The heat distortion temperature (HDT) of the resin, determined in accordance with EN ISO 75-1:2013 shall be at least 20°C higher than the maximum service temperature of the tank, but shall in any case not be lower than 70 °C. 6.9.2.3.3 Reinforcement fibres The reinforcement material of the structural layers shall be a suitable grade of fibres such as glass fibres of type E or ECR according to ISO 2078:1993. For the internal surface liner, glass fibres of type C according to ISO 2078:1993 may be used. Thermoplastic veils may only be used for the internal liner when their compatibility with the intended contents has been demonstrated. 6.9.2.3.4 Thermoplastic liner material Thermoplastic liners, such as unplastified polyvinyl chloride (PVC-U), polypropylene (PP), polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE), etc. may be used as lining materials. 6.9.2.3.5 Additives Additives necessary for the treatment of the resin, such as catalysts, accelerators, hardeners and thixotropic substances as well as materials used to improve the tank, such as fillers, colours, pigments etc. shall not cause weakening of the material, taking into account lifetime and temperature expectancy of the design. 6.9.2.4 Shells, their attachments and their service and structural equipment shall be designed to withstand without loss of contents (other than quantities of gas escaping through any degassing vents) during the design lifetime: - 498 - 6.9.2.5 - the static and dynamic loads in normal conditions of carriage; - the prescribed minimum loads as defined in 6.9.2.5 to 6.9.2.10. At the pressures as indicated in 6.8.2.1.14 (a) and (b), and under the static gravity forces caused by the contents with maximum density specified for the design and at maximum filling degree, the design stress  in longitudinal and circumferential direction of any layer of the shell shall not exceed the following value:  Rm K where: Rm = the value of tensile strength given by taking the mean value of the test results minus twice the standard deviation of the test results. The tests shall be carried out, in accordance with the requirements of EN ISO 527-4:1997 and EN ISO 527-5:2009, on not less than six samples representative of the design type and construction method; K = S  K0  K1  K2  K3 where K shall have a minimum value of 4, and S K0 = = the safety coefficient. For the general design, if the tanks are referred to in Column (12) of Table A of Chapter 3.2 by a tank code including the letter "G" in its second part (see 4.3.4.1.1), the value for S shall be equal to or more than 1.5. For tanks intended for the carriage of substances which require an increased safety level, i.e. if the tanks are referred to in Column (12) of Table A of Chapter 3.2 by a tank code including the number "4" in its second part (see 4.3.4.1.1), the value of S shall be multiplied by a factor of two, unless the shell is provided with protection against damage consisting of a complete metal skeleton including longitudinal and transverse structural members; a factor related to the deterioration in the material properties due to creep and ageing and as a result of the chemical action of the substances to be carried. It shall be determined by the formula: Ko  1  where "" is the creep factor and "" is the ageing factor determined in accordance with EN 978:1997 after performance of the test according to EN 977:1997. Alternatively, a conservative value of K0 = 2 may be applied. In order to determine  and  the initial deflection shall correspond to 2; K1 = a factor related to the service temperature and the thermal properties of the resin, determined by the following equation, with a minimum value of 1: K1 = 1.25 - 0.0125 (HDT - 70) where HDT is the heat distortion temperature of the resin, in ºC; K2 = a factor related to the fatigue of the material; the value of K2 = 1.75 shall be used unless otherwise agreed with the competent authority. For the dynamic design as outlined in 6.9.2.6 the value of K2 = 1.1 shall be used; - 499 - K3 = a factor related to curing and has the following values: - 1.1 where curing is carried out in accordance with an approved and documented process; - 1.5 in other cases. 6.9.2.6 At the dynamic stresses, as indicated in 6.8.2.1.2 the design stress shall not exceed the value specified in 6.9.2.5, divided by the factor . 6.9.2.7 At any of the stresses as defined in 6.9.2.5 and 6.9.2.6, the resulting elongation in any direction shall not exceed 0.2% or one tenth of the elongation at fracture of the resin, whichever is lower. 6.9.2.8 At the specified test pressure, which shall not be less than the relevant calculation pressure as specified in 6.8.2.1.14 (a) and (b) the maximum strain in the shell shall not be greater than the elongation at fracture of the resin. 6.9.2.9 The shell shall be capable of withstanding the ball drop test according to 6.9.4.3.3 without any visible internal or external defects. 6.9.2.10 The overlay laminates used in the joints, including the end joints, the joints of the surge plates and the partitions with the shell shall be capable of withstanding the static and dynamic stresses mentioned above. In order to avoid concentrations of stresses in the overlay lamination, the applied tapper shall not be steeper than 1:6. The shear strength between the overlay laminate and the tank components to which it is bonded shall not be less than:  Q R  l K where: R is the bending shear strength according to EN ISO 14125:1998 + AC:2002 + A1:2011 (three points method) with a minimum of R = 10 N/mm2, if no measured values are available; Q is the load per unit width that the joint shall carry under the static and dynamic loads; K is the factor calculated in accordance with 6.9.2.5 for the static and dynamic stresses; l is the length of the overlay laminate. 6.9.2.11 Openings in the shell shall be reinforced to provide at least the same safety factors against the static and dynamic stresses as specified in 6.9.2.5 and 6.9.2.6 as that for the shell itself. The number of openings shall be minimized. The axis ratio of oval-shaped openings shall be not more than 2. 6.9.2.12 For the design of flanges and pipework attached to the shell, handling forces and the fastening of bolts shall also be taken into account. 6.9.2.13 The tank shall be designed to withstand, without significant leakage, the effects of a full engulfment in fire for 30 minutes as specified by the test requirements in 6.9.4.3.4. Testing may be waived with the agreement of the competent authority, where sufficient proof can be provided by tests with comparable tank designs. 6.9.2.14 Special requirements for the carriage of substances with a flash-point of not more than 60 °C FRP tanks used for the carriage of substances with a flash-point of not more than 60°C shall be constructed so as to ensure the elimination of static electricity from the various component parts so as to avoid the accumulation of dangerous charges. 6.9.2.14.1 The electrical surface resistance of the inside and outside of the shell as established by measurements shall not be higher than 109 ohms. This may be achieved by the use of additives in the resin or interlaminate conducting sheets, such as metal or carbon network. - 500 - 6.9.2.14.2 The discharge resistance to earth as established by measurements shall not be higher than 107 ohms. 6.9.2.14.3 All components of the shell shall be electrically connected to each other and to the metal parts of the service and structural equipment of the tank and to the vehicle. The electrical resistance between components and equipment in contact with each other shall not exceed 10 ohms. 6.9.2.14.4 The electrical surface-resistance and discharge resistance shall be measured initially on each manufactured tank or a specimen of the shell in accordance with a procedure recognized by the competent authority. 6.9.2.14.5 The discharge resistance to earth of each tank shall be measured as part of the periodic inspection in accordance with a procedure recognized by the competent authority. 6.9.3 Items of equipment 6.9.3.1 The requirements of 6.8.2.2.1, 6.8.2.2.2 and 6.8.2.2.4 to 6.8.2.2.8 shall apply. 6.9.3.2 In addition, when they are shown under an entry in Column (13) of Table A of Chapter 3.2, the special provisions of 6.8.4 (b) (TE) shall also apply. 6.9.4 Type testing and approval 6.9.4.1 For any design of a FRP tank type, its materials and a representative prototype shall be subjected to the design type testing as outlined below. 6.9.4.2 Material testing 6.9.4.2.1 The elongation at fracture according to EN ISO 527-4:1997 or EN ISO 527-5:2009 and the heat distortion temperature according to EN ISO 75-1:2013 shall be determined for the resins to be used. 6.9.4.2.2 The following characteristics shall be determined for samples cut out of the shell. Samples manufactured in parallel may only be used, if it is not possible to use cutouts from the shell. Prior to testing, any liner shall be removed. The tests shall cover: - Thickness of the laminates of the central shell wall and the ends; - Mass content and composition of glass, orientation and arrangement of reinforcement layers; - Tensile strength, elongation at fracture and modulus of elasticity according to EN ISO 5274:1997 or EN ISO 527-5:2009 in the direction of stresses. In addition, the elongation at fracture of the resin shall be established by means of ultrasound; - Bending strength and deflection established by the bending creep test according to EN ISO 14125:1998 + AC:2002 + A1:2011 for a period of 1000 hours using a sample with a minimum width of 50 mm and a support distance of at least 20 times the wall thickness. In addition, the creep factor  and the ageing factor  shall be determined by this test and according to EN 978:1997. 6.9.4.2.3 The interlaminate shear strength of the joints shall be measured by testing representative samples in the tensile test according to EN ISO 14130:1997. 6.9.4.2.4 The chemical compatibility of the shell with the substances to be carried shall be demonstrated by one of the following methods with the agreement of the competent authority. This demonstration shall account for all aspects of the compatibility of the materials of the shell and its equipment with the substances to be carried, including chemical deterioration of the shell, initiation of critical reactions of the contents and dangerous reactions between both. - In order to establish any deterioration of the shell, representative samples taken from the shell, including any internal liners with welds, shall be subjected to the chemical compatibility test according to EN 977:1997 for a period of 1 000 hours at 50°C. Compared with a virgin sample, - 501 - the loss of strength and elasticity modulus measured by the bending test according to EN 978:1997 shall not exceed 25%. Cracks, bubbles, pitting effects as well as separation of layers and liners and roughness shall not be acceptable. 6.9.4.3 - Certified and documented data of positive experiences on the compatibility of the filling substances in question with the materials of the shell with which they come into contact at given temperatures, times and any other relevant service conditions. - Technical data published in relevant literature, standards or other sources, acceptable to the competent authority. Type testing A representative prototype tank shall be subjected to tests as specified below. For this purpose service equipment may be replaced by other items if necessary. 6.9.4.3.1 The prototype shall be inspected for compliance with the design type specification. This shall include an internal and external visual inspection and measurement of the main dimensions. 6.9.4.3.2 The prototype, equipped with strain gauges at all locations where a comparison with the design calculation is required, shall be subjected to the following loads and the strains shall be recorded: - Filled with water to the maximum filling degree. The measuring results shall be used to calibrate the design calculation according to 6.9.2.5; - Filled with water to the maximum filling degree and subjected to accelerations in all three directions by means of driving and braking exercises with the prototype attached to a vehicle. For comparison with the design calculation according to 6.9.2.6 the strains recorded shall be extrapolated in relation to the quotient of the accelerations required in 6.8.2.1.2 and measured; - Filled with water and subjected to the specified test pressure. Under this load, the shell shall exhibit no visual damage or leakage. 6.9.4.3.3 The prototype shall be subjected to the ball drop test according to EN 976-1:1997, No. 6.6. No visible damage inside or outside the tank shall occur. 6.9.4.3.4 The prototype with its service and structural equipment in place and filled to 80% of its maximum capacity with water, shall be exposed to a full engulfment in fire for 30 minutes, caused by an open heating oil pool fire or any other type of fire with the same effect. The dimensions of the pool shall exceed those of the tank by at least 50 cm to each side and the distance between fuel level and tank shall be between 50 cm and 80 cm. The rest of the tank below liquid level, including openings and closures, shall remain leakproof except for drips. 6.9.4.4 Type approval 6.9.4.4.1 The competent authority or a body designated by that authority shall issue in respect of each new type of tank an approval attesting that the design is suitable for the purpose for which it is intended and meets the construction and equipment requirements of this chapter as well as the special provisions applicable to the substances to be carried. 6.9.4.4.2 The approval shall be based on the calculation and the test report, including all material and prototype test results and its comparison with the design calculation, and shall refer to the design type specification and the quality assurance programme. 6.9.4.4.3 The approval shall include the substances or group of substances for which compatibility with the shell is provided. Their chemical names or the corresponding collective entry (see 2.1.1.2), and their class and classification code shall be indicated. 6.9.4.4.4 In addition, it shall include design and threshold values (such as life-time, service temperature range, working and test pressures, material data) specified and all precautions to be taken for the manufacture, testing, type approval, marking and use of any tank, manufactured in accordance with the approved design type. - 502 - 6.9.5 Inspections 6.9.5.1 For every tank, manufactured in conformity with the approved design, material tests and inspections shall be performed as specified below. 6.9.5.1.1 The material tests according to 6.9.4.2.2, except for the tensile test and for a reduction of the testing time for the bending creep test to 100 hours shall be performed with samples taken from the shell. Samples manufactured in parallel may only be used, if no cutouts from the shell are possible. The approved design values shall be met. 6.9.5.1.2 Shells and their equipment shall either together or separately undergo an initial inspection before being put into service. This inspection shall include: - a check of conformity to the approved design; - a check of the design characteristics; - an internal and external examination; - a hydraulic pressure test at the test pressure indicated on the plate prescribed in 6.8.2.5.1; - a check of operation of the equipment; - a leakproofness test, if the shell and its equipment have been pressure tested separately. 6.9.5.2 For the periodic inspection of tanks the requirements of 6.8.2.4.2 to 6.8.2.4.4 shall apply. In addition, the inspection in accordance with 6.8.2.4.3 shall include an examination of the internal condition of the shell. 6.9.5.3 The inspections and tests in accordance with 6.9.5.1 and 6.9.5.2 shall be carried out by the expert approved by the competent authority. Certificates shall be issued showing the results of these operations. These certificates shall refer to the list of the substances permitted for carriage in this shell in accordance with 6.9.4.4. 6.9.6 Marking 6.9.6.1 The requirements of 6.8.2.5 shall apply to the marking of FRP tanks, with the following amendments: 6.9.6.2 - the tank plate may also be laminated to the shell or be made of suitable plastics materials; - the design temperature range shall always be marked. In addition, when they are shown under an entry in Column (13) of Table A of Chapter 3.2, the special provisions of 6.8.4 (e) (TM) shall also apply. - 503 - CHAPTER 6.10 REQUIREMENTS FOR THE CONSTRUCTION, EQUIPMENT, TYPE APPROVAL, INSPECTION AND MARKING OF VACUUM-OPERATED WASTE TANKS NOTE 1: For portable tanks and UN multiple-element gas containers (MEGCs) see Chapter 6.7; for fixed tanks (tank-vehicles), demountable tanks and tank containers and tank swap bodies, with shells made of metallic materials, and battery-vehicles and multiple element gas containers (MEGCs) other than UN MEGCs see Chapter 6.8; for fibre-reinforced plastic tanks see Chapter 6.9. NOTE 2: This Chapter applies to fixed tanks, demountable tanks, tank-containers and tank swap bodies. 6.10.1 General 6.10.1.1 Definition NOTE: A tank which fully complies with the requirements of Chapter 6.8 is not considered to be a "vacuum-operated waste tank". 6.10.1.1.1 The term "protected area" means the areas located as follows: (a) The lower part of the tank in a zone which extends over a 60o angle on either side of the lower generating line; (b) The top part of the tank in a zone which extends over a 30° angle on either side of the top generating line; (c) On the end front of the tank on motor vehicles; (d) On the rear end of the tank inside the protection volume formed by the device stipulated in 9.7.6. 6.10.1.2 Scope 6.10.1.2.1 The special requirements of 6.10.2 to 6.10.4 complete or modify Chapter 6.8 and are applied to vacuum-operated waste tanks. Vacuum-operated waste tanks may be equipped with openable ends, if the requirements of Chapter 4.3 allow bottom discharge of the substances to be carried (indicated by letters "A" or "B" in Part 3 of the tank code given in Column (12) of Table A of Chapter 3.2, in accordance with 4.3.4.1.1). Vacuum-operated waste tanks shall comply with all requirements of Chapter 6.8, with the exception of requirements overtaken by a special provision in this Chapter. However the requirements of 6.8.2.1.19, 6.8.2.1.20, and 6.8.2.1.21 shall not apply. 6.10.2 Construction 6.10.2.1 Tanks shall be designed for a calculation pressure equal to 1.3 times the filling or discharge pressure but not less than 400 kPa (4 bar) (gauge pressure). For the carriage of substances for which a higher calculation pressure of the tank is specified in Chapter 6.8, this higher pressure shall apply. 6.10.2.2 Tanks shall be designed to withstand a negative internal pressure of 100 kPa (1 bar). - 505 - 6.10.3 Items of equipment 6.10.3.1 The items of equipment shall be so arranged as to be protected against the risk of being wrenched off or damaged during carriage or handling. This requirement can be fulfilled by placing the items of equipment in a so called "protected area" (see 6.10.1.1.1). 6.10.3.2 The bottom discharge of shells may be constituted by external piping with a stop-valve fitted as close to the shell as practicable and a second closure which may be a blank flange or other equivalent device. 6.10.3.3 The position and closing direction of the stop-valve(s) connected to the shell, or to any compartment in the case of compartmented shells, shall be unambiguous, and be able to be checked from the ground. 6.10.3.4 In order to avoid any loss of contents in the event of damage to the external filling and discharge fittings (pipes, lateral shut-off devices), the internal stop-valve, or the first external stop-valve (where applicable), and its seatings shall be protected against the danger of being wrenched off by external stresses or shall be so designed as to withstand them. The filling and discharge devices (including flanges or threaded plugs) and protective caps (if any) shall be capable of being secured against any unintended opening. 6.10.3.5 The tanks may be equipped with openable ends. Openable ends shall comply with the following conditions: 6.10.3.6 (a) The ends shall be designed to be secured leaktight when closed; (b) Unintentional opening shall not be possible; (c) Where the opening mechanism is power operated the end shall remain securely closed in the event of a power failure; (d) A safety or breakseal device shall be incorporated to ensure that the openable end cannot be opened when there is still a residual over pressure in the tank. This requirement does not apply to openable ends which are power-operated, where the movement is positively controlled. In this case the controls shall be of the dead-man type and be so positioned that the operator can observe the movement of the openable end at all times and is not endangered during opening and closing of the openable end; and (e) Provisions shall be made to protect the openable end and prevent it from being forced open during a roll-over of the vehicle, tank-container or tank swap body. Vacuum-operated waste tanks which are fitted with an internal piston to assist in the cleaning of the tank or discharging shall be provided with stop-devices to prevent the piston in every operational position being ejected from the tank when a force equivalent to the maximum working pressure of the tank is applied to the piston. The maximum working pressure for tanks or compartments with pneumatic operated piston shall not exceed 100 kPa (1.0 bar). The internal piston shall be constructed in a manner and of materials which will not cause an ignition source when the piston is moved. The internal piston may be used as a compartment provided it is secured in position. Where any of the means by which the internal piston is secured is external to the tank, it shall be placed in a position not liable to accidental damage. 6.10.3.7 The tanks may be equipped with suction booms if: (a) The boom is fitted with an internal or external stop-valve fixed directly to the shell, or directly to a bend that is welded to the shell; a rotation crown wheel can be fitted between the shell or the bend and the external stop valve, if this rotation crown wheel is located in the protected area and the stop-valve control device is protected with a housing or cover against the danger of being wrenched off by external loads; (b) The stop-valve mentioned in (a) is so arranged that carriage with the valve in an open position is prevented; and - 506 - (c) 6.10.3.8 6.10.3.9 The boom is constructed in such a way that the tank will not leak as a result of accidental impact on the boom. The tanks shall be fitted with the following additional service equipment: (a) The outlet of a pump/exhauster unit shall be so arranged as to ensure that any flammable or toxic vapours are diverted to a place where they will not cause a danger; (b) A device to prevent immediate passage of flame shall be fitted to all openings of a vacuum pump/exhauster unit which may provide a source of ignition and which is fitted on a tank used for the carriage of flammable wastes, or the tank shall be explosion pressure shock resistant, which means being capable of withstanding without leakage, but allowing deformation, an explosion resulting from the passage of the flame; (c) Pumps which can deliver a positive pressure shall have a safety device fitted in the pipework which can be pressurised. The safety device shall be set to discharge at a pressure not exceeding the maximum working pressure of the tank; (d) A stop-valve shall be fitted between the shell, or the outlet of the overfill prevention device fitted to the shell, and the pipework connecting the shell to the pump/exhauster unit; (e) The tank shall be fitted with a suitable pressure/vacuum manometer which shall be mounted in a position where it can be easily read by the person operating the pump/exhauster unit. A distinguishing line shall be marked on the scale to indicate the maximum working pressure of the tank; (f) The tank, or in case of compartmented tanks, every compartment, shall be equipped with a level indicating device. Sight glasses may be used as level indicating devices provided: (i) they form a part of the tank wall and have a resistance to the pressure comparable to that of the tank; or they are fitted external to the tank; (ii) the top and bottom connections to the tank are equipped with shut-off valves fixed directly to the shell and so arranged that carriage with the valves in an open position is prevented; (iii) are suitable for operation at the maximum working pressure of the tank; and (iv) are placed in a position where they will not be liable to accidental damage. The shells of vacuum-operated waste tanks shall be fitted with a safety valve preceded by a bursting disc. The valve shall be capable of opening automatically at a pressure between 0.9 and 1.0 times the test pressure of the tank to which it is fitted. The use of dead weight or counterweight valves is prohibited. The bursting disc shall burst at the earliest when the initial opening pressure of the valve is reached and at the latest when this pressure reaches the test pressure of the tank to which it is fitted. Safety devices shall be of such a type as to resist dynamic stresses, including liquid surge. The space between the bursting disc and the safety valve shall be provided with a pressure gauge or suitable tell-tale indicator for the detection of disc rupture, pinholing or leakage wich could cause a malfunction of the safety valve. 6.10.4 Inspection Vacuum-operated waste tanks shall be subject every three years for fixed tanks or demountable tanks and at least every two and a half years for tank-containers and tank swap bodies to an examination of the internal condition, in addition to the tests according to 6.8.2.4.3. - 507 - CHAPTER 6.11 REQUIREMENTS FOR THE DESIGN, CONSTRUCTION, INSPECTION AND TESTING OF BULK CONTAINERS 6.11.1 (Reserved) 6.11.2 Application and general requirements 6.11.2.1 Bulk containers and their service and structural equipment shall be designed and constructed to withstand, without loss of contents, the internal pressure of the contents and the stresses of normal handling and carriage. 6.11.2.2 Where a discharge valve is fitted, it shall be capable of being made secure in the closed position and the whole discharge system shall be suitably protected from damage. Valves having lever closures shall be able to be secured against unintended opening and the open or closed position shall be readily apparent. 6.11.2.3 Code for designating types of bulk container The following table indicates the codes to be used for designating types of bulk containers: Types of bulk containers Sheeted bulk container Closed bulk container Code BK1 BK2 6.11.2.4 In order to take account of progress in science and technology, the use of alternative arrangements which offer at least equivalent safety as provided by the requirements of this chapter may be considered by the competent authority. 6.11.3 Requirements for the design, construction, inspection and testing of containers conforming to the CSC used as BK1 or BK2 bulk containers 6.11.3.1 Design and construction requirements 6.11.3.1.1 The general design and construction requirements of this sub-section are deemed to be met if the bulk container complies with the requirements of ISO 1496-4:1991 "Series 1 Freight containersSpecification and testing – Part 4: Non pressurized containers for dry bulk" and the container is siftproof. 6.11.3.1.2 Containers designed and tested in accordance with ISO 1496-1:1990 "Series 1 Freight containersSpecification and testing - Part 1: General cargo containers for general purposes" shall be equipped with operational equipment which is, including its connection to the container, designed to strengthen the end walls and to improve the longitudinal restraint as necessary to comply with the test requirements of ISO 1496-4:1991 as relevant. 6.11.3.1.3 Bulk containers shall be siftproof. Where a liner is used to make the container siftproof it shall be made of a suitable material. The strength of material used for, and the construction of, the liner shall be appropriate to the capacity of the container and its intended use. Joins and closures of the liner shall withstand pressures and impacts liable to occur under normal conditions of handling and carriage. For ventilated bulk containers any liner shall not impair the operation of ventilating devices. 6.11.3.1.4 The operational equipment of bulk containers designed to be emptied by tilting shall be capable of withstanding the total filling mass in the tilted orientation. 6.11.3.1.5 Any movable roof or side or end wall or roof section shall be fitted with locking devices with securing devices designed to show the locked state to an observer at ground level. - 509 - 6.11.3.2 Service equipment 6.11.3.2.1 Filling and discharge devices shall be so constructed and arranged as to be protected against the risk of being wrenched off or damaged during carriage and handling. The filling and discharge devices shall be capable of being secured against unintended opening. The open and closed position and direction of closure shall be clearly indicated. 6.11.3.2.2 Seals of openings shall be so arranged as to avoid any damage by the operation, filling and emptying of the bulk container. 6.11.3.2.3 Where ventilation is required bulk containers shall be equipped with means of air exchange, either by natural convection, e.g. by openings, or active elements, e.g. fans. The ventilation shall be designed to prevent negative pressures in the container at all times. Ventilating elements of bulk containers for the carriage of flammable substances or substances emitting flammable gases or vapours shall be designed so as not to be a source of ignition. 6.11.3.3 Inspection and testing 6.11.3.3.1 Containers used, maintained and qualified as bulk containers in accordance with the requirements of this section shall be tested and approved in accordance with the CSC. 6.11.3.3.2 Containers used and qualified as bulk containers shall be inspected periodically according to the CSC. 6.11.3.4 Marking 6.11.3.4.1 Containers used as bulk containers shall be marked with a Safety Approval Plate in accordance with the CSC. 6.11.4 Requirements for the design, construction and approval of BK1 or BK2 bulk containers other than containers conforming to the CSC NOTE: When containers conforming to the provisions of this section are used for the carriage of solids in bulk, the following statement shall be shown on the transport document: "Bulk container BK(x) approved by the competent authority of ……". (see 5.4.1.1.17)". 6.11.4.1 Bulk containers covered in this section include skips, offshore bulk containers, bulk bins, swap bodies, trough shaped containers, roller containers, and load compartments of vehicles. NOTE: These bulk containers also include containers conforming to the UIC leaflets 591, 592 and 592-2 to 592-4 as mentioned in 7.1.3 which do not conform to the CSC. 6.11.4.2 These bulk containers shall be designed and constructed so as to be strong enough to withstand the shocks and loadings normally encountered during carriage including, as applicable, transhipment between modes of transport. 6.11.4.3 (Reserved) 6.11.4.4 These bulk containers shall be approved by the competent authority and the approval shall include the code for designating types of bulk containers in accordance with 6.11.2.3 and the requirements for inspection and testing as appropriate. 6.11.4.5 Where it is necessary to use a liner in order to retain the dangerous goods it shall meet the provisions of 6.11.3.1.3. - 510 - CHAPTER 6.12 REQUIREMENTS FOR THE CONSTRUCTION, EQUIPMENT, TYPE APPROVAL, INSPECTIONS AND TESTS, AND MARKING OF TANKS, BULK CONTAINERS AND SPECIAL COMPARTMENTS FOR EXPLOSIVES OF MOBILE EXPLOSIVES MANUFACTURING UNITS (MEMUs) NOTE 1: For portable tanks, see Chapter 6.7; for fixed tanks (tank-vehicles), demountable tanks, tankcontainers and tank swap bodies, with shells made of metallic materials, see Chapter 6.8; for fibrereinforced plastics tanks see Chapter 6.9; for vacuum operated waste tanks see Chapter 6.10; for bulk containers see Chapter 6.11. NOTE 2: This Chapter applies to fixed tanks, demountable tanks, tank-containers, tank swap bodies, which do not comply with all requirements of the Chapters mentioned in Note 1 as well as bulk containers and special compartments for explosives. 6.12.1 Scope The requirements of this Chapter are applicable to tanks, bulk containers and special compartments intended for the carriage of dangerous goods on MEMUs. 6.12.2 General provisions 6.12.2.1 Tanks shall meet the requirements of Chapter 6.8, notwithstanding the minimum capacity defined in section 1.2.1 for fixed tanks, as modified by the special provisions of this Chapter. 6.12.2.2 Bulk containers intended for the carriage of dangerous goods on MEMUs shall comply with the requirements for bulk containers of type BK2. 6.12.2.3 Where a single tank or bulk container contains more than one substance each substance shall be separated by at least two walls with drained air space between. 6.12.3 Tanks 6.12.3.1 Tanks with a capacity of 1 000 litres or more 6.12.3.1.1 These tanks shall meet the requirements of section 6.8.2. 6.12.3.1.2 For UN Nos. 1942 and 3375, the tank shall meet the requirements of Chapters 4.3 and 6.8 concerning breather devices and, in addition, shall have bursting discs or other suitable means of emergency pressure relief, approved by the competent authority of the country of use. 6.12.3.1.3 For shells not of a circular cross-section, for example box-shaped or elliptical shells, which cannot be calculated according to 6.8.2.1.4 and standards or technical code mentioned therein, the ability to withstand the permissible stress may be demonstrated by a pressure test specified by the competent authority. These tanks shall meet the requirements of sub-section 6.8.2.1 other than 6.8.2.1.3, 6.8.2.1.4 and 6.8.2.1.13 to 6.8.2.1.22. - 511 - The thickness of these shells shall not be less than the values given in the table below: Material Stainless austenitic steels Other steels Aluminium alloys Pure aluminium of 99.80% Minimum thickness 2.5 mm 3 mm 4 mm 6 mm Protection of the tank against damage through lateral impact or overturning shall be provided. Protection shall be provided according to 6.8.2.1.20 or the competent authority shall approve alternative protection measures. 6.12.3.1.4 By derogation from the requirements of 6.8.2.5.2 tanks do not need to be marked with the tank code and the special provisions, as applicable. 6.12.3.2 Tanks with a capacity of less than 1 000 litres 6.12.3.2.1 The construction of these tanks shall meet the requirements of sub-section 6.8.2.1 other than 6.8.2.1.3, 6.8.2.1.4, 6.8.2.1.6, 6.8.2.1.10 to 6.8.2.1.23 and 6.8.2.1.28. 6.12.3.2.2 The equipment of these tanks shall meet the requirements of 6.8.2.2.1. For UN Nos. 1942 and 3375, the tank shall meet the requirements of Chapters 4.3 and 6.8 concerning breather devices and, in addition, shall have bursting discs or other suitable means of emergency pressure relief, approved by the competent authority of the country of use. 6.12.3.2.3 The thickness of these shells shall not be less than the values given in the table below: Material Stainless austenitic steels Other steels Aluminium alloys Pure aluminium of 99.80% Minimum thickness 2.5 mm 3 mm 4 mm 6 mm 6.12.3.2.4 Tanks may have constructional parts that are without a radius of convexity. Alternative supportive measures may be curved walls, corrugated walls or ribs. In at least one direction the distance between parallel supports on each side of the tank shall not be greater than 100 times the wall thickness. 6.12.3.2.5 Welds shall be skilfully made and shall afford the fullest safety. Welding shall be performed by skilled welders using a welding process whose effectiveness (including any heat treatments required) has been demonstrated by test. 6.12.3.2.6 The requirements of 6.8.2.4 do not apply. However, the initial and periodic inspections of these tanks shall be carried out under the responsibility of the user or owner of the MEMU. Shells and their equipment shall be subject to visual examination of their external and internal condition and a leakproofness test to the satisfaction of the competent authority at least every three years. 6.12.3.2.7 The requirements for type approval of 6.8.2.3 and for marking of 6.8.2.5 do not apply. - 512 - 6.12.4 Items of equipment 6.12.4.1 Tanks with bottom discharge for UN 1942 and UN 3375 shall have at least two closures. One of these closures may be the product mixing or discharge pump or auger. 6.12.4.2 Any piping after the first closure shall be of a fusible material (i.e. rubber hose) or have fusible elements. 6.12.4.3 In order to avoid any loss of contents in the event of damage to the external pumps and discharge fittings (pipes), the first closure and its seatings shall be protected against the danger of being wrenched off by external stresses or shall be so designed as to withstand them. The filling and discharge devices (including flanges or threaded plugs) and protective caps (if any) shall be capable of being secured against any unintended opening. 6.12.4.4 Breather devices in accordance with 6.8.2.2.6 on tanks for UN 3375 may be substituted by "goose necks". Such equipment shall be protected against the danger of being wrenched off by external stresses or shall be so designed as to withstand them. 6.12.5 Special compartments for explosives Compartments for packages of explosives containing detonators and/or detonator assemblies and those containing substances or articles of compatibility group D shall be designed to provide effective segregation such that there is no danger of transmission of detonation from the detonators and/or detonator assemblies to the substances or articles of compatibility group D. Segregation shall be achieved by the use of separate compartments or by placing one of the two types of explosive in a special containment system. Either method of segregation shall be approved by the competent authority. If the material used for the compartment is metal, the complete inside of the compartment shall be covered with materials providing suitable fire resistance. The explosives compartments shall be located where they are protected from impact and from damage on rough terrain and dangerous interaction with other dangerous goods on board and from ignition sources on the vehicle e.g. exhausts etc. NOTE: Materials classified as class B-s3-d2 according to standard EN 13501-1:2007 + A1:2009 are deemed to fulfil the fire resistance requirement. - 513 - PART 7 Provisions concerning the conditions of carriage, loading, unloading and handling - CHAPTER 7.1 GENERAL PROVISIONS 7.1.1 The carriage of dangerous goods is subject to the mandatory use of a particular type of transport equipment in accordance with the provisions of this Chapter and Chapter 7.2 for carriage in packages, Chapter 7.3 for carriage in bulk and Chapter 7.4 for carriage in tanks. In addition, the provisions of Chapter 7.5 concerning loading, unloading and handling shall be observed. Columns (16), (17) and (18) of Table A of Chapter 3.2 show the particular provisions of this Part that apply to specific dangerous goods. 7.1.2 In addition to the provisions of this Part, vehicles used for the carriage of dangerous goods shall, as regards their design, construction and, if appropriate, their approval, conform to the relevant requirements of Part 9. 7.1.3 Large containers, portable tanks and tank-containers which meet the definition of "container" given in the CSC (1972), as amended, or in UIC leaflets 591 (status at 01.10.2007, 3rd edition), 592 (status at 01.10.2013, 2nd edition), 592-2 (status at 01.10.2004, 6th edition), 592-3 (status at 01.01.1998, 2nd edition) and 592-4 (status at 01.05.2007, 3rd edition) may not be used to carry dangerous goods unless the large container or the frame of the portable tank or tank-container satisfies the provisions of the CSC or of UIC leaflets 591, 592 and 592-2 to 592-4. 7.1.4 A large container may be presented for carriage only if it is structurally serviceable. "Structurally serviceable" means that the container is free from major defects in its structural components, e.g. top and bottom side rails, doorsill and header, floor cross members, corner posts, and corner fittings. "Major defects" are dents or bends in structural members greater than 19 mm in depth, regardless of length; cracks or breaks in structural members; more than one splice or an improper splice (e.g. a lapped splice) in top or bottom end rails or door headers or more than two splices in any one top or bottom side rail or any splice in a door sill or corner post; door hinges and hardware that are seized, twisted, broken, missing or otherwise inoperative; non-closing gaskets and seals; any distortion of the overall configuration sufficient to prevent proper alignment of handling equipment, mounting and securing on a chassis or vehicle. In addition, deterioration in any component of the container, such as rusted metal in side walls or disintegrated fibreglass is unacceptable, regardless of the material of construction. Normal wear, including oxidization (rust), slight dents and scratches and other damage that do not affect serviceability or weather-tightness are, however, acceptable. Prior to loading the container shall also be checked to ensure that it is free from any residue of a previous load and that the interior floor and walls are free from protrusions. 7.1.5 Large containers shall meet the requirements concerning the body of the vehicle laid down in this Part and, if appropriate, those laid down in Part 9 for the load in question; the body of the vehicle need not then satisfy those provisions. However, large containers carried on vehicles whose platforms have insulation and heat-resistant qualities which satisfy those requirements need not then satisfy the said requirements. This provision also applies to small containers for the carriage of explosive substances and articles of Class 1. 7.1.6 Subject to the provisions of the last part of the first sentence of 7.1.5, the fact that dangerous goods are contained in one or more containers shall not affect the conditions to be met by the vehicle by reason of the nature and quantities of the dangerous goods carried. - 517 - CHAPTER 7.2 PROVISIONS CONCERNING CARRIAGE IN PACKAGES 7.2.1 Unless otherwise provided in 7.2.2 to 7.2.4, packages may be loaded: (a) in closed vehicles or in closed containers; or (b) in sheeted vehicles or in sheeted containers; or (c) in open vehicles or in open containers. 7.2.2 Packages comprising packagings made of materials sensitive to moisture shall be loaded on to closed or on to sheeted vehicles or into closed or sheeted containers. 7.2.3 (Reserved) 7.2.4 When they are shown under an entry in Column (16) of Table A of Chapter 3.2, the following special provisions apply: V1 Packages shall be loaded on to closed or sheeted vehicles or into closed or sheeted containers. V2 (1) Packages shall only be loaded on to EX/II or EX/III vehicles which satisfy the relevant requirements of Part 9. The choice of vehicle depends on the quantity to be carried, which is limited per transport unit in accordance with the provisions concerning loading (see 7.5.5.2). (2) Trailers, except semi-trailers, which satisfy the requirements for EX/II or EX/III vehicles may be drawn by motor vehicles which do not satisfy those requirements. For carriage in containers, see also 7.1.3 to 7.1.6. Where substances or articles of Class 1 in quantities requiring a transport unit made up of EX/III vehicle(s) are being carried in containers to or from harbour areas, rail terminals or airports of arrival or departure as part of a multimodal journey, a transport unit made up of EX/II vehicle(s) may be used instead, provided that the containers being carried comply with the appropriate requirements of the IMDG Code, the RID or the ICAO Technical Instructions. V3 For free-flowing powdery substances and for fireworks the floor of a container shall have a non-metallic surface or covering. V4 (Reserved) V5 Packages may not be carried in small containers. V6 Flexible IBCs shall be carried in closed vehicles or in closed containers, in sheeted vehicles or in sheeted containers. The sheet shall be of an impermeable and non-combustible material. V7 (Reserved) V8 (1) Substances stabilized by temperature control shall be forwarded in such manner that the control temperatures indicated in 2.2.41.1.17 and 2.2.41.4 or in 2.2.52.1.16 and 2.2.52.4, as appropriate, are never exceeded. - 519 - (2) (3) The means of temperature control chosen for the transport operation depends on a number of factors such as: - the control temperature(s) of the substance(s) to be carried; - the difference between the control temperature and the expected ambient temperature; - the effectiveness of the thermal insulation; - the duration of the transport operation; and - the safety margin to be allowed for delays en route. Suitable methods to prevent the control temperature from being exceeded are listed below, in ascending order of effectiveness: R1 Thermal insulation, provided that the initial temperature of the substance(s) is sufficiently below the control temperature; R2 Thermal insulation and coolant system, provided that: an adequate quantity of non-flammable coolant (e.g. liquid nitrogen or solid carbon dioxide), allowing a reasonable margin for possible delay, is carried or a means of replenishment is assured; - liquid oxygen or air is not used as coolant; - there is a uniform cooling effect even when most of the coolant has been consumed; and - the need to ventilate the transport unit before entering is clearly indicated by a warning on the door(s); R3 Thermal insulation and single mechanical refrigeration, provided that for substances with a flash-point lower than the sum of the emergency temperature plus 5 °C explosion-proof electrical fittings, EEx IIB T3, are used within the cooling compartment to prevent ignition of flammable vapours from the substances; R4 Thermal insulation and combined mechanical refrigeration system and coolant system, provided that: R5 (4) - - the two systems are independent of one another; and - the requirements of methods R2 and R3 above are met; Thermal insulation and dual mechanical refrigeration system, provided that: - apart from the integral power supply unit, the two systems are independent of one another; - each system alone is capable of maintaining adequate temperature control; and - for substances with a flash-point lower than the sum of the emergency temperature plus 5 °C explosion-proof electrical fittings, EEx IIB T3, are used within the cooling compartment to prevent ignition of flammable vapours from the substances. Methods R4 and R5 may be used for all organic peroxides and self-reactive substances. - 520 - Method R3 may be used for organic peroxides and self-reactive substances of Types C, D, E and F and, when the maximum ambient temperature to be expected during carriage does not exceed the control temperature by more than 10 °C, for organic peroxides and self-reactive substances of Type B. Method R2 may be used for organic peroxides and self-reactive substances of Types C, D, E and F when the maximum ambient temperature to be expected during carriage does not exceed the control temperature by more than 30 °C. Method R1 may be used for organic peroxides and self-reactive substances of Types C, D, E and F when the maximum ambient temperature to be expected during carriage is at least 10 °C below the control temperature. (5) Where substances are required to be carried in insulated, refrigerated or mechanicallyrefrigerated vehicles or containers, these vehicles or containers shall satisfy the requirements of Chapter 9.6. (6) If substances are contained in protective packagings filled with a coolant, they shall be loaded in closed or sheeted vehicles or closed or sheeted containers. If the vehicles or containers used are closed they shall be adequately ventilated. Sheeted vehicles and containers shall be fitted with sideboards and a tailboard. The sheets of these vehicles and containers shall be of an impermeable and non-combustible material. (7) Any control and temperature sensing devices in the refrigeration system shall be readily accessible and all electrical connections shall be weatherproof. The temperature of the air inside the transport unit shall be measured by two independent sensors and the output shall be recorded so that any change in temperature is readily detectable. When substances having a control temperature of less than +25 °C are carried, the transport unit shall be equipped with visible and audible alarms, powered independently of the refrigeration system and set to operate at or below the control temperature. (8) A back-up refrigeration system or spare parts shall be available. NOTE: This provision V8 does not apply to substances referred to in 3.1.2.6 when substances are stabilized by the addition of chemical inhibitors such that the SADT is greater than 50 °C. In this latter case, temperature control may be required under conditions of carriage where the temperature may exceed 55 °C. V9 (Reserved) V10 IBCs shall be carried in closed or sheeted vehicles or closed or sheeted containers. V11 IBCs other than metal or rigid plastics IBCs shall be carried in closed or sheeted vehicles or closed or sheeted containers. IBCs of type 31HZ2 (31HA2, 31HB2, 31HN2, 31HD2 and 31HH2) shall be carried in closed vehicles or containers. V12 V13 When packed in 5H1, 5L1 or 5 M1 bags, shall be carried in closed vehicles or containers. V14 Aerosols carried for the purposes of reprocessing or disposal under special provision 327 in Chapter 3.3 shall only be carried in ventilated or open vehicles or containers. - 521 - CHAPTER 7.3 PROVISIONS CONCERNING CARRIAGE IN BULK 7.3.1 General provisions 7.3.1.1 Goods may not be carried in bulk in bulk containers, containers or vehicles unless: (a) either a special provision, identified by the code "BK" or a reference to a specific paragraph, explicitly authorizing this mode of carriage is indicated in column (10) of Table A of Chapter 3.2 and the relevant conditions of 7.3.2 are satisfied in addition to those of this section; or (b) a special provision, identified by the code "VC" or a reference to a specific paragraph, explicitly authorizing this mode of carriage is indicated in column (17) of Table A of Chapter 3.2 and the conditions of this special provision, together with any additional provision identified with the code(s) "AP", as laid down in 7.3.3 are satisfied in addition to those of this section. Nevertheless, empty packagings, uncleaned, may be carried in bulk if this mode of carriage is not explicitly prohibited by other provisions of ADR. NOTE: For carriage in tanks, see Chapters 4.2 and 4.3. 7.3.1.2 Substances which may become liquid at temperatures likely to be encountered during carriage, are not permitted for carriage in bulk. 7.3.1.3 Bulk containers, containers or bodies of vehicles shall be siftproof and shall be so closed that none of the contents can escape under normal conditions of carriage including the effect of vibration, or by changes of temperature, humidity or pressure. 7.3.1.4 Substances shall be loaded and evenly distributed in a manner that minimises movement that could result in damage to the bulk container, container or vehicle or leakage of the dangerous goods. 7.3.1.5 Where venting devices are fitted they shall be kept clear and operable. 7.3.1.6 Substances shall not react dangerously with the material of the bulk container, container, vehicle, gaskets, equipment including lids and tarpaulins and with protective coatings which are in contact with the contents or significantly weaken them. Bulk containers, containers or vehicles shall be so constructed or adapted that the goods cannot penetrate between wooden floor coverings or come into contact with those parts of the bulk container, container or vehicle that may be affected by the materials or residues thereof. 7.3.1.7 Before being filled and handed over for carriage, each bulk container, container or vehicle shall be inspected and cleaned to ensure that it does not contain any residue on the interior or exterior of the bulk container, container or vehicle that could: - cause a dangerous reaction with the substance intended for carriage; - detrimentally affect the structural integrity of the bulk container, container or vehicle; or - affect the dangerous goods retention capabilities of the bulk container, container or vehicle. 7.3.1.8 During carriage, no dangerous residues shall adhere to the outer surfaces of bulk containers, containers or of the bodies of vehicles. 7.3.1.9 If several closure systems are fitted in series, the system which is located nearest to the substance to be carried shall be closed first before filling. 7.3.1.10 Empty bulk containers, containers or vehicles which have carried a dangerous solid substance in bulk shall be treated in the same manner as is required by ADR for a filled bulk container, container or vehicle, unless adequate measures have been taken to nullify any hazard. - 523 - 7.3.1.11 If bulk containers, containers or vehicles are used for the carriage in bulk of goods liable to cause a dust explosion, or evolve flammable vapours (e. g. for certain wastes) measures shall be taken to exclude sources of ignition and prevent dangerous electrostatic discharge during carriage, filling or discharge of the substance. 7.3.1.12 Substances, for example wastes, which may react dangerously with one another and substances of different classes and goods not subject to ADR, which are liable to react dangerously with one another shall not be mixed together in the same bulk container, container or vehicle. Dangerous reactions are: 7.3.1.13 (a) Combustion and/or evolution of considerable heat; (b) Emission of flammable and/or toxic gases; (c) Formation of corrosive liquids; or (d) Formation of unstable substances. Before a bulk container, container or vehicle is filled it shall be visually examined to ensure it is structurally serviceable, its interior walls, ceiling and floors are free from protrusions or damage and that any inner liners or substance retaining equipment are free from rips, tears or any damage that would compromise its cargo retention capabilities. Structurally serviceable means the bulk container, container or vehicle does not have major defects in its structural components, such as top and bottom side rails, top and bottom end rails, door sill and header, floor cross members, corner posts, and corner fittings in a bulk container or container. Major defects include: (a) Bends, cracks or breaks in the structural or supporting members that affect the integrity of the bulk container, container or of the body of the vehicle; (b) More than one splice or an improper splice (such as a lapped splice) in top or bottom end rails or door headers; (c) More than two splices in any one top or bottom side rail; (d) Any splice in a door sill or corner post; (e) Door hinges and hardware that are seized, twisted, broken, missing, or otherwise inoperative; (f) Gaskets and seals that do not seal; (g) Any distortion of the overall configuration of a bulk container or container great enough to prevent proper alignment of handling equipment, mounting and securing on a chassis or vehicle; (h) Any damage to lifting attachments or handling equipment interface features; or (i) Any damage to service or operational equipment. 7.3.2 Provisions for the carriage in bulk when the provisions of 7.3.1.1 (a) are applied 7.3.2.1 In addition to the general provisions of section 7.3.1, the provisions of this section are applicable. The codes BK1 and BK2 in column (10) of Table A of Chapter 3.2 have the following meanings: BK1: BK2: Carriage in bulk in sheeted bulk containers is permitted; Carriage in bulk in closed bulk containers is permitted. 7.3.2.2 The bulk container used shall conform to the requirements of Chapter 6.11. 7.3.2.3 Goods of Class 4.2 The total mass carried in a bulk container shall be such that its spontaneous ignition temperature is greater than 55 °C. - 524 - 7.3.2.4 Goods of Class 4.3 These goods shall be carried in bulk containers which are waterproof. 7.3.2.5 Goods of Class 5.1 Bulk containers shall be so constructed or adapted that the goods cannot come into contact with wood or any other incompatible material. 7.3.2.6 Goods of Class 6.2 7.3.2.6.1 Animal material containing infectious substances (UN Nos. 2814, 2900 and 3373) is authorized for carriage in bulk containers provided the following conditions are met: (a) Sheeted bulk containers BK1 are permitted provided that they are not filled to maximum capacity to avoid substances coming into contact with the sheeting. Closed bulk containers BK2 are also permitted; (b) Closed and sheeted bulk containers, and their openings, shall be leak-proof by design or by the fitting of a suitable liner; (c) The animal material shall be thoroughly treated with an appropriate disinfectant before loading prior to carriage; (d) Sheeted bulk containers shall be covered by an additional top liner weighted down by absorbent material treated with an appropriate disinfectant; (e) Closed or sheeted bulk containers shall not be re-used until after they have been thoroughly cleaned and disinfected. NOTE: Additional provisions may be required by appropriate national health authorities. 7.3.2.6.2 Wastes of Class 6.2 (UN 3291) (a) (Reserved); (b) Closed bulk containers and their openings shall be leakproof by design. These bulk containers shall have non porous interior surfaces and shall be free from cracks or other features which could damage packagings inside, impede disinfection or permit inadvertent release; (c) Wastes of UN No. 3291 shall be contained within the closed bulk container in UN type tested and approved sealed leakproof plastics bags tested for solids of packing group II and marked in accordance with 6.1.3.1. Such plastics bags shall be capable of passing the tests for tear and impact resistance according to ISO 7765-1:1988 "Plastics film and sheeting - Determination of impact resistance by the free-falling dart method - Part 1: Staircase methods" and ISO 63832:1983 "Plastics - Film and sheeting - Determination of tear resistance. Part 2: Elmendorf method". Each bag shall have an impact resistance of at least 165 g and a tear resistance of at least 480 g in both parallel and perpendicular planes with respect to the length of the bag. The maximum net mass of each plastics bag shall be 30 kg; (d) Single articles exceeding 30 kg such as soiled mattresses may be carried without the need for a plastics bag when authorized by the competent authority; (e) Wastes of UN No. 3291 which contain liquids shall only be carried in plastics bags containing sufficient absorbent material to absorb the entire amount of liquid without it spilling in the bulk container; (f) Wastes of UN No. 3291 containing sharp objects shall only be carried in UN type tested and approved rigid packagings meeting the provisions of packing instructions P621, IBC620 or LP621; (g) Rigid packagings specified in packing instructions P621, IBC620 or LP621 may also be used. They shall be properly secured to prevent damage during normal conditions of carriage. - 525 - Wastes carried in rigid packagings and plastics bags together in the same closed bulk container shall be adequately segregated from each other, e.g. by suitable rigid barriers or dividers, mesh nets or otherwise securing, such that they prevent damage to the packagings during normal conditions of carriage; 7.3.2.7 (h) Wastes of UN No. 3291 in plastics bags shall not be compressed in a closed bulk container in such a way that bags may be rendered no longer leakproof; (i) The closed bulk container shall be inspected for leakage or spillage after each journey. If any wastes of UN No. 3291 have leaked or been spilled in the closed bulk container, it shall not be re-used until after it has been thoroughly cleaned and, if necessary, disinfected or decontaminated with an appropriate agent. No other goods shall be carried together with UN No. 3291 other than medical or veterinary wastes. Any such other wastes carried in the same closed bulk container shall be inspected for possible contamination. Material of Class 7 For the carriage of unpackaged radioactive material, see 4.1.9.2.4. 7.3.2.8 Goods of Class 8 These goods shall be carried in bulk containers which are watertight. 7.3.2.9 Goods of Class 9 7.3.2.9.1 For UN 3509, only closed bulk containers (code BK2) may be used. Bulk containers shall be made leak tight or fitted with a leak tight and puncture resistant sealed liner or bag, and shall have a means of retaining any free liquid that might escape during carriage, e.g. absorbent material. Packagings, discarded, empty, uncleaned with residues of Class 5.1 shall be carried in bulk containers which have been so constructed or adapted that the goods cannot come into contact with wood or any other combustible material. 7.3.3 Provisions for carriage in bulk when the provisions of 7.3.1.1 (b) are applied 7.3.3.1 In addition to the general provisions of section 7.3.1, the provisions of this section are applicable, when they are shown under an entry in column (17) of Table A of Chapter 3.2. Sheeted or closed vehicles or sheeted or closed containers used under this section need not be in conformity with the requirements of Chapter 6.11. The codes VC1, VC2 and VC3 in column (17) of Table A of Chapter 3.2 have the following meanings: VC1 Carriage in bulk in sheeted vehicles, sheeted containers or sheeted bulk containers is permitted; VC2 Carriage in bulk in closed vehicles, closed containers or closed bulk containers is permitted; VC3 Carriage in bulk is permitted in specially equipped vehicles or containers in accordance with standards specified by the competent authority of the country of origin. If the country of origin is not a Contracting Party to ADR, the conditions laid down shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. 7.3.3.2 When the VC bulk codes are used, the following additional provisions shown in column (17) of Table A of Chapter 3.2 shall apply: 7.3.3.2.1 Goods of Class 4.1 AP1 Vehicles and containers shall have a metal body and where fitted the sheet shall be noncombustible. AP2 Vehicles and containers shall have adequate ventilation. - 526 - 7.3.3.2.2 Goods of Class 4.2 AP1 7.3.3.2.3 Vehicles and containers shall have a metal body and where fitted the sheet shall be noncombustible. Goods of Class 4.3 AP2 Vehicles and containers shall have adequate ventilation. AP3 Sheeted vehicles and sheeted containers shall be used only when the substance is in pieces (not in powder, granular, dust or ashes form). AP4 Closed vehicles and closed containers shall be equipped with hermetically closed openings used for loading and unloading to prevent the exit of gas and exclude the ingress of moisture. AP5 The cargo doors of the closed vehicles or closed containers shall be marked with the following in letters not less than 25 mm high: "WARNING NO VENTILATION OPEN WITH CAUTION" This shall be in a language considered appropriate by the consignor. 7.3.3.2.4 7.3.3.2.5 Goods of Class 5.1 AP6 If the vehicle or container is made of wood or other combustible material, an impermeable surfacing resistant to combustion or a coating of sodium silicate or similar substance shall be provided. Sheeting shall also be impermeable and non-combustible. AP7 Carriage in bulk shall only be as a full load. Goods of Class 6.1 AP7 7.3.3.2.6 Carriage in bulk shall only be as a full load. Goods of Class 8 AP7 Carriage in bulk shall only be as a full load. AP8 The design of the load compartment of vehicles or containers shall take account of any residual currents and impacts from the batteries. The load compartments of vehicles or containers shall be of steel resistant to the corrosive substances contained in the batteries. Less resistant steels may be used when there is a sufficiently great wall thickness or a plastics lining/layer resistant to the corrosive substances. NOTE: Steel exhibiting a maximum rate of progressive reduction of 0.1 mm per year under the effects of the corrosive substances may be considered as resistant. The load compartments of vehicles or containers shall not be loaded above the top of their walls. Carriage is also permitted in small plastics containers which shall be capable of withstanding, when fully loaded, a drop from a height of 0.8 m onto a hard surface at -18 °C, without breakage. - 527 - 7.3.3.2.7 Goods of Class 9 AP2 Vehicles and containers shall have adequate ventilation. AP9 Carriage in bulk is permitted for solids (substances or mixtures, such as preparations or wastes) containing on average not more than 1 000 mg/kg of substance to which this UN number is assigned. At no point of the load shall the concentration of this substance or these substances be higher than 10 000 mg/kg. AP10 Vehicles and containers shall be made leak tight or fitted with a leak tight and puncture resistant sealed liner or bag, and shall have a means of retaining any free liquid that might escape during carriage, e.g. absorbent material. Packagings, discarded, empty, uncleaned with residues of Class 5.1 shall be carried in vehicles and containers which have been so constructed or adapted that the goods cannot come into contact with wood or any other combustible material. - 528 - CHAPTER 7.4 PROVISIONS CONCERNING CARRIAGE IN TANKS 7.4.1 Dangerous goods may not be carried in tanks unless a code is indicated in Columns (10) or (12) of Table A of Chapter 3.2 or unless a competent authority approval is granted as detailed in 6.7.1.3. The carriage shall be in accordance with the provisions of Chapters 4.2, 4.3, 4.4 or 4.5 as applicable. The vehicles, whether they be rigid vehicles, drawing vehicles, trailers or semi-trailers, shall satisfy the relevant requirements of Chapters 9.1, 9.2 and 9.7.2 concerning the vehicle to be used, as indicated in Column (14) of Table A in Chapter 3.2. 7.4.2 The vehicles designated by the codes EX/III, FL, OX or AT in 9.1.1.2 shall be used as follows: - Where an EX/III vehicle is prescribed, only an EX/III vehicle may be used; - Where a FL vehicle is prescribed, only an FL vehicle may be used; - Where a OX vehicle is prescribed, only an OX vehicle may be used; - Where a AT vehicle is prescribed, AT, FL and OX vehicles may be used. - 529 - CHAPTER 7.5 PROVISIONS CONCERNING LOADING, UNLOADING AND HANDLING 7.5.1 General provisions concerning loading, unloading and handling NOTE: Within the meaning of this section, placing a container, bulk-container, tank-container or portable tank onto a vehicle is considered as loading, and removing it is considered as unloading. 7.5.1.1 The vehicle and its driver, as well as the large container(s), bulk-container(s), tank-container(s) or portable tank(s) if any, shall comply with the regulatory provisions (especially those concerning safety, security, cleanliness and satisfactory operation of the equipment used in loading and unloading) upon arrival at the loading and unloading sites, which include container terminals. 7.5.1.2 Unless otherwise specified in ADR, the loading shall not be carried out if: (a) an examination of the documents; or (b) a visual inspection of the vehicle or of the large container(s), bulk-container(s), tankcontainer(s) or portable tank(s) if any, as well as of their equipment used in loading and unloading, shows that the vehicle, the driver, a large container, a bulk-container, a tank-container, a portable tank or their equipment do not comply with the regulatory provisions. The interior and exterior of a vehicle or container shall be inspected prior to loading to ensure that there is no damage that could affect its integrity or that of the packages to be loaded in it. 7.5.1.3 Unless otherwise specified in ADR, the unloading shall not be carried out, if the above-mentioned inspections reveal deficiencies that might affect the safety or the security of the unloading. 7.5.1.4 In accordance with the special provisions of 7.3.3 or 7.5.11, in conformity with Columns (17) and (18) of Table A of Chapter 3.2, certain dangerous goods shall only be forwarded as a "full load" (see definition in 1.2.1). In such a case, the competent authorities may require the vehicle or large container used for such carriage to be loaded at only one point and unloaded at only one point. 7.5.1.5 When orientation arrows are required packages and overpacks shall be oriented in accordance with such markings. NOTE: Liquid dangerous goods shall be loaded below dry dangerous goods whenever practicable. 7.5.1.6 All means of containment shall be loaded and unloaded in conformity with a handling method for which they have been designed and, where required, tested. 7.5.2 Mixed loading prohibition 7.5.2.1 Packages bearing different danger labels shall not be loaded together in the same vehicle or container unless mixed loading is permitted according to the following Table based on the danger labels they bear. NOTE: In accordance with 5.4.1.4.2, separate transport documents shall be drawn up for consignments that cannot be loaded together in the same vehicle or container. - 531 - Labels Nos. 1 1.4 1.5 1.6 2.1, 2.2, 2.3 3 4.1 4.1 +l 4.2 4.3 5.1 5.2 5.2 +1 6.1 6.2 7 A, B, C 8 d 1 a 1.4 a a a a a 9 b a a a a a a b See 7.5.2.2 c 1.5 b 1.6 b 2.1, 2.2, 2.3 a X X X X X X X X X X X X 3 a X X X X X X X X X X X X 4.1 a X X X X X X X X X X X X X 4.1 + 1 4.2 a X X X X X X X X X X X X 4.3 a X X X X X X X X X X X X a X X X X X X X X X X X X a X X X X X X X X X X X X X X X d 5.1 5.2 5.2 + 1 6.1 a X X X X X X X X X X X X 6.2 a X X X X X X X X X X X X 7A, B, C a X X X X X X X X X X X X 8 a X X X X X X X X X X X X X X X X X X X X X X X X 9 b a b b b c X Mixed loading permitted. a Mixed loading permitted with 1.4S substances and articles. b Mixed loading permitted between goods of Class 1 and life-saving appliances of Class 9 (UN Nos. 2990, 3072 and 3268). c Mixed loading permitted between safety devices, pyrotechnic of Division 1.4, compatibility group G, (UN No. 0503) and safety devices, electrically initiated of Class 9 (UN No. 3268). d Mixed loading permitted between blasting explosives (except UN No. 0083 explosive, blasting, type C) and ammonium nitrate (UN Nos. 1942 and 2067) and alkali metal nitrates and alkaline earth metal nitrates provided the aggregate is treated as blasting explosives under Class 1 for the purposes of placarding, segregation, stowage and maximum permissible load. Alkali metal nitrates include caesium nitrate (UN 1451), lithium nitrate (UN 2722), potassium nitrate (UN 1486), rubidium nitrate (UN 1477) and sodium nitrate (UN 1498). Alkaline earth metal nitrates include barium nitrate (UN 1446), beryllium nitrate (UN 2464), calcium nitrate (UN 1454), magnesium nitrate (UN 1474) and strontium nitrate (UN 1507). - 532 - 7.5.2.2 Packages containing substances or articles of Class 1, bearing a label conforming to models Nos. 1, 1.4, 1.5 or 1.6 which are assigned to different compatibility groups shall not be loaded together in the same vehicle or container, unless mixed loading is permitted in accordance with the following Table for the corresponding compatibility groups. Compatibility Group A A X B B X C D C a E D E F G H J L N X a X X X X b c X X X X X b c X X X X X b c X X F X G S X X X X X X H X X J X d L N b c b c b c X X X X X X X X X S X X Mixed loading permitted. a Packages containing articles of compatibility group B and those containing substances or articles of compatibility group D may be loaded together on one vehicle or in one container provided they are effectively segregated such that there is no danger of transmission of detonation from the articles of compatibility group B to the substances or articles of compatibility group D. Segregation shall be achieved by the use of separate compartments or by placing one of the two types of explosive in a special containment system. Either method of segregation shall be approved by the competent authority. b Different types of articles of division 1.6, compatibility group N, may be carried together as articles of division 1.6, compatibility group N, only when it is proven by testing or analogy that there is no additional risk of sympathetic detonation between the articles. Otherwise they should be treated as hazard division 1.1. c When articles of compatibility group N are carried with substances or articles of compatibility groups C, D or E, the articles of compatibility group N should be considered as having the characteristics of compatibility group D. d Packages containing substances and articles of Compatibility Group L may be loaded together on one vehicle or in one container with packages containing the same type of substances and articles of that compatibility group. - 533 - X b 7.5.2.3 For the purpose of the application of the prohibitions of mixed loading on one vehicle, no account shall be taken of substances contained in closed containers with complete sides. Nevertheless, the mixed loading prohibitions laid down in 7.5.2.1 concerning mixed loading of packages bearing labels conforming to models Nos. 1, 1.4, 1.5 or 1.6 with other packages, and in 7.5.2.2 concerning mixed loading of explosives of different compatibility groups shall also apply between dangerous goods contained in a container and the other dangerous goods loaded on the same vehicle, whether or not the latter goods are enclosed in one or more other containers. 7.5.2.4 Mixed loading of dangerous goods packed in limited quantities with any type of explosive substances and articles, except those of Division 1.4 and UN Nos. 0161 and 0499, is prohibited. 7.5.3 (Reserved) 7.5.4 Precautions with respect to foodstuffs, other articles of consumption and animal feeds If special provision CV28 is indicated for a substance or article in Column (18) of Table A of Chapter 3.2, precautions with respect to foodstuffs, other articles of consumption and animal feeds shall be taken as follows. Packages as well as uncleaned empty packagings, including large packagings and intermediate bulk containers (IBCs), bearing labels conforming to models Nos. 6.1 or 6.2 and those bearing labels conforming to model No. 9 containing goods of UN Nos. 2212, 2315, 2590, 3151, 3152 or 3245, shall not be stacked on or loaded in immediate proximity to packages known to contain foodstuffs, other articles of consumption or animal feeds in vehicles, in containers and at places of loading, unloading or transhipment. When these packages, bearing the said labels, are loaded in immediate proximity of packages known to contain foodstuffs, other articles of consumption or animal feeds, they shall be kept apart from the latter: (a) By complete partitions which should be as high as the packages bearing the said labels; (b) By packages not bearing labels conforming to models Nos. 6.1, 6.2 or 9 or packages bearing labels conforming to model No.9 but not containing goods of UN Nos. 2212, 2315, 2590, 3151, 3152 or 3245; or (c) By a space of at least 0.8 m; unless the packages bearing the said labels are provided with an additional packaging or are completely covered (e.g. by a sheeting, a fibreboard cover or other measures). 7.5.5 Limitation of the quantities carried 7.5.5.1 If the provisions below, or the additional provisions of 7.5.11 to be applied according to Column (18) of Table A of Chapter 3.2 require a limitation of the quantity of specific goods that can be carried, the fact that dangerous goods are contained in one or more containers shall not affect the mass limitations per transport unit laid down by these provisions. 7.5.5.2 Limitations with respect to explosive substances and articles 7.5.5.2.1 Substances and quantities carried The total net mass in kg of explosive substance (or in the case of explosive articles, the total net mass of explosive substance contained in all the articles combined) which may be carried on one transport unit shall be limited as indicated in the table below (see also 7.5.2.2 as regards the prohibition of mixed loading): - 534 - Maximum permissible net mass in kg of explosive in Class 1 goods per transport unit Transport Unit Division 1.1 Compatibility 1.1A group EX/II a EX/III a a 1.2 1.3 Other than 1.1A 1.4 Other than 1.4S 1.4S 1.5 and 1.6 Empty uncleaned packagings 6.25 1 000 3 000 5 000 15 000 Unlimited 5 000 Unlimited 18.75 16 000 16 000 16 000 16 000 Unlimited 16 000 Unlimited For the description of EX/II and EX/III vehicles see Part 9. 7.5.5.2.2 Where substances and articles of different divisions of Class 1 are loaded on one transport unit in conformity with the prohibitions of mixed loading contained in 7.5.2.2, the load as a whole shall be treated as if it belonged to the most dangerous division (in the order 1.1, 1.5, 1.2, 1.3, 1.6, 1.4). However, the net mass of explosives of compatibility group S shall not count towards the limitation of quantities carried. Where substances classified as 1.5D are carried on one transport unit together with substances or articles of division 1.2, the entire load shall be treated for carriage as if it belonged to division 1.1. 7.5.5.2.3 Carriage of explosives on MEMUs Carriage of explosives on MEMUs is only permitted subject to the following conditions: (a) The competent authority shall authorize the transport operation within its territory; (b) The type and quantity of packaged explosives carried shall be limited to those necessary for the quantity of material to be manufactured on the MEMU, and in any case shall not exceed: - 200 kg of explosives of compatibility group D; and - a total of 400 units of detonators or detonator assemblies, or a mixture of both, unless otherwise approved by the competent authority; (c) Packaged explosives shall only be carried in compartments that meet the requirements of 6.12.5; (d) No other dangerous goods may be carried in the same compartment as the packaged explosives; (e) Packaged explosives shall only be loaded onto the MEMU once the loading of other dangerous goods has been completed and immediately prior to carriage; (f) 7.5.5.3 7.5.6 When mixed loading is permitted between explosives and substances of Class 5.1 (UN 1942 and UN 3375) the aggregate is treated as blasting explosives under Class 1 for the purposes of segregation, stowage and maximum permissible load. The maximum quantity of organic peroxides of Class 5.2 and self-reactive substances of Class 4.1 of Types B, C, D, E or F is limited to 20 000 kg per transport unit. (Reserved) - 535 - 7.5.7 Handling and stowage 7.5.7.1 Where appropriate the vehicle or container shall be fitted with devices to facilitate securing and handling of the dangerous goods. Packages containing dangerous substances and unpackaged dangerous articles shall be secured by suitable means capable of restraining the goods (such as fastening straps, sliding slatboards, adjustable brackets) in the vehicle or container in a manner that will prevent any movement during carriage which would change the orientation of the packages or cause them to be damaged. When dangerous goods are carried with other goods (e.g. heavy machinery or crates), all goods shall be securely fixed or packed in the vehicles or containers so as to prevent the release of dangerous goods. Movement of packages may also be prevented by filling any voids by the use of dunnage or by blocking and bracing. Where restraints such as banding or straps are used, these shall not be over-tightened to cause damage or deformation of the package1. The requirements of this paragraph are deemed to be complied with if the cargo is secured in accordance with standard EN 12195-1:2010. 7.5.7.2 Packages shall not be stacked unless designed for that purpose. Where different design types of packages that have been designed for stacking are to be loaded together, consideration shall be given to their compatibility for stacking with each other. Where necessary, stacked packages shall be prevented from damaging the package below by the use of load-bearing devices. 7.5.7.3 During loading and unloading, packages containing dangerous goods shall be protected from being damaged. NOTE: Particular attention shall be paid to the handling of packages during their preparation for carriage, the type of vehicle or container on which they are to be carried and to the method of loading or unloading, so that accidental damage is not caused through dragging or mishandling the packages. 7.5.7.4 The provisions of 7.5.7.1 also apply to the loading, stowage and unloading of containers, tankcontainers, portable tanks and MEGCs on to and from vehicles. 7.5.7.5 Members of the vehicle crew may not open a package containing dangerous goods. 1 Guidance on the stowage of dangerous goods can be found in the European Best Practice Guidelines on Cargo Securing for Road Transport published by the European Commission. Other guidance is also available from competent authorities and industry bodies. - 536 - 7.5.8 Cleaning after unloading 7.5.8.1 If, when a vehicle or container which has contained packaged dangerous goods is unloaded, some of the contents are found to have escaped, the vehicle or container shall be cleaned as soon as possible and in any case before reloading. If it is not possible to do the cleaning locally, the vehicle or container shall be carried, with due regard to adequate safety, to the nearest suitable place where cleaning can be carried out. 7.5.8.2 Carriage is adequately safe if suitable measures have been taken to prevent the uncontrolled release of the dangerous goods that have escaped. Vehicles or containers which have been loaded with dangerous goods in bulk shall be properly cleaned before reloading unless the new load consists of the same dangerous goods as the preceding load. 7.5.9 Prohibition of smoking Smoking shall be prohibited during handling operations in the vicinity of vehicles or containers and inside the vehicles or containers. This prohibition of smoking is also applicable to the use of electronic cigarettes and similar devices. 7.5.10 Precautions against electrostatic charges In the case of flammable gases, or liquids with a flash-point of 60 °C or below, or UN No. 1361, carbon or carbon black, packing group II, a good electrical connection from the chassis of the vehicle, the portable tank or the tank-container to earth shall be established before tanks are filled or emptied. In addition, the rate of filling shall be limited. 7.5.11 Additional provisions applicable to certain classes or specific goods In addition to the provisions of sections 7.5.1 to 7.5.10, the following provisions shall apply when they are shown under an entry indicated in Column (18) of Table A of Chapter 3.2. CV1 (1) The following operations are prohibited: (a) Loading or unloading goods in a public place in a built-up area without special permission from the competent authorities; (b) Loading or unloading goods in a public place elsewhere than in a built-up area without prior notice thereof having been given to the competent authorities, unless these operations are urgently necessary for reasons of safety. CV2 (2) If, for any reason, handling operations have to be carried out in a public place, then substances and articles of different kinds shall be separated according to the labels. (1) Before loading, the loading surface of the vehicle or container shall be thoroughly cleaned. (2) The use of fire or naked flame shall be prohibited on vehicles and containers carrying goods, in their vicinity and during the loading and unloading of these goods. CV3 See 7.5.5.2. CV4 Substances and articles of compatibility group L shall only be carried as a full load. CV5 to CV8 CV9 (Reserved) Packages shall not be thrown or subjected to impact. Receptacles shall be so stowed in the vehicle or container that they cannot overturn or fall. - 537 - CV10 Cylinders as defined in 1.2.1, shall be laid parallel to or at right angles to the longitudinal axis of the vehicle or container; however, those situated near the forward transverse wall shall be laid at right angles to the said axis. Short cylinders of large diameter (about 30 cm and over) may be stowed longitudinally with their valve-protecting devices directed towards the middle of the vehicle or container. Cylinders which are sufficiently stable or are carried in suitable devices effectively preventing them from overturning may be placed upright. Cylinders which are laid flat shall be securely and appropriately wedged, attached or secured so that they cannot shift. CV11 Receptacles shall always be placed in the position for which they were designed and be protected against any possibility of being damaged by other packages. CV12 When pallets loaded with articles are stacked, each tier of pallets shall be evenly distributed over the lower tier, if necessary by the interposition of a material of adequate strength. CV13 If any substances have leaked and been spilled in a vehicle or container, it may not be reused until after it has been thoroughly cleaned and, if necessary, disinfected or decontaminated. Any other goods and articles carried in the same vehicle or container shall be examined for possible contamination. CV14 Goods shall be shielded from direct sunlight and heat during carriage. Packages shall be stored only in cool, well-ventilated places away from heat sources. CV15 See 7.5.5.3. CV16 to CV19 (Reserved) CV20 The provisions of Chapter 5.3 and special provisions V1 and V8(5) and (6) of Chapter 7.2 shall not apply provided that the substance is packaged in accordance with packing method OP1 or OP2 of packing instruction P520 in 4.1.4.1, as required, and the total quantity of substances to which this derogation applies per transport unit is limited to 10 kg. CV21 The transport unit shall be thoroughly inspected prior to loading. Before carriage, the carrier shall be informed: - about the operation of the refrigeration system, including a list of the suppliers of coolant available en route; - procedures to be followed in the event of loss of temperature control. In the case of temperature control in accordance with methods R2 or R4 of special provision V8(3) of Chapter 7.2, a sufficient quantity of non-flammable refrigerant (e.g. liquid nitrogen or dry ice), including a reasonable margin for possible delays, shall be carried unless a means of replenishment is assured. Packages shall be so stowed as to be readily accessible. The specified control temperature shall be maintained during the whole transport operation, including loading and unloading, as well as any intermediate stops. CV22 Packages shall be loaded so that a free circulation of air within the loading space provides a uniform temperature of the load. If the contents of one vehicle or large container exceed 5 000 kg of flammable solids and/or organic peroxides, the load shall be divided into stacks of not more than 5 000 kg separated by air spaces of at least 0.05 m. - 538 - CV23 When handling packages, special measures shall be taken to ensure that they do not come into contact with water. CV24 Before loading, vehicles and containers shall be thoroughly cleaned and in particular be free of any combustible debris (straw, hay, paper, etc.). The use of readily flammable materials for stowing packages is prohibited. CV25 (1) Packages shall be so stowed that they are readily accessible. (2) When packages are to be carried at an ambient temperature of not more than 15 °C or refrigerated, the temperature shall be maintained when unloading or during storage. (3) Packages shall be stored only in cool places away from sources of heat. CV26 The wooden parts of a vehicle or container which have come into contact with these substances shall be removed and burnt. CV27 (1) Packages shall be so stowed that they are readily accessible. (2) When packages are to be carried refrigerated, the functioning of the cooling chain shall be ensured when unloading or during storage. (3) Packages shall only be stored in cool places away from sources of heat. CV28 See 7.5.4. CV29 to CV32 CV33 (Reserved) NOTE 1: "Critical group" means a group of members of the public which is reasonably homogeneous with respect to its exposure for a given radiation source and given exposure pathway and is typical of individual receiving the highest effective dose by the given exposure pathway from the given source. NOTE 2: "Members of the public" means in a general sense, any individuals in the population except when subject to occupational or medical exposure. NOTE 3: "Workers" are any persons who work, whether full time, part-time or temporarily, for an employer and who have recognised rights and duties in relation to occupational radiation protection. (1) Segregation (1.1) Packages, overpacks, containers and tanks containing radioactive material and unpacked radioactive material shall be segregated during carriage: (a) from workers in regularly occupied working areas: (i) in accordance with Table A below; or (ii) by distances calculated using a dose criterion of 5 mSv in a year and conservative model parameters; NOTE: Workers subject to individual monitoring for the purposes of radiation protection shall not be considered for the purposes of segregation. (b) from members of the public, in areas where the public has regular access: (i) in accordance with Table A below; or (ii) by distances calculated using a dose criterion of 1 mSv in a year and conservative model parameters; - 539 - (c) from undeveloped photographic film and mailbags: (i) in accordance with Table B below; or (ii) by distances calculated using a radiation exposure criterion for undeveloped photographic film due to the transport of radioactive material for 0.1 mSv per consignment of such film; and NOTE: Mailbags shall be assumed to contain undeveloped film and plates and therefore be separated from radioactive material in the same way. (d) Table A: from other dangerous goods in accordance with 7.5.2. Minimum distances between packages of category II-YELLOW or of category III-YELLOW and persons Sum of transport indexes not more than 2 4 8 12 20 30 40 50 Table B: Exposure time per year (hours) Areas where members of the Regularly occupied working public have regular access areas 50 250 50 250 Segregation distance in metres, no shielding material intervening, from: 1 3 0.5 1 1.5 4 0.5 1.5 2.5 6 1.0 2.5 3 7.5 1.0 3 4 9.5 1.5 4 5 12 2 5 5.5 13.5 2.5 5.5 6.5 15.5 3 6.5 Minimum distances between packages of category II-YELLOW or of category III-YELLOW and packages bearing the word "FOTO", or mailbags Total number of Sum of packages not transport more than indexes not more than Category IIIIIyellow yellow 0.2 0.5 1 1 2 2 4 4 8 8 1 10 10 2 20 20 3 30 30 4 40 40 5 50 50 Journey or storage duration, in hours 1 2 4 10 24 48 120 240 2 3 5 7 9 13 14 20 25 30 32 3 5 7 9 13 18 20 30 35 40 45 Minimum distances in metres 0.5 0.5 0.5 0.5 1 1 1 1.5 2 3 3 0.5 0.5 0.5 1 1 1.5 2 3 3 4 4 0.5 0.5 1 1 1.5 2 3 4 5 5 6 0.5 1 1 1.5 3 4 4 6 7 8 9 1 1 2 3 4 6 7 9 11 13 14 1 2 3 4 6 8 9 13 16 18 20 (1.2) Category II-YELLOW or III-YELLOW packages or overpacks shall not be carried in compartments occupied by passengers, except those exclusively reserved for couriers specially authorized to accompany such packages or overpacks. - 540 - (1.3) No persons other than members of the vehicle crew shall be permitted in vehicles carrying packages, overpacks or containers bearing category IIYELLOW or III-YELLOW labels. (2) Activity limits The total activity in a vehicle, for carriage of LSA material or SCO in Industrial Packages Type 1 (Type IP-1), Type 2 (Type IP-2), Type 3 (Type IP-3) or unpackaged, shall not exceed the limits shown in Table C below. Table C: Vehicle activity limits for LSA industrial packages or unpackaged Nature of material or object LSA-I LSA-II and LSA-III non-combustible solids LSA-II and LSA-III combustible solids, and all liquids and gases SCO (3) material and SCO in Activity limit for vehicle No limit No limit 100 A2 100 A2 Stowage during carriage and storage in transit (3.1) Consignments shall be securely stowed. (3.2) Provided that its average surface heat flux does not exceed 15 W/m2 and that the immediately surrounding cargo is not in bags, a package or overpack may be carried or stored among packaged general cargo without any special stowage provisions except as may be specifically required by the competent authority in an applicable certificate of approval. (3.3) Loading of containers and accumulation of packages, overpacks and containers shall be controlled as follows: (a) Except under the condition of exclusive use, and for consignments of LSA-I material, the total number of packages, overpacks and containers aboard a single vehicle shall be so limited that the total sum of the transport indexes aboard the vehicle does not exceed the values shown in Table D below; (b) The radiation level under routine conditions of carriage shall not exceed 2 mSv/h at any point on, and 0.1 mSv/h at 2 m from, the external surface of the vehicle, except for consignments carried under exclusive use, for which the radiation limits around the vehicle are set forth in (3.5) (b) and (c); (c) The total sum of the criticality safety indexes in a container and aboard a vehicle shall not exceed the values shown in Table E below. - 541 - Table D: Transport Index limits for containers and vehicles not under exclusive use Type of container or vehicle Small container Limit on total sum of transport indexes in a container or aboard a vehicle 50 Large container 50 Vehicle 50 Table E: Criticality Safety Index for containers and vehicles containing fissile material Type of container or vehicle Not under exclusive use Under exclusive use Small container 50 n.a. Large container 50 100 Vehicle 50 100 Limit on total sum of criticality safety indexes (3.4) Any package or overpack having either a transport index greater than 10, or any consignment having a criticality safety index greater than 50, shall be carried only under exclusive use. (3.5) For consignments under exclusive use, the radiation level shall not exceed: (a) (4) 10 mSv/h at any point on the external surface of any package or overpack, and may only exceed 2 mSv/h provided that: (i) the vehicle is equipped with an enclosure which, during routine conditions of carriage, prevents the access of unauthorized persons to the interior of the enclosure; (ii) provisions are made to secure the package or overpack so that its position within the vehicle enclosure remains fixed during routine conditions of carriage, and (iii) there is no loading or unloading during the shipment; (b) 2 mSv/h at any point on the outer surfaces of the vehicle, including the upper and lower surfaces, or, in the case of an open vehicle, at any point on the vertical planes projected from the outer edges of the vehicle, on the upper surface of the load, and on the lower external surface of the vehicle; and (c) 0.1 mSv/h at any point 2 m from the vertical planes represented by the outer lateral surfaces of the vehicle, or, if the load is carried in an open vehicle, at any point 2 m from the vertical planes projected from the outer edges of the vehicle. Additional requirements relating to carriage and storage in transit of fissile material (4.1) Any group of packages, overpacks, and containers containing fissile material stored in transit in any one storage area shall be so limited that the total sum of the CSIs in the group does not exceed 50. Each group shall be stored so as to maintain a spacing of at least 6 m from other such groups. - 542 - (4.2) Where the total sum of the criticality safety indexes on board a vehicle or in a container exceeds 50, as permitted in Table E above, storage shall be such as to maintain a spacing of at least 6 m from other groups of packages, overpacks or containers containing fissile material or other vehicles carrying radioactive material. (4.3) Fissile material meeting one of the provisions (a) to (f) of 2.2.7.2.3.5 shall meet the following requirements: (5) (a) Only one of the provisions (a) to (f) of 2.2.7.2.3.5 is allowed per consignment; (b) Only one approved fissile material in packages classified in accordance with 2.2.7.2.3.5 (f) is allowed per consignment unless multiple materials are authorized in the certificate of approval; (c) Fissile material in packages classified in accordance with 2.2.7.2.3.5 (c) shall be carried in a consignment with no more than 45 g of fissile nuclides; (d) Fissile material in packages classified in accordance with 2.2.7.2.3.5 (d) shall be carried in a consignment with no more than 15 g of fissile nuclides; (e) Unpackaged or packaged fissile material classified in accordance with 2.2.7.2.3.5 (e) shall be carried under exclusive use on a vehicle with no more than 45 g of fissile nuclides. Damaged or leaking packages, contaminated packagings (5.1) If it is evident that a package is damaged or leaking, or if it is suspected that the package may have leaked or been damaged, access to the package shall be restricted and a qualified person shall, as soon as possible, assess the extent of contamination and the resultant radiation level of the package. The scope of the assessment shall include the package, the vehicle, the adjacent loading and unloading areas, and, if necessary, all other material which has been carried in the vehicle. When necessary, additional steps for the protection of persons property and the environment, in accordance with provisions established by the competent authority, shall be taken to overcome and minimize the consequences of such leakage or damage. (5.2) Packages damaged or leaking radioactive contents in excess of allowable limits for normal conditions of carriage may be removed to an acceptable interim location under supervision, but shall not be forwarded until repaired or reconditioned and decontaminated. (5.3) A vehicle and equipment used regularly for the carriage of radioactive material shall be periodically checked to determine the level of contamination. The frequency of such checks shall be related to the likelihood of contamination and the extent to which radioactive material is carried. - 543 - (5.4) Except as provided in paragraph (5.5), any vehicle, or equipment or part thereof which has become contaminated above the limits specified in 4.1.9.1.2 in the course of carriage of radioactive material, or which shows a radiation level in excess of 5 µSv/h at the surface, shall be decontaminated as soon as possible by a qualified person and shall not be re-used unless the following conditions are fulfilled: (a) the non-fixed contamination shall not exceed the limits specified in 4.1.9.1.2; (b) the radiation level resulting from the fixed contamination shall not exceed 5 Sv/h at the surface. (5.5) A container, tank, intermediate bulk container or vehicle dedicated to the carriage of unpackaged radioactive material under exclusive use shall be excepted from the requirements of the previous paragraph (5.4) and in 4.1.9.1.4 solely with regard to its internal surfaces and only for as long as it remains under that specific exclusive use. (6) Other provisions Where a consignment is undeliverable, the consignment shall be placed in a safe location and the competent authority shall be informed as soon as possible and a request made for instructions on further action. CV34 Prior to carriage of pressure receptacles it shall be ensured that the pressure has not risen due to potential hydrogen generation. CV35 If bags are used as single packagings, they shall be adequately separated to allow for the dissipation of heat. CV36 Packages shall preferably be loaded in open or ventilated vehicles or open or ventilated containers. If this is not feasible and packages are carried in other closed vehicles or containers, the cargo doors of the vehicles or containers shall be marked with the following in letters not less than 25 mm high: "WARNING NO VENTILATION OPEN WITH CAUTION" This shall be in a language considered appropriate by the consignor. CV37 Before carriage, aluminium smelting by-products or aluminium remelting by-products shall be cooled to ambient temperature prior to loading. Sheeted vehicles and sheeted containers shall be waterproof. The cargo doors of the closed vehicles and closed containers shall be marked with the following in letters not less than 25 mm high: "WARNING CLOSED MEANS OF CONTAINMENT OPEN WITH CAUTION" This shall be in a language considered appropriate by the consignor. - 544 - ANNEX B PROVISIONS CONCERNING TRANSPORT EQUIPMENT AND TRANSPORT OPERATIONS PART 8 Requirements for vehicle crews, equipment, operation and documentation CHAPTER 8.1 GENERAL REQUIREMENTS CONCERNING TRANSPORT UNITS AND EQUIPMENT ON BOARD 8.1.1 Transport units A transport unit loaded with dangerous goods may in no case include more than one trailer (or semi-trailer). 8.1.2 Documents to be carried on the transport unit 8.1.2.1 In addition to the documents required under other regulations, the following documents shall be carried on the transport unit: 8.1.2.2 (a) The transport documents prescribed in 5.4.1, covering all the dangerous goods carried and, when appropriate, the large container or vehicle packing certificate prescribed in 5.4.2; (b) The instructions in writing prescribed in 5.4.3; (c) (Reserved); (d) Means of identification, which include a photograph, for each member of the vehicle crew, in accordance with 1.10.1.4. Where the provisions of ADR require the following documents to be drawn up, they shall likewise be carried on the transport unit: (a) The certificate of approval referred to in 9.1.3 for each transport unit or element thereof; (b) The driver's training certificate prescribed in 8.2.1; (c) A copy of the competent authority approval, when required in 5.4.1.2.1 (c) or (d) or 5.4.1.2.3.3. 8.1.2.3 The instructions in writing prescribed in 5.4.3 shall be kept readily available. 8.1.2.4 (Deleted) 8.1.3 Placarding and marking Transport units carrying dangerous goods shall be placarded and marked in conformity with Chapter 5.3. 8.1.4 Fire-fighting equipment 8.1.4.1 The following table shows the minimum provisions for portable fire extinguishers for the inflammability Classes1 A, B and C that apply to transport units carrying dangerous goods except for those referred to in 8.1.4.2: 1 For the definition of the inflammability classes, see Standard EN 2:1992 + A1:2004 Classification of fires. - 549 - (1) Transport unit maximum permissible mass ≤ 3.5 tonnes (4) (5) (3) (2) Extinguisher suitable for Additional Minimum Minimum extinguisher(s) number of total capacity engine or cab fire. At least per transport one with a minimum requirement. At least fire unit capacity of: one extinguisher shall extinguishers have a minimum capacity of: 2 4 kg 2 kg 2 kg > 3.5 tonnes ≤ 7.5 tonnes 2 8 kg 2 kg 6 kg >7.5 tonnes 2 12 kg 2 kg 6 kg The capacities are for dry powder devices (or an equivalent capacity for any other suitable extinguishing agent). 8.1.4.2 Transport units carrying dangerous goods in accordance with 1.1.3.6 shall be equipped with one portable fire extinguisher for the inflammability classes1 A, B and C, with a minimum capacity of 2 kg dry powder (or an equivalent capacity for any other suitable extinguishing agent). 8.1.4.3 The portable fire extinguishers shall be suitable for use on a vehicle and shall comply with the relevant requirements of EN 3 Portable fire extinguishers, Part 7 (EN 3-7:2004 + A1:2007). If the vehicle is equipped with a fixed fire extinguisher, automatic or easily brought into action for fighting a fire in the engine, the portable extinguisher need not be suitable for fighting a fire in the engine. The extinguishing agents shall be such that they are not liable to release toxic gases into the driver’s cab or under the influence of the heat of the fire. 8.1.4.4 The portable fire extinguishers conforming to the provisions of 8.1.4.1 or 8.1.4.2 shall be fitted with a seal which allows verifying that they have not been used. The fire extinguishers shall be subjected to inspections in accordance with authorized national standards in order to guarantee their functional safety. They shall bear a mark of compliance with a standard recognized by a competent authority and a marking indicating the date (month, year) of the next inspection or of the maximum permissible period of use, as applicable. 8.1.4.5 The fire extinguishers shall be installed on the transport units in a way that they are easily accessible to the vehicle crew. The installation shall be carried out in such a way that the fire extinguishers shall be protected against effects of the weather so that their operational safety is not affected. During carriage, the date required in 8.1.4.4 shall not have expired. 8.1.5 Miscellaneous equipment and equipment for personal protection 8.1.5.1 Each transport unit carrying dangerous goods shall be provided with items of equipment for general and personal protection in accordance with 8.1.5.2. The items of equipment shall be selected in accordance with the danger label number of the goods loaded. The label numbers can be identified through the transport document. 8.1.5.2 The following equipment shall be carried on board the transport unit: - For each vehicle, a wheel chock of a size suited to the maximum mass of the vehicle and to the diameter of the wheel; - Two self-standing warning signs; - Eye rinsing liquid2; and for each member of the vehicle crew 1 For the definition of the inflammability classes, see Standard EN 2:1992 + A1:2004 Classification of fires. 2 Not required for danger label numbers 1, 1.4, 1.5, 1.6, 2.1, 2.2 and 2.3. - 550 - 8.1.5.3 3 4 - A warning vest (e.g. as described in the EN 471:2003 + A1:2007 standard); - Portable lighting apparatus conforming to the provisions of 8.3.4; - A pair of protective gloves; and - Eye protection (e.g. protective goggles). Additional equipment required for certain classes: - An emergency escape mask3 for each member of the vehicle crew shall be carried on board the vehicle for danger label numbers 2.3 or 6.1; - A shovel4; - A drain seal4; - A collecting container4. For example an emergency escape mask with a combined gas/dust filter of the A1B1E1K1-P1 or A2B2E2K2-P2 type which is similar to that described in the EN 141 standard. Only required for solids and liquids with danger label numbers 3, 4.1, 4.3, 8 or 9. - 551 - CHAPTER 8.2 REQUIREMENTS CONCERNING THE TRAINING OF THE VEHICLE CREW 8.2.1 Scope and general requirements concerning the training of drivers 8.2.1.1 Drivers of vehicles carrying dangerous goods shall hold a certificate issued by the competent authority stating that they have participated in a training course and passed an examination on the particular requirements that have to be met during carriage of dangerous goods. 8.2.1.2 Drivers of vehicles carrying dangerous goods shall attend a basic training course. Training shall be given in the form of a course approved by the competent authority. Its main objectives are to make drivers aware of hazards arising in the carriage of dangerous goods and to give them basic information indispensable for minimizing the likelihood of an incident taking place and, if it does, to enable them to take measures which may prove necessary for their own safety and that of the public and the environment, for limiting the effects of an incident. This training, which shall include individual practical exercises, shall act as the basis of training for all categories of drivers covering at least the subjects defined in 8.2.2.3.2. The competent authority may approve basic training courses limited to specific dangerous goods or to a specific class or classes. These restricted basic training courses shall not confer the right to attend the training courses referred to in 8.2.1.4. 8.2.1.3 Drivers of vehicles or MEMUs carrying dangerous goods in fixed tanks or demountable tanks with a capacity exceeding 1 m3, drivers of battery-vehicles with a total capacity exceeding 1 m3 and drivers of vehicles or MEMUs carrying dangerous goods in tank-containers, portable tanks or MEGCs with an individual capacity exceeding 3 m3 on a transport unit, shall attend a specialization training course for carriage in tanks covering at least the subjects defined in 8.2.2.3.3. The competent authority may approve tank specialization training courses limited to specific dangerous goods or to a specific class or classes. These restricted tank specialization training courses shall not confer the right to attend the training courses referred to in 8.2.1.4. 8.2.1.4 Drivers of vehicles carrying dangerous goods of Class 1, other than substances and articles of Division 1.4, compatibility group S, or Class 7 shall attend specialization training courses covering at least the subjects defined in 8.2.2.3.4 or 8.2.2.3.5, as applicable. 8.2.1.5 All training courses, practical exercises, examinations and the role of competent authorities shall comply with the provisions of 8.2.2. 8.2.1.6 All training certificates conforming to the requirements of this section and issued in accordance with 8.2.2.8 by the competent authority of a Contracting Party shall be accepted during their period of validity by the competent authorities of other Contracting Parties. 8.2.2 Special requirements concerning the training of drivers 8.2.2.1 The necessary knowledge and skills shall be imparted by training covering theoretical courses and practical exercises. The knowledge shall be tested in an examination. 8.2.2.2 The training body shall ensure that the training instructors have a good knowledge of, and take into consideration, recent developments in regulations and training requirements relating to the carriage of dangerous goods. The training shall be practice-related. The training programme shall conform with the approval referred to in 8.2.2.6, on the subjects set out in 8.2.2.3.2 to 8.2.2.3.5. The training shall also include individual practical exercises (see 8.2.2.3.8). 8.2.2.3 Structure of training 8.2.2.3.1 Training shall be given in the form of a basic training course and, when applicable, specialization training courses. Basic training courses and specialization training courses may be given in the form of comprehensive training courses, conducted integrally, on the same occasion and by the same training body. - 553 - 8.2.2.3.2 8.2.2.3.3 8.2.2.3.4 8.2.2.3.5 8.2.2.3.6 Subjects to be covered by the basic training course shall be, at least: (a) General requirements governing the carriage of dangerous goods; (b) Main types of hazard; (c) Information on environmental protection in the control of the transfer of wastes; (d) Preventive and safety measures appropriate to the various types of hazard; (e) What to do after an accident (first aid, road safety, basic knowledge about the use of protective equipment, instructions in writing, etc.); (f) Marking, labelling, placarding and orange-coloured plate marking; (g) What a driver should and should not do during the carriage of dangerous goods; (h) Purpose and the method of operation of technical equipment on vehicles; (i) Prohibitions on mixed loading in the same vehicle or container; (j) Precautions to be taken during loading and unloading of dangerous goods; (k) General information concerning civil liability; (l) Information on multimodal transport operations; (m) Handling and stowage of packages; (n) Traffic restrictions in tunnels and instructions on behaviour in tunnels (prevention of incidents, safety, action in the event of fire or other emergencies, etc.); (o) Security awareness. Subjects to be covered by the specialization training course for carriage in tanks shall be, at least: (a) Behaviour of vehicles on the road, including movements of the load; (b) Specific requirements of the vehicles; (c) General theoretical knowledge of the various and different filling and discharge systems; (d) Specific additional provisions applicable to the use of those vehicles (certificates of approval, approval marking, placarding and orange-coloured plate marking, etc.). Subjects to be covered by the specialization training course for the carriage of substances and articles of Class 1 shall be, at least: (a) Specific hazards related to explosive and pyrotechnical substances and articles; (b) Specific requirements concerning mixed loading of substances and articles of Class 1. Subjects to be covered by the specialization training course for the carriage of radioactive material of Class 7 shall be, at least: (a) Specific hazards related to ionizing radiation; (b) Specific requirements concerning packing, handling, mixed loading and stowage of radioactive material; (c) Special measures to be taken in the event of an accident involving radioactive material. Teaching units are intended to last 45 minutes. - 554 - 8.2.2.3.7 Normally, not more than eight teaching units are permitted on each training day. 8.2.2.3.8 The individual practical exercises shall take place in connection with the theoretical training, and shall at least cover first aid, fire-fighting and what to do in case of an incident or accident. 8.2.2.4 Initial training programme 8.2.2.4.1 The minimum duration of the theoretical element of each initial training course or part of the comprehensive training course shall be as follows: Basic training course 18 teaching units Specialization training course for carriage in tanks 12 teaching units Specialization training course for carriage of substances and articles of Class 1 8 teaching units Specialization training course for carriage of radioactive material of Class 7 8 teaching units For the basic training course and the specialization training course for carriage in tanks, additional teaching units are required for practical exercises referred to in 8.2.2.3.8 which will vary depending on the number of drivers under instruction. 8.2.2.4.2 The total duration of the comprehensive training course may be determined by the competent authority, who shall maintain the duration of the basic training course and the specialization training course for tanks, but may supplement it with shortened specialization training courses for Classes 1 and 7. 8.2.2.5 Refresher training programme 8.2.2.5.1 Refresher training undertaken at regular intervals serves the purpose of bringing the drivers' knowledge up to date; it shall cover new technical, legal and substance-related developments. 8.2.2.5.2 The duration of the refresher training including individual practical exercises shall be of at least two days for comprehensive training courses, or at least one half the duration allocated to the corresponding initial basic or initial specialization training courses as specified in 8.2.2.4.1 for individual training courses. 8.2.2.5.3 A driver may replace a refresher training course and examination with the corresponding initial training course and examination. 8.2.2.6 Approval of training 8.2.2.6.1 The training courses shall be subject to approval by the competent authority. 8.2.2.6.2 Approval shall only be given with regard to applications submitted in writing. 8.2.2.6.3 The following documents shall be attached to the application for approval: 8.2.2.6.4 (a) A detailed training programme specifying the subjects taught and indicating the time schedule and planned teaching methods; (b) Qualifications and fields of activities of the teaching personnel; (c) Information on the premises where the courses take place and on the teaching materials as well as on the facilities for the practical exercises; (d) Conditions of participation in the courses, such as number of participants. The competent authority shall organize the supervision of training and examinations. - 555 - 8.2.2.6.5 Approval shall be granted in writing by the competent authority subject to the following conditions: (a) The training shall be given in conformity with the application documents; (b) The competent authority shall be granted the right to send authorized persons to be present at the training courses and examinations; (c) The competent authority shall be advised in time of the dates and the places of the individual training courses; (d) The approval may be withdrawn if the conditions of approval are not complied with. 8.2.2.6.6 The approval document shall indicate whether the courses concerned are basic or specialization training courses, initial or refresher training courses, and whether they are limited to specific dangerous goods or a specific class or classes. 8.2.2.6.7 If the training body, after a training course has been given approval, intends to make any alterations with respect to such details as were relevant to the approval, it shall seek permission in advance from the competent authority. This applies in particular to changes concerning the training programme. 8.2.2.7 Examinations 8.2.2.7.1 Examinations for the basic training course 8.2.2.7.1.1 After completion of the basic training, including the practical exercises, an examination shall be held on the corresponding basic training course. 8.2.2.7.1.2 8.2.2.7.1.3 In the examination, the candidate has to prove that he has the knowledge, insight and skill for the practice of professional driver of vehicles carrying dangerous goods as provided in the basic training course. For this purpose the competent authority shall prepare a catalogue of questions which refer to the items summarized in 8.2.2.3.2. Questions in the examination shall be drawn from this catalogue. The candidates shall not have any knowledge of the questions selected from the catalogue prior to the examination. 8.2.2.7.1.4 A single examination for comprehensive training courses may be held. 8.2.2.7.1.5 Each competent authority shall supervise the modalities of the examination. 8.2.2.7.1.6 The examination shall take the form of a written examination or a combination of a written and oral examination. Each candidate shall be asked at least 25 written questions for the basic training course. If the examination follows a refresher training course, at least 15 written questions shall be asked. The duration of these examinations shall be at least 45 and 30 minutes respectively. The questions may be of a varying degree of difficulty and be allocated a different weighting. 8.2.2.7.2 Examinations for specialization training courses for carriage in tanks or carriage of substances and articles of Class 1 or radioactive material of Class 7 8.2.2.7.2.1 After having sat the examination on the basic training course and after having attended the specialization training course for carriage in tanks or carriage of substances and articles of Class 1 or radioactive material of Class 7, the candidate shall be allowed to take part in the examination corresponding to the training. 8.2.2.7.2.2 This examination shall be held and supervised on the same basis as in 8.2.2.7.1. The catalogue of questions shall refer to the items summarized in 8.2.2.3.3, 8.2.2.3.4 or 8.2.2.3.5, as appropriate. 8.2.2.7.2.3 With respect to each specialization training examination, at least 15 written questions shall be asked. If the examination follows a refresher training course, at least 10 written questions shall be asked. The duration of these examinations shall be at least 30 and 20 minutes respectively. 8.2.2.7.2.4 If an examination is based on a restricted basic training course, this limits the examination of the specialization training course to the same scope. - 556 - 8.2.2.8 Certificate of driver's training 8.2.2.8.1 The certificate referred to in 8.2.1.1 shall be issued: 8.2.2.8.2 (a) After completion of a basic training course, provided the candidate has successfully passed the examination in accordance with 8.2.2.7.1; (b) If applicable, after completion of a specialization training course for carriage in tanks or carriage of substances and articles of Class 1 or radioactive material of Class 7, or after having acquired the knowledge referred to in special provisions S1 and S11 in Chapter 8.5, provided the candidate has successfully passed an examination in accordance with 8.2.2.7.2; (c) If applicable, after completion of a restricted basic or restricted tank specialization training course, provided the candidate has successfully passed the examination in accordance with 8.2.2.7.1 or 8.2.2.7.2. The certificate issued shall clearly indicate its limited scope of validity to the relevant dangerous goods or class(es). The date of validity of a driver training certificate shall be five years from the date the driver passes an initial basic or initial comprehensive training examination. The certificate shall be renewed if the driver furnishes proof of participation in refresher training in accordance with 8.2.2.5 and has passed an examination in accordance with 8.2.2.7 in the following cases: (a) In the twelve months before the date of expiry of the certificate. The competent authority shall issue a new certificate, valid for five years, the period of validity of which shall begin with the date of expiry of the previous certificate; (b) Prior to the twelve months before the date of expiry of the certificate. The competent authority shall issue a new certificate, valid for five years, the period of validity of which shall begin from the date on which the refresher examination was passed. Where a driver extends the scope of his certificate during its period of validity, by meeting the requirements of 8.2.2.8.1 (b) and (c), the period of validity of a new certificate shall remain that of the previous certificate. When a driver has passed a specialization training examination, the specialization shall be valid until the date of expiry of the certificate. 8.2.2.8.3 The certificate shall have the layout of the model shown in 8.2.2.8.5. Its dimensions shall be in accordance with ISO 7810:2003 ID-1 and it shall be made of plastic. The colour shall be white with black lettering. It shall include an additional security feature such as a hologram, UV printing or guilloche patterns. 8.2.2.8.4 The certificate shall be prepared in the language(s) or one of the languages of the country of the competent authority which issued the certificate. If none of these languages is English, French or German, the title of the certificate, the title of item 8 and the titles on the back shall also be drawn up in English, French or German. - 557 - 8.2.2.8.5 Model for the training certificate for drivers of vehicles carrying dangerous goods ADR DRIVER TRAINING CERTIFICATE ** Front 1. (CERTIFICATE No.)* 2. (SURNAME)* 3. (OTHER NAME(S))* 4. (DATE OF BIRTH dd/mm/yyyy)* (Insert driver photograph) 5. (NATIONALITY)* * 6. (DRIVER SIGNATURE)* 7. (ISSUING BODY)* 8. VALID TO: (dd/mm/yyyy)* VALID FOR CLASS(ES) OR UN Nos.: Back * TANKS OTHER THAN TANKS 9. (Enter Class or UN Number(s))* 10. (Enter Class or UN Number(s))* Replace the text with appropriate data. ** Distinguishing sign used on vehicles in international traffic (for Parties to the 1968 Convention on Road Traffic or the 1949 Convention on Road Traffic, as notified to the Secretary General of the United Nations in accordance with respectively article 45(4) or annex 4 of these conventions). 8.2.2.8.6 Contracting Parties shall provide the UNECE secretariat with an example of the national model for any certificate intended for issue in accordance with this section, along with examples of models for certificates which are still valid. A Contracting Party may additionally provide explanatory notes. The UNECE secretariat shall make the information received available to all Contracting Parties. 8.2.3 Training of persons other than the drivers holding a certificate in accordance with 8.2.1, involved in the carriage of dangerous goods by road Persons whose duties concern the carriage of dangerous goods by road shall have received training in the requirements governing the carriage of such goods appropriate to their responsibilities and duties according to Chapter 1.3. This requirement shall apply to individuals such as personnel who are employed by the road vehicle operator or the consignor, personnel who load or unload dangerous goods, personnel in freight forwarding or shipping agencies and drivers of vehicles other than drivers holding a certificate in accordance with 8.2.1, involved in the carriage of dangerous goods by road. . - 558 - CHAPTER 8.3 MISCELLANEOUS REQUIREMENTS TO BE COMPLIED WITH BY THE VEHICLE CREW 8.3.1 Passengers Apart from members of the vehicle crew, no passengers may be carried in transport units carrying dangerous goods. 8.3.2 Use of fire-fighting appliances Members of the vehicle crew shall know how to use the fire-fighting appliances. 8.3.3 Prohibition on opening packages A driver or a driver's assistant may not open a package containing dangerous goods. 8.3.4 Portable lighting apparatus The portable lighting apparatus used shall not exhibit any metal surface liable to produce sparks. 8.3.5 Prohibition on smoking Smoking shall be prohibited during handling operations in the vicinity of vehicles and inside the vehicles. This prohibition of smoking is also applicable to the use of electronic cigarettes and similar devices. 8.3.6 Running the engine during loading or unloading Except where the engine has to be used to drive the pumps or other appliances for loading or unloading the vehicle and the laws of the country in which the vehicle is operating permit such use, the engine shall be shut off during loading and unloading operations. 8.3.7 Use of the parking brakes and wheel chocks No vehicles carrying dangerous goods may be parked without the parking brakes being applied. Trailers without braking devices shall be restrained from moving by applying at least one wheel chock as described in 8.1.5.2. 8.3.8 Use of cables In the case of a transport unit equipped with an anti-lock braking system, consisting of a motor vehicle and a trailer with a maximum mass exceeding 3.5 tonnes, the connections referred to in paragraph 9.2.2.6.3 shall be connecting the towing vehicle and the trailer at all times during carriage. - 559 - CHAPTER 8.4 REQUIREMENTS CONCERNING THE SUPERVISION OF VEHICLES 8.4.1 Vehicles carrying dangerous goods in the quantities shown in special provisions S1 (6) and S14 to S24 of Chapter 8.5 for a given substance according to Column (19) of Table A of Chapter 3.2 shall be supervised or alternatively may be parked, unsupervised, in a secure depot or secure factory premises. If such facilities are not available, the vehicle, after having been properly secured, may be parked in an isolated position meeting the requirements of (a), (b) or (c) below: (a) A vehicle park supervised by an attendant who has been notified of the nature of the load and the whereabouts of the driver; (b) A public or private vehicle park where the vehicle is not likely to suffer damage from other vehicles; or (c) A suitable open space separated from the public highway and from dwellings, where the public does not normally pass or assemble. The parking facilities permitted in (b) shall be used only if those described in (a) are not available, and those described in (c) may be used only if facilities described in (a) and (b) are not available. 8.4.2 Loaded MEMUs shall be supervised or alternatively may be parked, unsupervised, in a secure depot or secure factory premises. Empty uncleaned MEMUs are exempted from this requirement. - 561 - CHAPTER 8.5 ADDITIONAL REQUIREMENTS RELATING TO PARTICULAR CLASSES OR SUBSTANCES In addition to the requirements of Chapters 8.1 to 8.4, when reference is made to them in Column (19) of Table A of Chapter 3.2, the following requirements shall apply to the carriage of the substances or articles concerned. In the event of conflict with the requirements of Chapters 8.1 to 8.4, the requirements of this Chapter shall take precedence. S1: Requirements concerning the carriage of explosive substances and articles (Class 1) (1) Special training of drivers If, according to other regulations applicable in the country of a Contracting Party, a driver has followed equivalent training under a different regime or for a different purpose, covering the subjects defined in 8.2.2.3.4, the specialization training course may be totally or partially dispensed with. (2) Approved official If the national regulations so provide, the competent authority of a country contracting party to ADR may require an approved official to be carried in the vehicle at the carrier's expense. (3) Prohibition of smoking, fire and naked flame Smoking, the use of fire or of naked flames shall be prohibited on vehicles carrying substances and articles of Class 1, in their vicinity and during the loading and unloading of these substances and articles. This prohibition of smoking is also applicable to the use of electronic cigarettes and similar devices. (4) (5) Places of loading and unloading (a) Loading or unloading of substances and articles of Class 1 shall not take place in a public place in a built-up area without special permission from the competent authorities; (b) Loading or unloading of substances and articles of Class 1 in a public space elsewhere than in a built-up area without prior notice thereof having been given to the competent authorities shall be prohibited, unless operations are urgently necessary for reasons of safety; (c) If, for any reason, handling operations have to be carried out in a public place, then substances and articles of different kinds shall be separated according to the labels; (d) When vehicles carrying substances and articles of Class 1 are obliged to stop for loading or unloading operations in a public place, a distance of at least 50 m shall be maintained between the stationary vehicles. This distance shall not apply to vehicles belonging to the same transport unit. Convoys (a) (b) When vehicles carrying substances and articles of Class 1 travel in convoy, a distance of not less than 50 m shall be maintained between each transport unit and the next; The competent authority may lay down rules for the order or composition of convoys. - 563 - (6) Supervision of vehicles The requirements of Chapter 8.4 shall be applicable only when substances and articles of Class 1 having a total net mass of explosive substance above the limits set below are carried in a vehicle: Division 1.1: Division 1.2: Division 1.3, compatibility group C: Division 1.3, other than compatibility group C: Division 1.4, other than those listed below: Division 1.5: Division 1.6: Substances and articles of Division 1.4 belonging to UN numbers 0104, 0237,0255, 0267, 0289, 0361, 0365, 0366, 0440, 0441, 0455, 0456 and 0500: 0 kg 0 kg 0 kg 50 kg 50 kg 0 kg 50 kg 0 kg For mixed loads the lowest limit applicable to any of the substances or articles carried shall be used for the load as a whole. In addition, these substances and articles shall be supervised at all times in order to prevent any malicious act and to alert the driver and the competent authorities in the event of loss or fire. Empty uncleaned packagings are exempted. (7) Locking of vehicles Doors and rigid covers in the load compartments of EX/II vehicles and all openings in the load compartments of EX/III vehicles carrying substances and articles of Class 1 shall be locked during transport, except for the periods of loading and unloading. S2: Additional requirements concerning the carriage of flammable liquids or gases (1) Portable lighting apparatus The load compartment of closed vehicles carrying liquids having a flash-point of not more than 60 °C or flammable substances or articles of Class 2, shall not be entered by persons carrying portable lighting apparatus other than those so designed and constructed that they cannot ignite any flammable vapours or gases which may have penetrated into the interior of the vehicle. (2) Operation of combustion heaters during loading or unloading The operation of combustion heaters of vehicles of type FL (see Part 9) is forbidden during loading and unloading and at loading sites. (3) Precautions against electrostatic charges In the case of vehicles of type FL (see Part 9), a good electrical connection from the vehicle chassis to earth shall be established before tanks are filled or emptied. In addition, the rate of filling shall be limited. S3: Special provisions concerning the carriage of infectious substances The requirements of the table columns (2), (3) and (5) in 8.1.4.1 and 8.3.4 shall not apply. S4: Additional requirements concerning carriage under controlled temperatures Maintenance of the prescribed temperature is essential for safe carriage. In general, there shall be: - thorough inspection of the transport unit prior to loading; - instructions to the carrier about the operation of the refrigeration system, including a list of the suppliers of coolant available en route; - 564 - - procedures to be followed in the event of loss of control; - regular monitoring of operating temperatures; and - availability of a back-up refrigeration system or spare parts. The temperature of the air space within the transport unit shall be measured by two independent sensors and the output shall be so recorded that temperature changes are readily detectable. The temperature shall be checked every four to six hours and logged. If the control temperature is exceeded during carriage, an alert procedure shall be initiated involving any necessary repairs to the refrigeration equipment or an increase in the cooling capacity (e.g. by adding liquid or solid coolant). There shall also be frequent checking of the temperature and preparations for implementation of the emergency procedures. If the emergency temperature (see also 2.2.41.1.17 and 2.2.52.1.15 to 2.2.52.1.18) is reached, the emergency procedures shall be set in operation. NOTE: This provision S4 does not apply to substances referred to in 3.1.2.6 when substances are stabilized by the addition of chemical inhibitors such that the SADT is greater than 50 °C. In this latter case, temperature control may be required under conditions of carriage where the temperature may exceed 55 °C. S5: Special provisions common to the carriage of radioactive material of Class 7 in excepted packages (UN Nos. 2908, 2909, 2910 and 2911) only The requirements of the instructions in writing of 8.1.2.1 (b) and of 8.2.1, 8.3.1 and 8.3.4 shall not apply. S6: Special provisions common to the carriage of radioactive material of Class 7 other than in excepted packages The provisions of 8.3.1 shall not apply to vehicles carrying only packages, overpacks or containers bearing category I-WHITE labels. The provisions of 8.3.4 shall not apply provided there is no subsidiary risk. Other additional requirements or special provisions S7: (Deleted) S8: When a transport unit is loaded with more than 2 000 kg of these substances, stops for service requirements shall as far as possible not be made near inhabited places or frequented places. A longer stop near such places is permissible only with the consent of the competent authorities. S9: During the carriage of these substances, stops for service requirements shall as far as possible not be made near inhabited places or frequented places. A longer stop near such places is permissible only with the consent of the competent authorities. S10: During the period April to October, when a vehicle is stationary, the packages shall, if the legislation of the country in which the vehicle is halted so requires, be effectively protected against the action of the sun, e.g. by means of sheets placed not less than 20 cm above the load. S11: If, according to other regulations applicable in the country of a Contracting Party, a driver has followed equivalent training under a different regime or for a different purpose covering the subjects defined in 8.2.2.3.5, the specialization training course may be totally or partially dispensed with. - 565 - S12: If the total number of packages containing radioactive material carried in the transport unit does not exceed 10, the sum of the transport indexes does not exceed 3 and there are no subsidiary risks, the requirements in 8.2.1 concerning the training of drivers need not be applied. However, drivers shall then receive appropriate training in the requirements governing the carriage of radioactive material, commensurate with their duties. This training shall provide them with an awareness of the radiation hazards involved in the carriage of radioactive material. Such awareness training shall be confirmed by a certificate provided by their employer. See also 8.2.3. S13: (Deleted) S14: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply for vehicles carrying any amount of these substances. S15: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply for vehicles carrying any amount of these substances. However, the provisions of Chapter 8.4 need not be applied when the loaded compartment is locked or the packages carried are otherwise protected against any illicit unloading. S16: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply when the total mass of these substances in the vehicle exceeds 500 kg. In addition, vehicles carrying more than 500 kg of these substances shall be subject at all times to supervision to prevent any malicious act and to alert the driver and competent authorities in the event of loss or fire. S17: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply when the total mass of these substances in the vehicle exceeds 1 000 kg. S18: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply when the total mass of such substances in the vehicle exceeds 2 000 kg. S19: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply when the total mass of such substances in the vehicle exceeds 5 000 kg. S20: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply when the total mass or volume of these substances in the vehicle exceeds 10 000 kg as packaged goods or 3 000 litres in tanks. S21: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply to all material, in whatever mass. In addition, these goods shall be subject at all times to supervision to prevent any malicious act and to alert the driver and the competent authorities in the event of loss or fire. However, the provisions of Chapter 8.4 need not be applied where: (a) The loaded compartment is locked or the packages carried are otherwise protected against illicit unloading; and (b) The dose rate does not exceed 5Sv/h at any accessible point on the outer surface of the vehicle. S22: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply when the total mass or volume of these substances in the vehicle exceeds 5 000 kg as packaged goods or 3 000 litres in tanks. S23: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply when this substance is carried in bulk or in tanks and when the total mass or volume in the vehicle exceeds 3 000 kg or 3 000 litres, as applicable. S24: The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply when the total mass of these substances in the vehicle exceeds 100 kg. - 566 - CHAPTER 8.6 ROAD TUNNEL RESTRICTIONS FOR THE PASSAGE OF VEHICLES CARRYING DANGEROUS GOODS 8.6.1 General provisions The provisions of this Chapter apply when the passage of vehicles through road tunnels is restricted in accordance with 1.9.5. 8.6.2 Road signs or signals governing the passage of vehicles carrying dangerous goods The tunnel category, assigned in accordance with 1.9.5.1 by the competent authority to a given road tunnel for the purpose of restricting the passage of transport units carrying dangerous goods, shall be indicated as follows by means of road signs and signals: Sign and signal No sign Sign with an additional panel bearing a letter B Sign with an additional panel bearing a letter C Sign with an additional panel bearing a letter D Sign with an additional panel bearing a letter E Tunnel category Tunnel category A Tunnel category B Tunnel category C Tunnel category D Tunnel category E 8.6.3 Tunnel restriction codes 8.6.3.1 The restrictions for the transport of specific dangerous goods through tunnels are based on the tunnel restriction code of these goods, indicated in Column (15) of Table A of Chapter 3.2. The tunnel restriction codes are put between brackets at the bottom of the cell. When ‘(─)’ is indicated instead of one of the tunnel restriction codes, the dangerous goods are not subject to any tunnel restriction; for the dangerous goods assigned to UN Nos. 2919 and 3331, restrictions to the passage through tunnels may, however, be part of the special arrangement approved by the competent authority(ies) on the basis of 1.7.4.2. 8.6.3.2 When a transport unit contains dangerous goods to which different tunnel restriction codes have been assigned, the most restrictive of these tunnel restriction codes shall be assigned to the whole load. 8.6.3.3 Dangerous goods carried in accordance with 1.1.3 are not subject to the tunnel restrictions and shall not be taken into account when determining the tunnel restriction code to be assigned to the whole load of a transport unit, except if the transport unit is required to be marked in accordance with 3.4.13 subject to 3.4.141 8.6.4 Restrictions for the passage of transport units carrying dangerous goods through tunnels The restrictions for passage through tunnels shall apply: to transport units for which marking is required by 3.4.13 subject to 3.4.141, through tunnels of category E; and - to transport units for which an orange-coloured plate marking is required according to 5.3.2, in accordance with the table below once the tunnel restriction code to be assigned to the whole load of the transport unit has been determined. 1 or in accordance with 3.4.10 subject to 3.4.11 of ADR as applicable until 31 December 2010 if the transitional measures of 1.6.1.20 are applied. - 567 - Tunnel restriction code of the whole load B B1000C B/D B/E C C5000D C/D C/E D D/E E - Restriction Passage forbidden through tunnels of category B, C, D and E Carriage where the total net explosive mass per transport unit exceeds 1000 kg: Passage forbidden through tunnels of category B, C, D and E; does not exceed 1000 kg: Passage forbidden through tunnels of category C, D and E Tank carriage: Passage forbidden through tunnels of category B, C, D and E; Other carriage: Passage forbidden through tunnels of category D and E Tank carriage: Passage forbidden through tunnels of category B, C, D and E; Other carriage: Passage forbidden through tunnels of category E Passage forbidden through tunnels of category C, D and E Carriage where the total net explosive mass per transport unit exceeds 5000 kg: Passage forbidden through tunnels of category C, D and E; does not exceed 5000 kg: Passage forbidden through tunnels of category D and E Tank carriage: Passage forbidden through tunnels of category C, D and E; Other carriage: Passage forbidden through tunnels of category D and E Tank carriage: Passage forbidden through tunnels of category C, D and E; Other carriage: Passage forbidden through tunnels of category E Passage forbidden through tunnels of category D and E Bulk or tank carriage: Passage forbidden through tunnels of category D and E; Other carriage: Passage forbidden through tunnels of category E Passage forbidden through tunnels of category E Passage allowed through all tunnels (For UN Nos. 2919 and 3331, see also 8.6.3.1). NOTE 1: For example, the passage of a transport unit carrying UN 0161, powder, smokeless, classification code 1.3C, tunnel restriction code C5000D, in a quantity representing a total net explosive mass of 3000 kg is forbidden in tunnels of categories D and E. NOTE 2: Dangerous goods packed in limited quantities carried in containers or transport units marked in accordance with the IMDG Code are not subject to the restrictions for passage through tunnels of category E when the total gross mass of the packages containing dangerous goods packed in limited quantities does not exceed 8 tonnes per transport unit. - 568 - PART 9 Requirements concerning the construction and approval of vehicles CHAPTER 9.1 SCOPE, DEFINITIONS AND REQUIREMENTS FOR THE APPROVAL OF VEHICLES 9.1.1 Scope and definitions 9.1.1.1 Scope The requirements of Part 9 shall apply to vehicles of categories N and O, as defined in Annex 7 of the Consolidated Resolution on the Construction of Vehicles (R.E.3)1, intended for the carriage of dangerous goods. These requirements refer to vehicles, as regards their construction, type approval, ADR approval and annual technical inspection. 9.1.1.2 Definitions For the purposes of Part 9: "Vehicle" means any vehicle, whether complete, incomplete or completed, intended for the carriage of dangerous goods by road; "EX/II vehicle" or "EX/III vehicle" means a vehicle intended for the carriage of explosive substances and articles (Class 1); "FL vehicle" means: (a) A vehicle intended for the carriage of liquids having a flash-point of not more than 60°C (with the exception of diesel fuel complying with standard EN 590:2009 + A1:2010, gas oil, and heating oil (light) - UN No. 1202 - with a flash-point as specified in standard EN 590:2009 + A1:2010) in fixed tanks or demountable tanks with a capacity exceeding 1 m3 or in tank-containers or portable tanks with an individual capacity exceeding 3 m3; or (b) A vehicle intended for the carriage of flammable gases in fixed tanks or demountable tanks with a capacity exceeding 1 m3 or in tank-containers, portable tanks or MEGCs with an individual capacity exceeding 3 m3; or, (c) A battery-vehicle with a total capacity exceeding 1 m3 intended for the carriage of flammable gases; "OX vehicle" means a vehicle intended for the carriage of hydrogen peroxide, stabilized or hydrogen peroxide, aqueous solution stabilized with more than 60% hydrogen peroxide (Class 5.1, UN No. 2015) in fixed tanks or demountable tanks with a capacity exceeding 1 m3 or in tank-containers or portable tanks with an individual capacity exceeding 3 m3; "AT vehicle" means: (a) A vehicle, other than EX/III, FL or OX vehicle or than a MEMU, intended for the carriage of dangerous goods in fixed tanks or demountable tanks with a capacity exceeding 1 m3 or in tank-containers, portable tanks or MEGCs with an individual capacity exceeding 3 m3; or (b) A battery-vehicle with a total capacity exceeding 1 m3 other than a FL vehicle; "MEMU" means a vehicle meeting the definition of mobile explosives manufacturing unit in 1.2.1. "Complete vehicle" means any vehicle which does not need any further completion (e.g. one stage built vans, lorries, tractors, trailers); 1 United Nations document ECE/TRANS/WP.29/78/Rev.3 - 571 - "Incomplete vehicle" means any vehicle which still needs completion in at least one further stage (e.g. chassis-cab, trailer chassis); "Completed vehicle" means any vehicle which is the result of a multi-stage process (e.g. chassis or chassis-cab fitted with a bodywork); "Type-approved vehicle" means any vehicle which has been approved in accordance with ECE Regulation No. 1052; "ADR approval" means certification by a competent authority of a Contracting Party that a single vehicle intended for the carriage of dangerous goods satisfies the relevant technical requirements of this Part as an EX/II, EX/III, FL, OX, or AT vehicle or as a MEMU. 9.1.2 Approval of EX/II, EX/III, FL, OX and AT vehicles and MEMUs NOTE: No special certificates of approval shall be required for vehicles other than EX/II, EX/III, FL, OX and AT vehicles and MEMUs, apart from those required by the general safety regulations normally applicable to vehicles in the country of origin. 9.1.2.1 General EX/II, EX/III, FL, OX and AT vehicles and MEMUs shall comply with the relevant requirements of this Part. Every complete or completed vehicle shall be subjected to a first inspection by the competent authority in accordance with the administrative requirements of this Chapter to verify conformity with the relevant technical requirements of Chapters 9.2 to 9.8. The competent authority may waive the first inspection for a tractor for a semi trailer type-approved in accordance with 9.1.2.2 for which the manufacturer, his duly accredited representative or a body recognised by the competent authority has issued a declaration of conformity with the requirements of Chapter 9.2. The conformity of the vehicle shall be certified by the issue of a certificate of approval in accordance with 9.1.3. When vehicles are required to be fitted with an endurance braking system, the manufacturer of the vehicle or his duly accredited representative shall issue a declaration of conformity with the relevant prescriptions of Annex 5 of ECE Regulation No. 133. This declaration shall be presented at the first technical inspection. 9.1.2.2 Requirements for type-approved vehicles At the request of the vehicle manufacturer or his duly accredited representative, vehicles subject to ADR approval according to 9.1.2.1 may be type-approved by a competent authority. The relevant technical requirements of Chapter 9.2 shall be considered to be fulfilled if a type approval certificate has been issued by a competent authority in accordance with ECE Regulation No. 1052 provided that the technical requirements of the said Regulation correspond to those of Chapter 9.2 of this Part and provided that no modification of the vehicle alters its validity. In the case of MEMUs, the type approval mark affixed in accordance with ECE Regulation No. 105 may identify the vehicle as either MEMU or EX/III. MEMUs need only be identified as such on the certificate of approval issued in accordance with 9.1.3. This type approval, granted by one Contracting Party, shall be accepted by the other Contracting Parties as ensuring the conformity of the vehicle when the single vehicle is submitted for inspection for ADR approval. 2 ECE Regulation No. 105 (Uniform provisions concerning the approval of vehicles intended for the carriage of dangerous goods with regard to their specific constructional features). 3 ECE Regulation No. 13 (Uniform provisions concerning the approval of vehicles of categories M, N and O with regards to braking). - 572 - At the inspection for ADR approval, only those parts of the type-approved incomplete vehicle which have been added or modified in the process of completion shall be inspected for compliance with the applicable requirements of Chapter 9.2. 9.1.2.3 Annual technical inspection EX/II, EX/III, FL, OX and AT vehicles and MEMUs shall be subject to an annual technical inspection in their country of registration to make sure that they conform to the relevant requirements of this Part, and to the general safety regulations (concerning brakes, lighting, etc.) in force in their country of registration. The conformity of the vehicle shall be certified either by the extension of validity of the certificate of approval or by the issue of a new certificate of approval in accordance with 9.1.3. 9.1.3 Certificate of approval 9.1.3.1 Conformity of EX/II, EX/III, FL, OX and AT vehicles and MEMUs with the requirements of this Part is subject to a certificate of approval (certificate of ADR approval) issued by the competent authority of the country of registration for each vehicle whose inspection yields satisfactory results or has resulted in the issue of a declaration of conformity with the requirements of Chapter 9.2 in accordance with 9.1.2.1. 9.1.3.2 A certificate of approval issued by the competent authority of one Contracting Party for a vehicle registered in the territory of that Contracting Party shall be accepted, so long as its validity continues, by the competent authorities of the other Contracting Parties. 9.1.3.3 The certificate of approval shall have the same layout as the model shown in 9.1.3.5. Its dimensions shall be 210 mm × 297 mm (format A4). Both front and back may be used. The colour shall be white, with a pink diagonal stripe. It shall be drawn up in the language or one of the languages of the country issuing it. If that language is not English, French or German, the title of the certificate of approval and any remarks under No. 11 shall also be drawn up in English, French or German. The certificate of approval for a vacuum-operated waste tank-vehicle shall bear the following remark: "vacuum-operated waste tank-vehicle". 9.1.3.4 The validity of a certificate of approval shall expire not later than one year after the date of the technical inspection of the vehicle preceding the issue of the certificate. The next approval term shall, however, be related to the last nominal expiry date, if the technical inspection is performed within one month before or after that date. However, in the case of tanks subject to compulsory periodic inspection this provision shall not mean that tightness (leakproofness) tests, hydraulic pressure tests or internal inspections of tanks have to be carried out at intervals shorter than those laid down in Chapters 6.8 and 6.9. - 573 - 9.1.3.5 Model for certificate of approval for vehicles carrying certain dangerous goods CERTIFICATE OF APPROVAL FOR VEHICLES CARRYING CERTAIN DANGEROUS GOODS This certificate testifies that the vehicle specified below fulfils the conditions prescribed by the European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR). 4. Registration number (if any): 1. Certificate No.: 2. Vehicle manufacturer: 3. Vehicle Identification No.: 5. Name and business address of carrier, operator or owner: 6. Description of vehicle: 1 7. Vehicle designation(s) according to 9.1.1.2 of ADR:2 EX/II EX/III FL OX AT MEMU Endurance braking system:3 □ Not applicable □ The effectiveness according to 9.2.3.1.2 of ADR is sufficient for a total mass of the transport unit of ____t4 8. Description of the fixed tank(s)/battery-vehicle (if any): 9.1 Manufacturer of the tank: 9.2 Approval number of the tank/battery-vehicle: 9.3 Tank manufacturer's serial number/Identification of elements of battery-vehicle: 9.4 Year of manufacture: 9.5 Tank code according to 4.3.3.1 or 4.3.4.1 of ADR: 9.6 Special provisions TC and TE according to 6.8.4 of ADR (if applicable)6: 10. Dangerous goods authorised for carriage: The vehicle fulfils the conditions required for the carriage of dangerous goods assigned to the vehicle designation(s) in No. 7. 9. 10.1 In the case of an EX/II □ goods of Class 1 including compatibility group J or EX/III vehicle 3 □ goods of Class 1 excluding compatibility group J 10.2 In the case of a tank-vehicle/battery-vehicle 3 □ only the substances permitted under the tank code and any special provisions specified in No. 9 may be carried5 or □ only the following substances (Class, UN number, and if necessary packing group and proper shipping name) may be carried: Only substances which are not liable to react dangerously with the materials of the shell, gaskets, equipment and protective linings (if applicable) may be carried. 11. Remarks: Stamp of issuing service 12. Valid until: 1 2 3 4 5 6 Place, Date, Signature According to the definitions for power-driven vehicles and for trailers of categories N and O as defined in Annex 7 of the Consolidated Resolution on the Construction of Vehicles (R.E.3) or in Directive 2007/46/EC. Strike out what is not appropriate. Mark the appropriate. Enter appropriate value. A value of 44t will not limit the "registration / in-service maximum permissible mass" indicated in the registration document(s). Substances assigned to the tank code specified in No. 9 or to another tank code permitted under the hierarchy in 4.3.3.1.2 or 4.3.4.1.2, taking account of the special provision(s), if any. Not required when the authorized substances are listed in No. 10.2. - 575 - 13. Validity extended until Extensions of validity Stamp of issuing service, place, date, signature: NOTE: This certificate shall be returned to the issuing service when the vehicle is taken out of service; if the vehicle is transferred to another carrier, operator or owner, as specified in No. 5; on expiry of the validity of the certificate; and if there is a material change in one or more essential characteristics of the vehicle. - 576 - CHAPTER 9.2 REQUIREMENTS CONCERNING THE CONSTRUCTION OF VEHICLES 9.2.1 Compliance with the requirements of this Chapter 9.2.1.1 EX/II, EX/III, FL, OX and AT vehicles shall comply with the requirements of this Chapter, according to the table below. For vehicles other than of EX/II, EX/III, FL, OX and AT: - the requirements of 9.2.3.1.1 (Braking equipment in accordance with ECE Regulation No. 13 or Directive 71/320/EEC) are applicable to all vehicles first registered (or which entered into service if the registration is not mandatory) after 30 June 1997; - the requirements of 9.2.5 (Speed limitation device in accordance with ECE Regulation No. 89 or Directive 92/24/EEC) are applicable to all motor vehicles with a maximum mass exceeding 12 tonnes first registered after 31 December 1987 and all motor vehicles with a maximum mass exceeding 3.5 tonnes but not more than 12 tonnes first registered after 31 December 2007. - 577 - - 578 - X X 9.2.3.1 Xc Endurance braking system X X X Anti-lock braking system Xc Xc b X b X b X X X X 9.2.2.6 9.2.3 X 9.2.2.5.2 Electrical installation at rear of cab BRAKING EQUIPMENT General provisions Permanently energized circuits 9.2.2.5 9.2.2.5.1 X Batteries 9.2.2.4 X X X 9.2.2.3.4 X Xa X FL X X AT 9.2.2.3.3 X 9.2.2.3.2 X Xa ELECTRICAL EQUIPMENT Wiring Battery master switch EX/II EX/III 9.2.2.3.1 9.2.2.2 9.2.2.3 9.2.2 TECHNICAL SPECIFICATIONS VEHICLES Xc Xb X X OX Applicable to motor vehicles with a maximum mass exceeding 16 tonnes or authorized to tow a trailer with a maximum mass exceeding 10 tonnes. The endurance braking system shall be of type IIA. c Applicable to motor vehicles (tractors and rigid vehicles) with a maximum mass exceeding 16 tonnes and motor vehicles authorized to tow trailers (i.e. full-trailers, semi-trailers and centre axle-trailers) with a maximum mass exceeding 10 tonnes. Motor vehicles shall be equipped with a category 1 anti-lock braking system. Applicable to trailers (i.e. full-trailers, semi-trailers and centre axle-trailers) with a maximum mass exceeding 10 tonnes. Trailers shall be equipped with a category A anti-lock braking system. b The last sentence of 9.2.2.3.1 is applicable to vehicles first registered (or which entered into service if registration is not mandatory) as from 1 July 2005. a COMMENTS - 579 - Fuel tanks Engine Exhaust system Vehicle endurance braking Combustion heaters 9.2.4.2 9.2.4.3 9.2.4.4 9.2.4.5 9.2.4.6 X Xe X Xe X SPEED LIMITATION DEVICE COUPLING DEVICE OF TRAILERS 9.2.5 9.2.6 Xd X X X X X Xd X X X EX/II EX/III 9.2.4.7.6 9.2.4.7.1 9.2.4.7.2 9.2.4.7.5 9.2.4.7.3 9.2.4.7.4 9.2.4.7 PREVENTION OF FIRE RISKS Vehicle cab 9.2.4 TECHNICAL SPECIFICATIONS Xe Xd X AT Xe Xd Xd X X X X FL VEHICLES Xe Xd X X X X OX Applicable to motor vehicles with a maximum mass exceeding 12 tonnes first registered after 31 December 1987, and all motor vehicles with a maximum mass exceeding 3.5 tonnes but not more than 12 tonnes registered after 31 December 2007. e Applicable to motor vehicles equipped after 30 June 1999. Mandatory compliance by 1 January 2010 for vehicles equipped before 1 July 1999. If the date of equipping is not available the date of first registration of the vehicle shall be used instead. d Applicable to motor vehicles equipped after 30 June 1999. Mandatory compliance by 1 January 2010 for vehicles equipped before 1 July 1999. If the date of equipping is not available the date of first registration of the vehicle shall be used instead. d COMMENTS 9.2.1.2 MEMUs shall comply with the requirements of this Chapter applicable to EX/III-vehicles. 9.2.2 Electrical equipment 9.2.2.1 General provisions The electrical installation as a whole shall meet the provisions of 9.2.2.2 to 9.2.2.6 in accordance with the table of 9.2.1. 9.2.2.2 Wiring 9.2.2.2.1 The size of conductors shall be large enough to avoid overheating. Conductors shall be adequately insulated. All circuits shall be protected by fuses or automatic circuit breakers, except for the following: - from the battery to the cold start and stopping systems of the engine; - from the battery to the alternator; - from the alternator to the fuse or circuit breaker box; - from the battery to the starter motor; - from the battery to the power control housing of the endurance braking system (see 9.2.3.1.2), if this system is electrical or electromagnetic; - from the battery to the electrical lifting mechanism for lifting the bogie axle. The above unprotected circuits shall be as short as possible. 9.2.2.2.2 Cables shall be securely fastened and positioned in such a way that the conductors are adequately protected against mechanical and thermal stresses. 9.2.2.3 Battery master switch 9.2.2.3.1 A switch for breaking the electrical circuits shall be placed as close to the battery as practicable. If a single pole switch is used it shall be placed in the supply lead and not in the earth lead. 9.2.2.3.2 A control device to facilitate the disconnecting and reconnecting functions of the switch shall be installed in the driver's cab. It shall be readily accessible to the driver and be distinctively marked. It shall be protected against inadvertent operation by either adding a protective cover, by using a dual movement control device or by other suitable means. Additional control devices may be installed provided they are distinctively marked and protected against inadvertent operation. If the control device(s) are electrically operated, the circuits of the control device(s) are subject to the requirements of 9.2.2.5. 9.2.2.3.3 The switch shall have a casing with protection degree IP 65 in accordance with IEC Standard 60529. 9.2.2.3.4 The cable connections on the switch shall have protection degree IP 54. However, this does not apply if these connections are contained in a housing which may be the battery box. In this case it is sufficient to insulate the connections against short circuits, for example with a rubber cap. 9.2.2.4 Batteries The battery terminals shall be electrically insulated or covered by an insulating battery box cover. If the batteries are not located under the engine bonnet, they shall be fitted in a vented box. - 580 - 9.2.2.5 Permanently energized circuits 9.2.2.5.1 (a) Those parts of the electrical installation including the leads which shall remain energized when the battery master switch is open, shall be suitable for use in hazardous areas. Such equipment shall meet the general requirements of IEC 60079, parts 0 and 141 and the additional requirements applicable from IEC 60079, parts 1, 2, 5, 6, 7, 11, 15 or 18; (b) For the application of IEC 60079 part 141, the following classification shall be used: Permanently energized electrical equipment including the leads which is not subject to 9.2.2.3 and 9.2.2.4 shall meet the requirements for Zone 1 for electrical equipment in general or meet the requirements for Zone 2 for electrical equipment situated in the driver's cab. The requirements for explosion group IIC, temperature class T6 shall be met. However, for permanently energized electrical equipment installed in an environment where the temperature caused by non-electrical equipment situated in that environment exceeds the T6 temperature limit, the temperature classification of the permanently energized electrical equipment shall be at least that of the T4 temperature class. (c) The supply leads for permanently energised equipment shall either comply with the provisions of IEC 60079, part 7 ("Increased safety") and be protected by a fuse or automatic circuit breaker placed as close to the source of power as practicable or, in the case of "intrinsically safe equipment", they shall be protected by a safety barrier placed as close to the source of power as practicable. 9.2.2.5.2 Bypass connections to the battery master switch for electrical equipment which must remain energized when the battery master switch is open shall be protected against overheating by suitable means, such as a fuse, a circuit breaker or a safety barrier (current limiter). 9.2.2.6 Provisions concerning that part of the electrical installation situated to the rear of the driver's cab The whole installation shall be so designed, constructed and protected such that it cannot provoke any ignition or short-circuit under normal conditions of use of vehicles and that these risks can be minimized in the event of an impact or deformation. In particular: 9.2.2.6.1 Wiring The wiring located to the rear of the driver's cab shall be protected against impact, abrasion and chafing during normal vehicle operation. Examples of appropriate protection are given in figures 1, 2, 3 and 4 below. However, the sensor cables of anti-lock braking devices do not need additional protection. 1 The requirements of IEC 60079 part 14 do not take precedence over the requirement of this Part. - 581 - Figure N°1 Corrugated polyamide conduit Separate insulated wires Figure N°2 Corrugated polyamide conduit Insulating sheath Separate insulated wires Figure N°3 Polyurethane sheath With inner sheath Separate insulated wires Figure N°4 Outer layer Inner layer Separate insulated wires Metal-threaded protection - 582 - 9.2.2.6.2 Lighting Lamp with a screw cap shall not be used. 9.2.2.6.3 Electrical connections Electrical connections between motor vehicles and trailers shall have a protection degree IP54 in accordance with IEC 60529 and be designed to prevent accidental disconnection. Connectors shall be in conformity with ISO 25981:20082, ISO 12098:20042, ISO 7638:20032 and EN 15207:2006 as appropriate. 9.2.3 Braking equipment 9.2.3.1 General provisions 9.2.3.1.1 Motor vehicles and trailers intended for use as transport units for dangerous goods shall fulfil all relevant technical requirements of ECE Regulation No.133 or Directive 71/320/EEC3, as amended, in accordance with the dates of application specified therein. 9.2.3.1.2 EX/III, FL, OX and AT vehicles shall fulfil the requirements of ECE Regulation No.133, Annex 5. 9.2.3.2 (Deleted) 9.2.4 Prevention of fire risks 9.2.4.1 General provisions The following technical provisions shall apply in accordance with the table of 9.2.1. 9.2.4.2 Vehicle cab Unless the driver's cab is made of materials which are not readily flammable, a shield made of metal or other suitable material of the same width as the tank shall be fitted at the rear of the cab. Any windows in the rear of the cab or in the shield shall be hermetically closed and made of fire-resistant safety glass with fire-resistant frames. Furthermore, there shall be a clear space of not less than 15 cm between the tank and the cab or the shield. 9.2.4.3 Fuel tanks The fuel tanks for supplying the engine of the vehicle shall meet the following requirements: 9.2.4.4 (a) In the event of any leakage, the fuel shall drain to the ground without coming into contact with hot parts of the vehicle or the load; (b) Fuel tanks containing petrol shall be equipped with an effective flame trap at the filler opening or with a closure enabling the opening to be kept hermetically sealed. Engine The engine propelling the vehicle shall be so equipped and situated to avoid any danger to the load through heating or ignition. In the case of EX/II and EX/III vehicles the engine shall be of compression-ignition construction. 2 ISO 4009, referred to in this standard, need not be applied. ECE Regulation No. 13 (Uniform provisions concerning the approval of vehicles of categories M, N and O with regard to braking). 3 - 583 - 9.2.4.5 Exhaust system The exhaust system (including the exhaust pipes) shall be so directed or protected to avoid any danger to the load through heating or ignition. Parts of the exhaust system situated directly below the fuel tank (diesel) shall have a clearance of at least 100 mm or be protected by a thermal shield. 9.2.4.6 Vehicle endurance braking Vehicles equipped with endurance braking systems emitting high temperatures placed behind the rear wall of the driver's cab shall be equipped with a thermal shield securely fixed and located between this system and the tank or load so as to avoid any heating, even local, of the tank wall or the load. In addition, the thermal shield shall protect the braking system against any outflow or leakage, even accidental, of the load. For instance, a protection including a twin-shell shield shall be considered satisfactory. 9.2.4.7 Combustion heaters 9.2.4.7.1 Combustion heaters shall comply with the relevant technical requirements of ECE Regulation No. 1224, as amended, in accordance with the dates of application specified therein and the provisions of 9.2.4.7.2 to 9.2.4.7.6 applicable according to the table in 9.2.1. 9.2.4.7.2 The combustion heaters and their exhaust gas routing shall be designed, located, protected or covered so as to prevent any unacceptable risk of heating or ignition of the load. This requirement shall be considered as fulfilled if the fuel tank and the exhaust system of the appliance conform to provisions similar to those prescribed for fuel tanks and exhaust systems of vehicles in 9.2.4.3 and 9.2.4.5 respectively. 9.2.4.7.3 The combustion heaters shall be put out of operation by at least the following methods: 9.2.4.7.4 (a) Intentional manual switching off from the driver's cab; (b) Stopping of the vehicle engine; in this case the heating device may be restarted manually by the driver; (c) Start up of a feed pump on the motor vehicle for the dangerous goods carried. 9.2.4.7.5 Afterrunning is permitted after the combustion heaters have been put out of operation. For the methods of 9.2.4.7.3 (b) and (c) the supply of combustion air shall be interrupted by suitable measures after an afterrunning cycle of not more than 40 seconds. Only heaters shall be used for which proof has been furnished that the heat exchanger is resistant to the reduced afterrunning cycle of 40 seconds for the time of their normal use. The combustion heater shall be switched on manually. Programming devices shall be prohibited. 9.2.4.7.6 Combustion heaters with gaseous fuels are not permitted. 9.2.5 Speed limitation device Motor vehicles (rigid vehicles and tractors for semi-trailers) with a maximum mass exceeding 3.5 tonnes, shall be equipped with a speed limitation device according to the technical requirements of ECE Regulation No. 895, as amended. The device shall be set in such a way that the speed cannot exceed 90 km/h, bearing in mind the technological tolerance of the device. 4 ECE Regulation No. 122 (Regulation with regard the type approval of a heating system and of a vehicle with regard to its heating system). 5 ECE Regulation No. 89: uniform provisions concerning the approval of: I. Vehicles with regard to limitation of their maximum speed; II. Vehicles with regard to the installation of a speed limitation device (SLD) of an approved type; III. Speed limitation devices (SLD). - 584 - 9.2.6 Coupling devices of trailers Coupling devices of trailers shall comply with the technical requirements of ECE Regulation No. 556 as amended, in accordance with the dates of application specified therein. 6 ECE Regulation No. 55 (Uniform provisions concerning the approval of mechanical coupling components of combinations of vehicles). - 585 - CHAPTER 9.3 ADDITIONAL REQUIREMENTS CONCERNING COMPLETE OR COMPLETED EX/II OR EX/III VEHICLES INTENDED FOR THE CARRIAGE OF EXPLOSIVE SUBSTANCES AND ARTICLES (CLASS 1) IN PACKAGES 9.3.1 Materials to be used in the construction of vehicle bodies No materials likely to form dangerous compounds with the explosive substances carried shall be used in the construction of the body. 9.3.2 Combustion heaters 9.3.2.1 Combustion heaters may only be installed on EX/II and EX/III vehicles for heating of the driver’s cab or the engine. 9.3.2.2 Combustion heaters shall meet the requirements of 9.2.4.7.1, 9.2.4.7.2, 9.2.4.7.5 and 9.2.4.7.6. 9.3.2.3 The switch of the combustion heater may be installed outside the driver's cab. It is not necessary to prove that the heat exchanger is resistant to the reduced afterrunning cycle. 9.3.2.4 No combustion heaters or fuel tanks, power sources, combustion air or heating air intakes as well as exhaust tube outlets required for the operation of the combustion heater shall be installed in the load compartment. 9.3.3 EX/II vehicles The vehicles shall be designed, constructed and equipped so that the explosives are protected from external hazards and the weather. They shall be either closed or sheeted. Sheeting shall be resistant to tearing and be of impermeable material, not readily flammable1. It shall be tautened so as to cover the loading area on all sides. All openings in the load compartment of closed vehicles shall have lockable, close-fitting doors or rigid covers. The driver’s compartment shall be separated from the load compartment by a continuous wall. 9.3.4 EX/III vehicles 9.3.4.1 The vehicles shall be designed, constructed and equipped so that the explosives are protected from external hazards and the weather. These vehicles shall be closed. The driver’s compartment shall be separated from the load compartment by a continuous wall. The loading surface shall be continuous. Load restraint anchorage points may be installed. All joints shall be sealed. All openings shall be capable of being locked. They shall be so constructed and placed as to overlap at the joints. 9.3.4.2 The body shall be made from heat and flame resistant materials with a minimum thickness of 10 mm. Materials classified as Class B-s3-d2 according to standard EN 13501-1:2007 + A1:2009 are deemed to fulfil this requirement. If the material used for the body is metal, the complete inside of the body shall be covered with materials fulfilling the same requirement. 1 In the case of flammability, this requirement will be deemed to be met if, in accordance with the procedure specified in ISO standard 3795:1989 ‘Road vehicles, and tractors and machinery for agriculture and forestry Determination of burning behaviour of interior materials’, samples of the sheeting have a burn rate not exceeding 100 mm/min. - 587 - 9.3.5 Engine and load compartment The engine propelling an EX/II or EX/III vehicle shall be placed forward of the front wall of the load compartment; it may nevertheless be placed under the load compartment, provided this is done in such a way that any excess heat does not constitute a hazard to the load by raising the temperature on the inner surface of the load compartment above 80 ºC. 9.3.6 External heat sources and load compartment The exhaust system of EX/II and EX/III vehicles or others parts of these complete or completed vehicles shall be so constructed and situated that any excess heat shall not constitute a hazard to the load by raising the temperature on the inner surface of the load compartment above 80 ºC. 9.3.7 Electrical equipment 9.3.7.1 The rated voltage of the electrical system shall not exceed 24V. 9.3.7.2 Any lighting in the load compartment of EX/II vehicles shall be on the ceiling and covered, i.e. with no exposed wiring or bulb. In the case of Compatibility Group J, the electrical installation shall be at least IP65 (e.g. flame-proof Eex d). Any electrical equipment accessible from the inside of the load compartment shall be sufficiently protected from mechanical impact from the inside. 9.3.7.3 The electrical installation on EX/III vehicles shall meet the relevant requirements of 9.2.2.2, 9.2.2.3, 9.2.2.4, 9.2.2.5.2 and 9.2.2.6. The electrical installation in the load compartment shall be dust-protected (at least IP54 or equivalent) or, in the case of Compatibility Group J, at least IP65 (e.g. flame-proof Eex d). - 588 - CHAPTER 9.4 ADDITIONAL REQUIREMENTS CONCERNING THE CONSTRUCTION OF THE BODIES OF COMPLETE OR COMPLETED VEHICLES INTENDED FOR THE CARRIAGE OF DANGEROUS GOODS IN PACKAGES (OTHER THAN EX/II AND EX/III VEHICLES) 9.4.1 Combustion heaters shall meet the following requirements: (a) The switch may be installed outside the driver's cab; (b) The device may be switched off from outside the load compartment; and (c) It is not necessary to prove that the heat exchanger is resistant to the reduced afterrunning cycle. 9.4.2 If the vehicle is intended for the carriage of dangerous goods for which a label conforming to models Nos. 1, 1.4, 1.5, 1.6, 3, 4.1, 4.3, 5.1 or 5.2 is prescribed, no fuel tanks, power sources, combustion air or heating air intakes as well as exhaust tube outlets required for the operation of the combustion heater shall be installed in the load compartment. It shall be ensured that the heating air outlet cannot be blocked by cargo. The temperature to which packages are heated shall not exceed 50º C. Heating devices installed inside the load compartments shall be designed so as to prevent the ignition of an explosive atmosphere under operating conditions. 9.4.3 Additional requirements concerning the construction of the bodies of vehicles intended for the carriage of given dangerous goods or specific packagings may be included in Part 7, Chapter 7.2 in accordance with the indications in Column (16) of Table A of Chapter 3.2, for a given substance. - 589 - CHAPTER 9.5 ADDITIONAL REQUIREMENTS CONCERNING THE CONSTRUCTION OF THE BODIES OF COMPLETE OR COMPLETED VEHICLES INTENDED FOR THE CARRIAGE OF DANGEROUS SOLIDS IN BULK 9.5.1 Combustion heaters shall meet the following requirements: (a) The switch may be installed outside the driver's cab; (b) The device may be switched off from outside the load compartment; and (c) It is not necessary to prove that the heat exchanger is resistant to the reduced afterrunning cycle. 9.5.2 If the vehicle is intended for the carriage of dangerous goods for which a label conforming to models Nos. 4.1, 4.3 or 5.1 is prescribed, no fuel tanks, power sources, combustion air or heating air intakes as well as exhaust tube outlets required for the operation of the combustion heater shall be installed in the load compartment. It shall be ensured that the heating air outlet cannot be blocked by cargo. The temperature to which the load is heated shall not exceed 50 ºC. Heating devices installed inside the load compartments shall be designed so as to prevent the ignition of an explosive atmosphere under operating conditions. 9.5.3 The bodies of vehicles intended for the carriage of dangerous solids in bulk shall meet the requirements of Chapter 6.11 and 7.3, as appropriate, including those of 7.3.2 or 7.3.3 which may be applicable in accordance with the indications in columns (10) or (17) respectively of Table A of Chapter 3.2 for a given substance. - 591 - CHAPTER 9.6 ADDITIONAL REQUIREMENTS CONCERNING COMPLETE OR COMPLETED VEHICLES INTENDED FOR THE CARRIAGE OF TEMPERATURE CONTROLLED SUBSTANCES 9.6.1 9.6.2 Insulated, refrigerated and mechanically-refrigerated vehicles intended for the carriage of temperature controlled substances shall conform to the following conditions: (a) the vehicle shall be such and so equipped as regards its insulation and means of refrigeration, that the control temperature prescribed in 2.2.41.1.17 and 2.2.52.1.16 and in 2.2.41.4 and 2.2.52.4 for the substance to be carried is not exceeded. The overall heat transfer coefficient shall be not more than 0.4 W/m2K; (b) the vehicle shall be so equipped that vapours from the substances or the coolant carried cannot penetrate into the driver's cab; (c) a suitable device shall be provided enabling the temperature prevailing in the loading space to be determined at any time from the cab; (d) the loading space shall be provided with vents or ventilating valves if there is any risk of a dangerous excess pressure arising therein. Care shall be taken where necessary to ensure that refrigeration is not impaired by the vents or ventilating valves; (e) the refrigerant shall not be flammable; and (f) the refrigerating appliance of a mechanically refrigerated vehicle shall be capable of operating independently of the engine used to propel the vehicle. Suitable methods (see V8(3)) to prevent the control temperature from being exceeded are listed in Chapter 7.2 (R1 to R5). Depending on the method used, additional provisions concerning the construction of vehicle bodies may be included in Chapter 7.2. - 593 - CHAPTER 9.7 ADDITIONAL REQUIREMENTS CONCERNING FIXED TANKS (TANK-VEHICLES), BATTERY-VEHICLES AND COMPLETE OR COMPLETED VEHICLES USED FOR THE CARRIAGE OF DANGEROUS GOODS IN DEMOUNTABLE TANKS WITH A CAPACITY GREATER THAN 1 M3 OR IN TANKCONTAINERS, PORTABLE TANKS OR MEGCs OF A CAPACITY GREATER THAN 3 M3 (EX/III, FL, OX AND AT VEHICLES) 9.7.1 General provisions 9.7.1.1 In addition to the vehicle proper, or the units of running gear used in its stead, a tank-vehicle comprises one or more shells, their items of equipment and the fittings for attaching them to the vehicle or to the running-gear units. 9.7.1.2 Once the demountable tank has been attached to the carrier vehicle, the entire unit shall meet the requirements prescribed for tank-vehicles. 9.7.2 Requirements concerning tanks 9.7.2.1 Fixed tanks or demountable tanks made of metal shall meet the relevant requirements of Chapter 6.8. 9.7.2.2 Elements of battery-vehicles and of MEGCs shall meet the relevant requirements of Chapter 6.2 in the case of cylinders, tubes, pressure drums and bundles of cylinders and the requirements of Chapter 6.8 in the case of tanks. 9.7.2.3 Tank-containers made of metal shall meet the requirements of Chapter 6.8, portable tanks shall meet the requirements of Chapter 6.7 or, if applicable, those of the IMDG Code (see 1.1.4.2). 9.7.2.4 Tanks made of fibre-reinforced plastics material shall meet the requirements of Chapter 6.9. 9.7.2.5 Vacuum-operated waste tanks shall meet the requirements of Chapter 6.10. 9.7.3 Fastenings Fastenings shall be designed to withstand static and dynamic stresses in normal conditions of carriage, and minimum stresses as defined in 6.8.2.1.2, 6.8.2.1.11 to 6.8.2.1.15 and 6.8.2.1.16 in the case of tank-vehicles, battery-vehicles, and vehicles carrying demountable tanks. 9.7.4 Earthing of FL vehicles Tanks made of metal or of fibre-reinforced plastics material of FL tank-vehicles and battery elements of FL battery-vehicles shall be linked to the chassis by means of at least one good electrical connection. Any metal contact capable of causing electrochemical corrosion shall be avoided. NOTE: See also 6.9.1.2 and 6.9.2.14.3. 9.7.5 Stability of tank-vehicles 9.7.5.1 The overall width of the ground-level bearing surface (distance between the outer points of contact with the ground of the right-hand tyre and the left-hand tyre of the same axle) shall be at least equal to 90% of the height of the centre of gravity of the laden tank-vehicle. In an articulated vehicle the mass on the axles of the load-carrying unit of the laden semi-trailer shall not exceed 60% of the nominal total laden mass of the complete articulated vehicle. - 595 - 9.7.5.2 In addition, tank-vehicles with fixed tanks with a capacity of more than 3 m3 intended for the carriage of dangerous goods in the liquid or molten state tested with a pressure of less than 4 bar, shall comply with the technical requirements of ECE Regulation No. 111 1 for lateral stability, as amended, in accordance with the dates of application specified therein. The requirements are applicable to tankvehicles which are first registered as from 1 July 2003. 9.7.6 Rear protection of vehicles A bumper sufficiently resistant to rear impact shall be fitted over the full width of the tank at the rear of the vehicle. There shall be a clearance of at least 100 mm between the rear wall of the tank and the rear of the bumper (this clearance being measured from the rearmost point of the tank wall or from projecting fittings or accessories in contact with the substance being carried). Vehicles with a tilting shell for the carriage of powdery or granular substances and a vacuum-operated waste tank with a tilting shell with rear discharge do not require a bumper if the rear fittings of the shell are provided with a means of protection which protects the shell in the same way as a bumper. NOTE 1: This provision does not apply to vehicles used for the carriage of dangerous goods in tank-containers, MEGCs or portable tanks. NOTE 2: For the protection of tanks against damage by lateral impact or overturning, see 6.8.2.1.20 and 6.8.2.1.21 or, for portable tanks, 6.7.2.4.3 and 6.7.2.4.5. 9.7.7 Combustion heaters 9.7.7.1 Combustion heaters shall meet the requirements of 9.2.4.7.1, 9.2.4.7.2, 9.2.4.7.5 and the following: (a) The switch may be installed outside the driver's cab; (b) The device may be switched off from outside the load compartment; and (c) It is not necessary to prove that the heat exchanger is resistant to the reduced afterrunning cycle. In addition for FL vehicles, they shall meet the requirements of 9.2.4.7.3 and 9.2.4.7.4. 9.7.7.2 If the vehicle is intended for the carriage of dangerous goods for which a label conforming to models Nos. 1.5, 3, 4.1, 4.3, 5.1 or 5.2 is prescribed, no fuel tanks, power sources, combustion air or heating air intakes as well as exhaust tube outlets required for the operation of the combustion heater shall be installed in the load compartment. It shall be ensured that the heating air outlet cannot be blocked by cargo. The temperature to which the load is heated shall not exceed 50 ºC. Heating devices installed inside the load compartments shall be designed so as to prevent the ignition of an explosive atmosphere under operating conditions. 9.7.8 Electrical equipment 9.7.8.1 The electrical installation on FL vehicles shall meet the relevant requirements of 9.2.2.2, 9.2.2.3, 9.2.2.4, 9.2.2.5.1 and 9.2.2.6. However additions to or modifications of the electrical installations of the vehicle shall meet the requirements for the electrical apparatus of the relevant group and temperature class according to the substances to be carried. NOTE: For transitional provisions, see also 1.6.5. 1 ECE Regulation No. 111: Uniform provisions concerning the approval of tank-vehicles of categories N and O with regard to rollover stability. - 596 - 9.7.8.2 Electrical equipment on FL vehicles, situated in areas where an explosive atmosphere is, or may be expected to be, present in such quantities as to require special precautions, shall be suitable for use in a hazardous area. Such equipment shall meet the general requirements of IEC 60079 parts 0 and 14 and the additional requirements applicable from IEC 60079 parts 1, 2, 5, 6, 7, 11 or 18. The requirements for the electrical apparatus of the relevant group and temperature class according to the substances to be carried shall be met. For the application of IEC 60079 part 14, the following classification shall be used: ZONE 0 Inside tank compartments, fittings for filling and discharge and vapour recovery lines. ZONE 1 Inside cabinets for equipment used for filling and discharge and within 0.5 m of venting devices and pressure relief safety valves. 9.7.8.3 Permanently energized electrical equipment, including the leads, which is situated outside Zones 0 and 1 shall meet the requirements for Zone 1 for electrical equipment in general or meet the requirements for Zone 2 according to IEC 60079 part 14 for electrical equipment situated in the driver's cab. The requirements for the relevant group of electrical apparatus according to the substances to be carried shall be met. 9.7.9 Additional safety requirements concerning EX/III vehicles 9.7.9.1 EX/III vehicles shall be equipped with automatic fire extinguisher systems for the engine compartment. 9.7.9.2 Protection of the load by metal thermal shields against tyre fire shall be provided. - 597 - CHAPTER 9.8 ADDITIONAL REQUIREMENTS CONCERNING COMPLETE AND COMPLETED MEMUs 9.8.1 General provisions In addition to the vehicle proper, or the units of running gear used in its stead, a MEMU comprises one or more tanks and bulk containers, their items of equipment and the fittings for attaching them to the vehicle or to the running-gear units. 9.8.2 Requirements concerning tanks and bulk containers Tanks, bulk containers and special compartments for packages of explosives of MEMUs shall meet the requirements of Chapter 6.12. 9.8.3 Earthing of MEMUs Tanks, bulk containers and special compartments for packages of explosives made of metal or of fibre-reinforced plastics material shall be linked to the chassis by means of at least one good electrical connection. Any metal contact capable of causing electro-chemical corrosion or reacting with the dangerous goods carried in the tanks and bulk containers shall be avoided. 9.8.4 Stability of MEMUs The overall width of the ground-level bearing surface (distance between the outer points of contact with the ground of the right-hand tyre and the left-hand tyre of the same axle) shall be at least equal to 90% of the height of the centre of gravity of the laden vehicle. In an articulated vehicle the mass on the axles of the load-carrying unit of the laden semi-trailer shall not exceed 60% of the nominal total laden mass of the complete articulated vehicle. 9.8.5 Rear protection of MEMUs A bumper sufficiently resistant to rear impact shall be fitted over the full width of the tank at the rear of the vehicle. There shall be a clearance of at least 100 mm between the rear wall of the tank and the rear of the bumper (this clearance being measured from the rearmost point of the tank wall or from protecting fittings or accessories in contact with the substance being carried). Vehicles with a tilting shell with rear discharge do not require a bumper if the rear fittings of the shell are provided with a means of protection which protects the shell in the same way as a bumper. NOTE: This provision does not apply to MEMUs where the tanks are protected adequately against rear impact by other means, e.g. machinery or piping not containing dangerous goods. 9.8.6 Combustion heaters 9.8.6.1 Combustion heaters shall meet the requirements of 9.2.4.7.1, 9.2.4.7.2, 9.2.4.7.5, 9.2.4.7.6 and the following: (a) the switch may be installed outside the driver's cab; (b) the device shall be switched off from outside the MEMU compartment; and (c) it is not necessary to prove that the heat exchanger is resistant to the reduced afterrunning cycle. - 599 - 9.8.6.2 No fuel tanks, power sources, combustion air or heating air intakes as well as exhaust tube outlets required for the operation of the combustion heater shall be installed in the load compartments containing tanks. It shall be ensured that the heating air outlet cannot be blocked. The temperature to which any equipment is heated shall not exceed 50 ºC. Heating devices installed inside the compartments shall be designed so as to prevent the ignition of any explosive atmosphere under operating conditions. 9.8.7 Additional safety requirements 9.8.7.1 MEMUs shall be equipped with automatic fire extinguisher systems for the engine compartment. 9.8.7.2 Protection of the load by metal thermal shields against tyre fire shall be provided. 9.8.8 Additional security requirements Process equipment and special compartments in MEMUs shall be fitted with locks. - 600 -

A დანართი ზოგადი დებულებები და სახიფათო ნივთიერებებსა და ნაკეთობებთან დაკავშირებული დებულებები 1 2 ნაწილი 1 ზოგადი დებულებები 3 4 თავი 1.1 მოქმედების არეალი და გამოყენებადობა 1.1.1 სტრუქტურა ADR-ის A და B დანართები დაჯგუფებულია ცხრა ნაწილად. A დანართი შედგება 1-დან 7მდე ნაწილისგან, ხოლო B დანართი - მე-8 და მე-9 ნაწილებისგან. თითოეული ნაწილი, თავის მხრივ, იყოფა თავებად, ხოლო ყოველი თავი - პუნქტებად და ქვეპუნქტებად. ყოველი ნაწილის ფარგლებში ნაწილის ნომერი გათვალისწინებულია თავების, პუნქტებისა და ქვეპუნქტების ნომრებში, მაგალითად, ნაწილი 4, თავი 2, პუნქტი 1 წარმოდგენილია, როგორც „4.2.1“. 1.1.2 მოქმედების არეალი 1.1.2.1 ADR-ის მე-2 მუხლის მიზნებიდან გამომდინარე, A დანართი ითვალისწინებს: 1.1.2.2 (ა) სახიფათო ტვირთებს, რომელთა საერთაშორისო გადაზიდვაც აკრძალულია; (ბ) სახიფათო ტვირთებს, რომელთა საერთაშორისო გადაზიდვაც ნებადართულია და ექვემდებარება შესაბამის პირობებს (გამონაკლისების ჩათვლით), კერძოდ, შემდეგთან დაკავშირებით: - ტვირთების კლასიფიკაცია, კლასიფიცირების კრიტერიუმებისა და შესაბამისი გამოცდის მეთოდების ჩათვლით; - ტარის გამოყენება (ერთობლივი შეფუთვის ჩათვლით); - ცისტერნების გამოყენება (შევსების ჩათვლით); - ტვირთის გაგზავნის პროცედურები (შეფუთვებზე მარკირებისა და უსაფრთხოების ნიშნების განთავსებისა და გადასაზიდ საშუალებებზე საინფორმაციო დაფებისა და აღნიშვნების განთავსების, ასევე აუცილებელი დოკუმენტაციისა და ინფორმაციის უზრუნველყოფის ჩათვლით); - ტარისა და ცისტერნების დამზადებასთან, გამოცდასა და გადაზიდვებზე დაშვებასთან დაკავშირებული დებულებები; - გადასაზიდი საშუალებების გამოყენება დატვირთვისა და გადმოტვირთვის ჩათვლით). (დატვირთვის, ერთობლივი A დანართი ითვალისწინებს გარკვეულ დებულებებს, რომლებიც, ADR-ის მე-2 მუხლის თანახმად, ეხება როგორც B დანართს, ასევე A და B დანართებს და წარმოდგენილია შემდეგი სახით: 1.1.1 1.1.2.3 1.1.2.4 1.1.3.1 1.1.3.6 1.1.4 1.1.4.5 თავი 1.2 სტრუქტურა (B დანართის მოქმედების არეალი) სატრანსპორტო ოპერაციის მახასიათებლებიდან გამომდინარე გამონაკლისები ყოველი სატრანსპორტო ერთეულის მიერ გადაზიდულ რაოდენობებთან დაკავშირებული გამონაკლისები სხვა წესების მოქმედება სხვა გადაზიდვები, გარდა საგზაო გადაზიდვებისა განმარტებები და საზომი ერთეულები 5 თავი 1.3 თავი 1.4 თავი 1.5 თავი 1.6 თავი 1.8 სახიფათო ტვირთების გადაზიდვებში ჩართული პირების მომზადება გადაზიდვების მონაწილეების ვალდებულებები უსაფრთხოების საკითხში გადახვევები დადგენილი წესებიდან გარდამავალი ღონისძიებები შემოწმებები და უსაფრთხოების მოთხოვნებთან შესაბამისობის უზრუნველყოფისკენ მიმართული სხვა დამხმარე ღონისძიებები თავი 1.9 კომპეტენტური ორგანოების მიერ დადგენილი სატრანსპორტო შეზღუდვები თავი 1.10 უსაფრთხოების უზრუნველყოფასთან დაკავშირებული დებულებები თავი 3.1 ზოგადი დებულებები თავი 3.2 სვეტები (1), (2), (14), (15) და (19) (მე-8 და მე-9 ნაწილების დებულებების გამოყენება ინდივიდუალურ ნივთიერებებსა თუ ნაკეთობებთან დაკავშირებით). 1.1.2.3 ADR-ის მე-2 მუხლის მიზნებიდან გამომდინარე, B დანართი ითვალისწინებს პირობებს გადაზიდვებზე დაშვებული სახიფათო ტვირთების გადამზიდი ავტოსატრანსპორტო საშუალებების კონსტრუირებასთან, აღჭურვასა და ექსპლუატაციასთან დაკავშირებით: - ავტოსატრანსპორტო საშუალებების ეკიპაჟთან, აღჭურვილობასთან, ექსპლუატაციასა და დოკუმენტაციასთან დაკავშირებული მოთხოვნები; - ავტოსატრანსპორტო საშუალებების კონსტრუირებასა და გადაზიდვებზე დაშვებასთან დაკავშირებული მოთხოვნები. 1.1.2.4 ADR-ის 1(გ) მუხლში, ტერმინი „ავტოსატრანსპორტო საშუალება“ არ გულისხმობს აუცილებლად ერთსა და იმავე ავტოსატრანსპორტო საშუალებას. საერთაშორისო სატრანსპორტო ოპერაცია შესაძლებელია განხორციელდეს რამდენიმე სხვადასხვა ავტოსატრანსპორტო საშუალების მიერ იმ პირობით, რომ აღნიშნული ოპერაცია განხორციელდება ADR-ის მინიმუმ ორი ხელშემკვრელი მხარის ტერიტორიაზე სატრანსპორტო დოკუმენტში გათვალისწინებულ ტვირთგამგზავნსა და ტვირთმიმღებს შორის. 1.1.3 გამონაკლისები 1.1.3.1 სატრანსპორტო ოპერაციის მახასიათებლებიდან გამომდინარე გამონაკლისები ADR-ში გათვალისწინებული დებულებები არ გამოიყენება შემდეგთან დაკავშირებით: (ა) სახიფათო ტვირთების გადაზიდვა კერძო პირების მიერ, როდესაც აღნიშნული ტვირთი შეფუთულია საცალო რეალიზაციის მიზნით და გათვალისწინებულია პირადი თუ საყოფაცხოვრებო მოხმარებისთვის, დასასვენებელი ან სპორტული ღონისძიებებისთვის იმ პირობით, რომ მოხდება შესაბამისი ზომების მიღება გადაზიდვის ნორმალურ პირობებში ტვირთის შიგთავსის გაჟონვის პრევენციის მიზნით. იმ შემთხვევაში, თუ აღნიშნული ტვირთი წარმოდგენილია ადვილაალებადი სითხეების სახით, რომლის გადაზიდვაც ხორციელდება კერძო პირების მიერ ან მათთვის შევსებული მრავალჯერადი გამოყენების ჭურჭლით, აღნიშნული სითხის საერთო რაოდენობამ არ უნდა გადააჭარბოს 60 ლიტრს ყოველ ჭურჭელზე და 240 ლიტრს - ყოველ სატრანსპორტო ერთეულზე. მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებში, მსხვილგაბარიტიან ტარასა თუ ცისტერნებში მოთავსებული სახიფათო ტვირთი არ ჩაითვლება შეფუთულად საცალო გაყიდვების მიზნით; 6 (ბ) იმ მექანიზმებისა თუ მოწყობილობების გადაზიდვა, რომლებიც არ არის გათვალისწინებული წინამდებარე დანართში და სავარაუდოდ შეიცავს სახიფათო ტვირთებს მათ შიდა ან საექსპლუატაციო მოწყობილობებში, თუმცა იმ პირობით, რომ მოხდება შესაბამისი ზომების მიღება გადაზიდვის ნორმალურ პირობებში ტვირთის შიგთავსის გაჟონვის პრევენციის მიზნით; (გ) საწარმოების მიერ განხორციელებული გადაზიდვები მათ ძირითად საქმიანობაზე დამატების სახით, როგორიცაა, მაგალითად, ტვირთების მიწოდება სამშენებლო ან საინჟინრო-ტექნიკურ ობიექტებზე ან მათი დაბრუნება აღნიშნული ობიექტებიდან, ან აზომვით, სარემონტო და ტექნიკურ უზრუნველყოფასთან დაკავშირებულ სამუშაოებთან მიმართებაში, არაუმეტს 450 ლიტრის რაოდენობით ცალკეულ ტარაზე და 1.1.3.6 პუნქტში გათვალისწინებული მაქსიმალური ოდენობის ფარგლებში. გადაზიდვის ნორმალურ პირობებში ტვირთის შიგთავსის გაჟონვის პრევენციის მიზნით უნდა განხორციელდეს შესაბამისი ზომები. აღნიშნული გამონაკლისები არ გამოიყენება მე-7 კლასის შემთხვევაში. ასევე ზემოაღნიშნული გამონაკლისი არ ეხება იმ გადაზიდვებს, რომლებიც სრულდება ამ საწარმოების მიერ საკუთარი მიწოდების ან გარე თუ შიდა განაწილების მიზნით; (დ) კომპეტენტური ორგანოების მიერ განხორციელებული გადაზიდვები ავარიული სამუშაოების ჩასატარებლად ან მათი ზედამხედველობის მიზნით, რამდენადაც აღნიშნული გადაზიდვები აუცილებელია ავარიული სამუშაოების განსახორციელებლად, განსაკუთრებით შემდეგი გზით განხორციელებული გადაზიდვების შემთხვევაში: - ტექნიკური დახმარების ავტოსატრანსპორტო საშუალებები, რომლებიც გამოიყენება ავტოსაგზაო შემთხვევაში მოყოლილი, გაუმართავი და სახიფათო ტვირთების შემცველი ავტოსატრანსპორტო საშუალებების გადასაზიდად; - უბედურ ან ავტოსაგზაო შემთხვევაში მოყოლილი სახიფათო ტვირთის ლოკალიზებისა და აღდგენის და მათი უახლოეს სათანადო, უსაფრთხო ადგილზე გადატანის მიზნით; (ე) ადამიანების გადასარჩენად და გარემოს დასაცავად გათვალისწინებული ავარიული გადაზიდვები იმ პირობით, რომ მოხდება ყოველგვარი აუცილებელი ზომის მიღება აღნიშნული გადაზიდვების სრული უსაფრთხოების უზრუნველყოფის მიზნით; (ვ) გაუსუფთავებელი, ცარიელი, სტაციონარული, შესანახი რეზერვუარების გადაზიდვა, რომელიც შეიცავდა მე-2 კლასის ა, პ ან ვ ჯგუფის აირებს, მე-3 ან მე-9 კლასის ნივთიერებებს, რომლებიც განეკუთვნება II ან III შეფუთვის ჯგუფებს ან II ან III ჯგუფში შემავალი 6.1 კლასის პესტიციდებს, შემდეგი პირობების დაცვით: - ყველა ნახვრეტი, წნევის შემზღუდველი მოწყობილობის დამაგრების შემთხვევაში), ჰერმეტულად არის დახურული; - მიღებულ იქნა შესაბამისი ზომები გადაზიდვის ნორმალურ პირობებში ტვირთის შიგთავსის გაჟონვის პრევენციის მიზნით; და - ტვირთი დამაგრებულია ჩარჩოებზე, გისოსსა თუ სხვა სატრანსპორტოსატვირთო მოწყობილობაზე ან ავტოსატრანსპორტო საშუალებებსა თუ 7 გარდა (მისი კონტეინერებზე ისე, რომ შეუძლებელი იყოს მისი მოშვება ან გადაადგილება გადაზიდვის ნორმალურ პირობებში. ზემოაღნიშნული გამონაკლისი არ მოქმედებს იმ სტაციონარულ, შესანახ რეზერვუარებთან დაკავშირებით, რომელიც შეიცავს დესენსიბილიზებულ ფეთქებად ნივთიერებებს ან ისეთ ნივთიერებებს, რომელთა გადაზიდვაც იკრძალება ADR-ის მიერ. შენიშვნა: რადიოაქტიურ მასალებთან დაკავშირებით, იხილეთ 1.7.1.4 პუნქტი. 1.1.3.2 აირების გადაზიდვასთან დაკავშირებული გამონაკლისები ADR-ში გათვალისწინებული დებულებები გადაზიდვასთან დაკავშირებით: არ გამოიყენება შემდეგი ტვირთის (ა) იმ ავტოსატრანსპორტო საშუალებების ცისტერნებში შემავალი აირები, რომლებიც ასრულებენ სატრანსპორტო ოპერაციას და გათვალისწინებულია მისი წევისთვის ან მისი ნებისმიერი მოწყობილობის ექსპლუატაციისთვის (მაგალითად, მაცივებელი აღჭურვილობა); (ბ) ტრანსპორტირებული ავტოსატრანსპორტო საშუალებების საწვავის ავზებში შემავალი აირები. საწვავის ონკანი აირის ავზსა და ძრავს შორის უნდა დაიკეტოს, ხოლო ელექტრო კონტაქტი კი დარჩეს ღია; (გ) ა და პ ჯგუფის აირები (2.2.2.1 პუნქტის თანახმად) იმ შემთხვევაში, თუ აირის წნევა რეზერვუარსა თუ ცისტერნაში 200C ტემპერატურაზე არ აღემატება 200 კპა-ს (2 ბარს) და თუ აირი არ წარმოადგენს გათხევადებულ ან გაცივებულ, გათხევადებულ აირს. აქ იგულისხმება ნებისმიერი სახის რეზერვუარი ან ცისტერნა, მაგალითად, ისინიც, რომლებიც წარმოადგენს მანქანებისა და აპარატურის ნაწილებს; შენიშვნა: აღნიშნული გამონაკლისები არ ვრცელდება ნათურებზე. ნათურებთან დაკავშირებით იხილეთ ქვეპუნქტი 1.1.3.10. (დ) ავტოსატრანსპორტო საშუალებების ექსპლუატაციისთვის გამოყენებულ მოწყობილობაში შემავალი აირები (მაგალითად, ცეცხლმაქრები), სათადარიგო ნაწილების (მაგალითად, ამობურცული პნევმატური საბურავების) ჩათვლით; ზემოაღნიშნული გამონაკლისი ასევე გამოიყენება ტვირთების სახით გადატანილი ამობურცული პნევმატური საბურავების შემთხვევაშიც; (ე) ავტოსატრანსპორტო საშუალებების სპეციალურ მოწყობილობაში შემავალი აირები, რომლებიც აუცილებელია აღნიშნული სპეციალური მოწყობილობის ექსპლუატაციისთვის გადაზიდვების დროს (მაგალითად, მაცივებელი სისტემები, თევზების მოსათავსებელი რეზერვუარები, რადიატორები და ა.შ.), ასევე სათადარიგო სათავსები აღნიშნული მოწყობილობებისთვის ან გაუსუფთავებელი ცარიელი შემცვლელი სათავსები, რომელთა გადაზიდვაც ხდება იგივე სატრანსპორტო ერთეულში; (ვ) საკვებ პროდუქტებში შემავალი აირები (გარდა გაეროს N1950-სა), გაზირებული სასმელების ჩათვლით; და (ზ) სპორტული მოხმარების ბურთებში შემავალი აირები; (თ) (ამოღებულია) 8 1.1.3.3 თხევადი საწვავის გადაზიდვასთან დაკავშირებული გამონაკლისები ADR-ში გათვალისწინებული დებულებები გადაზიდვასთან დაკავშირებით: (ა) არ გამოიყენება შემდეგი ტვირთების იმ სატრანსპორტო საშუალებების ცისტერნებში შემავალი საწვავი, რომლებიც ასრულებს სატრანსპორტო ოპერაციას და განკუთვნილია მისი წევის უზრუნველსაყოფად ან მისი იმ ნებისმიერი მოწყობილობის ექსპლუატაციისთვის, რომლებიც გამოიყენება ან გათვალისწინებულია გადაზიდვების დროს გამოყენებისთვის. საწვავის გადაზიდვა შესაძლებელია დამონტაჟებულ საწვავის ცისტერნებში, რომლებიც უშუალოდ არის დაკავშირებული ავტოსატრანსპორტო საშუალების ძრავსა და/ან დამხმარე მოწყობილობებთან და აკმაყოფილებს შესაბამისი ნორმატიულ-სამართლებრივი აქტების მოთხოვნებს, ან შესაძლებელია მათი გადაზიდვა გადამზიდი საწვავის კონტეინერებით (მაგალითად, კანისტრებით). დამონტაჟებული ცისტერნების სრულმა მოცულობამ არ უნდა გადააჭარბოს 1500 ლიტრს ყოველ სატრანსპორტო ერთეულზე, ხოლო მისაბმელზე დამონტაჟებული ცისტერნის მოცულობამ არ უნდა გადააჭარბოს 500 ლიტრს. საწვავის გადამზიდ კონტეინერებში შესაძლებელია მაქსიმუმ 60 ლიტრის გადაზიდვა ყოველ სატრანსპორტო ერთეულზე. აღნიშნული შეზღუდვები არ მოქმედებს გადაუდებელი დახმარების სამსახურებში გამოყენებულ ავტოსატრანსპორტო საშუალებებთან დაკავშირებით; (ბ) ავტოსატრანსპორტო საშუალებებისა თუ სხვა გადასაზიდი საშუალებების (როგორიცაა, გემები) ცისტერნებში წარმოდგენილი საწვავი, რომლის გადაზიდვაც ხორციელდება ტვირთის სახით, თუ აღნიშნული საწვავი განკუთვნილია წევის უზრუნველყოფისა თუ მათი ნებისმიერი მოწყობილობის ექსპლუატაციის მიზნით. გადაზიდვის დროს აუცილებელია დაიხუროს საწვავის ყველა ონკანი ძრავსა თუ მოწყობილობასა და საწვავის ავზს შორის გარდა იმ შემთხვევისა, როდესაც მოწყობილობა უნდა დარჩეს საოპერაციო მდგომარეობაში. აუცილებლობის შემთხვევაში, ავტოსატრანსპორტო საშუალებები ან გადაზიდვის სხვა საშუალებები უნდა დაიტვირთოს ვერტიკალურ მდგომარეობაში და დამაგრდეს ყოველგვარი ხარვეზის გამორიცხვით. (გ) არასაგზაო მოძრავი ტექნიკის 1 ცისტერნებში წარმოდგენილი საწვავი, რომლის გადაზიდვაც ხორციელდება ტვირთის სახით, თუ აღნიშნული საწვავი განკუთვნილია წევის უზრუნველყოფისა თუ მათი ნებისმიერი მოწყობილობის ექსპლუატაციის მიზნით. საწვავის გადაზიდვა შესაძლებელია პირდაპირ სატრანსპორტო საშუალების ძრავთან და/ან აღჭურვილობასთან მიერთებული დამონტაჟებული საწვავი ცისტერნებით, რომლებიც პასუხობს სამარრთლებრივ მოთხოვნებს. აუცილებლობის შემთხვევაში, აღნიშნული ტექნიკა უნდა 1 არასაგზაო მოძრავი ტექნიკის განმარტება წარმოდგენილია სატრანსპორტო საშუალებების კონსტრუირების შესახებ კონსოლიდირებული რეზოლუციის (R.E.3) (გაეროს დოკუმენტი ECE/TRANS/WP.29/78/Rev.3) 2.7 პუნქტში ან არასაგზაო მოძღავ ტექნიკაში დამონტაჟებული შიგაწვის ძრავებიდან გამონაბოლქვისა და მყარი ნაწილაკების გამოყოფის წინააღმდეგ მიღებულ ღონისძიებებთან დაკავშირებით წევრი სახელმწიფოების კანონმდებლობის მიახლოვების შესახებ ევროპარლამენტისა და საბჭოს 1997 წლის 16 დეკემბრის 97/68/EC დირექტივის მე-2 მუხლში (ევროპული კომიტეტის ოფიციალური ჟურნალი #L059, 1998 წლის 27 თებერვალი). 9 დაიტვირთოს ვერტიკალურ მდგომარეობაში და დამაგრდეს ყოველგვარი ხარვეზის გამორიცხვით. 1.1.3.4 სპეციალურ დებულებებთან ან შეზღუდულ ან გამოთავისუფლებულ ოდენობებად შეფუთულ სახიფათო ტვირთებთან დაკავშირებული გამონაკლისები შენიშვნა: რადიოაქტიურ მასალებთან დაკავშირებით, იხილეთ 1.7.1.4 პუნქტი. 1.1.3.4.1 3.3 თავის ზოგიერთი სპეციალური დებულება ნაწილობრივ ან სრულად ათავისუფლებს კონკრეტული სახიფათო ტვირთების გადაზიდვას ADR-ის მოთხოვნებისგან. აღნიშნული გამონაკლისი მოქმედებს იმ შემთხვევაში, თუ 3.2 თავის A ცხრილის (6) სვეტში, შესაბამისი სახიფათო ტვირთების გრაფაში გათვალისწინებულია სპეციალური დებულება. 1.1.3.4.2 ზოგიერთი სახიფათო ტვირთი შესაძლებელია დაექვემდებაროს გამონაკლისს იმ პირობით, თუ დაკმაყოფილდება 3.4 თავში გათვალისწინებული მოთხოვნები. 1.1.3.4.3 ზოგიერთი სახიფათო ტვირთი შესაძლებელია დაექვემდებაროს გამონაკლისს იმ პირობით, თუ დაკმაყოფილდება 3.5 თავში გათვალისწინებული პირობები. 1.1.3.5 ცარიელ, გაუსუფთავებელ ტარასთან დაკავშირებული გამონაკლისები ADR-ის მოთხოვნები არ ვრცელდება ცარიელ, გაუსუფთავებელ ტარაზე (მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებისა და მსხვილგაბარიტიანი ტარის ჩათვლით), რომელიც შეიცავს 2, 3, 4.1, 5.1, 6.1, 8 და 9 კლასებით გათვალისწინებულ ნივთიერებებს იმ შმთხვევაში, თუ განხორციელდება შესაბამისი ზომები ნებისმიერი საშიშროების აღმოსაფხვრელად. საშიშროება ჩაითვლება აღმოფხვრილად იმ შემთხვევაში, თუ ადგილი ექნება შესაბამისი ზომების განხორციელებას 1-დან 9 კლასებით გათვალისწინებული საშიშროებების განეიტრალების მიზნით. 1.1.3.6 ერთი სატრანსპორტო გამონაკლისები ერთეულით გადატანილ ოდენობებთან დაკავშირებული 1.1.3.6.1 წინამდებარე ქვეპუნქტის მიზნებიდან გამომდინარე, სახიფათო ტვირთები განეკუთვნება 0, 1, 2, 3 ან 4 სატრანსპორტო კატეგორიებს, როგორც ეს მითითებულია 3.2 თავის A ცხრილის (15) სვეტში. ცარიელი, გაუსუფთავებელი ტარა, რომელიც შეიცავს „0“ სატრანსპორტო კატეგორიისათვის მიკუთვნებულ ნივთიერებებს, ასევე განეკუთვნება სატრანსპორტო კატეგორიას „0“. ცარიელი, გაუსუფთავებელი ტარა, რომელიც შეიცავს იმ ნივთიერებებს, რომლებიც არ მიეკუთვნება „0“ სატრანსპორტო კატეგორიას, წარმოდგენილია სატრანსპორტო კატეგორიაში „4“. 1.1.3.6.2 იმ შემთხვევაში, თუ ერთი სატრანსპორტო ერთეულით გადატანილი სახიფათო ტვირთის რაოდენობა არ აღემატება 1.1.3.6.3 პუნქტის ცხრილის (3) სვეტში გათვალისწინებულ მნიშვნელობებს მოცემულ სატრანსპორტო კატეგორიასთან დაკავშირებით (როდესაც სატრანსპორტო ერთეულში გადატანილი სახიფათო ტვირთი განეკუთვნება ერთსა და იმავე კატეგორიას) ან 1.1.3.6.4 პუნქტის თანახმად გამოთვლილ მნიშვნელობას (როდესაც სატრანსპორტო ერთეულით გადატანილი სახიფათო ტვირთი განეკუთვნება სხვადასხვა სატრანსპორტო კატეგორიას), აღნიშნული სახიფათო ტვირთების გადაზიდვა შესაძლებელია შეფუთვების სახით ერთ სატრანსპორტო ერთეულში შემდეგი დებულებების გამოყენების გარეშე: - თავი 1.10, გარდა პირველი კლასით გათვალისწინებული ფეთქებადი ნივთიერებებისა გაეროს ნომრებით: 0029, 0030, 0059, 0065, 0073, 0104, 0237, 0255, 0267, 0289, 0290, 0360, 10 - - 0361, 0364, 0365, 0366, 0439, 0440, 0441, 0455, 0456 და 0500 და გარდა მე-7 კლასით გათვალისწინებული გამოთავისუფლებული შეფუთვებისა გაეროს ნომრებით: 0291 და 2911 იმ შემთხვევაში, თუ აქტივობის დონე აღემატება A2 მნიშვნელობას; თავი 5.3; კარი 5.4.3; თავი 7.2, გარდა 7.2.4 პუნქტის V5 და V8-სა; 7.5.11 პუნქტის CV1; მე-8 ნაწილი, გარდა 8.1.2.1(ა) პუნქტისა; 8.1.4.2-დან 8.1.4.5 პუნქტებისა; 8.2.3 პუნქტისა; 8.3.3 პუნქტისა; 8.3.4 პუნქტისა; 8.3.5 პუნქტისა; 8.4 თავისა; S1(3) და (6); S2(1); S4, S5; S14-დან S21-მდე; და 8.5 თავის S24. მე-9 ნაწილი. 1.1.3.6.3 იმ შემთხვევაში, როდესაც სატრანსპორტო ერთეულით გადატანილი სახიფათო ტვირთები განეკუთვნება ერთსა და იმავე კატეგორიას, ერთ სატრანსპორტო ერთეულზე მაქსიმალური საერთო რაოდენობა წარმოდგენილია ქვემოთ მოყვანილი ცხრილის (3) სვეტში. სატრანსპორტო კატეგორია (1) 0 ნივთიერებები ან ნაკეთობები შეფუთვის ჯგუფი ან კლასიფიკაციის კოდი/ჯგუფი ან გაეროს № კლასი 1: კლასი 3: კლასი 4.2 კლასი 4.3: კლასი 5.1: კლასი 6.1: კლასი 6.2: კლასი 7: კლასი 8: კლასი 9: (2) 1.1A/1.1L/1.2L/1.3L და გაეროს №0190 გაეროს №3343 I შეფუთვის ჯგუფს განკუთვნილი ნივთიერებები გაეროს № 1183, 1242, 1295, 1340, 1390, 1403, 1928, 2813, 2965, 2968, 2988, 3129, 3130, 3131, 3134, 3148, 3396, 3398 და 3399 გაეროს № 2426 გაეროს № 1051, 1600, 1613, 1614, 2312, 3250 და 3294 გაეროს № 2814 და 2900 გაეროს № 2912-დან 2919-მდე, 2977, 2978 და 3321-დან 3333-მდე გაეროს № 2215 (მალეინის ანჰიდრიდი, მდნარი) გაეროს № 2315, 3135, 3152 და 3432 და აღნიშნული ნივთიერებებისა და ნარევების, ასევე ცარიელი, გაუსუფთავებელი ტარის შემცველი აპარატურა, გარდა გაეროს №2908 კლასიფიცირებული ტარისა, რომელიც შეიცავს აღნიშნულ სატრანსპორტო 11 მაქსიმალური საერთო რაოდენობა ერთ სატრანსპორტო ერთეულზე (3) 0 სატრანსპორტო კატეგორია ნივთიერებები ან ნაკეთობები შეფუთვის ჯგუფი ან კლასიფიკაციის კოდი/ჯგუფი ან გაეროს № (1) (2) კატეგორიაში კლასიფიცირებულ ნივთიერებებს. I შეფუთვის ჯგუფში შემავალი ნივთიერებები და ნაკეთობები, რომლებიც არ არის კლასიფიცირებული „0“ სატრანსპორტო კატეგორიაში. კლასი 1: 1.1B-დან 1.1J-მდეა / 1.2B-დან 1.2J-მდე / 1.3C / 1.3G / 1.3H / 1.3J / 1.5Dა კლასი 2: ჯგუფები T, TCა, TO, TF, TOCა და RFC. აეროზოლები: ჯგუფები C, CO, FC, T, TF, TC, TO, TFC და TOC ქიმიური ნივთიერებები წნევის ქვეშ: გაეროს №3502, 3503, 0504 და 3505 კლასი 4.1: გაეროს № 3221-დან 3224-მდე და 3231-დან 3240-მდე კლასი 5.2: გაეროს № 3101-დან 3104-მდე და 3111-დან 3120-მდე. II შეფუთვის ჯგუფში შემავალი ნივთიერებები და ნაკეთობები, რომლებიც არ არის კლასიფიცირებული „0“, „1“ ან „4“ სატრანსპორტო კატეგორიებში. კლასი 1: 1.4B-დან 1.4G-მდე 1.6N კლასი 2: ჯგუფი F აეროზოლები: ჯგუფი F ქიმიური ნივთიერებები წნევის ქვეშ: გაეროს №3501 კლასი 4.1: გაეროს № 3225-დან 3230-მდე კლასი 5.2: გაეროს № 3105-დან 3110-მდე კლასი 6.1: II შეფუთვის ჯგუფში შემავალი ნივთიერებები და ნაკეთობები კლასი 9: გაეროს №3245 III შეფუთვის ჯგუფში შემავალი ნივთიერებები და ნაკეთობები, რომლებიც არ არის კლასიფიცირებულიი „0“, „2“ ან „4“ სატრანსპორტო კატეგორიებში. კლასი 2: ჯგუფები A და O აეროზოლები: ჯგუფები A და O ქიმიური ნივთიერებები წნევის ქვეშ: გაეროს №3500 კლასი 3: გაეროს №3473 კლასი 4.3: გაეროს №3476 კლასი 8: გაეროს №2794, 2795, 2800, 3028 და 3477 კლასი 9: გაეროს №2990 და 3072 კლასი 1: 1.4S კლასი 4.1: გაეროს №1331, 1345, 1944, 1945, 2254 და 2623 კლასი 4.2: გაეროს №1361 და 1362, შეფუთვის ჯგუფი III კლასი 7: გაეროს №2908 და 2911 კლასი 9: გაეროს №3268, 3499 და 3509 და ცარიელი, გაუსუფთავებელი, სახიფათო ტვირთის შემცველი ტარა, გარდა 0 სატრანსპორტო კატეგორიაში კლასიფიცირებული ტვირთებისა. 1 2 3 4 ა მაქსიმალური საერთო რაოდენობა ერთ სატრანსპორტო ერთეულზე (3) 20 333 1 000 შეუზღუდავი გაეროს №0081, 0082, 0084, 0241, 0331, 0332, 0482, 1005 და 1017 დაკავშირებით, ერთ სატრანსპორტო ერთეულზე მაქსიმალური საერთო რაოდენობა უნდა შეადგენდეს 50 კგ-ს. 12 ზემოაღნიშნულ ცხრილში, „ერთ სატრანსპორტო ერთეულზე მაქსიმალური საერთო რაოდენობა“ ნიშნავს: - ნაკეთობების შემთხვევაში - საერთო მასა კილოგრამებში (I კლასის ნაკეთობების შემთხვევაში - ფეთქებადი ნივთიერებების სუფთა მასა კილოგრამებში; აღნიშნულ დანართში გათვალისწინებულ მექანიზმებსა და მოწყობილობებში წარმოდგენილი სახიფათო ტვირთების შემთხვევაში, მასში შემავალი სახიფათო ტვირთების საერთო რაოდენობა კილოგრამებსა თუ ლიტრებში, კონკრეტული შემთხვევიდან გამომდინარე); - მყარი ნივთიერებების, თხევადი აირების, გაყინული თხევადი აირებისა და გახსნილი აირების შემთხვევაში, სუფთა მასა კილოგრამებში; - სითხეების შემთხვევაში, სახიფათო ტვირთის საერთო რაოდენობა ლიტრებში; - შეკუმშული აირების, ადსორბირებული აირებისა და წნევის ქვეშ მყოფი ქიმიური ნივთიერებების შემთხვევაში, ჭურჭლის ნომინალური მოცულობა ლიტრებში. 1.1.3.6.4 იმ შემთხვევაში, თუ სხვადასხვა სატრანსპორტო კატეგორიებში შემავალი სახიფათო ტვირთების გადაზიდვა ხორციელდება ერთი და იმავე სატრანსპორტო ერთეულით, შემდეგი მნიშვნელობების ჯამმა: - პირველ სატრანსპორტო კატეგორიაში შემავალი ნივთიერებებისა და ნაკეთობების რაოდენობა გამრავლებული „50“-ზე; - 1.1.3.6.3 ცხრილის შენიშვნაში გათვალისწინებული პირველ სატრანსპორტო კატეგორიაში შემავალი ნივთიერებებისა და ნაკეთობების რაოდენობა გამრავლებული „20“-ზე; - მე-2 სატრანსპორტო კატეგორიაში შემავალი ნივთიერებებისა და ნაკეთობების რაოდენობა გამრავლებული „3“-ზე; და - მე-3 სატრანსპორტო კატეგორიაში შემავალი ნივთიერებებისა და ნაკეთობების რაოდენობა; არ უნდა გადააჭარბოს „1 000“-ს. 1.1.3.6.5 წინამდებარე ქვეპუნქტის მიზნებიდან გამომდინარე, მხედველობაში არ მიიღება ის სახიფათო ტვირთები, რომლებიც გათავისუფლებულია 1.1.3.1(ა), (ბ) და (დ)-(ვ), 1.1.3.21.1.3.5, 1.1.3.7, 1.1.3.9 და 1.1.3.10 პუნქტების შესაბამისად. 1.1.3.7 ელექტროენერგიის აკუმულირებისა დაკავშირებული გამონაკლისები და წარმოების სისტემების გადაზიდვასთან ADR-ში გათვალისწინებული დებულებები არ გამოიყენება ელექტროენერგიის აკუმულირებისა და წარმოების სისტემების გადაზიდვასთან დაკავშირებით (მაგალითად, ლითიუმის ბატარეები, ელექტრო კონდენსატორები, ასიმეტრიული კონდენსატორები, ლითონის ჰიდრიდის შესანახი სისტემები და საწვავი ელემენტები): (ა) რომლებიც დამონტაჟებულია ავტოსატრანსპორტო საშუალებაში, ასრულებს სატრანსპორტო ოპერაციებს და გათვალისწინებულია მისი წევისა თუ მისი ნებისმიერი მოწყობილობის ფუნქციონირების უზრუნველსაყოფად; 13 (ბ) რომლებიც წარმოდგენილია აღნიშნული მოწყობილობის ფუნქციონირების უზრუნველყოფის მოწყობილობაში, რომელიც გამოიყენება ან გათვალისწინებულია გამოსაყენებლად გადაზიდვების დროს (მაგალითად, ლეპტოპი). 1.1.3.8 (რეზერვირებულია) 1.1.3.9. გადაზიდვების დროს მაცივებელი ან კონდიცირების საშუალების სახით გამოყენებულ სახიფათო ტვირთთან დაკავშირებული გამონაკლისები სატრანსპორტო საშუალებებში ან კონტეინერებში გაცივების ან კონდიცირების მიზნით გამოყენებისას, სახიფათო ტვირთი, რომელსაც გააჩნია მხოლოდ მხუთავი თვისებები (მათ შორის ტვირთი, რომელიც ახდენს განზავებას ან ცვლის ჩვეულებრივ ატმოსფეროში შემავალ ჟანგბადს), ექვემდებარება მხოლოდ 5.5.3 პუნქტის მოქმედებას. 1.1.3.10 სახიფათო ტვირთის გამონაკლისები შემცველი ნათურების გადაზიდვასთან დაკავშირებული ADR-ში გათვალისწინებული დებულებები არ გამოიყენება შემდეგი ნათურების მიმართ მხოლოდ იმ შემთხვევაში, თუ ისინი არ შეიცავს რადიოაქტიურ ნივთიერებებს და ვერცხლისწყალს 3.3 თავის 366-ე სპეციალური დებულებით გათვალისწინებულ ოდენობაზე მეტი რაოდენობით: (ა) ნათურები, რომელთა შეგროვებაც ხდება უშუალოდ კერძო პირებისგან თუ საყოფაცხოვრებო მეურნეობიდან, მათი შეგროვების ან უტილიზაციის პუნქტში გადაზიდვისას; შენიშვნა: აღნიშნული ასევე მოქმედებს იმ ნათურებთან დაკავშირებით, რომელთა მოწოდებასაც უზრუნველყოფენ კერძო პირები შეგროვების პირველად პუნქტში, და შემდგომ ამისა, რომელთა გადაზიდვაც ხორციელდება სხვა შეგროვების, შუალედური დამუშავების ან უტილიზაციის პუნქტებში. (ბ) ნათურები, რომლებიც შეიცავს 1 გრამზე მეტ სახიფათო ტვირთს და შეფუთულია იმ სახით, რომ ყოველ შეფუთვაში არ იყოს წარმოდგენილი 30 გრამზე მეტი სახიფათო ტვირთი იმ პირობით, თუ: (i) ნათურები დამზადებულია ხარისხის მართვის სერტიფიცირებული სისტემის შესაბამისად; შენიშვნა: აღნიშნული მიზნისთვის სტანდარტი ISO 9001:2008. შესაძლებელია გამოყენებულ იქნეს და (ii) (გ) ყოველი ნათურა, იმის მიუხედავად იქნება თუ არა შეფუთული შიდა ტარაში, ერთმანეთისგან გამოყოფილი ტიხრებით, ან წარმოდგენილი სადებ მასალაში ნათურების დაცვის მიზნით და განთავსებული მყარ გარე ტარაში, რომელიც აკმაყოფილებს 4.1.1.1 პუნქტით გათვალისწინებულ ზოგად დებულებებს და ასევე შეუძლია გაიაროს 1,2 მეტრის სიმაღლიდან ჩამოვარდნის გამოცდა; გამოყენებული, დაზიანებული ან წუნდებული ნათურები, რომლებიც შეიცავს არაუმეტეს 1 გრამ სახიფათო ტვირთს, ყოველ შეფუთვაში არაუმეტეს 30 გრამ სახიფათო ტვირთის შემცველობასთან ერთად, როდესაც მათი გადაზიდვა ხდება შეგროვების ან უტილიზაციის პუნქტიდან. ნათურები უნდა შეიფუთოს საკმარისად გამძლე გარე ტარაში, რათა თავიდან იქნეს აცილებული გადაზიდვის ნორმალურ 14 პირობებში შიგთავსის გამოთავისუფლება, უნდა აკმაყოფილებდეს 4.1.1.1 პუნქტით გათვალისწინებულ ზოგად დებულებებს და გაიაროს არანაკლებ 1,2 მეტრის სიმაღლიდან ჩამოვარდნის გამოცდა; (დ) ნათურები, რომლებიც შეიცავს მხოლოდ A და O ჯგუფის აირებს (2.2.2.1 ქვეპუნქტის თანახმად) იმ პირობით, თუ მათი შეფუთვა მოხდება ისე, რომ ნათურის წყვეტის შედეგად გამოწვეული ფეთქებადი ეფექტი შეკავებული იქნეს შეფუთვის ფარგლებში. შენიშვნა: რადიოაქტიური 2.2.7.2.2.2(ბ) პუნქტში. მასალის შემცველი ნათურები წარმოდგენილია 1.1.4 სხვა დებულებების გამოყენებადობა 1.1.4.1 (რეზერვირებულია) 1.1.4.2 გადაზიდვა სატრანსპორტო ჯაჭვში საზღვაო თუ საჰაერო გადაზიდვების ჩათვლით 1.1.4.2.1 შეფუთვები, კონტეინერები, გადასატანი ცისტერნები და კონტეინერ-ცისტერნები, რომლებიც სრულად ვერ აკმაყოფილებს ADR-ის მოთხოვნებს შეფუთვასთან, კომბინირებულ შეფუთვასთან, მარკირებასთან, შეფუთვებზე უსაფრთხოების ნიშნების ან საინფორმაციო ფირფიტებისა და ნარინჯისფერი ტაბლოების განთავსებასთან დაკავშირებით, თუმცა შეესაბამება სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსით ან ICAO-ს ტექნიკური ინსტრუქციებით გათვალისწინებულ მოთხოვნებს, დაიშვება გადაზიდვებზე სატრანსპორტო ჯაჭვში, საზღვაო თუ საჰაერო გადაზიდვების ჩათვლით, შემდეგი პირობების დაცვით: (ა) იმ შემთხვევაში, თუ შეფუთვები არ არის მარკირებული და აღჭურვილი უსაფრთხოების ნიშნებით ADR-ს შესაბამისად, უნდა განხორციელდეს მათი მარკირება და უსაფრთხოების ნიშნებით აღჭურვა სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსითა თუ ICAO-ს ტექნიკური ინსტრუქციებით გათვალისწინებული მოთხოვნების შესაბამისად; (ბ) სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსითა თუ ICAO-ს ტექნიკური ინსტრუქციებით გათვალისწინებული მოთხოვნები გამოიყენება ერთობლივ შეკვრაში წარმოდგენილი ყოველი შეფუთვის მიმართ; (გ) იმ შემთხვევაში, თუ სატრანსპორტო ჯაჭვში გადაზიდვების შემთხვევაში, საზღვაო გადაზიდვების ჩათვლით, კონტეინერები, გადასატანი ცისტერნები, კონტეინერცისტერნები თუ მრავალელემენტიანი აირის კონტეინერები არ არის მარკირებული ან აღჭურვილი საინფორმაციო ტაბლოთი წინამდებარე დანართის 5.3 თავის შესაბამისად, მათი მარკირება და საინფორმაციო ტაბლოთი აღჭურვა უნდა მოხდეს სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსის 5.3 თავის შესაბამისად. მოცემულ შემთხვევაში მოქმედებს მხოლოდ წინამდებარე დანართის 5.3.2.1.1 ქვეპუნქტი ავტოსატრანსპორტო საშუალების მარკირების შესახებ. ცარიელი, გაუსუფთავებელი გადამზიდი ცისტერნების, კონტეინერ-ცისტერნების და მრავალელემენტიანი აირის კონტეინერების შემთხვევაში, აღნიშნული მოთხოვნა ასევე ვრცელდება საწმენდ სადგურში მის შემდგომ მიწოდებაზე. 15 აღნიშნული გამონაკლისი არ მოქმედებს იმ ტვირთებთან დაკავშირებით, რომლებიც კლასიფიცირებულია სახიფათო ტვირთების სახით ADR-ს 1-დან მე-9 კლასებში და განიხილება როგორც არასახიფათო ტვირთი სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსითა თუ ICAO-ს ტექნიკური ინსტრუქციებით გათვალისწინებული მოთხოვნების შესაბამისად. 1.1.4.2.2 ერთი ან რამდენიმე ავტოსატრანსპორტო საშუალებისგან შემდგარი სატრანსპორტო ერთეულები, იმ სატრანსპორტო ერთეულების გარდა, რომლებიც უზრუნველყოფს კონტეინერების, გადამზიდი ცისტერნებისა თუ კონტეინერ-ცისტერნების გადაზიდვას 1.1.4.2.1(გ) ქვეპუნქტში გათვალისწინებული პირობების შესაბამისად, რომლებზეც არ არის განთავსებული საინფორმაციო ტაბლო ADR-ს 5.3.1 დებულების თანახმად, თუმცა მარკირებულია და აღჭურვილია საინფორმაციო ტაბლოთი სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსის 5.3 თავის შესაბამისად, დაიშვება სატრანსპორტო ჯაჭვში გადაზიდვებზე, საზღვაო გადაზიდვების ჩათვლით იმ პირობით, თუ შესრულდება ADR-ის 5.3.2 დებულება ნარინჯისფერ ტაბლოთი მარკირების შესახებ. 1.1.4.2.3 სატრანსპორტო ჯაჭვში გადაზიდვების შემთხვევაში, საზღვაო და საჰაერო გადაზიდვების ჩათვლით, 5.4.1 და 5.4.2 პუნქტებით, ასევე 3.3 თავის ნებისმიერი სპეციალური დებულების თანახმად მოთხოვნილი ინფორმაცია შესაძლებელია შეიცვალოს სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსითა თუ ICAO-ს ტექნიკური ინსტრუქციებით მოთხოვნილი სატრანსპორტო დოკუმენტაციითა და ინფორმაციით, შესაბამისად, იმ პირობით, რომ მოხდება ADR-ს მიერ მოთხოვნილი ნებისმიერი დამატებითი ინფორმაციის გათვალისწინება. შენიშვნა: 1.1.4.2.1 ქვეპუნქტის თანახმად განხორციელებულ გადაზიდვებთან დაკავშირებით, იხილეთ ასევე 5.4.1.1.7 ქვეპუნქტი; კონტეინერებში გადაზიდვებთან დაკავშირებით, იხილეთ აგრეთვე 5.4.2 პუნქტი. 1.1.4.3 საზღვაო გადაზიდვებზე დაშვებული საერთაშორისო საზღვაო ორგანიზაციის (სსო) ტიპის გადამზიდი ცისტერნების გამოყენება საერთაშორისო საზღვაო ორგანიზაციის ტიპის გადამზიდი ცისტერნები (1, 2, 5 და 7 ტიპები), რომლებიც ვერ აკმაყოფილებს 6.7 ან 6.8 თავით გათვალისწინებულ მოთხოვნებს, მაგრამ მომზადდა და დამტკიცდა 2003 წლის 1 იანვარს სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსის (29-98 შესწორება) დებულებების შესაბამისად, შესაძლებელია გამოყენებულ იქნეს იმ პირობით, თუ ისინი აკმაყოფილებს სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსის 1 დებულებებს შემოწმებასა და გამოცდასთან დაკავშირებით. გარდა ამისა, ისინი უნდა აკმაყოფილებდეს ADR-ს 3.2 თავის (10) და (11) სვეტებით გათვალისწინებულ ინსტრუქციების შესაბამის დებულებებსა და 4.2 თავით გათვალისწინებულ დებულებებს. აგრეთვე იხილეთ სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსის 4.2.0.1 პუნქტი. 1.1.4.4 (რეზერვირებულია) 1 საერთაშორისო საზღვაო ორგანიზაციამ (სსო) გამოსცა „არსებული საერთაშორისო საზღვაო ორგანიზაციის ტიპის გადამზიდი ცისტერნებისა და საზღვაო ავტოცისტენების უწყვეტ გამოყენებასთან დაკავშირებული მითითებები სახიფათო ტვირთების ტრანსპორტირების მიზნით“, როგორც ცირკულარი DSC.1/Circ.12 და შესწორებები. აღნიშნული მითითებების ტექსტის ხილვა შესაძლებელია სსო-ს ვებ-გვერდზე: www.imo.org. 16 1.1.4.5 სხვა გადაზიდვები, გარდა საგზაო გადაზიდვებისა 1.1.4.5.1 იმ შემთხვევაში, თუ ავტოსატრანსპორტო საშუალება, რომელიც ახორციელებს სატრანსპორტო ოპერაციას და რომელიც ექვემდებარება ADR-ს მოთხოვნებს, გადაადგილდება გზის გარკვეულ მონაკვეთზე არა საავტომობილო წევის ხარჯზე, მაშინ აღნიშნულ გზის მონაკვეთზე მოქმედებს ნებისმიერი ეროვნული თუ საერთაშორისო წესები, რომლებიც არეგულირებს სახიფათო ტვირთების გადაზიდვას იმ ტრანსპორტის სახით, რომელიც გამოიყენება საგზაო ავტოსატრანსპორტო საშუალებების გადაადგილებისთვის გზის მხოლოდ აღნიშნულ მონაკვეთზე. 1.1.4.5.2 ზემოაღნიშნულ 1.1.4.5.1 ქვეპუნქტში გათვალისწინებულ შემთხვევებში, ADR-ის დაინტერესებული ხელშემკვრელი მხარეები შესაძლებელია შეთანხმდნენ ADR-ის მოთხოვნების გამოყენებასთან დაკავშირებით გზის იმ მონაკვეთზე, სადაც მიმდინარეობს ავტოსატრანსპორტო საშუალების გადაადგილება არა საავტომობილო წევის ხარჯზე, ასევე, იმ შემთხვევაში თუ ჩათვლიან მიზანშეწონილად, დამატებითი მოთხოვნებით, თუ ADR-ის დაინტერესებულ ხელშემკვრელ მხარეებს შორის გაფორმებულ შეთანხმებებს არ დაუპირისპირდება საერთაშორისო კონვენციების ის პუნქტები, რომლებიც არეგულირებს სახიფათო ტვირთების გადაზიდვებს იმ სახის ტრანსპორტით, რომელიც გამოიყენება საგზაო ავტოსატრანსპორტო საშუალების გადაადგილებისთვის გზის მოცემულ მონაკვეთზე, მაგალითად, საერთაშორისო კონვენცია ზღვაზე ადამიანთა სიცოცხლის დაცვის შესახებ, რომლის ხელშემკვრელ მხარეებსაც ასევე წარმოადგენს ADR-ის აღნიშნული ხელშემკვრელი მხარეები. აღნიშნული შეთანხმებების შესახებ შეტყობინებას გასცემს ის ხელშემკვრელი მხარე, რომელმაც გამოიჩინა მათი გაფორმების ინიციატივა გაერთიანებული ერების ორაგნიზაციის ევროპული ეკონომიკური კომისიის სამდივნოს მიმართ, რომელიც, თავის მხრივ, წარუდგენს მას ყველა ხელშემკვრელ მხარეს. 1.1.4.5.3 იმ შემთხვევაში, თუ ADR-ის დებულებებს დაქვემდებარებული სატრანსპორტო ოპერაციის როგორც მთლიან მარშრუტზე, ასევე მის ნაწილზე ვრცელდება მოცემული სახის ტრანსპორტით, გარდა საგზაო საავტომობილო ტრანსპორტისა, სახიფათო ტვირთების გადაზიდვების მარეგულირებელი საერთაშორისო კონვენციის დებულებები, რომლებიც ასევე ვრცელდება გარკვეულ საგზაო მომსახურებაზე, მაშინ აღნიშნული საერთაშორისო კონვენციის დებულებები გამოიყენება მოცემულ მარშრუტთან დაკავშირებით ADR-ის იმ დებულებების პარალელურად, რომლებიც არ ეწინააღმდეგება მათ; აღნიშნულ მარშრუტთან დაკავშირებით არ გამოიყენება ADR-ის სხვა დებულებები. 1.1.5 სტანდარტების გამოყენება იმ შემთხვევაში, თუ აუცილებელია რომელიმე სტანდარტის გამოყენება და აღნიშნულ სტანდარტსა და ADR-ით გათვალისწინებულ დებულებებს შორის ადგილი აქვს რაიმე შეუსაბამობას, უპირატესობა მიენიჭება ADR-ით გათვალისწინებულ დებულებებს. მოცემული სტანდარტის მოთხოვნები, რომელიც არ ეწინააღმდეგება ADR-ს, გამოიყენება მითითებული წესით, ნებისმიერი სხვა სტანდარტის ან იმ სტანდარტის ნაწილის მოთხოვნების ჩათვლით, რომელთან დაკავშირებითაც გაკეთდა ნორმატიული მითითება აღნიშნულ სტანდარტში. 17 18 თავი 1.2 განმარტებები და საზომი ერთეულები 1.2.1 განმარტებები შენიშვნა: წინამდებარე პუნქტი მოიცავს ყველა ზოგად და სპეციალურ განმარტებას. ADR-ის მიზნებიდან გამომდინარე: ა „ADN“ ნიშნავს ევროპის შეთანხმებას სახიფათო ტვირთების საერთაშორისო შიდა საზღვაო გზებით გადაზიდვების შესახებ; „ადვილაალებადი კომპონენტი“ აეროზოლებისთვის, ნიშნავს ადვილაალებად სითხეებს, ადვილაალებად მყარ ნივთიერებებს ან ადვილაალებად აირებსა თუ აირების ნარევებს, როგორც ეს განსაზღვრულია ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 31.1.3 ქვეპუნქტების 1-3 შენიშვნებით. აღნიშნული დასახელება არ ვრცელდება პიროფორულ, ავტომატურად გამათბობელ ან წყალთან რეაგირებად ნივთიერებებზე. წვის ქიმიური სითბო განისაზღვრება ერთ-ერთი შემდეგი მეთოდით: ASTM D 240, ISO/FDIS 13943:1999 (E/F) 86.1-86.3 ან NFPA 30B; „აეროზოლი ან აეროზოლური გამფრქვევი“ ნიშნავს ნებისმიერი სახის არა-მრავალჯერადი გამოყენების ჭურჭელს, რომელიც აკმაყოფილებს 6.2.6 პუნქტის მოთხოვნებს, დამზადებულია ლითონის, მინისა თუ პლასტმასის მასალისგან და შეიცავს შეკუმშულ, გათხევადებულ ან წნევის ქვეშ გახსნილ აირს, სითხესთან, პასტასა თუ ფხვნილთან ერთად ან მათ გარეშე და აღჭურვილია გამოსაფრქვევი მოწყობილობით, რომელიც იძლევა შიგთავსის მყარი ან თხევადი ნაწილაკების სახით გამოფრქვევის საშუალებას სუსპენზიაში, აირში ქაფის, პასტისა თუ ფხვნილის სახით, როგორც თხევად, ასევე აიროვან მდგომარეობაში; „ავარიული ტარა“ ნიშნავს სპეციალურ ტარას, რომელშიც განთავსებულია დაზიანებული, წუნდებული ან მჟონავი სახიფათო ტვირთების შეფუთვები, ან დაღვრილი ან გაჟონილი სახიფათო ტვირთები გადაზიდვებისთვის აღდგენის ან გაუქმების მიზნით; „ავარიული ტემპერატურა“ ნიშნავს ტემპერატურას, რომელზეც განხორციელდება გადაუდებელი ღონისძიებები ტემპერატურის მართვის შესაძლებლობის დაკარგვის შემთხვევაში; „ავარიული წნევის ჭურჭელი“ ნიშნავს არაუმეტეს 1 000 ლიტრის ტევადობის მქონე წნევის ჭურჭელს, რომელიც თავსდება დაზიანებულ წუნდებულ, მჟონავ ან არასათანადო წნევის ჭურჭელში (ჭურჭლებში) გადაზიდვისას, მაგალითად, აღდგენის ან გაუვნებელყოფის მიზნით; „ავტოსატრანსპორტო საშუალება“, იხილეთ „ავტოსატრანსპორტო საშუალება-ბატარეა“, „დახურული ავტოსატრანსპორტო საშუალება“, „ღია ავტოსატრანსპორტო საშუალება“, „ბრეზენტით გადახურული ავტოსატრანპორტო საშუალება“ და „ავტოცისტერნა“; „ავტოსატრანსპორტო საშუალება - ბატარეა“ ნიშნავს იმ ელემენტებით დაკომპლექტებულ ავტოსატრანსპორტო საშუალებას, რომლებიც ერთმანეთს უკავშირდება კოლექტორით და სტაციონარულად მაგრდება აღნიშნულ სატრანსპორტო საშუალებაზე. ავტოსატრანსპორტო საშუალება-ბატარეის ელემენტებად ითვლება შემდეგი ელემენტები: ბალონები, ცილინდრები, ბალონების შეკვრა (რომლებიც ასევე ცნობილია ჩარჩოს 19 სახელით), წნევის დოლურები, ასევე აირების გადაზიდვისთვის გათვალისწინებული ცისტერნები, როგორც ეს გათვალისწინებულია 2.2.2.1.1 ქვეპუნქტით, 450 ლიტრზე მეტი ტევადობით; „ავტოსატრანსპორტო საშუალების ეკიპაჟის წევრი“ ნიშნავს მძღოლს ან მძღოლის თანმხლებ ნებისმიერ სხვა პირს საექსპლუატაციო უსაფრთხოების, უსაფრთხოების, მომზადებისა თუ ექსპლუატაციის უზრუნველყოფის მიზნით; საერთო „ავტოცისტერნა“ ნიშნავს ავტოსატრანსპორტო საშუალებას, რომელიც გათვალისწინებულია სითხეების, აირების, ფხვიერი ან გრანულირებული ნივთიერებების გადასაზიდად და შედგება ერთი ან რამდენიმე დამონტაჟებული ცისტერნისგან. საკუთარი ავტოსატრანსპორტო საშუალებისა თუ სავალი მექანიზმების ნაწილების გარდა, ავტოცისტერნა მოიცავს ერთ ან რამდენიმე კორპუსს, მათი აღჭურვილობის ელემენტებსა და ავტოსატრანსპორტო საშუალებებსა თუ სავალი მექანიზმების ნაწილებზე მათ დასამაგრებელ აღჭურვილობას; „აირი“ ნიშნავს ნივთიერებას, რომელსაც: (ა) 500C ტემპერატურაზე აღენიშნება 300 კპა-ზე (3 ბარზე) მეტი ორთქლის წნევა; ან (ბ) წარმოადგენს სრულად აიროვანს 200C ტემპერატურაზე და 101.3 კპა სტანდარტულ წნევაზე. „აირის ბალონი“, იხილეთ „აირის შემცველი მცირე მოცულობის რეზერვუარი“; „აირის (აირის ბალონების) შემცველი მცირე მოცულობის ჭურჭელი“ ნიშნავს ერთჯერადი გამოყენების ჭურჭელს, რომლის მოცულობა წყალში არ აღემატება 1 000 მლ-ს ლითონისგან დამზადებული ჭურჭლის შემთხვევაში და 500 მლ-ს - სინთეტიკური მასალისგან ან მინისგან დამზადებული ჭურჭლის შემთხვევაში და წნევის ქვეშ შეიცავს აირს ან აირების ნარევს. იგი შეიძლება აღჭურვილი იყოს სარქველით; „არადრეკადი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების რეგულარული ტექნიკური უზრუნველყოფა“ ნიშნავს ლითონის, არადრეკადი პლასტმასისა თუ რთული მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებზე ისეთი ოპერაციების რეგულარულ შესრულებას, როგორიცაა: (ა) წმენდა; (ბ) კორპუსის ჩამკეტების (მათ შორის შესაბამისი შუასადებების) ან სერვისული მოწყობილობების მოხსნა და ხელახლა დაყენება ან შეცვლა, მწარმოებლის საწყისი ტექნიკური მოთხოვნების შესაბამისად მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების ჰერმეტულობის შემოწმების პირობით; ან (გ) იმ კონსტრუქციული მოწყობილობის აღდგენა, რომელიც უშუალოდ არ ასრულებს სახიფათო ტვირთების შემცველობის ან დაჭირხვნის წნევის შეკავების ფუნქციას, რათა უზრუნველყოს შესაბამისობა კონსტრუქციის ტიპთან (მაგალითად, დგარების ან ამწე მოწყობილობების გასწორება) იმ პირობით, რომ არ განხორციელდეს რაიმე გავლენა მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერის მიერ პროდუქტის შემცველობის ფუნქციაზე; „აფეთქების ტემპერატურა“ ნიშნავს სითხის ყველაზე დაბალ ტემპერატურას, რომელზეც მისი ორთქლი წარმოქმნის ადვილაალებად ნარევს ჰაერთან; 20 „ASTM“ ნიშნავს ამერიკულ საზოგადოებას ტესტირებებსა და მასალებთან დაკავშირებით (ASTM International, ამერიკის შეერთებული შტატები,19428-2959, პენსილვანია, დასავლეთ კონსჰოოკენი, საფოსტო ყუთი C700, ბარ ჰარბორ დრაივი 100); „აღდგენილი ტარა“ კონკრეტულად ნიშნავს: (ა) ლითონის დოლურებს, რომლებიც: (i) იწმინდება მათ საწყის საკონსტრუქციო მასალამდე, ისე რომ მოშორებულ იქნეს ყოველგვარი მანამდე არსებული შიგთავსი, შიდა და გარეგანი კოროზია, გარე საფარი და ნიშნები; (ii) აღდგება საწყის ფორმასა და პროფილამდე, რისთვისაც უნდა მოხდეს ნაწიბურების (ასეთის არსებობის შემთხვევაში) გასწორება და შემჭიდროვება და ყველა სახსნელი შუასადების შეცვლა; და (iii) მოწმდება გაწმენდის შემდეგ, მაგრამ შეღებვის წინ, რის შემდეგაც მოხდება იმ ტარის წუნდება, რომელსაც აღენიშნება ხილული, წერტილოვანი კოროზია, მასალების სისქის საყურადღებოდ შემცირება, ლითონის დაღლილობა, დაზიანებული კუთხვილები თუ საკეტები ან სხვა საყურადღებო დეფექტები; (ბ) პლასტმასის დოლურებს და კანისტრებს, რომლებიც: (i) იწმინდება მათ საწყის საკონსტრუქციო მასალამდე, ისე რომ მოშორებულ იქნეს ყოველგვარი ადრე არსებული შიგთავსი, გარე საფარი და ნიშნები; (ii) შეეცვლება ყველა სახსნელი შუასადები; და (iii) მოწმდება გაწმენდის შემდეგ, რის შემდეგაც მოხდება იმ ტარის წუნდება, რომელსაც აღენიშნება ხილული დაზიანებები, როგორიცაა წყვეტები, ნაკეცები თუ ბზარები, დაზიანებული კუთხვილები თუ საკეტები ან სხვა საყურადღებო დეფექტები; ბ „ბალონების შეკვრა“ ნიშნავს ბალონების კომპლექტს, რომლებიც დამაგრებულია ერთად, დაკავშირებულია ერთმანეთთან კოლექტორის საშუალებით და რომლის გადაზიდვაც ხდება ერთი მთლიანობის სახით. წყლის შემთხვევაში შეკვრის სრული მოცულობა არ უნდა აღემატებოდეს 3 000 ლიტრს მაშინ, როდესაც მე-2 კლასში შემავალი ტოქსიკური აირების გადასაზიდად განკუთვნილი შეკვრები (ის ჯგუფები, რომლებიც იწყება T ასოთი 2.2.2.1.3 ქვეპუნქტის შესაბამისად) შემოიფარგლება 1 000 ლიტრი წყლის მოცულობით; „ბალონი“ ნიშნავს არაუმეტეს 150 ლიტრის წყლის მოცულობის გადამზიდ წნევის ჭურჭელს (იხილეთ აგრეთვე „ბალონების შეკვრა“); „ბოჭკოვანი მუყაოსგან დამზადებული მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“ ნიშნავს ბოჭკოვანი მუყაოსგან დამზადებულ კორპუსს, რომელზეც წარმოადგენილია ან არ არის წარმოდგენილი ზედა და ქვედა ხუფები, საჭიროების შემთხვევაში, შიდა შუასადები (თუმცა არა შიდა ტარა) და შესაბამისი სერვისული და კონსტრუქციული აღჭურვილობა; „ბრეზენტით გადახურული ავტოსატრანსპორტო საშუალება“ ნიშნავს ჩატვირთული ტვირთის დაცვის მიზნით ბრეზენტით გადახურულ ავტოსატრანსპორტო საშუალებას; 21 „ბრეზენტით გადახურული კონტეინერი“, იხილეთ „კონტეინერი“; „ბრეზენტით გადახურული მასიური ტვირთის კონტეინერი“, იხილეთ „მასიური ტვირთის კონტეინერი“; გ „გადაზიდვა“ ნიშნავს სახიფათო ტვირთების ადგილ-მდებარეობის შეცვლას, ტრანსპორტირების პირობების შესაბამისად მოთხოვნილი აუცილებელი გაჩერებების ჩათვლით და სახიფათო ტვირთის მიერ ავტოსატრანსპორტო საშუალებებში, ცისტერნებსა და კონტეინერებში გატარებულ ნებისმიერ პერიოდს, რის აუცილებლობაც განპირობებულია გადაზიდვის პირობებით ადგილ-მდებარეობის შეცვლამდე, შეცვლის დროსა და მის შემდეგ. აღნიშნული განმარტება ითვალისწინებს სახიფათო ტვირთების შუალედურ, დროებით დასაწყობებას სატრანსპორტო საშუალებების სახეობის ან საშუალებების შეცვლის მიზნით (გადატვირთვა). სატრანსპორტო დოკუმენტები ხელმისაწვდომი უნდა იყოს მოთხოვნისთანავე, სადაც მითითებული იქნება ტვირთის გაგზავნისა და მიღების ადგილი, ასევე ის ფაქტი, რომ შეალუდური დასაწყობების დროს შეფუთვები და ცისტერნები არ გაიხსნება, გარდა კომპეტენტური ორგანოების მიერ განხორციელებული შემოწმებების შემთხვევებისა. „გადაზიდვის საშუალება“, ტვირთების საავტომობილო ან სარკინიგზო გადაზიდვების შემთხვევაში, ნიშნავს ავტოსატრანსპორტო საშუალებას ან ვაგონს; „გადამზიდველი“ ნიშნავს გადაზიდვების ხელშეკრულების საფუძველზე ან მის გარეშე სატრანსპორტო ოპერაციების განმახორციელებელ საწარმოს; „გადამზიდი ცისტერნა“ ნიშნავს 2.2.2.1.1 პუნქტში განსაზღვრულ, 450 ლიტრზე მეტი მოცულობის აირების გადასაზიდად გამოყენებულ კომბინირებულ ცისტერნას, 6.7 თავის ან სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსით გათვალისწინებული განმარტების შესაბამისად, რაც ასევე მითითებულია 3.2 თავის A ცხრილის (10) სვეტში წარმოდგენილ ინსტრუქციებში (T კოდი) გადამზიდი ცისტერნების შესახებ; „გადამზიდი ცისტერნის ოპერატორი“, იხილეთ „კონტეინერ-ცისტერნის/გადამზიდი ცისტერნის ოპერატორი“; „გადმომტვირთი“ ნიშნავს ნებისმიერ საწარმოს, რომელიც: (ა) ხსნის კონტეინერს, მასიური ტვირთის კონტეინერს, მრავალელემენტიანი აირის კონტეინერს, კონტეინერ-ცისტერნასა თუ გადასატან კონტეინერს ავტოსატრანსპორტო საშუალებიდან; ან (ბ) ახდენს შეფუთული სახიფათო ტვირთების, მცირე მოცულობის კონტეინერებისა თუ გადასატანი ცისტერნების გადმოტვირთვას ავტოსატრანსპორტო საშუალებიდან ან კონტეინერიდან; ან (გ) უშვებს სახიფათო ტვირთებს ცისტერნიდან (ავტოცისტერნიდან, სახსნელი ცისტერნიდან, გადასატანი ცისტერნიდან ან კონტეინერ-ცისტერნიდან) ან ავტოსატრანსპორტო საშუალება-ბატარეიდან, ფეთქებადი ნივთიერებების მობილური დანადგარიდან ან მრავალელემენტიანი აირის კონტეინერიდან, ასევე საყარი ტვირთის ან მასიური ტვირთის გადასაზიდად გამოყენებული 22 ავტოსატრანსპორტო საშუალებიდან, მსხვილგაბარიტიანი ან მცირე მოცულობის კონტეინერებიდან; „გაერთიანებული ერების ორგანიზაციის ნომერი“ ნიშნავს გაერთიანებული ერების ორგანიზაციის ტიპიური წესებიდან აღებული ნივთიერებისა თუ ნაკეთობის ოთხციფრიან საიდენტიფიკაციო ნომერს; „გაერთიანებული ერების ორგანიზაციის ტიპიური წესები“ ნიშნავს გაერთიანებული ერების ორგანიზაციის მიერ გამოცემულ სახიფათო ტვირთების გადაზიდვების შესახებ რეკომენდაციების მეთვრამეტე შემოწმებულ გამოცემაზე დართულ ტიპიურ წესებს (ST/SG/AC.10/1/Rev.18); “გაეროს ეეკ“ ნიშნავს გაერთიანებული ერების ორგანიზაციის ევროპულ ეკონომიკურ კომისიას (UNECE, შვეიცარია, ჟენევა GH-1211, მშვიდობის გამზირი 8-14, ერთა სასახლე); „გათხევადებული საწვავი აირი (LPG)“ ნიშნავს დაბალი წნევის მქონე გათხევადებულ აირს, რომელიც შედგება ერთი ან ერთზე მეტი მსუბუქი ნახშირწყალბადისგან, რომელსაც ენიჭება გაეროს №1011, 1075, 1965, 1969 ან 1978 მხოლოდ და რომლის ძირითად კომპონენტს წარმოადგენს პროპანი, პროპილენი, ბუტანი, ბუტანის იზომერი, ბუტილენი რიგი სხვა ნახშირწყალბადის აირების თანხლებით. შენიშვნა 1: ადვილაალებადი აირები, რომელთაც მინიჭებული აქვთ გაეროს სხვა ნომრები, არ ითვლება გახევადებულ საწვავ აირებად. შენიშვნა 2: გაეროს №1075-თან დაკავშირებით იხილეთ შენიშვნა 2 გრაფაში 2F, გაეროს №1965-თან დაკავშირებით - 2.2.2.3 პუნქტში მითითებული გათხევადებული აირების ცხრილი. „გამოსხივების დეტექტირების სისტემა“ ნიშნავს მოწყობილობას, რომლის შემადგენელ ელემენტებსაც წარმოადგენს გამოსხივების დეტექტორები. „გამოსხივების დონე“, რადიოაქტიური მასალების გადაზიდვასთან დაკავშირებით, ნიშნავს შესაბამისი დოზის განაკვეთს, რომელიც გამოისახება მილიზივერტით საათში; „გამოცდა ჰერმეტულობაზე“ ნიშნავს გამოცდას ცისტერნის, ტარისა თუ მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერის, ასევე მოწყობილობებისა და საკეტი დანადგარების ჰერმეტულობის განსაზღვრის მიზნით; შენიშვნა: გადამზიდ ცისტერნებთან დაკავშირებით, იხილეთ 6.7 თავი. „განაწესი ECE“ ნიშნავს თვლიანი ავტოსატრანსპორტო საშუალებებისთვის და იმ მოწყობილობებისა და ნაწილების საგნებისთვის, რომლებიც შესაძლებელია დაყენდეს ან/და გამოყენებულ იქნეს თვლიან სატრანსპორტო საშუალებებზე ერთგვარი ტექნიკური მიწორილობების მიღებისა და ამ მიწერილობების საფუძველზე გაცემული ოფიციალური დამტკიცების ურთიერთაღიარების პირობების შესახებ ხელშეკრულებაზე დართულ წესებს (1958 წლის შეთანხმება, შესწორებებთან ერთად); „განმცხადებელი“, შესაბამისობის შეფასების შემთხვევაში, ნიშნავს მწარმოებელს ან მის უფლებამოსილ წარმომადგენელს იმ ქვეყანაში, რომელიც წარმოადგენს ხელშემკვრელ მხარეს. პერიოდული შემოწმებების, შუალედური შემოწმებებისა და დაუგეგმავი შემოწმებების შემთხვევაში, განმცხადებელი ნიშნავს გამომცდელ ორგანიზაციას, ოპერატორს ან მათ ნებადართულ წარმომადგენელს იმ ქვეყანაში, რომელიც წარმოადგენს ხელშემკვრელ მხარეს; 23 შენიშვნა: გამონაკლის შემთხვევებში, ნებისმიერ მესამე მხარეს (მაგალითად, ოპერატორს 1.2.1 პუნქტით გათვალისწინებული განმარტების შესაბამისად) შეუძლია გააკეთოს მიმართვა შესაბამისობის შეფასებასთან დაკავშირებით. „გარე ტარა“ ნიშნავს შედგენილი ან კომბინირებული ტარის გარეგან დაცვას, ნებისმიერ მააბსორბირებელ ან შუასადებ მასალებსა თუ ნებისმიერ სხვა კომპონენტთან ერთად, რაც აუცილებელია შიდა ჭურჭლისა თუ შიდა ტარის შემცველობისა და დაცვისთვის; „გაყოფადი მასალის შემცველ შეფუთვასთან, სატრანსპორტო პაკეტსა თუ კონტეინერთან დაკავშირებით განსაზღვრული კრიტიკულობის უსაფრთხოების ინდექსი“, მე-7 კლასით გათვალისწინებული მასალების გადაზიდვისას, ნიშნავს რიცხვს, რომელიც გამოიყენება გაყოფადი მასალის შემცველი შეფუთვების, სატრანსპორტო პაკეტებისა თუ კონტეინერების საერთო ოდენობაზე კონტროლის უზრუნველყოფის მიზნით; „გისოსი“ ნიშნავს არასრული ზედაპირის მქონე გარე ტარას; “GHS” ნიშნავს გაერთიანებული ერების ორგანიზაციის მიერ ST/SG/AC.10/30/Rev.3 სახით გამოცემულ შეთანხმებას ქიმიური პროდუქტების საშიშროების კლასიფიცირებისა და მარკირების გლობალურად ჰარმონიზებული სისტემების შესახებ, მესამე გადასინჯულ გამოცემას; დ „დამტკიცება“ „მრავალმხრივი დამტკიცება“, რადიოაქტიური მასალების გადაზიდვის შემთხვევაში, ნიშნავს შესაბამისი კომპეტენტური ორგანოს მიერ კონსტრუირებისა თუ გადაზიდვების განმახორციელებელი ქვეყნის დამტკიცებას, ასევე დამტკიცებას იმ ქვეყნების კომპეტენტური ორგანოს მიერ, რომლის ტერიტორიის გავლითაც და რომელზეც ხორციელდება აღნიშნული გადაზიდვა. „ცალმხრივი დამტკიცება“, რადიოაქტიური მასალების გადაზიდვის შემთხვევაში, ნიშნავს კონსტრუქციის დამტკიცებას, რომელსაც მოითხოვს კომპეტენტური ორგანო მხოლოდ აღნიშნული კონსტრუქციის განხორციელების ქვეყანაში. იმ შემთხვევაში, თუ წარმოშობის ქვეყანა არ წარმოადგენს ADR-ის ხელშემკვრელ მხარეს, აღნიშნული დამტკიცება მოითხოვს დამტკიცებას ტვირთების გადაზიდვის მარშრუტზე ADR-ის პირველი ხელშემკვრელი მხარის კომპეტენტური ორგანოს მიერ (იხილეთ პუნქტი 6.4.22.6); „დადგენილი წნევა“ ნიშნავს წნევის ჭურჭლის შიგთავსის წნევას, რომელიც იმყოფება თერმულ და დიფუზიურ წონასწორობაში; „დამონტაჟებული ცისტერნა“ ნიშნავს 1000 ლიტრზე მეტი მოცულობის ცისტერნას, რომელიც სტაციონარულად არის დამაგრებული ავტოსატრანსპორტო საშუალებაზე (რომელიც მოცემულ შემთხვევაში ხდება ავტოცისტერნა) ან წარმოადგენს აღნიშნული ავტოსატრანსპორტო საშუალების კორპუსის შემადგენელ ნაწილს; „დაცული მტსტკ“ (ლითონის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერთან დაკავშირებით) ნიშნავს მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერს, უზრუნველყოფილს დარტყმისგან დამატებითი დაცვით, მაგალითად, მრავალშრიანი (სენდვიჩის ფორმის) ან ორმაგი კედლის კონსტრუქციის ფორმით ან ლითონის ცხაურის გარსის კორპუსის სახით. 24 „დაჭირხვნის წნევა“ ნიშნავს მაქსიმალურ წნევას, რომელიც ფაქტიურად მიიღწევა ცისტერნაში მაშინ, როდესაც მოხდება მისი დაჭირხვნა წნევის ქვეშ (იხილეთ აგრეთვე „გაანგარიშების წნევა“, „შევსების წნევა“, „მაქსიმალური სამუშაო წნევა (მანომეტრული წნევა)“ და „საცდელი წნევა“); „დახურული კონტეინერი“, იხილეთ „კონტეინერი“; „დახურული ავტოსატრანსპორტო საშუალება“, ნიშნავს ავტოსატრანსპორტო საშუალებას, დახურვის შესაძლებლობის მქონე ძარით; „დიდი მოცულობის კონტეინერი“, იხილეთ „კონტეინერი“; „დირექტივა EC“ ნიშნავს ევროპული საზოგადოების კომპეტენტური ორგანოების მიერ დადგენილ დებულებებს, რომელსაც გააჩნია სავალდებულო ძალა, მისაღწევი მიზნის თვალსაზრისით, ყოველი წევრი სახელმწიფოსთვის, რომლის მიმართაც იგი გამოიყენება, თუმცა ეროვნულ ორგანოებს უტოვებს ფორმისა და მეთოდის არჩევის თავისუფალ უფლებას; „დოლურა“ ნიშნავს ლითონისგან, ბოჭკოვანი მუყაოსგან, პლასტმასისგან, ფანერისგან ან სხვა შესაბამისი მასალისგან დამზადებულ ცილინდრული ფორმის ტარას ბრტყელი ან ამოზნექილი ძირით. აღნიშნული განმარტება ასევე ვრცელდება სხვა ფორმის, მაგალითად, მრგვალ, კონუსისებრ ტარასა თუ ვედროს ფორმის ტარაზე. აღნიშნული განმარტება არ ითვალისწინებს ხის კასრებს და კანისტრებს; „დრეკადი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“ ნიშნავს კორპუსს, რომელიც დამზადებულია ფირისგან, ქსოვილის მასალისგან ან ნებისმიერი სხვა დრეკადი მასალისა თუ მათი კომბინაციისგან, რომელიც, აუცილებლობის შემთხვევაში, უზრუნველყოფს შიდა საფარს ან ჩანართს, ნებისმიერ შესაბამის სერვისულ მოწყობილობასა და დამამუშავებელ საშუალებებთან ერთად; “დრეკადი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების რეგულარული ტექნიკური ტესტირება” ნიშნავს პლასტმასის ან ტექსტილის მასიური ტვირთის საშუალო ტვირთამწეობის როგორიცაა: კონტეინერებზე ისეთი ოპერაციების რეგულარულ შესრულებას, (ა) გასუფთავება; ან (ბ) სახსნელი კომპონენტების, როგორიცაა სახსნელი შუასადებები და ჩამკეტი არმატურა, შეცვლა იმ კომპონენტებით, რომლებიც შეესაბამება მწარმოებლის საწყის ტექნიკურ მოთხოვნებს; იმ პირობით, რომ აღნიშნული ოპერაციები არ მოახდენს უარყოფით გავლენას დრეკადი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების პროდუქტის შემცველობის ფუნქციაზე ან შეცვლის მისი კონსტრუქციის ტიპს. „დრეკადი მტსტკ-ის რეგულარული ტექნიკური უზრუნველყოფა“, იხილეთ „მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“; ე „ერთობლივი პოზიცია“ ნიშნავს პოზიციას ნივთიერებებისა თუ ნაკეთობების კარგად განსაზღვრულ ჯგუფისთვის (იხილეთ 2.1.1.2 პუნქტის ბ, გ და დ ქვეპუნქტები); 25 „ექსკლუზიური გამოყენება“, რადიოაქტიური მასალების გადაზიდვის შემთხვევაში, ნიშნავს მხოლოდ ერთი ტვირთგამგზავნის მიერ ავტოსატრანსპორტო საშუალებისა თუ დიდი მოცულობის კონტეინერის ერთპიროვნულ გამოყენებას, რომელთან დაკავშირებითაც ყოველგვარი საწყისი, შუალედური და საბოლოო ჩატვირთვაგადმოტვირთვის ოპერაციები ხორციელდება ტვირთგამგზავნისა თუ ტვირთმიმღების მითითებების შესაბამისად, როდესაც აღნიშნული მოთხოვნილია ADR-ის ფარგლებში; ვ “ვაკუუმური სარქველი“ ნიშნავს ზამბარიან მოწყობილობას, რომელიც ავტომატურად აქტიურდება წნევის მოქმედებით იმ მიზნით, რომ დაიცვას ცისტერნა დაუშვებელი ნეგატიური შიგა წნევისგან; „ვალდებულება“, იხილეთ „საწარმო“; თ „თადტ“ იხილეთ „თვითაჩქარებული დაშლის ტემპერატურა“; „თვითაჩქარებული დაშლის ტემპერატურა (თადტ)“ ნიშნავს ყველაზე დაბალ ტემპერატურას, რომელზეც შესაძლებელია ადგილი ჰქონდეს გადაზიდვების დროს გამოყენებული ნივთიერებების თვითაჩქარებულ დაშლას ტარაში. თვითაჩქარებული დაშლის ტემპერატურის განმსაზღვრელი დებულებები და თბობის ეფექტები ჩაკეტილ სივრცეში წარმოდგენილია ცდებისა და კრიტერიუმების სახელმძღვანელოს II ნაწილში; „თხელფურცლოვანი ლითონის ტარა“ ნიშნავს მრგვალი, ელიფსის ფორმის, მართკუთხა ან მრავალკუთხა (ასევე კონუსურ) ტარას ჯვარედინი ჭრილებით, ასევე შევიწროვებულ ან ვედროს ფორმის ტარას, რომელიც დამზადებულია ლითონისგან, გააჩნია 0.5 მმ-ზე ნაკლები სისქის კედლები (მაგალითად, ფურცლოვანი თუნუქი), ბრტყელი ან ამოზნექილი ძირი, ერთი ან რამდენიმე ნახვრეტი, რაც არ არის გათვალისწინებული დოლურების ან კანისტრების განმარტებაში; ი “IAEA” ნიშნავს ატომური ენერგიის საერთაშორისო სააგენტოს (IAEA, ვენა, საფოსტო ყუთი 100 – A – 1400); “ICAO” ნიშნავს სამოქალაქო ავიაციის საერთაშორისო ორგანიზაციას (ICAO, კანადა, H3C 5H7, კვებეკი, მონრეალი, უნივერსიტეტის ქუჩა 999); „ICAO-ს ტექნიკური ინსტრუქციები“ ნიშნავს სახიფათო ტვირთების უსაფრთხო საჰარო გადაზიდვების შესახებ ტექნიკურ ინსტრუქციას, რომელიც თან ერთვის მონრეალში სამოქალაქო ავიაციის საერთაშორისო ორგანიზაციის (ICAO) მიერ გამოცემულ საერთაშორისო სამოქალაქო ავიაციის შესახებ ჩიკაგოს კონვენციის მე-18 დანართს (ჩიკაგო, 1944 წელი); კ „კანისტრა“ ნიშნავს მართკუთხა ან მრავალკუთხა ფორმის ჭრილის მქონე ლითონის ან პლასტმასის ტარას, რომელზეც წარმოდგენილია ერთი ან რამდენიმე ნახვრეტი; 26 „კომბინირებული ტარა“ ნიშნავს სატრანსპორტო დანიშნულების ტარის კომბინაციას, რომელიც შედგება გარე ტარაში მოთავსებული ერთი ან რამდენიმე შიდა ტარისგან 4.1.1.5 პუნქტის შესაბამისად; შენიშვნა: „კომბინირებული ტარის“ „შიდა შემადგენელი ნაწილები“ ყოველთვის განისაზღვრება, როგორც „შიდა ტარა“ და არა როგორც შედგენილი ტარისთვის გამოყენებული „შიდა ჭურჭელი“. „კონტეინერი“ ნიშნავს სატრანსპორტო მოწყობილობის საგანს (საწეველას ან სხვა მსგავს კონსტრუქციას): - რომელსაც გააჩნია მდგრადი ხასიათი და შესაბამისად საკმაოდ მძლავრია იმისათვის, რომ უზრუნველყოს მისი მრავალჯერადი გამოყენება; - სპეციალურად არის კონსტრუირებული იმისათვის, რომ ხელი შეუწყოს ტვირთების გადაზიდვას ერთი ან რამდენიმე სახეობის სატრანსპორტო საშუალებით, ტვირთის დაზიანების გარეშე; - აღჭურვილია იმ დანადგარებით, რომლებიც იძლევა მისი აწყობისა და დამუშავების საშუალებას განსაკუთრებით იმ შემთხვევაში, როდესაც ადგილი აქვს მის გადატვირთვას ერთი სატრანსპორტო საშუალებიდან მეორეზე; - დაპროექტებულია იმ სახით, რომ შესაძლებელი იყოს მისი ადვილად შევსება და დაცლა; - გააჩნია არანაკლებ 1 მ3 შიდა მოცულობა, გარდა იმ კონტეინერებისა, რომლებიც გათვალისწინებულია რადიოაქტიური მასალების გადასაზიდად. გარდა ამისა, „მცირე მოცულობის კონტეინერი“ ნიშნავს კონტეინერს, რომელსაც გააჩნია არანაკლებ 1.5 მეტრის გარეგანი გაბარიტები (სიგრძე, სიგანე ან სიმაღლე) ან არაუმეტეს 3მ3 შიდა მოცულობა. „დიდი მოცულობის კონტეინერი“ ნიშნავს: (ა) კონტეინერს, რომელიც ვერ აკმაყოფილებს მცირე მოცულობის კონტეინერთან დაკავშირებით არსებულ განმარტებას; (ბ) უსაფრთხო კონტეინერების შესახებ საერთაშორისო კონვენციის (CSC) მნიშვნელობით, იმ ზომის კონტეინერს, რომლის ოთხ გარე ქვედა კუთხეს შორის არსებული სივრცე შეადგენდეს: (i) მინიმუმ 14მ2 (150 კვადრატულ ფუტს); ან (ii) მინიმუმ 7მ2 (75 კვადრატულ ფუტს) იმ შემთხვევაში, თუ დამაგრებულია ზედა კუთხის მოწყობილობებით. „დახურული კონტეინერი“ ნიშნავს სრულად დახურულ კონტეინერს, რომელსაც გააჩნია მყარი სახურავი, მყარი გვერდითი კედლები, მყარი ტორსული კედლები და იატაკი. აღნიშნული ტერმინი ითვალისწინებს ღია სახურავის მქონე კონტეინერებს, რომლის სახურავიც შესაძლებელია დაიხუროს ტრანსპორტირების დროს; „ღია კონტეინერი“ ნიშნავს ღია ზედა ნაწილის მქონე ან პლატფორმის საყრდენის მქონე კონტეინერს; 27 „ბრეზენტით დახურული კონტეინერი“ ნიშნავს დატვირთული ტვირთის დაცვის მიზნით შესაბამისი საფარით აღჭურვილ კონტეინერს; „სახსნელი ძარა“ ნიშნავს კონტეინერს, რომელსაც EN 283:1991 სტანდარტის შესაბამისად, გააჩნია შემდეგი მახასიათებლები: - მექანიკური სიმძლავრის თვალსაზრისით, ის დამზადებულია სარკინიგზო პლატფორმაზე ან სახმელეთო ავტოსატრანსპორტო საშუალებაზე ან სამიმოსვლო გემებზე ტვირთის გადასაზიდად; - არ ექვემდებარება დაშტაბელებას; - შესაძლებელია მისი მოხსნა ავტოსატრანსპორტო საშუალებებიდან ავტოსატრანსპორტო საშუალებებზე ან მის საკუთარ საყრდენებზე არსებული მოწყობილობების დახმარებით და შესაძლებელია მათი ხელახალი დატვირთვა; შენიშვნა: ტერმინი „კონტეინერი“ არ ითვალისწინებს ჩვეულებრივი ტიპის ტარას, მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებს, კონტეინერ-ცისტერნებსა თუ ავტოსატრანსპორტო საშუალებებს. გარდა ამისა, კონტეინერის გამოყენება შესაძლებელია ტარის სახით რადიოაქტიური მასალების გადაზიდვისას. „კონტეინერ-ცისტერნა“ ნიშნავს სატრანსპორტო აღჭურვილობის საგანს, რომელიც აკმაყოფილებს ტერმინის - „კონტეინერი“ - განმარტებას და შედგება კორპუსისა და აღჭურვილობის ელემენტებისგან იმ აღჭურვილობის ჩათვლით, რომელიც უზრუნველყოფს კონტეინერ-ცისტერნის გადაადგილების შესაძლებლობას მისი მდგომარეობის მნიშვნელოვანი ცვლილების გარეშე, გამოიყენება აირების, სითხის, ფხვიერი თუ გრანულირებული ნივთიერებების გადასაზიდად, ხოლო 2.2.1.1.1.1 ქვეპუნქტში გათვალისწინებული განსაზღვრების მიხედვით აირების გადაზიდვისთვის გამოყენების შემთხვევაში, გააჩნია 0.45მ3 (450 ლიტრზე) მეტი ტევადობა; შენიშვნა: კონტეინერ-ცისტერნებად არ ჩაითვლება ის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები, რომლებიც აკმაყოფილებს 6.5 თავის მოთხოვნებს. „კონტეინერ-ცისტერნის/გადასატანი ცისტერნის ოპერატორი“ ნიშნავს ნებისმიერ საწარმოს, რომლის სახელზეც რეგისტრირებულია კონტეინერ-ცისტერნა/გადასატანი ცისტერნა; „კონსტრუქცია“, რადიოაქტიური მასალების გადაზიდვასთან დაკავშირებით, ნიშნავს სპეციალური ფორმის რადიოაქტიური მასალების, დაბალი დისპერსიის მქონე რადიოაქტიური მასალების, შეფუთვისა თუ ტარის აღწერილობას, რომელიც უზრუნველყოფს აღნიშნული საგნის სრულად იდენტიფიცირების საშუალებას. აღწერილობა შეიძლება მოიცავდეს სპეციფიკაციებს, საინჟინრო-ტექნიკურ ნახაზებს, მარეგულირებელ მოთხოვნებთან შესაბამისობის ამსახველ ანგარიშებსა და სხვა შესაბამის დოკუმენტაციას; „კონსტრუქციული აღჭურვილობა“ (ა) ავტოცისტერნების ან სახსნელი ცისტერნების კორპუსის შემთხვევაში - ნიშნავს კორპუსის გარეგან და შინაგან გამაძლიერებელ, დასამაგრებელ, დამცავ თუ დამასტაბილურებელ ელემენტებს; (ბ) ავტოცისტერნების კორპუსების შემთხვევაში - ნიშნავს კორპუსის გარეგან და შინაგან გამაძლიერებელ, დასამაგრებელ, დამცავ თუ დამასტაბილურებელ ელემენტებს; 28 (გ) ავტოსატრანსპორტო საშუალება-ბატარეებისა თუ მრავალელემენტიანი აირის კონტეინერების ელემენტების შემთხვევაში - კორპუსის ან ჭურჭლის გარეგან და შინაგან გამაძლიერებელ, დასამაგრებელ, დამცავ თუ დამასტაბილურებელ ელემენტებს; (დ) მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების შემთხვევაში, გარდა დრეკადი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებისა - ნიშნავს კორპუსის გამაძლიერებელ, დასამაგრებელ, ტვირთების დამამუშავებელ, დამცავ თუ დამასტაბილურებელ ელემენტებს (პლასტმასის შიდა ჭურჭელთან ერთად მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებისთვის საყრდენი ქვეშების ჩათვლით); შენიშვნა: გადასატან ცისტერნებთან დაკავშირებით, იხილეთ 6.7 თავი. „კორპუსი“ (მტსტკ-ს ყველა კატეგორიისთვის, გარდა შედგენილი მტსტკ-სა) ნიშნავს კონკრეტულად ჭურჭელს, ნახვრეტებისა და ტიხრების ჩათვლით, თუმცა აღნიშნული არ ითვალისწინებს სერვისულ მოწყობილობებს; „კორპუსი“ (ცისტერნებთან დაკავშირებით), ნიშნავს გადაზიდვისთვის განკუთვნილი ნივთიერების შემცველ ცისტერნას, ნახვრეტებისა და მათი საკეტების ჩათვლით, თუმცა არ გულისხმობს სერვისულ აღჭურვილობას ან გარე სტრუქტურულ აღჭურვილობას; შენიშვნა: გადასატან ცისტერნებთან დაკავშირებით, იხილეთ 6.7 თავი. „კორპუსის ან კორპუსის განყოფილების მოცულობა“ ცისტერნებთან დაკავშირებით ნიშნავს კორპუსის ან კორპუსის განყოფილების მთლიან შიდა მოცულობას, გამოსახულს ლიტრებში ან კუბურ მეტრებში. იმ შემთხვევაში, თუ არ არის შესაძლებელი კორპუსი ან კორპუსის განყოფილების სრულად შევსება მისი ფორმისა თუ კონსტრუქციის გამო, ცისტერნების შევსების ხარისხისა და მარკირების განსაზღვრის მიზნით გამოიყენება აღნიშნული შემცირებული ტევადობა; „კოჭა“ (პირველი კლასი) ნიშნავს პლასტმასისგან, ხისგან, ბოჭკოვანი მუყაოსგან, ლითონისა თუ სხვა სათანადო მასალისგან დამზადებულ მოწყობილობას, რომელიც შედგება ცენტრალური ღერძისგან, რომლის ყოველ მხარეს წარმოდგენილია ან არ არის წარმოდგენილი მილტუჩები. ნაკეთობები და ნივთიერებები შეიძლება დახვეულ იქნეს ღერძზე და დამაგრდეს მილტუჩებით; „კრიოგენული ჭურჭელი“ ნიშნავს თერმოიზოლირებული წნევის ჭურჭელს, რომელიც გამოიყენება არაუმეტეს 1 000 ლიტრის წყლის მოცულობის გაცივებული თხევადი აირების გადასატანად (იხილეთ აგრეთვე „ღია კრიოგენული ჭურჭელი“); „კრიტიკული ტემპერატურა“ ნიშნავს ტემპერატურას, რომლის ზემოთ შეუძლებელია ნივთიერების არსებობა თხევად მდგომარეობაში; ლ „ლითონის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“ ნიშნავს ლითონის კორპუსს შესაბამის სერვისულ და კონსტრუქციულ მოწყობილობასთან ერთად; „ლითონის ჰიდრიდის შესანახი სისტემა“ ნიშნავს წყალბადის შესანახ ცალკეულ სრულ სისტემას, რომელიც შედგება ჭურჭლისგან, ლითონის ჰიდრიდისგან, წნევის შემზღუდველისგან, საცობი სარქველისგან, სერვისული მოწყობილობისა და შიდა კომპონენტებისგან და გამოიყენება მხოლოდ წყალბადის გადაზიდვებისთვის; 29 „ლოკალიზაციის სისტემა“, რადიოაქტიური მასალების გადაზიდვასთან დაკავშირებით, ნიშნავს გაყოფადი მასალებისა და შეფუთვის კომპონენტების კრებულს, რომელიც განისაზღვრება დამპროექტებლის მიერ და დასტურდება კომპეტენტური ორგანოს მიერ, კრიტიკული უსაფრთხოების უზრუნველყოფის მიზნით; მ „მართვის სისტემა“, რადიოაქტიური მასალის გადაზიდვის შემთხვევაში, ნიშნავს ურთიერთდაკავშირებული ან ურთიერთმოქმედი ელემენტების ერთობლიობას (სისტემას) სათანადო პოლიტიკისა და მიზნების დასახვისა და აღნიშნული მიზნების ეფექტური და შედეგიანი მიღწევის უზრუნველსაყოფად; „მასიური ტვირთების გადაზიდვა“ ნიშნავს შეუფუთავი, მყარი ნივთიერებებისა თუ ნაკეთობების გადაზიდვას ავტოსატრანსპორტო საშუალებებში, კონტეინერებსა თუ მასიური ტვირთის კონტეინერებში. აღნიშნული ტერმინი არ გამოიყენება ცისტერნებით გადატანილ შეფუთულ საქონელსა თუ ნივთიერებებთან დაკავშირებით; „მასიური ტვირთის დახურულ კონტეინერთან“ დაკავშირებით იხილეთ „მასიური ტვირთის კონტეინერი“; „მასიური ტვირთის კონტეინერები“ გულისხმობს შესანახ სისტემას (ნებისმიერი შუასადებისა თუ საფარის ჩათვლით), რომელიც გათვალისწინებულია შესანახ სისტემასთან უშუალო კონტაქტში მყოფი მყარი ნივთიერებების გადასაზიდად. აღნიშნულში არ იგულისხმება ტარა, მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები, მსხვილგაბარიტიანი ტარა და ცისტერნები. მასიური ტვირთის კონტეინერებს: - გააჩნიათ მდგრადი ხასიათი და შესაბამისად საკმარისი სიმძლავრე მრავალჯერადი გამოყენების უზრუნველსაყოფად; - არის საგანგებოდ კონსტრუირებული ტვირთების შუალედური გადმოტვირთვის გარეშე ერთი ან რამდენიმე სახეობის სატრანსპორტო საშუალებით ტვირთების გადაზიდვის გაადვილების მიზნით; - აღჭურვილია იმ მოწყობილობებით, რომლებიც უზრუნველყოფს მათი დატვირთვაგადმოტვირთვის ოპერაციებს; - გააჩნიათ არანაკლებ 1.0მ3 მოცულობა. მასიური ტვირთის კონტეინერების მაგალითებს წარმოადგენს კონტეინერები, მასიური ტვირთის საზღვაო კონტეინერები, სკიპებიანი საწეველები, მასიური ტვირთის გადასატანი ბუნკერები, სახსნელი ძარები, ვარცლის ფორმის კონტეინერები, გორგოლაჭებიანი კონტეინერები, ავტოსატრანსპორტო საშუალებების სატვირთო განყოფილებები; შენიშვნა: მოცემული განმარტება გამოიყენება მხოლოდ იმ მასიური ტვირთის კონტეინერებთან დაკავშირებით, რომლებიც აკმაყოფილებს 6.11 თავით გათვალისწინებულ მოთხოვნებს: „მასიური ტვირთის დახურული კონტეინერი“ ნიშნავს მასიური ტვირთის სრულად დახურულ კონტეინერს, როელსაც გააჩნია მყარი საფარი, გვერდითი კედლები, უკანა კედელი და იატაკი (ბუნკერის ტიპის ძირის ჩათვლით). აღნიშნული ტერმინი აგრეთვე 30 გულისხმობს მასიური ტვირთის კონტეინერებს ღია სახურავით, გვერდითი ან უკანა კედლით, რომლებიც შესაძლებელია დაიხუროს გადაზიდვის დროს. მასიური ტვირთის დახურული კონტეინერი შესაძლებელია აღჭურვილი იყოს ნავრეტებით, რაც იძლევა ორთქლისა და აირების გამოშვებისა და ჰაერის შეშვების შესაძლებლობას, რაც გადაზიდვის ჩვეულებრივი პირობების დროს ხელს უწყობს მყარი შემცველობის შიგთავსის გამოშვებისა და წვიმის წყლისა და შხეფების შეღწევის თავიდან აცილებას. „მასიური ტვირთის ბრეზენტით გადახურული კონტეინერი“ ნიშნავს მასიური ტვირთის ზემოდან ღია კონტეინერს მყარი ძირით (ბუნკერის ტიპის ძირის ჩათვლით), გვერდითი და უკანა კედლით და არამყარი საფარით; „მასიური ტვირთის საზღვაო კონტეინერი“ ნიშნავს მასიური ტვირთის საზღვაო კონტეინერს, რომელიც სპეციალურად არის დამზადებული ოფშორულ ობიექტებზე, მათგან ამ მათ შორის მრავალჯერადი გადაზიდვისთვის. მასიური ტვირთის საზღვაო კონტეინერი კონსტრუირებული და დამზადებულია ღია ზღვაში დამუშავებული საზღვაო კონტეინერების დამტკიცებასთან დაკავშირებული ინსტრუქციების შესაბამისად, რაც მითითებულია საერთაშორისო საზღვაო ორგანიზაციის (სსო) მიერ შედგენილ დოკუმენტში MSC/Circ.860; „მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“ ნიშნავს მყარ ან დრეკად გადასატან ტარას, რომელიც განსხვავდება 6.1 თავში გათვალისწინებული ტარისგან და რომელსაც: (ა) გააჩნია შემდეგი მოცულობა: (i) არაუმეტეს 3მ3 II და III შეფუთვის ჯგუფებით გათვალისწინებული მყარი და თხევადი ნივთიერებების შემთხვევაში; (ii) არაუმეტეს 1.5მ3 I შეფუთვის ჯგუფის მყარ ნივთიერებებთან დაკავშირებით, როდესაც გამოყენებულია დრეკადი, მყარი პლასტმასის, შედგენილი, ბოჭკოვანი მუყაოსა თუ ხის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები; (iii) არაუმეტეს 3მ3 I შეფუთვის ჯგუფის მყარ ნივთიერებებთან დაკავშირებით, როდესაც გამოყენებულია ლითონის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები; (iv) არაუმეტეს 3მ3 მე-7 კლასით გათვალისწინებულ რადიოაქტიურ ნივთიერებებთან დაკავშირებით; (ბ) გათვალისწინებულია მექანიკური დამუშავებისთვის; (გ) მედეგია დატვირთვა-გადმოტვირთვისა და ტრანსპორტირების ოპერაციების დროს წარმოდგენილი დატვირთვების მიმართ, როგორც ეს განსაზღვრულია 6.5 თავში გათვალისწინებული ცდების მიხედვით; მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი პლასტმასის შიდა ჭურჭლით“, „ბოჭკოვანი მუყაოს მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“, „დრეკადი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“, „ლითონის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“, „მყარი პლასტმასის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“ და „ხის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“). (იხილეთ აგრეთვე „შედგენილი 31 შენიშვნა: 1: გადასატანი ცისტერნები ან კონტეინერ-ცისტერნები, რომლებიც აკმაყოფილებს 6.7 ან 6.8 თავებით გათვალისწინებულ მოთხოვნებს, და შესაბამისად არ განიხილება მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებად. შენიშვნა 2: მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები, რომლებიც აკმაყოფილებს 6.5 თავით გათვალისწინებულ მოთხოვნებს, და არ განიხილება კონტეინერებად ADR-ის მიზნებთან დაკავშირებით. „მაქსიმალური დასაშვები დატვირთვა“ (დრეკადი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებთან დაკავშირებით) ნიშნავს მაქსიმალურ სუფთა მასას, რომელზეც გათვლილია მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები და რომელიც დაშვებულია გადასაზიდად; „მაქსიმალური დასაშვები საერთო მასა“ (ა) (მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებთან დაკავშირებით) ნიშნავს მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერისა და ნებისმიერი სერვისული ან კონსტრუქციული მოწყობილობის მასას მაქსიმალურ სუფთა მასასთან ერთად; (ბ) (ცისტერნებთან დაკავშირებით) ნიშნავს გადაზიდვებზე დაშვებულ ცარიელ ცისტერნას და მაქსიმალურ დატვირთვას; შენიშვნა: გადასატან ცისტერნებთან დაკავშირებით, იხილეთ 6.7 თავი. „მაქსიმალური მუშა წნევა (მანომეტრული წნევა)“ ნიშნავს უმაღლეს მნიშვნელობას შემდეგი სამი წნევიდან: (ა) შევსების დროს ცისტერნაში დაშვებულ უდიდეს ფაქტიურ წნევას (მაქსიმალურად დასაშვები შევსების წნევა); (ბ) დაცლის დროს ცისტერნაში დაშვებულ უდიდეს ფაქტიურ წნევას (მაქსიმალურად დასაშვები დაცლის წნევა); და (გ) ფაქტიურ მანომეტრულ წნევას, რომელსაც ექვემდებარება ცისტერნა მისი შიგთავსით (აღნიშნული ითვალისწინებს გარეშე აირებს, რომლებიც შეიძლება წარმოდგენილი იყოს მასში) მაქსიმალურ მუშა ტემპერატურაზე. გარდა 4.3 თავით გათვალისწინებული მოთხოვნებით სხვაგვარად განპირობებული შემთხვევებისა, აღნიშნული მუშა წნევის (მანომეტრული წნევის) რიცხობრივი მნიშვნელობა 500C ტემპერატურაზე არ უნდა იყოს შემავსებელი ნივთიერების ორთქლის წნევაზე (აბსოლუტურ წნევაზე) ნაკლები. უსაფრთხოების სარქველებით აღჭურვილ ცისტერნებთან დაკავშირებით (ასაფეთქებელ მემბრანებთან ერთად ან მათ გარეშე), იმ ცისტერნების გარდა, რომლებიც გამოიყენება მე2 კლასით გათვალისწინებული შეკუმშული, გათხევადებული ან გახსნილი აირების გადასაზიდად, მაქსიმალური მუშა წნევა (მანომეტრული წნევა) უნდა იყოს აღნიშნული უსაფრთხოების სარქველების ნახვრეტების წნევის თანაბარი. (იხილეთ აგრეთვე „საანგარიშო წნევა“, „გამოშვების წნევა“, „შევსების წნევა“ და „საცდელი წნევა“). შენიშვნა 1: გადასატან ცისტერნებთან დაკავშირებით, იხილეთ 6.7 თავი. 32 შენიშვნა 2: დახურულ კრიოგენულ ჭურჭელთან დაკავშირებით, იხილეთ 6.2.1.3.6.5 ქვეპუნქტის შენიშვნა. „მაქსიმალური ნორმალური მუშა წნევა“, რადიოაქტიური მასალების გადაზიდვის შემთხვევაში, ნიშნავს მაქსიმალურ წნევას, რომელიც აღემატება ზღვის დონეზე არსებულ ატმოსფერული წნევას, რაც შეიძლება წარმოიშვას დამცავი გარსის სისტემაში ერთი წლის განმავლობაში ტემპერატურული რეჟიმისა და მზის გამოსხივების პირობებში და შეესაბამება გარემოს პირობებს დამხმარე სისტემების მიერ ვენტილაციისა, გარეშე გაგრილების ან გადაზიდვის დროს საოპერაციო კონტროლის გარეშე; „მაქსიმალური სუფთა მასა“ ნიშნავს ცალკეული ტარის შიგთავსის მაქსიმალურ შიდა მასას ან მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებისა და მსხვილგაბარიტიანი ტარისა და მისი შიგთავსის მაქსიმალურ კომბინირებულ მასას, რაც გამოსახულია კილოგრამებში; „მაქსიმალური ტევადობა“ ნიშნავს ჭურჭლისა თუ ტარის, მათ შორის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებისა და მსხვილგაბარიტიანი ტარის მაქსიმალურ შიდა მოცულობას, გამოსახულს კუბურ მეტრებსა და ლიტრებში; „მეაკ“, იხილეთ „მრავალელემენტიანი აირის კონტეინერი“; “MEMU” იხილეთ „ფეთქებადი ნივთიერებების მობილური დანადგარი“; „მილი“ (მე-2 კლასი) ნიშნავს უნაკერო, გადამზიდ წნევის ჭურჭელს, რომლის წყლის ტევადობა მეტია 150 ლიტრზე, თუმცა არ აღემატება 3 000 ლიტრს; „მრავალელემენტიანი აირის კონტეინერი (მეაკ)“ ნიშნავს იმ ელემენტების შემცველ კონტეინერს, რომლებიც ერთმანეთს უკავშირდება კოლექტორით და აღმართულია ჩარჩო კონსტრუქციაზე. შემდეგი ელემენტები განიხილება მრავალელემენტიანი აირის კონტეინერის შემადგენელ ელემენტებად: ცილინდრები, მილები, წნევის დოლურები და ცილინდრების კვანძები, ასევე აირების გადასატანი ცისტერნები, რომლებსაც, 2.2.2.1.1 პუნქტის თანახმად, გააჩნია 450 ლიტრზე მეტი ტევადობა; შენიშვნა: გაერთიანებული ერების ორგანიზაციის კონტეინერებთან დაკავშირებით, იხილეთ 6.7 თავი. მრავალელემენტიანი აირის „მრავალჯერადი გამოყენების მსხვილგაბარიტიანი ტარა“ ნიშნავს მსხვილგაბარიტიან ტარას, რომელიც გამოიყენება ხელახლა შესავსებად და რომელიც შემოწმდა და დამტკიცდა, რომ თავისუფალია ყოველგვარი წუნისგან, რომელიც გავლენას მოახდენდა მისი საექსპლუატაციო უნარის შემოწმების შესაძლებლობაზე; აღნიშნული ტერმინი ვრცელდება იმ ტარაზე, რომელიც ივსება იგივე ან მსგავსი სახის შიგთავსით და ექვემდებარება გადაზიდვას ტვირთგამგზავნის მიერ კონტროლირებული მანაწილებელი ჯაჭვების ფარგლებში; „მრავალჯერადი გამოყენების ტარა“ ნიშნავს ტარას, რომელიც შემოწმდა და დამტკიცდა, რომ თავისუფალია ყოველგვარი წუნისგან, რომელიც გავლენას მოახდენდა მისი საექსპლუატაციო უნარის შემოწმების შესაძლებლობაზე. აღნიშნული ტერმინი ვრცელდება იმ ტარაზე, რომელიც ივსება იგივე ან მსგავსი სახის შიგთავსით და ექვემდებარება გადაზიდვას ტვირთგამგზავნის მიერ კონტროლირებული მანაწილებელი ჯაჭვების ფარგლებში; 33 „მრავალჯერადი გამოყენების პლასტმასის მასალა“ ნიშნავს გამოყენებული სამრეწველო ტარიდან აღდგენილ მასალას, რომელიც გასუფთავდა და მომზადდა ახალ ტარაში გადამუშავების მიზნით; „მტვირთავი“ ნიშნავს ნებისმიერ საწარმოს, რომელიც: (ა) უზრუნველყოფს შეფუთული სახიფათო ტვირთების, მცირე ზომის კონტეინერებისა თუ გადასატანი ცისტერნების დატვირთვას ავტოსატრანსპორტო საშუალებებსა თუ კონტეინერებზე ან მათ შიგნით; (ბ) უზრუნველყოფს კონტეინერის, მასიური ტვირთის კონტეინერის, მრავალელემენტიანი აირის კონტეინერის, კონტეინერ-ცისტერნისა თუ გადასატანი ცისტერნის დატვირთვას ავტოსატრანსპორტო საშუალებაზე. „მტსტკ“, იხილეთ „მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“; „მსხვილგაბარიტიანი ტარა“ ნიშნავს ტარას, რომელიც შედგება ნაკეთობებისა თუ შიდა ტარის შემცველი გარე ტარისგან და რომელიც (ა) გათვალისწინებულია მექანიკური დამუშავებისთვის; (ბ) აღემატება 400 კგ სუფთა მასას ან 450 ლიტრ ტევადობას, თუმცა მისი ტევადობა არ აჭარბებს 3მ3-ს. „მსხვილგაბარიტიანი ავარიული ტარა“ ნიშნავს სპეციალურ ტარას, რომელიც (ა) გათვალისწინებულია მექანიკური დამუშავებისთვის; და (ბ) აღემატება 400 კგ სუფთა მასას ან 450 ლიტრ ტევადობას, თუმცა მისი ტევადობა არ აჭარბებს 3მ3-ს. რომელშიც თავსდება დაზიანებული, წუნდებული ან მჟონავი სახიფათო ტვირთის შემცველი შეფუთვები ან გაჟონილი სახიფათო ტვირთი, აღდგენის ან გაუვნებელყოფის მიზნით გადაზიდვისთვის. „მუშა წნევა“ ნიშნავს შევსებული წნევის ჭურჭელში 150C სტანდარტულ ტემპერატურაზე შეკუმშული აირის დადგენილ წნევას; შენიშვნა: ცისტერნებთან დაკავშირებით, იხილეთ „მაქსიმალური მუშა წნევა“; „მყარი ნივთიერება“ ნიშნავს: (ა) ნივთიერებას, რომლის დნობის წერტილის ან საწყისი დნობის წერტილის ტემპერატურა აღემატება 200C-ს 101.3 კპა წნევაზე; ან (ბ) ნივთიერებას, რომელიც არ წარმოადგენს თხევადს ASTM D4359-90 საცდელი მეთოდის შესაბამისად ან წარმოადგენს ბლანტს იმ კრიტერიუმების შესაბამისად, რომლებიც მოქმედებს 2.3.4 პუნქტში აღწერილ დენადობის განმსაზღვრელ ცდასთან (პენეტრომეტრის გამოყენების ტესტი) დაკავშირებით; „მცირე მოცულობის კონტეინერი“, იხილეთ „კონტეინერი“; ნ „ნარჩენები“ ნიშნავს ნივთიერებებს, ხსნარებს, ნარევებსა თუ ნაკეთობებს, რომლებიც არ არის გათვალისწინებული პირდაპირი გამოყენებისთვის, თუმცა მათი ტრანსპორტირება 34 ხორციელდება მათი გადამუშავების, დამარხვის, დაწვის გზით განადგურების ან გაუვნებელყოფის ნებისმიერი სხვა საშუალებების გამოყენების მიზნით; „ნარჩენების ვაკუუმური ცისტერნა“ ნიშნავს დამონტაჟებულ ცისტერნას, სახსნელ ცისტერნას, კონტეინერ-ცისტერნასა თუ სახსნელ ძარა-ცისტერნას, რომელიც ძირითადად გამოიყენება სახიფათო ნარჩენების გადასაზიდად და გააჩნია სპეციალური კონსტრუირებული მახასიათებლები და/ან მოწყობილობა, ნაჩენების ჩატვირთვაგადმოტვირთვის უზრუნველსაყოფად, როგორც ეს გათვალისწინებულია 6.10 თავში. ცისტერნა, რომელიც სრულად შეესაბამება 7.6 ან 6.8 თავის მოთხოვნებს, არ განიხილება ნარჩენების ვაკუუმურ ცისტერნად; „ნეიტრონული გამოსხივების დეტექტორი“ ნიშნავს ნეიტრონული გამოსხივების გამოსავლენ მოწყობილობას. აღნიშნულ მოწყობილობაში აირი შესაძლებელია წარმოდგენილი იყოს ჰერმეტულად დახურულ ელექტრონულ გარდამქმნელში, რომელიც უზრუნველყოფს ნეიტრონის გამოსხვივების გარდაქმნას გაზომვად ელექტრონულ სიგნალად; პ „პოზიცია, რომელიც კონკრეტულად არ არის მითითებული N.O.S.“ ნიშნავს ერთობლივ პოზიციას, რომელსაც მიეკუთვნება ნივთიერებები, ნარევები, ხსნარები თუ ნაკეთობები იმ შემთხვევაში, თუ ისინი: (ა) არ არის მითითებული დასახელებით 3.2. თავის ა ცხრილში; და (ბ) ავლენს კონკრეტულად განუსაზღვრელი პოზიციის კლასის, კლასიფიკაციის კოდის, შეფუთვის ჯგუფის, დასახელებისა და აღწერილობის ქიმიურ, ფიზიკურ და/ან სახიფათო თვისებებს; რ „რადიოაქტიური შემადგენლობა“, რადიოაქტიური მასალების გადაზიდვასთან დაკავშირებით, ნიშნავს რადიოაქტიურ მასალას შეფუთვაში წარმოდგენილ ნებისმიერ რადიოაქტიურად დამაბინძურებელ ან გააქტიურებულ მყარ ნივთიერებებთან, სითხეებსა თუ აირებთან ერთად; „რბილი ფოლადი“ ნიშნავს 360-დან 440 ნ/მმ2-მდე წყვეტაზე მინიმალური სიმტკიცის მქონე ფოლადს; შენიშვნა: გადასატან ცისტერნებთან დაკავშირებით, იხილეთ 6.7 თავი. „რეკონსტრუირებული მტსტკ“, იხილეთ „მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“; „რეკონსტრუირებული მსხვილგაბარიტიანი ტარა“ ნიშნავს ლითონის ან არადრეკადი პლასტმასის მსხვილგაბარიტიან ტარას, რომელიც: (ა) დამზადებულია გაერთიანებული ერების ორგანიზაციის მიერ რეკომენდებული ტიპის სახით იმ ტიპისგან, რომელიც არ შეესაბამება გაერთიანებული ერების ორგანიზაციის რეკომენდაციებს; ან (ბ) გარდაიქმნება გაერთიანებული ერების ორგანიზაციის მიერ რეკომენდებული კონსტრუქციის ერთი ტიპიდან გაერთიანებული ერების ორგანიზაციის მიერ რეკომენდებული კონსტრუქციის მეორე ტიპად. 35 რეკონსტრუირებული მსხვილგაბარიტიანი ტარა ექვემდებარება ADR-ის იგივე მოთხოვნებს, რომლებიც მოქმედებს იგივე ტიპის ახალ მსხვილგაბარიტიან ტარასთან დაკავშირებით (კონსტრუქციის ტიპის განმარტება იხილეთ აგრეთვე 6.6.5.1.2 პუნქტში); „რეკონსტრუირებული ტარა“ კონკრეტულად ნიშნავს: (ა) ლითონის დოლურებს, რომლებიც: (i) დამზადებულია გაერთიანებული ერების ორგანიზაციის ტარის ტიპის სახით, 6.1 თავის მოთხოვნების შესაბამისად, იმ ტიპის ტარისგან, რომელიც არ შეესაბამება გაერთიანებული ერების ორგანიზაციის მოთხოვნებს; (ii) გარდაიქმნება გაერთიანებული ერების ორგანიზაციის ტარის ერთი ტიპიდან, 6.1 თავის მოთხოვნების შესაბამისად, გაერთიანებული ერების ორგანიზაციის ტარის სხვა ტიპად; ან (iii) დაექვემდებარება შიდა კონსტრუქციული (მაგალითად, არასახსნელი თავების); ელემენტების გამოცვლას (ბ) პლასტმასის დოლურებს, რომლებიც: (i) გარდაიქმნება გაერთიანებული ერების ორგანიზაციის ტარის ერთი ტიპიდან გაერთიანებული ერების ორგანიზაციის ტარის სხვა ტიპად (მაგალითად, 1H1დან 1Р2-ზე); ან (ii) დაექვემდებარება შიდა კონსტრუქციული ელემენტების გამოცვლას. რეკონსტრუირებული დოლურები ექვემდებარება 6.1 თავის იმავე რომლებიც მოქმედებს იგივე ტიპის ახალ დოლურებთან დაკავშირებით; მოთხოვნებს, “RID” ნიშნავს წესებს სახიფათო ტვირთის საერთაშორისო სარკინიგზო გადაზიდვების შესახებ (COFIT-ის (კონვენცია საერთაშორისო სარკინიგზო გადაზიდვების შესახებ) C დანართი); ს „საანგარიშო წნევა“ ნიშნავს მინიმალური საცდელი წნევის თანაბარ თეორიულ წნევას, რომელიც გადასაზიდი ნივთიერებების საშიშროების ხარისხის მიხედვით, შესაძლებელია იყოს სამუშაო წნევაზე მეტი ან ნაკლები. ის გამოიყენება მხოლოდ კორპუსის კედლების სისქის განსაზღვრის მიზნით ნებისმიერი სახის გარე ან შიდა გამაძლიერებელი მოწყობილობებისგან დამოუკიდებლად (იხილეთ აგრეთვე „დაჭირხნის წნევა“, „შევსების წნევა“, „მაქსიმალური მუშა წნევა“ (მანომეტრული წნევა) და „საცდელი წნევა“); შენიშვნა: გადასატან ცისტერნებთან დაკავშირებით, იხილეთ 6.7 თავი. „სადები“ ნიშნავს ტარაში გათვალისწინებულ მილს ან ტომარას, მსხვილგაბარიტიანი ტარისა თუ მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების ჩათვლით, თუმცა არ წარმოადგენს მის შემადგენელ ნაწილს, ასევე მისი ნახვრეტების ჩამკეტებს; „საინსპექციო ორგანო“ ნიშნავს კომპეტენტური ორგანოს მიერ დამტკიცებულ დამოუკიდებელი კონტროლისა და ცდების განმახორციელებელ ორგანოს; „საკეტი“ ნიშნავს ჭურჭელზე არსებული ღიობების ჩამკეტ მოწყობილობას; 36 „საკონტროლო ტემპერატურა“ ნიშნავს მაქსიმალურ ტემპერატურას, რომელზეც შესაძლებელია ორგანული პეროქსიდის ან თვითრეაქტიული ნივთიერებების უსაფრთხო გადაზიდვა; „სატრანსპორტო ერთეული“ ნიშნავს ავტოსატრანსპორტო საშუალებას მისაბმელის გარეშე ან ძრავიანი ავტოსატრანსპორტო საშუალებისა და მასზე მიმაგრებული მისაბმელის კომბინაციას; „სატრანსპორტო ინდექსი, რომელიც მინიჭებულია შეფუთვაზე, სატრანსპორტო პაკეტსა თუ კონტეინერზე, შეუფუთავ LSA-I-სა თუ SCO-I-ზე“, რადიოაქტიური მასალების გადაზიდვასთან შემთხვევაში, ნიშნავს ციფრს, რომელიც გამოიყენება რადიაციული გამოსხივების კონტროლის უზრუნველყოფის მიზნით; „სატრანსპორტო პაკეტი“ ნიშნავს (რადიოაქტიური მასალის შემთხვევაში ერთი ტვირთგამგზავნის მიერ) გამოყენებულ გარსს, ერთი ან რამდენიმე შეფუთვის გასაერთიანებლად ერთ გადაზიდვების დროს დანადგარში ჩატვირთვა-გადმოტვირთვის ოპერაციებისა და დაწყობის გაადვილების მიზნით. პაკეტის მაგალითებია: (ა) დასატვირთი საშუალებები, როგორიცაა, მაგალითად, ქვეშები, რომელზეც ხდება რამდენიმე შეფუთვის განლაგება ან დაშტაბელება, მაგრდება პლასტმასის ლენტით, შემავიწროვებელი ან დასაჭიმი ფირით ან სხვა შესაბამისი მასალით; ან (ბ) გარე დამცავი ტარა, მაგალითად, ყუთი ან გისოსი; „საცდელი წნევა“ ნიშნავს საწყისი ან პერიოდული შემოწმების დროს წნევის გამოცდის განმავლობაში გამოყენებულ აუცილებელ წნევას (იხილეთ აგრეთვე „საანგარიშო წნევა“, „გამოსაშვები წნევა“, „შევსების წნევა“ და „მაქსიმალური მუშა წნევა (დაჭირხვნის წნევა)“); შენიშვნა: გადამზიდ ცისტერნებთან დაკავშირებით, იხილეთ 6.7 თავი. „საწარმო“ ნიშნავს ნებისმიერ ფიზიკურსა თუ იურიდიულ პირს, რომელიც ეწევა კომერციულ თუ არაკომერციულ საქმიანობას, სამართალსუბიექტურობის არმქონე ნებისმიერ ასოციაციასა თუ ადამიანთა ჯგუფს, რომელიც ეწევა კომერციულ თუ არაკომერციულ საქმიანობას, ასევე ნებისმიერ ოფიციალურ ორგანიზაციას, რომელიც თავად ფლობს სამართალსუბიექტურობას ან დამოკიდებულია აღნიშნული სამართალსუბიექტურობის მფლობელ ნებისმიერ ორგანოზე; „საწვავის ელემენტი“ ნიშნავს ელექტროქიმიურ მოწყობილობას, რომელიც გარდაქმნის საწვავის ქიმიურ ენერგიას ელექტროენერგიად, სითბოდ და რეაქციის პროდუქტებად; „საწვავის ელემენტის ძრავი“ ნიშნავს მოწყობილობას, რომელიც გამოიყენება აღჭურვილობის კვების წყაროს სახით და რომელიც შედგება საწვავის ელემენტისა და მისი საწვავის მიწოდების მოწყობილობისგან, იმის მიუხედავად წარმოდგენილია თუ არა საწვავის ელემენტთან ერთად და მოიცავს ყოველგვარ დამხმარე ნაწილს, რაც აუცილებელია მისი ფუნქციების სისრულეში მოსაყვანად; „სახიფათო ტვირთები“ ნიშნავს იმ ნივთიერებებსა და ნაკეთობებს, რომელთა გადაზიდვაც იკრძალება ADR-ით, ან ნებადართულია მხოლოდ მასში გათვალისწინებული პირობებით; „სახიფათო რეაქცია“ ნიშნავს: (ა) წვას ან სითბოს მნიშვნელოვანი რაოდენობით გამოყოფას; 37 (ბ) ადვილაალებადი, ტოქსიკური, მჟანგავი ან ტოქსიკური აირების გამოყოფას; (გ) კოროზიული ნივთიერებების წარმოქმნას; (დ) არამდგრადი ნივთიერებების წარმოქმნას; ან (ე) წნევის სახიფათო ზრდა (მხოლოდ ცისტერნებისთვის). „სახსნელი ცისტერნა“ ნიშნავს ცისტერნას, რომელიც არ წარმოადგენს დამონტაჟებულ ცისტერნას, გადასატან ცისტერნას, კონტეინერ-ცისტერნასა თუ ავტოსატრანსპორტო საშუალება-ბატარეის ელემენტს ან მრავალელემენტიანი აირის კონტეინერს, რომლის მოცულობაც აღემატება 450 ლიტრს, და რომელიც არ არის გათვალისწინებული ტვირთების გადასაზიდად, გადატვირთვის გარეშე და ჩვეულებრივ ექვემდებარება დამუშავებას მხოლოდ ცარიელ მდგომარეობაში; „სახსნელი ძარა“ , იხილეთ „კონტეინერი“; „სახსნელი ძარა-ცისტერნა“ განიხილება, როგორც კონტეინერ-ცისტერნა; „სერვისული აღჭურვილობა“ (ა) ცისტერნების შემთხვევაში - ნიშნავს შევსებისა და დაცლის, სავენტილაციო, გამათბობელ და თბოიზოლაციის აღჭურვილობასა და საზომ ხელსაწყოებს; (ბ) ავტოსატრანსპორტო საშუალება-ბატარეებისა თუ მრავალელემენტიანი აირის კონტეინერების შემთხვევაში - ნიშნავს შევსებისა და დაცლის მოწყობილობებს, კოლექტორის, უსაფრთხოების მოწყობილობებისა და საზომი ხელსაწყოების ჩათვლით; (გ) მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერის შემთხვევაში - ნიშნავს შევსებისა და გამოშვების მოწყობილობებს, ასევე ნებისმიერ წნევის გამომშვებსა თუ სავენტილაციო, უსაფრთხოების უზრუნველყოფის, გათბობისა და თბოიზოლაციის მოწყობილობებსა და საზომ ხელსაწყოებს; შენიშვნა: გადამზიდ ცისტერნებთან დაკავშირებით, იხილეთ 6.7 თავი. „სითხე“ ნიშნავს ნივთიერებას, რომელსაც 500C ტემპერატურაზე გააჩნია არაუმეტეს 300 კპა (3 ბარი) ორთქლის წნევა, არ წარმოადგენს სრულად აიროვანს 200C ტემპერატურასა და 101.3 კპა წნევაზე და რომელსაც (ა) აღენიშნება 200C დნობის წერტილი ან საწყისი დნობის წერტილი ან უფრო ნაკლები 101.3 კპა წნევაზე; (ბ) წარმოადგენს სითხეს ASTM D 4359-90 ცდების მეთოდის შესაბამისად; (გ) არ წარმოადგენს ბლანტს 2.3.4 პუნქტში გათვალისწინებული დენადობის განმსაზღვრელ ცდასთან (პენეტრომეტრის გამოყენების ცდა) დაკავშირებით მოქმედი კრიტერიუმების შესაბამისად; შენიშვნა: „გადაზიდვა დაკავშირებით, ნიშნავს: თხევად მდგომარეობაში“ ცისტერნის მოთხოვნებთან - სითხეების გადაზიდვას ზემოაღნიშნული განმარტების თანახმად; ან - მყარი ნივთიერებების გადაზიდვას, რომლებიც მდგომარეობაში ტრანსპორტირებისთვის. 38 წარმოდგენილია მდნარ „სრული დატვირთვა“ ნიშნავს ერთი ტვირთგამგზავნის მიერ გაგზავნილ ნებისმიერ ტვირთს, რომლისთვისაც გამოიყენება ექსკლუზიურად მთლიანი ავტოსატრანპორტო საშუალება ან დიდი მოცულობის კონტეინერი და რომლის დატვირთვა-გადმოტვირთვის ყველა ოპერაცია ხორციელდება ტვირთგამგზავნის ან ტვირთმიმღების მითითებების შესაბამისად; შენიშვნა: რადიოაქტიურ მასალასთან შესაბამის ტერმინს წარმოადგენს „ექსკლუზიური გამოყენება“. „სსო“ ნიშნავს საერთაშორისო საზღვაო ორგანიზაციას (სსო, გაერთიანებული სამეფო, SE1 7SR ლონდონი, ალბერტის სანაპირო 4); „სტანდარტი EN“ ნიშნავს ევროპის სტანდარტიზაციის კომიტეტის მიერ გამოცემულ ევროპულ სტანდარტს (CEN, ბრიუსელი, B-1000, მარნიქსის გამზირი 17); „სტანდარტი ISO“ ნიშნავს სტანდარტიზაციის საერთაშორისო ორგანიზაციის (ISO) მიერ გამოცემულ საერთაშორისო სტანდარტს (ISO - ჟენევა 20, CH-1204, ვარემბეს ქუჩა 1); „სტანდარტული ფოლადი“ ნიშნავს ფოლადს 370 ნ/მმ2 სიმტკიცით გლეჯაზე და 27% წყვეტაზე დაგრძელებით; „სტსსგ კოდექსი“ ნიშნავს საერთაშორისო კოდექსს სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ, ლონდონში, საერთაშორისო საზღვაო ორგანიზაციის (სსო) მიერ გამოცემული ზღვაზე ადამიანთა სიცოცხლის დაცვის 1974 წლის საერთაშორისო კონვენციის (SOLAS კონვენცია) ა ნაწილის VII თავის შესაბამისად; „სუფთა ფეთქებადი მასა (NEM)“ ნიშნავს ფეთქებადი ნივთიერების საერთო მასას, ტარის, კორპუსის და ა.შ. გარეშე (სუფთა ფეთქებადი ოდენობა (NEW), სუფთა ფეთქებადი შიგთავსი (NEC), სუფთა ფეთქებადი წონა (NEW) ან ფეთქებადი შიგთავსის სუფთა მასა ხშირად გამოიყენება იგივე მნიშვნელობის აღსანიშნავად); „CIM“ ნიშნავს სარკინიგზო ტრანსპორტით ტვირთების საერთაშორისო გადაზიდვის შესახებ ხელშეკრულებასთან დაკავშირებულ ერთგვაროვან წესებს (სარკინიგზო ტრანსპორტით ტვირთების საერთაშორისო გადაზიდვის შესახებ კონვენციის (COTIF) B დანართი, ცვლილებებთან ერთად); “CMR” ნიშნავს ტვირთების საერთაშორისო საგზაო ხელშეკრულებასთან დაკავშირებულ კონვენციას (ჟენევა, შესწორებებთან ერთად; გადაზიდვების შესახებ 1956 წლის 19 მაისი), „CSC“ ნიშნავს საერთაშორისო კონვენციას უსაფრთხო კონტეინერების შესახებ (ჟენევა, 1972 წ.), მასში შეტანილ ცვლილებებთან ერთად, რომელიც საერთაშორისო საზღვაო ორგანიზაციის (სსო) მიერ ლონდონში; გამოქვეყნებულია ტ „ტარა“ ნიშნავს ერთ ან რამდენიმე ჭურჭელსა და ნებისმიერ სხვა კომპონენტსა თუ მასალას, რაც აუცილებელია ჭურჭლის მიერ პროდუქტის შემცველობისა და სხვა ფუნქციების სისრულეში მოსაყვანად (იხილეთ აგრეთვე „კომბინირებული ტარა“, „შედგენილი ტარა“, „შიდა ტარა“, „მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი (IBC)“, „შუალედური ტარა“, „მსხვილგაბარიტიანი ტარა“, „თხელფურცლოვანი ლითონის ტარა“, „გარე ტარა“, „აღდგენილი ტარა“, 39 „რეკონსტრუირებული ტარა“, „მრავალჯერადი გამოყენების ტარა“, „ავარიული ტარა“ და „ფხვნილისებრი ნივთიერებების მიმართ მედეგი ტარა“). „ტერიტორიის გავლით ან ტერიტორიაზე“, რადიოაქტიური მასალების გადაზიდვასთან დაკავშირებით, ნიშნავს იმ ქვეყნების ტერიტორიის გავლით ან მათ ტერიტორიაზე, რომელზეც ხორციელდება ტვირთის გადაზიდვა; თუმცა აღნიშნული არ ვრცელდება იმ ქვეყნებზე, რომლის „ტერიტორიის ზემოთაც“ ხორციელდება გადაზიდვა საჰაერო გზით იმ პირობით, რომ ამ ქვეყნებში არ არის გათვალისწინებული ტვირთის გეგმიური დაშვება; „ტექნიკური დასახელება“ ნიშნავს საყოველთაოდ აღიარებულ ქიმიურ დასახელებას იმ შემთხვევაში, თუ შეესაბამება ბიოლოგიურ დასახელებას ან ამჟამად სამეცნიერო და ტექნიკურ სახელმძღვანელოებში, ჟურნალებსა და ტექსტებში გამოყენებულ სხვა დასახელებებს (იხილეთ პუნქტი 3.1.2.8.1.1); „ტვირთის სატრანსპორტო ერთეული“ ნიშნავს ავტოსატრანსპორტო საშუალებას, კონტეინერს, კონტეინერ-ცისტერნას, გადამზიდ ცისტერნასა თუ მრავალელემენტიან აირის კონტეინერს; შენიშვნა: აღნიშნული განმარტება გამოიყენება მხოლოდ 3.3 თავის 302-ე სპეციალურ დებულებასა და 5.5 თავთან დაკავშირებით; „ტვირთგამგზავნი“ ნიშნავს საწარმოს, რომელიც ახორციელებს სახიფათო ტვირთების გაგზავნას როგორც საკუთარი მიზნებისთვის, ასევე მესამე მხარეების სახელით. იმ შემთხვევაში, თუ ტრანსპორტირების ოპერაცია ხორციელდება გადაზიდვების შესახებ ხელშეკრულების საფუძველზე, ტვირთგამგზავნი წარმოადგენს ტვირთგამგზავნს აღნიშნული გადაზიდვების შესახებ ხელშეკრულების თანახმად; „ტვირთი“ ნიშნავს ტვირთგამგზავნის მიერ გადაზიდვებისთვის წარმოდგენილ ნებისმიერი სახის შეფუთვასა თუ შეფუთვებს, ან სახიფათო ტვირთების ნებისმიერ პარტიას. „ტვირთის დამუშავების მოწყობილობა“ (დრეკადი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებთან დაკავშირებით) ნიშნავს ნებისმიერი სახის საკიდს, მარყუჟს, ნახვრეტსა თუ ჩარჩოს, რომელიც დამაგრებულია მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერის კორპუსზე ან შექმნილია მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერის კორპუსის მასალის მდგრადობის უზრუნველსაყოფად; „ტვირთმიმღები“ ნიშნავს ტვირთმიმღებს გადაზიდვების შესახებ ხელშეკრულების შესაბამისად. იმ შემთხვევაში, თუ ტვირთმიმღები წარმოადგენს მესამე მხარეს გადაზიდვების შესახებ ხელშეკრულებით გათვალისწინებული დებულებების შესაბამისად, აღნიშნული პირი განიხილება, როგორც ტვირთმიმღები ADR-ის მნიშვნელობის ფარგლებში. იმ შემთხვევაში, თუ ტრანსპორტირების ოპერაცია ხორციელდება გადაზიდვების შესახებ ხელშეკრულების გაფორმების გარეშე, ის საწარმო, რომელიც იღებს პასუხისმგებლობას სახიფათო ტვირთზე მისი ჩამოსვლისას, ჩაითვლება ტვირთმიმღებად; „ტომარა“ ნიშნავს რბილ ტარას, რომელიც დამზადებულია ქაღალდისგან, პლასტმასის ლენტისგან, ტექსტილისგან, ქსოვილის მასალისა თუ სხვა შესაბამისი მასალისგან; უ 40 „უსაფრთხოების სარქველი“ ნიშნავს ზამბარით აღჭურვილ მოწყობილობას, რომელიც ავტომატურად აქტიურდება წნევის მოქმედებით იმ მიზნით, რომ დაიცვას ცისტერნა დაუშვებელი ჭარბი შიგა წნევისგან; “UIC” ნიშნავს სარკინიგზო გზების საერთაშორისო კავშირს (UIC, საფრანგეთი, პარიზი F75015, ჟან რეის ქუჩა 16); ფ „ფეთქებადი ნივთიერებების მობილური დანადგარი“ ნიშნავს დანადგარს ან ავტოსატრანსპორტო საშუალებას, რომელზეც აღმართულია აღნიშნული დანადგარი, იმ სახიფათო ტვირთებისგან ფეთქებადი ნივთიერებების დასამზადებლად და დასამუხტად, რომლებიც არ წარმოადგენს ფეთქებადს. დანადგარი შედგება სხვადასხვა ცისტერნისგან, მასიური ტვირთების კონტეინერებისგან და ტექნოლოგიური მოწყობილობებისგან, ასევე ტუმბოებისა და შესაბამისი მოწყობილობებისგან. MEMU შეიძლება აღჭურვილი იყოს სპეციალური განყოფილებებით ფეთქებადი ნივთიერებების შეფუთვის მიზნით; შენიშვნა: მიუხედავად იმისა, რომ MEMU-ს განმარტება ითვალისწინებს გამონათქვამს „ფეთქებადი ნივთიერებების დამზადება და დამუხტვა“, MEMU-თან დაკავშირებული მოთხოვნები გამოიყენება მხოლოდ გადაზიდვებთან და არა ფეთქებადი ნივთიერებების დამზადებასა და დამუხტვასთან დაკავშირებით. ქ „ქსოვილის პლასტიკური მასალა“ (დრეკად მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებთან დაკავშირებით) ნიშნავს დაჭიმული ლენტისგან პოლიმერული მასალის ერთი ძაფისგან დამზადებულ მასალას. ან შესაბამისი ღ „ღარი“ (პირველი კლასი) ნიშნავს ლითონის, პლასტმასის, ბოჭკოვანი მუყაოსა თუ სხვა შესაბამისი მასალის ფურცელს, რომელიც განთავსებულია შიდა, შუალედურ თუ გარე ტარაზე და უზრუნველყოფს ტვირთის ზუსტ მოთავსებას აღნიშნულ ტარაში. ღარის ზედაპირი შესაძლებელია იყოს იმ ფორმის, რომ შესაძლებელი გახდეს ტარისა თუ ნაკეთობების მოთავსება, საიმედოდ დამაგრება და ერთმანეთისგან განცალკევება; „ღია ავტოსატრანსპორტო საშუალება“ ნიშნავს ავტოსატრანსპორტო საშუალებას, რომლის პლატფორმასაც არ გააჩნია დაშენებები ან ძირითადად უზრუნველყოფილია გვერდით და უკანა დაფებით; „ღია კონტეინერი“, იხილეთ „კონტეინერი“; „ღია კრიოგენული ჭურჭელი“ ნიშნავს გადასატან, თერმოიზოლირებულ ჭურჭელს, რომელიც განკუთვნილია ატმოსფერულ წნევაზე შენახული გაცივებული, გათხევადებული აირებისთვის, გაცივებული გათხევადებული აირის უწყვეტი ვენტილაციის გზით; ყ „ყუთი“ ნიშნავს ლითონისგან, ხისგან, ფანერისგან, დამუშავებული ხის მასალისგან, ბოჭკოვანი მუყაოსგან, პლასტმასისა თუ სხვა შესაბამისი მასალისგან დამზადებულ ტარას სრული მართკუთხა ან მრავალკუთხა წახნაგებით. დასაშვებია მცირე ხვრელების 41 გათვალისწინება დამუშავებისა თუ გაღების გაადვილების, ასევე კლასიფიკაციის მოთხოვნებთან შესაბამისობის უზრუნველყოფის მიზნით იმ შემთხვევაში, თუ აღნიშნული არ არღვევს ტარის მთლიანობას გადაზიდვების დროს; შ „შაა“ (CGA) - შეკუმშული აირების ასოციაცია (CGA, ამერიკის შეერთებული შტატები, ვირჯინია 20151-2923, შანტილი, ვოლნეი როუდ 4221, მე-5 სართული); „შედგენილი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი პლასტმასის შიდა ჭურჭლით“ ნიშნავს მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერს, რომელიც შედგება მყარი გარე გარსის სახით წარმოდგენილ კონსტრუქციული აღჭურვილობისგან, სადაც მოთავსებულია პლასტმასის შიდა ჭურჭელი სხვა სერვისულ ან კონსტრუქციულ მოწყობილობასთან ერთად. ის დამზადებულია იმ სახით, რომ შიდა ჭურჭელი და გარე გარსი წარმოადგენდეს ერთ მთლიან ნაკეთობას და გამოიყენებოდეს როგორც ერთი ინტეგრირებული ერთეული, რომელიც უნდა შეივსოს, შეინახოს, გადატანილ იქნეს ან დაიცალოს. შენიშვნა: ტერმინი „პლასტმასის მასალა“, როდესაც გამოიყენება კომბინირებული მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების შიდა ჭურჭელთან დაკავშირებით, გულისხმობს აგრეთვე სხვა პოლიმერულ მასალებსაც, როგორიცაა რეზინი. „შედგენილი ტარა“ ნიშნავს შიდა ჭურჭლისა და გარე ტარისგან დამზადებულ ტარას, შიდა ჭურჭელი და გარე ტარა წარმოადგენს ერთ მთლიან ტარას. აწყობის შემთხვევაში, აღნიშნული რჩება განუყოფელ ერთეულად, რომელიც ივსება, ინახება, გადატანილია ან იცლება ერთგვარი სახით; შენიშვნა: „კომბინირებული ტარის“ „შიდა ჭურჭელი“ ყოველთვის განისაზღვრება, როგორც „შიდა ტარა“ და არა როგორც შედგენილი ტარისთვის გამოყენებული „შიდა შემადგენელი ნაწილები“. მაგალითად, 6HA1 ტიპის ტარის (შედგენილი ტარა, დამზადებული პლასტმასის მასალისგან) „შიდა შემადგენლობა“ წარმოადგენს ერთგვარი სახის „შიდა ჭურჭელს“, ვინაიდან ის ჩვეულებრივ არ არის განსაზღვრული პროდუქტის შემცველობითი ფუნქციის შესასრულებლად მისი „გარე ტარის“ გარეშე და შესაბამისად წარმოდგენილია, როგორც „შიდა ტარა“. იმ შემთხვევაში, თუ ტერმინის - „შედგენილი ტარა“ შემდეგ მასალა მითითებულია ბრჭყალებში, აღნიშნული გულისხმობს შიდა ჭურჭელს. „შემჭიდროვებული ტარა“ ნიშნავს შეუღწევად ტარას მშრალი შიგთავსისთვის, გადაზიდვის დროს წარმოქმნილი წვრილი, მყარი მასალების ჩათვლით; „შესაბამისობის შეფასება“ ნიშნავს 1.8.6 და 1.8.7 პუნქტებით გათვალისწინებული დებულებების თანახმად პროდუქტის შესაბამისობის შემოწმების პროცედურას, რაც დაკავშირებულია ტიპის დამტკიცებასთან, წარმოების ზედამხედველობასთან, საწყის შემოწმებასა და გამოცდასთან; „შევსების კოეფიციენტი“ ნიშნავს აირის მასის თანაფარდობას წყლის მასასთან 150C ტემპერატურაზე, რომელიც სრულად შეავსებდა ექსპლუატაციისთვის მზა წნევის ჭურჭელს; 42 „შევსების წნევა“ ნიშნავს მაქსიმალურ წნევას, რომელიც ფაქტიურად მიიღწევა ჭურჭელში მაშინ, როდესაც მოხდება მისი შევსება წნევის ქვეშ (იხილეთ აგრეთვე „გაანგარიშების წნევა“, „დაჭირხვნის წნევა“, „მაქსიმალური მუშა წნევა (მანომეტრული წნევა)“ და „საცდელი წნევა“); „შეკეთებული მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“ ნიშნავს ლითონის, მყარი პლასტმასისა თუ რთულ მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერს, რომელიც დარტყმისა თუ ნებისმიერი სხვა მიზეზით (მაგალითად, კოროზიის, სიმყიფისა თუ გამძლეობის შემცირების სხვა ნიშნების გამოვლენის მიზეზით კონსტრუქციის ტიპთან შედარებისას) აღდგება იმისათვის, რომ უპასუხოს კონსტრუქციის ტიპის მოთხოვნებს და შეძლოს კონსტრუქციის ტიპის გამოცდის გავლა. ADR-ის მიზნებთან დაკავშირებით, რთული მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერის მყარი შიდა ჭურჭლის შეცვლა იმ ჭურჭლით, რომელიც შეესაბამება იმავე მწარმოებლის მიერ დადგენილი საწყისი ტიპის კონსტრუქციის მოთხოვნებს, ითვლება შეკეთებად. თუმცა მყარი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების მიმდინარე ტექნიკური უზრუნველყოფა არ ითვლება შეკეთებად. მყარი პლასტმასის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების კორპუსები და რთული მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების შიდა ჭურჭლები არ ექვემდებარება შეკეთებას. დრეკადი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები არ ექვემდებარება შეკეთებას, გარდა კომპეტენტური ორგანოებისგან შესაბამისი ნებართვის მიღების შემთხვევებისა; „შეკეთებული კონტეინერი“; მტსტკ“, იხილეთ „მასიური ტვირთის საშუალო ტვირთამწეობის „შემავსებელი“ ნიშნავს საწარმოს, რომელიც უზრუნველყოფს სახიფათო ტვირთების დატვირთვას ცისტერნაში (ავტოცისტერნაში, სახსნელ ცისტერნაში, გადასატან ცისტერნასა თუ კონტეინერ-ცისტერნაში) და/ან ავტოსატრანსპორტო საშუალებებში, მასიური ტვირთის გადაზიდვისთვის განკუთვნილ დიდ თუ მცირე მოცულობის კონტეინერებში, ან ავტოსატრანსპორტო საშუალება-ბატარეებსა თუ მრავალელემენტიან აირის კონტეინერებში; „შემფუთველი“ ნიშნავს ნებისმიერ საწარმოს, რომელიც უზრუნველყოფს სახიფათო ტვირთების მოთავსებას ტარაში, მათ შორის მსხვილგაბარიტიან ტარასა და მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებში და, საჭიროების შემთხვევაში, მოამზადებს შეფუთვებს გადასაზიდად; „შეფუთვის ჯგუფი“ ნიშნავს ჯგუფს, რომელსაც შეფუთვის მიზნით, შესაძლებელია მიეკუთვნოს გარკვეული ნივთიერებები მათი საშიშროების ხარისხის მიხედვით. შეფუთვის ჯგუფებს გააჩნიათ ქვემოთ გათვალისწინებული მნიშვნელობები, რაც კიდევ უფრო დაწვრილებით არის განმარტებული მე-2 ნაწილში: შეფუთვის ჯგუფი I: მაღალი საშიშროების მქონე ნივთიერებები; შეფუთვის ჯგუფი II: საშუალო საშიშროების მქონე ნივთიერებები; და შეფუთვის ჯგუფი III: დაბალი საშიშროების მქონე ნივთიერებები. შენიშვნა: შეფუთვის ჯგუფს მიეკუთვნება სახიფათო ტვირთების შემცველი გარკვეული ნაკეთობები. 43 „შესაბამისობის უზრუნველყოფა“ (რადიოაქტიური მასალა) ნიშნავს კომპეტენტური ორგანოს მიერ გამოყენებულ სისტემატიური ღონისძიებების პროგრამას, რომლის მიზანია ADR-ის მოთხოვნების დაკმაყოფილება პრაქტიკაში; „შეფუთვა“ ნიშნავს შეფუთვის ოპერაციის დასრულებულ პროდუქტს, რომელიც შედგება გადაზიდვისთვის მომზადებული ტარისგან, მსხვილგაბარიტიანი ტარისგან ან მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერისა და მისი შიგთავსისგან. აღნიშნული ტერმინი ვრცელდება მიმდინარე პუნქტისთვის განსაზღვრული აირების ჭურჭლებზე, ასევე ნაკეთობებზე, რომლებიც, მათი ზომიდან, მასიდან ან კონფიგურაციიდან გამომდინარე, შეიძლება გადაზიდულ იქნეს შეუფუთავი სახით ან ჩარჩოებში, გისოსებსა თუ სატრანსპორტო-გადატვირთვის საშუალებებში. რადიოაქტიური მასალის გადაზიდვის გარდა, აღნიშნული ტერმინი არ ვრცელდება იმ ტვირთებზე, რომელთა გადაზიდვაც ხორციელდება დაყრით, ასევე ცისტერნებით გადაზიდულ ნივთიერებებზე; შენიშვნა: რადიოაქტიურ მასალებთან დაკავშირებით იხილეთ, პუნქტი 2.2.72., ქვეპუნქტი 4.1.9.1.1 და თავი 6.4. „შეფუთვის მასა“ ნიშნავს შეფუთვის ჯამურ მასას, თუ სხვაგვარად არ არის მითითებული. ტვირთების გადასაზიდად განკუთვნილი კონტეინერებისა და ცისტერნების მასა არ არის გათვალისწინებული ჯამურ მასაში; „შიდა ტარა“ ნიშნავს ტარას, რომელიც გადაზიდვისას მოთავსებულია გარე ტარაში; „შიდა ჭურჭელი“ ნიშნავს ჭურჭელს, რომელიც საჭიროებს გარე ტარას მისი პროდუქტების შემცველობის ფუნქციის სისრულეში მოსაყვანად; „შუალედური ტარა“ ნიშნავს შიდა ტარასა თუ ნაკეთობებსა და გარე ტარას შორის განთავსებულ ტარას; ჩ „ჩანაწერი ცისტერნის შესახებ“ ნიშნავს ცისტერნის, ავტოსატრანსპორტო საშუალებაბატარეისა თუ მრავალელემენტიანი აირის კონტეინერის შესახებ მნიშვნელოვანი ინფორმაციის შემცველ ფაილს, როგორიცაა 6.8.2.3, 6.8.2.4 და 6.8.3.4 პუნქტებით გათვალისწინებული სერთიფიკატები; ც „ცდებისა და კრიტერიუმების სახელმძღვანელო“ ნიშნავს გაერთიანებული ერების ორგანიზაციის მიერ გამოცემულ ცდებისა და კრიტერიუმების სახელმძღვანელოს რეკომენდაციებს სახიფათო ტვირთების გადაზიდვების შესახებ, მეხუთე გადასინჯულ გამოცემას (ST/SG/AC.10/11/Rev.5, რომელშიც შეტანილი იქნა შესაბამისი ცვლილებები დოკუმენტებით ST/SG/AC.10/11/Rev.5/Amend.1 და ST/SG/AC.10/11/Rev.5/Amend.2); „ცისტერნა“ ნიშნავს კორპუსს, მისი სერვისული და კონსტრუქციული აღჭურვილობის ჩათვლით. ტერმინის „ცისტერნა“ ცალკე გამოყენების შემთხვევაში, გულისხმობს კონტეინერ-ცისტერნას, გადამზიდ ცისტერნას, სახსნელ ცისტერნასა თუ დამონტაჟებულ ცისტერნას, რომელთა განმარტებაც წარმოდგენილია წინამდებარე ნაწილში, იმ ცისტერნების ჩათვლით, რომლებიც წარმოადგენს ავტოსატრანსპორტო საშუალებაბატარეებისა და მრავალელემენტიანი აირის კონტეინერების ელემენტებს (იხილეთ აგრეთვე „სახსნელი ცისტერნა“, „დამონტაჟებული ცისტერნა“, „გადამზიდი ცისტერნა“ და „მრავალელემენტიანი აირის კონტეინერი“); 44 შენიშვნა: გადამზიდ ცისტერნებთან დაკავშირებით, იხილეთ 6.7.4.1 პუნქტი. „ცხოველური წარმოშობის მასალა“ ნიშნავს დაკლულ ცხოველს, ცხოველის სხეულის ნაწილებსა თუ ცხოველურ საკვებს პროდუქტებს; წ „წვის დანადგარი“ ნიშნავს ხელსაწყოს, რომელიც პირდაპირ იყენებს თხევად ან აირის საწვავს და არ იყენებს ავტოსატრანსპორტო საშუალების მამოძრავებელი ძრავის ნარჩენ სითბოს; „წნევის დოლურა“ ნიშნავს 150 ლიტრზე მეტსა და არაუმეტეს 1000 ლიტრის წყლის მოცულობის შედუღებულ ტრანსპორტირებად წნევის ჭურჭელს (მაგალითად, მბრუნავი რგოლებით, სამუხრუჭე ხუნდებზე სფეროსებრი ჭურჭლით აღჭურვილი ცილინდრული ჭურჭლები); „წნევის ჭურჭელი“ ნიშნავს საერთო ტერმინს, რომელიც მოიცავს ცილინდრებს, მილებს, წნევის დოლურებს, დახურულ კრიოგენულ ჭურჭლებს, ლითონის ჰიდრიდის შესანახ სისტემებს, ცილინდრების შეკვრებსა და ავარიულ წნევის ჭურჭლებს; „წნევის ქვეშ მომუშავე აირის ბალონი“, იხილეთ „აეროზოლი ან აეროზოლური გამფრქვევი“; ჭ „ჭურჭელი“ (პირველი კლასი) ნიშნავს ყუთებს, ბოთლებს, ქილებს, დოლურებს, კანისტრებსა და ცილინდრებს, მათ შორის შიდა და შუალედურ ტარაში გამოყენებული ნებისმიერი ჩამკეტი საშუალების ჩათვლით; „ჭურჭელი“ ნიშნავს ნივთიერებებისა თუ ნაკეთობების, ნებისმიერი დაცობის საშუალების ჩათვლით, მიმღებ და შემაკავებელ ჭურჭელს. აღნიშნული განმარტება არ ვრცელდება კორპუსებზე (იხილეთ აგრეთვე „კრიოგენული ჭურჭელი“, „შიდა ჭურჭელი“, „წნევის ჭურჭელი“, „მყარი შიდა ჭურჭელი“ და „აირის ბალონი“); ხ „ხარისხის უზრუნველყოფა“ ნიშნავს ნებისმიერი ორგანიზაციისა თუ ორგანოს მიერ განხორციელებული კონტროლისა და შემოწმების სისტემატიურ პროგრამას, რომლის მიზანია საკმარისი გარანტიის უზრუნველყოფა იმასთან დაკავშირებით, რომ ADR-ში გათვალისწინებული უსაფრთხოების ნორმები განხორციელებულ იქნა პრაქტიკაში; „ხის კასრი“ ნიშნავს ბუნებრივი ხისგან დამზადებულ ტარას, მრგვალი ფორმის ჯვარედინი ჭრილებითა და ამოზნექილი კედლებით, რომელიც შედგება რგოლებით დამაგრებული გვერდითი ფიცრებისა და ზედა ნაწილისგან; „ხის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“ ნიშნავს ხისტ ან დასაშლელ ხის კორპუსს შიდა შუასადებთან ერთად (თუმცა არა შიდა ტარას) და შესაბამის სერვისულ ან კონსტრუქციულ აღჭურვილობას; „ხისტი მტსტკ-ის რეგულარული ტექნიკური უზრუნველყოფა“, იხილეთ „მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი“; „ხისტი შიდა ჭურჭელი“ (შედგენილი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების შემთხვევაში) ნიშნავს ჭურჭელს, რომელიც ინარჩუნებს მის ჩვეულებრივ 45 ფორმას დაცლისას ჩამკეტებისა და გარე გარსის გამოყენების გარეშე. ნებისმიერი შიდა ჭურჭელი, რომელიც არ წარმოადგენს „ხისტს“ განიხილება, როგორც „დრეკადი“; „ხისტი პლასტმასის მტსტკ“ ნიშნავს ხისტ პლასტმასის კორპუსს, რომელიც შეიძლება აღჭურვილი იყოს კონსტრუქციული აღჭურვილობასთან ერთად; მოწყობილობით სათანადო სერვისულ ჰ „ჰერმეტიზების სისტემა“, რადიოაქტიური მასალის გადაზიდვასთან დაკავშირებით, ნიშნავს დამპროექტებლის მიერ განსაზღვრული შეფუთვის კომპონენტების კრებულს, რაც განკუთვნილია გადაზიდვების დროს რადიოაქტიური მასალის შესაკავებლად; „ჰერმეტულად დახურული ცისტერნა“ ნიშნავს მინიმუმ 4 ბარის საანგარიშო წნევის მქონე თხევადი ნივთიერებების გადასაზიდად განკუთვნილ ცისტერნას ან მყარი (ფხვნილოვანი ან გრანულირებული) ნივთიერებების გადასაზიდად განკუთვნილ ცისტერნას, მიუხედავად მისი საანგარიშო წნევისა, რომლის ნახვრეტები ჰერმეტულად არის დახურული და რომელიც: - არ არის აღჭურვილი უსაფრთხოების სარქველებით, ფეთქებადი მემბრანებით, სხვა ანალოგიური უსაფრთხოების მოწყობილობებითა თუ ვაკუუმური სარქველებით; ან - არ არის აღჭურვილი უსაფრთხოების სარქველებით, ფეთქებადი მემბრანებით ან სხვა ანალოგიური უსაფრთხოების მოწყობილობებით, თუმცა აღჭურვილია ვაკუუმური სარქველებით, 6.8.2.2.3 პუნქტის მოთხოვნების შესაბამისად; - აღჭურვილია უსაფრთხოების სარქველებით, რომლის წინ დაყენებულია ფეთქებადი მემბრანები 6.8.2.2.10 პუნქტის მოთხოვნების შესაბამისად, თუმცა არ არის აღჭურვილი ვაკუუმური სარქველებით; - აღჭურვილია უსაფრთხოების სარქველებით, რომლის წინ დაყენებულია ფეთქებადი მემბრანები 6.8.2.2.10 პუნქტის მოთხოვნების შესაბამისად და ვაკუუმური სარქველებით, 6.8.2.2.3 პუნქტის მოთხოვნების შესაბამისად. 46 1.2.2. საზომი ერთეულები 1.2.1.1 ADR-ში გამოიყენება შემდეგი საზომი ერთეულებია: სიდიდე ერთეულთა სსბ სიგრძე ფართობი მოცულობა დრო მ (მეტრი) მ2 (კვადრატული მეტრი) მ3 (კუბური მეტრი) წმ (წამი) მასა კგ (კილოგრამი) სიმკვრივე ტემპერატურა ტემპერატურის სხვაობა ძალა წნევა კგ/მ3 კ (კელვინი) კ (კელვინი) ნ (ნიუტონი) პა (პასკალი) ძაბვა სამუშაო ენერგია სითბოს ოდენობა სიმძლავრე კინემატიკური სიბლანტე დინამიკური სიბლანტე აქტივობა ეკვივალენტური დოზა ნ/მ2 დასაშვები ალტერნატიული ერთეული ლგ (ლიტრი) წთ (წუთი) სთ (საათი) დღ (დღე) გ (გრამი) ტ (ტონა) კგ/ლ 0C (გრადუსი ცელსიუსი) 0C (გრადუსი ცელსიუსი) ბარი (ბარი) ნ/მმ2 კვტ/სთ (კილოვატ/საათი) ჯ (ჯოული) ევ (ელექტრონვოლტი) მმ2/წთ მპა.წთ ვ (ვატი) მ2/წმ პა.წმ ბკ (ბეკერელი) ზვ (ზივერტი) ურთიერთკავშირი ერთეულებს შორის 1 ლ = 10-3მ3 1 წთ = 60 წმ 1 სთ = 3 600 წმ 1 დღ = 86 400 წმ 1 გ = 10-3კგ 1 ტ = 103კგ 1 კგ/ლ = 103 კგ/მ3 0 0C = 273.15 კ 1 0C = 1 კ 1 ნ = 1 კგ.მ/წმ2 1 პა = 1 ნ/მ2 1 ბარი = 105 პა 1 ნ/მმ2 = 1 მპა 1 კვტ/სთ = 3.6 მჯ 1 ჯ = 1 ნ.მ = 1 ვ.წმ 1 ევ = 0.1602 ჰ 10-18 ჯ 1 ვ = 1 ჯ/წმ = 1 ნ.მ/წმ 1 მმ2/წთ = 10-6 მ2/წთ 1 მპა.წთ = 10-3 პა.წმ ზემოაღნიშნული, სს ერთეულებში გამოყენებული ერთეულების გარდაქმნისთვის გამოიყენება შემდეგი დამრგვალებული მნიშვნელობები: ა ძალა 1 კგ 1ნ = = წნევა 1 პა = 1 ბარი = 1 კგ/სმ2 = 1 თორი = ძაბვა 1 კგ/მმ2 = 1 ნ/მმ2 = 9.807 ნ 0.102 კგ = = = = 1.02 X 10-5 კგ/სმ2 750 თორი 736 თორი 1.36X10-3 კგ/სმ2 ენერგია, სამუშაო, სითბოს რაოდენობა 1ჯ = 1 ნ.მ = 0.278X10-6 კვტ/სთ = 1 კვტ/სთ = 3.6X106 ჯ = 367 X 103 კგ/მ = 1 კგ/მ = 9.807 ჯ = 2.72X10-6 კვტ/სთ = 1 კკალ = 4.19X103 ჯ = 1.16X10-3 კვტ/სთ = 0.102 კგ/მ = 860 კკალ 2.34X10-3 კკალ 427 კგ/მ ძალა 1ვ = 1 კგ/მ/წმ = 1 კკალ/სთ = 1 ნ/მ2 105 პა 9.807 X 104 პა 1.33X102 პა 0.102 კგ/მ/წმ 9.807 ვ 1.16 ვ = = = = = = = 10-5 ბარი 1.02 კგ/სმ2 0.9807 ბარი 1.33X10-3 ბარი 9.807 ნ/მმ2 0.102 კგ/მმ2 = 0.75X10-2 თორი 0.239X10-3 კკალ კინემატიკური სიბლანტე 1 მ2/წმ = 104 სტ (სტოკი) 1 სტ = 10-4 მ2/წმ 0.86 კკალ/სთ 8.43 კკალ/სთ 0.119 კგ/მ/წმ 47 დინამიკური სიბლანტე 1 პა.წმ = 1 ნ.წმ/მ2 1პ = 0.1 პა.წმ 1 კგ.წმ/მ2 = 9.807 პა.წმ = = = 10 პ (პუაზი) 0.1 ნ.წმ/მ2 9.807ნ.წმ/მ2 = = = 0.102 კგ.წმ/მ2 1.02X10-2 კგ.წმ/მ2 98.07 პ ერთეულთა საერთაშორისო სისტემა (სს) წარმოადგენს წონისა და ზომის შესახებ გენერალურ კონფერენციაზე მიღებული გადაწყვეტილების შედეგს (მისამართი: სერვი 310 F-92, სენტ-კლოდის პარკი, ბრეტუის პავილიონი). გ ლიტრებთან დაკავშირებული აბრევიატურა „L“ შესაძლებელია აგრეთვე გამოყენებულ იქნეს „l“ აბრევიატურის სანაცვლოდ, როდესაც მბეჭდავს არ შეუძლია გაარჩიოს ციფრი „1“ და ასო „l“ ერთმანეთისგან. ბ ათწილადი ჯერადი და წილადი ერთეულები შესაძლებელია ჩამოყალიბებულ იქნეს შემდეგი მნიშვნელობის მქონე პრეფიქსებითა და სიმბოლოებით, რომელიც მოთავსდება ერთეულის დასახელების ან სიმბოლოს წინ: ფაქტორი 1 000 000 000 000 000 000 1 000 000 000 000 000 1 000 000 000 000 1 000 000 000 1 000 000 1 000 100 10 0.1 0.01 0.001 0.000 001 0.000 000 001 0.000 000 000 001 0.000 000 000 000 001 0.000 000 000 000 000 001 = 1018 = 1015 = 1012 = 109 = 106 = 103 = 102 = 101 = 10-1 = 10-2 = 10-3 = 10-6 = 10-9 = 10-12 = 10-15 = 10-18 კვინტილიონი კვადრილიონი ტრილიონი მილიარდი მილიონი ათასი ასი ათი მეათედი მეასედი მეათასედი მემილიონედი მემილიარდედი მეტრილიონედი კვადრილიონედი კვინტილიონედი პრეფიქსი სიმბოლო ექსა პეტა ტერა გიგა მეგა კილო ჰექტო დეკა დეცი ცენტი მილი მიკრო ნანო პიკო ფემტო ატტო E P T G M k h da d c m μ n p f a შენიშვნა: 109 მილიარდი გაერთიანებული ერების ორგანიზაციაში შემავალ ქვეყნებში გამოიყენება ინგლისურად. ანალოგიურად, 10-9 = 1 მემილიარდედი. 1.2.2.2 თუ კონკრეტულად არ არის მითითებული სხვაგვარად, ADR-ში სიმბოლო „%“ წარმოადგენს: (ა) მყარი ნივთიერებებისა თუ სითხეების ნარევების შემთხვევაში, ასევე ხსნარებისა და სითხეში დასველებული მყარი ნივთიერებების შემთხვევაში, პროცენტული მასა გამოითვლება ნარევის, ხსნარისა თუ დასველებული მყარი მასალების საერთო მასიდან; (ბ) შეკუმშული აირების შემთხვევაში, წნევის ქვეშ დატვირთვისას - აიროვანი ნარევის საერთო მოცულობის პროცენტულობის სახით მითითებული მოცულობის 48 პროცენტული წილი, ან, დაყრით დატვირთვის შემთხვევაში - ნარევის საერთო მასის საფუძველზე გაანგარიშებული მასის პროცენტული წილი; (გ) თხევადი აირებისა და გახსნილი აირების ნარევის შემთხვევაში - ნარევის საერთო მასის საფუძველზე გაანგარიშებული მასის პროცენტული წილი. 1.2.2.3 ჭურჭელთან დაკავშირებული ყველა სახის წნევა (როგორიცაა საცდელი წნევა, შიგა წნევა, უსაფრთხოების სარქველის მოხსნის წნევა) ყოველთვის მითითებულია, როგორც მანომეტრული წნევა (წნევა, რომელიც აღემატება ატმოსფერულ წნევას); თუმცა ნივთიერებების ორთქლის წნევა ყოველთვის გამოხატულია აბსოლუტური წნევის სახით. 1.2.2.4 იმ შემთხვევაში, თუ ADR-ში გათვალისწინებულია ჭურჭლის შევსების ხარისხი, აღნიშნული ყოველთვის უკავშირდება ნივთიერებების 150C სტანდარტულ ტემპერატურას, თუ რაიმე სხვა ტემპერატურა არ არის მითითებული. 49 თავი 1.3 სახიფათო ტვირთების გადაზიდვებში მონაწილე პირების მომზადება 1.3.1 მოქმედების არეალი და გამოყენებადობა 1.4 თავში გათვალისწინებული გადაზიდვების მონაწილეებთან დასაქმებული პირები, რომელთა მოვალეობებიც დაკავშირებულია სახიფათო ტვირთების გადაზიდვებთან, გაივლიან მომზადებას აღნიშნული სახის ტვირთების მარეგულირებელ მოთხოვნებთან დაკავშირებით მათი პასუხისმგებლობებისა და მოვალეობების შესაბამისად. მუშაკების მომზადება მოხდება 1.3.2 პუნქტის შესაბამისად, საკუთარ თავზე პასუხისმგებლობების აღებამდე და სისრულეში მოიყვანენ მათზე დაკისრებულ ფუნქციებს, თუ მომზადება ჯერ არ განხორციელებულა, მხოლოდ კარგად მომზადებული პირის უშუალო მეთვალყურეობის ქვეშ. აღნიშნული მომზადება ასევე უნდა მოიცავდეს 1.10 თავში გათვალისწინებულ სპეციალურ მოთხოვნებს სახიფათო ტვირთების უსაფრთხო გადაზიდვების უზრუნველყოფის შესახებ. შენიშვნა 1: უსაფრთხოების საკითხებში კონსულტანტის მომზადებასთან დაკავშირებით იხილეთ 1.8.3 პუნქტი, ნაცვლად წინამდებარე ნაწილისა. შენიშვნა 2: ავტოსატრანსპორტო საშუალებების ეკიპაჟის მომზადებასთან დაკავშირებით იხილეთ 8.2 პუნქტი, ნაცვლად წინამდებარე ნაწილისა. შენიშვნა 3: მე-7 კლასით გათვალისწინებული მუშაკების მომზადებასთან დაკავშირებით იხილეთ 1.7.2.5 პუნქტი. 1.3.2 მომზადების ხასიათი მომზადება უნდა განხორციელდეს შემდეგი პასუხისმგებლობისა და მოვალეობების შესაბამისად. 1.3.2.1 ფორმით, შესაბამისი პირების ზოგადსაინფორმაციო ხასიათის მომზადება პერსონალმა უნდა გაიაროს მომზადება სახიფათო ტვირთების გადაზიდვებთან დაკავშირებული წესებით გათვალისწინებული მოთხოვნების შესაბამისად, უშუალოდ მათი ვალდებულებებისა და პასუხისმგელობების მიხედვით. იმ შემთხვევაში, თუ სახიფათო ტვირთების გადაზიდვა დაკავშირებულია სხვადასხვა სატრანსპორტო ოპერაციასთან, პერსონალი კარგად უნდა იცნობდეს ტრანსპორტის სხვა სახეებთან დაკავშირებულ მოთხოვნებს. 1.3.2.3 მომზადება უსაფრთხოების საკითხებში ტრავმის მიღებისა თუ სახიფათო ზემოქმედების რისკის ხარისხის გათვალისწინებით, რაც შეიძლება წარმოიშვას სახიფათო ტვირთების გადაზიდვებთან დაკავშირებით, ჩატვირთვა-გადმოტვირთვის ოპერაციების დროს, პერსონალმა უნდა გაიაროს მომზადება სახიფათო ტვირთების მიერ წარმოდგენილ საფრთხეებსა და საშიშროებებთან დაკავშირებით. მომზადების მიზანი უნდა იყოს პერსონალის შემეცნების ამაღლება სახიფათო ტვირთების უსაფრთხო დამუშავებასა და გადაუდებელი ზომების მიღებასთან დაკავშირებით. 50 1.3.2.4 აღნიშნულ მომზადებას პერიოდულად უნდა დაემატოს განხორციელებული ცვლილებების გაზიარების მიზნით. 1.3.3 დოკუმენტაცია გადამზადება წესებში დამსაქმებელმა უნდა აწარმოოს ჩანაწერები წინამდებარე თავით გათვალისწინებული დებულებების შესაბამისად ჩატარებული მომზადების შესახებ, რომელიც გათვალისწინებულია მუშაკებისა თუ კომპეტენტური ორგანოებისთვის, მათი მოთხოვნისამებრ. აღნიშნული ჩანაწერები უნდა ინახებოდეს დამსაქმებლის მიერ კომპეტენტური ორგანოს მიერ განსაზღვრული ხანგრძლივობით. მომზადების მიღების შესახებ ჩანაწერები მოწმდება ყოველი ახალი სამუშაოს დაწყებისას. 51 თავი 1.4 გადაზიდვების მონაწილეების ვალდებულებები უსაფრთხოებასთან დაკავშირებით 1.4.1 უსაფრთხოების საერთო ზომები 1.4.1.1 სახიფათო ტვირთების გადაზიდვის ოპერაციებში მონაწილე პირებმა უნდა მიმართონ შესაბამის ზომებს, სავარაუდო საშიშროებების ხასიათიდან და მასშტაბურობიდან გამომდინარე, რათა თავიდან აიცილონ დაზიანება თუ ტრავმები და, აუცილებლობის შემთხვევაში, მინიმუმამდე შეამცირონ მათი ზემოქმედება. ნებისმიერ შემთხვევაში, მათ უნდა დააკმაყოფილონ ADR-ის მოთხოვნები მათი შესაბამისი მოქმედების არეალში. 1.4.1.2 იმ შემთხვევაში, თუ საზოგადოებრივ უსაფრთხოებას პირდაპირი საფრთხე ემუქრება, გადაზიდვების მონაწილეებმა დაუყოვნებლივ უნდა აცნობონ საავარიო-სამაშველო სამსახურებს და მიაწოდონ მათ შესაბამისი ზომების განსახორციელებლად აუცილებელი ინფორმაცია. 1.4.1.3 ADR-ში შესაძლებელია გათვალისწინებლი იყოს გადაზიდვების სხვადასხვა მონაწილის ზოგიერთი ვალდებულება. იმ შემთხვევაში, თუ ხელშემკვრელი მხარე მიიჩნევს, რომ აღნიშნული არ უზრუნველყოფს უსაფრთხოების დაცვას, მას შეუძლია, საკუთარი ეროვნული კანონმდებლობის ფარგლებში, გადასცეს რომელიმე კონკრეტულ მონაწილეზე განსაზღვრული ვალდებულებები ერთ ან რამდენიმე სხვა მონაწილეს, 1.4.2 და 1.4.3 პუნქტებით გათვალისწინებული ვალდებულებების შესრულების პირობით. ხელშემკვრელმა მხარემ უნდა აცნობოს აღნიშნული გადახვევები გაერთიანებული ერების ორგანიზაციის ევროპული ეკონომიკური კომისიის სამდივნოს, რომელიც, თავის მხრივ, შეატყობინებს სხვა ხელშემკვრელ მხარეებს. 1.2.1, 1.4.2 და 1.4.3 პუნქტებით გათვალისწინებული მოთხოვნები გადაზიდვების მონაწილეებისა და მათი შესაბამისი ვალდებულებების განმარტებასთან დაკავშირებით, არ მოახდენს არავითარ გავლენას იურიდიული შედეგების (სისხლის სამართლის, პასუხისმგებლობისა და ა.შ.) შესახებ ეროვნული კანონმდებლობის დებულებებზე, რაც წარმოიშვება იმ ფაქტიდან, რომ შესაბამისი მონაწილე წარმოადგენს, მაგალითად, იურიდიულ პირს, თვითდასაქმებულ მუშაკს, დამსაქმებელსა თუ დასაქმებულს. 1.4.2 ძირითადი მონაწილეების ვალდებულებები შენიშვნა 1: გადაზიდვების ზოგიერთი მონაწილე, რომელსაც წინამდებარე პუნქტის თანახმად მინიჭებული აქვს უსაფრთხოებასთან დაკავშირებული ვალდებულებები, შეიძლება იყოს ერთი და იგივე საწარმო. მეორეს მხრივ, ამა თუ იმ მონაწილის საქმიანობა და უსაფრთხოებასთან დაკავშირებული შესაბამისი დებულებები შესაძლებელია შესრულდეს რამდენიმე საწარმოს მიერ. შენიშვნა 2: რადიოაქტიურ მასალებთან დაკავშირებით, იხილეთ აგრეთვე 1.7.6 პუნქტი. 1.4.2.1 ტვირთგამგზავნი 1.4.2.1.1 სახიფათო ტვირთების გამგზავნი ვალდებულია, რომ გასაგზავნად წარმოადგინოს მხოლოდ ის ტვირთები, რომლებიც აკმაყოფილებს ADR-ის მოთხოვნებს. კონკრეტულად, 1.4.1 პუნქტის კონტექსტიდან გამომდინარე, ის უნდა: 52 (ა) დარწმუნდეს, რომ სახიფათო ტვირთები კლასიფიცირებული და დაშვებულია გადაზიდვებზე ADR-ის შესაბამისად; (ბ) გადამზიდველს მიაწოდოს ინფორმაცია და მონაცემები და, საჭიროების შემთხვევაში, აუცილებელი სატრანსპორტო დოკუმენტაცია და თანდართული დოკუმენტები (ნებართვები, დასტურები, უწყებები, სერთიფიკატები და ა.შ.) კონკრეტულად 5.4 თავისა და მე-3 ნაწილში წარმოდგენილი ცხრილების მოთხოვნების გათვალისწინებით; (გ) გამოიყენოს მხოლოდ ის ტარა, მსხვილგაბარიტიანი ტარა, მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები და ცისტერნები (ავტოცისტერნები, სახსნელი ცისტერნები, ავტოსატრანსპორტო საშუალება-ბატარეები, მრავალელემენტიანი აირის კონტეინერები, გადამზიდი ცისტერნები და კონტეინერ-ცისტერნები), რომლებიც დაშვებული და გათვალისწინებულია შესაბამისი ნივთიერებების გადასაზიდად და გააჩნია ADR-ში მითითებული მარკირება; (დ) აკმაყოფილებდეს გაგზავნის საშუალებებსა და გაგზავნასთან დაკავშირებით არსებული შეზღუდვების პირობებს; (ე) უზრუნველყოს, რომ ცარიელი, გაუსუფთავებელი და არადეგაზირებული ცისტერნებიც კი (ავტოცისტერნები, სახსნელი ცისტერნები, ავტოსატრანსპორტო საშუალება-ბატარეები, მრავალელემენტიანი აირის კონტეინერები, გადამზიდი ცისტერნები და კონტეინერ-ცისტერნები) ან ცარიელი, გაუსუფთავებელი ავტოსატრანსპორტო საშუალებები და მასიური ტვირთის დიდი და მცირე მოცულობის კონტეინერები იყოს შესაბამისად აღნიშნული და მარკირებული უსაფრთხოების ნიშნებით და რომ დახურული გაუსუფთავებელი ცისტერნები დაიხუროს და მათში დაცული იქნეს იგივე ჰერმეტულობა, როგორც მათი სისავსის შემთხვევაში. 1.4.2.1.2 იმ შემთხვევაში, თუ ტვირთგამგზავნი სარგებლობს გადაზიდვების სხვა მონაწილის (შემფუთველის, მტვირთავის, შემავსებლის და ა.შ.) მომსახურებებით, მან უნდა მიმართოს შესაბამის ზომებს, რათა უზრუნველყოს ტვირთის შესაბამისობა ADR-ის მოთხოვნებთან. თუმცა 1.4.2.1.1 პუნქტის (ა), (ბ), (გ) და (ე) ქვეპუნქტებით გათვალისწინებულ შემთხვევებში, მას შეუძლია დაეყრდნოს გადაზიდვების სხვა მონაწილეების მიერ მისთვის გაზიარებულ ყველანაირ ინფორმაციასა და მონაცემებს. 1.4.2.1.3 იმ შემთხვევაში, თუ ტვირთგამგზავნი მოქმედებს მესამე მხარის სახლით, ამ უკანასკნელმა უნდა აცნობოს წერილობითი ფორმით ტვირთგამგზავნს, რომ საქმე ეხება სახიფათო ტვირთებს და მიაწოდოს მას ყველანაირი ინფორმაცია და დოკუმენტი, რაც აუცილებელია მის მიერ ნაკისრი ვალდებულებების სისრულეში მოსაყვანად. 1.4.2.2 გადამზიდველი 1.4.2.2.1 1.4.1 პუნქტის კონტექსტიდან გამომდინარე, შესაბამის შემთხვევებში, გადამზიდველი უნდა: (ა) დარწმუნდეს, რომ გადასაზიდი სახიფათო ტვირთები დაშვებულია გადაზიდვებზე ADR-ის შესაბამისად; (ბ) დარწმუნდეს, რომ ADR-ში გათვალისწინებული ყოველგვარი ინფორმაცია გადასაზიდ სახიფათო ტვირთებთან დაკავშირებით, წარმოდგენილ იქნა 53 ტვირთგამგზავნის მიერ გადაზიდვამდე, რომ სატრანსპორტო ერთეულზე წარმოდგენილია აუცილებელი დოკუმენტაცია, ხოლო იმ შემთხვევაში, თუ ქაღალდზე შესრულებული დოკუმენტაციის სანაცვლოდ გამოიყენება მონაცემთა ელექტრონული დამუშავების მეთოდი ან ინფორმაციის ელექტრონული გაცვლის მეთოდი, გადაზიდვის დროს აღნიშნული მონაცემები ხელმისაწვდომი უნდა იყოს მინიმუმ ქაღალდზე შესრულებული დოკუმენტაციის ეკვივალენტური სახით; (გ) ვიზუალურად დარწმუნდეს, რომ ავტოსატრანსპორტო საშუალებებსა და ტვირთებს არ აღენიშნებათ რაიმე ხილული ხარვეზი, არ ჟონავს ან არ აღენიშნებათ ნახვრეტები, ასევე არ აკლიათ რაიმე მოწყობილობა და ა.შ. (დ) დარწმუნდეს, რომ ავტოცისტერნების, ავტოსატრანსპორტო საშუალება-ბატარეების, სახსნელი ცისტერნების, გადამზიდი ცისტერნების, კონტეინერ-ცისტერნებისა თუ მრავალელემენტიანი აირის კონტეინერების მომდევნო გამოცდის ვადა არ არის ამოწურული; შენიშვნა: თუმცა ცისტერნების, ავტოსატრანსპორტო საშუალება-ბატარეებისა და მრავალელემენტიანი აირის კონტეინერების გადაზიდვა დაშვებულია აღნიშნული ვადის ამოწურვის შემდეგაც 4.1.6.10 პუნქტში (იმ შემთხვევაში, თუ ავტოსატრანსპორტო საშუალება-ბატარეები და მრავალელემენტიანი აირის კონტეინერები შეიცავს წნევის ჭურჭელს ელემენტების სახით), 4.2.4.4, 4.3.2.4.4, 6.7.2.19.6, 6.7.3.15 ან 6.7.4.14.6 პუნქტებში გათვალისწინებული პირობების თანახმად. (ე) შეამოწმოს, ავტოსატრანსპორტო საშუალებები გადატვირთული ხომ არ არის; (ვ) დარწმუნდეს, რომ ავტოსატრანსპორტო საშუალებებზე განთავსებულია შესაბამისი საინფორმაციო ტაბლოები და აღნიშვნები; (ზ) დარწმუნდეს, რომ მძღოლის წერილობით ინსტრუქტაჟში გათვალისწინებული მოწყობილობები იმყოფება ავტოსატრანსპორტო საშუალებაში. სათანადო შემთხვევებში, აღნიშნული ღონისძიებები ხორციელდება სატრანსპორტო დოკუმენტებისა და თანხლები დოკუმენტების საფუძველზე, ავტოსატრანსპორტო საშუალების ან კონტეინერებისა და, საჭიროების შემთხვევაში, ტვირთის ვიზუალური დათვალიერების გზით. 1.4.2.2.2 1.4.2.2.1 პუნქტის (ა), (ბ), (ე) და (ვ) ქვეპუნქტებით გათვალისწინებულ შემთხვევებში, გადამზიდველს შეუძლია დაეყრდნოს გადაზიდვის სხვა მონაწილეების მიერ მიწოდებულ ინფორმაციასა და მონაცემებს. 1.4.2.2.3 იმ შემთხვევაში, თუ 1.4.2.2.1 პუნქტის შესაბამისად მოქმედებისას, გადამზიდველი გამოავლენს ADR-ის მოთხოვნების რაიმე სახით დარღვევას, მან არ უნდა მოახდინოს ტვირთის გაგზავნა მანამ, სანამ აღნიშნული დარღვევები არ იქნება აღმოფხვრილი. 1.4.2.2.4 იმ შემთხვევაში, თუ გადაზიდვების განმავლობაში თავს იჩენს ისეთი დარღვევა, რომელმაც შეიძლება საფრთხე შეუქმნას გადაზიდვის უსაფრთხოებას, ტვირთის გადაზიდვა უნდა შეჩერდეს შეძლებისდაგვარად სწრაფად მოძრაობის უსაფრთხოებასთან, ტვირთის უსაფრთხო შეჩერებასა და საზოგადოებრივ უსაფრთხოებასთან დაკავშირებული მოთხოვნების გათვალისწინებით. გადაზიდვის ოპერაცია შესაძლებელია გაგრძელდეს მხოლოდ ტვირთის მოქმედ წესებთან შესაბამისობაში მოყვანის შემდეგ. რეისის დანარჩენ ნაწილზე პასუხისმგებელ 54 კომპეტენტურ ორგანო(ებ)ს შეუძლია(თ) გასცენ ნებართვა სატრანსპორტო ოპერაციის გაგრძელებასთან დაკავშირებით. იმ შემთხვევაში, თუ შეუძლებელია მოთხოვნილი შესაბამისობის უზრუნველყოფა და რეისის დანარჩენ ნაწილზე ნებართვა არ არის გაცემული, კომპეტენტურმა ორგანომ (ორგანოებმა) უნდა აღმოუჩინოს (აღმოუჩინონ) საჭირო ადმინისტრაციული დახმარება გადამზიდველს. იგივე პირობა მოქმედებს იმ შემთხვევაში, თუ გადამზიდველი აუწყებს აღნიშნულ კომპეტენტურ ორგანო(ებ)ს იმის შესახებ, რომ იგი არ ყოფილა გაფრთხილებული ტვირთების სახიფათო თვისებების შესახებ ტვირთგამგზავნის მიერ და რომ, კონკრეტულად გადაზიდვების შესახებ ხელშეკრულებაში გათვალისწინებული კანონმდებლობის საფუძველზე, მას სურს აღნიშნული ტვირთის გადმოტვირთვა, განადგურება ან გაუვნებელყოფა. 1.4.2.2.5 (რეზერვირებულია). 1.4.2.3 ტვირთმიმღები 1.4.2.3.1 ტვირთმიმღები ვალდებულია არ შეაჩეროს ტვირთების მიღება საპატიო მიზეზების გარეშე და გადმოტვირთვის შემდეგ შეამოწმოს ის ფაქტი, რომ ტვირთთან დაკავშირებული ADR-ის მოთხოვნები შესრულებულ იქნა. 1.4.2.3.2 თუ, კონტეინერის შემთხვევაში, აღნიშნული შემოწმების შედეგად გამოვლინდება ADRის მოთხოვნების რაიმე დარღვევა, ტვირთმიმღებმა უნდა დაუბრუნოს კონტეინერი გადამზიდველს აღნიშნული დარღვევის აღმოფხვრის შემდეგ. 1.4.2.3.3 იმ შემთხვევაში, თუ ტვირთგამგზავნი მიმართავს გადაზიდვის სხვა მონაწილეების (გადმომტვირთავის, მწმენდავის, დასნებოვნების პრევენციის ობიექტისა და ა.შ.) მომსახურებებს, მან უნდა მიმართოს შესაბამის ზომებს ADR-ის 1.4.2.3.1 და 1.4.2.3.2 პუნქტებით გათვალისწინებული მოთხოვნების შესრულების უზრუნველყოფის მიზნით. 1.4.3 სხვა მონაწილეების ვალდებულებები ქვემოთ წარმოდგენილია გადაზიდვების სხვა მონაწილეების და მათზე განსაზღვრული ვალდებულებების არასრული ჩამონათვალი. გადაზიდვების აღნიშნული მონაწილეების ვალდებულებები გამომდინარეობს წინამდებარე 1.4.1 პუნქტიდან, ვინაიდან მათთვის ცნობილია ან უნდა ყოფილიყო ცნობილი იმ ფაქტის შესახებ, რომ მათი მოვალეობები სრულდება ADR-ის მიერ რეგლამენტირებული სატრანსპორტო ოპერაციის სახით. 1.4.3.1 მტვირთავი 1.4.3.1.1 1.4.1 პუნქტის მოვალეობებს: კონტექსტიდან გამომდინარე, მტვირთავი ასრულებს შემდეგ (ა) მან უნდა გადასცეს შეფუთული სახიფათო ტვირთი გადასაზიდად გადამზიდველს მხოლოდ იმ შემთხვევაში, თუ ისინი გადაზიდვებზე დაშვებულია ADR-ის შესაბამისად; (ბ) შეფუთული სახიფათო ტვირთებისა თუ ცარიელი, გაუსუფთავებელი ტარის გადასაზიდად გადაცემისას, მან უნდა შეამოწმოს დაზიანებულია თუ არა აღნიშნული ტარა. მან არ უნდა გადასცეს გადასაზიდად ის შეფუთვა, რომლის ტარაც დაზიანებულია, განსაკუთრებით არაჰერმეტული ტარა, საიდანაც ხდება ან შეიძლება მოხდეს სახიფათო ნივთიერებების გაჟონვა, სანამ არ აღმოიფხვრება 55 აღნიშნული დაზიანება; ეს ვალდებულება გაუსუფთავებელ ტარასთან დაკავშირებით; აგრეთვე მოქმედებს ცარიელ, (გ) სახიფათო ტვირთის ავტოსატრანსპორტო საშუალებასა თუ დიდი ან მცირე მოცულობის კონტეინერებში დატვირთვისას, მან უნდა იმოქმედოს ტვირთების დატვირთვასა და დამუშავებასთან დაკავშირებით მოქმედი სპეციალური მოთხოვნების შესაბამისად; (დ) სახიფათო ტვირთების კონტეინერებში დატვირთვის შემდეგ, მან უნდა შეასრულოს უსაფრთხოების ნიშნის მითითებასთან დაკავშირებული მოთხოვნები 5.3 თავის შესაბამისად; (ე) შეფუთვების დატვირთვისას მან უნდა დაიცვას კომბინირებულ დატვირთვასთან დაკავშირებული აკრძალვები ავტოსატრანსპორტო საშუალებასა თუ დიდი მოცულობის კონტეინერში უკვე ჩატვირთული სახიფათო ტვირთებისა და საკვები პროდუქტების, მოხმარების სხვა საგნებისა თუ ცხოველების საკვები პროდუქტების განცალკევებასთან დაკავშირებული მოთხოვნების გათვალისწინებით. 1.4.3.1.2 1.4.3.1.1 პუნქტის (ა), (დ) და (ე) ქვეპუნქტებით გათვალისწინებულ შემთხვევებში, მტვირთავს შეუძლია იმოქმედოს გადაზიდვის სხვა მონაწილეების მიერ მისთვის მიწოდებული ინფორმაციის და მონაცემების საფუძველზე. 1.4.3.2 შემფუთველი 1.4.1 კარის კონტექსტის თანახმად, შემფუთველმა უნდა დააკმაყოფილოს: 1.4.3.3. (ა) შეფუთვისა თუ შერეული შეფუთვის პირობებთან დაკავშირებული მოთხოვნები; და (ბ) გადაზიდვებისთვის შეფუთვების მომზადებისას - შეფუთვების მარკირებისა და უსაფრთხოების ნიშნების მითითების მოთხოვნები. შემავსებელი 1.4.1 პუნქტის კონტექსტიდან ვალდებულებები, კერძოდ: გამომდინარე, შემავსებელს ეკისრება შემდეგი (ა) ცისტერნების შევსებამდე ის უნდა დარწმუნდეს იმაში, რომ როგორც ცისტერნები, ასევე მისი აღჭურვილობა იმყოფება ტექნიკურად დამაკმაყოფილებელ მდგომარეობაში; (ბ) ის უნდა დარწმუნდეს, რომ ავტოცისტერნების, ავტოსატრანსპორტო საშუალებაბატარეების, სახსნელი ცისტერნების, გადამზიდი ცისტერნების, კონტეინერცისტერნებისა თუ მრავალელემენტიანი აირის კონტეინერების მომდევნო გამოცდის ვადა არ არის ამოწურული; (გ) მან უნდა შეავსოს ცისტერნები მხოლოდ იმ სახიფათო ტვირთებით, რომლებიც დაშვებულია აღნიშნულ ცისტერნებში გადასაზიდად; (დ) ცისტერნების შევსებისას, მან უნდა დააკმაყოფილოს მომიჯნავე განყოფილებებში განთავსებულ სახიფათო ტვირთებთან დაკავშირებული მოთხოვნები; (ე) ცისტერნების შევსებისას, მან უნდა დაიცვას შევსების მაქსიმალურად დასაშვები დონე ან შიგთავსის მაქსიმალურად დასაშვები მასა მოცულობის ყოველ ლიტრზე შესავსებ ნივთიერებასთან დაკავშირებით; 56 (ვ) ცისტერნის შევსების შემდეგ მან უნდა შეამოწმოს ჩამკეტი მოწყობილობების ჰერმეტულობა; (ზ) მან უნდა უზრუნველყოს, რომ მის მიერ შევსებული ცისტერნების გარე ზედაპირზე არ დარჩეს შემავსებელი ნივთიერებების რაიმე სახიფათო ნარჩენი; (თ) სახიფათო ტვირთების გადაზიდვებისთვის მომზადებისას, მან უნდა უზრუნველყოს, რომ ცისტერნებზე, ავტოსატრანსპორტო საშუალებებსა და მასიური ტვირთის გადასაზიდად განკუთვნილ დიდი და მცირე მოცულობის კონტეინერებზე განთავსებული იყოს შესაბამისი ნარინჯისფერო ტაბლოები, უსაფრთხოების ნიშნები ან საინფორმაციო ტაბლოები, ასევე ტემპერატურის მატების მიმართ მგრძნობიარე ნივთიერებებისა და გარემოსთვის სახიფათო ნივთერებების აღნიშვნები, არსებული მოთხოვნების შესაბამისად; 1.4.3.4 (ი) (რეზერვირებულია); (კ) ავტოსატრანსპორტო საშუალებებისა თუ კონტეინერების მასიური სახიფათო ტვირთებით შევსებისას, ის უნდა დარწმუნდეს, რომ 7.3 თავით გათვალისწინებული შესაბამისი დებულებები შესრულებულია. კონტეინერ-ცისტერნის/გადამზიდი ცისტერნის ოპერატორი 1.4.1 პუნქტის კონტექსტიდან ცისტერნის ოპერატორმა უნდა: კონტეინერ-ცისტერნის/გადამზიდი (ა) უზრუნველყოს კონსტრუქციასთან, აღჭურვილობასთან, გამოცდებსა მარკირებასთან დაკავშირებულ მოთხოვნებთან შესაბამისობის დაცვა; (ბ) მოახდინოს კორპუსებისა და მათი აღჭურვილობის ტექნიკური უზრუნველყოფა იმ სახით, რომ კონტეინერ-ცისტერნების/გადამზიდი ცისტერნების ნორმალური საექსპლუატაციო პირობები აკმაყოფილებდეს ADR-ის მოთხოვნებს მათ მომდევნო შემოწმებამდე; (გ) განახორციელოს დაუგეგმავი შემოწმება იმ შემთხვევაში, თუ კორპუსისა თუ მისი აღჭურვილობის უსაფრთხოება შესაძლებელია დაირღვეს შეკეთების, შეცვლისა თუ ავარიის შედეგად. 1.4.3.5 და 1.4.3.6 1.4.3.7 გამომდინარე, და (რეზერვირებულია). გადმომტვირთველი შენიშვნა: წინამდებარე პუნქტში ტერმინი „გადმოტვირთვა“ გულისხმობს ტვირთების მოხსნას, გადმოტვირთვასა და დაცლას 1.2.1 პუნქტში გათვალისწინებული ტერმინის „გადმომტვირთველი“ - განმარტების შესაბამისად. 1.4.3.7.1 1.4.1 პუნქტის კონტექსტიდან გამომდინარე, გადმომტვირთველი უნდა: (ა) დარწმუნდეს, რომ სრულდება სათანადო ტვირთის გადმოტვირთვა სატრანსპორტო დოკუმენტში გათვალისწინებული შესაბამისი ინფორმაციის შეფუთვაზე, კონტეინერზე, ცისტერნაზე, ფეთქებადი ნივთიერებების მობილურ დანადგარზე, მრავალელემენტიან აირის კონტეინერსა თუ სატრანსპორტო საშუალებაზე მითითებულ ინფორმაციასთან შედარების გზით; (ბ) გადმოტვირთვამდე ან მის განმავლობაში, შეამოწმოს აღენიშნება თუ არა ტარას, ცისტერნას, ავტოსატრანსპორტო საშუალებასა თუ კონტეინერს ისეთი დაზიანება, 57 რომელმაც შეიძლება საფრთხე შეუქმნას გადმოტვირთვის ოპერაციას. აღნიშნულ შემთხვევაში, დარწმუნდეს, რომ გადმოტვირთვა არ განხორციელდება შესაბამისი ზომების სისრულეში მოყვანამდე; (გ) შეასრულოს გადმოტვირთვასთან დაკავშირებული შესაბამისი მოთხოვნები; (დ) ცისტერნის, ავტოსატრანსპორტო გადმოტვირთვისთანავე: (i) საშუალებისა თუ კონტეინერის მოაშოროს ნებისმიერი სახიფათო ნარჩენი, რომელიც შეიძლება დარჩეს ცისტერნის, ავტოსატრანსპორტო საშუალებისა თუ კონტეინერის გარე ზედაპირზე გადმოტვირთვის პროცესის განმავლობაში; და (ii) უზრუნველყოს სარქველებისა და შესამოწმებელი ნახვრეტების დახურვა; (ე) უზრუნველყოს ავტოსატრანსპორტო საშუალებებისა თუ სათანადოდ გასუფთავება და ნარჩენების გაუვნებელყოფა; და კონტეინერების (ვ) უზრუნველყოს, რომ კონტეინერების სრულად გადმოტვირთვის, გაწმენდისა და გაუვნებელყოფის შემდეგ, მათზე აღარ იქნეს მითითებული უსაფრთხოების ნიშნები 5.3 თავის შესაბამისად. 1.4.3.7.2 იმ შემთხვევაში, თუ გადმომტვირთველი მიმართავს გადაზიდვების სხვა მონაწილეების (მწმენდავების, გაუვნებელყოფის ობიექტებისა და ა.შ.) მომსახურებებს, მან უნდა მიიღოს შესაბამისი ზომები, რათა უზრუნველყოს ADR-ის მოთხოვნების სრული დაცვა. 58 თავი 1.5 გადახვევები დადგენილი წესებიდან 1.5.1 დროებითი გადახვევები დადგენილი წესებიდან 1.5.1.1 ADR-ის მე-4 მუხლის მე-3 პუნქტის თანახმად, ხელშემკვრელი მხარეების კომპეტენტური ორგანოები შეიძლება შეთანხმდნენ უშუალოდ ერთმანეთთან, რომ დაუშვან გარკვეული სატრანსპორტო ოპერაციების განხორციელება საკუთარ ტერიტორიებზე ADR-ის მოთხოვნებიდან დროებითი გადახვევის საფუძველზე იმ პირობით, რომ აღნიშნული მოქმედება ზიანს არ მოახდენს უსაფრთხოებაზე. იმ ორგანომ, რომელიც საკუთარ თავზე აიღებს დროებით გადახვევასთან დაკავშირებულ ინიციატივას, უნდა აცნობოს აღნიშნული გადახვევის შესახებ გაერთიანებული ერების ორგანიზაციის ევროპული ეკომონიმიკური კომისიის სამდივნოს, რომელიც, თავის მხრივ, აცნობებს სხვა ხელშემკვრელ მხარეებს. 1 შენიშვნა: 1.7.4 პუნქტში გათვალისწინებული „სპეციალური პირობა“ არ განიხილება დადგენილი წესებიდან დროებით გადახვევად წინამდებარე პუნქტის შესაბამისად. 1.5.1.2 დროებითი გადახვევის მოქმედების ვადა არ უნდა აღემატებოდეს მისი ძალაში შესვლის თარიღიდან ხუთ წელიწადს. დროებითი გადახვევა ავტომატურად წყვეტს ძალას ADR-ის შესაბამისი შესწორების ძალაში შესვლისთანავე. 1.5.1.3 დროებითი გადახვევების საფუძველზე განხორციელებული სატრანსპორტო ოპერაციები წარმოადგენს სატრანსპორტო ოპერაციებს ADR-ში გათვალისწინებული თვალსაზრისით. 1.5.2 (რეზერვირებულია). 1 სამდივნოს შენიშვნა: წინამდებარე თავში გათვალისწინებულ სპეციალურ შეთანხმებებს შეგიძლიათ გაეცნოთ გაერთიანებული ერების ორგანიზაციის ევროპული ეკონომიკური კომისიის სამდივნოს ვებგვერდზე (http://www.unece.org/trans/danger/danger.htm). 59 თავი 1.6 გარდამავალი ღონისძიებები 1.6.1 ზოგადი დებულებები 1.6.1.1 თუ სხვაგვარად არ არის მითითებული, ADR-ით გათვალისწინებული ნივთიერებებისა და ნაკეთობების გადაზიდვა შესაძლებელია განხორციელდეს 2015 წლის 30 ივნისამდე, 2014 წლის 31 დეკემბრამდე დამტკიცებული ADR-ის მოთხოვნების შესაბამისად. 1.6.1.2 (ამოღებულია). 1.6.1.3 ნებისმიერი ხელშემკვრელი მხარის შეიარაღებული ძალების კუთვნილი, პირველი კლასით გათვალისწინებული ნივთიერებები და ნაკეთობები, რომელთა შეფუთვაც განხორციელდა 1990 წლის 1 იანვრამდე აღნიშნული დროისთვის მოქმედი ADR-ის მოთხოვნების შესაბამისად, შესაძლებელია გადაზიდულ იქნეს 1989 წლის 31 დეკემბრის შემდეგ იმ შემთხვევაში, თუ ტარის მთლიანობა არ არის დარღვეული და თუ სატრანსპორტო დოკუმენტში მითითებულია 1990 წლის 1 იანვრამდე შეფუთული სამხედრო ტვირთის სახით. აღნიშნულ კლასთან დაკავშირებით უნდა შესრულდეს 1990 წლის 1 იანვრიდან მოქმედი მოთხოვნები. 1.6.1.4 პირველი კლასით გათვალისწინებული ნივთიერებები და ნაკეთობები, რომელთა შეფუთვაც განხორციელდა 1990 წლის 1 იანვარსა და 1996 წლის 31 დეკემბერს შორის პერიოდში აღნიშნული დროისთვის მოქმედი ADR-ის მოთხოვნების შესაბამისად, შესაძლებელია გადაზიდულ იქნეს 1996 წლის 31 დეკემბრის შემდეგაც იმ შემთხვევაში, თუ ტარის მთლიანობა არ არის დარღვეული და თუ სატრანსპორტო დოკუმენტში მითითებულია 1990 წლის 1 იანვარსა და 1996 წლის 31 დეკემბერს შორის პერიოდში შეფუთული, პირველი კლასით გათვალისწინებული ტვირთის სახით. 1.6.1.5 (რეზერვირებულია) 1.6.1.6 2003 წლის 1 იანვრამდე დამზადებული და 2011 წლის 30 ივნისამდე მოქმედი მარგინალური ნომრის 3612 (1) მოთხოვნების შესაბამისი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები (მტსტკ), რომლებიც ვერ აკმაყოფილებს 6.5.2.1.1 პუნქტის მოთხოვნებს 2011 წლის 1 ივლისიდან დამტკიცებული ასოების, ციფრებისა და სიმბოლოების სიმაღლესთან დაკავშირებით, შესაძლებელია კვლავ იქნეს გამოყენებული. 1.6.1.7 2004 წლის 31 დეკემბრამდე მოქმედი 6.1.5.2.6 პუნქტის მოთხოვნების შესაბამისად 2003 წლის 1 ივლისამდე გაცემული მაღალი ან საშუალო მოლეკულური მასის მქონე პოლიეთილენისგან დამზადებული დოლურების, კანისტრებისა და შედგენილი ტარის ტიპის ოფიციალური დამტკიცება, რომლებიც არ შეესაბამება 4.1.1.19 პუნქტის მოთხოვნებს, ძალაში რჩება 2009 წლის 31 დეკემბრამდე. აღნიშნული ტიპის ოფიციალური დამტკიცების საფუძველზე დამზადებული და მარკირებული ნებისმიერი შეფუთვა შესაძლებელია გამოყენებულ იქნეს 4.1.1.15 პუნქტში განსაზღვრული ექსპლუატაციის ვადის ამოწურვამდე. 1.6.1.8 არსებული ნარინჯისფერი ტაბლოები, რომლებიც აკმაყოფილებს 2004 წლის 31 დეკემბრამდე მოქმედ 5.3.2.2 პუნქტის მოთხონებს, შესაძლებელია კვლავ იქნეს გამოყენებული 5.3.2.2.1 და 5.3.2.2.2 ქვეპუნქტების მოთხოვნების დაკმაყოფილების პირობით იმასთან დაკავშირებით, რომ ტაბლოები, ნომრები და ასოები უნდა დარჩეს 60 მიმაგრებულ მიუხედავად. 1.6.1.9 და 1.6.1.10 1.6.1.11 მდგომარეობაში ავტოსატრანსპორტო საშუალების მდგომარეობის (ამოღებულია) 2006 წლის 31 დეკემბრამდე მოქმედი 6.1.6.1 (ა) პუნქტის მოთხოვნების შესაბამისად 2007 წლის 1 ივლისამდე გაცემული მაღალი ან საშუალო მოლეკულური მასის მქონე პოლიეთილენისგან დამზადებული დოლურების, კანისტრებისა და შედგენილი ტარის, ასევე მაღალი მოლეკულური მასის მქონე პოლიეთილენისგან დამზადებული მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების ტიპის ოფიციალური დამტკიცება, რომლებიც არ შეესაბამება 2007 წლის 1 იანვრიდან მოქმედ 6.1.6.1 (ა) პუნქტის მოთხოვნებს, კვლავ რჩება ძალაში. 1.6.1.12 და 1.6.1.13 (ამოღებულია) 1.6.1.14 2011 წლის 1 იანვრამდე დამზადებული მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები, რომლებიც აკმაყოფილებს კონსტრუქციის იმ ტიპს, რომელმაც ვერ გაიარა 6.5.6.13 პუნქტით გათვალისწინებული გამოცდა ვიბრომედეგობაზე და რომლის მიმართაც აუცილებელი არ იყო 6.5.6.9.5 (დ) პუნქტით გათვალისწინებული კრიტერიუმების დაკმაყოფილების პირობა იმ დროისთვის, როდესაც ის ექვემდებარებოდა გამოცდას ვარდნაზე, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.1.15 არ არის აუცილებელი, რომ 2011 წლის 1 იანვრამდე დამზადებულ, აღდგენილ ან შეკეთებულ მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებზე გათვალისწინებული იყოს მარკირება დაშტაბელების მაქსიმალურად დასაშვები დატვირთვის მითითებით 6.5.2.2.2 პუნქტის შესაბამისად. აღნიშნული სახის მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები, რომლებიც არ არის მარკირებული 6.5.2.2.2 პუნქტის შესაბამისად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში 2010 წლის 31 დეკემბრის შემდეგ მხოლოდ იმ პირობით, რომ თუ მათი აღდგენა ან შეკეთება განხორციელდება 2010 წლის 31 დეკემბრის შემდეგ, მათი მარკირება უნდა შესრულდეს 6.5.2.2.2 პუნქტის თანახმად. 2011 წლის 1 იანვარსა და 2016 წლის 31 დეკემბერს შორის პერიოდში დამზადებული, აღდგენილი ან შეკეთებული მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერები, რომლებზეც აღნიშნულია 2014 წლის 31 დეკემბრამდე მოქმედი 6.5.2.2.2 პუნქტის შესაბამისად მაქსიმალური დასაშვები დატვირთვა დაშტაბელების დროს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.1.16 და 1.6.1.19 1.6.1.20 (ამოღებულია) 2011 წლის 1 იანვრიდან მოქმედი, 3.4 თავის მოთხოვნების მიუხედავად, შეზღუდული ოდენობებით შეფუთული სახიფათო ტვირთები, გარდა იმ ტვირთებისა, რომელთაც მინიჭებული აქვთ ციფრი „0“ 3.2 თავის A ცხრილის (7ა) სვეტში, შესაძლებელია კვლავ დაექვემდებაროს გადაზიდვებს 2015 წლის 30 ივნისამდე, 2010 წლის 31 დეკემბრამდე მოქმედი 3.4 თავის დებულებების შესაბამისად. თუმცა აღნიშნულ შემთხვევაში, 2011 წლის 1 იანვრიდან მოქმედი 3.4.12-3.4.15 პუნქტების დებულებები შესაძლებელია გამოყენებულ იქნეს 2011 წლის 1 იანვრიდან. 3.4.13 (ბ) პუნქტის ბოლო წინადადების გამოყენების მიზნით, იმ შემთხვევაში თუ გადაზიდულ კონტეინერზე მითითებულია 2010 წლის 31 დეკემბრამდე მოქმედი 3.4.12 პუნქტით გათვალისწინებული მარკირება, 61 მაშინ სატრანსპორტო ერთეულის მარკირება უნდა განხორციელდეს 2011 წლის 1 იანვრიდან მოქმედი 3.4.15 პუნქტით გათვალისწინებული ნიშნით. 1.6.1.21 ხელშემკვრელ მხარეებს შეუძლიათ განაგრძონ მძღოლთა მომზადების დამადასტურებელი მოწმობების გაცემა იმ მძღოლებზე, რომლებიც აკმაყოფილებენ 2010 წლის 31 დეკემბრამდე მოქმედ ნიმუშს, ნაცვლად 2012 წლის 31 დეკემბრამდე მოქმედი, 8.2.2.8.5 პუნქტის მოთხოვნებით გათვალისწინებული მოწმობებისა. აღნიშნული მოწმობების გამოყენება შესაძლებელია მათი ხუთწლიანი მოქმედების ვადის ამოწურვამდე. 1.6.1.22 2011 წლის 1 ივლისამდე დამზადებული შედგენილი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერების შიდა ჭურჭელი, რომელიც მარკირებულია 2010 წლის 31 დეკემბრამდე მოქმედი 6.5.2.2.4 მოთხოვნების შესაბამისად, შესაძლებელია კვლავ დაექვემდებაროს ექსპლუატაციას. 1.6.1.23 2010 წლის 31 დეკემბრამდე მოქმედი 8.1.4.3 პუნქტის თანახმად 2011 წლის 1 ივლისამდე დამზადებული ცეცხლმაქრები შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.1.24 (ამოღებულია) 1.6.1.25 2012 წლის 31 დეკემბრამდე მოქმედი ADR-ით გათვალისწინებული დებულებების შესაბამისად გაეროს ნიშნით აღნიშნული შეფუთვები და პაკეტები, რომლებიც არ შეესაბამება 2013 წლის ქ იანვრიდან მოქმედი 5.2.1.1 პუნქტით გათვალისწინებულ მოთხოვნებს გაეროს ნომრისა და ასოების „UN“ ზომასთან დაკავშირებით, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში 2013 წლის 31 დეკემბრამდე, ხოლო 60 ლიტრის ან ნაკლები ტევადობის მქონე ბალონების შემთხვევაში, მომდევნო პერიოდულ შემოწმებამდე, თუმცა არაუგვიანეს 2018 წლის 30 ივნისისა. 1.6.1.26. 2014 წლის 1 იანვრამდე დამზადებული ან აღდგენილი მსხვილგაბარიტიანი ტარა, რომელიც არ შეესაბამება 2013 წლის 1 იანვრიდან მოქმედი 6.6.3.1 პუნქტით გათვალისწინებულ მოთხოვნებს ასოების, ციფრებისა და სიმბოლოების სიმაღლესთან დაკავშირებით, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 2015 წლის 1 იანვრამდე დამზადებულ ან აღდგენილ ტარაზე არ არის აუცილებელი დაშტაბელების დროს მაქსიმალური დასაშვები დატვირთვის მითითება 6.6.3.3 პუნქტის შესაბამისად. აღნიშნული მსხვილგაბარიტიანი ტარა, რომლის მარკირებაც არ განხორციელდა 6.6.3.3 პუნქტის შესაბამისად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში 2014 წლის 31 დეკემბრის შემდეგაც, თუმცა უნდა იქნეს აღნიშნული 6.6.3.3 პუნქტის შესაბამისად, თუ მისი აღდგენა მოხდება მითითებული თარიღის შემდეგ. 2011 წლის 1 იანვარსა და 2016 წლის 31 დეკემბერს შორის პერიოდში დამზადებული ან აღდგენილი მსხვიგაბარიტიანი ტარა, რომელზეც აღნიშნულია 2014 წლის 31 დეკემბრამდე მოქმედი 6.6.3.3 პუნქტის შესაბამისად მაქსიმალური დასაშვები დატვირთვა დაშტაბელების დროს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.1.27 იმ აღჭურვილობის ან მანქანების შემადგენელი შემცველობის საშუალებები, რომლებიც შეიცავენ თხევად საწვავს გაეროს ნომრებით: 1202, 1203, 1223, 1268, 1863 და 3475 და დამზადებულია 2013 წლის 1 ივლისამდე, მაგრამ არ აკმაყოფილებს 2013 წლის 1 იანვრიდან მოქმედი 3.3 თავის 363-ე სპეციალური დებულების (ა) პუნქტით გათვალისწინებულ მოთხოვნებს, შესაძლებელია კვლავ იქნეს წარმოდგენილი ექსპლუატაციაში. 62 1.6.1.28 1.6.1.1 ქვეპუნქტით გათვალისწინებული დებულებებიდან გამონაკლისის სახით, 2015 წლის 28 თებერვლის შემდეგ არ იქნება აღიარებული აკრედიტაციები EN ISO/IEC 17020:2004 სტანდარტის შესაბამისად 1.8.6.8, 6.2.2.11. 6.2.3.6.1 პუნქტებისა და 6.8.4 პუნქტით გათვალისწინებულ TA4 და TT9 სპეციალური დებულებების მიზნებისთვის. 1.6.1.29 ცდებისა და კრიტერიუმების სახელმძღვანელოს მე-3 გამოცემის პირველი ცვლილების 38.3 ქვეპუნქტით გათვალისწინებული მოთხოვნებით წარმოდგენილი ტიპის, ასევე ტიპის გამოცდის თარიღისთვის მოქმედი ნებისმიერი შემდგომი მიმოხილვისა და ცვლილების შესაბამისად დამზადებული ლითიუმის ელემენტები და ბატარეები შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში, გარდა ADR-ით სხვაგვარად გათვალისწინებული შემთხვევებისა. ცდებისა და კრიტერიუმების სახელმძღვანელოს მე-3 გამოცემის მოთხოვნების შესაბამისად 2003 წლის 1 ივლისამდე დამზადებული ლითიუმის ელემენტები და ბატარეები შესაძლებელია კვლავ დაექვემდებაროს გადაზიდვას, ყველა მოთხოვნის დაკმაყოფილების შემთხვევაში. 1.6.1.30 ნიშნები, საინფორმაციო ტაბლოები და აღნიშვნები, რომლებიც პასუხობს 2014 წლის 31 დეკემბრამდე მოქმედ 3.4.7, 3.4.8, 3.5.4.2, 3.5.1.8.3, 5.2.2.2.1.1, 5.3.1.7.1, 5.3.3, 5.3.6, 5.5.2.3.2 და 5.5.3.6.2 პუნქტებით გათვალისწინებულ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში 2016 წლის 31 დეკემბრამდე. 1.6.1.31 სატრანსპორტო პაკეტები, რომლებზეც დატანილია მარკირება „სატრანსპორტო პაკეტი“ 2014 წლის 31 დეკემბრამდე მოქმედი ADR-ით გათვალისწინებული დებულებების შესაბამისად და რომელიც არ აკმაყოფილებს 2015 წლის 1 იანვრიდან მოქმედი 5.1.2.1(ა) პუნქტით გათვალისწინებულ მოთხოვნებს ასოების ზომასთან დაკავშირებით, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში 2015 წლის 31 დეკემბრამდე. 1.6.1.32 ავარიული ტარა და ავარიული ჭურჭელი წნევის ქვეშ, რომლებზეც დატანილია მარკირება „ავარიული“ 2014 წლის 31 დეკემბრამდე მოქმედი ADR-ით გათვალისწინებული დებულებების შესაბამისად და რომელიც არ აკმაყოფილებს 2015 წლის 1 იანვრიდან მოქმედი 5.1.2.3 პუნქტით გათვალისწინებულ მოთხოვნებს ასოების ზომასთან დაკავშირებით, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში 2015 წლის 31 დეკემბრამდე. 1.6.1.33 არ არის აუცილებელი 2016 წლის 1 იანვრამდე დამზადებული, გაეროს №3499 მქონე ორმაგი ელექტრო შრის მქონე კონდენსატორების აღნიშვნა ვატი/სთ ენერგომოცულობის მითითებით, როგორც ეს მოთხოვნილია 3.3 თავის 361-ე სპეციალური დებულების (ე) ქვეპუნქტის თანახმად. 1.6.1.34 არ არის აუცილებელი 2016 წლის 1 იანვრამდე დამზადებული, გაეროს №3508 მქონე ასიმეტრიული კონდენსატორების აღნიშვნა ვატი/სთ ენერგომოცულობის მითითებით, როგორც ეს მოთხოვნილია 3.3 თავის 372-ე სპეციალური დებულების (გ) ქვეპუნქტის თანახმად. 1.6.1.35 2014 წლის 31 დეკემბრამდე მოქმედი ADR-ის მოთხოვნების შესაბამისი წერილობითი ინსტრუქციები, რომლებიც არ აკმაყოფილებს 2015 წლის 1 იანვრიდან მოქმედ 5.4.3 პუნქტით გათვალისწინებულ მოთხოვნებს, შესაძლებელია კვლავ იქნეს წარმოდგენილი ექსპლუატაციაში 2017 წლის 30 ივნისამდე. 63 1.6.1.36 2014 წლის 1 იანვრამდე გაცემული მძღოლის მომზადების დამადასტურებელი მოწმობა, რომელიც არ შეესაბამება 2013 წლის 1 იანვრიდან მოქმედ 8.2.2.8.5 პუნქტით გათვალისწინებულ მოთხოვნებს, მოწმობის უკანა მხარეს მე-4 და მე-8 ნომრებით წარმოდგენილი თარიღების ელემენტების მითითების თანმიმდევრობას, ფერს (თეთრი შავი შრიფტით) და მოწმობის უკანა მხარეს წარმოდგენილი მე-9 და მე-10 ნომრებს შესაბამისი კლასების ჩამონათვალის წარდგენასთან დაკავშირებით, რომლებთან მიმართებაშიც გამოიყენება აღნიშნული მოწმობა, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში მათი ვადის ამოწურვის თარიღამდე. 1.6.2 წნევის ჭურჭლები და ჭურჭლები მე-2 კლასთან დაკავშირებით 1.6.2.1 1997 წლის 1 იანვრამდე დამზადებული ჭურჭლების, რომლებიც ვერ აკმაყოფილებს 1997 წლის 1 იანვრიდან მოქმედ ADR-ის მოთხოვნებს, თუმცა რომელთა გადაზიდვაც ნებადართულია 1996 წლის 31 დეკემბრამდე მოქმედი ADR-ის მოთხოვნების საფუძველზე, ტრანსპორტირება შესაძლებელია აღნიშნული თარიღის შემდეგ იმ შემთხვევაში, თუ P200 და P203 შეფუთვის ინსტრუქციებით გათვალისწინებული პერიოდული გამოცდების მოთხოვნები შესრულდება. 1.6.2.2 (ამოღებულია) 1.6.2.3 მე-2 კლასით გათვალისწინებული ნივთიერებების გადასაზიდად განკუთვნილ ჭურჭელზე, რომელიც დამზადებულია 2003 წლის 1 იანვრამდე, შესაძლებელია მითითებულ იქნეს 2002 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისი მარკირება 2003 წლის 1 იანვრის შემდეგაც. 1.6.2.4 იმ ტექნიკური კოდების შესაბამისად კონსტრუირებული და დამზადებული წნევის ჭურჭელი, რომლებიც აღარ იმყოფება ძალაში 6.2.5 პუნქტის თანახმად, შესაძლებელია კვლავ იქნეს წარმოდგენილი ექსპლუატაციაში. 1.6.2.5 იმ სტანდარტების შესაბამისად კონსტრუირებული და დამზადებული წნევის ჭურჭელი და მათი საკეტები, რომლებიც მათი დამზადების დროისთვის იმყოფებოდა ძალაში (იხილეთ 6.2.4 პუნქტი) აღნიშნული დროისთვის მოქმედი ADR-ის მოთხოვნების საფუძველზე, შესაძლებელია კვლავ იქნეს წარმოდგენილი ექსპლუატაციაში, თუ მათი ექსპლუატაცია არ იზღუდება ცალკეული გარდამავალი ღონისძიებით. 1.6.2.6 იმ ნივთიერებებისთვის განკუთვნილი წნევის ჭურჭელი, რომელიც არ მიეკუთვნება მე-2 კლასს, დამზადებულია 2009 წლის 1 ივლისამდე, 2008 წლის 31 დეკემბრამდე მოქმედი 4.1.4.4 პუნქტის შესაბამისად, თუმცა ვერ აკმაყოფილებს 2009 წლის 1 იანვრიდან მოქმედ 4.1.3.6 მოთხოვნებს, შესაძლებელია კვლავ იქნეს წარმოდგენილი ექსპლუატაციაში იმ პირობით, რომ დაცული იქნება 2008 წლის 31 დეკემბრამდე მოქმედი 4.1.4.4 პუნქტის მოთხოვნები. 1.6.2.7 - 1.6.2.8 1.6.2.9 (ამოღებულია) 2010 წლის 31 დეკემბრამდე მოქმედი 4.1.4.1 პუნქტში წარმოდგენილი P200 (10) შეფუთვის ინსტრუქციით გათვალისწინებული სპეციალური დებულება შეფუთვის შესახებ შესაძლებელია გამოყენებულ იქნეს ADR-ის ხელშემკვრელი მხარეების მიერ 2015 წლის 1 იანვრამდე დამზადებულ ბალონებთან დაკავშირებით. 64 1.6.2.10. გაეროს #1011, 1075, 1965, 1969 ან 1978 საფუძველზე აირების გადასაზიდად განკუთვნილი მრავალჯერადი გამოყენების შენადუღი ფოლადის ბალონები, რომლებთან დაკავშირებითაც გადაზიდვის ქვეყნ(ებ)ის კომპეტენტურმა ორგანოებმა განსაზღვრეს 15წლიანი ინტერვალით პერიოდული შემოწმებების განხორციელება 2010 წლის 31 დეკემბრამდე მოქმედი 4.1.4.1 პუნქტში მითითებული P200 (10) შეფუთვის ინსტრუქციით გათვალისწინებული შეფუთვის შესახებ სპეციალური დებულების მიხედვით, შესაძლებელია კვლავ დაექვემდებაროს პერიოდულ შემოწმებას ზემოაღნიშნული დებულებების შესაბამისად. 1.6.2.11 2013 წლის 1 იანვრამდე დამზადებული და წარმოებული აირის ბალონები, რომლებთან მიმართებაშიც არ გამოიყენება 1.8.6, 1.8.7 ამ 1.8.8 პუნქტებით გათვალისწინებული მოთხოვნები აირის ბალონების შესაბამისობის შეფასებასთან დაკავშირებით, შესაძლებელია კვლავ დაექვემდებაროს გადაზიდვას აღნიშნული თარიღის შემდგომ იმ პირობით, თუ დაკმაყოფილდება ADR-ით გათვალსიწინებული ყველა სხვა მოქმედი დებულება. 1.6.1.12 ავარიული ჭურჭლები წნევის ქვეშ შესაძლებელია კვლავ იქნეს დამზადებული და დამტკიცებული 2013 წლის 31 დეკემბრამდე მოქმედი ეროვნული წესების შესაბამისად. 2014 წლის 1 იანვრამდე მოქმედი ეროვნული წესების შესაბამისად დამზადებული და დამტკიცებული ავარიული ჭურჭლები წნევის ქვეშ შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში მათი გამოყენების ქვეყნის კომპეტენტური ორგანოების ნებართვით. 1.6.1.13 2013 წლის 1 ივლისამდე დამზადებული ბალონების შეკვრა, რომლებიც არ არის აღნიშნული 2013 წლის 1 იანვრიდან მოქმედი 6.2.3.9.7.2 და 6.2.3.9.7.3 პუნქტების ან 2015 წლის 1 იანვრიდან მოქმედი 6.2.3.9.7.2 პუნქტის შესაბამისად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში მომდევნო პერიოდული შემოწმების ჩატარებამდე 2015 წლის 1 ივლისის შემდგომ. 1.2.6.14 ბალონები, რომლებიც დამზადებულია 2016 წლის 1 იანვრამდე 6.2.3 პუნქტისა და გადაზიდვისა და გამოყენების ქვეყნების კომპეტენტური ორგანოების მიერ დამტკიცებული ტექნიკური პირობების შესაბამისად, თუმცა არა ბალონები, რომლებიც დამზადებულია 4.1.4.1 პუნქტით მოთხოვნილი ISO 11513:2011 ან ISO 9809-1:2010 სტანდარტებით P208(1) შეფუთვის ინსტრუქციის შესაბამისად, შესაძლებელია გამოყენებულ იქნეს ადსორბირებული აირების გადაზიდვისთვის იმ პირობით, თუ დაკმაყოფილდება 4.1.6.1 პუნქტით გათვალისწინებული ზოგადი მოთხოვნები შეფუთვასთან დაკავშირებით. 1.2.6.15 2015 წლის 1 ივლისამდე პერიოდულად შემოწმებული ბალონების შეკვრა, რომლებიც არ არის აღნიშნული 2015 წლის 1 იანვრიდან მოქმედი 6.2.39.7.3 პუნქტის შესაბამისად, შესაძლებელია გამოყენებულ იქნეს მომდევნო პერიოდული შემოწმების ჩატარებამდე, 2015 წლის 1 იანვრის შემდგომ. 1.6.3 დამონტაჟებული ცისტერნები (ავტოცისტერნები), ავტოსატრანსპორტო საშუალება-ბატარეები 1.6.3.1 1978 წლის 1 ოქტომბრიდან მიღებული მოთხოვნების ძალაში შესვლამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები), სახსნელი ცისტერნები და ავტოსატრანსპორტო საშუალება-ბატარეები შესაძლებელია კვლავ იქნეს წარმოდგენილი 65 სახსნელი ცისტერნები და ექსლუატაციაში იმ შემთხვევაში, თუ კორპუსის აღჭურვილობა აკმაყოფილებს 6.8 თავის მოთხოვნებს. კორპუსის კედლების სისქე, გარდა მე-2 კლასით გათვალისწინებული გაცივებული, გათხევადებული აირების გადასაზიდად განკუთვნილი კორპუსებისა, უნდა შეესაბამებოდეს არანაკლებ 0.4 მპა-ს (4 ბარის) ოდენობის საანგარიშო წნევას (მანომეტრული წნევა) რბილი ფოლადით დამზადებული კორპუსების შემთხვევაში ან არანაკლებ 200 კპა-ს (2 ბარს) (მანომეტრული წნევა) ალუმინის ან ალუმინის შენადნობისგან დამზადებული კორპუსების შემთხვევაში. იმ ცისტერნების შემთხვევაში, რომელთაც არ გააჩნიათ მრგვალი, ჯვარედინი ჭრილი, გაანგარიშების საფუძვლის სახით გამოიყენება წრის დიამეტრი, რომლის ფართობიც თანაბარია ცისტერნის ფაქტიური ჯვარედინი ჭრილის ფართობისა. 1.6.3.2 წინამდებარე გარდამავალი მოთხოვნების შესაბამისად ექსპლუატაციაში წარმოდგენილი დამონტაჟებული ცისტერნების (ავტოცისტერნების), სახსნელი ცისტერნებისა და ავტოსატრანსპორტო საშუალება-ბატარეების პერიოდული ტესტირება უნდა ჩატარდეს 6.8.2.4 და 6.8.3.4 პუნქტებით გათვალისწინებული მოთხოვნებისა და სხვადასხვა კლასებთან დაკავშირებული სათანადო სპეციალური მოთხოვნების შესაბამისად. იმ შემთხვევაში, თუ ადრე მოქმედი მოთხოვნებით არ არის გათვალისწინებული უფრო მაღალი საცდელი წნევა, მაშინ ალუმინისა და ალუმინის შენადნობისგან დამზადებული კორპუსებისთვის საკმარისი იქნება 200 კპა (2 ბარი) (მანომეტრული წნევა) საცდელი წნევა. 1.6.3.3 ის დამონტაჟებული ცისტერნები (ავტოცისტერნები), სახსნელი ცისტერნები და ავტოსატრანსპორტო საშუალება-ბატარეები, რომლებიც აკმაყოფილებს 1.6.3.1 და 1.6.3.2 პუნქტებით გათვალისწინებულ გარდამავალ მოთხოვნებს, შესაძლებელია წარმოდგენილი იყოს ექსპლუატაციაში 1993 წლის 30 დეკემბრამდე იმ სახიფათო ტვირთებთან დაკავშირებით, რომელთა გადაზიდვებზეც მოხდა მათი დაშვება. აღნიშნული გარდამავალი პერიოდი არ მოქმედებს მე-2 კლასით გათვალისწინებული ნივთიერებების გადაზიდვებისთვის განკუთვნილ დამონტაჟებულ ცისტერნებთან (ავტოცისტერნებთან), სახსნელ ცისტერნებსა და ავტოსატრანსპორტო საშუალებაბატარეებთან დაკავშირებით ან იმ დამონტაჟებულ ცისტერნებთან (ავტოცისტერნებთან), სახსნელ ცისტერნებსა და ავტოსატრანსპორტო საშუალება-ბატარეებთან დაკავშირებით, რომელთა კედლების სისქე და აღჭურვილობა აკმაყოფილებს 6.8 თავის მოთხოვნებს. 1.6.3.4 (ა) ADR-ის მოთხოვნების შესაბამისად 1985 წლის 1 მაისამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები), სახსნელი ცისტერნები და ავტოსატრანსპორტო საშუალება-ბატარეები, რომლებიც ძალაშია 1978 წლის 1 ოქტომბრიდან 1985 წლის 30 აპრილამდე პერიოდში, თუმცა ვერ აკმაყოფილებდა 1985 წლის 1 მაისიდან მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში აღნიშნული თარიღის შემდეგაც; (ბ) 1985 წლის 1 მაისსა და 1988 წლის 1 იანვრიდან მიღებული მოთხოვნების ძალაში შესვლის თარიღს შორის დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები), სახსნელი ცისტერნები და ავტოსატრანსპორტო საშუალებაბატარეები, რომლებიც ვერ პასუხობს აღნიშნულ მოთხოვნებს, თუმცა დამზადდა აღნიშნულ თარიღამდე მოქმედი ADR-ის მოთხოვნების შესაბამისად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში აღნიშნული თარიღის გასვლის შემდეგაც; 66 1.6.3.5 1992 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 1993 წლის 1 იანვრამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები), სახსნელი ცისტერნები და ავტოსატრანსპორტო საშუალება-ბატარეები, რომლებიც ვერ პასუხობს 1993 წლის 1 იანვრიდან მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში აღნიშნული თარიღის შემდეგაც. 1.6.3.6 (ა) იმ შემთხვევაში, თუ 1978 წლის 1 იანვარსა და 1984 წლის 31 დეკემბერს შორის პერიოდში დამზადებული დამონტაჟებული ცისტერნების (ავტოცისტერნების), სახსნელი ცისტერნებისა და ავტოსატრანსპორტო საშუალება-ბატარეების გამოყენება მოხდება 2004 წლის 31 დეკემბრის შემდეგ, ისინი უნდა აკმაყოფილებდეს 1990 წლის 1 იანვრიდან მოქმედი მარგინალური ნომრის 211 127 (5) მოთხოვნებს კედლების სისქესა და დაზიანებისგან დაცვასთან დაკავშირებით; (ბ) იმ შემთხვევაში, თუ 1985 წლის 1 იანვარსა და 1989 წლის 31 დეკემბერს შორის პერიოდში დამზადებული დამონტაჟებული ცისტერნების (ავტოცისტერნების), სახსნელი ცისტერნებისა და ავტოსატრანსპორტო საშუალება-ბატარეების გამოყენება მოხდება 2010 წლის 31 დეკემბრის შემდეგ, ისინი უნდა აკმაყოფილებდეს 1990 წლის 1 იანვრიდან მოქმედი მარგინალური ნომრის 211 127 (5) მოთხოვნებს კედლების სისქესა და დაზიანებისგან დაცვასთან დაკავშირებით. 1.6.3.7 1998 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 1999 წლის 1 იანვრამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები), სახსნელი ცისტერნები და ავტოსატრანსპორტო საშუალება-ბატარეები, რომლებიც ვერ პასუხობს 1999 წლის 1 იანვრიდან მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.8 იმ შემთხვევებში, თუ ADR-ში შესაბამისი შესწორებების შეტანის შედეგად შეიცვლება აირების ზოგიერთი შესაბამისი გადაზიდვის დასახელება, აუცილებელია ტაბლოებსა თუ თავად კორპუსზე მითითებული დასახელებების შეცვლა (იხილეთ 6.8.3.5.2 ან 6.8.3.5.3 ქვეპუნქტები) იმ პირობით, რომ დამონტაჟებულ ცისტერნებზე (ავტოცისტერნებზე), სახსნელ ცისტერნებსა და ავტოსატრანსპორტო საშუალება-ბატარეებზე ან ტაბლოებზე მითითებული აირების დასახელებების (იხილეთ 6.8.3.5.6 (ბ) ან (გ) ქვეპუნქტები) ადაპტირება უზრუნველყოფილი იქნეს პირველი პერიოდული გამოცდის ჩატარების დროს. 1.6.3.9 და 1.6.3.10 (რეზერვირებულია) 1.6.3.11 1996 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 1997 წლის 1 იანვრამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც ვერ პასუხობს 1997 წლის 1 იანვრიდან მოქმედ 211 332 და 211 333 მარგინალური ნომრების მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.12 (რეზერვირებულია) 1.6.3.13 (ამოღებულია) 1.6.3.14 (რეზერვირებულია) 1.6.3.15 (ამოღებულია) 67 1.6.3.16 იმ შემთხვევაში, თუ 2007 წლის 1 იანვრამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები ვერ პასუხობს ცისტერნის ჩანაწერთან დაკავშირებით მოქმედ 4.3.2, 6.8.2.3, 6.8.2.4 და 6.8.3.4 პუნქტების მოთხოვნებს, ცისტერნის ჩანაწერებისთვის ფაილების შეგროვება უნდა დაიწყოს არაუგვიანეს მომდევნო პერიოდული შემოწმებისა. 1.6.3.17 2006 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2007 წლის 1 ივლისამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც გათვალისწინებულია მე-3 კლასის I შეფუთვის ჯგუფის ნივთიერებების გადასაზიდად, რომლის ორთქლის წნევა არ აღემატება 175 კპა-ს (1.75 ბარს) (აბსოლუტური წნევა) 500C ტემპერატურაზე, და რომელზეც მინიჭებულია ცისტერნის კოდი L1.5BN 2006 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში ზემოაღნიშნული ნივთიერებების გადაზიდვებთან დაკავშირებით, 2018 წლის 31 დეკემბრამდე. 1.6.3.18 2001 წლის 30 ივნისამდე მოქმედი მოთხოვნების შესაბამისად 2003 წლის 1 იანვრამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები), სახსნელი ცისტერნები და ავტოსატრანსპორტო საშუალება-ბატარეები, რომლებიც ვერ პასუხობს 2001 წლის 1 ივლისიდან მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში შესაბამისი ცისტერნის კოდის მინიჭების პირობით. 1.6.3.19 2002 წლის 31 დეკემბრამდე მოქმედი 6.8.2.1.7 პუნქტით გათვალისწინებული მოთხოვნების შესაბამისად 2003 წლის 1 იანვრამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც ვერ პასუხობს 2003 წლის 1 იანვრიდან მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.20 2002 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2003 წლის 1 ივლისამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც ვერ პასუხობს 2003 წლის 1 იანვრიდან მოქმედ 6.8.2.1.7 პუნქტით გათვალისწინებულ მოთხოვნებსა და 2003 წლის 1 იანვრიდან მოქმედ 6.8.4(ბ) პუნქტით გათვალისწინებულ TE15 სპეციალური დებულების მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.21 (ამოღებულია) 1.6.3.22-დან 1.6.3.23-მდე (რეზერვირებულია) 1.6.3.25 (ამოღებულია) 1.6.3.26 2006 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2007 წლის 1 იანვრამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც ვერ პასუხობს 2007 წლის 1 იანვრიდან მოქმედ 6.8.2.5.1 პუნქტის შესაბამისად გათვალისწინებულ მოთხოვნებს გარე საანგარიშო წნევის მარკირების შესახებ, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.27-დან 1.6.3.29-მდე (რეზერვირებულია) 1.6.3.30 2004 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2005 წლის 1 ივლისამდე დამზადებული ნარჩენების ვაკუუმური დამონტაჟებული ცისტერნები (ავტოცისტერნები) 68 და სახსნელი ცისტერნები, რომლებიც ვერ პასუხობს 2005 წლის 1 იანვრიდან მოქმედ 6.10.3.9 პუნქტით გათვალისწინებულ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.31 დამონტაჟებული ცისტერნები (ავტოცისტერნები), სახსნელი ცისტერნები და ის ცისტერნები, რომლებიც წარმოადგენს ავტოსატრანსპორტო საშუალება-ბატარეის ელემენტებს და კონსტრუირებული და დამზადებულია მათი დამზადების დროისთვის აღიარებული ტექნიკური წესების თანახმად, მითითებული პერიოდისთვის მოქმედი 6.8.2.7 პუნქტის შესაბამისად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.32 2006 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2007 წლის 1 ივლისამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც აღჭურვილია სამზერი ლუქების საფარის კომპლექტით 2006 წლის 31 დეკემბრამდე მოქმედი 6.8.2.6 პუნქტში გათვალისწინებულ ცხრილში წარმოდგენილი EN 13317:2002 სტანდარტის დებულებების შესაბამისად, აღნიშნული სტანდარტის B დანართის ნახატისა და B.2 ცხრილის ჩათვლით, რომელიც აღარ იმყოფება ძალაში 2007 წლის 1 იანვრის შემდეგ, ან მასალები, რომლებიც ვერ აკმაყოფილებს EN 13094:2004 სტანდარტის 5.2 პუნქტის მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.33 იმ შემთხვევაში, თუ დამონტაჟებული ცისტერნებისა (ავტოცისტერნების) და სახსნელი ცისტერნების კორპუსი უკვე დაყოფილია ტიხრებით ან ტალღების ჩამხშობი ფირფიტებით არაუმეტეს 7 500 ლიტრის მოცულობის განყოფილებებად 2009 წლის 1 იანვრამდე, არ არის აუცილებელი, რომ კორპუსის მოცულობას დაემატოს სიმბოლო „S“ 6.8.2.5.1 პუნქტის თანახმად მოთხოვნილ მახასიათებლებში, სანამ არ განხორციელდება მომდევნო პერიოდული შემოწმება 6.8.2.4.2 პუნქტის შესაბამისად. 1.6.3.34 მიუხედავად 4.3.2.2.4 პუნქტით გათვალისწინებული დებულებებისა, გათხევადებული აირების ან გაცივებული, გათხევადებული აირების გადასაზიდად განკუთვნილი დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც აკმაყოფილებს კონსტრუქციის შესახებ ADR-ის მოქმედ მოთხოვნებს, მაგრამ რომლებიც დაყოფილია ტიხრებით ან ტალღების ჩამხშობი ფირფიტებით 7 500 ლიტრზე მეტი მოცულობის განყოფილებებად 2009 წლის 1 ივლისამდე, შესაძლებელია კვლავ შეივსოს მათი მოცულობის 20%-ზე მეტად და 80%-ზე ნაკლებად. 1.6.3.35 (ამოღებულია) 1.6.3.36 2011 წლის 1 ივლისამდე დამზადებული, გათხევადებული, არატოქსიკური, ადვილაალებადი აირების გადასაზიდად განკუთვნილი დამონტაჟებული ცისტერნები (ავტოცისტერნები), რომლებიც აღჭურვილია უკუსარქველებით, ნაცვლად შიდა საჩერებელი სარქველებისა და რომლებიც არ შეესაბამება 6.8.3.2.3 პუნქტით გათვალისწინებულ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.37 (ამოღებულია) 1.6.3.38 დამონტაჟებული ცისტერნები (ავტოცისტერნები), სახსნელი ცისტერნები და ავტოსატრანსპორტო საშუალება-ბატარეები, კონსტრუირებული და დამზადებულია მათი დამზადების დროისთვის აღიარებული სტანდარტების შესაბამისად (იხილეთ 6.8.2.6 და 6.8.3.6 პუნქტები) მოცემული პერიოდისთვის მოქმედი ADR-ით 69 გათვალისწინებული დებულებების თანახმად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში, თუ მათი ექსპლუატაცია არ იზღუდება კონკრეტული გარდამავალი ღონისძიებებით. 1.6.3.39 2010 წლის 31 დეკემბრამდე მოქმედი 6.8.2.2.3 პუნქტით გათვალისწინებული მოთხოვნების შესაბამისად 2011 წლის 1 ივლისამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც ვერ პასუხობს 6.8.2.2.3 პუნქტის მესამე პარაგრაფით გათვალისწინებულ მოთხოვნებს ალის საჭერ ან ალის ჩამკეტ მოწყობილობასთან დაკავშირებით, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.40 გაეროს # 1092, 1238, 1239, 1244, 1251, 1510, 1580, 1810, 1834, 1838, 2474, 2486, 2668, 3381, 3383, 3385, 3387 და 3389 გათვალისწინებული საინჰალაციო ნივთიერებებით ტოქსიკაციის შემთხვევაში, 2010 წლის 31 დეკემბრამდე მოქმედი 3.2 თავის A ცხრილის (12) სვეტში მითითებული ცისტერნის კოდი შეიძლება კვლავ იქნეს გამოყენებული 2016 წლის 31 დეკემბრამდე, 2011 წლის 1 ივლისამდე დამზადებულ დამონტაჟებულ ცისტერნებსა (ავტოცისტერნებსა) და სახსნელ ცისტერნებთან დაკავშირებით. 1.6.3.41 2012 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2013 წლის 1 ივლისამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც არ აკმაყოფილებს 2013 წლის 1 იანვრიდან მოქმედ 6.8.2.5.26.8.3.5.6 პუნქტებით გათვალისწინებულ დებულებებს აღნიშვნასთან დაკავშირებით, შესაძლებელია კვლავ იქნეს აღნიშნული 2012 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად მომდევნო პერიოდული შემოწმების ჩატარებამდე 2013 წლის 1 ივლისის შემდეგ. 1.6.3.42 2012 წლის 31 დეკემბრამდე მოქმედი 3.2 თავის A ცხრილის (12) სვეტში მითითებული ცისტერნის გაეროს №2381 შესაძლებელია კვლავ იქნეს გამოყენებული 2018 წლის 31 დეკემბრამდე 2013 წლის 1 ივლისამდე დამზადებულ დამონტაჟებულ ცისტერნებთან (ავტოცისტერნებთან) და სახსნელ ცისტერნებთან დაკავშირებით. 1.6.3.43 2012 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2012 წლის 1 იანვრამდე დამზადებული დამონტაჟებული ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც არ აკმაყოფილებს 2011 წლის 1 იანვრიდან მოქმედ 6.8.2.6 პუნქტით გათვალისწინებულ დებულებებს EN 14432:2006 და EN 14433:2006 სტანდარტებთან დაკავშირებით, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.3.44 ცისტერნები (ავტოცისტერნები) და სახსნელი ცისტერნები, რომლებიც გათვალისწინებულია გაეროს №1202, 1203, 1223, 3475 გადაზიდვებისა და გაეროს №1268 ან 1863 კლასიფიცირებილი საავიაციო საწვავისთვის და აღჭურვილია 2015 წლის 1 ივლისამდე მოქმედი ეროვნული დებულებების შესაბამისად კონსტრუირებული და დამზადებული დამატებითი საშუალებებით, თუმცა არ აკმაყოფილებს 2015 წლის 1 იანვრიდან მოქმედი 3.3 თავის 664-ე სპეციალური დებულებით გათვალისწინებულ მოთხოვნებს დამზადებასთან, დამტკიცებასა და გამოცდასთან დაკავშირებით, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში, მათ პირველ შუალედურ ან პერიოდულ შემოწმების განხორციელებამდე 2015 წლის 31 დეკემბრის შემდგომ. აღნიშნული თარიღის შემდეგ, მათი ექსპლუატაცია შესაძლებელი იქნება მხოლოდ იმ ქვეყნების კომპეტენტური ორგანოების ნებართვით, სადაც მოხდება მათი ექსპლუატაცია. 70 1.6.3.45-დან 1.6.3.49-მდე 1.6.3.50 (რეზერვირებულია) პლასტმასის ბოჭკოებით არმირებული (პბა) ცისტერნები 2002 წლის 1 ივლისამდე დამზადებული პლასტმასის ბოჭკოებით არმირებული ცისტერნები, რომლებიც შეესაბამება 2011 წლის 1 ივლისამდე ოფიციალურად დამტკიცებული კონსტრუქციის ტიპს 2011 წლის 30 ივნისამდე მოქმედი B.1C დანართის მოთხოვნების შესაბამისად, შესაძლებელია კვლავ იქნეს წარმოდგენილი ექსპლუატაციაში მათი საექსპლუატაციო ვადის ბოლომდე იმ პირობით, რომ 2001 წლის 30 ივნისამდე მოქმედი ყველა მოთხოვნა უკვე დაკმაყოფილდა და კვლავაც მოხდება მათი დაკმაყოფილება. თუმცა 2011 წლის 1 ივლისიდან შეუძლებელია ახალი კონსტრუქციის ტიპის ოფიციალური დამტკიცება 2011 წლის 30 ივნისამდე მოქმედი მოთხოვნების შესაბამისად. 1.6.4 კონტეინერ-ცისტერნები, გადასაზიდი ცისტერნები და მრავალელემენტიანი აირის კონტეინერები 1.6.4.1 1987 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 1988 წლის 1 იანვრამდე დამზადებული კონტეინერ-ცისტერნები, რომლებიც ვერ პასუხობს 1988 წლის 1 იანვრიდან მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.4.2 1992 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 1993 წლის 1 იანვრამდე დამზადებული კონტეინერ-ცისტერნები, რომლებიც ვერ პასუხობს 1993 წლის 1 იანვრიდან მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.4.3 1998 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 1999 წლის 1 იანვრამდე დამზადებული კონტეინერ-ცისტერნები, რომლებიც ვერ პასუხობს 1999 წლის 1 იანვრიდან მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.4.4 (რეზერვირებულია) 1.6.4.5 იმ შემთხვევაში, თუ ADR-ში შეტანილი შესწორებების შედეგად შეიცვლება აირების გადაზიდვის ზოგიერთი შესაბამისი დასახელება, აუცილებელი არ არის ასევე შეიცვალოს ტაბლოებზე ან თავად კორპუსებზე მითითებული დასახელებებიც (იხილეთ 6.8.3.5.2 ან 6.8.3.5.3 პუნქტები) იმ პირობით, რომ კონტეინერ-ცისტერნებსა და მრავალელემენტიან აირის კონტეინერებზე ან ტაბლოებზე [იხილეთ 6.8.3.5.6 (ბ) ან (გ) პუნქტები] წარმოდგენილი აირების დასახელებები შესაბამისად შეიცვლება პირველი პერიოდული ტესტირების განხორციელებისთანავე. 1.6.4.6 2006 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2007 წლის 1 იანვრამდე დამზადებული კონტეინერ-ცისტერნები, რომლებიც ვერ პასუხობს 2007 წლის 1 იანვრიდან მოქმედ მოთხოვნებს გარე საანგარიშო წნევის მარკირებასთან დაკავშირებით 6.8.2.5.1 პუნქტის შესაბამისად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.4.7 1996 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 1997 წლის 1 იანვრამდე დამზადებული კონტეინერ-ცისტერნები, რომლებიც ვერ პასუხობს 1997 წლის 1 71 იანვრიდან მოქმედი 212 332 და 212 333 მარგინალური ნომრებით გათვალისწინებულ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.4.8 (რეზერვირებულია) 1.6.4.9 კონტეინერ-ცისტერნები და მრავალელემენტიანი გზის კონტეინერები, რომლებიც კონსტრუირებული და დამზადებულია მათი დამზადების დროისთვის საყოველთაოდ აღიარებული ტექნიკური წესების თანახმად, მითითებული პერიოდისთვის მოქმედი 6.8.2.7 პუნქტის შესაბამისად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.4.10 (ამოღებულია) 1.6.4.11 (რეზერვირებულია) 1.6.4.12 2001 წლის 30 ივნისამდე მოქმედი მოთხოვნების შესაბამისად 2003 წლის 1 იანვრამდე დამზადებული კონტეინერ-ცისტერნები და მრავალელემენტიანი აირის კონტეინერები, რომლებიც ვერ პასუხობს 2001 წლის 1 ივლისიდან მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. თუმცა ისინი უნდა აღინიშნოს შესაბამისი ცისტერნის კოდითა და, შესაძლებლობის შემთხვევაში, TC და TE სპეციალური დებულებების შესაბამისი ასოებით და ციფრებით გამოსახული კოდებით, 6.8.4 პუნქტის შესაბამისად. 1.6.4.13 2002 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2003 წლის 1 ივლისამდე დამზადებული კონტეინერ-ცისტერნები, რომლებიც ვერ პასუხობს 2003 წლის 1 იანვრიდან მოქმედ 6.8.2.1.7 პუნქტით გათვალისწინებულ და 2003 წლის 1 იანვრიდან 2006 წლის 31 დეკემბრამდე მოქმედ 6.8.4 (ბ) პუნქტის TE15 სპეციალური დებულების მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.4.14 (რეზერვირებულია) 1.6.4.15 6.8.2.5.1 პუნქტით მოთხოვნილი გამოცდის ტიპის („P“ ან „L“) მითითება არ არის აუცილებელი ცისტერნის ტაბლოზე 2007 წლის 1 იანვრის შემდეგ პირველი გამოცდის ჩატარებამდე. 1.6.4.16 (ამოღებულია) 1.6.4.17 (ამოღებულია) 1.6.4.18 2007 წლის 1 იანვრამდე დამზადებული კონტეინერ-ცისტერნებისა და მრავალელემენტიანი აირის კონტეინერების შემთხვევაში, რომლებიც ვერ აკმაყოფილებს 4.3.2, 6.8.2.3, 6.8.2.4 და 6.8.3.4 პუნქტების მოთხოვნებს ცისტერნების შესახებ არსებული ჩანაწერის შესაბამისად, ცისტერნის შესახებ ჩანაწერისთვის ფაილების შეგროვება უნდა დაიწყოს არაუგვიანეს მომდევნო პერიოდული შემოწმებისა. 1.6.4.19 2006 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2007 წლის 1 ივლისამდე დამზადებული კონტეინერ-ცისტერნები, გათვალისწინებული მე-3 კლასის I შეფუთვის ჯგუფის ნივთიერებების გადასაზიდად, რომელთა ორთქლის წნევა არ აღემატება 175 კპას (1.75 ბარს) (აბსოლუტური წნევა) 500C ტემპერატურაზე და რომლის მიმართაც მინიჭებულია ცისტერნის კოდი L1.5BN 2006 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად, შესაძლებელია კვლავ იყოს გამოყენებული ზემოაღნიშნული ნივთიერებების გადასაზიდად 2016 წლის 31 დეკემბრამდე. 72 1.6.4.20 2004 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2005 წლის 1 ივლისამდე დამზადებული ვაკუუმური ნარჩენების კონტეინერ-ცისტერნები, რომლებიც ვერ პასუხობს 2005 წლის 1 იანვრიდან მოქმედ 6.10.3.9 პუნქტით გათვალისწინებულ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.4.21-დან 1.6.4.29-მდე (რეზერვირებულია) 1.6.4.30 გადასატანი ცისტერნები და გაეროს მრავალელემენტიანი აირის კონტეინერები, რომლებიც ვერ აკმაყოფილებს 2007 წლის 1 იანვრიდან მოქმედ მოთხოვნებს კონსტრუქციის შესახებ, მაგრამ დამზადებულია 2008 წლის 1 იანვრამდე გაცემული მოწმობის თანახმად კონსტრუქციის ოფიციალური დამტკიცების შესახებ, შესაძლებელია კვლავ იქნეს გამოყენებული. 1.6.4.31 (ამოღებულია) 1.6.4.32 იმ შემთხვევაში, თუ კონტეინერ-ცისტერნის კორპუსი უკვე დაყოფილია ტიხრებით ან ტალღების ჩამხშობი ფირფიტებით არაუმეტეს 7 500 ლიტრის მოცულობის განყოფილებებად 2009 წლის 1 იანვრამდე, არ არის აუცილებელი, რომ კორპუსის მოცულობას დაემატოს სიმბოლო „S“ 6.8.2.5.1 პუნქტის თანახმად მოთხოვნილ მახასიათებლებში, სანამ არ განხორციელდება მომდევნო პერიოდული შემოწმება 6.8.2.4.2 პუნქტის შესაბამისად. 1.6.4.33 მიუხედავად 4.3.2.2.4 პუნქტით გათვალისწინებული დებულებებისა, გათხევადებული აირების ან გაყინული გათხევადებული აირების გადასაზიდად განკუთვნილი კონტეინერ-ცისტერნები, რომლებიც აკმაყოფილებს კონსტრუქციის შესახებ ADR-ის მოქმედ მოთხოვნებს, მაგრამ რომელთა დაყოფაც მოხდა 2009 წლის 1 ივლისამდე, ტიხრებით ან ტალღების ჩამხშობი ფირფიტებით 7 500 ლიტრზე მეტი ტევადობის განყოფილებებად, შესაძლებელია კვლავ შეივსოს მათი მოცულობის 20%-ზე მეტად და 80%-ზე ნაკლებად. 1.6.4.34 და 1.6.4.35 (ამოღებულია) 1.6.4.36 იმ ნივთიერებების შემთხვევაში, რომელთა მიმართაც 3.2 თავის A ცხრილის (11) სვეტში მინიჭებულია TP37, 2010 წლის 31 დეკემბრამდე მოქმედი, ADR-ში გათვალისწინებული გადასატანი ცისტერნების ინსტრუქცია, შესაძლებელია კვლავ იქნეს მიღებული 2016 წლის 31 დეკემბრამდე. 1.6.4.37 2012 წლის 1 იანვრამდე დამზადებული გადასატანი ცისტერნები და მრავალელემენტიანი აირის კონტეინერები, რომლებიც პასუხობს 2010 წლის 31 დეკემბრამდე მოქმედ 6.7.2.20.1, 6.7.3.16.1, 6.7.4.15.1 ან 6.7.5.13.1 პუნქტებით გათვალისწინებული მარკირების მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში იმ შემთხვევაში, თუ აკმაყოფილებს 2011 წლის 1 იანვრიდან მოქმედ ADR-ით გათვალისწინებულ მოთხოვნებს, მათ შორის, შესაბამისობის შემთხვევაში, 6.7.2.20.1 (ზ) პუნქტის მოთხოვნებს ტაბლოზე „S“ სიმბოლოს მარკირებასთან დაკავშირებით, როდესაც კორპუსი დაყოფილია ტიხრებით ან ტალღების ჩამხშობი ფირფიტებით 7 500 ლიტრზე მეტი მოცულობის განყოფილებებად. იმ შემთხვევაში, თუ კორპუსი ან დანაყოფი უკვე დაყოფილია ტალღების ჩამხშობი ფირფიტებით არაუმეტეს 7 500 ლიტრის მოცულობის განყოფილებებად 2012 წლის 1 იანვრამდე, არ არის აუცილებელი, რომ კორპუსის ან შესაბამისად განყოფილებების მოცულობას დაემატოს სიმბოლო „S“ 6.7.2.19.5 პუნქტის თანახმად მოთხოვნილ მახასიათებლებში, სანამ არ განხორციელდება მომდევნო პერიოდული შემოწმება 6.7.2.19.5 პუნქტის შესაბამისად. 73 1.6.4.38 არ არის აუცილებელი 2014 წლის 1 იანვრამდე დამზადებული გადასატანი ცისტერნების მარკირება 6.7.2.20.2, 6.7.3.16.2 და 6.7.4.15.2 პუნქტების თანახმად მოთხოვნილი გადასატანი ცისტერნის ინსტრუქციის შესაბამისად მომდევნო პერიოდული შემოწმებისა და გამოცდის განხორციელებამდე. 1.6.4.39 ის კონტეინერ-ცისტერნები და მრავალელემენტიანი აირის კონტეინერები, რომლებიც კონსტრუირებული და დამზადებულია მათი წარმოების დროისთვის მოქმედი სტანდარტების შესაბამისად (იხილეთ 6.8.2.6 და 6.8.3.6 პუნქტები), მითითებული პერიოდისთვის დამტკიცებული ADR-ის დებულებების თანახმად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში, თუ მათი ექსპლუატაცია არ იზღუდება რაიმე სპეციალური გარდამავალი ღონისძიებით. 1.6.4.40 2010 წლის 31 დეკემბრამდე მოქმედი 6.8.2.2.3 პუნქტით გათვალისწინებული მოთხოვნების შესაბამისად 2011 წლის 1 ივლისამდე დამზადებული კონტეინერცისტერნები, რომლებიც ვერ პასუხობს 6.8.2.2.3 პუნქტის მესამე პარაგრაფით გათვალისწინებულ მოთხოვნებს ალის საჭერ ან ალის ჩამკეტ მოწყობილობასთან დაკავშირებით, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.4.41 გაეროს # 1092, 1238, 1239, 1244, 1251, 1510, 1580, 1810, 1834, 1838, 2474, 2486, 2668, 3381, 3383, 3385, 3387 და 3389 გათვალისწინებული საინჰალაციო ნივთიერებებით ტოქსიკაციის შემთხვევაში, 2010 წლის 31 დეკემბრამდე მოქმედი 3.2 თავის A ცხრილის (12) სვეტში მითითებული ცისტერნის კოდი შეიძლება კვლავ იქნეს გამოყენებული 2016 წლის 31 დეკემბრამდე, 2011 წლის 1 ივლისამდე წარმოებულ კონტეინერ-ცისტერნებთან დაკავშირებით. 1.6.4.42 2012 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2013 წლის 1 ივლისამდე დამზადებული კონტეინერ-ცისტერნები, რომლებიც არ აკმაყოფილებს 2013 წლის 1 იანვრიდან მოქმედი 6.8.2.5.2 ან 6.8.3.5.6 პუნქტებით გათვალისწინებულ დებულებებს აღნიშვნასთან დაკავშირებით, შესაძლებელია კვლავ აღინიშნოს 2012 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად, მომდევნო პერიოდული შემოწმების ჩატარებადე, 2013 წლის 1 ივლისის შემდეგ. 1.6.4.43 არ არის აუცილებელი, რომ 2014 წლის 1 იანვრამდე დამზადებული გადამზიდავი ცისტერნები და მრავალელემენტიანი აირის კონტეინერები აკმაყოფილებდეს 6.7.2.13.1(ვ), 6.7.3.9.1(ე), 6.7.4.8.1(ე) და 6.7.5.6.1(დ) პუნქტებით გათვალისწინებულ მოთხოვნებს წნევის შემზღუდველების აღნიშვნასთან დაკავშირებით. 1.6.4.44 იმ ნივთიერებების შემთხვევაში, რომლებთან დაკავშირებითაც 3.2 თავის A ცხრილის (11) სვეტში მითითებულია 2012 წლის 31 დეკემბრამდე მოქმედ ADR-ში გადამზიდავ ცისტერნებთან დაკავშირებით გათვალისწინებულ ინსტრუქციაში წარმოდგენილი TP38 ან TP39 სპეციალური დებულებები, შესაძლებელია კვლავ იქნეს გამოყენებილი 2018 წლის 31 დეკემბრამდე. 1.6.4.45 2012 წლის 31 დეკემბრამდე მოქმედი 3.2 თავის A ცხრილის (12) სვეტში მითითებული ცისტერნის გაეროს №2381 შესაძლებელია კვლავ იქნეს გამოყენებული 2018 წლის 31 დეკემბრამდე 2013 წლის 1 ივლისამდე დამზადებულ კონტეინერ-ცისტერნებთან დაკავშირებით. 1.6.4.46 2012 წლის 31 დეკემბრამდე მოქმედი მოთხოვნების შესაბამისად 2012 წლის 1 იანვრამდე დამზადებული კონტეინერ-ცისტერნები, რომლებიც არ აკმაყოფილებს 2011 წლის 1 იანვრიდან მოქმედ 6.8.2.6 პუნქტით გათვალისწინებულ დებულებებს EN 14432:2006 და 74 EN 14433:2006 სტანდარტებთან წარმოდგენილი ექსპლუატაციაში. 1.6.5 დაკავშირებით, შესაძლებელია კვლავ იყოს ავტოსატრანსპორტო საშუალებები 1.6.5.1 და 1.6.5.2 (რეზერვირებულია) 1.6.5.3 (ამოღებულია) 1.5.6.4 რაც შეეხება EX/II, EX/III, FL, OX და AT ავტოსატრანსპორტო საშუალებების კონსტრუქციას, 2014 წლის 31 დეკემბრამდე მოქმედი მე-9 ნაწილის მოთხოვნები შესაძლებელია გამოყენებულ იქნეს 2016 წლის 31 მარტამდე. 1.5.6.5 2003 წლის 1 იანვრამდე რეგისტრირებული ან ექსპლუატაციაში ჩაშვებული ავტოსატრანსპორტო საშუალებები, რომელთა ელექტრო მოწყობილობა ვერ აკმაყოფილებს 9.2.2, 9.3.7 ან 9.7.8 პუნქტებით გათვალისწინებულ მოთხოვნებს, მაგრამ პასუხობს 2001 წლის 30 ივნისამდე მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იქნეს გამოყენებული. 1.6.5.6 (ამოღებულია) 1.6.5.7 სრული ან დასრულებული ავტოსატრანსპორტო საშუალებები, რომელთა ტიპიც ოფიციალურად იქნა დამტკიცებული 2002 წლის 31 დეკემბრამდე №105 ECE წესის შესაბამისად1, მასში შეტანილი შესწორებების 01 სერიით ან 98/91/EC დირექტივის დებულებებით2 გათვალისწინებულ შესწორებებთან ერთად, რომლებიც ვერ აკმაყოფილებს 9.2. თავის მოთხოვნებს, მაგრამ პასუხობს 2001 წლის 30 ივნისამდე მოქმედ საბაზო ავტოსატრანსპორტო საშუალებების კონსტრუქციასთან დაკავშირებულ მოთხოვნებს (B.2 დანართის 220 100-დან 220 540-მდე მარგინალური ნომრები), შესაძლებელია კვლავ იყოს დაშვებული გადაზიდვებზე და ჩაშვებული ექსპლუატაციაში იმ პირობით, რომ მათი პირველი რეგისტრაცია ან მათი ექსპლუატაციაში ჩაშვება განხორციელდა 2003 წლის 1 ივლისამდე. 1.6.5.8 EX/II და EX/III ავტოსატრანსპორტო საშუალებები, რომელთა პირველი დაშვება გადაზიდვებზე მოხდა 2005 წლის 1 ივლისამდე და რომლებიც აკმაყოფილებს 2004 წლის 31 დეკემბრამდე მოქმედ მე-9 ნაწილის მოთხოვნებს, თუმცა ვერ პასუხობს 2005 წლის 1 იანვრიდან მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. №105 ECE წესი (იმ ავტოსატრანპორტო საშუალებების ოფიციალურ დამტკიცებასთან დაკავშირებული ერთგვარი დებულებები, რომლებიც გათვალისწინებულია სახიფათო ტვირთების გადასაზიდად, მათი სპეციალური კონსტრუქციული მახასიათებლების გათვალისწინებით). 2 ევროპარლამენტისა და საბჭოს 1998 წლის 14 დეკემბრის 98/91/EC დირექტივა სახიფათო ტვირთების საგზაო გადაზიდვებისთვის განკუთვნილ ავტოსატრანსპორტო საშუალებებსა და მათ მისაბმელებთან დაკავშირებით, ასევე ცვლილების შეტანის შესახებ 70/156/EEC დირექტივა ავტოსატრანსპორტო საშუალებებისა და მისაბმელების ტიპის ოფიციალურ დამტკიცებასთან დაკავშირებით (ევროპული გაერთიანების ოფიციალური ჟურნალი №L011, 1999 წლის 16 იანვარი, გვ. 0025-0036). 1 75 1.6.5.9 3მ3 მეტი ტევადობის დამონტაჟებული ცისტერნების მქონე ავტოცისტერნები, რომლებიც გათვალისწინებულია არანაკლებ 4 ბარის ოდენობის წნევაზე გამოცდილი, თხევად ან მდნარ მდგომარეობაში არსებული სახიფათო ტვირთების გადასაზიდად, და რომლებიც ვერ აკმაყოფილებს 2004 წლის 1 ივლისამდე პირველად რეგისტრირებულ (ან ექსპლუატაციაში გაშვებულ იმ შემთხვევაში, თუ რეგისტრაცია სავალდებულო არაა) 9.7.5.2 პუნქტის მოთხოვნებს, შეიძლება კვლავ იქნეს გამოყენებული. 1.6.5.10 გადაზიდვებზე დაშვების მოწმობები, რომლებიც აკმაყოფილებს 2006 წლის 31 დეკემბრამდე მოქმედ 9.1.3.5 პუნქტში წარმოდგენილ ნიმუშს და ისინი, რომლებიც აკმაყოფილებს 2007 წლის 1 იანვრიდან 2008 წლის 31 დეკემბრამდე მოქმედ 9.1.3.5 პუნქტში აღწერილ ნიმუშს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 2009 წლის 1 იანვრდიან 2014 წლის 31 დეკემბრამდე მოქმედი 9.1.3.5 პუნქტით გათვალისწინებული ნიმუშის შესაბამისი გადაზიდვებზე დაშვების მოწმობები შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.5.11 ეროვნული კანონმდებლობით გათვალისწინებული დებულებების შესაბამისად 2009 წლის 1 ივლისამდე დამზადებული და გადაზიდვებზე დაშვებული ფეთქებადი ნივთიერებების მობილური დანადგარები, რომლებიც ვერ პასუხობს 2009 წლის 1 იანვრამდე მოქმედ მოთხოვნებს კონსტრუქციასა და გადაზიდვებზე დაშვებასთან დაკავშირებით, შესაძლებელია გამოყენებულ იქნეს მათი გამოყენების ქვეყნების კომპეტენტური ორგანოების დასტურით. 1.6.5.12 EX/III და FL ავტოსატრანსპორტო საშუალებები, რომელთა პირველი რეგისტრაცია და ექსპლუატაციაში ჩაშვება განხორციელდა 2012 წლის 1 აპრილამდე და რომელთა ელექტროკავშირი ვერ აკმაყოფილებს 9.2.2.6.3 პუნქტით გათვალისწინებულ მოთხოვნებს, თუმცა პასუხობს 2010 წლის 31 დეკემბრამდე მოქმედ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.5.13 1995 წლის 1 ივლისამდე პირველად რეგისტრირებული (ან ექსპლუატაციაში ჩაშვებული, იმ შემთხვევაში, თუ რეგისტრაცია არ არის სავალდებულო) მისაბმელები, რომლებიც აღჭურვილია ბლოკირების საწინააღმდეგო სამუხრუჭე სისტემით №13 ECE განაწესის, შესწორებების 06 სერიის შესაბამისად, მაგრამ ვერ აკმაყოფილებს ა კატეგორიის ბლოკირების საწინააღმდეგო სამუხრუჭე სისტემის ტექნიკურ მოთხოვნებს, შესაძლებელია კვლავ იქნეს გამოყენებული. 1.6.5.14 2012 წლის 31 დეკემბრამდე მოქმედი ADR-ით გათვალისწინებული დებულებების შესაბამისად 2013 წლის 1 ივლისამდე დამტკიცებული ფეთქებადი ნივთიერებების მობილური დანადგარები, რომლებიც არ აკმაყოფილებს 2013 წლის 1 იანვრიდან მოქმედ 6.12.3.1.2 ან 6.12.3.2.2 პუნქტით გათვალისწინებულ მოთხოვნებს, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 2009 წლის 13 ივლისის (EC) №661/2009 რეგლამენტი სატრანსპორტო საშუალებების, მათი მისაბმელებისა და სისტემების, კომპონენტებისა და ცალკეული ტექნიკური კვანძების ზოგადი უსაფრთხოების უზრუნველყოფის მიზნით ტიპის ოფიციალური დამტკიცებასთან დაკავშირებული მოთხოვნების შესახებ (ოფიციალური ჟურნალი L200, 31.7.2009, გვ. 1). 1 76 1.6.5.15 რაც შეეხება მე-9 ნაწილით გათვალისწინებული დებულებების გამოყენებას, 2014 წლის 1 ნოემბრამდე პირველად დარეგისტრირებული ან ექსპლუატაციაში გაშვებული სატრანსპორტო საშუალება, რომელიც ოფიციალურად იქნა დამტკიცებული (EC) №661/2009 რეგლამენტით3 შეცლილი დირექტივებით გათვალისწინებული დებულებების შესაბამისად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში. 1.6.6 მე-7 კლასი 1.6.6.1 შეფუთვები, რომლებიც არ საჭიროებს კომპეტენტური ორგანოს მიერ კონსტრუქციის დამტკიცებას №6 IAEA უსაფრთხოების სერიების 1985 წლისა და 1985 წლის გამოცემების (შესწორებული 1990 წელს) შესაბამისად შეფუთვები, რომლებიც არ საჭიროებს კომპეტენტური ორგანოს მიერ კონსტრუქციის დამტკიცებას (გამოთავისუფლებული შეფუთვები, IP-1 ტიპის, IP-2 ტიპის, IP-3 ტიპისა და A ტიპის შეფუთვები) სრულად უნდა აკმაყოფილებდეს ADR-ით გათვალისწინებულ მოთხოვნებს, იმ შეფუთვების გამოკლებით, რომლებიც აკმაყოფილებს რადიოაქტიური მასალის უსაფრთხო ტრანსპორტირების შესახებ IAEA რეგლამენტის (№6 IAEA უსაფრთხოების სერიების) 1985 წლისა და 1985 წლის გამოცემების (შესწორებული 1990 წელს) მოთხოვნებს: (ა) შესაძლებელია კვლავ იყოს გამოყენებული გადაზიდვებისთვის იმ პირობით, თუ ისინი მომზადდება გადასაზიდად 2003 წლის 31 დეკემბრამდე, და შესაბამისად მათზე გავრცელდება 1.6.6.3 პუნქტით გათვალისწინებული მოთხოვნები; (ბ) შესაძლებელია კვლავ იყოს გამოყენებული გადაზიდვებისთვის იმ პირობით, თუ: (i) ისინი არ არის განსათავსებლად; გათვალისწინებული ურანის (ii) გამოიყენება 1.7.3 პუნქტით გათვალისწინებული მოქმედი მოთხოვნები; (iii) გამოიყენება 2.2.7 პუნქტით საქმიანობასთან გათვალისწინებული ლიმიტები და კლასიფიკაცია; ჰექსაფტორიდის დაკავშირებით (iv) გამოიყენება 1, 3, 4, 5 და 7 ნაწილებით გადაზიდვასთან დაკავშირებებით გათვალისწინებული მოთხოვნები და კონტროლი; (v) შეფუთვის კომპლექტი არ იყო დამზადებული ან შეცვლილი 2003 წელის 31 დეკემბრის შემდგომ. 1.6.6.2 შეფუთვები, რომლებიც დამტკიცებულია №6 IAEA უსაფრთხოების სერიების 1973 წლის, 1973 წლის (შესწორებული), 1985 წლისა და 1985 წლის (შესწორებული 1990 წელს) გამოცემების თანახმად 1.6.6.2.1 შეფუთვები, რომლებიც საჭიროებს კომპეტენტური ორგანოს მიერ კონსტრუქციის დამტკიცებას, სრულად უნდა აკმაყოფილებდეს ADR-ით გათვალისწინებულ მოთხოვნებს, თუ არ შესრულდება შემდეგი პირობები: (ა) შეფუთვის კომპლექტები დამზადდება კომპეტენტური ორგანოს მიერ №6 IAEA უსაფრთხოების სერიების 1973 წლის ან 1973 წლის (შეწორებული) ან 1985 წლის ან 77 1985 წლის (შესწორებული 1990 წელს) გამოცემებით გათვალისწინებული დებულებების შესაბამისად; (ბ) შეფუთვის კონსტრუქცია ექვემდებარება მრავალმხრივ დამტკიცებას; (გ) გამოიყენება 1.7.3 პუნქტით გათვალისწინებული მოქმედი მოთხოვნები; (დ) გამოიყენება 2.2.7 პუნქტით საქმიანობასთან დაკავშირებით გათვალისწინებული ლიმიტები და კლასიფიკაცია; (ე) გამოიყენება 1, 3, 4, 5 და 7 ნაწილებით გადაზიდვასთან დაკავშირებებით გათვალისწინებული მოთხოვნები და კონტროლი; (ვ) (რეზერვირებულია) (ზ) იმ შეფუთვების შემთხვევაში, რომლებიც აკმაყოფილებს №6 IAEA უსაფრთხოების სერიების 1973 წლის ან 1973 წლის (შეწორებული) გამოცემებით გათვალისწინებული მთხოვნებს: (i) №6 IAEA უსაფრთხოების სერიების 1973 წლის ან 1973 წლის (შეწორებული) გამოცემებით რადიოაქტიური მასალის უსაფრთხოდ გადაზიდვასთან დაკავშირებით გათვალისწინებული გადაზიდვების ავარიულ პირობებში, მოცემული გადაზიდვებისთვის ნებადართული მაქსიმალური რადიოაქტიური შემცველობის არსებობისას, შეფუთვებმა უნდა შეინარჩუნონ საკმარისი დაცვა, რათა უზრუნველყონ, რომ გამოსხივების დონე შეფუთვის ზედაპირიდან 1 მეტრის მანძილზე არ აღემატებოდეს 10 მილისივერტ/საათს; (ii) შეფუთვებში არ გამოიყენება უწყვეტი ვენტილაცია; (iii) ყოველ შეფუთვის კომპლექტს ენიჭება სერიული ნომერი 5.2.1.7.5 პუნქტის შესაბამისად, რომელიც წარმოდგენილი იქნება შეფუთვის კომპლექტის გარე ზედაპირზე. 1.6.6.2.2 არ დაიშვება ახალი შეფუთვის კომპლექტების დამზადების დაწყება იმ შეფუთვის კონსტრუქციის შესაბამისად, რომელიც აკმაყოფილებს №6 IAEA უსაფრთხოების სერიების 1973 წლის, 1973 წლის (შესწორებული), 1985 წლისა და 1985 წლის (შესწორებული 1990 წელს) გამოცემებით გათვალისწინებულ დებულებებს. 1.6.6.3 შეფუთვები, რომლებიც გათავისუფლებულია გაყოფად მასალასთან დაკავშირებით ADR-ის 2011 წლისა და 2013 წლის გამოცემების თანახმად (№RS-R-1 IAEA უსაფრთხოების სერიების 2009 წლის გამოცემება) იმ გაყოფადი მასალის შემცველი შეფუთვების გადაზიდვა, რომელიც არ არის კლასიფიცირებული „გაყოფადი“ ნიშნით ADR-ის 2011 წლისა და 2013 წლის გამოცემების 2.2.7.2.3.5(ა) (i) ან (iii) პუნქტის (რადიოაქტიური მასალის უსაფრთხო გადაზიდვის შესახებ IAEA წესების 2009 წის გამოცემის 417 (ა)(i) ან (iii) პუნქტის) თანახმად, რომელიც მომზადებულია გადაზიდვისთვის 2014 წლის 31 დეკემბრამდე, შესაძლებელია კვლავ გაგრძელდეს და კლასიფიცირებული იქნეს „არა-გაყოფადი“ ან „გაყოფისგან გათავისუფლებული“ ნიშნით, იმ გამონაკლისით, რომ სატრანსპორტო საშუალებებზე უნდა გავრცელდეს აღნიშნული გამოცემების 2.2.7.2.3.5 ცხრილით ტვირთის გადაზიდვასთან დაკავშირებული შეზღუდვები. ტვირთის გადაზიდვა უნდა განხორციელდეს ექსკლუზიური გამოყენების პირობით. 78 1.6.6.4 სპეციალური ფორმის რადიოაქტიური მასალა, რომელიც დამტკიცებულია №6 IAEA უსაფრთხოების სერიების 1973 წლის, 1973 წლის (შესწორებული), 1985 წლისა და 1985 წლის (შესწორებული 1990 წელს) გამოცემების თანახმად იმ კონსტრუქციის თანახმად დამზადებული სპეციალური ფორმის რადიოაქტიური მასალა, რომელსაც მიღებული აქვს ცალმხრივი დამტკიცება კომპეტენტური ორგანოსგან №6 IAEA უსაფრთხოების სერიების 1973 წლის, 1973 წლის (შესწორებული), 1985 წლისა და 1985 წლის (შესწორებული 1990 წელს) გამოცემების თანახმად, შესაძლებელია კვლავ იყოს წარმოდგენილი ექსპლუატაციაში იმ შემთხვევაში, თუ შეესაბამება 1.7.3 პუნქტის მიმდინარე მოთხოვნების შესაბამისად წარმოდგენილ ხარისხის უზრუნველყოფის სავალდებულო პროგრამას. არ დაიშვება აღნიშნული სპეციალური ფორმის რადიოაქტიური მასალის ახალი წარმოების დაწყება. 79 თავი 1.7 რადიოაქტიურ მასალასთან დაკავშირებული ზოგადი დებულებები 1.7.1 მოქმედების არეალი და გამოყენებადობა შენიშვნა 1: რადიოაქტიური მასალების გადაზიდვის დროს ავარიის ან რაიმე ინციდენტის შემთხვევაში, დაცული უნდა იქნეს შესაბამისი ეროვნული და/ან საერთაშორისო ორგანიზაციის მიერ დადგენილი ავარიული სიტუაციების მარეგულირებელი დებულებები ადამიანების, საკუთრებისა და გარემოს დაცვის უზრუნველყოფის მიზნით. აღნიშნულ დებულებებთან დაკავშირებული შესაბამისი მითითებები გათვალისწინებულია პუბლიკაციაში „რადიოაქტიურ მასალებთან დაკავშირებულ სატრანსპორტო ავარიებზე გადაუდებელი რეაგირების დაგეგმვა და მზადყოფნა“, №TS-G-1.2 (ST-3) უსაფრთხოების სტანდარტული სერიები, IAEA, ვენა (2002 წ.). შენიშვნა 2: ავარიული პროცედურები უნდა ითვალისწინებდეს სხვა სახიფათო ნივთიერებების ფორმირების შესაძლებლობას, რაც შეიძლება გამოიწვიოს ავარიის შემთხვევაში ტვირთის შიგთავსისა და გარემოს ურთიერთქმედებამ. 1.7.1.1 ADR განსაზღვრავს უსაფრთხოების ნორმებს, რომლებიც უზრუნველყოფს სათანადო დონის კონტროლს გამოსხივებაზე, ასევე რადიოაქტიურ მასალის გადაზიდვასთან დაკავშირებული ადამიანების, საკუთრებისა და გარემოს კრიტიკულობასა და თერმულ საფრთხეებზე. აღნიშნული ნორმები დაფუძნებულია IAEA წესებზე რადიოაქტიური მასალის უსაფრთხო გადაზიდვების შესახებ, 2012 წელის გამოცემა, №TS-R-1, უსაფრთხოების ნორმების სერიები, IAEA, ვენა (2012 წ.). განმარტებითი მასალის მოძიება შესაძლებელია „საცნობარო მასალაში რადიოაქტიური მასალის უსაფრთხო გადაზიდვებთან დაკავშირებული IAEA წესების შესახებ (2012 წლის გამოცემა)“, №SSG26 უსაფრთხოებოს ნორმების სერიებში, IAEA, ვენა (2014 წ.). 1.7.1.2 ADR-ის მიზანია იმ მოთხოვნების განსაზღვრა, რომლებიც უნდა დაკმაყოფილდეს რადიოაქტიური მასალის გადაზიდვისას უსაფრთხოების უზრუნველყოფისა და ადამიანების, საკუთრებისა და გარემოს რადიაციული მოქმედებისგან დაცვის მიზნით. აღნიშნული სახის დაცვის უზრუნველყოფა მოხდება შემდეგი პირობების დანერგვით: (ა) რადიოაქტიური შემცველობის დამცავი გარსი; (ბ) გამოსხივების გარე დონეების კონტროლი; (გ) კრიტიკულობის პრევენცია; და (დ) სითბოს მოქმედების შედეგად გამოწვეული ზიანის პრევენცია. აღნიშნული მოთხოვნების დაკმაყოფილება ხდება, პირველ რიგში, შეფუთვებსა და ავტოსატრანსპორტო საშუალებებთან დაკავშირებული შიგთავსის ფარგლებსა და რადიოაქტიური შიგთავსის საშიშროებაზე დამოკიდებული შეფუთვის კონსტრუქციების ნორმატიულ მახასიათებლებთან ეტაპობრივი მიახლოების გზით. მეორე რიგში, მათი მიღწევა ხდება შეფუთვების კონსტრუქციასა და ექსპლუატაციასთან დაკავშირებით, ასევე შეფუთვების ტექნიკურ უზრუნველყოფასთან დაკავშირებით მოთხოვნების განსაზღვრის გზით, რადიოაქტიური შიგთავსის მახასიათებლების გათვალისწინების ჩათვლით. და ბოლოს, მოთხოვნების დაკმაყოფილება ხდება ადმინისტრაციული 80 კონტროლის ზომების მიღებით, შესაბამისობის შემთხვევაში, კომპეტენტური ორგანოების მიერ ოფიციალური დამტკიცების პროცედურების ჩათვლით. 1.7.1.3 1.7.1.4 ADR გამოიყენება რადიოაქტიური მასალების საგზაო გადაზიდვებთან დაკავშირებით რადიოაქტიური მასალების გამოყენებასთან დაკავშირებული გადაზიდვების ჩათვლით. გადაზიდვა ითვალისწინებს ყოველგვარ ოპერაციასა და პირობას, რაც დაკავშირებულია და ჩართულია რადიოაქტიური მასალების გადაზიდვაში; აღნიშნული გულისხმობს შეფუთვების დაპროექტებას, წარმოებას, ტექნიკურ უზრუნველყოფასა და შეკეთებას, ასევე რადიოაქტიური მასალებისა და შეფუთვების ტვირთების მომზადებას, გადაცემას, დატვირთვას, გადაზიდვას სატრანზიტო შენახვის ჩათვლით, გადმოტვირთვასა და მიღებას საბოლოო დანიშნულების ადგილზე. ეტაპობრივი მიდგომა გამოიყენება ADRის სამოქმედო ნორმებთან დაკავშირებით, რომლებიც სირთულის მიხედვით ხასიათდება სამი ზოგადი დონით: (ა) გადაზიდვების ჩვეულებრივი პირობები (ყოველგვარი ინციდენტის გარეშე); (ბ) გადაზიდვის ნორმალური პირობები (უმნიშვნელო შემთხვევები); (გ) გადაზიდვის ავარიული პირობები. ADR-ში გათვალისწინებული დებულებები არ გამოიყენება შემდეგი ნივთიერებების გადაზიდვებთან დაკავშირებით: (ა) რადიოაქტიური მასალები, რომლებიც საშუალებების განუყოფელ ნაწილს; წარმოადგენს ავტოსატრანსპორტო (ბ) ნებისმიერი დაწესებულების ფარგლებში გადატანილი რადიოაქტიური მასალები, რომლებიც ექვემდებარება აღნიშნულ დაწესებულებაში მოქმედი სათანადო უსაფრთხოების წესებს, როდესაც გადაადგილება არ ეხება საზოგადოებრივი სარგებლობის საავტომობილო გზებსა და რკინიგზებს; (გ) ადამიანისა თუ ცხოველის ორგანიზმში იმპლანტირებული ან შეყვანილი რადიოაქტიური მასალები, რომლებიც განკუთვნილია სადიაგნოსტიკო ან სამკურნალო მიზნებისთვის; (დ) რადიოაქტიური მასალები სამკურნალო მიზნებისთვის გადაყვანილი ადამიანის სხეულში ან სხეულზე, თუ აღნიშნული პირის მიერ ადგილი ჰქონდა რადიოაქტიური მასალის შემთხვევით ან განზრახ მიღებას ან დაბინძურების ზემოქმედებას; (ე) მოხმარების საგნებში წარმოდგენილი რადიოაქტიური მასალები, რომელთა გამოყენებაც დაშვებულია მარეგულირებელი ორგანოების მიერ საბოლოო მომხმარებელზე მათი მიყიდვის შემდეგ; (ვ) ბუნებრივი რადიონუკლიდების შემცველი ბუნებრივი მასალები და მადნები (რომლებიც შესაძლებელია ყოფილიყო დამუშავებული), იმ პირობით, რომ აღნიშნული მასალის აქტივობის კონცენტრაცია 10-ჯერ არ გადააჭარბებს 2.2.7.2.2.1 პუნქტით გათვალისწინებულ ან 2.2.7.2.2.2(ა) და 2.2.7.2.2.3-2.2.7.2.2.6 პუნქტებით გამოთვლილ მნიშვნელობებს. ბუნებრივი რადიონუკლიდების შემცველი ბუნებრივი მასალებისა და მადნების შემთხვევაში, რომლებიც არ არის წარმოდგენილი ასწლოვან წონასწორობაში, აქტოვობის კონცენტრაციის გამოთვლა უნდა მოხდეს 2.2.7.2.2.4 პუნქტის შესაბამისად; 81 1.7.1.5 გამოთავისუფლებული შეფუთვების გადაზიდვებთან დაკავშირებული სპეციალური დებულებები 1.7.1.5.1 გამოთავისუფლებული შეფუთვები, რომლებიც შესაძლებელია შეიცავდეს შეზღუდული ოდენობის რადიოაქტიურ მასალებს, ხელსაწყოებს, საწარმოო ნაკეთობებსა და ცარიელ შეფუთვებს 2.2.7.2.4.1 პუნქტის შესაბამისად, უნდა დაექვემდებარონ მხოლოდ 5-7 ნაწილებში გათვალისწინებულ შემდეგ დებულებებს: (ა) 5.1.2, 5.1.3.2, 5.1.5.2.2, 5.1.5.2.3, 5.1.5.4, 5.2.1.9, 7.5.11 CV33 (3.1), (5.1)-(5.4) და (6) პუნქტებში გათვალისწინებულ მოქმედ დებულებებს; (ბ) 6.4.4 პუნქტში მითითებულ მოთხოვნებს გამოთავისუფლებულ შეფუთვებთან დაკავშირებით; და გარდა იმ შემთხვევებისა, როდესაც რადიოაქტიურ მასალას გააჩნია სხვა სახიფათო თვისებები და აუცილებელია მისი კლასიფიცირება მე-7 კლასის გარდა სხვა კლასშიც 3.3 თავის 290-ე ან 369-ე სპეციალური დებულების თანახმად, რა შემთხვევაშიც ზემოაღნიშნულ (ა) და (ბ) ქვეპუნქტებში გათვალისწინებული პირობები გამოიყენება მხოლოდ შესაბამისობისამებრ და ძირითად კლასთან დაკავშირებულ პირობებზე დამატებით. 1.7.1.5.2 გამოთავისუფლებული შეფუთვები ექვემდებარება ADR-ის ყველა დანარჩენი ნაწილით გათვალისწინებულ შესაბამის დებულებებს. იმ შემთხვევაში, თუ გამოთავისუფლებული შეფუთვები შეიცავს გაყოფად მასალას, გამოიყენება 2.2.7.2.3.5 პუნქტში გათვალისწინებული გამონაკლისები გაყოფად მასალასთან დაკავშირებით, ხოლო 7.5.11 CV33 (4.3) პუნქტით გათვალისწინებული მოთხოვნები ექვემდებარება შესრულებას. 1.7.2 გამოსხივებისგან დაცვის პროგრამა 1.7.2.1 რადიოაქტიური მასალების გადაზიდვა უნდა განხორციელდეს გამოსხივებისგან დაცვის პროგრამის შესაბამისად, რომელიც შედგება იმ სისტემატიური ღონისძიებებისგან, რომელთა მიზანია გამოსხივებისგან დაცვის ზომების სათადოდ განხორციელების უზრუნველყოფა. 1.7.2.2 ინდივიდუალურ პირებზე გამოყოფილი დოზები არ უნდა აღემატებოდეს შესაბამისი დოზების ფარგლებს. უნდა მოხდეს დაცვისა და უსაფრთხოების ოპტიმიზაცია იმ სახით, რომ ინდივიდუალური დოზების ზომა, დასხივებული ადამიანების რაოდენობა და დასხივების ალბათობა უნდა იყოს შენარჩუნებული ჯეროვნად მისაღწევ დაბალ დონეზე, ეკონომიკური და სოციალური ფაქტორების გათვალისწინებით იმ შეზღუდვების ფარგლებში, რომ ინდივიდუალური პირების მიერ მიღებული დოზები ექვემდებარება შეზღუდული დოზების მოქმედებას. მიღებულ უნდა იქნეს სტრუქტურული და სისტემატიური მიდგომა, რომელშიც ადგილი უნდა ჰქონდეს ურთიერთკავშირებს გადაზიდვებსა და სხვა სახის ღონისძიებებს შორის. 1.7.2.3 პროგრამის ფარგლებში გათვალისწინებული ღონისძიებების ხასიათი და მასშტაბურობა უნდა იყოს განპირობებული რადიაციული გამოსხივების სიდიდითა და ალბათობით. პროგრამა უნდა ითვალისწინებდეს 1.7.2.2, 1.7.2.4, 1.7.2.5 და 1.7.11 CV33 (1.1) პუნქტებში წარმოდგენილ მოთხოვნებს. პროგრამით გათვალისწინებული დოკუმენტები ხელმისაწვდომი უნდა იყოს მოთხოვნისთანავე კომპეტენტური ორგანოს მიერ შემოწმების განხორციელების მიზნით. 82 1.7.2.4 სატრანსპორტო ღონისძიებების საფუძველზე პროფესიული დასხივების შემთხვევაში, როდესაც შეფასების მიხედვით ეფექტური დოზა: (ა) სავარაუდოდ წარმოდგენილია 1-დან 6 მზვ-მდე წელიწადში, ამ შემთხვევაში უნდა განხორციელდეს დოზების შეფასების პროგრამა სამუშაო ადგილის მონიტორინგისა თუ ინდივიდუალური მონიტორინგის გზით; (ბ) სავარაუდოდ აღემატება 6 მზვ-ს წელიწადში, განხორციელდეს ინდივიდუალური მონიტორინგი. ამ შემთხვევაში უნდა ინდივიდუალური მონიტორინგის ან სამუშაო ადგილის მონიტორინგის შემთხვევაში, აუცილებელია შესაბამისი ჩანაწერების წარმოება. შენიშვნა: გადაზიდვებთან დაკავშირებული ღონისძიებების საფუძველზე წარმოშობილი პროფესიული დასხივების შემთხვევაში, როდესაც, შეფასების თანახმად, არსებობს ნაკლები ალბათობა იმისა, რომ ეფექტური დოზა აღემატებოდეს 1 მზვ-ს წელიწადში, არ იქნება აუცილებელი რაიმე სპეციალური სამუშაოს რეჟიმის დაწესება, დეტალური მონიტორინგის განხორციელება, დოზების შეფასების პროგრამების ჩატარება თუ ინდივიდუალური ჩანაწერების წარმოება. 1.7.2.5 მუშებს (იხილეთ 7.5.11, CV33 პუნქტი, მე-3 შენიშვნა) გავლილი უნდა ჰქონდეთ სათანადო მომზადება გამოსხივებისგან დაცვის სფეროში, სიფრთხილის ზომების ჩათვლით, რომელთა დაცვაც აუცილებელია მათი პროფესიული დასხივებისა და იმ სხვა პირების დასხივების შეზღუდვის მიზნით, რომელთაც შეიძლება ზიანი მიადგეს მათი მოქმედებების შედეგად. 1.7.3 მართვის სისტემა კომპეტენტური ორგანოსთვის მისაღებ საერთაშორისო, ეროვნულ თუ სხვა ნორმებზე დაფუძნებული მართვის სისტემა უნდა იქნეს შემუშავებული და განხორციელებული 1.7.1.3 პუნქტით გათვალისწინებული წესით, ADR-ის ფარგლებში განხორციელებულ ყოველგვარ მოქმედებასთან დაკავშირებით, ADR-ის დებულებებთან შესაბამისობის უზრუნველსაყოფად. კომპეტენტურ ორგანოს უნდა შეეძლოს დასტურის მიღება კონსტრუქციის სპეციფიკაციის სრულად განხორციელებასთან დაკავშირებით. მწარმოებელი, ტვირთგამგზავნი ან მომხმარებელი უნდა იყვნენ მზად, რათა: (ა) უზრუნველყონ შემოწმების შესაძლებლობა დამზადებისა თუ ექსპლუატაციის განმავლობაში; და (ბ) კომპეტენტურ ორგანოს უჩვენონ ADR-ით გათვალისწინებულ პირობებთან სრული შესაბამისობა. იმ შემთხვევაში, თუ აუცილებელია კომპეტენტური ორგანოს დასტური, აღნიშნული ოფიციალური დასტური გათვალისწინებული და წარმოდგენილი უნდა მართვის სისტემის ადეკვატურობის დადგენისთანავე. 1.7.4 სპეციალური პირობები 1.7.4.1 სპეციალური პირობები ნიშნავს კომპეტენტური ორგანოს მიერ დამტკიცებულ პირობებს, რომლის თანახმადაც შესაძლებელია ისეთი ტვირთების გადაზიდვა, 83 რომლებიც ვერ აკმაყოფილებს რადიოაქტიურ მასალებთან დაკავშირებით მოქმედ ADRის მოთხოვნებს. შენიშვნა: სპეციალური პირობები არ განიხილება, როგორც დროებითი გადახვევა 1.5.1 პუნქტის თანახმად. 1.7.4.2 ის ტვირთები, რომლებთან დაკავშირებითაც მე-7 კლასით გათვალისწინებულ ნებისმიერ დებულებასთან შესაბამისობა პრაქტიკულად შეუძლებელია, არ ექვემდებარება გადაზიდვებს, გარდა სპეციალური პირობებით გათვალისწინებული შემთხვევებისა. იმ შემთხვევაში, თუ კომპეტენტური ორგანო აღიარებს, რომ ADR-ით გათვალისწინებულ მე-7 კლასის დებულებებთან შესაბამისობა პრაქტიკულად შეუძლებელია და რომ ADR-ის მიერ დადგენილი უსაფრთხოების აუცილებელი ნორმების საფუძველზე, ალტერნატიული საშუალებების გამოყენების გზით, ნაჩვენები იქნა, რომ კომპეტენტურ ორგანოს შეუძლია დაადასტუროს სპეციალური პირობებით გათვალისწინებული სატრანსპორტო ოპერაციები მრავალჯერადი გადაზიდვების ერთი ან გეგმიური სერიებისთვის. გადაზიდვებში უსაფრთხოების საყოველთაო დონე უნდა იყოს ეკვივალენტური მინიმუმ იმ დონისა, რომელიც იქნებოდა უზრუნველყოფილი იმ შემთხვევაში, ყველა მოქმედი მოთხოვნის დაკმაყოფილებას რომ ჰქონოდა ადგილი. აღნიშნული ტიპის საერთაშორისო ტვირთების შემთხვევაში აუცილებელია მრავალმხრივი დამტკიცება. 1.7.5 სხვა სახიფათო თვისებების მქონე რადიოაქტიური მასალები რადიოაქტიური და გაყოფის თვისებების გარდა დოკუმენტაციასთან, შეფუთვასთან, უსაფრთხოების ნიშნებთან, მარკირებასთან, საინფორმაციო ტაბლოებთან, დასაწყობებასთან, დაყოფასა და გადაზიდვებთან დაკავშირებით გათვალისწინებული უნდა იქნეს შეფუთვის შიგთავსთან დაკავშირებული ნებისმიერი დამატებითი რისკი, როგორიცაა ფეთქებადობა, აალებადობა, პიროფორულობა, ქიმიური ტოქსიკურობა და კოროზიულობა, სახიფათო ტვირთების შესახებ ADR-ით გათვალისწინებულ დებულებებთან შესაბამისობის უზრუნველყოფის მიზნით. 1.7.6 შეუსაბამობა 1.7.6.1 ADR-ში გამოსხივებისა და დაბინძურების დონესთან დაკავშირებით დადგენილ ნებისმიერ ზღვართან შეუსაბამობის შემთხვევაში, (ა) (ბ) ტვირთგამგზავნს, ტვირთმიმღებს, გადამზიდველსა და გადაზიდვების მონაწილე ნებისმიერ ორგანიზაციას, რომელთაც შესაძლებელია მიადგეს ზიანი, უნდა ეცნობოთ მოთხოვნებთან შეუსაბამობის შემთხვევა: (i) გადამზიდველის მიერ იმ შემთხვევაში, თუ მოთხოვნებთან შეუსაბამობის ფაქტი გამოვლინდება გადაზიდვების დროს; (ii) ტვირთმიმღების მიერ იმ შემთხვევაში, თუ მოთხოვნებთან შეუსაბამობის ფაქტი გამოვლინდება ტვირთის მიღებისას; გადამზიდველმა, ტვირთგამგზავნმა შემთხვევიდან გამომდინარე: 84 ან ტვირთმიმღებმა, კონკრეტული (i) სასწრაფოდ უნდა მიიღონ შესაბამისი ზომები მოთხოვნებთან შეუსაბამობით გამოწვეული შედეგების გამოსასწორებლად; (ii) უნდა გამოიკვლიონ შეუსაბამობა გარემოებები და შედეგები; და მისი გამომწვევი მიზეზები, (iii) მიიღონ სათანადო ზომები, რათა აღმოფხვრან ის მიზეზები და გარემოებები, რომელთაც ხელი შეუწყეს შეუასაბამობას და მოახდინონ შეუსაბამობის გამომწვევი მსგავსი გარემოებების განმეორების პრევენცია; და (iv) შეატყობინონ კომპეტენტურ ორგანო(ებ)ს შეუსაბამობის გამომწვევი მიზეზები და განხორციელებული ან განსახორცილებელი მაკორექტირებელი ან პრევენციული ღონისძიებები; და (გ) შეუსაბამობის შესახებ უნდა ეცნობოს ტვირთგამგზავნსა და, შესაბამისად, კომპეტენტურ ორგანო(ებ)ს შეძლებისდაგვარად სწრაფად, ხოლო გამოსხივების ავარიული სიტუაციის გამოვლენის ან განვითარების შემთხვევაში დაუყოვნებლივ. 85 თავი 1.8 შემოწმებები და სხვა დამხმარე ღონისძიებები, რომლებიც უზრუნველყოფს უსაფრთხოებასთან დაკავშირებულ მოთხოვნებთან შესაბამისობას 1.8.1 სახიფათო ტვირთების ადმინისტრაციული კონტროლი 1.8.1.1 ხელშემკვრელი მხარეების კომპეტენტურ ორგანოებს შეუძლიათ მათი ეროვნული ტერიტორიის ფარგლებში, ნებისმიერ დროს, შეამოწმონ სახიფათო ტვირთების გადაზიდვებთან დაკავშირებული მოთხოვნების დაცვა, 1.10.1.5 პუნქტით გათვალისწინებული უსაფრთხოების ღონისძიებებით გათვალისწინებული მოთხოვნების ჩათვლით. თუმცა აღნიშნული შემოწმებები უნდა განხორციელდეს იმ სახით, რომ საფრთხე არ შეექმნას ადამიანებს, საკუთრებასა თუ გარემოს, ასევე მნიშვნელოვნად არ შეეშალოს ხელი საავტომობილო გზებით სარგებლობას. 1.8.1.2 სახიფათო ტვირთების გადაზიდვების მონაწილეებმა (თავი 1.4), ყოველგვარი დაგვიანების გარეშე, ნაკისრი სათანადო ვალდებულებების ფარგლებში უნდა მიაწოდონ კომპეტენტურ ორგანოებსა და მათ უფლებამოსილ პირებს ყოველგვარი აუცილებელი ინფორმაცია შემოწმებების განხორციელებასთან დაკავშირებით. 1.8.1.3 სახიფათო ტვირთების გადაზიდვებში მონაწილე საწარმოების შენობებში შემოწმებების განხორციელების მიზნით (თავი 1.4), კომპეტენტურ ორგანოებს ასევე შეუძლიათ ჩაატარონ შემოწმებები, შეისწავლონ საჭირო დოკუმენტები და აიღონ სახიფათო ტვირთებისა თუ ტარის ნიმუშები შესამოწმებლად ისე, რომ ამით საფრთხე არ შეექმნას უსაფრთხოებას. სახიფათო ტვირთების გადაზიდვების მონაწილეებმა (თავი 1.4) ასევე უნდა უზრუნველყონ ავტოსატრანსპორტო საშუალებებისა თუ მათი ნაწილების, აღჭურვილობისა და დანადგარების შესაძლო და ჯეროვანი ხელმისაწვდომობა შემოწმების მიზნით. იმ შემთხვევაში, თუ საჭიროდ მიიჩნევენ, მათ შეუძლიათ გამოჰყონ სპეციალური პირი საწარმოდან, რათა თან ახლდეს კომპეტენტური ორგანოს წარმომადგენელს. 1.8.1.4 იმ შემთხვევაში, თუ კომპეტენტური ორგანოები აღმოაჩენენ, რომ ADR-ის მოთხოვნები არ არის დაკმაყოფილებული, მათ შეუძლიათ აკრძალონ ტვირთის გაგზავნა ან შეაჩერონ ტრანსპორტირების ოპერაცია, სანამ არ მოხდება გამოვლენილი ხარვეზების აღმოფხვრა, ან უზრუნველყონ სხვა შესაბამისი ზომების მიღება. გადაზიდვა შეიძლება განხორციელდეს უშუალოდ ადგილზე ან ნებისმიერ სხვა ადგილზე, რომელსაც შეარჩევს კომპეტენტური ორგანო უსაფრთხოების დაცვის მიზნით. აღნიშნულმა ღონისძიებებმა არ უნდა გამოიწვიოს მნიშვნელოვანი შეფერხება საავტომობილო გზების ექსპლუატაციისას. 1.8.2 ორმხრივი ადმინისტრაციული მხარდაჭერა 1.8.2.1 ხელშემკვრელმა მხარეებმა უნდა აღმოუჩინონ ერთმანეთს ადმინისტრაციული მხარდაჭერა ADR-ის სისრულეში მოყვანის მიზნით. 1.8.2.2 იმ შემთხვევაში, თუ მხარეს გააჩნია სათანადო მიზეზი იმისათვის, რომ ჩათვალოს, რომ სახიფათო ტვირთების გადაზიდვის უსაფრთხოებას მის ტერიტორიაზე საფრთხე 86 ორმხრივი ექმნება იმ საწარმოების მიერ ძალზედ სერიოზული ან არაერთჯერადი დარღვევების შედეგად, რომელთაც გააჩნიათ სათაო ოფისი მეორე ხელშემკვრელი მხარის ტერიტორიაზე, მან უნდა აცნობოს აღნიშნული დარღვევების შესახებ შესაბამისი ხელშემკვრელი მხარის კომპეტენტურ ორგანოებს. ხელშემკვრელი მხარის კომპეტენტურ ორგანოებს, რომლის ტერიტორიაზეც გამოვლინდა ძალიან სერიოზული ან არაერთჯერადი დარღვევები, შეუძლიათ თხოვნით მიმართონ ხელშემკვრელი მხარის კომპეტენტურ ორგანოებს, რომელთაც ტერიტორიაზეც განთავსებულია საწარმოს სათაო ოფისი, მიიღოს შესაბამისი ზომები დამრღვევ(ებ)ის წინააღმდეგ. კონკრეტულ პირებთან დაკავშირებული მონაცემების გადაცემა დასაშვებია მხოლოდ იმ შემთხვევაში, როდესაც ეს აუცილებელია ძალიან სერიოზული ან არაერთჯერადი დარღვევებზე პასუხისმგებლობის ასაღებად. 1.8.2.3 იმ ორგანოებმა, რომელთაც მიეწოდათ შეტყობინება, უნდა აუწყონ შესაბამისი ხელშემკვრელი მხარის კომპეტენტურ ორგანოებს, რომელთა ტერიტორიაზეც გამოვლინდა დარღვევები, ის ღონისძიებები, რომლებიც, საჭიროების შემთხვევაში, განხორციელდა საწარმოსთან დაკავშირებით. 1.8.3 კონსულტანტი უსაფრთხოების საკითხებში 1.8.3.1 ნებისმიერმა საწარმომ, რომლის ვალდებულებებშიც შედის სახიფათო ტვირთების საგზაო გადაზიდვები ან აღნიშნულთან დაკავშირებული შეფუთვის ოპერაციები, დატვირთვა, შევსება თუ გადმოტვირთვა, უნდა დანიშნოს ერთი ან რამდენიმე კონსულტანტი სახიფათო ტვირთების გადაზიდვების უსაფრთხოების საკითხებში, რომელთა პასუხისმგებლობაშიც შევა ცალკეულ პირებთან, საკუთრებასა თუ გარემოსთან დაკავშირებით აღნიშნული ქმედებებით გამოწვეული რისკების პრევენცია. 1.8.3.2 ხელშემკვრელი მხარეების კომპეტენტურ ორგანოებს შეუძლიათ უზრუნველყონ, რომ მოხდეს აღნიშნული მოთხოვნების გამოყენება იმ საწარმოებთან დაკავშირებით: 1.8.3.3 (ა) რომელთა საქმიანობა მოიცავს სახიფათო ტვირთების გადაზიდვას უფრო მცირე რაოდენობებით ყოველ სატრანსპორტო ერთეულში, ვიდრე ეს მითითებულია 1.1.3.6, 1.7.1.4 პუნქტებსა და 3.3, 3.4 და 3.5 თავებში; ან (ბ) რომელთა ძირითადი ან დამატებითი საქმიანობა არ ითვალისწინებს ტვირთების გადაზიდვას ან აღნიშნულთან დაკავშირებულ დატვირთვა-გადმოტვირთვის ოპერაციებს, თუმცა რომელიც პერიოდულად ახორციელებს სახიფათო ტვირთების შიდა გადაზიდვებსა და მასთან დაკავშირებული ჩატვირთვა-გადმოტვირთვის ოპერაციებს, რასაც თან ახლავს დაბინძურების უმნიშვნელო საშიშროება ან რისკი. იმ კონსულტანტის ძირითადი დავალება, რომელიც ანგარიშვალდებულია საწარმოს ხელმძღვანელის წინაშე, ითვალისწინებს ყოველგვარი საშუალების მოძიებასა და ყოველგვარი სათანადო ზომის განხორციელებას, აღნიშნული საწარმოს შესაბამისი საქმიანობის ფარგლებში, რათა ხელი შეუწყოს საქმიანობის განხორციელებას მოქმედი მოთხოვნების შესაბამისად და მაქსიმალურად უსაფრთხო პირობებში. საწარმოს საქმიანობასთან მოვალეობები: - დაკავშირებით, სახიფათო ტვირთების გადაზიდვების შესრულების მონიტორინგი; 87 კონსულტანტს აკისრია მარეგულირებელი შემდეგი მოთხოვნების - კონსულტაციების გაწევა მისი გადაზიდვასთან დაკავშირებით; საწარმოს მიმართ სახიფათო ტვირთების - ყოველწლიური ანგარიშის მომზადება მისი საწარმოს ხელმძღვანელობის ან, აუცილებლობის შემთხვევაში, ადგილობრივი საჯარო ხელისფლების ორგანოს მიმართ სახიფათო ტვირთების გადაზიდვასთან დაკავშირებით საწარმოს საქმიანობის შესახებ. აღნიშნული წლიური ანგარიშები ინახება ხუთი წლის განმავლობაში და ხელმისაწვდომია ეროვნული ხელისუფლების ორგანოებისთვის მოთხოვნისთანავე. კონსულტანტის მოვალეობებში ასევე შედის საწარმოს სათანადო საქმიანობასთან დაკავშირებული შემდეგი პრაქტიკებისა და პროცედურების მონიტორინგი: - გადასატანი სახიფათო ტვირთების იდენტიფიკაციასთან მოთხოვნებთან შესაბამისობის უზრუნველყოფის პროცედურები; - საწარმოს პრაქტიკა, რომ სატრანსპორტო საშუალებების შესყიდვისას მოახდინოს გადასატან სახიფათო ტვირთებთან დაკავშირებული სპეციალური მოთხოვნების გათვალისწინება; - სახიფათო ტვირთების გადაზიდვასთან, დატვირთვასა და გადმოტვირთვასთან დაკავშირებით გამოსაყენებელი აღჭურვილობის შემოწმების პროცედურები; - საწარმოს მუშაკების სათანადო მომზადება და აღნიშნული მომზადების შესახებ ჩანაწერების წარმოება; - სათანადო, გადაუდებელი ღონისძიებების სისრულეში მოყვანა ნებისმიერი ავარიისა თუ ინციდენტის შემთხვევაში, რომელმაც შეიძლება ზიანი მიაყენოს უსაფრთხოებას სახიფათო ტვირთების გადაზიდვის, დატვირთვისა და გადმოტვირთვის დროს; - სერიოზული ავარიების, ინციდენტებისა თუ მნიშვნელოვანი დარღვევების, რომლებიც ვლინდება სახიფათო ტვირთების გადაზიდვების, დატვირთვისა თუ გადმოტვირთვის დროს, გამოძიება და, აუცილებლობის შემთხვევაში, ანგარიშების მომზადება; - სათანადო ზომების სისრულეში მოყვანა ავარიების, ინციდენტებისა სერიოზული დარღვევების განმეორების თავიდან არიდების მიზნით; - ქვეკონტრაქტორების ან მესამე მხარეების მიერ შერჩეული ან გამოყენებული სახიფათო ტვირთების გადაზიდვასთან დაკავშირებული ნორმატიული მითითებებისა და სპევიალური მოთხოვნების ანგარიშგება; - იმ ფაქტის შემოწმება, რომ სახიფათო ტვირთების გადაზიდვებში, დატვირთვისა და გადმოტვირთვის ოპერაციებში ჩართული მუშაკები გაცნობილნი არიან დეტალურ საოპერაციო პროცედურებსა და ინსტრუქციებს; - იმ ღონისძიებების დანერგვა, რომლებიც გაზრდის ცოდნას სახიფათო ტვირთების გადაზიდვებთან, დატვირთვასა და გადმოტვირთვასთან დაკავშირებული რისკების შესახებ; - შემოწმების პროცედურების განხორციელება გადასაზიდ სატრანსპორტო საშუალებებზე დოკუმენტაციისა და უსაფრთხოების აღჭურვილობის არსებობის უზრუნველსაყოფად, რომლებიც თან უნდა ახლდეს ავტოსატრანსპორტო 88 დაკავშირებულ თუ საშუალებას, ასევე აღნიშნული დოკუმენტებისა და აღჭურვილობის შესაბამისობის უზრუნველყოფა მოქმედ წესებთან; - შემოწმების პროცედურების განხორციელება დატვირთვისა და გადმოტვირთვის ოპერაციების მარეგულირებელ მოთხოვნებთან შესაბამისობის უზრუნველყოფის მიზნით; - 1.10.3.2 პუნქტში მითითებული უსაფრთხოების უზრუნველყოფის გეგმის არსებობა. 1.8.3.4 კონსულტანტი ასევე შეიძლება წამოადგენდეს საწარმოს ხელმძღვანელს, საწარმოში სხვა ვალდებულებების მქონე პირს ან აღნიშნული საწარმოს მიერ არაპირდაპირი გზით დაქირავებულ პირს იმ პირობით, რომ აღნიშნულ პირს შეეძლება კონსულტანტის მოვალეობების სისრულეში მოყვანა. 1.8.3.5 ყოველმა საწარმომ, მოთხოვნისამებრ, უნდა შეატყობინოს მისი კონსულტანტის ვინაობა კომპეტენტურ ორგანოს ან აღნიშნული მიზნით ყოველი ხელშემკვრელი მხარის მიერ დანიშნულ ორგანოს. 1.8.3.6 იმ შემთხვევაში, თუ შესაბამისი საწარმოს მიერ განხორციელებული გადაზიდვების ან ჩატვირთვა-გადმოტვირთვის ოპერაციების დროს მოხდება ავარია, რომელიც ზიანს მიაყენებს ადამიანებს, საკუთრებასა თუ გარემოს ან გამოიწვევს საკუთრებისა თუ გარემოს დაზიანებას, კონსულტანტმა, ყოველგვარი სათანადო ინფორმაციის შეგროვების შემდეგ, უნდა მოამზადოს ანგარიში ავარიის შესახებ საწარმოს ხელმძღვანელობის ან, საჭიროების შემთხვევაში, ადგილობრივი ხელისუფლების ორგანოების მიმართ. აღნიშნულმა ანგარიშმა არ უნდა შეცვალოს საწარმოს ხელმძღვანელობის მიერ მომზადებული ანგარიში, რომელიც შეიძლება მოთხოვნილ იქნეს ნებისმიერი სხვა საერთაშორისო თუ ეროვნული კანონმდებლობის მიერ. 1.8.3.7 კონსულტანტი უნდა ფლობდეს საგზაო გადაზიდვებთან დაკავშირებით მოქმედი პროფესიული მომზადების მოწმობას. ამ მოწმობას გასცემს კომპეტენტური ორგანო ან ხელშემკვრელი მხარის მიერ აღნიშნული მიზნით დანიშნული სხვა ორგანო. 1.8.3.8 მოწმობის მისაღებად კანდიდატმა უნდა გაიაროს მომზადება და ჩააბაროს ხელშემკვრელი მხარის კომპეტენტური ორგანოს მიერ დამტკიცებული გამოცდა. 1.8.3.9 მომზადების ძირითად მიზანს წარმოადგენს კანდიდატების უზრუნველყოფა სახიფათო ტვირთების გადაზიდვასთან დაკავშირებული რისკების, კანონმდებლობის, წესებისა და ადმინისტრაციული დებულებების შესახებ ცოდნით, რომლებიც გამოიყენება შესაბამისი ტრანსპორტის სახეობებთან, ასევე 1.8.3.3 პუნქტში ჩამოთვლილ მოვალეობებთან. 1.8.3.10 გამოცდის ორგანიზებას უზრუნველყოფს კომპეტენტური ორგანო ან კომპეტენტური ორგანოს მიერ დანიშნული საგამოცდო ორგანო. საგამოცდო ორგანო არ უნდა წარმოადგენდეს მომზადების პროვაიდერს. საგამოცდო ორგანოს დანიშვნა ხდება წერილობითი ფორმით. აღნიშნულ დასტურს შესაძლებელია ჰქონდეს შეზღუდული ვადა და უნდა ითვალისწინებდეს შემდეგ კრიტერიუმებს: - საგამოცდო ორგანოს კომპეტენცია; - საგამოცდო ორგანოს მიერ წარმოდგენილი გამოცდების ფორმის აღწერილობა; - გამოცდების ობიექტურობის უზრუნველსაყოფად გამიზნული ღონისძიებები; 89 1.8.3.11 ორგანოს დამოუკიდებლობა ყველა იმ ფიზიკური თუ იურიდიული პირისგან, რომელთაც სამსახურში აჰყავთ კონსულტანტი უსაფრთხოების დარგში. გამოცდის მიზანია იმ ფაქტის შემოწმება, გააჩნიათ თუ არა კანდიდატებს ცოდნის აუცილებელი დონე უსაფრთხოების საკითხებში კონსულტანტებზე გათვალისწინებული, 1.8.3.3 პუნქტში მითითებული მოვალეობების შესასრულებლად და 1.8.3.7 ქვეპუნქტში მითითებული მოწმობის მისაღებად, და უნდა ითვალისწინებდეს მინიმუმ შემდეგ საკითხებს: (ა) შედეგების ტიპების ცოდნა, რომელიც შესაძლებელია გამოწვეული იყოს სახიფათო ტვირთებთან დაკავშირებული ავარიით, ასევე ავარიის ძირითადი მიზეზების ცოდნა; (ბ) ეროვნული კანონმდებლობით, საერთაშორისო კონვენციებითა და შეთანხმებებით გათვალისწინებული მოთხოვნები, კერძოდ, შემდეგ საკითხებთან დაკავშირებით: - სახიფათო ტვირთების კლასიფიკაცია (ხსნარებისა და ნარევების, ნივთიერებათა ჩამონათვალის სტრუქტურის, სახიფათო ტვირთების კლასებისა და მათი კლასიფიკაციის პრინციპების, გადატანილი სახიფათო ტვირთების რაობის, სახიფათო ტვირთების ფიზიკური, ქიმიური და ტოქსიკოლოგიური მახასიათებლების კლასიფიცირებასთან დაკავშირებული პროცედურები); - შეფუთვასთან დაკავშირებული ზოგადი დებულებები, ცისტერნებსა და კონტეინერ-ცისტერნებთან დაკავშირებული დებულებები (ტიპები, კოდები, მარკირება, კონსტრუირება, საწყისი და პერიოდული შემოწმება და გამოცდა); - მარკირება და უსაფრთხოების ნიშნების მითითება, საინფორმაციო ტაბლოებისა და ნარინჯისფერი ტაბლოების განთავსება (შეფუთვებზე მარკირებისა და უსაფრთხოების ნიშნების მითითება, საინფორმაციო და ნარინჯისფერი ტაბლოების განთავსება და მოხსნა); - ჩანაწერები სატრანსპორტო დოკუმენტებში (მოთხოვნილი ინფორმაცია); - ტვირთის გაგზავნის მეთოდი და შეზღუდვა გაგზავნაზე (გადაზიდვები სრული დატვირთვით, მასიური ტვირთის გადაზიდვა, გადაზიდვები მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებით, გადაზიდვები კონტეინერებით, გადაზიდვები დამონტაჟებული და სახსნელი ცისტერნებით); - მგზავრების ტრანსპორტირება; - ერთობლივ დატვირთვასთან დაკავშირებული აკრძალვები და სიფრთხილის ზომები; - ტვირთების გამოყოფა; - გადატანილ რაოდენობებთან და გამოთავისუფლებულ რაოდენობებთან დაკავშირებული შეზღუდვები; - ტვირთების დამუშავება და დასაწყობება (დატვირთვა და გადმოტვირთვა შევსების კოეფიციენტები - დასაწყობება და გაყოფა); 90 1.8.3.12 - გასუფთავება და/ან დეგაზირება დატვირთვის წინ და გადმოტვირთვის შემდეგ; - ეკიპაჟი, პროფესიული მომზადება; - ავტოსატრანსპორტო საშუალებებზე არსებული დოკუმენტები (სატრანსპორტო დოკუმენტები, წერილობითი ინსტრუქციები, ავტოსატრანსპორტო საშუალების გადაზიდვებზე დაშვების მოწმობა, მძღოლის მომზადების მოწმობა, დადგენილი წესებიდან ნებისმიერი გადახვევის ასლები, სხვა დოკუმენტები); - წერილობითი ინსტრუქციები აღჭურვილობის გამოყენება); - ზედამხედველობასთან დაკავშირებული მოთხოვნები (პარკირება); - მოძრაობის წესები და შეზღუდვები; - საოპერაციო გამონაბოლქვი შემთხვევითი გაჟონვა; - სატრანსპორტო აღჭურვილობასთან დაკავშირებული მოთხოვნები. (ინსტრუქციებისა ან და ეკიპაჟის დამაბინძურებელი დამცავი ნივთიერებების გამოცდები 1.8.3.12.1 გამოცდა შედგება წერილობითი ტესტირებისგან, რომელსაც შეიძლება დაემატოს ზეპირი გამოცდაც. 1.8.3.12.2 წერილობითი ტესტირებისას არ დაიშვება სხვა დოკუმენტაციის გამოყენება, გარდა საერთაშორისო ან ეროვნული წესებისა. 1.8.3.12.3 ელექტრონული საშუალებების გამოყენება შესაძლებელია მხოლოდ იმ შემთხვევაში, თუ ისინი წარმოდგენილია საგამოცდო ორგანოს მიერ. კანდიდატს არ შეუძლია შეიტანოს რაიმე დამატებითი მონაცემები წარმოდგენილ ელექტრონულ საშუალებაში; კანდიდატს შეუძლია მხოლოდ პასუხი გასცეს დასმულ შეკითხვებს. 1.8.3.12.4 წერილობითი ტესტი შედგება ორი ნაწილისგან: (ა) კანდიდატებს გადაეცემათ კითხვარები, რომელიც შედგება არანაკლებ 20 ღია შეკითხვისგან მინიმუმ 1.8.3.11 პუნქტში წარმოდგენილ სიაში მითითებული თემების შესახებ. თუმცა მასში შეიძლება გამოყენებულ იქნეს შეკითხვები პასუხების რამდენიმე ვარიანტთან ერთად, რომელთა შორისაც უნდა მოხდეს შესაბამისი პასუხის შერჩევა. აღნიშნულ შემთხვევაში, პასუხების რამდენიმე ვარიანტის მქონე ორი შეკითხვა ითვლება ერთ ღია შეკითხვად. მითითებულ თემებს შორის განსაკუთრებული ყურადღება უნდა დაეთმოს შემდეგ თემებს: - პრევენციული და უსაფრთხოების უზრუნველყოფის საერთო ღონისძიებები; - სახიფათო ტვირთების კლასიფიკაცია; - ზოგადი დებულებები შეფუთვის შესახებ, ცისტერნებთან, კონტეინერცისტერნებთან, ავტოცისტერნებთან და ა.შ. დაკავშირებული დებულებების ჩათვლით; - საშიშროების შესახებ მარკირება და უსაფრთხოების ნიშნები; 91 (ბ) 1.8.3.13 - სატრანსპორტო დოკუმენტში მითითებული ინფორმაცია; - ტვირთების დამუშავება და დასაწყობება; - ეკიპაჟი, პროფესიული მომზადება; - სატრანსპორტო საშუალებებში წარმოდგენილი დოკუმენტები და მოწმობები გადაზიდვების შესახებ; - წერილობითი ინსტრუქციები; - სატრანსპორტო აღჭურვილობასთან დაკავშირებული დებულებები. კანდიდატებმა უნდა შეასრულონ პრაქტიკული დავალება 1.8.3.3 პუნქტში გათვალისწინებულ კონსულტანტის მოვალეობებთან დაკავშირებით, რათა მოახდინონ მათი აუცილებელი კვალიფიკაციის დემონსტრირება კონსულტანტის ფუნქციების სისრულეში მოყვანის მიზნით. ხელშემკვრელ მხარეებს შეუძლიათ მიიღონ გადაწყვეტილება იმასთან დაკავშირებით, რომ საჭიროა იმ კანდიდატებისთვის, რომელთაც სურთ მუშაობა საწარმოსთვის და გააჩნიათ გამოცდილება სახიფათო ტვირთების გარკვეული ტიპების გადაზიდვაში, მხოლოდ შეკითხვების დასმა მათ სამუშაოსთან დაკავშირებული ნივთიერებების შესახებ. ტვირთების აღნიშნულ ტიპებს განეკუთვნება: - პირველი კლასი; - მე-2 კლასი; - მე-7 კლასი; - მე-3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 8 და 9 კლასები; - გაეროს №1202, 1203, 1223, 3475 და გაეროს №1268 ან 1863 კლასიფიცირებული საავიაციო საწვავი. 1.8.3.7 პუნქტში გათვალისწინებულ მოწმობაში გარკვევით უნდა იყოს მითითებული, რომ ის ძალაშია მხოლოდ სახიფათო ტვირთების ერთ ტიპთან დაკავშირებით, რომელიც მითითებულია წინამდებარე ქვეპუნქტში და რომელთან დაკავშირებითაც შეკითხვები დაესვა კონსულტანტს 1.8.3.12 პუნქტში განსაზღვრული პირობების თანახმად. 1.8.3.14 კომპეტენტური ორგანო ან გამომცდელი ორგანო ადგენს იმ შეკითხვების მიმდინარე სიას, რომლებიც გათვალისწინებულია გამოცდაში. 1.8.3.15 1.8.3.7 პუნქტში გათვალისწინებული მოწმობა მზადდება 1.8.3.18 პუნქტში წარმოდგენილი ფორმით, რომელიც აღირებული უნდა იყოს ყოველი ხელშემკვრელი მხარის მიერ. 1.8.3.16 მოწმობების მოქმედების ვადა და განახლება 1.8.3.16.1 მოწმობის მოქმედების ვადა შეადგენს ხუთ წელიწადს. მოწმობის მოქმედების ვადის გახანგრძლივება შესაძლებელია მისი ვადის ამოწურვის დღიდან ყოველ ჯერზე ხუთი წლით იმ შემთხვევაში, თუ მისი ვადის ამოწურვის წინა წელს მისი მფლობელი წარმატებით ჩააბარებს გამოცდას. გამოცდა უნდა დამტკიცდეს კომპეტენტური ორგანოს მიერ. 92 1.8.3.16.2 გამოცდის მიზანია იმ ფაქტის დამტკიცება, რომ მოწმობის მფლობელს გააჩნია სათანადო ცოდნა 1.8.3.3 პუნქტში გათვალისწინებული მოვალეობების სისრულეში მოსაყვანად. მოთხოვნილი ცოდნა წარმოდგენილია 1.8.3.11(ბ) პუნქტში და ითვალისწინებს იმ წესებში განხორციელებულ შესწორებებსაც, რომლებიც წარმოდგენილ იქნა ბოლო მოწმობის გაცემის შემდეგ. გამოცდის ჩატარება და კონტროლი მოხდება იგივე მოთხოვნების საფუძველზე, რაც წარმოდგენილია 1.8.3.10 და 1.8.3.12-1.8.3.14 პუნქტებში. თუმცა მოწმობის მფლობელს არ მოეთხოვება 1.8.3.12.4(ბ) პუნქტით გათვალისწინებული პრაქტიკული ამოცანის შესრულება. 1.8.3.17 (ამოღებულია). 93 1.8.3.18 მოწმობის ნიმუში სახიფათო ტვირთების გადაზიდვასთან დაკავშირებით უსაფრთხოების საკითხებში კონსულტანტის მომზადება მოწმობა #: ............................................................................................................................................................... მოწმობის გამცემი სახელმწიფოს განმასხვავებელი ნიშანი: ......................................................................... გვარი: ........................................................................................................................................................................ სახელ(ებ)ი: .............................................................................................................................................................. დაბადების თარიღი და ადგილი: ........................................................................................................................ მოქალაქეობა: .......................................................................................................................................................... მფლობელის ხელმოწერა: .................................................................................................................................... ძალაშია ................ -მდე იმ საწარმოებთან დაკავშირებით, რომლებიც ახდენენ სახიფათო ტვირთების გადაზიდვას, ასევე იმ საწარმოებთან დაკავშირებით, რომლებიც ახორციელებენ აღნიშნულ გადაზიდვებთან დაკავშირებულ დატვირთვა-გადმოტვირთვის ოპერაციებს: საავტომობილო გზით რკინიგზით შიდა საწყალოსნო გზით გაცემულია: ................................................................................................................................................... მიერ თარიღი: .................................................................... ხელმოწერა: ................................................................. გაგრძელებულია: ........................................... -მდე .............................................................................. მიერ თარიღი: .................................................................... ხელმოწერა: ................................................................. 94 1.8.4 კომპეტენტური ორგანოებისა და მათ მიერ შერჩეული ორგანიზაციების ჩამონათვალი ხელშემკვრელი მხარეები აცნობებენ გაერთიანებული ერების ორგანიზაციის ევროპული ეკონომიკური კომისიის სამდივნოს შესაბამისი ორგანოებისა და მათ მიერ შერჩეული ორგანიზაციების მისამართებს, რომელთაც მინიჭებული აქვთ სათანადო კომპეტენცია ეროვნული კანონმდებლობის თანახმად ADR-ის სისრულეში მოყვანასთან დაკავშირებით, ყოველ ჯერზე ADR-ის შესაბამისი მოთხოვნის, ასევე იმ მისამართების მითითებით, სადაც იგზავნება შესაბამისი განაცხადებები. გაერთიანებული ერების ორგანიზაციის ევროპული ეკონომიკური კომისიის სამდივნომ უნდა განსაზღვროს ჩამონათვალი მიღებული ინფორმაციის საფუძველზე და უზრუნველყოს მისი მუდმივი განახლება. მან უნდა მიაწოდოს აღნიშნული ჩამონათვალი და მასში გათვალისწინებული შესწორებები ხელშემკვრელ მხარეებს. 1.8.5 ცნობები სახიფათო ტვირთებთან დაკავშირებული შემთხვევების შესახებ 1.8.5.1 იმ შემთხვევაში, თუ რომელიმე ხელშემკვრელი სახელმწიფოს ტერიტორიაზე სახიფათო ტვირთების დატვირთვის, შევსების, გადაზიდვის ან გადმოტვირთვის დროს მოხდება სერიოზული ავარია ან ინციდენტი, მტვირთავი, შემავსებელი, გადამზიდველი ან ტვირთმიმღები, კონკრეტული სიტუაციიდან გამომდინარე, უნდა დარწმუნდეს, რომ შესაბამისი მხარის კომპეტენტური ორგანოს მიმართ განხორციელდა 1.8.5.4 პუნქტში გათვალისწინებული ნიმუშის შესაბამისი ანგარიშის წარდგენა. 1.8.5.2 აუცილებლობის შემთხვევაში, ხელშემკვრელი მხარე, თავის მხრივ, წარუდგენს ანგარიშს გაერთიანებული ერების ორგანიზაციის ევროპული ეკონომიკური კომისიის სამდივნოს სხვა ხელშემკვრელი მხარეებისთვის ინფორმაციის მიწოდების მიზნით. 1.8.5.3 შემთხვევას, რომელიც მოითხოვს ანგარიშის შედგენას 1.8.5.1 პუნქტის შესაბამისად, ადგილი აქვს იმ შემთხვევაში, თუ მოხდება სახიფათო ტვირთების გამოთავისუფლება ან თუ არსებობს პროდუქტის დაკარგვის გარდაუვალი საფრთხე ან ადგილი ექნება ფიზიკურ დაზიანებას, მატერიალურ ან ეკოლოგიურ ზარალსა თუ ხელისუფლების ორგანოების ჩარევას და აღნიშნული შემთხვევა პასუხობს ერთ ან რამდენიმე ქვემოთ გათვალისწინებულ კრიტერიუმს: ფიზიკური დაზიანება გულისხმობს შემთხვევას, როდესაც ადგილი აქვს სახიფათო ტვირთებთან დაკავშირებით გამოწვეული გარდაცვალების ან უშუალოდ დაზიანების ფაქტს და აღნიშნული დაზიანება: (ა) საჭიროებს ინტენსიურ სამედიცინო მკურნალობას; (ბ) მოითხოვს ჰოსპიტალურ მკურნალობას მინიმუმ ერთი დღის განმავლობაში მაინც; ან (გ) გამოიწვევს შრომისუნარიანობის დაკარგვას მინიმუმ სამი თანმიმდევრული დღის განმავლობაში. პროდუქტის დანაკარგი ნიშნავს სახიფათო ტვირთების გამოთავისუფლებას (ა) 0 ან 1 სატრანსპორტო კატეგორიის 50 კგ/50 ლ ან მეტი ოდენობით; (ბ) 2 სატრანსპორტო კატეგორიის 333 კგ/333 ლ ან მეტი ოდენობით; ან (გ) 3 ან 4 სატრანსპორტო კატეგორიის 1 000 კგ/1 000 ლ ან მეტი ოდენობით. პროდუქტის დანაკარგის კრიტერიუმები აგრეთვე გამოიყენება იმ შემთხვევაში, თუ არსებობს პროდუქტის დაკარგვის გარდაუვალი საფრთხე ზემოაღნიშნული 95 ოდენობებით. როგორც წესი, აღნიშნული საფრთხე შესაძლებელია ნავარაუდევი იყოს იმ შემთხვევაში, თუ, სტრუქტურული დაზიანების მიღებით, ტვირთის განთავსების საშუალებები უკვე აღარ არის ვარგისი შემდგომი გადაზიდვებისთვის, ან იმ შემთხვევაში, თუ, ნებისმიერი სხვა მიზეზის გამო, ვეღარ უზრუნველყოფს უსაფრთხოების სათანადო დონეს (მაგალითად, ცისტერნების ან კონტეინერების დეფორმაციის, ცისტერნის გადაბრუნების ან უშუალო სიახლოვეს ხანძრის წარმოშობის მიზეზით). თუ საქმე ეხება 6.2 კლასით გათვალისწინებულ სახიფათო ტვირთებს, მაშინ ანგარიშის წარდგენის ვალდებულება მოქმედებს ტვირთის რაოდენობის ნებისმიერი სახით შეზღუდვის გარეშე. თუ ადგილი ექნება რადიოაქტიური მასალებით გამოწვეულ შემთხვევას, პროდუქტის დანაკარგის კრიტერიუმები შემდეგში მდგომარეობს: (ა) რადიოაქტიური მასალის ნებისმიერი სახით გამოთავისუფლება შეფუთვებიდან; (ბ) გამოსხივება, რომელიც იწვევს იონიზირებული გამოსხივებისგან მუშებისა და საზოგადოების წევრების დაცვის შესახებ წესებით დადგენილი საზღვრების დარღვევას (#115 IAEA უსაფრთხოების სერიების II ცხრილი - „იონიზირებული გამოსხივებისგან დაცვისა და გამოსხივების წყაროების უსაფრთხოებასთან დაკავშირებული საერთაშორისო ძირითადი საბაზო ნორმები“); ან (გ) როდესაც არსებობს იმ ფაქტის დამაჯერებელი საფუძველი, რომ ადგილი ჰქონდა შეფუთვის (ტვირთის შიგთავსის, დამცავი გარსის, თერმული დაცვისა თუ კრიტიკულობის) უსაფრთხოების ფუნქციის მნიშვნელოვან გაუარესებას, რასაც შეეძლო გამოეწვია შეფუთვის არასათანადოობა გადაზიდვების გასაგრძელებლად დამატებითი უსაფრთხოების ღონისძიებების გარეშე. შენიშვნა: მიუწოდებელ ტვირთებთან დაკავშირებით, იხილეთ 7.5.11 CV33 (6) პუნქტით გათვალისწინებული მოთხოვნები. მატერიალური ან ეკოლოგიური ზარალი ნიშნავს სახიფათო ტვირთების გამოთავისუფლებას, მიუხედავად მათი რაოდენობისა, როდესაც ზიანის შეფასებული ოდენობა სცდება 50,000 ევროს. სახიფათო ტვირთების შემცველ, უშუალოდ დაკავშირებულ გადაზიდვის საშუალებებსა და აღნიშნული სახეობის ინფრასტრუქტურაზე მიყენებული ზიანი ამ შემთხვევაში მხედველობაში არ მიიღება. ხელისუფლების ორგანოების ჩარევა ნიშნავს ხელისუფლების ორგანოების ან გადაუდებელი დახმარების სამსახურების უშუალო ჩარევას იმ შემთხვევების მიმდინარეობისას, რომლებიც დაკავშირებულია სახიფათო ტვირთებთან, ასევე ხალხის ევაკუაციასა და საზოგადოებრივი სარგებლობის გზების (საავტომობილო გზების/რკინიგზების) ჩაკეტვასთან, მინიმუმ სამი საათის განმავლობაში, სახიფათო ტვირთებით გამოწვეული საფრთხის მიზეზით. აუცილებლობის შემთხვევაში, კომპეტენტურ ორგანოს შეუძლია მოითხოვოს შესაბამისი დამატებითი ინფორმაცია. 1.8.5.4 სახიფათო ტვირთების გადაზიდვისას მომხდარი შემთხვევების ანგარიშის ნიმუში 96 სახიფათო ტვირთების გადაზიდვისას მომხდარი შემთხვევების ანგარიშის ნიმუში RID/ADR-ის 1.8.5 პუნქტის შესაბამისად გადამზიდველი/სარკინიგზო ინფრასტრუქტურის ოპერატორი: ..................................................................................................................................................................................... მისამართი: ..................................................................................................................................................................................... საკონტაქტო პირის სახელი: ........................................ ტელეფონი: ......................... ფაქსი: ........................... (კომპეტენტურმა ორგანომ უნდა ამოიღოს წინამდებარე პირველი ფურცელი ანგარიშის გადაგზავნამდე) 97 1. ტრანსპორტის სახეობა სარკინიგზო ტრანსპორტი ვაგონის ნომერი (არასავალდებულო) საავტომობილო ტრანსპორტი ავტოსატრანსპორტო საშუალების სარეგისტრაციო ნომერი (არასავალდებულო) ........................................................................................... ...................................................................................... 2. შემთხვევის თარიღი და ადგილი წელი: ............................. თვე: ........................... დღე: ................................... სარკინიგზო ტრანსპორტი სადგური მანევრირების/სორტირების სადგური დატვირთვის/გადმოტვირთვის/ გადატვირთვის ადგილი ადგილი/ქვეყანა: ................................................. ან ღია ხაზი: ხაზის აღწერილობა: ........................................... კილომეტრები: ................................................... დრო: ................................. საავტომობილო ტრანსპორტი გაშენებული სივრცე დატვირთვის/გადმოტვირთვის/ გადატვირთვის ადგილი ღია გზა: ადგილი/ქვეყანა: ................................................. 3. ტოპოგრაფია დახრილობა/დაქანება გვირაბი ხიდი/ხიდის ქვეშ გასასვლელი გადაკვეთა 4. განსაკუთრებული კლიმატური პირობები წვიმა თოვლი ყინული ნისლი ჭექა-ქუხილი შტორმი ტემპერატურა: ........ 0C 6. შემთხვევების აღწერილობა: რელსებიდან /გზის სავალი ნაწილიდან გადასვლა შეჯახება ამოტრიალება/გადაბრუნება ხანძარი აფეთქება დაკარგვა ტექნიკური გაუმართაობა შემთხვევის დამატებითი აღწერილობა: ............................................................................................................................................................................................................................ ............................................................................................................................................................................................................................ ............................................................................................................................................................................................................................ ............................................................................................................................................................................................................................ ............................................................................................................................................................................................................................ ............................................................................................................................................................................................................................ ............................................................................................................................................................................................................................ ............................................................................................................................................................................................................................ ............................................................................................................................................................................................................................ 98 6. გადასატანი სახიფათო ტვირთები გაეროს კლასი შეფუთვის ნომერი(1) ჯგუფი დაკარგული პროდუქტის შეფასებული რაოდენობა (კგ ან ლ)(2) შემცველობის საშუალებები (3) შემცველობის საშუალებების მასალა შემცველობის საშუალებების დაზიანების ტიპი(4) ერთობლივ პოზიციებზე მიკუთვნებულ სახიფათო (2) მე-7 კლასთან დაკავშირებით, მიუთითეთ ტვირთებთან დაკავშირებით, რომელთა მიმართაც მოქმედებს მნიშვნელობები 1.8.5.3 პუნქტში წარმოდგენილი 274-ე დებულება, ასევე უნდა მიეთითოს ტექნიკური დასახელება. კრიტერიუმების შესაბამისად. (3) მიუთითეთ შესაბამისი ნომერი: (4) მიუთითეთ შესაბამისი ნომერი 1 ტარა 1 დაკარგვა 2 მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი 2 ხანძარი 3 მსხვილგაბარიტიანი ტარა 3 აფეთქება 4 მცირე მოცულობის კონტეინერი 4 სტრუქტურის დაზიანება 5 ვაგონი 6 ავტოსატრანპორტო საშუალება 7 ვაგონი-ცისტერნა 8 ავტოცისტერნა 9 ვაგონი-ბატარეა 10 ავტოსატრანსპორტო საშუალება-ბატარეა 11 ვაგონი სახსნელი ცისტერნებით 12 სახსნელი ცისტერნა 13 დიდი მოცულობის კონტეინერი 14 კონტეინერ-ცისტერნა 15 მრავალელემენტიანი აირის კონტეინერი 16 გადამზიდი ცისტერნა 7. შემთხვევის გამომწვევი მიზეზი (თუ ზუსტად არის ცნობილი) ტექნიკური გაუმართაობა ტვირთის არასწორად დამაგრება საოპერაციო მიზეზი (სარკინიგზო ოპერაცია) სხვა: ............................................................................................................................................................................................................................ ............................................................................................................................................................................................................................ ............................................................................................................................................................................................................................ 8. შემთხვევის შედეგები: გადასატან სახიფათო ტვირთებთან დაკავშირებული ფიზიკური დაზიანება: გარდაცვალება (ციფრი: .....) სხეულის დაზიანება (ციფრი: ...........) (1) პროდუქტის დაკარგვა: დიახ არა პროდუქტის დაკარგვის გარდაუვალი რისკი მატერიალური/ეკოლოგიური დაზიანება: ზიანის შეფასებული მოცულობა < 50.000 ევრო ზიანის შეფასებული მოცულობა > 50.000 ევრო ხელისუფლების ორგანოების ჩარევა: დიახ ადამიანების ევაკუაცია მინიმუმ სამი საათის განმავლობაში, შესაბამისი სახიფათო ტვირთების ხასიათიდან გამომდინარე. საზოგადოებრივი სარგებლობის გზების გადაკეტვა მინიმუმ სამი საათის განმავლობაში, შესაბამისი სახიფათო ტვირთების ხასიათიდან გამომდინარე. არა აუცილებლობის შემთხვევაში, კომპეტენტურ ორგანოს შეუძლია მოითხოვოს შესაბამისი დამატებითი ინფორმაცია. 99 1.8.6 1.8.7 პუნქტში აღწერილი შესაბამისობის შეფასებებთან, პერიოდულ შემოწმებებთან, შუალედურ შემოწმებებსა და დაუგეგმავ შემოწმებებთან დაკავშირებული ადმინისტრაციული კონტროლის ზომები 1.8.6.1 საინსპექციო ორგანოების დამტკიცება კომპეტენტურ ორგანოს შეუძლია დაამტკიცოს საინსპექციო ორგანოები შესაბამისობის შეფასებების, პერიოდული შემოწმებების, შუალედური შემოწმებების, დაუგეგმავი შემოწმებებისა და შიდა საინსპექციო სამსახურის კონტროლის განხორციელების მიზნით, რაც გათვალისწინებულია 1.8.7 პუნქტში. 1.8.6.2 კომპეტენტური ორგანოს, მისი საოპერაციო ვალდებულებები წარმომადგენლისა თუ საინსპექციო ორგანოს 1.8.6.2.1 კომპეტენტურმა ორგანომ, მის წარმომადგენელმა ან საინსპექციო ორგანომ უნდა უზრუნველყოს შესაბამისობის შეფასებების, პერიოდული შემოწმებების, შუალედური შემოწმებებისა და დაუგეგმავი შემოწმებების განხორციელება პროპორციული სახით, არასაჭირო დატვირთვების თავიდან აცილებით. კომპეტენტურმა ორგანომ, მის წარმომადგენელმა ან საინსპექციო ორგანომ სისრულეში უნდა მოიყვანოს საკუთარი საქმიანობა შესაბამისი საწარმოების ზომის, სექტორისა და სტრუქტურის, ტექნოლოგიების შედარებითი სირთულისა და წარმოების სერიული მახასიათებლების გათვალისწინებით. 1.8.6.2.2 მიუხედავად აღნიშნულისა, კომპეტენტურმა ორგანომ, მის წარმომადგენელმა თუ საინსპექციო ორგანომ უნდა დაიცვას სიმკაცრე და უზრუნველყოს დაცულობა იმ დონით, რაც აუცილებელია დადგენილ მოთხოვნებთან გადამზიდი წნევის მოწყობილობის შესაბამისობისთვის, მე-4 და მე-6 ნაწილების მოქმედი დებულებების თანახმად. 1.8.6.2.3 იმ შემთხვევაში, თუ კომპეტენტური ორგანო, მისი წარმომადგენელი ან საინსპექციო ორგანო აღმოაჩენს, რომ მე-4 ან მე-6 ნაწილებში გათვალისწინებული მოთხოვნები არ იქნა შესრულებული მწარმოებლის მიერ, მან უნდა მოთხოვოს მწარმოებელს შესაბამისი მაკორექტირებელი ზომების მიღება და არ უნდა გასცეს რაიმე ოფიციალური დამტკიცების მოწმობა ან შესაბამისობის დამადასტურებელი მოწმობა. 1.8.6.3 ინფორმაციის წარდგენის ვალდებულება ADR-ის ხელშემკვრელმა მხარეებმა უნდა გამოაქვეყნონ ინფორმაცია საინსპექციო ორგანოების შეფასებასთან, დანიშვნასა და მონიტორინგთან დაკავშირებით მათი ეროვნული პროცედურების შესახებ, ასევე აღნიშნულ ინფორმაციაში ნებისმიერი ცვლილების განხორციელების შესახებ. 1.8.6.4 ინსპექტირების დავალების სისრულეში მოყვანის ვალდებულების გადაცემა შენიშვნა: 1.8.6.4 პუნქტის დებულებები არ მოქმედებს 1.8.6.7 გათვალისწინებულ შიდა საინსპექციო სამსახურებთან დაკავშირებით. 1.8.6.4.1 პუნქტით იმ შემთხვევაში, თუ საინსპექციო ორგანო მიმართავს ნებისმიერი სხვა სუბიექტის (მაგალითად, ქვეკონტრაქტორის, ფილიალის) მომსახურებებს, რათა სისრულეში მოიყვანოს შესაბამისობის შეფასებებთან, პერიოდულ შემოწმებებთან, შუალედურ შემოწმებებსა და დაუგეგმავ შემოწმებებთან დაკავშირებული კონკრეტული ამოცანები, აღნიშნული სუბიექტი გათვალისწინებული უნდა იყოს საინსპექციო ორგანოს 100 აკრედიტაციაში ან მისი აკრედიტაცია უნდა მოხდეს ცალკე. ცალკე აკრედიტაციის შემთხვევაში, აღნიშნული სუბიექტი სათანადოდ უნდა იქნეს აკრედიტრიებული EN ISO/IEC 17025:2005 სტანდარტის შესაბამისად და უნდა იქნეს აღიარებული საინსპექციო ორგანოს მიერ დამოუკიდებელ და მიუკერძოებელ საგამოცდო ლაბორატორიად, რათა სისრულეში მოიყვანოს გამოცდებთან დაკავშირებული დავალებები მისი აკრედიტაციის შესაბამისად ან იქნეს აკრედიტირებული EN ISO/IEC 17020:2012 სტანდარტის (გარდა 8.1.3 პუნქტისა) შესაბამისად. საინსპექციო ორგანომ უნდა უზრუნველყოს აღნიშნული სუბიექტის მიერ მასზე გადაცემული დავალებებით გათვალისწინებული მოთხოვნების სისრულეში მოყვანა კომპეტენციისა და უსაფრთხოების იგივე დონეზე, რაც გათვალისწინებულია თავად საინსპექციო ორგანოებისთვის (იხილეთ პუნქტი 1.8.6.8) და საინსპექციო ორგანომ უნდა უზრუნველყოს ყოველივე აღნიშნულის მონიტორინგი. საინსპექციო ორგანომ უნდა მიაწოდოს ინფორმაცია კომპეტენტურ ორგანოს ზემოაღნიშნული პირობების შესახებ. 1.8.6.4.2 საინსპექციო ორგანომ უნდა აიღოს სრული პასუხისმგებლობა აღნიშნული სუბიექტების მიერ განხორციელებულ დავალებებთან დაკავშირებით, იმის მიუხედავად, თუ სად მოხდება აღნიშნული დავალებების სისრულეში მოყვანა. 1.8.6.4.3 საინსპექციო ორგანომ არ უნდა გადასცეს შესაბამისობის შეფასებებთან, პერიოდულ შემოწმებებთან, შუალედურ შემოწმებებსა და დაუგეგმავ შემოწმებებთან დაკავშირებული სრული დავალება. ნებისმიერ შემთხვევაში შეფასებებისა და მოწმობების გაცემას უზრუნველყოფს თვითონ საინსპექციო ორგანო. 1.8.6.4.4 შესაბამისი საქმიანობების სისრულეში მოყვანის დაუშვებელია განმცხადებლის თანხმობის გარეშე. 1.8.6.4.5 საინსპექციო ორგანომ უნდა უზრუნველყოს ზემოაღნიშნული სუბიექტების კვალიფიკაციის შეფასებასა და მათ მიერ განხორციელებულ სამუშაოებთან დაკავშირებული შესაბამისი დოკუმენტების კომპეტენტური ორგანოს მიმართ წარდგენა. 1.8.6.5 საინსპექციო ორგანოების ვალდებულებები ინფორმაციის წარდგენასთან დაკავშირებით ვალდებულების ყოველმა საინსპექციო ორგანომ უნდა შეატყობინოს შემდეგი კომპეტენტურ ორგანოს, რომელმაც უზრუნველყო მისი დამტკიცება: გადაცემა ინფორმაცია იმ (ა) გარდა იმ შემთხვევებისა, როდესაც მოქმედებს 1.8.7.2.4 ქვეპუნქტით გათვალისწინებული დებულებები, ტიპის ოფიციალური დამტკიცების მოწმობების გაცემაზე უარის, მოქმედების არეალის შეზღუდვის, მოქმედების შეწყვეტისა თუ ექსპლუატაციიდან ამოღების შესახებ ინფორმაცია; (ბ) ნებისმიერი გარემოება (გარემოებები), რომელიც გავლენას ახდენს კომპეტენტური ორგანოს მიერ გაცემული დასტურის მოქმედების არეალსა და პირობებზე; (გ) ნებისმიერი მოთხოვნა შესრულებული ღონისძიებების შესაბამისობის შეფასებასთან დაკავშირებულ ინფორმაციაზე, რომელიც მიღებულ იქნა იმ კომპეტენტური ორგანოებისგან, რომლებიც ახორციელებენ მონიტორინგს შესაბამისობაზე 1.8.1 პუნქტის ან 1.8.6.6 ქვეპუნქტის თანახმად; (დ) მოთხოვნისამებრ, მათი დასტურის ფარგლებში განხორციელებული შესაბამისობის შეფასების ღონისძიებები და ნებისმიერი სხვა შესრულებული ღონისძიებები, ფუნქციების გადაცემის ჩათვლით. 101 1.8.6.6 კომპეტენტურმა ორგანომ უნდა უზრუნველყოს საინსპექციო ორგანოების მონიტორინგი და უნდა გააუქმოს ან შეზღუდოს გაცემული დასტური იმ შემთხვევაში, თუ შენიშნავს, რომ დამტკიცების ორგანო აღარ იმყოფება შესაბამისობაში დასტურსა და 1.8.6.8 ქვეპუნქტით გათვალისწინებულ მოთხოვნებთან ან არ ასრულებს ADR-ის დებულებებით გათვალისწინებულ პროცედურებს. 1.8.6.7 იმ შემთხვევაში, თუ მოხდება საინსპექციო ორგანოს დამტკიცების გაუქმება ან შეზღუდვა ან საინსპექციო ორგანო შეწყვეტს საკუთარ საქმიანობას, კომპეტენტურ ორგანოს შეუძლია მიმართოს შესაბამის ზომებს, რათა უზრუნველყოს არსებული დოკუმენტაციის დამუშავება სხვა საინსპექციო ორგანოს მიერ ან დატოვოს ისინი ხელმისაწვდომი. 1.8.6.8 საინსპექციო ორგანოს უნდა: (ა) ჰყავდეს საორგანიზაციო სტრუქტურასთან გაერთიანებული, მომზადებული, კომპეტენური და გამოცდილი პერსონალი, რომელსაც შეეძლება მისი ტექნიკური ფუნქციების დამაკმაყოფილებელ დონეზე მოყვანა სისრულეში; (ბ) გააჩნდეს წვდომა სათანადო და შესაბამის საშუალებებსა და აღჭურვილობასთან; (გ) იმოქმედოს მიუკერძოებლად და თავისუფალი იყოს ნებისმიერი გავლენისგან, რომელმაც შეიძლება ხელი შეუშალოს აღნიშნულში; (დ) უზრუნველყოს მწარმოებლებისა და სხვა ორგანოების კომერციული და საკუთრების უპირობო უფლებებით გათვალისწინებული ღონისძიებების კომერციული კონფიდენციალობის დაცვა; (ე) შეინარჩუნოს აშკარა ზღვარი საინსპექციო ორგანოს ფაქტიურ ფუნქციებსა და იმ ფუნქციებს შორის, რომლებიც არ არის დაკავშირებული მასთან; (ვ) აღჭურვილი იყოს ხარისხის კონტროლის დოკუმენტური სისტემით; (ზ) უზრუნველყოს შესაბამის სტანდარტებსა და ADR-ში გათვალისწინებული ტესტებისა და შემოწმებების სისრულეში მოყვანა; და (თ) უზრუნველყოს ეფექტური და სათანადო ანგარიშგებისა და აღრიცხვის სისტემა 1.8.7 და 1.8.8 პუნქტების შესაბამისად. საინსპექციო ორგანო დამატებით უნდა იყოს აკრედიტებული 6.2.2.10, 6.2.3.6 ქვეპუნქტებითა და 6.8.4 პუნქტის TA4 და TT9 დებულებებით გათვალისწინებული EN ISO/IEC 17020:2004 სტანდარტის შესაბამისად. საინსპექციო ორგანო, რომელიც იწყებს ახალ საქმიანობას, შეიძლება დამტკიცდეს დროებით. დროებით დამტკიცებამდე, კომპეტენტურმა ორგანომ უნდა უზრუნველყოს შესაბამისი საინსპექციო ორგანოს მიერ EN ISO/IEC 17020:2004 სტანდარტით გათვალისწინებული მოთხოვნების სისრულეში მოყვანა. საინსპექციო ორგანოს აკრედიტაცია უნდა განხორციელდეს მისი საქმიანობის პირველივე წელიწადს, რათა უფლება ჰქონდეს განაგრძოს აღნიშნული ახალი საქმიანობა. 1.8.7 შესაბამისობის შეფასებებისა და პერიოდული შემოწმებების პროცედურები შენიშვნა: წინამდებარე პუნქტში, „შესაბამისი ორგანო“ ნიშნავს ორგანოს, რომელიც მითითებულია 6.2.2.11 ქვეპუნქტში გაეროს წნევის ჭურჭლების სერტიფიცირებასთან 102 დაკავშირებით, 6.2.3.6 ქვეპუნქტში - იმ წნევის ჭურჭლების სერტიფიცირებასთან დაკავშირებით, რომლებიც არ წარმოადგენს გაეროს ჭურჭლებს და 6.8.4 პუნქტის TA4 და TT9 დებულებებში. 1.8.7.1 ზოგადი დებულებები 1.8.7.1.1 1.8.7 პუნქტში გათვალისწინებული პროცედურები გამოიყენება 6.2.3.6 ქვეპუნქტის შესაბამისად იმ წნევის ჭურჭლების სერტიფიცირებასთან დაკავშირებით, რომლებიც არ წარმოადგენს გაეროს ჭურჭლებს და 6.8.4 პუნქტის TA4 და TT9 დებულებების შესაბამისად, ცისტერნებთან, ავტოსატრანსპორტო საშუალება-ცისტერნებსა და მრავალელემენტიანი აირის კონტეინერებთან დაკავშირებით. 1.8.7 პუნქტში გათვალისწინებული პროცედურების გამოყენება შესაძლებელია 6.2.2.11 პუნქტში წარმოდგენილი ცხრილის შესაბამისად, გაეროს წნევის ჭურჭლების სერტიფიცირებისას. 1.8.7.1.2 ყოველი განაცხადი (ა) 1.8.7.2 პუნქტის შესაბამისად ტიპის დამტკიცებასთან დაკავშირებით; ან (ბ) 1.8.7.3 პუნქტის შესაბამისად წარმოების მეთვალყურეობასთან ან 1.8.7.4 პუნქტის შესაბამისად საწყის შემოწმებასა და გამოცდასთან დაკავშირებით; ან (გ) 1.8.7.5 პუნქტის შესაბამისად პერიოდულ შემოწმებასთან, შემოწმებასა და დაუგეგმავ შემოწმებებთან დაკავშირებით შუალედურ უნდა იქნეს წარდგენილი განმცხადებლის მიერ კონკრეტული კომპეტენტური ორგანოს, მის წარმომადგენლისა თუ დამტკიცებული საინსპექციო ორგანოს მიმართ, საკუთარი არჩევანისამებრ. 1.8.7.1.3 1.8.7.1.4 განაცხადში გათვალისწინებული უნდა იყოს: (ა) განმცხადებლის დასახელება და მისამართი; (ბ) იმ შესაბამისობის შეფასების შემთხვევაში, როდესაც განმცხადებელი წარმოადგენს მწარმოებელს, მწარმოებლის დასახელება და მისამართი; (გ) წერილობითი განცხადება იმის შესახებ, რომ აღნიშნული განაცხადის წარდგენა არ მომხდარა ნებისმიერ სხვა კომპეტენტური ორგანოს, მისი წარმომადგენლისა თუ საინსპექციო ორგანოს მიმართ; (დ) 1.8.7.7 პუნქტით გათვალისწინებული შესაბამისი ტექნიკური დოკუმენტაცია; (ე) განცხადება, რომლის საფუძველზე კომპეტენტურ ორგანოს, მის წარმომადგენელსა თუ საინსპექციო ორგანოს ეძლევა დაშვების ნებართვა წარმოების, შემოწმების, გამოცდისა და შენახვის ადგილზე შემოწმების ჩატარების მიზნით და რომელიც უზრუნველყოფს მას ყოველგვარი აუცილებელი ინფორმაციით. არ იმ შემთხვევაში, თუ განმცხადებელს შეუძლია დაამტკიცოს 1.8.7.6 პუნქტის მოთხოვნებთან შესაბამისობა კომპეტენტური ორგანოსა თუ მის მიერ უფლებამოსილი საინსპექციო ორგანოსთვის დამაკმაყოფილებელ დონეზე, განმცხადებელს შეუძლია ჩამოაყალიბოს შიდა საინსპექციო სამსახური, რომელსაც შეეძლება შემოწმებებისა და გამოცდების ნაწილობრივ ან სრულად ჩატარება, როგორც ეს მითითებულია 6.2.2.11 ან 6.2.3.6 პუნქტებში. 103 1.8.7.1.5 კონსტრუქციის ტიპის ოფიციალური დამტკიცებისა და შესაბამისობის მოწმობები ტექნიკური დოკუმენტაციის ჩათვლით - უნდა იქნეს დაცული მწარმოებლის ან განმცხადებლის მიერ, რომელიც წარმოადგენს განაცხადს კონსტრუქციის ტიპის ოფიციალური დამტკიცების შესახებ იმ შემთხვევაში, თუ ის არ არის მწარმოებელი, ასევე მოწმობის გამცემი საინსპექციო ორგანოს მიერ, მსგავსი ტიპის პროდუქტების წარმოების ბოლო დღიდან მინიმუმ 20 წლის განმავლობაში. 1.8.7.1.6 იმ შემთხვევაში, თუ მწარმოებელს ან მფლობელს სურს საკუთარი საქმიანობის შეწყვეტა, მან უნდა გაუგზავნოს დოკუმენტაცია კომპეტენტურ ორგანოს. კომპეტენტურმა ორგანომ უნდა შეინახოს აღნიშნული დოკუმენტაცია 1.8.7.1.5 ქვეპუნქტში გათვალისწინებული დარჩენილი ვადის განმავლობაში. 1.8.7.2 კონსტრუქციის ტიპის დამტკიცება ტიპის ოფიციალური დამტკიცება ანიჭებს შესაბამის უფლებამოსილებას წნევის ჭურჭლების, ცისტერნების, ავტოსატრანსპორტო-საშუალება ცისტერნებისა თუ მრავალელემენტიანი აირის კონტეინერების მწარმოებელს აღნიშნული დამტკიცების მოქმედების ვადის განმავლობაში. 1.8.7.2.1 1.8.7.2.2 განმცხადებელმა უნდა: (ა) წნევის ჭურჭლების შემთხვევაში, გადასცეს განკარგულებაში შესაბამის ორგანოს შესაბამისი პროდუქციის საპრეზენტაციო ნიმუშები. შესაბამის ორგანოს შეუძლია მოითხოვოს დამატებითი ნიმუშები იმ შემთხვევაში, თუ აღნიშნულის საჭიროება განპირობებული იქნება საგამოცდო პროგრამით; (ბ) ცისტერნების, ავტოსატრანსპორტო საშუალება-კონტეინერებისა თუ მრავალელემენტიანი აირის კონტეინერების შემთხვევაში, უზრუნველყოს წვდომა ექსპერიმენტულ ნიმუშზე კონსტრუქციის ტიპის ტესტირებასთან დაკავშირებით. შესაბამისმა ორგანომ უნდა: (ა) შეისწავლოს 1.8.7.1.1 პუნქტით გათვალისწინებული ტექნიკური დოკუმენტაცია, რათა შეამოწმოს ის ფაქტი, რომ კონსტრუქცია აკმაყოფილებს ADR-ის შესაბამის დებულებებს და რომ ექსპერიმენტული ნიმუშისა თუ ექსპერიმენტული ნიმუშების პარტიის წარმოება მოხდა ტექნიკური დოკუმენტაციის შესაბამისად და წარმოადგენს კონსტრუქციის თავისებურებას; (ბ) უზრუნველყოს დათვალიერება და გადაამოწმოს ADR-ით გათვალისწინებული გამოცდები იმ მიზნით, რომ განსაზღვროს შესაბამისი დებულებების გამოყენებისა და შესრულების წესი, ასევე მწარმოებლის მიერ დამტკიცებული პროცედურების არსებულ მოთხოვნებთან შესაბამისობა; (გ) შეამოწმოს მასალების მწარმოებლ(ებ)ის მიერ გაცემული მოწმობა (მოწმობები) ADR-ის შესაბამის დებულებებთან მიმართებაში; (დ) შესაბამისობის მიხედვით, დაამტკიცოს მეთოდები ნაწილების მუდმივ შეერთებასთან დაკავშირებით ან შეამოწმოს ჰქონდა თუ არა მათ დამტკიცებას ადგილი ადრე, ასევე დარწმუნდეს, რომ პერსონალი, რომელიც უზრუნველყოფს ნაწილების მუდმივ შეერთებას და ახორციელებს ცდებს არადესტრუქციულობაზე, არის თუ არა სათანადოდ კვალიფიცირებული ან დამტკიცებული; 104 (ე) შეათანხმოს განმცხადებელთან ადგილ-მდებარეობა და გამოცდის ობიექტები, სადაც უნდა განხორციელდეს შემოწმებები და აუცილებელი ტესტირებები. შესაბამისი ორგანო გასცემს ტიპის შემოწმების შესახებ ანგარიშს განმცხადებლის მიმართ. 1.8.7.2.3 იმ შემთხვევაში, თუ ტიპი აკმაყოფილებს ყველა მოქმედ დებულებას, კომპეტენტურმა ორგანომ, მის წარმომომადგენელმა ან საინსპექციო ორგანომ უნდა გასცეს კონსტრუქციის ტიპის ოფიციალური დამტკიცების მოწმობა განმცხადებელზე. ზემოაღნიშნულ მოწმობაში გათვალისწინებული უნდა იყოს: (ა) მისი გამცემი ორგანოს დასახელება და მისამართი; (ბ) მწარმოებლისა და განმცხადებლის დასახელება განმცხადებელი არ წარმოადგენს მწარმოებელს; (გ) მითითება ADR-ის სტანდარტებზე; ვერსიასა და ტიპის და მისამართი, შემოწმებასთან როდესაც დაკავშირებულ (დ) შემოწმების შედეგად გამოწვეული ნებისმიერი მოთხოვნა; (ე) კონსტრუქციის ტიპისა და მისი ვარიანტების იდენტიფიკაციისთვის საჭირო მონაცემები, რაც გათვალისწინებულია შესაბამისი სტანდარტით; (ვ) მითითება ტიპის შემოწმების ანგარიშ(ებ)ზე; და (ზ) ტიპის ოფიციალური დამტკიცების მაქსიმალური მოქმედების ვადა. მოწმობას უნდა დაერთოს ტექნიკური დოკუმენტაციის ჩამონათვალი (იხილეთ 1.8.7.7.1 ქვეპუნქტი). 1.8.7.2.4 შესაბამისი ნაწილების ტიპის ოფიციალური დამტკიცება ძალაში უნდა იყოს მაქსიმუმ ათი წლის განმავლობაში. იმ შემთხვევაში, თუ აღნიშნული პერიოდის განმავლობაში ADR-ის შესაბამის ტექნიკურ მოთხოვნებში შევა ისეთი სახის ცვლილება (იმ სტანდარტების ჩათვლით, რომელზეც გაკეთებულია მითითება), რომ ოფიციალურად დამტკიცებული ტიპი აღარ იქნება მათთან შესაბამისობაში, ტიპის ოფიციალური დამტკიცების გამცემმა ორგანომ უნდა გამოითხოვოს იგი და შეატყობინოს ტიპის ოფიციალური დამტკიცების მფლობელს აღნიშნულის შესახებ. შენიშვნა: არსებული ტიპის ოფიციალური დამტკიცებების გამოთხოვის საბოლოო თარიღთან დაკავშირებით, იხილეთ 6.8.2.6 პუნქტის ცხრილებში გათვალისწინებული (5) სვეტი და 6.8.2.6 ან 6.8.3.6 პუნქტები, კონკრეტული სიტუაციის მიხედვით. იმ შემთხვევაში, თუ ტიპის ოფიციალურად დამტკიცების ვადა ამოიწურება ან მოხდება მისი გამოთხოვა, წნევის ჭურჭლების, ცისტერნების, ავტოსატრანსპორტო საშუალებაბატარეებისა თუ მრავალელემენტიანი აირის კონტეინერების მწარმოებლებს აღარ ექნებათ უფლებამოსილება აღნიშნული ტიპის ოფიციალურ დამტკიცებასთან დაკავშირებით. ამ შემთხვევაში, წნევის ჭურჭლების, ცისტერნების, ავტოსატრანსპორტო საშუალებაბატარეებისა თუ მრავალელემენტიანი აირის კონტეინერების გამოყენებასთან, პერიოდულ შემოწმებასა და შუალედურ შემოწმებასთან დაკავშირებული შესაბამისი დებულებები, რომლებიც გათვალისწინებულია ტიპის ოფიციალურ დამტკიცებაში და რომლის ვადაც ამოიწურა ან იქნა გამოთხოვილი, კვლავ იქნება კანონიერ ძალაში 105 აღნიშნულ წნევის ჭურჭელთან, ცისტერნებთან, ავტოსატრანსპორტო საშუალებაბატარეებთან ან მრავალელემენტიან აირის კონტეინერებთან დაკავშირებით, რომლებიც დამზადებულია ტიპის ოფიციალური დამტკიცების ვადის ამოწურვამდე ან მის გამოთხოვამდე, თუკი შესაძლებელია მათი კვლავ ექსპლუატაცია. მათი ხელახალი ექსპლუატაცია შესაძლებელია მანამ, სანამ ისინი პასუხობს ADR-ის მოთხოვნებს. იმ შემთხვევაში, თუ ისინი ვეღარ დააკმაყოფილებს ADR-ით გათვალისწინებულ მოთხოვნებს, მათი ექსპლუატაცია შესაძლებელი იქნება მხოლოდ იმ შემთხვევაში, თუ აღნიშნული ექსპლუატაცია ნებადართულია 1.6 თავში გათვალისწინებული შესაბამისი გარდამავალი ღონისძიებებით. ტიპის ოფიციალური დამტკიცებების განახლება შესაძლებელია სრული მიმოხილვისა და შეფასების საფუძველზე განახლების დროისთვის მოქმედი ADR-ის დებულებების შესაბამისად. განახლება დაუშვებელია ტიპის ოფიციალური დამტკიცების გამოთხოვის შემდეგ. ტიპის არსებული ოფიციალური დამტკიცების შუალედური შესწორებები (მაგალითად, წნევის ჭურჭელთან დაკავშირებით, უმნიშვნელო ცვლილებები, როგორიცაა დამატებითი ზომებისა და მოცულობების დართვა, რაც გავლენას არ მოახდენს შესაბამისობაზე, ან ცისტერნებთან დაკავშირებით იხილეთ 6.8.2.3.2 ქვეპუნქტი) არ უზრუნველყოფს მოწმობის თავდაპირველი ვადის გახანგრძლივებას ან შეცვლას. შენიშვნა: შესაბამისობის მიმოხილვა და შეფასება შესაძლებელია განხორციელდეს იმ ორგანოს მიერ, რომელიც არ წარმოადგენს თავდაპირველი ტიპის ოფიციალური დამტკიცების გამცემს. გამცემმა ორგანომ უნდა შეინახოს ტიპის ოფიციალურ დამტკიცებასთან დაკავშირებული ყოველგვარი დოკუმენტაცია (იხილეთ 1.8.7.7.1 ქვეპუნქტი) მისი მოქმედების სრული ვადის განმავლობაში, განახლებების ჩათვლით, მათი უზრუნველყოფის შემთხვევაში. 1.8.7.2.5 მოქმედი, ამოწურული მოქმედების ვადის მქონე ან გამოთხოვილი ტიპის ოფიციალური დამტკიცების მქონე წნევის ქვეშ ჭურჭელთან, ცისტერნასთან, სატრანსპორტო საშუალება-ბატარეასთან ან მრავალელემენტიანი აირის კონტეინერთან დაკავშირებით ცვლილების განხორციელების შემთხვევაში, გამოცდა, შემოწმება და დამტკიცება შემოიფარგლება შეცვლილი წნევის ქვეშ ჭურჭლის, ცისტერნის, სატრანსპორტო საშუალება-ბატარეის ან მრავალელემენტიანი აირის კონტეინერის ნაწილებით. ცვლილება უნდა აკმაყოფილებდეს აღნიშნული ცვლილების განხორციელების დროისთვის მოქმედი ADR-ით გათვალისწინებულ დებულებებს. წნევის ქვეშ ჭურჭლის, ცისტერნის, სატრანსპორტო საშუალება-ბატარეის ან მრავალელემენტიანი აირის კონტეინერის იმ ნაწილებთან დაკავშირებით, რომელთა მიმართაც არ განხორციელდა ცვლილება, ტიპის პირველადი ოფიციალური დამტკიცების დოკუმენტაცია დარჩება კანონიერ ძალაში. ცვლილება შესაძლებელია შეეხოს ტიპის ოფიციალური დამტკიცების ფარგლებში წარმოდგენილ ერთ ან ერთზე მეტ წნევის ქვეშ ჭურჭელს, ცისტერნას, სატრანსპორტო საშუალება-ბატარეას ან მრავალელემენტიან აირის კონტეინერს. ცვლილების ოფიციალურად დამტკიცების მოწმობა გაიცემა განმცხადებლის მიმართ ADR-ის ნებისმიერი ხელშემკვრელი მხარის კომპეტენტური ორგანოს მიერ ან აღნიშნული ორგანოს მიერ მითითებული ნებისმიერი უწყების მიერ. ცისტერნის, 106 სატრანსპორტო საშუალება-ბატარეის ან მრავალელემენტიანი აირის კონტეინერის შემთხვევაში, მოწმობის ასლი უნდა ინახებოდეს ცისტერნის ჩანაწერებში. განმცხადებელმა უნდა წარუდგინოს ცვლილების ოფიციალური დამტკიცების მოწმობის გაცემასთან დაკავშირებული განაცხადი კონკრეტულ კომპეტენტურ ორგანოს ან აღნიშნული ორგანოს მიერ დანიშნულ ნებისმიერ უწყებას. 1.8.7.3 წარმოების კონტროლი 1.8.7.3.1 წარმოების პროცესი უნდა დაექვემდებაროს შესაბამისი ორგანოს კონტროლს, კონსტრუქციის ტიპის ოფიციალურ დამტკიცებასთან პროდუქციის წარმოების შესაბამისობის უზრუნველყოფის მიზნით. 1.8.7.3.2 განმცხადებელმა სისრულეში უნდა მოიყვანოს ყოველგვარი აუცილებელი ღონისძიება, რათა უზრუნველყოს წარმოების პროცესის შესაბამისობა ADR-ის, ტიპის ოფიციალური დამტკიცების მოწმობისა და მისი დანართებით გათვალისწინებულ მოქმედ დებულებებთან. 1.8.7.3.3 შესაბამისმა ორგანომ უნდა: (ა) შეამოწმოს 1.8.7.7.2 ქვეპუნქტით გათვალისწინებულ ტექნიკურ მოთხოვნებთან შესაბამისობა; (ბ) შეამოწმოს შეესაბამება თუ არა პროდუქტების წარმოების პროცესი მასთან დაკავშირებული დოკუმენტაციით გათვალისწინებულ მოთხოვნებს; (გ) შეამოწმოს მასალების მეთვალყურეობის შესაძლებლობა მასალების მოწმობ(ებ)ი სპეციფიკაციებთან მიმართებაში; და გადაამოწმოს (დ) შესაბამისობის მიხედვით, შეამოწმოს, რომ პერსონალი, რომელიც უზრუნველყოფს ნაწილების მუდმივ შეერთებასა და გამოცდას არადესტრუქციულობაზე, არის სათანადოდ კვალიფიციური ან დამტკიცებული; (ე) შეუთანხმდეს განმცხადებელს იმ ადგილ-მდებარეობის შესახებ, სადაც უნდა განხორციელდეს შემოწმებები და აუცილებელი გამოცდები; და (ვ) აღრიცხოს მის მიერ განხორციელებული გამოკვლევის შედეგები. 1.8.7.4 თავდაპირველი შემოწმება და გამოცდები 1.8.7.4.1 განმცხადებელმა უნდა: 1.8.7.4.2 (ა) მიუთითოს ADR-ით გათვალისწინებული მარკირების ნიშნები; და (ბ) მიაწოდოს 1.8.7.7 ქვეპუნქტით გათვალისწინებული ტექნიკური დოკუმენტაცია შესაბამის ორგანოს. შესაბამისმა ორგანომ უნდა: (ა) განახორციელოს აუცილებელი შემოწმებები და გამოცდები, რათა შეამოწმოს მოხდა თუ არა პროდუქტების წარმოება ტიპის ოფიციალური დამტკიცებისა და სათანადო დებულებების შესაბამისად; (ბ) შეამოწმოს სერვისული აღჭურვილობის მწარმოებლების მიერ მოწოდებული მოწმობები სერვისულ აღჭურვილობასთან მიმართებაში; 107 (გ) გასცეს თავდაპირველი შემოწმებისა და გამოცდების შესახებ ანგარიში განმცხადებლის მიმართ, ჩატარებული გამოცდებისა და შემოწმებების დეტალურ აღწერასთან და შემოწმებულ ტექნიკურ დოკუმენტაციასთან დაკავშირებით; (დ) შეადგინოს მწარმოებლის შესაბამისობის წერილობითი მოწმობა და მიუთითოს მისი რეგისტრირებული ნიშანი იმ შემთხვევაში, როდესაც მწარმოებელი აკმაყოფილებს არსებულ დებულებებს; და (ე) შეამოწმოს რჩება თუ არა კანონიერ ძალაში ტიპის ოფიციალური დამტკიცება მას შემდეგ, რაც შეიცვლება ტიპის ოფიციალურ დამტკიცებასთან დაკავშირებული ADR-ის დებულებები (იმ სტანდარტების ჩათვლით, რომელთან დაკავშირებითაც გაკეთდა მითითება). (დ) ქვეპუნქტით გათვალისწინებული მოწმობა და (გ) ქვეპუნქტით გათვალისწინებული ანგარიში შესაძლებელია ითვალისწინებდეს იგივე ტიპის ნაკეთობების ნომერსაც (ჯგუფური მოწმობა ან ჯგუფური ანგარიში). 1.8.7.4.3 მოწმობა უნდა შეიცავდეს მინიმუმ შემდეგ ინფორმაციას: (ა) შესაბამისი ორგანოს დასახელებას და მისამართს; (ბ) მწარმოებლის დასახელებასა და მისამართს და განმცხადებლის დასახელებასა და მისამართს, თუ იგი არ წარმოადგენს მწარმოებელს; (გ) მითითებას ADR-ის ვერსიასა და სტანდარტებზე, რომლებიც თავდაპირველ შემოწმებებსა და გამოცდებთან დაკავშირებით; გამოიყენება (დ) შემოწმებისა და გამოცდების შედეგები; (ე) შემოწმებული პროდუქტ(ებ)ის იდენტიფიკაციისთვის საჭირო მონაცემები, მინიმუმ სერიული ნომერი ან, ერთჯერადი გამოყენების ბალონების შემთხვევაში, პარტიის ნომერი; ან (ვ) კონსტრუქციის ტიპის დამტკიცების ნომერი. 1.8.7.5 პერიოდული შემოწმება, შუალედური შემოწმება და გამონაკლისი შემოწმებები 1.8.7.5.1 შესაბამისმა ორგანომ უნდა: (ა) მოახდინოს იდენტიფიკაცია შესაბამისობა; და შეამოწმოს არსებულ დოკუმენტაციასთან (ბ) განახორციელოს შემოწმებები და გადაამოწმოს დაკმაყოფილების შემოწმების მიზნით; (გ) გასცეს ანგარიშები შემოწმებებისა და გამოცდების შედეგების შესახებ, რაც შეიძლება ითვალისწინებდეს გარკვეული ოდენობის ნაკეთობებს; და გამოცდები მოთხოვნების (დ) უზრუნველყოს აუცილებელი მარკირების ნიშნების მითითება. 1.8.7.5.2 ანგარიშები წნევის ჭურჭლების პერიოდული შემოწმებებისა და გამოცდების შესახებ უნდა ინახებოდეს განმცხადებლის მიერ მინიმუმ მომდევნო პერიოდულ შემოწმებამდე. შენიშვნა: ცისტერნებთან დაკავშირებით იხილეთ 4.3.2.1.7 ქვეპუნქტში მოყვანილი ცისტერნის შესახებ ჩანაწერებით გათვალისწინებული დებულებები. 1.8.7.6 განმცხადებლის შიდა საინსპექციო მომსახურების კონტროლი 108 1.8.7.6.1 განმცხადებელმა უნდა: (ა) შეასრულოს შიდა საინსპექციო მომსახურება 1.8.7.7.5 ქვეპუნქტის თანახმად და კონტროლის საფუძველზე დოკუმენტური სახით წარმოდგენილ შემოწმებებსა და ტესტირებებეთან დაკავშირებული ხარისხის მართვის სისტემის მიხედვით; (ბ) შეასრულოს დამტკიცებული ხარისხის მართვის სისტემის საფუძველზე წარმოშობილი ვალდებულებები და უზრუნველყოს მისი შესაბამისობისა და ეფექტურობის შენარჩუნება; (გ) შეარჩიოს კვალიფიციური და კომპეტენტური პერსონალი შიდა საინსპექციო მომსახურების უზრუნველსაყოფად; და (დ) შესაბამისობის შემთხვევაში, მიუთითოს საინსპექციო ორგანოს რეგისტრირებული ნიშანი. 1.8.7.6.2 საინსპექციო ორგანომ უნდა უზრუნველყოს საწყისი აუდიტის ჩატარება. დამაკმაყოფილებელი შედეგების მიღების შემთხვევაში, საინსპექციო ორგანომ უნდა გასცეს ნებართვა არაუმეტეს სამი წლის ვადით. უნდა შესრულდეს შემდეგი დებულებები: (ა) ზემოაღნიშნული აუდიტით უნდა დამტკიცდეს, რომ პროდუქტთან დაკავშირებით განხორციელებული შემოწმებები და გამოცდები შეესაბამება ADR-ით გათვალისწინებულ მოთხოვნებს; (ბ) საინსპექციო ორგანოს შეუძლია გასცეს ნებართვა განმცხადებლის შიდა საინსპექციო მომსახურებასთან დაკავშირებით, რათა მიუთითოს საინსპექციო ორგანოს რეგისტრირებული ნიშანი ყოველ დამტკიცებულ პროდუქტზე; (გ) ნებართვის მოქმედების ვადის გახანგრძლივება შესაძლებელია დამაკმაყოფილებელი აუდიტის შემდეგ, რომელიც განხორციელდება მისი ვადის ამოწურვამდე ბოლო წელიწადის განმავლობაში. მოქმედების ახალი ვადის ათვლა იწყება ნებართვის ვადის ამოწურვის დღიდან; და (დ) საინსპექციო ორგანოს აუდიტორები უნდა იყვნენ კომპეტენტურნი, რათა უზრუნველყონ ხარისხის მართვის სისტემით გათვალისწინებული პროდუქტის შესაბამისობის შეფასება. 1.8.7.6.3 საინსპექციო ორგანომ უნდა განახორციელოს პერიოდული აუდიტი ნებართვის მოქმედების ვადის განმავლობაში, რათა დარწმუნდეს, რომ განმცხადებელს გააჩნია და იყენებს ხარისხის მართვის სისტემას. უნდა მოხდეს შემდეგი დებულებების დაკმაყოფილება: (ა) 12-თვიანი პერიოდის განმავლობაში უნდა ჩატარდეს მინიმუმ ორი აუდიტი; (ბ) საინსპექციო ორგანოს შეუძლია მოითხოვოს დამატებითი ვიზიტების, მომზადებების, ტექნიკური ცვლილებების განხორციელება, ხარისხის მართვის სისტემის შეცვლა, განმცხადებლის მიერ განსახორციელებელი შემოწმებებისა და გამოცდების შეზღუდვა ან აკრძალვა; (გ) საინსპექციო ორგანომ უნდა შეაფასოს ხარისხის მართვის სისტემაში განხორციელებული ნებისმიერი ცვლილება და მიიღოს გადაწყვეტილება იმასთან დაკავშირებით, თუ რამდენად დააკმაყოფილებს შეცვლილი ხარისხის მართვის სისტემა საწყისი აუდიტის მოთხოვნებს ან საჭიროა თუ არა სრული გადაფასება; 109 (დ) საინსპექციო ორგანოს აუდიტორებს უნდა გააჩნდეთ სათანადო კომპეტენცია ხარისხის მართვის სისტემით გათვალისწინებული პროდუქტების შესაბამისობის შეფასების სისრულეში მოყვანის მიზნით; და (ე) საინსპექციო ორგანომ უნდა წარუდგინოს განმცხადებელს ანგარიში ვიზიტისა თუ აუდიტის შესახებ, ხოლო გამოცდის ჩატარების შემთხვევაში, ასევე ანგარიში გამოცდის შესახებ. 1.8.7.6.4 არსებულ მოთხოვნებთან შეუსაბამობის შემთხვევაში, საინსპექციო ორგანომ უნდა უზრუნველყოს მაკორექტირებელი ღონისძიებების განხორციელება. იმ შემთხვევაში, თუ ადგილი არ ექნება მაკორექტირებელი ღონისძიებების დროულად განხორციელებას, საინსპექციო ორგანომ უნდა შეაჩეროს ან გამოითხოვოს ნებართვა შიდა საინსპექციო მომსახურებასთან დაკავშირებით მისი საქმიანობის სისრულეში მოყვანის მიზნით. შეტყობინება ნებართვის შეჩერებისა თუ გამოთხოვის შესახებ უნდა მიეწოდოს კომპეტენტურ ორგანოს. განმცხადებელს უნდა მიეწოდოს ანგარიში, სადაც მითითებული იქნება საინსპექციო ორგანოს მიერ მიღებული გადაწყვეტილებების მიზეზების დეტალური აღწერილობა. 1.8.7.7 დოკუმენტები ტექნიკური დოკუმენტაციის საფუძველზე უზრუნველყოფილი უნდა იქნეს შეფასების განხორციელება სათანადო მოთხოვნების შესაბამისად. 1.8.7.7.1 კონსტრუქციის ტიპის დამტკიცებასთან დაკავშირებული დოკუმენტები შესაბამისობის შემთხვევაში, განმცხადებელმა უნდა წარმოადგინოს: (ა) დაპროექტებასა და წარმოებასთან დაკავშირებით გამოსაყენებელი სტანდარტების ჩამონათვალი; (ბ) კონსტრუქციის ტიპის აღწერილობა ყოველგვარი ვარიანტის ჩათვლით; (გ) 3.2. თავის A ცხრილის შესაბამის სვეტში მითითებული ინსტრუქციები ან შესაბამის პროდუქტებთან დაკავშირებით გადასატანი სახიფათო ტვირთების ჩამონათვალი; (დ) ნახაზისა თუ ნახაზების საერთო კრებული; (ე) პროდუქტის დეტალური ნახაზები, მათ შორის გაანგარიშებებისთვის გამოყენებული ზომების, სერვისული აღჭურვილობის, კონსტრუქციული აღჭურვილობის, მარკირებისა და/ან უსაფრთხოების ნიშნების მითითების ჩათვლით, რაც აუცილებელია შესაბამისობის შესამოწმებლად; (ვ) გაანგარიშებების შესახებ შენიშვნები, მიღებული შედეგები და დასკვნები; (ზ) სერვისული აღჭურვილობის ჩამონათვალი შესაბამისი ტექნიკური მონაცემებითა და ინფორმაციით უსაფრთხოების მოწყობილობების შესახებ, შესაბამისობის შემთხვევაში, გამოთავისუფლების შესაძლებლობის გაანგარიშების ჩათვლით; (თ) წარმოებასთან დაკავშირებული სტანდარტით მოთხოვნილი მასალების ჩამონათვალი, რომლებიც გამოიყენება ყოველი ნაწილისთვის, ნაწილის ელემენტისთვის, საფარისთვის, სერვისული და კონსტრუქციული აღჭურვილობისთვის, ასევე შესაბამისი მასალების ტექნიკური დახასიათება ან ADR-ის მოთხოვნებთან შესაბამისობის სათანადო განაცხადი; 110 (ი) მუდმივი შეკავშირების მეთოდის დამტკიცებული კვალიფიკაცია; (კ) თერმული დამუშავების პროცეს(ებ)ის აღწერილობა; და (ლ) სტანდარტებითა თუ ADR-ით გათვალისწინებული ყველა შესაბამისი ტესტირების პროცედურები, აღწერილობა და ჩანაწერები კონსტრუქციის ტიპის დამტკიცებასა და წარმოებასთან დაკავშირებით. 1.8.7.7.2 წარმოების კონტროლთან დაკავშირებული დოკუმენტები შესაბამისობის მიხედვით, განმცხადებელმა უნდა წარმოადგინოს: (ა) 1.8.7.7.1 პუნქტში გათვალისწინებული დოკუმენტები; (ბ) ტიპის დამტკიცების მოწმობის ასლი; (გ) საწარმოო პროცედურები ტესტირების პროცედურების ჩათვლით; (დ) ჩანაწერები წარმოების შესახებ; (ე) მუდმივი შეკავშირების შემსრულებელ ოპერატორთა კვალიფიკაციის დამტკიცება; (ვ) არადესტრუქციულობაზე გამოცდის კვალიფიკაციის დამტკიცება; (ზ) ანგარიშები შესახებ; დესტრუქციულობასა და განმახორციელებელ ოპერატორთა არადესტრუქციულობაზე გამოცდების (თ) ჩანაწერები თერმული დამუშავების შესახებ; და (ი) 1.8.7.7.3 ჩანაწერები გრადუირების შესახებ. თავდაპირველ შემოწმებასა და გამოცდასთან დაკავშირებული დოკუმენტები შესაბამისობის მიხედვით, განმცხადებელმა უნდა წარმოადგინოს: (ა) 1.8.7.7.1 და 14.8.7.7.2 ქვეპუნქტებით გათვალისწინებული დოკუმენტები; (ბ) იმ მასალების მოწმობები, რომლებიც გამოიყენება პროდუქტსა თუ მის ნებისმიერ ნაწილთან დაკავშირებით; (გ) შესაბამისობის დეკლარაციები და სერვისული აღჭურვილობის დასამზადებლად გამოყენებული მასალების მოწმობები; და (დ) შესაბამისობის დეკლარაცია, პროდუქტის აღწერილობისა და კონსტრუქციის ტიპის დამტკიცებიდან მიღებული ყველა ვარიანტის ჩათვლით. 1.8.7.7.4 პერიოდულ შემოწმებებთან, შუალედურ შემოწმებებსა და გამონაკლის შემოწმებებთან დაკავშირებული დოკუმენტები შესაბამისობის მიხედვით, განმცხადებელმა უნდა წარმოადგინოს: (ა) წნევის ჭურჭლის შემთხვევაში - სპეციალური მოთხოვნების ამსახველი დოკუმენტები, როდესაც აღნიშნული მოთხოვნილია წარმოების, პერიოდული შემოწმებისა და გამოცდების სტანდარტებით; (ბ) ცისტერნების შემთხვევაში: (i) ჩანაწერები ცისტერნის შესახებ; და 111 (ii) 1.8.7.7.5 1.8.7.7.1-1.8.7.7.3 ქვეპუნქტებით გათვალისწინებული ერთი ან რამდენიმე დოკუმენტი. შიდა საინსპექციო მომსახურების შეფასებასთან დაკავშირებული დოკუმენტები შიდა საინსპექციო მომსახურებასთან დაკავშირებით განაცხადის წარდგენის შემთხვევაში, განმცხადებელმა უნდა უზრუნველყოს ხარისხის მართვის სისტემის დოკუმენტაციის ხელმისაწვდომობა, არსებული შესაძლებლობის ფარგლებში, რაც ითვალისწინებს: (ა) საორგანიზაციო სტრუქტურას და პასუხისმგებლობას; (ბ) შესაბამის ინსტრუქციებს შემოწმებასა და გამოცდასთან, ხარისხის მართვასთან, ხარისხის უზრუნველყოფასა და ტექნოლოგიურ პროცესებთან დაკავშირებით, ასევე სისტემატიურ ღონისძიებებთან დაკავშირებით, რომლებიც უნდა განხორციელდეს; (გ) ხარისხის შესახებ ჩანაწერებს, როგორიცაა ჩანაწერები შემოწმების შესახებ, გამოცდების მონაცემები, გრადუირების მონაცემები და მოწმობები; (დ) ხელმძღვანელობის მიერ წარმოდგენილ მიმოხილვებს ხარისხის მართვის სისტემის ეფექტური ფუნქციონირების უზრუნველყოფის მიზნით, რომელთა შედგენაც ხდება 1.8.7.6 პუნქტის შესაბამისად ჩატარებული აუდიტის საფუძველზე; (ე) პროცესს, რომელიც აღწერს, თუ რა სახით ხდება შემკვეთისა და განაწესით გათვალისწინებული მოთხოვნების დაკმაყოფილება; (ვ) დოკუმენტაციის კონტროლისა და მათი მიმოხილვის პროცესს; (ზ) იმ პროდუქტებთან დაკავშირებულ პროცედურებს, რომლებიც ვერ აკმაყოფილებს არსებულ მოთხოვნებს; და (თ) შესაბამისი პერსონალის მოსამზადებელ ასამაღლებელ პროცედურებს. 1.8.7.8 პროგრამებს პროდუქტები, რომლებიც დამზადებულია, დამტკიცებულია, გამოცდილია შესაბამისი სტანდარტების თანახმად და კვალიფიკაციის შემოწმებული და 1.8.7.7 პუნქტით გათვალისწინებული მოთხოვნები ჩაითვლება შესრულებულად იმ შემთხვევაში, თუ, კონკრეტული სიტუაციიდან გამომდინარე, გამოიყენება შემდეგი სტანდარტები: 1.8.8 მოქმედი პუნქტები და ქვეპუნქტები მითითებები დოკუმენტის დასახელება 1.8.7.7.1-დან 1.8.7.7.4-მდე EN 12972:2007 სახიფათო ტვირთების გადამზიდი ცისტერნები - ლითონის ცისტერნების გამოცდა, შემოწმება და მარკირება აირის ბალონების შესაბამისობის შეფასების პროცედურები აირის ბალონების შესაბამისობის წარმოდგენილი პროცედურა: შეფასებისას, 112 გამოიყენება ერთ-ერთი ქვემოთ (ა) 1.8.7 პუნქტში გათვალისწინებული პროცედურა იმ წნევის ჭურჭელთან დაკავშირებით, რომელიც არ შეესაბამება გაეროს რეკომენდაციებს, გარდა 1.8.7.5 პუნქტისა; ან (ბ) 1.8.8.1-1.8.8.7 პუნქტებით გათვალისწინებული პროცედურები. 1.8.8.1 ზოგადი დებულებები 1.8.8.1.1 წარმოების კონტროლი უნდა განხორციელდეს Xa ტიპის ორგანოს მიერ, ხოლო 6.2.6 პუნქტით მოთხოვნილი გამოცდა უნდა ჩატარდეს Xa ტიპის ორგანოს ან Xa ტიპის ორგანოს მიერ დამტკიცებული IS ტიპის ორგანოს მიერ; Xa და IS ტიპის ორგანოების განმარტებები იხილეთ 6.2.3.6.1 ქვეპუნქტში. შესაბამისობის შეფასებას უზრუნველყოფს ADR-ის ხელშემკვრელი მხარის კომპეტენური ორგანო, მისი წარმომადგენელი ან მის მიერ დამტკიცებული კომპეტენტური ორგანო. 1.8.8.1.2 1.8.8 პუნქტის თანახმად, განმცხადებელმა უნდა აჩვენოს, უზრუნველყოს და განაცხადოს, საკუთარი ერთპიროვნული პასუხისმგებლობით, აირის ბალონების შესაბამისობა 6.2.6 პუნქტით გათვალისწინებულ მოთხოვნებსა და ADR-ის სხვა მოქმედ დებულებებთან. 1.8.8.1.3 განმცხადებელმა უნდა: (ა) განახორციელოს აირის ბალონების ყოველი კონსტრუქციის ტიპის (გამოსაყენებელი მასალისა და აღნიშნული ტიპის ვარიანტების, მაგალითად, მოცულობისა და წნევის მნიშვნელობების, ნახაზებისა და ჩამკეტი და გამშვები მოწყობილობების ჩათვლით) შემოწმება, 1.8.8.2 პუნქტის შესაბამისად; (ბ) უზრუნველყოს დამტკიცებული ხარისხის მართვის სისტემის ექსპლუატაცია 1.8.8.3 პუნქტის შესაბამისად დაპროექტებასთან, წარმოებასთან, შემოწმებასა და გამოცდასთან დაკავშირებით; (გ) მოახდინოს დამტკიცებული გამოცდის რეჟიმის ექსპლუატაცია 1.8.8.4 პუნქტის შესაბამისად 6.2.6 პუნქტით მოთხოვნილ გამოცდებთან დაკავშირებით; (დ) მიმართოს მისი ხარისხის მართვის სისტემის დამტკიცებასთან დაკავშირებით წარმოების კონტროლისა და გამოცდის მიზნით ხელშემკვრელი მხარის ერთ Xa ტიპის ორგანოს, საკუთარი შეხედულებისამებრ; იმ შემთხვევაში, თუ განმცხადებელი არ არის დაფუძნებული ხელშემკვრელი მხარის ფარგლებში, მან უნდა მიმართოს ხელშემკვრელი მხარის ერთ Xa ტიპის ორგანოს შესაბამისი ხელშემკვრელი მხარის ტერიტორიაზე პირველი გადაზიდვის განხორციელებამდე; (ე) იმ შემთხვევაში, თუ ადგილი ექნება აირის ბალონების საბოლოო აწყობას განმცხადებლის მიერ დამზადებული ნაწილებისგან ერთი ან რამდენიმე სხვა საწარმოს მიერ, მან უნდა წარმოადგინოს წერილობითი ინსტრუქცია აირის ბალონების აწყობისა და შევსების შესახებ, კონსტრუქციის ტიპის შემოწმების მოწმობით გათვალისწინებული დებულებების შესაბამისად. 1.8.8.1.4 იმ შემთხვევაში, თუ განმცხადებელსა და იმ საწარმოებს, რომლებიც ახდენენ აირის ბალონების აწყობასა თუ შევსებას განმცხადებლის ინსტრუქციების შესაბამისად, შეუძლიათ Xa ტიპის ორგანოს მოთხოვნების თანახმად უზრუნველყონ 1.8.7.6 პუნქტით გათვალისწინებულ დებულებებთან შესაბამისობა, 1.8.7.6.1 (დ) და 1.8.7.6.2 (ბ) ქვეპუნქტების გარდა, მათ შეუძლიათ უზრუნველყონ შიდა საინსპექციო მომსახურება, რომლის საფუძველზეც განხორციელდება 6.2.6 პუნქტით გათვალისწინებულ ზოგიერთი ან ყველა შემოწმება და გამოცდა. 113 1.8.8.2 კონსტრუქციის ტიპის შემოწმება 1.8.8.2.1 განმცხადებელმა უნდა შეადგინოს ტექნიკური დოკუმენტაცია აირის ბალონის თითოეულ ტიპთან დაკავშირებით, გამოყენებული ტექნიკური სტანდარტ(ებ)ის ჩათვლით. იმ შემთხვევაში, თუ ის უპირატესობას მიანიჭებს იმ სტანდარტის გამოყენებას, რომელიც არ არის გათვალისწინებული 6.2.6 პუნქტში, მან უნდა დაურთოს გამოყენებული სტანდარტი დოკუმენტაციას. 1.8.8.2.2 განმცხადებელმა უნდა შეინახოს ტექნიკური დოკუმენტაცია აღნიშნული ტიპის ნიმუშებთან ერთად Xa ტიპის ორგანოს მიმართ წარდგენის მიზნით წარმოების პროცესში და მის შემდეგ მინიმუმ ხუთი წლის განმავლობაში, აღნიშნული ვადის ათვლა დაიწყება აირის ბალონების წარმოების ბოლო დღიდან, კონსტრუქციის შესაბამისი ტიპის შემოწმების მოწმობის თანახმად. 1.8.8.2.3 გულდასმით შემოწმების შემდეგ, განმცხადებელმა უნდა გასცეს კონსტრუქციის ტიპის მოწმობა, რომელიც ძალაში იქნება მაქსიმუმ ათი წლის განმავლობაში; მან უნდა დაურთოს აღნიშნული მოწმობა დოკუმენტაციას. მოცემული მოწმობა უფლებამოსილს ხდის მას აწარმოოს აღნიშნული ტიპის აირის ბალონები შესაბამისი პერიოდის განმავლობაში. 1.8.8.2.4 იმ შემთხვევაში, თუ ზემოაღნიშნული პერიოდის განმავლობაში შეიცვლება ADR-ის შესაბამისი ტექნიკური მოთხოვნები (მითითებული სტანდარტების ჩათვლით), რის შედეგადაც კონსტრუქციის ტიპი აღარ იქნება მათთან შესაბამისობაში, განმცხადებელმა უნდა გამოითხოვოს მისი ტიპის შემოწმების მოწმობა და შეატყობინოს აღნიშნულის შესახებ Xa ტიპის ორგანოს. 1.8.8.2.5 ყურადღებით და სრული მიმოხილვის შემდეგ, განმცხადებელს შეუძლია ხელახლა გასცეს მოწმობა კიდევ ერთი, მაქსიმუმ ათწლიანი პერიოდით. 1.8.8.3 წარმოების კონტროლი 1.8.8.3.1 კონსტრუქციის ტიპის შემოწმების პროცედურის, ასევე წარმოების პროცესის შემოწმება უნდა მოხდეს Xa ტიპის ორგანოს მიერ იმ ფაქტის უზრუნველყოფის მიზნით, რომ განმცხადებლის მიერ დამტკიცებული ტიპი და წარმოებული პროდუქტი შეესაბამება კონსტრუქციის ტიპის მოწმობით გათვალისწინებულ და ADR-ის მოქმედ დებულებებს. 1.8.8.1.3(ე) ქვეპუნქტის გამოყენების შემთხვევაში, აღნიშნულ პროცედურაში უნდა მოხდეს აწყობისა და შევსების შემსრულებელი საწარმოების გათვალისწინება. 1.8.8.3.2 განმცხადებელმა უნდა მიმართოს ყოველგვარ აუცილებელ ზომას, რათა უზრუნველყოს წარმოების პროცესის შესაბამისობა ADR-ის, წინამდებარე კონსტრუქციის ტიპის მოწმობისა და მისი დანართების მოქმედ დებულებებთან. 1.8.8.1.3(ე) ქვეპუნქტის გამოყენების შემთხვევაში, აღნიშნულ პროცედურაში უნდა მოხდეს აწყობისა და შევსების შემსრულებელი საწარმოების გათვალისწინება. 1.8.8.3.3 Xa ტიპის ორგანომ უნდა (ა) (ბ) შეამოწმოს განმცხადებლის მიერ განხორციელებული კონსტრუქციის ტიპის შემოწმების შესაბამისობა და აირის ბალონების ტიპის შესაბამისობა 1.8.8.2 პუნქტით გათვალისწინებულ ტექნიკურ დოკუმენტაციასთან; შეამოწმოს პროდუქტების წარმოების პროცესის შესაბამისობა მასთან დაკავშირებით მოქმედ მოთხოვნებსა და დოკუმენტაციასთან; იმ შემთხვევაში, თუ აირის ბალონის საბოლოო აწყობას განმცხადებლის მიერ დამზადებული 114 ნაწილებისგან უზრუნველყოფს ერთი ან რამდენიმე მწარმოებელი, Xa ტიპის ორგანომ ასევე უნდა შეამოწმოს, სრულად აკმაყოფილებს თუ არა აირის ბალონი მოქმედ დებულებებს საბოლოო აწყობისა და შევსების შემდეგ და სწორად არის თუ არა გამოყენებული განმცხადებლის ინსტრუქციები; (გ) შეამოწმოს არის თუ არა ნაწილების მუდმივ შეკავშირებასა და გამოცდაზე პასუხისმგებელი პერსონალი სათანადოდ კვალიფიციური და დამტკიცებული; (დ) აღრიცხოს მის მიერ განხორციელებული შემოწმებების შედეგები. 1.8.8.3.4 იმ შემთხვევაში, თუ Xa ტიპის ორგანოს მიერ მიღებული მონაცემების თანახმად, ადგილი აქვს განმცხადებლის მიერ გაცემული კონსტრუქციის ტიპის მოწმობისა თუ წარმოების პროცესის შეუსაბამობას, მან უნდა მოითხოვოს განმცხადებლისგან სათანადო მაკორექტირებელი ღონისძიებების განხორციელება ან უკან გამოიწვიოს მოწმობა. 1.8.8.4 გამოცდა ჰერმეტულობაზე 1.8.8.4.1 განმცხადებელმა და იმ საწარმოებმა, რომლებიც უზრუნველყოფენ აირის ბალონების საბოლოო აწყობასა და შევსებას განმცხადებლის ინსტრუქციების შესაბამისად, უნდა: (ა) (ბ) (გ) მოიყვანონ სისრულეში 6.2.6 პუნქტით გათვალისწინებული ცდები; აღრიცხონ ცდების შედეგები; გასცენ შესაბამისობის მოწმობა მხოლოდ იმ აირის ბალონებზე, რომლებიც სრულად აკმაყოფილებს მისი კონსტრუქციის ტიპის შემოწმებით გათვალისწინებულ დებულებებსა და ADR-ის მოქმედ დებულებებს და წარმატებით გაიარეს 6.2.6 პუნქტით მოთხოვნილი გამოცდა; (დ) შეინახონ 1.8.8.7 ქვეპუნქტით გათვალისწინებული დოკუმენტაცია წარმოების და მის შემდეგ მინიმუმ ხუთი წლის განმავლობაში, აღნიშნული ვადის ათვლა იწყება იმ აირის ბალონების წარმოების ბოლო დღიდან, რომლებიც მიეკუთვნება ერთ ტიპს Xa ტიპის ორგანოს მიერ თავისუფალი ინტერვალებით შემოწმების ჩატარების მიზნით; (ე) მიუთითოს მდგრადი და მკაფიო ნიშანი აირის ბალონის ტიპის, განმცხადებლისა და წარმოების თარიღის ან პარტიის ნომრის მითითებით; იმ შემთხვევაში, თუ შეზღუდული სივრცის არსებობის მიზეზით შეუძლებელია ნიშნის სრულად მითითება აირის ბალონის კორპუსზე, მან უნდა წარმოადგინოს აღნიშნული ინფორმაციის შემცველი მდგრადი ეტიკეტი აირის კონტეინერზე ან მოათავსოს იგი აირის კონტეინერთან ერთად შიდა ტარაში. 1.8.8.4.2 Xa ტიპის ორგანომ უნდა (ა) (ბ) (გ) მოიყვანოს სისრულეში აუცილებელი შემოწმებები და ცდები არარეგულარული ინტერვალით, მაგრამ აირის ბალონების შესაბამისი ტიპის წარმოების დაწყებიდან მოკლე დროში და შემდგომ ამისა, მინიმუმ ყოველ სამ წელიწადში ერთხელ მაინც იმ მიზნით, რათა დარწმუნდეს, რომ განმცხადებლის კონსტრუქციის ტიპის შემოწმების პროცედურა, ასევე პროდუქტის წარმოება და ტესტირება ხორციელდება კონსტრუქციის ტიპის მოწმობისა და სათანადო დებულებების შესაბამისად; შეამოწმოს განმცხადებლის მიერ მოწოდებული მოწმობები; ჩაატაროს ცდები 6.2.6 პუნქტით გათვალისწინებული მოთხოვნების შესაბამისად ან დაამტკიცოს საცდელი პროგრამა და შიდა საინსპექციო მომსახურება, ცდების განხორციელების მიზნით. 115 1.8.8.4.3 მოწმობა უნდა ითვალისწინებდეს მინიმუმ შემდეგ ინფორმაციას: (ა) განმცხადებლის დასახელება და მისამართი და, იმ შემთხვევაში, თუ საბოლოო აწყობა სრულდება არა განმცხადებლის, არამედ საწარმოსა თუ საწარმოების მიერ, განმცხადებლის წერილობითი ინსტრუქციების შესაბამისად, აღნიშნული საწარმოების სახელ(ებ)ი და მისამართ(ებ)ი; (ბ) მითითება ADR-ის ვარიანტსა და წარმოებასა და გამოცდასთან დაკავშირებით გამოყენებულ სტანდარტ(ებ)თან; (გ) შემოწმებებისა და გამოცდების შედეგები; (დ) მარკირებასთან დაკავშირებული მონაცემები, 1.8.7.4.1(ე) პუნქტით გათვალისწინებული მოთხოვნის შესაბამისად. 1.8.8.5 (რეზერვირებულია) 1.8.8.6 შიდა საინსპექციო მომსახურების კონტროლი იმ შემთხვევაში, თუ განმცხადებელი ან საწარმო, რომელიც ახდენს აირის ბალონების აწყობას ან შევსებას, დააფუძნებს შიდა საინსპექციო სამსახურს, მოქმედებს 1.8.7.6 პუნქტით გათვალისწინებული დებულებები, გარდა 1.8.7.6.1(დ) და 1.8.7.6.2(ბ) ქვეპუნქტებისა. საწარმო, რომელიც უზრუნველყოფს აირის ბალონების აწყობას ან შევსებას, უნდა აკმაყოფილებდეს განმცხადებელთან დაკავშირებით მოქმედ დებულებებს. 1.8.8.7 დოკუმენტები გამოყენებულ უნდა იქნეს 1.8.7.7.1, 1.8.7.7.2, 1.8.7.7.3 და 1.8.7.7.5 ქვეპუნქტით გათვალისწინებული დებულებები. 116 თავი 1.9 კომპეტენტური ორგანოების მიერ დაწესებული შეზღუდვები გადაზიდვებთან დაკავშირებით 1.9.1 ADR-ის მე-4 მუხლის პირველი პუნქტის თანახმად, სახიფათო ტვირთების შესვლა ხელშემკვრელი მხარის ტერიტორიაზე შესაძლებელია რეგლამენტირებული იქნეს წესებით ან აიკრძალოს გადაზიდვების დროს, უსაფრთხოების გარდა სხვა მიზეზით. 1.9.2 1.9.3 პუნქტით გათვალისწინებული დებულებების საფუძველზე, ხელშემკვრელ მხარეს შეუძლია გამოიყენოს ისეთ ავტოსატრანსპორტო საშუალებებთან, რომლებიც ახორციელებს სახიფათო ტვირთების საერთაშორისო საგზაო გადაზიდვებს მის ტერიტორიაზე, გარკვეული დამატებითი დებულებები, რომლებიც არ არის გათვალისწინებული ADR-ში იმ პირობით, რომ აღნიშნული დებულებები არ ეწინააღმდეგება შეთანხმების მე-2 მუხლის მე-2 პუნქტს და წარმოდგენილია მის შიდა კანონმდებლობაში, რომელიც თანაბრად გამოიყენება იმ ავტოსატრანსპორტო საშუალებებთან დაკავშირებით, რომლებიც უზრუნველყოფს სახიფათო ტვირთების შიდა საგზაო გადაზიდვებს აღნიშნული ხელშემკვრელი მხარის ტერიტორიაზე. 1.9.3 1.9.2 პუნქტის ფარგლებში გათვალისწინებული დამატებითი დებულებები შემდეგში მდგომარეობს: (ა) უსაფრთხოებასთან დაკავშირებით დამატებითი მოთხოვნები ან შეზღუდვები იმ ავტოსატრანსპორტო საშუალებების მიმართ, რომლებიც იყენებს გარკვეულ სტრუქტურებს, მაგალითად, ხიდებს, ასევე კომბინირებული სატრანსპორტო სახეობებით, მაგალითად, ბორნებით ან მატარებლებით, მოსარგებლე ავტოსატრანსპორტო საშულებების ან პორტებსა თუ სხვა სატრანსპორტო ტერმინალებში შემავალი და გამომავალი ავტოსატრანსპორტო საშუალებების მიმართ. (ბ) ავტოსატრანსპორტო საშუალებებთან დაკავშირებული მოთხოვნები დადგენილ მარშრუტზე გადაადგილების შესახებ, რათა თავი აარიდონ კომერციულ ან დასახლებულ ადგილებს, ეკოლოგიურად მგრძნობიარე ადგილებს, სამრეწველო ზონებს, სადაც წარმოდგენილია სახიფათო ობიექტები ან გზებს, რომლებზეც არსებობს სერიოზული ფიზიკური დაშავების საშიშროება; (გ) საგანგებო მოთხოვნები იმ ავტოსატრანსპორტო საშუალებების გადაადგილების მარშრუტებსა თუ პარკირებებთან დაკავშირებით, რომლებიც ახორციელებს სახიფათო ტვირთების გადაზიდვებს, რაც განპირობებულია არახელსაყრელი კლიმატური პირობებით, მიწისძვრით, ავარიით, გაფიცვით, სამოქალაქო არეულობით ან სამხედრო მოქმედებებით; (დ) შუზღუდვები სახიფათო ტვირთების გადამზიდი ავტოსატრანსპორტო საშუალებების გადაადგილებაზე კვირის ან წლის გარკვეულ დღეებში. 1.9.4 ხელშემკვრელი მხარის კომპეტენტურმა ორგანომ, რომელიც იყენებს მის ტერიტორიაზე ზემოაღნიშნული 1.9.3 პუნქტის (ა) და (დ) ქვეპუნქტების ფარგლებში წარმოდგენილ ნებისმიერ დამატებით დებულებას, უნდა აცნობოს გაერთიანებული ერების 117 ორგანიზაციის ევროპული ეკონომიკური კომისიის სამდივნოს აღნიშნული დამატებითი დებულებები, რომელსაც სამდივნო, თავის მხრივ, გააცნობს ხელშემკვრელ მხარეებს 1. 1.9.5 შეზღუდვები გვირაბებთან დაკავშირებით შენიშვნა: 8.6 თავში აგრეთვე გათვალისწინებულია დებულებები ავტოსატრანსპორტო საშუალებების საგზაო გვირაბებში გავლასთან დაკავშირებული შეზღუდვების შესახებ. 1.9.5.1 ზოგადი დებულებები სახიფათო ტვირთების გადამზიდი ავტოსატრანსპორტო საშუალებების გვირაბებში გავლასთან დაკავშირებული შეზღუდვებით სარგებლობისას, კომპეტენტურმა ორგანომ უნდა მიაკუთვნოს ავტოსაგზაო გვირაბი 1.9.5.2.2 ქვეპუნქტში გათვალისწინებული გვირაბების რომელიმე კატეგორიას. ყურადღება უნდა მიექცეს გვირაბის მახასიათებლებს, რისკების შეფასებას, ალტერნატიული გადაადგილების მარშრუტების და ავტოსატრანსპორტო საშუალებების სახეობების ხელმისაწვდომობისა და მდგრადობის ჩათვლით, ასევე საგზაო მოძრაობის მართვასთან დაკავშირებულ მოსაზრებებს. ერთი და იგივე გვირაბი შესაძლებელია გათვალისწინებული იყოს გვირაბების ერთზე მეტ კატეგორიაში, მაგალითად, დღის საათების, კვირის დღეებისა და ა.შ. მიხედვით. 1.9.5.1.1 კატეგორიებად დაყოფა 1.9.5.2.1 კატეგორიებად დაყოფა ეფუძნება იმ ვარაუდს, რომ გვირაბებში არსებობს სამი ძირითადი საფრთხე, რომელთაც შეიძლება გამოიწვიოს უამრავი მსხვერპლი ან მიაყენოს სერიოზული ზიანი გვირაბის სტრუქტურას: (ა) (ბ) (გ) 1.9.5.2.2 აფეთქებები; მომწამვლელი აირის ან აქროლადი მომწამვლელი სითხის გამოყოფა; ხანძარი. ქვემოთ წარმოდგენილია გვირაბების ხუთი კატეგორია: ა კატეგორიის გვირაბები: სახიფათო ტვირთების გადაზიდვა არ იზღუდება. ბ კატეგორიის გვირაბები: იზღუდება იმ სახიფათო ტვირთების გამოიწვიოს ძალიან ძლიერი აფეთქება; გადაზიდვა, რომლებმაც შესაძლებელია შემდეგი სახიფათო ტვირთები განიხილება ამ კრიტერიუმის შესაბამისად2: კლასი 1: კლასი 3: კლასი 4.1: A და L შეთავსებადობის ჯგუფები; კლასიფიცირების კოდი D (გაეროს №1204, 2059, 3064, 3343, 3357 და 3379); კლასიფიცირების კოდები D და DT; და 1 სახიფათო ტვირთების საგზაო გადაზიდვასთან დაკავშირებული რისკების გაანგარიშების საერთო მითითებების ხილვა შესაძლებელია გაერთიანებული ერების ორგანიზაციის ევროპული ეკონომიკური კომისიის სამდივნოს ვებ-გვერდზე (http://www.unece.org/trans/danger/danger.htm). 2 აღნიშნული შეფასება დაფუძნებულია ტვირთების შიდა სახიფათო მახასიათებლებზე, მათი შიგთავსის ტიპსა და გადატანილ რაოდენობაზე. 118 თვითრეაქტიული ნივთიერებები, ტიპი B (გაეროს №3221, 3222, 3231 და 3232); კლასი 5.2: ორგანული პეროქსიდები, ტიპი B (გაეროს № 3101, 3102, 3111 და 3112). იმ შემთხვევაში, თუ ფეთქებადი ნივთიერებების საერთო სუფთა მასა ყოველ სატრანსპორტო ერთეულზე აღემატება 1000 კგ-ს: კლასი 1: დანაყოფები 1.1, 1.2 და 1.5 (გარდა A და L შეთავსებადობის ჯგუფებისა). ცისტერნებით გადაზიდვის შემთხვევაში: კლასი 2: კლასიფიცირების კოდები F, TF და TFC; კლასი 4.2: შეფუთვის ჯგუფი I; კლასი 4.3: შეფუთვის ჯგუფი I; კლასი 5.1: შეფუთვის ჯგუფი I; კლასი 6.1: გაეროს № 1510. გ კატეგორიის გვირაბები: იმ სახიფათო ტვირთების გადაზიდვების შეზღუდვა, რომლებმაც შესაძლებელია გამოიწვიოს ძალიან ძლიერი აფეთქება, ძლიერი აფეთქება ან მომწამვლელი ნივთიერებების დიდი რაოდენობით გამოყოფა; შემდეგი სახიფათო ტვირთები განიხილება მოცემული კრიტერიუმის შესაბამისად2: - სახიფათო ტვირთები, რომელთა გადაზიდვაც იკრძალება ბ კატეგორიის გვირაბებში; და შემდეგი სახიფათო ტვირთები: კლასი 1: ქვეკლასები 1.1, 1.2 და 1.5 (გარდა A და L შეთავსებადობის ჯგუფებისა); და ქვეკლასი 1.3 (H და J შეთავსებადობის ჯგუფები); კლასი 7: გაეროს № 2977 და 2978. იმ შემთხვევაში, თუ ფეთქებადი ნივთიერებების სუფთა მასა ყოველ სატრანსპორტო ერთეულზე აღემატება 5000 კგ-ს: კლასი 1: ქვეკლასი 1.3 (C და G შეთავსებადობის ჯგუფები). ცისტერნებით გადაზიდვის შემთხვევაში: კლასი 2: კლასიფიცირების კოდები 2A, 2O, 3A და 3O და მხოლოდ T ასოს ან TC, TO და TOC ასოთა ჯგუფების შემცველი კლასიფიცირების კოდები; კლასი 3: I შეფუთვის ჯგუფი FC, FT1, FT2 და FTC კლასიფიცირების კოდებისთვის; კლასი 6.1: I შეფუთვის ჯგუფი გაეროს № 1510 გარდა; კლასი 8: I შეფუთვის ჯგუფი CT1, CFT და COT კლასიფიცირების კოდებისთვის. დ კატეგორიის გვირაბები: იმ სახიფათო ტვირთების გადაზიდვების შეზღუდვა, რომლებმაც შესაძლებელია გამოიწვიოს ძალიან ძლიერი აფეთქება, ძლიერი აფეთქება ან მომწამვლელი ნივთიერებების დიდი რაოდენობით გამოყოფა ან მასშტაბური ხანძარი; შემდეგი სახიფათო ტვირთები განიხილება ამ კრიტერიუმის შესაბამისად2: - სახიფათო ტვირთები, რომელთა გადაზიდვაც იკრძალება გ კატეგორიის გვირაბებში; და - შემდეგი სახიფათო ტვირთები: აღნიშნული შეფასება დაფუძნებულია ტვირთების შიდა სახიფათო მახასიათებლებზე, მათი შიგთავსის ტიპსა და გადატანილ რაოდენობაზე. 2 119 კლასი 1: კლასი 2: კლასი 4.1: ქვეკლასი 1.3 (C და G შეთავსებადობის ჯგუფები); კლასიფიცირების კოდები F, FC, T, TF, TC, TO, TFC და TOC; თვითრეაქტიული ნივთიერებები, ტიპები C, D, E და F; და გაეროს № 2956, 3241, 3242 და 3251; კლასი 5.2: ორგანული პეროქსიდები, ტიპები C, D, E და F; კლასი 6.1: I შეფუთვის ჯგუფი TF1, TFC და TFW კლასიფიცირების კოდებისთვის; და ასევე შესუნთქვისას მომწამვლელი ნივთიერებები, რომლებსაც განესაზღვრათ სპეციალური დებულება 345 3.2 თავის A ცხრილის (6) სვეტში და გაეროს №3381-დან 3390-მდე გათვალისწინებული შესუნთქვისას მომწამვლელი ნივთიერებები; კლასი 8: I შეფუთვის ჯგუფი CT1, CFT და COT კლასიფიცირების კოდებისთვის; კლასი 9: კლასიფიცირების კოდები M9 და M10. ცისტერნებით გადაზიდვის შემთხვევაში: კლასი 3: კლასი 4.2: II შეფუთვის ჯგუფი; კლასი 4.3: II შეფუთვის ჯგუფი; კლასი 6.1: II შეფუთვის ჯგუფი; და III შეფუთვის ჯგუფი TF2 კლასიფიცირების კოდისთვის; კლასი 8: I შეფუთვის ჯგუფი CF1, CFT და CW1 კლასიფიცირების კოდებისთვის; და შეფუთვის ჯგუფი II CF1 და CFT კლასიფიცირების კოდებისთვის; კლასი 9: კლასიფიცირების კოდები M2 და M3. ე კატეგორიის გვირაბები: ყველა სახიფათო ტვირთის გადაზიდვის შეზღუდვა, გარდა გაეროს № 2919, 3291, 3331, 3359 და 3373 გათვალისწინებული სახიფათო ტვირთებისა, და 3.4 თავით გათვალისწინებული დებულებების შესაბამისად ყველა სახიფათო ტვირთის გადაზიდვის შეზღუდვა იმ შემთხვევაში, თუ მათი მოცულობა აღემატება 8 ტონა მთლიან მასას ყოველ სატრანსპორტო ერთეულზე. შენიშვნა: იმ სახიფათო ტვირთების შემთხვევაში, რომლებსაც მინიჭებული აქვთ გაეროს №2919-დან 3331-მდე, გვირაბში გავლის შეზღუდვა შესაძლებელია წარმოადგენდეს კომპეტენრური ორგანო(ებ)ის მიერ 1.7.4.2 პუნქტის საფუძველზე დამტკიცებული სპეციალური პირობის ნაწილს. 1.9.5.3 საგზაო ნიშნებსა და შეზღუდვების მაუწყებელ შეტყობინებებთან დაკავშირებული დებულებები 1.9.5.3.1 ხელშემკვრელ მხარეს შეუძლია მიუთითოს გვირაბში გავლის აკრძალვებსა და ალტერნატიულ მარშრუტებზე ნიშნებისა და სიგნალების საშუალებით. 1.9.5.3.2 ამ მიზნით მათ შეუძლიათ გამოიყენონ C, 3h და D, 10a, 10b და 10c ნიშნები და სიგნალები ავტოსაგზაო ნიშნებისა და სიგნალების შესახებ ვენის კონვენციის (ვენა, 1968 წ.) და ავტოსაგზაო ნიშნებისა და სიგნალების შესახებ კონვენციის დანართი ევროპული შეთანხმების მიხედვით (ჟენევა, 1971 წ.), რაც განმარტებულია გაეროს ევროპული ეკონომიკური კომისიის შიდა ტრანსპორტის კომიტეტის ავტოსაგზაო ტრანსპორტის საკითხებში ძირითადი სამუშაო ჯგუფის გადაწყვეტილებით ავტოსაგზაო ნიშნებისა და სიგნალების შესახებ (R.E.2), მასში გათვალისწინებულ შესწორებებთან ერთად. 120 1.9.5.3.3 ნიშნების საერთაშორისო დონეზე შემეცნების გასაადვილებლად, ვენის კონვენციაში გათვალისწინებული ნიშნებისა და სიგნალების სისტემა ეფუძნება სიგნალის ყოველი კლასისთვის დამახასიათებელი ფორმისა და ფერის გამოყენებას, ასევე, შესაძლებლობის მიხედვით, გრაფიკული სიმბოლოებისა და არა წარწერების გამოყენებას. იმ შემთხვევაში, თუ ხელშემკვრელი მხარეები საჭიროდ მიიჩნევენ დადგენილი ნიშნებისა და სიმბოლოების შეცვლას, განხორციელებული ცვლილებები არ უნდა შეეხოს მათ ძირითად მახასიათებლებს. იმ შემთხვევაში, თუ ხელშემკვრელი მხარეები არ მიმართავენ ვენის კონვენციას, დადგენილი ნიშნები და სიმბოლოები შესაძლებელია შეიცვალოს იმ პირობით, რომ განხორციელებული ცვლილებები არ მოახდენს გავლენას მათ ძირითად მნიშვნელობაზე. 1.9.5.3.4 ის საგზაო ნიშნები და სიგნალები, რომლებიც გათვალისწინებულია სახიფათო ტვირთების გადამზიდი ავტოსატრანსპორტო საშუალებების საგზაო გვირაბებში დაშვების აკრძალვის მიზნით, უნდა იქნეს მითითებული ისეთ ადგილზე, საიდანაც შესაძლებელი იქნება ალტერნატიული მარშრუტის არჩევა. 1.9.5.3.5 იმ შემთხვევაში, თუ მოძრაობა გვირაბებში გავლით შეზღუდულია ან დადგენილია ალტერნატიული მარშრუტები, ნიშნები წარმოდგენილი უნდა იყოს შემდეგ დამატებით ტაბლოებთან ერთად: არავითარი ნიშანი: არ არის შეზღუდვა; ნიშანი დამატებითი ტაბლოთი, რომელზეც მითითებულია B ასო: გამოიყენება იმ სახიფათო ტვირთების გადამზიდ ავტოსატრანსპორტო საშუალებებთან დაკავშირებით, რომელთა გადაადგილებაც ბ კატეგორიით გათვალისწინებულ გვირაბებში არ არის დაშვებული; ნიშანი დამატებითი ტაბლოთი, რომელზეც მითითებულია C ასო: გამოიყენება იმ სახიფათო ტვირთების გადამზიდ ავტოსატრანსპორტო საშუალებებთან დაკავშირებით, რომელთა გადაადგილებაც გ კატეგორიით გათვალისწინებულ გვირაბებში არ არის დაშვებული; ნიშანი დამატებითი ტაბლოთი, რომელზეც მითითებულია D ასო: გამოიყენება იმ სახიფათო ტვირთების გადამზიდ ავტოსატრანსპორტო საშუალებებთან დაკავშირებით, რომელთა გადაადგილებაც დ კატეგორიით გათვალისწინებულ გვირაბებში არ არის დაშვებული; ნიშანი დამატებითი ტაბლოთი, რომელზეც მითითებულია E ასო: გამოიყენება იმ სახიფათო ტვირთების გადამზიდ ავტოსატრანსპორტო საშუალებებთან დაკავშირებით, რომელთა გადაადგილებაც ე კატეგორიით გათვალისწინებულ გვირაბებში არ არის დაშვებული. 1.9.5.3.6 გვირაბებთან დაკავშირებული შეზღუდვები გამოიყენება იმ სატრანსპორტო ერთეულების მიმართ, რომლებზეც წარმოდგენილია ნარინჯისფერი ფირფიტა 5.3.2 პუნქტის შესაბამისად, იმ სახიფათო ტვირთის გადაზიდვის გამორიცხვით, რომელთან დაკავშირებითაც 3.2 თავის A ცხრილის (15) სვეტში მითითებულია ნიშანი ‘(-)’. იმ სახიფათო ტვირთთან დაკავშირებით, რომელთაც მინიჭებული აქვს გაეროს №2919 და 3331, გვირაბის გავლასთან დაკავშირებული შეზღუდვები შესაძლებელია წარმოადგენდეს კომპეტენტური ორგანო(ები)ს მიერ 1.7.4.2 პუნქტის საფუძველზე დამტკიცებული სპეციალური შეთანხმებების საგანს. ე კატეგორიის გვირაბების შემთხვევაში, ისინი აგრეთვე გამოიყენება იმ სატრანსპორტო ერთეულებთან დაკავშირებით, რომლებზეც წარმოდგენილია აღნიშვნა 3.4.13 პუნქტის შესაბამისად ან 121 კონტეინერების გადამზიდავ სატრანსპორტო ერთეულებთან დაკავშირებით, რომელზეც წარმოდგენილია აღნიშვნა 3.4.13 პუნქტის შესაბამისად. გვირაბებთან დაკავშირებული შეზღუდვები არ გამოიყენება იმ შემთხვევებში, როდესაც სახიფათო ტვირთების გადაზიდვა სრულდება 1.1.3 პუნქტის შესაბამისად, გარდა იმ სატრანსპოტო საშუალებებისა, რომლებზეც წარმოდგენილია აღნიშვნა 3.4.13 პუნქტის თანახმად, 3.4.133 პუნქტის გათვალისწინებით. 1.9.5.3.7 შეზღუდვები ქვეყნდება ოფიციალურად და ხელმისაწვდომია საზოგადოებისთვის. ხელშემკვრელმა მხარეებმა უნდა აცნობონ გაეროს ევროპული ეკონომიკური კომისიის სამდივნოს აღნიშნული შეზღუდვების შესახებ, ხოლო სამდივნო უზრუნველყოფს ამ ინფორმაციის საჯაროდ ხელმისაწვდომობას მის ვებ-გვერდზე. 1.9.5.3.8 იმ შემთხვევაში, თუ ხელშემკვრელი მხარეები მიმართავენ კონკრეტულ საოპერაციო ზომებს, რომლებიც მიმართულია რისკების მინიმუმამდე შემცირებისკენ და უკავშირდება გვირაბებით მოსარგებლე გარკვეულ ან ყველა ავტოსატრანსპორტო საშუალებას, როგორიცაა განაცხადი შესვლამდე ან მოძრაობა კოლონის შემადგენლობაში ავტოსატრანსპორტო საშუალებების თანხლებით, აღნიშნული საოპერაციო ზომები უნდა გამოქვეყნდეს ოფიციალურად და ხელმისაწვდომი იყოს საზოგადოებისთვის. ან 3.4.10 პუნქტის შესაბამისად, 2010 წლის 31 დეკემბრამდე მოქმედი ADR-ის 3.4.11 პუნქტის გათვალისწინებით იმ შემთხვევაში, თუ გამოიყენება 1.6.1.20 პუნქტში წარმოდგენილი გარდამავალი ღონისძიებები. 1 122 თავი 1.10 უსაფრთხოების უზრუნველყოფასთან დაკავშირებული დებულებები შენიშვნა: წინამდებარე თავში გათვალისწინებული მიზნებიდან გამომდინარე, უსაფრთხოების უზრუნველყოფა ნიშნავს შესაბამის ღონისძიებებს ან სიფრთხილის ზომებს, რომლებიც მინიმუმამდე ამცირებს ქურდობის ან სახიფათო ტვირთების ბოროტად გამოყენების შემთხვევებს, რის შედეგადაც შეიძლება საფრთხე შეექმნას ადამიანებს, საკუთრებასა თუ გარემოს. 1.10.1 ზოგადი დებულებები 1.10.1.1 სახიფათო ტვირთების გადაზიდვებში ჩართულმა ყოველმა პირმა უნდა გაითვალისწინოს წინამდებარე თავში წარმოდგენილი უსაფრთხოების უზრუნველყოფის მოთხოვნები, მათი პასუხისმგებლობის შესაბამისად. 1.10.1.2 სახიფათო ტვირთების გადაზიდვების შეთავაზება უნდა მოხდეს მხოლოდ იმ გადამზიდველების მიმართ, რომელთა პირადობაც ჯეროვნად არის დადგენილი. 1.10.1.3 დროებითი საცავი ტერმინალების ფარგლებში გათვალისწინებული ზონები, დროებითი საცავი მონაკვეთები, ავტოსატრანსპორტო საშუალებების დეპოები, ხომალდების სადგომი მონაკვეთები და გადაზიდვების დროს სახიფათო ტვირთების დროებით დასაწყობებისთვის გამოყენებული სორტირების სადგურები უნდა იყოს სათანადოდ დაცული, კარგად განათებული და, შესაძლებლობისა და აუცილებლობის შემთხვევაში, მიუწვდომელი უცხო პირებისთვის. 1.10.1.4 სახიფათო ტვირთების გადაზიდვის დროს, ავტოსატრანსპორტო საშუალების ეკიპაჟის ყოველმა წევრმა თან უნდა იქონიოს პირადობის დამადასტურებელი საბუთი ფოტოსურათთან ერთად. 1.10.1.5 1.8.1 პუნქტითა და 7.5.1.1 ქვეპუნქტით გათვალისწინებული უსაფრთხოების შემოწმებები უნდა მოიცავდეს უსაფრთხოების დაცვის შესაბამის ზომებსაც. 1.10.1.6 კომპეტენტურმა ორგანომ უნდა აწარმოოს 8.2.1 პუნქტით გათვალისწინებული მძღოლებისთვის შესაბამისი მომზადების გავლის მოქმედი მოწმობების მუდმივად განახლებადი რეესტრები, რომელიც გაცემულია აღნიშნული კომპეტენტური ორგანოსა თუ ნებისმიერი აღიარებული ორგანიზაციის მიერ. 1.10.2 სწავლება უსაფრთხოების ზომების შესახებ 1.10.2.1 1.3 თავში გათვალისწინებული მომზადება და გადამზადება ასევე უნდა მოიცავდეს უსაფრთხოების სფეროში ცნობიერების ამაღლების ელემენტებს. არ არის აუცილებელი, რომ უსაფრთხოების სფეროში გადამზადება უკავშირდებოდეს მხოლოდ წესების შეცვლას. 1.10.2.2 უსაფრთხოების ზომების შემეცნების ამაღლებასთან დაკავშირებული მომზადება უნდა ითვალისწინებდეს უსაფრთხოებასთან დაკავშირებული რისკების ხასიათს, უსაფრთხოებასთან დაკავშირებული რისკების აღიარებას, აღნიშნული რისკების დარეგულირებისა და შემცირების მეთოდებსა და იმ ღონისძიებებს, რომლებიც სისრულეში უნდა იქნეს მოყვანილი უსაფრთხოების პირობების დარღვევის შემთხვევაში. აღნიშნული მომზადება უნდა ითვალისწინებდეს უსაფრთხოების 123 უზრუნველყოფის გეგმების შესახებ შემეცნების ამაღლებას (შესაბამის შემთხვევებში) ცალკეულ პირთა პასუხისმგებლობებსა და ვალდებულებებთან ერთად და მათ როლს უსაფრთხოების უზრუნვეყოფასთან დაკავშირებული გეგმების განხორციელებაში. 1.10.2.3 აღნიშნული მომზადება უზრუნველყოფილი ან შემოწმებული უნდა იქნეს იმ პოზიციაზე დასაქმების შემთხვევაში, რომელიც დაკავშირებულია სახიფათო ტვირთების გადაზიდვასთან და, გარდა ამისა, პერიოდულად უნდა ჩატარდეს გადამზადება. 1.10.2.4 დამსაქმებელმა უნდა აწარმოოს ჩანაწერები უსაფრთხოებასთან დაკავშირებით ყოველი ჩატარებული მომზადების შესახებ, რომელიც ხელმისაწვდომი უნდა იყოს მუშაკისა თუ კომპეტენტური ორგანოსთვის მოთხოვნისთანავე. ჩანაწერები ინახება დამსაქმებელთან კომპეტენტური ორგანოს მიერ დადგენილი დროის განმავლობაში. 1.10.3 დებულებები მაღალი საფრთხის შემცველი ტვირთების გადაზიდვების შესახებ 1.10.3.1 მაღალი საფრთხის შემცველი ტვირთების განმარტება 1.10.3.1.1 მაღალი საფრთხის შემცველ ტვირთებს წარმოადგენს ის ტვირთები, რომლებსაც გააჩნია სათანადო პოტენციალი იმისათვის, რომ ბოროტად იქნეს გამოყენებული ტერორისტულ ქმედებებში და რომლებიც, აღნიშნულის შედეგად, გამოიწვევს ისეთ სერიოზულ შედეგებს, როგორიცაა დიდძალი ადამიანური დანაკარგები ან მასობრივი ნგრევა, ან განსაკუთრებით, მე-7 კლასით გათვალისწინებული ტვირთის შემთხვევაში, მასიური სოციო-ეკონომიკურ ძვრებს. 1.10.3.1.2 სხვადასხვა კლასის, გარდა მე-7 კლასისა, მაღალი საფრთხის შემცველი ტვირთების ჩამონათვალი წარმოდგენილია ქვემთ მოყვანილ 1.10.3.1.2 ცხრილში და მათი გადაზიდვა ხდება ცხრილში მითითებულ ოდენობაზე მეტი ოდენობით. 124 ცხრილი 1.10.3.1.2: მაღალი საფრთხის შემცველი ტვირთების ჩამონათვალი კლასი 1 დანაყოფი 1.1 1.2 1.3 1.4 1.5 2 3 4.1 4.2 4.3 5.1 6.1 6.2 8 ა ბ გ დ ნივთიერება ან ნაკეთობა ფეთქებადი ნივთიერებები ფეთქებადი ნივთიერებები გ შეთავსებადობის ჯგუფის ფეთქებადი ნივთიერებები გაეროს № 0104, 0237, 0255, 0267, 0289, 0361, 0365, 0366, 0440, 0441, 0455, 0456 და 0500 გათვალისწინებული ფეთქებადი ნივთიერებები ფეთქებადი ნივთიერებები ადვილაალებადი აირები (მხოლოდ F ასოს შემცველი კლასიფიცირების კოდები) ტოქსიკური აირები (T, TF, TC, TO, TFC ან TOC ასოების შემცველი კლასიფიცირების კოდები) I და II ჯგუფების ადვილაალებადი სითხეები დესენსიბილიზებული ფეთქებადი ნივთიერებები დესენსიბილიზებული ფეთქებადი ნივთიერებები I შეფუთვის ჯგუფის ნივთიერებები I შეფუთვის ჯგუფის ნივთიერებები I შეფუთვის ჯგუფის მჟანგავი სითხეები პერქლორატები, ამონიუმის ნიტრატი, ამონიუმის ნიტრატის სასუქები და ამონიუმის ნიტრატის ემულსიები, სუსპენზები ან გელები I შეფუთვის ჯგუფის ტოქსიკური ნივთიერებები ა კატეგორიის ინფექციური ნივთიერებები (გაეროს № 2814 და 2900, გარდა ცხოველური წარმოშობის მასალებისა) I ჯგუფის შეფუთვის კოროზიული ნივთიერებები ცისტერნა (ლ)გ რაოდენობა მასიური ტვირთი (კგ)დ ა ა ა ა ა ა ა ა 0 0 3000 ა 0 ა ბ 0 ა 0 3000 ა ბ 0 ა 0 ა ა 0 3000 3000 3000 3000 ა ბ ა ბ შეფუთვები (კგ) 0 0 0 ა ბ 3000 ბ 0 ა 0 ა 0 0 3000 ა ბ არ შეესაბამება. 1.10.3 პუნქტის დებულებები არ გამოიყენება, მიუხედავად რაოდენობისა. აღნიშნულ სვეტში წარმოდგენილი მნიშვნელობა მოქმედებს მხოლოდ იმ შემთხვევაში, თუ ცისტერნებით გადაზიდვა ნებადართულია 3.2 თავის A ცხრილის (10) ან (12) სვეტის შესაბამისად. იმ ნივთიერებების შემთხვევაში, რომელთა გადაზიდვაც ცისტერნებში არ არის ნებადართული, აღნიშნულ სვეტში წარმოდგენილ მითითებას არავითარი მნიშვნელობა არ გააჩნია. აღნიშნულ სვეტში წარმოდგენილი მნიშვნელობა მოქმედებს მხოლოდ იმ შემთხვევაში, თუ მასიური ტვირთის სახით გადაზიდვა ნებადართულია 3.2 თავის A ცხრილის (10) ან (17) სვეტის შესაბამისად. იმ ნივთიერებების შემთხვევაში, რომელთა გადაზიდვაც მასიური ტვირთის სახით არ არის ნებადართული, აღნიშნულ სვეტში წარმოდგენილ მითითებას არავითარი მნიშვნელობა არ გააჩნია. 125 1.10.3.1.3 მე-7 კლასით გათვალისწინებული სახიფათო ტვირთის შემთხვევაში, მაღალი საფრთხის შემცველ რადიოაქტიურ მასალას წარმოადგენს ის რადიოაქტიური მასალა, რომლის აქტივობის მნიშვნელობა ტოლია ან მეტია ცალკე შეფუთვაზე 3000 A2 გადაზიდვების უსაფრთხოების ზღვრისა (იხილეთ აგრეთვე 2.2.7.2.2.1 პუნქტი), გარდა შემდეგი რადიონუკლიდებისა, რა შემთხვევაშიც გადაზიდვის უსაფრთხოების ზღვარი მითითებულია ქვემოთ წარმოდგენილ 1.10.3.1.3 ცხრილში. ცხრილი 1.10.3.1.3: ცალკეული რადიონუკლიდების გადაზიდვასთან დაკავშირებული უსაფრთხოების ზღვარი ელემენტი რადიონუკლიდი ამერიციუმი ოქრო კადმიუმი კალიფორნიუმი კურიუმი კობალტი კობალტი ცესიუმი რკინა გერმანიუმი გადოლინიუმი ირიდიუმი ნიკელი პალადიუმი პრომეთიუმი პოლონიუმი პლუტონიუმი პლუტონიუმი რადიუმი რუთენიუმი სელენიუმი სტრონციუმი თალიუმი თულიუმი იტერბიუმი Am-241 Au-198 Cd-109 Cf-252 Cm-244 Co-57 Co-60 Cs-137 Fe-55 Ge-68 Gd-153 Ir-192 Ni-63 Pd-103 Pm-147 Po-210 Pu-238 Pu-239 Ra-226 Ru-106 Se-75 Sr-90 Tl-204 Tm-170 Yb-169 გადაზიდვის უსაფრთხოების ზღვარი (TBq) 0.6 2 200 0.2 0.5 7 0.3 1 8000 7 10 0.8 600 900 400 0.6 0.6 0.6 0.4 3 2 10 200 200 3 1.10.3.1.4 რადიონუკლიდების ნარევის შემთხვევაში, გადაზიდვის უსაფრთხოების ზღვარის მიღწევის ან გადაჭარბების ფაქტი შესაძლებელია განისაზღვროს მოცემული რადიონუკლიდის გადაზიდვის უსაფრთხოების ზღვარის მნიშვნელობაზე ყოველი რადიონუკლიდის აქტივობის გაყოფის შედეგად მიღებული კოეფიციენტების შეჯამებით. იმ შემთხვევაში, თუ კოეფიციენტების ჯამი შეადგენს 1-ზე ნაკლებს, მაშინ მოცემული ნარევის რადიოაქტივობის ზღვარი არ არის მიღწეული და გადაჭარბებული. გამოთვლა შესაძლებელია განხორციელდეს შემდეგი ფორმულის გამოყენებით: 126 რა შემთხვევაშიც: Ai = შეფუთვაში წარმოდგენილი რადიონუკლიდი i-ს აქტივობა (TBq) Ti = რადიონუკლიდი i-ს გადაზიდვის უსაფრთხოების ზღვარი (TBq) 1.10.3.1.5 იმ შემთხვევაში, თუ რადიოაქტიური მასალისთვის დამახასიათებელია სხვა კლასებისთვის განსაზღვრული დამატებითი საფრთხე, მხედველობაში უნდა იქნეს მიღებული 1.10.3.1.2 ცხრილით გათვალისწინებული კრიტერიუმები (იხილეთ აგრეთვე პუნქტი 1.7.5). 1.10.3.2 უსაფრთხოების უზრუნველყოფის გეგმები 1.10.3.2.1 გადამზიდველებმა, ტვირთგამგზავნებმა და 1.4.2 და 1.4.3 პუნქტებით გათვალისწინებული მაღალი საფრთხის შემცველი ტვირთების (იხილეთ ცხრილი 1.10.3.1.2) ან მაღალი საფრთხის შემცველი რადიოაქტიური მასალების (იხილეთ ცხრილი 1.10.3.1.3) გადაზიდვების სხვა მონაწილეებმა უნდა მიიღონ, სისრულეში მოიყვანონ და იმოქმედონ უსაფრთხოების უზრუნველყოფის გეგმების შესაბამისად, რომლებიც ითვალისწინებს მინიმუმ 1.10.3.2.2 პუნქტით წარმოდგენილ ელემენტებს. 1.10.3.2.2 უსაფრთხოების უზრუნვეყოფის გეგმა უნდა მოიცავდეს მინიმუმ შემდეგ ელემენტებს: (ა) უსაფრთხოების უზრუნველყოფასთან დაკავშირებული პასუხისმგებლობის კონკრეტულად განაწილება კომპეტენტურ და კვალიფიციურ პირებზე, რომელთაც გააჩნიათ მათი პასუხისმგებლობის განსახორციელებლად საჭირო უფლებამოსილება; (ბ) შესაბამისი სახიფათო ტვირთებისა თუ სახიფათო ტვირთების ტიპების შესახებ ჩანაწერები; (გ) მიმდინარე ოპერაციების მიმოხილვა და უსაფრთხოებასთან დაკავშირებული რისკების შეფასება, მათ შორის სატრანსპორტო ოპერაციისთვის აუცილებელი ნებისმიერი გაჩერება, სახიფათო ტვირთების შენახვა ავტოსატრანპორტო საშუალებაში, ცისტერნასა თუ კონტეინერში რეისამდე, რეისის განმავლობაში ან მის შემდეგ და სახიფათო ტვირთების შუალედური, დროებითი დასაწყობება ტრანსპორტის სახეობების შეცვლის პროცესსა თუ ერთეულებს შორის გადაზიდვების პროცესში, კონკრეტული სიტუაციიდან გამომდინარე; (დ) იმ ღონისძიებების შესახებ საყოველთაოდ გასაგებად განცხადება, რომლებიც მიღებულ უნდა იქნეს მონაწილის პასუხისმგებლობისა და ვალდებულებების შესაბამის უსაფრთხოებასთან დაკავშირებული რისკების შესამცირებლად, აღნიშნულს განეკუთვნება: - მომზადება; - უსაფრთხოების უზრუნველყოფის პოლიტიკა (მაგალითად, რეაგირება მომატებული საფრთხის პირობებზე, ახალი მუშაკის/საქმიანობის შემოწმება და ა.შ.); 127 - საოპერაციო პრაქტიკები (მაგალითად, ნაცნობი მარშრუტების არჩევა/გამოყენება, შუალედურ დროებით საცავში არსებულ სახიფათო ტვირთებზე დაშვება (რაც გათვალისწინებულია (გ) ქვეპუნქტში), ინფრასტრუქტურის დაუცველ ობიექტებთან სიახლოვე და ა.შ.); - აღჭურვილობა და რესურსები, რომელთა გამოყენებაც უნდა მოხდეს უსაფრთხოებასთან დაკავშირებული რისკების შესამცირებლად; (ე) უსაფრთხოებასთან დაკავშირებული მუქარების, უსაფრთხოების დარღვევებისა და უსაფრთხოებასთან დაკავშირებული შემთხვევების შესახებ ანგარიშგებისა და მათი მოგვარების ეფექტური და განახლებული პროცედურები; (ვ) უსაფრთხოების გეგმების შეფასებასა და გამოცდასთან პროცედურები და გეგმების პერიოდული მიმოხილვისა პროცედურები; (ზ) უსაფრთხოების უზრუნველყოფის გეგმით წარმოდგენილი გადაზიდვების შესახებ ინფორმაციის ფიზიკური უსაფრთხოების უზრუნველყოფის ზომები; (თ) იმ ფაქტის უზრუნველყოფის ზომები, რომ უსაფრთხოების უზრუნველყოფის გეგმით გათვალისწინებული სატრანსპორტო ოპერაციების შესახებ ინფორმაციის განაწილება შემოიფარგლება მხოლოდ იმ პირებზე, რომლებიც საჭიროებენ მას. აღნიშნული ზომები ხელს არ უნდა უშლიდეს ADR-ის სხვა დებულებებით მოთხოვნილი ინფორმაციის წარდგენას. დაკავშირებული და განახლების შენიშვნა: გადამზიდველებმა, ტვირთგამგზავნებმა და ტვირთმიმღებებმა უნდა ითანამშრომლონ ერთმანეთთან და კომპეტენტურ ორგანოებთან, რათა გაცვალონ ინფორმაცია არსებული საფრთხის შესახებ, მიმართონ უსაფრთხოების უზრუნველყოფასთან დაკავშირებულ სათანადო ზომებს და მოახდინონ რეაგირება უსაფრთხოებასთან დაკავშირებულ ინციდენტებზე. 1.10.3.3 უნდა მოხდეს იმ დანადგარების, აღჭურვილობისა თუ მოწყობილობების გამოყენება, რომლებიც უზრუნველყოფს მაღალი საფრთხის შემცველი ტვირთების გადამზიდი ავტოსატრანსპორტო საშუალებების (იხილეთ ცხრილი 1.10.3.1.2) ან მაღალი საფრთხის შემცველი რადიოაქტიური მასალისა (იხილეთ ცხრილი 1.10.3.1.3) და მისი ტვირთის მოპარვის პრევენციას და მიღებულ უნდა იქნეს სათანადო ზომები, რათა აღნიშნული დანადგარები, აღჭურვილობა თუ მოწყობილობები ყოველთვის წარმოდგენილი იყოს გამართულ საოპერაციო და მუშა მდგომარეობაში. აღნიშნული დამცავი ღონისძიებების გამოყენებამ საფრთხე არ უნდა შეუქმნას გადაუდებელი რეაგირების უზრუნველყოფას. შენიშვნა: საჭიროების შემთხვევაში და როდესაც აუცილებელი მოწყობილობა უკვე დაყენებულია, გამოყენებულ უნდა იქნეს სატრანსპორტო ტელემეტრიისა თუ სხვა მეთვალყურეობის მეთოდები ან დანადგარები მაღალი საფრთხის შემცველი ტვირთების (იხილეთ ცხრილი 1.10.3.1.2) ან მაღალი საფრთხის შემცველი რადიოაქტიური მასალის (იხილეთ ცხრილი 1.10.3.1.3) გადაადგილებაზე მონიტორინგის უზრუნველყოფის მიზნით. 1.10.4 1.1.3.6 პუნქტით გათვალისწინებული დებულებების თანახმად, 1.10.1, 1.10.2, 1.10.3 პუნქტებისა და 8.1.2.1(დ) ქვეპუნქტის მოთხოვნები არ ვრცელდება იმ შემთხვევებზე, როდესაც ერთ სატრანსპორტო ერთეულში შეფუთვებში გადატანილი ტვირთების რაოდენობა არ აღემატება 1.1.3.6.3 ქვეპუნქტში გათვალისწინებულ ოდენობას, გაეროს 128 №0029, 0030, 0059, 0065, 0073, 0104, 0237, 0255, 0267, 0288, 0289, 0361, 0364, 0365, 0366, 0439, 0440, 0441, 0455, 0456 და 0500 გარდა (იხილეთ 1.1.3.6.2 ქვეპუნქტის პირველი აბზაცი). გარდა ამისა, 1.10.1, 1.10.2, 1.10.3 პუნქტებისა და 8.1.2.1(დ) ქვეპუნქტის მოთხოვნები არ ვრცელდება ასევე იმ შემთხვევებზე, როდესაც ერთ სატრანსპორტო ერთეულზე ცისტერნებითა თუ მასიური ტვირთის სახით გადატანილი ტვირთების რაოდენობა არ აღემატება 1.1.3.6.3 ქვეპუნქტში გათვალისწინებულ ოდენობას. გარდა ამისა, წინამდებარე თავით გათვალისწინებული დებულებები არ გამოიყენება გაეროს №2912 - რადიოაქტიური მასალა, დაბალი კუთრი აქტივობა (LSA-I) და გაეროს №2913 რადიოაქტიური მასალა, რადიოაქტიური დაზიანების მქონე ზედაპირი (SCO-I) გადაზისვასთან დაკავშირებით. 1.10.5 1 2 რადიოაქტიურ მასალებთან დაკავშირებით, წინამდებარე თავის დებულებები ითვლება შესრულებულად იმ შემთხვევაში, თუ გამოიყენება ბირთვული მასალების ფიზიკური დაცვის შესახებ კონვენციისა 1 და „ბირთვული მასალებისა და ბირთვული ობიექტების ფიზიკური დაცვის“2 შესახებ ატომური ენერგიის საერთაშორისო სააგენტოს საინფორმაციო ცირკულარი. INFCIRK/274/Rev.1, ატომური ენერგიის საერთაშორისო სააგენტო, ვენა (1980 წ.). INFCIRC/225/Rev.4 (შესწორებული), IAEA, ვენა (1999 წ,). 129 ნაწილი 2 კლასიფიკაცია 131 132 თავი 2.1 ზოგადი დებულებები 2.1.1 შესავალი 2.1.1.1 ADR-ის მიხედვით სახიფათო ტვირთების კლასები წარმოდგენილია შემდეგი სახით: 2.1.1.2 კლასი 1 ფეთქებადი ნივთიერებები და ნაკეთობები კლასი 2 აირები კლასი 3 ადვილაალებადი სითხეები კლასი 4.1 ადვილაალებადი მყარი ნივთიერებები, თვითრეაქტიული ნივთიერებები და მყარი, დესენსიბილიზებული ფეთქებადი ნივთიერებები კლასი 4.2 თვითაალებისკენ მიდრეკილი ნივთიერებები კლასი 4.3 ნივთიერებები, რომლებიც ადვილაალებად აირებს კლასი 5.1 მჟანგავი ნივთიერებები კლასი 5.2 ორგანული პეროქსიდები კლასი 6.1 ტოქსიკური ნივთიერებები კლასი 6.2 ინფექციური ნივთიერებები კლასი 7 რადიოაქტიური მასალები კლასი 8 კოროზიული ნივთიერებები კლასი 9 სხვადასხვა სახიფათო ნივთიერებები და ნაკეთობები წყალთან შეხებისას გამოჰყოფს სხვადასხვა კლასებში გათვალისწინებულ ყოველ პოზიციას მინიჭებული აქვს გაეროს ნომერი. გამოიყენება შემდეგი პოზიციების ტიპები: ა. ცალკეული პოზიციები კარგად განსაზღვრული ნივთიერებებისა თუ ნაკეთობებისთვის, რამდენიმე იზომერის შემცველ ნივთიერებებთან დაკავშირებული პოზიციების ჩათვლით, მაგალითად: გაეროს № 1090 გაეროს № 1104 გაეროს № 1194 ბ. გენერიული ნივთიერებებისა თუ ნაკეთობების ჯგუფისთვის, რომლებიც არ წარმოადგენს იმ კონკრეტულად არ არის განსაზღვრული, მაგალითად: გაეროს № 1133 გაეროს № 1266 გაეროს № 2757 გაეროს № 3101 გ. აცეტონი ამილაცეტატები ეთილნიტრიტის ხსნარი კარგად განსაზღვრული პოზიციებს, რომლებიც წებო პარფიუმერული პროდუქცია კარბამატული პესტიციდები, მყარი, ტოქსიკური B ტიპის, თხევადი, ორგანული პეროქსიდი სპეციფიკური n.o.s. პოზიციები, რომლებიც მოიცავს განსაკუთრებული ქიმიური ან ფიზიკური თვისებების მქონე ნვთიერებებისა თუ ნაკეთობების ჯგუფს, თუ კონკრეტულად სხვა რამ არ არის მითითებული, მაგალითად: გაეროს № 1477 არაორგანული ნიტრატები, N.O.S. 133 გაეროს № 1987 დ. სპირტები, N.O.S. საერთო პოზიციები, რომლებიც კონკრეტულად არ არის განსაზღვრული და მოიცავს ერთი ან რამდენიმე სახიფათო თვისების მქონე ნვთიერებებისა თუ ნაკეთობების ჯგუფს, თუ კონკრეტულად სხვა რამ არ არის მითითებული, მაგალითად: გაეროს № 1325 გაეროს № 1993 ორგანული, ადვილაალებადი, მყარი ნივთიერებები, N.O.S. ადვილაალებადი სითხეები, N.O.S. ბ, გ და დ პუნქტებით გათვალისწინებული პოზიციები განისაზღვრება ერთობლივი პოზიციების სახით. 2.1.1.3 შეფუთვის მიზნებიდან გამომდინარე, ნივთიერებები, 1, 2, 5.2, 6.2 და 7 კლასებით გათვალისწინებული ნივთიერებებისა და 4.1 კლასით გათვალისწინებული თვითრეაქტიული ნივთიერებების გარდა, მიეკუთვნება შესაბამის შეფუთვის ჯგუფებს მათ მიერ წარმოდგენილი საშიშროების ხარისხის მიხედვით: I შეფუთვის ჯგუფი: მაღალი ხარისხის საშიშროების მქონე ნივთიერებები; II შეფუთვის ჯგუფი: საშუალო ხარისხის საშიშროების მქონე ნივთიერებები; III შეფუთვის ჯგუფი: დაბალი ხარისხის საშიშროების მქონე ნივთიერებები. შეფუთვის ჯგუფ(ებ)ი, რომელსაც განეკუთვნება ესა თუ ის ნივთიერება, მითითებულია 3.2 თავის A ცხრილში. შეფუთვის ჯგუფებში არ შედის ნაკეთობები. შეფუთვის მიზნებისთვის საექსპლუატაციო მახასიათებლების კონკრეტულ დონესთან დაკავშირებული ნებისმიერი მოთხოვნა წარმოდგენილია მოქმედ შეფუთვის ინსტრუქციაში. 2.1.2 კლასიფიკაციის პრინციპები 2.1.2.1 ამა თუ იმ კლასის დასახელებაში გათვალისწინებული სახიფათო ტვირთები განისაზღვრება მათი თვისებების მიხედვით შესაბამისი კლასის 2.2.x.1 ქვეპუნქტის თანახმად. სახიფათო ტვირთების ამა თუ იმ კლასის და შეფუთვის ჯგუფისთვის მიკუთვნება ხორციელდება იგივე 2.2.x.1 ქვეპუნქტში გათვალისწინებული კრიტერიუმების შესაბამისად. ერთი ან რამდენიმე სახის დამატებითი რისკ(ებ)ის მინიჭება რომელიმე სახიფათო ნივთიერებისა თუ ნაკეთობის მიმართ ხორციელდება აღნიშნული რისკების შესაბამისი კლასისა თუ კლასების კრიტერიუმების მიხედვით, რაც მითითებულია შესაბამის 2.2.x.1 ქვეპუნქტ(ებ)ში. 2.1.2.2 3.2 თავის A ცხრილში ჩამოთვლილია სახიფათო ტვირთების ყველა პოზიცია მათი გაეროს ნომერის რიცხობრივი წესითაც. აღნიშნული ცხრილი მოიცავს შესაბამის ინფორმაციას მასში ჩამოთვლილი ტვირთების შესახებ, როგორიცაა დასახელება, კლასი, შეფუთვის ჯგუფ(ებ)ი, მითითებული უსაფრთხოების ნიშანი (ნიშნები), შეფუთვასა და გადაზიდვასთან დაკავშირებული დებულებები1. 1 სამდივნოს შენიშვნა: აღნიშნული პოზიციების ანბანური სია მომზადდა სამდივნოს მიერ და განმეორებით წარმოდგენილია 3.2 თავის ბ ცხრილში. ეს ცხრილი არ წარმოადგეს ADR-ის ოფიციალურ ნაწილს. 134 2.1.2.3 ნივთიერება შესაძლებელია შეიცავდეს ტექნიკურ მინარევებს (მაგალითად, წარმოების პროცესის შედეგად წარმოშობილ მინარევებს) ან დანამატებს, სტაბილურობის ან სხვა მიზნებისთვის, რაც გავლენას არ მოახდენს მათ კლასიფიკაციაზე. მიუხედავად აღნიშნულისა, დასახელებით მითითებული ნივთიერება, ანუ წამოდგენილი ცალკეული პოზიციის სახით 3.2. თავის A ცხრილში, რომელიც შეიცავს ტექნიკურ მინარევებსა თუ დანამატებს სტაბილურობის გაუმჯობესებისა თუ მის კლასიფიკაციაზე მოქმედი სხვა მიზნებისთვის, განიხილება ხსნარის ან მინარევის სახით (იხილეთ 2.1.3.3 პუნქტი). 2.1.2.4 გადაზიდვებზე არ დაიშვება ის სახიფათო ტვირთები, რომლებიც ჩამოთვლილი ან განსაზღვრულია ყოველი კლასის 2.2.x.1 ქვეპუნქტში. 2.1.2.5 ტვირთები, რომლებიც არ არის მითითებული დასახელებით, ანუ ტვირთები, რომლებიც არ არის წარმოდგენილი ცალკეული პოზიციის სახით 3.2 თავის A ცხრილში და ასევე არ არის ჩამოთვლილი ან განსაზღვრული ზემოაღნიშნულ 2.2.x.1 ქვეპუნქტებში, უნდა მიეკუთვნოს შესაბამის კლასს 2.1.3 პუნქტით გათვალისწინებული პროცედურის შესაბამისად. გარდა ამისა, უნდა განისაზღვროს დამატებითი რისკის სახეობა (ასეთის არსებობის შემთხვევაში) და შეფუთვის ჯგუფი (ასეთის არსებობის შემთხვევაში). კლასის, დამატებითი რისკის სახეობისა (ასეთის არსებობის შემთხვევაში) და შეფუთვის ჯგუფის (ასეთის არსებობის შემთხვევაში) განსაზღვრის შემდეგ, უნდა განისაზღვროს შესაბამისი გაეროს ნომერი. ყოველი კლასის ბოლოს 2.2.x.1 ქვეპუნქტებში წარმოდგენილი მიღებული გადაწყვეტილებების სქემები (ერთობლივი პოზიციების ჩამონათვალი) ითვალისწინებს სათანადო პარამეტრებს შესაბამისი ერთობლივი პოზიციის (გაეროს ნომრის) შესარჩევად. ნებისმიერ შემთხვევაში, 2.1.1.2 ქვეპუნქტში ბ, გ და დ ასოებით წარმოდგენილი იერარქიული წყობის შესაბამისად უნდა შეირჩეს ყველაზე კონკრეტული ერთობლივი პოზიცია, სადაც გათვალისწინებული იქნება ნივთიერებებისა თუ ნაკეთობების თვისებები. თუ შეუძლებელია ნივთიერებისა თუ ნაკეთობის კლასიფიცირება B ან C ტიპის პოზიციებად 2.1.1.2 ქვეპუნქტის შესაბამისად, მხოლოდ ამ შემთხვევაში მისი კლასიფიცირება უნდა მოხდეს D ტიპის პოზიციაზე. 2.1.2.6 2.3 თავით გათვალისწინებული ტესტირებს პროცედურების, ასევე სხვადასხვა კლასის 2.2.x.1 ქვეპუნქტებში მოყვანილი კრიტერიუმების საფუძველზე, როდესაც პირდაპირ არის მითითებული, შესაძლებელია იმის განსაზღვრა, რომ გარკვეულ კლასში შემავალი ნივთიერება, ხსნარი ან ნარევი, რომელიც მითითებულია დასახელებით 3.2 თავის A ცხრილში, არ აკმაყოფილებს აღნიშნული კლასის კრიტერიუმებს. ამ შემთხვევაში ჩაითვლება, რომ მოცემული ნივთიერება, ხსნარი თუ ნარევი არ განეკუთვნება ამ კლასს. 2.1.2.7 კლასიფიკაციის მიზნებიდან გამომდინარე, ის ნივთიერებები, რომელთაც აღენიშნებათ 101.3 კპა წნევაზე 200C ან უფრო დაბალი ტემპერატურის დნობის წერტილი ან საწყისი დნობის წერტილი, განიხილება სითხეებად. ბლანტი ნივთიერება, რომელთან დაკავშირებითაც შეუძლებელია კონკრეტული დნობის წერტილის განსაზღვრა, ექვემდებარება 2.3.4 პუნქტში განსაზღვრულ ASTM D4359-90 გამოცდასა თუ დენადობის განმსაზღვრელ გამოცდას (გამოცდა პენეტრომეტრის გამოყენებით). 2.1.3 ნივთიერებების კლასიფიკაცია, ხსნარებისა და ნარევების ჩათვლით (როგორიცაა პრეპარატები და მათი ნარჩენები), რომლებიც არ არის მოხსენებული მათი დასახელებით 135 2.1.3.1 ნივთიერებები, ხსნარებისა და ნარევების ჩათვლით, რომლებიც არ არის მოხსენებული მათი დასახელებით, კლასიფიცირდება მათი საშიშროების ხარისხის მიხედვით, სხვადასხვა კლასის 2.2.x.1 ქვეპუნქტში გათვალისწინებული კრიტერიუმების საფუძველზე. ამა თუ იმ ნივთიერების მიერ წარმოდგენილი საშიშროების სახე(ები) განისაზღვრება მისი ფიზიკური და ქიმიური მახასიათებლებისა და ფიზიოლოგიური თვისებების საფუძველზე. აღნიშნული მახასიათებლები და თვისებები ასევე მიიღება მხედველობაში მაშინ, როდესაც აღნიშნული გამოცდილება განაპირობებს ნივთერებების მიკუთვნებას კიდევ უფრო მკაცრი მოთხოვნების შესაბამის კატეგორიაზე. 2.1.3.2 ნივთიერებების კლასიფიკაცია, რომლებიც არ არის მითითებული დასახელებით 3.2 თავის A ცხრილში და წარმოდგენს ერთ-ერთი სახეობის საშიშროებას, უნდა მოხდეს შესაბამის კლასში, ამ კლასის 2.2.x.1 ქვეპუნქტში გათვალისწინებული ერთ-ერთი ერთობლივი პოზიციის საფუძველზე. 2.1.3.3 ხსნარსა თუ ნარევს, რომელიც შედგება 3.2 თავის A ცხრილში დასახელებით მითითებული ცალკეული პრედომინანტური ნივთიერებისგან, ასევე ერთ ან რამდენიმე ნივთიერებას, რომელიც არ ექვემდებარება ADR-ის ან 3.2 თავის A ცხრილში სახელწოდებით მითითებული ერთი ან რამდენიმე ნივთიერების თანმიმდევრობას, უნდა მიენიჭოს გაეროს ნომერი და 3.2 თავის A ცხრილში დასახელებით მითითებული პრედომინანტური ნივთიერების სათანადო გადაზიდვის დასახელება, გარდა შემდეგი შემთხვევებისა: (ა) 3.2 თავის A ცხრილში დასახელებით მითითებული ხსნარები ან ნარევები; (ბ) იმ ნივთიერების სახელი და აღწერილობა, რომელიც 3.2 თავის A ცხრილში მითითებულია დასახელებით, კონკრეტულად კი იმის მითითებით, რომ მათი გამოყენება ხდება მხოლოდ სუფთა ნივთიერების მიმართ; (გ) ხსნარისა თუ ნარევის კლასი, კლასიფიკაციის კოდი, შეფუთვის ჯგუფი ან ფიზიკური მდგომარეობა განსხვავდება 3.2 თავის A ცხრილში დასახელებით მითითებული ნივთიერებისგან; ან (დ) ხსნარებისა თუ ნარევების სახიფათო მახასიათებლები და თვისებები, რომლებიც საჭიროებს 3.2 თავის A ცხრილში დასახელებით მითითებულ ნივთიერებასთან დაკავშირებით გათვალისწინებული ღონისძიებებისგან განსხვავებული გადაუდებელი ღონისძიებების განხორციელებას. დანარჩენ სხვა შემთხვევაში, გარდა (ა) ქვეპუნქტით გათვალისწინებული შემთხვევისა, ხსნარისა თუ ნარევის კლასიფიკაცია უნდა განხორციელდეს იმ ნივთიერების სახით, რომელიც არ არის მითითებული დასახელებით შესაბამის კლასში აღნიშნული კლასის 2.2.x.1 ქვეპუნქტში გათვალისწინებული ერთ-ერთი ერთობლივი პოზიციის საფუძველზე, აღნიშნული ხსნარის ან ნარევის მიერ წარმოდგენილი დამატებითი რისკების გათვალისწინებით, ასეთის არსებობის შემთხვევაში, გარდა იმ შემთხვევისა, როდესაც ხსნარი ან ნარევი არ აკმაყოფილებს ნებისმიერი კლასით გათვალისწინებულ კრიტერიუმებს და რა შემთხვევაშიც ის არ ექვემდებარება ADR-ს. 2.1.3.4 იმ ნივთიერებების შემცველი ხსნარების თუ ნარევების, რომლებიც მიეკუთვნება 2.1.3.4.1 ან 2.1.3.4.2 ქვეპუნქტებით გათვალისწინებულ ერთ-ერთ პოზიციას, კლასიფიკაცია უნდა განხორციელდეს აღნიშნული ქვეპუნქტების დებულებების მიხედვით. 136 2.1.3.4.1 დასახელებით მითითებული ერთ-ერთი ქვემოთ წარმოდგენილი ნივთიერებების შემცველი ხსნარებისა და ნარევების კლასიფიკაცია ყოველთვის უნდა განხორციელდეს იგივე პოზიციაზე, როგორც მათში წარმოდგენილი ნივთიერებები შემთხვევაში იმ პირობით, რომ მათ არ აღენიშნებათ 2.1.3.5.3 ქვეპუნქტში მითითებული სახიფათო მახასიათებლები: - კლასი 3 გაეროს №1921 - პროპილენიმინი, სტაბლიზებული; გაეროს №3064 ნიტროგლიცერინის სპირტის ხსნარი, 1%-ზე მეტი, მაგრამ 5%-ზე ნაკლები ნიტროგლიცერინის შემცველობით; - კლასი 6.1 გაეროს №1051 - წყალბადის ციანიდი, სტაბილიზებული, 3%-ზე ნაკლები წყლის შემცველობით; გაეროს №1185 - ეთილენიმინი, სტაბილიზებული; გაეროს №1259 ნიკელის კარბონილი; გაეროს №1613 - წყალბადციანიდის მჟავა, წყალხსნარი (ციანიდის წყალბადი, წყალხსნარი), 20%-ზე მეტი წყალბადის ციანიდის შემცველობით; გაეროს №1614 - წყალბადის ციანიდი, სტაბილიზებული, 3%-ზე მეტი წყლის შემცველობით და აბსორბირებული ფოროვან ინერტულ მასალაში; გაეროს №1994 - რკინის პენტაკარბონილი; გაეროს №2480 - მეთილიზოციანატი; გაეროს №2481 ეთილიზოციანატი; გაეროს №3294 - წყალბადის ციანიდი, სპირტის ხსნარი, არაუმეტეს 45% წყალბადის ციანიდის შემცველობით; - კლასი 8 გაეროს №1052 - ფტორწყალბადი, უწყლო; გაეროს №1744 - ბრომი ან გაეროს №1744 - ბრომის ხსნარი; გაეროს №1790 - ფტორწყალბადის მჟავა, 85%-ზე მეტი ფტორწყალბადის შემცველობით; გაეროს №2576 - ფოსფორის ბრომის ჟანგი; მდნარი; 2.1.3.4.2 იმ ნივთიერების შემცველი ხსნარებისა და ნარევების, რომლებიც მიეკუთვნება მე-9 კლასის ერთ-ერთ შემდეგ პოზიციას: გაეროს № 2315 - პოლიქლორობიფენილები, თხევადი; გაეროს № 3151 - პოლიჰალოგენირებული ბიფენილები, თხევადი; გაეროს № 3151 - პოლიჰალოგენირებული ტერფენილები, თხევადი; გაეროს № 3152 - პოლიჰალოგენირებული ბიფენილები, მყარი; გაეროს № 3152 - პოლიჰალოგენირებული ტერფენილები, მყარი; ან გაეროს № 3432 - პოლიქლორობიფენილები, მყარი კლასიფიკაცია უნდა განხორციელდეს იგივე მე-9 კლასის პოზიციის მიხედვით, იმ პირობით, რომ: 2.1.3.4.3 - ისინი არ შეიცავს რაიმე დამატებით სახიფათო კომპონენტს, გარდა 3, 4.1, 4.2, 4.3, 5.1, 6.1 ან 8 კლასების III შეფუთვის ჯგუფის კომპონენტებისა; და - მათ არ გააჩნიათ 2.1.3.5.3 ქვეპუნქტში მითითებული სახიფათო მახასიათებლები. ის ნივთიერებები, რომლებიც არ არის მითითებული 3.2 თავის A ცხრილში დასახელებით, გააჩნიათ ერთზე მეტი სახიფათო თვისება, ასევე რამდენიმე სახიფათო ნივთიერების შემცველი ხსნარებისა თუ ნარევების კლასიფიკაცია უნდა მოხდეს 137 შესაბამისი კლასის ერთობლივ პოზიციაზე (იხილეთ 2.1.2.5 ქვეპუნქტი) და შეფუთვის ჯგუფში მათი სახიფათო თვისებების შესაბამისად. სახიფათო თვისებების მიხედვით აღნიშნული კლასიფიკაცია ხორციელდება შემდეგნაირად: 2.1.3.5.1 ფიზიკური და ქიმიური მახასიათებლები და ფიზიოლოგიური თვისებები განისაზღვრება გაზომვის ან გაანგარიშების გზით, ხოლო ნივთიერების, ხსნარისა თუ ნარევის კლასიფიკაცია უნდა მოხდეს სხვადასხვა კლასების 2.2.x.1 ქვეპუნქტში გათვალისწინებული კრიტერიუმების შესაბამისად. 2.1.3.5.2 იმ შემთხვევაში, თუ შეუძლებელია აღნიშნულის განსაზღვრა არაპროპორციული ხარჯებისა თუ ძალისხმევების გარეშე (მაგალითად, ნარჩენების გარკვეულ სახეობებთან დაკავშირებით), ნივთიერების, ხსნარისა თუ მინარევის კლასიფიცირება უნდა განხორციელდეს ძირითადი საშიშროების წარმომდგენი კომპონენტის კლასში. 2.1.3.5.3 იმ შემთხვევაში, თუ ნივთიერების, ხსნარისა თუ ნარევის სახიფათო მახასიათებლები წარმოდგენილია ერთზე მეტ კლასში ან ქვემოთ მითითებული ნივთიერებების ერთზე მეტ ჯგუფში, მაშინ ნივთიერების, ხსნარისა თუ ნარევის კლასიფიცირება უნდა განხორციელდეს ძირითადი საშიშროების შესაბამისი ნივთიერებების კლასსა თუ ჯგუფში, შემდეგი პრიორიტეტულობის წესის საფუძველზე: (ა) მე-7 კლასის მასალები (გარდა რადიოაქტიური მასალებისა, გამოთავისუფლებულ შეფუთვებში, რომელთან დაკავშირებითაც გამოიყენება 3.3 თავის 290-ე დებულება, როდესაც პრიორიტეტი ენიჭება სხვა სახიფათო მახასიათებლებს); (ბ) პირველი კლასის ნივთიერებები; (გ) მე-2 კლასის ნივთიერებები; (დ) მე-3 კლასის თხევადი, დესენსიბილიზებული ფეთქებადი ნივთიერებები; (ე) 4.1 კლასის თვითრეაქტიული ნივთიერებები და მყარი დესენსიბილიზებული ფეთქებადი ნივთიერებები; (ვ) 4.2 კლასის პიროფორული ნივთიერებები; (ზ) 5.2 კლასის ნივთიერებები; (თ) 6.1 კლასის ნივთიერებები, რომლებიც აკმაყოფილებს I შეფუთვის ჯგუფის საინჰალაციო ტოქსიკურობის კრიტერიუმებს (ნივთიერებები, რომლებიც პასუხობს მე-8 კლასით გათვალისწინებულ კლასიფიცირების კრიტერიუმებს და გააჩნიათ მტვრისა და ნისლის საინჰალაციო ტოქსიკურობა (LC50) I შეფუთვის ჯგუფის არეალში, ასევე ტოქსიკურობა პერორალური მიღებისა თუ კანზე შეხებისას მხოლოდ III ან უფრო დაბალი შეფუთვის ჯგუფის არეალში, უნდა მიეკუთვნოს მე-8 კლასს); (ი) 2.1.3.5.4 6.2 კლასის ინფექციური ნივთიერებები. იმ შემთხვევაში, თუ ნივთიერების სახიფათო მახასიათებლები წარმოდგენილია ერთზე მეტ კლასსა თუ იმ ნივთიერებების ერთზე მეტ ჯგუფში, რომლებიც არ არის გათვალისწინებული ზემოაღნიშნულ 2.1.3.5.3 ქვეპუნქტში, ნივთიერების კლასიფიკაცია უნდა განხორციელდეს იგივე პროცედურის შესაბამისად, თუმცა შესაბამისი კლასი შეირჩევა 2.1.3.10 ქვეპუნქტში წარმოდგენილი სახიფათო მახასიათებლების პრიორიტეტულობის ცხრილის მიხედვით. 138 2.1.3.5.5 იმ შემთხვევაში, თუ გადასაზიდი ნივთიერება მოიცავს ნარჩენებს, რომლის შემადგენლობაც ზუსტად არ არის ცნობილი, მისი მეკუთვნება გაეროს ნომერსა და შესაბამის შეფუთვის ჯგუფზე 2.1.3.5.2 ქვეპუნქტის შესაბამისად, შესაძლებელია განაპირობოს აღნიშნული ნარჩენების, ასევე ყველა არსებული ტექნიკური და უსაფრთხოების უზრუნველყოფასთან დაკავშირებული მონაცემების შესახებ ტვირთგამგზავნის ცოდნამ, რაც მოთხოვნილია უსაფრთხოებისა და გარემოს შესახებ მოქმედი კანონმდებლობით2. რაიმე ეჭვის არსებობის შემთხვევაში, მაჩვენებლის სახით აღებული უნდა იქნეს საშიშროების უფრო მაღალი დონე. თუმცა იმ შემთხვევაში, თუ ნარჩენების შემადგენლობისა და იდენტიფიცირებული კომპონენტების ფიზიკური და ქიმიური თვისებების შესახებ არსებული ცოდნის საფუძველზე შესაძლებელია იმ ფაქტის დადგენა, რომ ნარჩენების თვისებები არ შეესაბამება I შეფუთვის ჯგუფის დონეზე გათვალისწინებულ თვისებებს, ნარჩენების კლასიფიცირება შესაძლებელია განხორციელდეს ავტომატურად II შეფუთვის ჯგუფის ყველაზე შესაბამის N.O.S. პოზიციაზე. თუმცა იმ შემთხვევაში, თუ ცნობილი გახდება, რომ ნარჩენებისთვის დამახასიათებელია მხოლოდ გარემოსთვის სახიფათო თვისებები, აღნიშნული შესაძლებელია შეყვანილ იქნეს III შეფუთვის ჯგუფში გაეროს ნომრით: 3077 ან 3082. აღნიშნული პროცედურა შესაძლებელია არ იქნეს გამოყენებული იმ ნარჩენებთან დაკავშირებით, რომლებიც შეიცავს 2.1.3.5.3 ქვეპუნქტით გათვალისწინებულ ნივთიერებებს, 4.3 კლასის ნივთიერებებს, 2.1.3.7 ქვეპუნქტში გათვალისწინებულ შემთხვევებთან დაკავშირებით გამოყენებულ ნივთიერებებსა თუ იმ ნივთიერებებს, რომლებიც არ დაიშვება გადაზიდვებზე 2.2.x.1 ქვეპუნქტის თანახმად. 2.1.3.6 ნებისმიერი შემთხვევაში გამოყენებულ უნდა იქნეს ყველაზე კონკრეტული, შესაბამისი, ერთობლივი პოზიცია (იხილეთ 2.1.2.5 ქვეპუნქტი), ანუ საერთო N.O.S. პოზიცია გამოიყენება მხოლოდ იმ შემთხვევაში, როდესაც გენერიული პოზიციისა თუ კონკრეტული N.O.S. პოზიციის გამოყენება შეუძლებელია. 2.1.3.7 მჟანგავი ნივთიერებებისა თუ ჟანგვის დამატებითი საშიშროების მქონე ნივთიერებების შემცველ ხსნარებსა და ნარევებს შესაძლებელია აღენიშნოთ ფეთქებადი თვისებები. მოცემულ შემთხვევაში, ისინი გადაზიდვებზე დაიშვება მხოლოდ პირველ კლასთან დაკავშირებული მოთხოვნების დაკმაყოფილების შემთხვევაში. აღნიშნულ კანონმდებლობას წარმოადგენს, მაგალითად, კომისიის 2000 წლის 3 მაისის 2000/532/EC გადაწყვეტილება, შემცვლელი გადაწყვეტილება 94/3/EC, რომელშიც განსაზღვრულია ნარჩენების ჩამონათვალი ნარჩენების შესახებ საბჭოს 75/442/EEC დირექტივის 1(ა) მუხლის (რომელიც შეიცვალა ევროპარლამენტისა და საბჭოს 2006/12/EC დირექტივით (ევროკავშირის ოფიციალური ჟურნალი #L114, 2006 წლის 27 აპრილი, გვ. 9)) და საბჭოს 94/904/EC დირექტივის შესაბამისად, რომელშიც განსაზღვრულია სახიფათო ნარჩენების ჩამონათვალი სახიფათო ნარჩენების შესახებ საბჭოს 91/689/EEC დირექტივის 1(4) მუხლის შესაბამისად (ევროკავშირის ოფიციალური ჟურნალი #L226, 2000 წლის 6 სექტემბერი, გვ. 3). 2 139 2.1.3.8 1-6.2, 8 და 9 კლასებით გათვალისწინებული ნივთიერებები, გარდა იმ ნივთიერებებისა, რომელთაც მინიჭებული აქვთ გაეროს #3077 ან 3082, და აკმაყოფილებს 2.2.9.1.10 ქვეპუნქტში მოყვანილ კრიტერიუმებს, 1-6.2, 8 და 9 კლასებით გათვალისწინებული საშიშროებების სახეობების გარდა, განიხილება, როგორც გარემოსთვის სახიფათო ნივთიერებები. სხვა ნივთიერებებს, რომლებიც პასუხობს 2.2.9.1.10 ქვეპუნქტში მოყვანილ კრიტერიუმებს, უნდა მიენიჭოთ გაეროს #3077 ან 3082, კონკრეტული შემთხვევიდან გამომდინარე. 2.1.3.9 იმ ნარჩენების გადაზიდვა, რომლებიც ვერ პასუხობს 1-9 კლასებით გათვალისწინებულ კლასიფიცირების კრიტერიუმებს, თუმცა გათვალისწინებულია ბაზელის კონვენციაში სახიფათო ნარჩენების ტრანსსასაზღვრო გადაზიდვებისა და მათი გაუვნებელყოფის კონტროლის შესახებ, დასაშვებია გაეროს # 3077 ან 3082 საფუძველზე. 140 საშიშროებების პრიორიტეტულობის ცხრილი 2.1.3.10 კლასი და 4.1, II 4.1, III 4.2, II 4.2, III 4.3, I 4.3, II 4.3, III 5.1, I 5.1, II 5.1, III შეფუთვის 6.1, I 6.1, I DERMAL ORAL 6.1, II 6.1, III 8.I 8.II 8.III 9 3, I 3, I 3, I 3, I 3, I 3, I 3, I 3, I 3, I 3, I 3, II 3, II 8, I 3, II 3, II 3, II 6.1, I 6.1, I 6.1, III 3, IIIა 8, I 8, II 3, III 3, III 6.1, I 6.1, I ჯგუფი 3, I 3, II 3, III 4.1, II SOL LIQ SOL LIQ SOL LIQ SOL LIQ 4.1 3.I 4.1 3.I 4.2 3.I 4.2 3.I SOL LIQ SOL LIQ SOL LIQ SOL LIQ 4.1 3.II 4.1 3.II 4.2 3.II 4.2 3.II SOL LIQ SOL LIQ SOL LIQ SOL LIQ 4.1 3.II 4.1 3.III 4.2 3.II 4.2 3.III 4.2, II 4.3, I 4.3, I 4.3, I SOL LIQ 5.1, I 3, I 4.2, II 4.3, I 4.3, II 4.3, II SOL LIQ 5.1, II 3, II 4.3, I 4.3, I 4.3, II 4.3, II 4.3, III 4.3, II SOL LIQ SOL LIQ SOL LIQ 5.1, I 3, I 5.1, I 3, I SOL SOL LIQ LIQ 5.1, II 3, II SOL LIQ 5.1, II 3, II SOL LIQ 5.1, II 3, I 5.1, II 3, II 5.1, III 3, III 5.1, I 4.1, II 4.1, II SOL LIQ 4.1, II 6.1, II 4.1, III 4.2, II 4.2, III 4.3, I 4.3, II 4.3, III 5.1, I 4.1, II 4.1, III 6.1, I 6.1, I 6.1, II SOL LIQ 8, I SOL 4.1, II 6.1, II SOL LIQ 4.1, II 8, II LIQ 8, I 8, II SOL 4.1, III 6.1, III 4.2, II 4.3, I 4.3, II 4.3, II 5.1, I 4.2, II 4.2, III 6.1, I 6.1, I 4.2, II 4.2, II 4.2, III 4.3, I 4.3, II 4.3, III SOL LIQ 4.1, II 4.1, II 8, II LIQ 4.1, III 4.1, III 8, III 8, I 4.2, II 4.2, II 4.2, II 4.2, III 5.1, I 5.1, II 4.2, III 6.1, I 6.1, I 6.1, II 4.2, III 8, I 8, II 4.2, III 4.3, I 5.1, I 4.3, I 4.3, I 6.1, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, II 5.1, I 4.3, II 4.3, II 6.1, I 4.3, I 4.3, II 4.3, II 8, I 4.3, II 4.3, II 4.3, II 4.3, III 5.1, I 5.1 II 4.3, III 4.3, III 6.1, I 6.1, I 6.1, II 4.3, III 8, I 8, II 4.3, III 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, II 6.1, I 5.1, I 5.1, II 5.1, II 8, I 5.1, II 5.1, II 5.1, II 5.1, III 6.1, I 6.1, I 6.1, II 5.1, III 8, I 8, II 5.1, III 5.1, III 6.1, I 6.1, I 6.1, I 6.1, I 6.1, I 6.1, I 6.1, II 6.1, II 6.1, II 6.1, II 6.1, II 6.1, II 6.1, II 8, III 6.1, III 6.1, I SOL LIQ DERMAL 6.1, I 8, I 6.1, I SOL LIQ ORAL 6.1, I 8, I 6.1, II SOL LIQ INHAL 6.1, I 8, I SOL LIQ SOL LIQ 6.1, I 8, I 6.1, II 8, II SOL LIQ 6.1, II 8, II 6.1, II DERMAL 6.1, II ORAL 6,1 III 8, I SOL LIQ DERMAL ORAL INHAL ა = = = = = მყარი ნივთიერებები და ნარევები თხევადი ნივთიერებები, ნარევები კანისმიერი ტოქსიკურობა პერორალური ტოქსიკურობა საინჰალაციო ტოქსიკურობა 6.1 კლასი პესტიციდებთან დაკავშირებით 8.1 8, I 8, II 8, I 8, II 8, II 8, III 8, III 141 შენიშვნა 1: მაგალითები, რომლებიც განმარტავს ცხრილის გამოყენების წესს. ცალკეული ნივთიერებების კლასიფიკაცია იმ ნივთიერებების აღწერილობა, რომლებიც ექვემდებარება კლასიფიკაციას: ამინი, რომელიც არ არის მითითებული დასახელებით, შეესაბამება მე-3 კლასის I შეფუთვის ჯგუფით, ასევე მე-8 კლასის I შეფუთვის ჯგუფით გათვალისწინებულ კრიტერიუმებს. პროცედურა: 3 II ხაზის გადაკვეთა 8 I სვეტთან იძლევა 8 I-ს. შესაბამისად აღნიშნული ამინის კლასიფიკაცია მოხდება მე-8 კლასში შემდეგ პოზიციაზე: გაეროს №2734 - თხევადი ამინები, კოროზიული, ადვილაალებადი, N.O.S. ან გაეროს №2734 - პოლიამინები თხევადი, კოროზიული, ადვილაალებადი, N.O.S. შეფუთვის ჯგუფი I ნარევის კლასიფიკაცია კლასიფიკაციას დაქვემდებარებული ნარევის აღწერილობა: ნარევი, რომელიც შედგება მე-3 კლასის III შეფუთვის ჯგუფში კლასიფიცირებული ადვილაალებადი სითხისგან, 6.1 კლასის II შეფუთვის ჯგუფში კლასიფიცირებული ტოქსიკური ნივთიერებისგან და მე-8 კლასის I შეფუთვის ჯგუფში კლასიფიცირებული კოროზიული ნივთიერებისგან. პროცედურა: 3 III ხაზის გადაკვეთა 6.1 II სვეტთან იძლევა 6.1 II-ს. 6.1 II ხაზის გადაკვეთა 8 I სვეტთან იძლევა 8 I LIQ-ს. შესაბამისად აღნიშნული ნარევის, რომელიც შემდგომში არ ექვემდებარება დაზუსტებას, კლასიფიკაცია უნდა მოხდეს მე-8 კლასში შემდეგ პოზიციაზე: გაეროს №2922 - კოროზიული სითხე, ტოქსიკური N.O.S. შეფუთვის ჯგუფი I. შენიშვნა 2: ნარევებისა და ხსნარების კლასიფიცირების მაგალითები შესაბამის კლასსა და შეფუთვის ჯგუფში: 6.1 (II) კლასში გათვალისწინებული ფენოლის ხსნარი 3 (II) კლასის ბენზოლში კლასიფიცირდება მე-3 (II) კლასში; აღნიშნული ხსნარის კლასიფიკაცია უნდა განხორციელდეს შემდეგ პოზიციაზე: გაეროს № 1992 - ადვილაალებადი სითხეები, ტოქიკური, N.O.S., მე-3 (II) კლასი, ფენოლის ტოქსიკურობის სახით. 6.1 (II) კლასით გათვალისწინებული ნატრიუმის არსენატის მყარი ნარევი და მე-8 (II) კლასით გათვალისწინებული ნატრიუმის ჰიდროჟანგი კლასიფიცირდება შემდეგ პოზიციაზე: გაეროს №3290 - ტოქსიკური მყარი ნივთიერება, კოროზიული, არაორგანული, N.O.S., 6.1 (II) კლასში. 4.1 (II) კლასის ნედლი ან გასუფთავებული ნაფტალინის ხსნარი მე-3 (II) კლასის ბენზინში კლასიფიცირდება შემდეგ პოზიციაზე: გაეროს №3295 - ნახშირწყალბადები, თხევადი, N.O.S., მე-3 (II) კლასში. 142 მე-3 (III) კლასის ნახშირწყალბადებისა და მე-9 (II) კლასის პოლიქლორბიფენილების (პქდ) ნარევი კლასიფიცირდება შემდეგ პოზიციაზე: გაეროს №2315 პოლიქლორბიფენილები, თხევადი ან გაეროს № 3432 - პოლიქლორბიფენილები, მყარი, მე-9 (II) კლასში. მე-3 კლასის პროპილენიმინისა და მე-9 (II) კლასის პოლიქლორბიფენილების (პქდ) ნარევი კლასიფიცირდება პოზიციაზე გაეროს №1921 - პროპილენიმინი, ინჰიბირებული, მე-3 კლასში. 2.1.4 ნიმუშების კლასიფიკაცია 2.1.4.1 იმ შემთხვევაში, თუ ნივთიერების კლასი გაურკვეველია და მისი გადაზიდვა ხორციელდება დამატებითი გამოცდების ჩატარების მიზნით, მას განესაზღვრება დროებითი კლასი, გადაზიდვის შესაბამისი დასახელება და გაეროს ნომერი აღნიშნული ნივთიერების შესახებ ტვირთგამგზავნის ცოდნისა და შემდეგის გამოყენების საფუძველზე: (ა) 2.2 თავით გათვალისწინებული კლასიფიცირების კრიტერიუმები; და (ბ) წინამდებარე თავის მოთხოვნები. შერჩეული გადაზიდვის შესაბამის დასახელებასთან დაკავშირებით შეძლებისდაგვარად გამოყენებულ უნდა იქნეს ყველაზე შეზღუდული შეფუთვის ჯგუფი. აღნიშნული დებულების გამოყენების შემთხვევაში, გადაზიდვის დასახელებას დაემატება სიტყვა „ნიმუში“ (მაგალითად, „ადვილაალებადი სითხე, N.O.S. ნიმუში“). გარკვეულ შემთხვევებში, როდესაც ნივთიერების ნიმუშთან დაკავშირებით, რომელიც, როგორც ითვლება, რომ აკმაყოფილებს გარკვეული კლასიფიკაციის კრიტერიუმებს, გათვალისწინებულს კონკრეტული გადაზიდვის შესაბამისი დასახელებით (მაგალითად, აირის ნიმუში, არა-წნევის ქვეშ, ადვილაალებადი, გაეროს №3167), გამოყენებულ უნდა იქნეს აღნიშნული გადაზიდვის შესაბამისი დასახელება. იმ შემთხვევაში, თუ ნიმუშის გადასაზიდად გამოიყენება N.O.S. პოზიცია 3.3 თავის 274-ე სპეციალური დებულების შესაბამისად, აუცილებელი არ არის ტექნიკური დასახელების დამატება გადაზიდვის შესაბამის დასახელებაზე. 2.1.4.2 ნივთიერებების ნიმუშების გადაზიდვა უნდა მოხდეს დროებით დადგენილი გადაზიდვის შესაბამისი დასახელებასთან დაკავშირებული მოთხოვნების შესაბამისად იმ პირობით, რომ (ა) მოცემული ნივთიერება არ განიხილება იმ ნივთიერებად, რომელიც არ დაიშვება გადაზიდვებზე 2.2 თავის 2.2.x.2 ქვეპუნქტის ან 3.2 თავის შესაბამისად; (ბ) მოცემული ნივთიერება არ განიხილება პირველი კლასის კრიტერიუმებთან შესაბამისად ან ითვლება ინფექციურ ნივთიერებად ან რადიოაქტიურ მასალად; (გ) ნივთიერება პასუხობს 2.2.41.1.15 ან 2.2.52.1.9 ქვეპუნქტის მოთხოვნებს იმ შემთხვევაში, თუ ის წარმოადგენს თვითრეაქტიულ ნივთიერებას ან ორგანულ პეროქსიდს, შესაბამისად; (დ) ნიმუშის გადატანა ხდება კომბინირებულ ტარაში, რომლის სუფთა მასა ყოველ შეკვრაზე არ აღემატება 2.5 კგ-ს; და (ე) ნიმუშები არ არის შეფუთული სხვა ტვირთებთან ერთად. 143 2.1.5. წუნდებული, ცარიელი, გაუსუფთავებელი ტარის კლასიფიკაცია ცარიელ, გაუსუფთავებელ ტარას, მსხვილგაბარიტიან ტარას ან მასიური ტვირთის კონტეინერებს, ან მათ ნაწილებს, რომელთა გადაზიდვაც ხორციელდება გაუვნებელყოფის, უტილიზაციის ან მათი მასალების რეკუპერაციის მიზნით, გარდა აღდგენის, შეკეთების, რეგულარული ტექნიკური მომსახურების, რეკონსტრუირების ან განმეორებით გამოყენების მიზნებისა, შესაძლებელია მიენიჭოს გაეროს №3509 იმ შემთხვევაში, თუ აკმაყოფილებს აღნიშნული პოზიციისთვის განსაზღვრულ მოთხოვნებს. 144 თავი 2.2 ცალკეული კლასისთვის დამახასიათებელი დებულებები 2.2.1 პირველი კლასი 2.2.1.1 კრიტერიუმები 2.2.1.1.1 პირველი კლასის სათაურები მოიცავს შემდეგს: (ა) ფეთქებადი ნივთიერებები და ნაკეთობები ფეთქებადი ნივთიერებები: მყარი ან თხევადი ნივთიერებები (ან ნივთიერებების ნარევები), რომელთაც ქიმიური რეაქციის შედეგად შეუძლიათ აირების გამოყოფა იმ ტემპერატურასა და წნევაზე, ასევე იმ სიჩქარით, რაც ზიანს მიაყენებს გარშემო არსებულ ობიექტებს. პიროტექნიკური ნივთიერებები: ნივთიერებები ან ნივთიერებების ნარევი, რომლის დანიშნულებაა მოახდინოს ეფექტი სითბოს, განათების, ხმის, აირის, კვამლის ან მათი კომბინაციის სახით და მიიღება ავტომატური ეგზოთერმული ქიმიური რეაქციების შედეგად, რომელიც დეტონაციის გარეშე მიმდინარეობს; შენიშვნა 1: ის ნივთიერებები, რომლებიც არ ატარებს ფეთქებად ხასიათს, თუმცა აირთან, ორთქლსა თუ მტვერთან შეხებისას შეუძლია წარმოქმნას ფეთქებადი ნარევი, არ წარმოადგენს პირველი კლასის ნივთიერებებს. შენიშვნა 2: პირველი კლასის ნივთიერებებში ასევე არ შედის: წყალში ან სპირტში დასველებული ფეთქებადი ნივთიერებები, რომელშიც წყლის ან სპირტის შემცველობა აღემატება დადგენილ ზღვარს, ასევე ნივთიერებები, რომლებიც შეიცავს პლასტიფიკატორებს - აღნიშნული ფეთქებადი ნივთიერებები შედის მე-3 ან 4.1 კლასში, - ასევე ის ფეთქებადი ნივთიერებები, რომლებიც მათი მომატებული საფრთხის საფუძველზე, გათვალისწინებულია 5.2 კლასში. (ბ) ფეთქებადი ნაკეთობები: ნაკეთობები, რომლებიც შეიცავს ერთ ან რამდენიმე ფეთქებად ან პიროტექნიკურ ნივთიერებას; შენიშვნა: პირველი კლასით გათვალისწინებული მოთხოვნები არ ვრცელდება იმ მოწყობილობებზე, რომლებიც შეიცავს ისეთი მცირე რაოდენობის ან ისეთი სახის ფეთქებად ან პიროტექნიკურ ნივთიერებებს, რომ მათი გაუფრთხილებლობით გამოწვეული ან შემთხვევითი აალება ან ინიცირება გადაზიდვების დროს არ გამოიწვევს რაიმე გარე გამოვლინებას მოწყობილობის ფარგლებში ელემენტების გაფანტვის, ხანძრის, კვამლის, სიცხის ან ხმამაღალი ხმაურის შედეგად. (გ) ნივთიერებები და ნაკეთობები, რომლებიც არ არის მითითებული ზემოთ და რომლებიც მზადდება აფეთქებით პრაქტიკული ეფექტების ან პიროტექნიკური ეფექტების წარმოქმნის მიზნით. პირველი კლასით გათვალისწინებული მიზნებიდან გამომდინარე, გამოიყენება შემდეგი განმარტებები: ფლეგმატიზებული ნიშნავს იმ შემთხვევას, როდესაც ფეთქებად ნივთიერებას ემატება ესა თუ ის ნივთიერება (ანუ „ფლეგმატიზატორი“) მისი უსაფრთხოების გაზრდის მიზნით მისი დამუშავების ან გადაზიდვების დროს. ფლეგმატიზატორის დამატების შედეგად ფეთქებადი ნივთიერება კარგავს მგრძნობელობას ან ხდება ნაკლებად 145 მგრძნობიარე ზემოქმედების შემდეგი ფაქტორების მიმართ: სითბო, ბიძგი, დარტყმა, რყევა ან ხახუნი. ფლეგმატიზაციის ტიპიური ნივთიერებები მოიცავს, მაგრამ არ შემოიფარგლება შემდეგით: ცვილი, ქაღალდი, წყალი, პოლიმერები (მაგალითად, ქლორ-ფტორ-პოლიმერები), სპირტი ან ზეთები (მაგალითად, ვაზელინის ზეთი და პარაფინი). 2.2.1.1.2 ნებისმიერი ნივთიერება ან ნაკეთობა, რომელსაც გააჩნია ან მიიჩნევა, რომ გააჩნია ფეთქებადი თვისებები, უნდა განიხილოს პირველ კლასში ტესტირებებისა და კრიტერიუმების სახელმძღვანელოს I ნაწილში გათვალისწინებული ტესტირებების, პროცედურებისა და კრიტერიუმების შესაბამისად. პირველ კლასში გათვალისწინებული ნივთიერებებისა თუ ნაკეთობების დაშვება გადაზიდვებზე შესაძლებელია მხოლოდ იმ შემთხვევაში, თუ მას მინიჭებული აქვს 3.2 თავის A ცხრილში ჩამოთვლილი დასახელება ან N.O.S. პოზიცია და აკმაყოფილებს ტესტირებებისა და კრიტერიუმების სახელმძღვანელოში გათვალისწინებულ მოთხოვნებს. 2.2.1.1.3 პირველი კლასით გათვალისწინებულ ნივთიერებებსა და ნაკეთობებს უნდა მიენიჭოთ გაეროს ნებისმიერი ნომერი ან 3.2 თავის A ცხრილში ჩამოთვლილი დასახელება ან N.O.S. პოზიცია. 3.2 თავის A ცხრილში მითითებული ნივთიერებებისა და ნაკეთობების დასახელებების ინტერპრეტაცია უნდა მოხდეს 2.2.1.4 ქვეპუნქტში წარმოდგენილი სარჩევის მიხედვით. ახალი ან არსებული ფეთქებადი ნივთიერებებისა თუ ნაკეთობების ნიმუშები, რომელთა გადაზიდვაც ხორციელდება სხვა მიზნებთან ერთად საგამოცდო, კლასიფიკაციის, კვლევისა და განვითარების, ხარისხის მართვის მიზნით, ან კომერციული ნიმუშის სახით, მაინიცირებელი ფეთქებადი ნივთიერებების გარდა, შესაძლებელია მიეკუთვნოს გაეროს #0190 - ფეთქებადი ნივთიერებების ნიმუშები. იმ ნივთიერებებისა და ნაკეთობების მიკუთვნება, რომლებიც 3.2 თავის A ცხრილში არ არის მითითებული დასახელებით, პირველი კლასის ამა თუ იმ N.O.S. პოზიციაზე ან გაეროს #0190 - ფეთქებადი ნივთიერებების ნიმუშები, ასევე გარკვეული ნივთიერებების მიკუთვნება, რომელთა გადაზიდვაც ექვემდებარება კომპეტენტური ორგანოს მიერ გაცემულ კონკრეტულ ნებართვას 3.2 თავის A ცხრილის (6) სვეტში მითითებული სპეციალური დებულებების შესაბამისად, უნდა განხორციელდეს წარმოშობის ქვეყნის კომპეტენტური ორგანოს მიერ. აღნიშნულმა კომპეტენტურმა ორგანომ ასევე უნდა დაამტკიცოს წერილობითი ფორმით წინამდებარე ნივთიერებებისა და ნაკეთობების გადაზიდვის პირობები. იმ შემთხვევაში, თუ გადაზიდვის ქვეყანა არ წარმოადგენს ADRის ხელშემკვრელ მხარეს, მაშინ კლასიფიკაცია და გადაზიდვის პირობები აღიარებულ უნდა იქნეს იმ პირველივე ქვეყნის კომპეტენტური ორგანოს მიერ, რომელიც წარმოადგენს ADR-ის ხელშემკვრელ მხარეს ტვირთების გადაზიდვის მარშრუტზე. 2.2.1.1.4 პირველი კლასით გათვალისწინებული ნივთიერებები და ნაკეთობები უნდა მიეკუთვნოს ერთ-ერთ ქვეკლასს 2.2.1.1.5 ქვეპუნქტის შესაბამისად და რომელიმე შესაბამისობის ჯგუფს 2.2.1.1.6 ქვეპუნქტის შესაბამისად. ქვეკლასი განისაზღვრება 2.3.0 და 2.3.1 პუნქტებში აღწერილი გამოცდების შედეგების მიხედვით, 2.2.1.1.5 ქვეპუნქტში მოყვანილი განსაზღვრებების გამოყენებით. შესაბამისობის ჯგუფი უნდა განისაზღვროს 2.2.1.1.6 ქვეპუნქტში გათვალისწინებული განმარტებების შესაბამისად. კლასიფიკაციის კოდი შედგება ქვეკლასის ნომრისა და შესაბამისობის ჯგუფის განმსაზღვრელი ასოსგან. 146 2.2.1.1.5 ქვეკლასების განსაზღვრება ქვეკლასი 1.1 ნივთიერებები და ნაკეთობები, რომელთაც ახასიათებთ მასიური აფეთქების საშიშროება (მასიური აფეთქება ნიშნავს აფეთქებას, რომელიც პრაქტიკულად მყისიერად ვრცელდება თითქმის მთელ ტვირთზე). ქვეკლასი 1.2 ნივთიერებები და ნაკეთობები, რომელთაც ახასიათებთ გაფანტვის საშიშროება, მაგრამ არა მასიური აფეთქების საშიშროება. ქვეკლასი 1.3 ნივთიერებები და ნაკეთობები, რომელთაც თან ახლავთ ხანძრის გაჩენის საშიშროება, ასევე უმნიშვნელო აფეთქების საშიშროება ან უმნიშვნელო გაფანტვის საშიშროება თუ ორივე ერთად, თუმცა არა მასიური აფეთქების საშიშროება: (ა) რომლებიც წვის დროს გამოჰყოფს მნიშვნელოვან რაოდენობას, ან რადიაციული სითბოს (ბ) რომლებსაც, თანმიმდევრულად წვისას, ახასიათებთ უმნიშვნელო აფეთქების ან გავრცელების ეფექტები ან ორივე მათგანი. ქვეკლასი 1.4 ნივთიერებები და ნაკეთობები, რომლებიც წარმოადგენს აფეთქების მხოლოდ უმნიშვნელო საშიშროებას გადაზიდვების დროს აალების ან ინიცირების შემთხვევაში. აღნიშნული ეფექტები ძირითადად თავს იჩენს შეფუთვის შიგნით და ამ შემთხვევაში არ არის მოსალოდნელი მნიშვნელოვანი ზომისა თუ მოცულობის ნატეხების გავრცელება. გარეგანმა ხანძარმა არ უნდა გამოიწვიოს შეფუთვის თითქმის მთლიანი შიგთავსის პრაქტიკულად მყისიერი აფეთქება. ქვეკლასი 1.5 ძალიან დაბალი მგრძნობელობის ნივთიერებები, რომელთაც ახასიათებთ მასიური აფეთქების საშიშროება, თუმცა აღენიშნებათ იმდენად დაბალი მგრძნობელობა, რომ არსებობს მათი ინიცირების ან წვიდან დეტონაციის მდგომარეობაში გადასვლის ძალიან მცირე ალბათობა გადაზიდვების ნორმალურ პირობებში. მინიმალური მოთხოვნების შესაბამისად, ისინი არ უნდა აფეთქდნენ მათი გამოცდისას ხანძრის მიმართ მედეგობაზე. ქვეკლასი 1.6 უკიდურესად დაბალი მგრძნობელობის ნაკეთობები, რომელთაც არ აღენიშნებათ მასიური აფეთქების საშიშროება. აღნიშნული ნაკეთობები შეიცავს მხოლოდ უკიდურესად არამგრძნობიარე მადეტონირებელ ნივთიერებებს და ავლენს ააფეთქების ინიცირებისა თუ გავრცელების უმნიშვნელო ალბათობას. შენიშვნა: 1.6 ქვეკლასით გათვალისწინებული ნაკეთობებისთვის დამახასიათებელი საშიშროება შემოიფარგლება ერთი ნაკეთობის აფეთქებით. 2.2.1.1.6 ნივთიერებებისა და ნაკეთობების შესაბამისობის ჯგუფების განმარტება A. პირველადი ფეთქებადი ნივთიერებები. B. ნაკეთობები, რომლებიც შეიცავს პირველად ფეთქებად ნივთიერებებს და არ გააჩნიათ ორი ან მეტი ეფექტური დამცავი მოწყობილობები. აღნიშნულ ჯგუფში გათვალისწინებულია ზოგიერთი ისეთი ნაკეთობა, როგორიცაა დეტონატორები ასაფეთქებელი სამუშაოებისთვის, დეტონატორების კრებულები ასაფეთქებელი 147 სამუშაოებისა და კაფსულა-მაალებელისთვის იმ შემთხვევაშიც კი, თუ ისინი არ შეიცავს პირველად ფეთქებად ნივთიერებებს. G. საწვავი ფეთქებადი ნივთიერება ან სხვა ადვილაალებადი ფეთქებადი ნივთიერება ან ნაკეთობა, რომლებიც შეიცავს აღნიშნულ ფეთქებად ნივთიერებას. D. მეორეხარისხოვანი მადეტონირებელი ფეთქებადი ნივთიერება ან შავი ფხვნილი ან ნაკეთობა, რომელიც შეიცავს მეორეხარისხოვან მადეტონირებელ ნივთიერებას, ნებისმიერ შემთხვევაში არ გააჩნია ინიცირების საშუალებები თუ სატყორცნი მუხტი, ან საწყისი ფეთქებადი ნივთიერების შემცველი ნაკეთობა, თუმცა გააჩნია ორი ან მეტი ეფექტური დამცავი მოწყობილობები. E. მეორეხარისხოვანი მადეტონირებელი ფეთქებადი ნივთიერების შემცველი ნაკეთობა, ინიცირების საშუალების გარეშე, თუმცა სატყორცნი მუხტით (იმ მუხტის გარეშე, რომელიც შეიცავს ადვილაალებად სითხეს ან გელს ან თვითაალებად სითხეებს). F. მეორეხარისხოვანი მადეტონირებელი ფეთქებადი ნივთიერების შემცველი ნაკეთობა, ინიცირების საკუთარი საშუალებასთან ერთად, სატყორცნი მუხტით (იმ მუხტის გარეშე, რომელიც შეიცავს ადვილაალებად სითხეს ან გელს ან თვითაალებად სითხეებს) ან სატყორცნი მუხტის გარეშე. G. პიროტექნიკური ნივთიერება ან პიროტექნიკური ნივთიერების შემცველი ნაკეთობა ან როგორც ფეთქებადი ნივთიერების, ასევე გამანათებელი, ამნთები, ცრემლსადენი ან კვამლის წარმომშობი ნივთიერების შემცველი ნაკეთობა (გარდა წყალზე მომუშავე ნაკეთობისა თუ იმ ნაკეთობისა, რომელიც შეიცავს თეთრ ფოსფორს, ფოსფიდებს, პიროფორულ ნივთიერებას, ადვილაალებად სითხეს ან გელსა თუ თვითაალებად სითხეებს). H. როგორც ფეთქებადი ნაკეთობები. J. როგორც ფეთქებადი ნივთიერების, ასევე ადვილაალებადი სითხისა თუ გელის შემცველი ნაკეთობები. K. როგორც ფეთქებადი ნივთიერების, ასევე ტოქსიკური ქიმიური ნივთიერების შემცველი ნაკეთობები. L. ფეთქებადი ნივთიერება ან ფეთქებადი ნივთიერების შემცველი ნაკეთობა, რომელიც წარმოადგენს განსაკუთრებულ საშიშროებას (მაგალითად, წყალზე გააქტიურების ან თვითაალებადი სითხეების, ფოსფიდების ან პიროფორული ნივთიერების არსებობის მიზეზით), რაც მოითხოვს ყოველი ტიპის იზოლირებას. N. მხოლოდ უკიდურესად არამგრძნობიარე საშუალების შემცველი ნაკეთობები. S. ნივთიერება ან ნაკეთობა, რომელიც შეფუთულია ან კონსტრუირებულია იმ სახით, რომ შემთხვევითი ამოქმედების შედეგად წარმოშობილი ნებისმიერი სახიფათო ეფექტები არ გაცდება შეფუთვის ფარგლებს, ხოლო იმ შემთხვევაში, თუ შეფუთვა დაზიანებულია ხანძრის შედეგად, აფეთქების ან გავრცელების ყველა ეფექტი შემოიფარგლება იმ მოცულობით, რა მოცულობითაც ისინი არსებითად არ უშლის ხელს ან ახდენს ხასნძარსაწინააღმდეგო ან სხვა გადაუდებელი ღონისძიებების პრევენციას შეფუთვის უშუალო სიახლოვეში. ნივთიერების, ასევე თეთრი ფოსფორის შემცველი შენიშვნა 1: კონკრეტულ ტარაში შეფუთული ყოველი ნივთიერება ან ნაკეთობა შესაძლებელია განეკუთვნოს მხოლოდ ერთ შესაბამისობის ჯგუფს. ვინაიდან S 148 შესაბამისობის ჯგუფის კრიტერიუმები ეფუძნება გამოცდილებას, ნივთიერებებისა და ნაკეთობების მიკუთვნება აღნიშნულ ჯგუფზე უკავშირდება კლასიფიკაციის კოდის დადგენის მიზნით ჩატარებულ გამოცდას. შენიშვნა 2: D და E შესაბამისობის ჯგუფების ნაკეთობები შესაძლებელია მორგებული იქნეს ან შეიფუთოს ინიცირების საკუთარ საშუალებებთან ერთად იმ პირობით, რომ აღნიშნულ საშუალებებს ექნებათ მინიმუმ ორი ეფექტური დამცავი მოწყობილობა აფეთქების პრევენციის უზრუნველსაყოფად ინიცირების საშუალებების შემთხვევითი ამოქმედების შემთხვევაში. აღნიშნული ნაკეთობები და შეფუთვები განეკუთვნება D ან E შესაბამისობის ჯგუფებს. შენიშვნა 3: D და E შესაბამისობის ჯგუფების ნაკეთობები შესაძლებელია შეიფუთოს ინიცირების საკუთარ საშუალებებთან ერთად იმ პირობით, რომელთაც არ გააჩნიათ ორი ეფექტური დამცავი მოწყობილობა (ანუ B შესაბამისობის ჯგუფს განკუთვნილი ინიცირების საშუალებები) იმ პირობით, რომ ისინი უპასუხებს 4.1.10 პუნქტის MP21 ერთობლივი შეფუთვის დებულებით გათვალისწინებულ მოთხოვნებს. აღნიშნული შეფუთვები განეკუთვნება D ან E შესაბამისობის ჯგუფებს. შენიშვნა 4: ნაკეთობები შესაძლებელია მორგებული იქნეს ან შეიფუთოს აალების საკუთარ საშუალებებთან ერთად იმ პირობით, რომ აალების საშუალებების ამოქმედება გადაზიდვის ნორმალურ პირობებში გამორიცხულია. შენიშვნა 5: C, D და E შეთავსებადობის ჯგუფის ნაკეთობები შესაძლებელია შეიფუთოს ერთად. აღნიშნული შეფუთვები განეკუთვნება E შესაბამისობის ჯგუფს. 2.2.1.1.7 პიროტექნიკური ნაკეთობების მიკუთვნება შესაბამის ქვეკლასებზე. 2.2.1.1.7.1 პიროტექნიკური ნაკეთობები ჩვეულებრივ განეკუთვნება 1.1, 1.2, 1.3 და 1.4 ქვეკლასებს ცდებისა და კრიტერუმების სახელმძღვანელოს მე-6 ცდების სერიების შედეგად განხორციელებული ცდების მონაცემების საფუძველზე. თუმცა, ვინაიდან აღნიშნული ნაკეთობების ნომენკლატურა ძალზედ ვრცელია, ხოლო საცდელი მოწყობილობების ხელმისაწვდომობა შესაძლებელია შეზღუდული იყოს, მათი ამა თუ იმ ქვეკლასზე მიკუთვნება შესაძლებელია განხორციელდეს 2.2.1.1.7.2 ქვეპუნქტით გათვალისწინებული პროცედურის შესაბამისად. 2.2.1.1.7.2 პიროტექნიკური ნაკეთობების მიკუთვნება გაეროს #0333, 0334, 0335 და 0336 შესაძლებელია განხორციელდეს ანალოგიურ საფუძველზე, მე-6 სერიით გათვალისწინებული გამოცდების განხორციელების საჭიროების გარეშე, 2.2.1.1.7.5 ქვეპუნქტში მოყვანილი პიროტექნიკური ნაკეთობების კლასიფიკაციის ცხრილთან ავტომატური შესაბამისობით. ზემოაღნიშნული სახის მიკუთვნება ხორციელდება კომპეტენტურ ორგანოსთან შეთანხმებით. იმ ნაკეთობების კლასიფიკაცია, რომელიც არ არის გათვალისწინებული ცხრილში, უნდა განხორციელდეს მე-6 ცდების სერიებიდან მიღებული გამოცდების მონაცემების საფუძველზე. შენიშვნა 1: პიროტექნიკური ნაკეთობების სხვა ტიპების დამატება 2.2.1.1.7.5 ქვეპუნქტში გათვალისწინებული ცხრილის პირველ სვეტში შესაძლებელია განხორციელდეს მხოლოდ სახიფათო ტვირთების გადაზიდვების საკითხებში გაეროს ექსპერტთა ქვეკომიტეტის მიმართ განსახილველად წარდგენილი გამოცდების სრული მონაცემების საფუძველზე. 149 შენიშვნა 2: კომპეტენტური ორგანოების მიერ მიღებული გამოცდების მონაცემები, რომლებიც ადასტურებს ან ეწინააღმდეგება 2.2.1.1.7.5 ქვეპუნქტში გათვალისწინებული ცხრილის მე-4 სვეტში მითითებული პიროტექნიკური სამუშაოების მიკუთვნებას მე-5 სვეტში მოყვანილ ქვეკლასებზე, უნდა წარედგინოს სახიფათო ტვირთების გადაზიდვების საკითხებში გაეროს ექსპერტთა ქვეკომიტეტს ინფორმაციისთვის. 2.2.1.1.7.3 იმ შემთხვევაში, თუ ერთ ტარაში წარმოდგენილია ერთზე მეტ ქვეკლასს განკუთვნილი პიროტექნიკური ნაკეთობები, მათი კლასიფიკაცია უნდა მოხდეს ყველაზე სახიფათო ქვეკლასის საფუძველზე, თუ მე-6 ცდების სერიის საფუძველზე მიღებული მონაცემები სხვაგვარად არ მოითხოვს. 2.2.1.1.7.4 2.2.1.1.7.5 ქვეპუნქტში გათვალისწინებულ ცხრილში წარმოდგენილი კლასიფიკაცია მოქმედებს მხოლოდ ბოჭკოვანი მუყაოსგან (4G) დამზადებულ ყუთებში შეფუთულ ნაკეთობებთან დაკავშირებით. 2.2.1.1.7.5 პიროტექნიკური ნაკეთობების ავტომატური კლასიფიკაციის ცხრილი 1 შენიშვნა 1: ცხრილში პროცენტულ წილებზე წარმოდგენილი მითითებები, თუ სხვაგვარად არ არის მითითებული, წარმოადგენს ყველა პიროტექნიკური ნივთიერების (მაგალითად, სარაკეტო ძრავების, ასაწევი მუხტის, ფეთქებადი მუხტისა და შესაბამისი ეფექტების მისაღები მუხტის) მასაზე განსაზღვრულ პროცენტულ წილებს. შენიშვნა 2: წინამდებარე ცხრილში წარმოდგენილი „მანათობელი შემადგენლობა“ გულისხმოს ფხვნილის ფორმით წარმოდგენილ პიროტექნიკურ ნივთიერებებს ან პიროტექნიკურ ნაკეთობებში წარმოდგენილ პიროტექნიკურ კომპონენტებს, რომლებიც გამოიყენება აკუსტიკური ეფექტის მისაღებად ან ფეთქებადი მუხტისა თუ სატყორცნი მუხტის სახით, გარდა იმ შემთხვევისა, როდესაც ცდებისა და კრიტერიუმების სახელმძღვანელოს მე-7 დანართში გათვალისწინებული სახიფათო ნივთიერებების ჩამონათვალის აალების შემადგენლობის გამოცდის დროს წნევის აწევასთან დაკავშირებით განსაზღვრული დრო ნაჩვენებია, რომ აღემატება 6 მლ/წმ-ს ყოველ 0.5 გრამ პიროტექნიკურ ნივთიერებაზე. შენიშვნა 3: მილიმეტრებში დაკავშირებით: წარმოდგენილი ზომები გამოიყენება შემდეგთან - სფეროსებრი კორპუსებსა და მრავალი წყვეტის მქონე კორპუსებთან დაკავშირებით კორპუსის სფეროს დიამეტრი; - ცილინდრულ კორპუსებთან დაკავშირებით - კორპუსის სიგრძე; - მორტირებში წარმოდგენილ კორპუსებთან, რომაულ სანათებთან, საფანტ მილისებრ პიროტექნიკურ საშუალებებსა თუ ნახვრეტებთან დაკავშირებით - პიროტექნიკური ნაკეთობებისგან შემდგარი ან მათი შემცველი მილის შიგა დიამეტრი; - ქაღალდის ნახვრეტებთან ან ცილინდრული ფორმის ნახვრეტებთან დაკავშირებით ნახვრეტებზე გათვალისწინებული დუღაბის შიგა დიამეტრი. 1 აღნიშნული ცხრილი შეიცავს პიროტექნიკური ნაკეთობების კლასიფიკაციების ჩამონათვალს, რომელიც შესაძლებელია გამოყენებულ იქნეს მე-6 ცდების სერიებით მიღებული შედეგების არარსებობის შემთხვევაში (იხილეთ 2.2.1.1.7.2 ქვეპუნქტი). 150 ტიპი სფერული ან ცილინდრული კორპუსი შეიცავს: / სინონიმი: სფერული კორპუსი საჩვენებელი ღონისძიებებისთვის: აკუსტიკური კორპუსი, ფერადი კორპუსი, ფერითი კორპუსი, მრავალი წყვეტის მქონე კორპუსი, მრავალი ეფექტის მქონე კორპუსი, საზღვაო კორპუსი, კორპუსი-პარაშუტი, კვამლის კორპუსი, ვარსკვლავისებრი კორპუსი; გადაცემის კორპუსის: ხმოვანი რაკეტა, სალუტი, ბგერითი კორპუსი, ტანდერი, საჰაერო კორპუსის კომპლექტი განმარტება მოწყობილობა სატყორცნი მუხტით ან მის გარეშე, შენელებულ ან ასაფეთქებელ მუხტთან, პიროტექნიკურ ერთეულ(ებ)თან და ფხვიერ პიროტექნიკურ ნივთიერებებთან ერთად, რომლის გასროლაც გათვალისწინებულია მორტირიდან მრავალი წყვეტის მქონე კორპუსი (კორპუსი-არაქისი) ხელსაწყო ორ ან ორზე მეტ სფერულ საჰაერო კორპუსის საერთო მასრაში, რომლის გასროლაც ხდება ერთი და იგივე სატყორცნი მუხტით, განცალკევებული გარე შენელების მცველთან ერთად გამშვები მორტირის შიგნით წარმოდგენილი სფერული ან ცილინდრული კორპუსისგან შემდგარი აგრეგატი, საიდანაც ხდება კორპუსის გასროლა წინასწარ დამუხტული მორტირი, კორპუსი მორტირში კორპუსების კორპუსი (სფერული) (კორპუსების კორპუსთან დაკავშირებული პროცენტული წილის მაჩვენებლები წარმოადგენს პიროტექნიკური ნაკეთობების საერთო მასას) ხელსაწყო სატყორცნი მუხტის გარეშე, შემანელებელ და ასაფეთქებელ მუხტთან ერთად, რომელიც მოიცავს გადამცემ კორპუსებსა თუ ინერტულ მასალას და განკუთვნილია სატყორცნი მორტირიდან სასროლად 151 სპეციფიკაცია ყველა გადამცემი კორპუსი ფერადი კორპუსი: > 180 მმ ფერადი კორპუსი: <180 მმ >25% ფეთქებადი შემადგენლობით, ფხვიერი ფხვნილისა და/ან ხმოვანი ეფექტების სახით ფერადი კორპუსი: <180 მმ <25% ფეთქებადი შემადგენლობით, ფხვიერი ფხვნილისა და/ან ხმოვანი ეფექტების სახით ფერადი კორპუსი: <50 მმ ან < 60 გრ პიროტექნიკური ნივთიერება, < 2% ფხვიერი ფხვნილისა და/ან ხმოვანი ეფექტების სახით კლასიფიკაცია 1.1G 1.1G 1.1G 1.3G 1.4G კლასიფიკაცია განისაზღვრება ყველაზე სახიფათო სფერული კორპუსების მიხედვით ყველა გადამცემიკორპუსი 1.1G ფერადი კორპუსი: > 180 მმ 1.1G ფერადი კორპუსი: >25% ფეთქებადი შემადგენლობით, ფხვიერი ფხვნილისა და/ან ხმოვანი ეფექტების სახით ფერადი კორპუსი: > 50 მმ და <180 მმ ფერადი კორპუსი: <50 მმ ან < 60 გრ პიროტექნიკური ნივთიერება, < 25% ფხვიერი ფხვნილისა და/ან ხმოვანი ეფექტების სახით > 120 მმ 1.1G 1.2G 1.3G 1.1G ტიპი სფერული ან ცილინდრული კორპუსი (გაგრძელება) ბატარეა / კომბინაცია რომაული ნათურა შეიცავს: / სინონიმი: ცეცხლის ტალღა, პატარა ბომბები, ბრიკეტები, საფინალო კოლოფები, ყვავილების ჩასადები, ჰიბრიდი, მრავლობითი მილები, კორპუსის ბრიკეტები, ბატარეა-პეტარდა, ბატარეა-პეტარდა აფეთქებით საჩვენებელი ნათურა, ნათურა, კომეტები განმარტება ხელსაწყო სატყორცნი მუხტის გარეშე, შემანელებელ და ასაფეთქებელ მუხტთან ერთად, რომელიც შეიცავს ყოველ გადამცემ ერთეულზე < 25 გრ ფეთქებადი შემადგენლობის მქონე გადამცემ კორპუსებს, <33% ფეთქებად შემადგენლობასა და > 60% ინერტულ მასალასთან ერთად და განკუთვნილია სატყორცნი მორტირიდან სასროლად ხელსაწყო სატყორცნი მუხტის გარეშე, შემანელებელ და ასაფეთქებელ მუხტთან ერთად, რომელიც მოიცავს ფერად კორპუსებსა და/ან პიროტექნიკურ ელემენტებს და განკუთვნილია სატყორცნი მორტირიდან სასროლად ხელსაწყო სატყორცნი მუხტის გარეშე, შემანელებელ და ასაფეთქებელ მუხტთან ერთად, რომელიც შეიცავს < 70 ფერად კორპუსებსა და/ან პიროტექნიკურ ელემენტებს, <25% ფეთქებად შემადგენლობასა და < 60% პიროტექნიკურ ნივთიერებასთან ერთად და განკუთვნილია სატყორცნი მორტირიდან სასროლად ხელსაწყო სატყორცნი მუხტით, შემანელებელ და ასაფეთქებელ მუხტთან ერთად, რომელიც შეიცავს < 70 ფერად კორპუსებსა და/ან პიროტექნიკურ ელემენტებს, <25% ფეთქებად შემადგენლობასა და < 60% პიროტექნიკურ ნივთიერებასთან ერთად და განკუთვნილია სატყორცნი მორტირიდან სასროლად კრებული, წინამდებარე ცხრილით გათვალისწინებული პიროტექნიკური ნაკეთობების ერთი და იგივე ტიპის ან სხვადასხვა ტიპების რამდენიმე ელემენტის შემცველობით, აალების ერთ ან რამდენიმე წერტილთან ერთად სპეციფიკაცია < 120 მმ იმ პიროტექნიკური ელემენტების სერიების შემცველი მილი, რომელიც შედგება ალტერნატიული პიროტექნიკური ნივთიერებისგან, სატყორცნი მუხტისა და გადამცემი სადგმულისგან > 50 მმ შიდა დიამეტრი ფეთქებად შემადგენლობასთან ერთად ან < 50 მმ >25% ფეთქებად შემადგენლობასთან ერთად > 50 მმ შიდა დიამეტრი ფეთქებადი შემადგენლობის გარეშე < 50 მმ შიდა დიამეტრი და < 25% ფეთქებადი შემადგენლობა < 30 მმ შიდა დიამეტრი, ყოველი პიროტექნიკური ელემენტი > 25 გრ 152 კლასიფიკაცია 1.3G > 300 მმ 1.1G >200 მმ და < 300 მმ 1.3G < 200 მმ 1.3G კლასიფიკაცია ხორციელდება პიროტექნიკური ნაკეთობის ყველაზე სახიფათო ტიპის მიხედვით 1.1G 1.2G 1.3G 1.4G ტიპი შეიცავს: / სინონიმი: განმარტება ცალკეული სალუტი ცალკეული რომაული ნათურა, მცირე ზომის წინასწარ დატვირთული მორტირი იმ პიროტექნიკური ელემენტის შემცველი მილი, რომელიც შედგება პიროტექნიკური ნივთიერებისგან, სატყორცნი მუხტისგან პიროტექნიკური სადგმულითა თუ მის გარეშე რაკეტა ნაღმი ხმოვანი რაკეტა, სასიგნალო რაკეტა, სასტვენი რაკეტა, ბოთლის რაკეტა, ცის რაკეტა, საბრძოლო იარაღის ტიპის რაკეტა, მაგიდის რაკეტა პარკის ფოიერვერკები, სახმელეთო ნაღმები, ტომრის ნაღმები, ცილინდრული ნაღმები იმ პიროტექნიკური ნივთიერებისა და/ან პიროტექნიკური ელემენტების შემცველი მილი, რომელიც აღჭურვილია ფრენის სტაბილიზატორ(ებ)ითა თუ სხვა საშუალებებით და განსაზღვრულია ჰაერში გასატყორცნად სატყორცნი მუხტისა და პიროტექნიკური ელემენტების შემცველი მილები, რომლებიც დამზადებულია მიწაზე განსათავსებლად ან დასამაგრებლად. მის მთავარ ეფექტს წარმოადგენს ყოველი პიროტექნიკური ელემენტის ერთდროულად გატყორცნა ჰაერში მასშტაბურ ვიზუალურ და/ან ხმოვან ეფექტთან ერთად; ან სატყორცნი მუხტისა და პიროტექნიკური ელემენტების შემცველი ქსოვილი ან ქაღალდის ტომარა ან ქსოვილის ან ქაღალდის ცილინდრი, რომელიც გათვალისწინებულია მორტირში მოსათავსებლად ან ნაღმის სახით ფუნქციონირების მიზნით 153 სპეციფიკაცია და < 5% ფეთქებადი შემადგენლობით < 30 მმ შიდა დიამეტრი, ყოველი პიროტექნიკური ელემენტი > 25 გრ ან > 5% და <25% ფეთქებადი შემადგენლობით < 30 მმ შიდა დიამეტრი, პიროტექნიკური ელემენტი < 25 გრ და < 5% ფეთქებადი შემადგენლობით მხოლოდ ფეთქებადი შემადგენლობის ეფექტები ფეთქებადი შემადგენლობა > 25% პიროტექნიკური ნივთიერება > 20 გ პიროტექნიკური ნივთიერება და < 25 ფეთქებადი შემადგენლობა < 30 მმ შიდა დიამეტრი, ყოველი პიროტექნიკური ელემენტი > 25 გრ და < 5% ფეთქებადი შიგთავსით >25% ფეთქებადი შემადგენლობა, ფხვიერი ფხვნილისა და/ან ხმოვანი ეფექტების სახით > 180 მმ და <25% ფეთქებადი შემადგენლობა, ფხვიერი ფხვნილისა და/ან ხმოვანი ეფექტების სახით < 180 მმ და <25% ფეთქებადი შემადგენლობა, ფხვიერი ფხვნილისა და/ან ხმოვანი ეფექტების სახით < 150 გრ პიროტექნიკური ნივთიერება, რომელიც შეიცავს < 5% ფეთქებად შემადგენლობას ფხვიერი ფხვნილისა და/ან ხმოვანი ეფექტების სახით. ყოველი პიროტექნიკური ელემენტი < 25 გრ, ყოველი ხმოვანი ეფექტი < 2გრ; ყოველი სასტვენი ეფექტი, ასეთის არსებობის შემთხვევაში, < 3 გრ კლასიფიკაცია 1.3G 1.4G 1.1G 1.1G 1.3G 1.4G 1.1G 1.1G 1.3G 1.4G ტიპი შადრევანი სპარკლერი ბენგალური ნათურა შეიცავს: / სინონიმი: ვულკანები, გვირგვინები, წყლის შადრევნები, ჩანჩქერები, ბენგალური ცეცხლი, მოფარფატე ნაპერწკალი, ცილინდრული შადრევნები, კონუსური შადრევნები, გასანათებელი ჩირაღდანი მექანიკური სპარკლერი, არამექანიკური სპარკლერი, სპარკლერ-სადენი ჩაღრმავებული ჯოხი განმარტება არალითონის კორპუსი, რომელიც შეიცავს შეკუმშული ან გამკვრივებული სახით წარმოდგენილ, ნაპერწკლების ან ალის წარმომქმნელ პიროტექნიკურ ნივთიერებას სპეციფიკაცია > 1 კგ პიროტექნიკური ნივთიერება კლასიფიკაცია 1.3G < 1 კგ პიროტექნიკური ნივთიერება 1.4G ხისტი სადენი, ნაწილობრივ დაფარული (ერთ მხარეს) ნელი წვის პიროტექნიკური ნივთიერებით, ამნთებით ან ამნთების გარეშე სპარკლერები პერქლორატის ბაზაზე: >5 გრ ყოველ ნაკეთობაზე ან > 10 ნაკეთობა ყოველ შეკვრაზე სპარკლერები პერქლორატის ბაზაზე: <5 გრ ყოველ ნაკეთობაზე ან <10 ნაკეთობა ყოველ შეკვრაზე; სპარკლერები ნიტრატის ბაზაზე: <30 გრ ყოველ ნაკეთობაზე სპარკლერები პერქლორატის ბაზაზე: >5 გრ ყოველ ნაკეთობაზე ან > 10 ნაკეთობა ყოველ შეკვრაზე სპარკლერები პერქლორატის ბაზაზე: <5 გრ ყოველ ნაკეთობაზე ან <10 ნაკეთობა ყოველ შეკვრაზე; სპარკლერები ნიტრატის ბაზაზე: <30 გრ ყოველ ნაკეთობაზე მგრგვინავი სატყორცნი ნივთიერებები და ჭრიალები შესაძლებელია შეიცავდეს 1.6 მგ ვერცხლის ფულმინატს; ჭრიალები და ტკაცუნები შესაძლებელია შეიცავდეს 16 მგ-მდე კალიუმის ქლორატს/წითელი ფოსფორის ნარევს; სხვა ნაკეთობები შესაძლებელია შეიცავდეს 5 გრ-მდე პიროტექნიკურ ნივთიერებებს, თუმცა არა ფეთქებადი შემადგენლობის ყოველ ნაკეთობაზე > 20 გრ პიროტექნიკური ნივთიერება შეიცავს <3% ფეთქებად შემადგენლობას, ხმოვანი ეფექტების სახით ან < 5 გრ სტვენის ეფექტების გამომწვევ 1.3G არალითონის ჯოხი, რომელიც ნაწილობრივ დაფარულია (ერთ მხარეს) ნელი წვის პიროტექნიკური ნივთიერებით და გათვალისწინებულია ხელში დასაკავებლად ნაკლებად სახიფათო პიროტექნიკური ნაკეთობები და ფოიერვერკები მაგიდის ბომბები, მგრგვინავი სატყორცნი ნივთიერებები, სასკდომი გრანულები, კვამლი, ნისლი, გველები, ციცინათელა, ფუტკრები, ტკაცუნები მოწყობილობა, რომელიც გათვალისწინებულია ძალინ შეზღუდული ხილვადობის და/ან სმენითი ეფექტების შესაქმნელად და რომელიც შეიცავს მცირე ოდენობით პიროტექნიკურ და/ან ფეთქებად ნივთიერებებს ტრიალა საჰაერო ტრიალა, შვეულმფრენი, გამანადგურებელი, მიწის ტრიალა არალითონის მილ(ებ)ი, რომლებიც შეიცავს აირების ან ნაპერწკლების წარმომქნელ პიროტექნიკურ ნივთიერებას, ხმაურის ეფექტების გამომწვევი შემადგენლობითა თუ მის გარეშე, ფრთებთან ერთად ან მათ გარეშე 154 1.4G 1.3G 1.4G 1.4G 1.3G ტიპი თვლები საჰაერო თვალი შეიცავს: / სინონიმი: თვლები „Catherine“, საქსონური მფრინავი ნივთები, ამო, მფრინავი თეფში განმარტება კრებული შეიცავს პიროტექნიკური ნივთიერებების შემცველ ამძრავებს, რომლებიც მაგრდება ღერძზე ისე, რომ თავისუფლად შეძლოს ბრუნვა მილები შეიცავს სატყორცნ მუხტებს და ნაპერწკლების-, ალის- და/ან ხმაურის წარმომქმნელ პიროტექნიკურ ნივთიერებებს, მილები მაგრდება საყრდენ რგოლზე 155 სპეციფიკაცია შემადგენლობას ყოველ ნაკეთობაზე < 20 გრ პიროტექნიკური ნივთიერება შეიცავს <3% ფეთქებად შემადგენლობას, ხმოვანი ეფექტების სახით ან < 5 გრ სტვენის ეფექტების გამომწვევ შემადგენლობას > 1 კგ პიროტექნიკური ნივთიერების საერთო რაოდენობა, არანაირი ხმოვანი ეფექტი, ყოველი სასტვენი (ასეთის არსებობის შემთხვევაში) < 25 გრ და < 50 გრ სასტვენი შემადგენლობა ყოველ თვალზე < 1 კგ პიროტექნიკური ნივთიერების საერთო რაოდენობა, არანაირი ხმოვანი ეფექტი, ყოველი სასტვენი (ასეთის არსებობის შემთხვევაში) < 5 გრ და < 10 გრ სასტვენი შემადგენლობა ყოველ თვალზე >200 გრ პიროტექნიკური ნივთიერების საერთო რაოდენობა ან >60 გრ პიროტექნიკური ნივთიერება ყოველ ამძრავზე, < 3% ფეთქებადი შემდაგენლობა ხმოვანი ეფექტის სახით, ყოველი სასტვენი (ასეთის არსებობის შემთხვევაში) < 25 გრ და < 50 გრ სასტვენი შემადგენლობა ყოველ თვალზე < 200 გრ პიროტექნიკური ნივთიერების საერთო რაოდენობა ან < 60 გრ პიროტექნიკური ნივთიერება ყოველ ამძრავზე, < 3% ფეთქებადი შემდაგენლობა ხმოვანი ეფექტის სახით, ყოველი სასტვენი (ასეთის არსებობის შემთხვევაში) < 5 გრ და < 10 გრ კლასიფიკაცია 1.4G 1.3G 1.4G 1.3G 1.4G ტიპი შეიცავს: / სინონიმი: განმარტება სპეციფიკაცია სასტვენი შემადგენლობა ყოველ თვალზე ფოიერვერკების კრებული სანახაობრივი ღონისძიებებისთვის განკუთვნილი ფოიერვერკების ყუთი, სანახაობრივი ღონისძიებებისთვის განკუთვნილი ფოიერვერკების კრებული, ბაღის ფოიერვერკების კრებული, შენობებს შიგნით წარმოსადგენი ფოიერვერკების კრებული; ასორტიმენტი საზეიმო სატკაცუნო, საზეიმო გლინი, ზონარიანი სატკაცუნო ერთზე მეტი ტიპის ფოიერვერკების კრებული, რომელთაგან თითოეული შეესაბამება წინამდებარე ცხრილში წარმოდგენილი ფოიერვერკების რომელიმე ტიპს კლასიფიკაცია განისაზღვრება ყველაზე სახიფათო ფოიერვერკის ტიპის მიხედვით მილების (ქაღალდის ან მუყაოს) ნაკრები, დაკავშირებული პიროტექნიკური სადგმულით, ყოველი მილი გათვალისწინებულია ხმოვანი ეფექტების წარმოსაქმნელად არალითონის მილი, რომელიც შეიცავს ხმოვან შემადგენლობას, რაც გათვალისწინებულია ხმაურის ეფექტის შესაქმნელად ყოველი მილი < 140 მგ ფეთქებადი შემადგენლობასთან ან < 1 გრ შავ დენთთან ერთად 1.4G > 2 გრ ფეთქებადი შემადგენლობა ყოველ ნაკეთობაზე 1.1G < 2 გრ ფეთქებადი შემადგენლობა ყოველ ნაკეთობაზე და < 10 გრ ყოველ შიდა ტარაზე < 1 გრ ფეთქებადი შემადგენლობა ყოველ ნაკეთობაზე და < 10 გრ ყოველ შიდა ტარაზე ან < 10 გრ შავი ფხვნილი ყოველ ნაკეთობაზე 1.3G სატკაცუნო სახმაურო ფოიერვერკი სალუტი, გამანათებელი სახმაურო ფოიერვერკი, ქალების სატკაცუნო 156 კლასიფიკაცია 1.4G 2.2.1.1.8 პირველი კლასიდან გამორიცხვა 2.2.1.1.8.1 ნაკეთობა ან ნივთიერება შესაძლებელია გამორიცხულ იქნეს პირველი კლასიდან გამოცდის შედეგებისა და პირველი კლასის განსაზღვრის საფუძველზე ADR-ის ფარგლებში შემავალი ნებისმიერი ხელშემკვრელი მხარის კომპეტენტური ორგანოს თანხმობით, რომელსაც ასევე შეუძლია აღიაროს იმ ქვეყნის კომპეტენტური ორგანოს მიერ გაცემული თანხმობა, რომელიც არ წარმოადგენს ADR-ის ხელშემკვრელ მხარეს იმ პირობით, თუ აღნიშნული თანხმობა გაიცემა RID, ADR, ADN, IMDG კოდექსის და ICAO ტექნიკური ინსტრუქციების შესაბამისად. 2.2.1.1.8.2 2.2.1.1.8.1 პუნქტის შესაბამისად კომპეტენტური ორგანოს მიერ გაცემული თანხმობით, ნაკეთობა შესაძლებელია გამოირიცხოს პირველი კლასიდან იმ შემთხვევაში, თუ სამი შეუფუთავი ნაკეთობა, რომელთა გააქტიურებაც ხდება ცალ-ცალკე, თვითინიცირების ან აალების საშუალებით ან გარეშე საშუალებების დახმარებით დადგენილ რეჟიმში ფუნქციონირების მიზნით, აკმაყოფილებს გამოცდასთან დაკავშირებით წარმოდგენილ შემდეგ კრიტერიუმებს: (ა) არცერთ გარე ზედაპირზე ტემპერატურა არ უნდა იყოს 650C-ზე მაღალი. დასაშვებია ტემპერატურის პიკური გაზრდა 2000C-მდე; (ბ) დაუშვებელია გარე კორპუსის წყვეტა ან ფრაგმენტაცია ან ნებისმიერი ნაკეთობისა თუ მისგან გამოყოფადი ნაწილების გადაადგილება ნებისმიერი მიმართულებით ერთ მეტრზე მეტი მანძილით; შენიშვნა: იმ შემთხვევაში, თუ ნაკეთობის მთლიანობა დაირღვევა გარე ხანძრის ზემოქმედებით, აღნიშნული კრიტერიუმები უნდა გადაისინჯოს ხანძარმედეგობაზე გამოცდით, რომლებიც წარმოდგენილია ISO 12097-3 სტანდარტით; (გ) დაუშვებელია 135 დბ(С) პიკურ მნიშვნელობაზე მაღალი ხმოვანი ეფექტის არსებობა ერთი მეტრის მანძილზე; (დ) დაუშვებელია აფეთქების ან კვამლის არსებობა, რომელიც ხელს შეუწყობს ისეთი მასალის აალებას, როგორიცაა 80+10 გრ/მ2 ქაღალდის ფურცელი ნაკეთობასთან შეხებისას; და (ე) დაუშვებელია იმ ოდენობის ორთქლის, კვამლისა თუ მტვრის არსებობა, რა შემთხვევაშიც შესაბამისი ზომის აფეთქებისგან დამცავი პანელებით აღჭურვილი ერთი კუბური მეტრის კამერაში ხილვადობა შემცირდება 50%-ზე ნაკლებად, კამერის საპირისპირო კედლების ცენტრში, სინათლის მუდმივი წყაროდან ერთი მეტრის მანძილზე განთავსებული დაკალიბრებული ლუქსმეტრის ან რადიომეტრის მიერ გამოთვლილი მნიშვნელობების თანახმად. შესაძლებელია გამოყენებული იქნეს ზოგადი სახელმძღვანელო მითითებები ISO 5659-1 სტანდარტის შესაბამისად ოპტიკური სიმკვრივის გამოცდასთან დაკავშირებით და ზოგადი სახელმძღვანელო მითითებები ISO 5659-2 სტანდარტის 7.5 პუნქტით გათვალისწინებულ ფოტომეტრიულ სისტემასთან დაკავშირებით; გარდა ამისა, შესაძლებელია გამოყენებულ იქნეს ოპტიკური სიმკვრივის გაზომვის სხვა ანალოგიური მეთოდები. გაფანტული ან გაჟონილი სინათლის, რომლის გამოსხივებაც არ ხდება უშუალოდ წყაროებიდან, ეფექტების მინიმუმამდე დაყვანის მიზნით, აუცილებელია 157 შესაბამისი საფარის გამოყენება, რომელიც დაფარავს ლუქსმეტრის უკანა და გვერდით მხარეებს. შენიშვნა 1: იმ შემთხვევაში, თუ ა), ბ), გ) და დ) კრიტერიუმებთან დაკავშირებული გამოცდების ჩატარებისას აღინიშნება უმნიშვნელო რაოდენობის კვამლის გამოყოფა, შესაძლებელია არ ჩატარდეს ე) ქვეპუნქტით გათვალისწინებული გამოცდა. შენიშნა 2: 2.2.1.1.8.1 პუნქტით გათვალისწინებულ კომპეტენტურ ორგანოს შეუძლია შეფუთული ფორმით წარმოდგენილი ნაკეთობების გამოცდის ჩატარების მოთხოვნა იმ შემთხვევაში, თუ დადგინდება, რომ ნაკეთობას იმ სახით, რა სახითაც იგი არის შეფუთული გადაზიდვის მიზნით, შეუძლია გამოიწვიოს კიდევ უფრო დიდი რისკი. 2.2.1.2 ნივთიერებები და ნაკეთობები, რომლებიც არ დაიშვება გადაზიდვებზე 2.2.1.2.1 გადაზიდვებზე არ დაიშვება ის ფეთქებადი ნივთიერებები, რომელთაც ახასიათებთ განსაკუთრებული მგძნობელობა ცდებისა და კრიტერიუმების სახელმძღვანელოს I ნაწილის თანახმად ან იწვევეს თვითნებულ რეაქციებს, ასევე ის ფეთქებადი ნივთიერებები და ნაკეთობები, რომელთა მიკუთვნებაც არ შეიძლება 3.2 თავის A ცხრილში გათვალისწინებულ რომელიმე დასახელებასა თუ N.O.S. პოზიციაზე. 2.2.1.2.2 K შესაბამისობის ჯგუფში გათვალისწინებული ნაკეთობები არ დაიშვება გადაზიდვებზე (1.2K, გაეროს N0200 და 1.3K, გაეროს N0021). 158 2.2.1.3 ერთობლივი პოზიციების ჩამონათვალი კლასიფიკაციის კოდი (იხილეთ 2.2.1.1.4 პუნქტი) 1.1A 1.1B 1.1C 1.1D 1.1E 1.1F 1.1G 1.1L 1.2B 1.2C 1.2D 1.2E 1.2F 1.2L 1.3C 1.3G 1.3L 1.4B 1.4C 1.4D 1.4F 1.4F 1.4G გაეროს N ნივთიერებისა თუ ნაკეთობის დასახელება 0473 0461 0474 0497 0498 0462 0475 0463 0464 0465 0476 0357 0354 0382 0466 0467 0468 0469 0358 0248 ნივთიერებები, ფეთქებადი, N.O.S. ელემენტები, ფეთქებადი ჯაჭვის, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. ფეთქებადი სატყორცნი ნივთიერება, თხევადი ფეთქებადი სატყორცნი ნივთიერება, მყარი ნაკეთობები, ფეთქებადი, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ელემენტები, ფეთქებადი ჯაჭვის, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. წყალზე მოქმედი მოწყობილობები, ფეთქებადი, სასროლი ან სატყორცნი მუხტით ნაკეთობები, ფეთქებადი, N.O.S. დეფლაგრირებადი ლითონის მარილები, არომატული ნიტროწარმოებულები, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. ფეთქებადი სატყორცნი ნივთიერება, თხევადი ფეთქებადი სატყორცნი ნივთიერება, მყარი ნაკეთობები, ფეთქებადი, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. წყალზე მოქმედი მოწყობილობები ფეთქებადი, სასროლი ან სატყორცნი მუხტით ნაკეთობები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ელემენტები, ფეთქებადი ჯაჭვის, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. ფეთქებადი სატყორცნი ნივთიერება, მყარი ნაკეთობები, ფეთქებადი, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ნივთიერებები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. 0355 0132 0477 0495 0499 0470 0478 0359 0249 0356 0350 0383 0479 0501 0351 0480 0352 0471 0472 0485 0353 159 კლასიფიკაციის კოდი (იხილეთ 2.2.1.1.4 პუნქტი) 1.4S გაეროს N ნივთიერებისა თუ ნაკეთობის დასახელება 1.5D 0481 0349 0384 0482 1.6N 0486 ნივთიერებები, ფეთქებადი, N.O.S. ნაკეთობები, ფეთქებადი, N.O.S. ელემენტები, ფეთქებადი ჯაჭვის, N.O.S. ნივთიერებები, ფეთქებადი, ძალიან დაბალი მგრძნობელობის (ნივთიერებები, ძდმნ), N.O.S. ნაკეთობები ფეთქებადი, უკიდურესად დაბალი მგრძნობელობის (ნივთიერებები, უდმნ), N.O.S. ფეთქებადი ნიმუშები, გარდა მაინიცირებელი ფეთქებადი ნივთიერებებისა. 0190 შენიშვნა: ქვეკლასი და შესაბამისობის ჯგუფი უნდა განისაზღვროს კომპეტენტური ორგანოს მითითებისამებრ და 2.2.1.1.4 ქვეპუნქტში გათვალისწინებული პრინციპების თანახმად. 160 2.2.1.1.8 დასახელებების სარჩევი შენიშვნა 1: წინამდებარე სარჩევში წარმოდგენილი აღწერილობების გამოყენება არ შეიძლება როგორც პირველი კლასით გათვალისწინებული ამა თუ იმ ნივთიერებისა თუ ნაკეთობის გამოსაცდელი პროცედურების შეცვლის, ასევე მათი საშიშროების კლასიფიკაციის განსაზღვრის მიზნით. შესაბამის ქვეკლასზე მიკუთვნება და გადაწყვეტილების მიღება იმასთან დაკავშირებით, განეკუთვნება თუ არა ნივთიერება S შესაბამისობის კლასს, უნდა ეფუძნებოდეს პროდუქტზე განხორციელებულ ცდებს ცდებისა და კრიტერიუმების სახელმძღვანელოს პირველი ნაწილის შესაბამისად ან უნდა განხორციელდეს ანალოგიურად მსგავსი სახის პროდუქტებთან მიმართებაში, რომლებსაც უკვე ჩაუტარდათ გამოცდა და მოხდა მათი კლასიფიცირება ცდებისა და კრიტერიუმების სახელმძღვანელოში გათვალისწინებული პროცედურების შესაბამისად. შენიშვნა 2: დასახელებების შემდეგ მითითებული ციფრები ნიშნავს გაეროს შესაბამის ნომრებს (3.2 თავის A ცხრილის პირველი სვეტი). კლასიფიკაციის კოდთან დაკავშირებით იხილეთ 2.2.1.1.4 ქვეპუნქტი. აალებადი კაფსულები: გაეროს N004, 0377, 0378 ნაკეთობები, რომლებიც შედგება ლითონის ან პლასტმასის სახურავისგან და შეიცავს დარტყმისას ადვილაალებადი ნარევის მცირე რაოდენობას. მათი გამოყებება ხდება ადვილაალებადი ელემენტების სახით სასროლი იარაღის ვაზნებში და სატყორცნი მუხტების აალების დარტყმის საშუალებებში. ადვილაალებადი სითხის მქონე ყუმბარები, სასკდომი მუხტით გაეროს N0399, 0400 საფრენი აპარატიდან ჩამოსაგდები ნაკეთობები შევსებული ცისტერნები სასკდომი მუხტით. და ადვილაალებადი სითხით არადეტონაციური ასაფეთქებელი: გაეროს N0101 ნაკეთობა, ბამბის ძაფების შემადგენლობით, რომელიც გაჟღენთილია წვრილი გრანულების მქონე შავი დენთით (სწრაფად აალებადი ცეცხლგამტარი სადენი). მის აალებას თან ერთვის ღია ალი და იგი გამოიყენება ცეცხლოვან ჯაჭვში პიროტექნიკური საშუალებების აალებისათვის და ა.შ. არაელექტრო დეტონატორები ასაფეთქებელი სამუშაობისათვის: გაეროს N0029, 0267, 0455 ნაკეთობები, სპეციალურად განკუთვნილი ბრიზანტული ფეთქებადი ნივთიერების ინიცირებისათვის. აღნიშნული დენონატორები შეიძლება შემუშავებულ იქნან მყისიერი დეტონაციისათვის ან შეიძლება შეიცავდეს დამაყოვნებლებს. არაელექტრო დეტონატორები მოქმედებაში მოჰყავთ ისეთი საშუალებებით, როგორიცაა დეტონაციური მილი, ამნთები მილი, უსაფრთხო ცეცხლგამტარი სადენი, სხვა აალებადი მოწყობილობები ან მოქნილი მადეტონირებული სადენი. მათ მიეკუთვნება დეტონაციური რელე დეტონირებული სადენის გარეშე. 161 არაელექტრო დეტონატორების კრებულები ასაფეთქებელი სამუშაოებისათვის: გაეროს N0360, 0361, 0500 ერთად შეკრებილი არაელექტრო დეტონატორები, ინიცირებული ისეთი საშუალებებით, როგორიცაა უსაფრთხო ცეცხლგამტარი სადენი, დეტონაციური მილი, ფეთქებადი მილი ან მადეტონირებული სადენი. ისინი შეიძლება იყოს მყისიერი მოქმედების ან შემაყოვნებლები. მათ განეკუთვნება დეტონაციური რელე, რომელიც შეიცავს მადეტონირებულ სადენს. ასაფეთქებელი მუხტები: გაეროს N0048 ნაკეთობები, დამზადებული დეტონირებული ფეთქებადი ნივთიერების მუხტის შემცველობის ბოჭკოვანი მუყაოსგან, პლასტმასისგან, ლითონისგან ან სხვა მასალისგან. ნაკეთობები ინიცირების გარეშე ან ინიცირების საშუალებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობებით. შენიშვნა: აღნიშნული ტერმინი არ მოიცავს იმ ნაკეთობებს, რომლებიც წარმოდგენილია ცალკე: ბომბები, ნაღმები, ჭურვები აფეთქების ჯაჭვის ელემტები. N.O.S.: გაეროს N0382, 0383, 0384, 0461 ნაკეთობები, ფეთქებადი ნივთიერების შემადგენლობით და განკუთვნილი აფეთქების ჯაჭვით (აალების ჯაჭვით) დეტონაციის ან დეფლაგრაციის გადაცემისთვის. ბომბები სასკდომი მუხტით: გაეროს N0034, 0035 საფრენი აპარატიდან ჩამოსაგდები ფეთქებადი ნაკეთობა, ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით. ბრიზანტული ფეთქებადი ნივთიერება, ტიპი A: გაეროს N0081 ნივთიერებები, თხევადი, ორგანული ნიტრატების შემცველობით, როგორიცაა ნიტროგლიცერინი, ან შედგენილი ერთი ან მეტი კომპონენტების ნარევისგან ნივთიერებებისგან: ნიტროცელულოზა, ამონიუმის ნიტრატი ან სხვა არაორგანული ნიტრატები; არომატიზებული რიგის ნიტროწარმომქმნელები ან აალებადი ლითონები, როგორიცაა ხის ფქვილი და ალუმინის ფხვნილი. ისინი შეიძლება შეიცავდეს ინერტულ კომპონენტებს, როგორიცაა კიზელგური, საღებავებისა და სტაბილიზატორების მინარევები. აღნიშნული ტერმინი მოიცავს ბრიზანტულ დინამიტსა და ჟელატინდინამიტს. ბრიზანტული ფეთქებადი ნივთიერება, ტიპი B: გაეროს N0082, 0331 162 ნივთიერება, რომელიც შედგება: ა) ამონიუმის ნიტრატის ან სხვა არაორგანული ნიტრატების, ტრინიტროტოლუოლის ტიპის ფეთქებად ნივთიერებებთან ნარევისგან, ხის ფქვილის ან ალუმინის ფხვნილის ტიპის სხვა ნივთიერებების შემადგენლობით ან მათი შემადგენლობის გარეშე; ან ბ) ამონიუმის ნიტრატის ან არაორგანული ნიტრატების სხვა აალებად ნივთიერებებთან ნარევისგან, რომლებიც არ შეიცავს ფეთქებად კომპონენტებს. ორივე შემთხვევაში ისინი შეიძლება შეიცავდეს ისეთ ინერტულ კომპონენტებს, როგორიცაა კიზელგური და საღებავებისა და სტაბილიზატორების მინარევები. ეს ფეთქებადი ნივთიერებები არ უნდა შეიცავდეს ნიტროგლიცერინს, მის მსგავს თხევად ორგანულ ნიტრატებსა და ქლორატებს. ბრიზანტული ფეთქებადი ნივთიერება, ტიპი C: გაეროს N0083 ნივთიერებები, შედგენილი კალიუმის ქლორატისა და ნატრიუმის ნარევის, ან კალიუმის პერქლორატის, ნატრიუმის ან ამონიუმისისგან ორგანული ნიტრომწარმომქმნელების შემადგენლობით, ან ისეთი აალებადი მასალებისგან, როგორიცაა ხის ფქვილი, ალუმინის ფხვნილი ან ნახშირწყალბადი. ისინი შეიძლება შეიცავდეს ინერტულ კომპონენტებს, როგორიცაა კიზელგური, საღებავებისა და სტაბილიზატორების მინარევები. აღნიშნული ფეთქებადი ნივთიერებები არ უნდა შეიცავდეს ნიტროგლიცერინს ან მის მსგავს თხევად, ორგანულ ნიტრატებს. ბრიზანტული ფეთქებადი ნივთიერება, ტიპი D: გაეროს N0084 ნივთიერება, ორგანული ნიტრონაერთებისა და აალებადი მასალების ნარევების შემცველობით, როგორიცაა ნახშირწყალბადები და ალუმინის ფხვნილი. ისინი შეიძლება შეიცავდეს ისეთ ინერტულ კომპონენტებს, როგორიცაა კიზელგური და საღებავებისა და სტაბილიზატორების მინარევები. აღნიშნული ფეთქებადი ნივთიერებები არ უნდა შეიცავდეს ნიტროგლიცერინს ან მის მსგავს თხევად, ორგანულ ნიტრატებს, ქლორატებს ან ამონიუმის ნიტრატებს. წინამდებარე ტერმინი ჩვეულებრივ მოიცავს დრეკად ფეთქებად ნივთიერებებს. ბრიზანტული ფეთქებადი ნივთიერება, ტიპი E: გაეროს N0241, 0332 ნივთიერება, წყლის, როგორც ძირითადი კომპონენტის, და ამონიუმის ნიტრატის ან სხვა მჟანგავი ნივთიერების დიდი ნაწილის შემადგენლობით, რომელთაგან ზოგიერთი ან ყველა წარმოდგენილია ხსნარის შემადგენლობაში. სხვა კომპონენტები შეიძლება შეიცავდეს ტრინიტროტოლუოლის ტიპის ნიტროწარმომქმნელებს, ნახშირწყალბადს ან ალუმინის ფხვნილის. ისინი შეიძლება შეიცავდეს ისეთ ინერტულ კომპონენტებს, როგორიცაა კიზელგური და საღებავებისა და სტაბილიზატორების ნარევები. ტერმინი მოიცავს ემულსირებულ ფეთქებად ნივთიერებებს, სუსპენზირებულ ფეთქებად ნივთიერებებს, წყალში ხსნად ფეთქებად ნივთიერებებს და წყლიან, ჟელესებრ ფეთქებად ნივთიერებებს. გვარლის სატყორცნი რაკეტები: გაეროს N0238, 0240, 0453 163 ნაკეთობები, სარაკეტო ტყორცნისთვის. ძრავის შემადგენლობით და განკუთვნილი გვარლის დაგრძელებული, კუმულაციური რბილი მუხტები: გაეროს N0237, 0288 ნაკეთობები, რომლებიც მოიცავს დეტონირებული ფეთქებადი ნივთიერების ბირთვს Vმსგავს მონაკვეთზე, დაფარული რბილი ლითონის გარსით. დამატებითი ფეთქებადი მუხტები: გაეროს N0060 ნაკეთობები, რომლებიც შედგება მცირე ზომის სახსნელი მეორადი დეტონატორისგან, რომელიც ჭურვის ღრუში გამოიყენება ასაფეთქებელ და სასკდომ მუხტს შორის. დენთი ბრიკეტებში (დენთის პასტა), დასველებული სპირტის 17%-ზე ნაკლები მასური წილით. დენთი ბრიკეტებში (დენთის პასტა), დასველებული, წყლის 25%-ზე ნაკლები მასური წილით: გაეროს N0433, 0159 ნივთიერება, ნიტროცელულოზის შემცველობით, გაჟღენთილი არაუმეტეს 60%-იანი ნიტროგლიცერინით ან სხვა თხევადი ორგანული ნიტრატებითა თუ სხვა მინარევებით. დენთი პიროტექნიკური ნაკეთობებისათვის: გაეროს N0094, 0305 პიროტექნიკური ნივთიერება, რომელიც აალებისას გამოჰყოფს მკვეთრ სინათლეს. დეტონატორები საბრძოლო მასალებისთვის: გაეროს N0073, 0364, 0365, 0366 ნაკეთობები, რომლებიც შედგება მცირე ზომის ლითონისა და პლასტმასის მილისგან, ასევე ფეთქებადი ნივთიერებისაგან, როგორიცაა ტყვიის აზიდი, პეტნ ან ფეთქებადი ნივთიერების ნარევი. ისინი განკუთვნილია დეტონაციის ჯაჭვის აღძვრისთვის. დეტონაციური მილები დამცავი ელემენტებით: გაეროს N0408, 0409, 0410 ნაკეთობები, ფეთქებადი კომპონენტების შემცველობით, განკუთვნილი საბრძოლო მასალებში დეტონაციის უზრუნველსაყოფად. ისინი შეიცავს მექანიკურ, ელექტრო, ქიმიურ ან ჰიდროსტატიკურ კომპონენტებს დეტონაციის ინიცირებისთვის. დეტონაციური მილები უნდა შეიცავდეს ორ ან მეტ ეფექტურ დამცავ ელემენტს. დეტონაციური მილები: გაეროს N0106, 0107, 0257, 0367 ნაკეთობები, ფეთქებადი კომპონენტების შემცველობით, განკუთვნილი საბრძოლო მასალებში დეტონაციის უზრუნველსაყოფად. ისინი შეიცავს მექანიკურ, ელექტრო, ქიმიურ ან ჰიდროსტატიკურ კომპონენტებს დეტონაციის ინიცირებისთვის. ჩვეულებრივ მათ გააჩნიათ დამცავი ელემენტები. 164 დეტონირებული სადენი (ფალია) ლითონის გარსში: გაეროს N0102, 0290 ნაკეთობა, რომელიც შედგება მილისებრი გარსით რბილი ლითონის ბირთვისგან დეტონირებული ფეთქებადი ნივთიერების სახით, დამცავი საფარით ან მის გარეშე. ელექტრო დეტონატორები ასაფეთქებელი სამუშაობისათვის: გაეროს N0030, 0255, 0456 ნაკეთობები, სპეციალურად განკუთვნილი ბრიზანტული ფეთქებადი ნივთიერების ინიცირებისათვის. აღნიშნული დეტონატორები შეიძლება შემუშავებულ იქნეს მყისიერი დეტონაციისათვის ან შეიძლება შეიცავდეს შემაყოვნებლებს. არაელექტრო დეტონატორები მოქმედებაში მოჰყავთ ელექტრო ნაკადით. ვაზნები ინერტული მუხტის მქონე იარაღისათვის: გაეროს N0328, 0417, 0339, 0012 საბრძოლო მასალები, რომელიც შედგება ჭურვისგან სასკდომი მუხტის გარეშე, მაგრამ სატყორცნი მუხტისგან კაფსულით ან მის გარეშე. ნაკეთობები შეიძლება შეიცავდეს ტრასერს იმ პირობით, რომ უპირატეს საშიშროებას წარმოადგენს სატყორცნი მუხტი. ვაზნები ხელსაწყოებისთვის, ფუჭი: გაეროს N0014 ხელსაწყოებში გამოყენებული ნაკეთობები, რომლებიც შედგება დახურული მასრისგან ცენტრალური და წლიური კაფსულით და უკვამლო ან შავი დენთის მუხტისგან, Tumca ტყვიის ან მუხტის გარეშე. ვაზნები სასკდომი მუხტის მქონე იარაღისთvის: გაეროს N0006, 0321, 0412 საბრძოლო მასალები, ფეთქებადი მუხტის მქონე ჭურვების შემცველობით, ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით, და სატყორცნი მუხტის კაფსულით ან მის გარეშე. აღნიშნული ტერმინი გულისხმობს საბოლოო ან არასაბოლოო საბრძოლო მასალების აღჭურვილობას და ცალკეული აღჭურვილობის მქონე საბრძოლო მასალებს იმ შემთხვევაში, თუ კომპონენტები ერთად არის შეფუთული. ვაზნები სასკდომი მუხტის მქონე იარაღისთვის: გაეროს N0005, 0007, 0348 საბრძოლო მასალები, ფეთქებადი მუხტის მქონე ჭურვების შემადგენლობით, ინიცირების საშუალებებით, ორი ან მეტი ეფექტური დამცავი მოწყობილობების აღჭურვის გარეშე, სატყორცნი მუხტის კაფსულით ან მის გარეშე. ტერმინი მოიცავს საბოლოო ან არასაბოლოო საბრძოლო მასალების აღჭურვილობას და ცალკეული აღჭურვილობის მქონე საბრძოლო მასალებს იმ შემთხვევაში, თუ კომპონენტები ერთად არის შეფუთული. ვაზნები მექანიზმების გაშვებისათვის: გაეროს N0275, 0276, 0323, 0381 165 ნაკეთობები, განკუთვნილი მექანიკური მოქმდების წარმოებისათვის. ისინი შედგება მასრებისგან, რომლებიც შეიცავს დეფლაგრირებული ფეთქებადი ნივთიერების მუხტს, აალებად საშუალებებს. დეფლაგრაციის აირის წარმომქმნელი პროდუქტები იწვევს წნევის მომატებას, ხაზოვან ან წრიულ მოძრაობას ან დიაფრაგმის, სარქველების ან გადამრთველების ფუნქციონირებას ან ჯაჭვური მოწყობილობებისა თუ ჩამქრობი აგენტის გამოდევნას. ვაზნები ნავთობის ჭაბურღილისთვის: გაეროს N0277, 0278 თხელი მუყაოს, ლითონის ან სხვადასხვა ლითონის გარსის მქონე ნაკეთობები, რომლებიც შეიცავს მხოლოდ სატყორცნ ფეთქებად ნივთიერებას, რომელიც გამოდევნის მყარ მუხტს ნავთობის ჭარბუღილის გარსაცმი მილების პერფორაციისთვის. შენიშვნა: ტერმინი არ მოიცავს იმ ნაკეთობებს, რომლებიც აღწერილია ცალკე: კუმულაციური მუხტები ვაზნები სასროლო იარაღისათვის: გაეროს N 0417, 0339, 0012 საბრძოლო მასალები, რომლებიც შედგება ცენტრალური და წრიული კაფსულის მქონე მასრისგან და შეიცავს როგორც სატყორცნ მუხტს, ასევე მყარ მუხტს. ისინი განკუთვნილია არანაკლებ 19.1 მმ კალიბრის იარაღიდან სასროლად. შენიშვნა: ტერმინი არ მოიცავს შემდეგ ნაკეთობებს, რომლებიც მითითებულია ცალკე: კუმულაციური მუხტები ვაზნები სასროლი იარაღისთვის: გაეროს N0417, 0339, 0012 საბრძოლო მასალები, რომლებიც შედგება ცენტრალური და წრიული კაფსულის მქონე მასრისგან და შეიცავს როგორც სატყორცნ მუხტს, ასევე მყარ მუხტს. ისინი განკუთვნილია არანაკლებ 19.1 მმ კალიბრის იარაღიდან სასროლად. აღნიშნული განსაზღვრება ვრცელდება ნებისმიერი კალიბრის იარაღის ვაზნებზე. შენიშვნა: ტერმინი არ მოიცავს ცარიელ ვაზნებს სასროლი იარაღისთვის, რომლებიც მოცემულია ცალკე, აგრეთვე სასროლი იარაღის რამდენიმე ვაზნას, მითითებულს პუნქტში - ვაზნები ინერტული მუხტის მქონე იარაღისათვის. თხევადი სატყორცნი ფეთქებადი ნივთიერება: გაეროს N0495, 0497 ნივთიერება, დეფლაგრირებული თხევადი ფეთქებადი ნივთიერების შემცველობით და გამოყენებული მოძრაობისთვის. თხევადი საწვავის ტორპედოები ინერტული ბირთვით: გაეროს N0450 ნაკეთობები, აღჭურვილი თხევად ფეთქებად საწვავზე მომუშავე ძრავით, წყლის ქვეშ ტორპედოს მოძრაობისათვის და ინერტული თავისთვის. 166 თხევადი საწვავის ტორპედოები, სასკდომი მუხტით ან მის გარეშე: გაეროს N0449 ნაკეთობები, აღჭურვილი თხევად ფეთქებად საწვავზე მომაშავე ძრავით, წყალქვეშ ტორპედოს მოძრაობისთვის, საბრძოლო ქობინით ან მის გარეშე; ან თხევად არაფეთქებად საწვავზე მომუშავე ძრავით, საბრძოლო ქობინით წყალქვეშ ტორპედოს მოძრაობისთვის, თხევადი საწვავით გამართული რაკეტები, სასკდომი მუხტით: გაეროს N0397, 0398 ნაკეთობები, ცილინდრის ერთი ან ორი საქშენის შემადგენლობით, გამართული თხევადი საწვავით და საბრძოლო ქობინით. ტერმინი მოიცავს მართვად სარაკეტო ჭურვებს. იარაღის ფუჭი ვაზნები: გაეროს N0326, 0413, 0327, 0338, 0014 საბრძოლო მასალები, რომლებიც შედგება დახურული მასრისგან ცენტრალური და წლიური კაფსულით და უკვამლო ან შავი დენთის მუხტისგან, ტყვიის ან მუხტის გარეშე. ისინი გამოსცემენ ძლიერ ხმას და გამოიყენება სწავლებისათის, სალუტებისთვის, სატყორცნი მუხტის სახით, სასტარტო პისტოლეტებში და ა.შ. ტერმინი მოიცავს ფუჭ საბრძოლო მასალებს. ინერტული ჭურვი ტრასერით: გაეროს N0345, 0424, 0425 ნაკეთობები, როგორიცაა ჭურვები, ტყვიები, ყუმბარა ან ნაღმები, რომელთა გასროლაც ხდება ქვემეხებიდან ან სხვა იარაღიდან, შაშხანისა თუ სხვა სასროლი იარაღიდან. კუმულატიური მუხტები დეტონატორის გარეშე: გაეროს N0059, 0439, 0440, 0441 ნაკეთობები, რომლებიც შედგება გარსისგან და მოიცავს დეტონირებული ფეთქებადი ნივთიერების მუხტს, შეწეული ღრუთი, დაფარულია მყარი მასალით, ინიცირების საშუალების გარეშე. ისინი განკუთვნილია ძლიერი, დამანგრეველი, კუმულატიური ეფექტის მისაღებად. ლითონის გარსის მქონე მილისებრი ამნთები: გაეროს N0103 ნაკეთობა, ლითონის მილის შემადგენლობით, დეფლაგრირებული ბირთვის მეშვეობით ფეთქებადი ნივთიერების სახით. მაალებლები: გაეროს N0121, 0314, 0315, 0325, 0454 ნაკეთობები, ერთი ან მეტი ფეთქებადი ნივთიერების შემადგენლობით და განკუთვნილი აფეთქების ჯაჭვში დეფლაგრაციის გამოსაწვევად. მათი მოქმედებაში მოყვანა შესაძლებელია ქიმიური, ელექტრო და მექანიკური საშუალებებით. შენიშვნა: ტერმინი არ მოიცავს იმ ნაკეთობებს, რომლებიც აღწერილია ცალკე: ცეცხლგამტარი სადენი; მილისებრი ამნთები, არადეტონირებული ასაფეთქებელი, 167 ამნთები მილები, ცეცხლგამტარი კაფსულის ტიპის მილები. სადენის მაალებლები, კაფსულა-მაალებლები, მანათობელი ვაზნები: გაეროს N0049, 0050 ნაკეთობები, რომლებიც შედგება მასრებისგან, კაფსულისა და მანათობელი შიგთავსისგან ერთობლივ კომპლექტში და რომლებიც იმყოფებიან სასროლ მზადყოფნაში. მანათობელი საბრძოლო მასალები, სასკდომი, მტვრევადი ან სატყორცნი მუხტით ან მათ გარეშე: გაეროს N0171, 0254, 0297 საბრძოლო მასალა, რომელიც განკუთვნილია ადგილის გასანათებლად ერთჯერადი ინტენსიური შუქის წყაროთი. ტერმინი მოიცავს მანათობელ ვაზნებს, ყუმბარებს და ჭურვებს, ასევე მანათობელ ყუმბარებსა და მიზნის ამომცნობ ყუმბარებს. შენიშვნა: ტერმინი არ მოიცავს იმ ნაკეთობებს, რომლებიც მოცემულია ცალკე: სასიგნალო ვაზნები, ხელის სიგნალის მოწყობილობები, კატასტროფის მაუწყებელი სიგნალები, მანათობელი საავიაციო რაკეტები, მანათობელი სახმელეთო რაკეტები. მეორადი დეტონატორები პირველადი დეტონატორის გარეშე: გაეროს N0042, 0283 ნაკეთობები, რომლების შედგება დეტონირებული ფეთქებადი ნივთიერების ჭურვისგან ინიცირების საშუალების გარეშე. ისინი გამოიყენება დეტონატორებისა და დეტონირების სადენის ინიცირების ეფექტის გასაძლიერებლად. მეორადი დეტონატორები პირველადი დეტონატორებით: გაეროს N0225, 0268 ნაკეთობები, რომლებიც შედგება დეტონირებული ფეთქებადი ნივთიერების მუხტისგან ინიცირების საშუალებებით. ისინი გამოიყენება დეტონატორების ან დეტონირების სადენის ინიცირების ეფექტის გასაძლიერებლად. მოქნილი დეტონირებული სადენი: გაეროს N0065, 0289 ნაკეთობა, რომელიც შედგება დეტონირებული ფეთქებადი ნივთიერების სახით წარმოდგენილი ბირთვისგან, მოთავსებული შტაპელის ქსოვილის გარსში პლასტიკური ან სხვაგვარი საფარით. იმ შემთხვევაში, თუ შტაპელის ქსოვილი დაცულია გაცვეთისგან, დაფარვა არ მოითხოვება. მშრალი ან დასველებული პენტოლიტი წყლის 15%-ზე გაეროს N0151 ნაკლები მასური წილით: ნივთიერება, შედგენილი ციკლოტეტრამეთილენტეტრანიტრამინისა ტრინიტროტოლუოლის (ტნტ) ერთგვაროვანი ნარევისგან. 168 (პეტნ) და მშრალი ან დასველებული ჰექსოლითი (ჰექსოტოლი)წყლის 15% -ზე ნაკლები მასური წილით, გაეროს N0118 ნივთიერება, რომელიც შედგება ციკლოტრიმეთილენტრინიტრამინისა და ტრინიტროტოლუოლისგან (ტნტ). აღნიშნული ტერმინი მოიცავს „B შემადგენლობა“-ს. მშრალი ან დასველებული ოქტოლიტი (ოქტოლი)წყლის 15%-ზე ნაკლები მასური წილით: გაეროს N0266 ნივთიერება, რომელიც შედგება ციკლოტეტრამეთილენტეტრანიტრამინისა ტრინიტროტოლუოლის (ტნტ) ერთგვაროვანი ნარევისგან. და ნაღმები სასკდომი მუხტით: გაეროს N0137, 0138 ნაკეთობები, ჩვეულებრივ ლითონის ან შედგენილი მოცულობის შემცველობით, რომელიც შევსებულია დეტონირებული ფეთქებადი ნივთიერებით, ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობებით. ისინი განკუთვნილია გემების, ავტოსატრანსპორტო საშუალებების მოქმედებაში მოსაყვანად ან პირადი შემადგენლობის გავლისას. ტერმინი მოიცავს „ბანგალორის ტორპედოებს“. ნაღმები სასკდომი მუხტით: გაეროს N0136, 0294 ნაკეთობები, ჩვეულებრივ ლითონის ან შედგენილი მოცულობის შემცველობით, რომელიც შევსებულია დეტონირებული ფეთქებადი ნივთიერებით, ინიცირების საშუალებებით, ორი ან მეტი ეფექტური დამცავი მოწყობილობების აღჭურვის გარეშე. ისინი განკუთვნილია გემების, ავტოსატრანსპორტო საშუალებების მოქმედებაში მოსაყვანად ან პირადი შემადგენლობის გავლისას. ტერმინი მოიცავს „ბანგალორის ტორპედოებს“. პერფორაციული ჭურვები ნავთობის ჭაბურღილებისათის დეტონატორის გარეშე: გაეროს N0124, 0494 ნაკეთობები, რომლებიც შედგება ფოლადის მილისაგან ან ლითონის ფირისგან მათში ჩართული კუმულატიური მუხტებით, შეერთებული დეტონირებული სადენით, ინიცირების საშუალების გარეშე. პლასტიფიცირებული სასკდომი მუხტები: გაეროს N0457, 0458, 0458, 0459, 0460 ნაკეთობები, რომლებიც შეიცავს დეტონირებული ფეთქებადი ნივთიერების პლასტიფიცირებულ მუხტს და რომელსაც გააჩნია სპეციალური ფორმა, გარსისა და ინიცირების საშუალების გარეშე. მათი გამოყენება ხდება საბრძოლო მასალების კომპონენტების სახით, როგორიცაა საბრძოლო ქობინი. 169 პიროტექნიკური ნაკეთობები ტექნიკური მიზნებისათვის: გაეროს N 0428, 0429, 0430, 0431, 0432 ნაკეთობები, რომლებიც შეიცავს პიროტექნიკურ ნივთიერებებს და გამოიყენება ტექნიკური მიზნებისთვის; სითბისა და აირის გამოსაყოფად, სასცენო ეფექტების მისაღებად და ა.შ. შენიშვნა: ტერმინი არ მოიცავს იმ ნაკეთობებს, რომლებიც აღწერილია ცალკე: საბრძოლო მასალების ყველა ტიპი; სასიგნალო ვაზნები; სადენის ასაფეთქებელი საჭრელები, პიროტექნიკური საშუალებები, საავიაციო მანათობელი; სახმელეთო მანათობელი რაკეტები, ფეთქებადი განცალკევების მოწყობილობა, ფეთქებადი მოქლონები, ხელის სასიგნალო მოწყობილობები; კატასტროფის მაუწყებელი სიგნალები, სარკინიგზო ფეთქებადი პეტარდები, საკვამლე სიგნალები. პიროფორული ნაკეთობები: გაეროს N0380 ნაკეთობები, პიროფორული ნივთიერების (ჰაერზე თვითაალებადი უნარით) და ფეთქებადი ნივთიერების ან კომპონენტის შემადგენლობით. ტერმინი არ მოიცავს ნაკეთობებს, რომლებიც შედგება თეთრი ფოსფორისაგან. პიროტექნიკური საშუალებები: გაეროს N0333, 0335, 0335, 0336, 0337 პიროტექნიკური საშუალებები, განკუთვნილი ფოიერვეკებისთვის. პრაქტიკული საბრძოლო მასალები: გაეროს N0362, 0488 საბრძოლო მასალები ძირითადი ფეთქებადი მუხტის გარეშე, მაგრამ აღჭურვილი ფეთქებადი მუხტით ან მტვრევადი მუხტით. ჩვეულებრივ ისინი ასევე შეიცავს ასაფეთქებელ და სატყორცნ მუხტს. შენიშვნა: ტერმინი არ შეიცავს იმ ნაკეთობებს, რომელიც აღწერილია ცალკე: პრაქტიკული ყუმბარა. რაკეტები, სასკდომი მუხტით: გაეროს N0436, 0437, 0438 ნაკეთობები, რომლებიც შედგება სარაკეტო ძრავისა და რაკეტის თავის ნაწილიდან სასარგებლო ტვირთის გამტყორცნი მუხტისაგან. ტერმინი მოიცავს სამართავდ სარაკეტო ჭურვებს. რაკეტები ინერტული თავით: გაეროს N0183, 0502 ნაკეთობები, სარაკეტო ძრავისა და ინერტული თავის შემადგენლობით. ტერმინი მოიცავს სამართავ სარაკეტო ჭურვებს. რაკეტები სასკდომი მუხტით: გაეროს N0181, 0182 170 ნაკეთობები, სარაკეტო ძრავისა და საბრძოლო ქობინის შემადგენლობით, ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით. ტერმინი მოიცავს სამართავ სარაკეტო ჭურვებს. რაკეტები სასკდომი მუხტით: გაეროს N0180, 0995 ნაკეთობები, სარაკეტო ძრავისა და საბრძოლო ქობინის შემადგენლობით, ინიცირების საშუალებებით, ორი ან მეტი ეფექტური დამცავი მოწყობილობის აღჭურვის გარეშე. ტერმინი მოიცავს სამართავ სარაკეტო ჭურვებს. ოქტონალი: გაეროს N0496 ნივთიერება, რომელიც შედგება ციკლოტეტრამეთილენტეტრანიტრამინის, ტრინიტროტოლუოლის (ტნტ) და ალუმინის ერთგვაროვანი ნარევისგან. რაკეტის საბრძოლო ქობინი სასკდომი მუხტით: გაეროს N0286, 0287 ნაკეთობა, დეტონირებადი ფეთქებადი ნივთიერების შემცველობით, ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით. ისინი განკუთვნილია რაკეტაში დასამონტაჟებლად. ტერმინი მოიცავს საბრძოლო ქობინს სამართავი სარაკეტო მუხტისთვის. რაკეტის საბრძოლო ქობინი სასკდომი მუხტით: გაეროს N0369 ნაკეთობა, დეტონირებადი ფეთქებადი ნივთიერების შემცველობით, ინიცირების საშუალებებით, ორი ან მეტი ეფექტური დამცავი მოწყობილობების აღჭურვის გარეშე. ისინი განკუთვნილია რაკეტაში დასამონტაჟებლად. ტერმინი მოიცავს საბრძოლო ქობინს სამართავი სარაკეტო მუხტისთვის. რაკეტის საბრძოლო ქობინი სასკდომი და სამტვრევი მუხტით: გაეროს N0370 ნაკეთობა, ინერტული საბრძოლო ნაწილის და დეტონირებული ან დეფლაგრირებული ფეთქებადი ნივთიერების მცირე ზომის მუხტის შემცველობით ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობებით. ისინი განკუთვნილია სარაეკეტო ძრავაში დასამონტაჟებლად, ინერტული ელემენტის გამოცალკევებისთვის. ტერმინი მოიცავს საბრძოლო ქობინს სამართავი სარაკეტო მუხტისთვის. რაკეტის საბრძოლო ქობინი სასკდომი და სამტვრევი მუხტით: გაეროს N0371 ნაკეთობა, ინერტული საბრძოლო ნაწილის და დეტონირებული ან დეფლაგრირებული ფეთქებადი ნივთიერების მცირე ზომის მუხტის შემცველობით ინიცირების საშუალებებით, ორი ან მეტი ეფექტური დამცავი მოწყობილობის აღჭურვის გარეშე. ისინი განკუთვნილია სარაკეტო ძრავაში დასამონტაჟებლად. ინერტული ელემენტის 171 გამოცალკევებისთვის. ტერმინი მოიცავს საბრძოლო ქობინს სამართავი სარაკეტო მუხტისთვის. საავიაციო მანათობელი რაკეტები: გაეროს N0093, 0403, 0404, 0420, 0421 ნაკეთობები პიროტექნიკური ნივთიერების შემცველობით, რომლებიც გათალისწინებულია საფრენი აპარატიდან ჩამოსაგდებად და განკუთვნილია განათებისათვის, სიგნალიზაციისათვის ან გაფრთხილებისათვის. საკვამლე დენთი (შავი დენთი), წარმოდგენილი გრანულების ან გაეროს N0027 ფხვნილის სახით: ნივთიერება, ხის ნახშირის ან სხვა ნახშირბადის და კალიუმის ნიტრატის ან ნატრიუმის ნიტრატის ნარევის შემცველობით, გოგირდის დამატებით ან მის გარეშე. საკვამლე დენთი (შავი დენთი), წნეხილი ან საკვამლე დენთი (შავი დენთი) კოჭებში: გაეროს N0028 ნივთიერება, საკვამლე დენთის შემადგენლობით, წარმოდგენილი კოჭების ფორმაში. საკვამლე საბრძოლო მასალა, სასკდომი, მტვრევადი და სატყორცნი მუხტით ან მათ გარეშე: გაეროს N0015, 0016, 0303 საბრძოლო მასალა, ისეთი კვამლის წარმომქმნელი ნივთიერების შემცველობით, როგორიცაა ქლორსულფონილმჟავას ან ტიტანის ტეტრაქლორიდის ნარევი; კვამლისწარმომქმნელი პიროტექნიკურიი ჯგუფი, ჰექსაქლორინატზე ან წითელ ფოსფორზე დაფუძნებული. იმ შმთხვევაში, თუ ნივთიერება თავისთავად არ არის ფეთქებადი, აღნიშნული საბრძოლო მასალები შეიცავს შემდეგ ერთ ან ერთზე მეტ კომპონენტს: სატყორცნი მუხტი, კაფსულით ან აალებადი მუხტით, სასკდომი ან მტვრევადი მუხტის მქონე ასაფეთქებელი. ტერმინი მოიცავს საკვამლე ჭურვებს. შენიშვნა: აღნიშნული განსაზღვრება არ მოიცავს საკვამლე სიგნალებს, რომელიც აღწერილია ცალკე. საკვამლე საბრძოლო მასალა თეთრი ფოსფორით, სასკდომი, მტვრევადი ან სატყორცნი მუხტით აღჭურვილი: გაეროს N0245, 0246 საბრძოლო მასალა, თეთრი ფორფორის შემცველობით კვამლისწარმომქმნელი ნივთიერების სახით. ისინი ასევე შეიცავს შემდეგ ერთ ან ერთზე მეტ კომპონენტს: სატყორცნი მუხტი, კაფსულით ან აალებადი მუხტით, სასკდომი, მტვრევადი მუხტის მქონე ასაფეთქებელი. ტერმინი მოიცავს საკვამლე ჭურვებს. საკვამლე სიგნალები: გაეროს N0196, 0196, 0313, 0487, 0507 172 ნაკეთობები, პიროტექნიკური ნივთიერების შემადგენლობით, რომლებიც გამოყოფს კვამლს. გარდა ამისა, ისინი შეიძლება შეიუცავდეს ხმოვანი სიგნალების გამოცემის მოწყობილობას. სამრეწველო ფეთქებადი მუხტები დეტონატორის გარეშე. გაეროს N0442, 0443, 0444, 0445 ნაკეთობები, რომლებიც შედგება დეტონირებული ფეთქებადი ნივთიერების მუხტისგან ინიცირების საშუალების გარეშე და რომელიც გამოიყენება შესადუღებლად, აფეთქების კავშირის დასამყარებლად, დაშტაბელებისა და სხვა მეტალურგიულ პროცესებისთვის. სარაკეტო ძრავები: გაეროს N0186, 0280, 0281 ნაკეთობები, ფეთქებადი ნივთიერების მუხტის შემცველობით, წარმოდგენილი ჩვეულებრივი სატყორცნი ფორმით, რომელიც მოთავსებულია ცილინდრში ერთ ან ერთზე მეტ საქშენთან ერთად. ისინი განკუთვნილია რაკეტებისა და სამართავი სარაკეტო ჭურვების მოქმედებაში მოსაყვანად. სასიგნალო ვაზნები: გაეროს N0054, 0312, 0405 ნაკეთობები, რომლებიც განკუთვნილია ფერადი სასიგნალო რაკეტებით ან სასიგნალო პისტოლეტებიდან სხვადასხვა სასიგნალო საშუალებებით სასროლად. სასროლი იარაღის ფუჭი ვაზნები. გაეროს N0014, 0327, 0338 საბრძოლო მასალები, რომლებიც შედგება დახურული მასრისგან ცენტრალური და წრიული კაფსულისა და უკვამლო ან შავი დენთის მუხტისგან. მასრები არ შეიცავს ტყვიას ან მუხტს. ისინი განკუთვნილია არანაკლებ 19.1 მმ კალიბრის იარაღიდან სასროლად, უზრუნველყოფს ძლიერი ხმის გამოცემას და გამოიყენება სასწავლო მიზნებისთვის, სალუტებისათის, სატყორცნი მუხტის სახით, სასტარტო პისტოლეტებში და ა.შ. სატყორცნი მუხტები: გაეროს N0271, 0272, 9451, 0491 ნაკეთობები, რომლებიც შედგება ნებისმიერი ფიზიკური ფორმით წარმოდგენილი სატყორცნი მუხტებისგან, კორპუსში ან კორპუსის გარეშე და გამოიყენება სარაკეტო ძრავების კომპონენტის სახით ან ჭურვის პირდაპირი წინააღმდეგობის შესამცირებლად. სატყორცნი მუხტები იარაღისთვის: გაეროს N0242, 0279, 0414 ფეთქებადი ნივთიერების სატყორცნი მუხტები, რომლებიც შედგება ნებისმიერი ფიზიკური ფორმით წარმოდგენილი ცალკეული დატენვის საქვემეხო საბრძოლო მასალისგან. 173 საცდელი საბრძოლო მასალა: გაეროს N0363 საბრძოლო მასალა, პიროტექნიკური ნივთიერების შემცველობით, რომელიც გამოიყენება მოქმედების ან ახალი საბრძოლო მასალის ან კვანძების ეფექტურობის და იარაღის კომპონენტების შესამოწმებლად. საწვავით გამართული თხევადი სარაკეტო ძრავები: გაეროს N0395, 0396 ნაკეთობები, რომლების შედგება ცილინდრისგან ერთი ან მეტი საქშენით, თხევადი საწვავით გამართული. ისინი განკუთვნილია რაკეტისა თუ სამართავი სარაკეტო ჭურვის მოქმედებაში მოსაყვანად. სახმელეთო მანათობელი რაკეტები: გაეროს N0092, 0418, 0419 ნაკეთობები, რომლებიც შედგება პიროტექნიკური ნივთიერებისგან და განკუთვნილია სახმელეთო პირობების დროს განათების, ამოცნობის, სიგნალიზაციის ან გაფრთხილების უზრუნველსაყოფად. სიღრმისეული ყუმბარები: გაეროს N0056 ნაკეთობა, დეტონირებული ფეთქებადი ნივთიერების შემადგენლობით, მოთავსებული ცილინდრში ან მუხტში ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დმცავი მოწყობილობებით. ისინი განკუთვნილია წყალქვეშა აფეთქებისთვის. სუსტი მოქმედების დეტონირებული სადენი (ფალია) ლითონის გარსში: გაეროს N0104 ნაკეთობა, რომელიც შედგება ბირთვისგან დეტონირებული ფეთქებადი ნივთიერების სახით წარმოდგენილი მილისებრი გარსით დაფარული რბილი ლითონისაგან, დამცავი საფარით ან მის გარეშე. ბირთვი შეიცავს ფეთქებადი ნივთიერების საკმაოდ მცირე რაოდენობას, რაც უზრუნველყოფს მის აალებისას უმნიშვნელო გარეგან გამოვლენას. ტორპედოები სასკდომი მუხტით: გაეროს N0451 ნაკეთობები, აღჭურვილი ძრავით, არაფეთქებად საწვავზე მომაშავე, განკუთვნილი წყალქვეშ ტორპედოს მოძრაობაში მოსაყვანად, საბრძოლო ქობინთან ერთად, ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით. ტორპედოები სასკდომი მუხტით: გაეროს N0329 ნაკეთობები, აღჭურვილი ძრავით, ფეთქებად საწვავზე მომაშავე, განკუთვნილი წყალქვეშ ტორპედოს მოძრაობაში მოსაყვანად, საბრძოლო ქობინით ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით. 174 ტორპედოები სასკდომი მუხტით: გაეროს N0330 ნაკეთობები, აღჭურვილი ძრავით, ფეთქებად ან არაფეთქებად საწვავზე მომაშავე, განკუთვნილი წყალქვეშ ტორპედოს მოძრაობაში მოსაყვანად, საბრძოლო ქობინით ინიცირების საშუალებებით, ორი ან მეტი ეფექტური დამცავი მოწყობილობის აღჭურვის გარეშე. ტრესერები საბრძოლო მასალებისათვის: გაეროს N0212, 0306 ჰერმეტული ნაკეთობები, პიროტექნიკური ნივთიერების განკუთვნილი ჭურვის (ტყვიის) ტრაექტორიის აღსანიშნავად. შემადგენლობით და ტრიტონალი: გაეროს N0390 ნივთიერება, ტრინიტრიტოლუოლისა (ტნტ) და ალუმინის ნარევის შემადგენლობით. ტორპედოს საბრძოლო ქობინი სასკდომი მუხტით: გაეროს N0221 ნაკეთობა, დეტონირებული ფეთქებადი ნივთიერების შემცველობით ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობებით. ისინი განკუთვნილია ტორპედოში დასამონტაჟებლად ინერტული ელემენტის გამოცალკევების მიზნით. აღნიშნული ტერმინი მოიცავს საბრძოლო ქობინს სამართავი სარაკეტო მუხტისთვის. უკვამლო დენთი: გაეროს N0160, 0161, 0509 ნივთიერება ნიტროცელულოზას ფუძეზე, გამოყენებული როგორც სატყორცნი ფეთქებადი ნივთიერება. ტერმინი მოიცავს ერთკომპონენტიან (მხოლოდ ნოტროცელულოზა), ორკომპონენტიან (ნიტროცელულოზა და ნიტროგლიცერინი) და სამკომპეტენტიან (ნიტროცელულოზა/ნიტროგლიცერინი/ნიტროგუანიდინი) სატყორცნ ფეთქებად ნივთიერებას. შენიშვნა: სხმული, წნეხილი ან კარტუზული მუხტები უკვამლო დენთით, მითითებული პუნქტში საყტორცნი მუხტები და სატყორცნი მუხტები ქვემეხებისთვის. უკიდურესად დაბალი მგრძნობელობის ფეთქებადი ნაკეთობები): გაეროს N0486 მქონე ფეთქებადი ნაკეთობები (უდმ ნაკეთობები, რომლებიც შეიცავს მხოლოდ ნივთიერებებს უაღრესად დაბალი მგრძნობელობით, რომლებიც უზრუნველყოფს შემთხვევითი ინიცირების ან გადაზიდვის ნორმალური პირობების დროს აფეთქების გავრცელების უმნიშვნელოდ მცირე ალბათობის დემონსტრირებას და რომელთაც გაიარეს მე-7 სერიის გამოცდა. უსაფრთხო ცეცხლგამტარი სადენი: გაეროს N0105 175 ნაკეთობა, ბირთვის შემადგენლობით, წარმოდგენილი წვრილმარცვლიანი საკვამლე დენთის სახით, მოთავსებული რბილი საქსოვი მასალის გარსში, ერთი ან მეტი გარეგანი დამცავი საფარით. აალებისას იწვის დადგენილი სიჩქარით გარეგანი ფეთქებადი ეფექტის გარეშე. უსაფრთხოების დამცავი პიროტექნიკური მოწყობილობები: გაეროს N0503 პიროტექნიკური ნივთიერებების ან სხვა კლასის სახიფათო ტვირთის შემცველი ნაკეთობები, რომლებიც გამოიყენება სატრანსპორტო საშუალებებში, გემებში ან საჰაერო ხომალდებში ადამიანთა უსაფრთხოების გაზრდის მიზნით. აღნიშნულის მაგალითებს წარმოადგენს: გასაბერი ბალიშების საჭირხნი ტუმბოები, გასაბერი ბალიშების მოდულები, უსაფრთხოების ღვედების წინასწარი დაჭიმვის მოწყობილობები და პირომექანიკური მოწყობილობები. აღნიშნული პირომექანიკური მოწყობილობების შემადგენლობაში შედის კვანძები, რომლებიც გათვალისწინებულია ისეთი ფუნქციების შესასრულებლად, რომლებიც ითვალისწინებს, მაგრამ არ შემოიფარგლება ბორტზე მყოფი პირების განცალკევებით, ბლოკირებით ან შეჩერებით. ფეთქებადი ნივთიერებების მაგალითები, ნივთიერებებისა: გაეროს N0190 გარდა მაინიცირებელი ფეთქებადი ახალი ან უკვე არსებული ფეთქებადი ნივთიერებები ან ნაკეთობები, რომლებიც ჯერ არ განეკუთვნება 3.2 ნაწილის A ცხრილის რომელიმე დასახელებას და კომპეტენტური ორგანოს მიერ მითითებების შესაბამისად მისი გადაზიდვა ხორციელდება, როგორც წესი, მცირე რაოდენობით, კერძოდ გამოცდის, კლასიფიკაციის, კვლევისა და კონსტრუქციული დამუშავების ან ხარისხის კონტროლის მიზნით, ან კომერციული ნიმუშის სახით. შენიშვნა: ფეთქებადი ნივთიერება და ნაკეთობები, რომლებიც უკვე განეკუთვნება 3.2 ნაწილის A ცხრილის რომელიმე დასახელებას, არ ითვალისწინებს აღნიშნულ განსაზღვრებას. ფეთქებადი მაცალკევებელი მოწყობილობები: გაეროს N0173 ნაკეთობები, ფეთქებადი ნივთიერების მცირე ზომის მუხტის შემცველობით ინიცირების საშუალებებით, განკუთვნილი ღეროებისა თუ რგოლებისთვის. ისინი ხეთქავენ ღეროებს ან მიმაგრების ადგილებს სწრაფი გაცალკევების მიზნით. ფეთქებადი სასადენე საჭრელები: გაეროს N0070 ნაკეთობები, რომლებიც შედგება საჭრელი მოწყობილობისგან და გამკუთვნილია გრდემლზე დარტყმით დეფლაგრირებული ფეთქებადი ნივთიერების მცირე მუხტის ასაფეთქებლად. ფეთქებადი სარკინიგზო პეტარდები: გაეროს N0192, 0193, 0492, 0493 176 ნაკეთობები, რომლებიც შეიცავს პიროტექნიკურ ნივთიერებას, რომელიც ფეთქდება ძლიერი ხმით ნაკეთობის გასანადგურებლად. ისინი განკუთვნილია რელსებზე დასამონტაჟებლად. ნაკეთობები, რომლებიც შედგება სარაკეტო ძრავისა ტერმინი მოიცავს სამართავ სარაკეტო ჭურვებს. და ინერტული ბირთვისგან. ფეთქებადი, სასკდომი მუხტები: გაეროს N0043 ნაკეთობები, ფეთქებადი ნივთიერების მცირე ზომის მუხტის შემადგენლობით, რომლებიც განკუთვნილია ჭურვების გარსის და სხვა საბრძოლო მასალების გახეთქვისათვის მათი შემცველობის გაფანტვის მიზნით. ფეთქებადი ხმოვანი სიგნალები: გაეროს N0374, 0375 ნაკეთობები, დეტონირებული ფეთქებადი ნივთიერების მუხტის შემადგენლობით ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით. მათ აგდებენ ხომალდებიდან და მოქმედებაში მოჰყავთ, როდესაც მიაღწევს განსაზღვრულ სიღრმეს ან ზღვის ფსკერს. ფეთქებადი ხმოვანი სიგნალები: გაეროს N0204, 0296 ნაკეთობები, დეტონირებული ფეთქებადი ნივთიერების მუხტის შემადგენლობით ინიცირების საშუალებებით, ორი ან მეტი ეფექტური დამცავი მოწყობილობის აღჭურვის გარეშე. მათ აგდებენ ხომალდებიდან და მოქმედებაში მოჰყავთ, როდესაც მიაღწევს განსაზღვრულ სიღრმეს ან ზღვის ფსკერს. ფეთქებადი მოქლონები: გაეროს N0174 ნაკეთობები, ფეთქებადი ნივთიერების მცირე ზომის შემადგენლობით, წარმოდფგენილი ლითონის მოქლონის შიგნით. ფეთქებადი ტორპედოები ნავთობის ჭაბურღილისთვის დეტონატორის გარეშე: გაეროს N0099 ნაკეთობები, დეტონირებული ფეთქებადი ნივთიერების მუხტის შემადგენლობით, რომელიც მოთავსებულია მასრაში, ინიცირების საშუალების გარეშე. ისინი გამოიყენება ღეროვანი ბურღის ირგვლივ კლდის სახეობების განადგურებისათვის, მიწის ზედაპირზე ნავთობის ამოსვლის ხელშეწყობის მიზნით. ფოტოავიაბომბები: გაეროს N0038 საფრენი აპარატიდან ჩამოსაგდები ნაკეთობები, ფოტოგრაფირების ობიექტის მოკლე ინტესიური განათების უზრუნველყოფის მიზნით. ისინი შეიცავს დეტონირებული 177 ფეთქებადი ნივთიერების მუხტს ინიცირების საშუალების გარეშე ან ინიცირების საშუალებებით, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით. ფოტოავიაბომბები: გაეროს N0037 საფრენი აპარატიდან ჩამოსაგდები ნაკეთობები, ფოტოგრაფირების ობიექტის მოკლე ინტესიური განათების უზრუნველყოფის მიზნით. ისინი შეიცავს დეტონირებული ფეთქებადი ნივთიერების მუხტს ინიცირების საშუალებებით, ორი ან მეტი ეფექტური დამცავი მოწყობილობის აღჭურვის გარეშე. ფოტოავიაბომბები: გაეროს N0039, 0299 საფრენი აპარატიდან ჩამოსაგდები ფეთქებადი ნაკეთობები, ფოტოგრაფირების ობიექტის მოკლე ინტესიური განათების უზრუნველყოფის მიზნით. ისინი შეიცავს ფოტოგასანათებელ შიგთავსს. ყუმბარები სასკდომი მუხტით: გაეროს N0033, 0291 საფრენი აპარატიდან ჩამოსაგდები ფეთქებადი ნაკეთობა, ინიცირების საშუალებებით, ორი ან მეტი ეფექტური დამცავი მოწყობილობის აღჭურვის გარეშე. ცარიელი ვაზნის მასრები კაფსულით: გაეროს N0379, 0055 ნაკეთობები, რომლებიც შედგება ლითონის, პლასტმასის ან სხვა არაალებადი მასალის ვაზნიც მასრისგან, რომელშიც ერთადერთ ასაფეთქებელ კომპონენტს წარმოადგენს კაფსულა. ცარიელი წვადი მასრები კაფსულის გარეშე: გაეროს N0447, 0446 ნაკეთობები, რომლებიც შედგება ვაზნიანი მასრებისგან, ნაწილობრივ ან მთლიანად დამზადებული ნიტროცელულოზისგან. ცეცხლგამჩენი მილები: გაეროს N0316, 0317, 0368 ნაკეთობები, პირველადი ფეთქებადი ნივთიერების შემადგენლობით, განკუთვნილი საბრძოლო მასალებში დეტონაციის გამოსაწვევად. ისინი შეიცავს მექანიკურ, ელექტრო, ქიმიურ ან ჰიდროსტატიკურ კომპონენტებს დეტონაციის გამოსაწვევად. ჩვეულებრივ მათ გააჩნიათ დამცავი ელემენტები. ცეცხლგამჩენი საბრძოლო მასალა, აღჭურვილი სასკდომი, მტვრევადი ან სატყორცნი მუხტით: გაეროს N 0009, 0010, 0300 საბრძოლო მასალა, ცეცხლგამჩენი ჯგუფის შემცველობით. იმ შემთხვევაში, თუ მოცემული შემადგენლობა თავისთავად არ არის ფეთქებადი, სღნიშნული საბრძოლო 178 მასალები შეიცავს შემდეგ ერთ ან ერთზე მეტ კომპონენტს: სატყორცნი მუხტი, კაფსულით ან აალებადი მუხტით, სასკდომი ან მტვრევადი მუხტის მქონე ასაფეთქებლით. ცეცხლგამჩენი საბრძოლო მასალა თეთრი ფოსფორით, მტვრევადი ან სატყორცნი მუხტით: გაეროს N0243, 0244 აღჭურვილი სასკდომი, საბრძოლო მასალა, თეთრი ფოსფორის შემცველობით, წარმოდგენილი ცეცხლგამჩენი ნივთიერების სახით. ისინი ასევე შეიცავს შემდეგ ერთ ან ერთზე მეტ კომპონენტს: სატყორცნი მუხტი, კაფსულით ან აალებადი მუხტით, სასკდომი ან მტვრევადი მუხტის მქონე ასაფეთქებლით. ცეცხლგამჩენი საბრძოლო მასალა, თხევადი ან ჟელესებრი ნივთიერების შემცველობით, სასკდომი, მტვრევადი ან სატყორცნი მუხტით: გაეროს N0247 ცეცხლგამჩენი საბრძოლო მასალა, თხევადი ან ჟელესებრი ნივთიერების შემცველობით. იმ შემთხვევაში, თუ ცეცხლგამჩენი ნივთიერება თავისთავად არ არის ფეთქებადი, ეს საბრძოლო მასალები შეიცავს შემდეგ ერთ ან ერტძე მეტ კომპონენტს: სატყორცნი მუხტი, კაფსულით ან აალებადი მუხტით, სასკდომი ან მტვრევადი მუხტის მქონე ასაფეთქებლით. ცეცხგამტარი სადენის მაალებლები: გაეროს N0319, 0320, 0367 ნაკეთობები, დამზადებული აალების პირველადი საშუალებებისგან და დეფლაგრირებული ფეთქებადი ნივთიერების დამხმარე მუხტის შემცველობით, როგორიცაა შავი დენთი, გამოყენებული საარტილერიო მასრაში სასროლი მუხტის აალების მიზნით და ა.შ. ცეცხლგამტარი სადენი: გაეროს N0066 ნაკეთობა, დამზადებული ტექსტილის ძაფებისგან, დაფარული შავი დენთით ან სხვა ადვილაალებადი პიროტექნიკური შემადგენლობით, და რბილი დამცავი გარსით; ან ბირთვისგან შავი დენთის სახით, დაფარული რბილი საქსოვი მასალით. აალება ვრცელდება თანდათან სადენის სიგრძეზე გარეგანი ალის სახით. ნაკეთობა გამოიყენება მოწყობილობიდან მუხტზე ან კაფსულაზე აალების გადაცემისათვის. ცრემლსადენი საბრძოლო მასალები სასკდომი, მტვრევადი ან სატყორცნი გაეროს N0018, 0019, 0301 მუხტით: საბრძოლო მასალები, ცრემლსადენი ნივთიერების შემცველობით. ისინი ასევე შეიცავს შემდეგ ერთ ან ერთზე მეტ კომპონენტს: პიროტექნიკური ნივთიერება; სატყორცნი მუხტი კაფსულით და აალებადი მუხტით; ფეთქებადი სასკდომი და მტვრევადი მუხტით. 179 ძალიან დაბალი მგრძნობელობის მქონე ფეთქებადი ნივთიერება (ძდმ ფეთქებადი ნივთიერება), N.O.S.: გაეროს N0482 ნივთიერებები, რომლებიც წარმოადგენს მასაში აფეთქების საშიშროებას, მაგრამ აღენიშება ისეთი დაბალი მგრძნობელობა, რომ არსებობს ინიცირების ან გადატანის ნორმალური პირობებისას აალებიდან დეტონაციაზე გადასვლის ძალზედ დაბალი ალბათობა, ასევე რომლებმაც გაიარეს მე-5 სერიის გამოცდა. წყალზე მომუშავე მოწყობილობები სასკდომი, მტვრევადი ან სატყორცნი მუხტით: გაეროს N0248, 0249 ნაკეთობები, რომლებიც წყლისა და მათი შემადგენლობის ფიზიკურ-ქიმიური რეაქციის შედეგად მოდის მოქმედებაში. ჭურვები სასკდომი მუხტით: გაეროს N0168, 0169, 0344 ნაკეთობები, როგორიცაა ჭურვები, ტყვიები, ყუმბარა ან ნაღმები, რომელთა გამოტყორცნაც ხდება ქვემეხებიდან ან სხვა იარაღიდან. მათ არ გააჩნიათ ინიცირების საშუალება ან გააჩნიათ ინიცირების საშუალებები, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით. ჭურვები სასკდომი მუხტით: გაეროს N0167, 0324 ნაკეთობები, როგორიცა ჭურვები, ტყვიები, ყუმბარა ან ნაღმები, რომლებიც გამოისროლება ქვემეხებიდან ან სხვა იარაღიდან. მათ გააჩნიათ ინიციირების საშუალებები, ორი ან მეტი ეფექტური დამცველის მოწყობილობების აღჭურვის გარეშე. ჭურვები, სასკდომი და მტვრევადი მუხტებით: გაეროს N0346, 0347 ნაკეთობები, ისეთი როგორიც ჭურვები, ტყვიები, ყუმბარა ან ნაღმები, რომელთა გამოტყორცნაც ხდება ქვემეხებიდან ან სხვა იარაღიდან. მათ არ გააჩნიათ ინიცირების საშუალება ან გააჩნიათ ინიცირების საშუალებები, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით. მათ იყენებენ საღებავი ელემენტების გამოსადევნად სროლის კორექციის მიზნით ან სხვა ინერტული მასალის მიმოსაბნევად. ჭურვები სასკდომი და მტვრევადი მუხტებით: გაეროს N0434, 0435 ნაკეთობები, როგორიცაა ჭურვები, ტყვიები, ყუმბარა ან ნაღმები, რომელთა გამოტყორცნაც ხდება ქვემეხებიდან ან სხვა იარაღიდან. მათ იყენებენ საღებავი ელემენტების გამოსადევნად სროლის კორექციის მიზნით ან სხვა ინერტული მასალის მიმოსაბნევად. ხელისა და საქვემეხო პრაქტიკული ჭურვები: გაეროს N0110, 0372, 0372, 0318, 0452 180 ნაკეთობები, ძირითადი სასკდომი მუხტის გარეშე, რომლებიც განკუთვნილია ხელით ან ყუმბართმტყორცნის დახმარებით სასროლად. ისინი შეიცავს საკაფსულე მოწყობილობას და შესაძლებელია აღჭურვილი იყოს სამიზნე სასკდომი მუხტით. ხელისა და საქვემეხო პრაქტიკული ჭურვები, სასკდომი მუხტით: გაეროს N0284, 0285 ნაკეთობები, რომლებიც განკუთვნილია ხელით ან ყუმბართმტყორცნის დახმარებით სროლისთვის. მათ არ გააჩნიათ ინიცირების საშუალება ან გააჩნიათ ინიცირების საშუალება, აღჭურვილი ორი ან მეტი ეფექტური დამცავი მოწყობილობით. ხელის და საქვემეხო ჭურვები, სასკდომი მუხტით: გაეროს N0284, 02850292, 0293 ნაკეთობები, რომლებიც განკუთვნილია ხელით ან ყუმბართმტყორცნის დახმარებით სროლისთვის. მათ გააჩნიათ ინიცირების საშუალება, ორი ან მეტი ეფექტური დამცავი მოწყობილობის აღჭურვის გარეშე ხელის სასიგნალო მოწყობილობა: გაეროს N0191, 0373 პორტატული მოწყობილობები, პიროტექნიკური ნივთიერების შემადგენლობით ვიზუალური სიგნალების ან გამაფრთხილებელი სიგნალების უზრუნველსაყოფად. ტერმინი მოიცავს ისეთ მცირე მანათობელ რაკეტებს, რომლის გაშვებაც ხდება ხმელეთიდან, როგორიცაა საგზაო სასიგნალო მაშხალები ან საგზაო პიროვაზნები, ასევე კატასტროფის მაუწყებელი მცირე ზომის სიგნალები. ხომალდების კატასტროფის მაუწყებელი სიგნალები: გაეროს N0194, 0195, 0505, 0506 ნაკეთობები, პიროტექნიკური ნივთიერების შემადგენლობით და განკუთვნილი ხმის, ცეცხლის, კვამლის ან მათი კომბინაციის გზით სიგნალის უზრუნველსაყოფად. ჰექსატონალი: გაეროს N0393 ნივთიერება, რომელიც შედგება ციკლოტრიმეთილენტრინიტრამინის, ტრინიტროტოლუოლის (ტნტ) და ალუმინის ერთგვარი ნარევისგან. ჰიპერგოლური სითხის მქონე სარაკეტო ძრავები, სასკდომი მუხტით ან მის გარეშე: გაეროს N0322, 0250 ნაკეთობები, რომლებიც შეიცავს ჰიპერგოლურ საწვავს, განთავსებულს ცილინდრში ერთ ან რამდენიმე საქშენთან ერთად. ისინი გათვალისწინებულია რაკეტის ან მართვადი სარაკეტო ჭურვის მოძრაობაში მოსაყვანად. 181 2.2.2 კლასი 2 აირები 2.2.2.1 კრიტერიუმები 2.2.2.1.1 მე-2 კლასის დასახელება მოიცავს სუფთა აირებს, აირების ნარევს, ერთი ან რამდენიმე აირის ნარევს ერთ ან ერთზე მეტ ნივთიერებასა და აღნიშნულ ნივთიერებებში შემავალ ნაკეთობებთან ერთად. აირი წარმოადგენს ნივთიერებას, რომელსაც: (ა) 500C ტემპერატურაზე ახასიათებს 300 კპა-ზე (3 ბარზე) მეტი ორთქლის წნევა; ან (ბ) არის სრულად აიროვანი 200C ტემპერატურაზე 101.3 კპა სტანდარტული წნევის შემთხვევაში. შენიშვნა 1: თუმცა გაეროს №1052 - ფტორწყალბადი, უწყლო - კლასიფიცირდება მე-8 კლასში. შენიშვნა 2: სუფთა აირი შესაძლებელია შეიცავდეს სხვა ელემენტებსაც, რომლებიც წარმოიშვება მისი წარმოების პროცესიდან ან დამატებულია პროდუქტის სტაბილურობის შესანარჩუნებლად იმ პირობით, რომ აღნიშნული ელემენტების დონე არ შეცვლის მის კლასიფიკაციას ან მისი გადაზიდვის პირობებს, როგორიცაა შევსების კოეფიციენტი, შევსების წნევა, საცდელი წნევა. შენიშვნა 3: 2.2.2.3 პუნქტში გათვალისწინებული N.O.S. პოზიცია შესაძლებელია ითვალისწინებდეს როგორც აირებს, ასევე ნარევებს. 2.2.2.1.2 მე-2 კლასის ნივთიერებები და ნაკეთობები, თავის მხრივ, იყოფა შემდეგნაირად: 1. შეკუმშული აირი: აირი, რომელიც გადაზიდვის მიზნით წნევის ქვეშ შეფუთვის შემთხვევაში, სრულიად აიროვანია -500C ტემპერატურაზე; აღნიშნული კატეგორია მოიცავს ყველა აირს, რომელთა კრიტიკული ტემპერატურაც ნაკლებია ან თანაბარია -500C ტემპერატურისა; 2. გათხევადებული აირი: აირი, რომელიც გადაზიდვის მიზნით წნევის ქვეშ შეფუთვის შემთხვევაში, ნაწილობრივ გათხევადებულია -500C-ზე მაღალ ტემპერატურაზე. ერთმანეთისგან უნდა განსხვავდეს: მაღალი წნევის მქონე გათხევადებული აირი: აირი, რომლის კრიტიკული ტემპერატურა -500C-ზე მეტია და ტოლია ან არ აღემატება +650C ტემპერატურას; დაბალი წნევის მქონე გათხევადებული აირი: აირი, რომლის კრიტიკული ტემპერატურა აღემატება +650C ტემპერატურას. 3. გაცივებული გათხევადებული აირი: აირი, რომელიც გადაზიდვის მიზნით წნევის ქვეშ შეფუთვის შემთხვევაში, ნაწილობრივ გათხევადდა დაბალი ტემპერატურის გამო; 4. გახსნილი აირი: აირი, რომელიც გადაზიდვის მიზნით წნევის ქვეშ შეფუთვის შემთხვევაში, გაიხსნა თხევად გამხსნელში; 5. აეროზოლური გამფრქვევები და ჭურჭელი, მცირე მოცულობის, აირის შემცველი (აირის ბალონი); 6. სხვა ნაკეთობები, რომლებიც შეიცავს აირს წნევის ქვეშ; 182 7. არა-წნევის ქვეშ მყოფი აირები, რომლებიც ექვემდებარება საგანგებო მოთხოვნებს (აირის ნიმუშები). 8. წნევის ქვეშ მყოფი ქიმიური პროდუქტები: სითხეები, პასტები ან ფხვნილები, რომლებიც წარმოდგენილია წნევის ქვეშ იმ სატყორც მუხტთან ერთად, რომელიც პასუხობს შეკუმშული ან გათხევადებული აირის ან აღნიშნული ნივთერებების ნარევის განსაზღვრებას. 9. ადსორბირებული აირი: აირი, რომელიც გადაზიდვისთვის შეფუთვის დროს ადსორბირდება მყარ ფოროვან მასალად, რის შედეგადაც ჭურჭელში შიდა წნევა შეადგენს 101.3 კპა-ზე ნაკლებს 200C ტემპერატურაზე და 300 კპა-ზე ნაკლებს - 500C ტემპერატურაზე. 2.2.2.1.3 მე-2 კლასში შემავალი ნივთიერებები და ნაკეთობები (გარდა აეროზოლებისა და წნევის ქვეშ არსებული ქიმიური პროდუქტებისა) მიეკუთვნება შემდეგი ჯგუფებიდან ერთერთს მათთვის დამახასიათებელი სახიფათო თვისებების შესაბამისად: A მხუთავი; O მჟანგავი; F ადვილაალებადი; T ტოქსიკური; TF ტოქსიკური, ადვილაალებადი; TC ტოქსიკური, კოროზიული; TFC ტოქსიკური, ადვილაალებადი, კოროზიული; TOC ტოქსიკური, მჟანგავი, კოროზიული იმ აირებისა და აირის ნარევების შემთხვევაში, რომელთაც აღენიშნებათ სახიფათო თვისებები და რომლებიც ასოცირდება ერთზე მეტ ჯგუფთან არსებული კრიტერიუმების შესაბამისად,T ასოთი აღნიშნულ ჯგუფებს ენიჭებათ უპირატესობა ყველა სხვა ჯგუფთან შედარებით. F ასოთი აღნიშნულ ჯგუფებს ენიჭებათ უპირატესობა A ან O ასოებით აღნიშნულ ჯგუფებთან შედარებით. შენიშვნა 1: გაეროს ტიპიურ წესებში, სახიფათო ტვირთების საერთაშორისო საზღვაო გადაზიდვების შესახებ კოდექსსა და ICAO-ს ტექნიკურ მითითებებში, აირები განეკუთვნება ერთ-ერთს შემდეგი სამი ქვეკლასიდან, ძირითადი საშიშროების მიხედვით: ქვეკლასი 2.1: ადვილაალებადი აირები (შეესაბამება F მთავრული ასოთი აღნიშნულ ჯგუფებს); ქვეკლასი 2.2: არა-ადვილაალებადი, არატოქსიკური აირები (შეესაბამება A ან O მთავრული ასოებით აღნიშნულ ჯგუფებს); ქვეკლასი 2.3: ტოქსიკური აირები (შეესაბამება T ანუ T, TF, TC, TO, TFC და TOC მთავრული ასოებით აღნიშნულ ჯგუფებს). შენიშვნა 2: მცირე ზომის, აირის შემცველი ჭურჭელი (გაეროს №2037) განეკუთვნება ATOC ჯგუფებს მისი შიგთავის სახიფათოობის მიხედვით. აეროზოლებთან 183 დაკავშირებით (გაეროს №1950) იხილეთ 2.2.2.1.6 ქვეპუნქტი. წნევის ქვეშ მყოფ ქიმიურ პროდუქტებთან (გაეროს №3500-3505) დაკავშირებით ისილეთ 2.2.2.1.7 ქვეპუნქტი. შენიშვნა 3: კოროზიული აირები ითვლება ტოქსიკურად და შესაბამისად განეკუთვნება TC, TFC ან TOC ჯგუფს. 2.2.2.1.4 იმ შემთხვევაში, თუ 3.2 თავის A ცხრილში დასახელებით მითითებული მე-2 კლასის ნარევი აკმაყოფილებს 2.2.2.1.2 და 2.2.2.1.5 ქვეპუნქტებში გათვალისწინებულ სხვადასხვა კრიტერიუმს, ნარევის კლასიფიცირება უნდა მოხდეს შესაბამისი კრიტერიუმის მიხედვით და მიეკუთვნოს შესაბამის N.O.S. პოზიციას. 2.2.2.1.5 მე-2 კლასში გათვალისწინებული ნივთიერებები და ნაკეთობები (გარდა აეროზოლებისა), რომლებიც არ არის მითითებული დასახელებით 3.2. თავის A ცხრილში, კლასიფიცირდება 2.2.2.3 პუნქტში ჩამოთვლილ ერთობლივ პოზიციაზე, 2.2.2.1.2 და 2.2.2.1.3 ქვეპუნქტების შესაბამისად. აღნიშნულ შემთხვევაში გამოიყენება შემდეგი კრიტერიუმები: მხუთავი აირები აირები, რომლებიც არ წარმოადგენს მჟანგავ, ადვილაალებად და ტოქსიკურ აირებს და რომლებიც ახდენს ჩვეულებრივ ატმოსფეროში შემავალი ჟანგბადის გახსნას ან შეცვლას. ადვილაალებადი აირები აირები, რომლებიც 200C ტემპერატურასა და 101.3 კპა სტანდარტულ წნევაზე: (ა) არის აალებადი, როდესაც წარმოდგენილია ჰაერთან 13% ან უფრო ნაკლები მოცულობის ნარევის სახით; ან (ბ) გააჩნია აალების დიაპაზონი ჰაერთან არანაკლებ 12 პროცენტიანი პუნქტით, მიუხედავად დაბალი აალების ლიმიტისა. აალებადობა განისაზღვრება ტესტებისა თუ გაანგარიშების გზით, დამტკიცებული მეთოდების შესაბამისად (იხილეთ ISO 10156:2010). ISO-ს მიერ როდესაც აღნიშნული მეთოდებით სარგებლობისთვის არ არის წარმოდგენილი საკმარისი მონაცემები, შესაძლებელია გამოყენებულ იქნეს წარმოშობის ქვეყნის კომპეტენტური ორგანოს მიერ აღიარებული შედარებითი მეთოდი. იმ შემთხვევაში, თუ წარმოშობის ქვეყანა არ წარმოადგენს ADR-ის ხელშემკვრელ მხარეს, აღნიშნული მეთოდები აღიარებულ უნდა იქნეს იმ პირველი ქვეყნის კომპეტენტური ორგანოს მიერ, რომელიც წარმოადგენს ADR-ის ხელშემკვრელ მხარეს ტვირთების გადაზიდვის მარშრუტზე. მჟანგავი აირები აირები, რომლებსაც შეუძლიათ ჩვეულებრივ ჟანგბადის გამოყოფით, გამოიწვიოს ან ხელი შეუწყოს სხვა მასალების წვას უფრო მეტი ხარისხით, ვიდრე ჰაერის შემთხვევაში. აღნიშნულ კატეგორიას მიეკუთვნება სუფთა აირები ან აირის ნარევები, რომელთა ჟანგვის შესაძლებლობაც აღემატება 23.5%-ს ISO 10156:2010 სტანდარტით გათვალისწინებული მეთოდის მიხედვით. ტოქსიკური აირები 184 შენიშვნა: აირები, რომლებიც ნაწილობრივ ან სრულად პასუხობს ტოქსიკურობასთან დაკავშირებულ კრიტერიუმებს მათი კოროზიული თვისებებიდან გამომდინარე, კლასიფიცირებული უნდა იქნეს, როგორც ტოქსიკური. იხილეთ აგრეთვე „კოროზიული აირების“ პუნქტში მოყვანილი კრიტერიუმები შესაძლო დამატებითი კოროზიულობის რისკთან დაკავშირებით. აირები, რომლებსაც: (ა) დამტკიცებულია, რომ გააჩნია იმდენად ძლიერი ტოქსიკური ან კოროზიული ზემოქმედება ადამიანებზე, რომ წარმოადგენს საშიშროებას მათი ჯანმრთელობისთვის; ან (ბ) ითვლება, რომ ახდენს ტოქსიკურ ან კოროზიულ ზემოქმედებას ადამიანებზე, ვინაიდან მათ გააჩნიათ 5 000 მლ/მ3 (მილიონზე ნაწილების რაოდენობა) თანაბარი ან ნაკლები LC50 მნიშვნელობა მწვავე ტოქსიკურობასთან დაკავშირებით, როდესაც ხდება მათი გამოცდა 2.2.61.1 პუნქტის შესაბამისად. აირის ნარევების არსებობის შემთხვევაში (სხვა კლასებიდან წარმოდგენილი ნივთიერებების ორთქლის ჩათვლით), შესაძლებელია გამოყენებულ იქნეს შემდეგი ფორმულა: LC50 ტოქსიკური (ნარევი) = სადაც: f1 = ნარევის ნივთიერების i კომპონენტის მოლური წილი Ti = ნარევის ნივთიერების i კომპონენტის ტოქსიკურობის მაჩვენებელი Ti უთანაბრდება LC50 მნიშვნელობას, რაც მითითებულია 4.1.4.1 პუნქტით გათვალისწინებულ P200 შეფუთვის ინსტრუქციაში. იმ შემთხვევაში, თუ 4.1.4.1 პუნქტით გათვალისწინებულ P200 შეფუთვის ინსტრუქციაში არ არის წარმოდგენილი LC50 მნიშვნელობა, მაშინ გამოიყენება სამეცნიერო ლიტერატურაში მითითებული LC50 მნიშვნელობა. როდესაც LC50 მნიშვნელობა უცნობია, ტოქსიკურობის მაჩვენებელი განისაზღვრება მსგავსი ფიზიოლოგიური და ქიმიური ეფექტების მქონე ნივთიერებების ყველაზე დაბალი LC50 მნიშვნელობის გამოყენებით ან გამოცდის საშუალებით, თუ აღნიშნული წარმოადგენს ერთადერთ პრაქტიკულ შესაძლებლობას. კოროზიული აირები აირები ან აირის ნარევები, რომლებიც სრულად აკმაყოფილებს ტოქსიკურობასთან დაკავშირებით არსებულ კრიტერიუმებს მათი კოროზიულობიდან გამომდინარე, კლასიფიცირებული უნდა იქნეს როგორც ტოქსიკური ნივთიერება, კოროზიული ზემოქმედების დამატებითი საშიშროებით. აირების ნარევს, რომელიც განიხილება, როგორც ტოქსიკური კოროზიულობისა და ტოქსიკურობის კომბინირებული მოქმედების მიზეზით, აღენიშნება კოროზიულობის დამატებითი რისკი იმ შემთხვევაში, თუ ადამიანთა გამოცდილებიდან ნაჩვენებია, რომ ნარევს გააჩნია დესტრუქციული მოქმედება კანზე, თვალსა თუ ლორწოვან გარსზე, ან 185 თუ ნარევის კოროზიული კომპონენტების LC50 მნიშვნელობა თანაბარია ან ნაკლებია 5 000 მლ/მ3-ზე (მილიონზე ნაწილების რაოდენობა), როდესაც LC50 მნიშვნელობის გაანგარიშება ხდება შემდეგი ფორმულის მიხედვით: LC50 კოროზიული (ნარევი) = სადაც: fc1 = ნარევის ნივთიერების კოროზიული i კომპონენტის მოლური წილი Tci = ნარევის ნივთიერების კოროზიული i კომპონენტის ტოქსიკურობის მაჩვენებელი. Tci უთანაბრდება LC50 მნიშვნელობას, რაც მითითებულია 4.1.4.1 პუნქტით გათვალისწინებულ P200 შეფუთვის ინსტრუქციაში. როდესაც LC50 მნიშვნელობა უცნობია, ტოქსიკურობის მაჩვენებელი განისაზღვრება მსგავსი ფიზიოლოგიური და ქიმიური ეფექტების მქონე ნივთიერებების ყველაზე დაბალი LC50 მნიშვნელობის გამოყენებით, ან ტესტირების საშუალებით, თუ აღნიშნული წარმოადგენს ერთადერთ პრაქტიკულ შესაძლებლობას. 2.2.2.1.6 აეროზოლები აეროზოლები (გაეროს N1950) მიეკუთვნება შემდეგი ჯგუფებიდან ერთ-ერთს მათთვის დამახასიათებელი სახიფათო თვისებებიდან გამომდინარე: A მხუთავი; O მჟანგავი; F ადვილაალებადი; T ტოქსიკური; C კოროზიული; CO კოროზიული, მჟანგავი FC ადვილაალებადი, კოროზიული; TF ტოქსიკური, ადვილაალებადი; TC ტოქსიკური, კოროზიული; TO ტოქსიკური, მჟანგავი; TFC ტოქსიკური, ადვილაალებადი, კოროზიული; TOC ტოქსიკური, მჟანგავი, კოროზიული კლასიფიკაცია დამოკიდებულია აეროზოლური გამფრქვევის შიგთავსის ხასიათზე. შენიშვნა: აირები, რომლებიც აკმაყოფილებს 2.2.2.1.5 ქვეპუნქტის შესაბამისად ტოქსიკურ აირებთან დაკავშირებულ განსაზღვრებას ან 4.1.4.1 პუნქტით გათვალისწინებულ P200 შეფუთვის ინსტრუქციის მე-2 ცხრილის გ შენიშვნის 186 შესაბამისად წარმოდგენილ განსაზღვრებას „მიჩნეულია, როგორც პიროფორული“, არ შეიძლება გამოყენებულ იქნეს სათბობის სახით აეროზოლურ გამფრქვევში. ის აეროზოლები, რომელთა შემცველობაც აკმაყოფილებს ტოქსიკურობასა თუ კოროზიულობასთან დაკავშირებით I შეფუთვის ჯგუფზე განსაზღვრულ კრიტერიუმებს, არ დაიშვება გადაზიდვებზე (იხილეთ აგრეთვე 2.2.2.2.2 ქვეპუნქტი). გამოიყენება შემდეგი კრიტერიუმები: (ა) A ჯგუფზე მიკუთვნება ხდება მაშინ, როდესაც შიგთავსი არ აკმაყოფილებს არცერთი სხვა ჯგუფის კრიტერიუმს ქვემოთ მოყვანილი (ბ)-(ვ) ქვეპუნქტების შესაბამისად; (ბ) O ჯგუფზე მიკუთვნებას ადგილი აქვს მაშინ, როდესაც აეროზოლი შეიცავს მჟანგავ აირს 2.2.2.1.5 ქვეპუნქტის შესაბამისად; (გ) F ჯგუფზე მიკუთვნება ხდება იმ შემთხვევაში, თუ შიგთავსი შეიცავს 85% ან უფრო მეტ ადვილაალებად კომპონენტს, ხოლო წვის ქიმიური სითბო შეადგენს 30 კჯ/გ-ს ან მეტს. მისი კლასიფიკაცია არ ხდება იმ შემთხვევაში, თუ შიგთავსი შეიცავს 1% ან უფრო ნაკლებ ადვილაალებად კომპონენტს, ხოლო წვის ქიმიური სითბო შეადგენს 20 კჯ/გ-ს ან ნაკლებს. წინააღმდეგ შემთხვევაში, აეროზოლის გამოცდა უნდა მოხდეს აალებაზე ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 31-ე კარში აღწერილი ტესტების შესაბამისად. უკიდურესად ადვილაალებადი და ადვილაალებადი აეროზოლები მიეკუთვნება F ჯგუფს. შენიშვნა: ადვილაალებად კომპონენტებს წარმოადგენს ადვილაალებადი სითხეები, ადვილაალებადი მყარი ნივთიერებები ან ადვილაალებადი აირები თუ აირის ნარევები, რაც განისაზღვრება ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 31.1.3 პუნქტის 1-3 შენიშვნის შესაბამისად. აღნიშნული აღნიშვნა არ მოიცავს პიროფორულ, თვითთბობად ან წყალთან რეაგირებად ნივთიერებებს. წვის ქიმიური სითბო განისაზღვრება შემდეგი მეთოდებიდან ერთ-ერთის მიხედვით: ASTDM D 240 ISO/FDIS 13943 (E/F) 86.1დან 86.3-მდე ან NFPA 30B. 2.2.2.1.7 (დ) T ჯგუფზე მიკუთვნება მოხდება იმ შემთხვევაში, როდესაც შიგთავსი, აეროზოლურ გამფრქვევში არსებული სათბობის გამოკლებით, კლასიფიცირდება მე-6.1 კლასის II ან III შეფუთვის ჯგუფში. (ე) C ჯგუფზე მიკუთვნება მოხდება იმ შემთხვევაში, როდესაც შიგთავსი, აეროზოლურ გამფრქვევში არსებული სათბობის გამოკლებით, აკმაყოფილებს მე8 კლასის II ან III შეფუთვის ჯგუფთან დაკავშირებულ კრიტერიუმებს. (ვ) იმ შემთხვევაში, თუ ადგილი აქვს O, F, T ან C ჯგუფებიდან ერთზე მეტი ჯგუფის კრიტერიუმების დაკმაყოფილებას, შესაბამისად მოხდება ნივთიერების მიკუთვნება CO, FC, TF, TC, TO, TFC ან TOC ჯგუფებზე. წნევის ქვეშ წარმოდგენილი ქიმიური პროდუქტები 187 წნევის ქვეშ წარმოდგენილი ქიმიური პროდუქტები (გაეროს N3500 ან 3505) მიეკუთვნება შემდეგი ჯგუფებიდან ერთ-ერთს მათთვის დამახასიათებელი სახიფათო თვისებებიდან გამომდინარე: A მხუთავი; F ადვილაალებადი; T ტოქსიკური; C კოროზიული; FC ადვილაალებადი, კოროზიული; TF ტოქსიკური, ადვილაალებადი; კლასიფიკაცია დამოკიდებულია საშიშროების ხასიათზე: სხვადასხვა მდგომარეობაში კომპონენტების სათბობი; თხევადი; ან მყარი ნივთიერება. შენიშვნა 1: აირები, რომლებიც აკმაყოფილებს 2.2.2.1.5 ქვეპუნქტის თანახმად ტოქსიკური აირების ან მჟანგავი აირების განსაზღვრებას ან აირები, რომლებიც 1.4.1 პუნქტით გათვალისწინებულ P200 შეფუთვის ინსტრუქციის მე-2 ცხრილის გ შენიშვნის შესაბამისად განსაზღვრულია, როგორც „მიჩნეულია, როგორც პიროფორული“, არ გამოიყენება სათბობი ნივთიერების სახით წნევის ქვეშ წარმოდგენილ ქიმიურ პროდუქტებში. შენიშვნა 2: წნევის ქვეშ წარმოდგენილი ქიმიური პროდუქტები, რომლის შიგთავსი აკმაყოფილებს ტოქსიკურობასა თუ კოროზიულობასთან დაკავშირებით I შეფუთვის ჯგუფით გათვალისწინებულ კრიტერიუმებს, ან რომლის შიგთავსი აკმაყოფილებს როგორც ტოქსიკურობასთან დაკავშირებით II ან III შეფუთვის ჯგუფში, ასევე კოროზიულობასთან დაკავშირებით II ან III შეფუთვის ჯგუფში გათვალისწინებულ კრიტერიუმებს, არ დაიშვება გადაზიდვებზე აღნიშნული გაეროს ნომრებით. შენიშვნა 3: წნევის ქვეშ წარმოდგენილი ქიმიური პროდუქტები, რომლის კომპონენტები აკმაყოფილებს პირველი კლასით; მე-3 კლასის გათვალისწინებული თხევადი არასენსიბილიზებული ფეთქებადი ნივთოერებების, 4.1 კლასით გათვალისწინებული თვითრეაქტიული ნივთიერებებისა და მყარი დესენსიბილიზებული ფეთქებადი ნივთიერებების; 4.2 კლასით; 4.3 კლასით; 5.1 კლასით; 6.2 კლასით ან მე-7 კლასით გათვალისწინებულ თვისებებს. შენიშვნა 4: წნევის ქვეშ წარმოდგენილი ქიმიური პროდუქტების, რომლებიც წარმოდგენილია აეროზოლურ გამფრქვევში, გადაზიდვა უნდა მოხდეს შემდეგი გაეროს №1950-ით. გამოიყენება შემდეგი კრიტერიუმები: (ა) A ჯგუფი განისაზღვრება იმ შემთხვევაში, თუ შიგთავსი არ აკმაყოფილებს ნებისმიერ სხვა ჯგუფთან დაკავშირებულ კრიტერიუმებს, ქვემოთ წარმოდგენილი (ბ)-(ე) ქვეპუნქტების თანახმად; 188 (ბ) (გ) F ჯგუფი განისაზღვრება იმ შემთხვევაში, თუ ერთერთი კომპონენტი, რომელიც შესაძლებელია იყოს სუფთა ნივთიერება ან ნაერთი, საჭიროებს კლასიფიცირებას ადვილაალებადი ნივთიერების სახით. ადვილაალებადი კომპონენტები წარმოადგენს ადვილაალებად სითხეს ან სითხის ნაერთებს, ადვილაალებად მყარ ნივთიერებებს და მყარი ნივთერებების ნაერთებს ან ადვილაალებად აირებს და აირების ნაერთებს, რომლებიც აკმაყოფილებს შემდეგ კრიტერიუმებს: i) ადვილაალებადი სითხე წარმოადგენს ტემპერატურა არ აღემატება 930C-ს; სითხეს, რომლის აფეთქების ii) ადვილაალებადი მყარი ნივთიერება რომელიც აკმაყოფილებს 2.2.41.1 კრიტერიუმებს; წარმოადგენს პუნქტით iii) ადვილაალებადი აირი წარმოადგენს აირს, რომელიც აკმაყოფილებს 2.2.2.1.5 პუნქტით გათვალისწინებულ კრიტერიუმებს; მყარ ნივთერებას, გათვალისწინებულ T ჯგუფი განისაზღვრება იმ შემთხვევაში, თუ შიგთავსი, გარდა სათბობი ნივთიერებებისა, კლასიფიცირებულია 6.1 კლასის II ან III შეფუთვის ჯგუფის სახიფათო ტვირთის სახით; (დ) C ჯგუფი განისაზღვრება იმ შემთხვევაში, თუ შიგთავსი, გარდა სათბობი ნივთიერებებისა, კლასიფიცირებულია მე-8 კლასის II ან III შეფუთვის ჯგუფის სახიფათო ტვირთის სახით; (ე) იმ შემთხვევაში, თუ F, T ან C ჯგუფებიდან ორი ჯგუფთან დაკავშირებით არსებული კრიტერიუმები დაკმაყოფილდება, შესაბამისად ისინი განისაზღვრება FC ან TF ჯგუფებში. 2.2.2.2 აირები, რომლებიც არ დაიშვება გადაზიდვებზე 2.2.2.2.1 მე-2 კლასის ქიმიურად არასტაბილური ნივთიერებები არ დაიშვება გადაზიდვებზე, სანამ არ მოხდება შესაბამისი ღონისძიებების მიღება ყოველგვარი სახიფათო რეაქციის, მაგალითად, გადაზიდვის ნორმალურ პირობებში დაშლის, დისმუტაციის ან პოლიმერიზაციის ყველა შესაძლებლობის პრევენციის მიზნით. აღნიშნული მიზნით განსაკუთრებული სიფრთხილის ზომები უნდა იქნეს დაცული იმ ფაქტის უზრუნველსაყოფად, რომ ჭურჭელი ან ცისტერნები არ შეიცავდეს რაიმე, აღნიშნული რეაქციების გამომწვევ ნივთიერებას. 2.2.2.2.2 გადაზიდვებზე არ დაიშვება შემდეგი ნივთიერებები და ნაკეთობები: - გაეროს № 2186 - წყალბადის ქლორიდი, გაცივებული, თხევადი; - გაეროს № 2421 - სამჟანგის აზოტი; - გაეროს № 2455 - მეთილნიტრიტი; - გაცივებული, გათხევადებული აირები, რომელთა მიმართაც შეუძლებელია 3A, 3O ან 3F კლასიფიკაციის კოდების მიკუთვნება; - გახსნილი აირები, რომელთა კლასიფიცირებაც შეუძლებელია გაეროს ნომრებით 1001, 2073 ან 3318; 189 - აეროზოლები, რომელშიც აირები, რომლებიც წარმოადგენს ტოქსიკურს 2.2.2.1.5 ქვეპუნქტის შესაბამისად ან პიროფორულს 4.1.4.1 პუნქტით გათვალისწინებულ P200 შეფუთვის ინსტრუქციის შესაბამისად, გამოიყენება სათბობის სახით; - აეროზოლები, რომელთა შიგთავსიც აკმაყოფილებს ტოქსიკურობასა თუ კოროზიულობასთან დაკავშირებული I შეფუთვის ჯგუფით გათვალისწინებულ კრიტერიუმებს (იხილეთ 2.2.61 და 2.2.8 პუნქტები); - ჭურჭელი, მცირე მოცულობის, აირების შემცველი, რომელიც წარმოადგენს ძალზედ ტოქსიკურს (LC50 ნაკლებია 200 მილიონზე ნაწილების რაოდენობაზე) ან პიროფორულს 4.1.4.1 პუნქტით გათვალისწინებულ P200 შეფუთვის ინსტრუქციის თანახმად. 190 ერთობლივი პოზიციების ჩამონათვალი 2.2.2.3 შეკუმშული აირები კლასიფიკაციის გაეროს კოდი № 1A 1956 1O 3156 1F 1964 1954 1T 1955 1 TF 1953 1 TC 3304 1 TO 3303 1 TFC 3305 1 TOC 3306 გათხევადებული აირები კლასიფიკაციის გაეროს კოდი № 2A 1058 1078 2O 1968 3163 3157 ნივთიერებისა თუ ნაკეთობის დასახელება შეკუმშული აირი, N.O.S. შეკუმშული აირი, მჟანგავი, N.O.S. ნახშირბადის აირის ნარევი, შემკუმშული N.O.S. შეკუმშული აირი, ადვილაალებადი, N.O.S. შეკუმშული აირი, ტოქსიკური, N.O.S. შეკუმშული აირი, ტოქსიკური, ადვილაალებადი N.O.S. შეკუმშული აირი, ტოქსიკური, კოროზიული N.O.S. შეკუმშული აირი, ტოქსიკური, მჟანგავი N.O.S. შეკუმშული აირი, ტოქსიკური, ადვილაალებადი, კოროზიული N.O.S. შეკუმშული აირი, ტოქსიკური, მჟანგავი, კოროზიული N.O.S. ნივთიერებისა თუ ნაკეთობის დასახელება გათხევადებული აირები, არა-ადვილაალებადი, დამუხტული აზოტით, ნახშიროჟანგით ან ჰაერით მაცივებელი აირი, N.O.S. როგორიცაა აირების ნარევები, მითითებული R ასოთი... როგორიცაა: ნარევი F1, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 1.3 მპა-ს (13 ბარს), ხოლო სიმკვრივე 500C ტემპერატურაზე არ ჩამოუვარდება დიქლორფტორმეთანის სიმკვრივეს (1.30 კგ/ლ); ნარევი F2, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 1.9 მპა-ს (19 ბარს), ხოლო სიმკვრივე 500C ტემპერატურაზე არ ჩამოუვარდება დიქლორდიფტორმეთანის სიმკვრივეს (1.21 კგ/ლ); ნარევი F3, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 3 მპა-ს (30 ბარს), ხოლო სიმკვრივე 500C ტემპერატურაზე არ ჩამოუვარდება ქლორდიფტორმეთანის სიმკვრივეს (1.309 კგ/ლ); შენიშვნა: ტრიქლორფტორმეთანი (მაცივებელი საშუალება R11), 1,1,2ტრიქლორ-1,2,2-ტრიფტორეთანი (მაცივებელი საშუალება R113), 1,1,1ტრიქლორ-2,2,2-ტრიფტორეთანი (მაცივებელი საშუალება 113ა), 1ქლორ-1,2,2-ტრიფტორეთანი (მაცივებელი საშუალება R133), და 1-ქლორ1,1,2-ტრიფტორეთანი (მაცივებელი საშუალება R133ბ) არ წარმოადგენს მე-2 კლასის ნივთიერებებს, თუმცა ისინი შესაძლებელია გათვალისწინებული იქნეს F1-F3 ნარევების შემადგენლობაში. ინსექტიციდური აირი, N.O.S. გათხევადებული აირი, N.O.S. გათხევადებული აირი, მჟანგავი N.O.S. 191 გათხევადებული აირები კლასიფიკაციის გაეროს კოდი № 2F 1010 (გაგრძელება) 1060 1065 ნივთიერებისა თუ ნაკეთობის დასახელება ბუტადიენებისა და ნახშირბადების ნარევი, სტაბილიზებული, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 1.1 მპა-ს (11 ბარს), ხოლო სიმკვრივე 500C ტემპერატურაზე არ ჩამოუვარდება 0.525 კგ/ლ-ს. შენიშვნა: სტაბილიზებული ბუტადიენები აგრეთვე კლასიფიცირდება გაეროს ნომრით 1010, იხილეთ 3.2 თავის A ცხრილი. მეთილაცეტილენისა და პროპადიენის ნარევი, სტაბილიზებული, როგორც მეთილაცეტილენისა და პროპადიენის ნარევები ნახშირბადებთან ერთად, როგორიცაა: ნარევი P1, შეიცავს არაუმეტეს 63% მოცულობის მეთილაცეტილენს და პროპადიენს და არაუმეტეს 24% მოცულობის პროპანსა და პროპილენს, C4- ნაჯერი ნახშირბადების პროცენტულობა უნდა შეადგენდეს მინიმუმ 14% მოცულობას; და ნარევი P2, შეიცავს არაუმეტეს 48% მოცულობის მეთილაცეტილენს და პროპადიენს და არაუმეტეს 50% მოცულობის პროპანსა და პროპილენს, C4- ნაჯერი ნახშირბადების პროცენტულობა უნდა შეადგენდეს მინიმუმ 5% მოცულობას; ასევე პროპადიენის ნარევები 1-4 მეთილაცეტილენით. ნახშირბადის აირის ნარევი, გათხევადებული, N.O.S. ისეთი ნარევები, როგორიცაა: ნარევი A, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 1.1 მპა-ს (11 ბარს), ხოლო სიმკვრივე 500C ტემპერატურაზე არ არის 0.525 კგ/ლ-ზე ნაკლები; ნარევი A01, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 1.6 მპა-ს (16 ბარს), ხოლო ფარდობითი სიმკვრივე 500C ტემპერატურაზე არ არის 0.516 კგ/ლ-ზე ნაკლები; ნარევი A02, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 1.6 მპა-ს (16 ბარს), ხოლო ფარდობითი სიმკვრივე 500C ტემპერატურაზე არ არის 0.505 კგ/ლ-ზე ნაკლები; ნარევი A0, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 1.6 მპა-ს (16 ბარს), ხოლო სიმკვრივე 500C ტემპერატურაზე არ არის 0.495 კგ/ლ-ზე ნაკლები; ნარევი A1, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 2.1 მპა-ს (21 ბარს), ხოლო სიმკვრივე 500C ტემპერატურაზე არ არის 0.485 კგ/ლ-ზე ნაკლები; ნარევი B1, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 2.6 მპა-ს (26 ბარს), ხოლო ფარდობითი სიმკვრივე 500C ტემპერატურაზე არ არის 0.474 კგ/ლ-ზე ნაკლები; ნარევი B2, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 2.6 მპა-ს (26 ბარს), ხოლო ფარდობითი სიმკვრივე 500C ტემპერატურაზე არ არის 0.463 კგ/ლ-ზე ნაკლები; ნარევი B, რომლის ორთქლის წნევა 700C ტემპერატურაზე არ აღემატება 3.1 მპა-ს (31 ბარს), ხოლო ფარდობითი სიმკვრივე 500C ტემპერატურაზე არ არის 0.440 კგ/ლ-ზე ნაკლები; 192 გათხევადებული აირები კლასიფიკაციის გაეროს კოდი № 2F (გაგრძელება) 2 TC 2 TO 2 TFC 3354 3161 1967 3162 3355 3160 3308 3307 3309 2 TOC 3310 2T 2 TF ნივთიერებისა თუ ნაკეთობის დასახელება შენიშვნა 1: ზემოაღნიშნული ნარევების აღწერის მიზნით აგრეთვე დასაშვებია სავაჭრო საქმიანობაში დამკვიდრებული შემდეგი დასახელებების გამოყენება: A, A01, A01 და A0 ნარევების შემთხვევაში: ბუტანი, C ნარევის შემთხვევაში: პროპანი. შენიშვნა 2: გაეროს #1075 - ნავთობის აირები, გათხევადებული, შესაძლებელია გამოყენებულ იქნეს ალტერნატიული პოზიციის სახით გაეროს #1965 - ნახშირბადის აირის ნარევი - გათხევადებული, N.O.S. გადაზიდვებისთვის საზღვაო თუ საჰაერო გადაზიდვების განხორციელებამდე ან მის შემდეგ. ინსექტიციდური აირი, ადვილაალებადი, N.O.S. გათხევადებული აირი, ადვილაალებადი N.O.S. ინსექტიციდური აირი, ტოქსიკური, N.O.S. გათხევადებული აირი, ტოქსიკური, N.O.S. ინსექტიციდური აირი, ტოქსიკური, ადვილაალებადი, N.O.S. გათხევადებული აირი, ტოქსიკური, ადვილაალებადი N.O.S. გათხევადებული აირი, ტოქსიკური, კოროზიული, N.O.S. გათხევადებული აირი, ტოქსიკური, მჟანგავი, N.O.S. გათხევადებული აირი, ტოქსიკური, ადვილაალებადი, კოროზიული, N.O.S. გათხევადებული აირი, ტოქსიკური, მჟანგავი, კოროზიული, N.O.S. გაცივებული გათხევადებული აირები კლასიფიკაციის გაეროს ნივთიერებისა თუ ნაკეთობის დასახელება კოდი № 3A 3158 აირი, გაცივებული, გათხევადებული, N.O.S. 3O 3311 აირი, გაცივებული, გათხევადებული, მჟანგავი, N.O.S. 3F 3312 აირი, გაცივებული, გათხევადებული, ადვილაალებადი, N.O.S. გახსნილი აირები კლასიფიკაციის გაეროს კოდი № 4 ნივთიერებისა თუ ნაკეთობის დასახელება გადაზიდვებზე დაიშვება მხოლოს 3.2 თავის A ცხრილში მითითებული ნივთიერებები აეროზოლები და ჭურჭელი, მცირე ზომის, აირების შემცველი კლასიფიკაციის გაეროს ნივთიერებისა თუ ნაკეთობის დასახელება კოდი № 5 1950 აეროზოლები 2037 ჭურჭელი, მცირე ზომის, აირების შემცველი (აირის ბალონები), გამომშვები მოწყობილობის გარეშე, არა-მრავალჯერადი შევსების. 193 წნევის ქვეშ აირის შემცველი სხვა ნაკეთობები კლასიფიკაციის გაეროს ნივთიერებისა თუ ნაკეთობის დასახელება კოდი № 6A 2857 მაცივებელი დანადგარები, რომლებიც შეიცავს არა-ადვილაალებად, არატოქსიკურ აირებს ან ამიაკის ხსნარებს (გაეროს #2672) 3164 პნევმატიკური წნევის ქვეშ წარმოდგენილი ნაკეთობები (შეიცავს არაადვილაალებად აირს), ან 3164 ჰიდრავლიკური წნევის ქვეშ წარმოდგენილი ნაკეთობები (შეიცავს არაადვილაალებად აირს) 6F 3150 მცირე ზომის, ნახშირბადის აირზე მომუშავე მოწყობილობები 3150 ნახშირბადის აირის შემავსებელი ბალონები მცირე ზომის მოწყობილობებისთვის, გამომშვებ მოწყობილობასთან ერთად 3478 საწვავის ელემენტების ბალონები, რომელიც შეიცავს გათხევადებულ, ადვილაალებად აირს, ან 3478 აღჭურვილობაში წარმოდგენილი საწვავის ელემენტების ბალონები, რომლებიც შეიცავს გათხევადებულ ადვილაალებად აირს, ან 3478 აღჭურვილობასთან ერთად შეფუთული საწვავის ელემენტების ბალონები, რომლებიც შეიცავს გათხევადებულ ადვილაალებად აირს, 3479 საწვავის ელემენტების ბალონები, რომლებიც შეიცავს წყალბადს ლითონის ჰიდრიდში, ან 3479 აღჭურვილობაში წარმოდგენილი საწვავის ელემენტების ბალონები, რომლებიც შეიცავს წყალბადს ლითონის ჰიდრიდში, ან 3479 აღჭურვილობასთან ერთად შეფუთული საწვავის ელემენტების ბალონები, რომლებიც შეიცავს წყალბადს ლითონის ჰიდრიდში. აირის ნიმუშები კლასიფიკაციის კოდი 7F გაეროს № 3167 2T 3169 7 TF 3168 ნივთიერებისა თუ ნაკეთობის დასახელება აირის ნიმუში, არა-წნევის ქვეშ, ადვილაალებადი, N.O.S. არ ცივდება თხევად მდგომარეობამდე აირის ნიმუში, არა-წნევის ქვეშ, ტოქსიკური, N.O.S. არ ცივდება თხევად მდგომარეობამდე აირის ნიმუში, არა-წნევის ქვეშ, ტოქსიკური, ადვილაალებადი, N.O.S. არ ცივდება თხევად მდგომარეობამდე წნევის ქვეშ წარმოდგენილი ქიმიური პროდუქტები კლასიფიკაციის გაეროს ნივთიერებისა თუ ნაკეთობის დასახელება კოდი № 8A 3500 ქიმიური პროდუქტი წნევის ქვეშ, N.O.S. 8F 3501 ქიმიური პროდუქტი წნევის ქვეშ, ადვილაალებადი, N.O.S. 8T 3502 ქიმიური პროდუქტი წნევის ქვეშ, ტოქსიკური, N.O.S. 8C 3503 ქიმიური პროდუქტი წნევის ქვეშ, კოროზიული, N.O.S. 8 TF 3504 ქიმიური პროდუქტი წნევის ქვეშ, ადვილაალებადი, ტოქსიკური, N.O.S. 8 FC 3505 ქიმიური პროდუქტი წნევის ქვეშ, ადვილაალებადი, კოროზიული, N.O.S. 194 195 ადსორბირებული აირები კლასიფიკაციის გაეროს კოდი № 9A 3511 9O 3513 9F 3510 9T 3512 9 TF 3514 9 TC 3516 9 TO 3515 9 TFC 3517 9 TOC 3518 ნივთიერებისა თუ ნაკეთობის დასახელება ადსორბირებული აირი, N.O.S. ადსორბირებული აირი, მჟანგავი, N.O.S. ადსორბირებული აირი, ადვილაალებადი N.O.S. ადსორბირებული აირი, ტოქსიკური, N.O.S. ადსორბირებული აირი, ტოქსიკური, ადვილაალებადი, N.O.S. ადსორბირებული აირი, ტოქსიკური, კოროზიული, N.O.S. ადსორბირებული აირი, ტოქსიკური, მჟანგავი, N.O.S. ადსორბირებული აირი, ტოქსიკური, ადვილაალებადი, კოროზიული, N.O.S. ადსორბირებული აირი, ტოქსიკური, მჟანგავი, კოროზიული, N.O.S. 196 2.2.3 კლასი 3 ადვილაალებადი სითხეები 2.2.3.1 კრიტერიუმები 2.2.3.1.1 მე-3 კლასის დასახელებაში შედის აღნიშნულ კლასში გათვალისწინებული ნივთიერებების შემცველი ნივთიერებები და ნაკეთობები, რომლებიც: - არის თხევადი, 1.2.1 პუნქტში „სითხეებთან“ დაკავშირებული განმარტების (ა) ქვეპუნქტის შესაბამისად; - რომლის ორთქლის წნევა 500C ტემპერატურაზე არ აღემატება 300 მპა-ს (3 ბარს), არ არის სრულად აიროვანი 200C ტემპერატურაზე და 101.3 კპა სტანდარტულ წნევაზე; - გააჩნია არაუმეტეს 600C აფეთქების ტემპერატურა (იხილეთ ქვეპუნქტი 2.3.3.1 შესაბამის გამოცდასთან დაკავშირებით). მე-3 კლასის დასახელებაში აგრეთვე შედის ის თხევადი ნივთიერებები და მდნარ მდგომარეობაში წარმოდგენილი მყარი ნივთიერებები, რომელთა აფეთქების ტემპერატურაც არ აღემატება 600C-ს და რომელთა გადაზიდვაც ან გადაზიდვისთვის გადაცემაც ხორციელდება იმ ტემპერატურაზე, რომელიც თანაბარია ან მაღალია მათი აფეთქების ტემპერატურაზე. აღნიშნულ ნივთიერებებს მიენიჭათ გაეროს #3256. მე-3 კლასის დასახელებაში ასევე შედის თხევადი დესენსიბილიზებული ფეთქებადი ნივთიერებები. თხევადი ფეთქებადი ნივთიერებები წარმოადგენს ნივთიერებებს, რომლებიც იხსნება ან სუსპენზირებს წყალსა თუ სხვა თხევად ნივთიერებებში, ერთგვარი თხევადი ნარევის ფორმირებისთვის მათი ფეთქებადი თვისებების ჩახშობის მიზნით. 3.2 თავის A ცხრილში აღნიშნულ პოზიციებს მინიჭებული აქვთ გაეროს #1204, 2059, 3064, 3343, 3357 და 3379. შენიშვნა 1: არატოქსიკური და არაკოროზიული ნივთიერებები, რომელთაც გააჩნია 350Cზე მაღალი აფეთქების ტემპერატურა და რომლებიც არ უწყობს ხელს წვას ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 32.2.5 პუნქტით გათვალისწინებული კრიტერიუმების შესაბამისად, არ წარმოადგენს მე-3 კლასით გათვალისწინებულ ნივთიერებებს; თუმცა თუ აღნიშნული ნივთიერებების გადასაზიდად გადაცემა და გადაზიდვა ხორციელდება გახურებულ მდგომარეობაში მათი აფეთქების ტემპერატურის ტოლ ან უფრო მაღალ ტემპერატურაზე, მაშინ ისინი უნდა მიეკუთვნოს მე-3 კლასს. შენიშვნა 2: ზემოაღნიშნული 2.2.3.1.1 ქვეპუნქტიდან გადახვევის შემთხვევაში, დიზელის საწვავი, გაზოილი, სათბობი ზეთი (მსუბუქი), რომელთაც გააჩნიათ 600C-ზე მაღალი, თუმცა 1000C-ზე დაბალი აფეთქების ტემპერატურა, ჩაითვლება მე-3 კლასში შემავალ ნივთიერებებად, გაეროს #1202. შენიშვნა 3: ადვილაალებადი სითხეები, რომლებიც ხასიათდება 2.2.61.1.4-2.2.61.1.9 ქვეპუნქტებით განსაზღვრული მაღალი საინჰალაციო ტოქსიკურობით და გააჩნიათ 230C ან უფრო მაღალი აფეთქების ტემპერატურა, წარმოადგენს 6.1 კლასის ნივთიერებებს (იხილეთ 2.2.61.1 პუნქტი). სითხეები, რომლებიც ხასიათდება მაღალი საინჰალაციო ტოქსიკურობით, განსაზღვრულია როგორც „ტოქსიკური ინჰალაციის შემთხვევაში“ მათი შესაბამის გადაზიდვის დასახელებაში (2) სვეტში ან 3.2 თავის A ცხრილის (6) სვეტის 354-ე სპეციალური დებულებით. 197 შენიშვნა 4: პესტიციდების სახით გამოყენებული ადვილაალებადი თხევადი ნივთიერებები და პრეპარატები, რომლებიც წარმოადგენს ძლიერტოქსიკურს, ტოქსიკურს ან მსუბუქად ტოქსიკურს და გააჩნია 230C-ის ტოლი ან უფრო მაღალი აფეთქების ტემპერატურა, წარმოადგენს 6.1 კლასის ნივთიერებებს (იხილეთ 2.2.61.1 პუნქტი). 2.2.3.1.2 მე-3 კლასით გათვალისწინებული ნივთიერებები და ნაკეთობები იყოფა შემდეგი სახით: F ადვილაალებადი სითხეები დამატებითი საშიშროების გარეშე: F1 600C-ის ტოლი ან უფრო ნაკლები აფეთქების ტემპარტურის მქონე ადვილაალებადი სითხეები; F2 600C-ზე მაღალი აფეთქების ტემპერატურის მქონე ადვილაალებადი სითხეები, რომელთა გადაზიდვაც ან გადაზიდვებისთვის გადაცემაც ხორციელდება იმ ტემპერატურაზე, რომელიც ტოლია ან აღემატება მათი აფეთქების ტემპერატურას (ნივთიერებები მომატებულ ტემპერატურაზე); F3 ადვილაალებადი სითხეების შემცველი ნაკეთობები; FT ადვილაალებადი სითხეები, ტოქსიკური: 2.2.3.1.3 FT1 ადვილაალებადი სითხეები, ტოქსიკური; FT2 პესტიციდები; FC ადვილაალებადი სითხეები, კოროზიული; FTC ადვილაალებადი სითხეები, ტოქსიკური, კოროზიული; D თხევადი, დესენსიბილიზებული ფეთქებადი ნივთიერებები. მე-3 კლასში კლასიფიცირებული ნივთიერებებისა და ნაკეთობების ჩამონათვალი წარმოდგენილია 3.2 თავის A ცხრილში. ის ნივთიერებები, რომლებიც დასახელებით არ არის მითითებული 3.2 თავის A ცხრილში, უნდა მიეკუთვნოს 2.2.3.3 პუნქტის შესაბამის პოზიციასა და შესაბამის შეფუთვის ჯგუფს წინამდებარე პუნქტის დებულებების თანახმად. ადვილაალებადი სითხეები უნდა მიეკუთვნოს შემდეგი შეფუთვის ჯგუფებიდან ერთ-ერთს იმ საშიშროების ხარისხის მიხედვით, რომელთაც ისინი წარმოადგენს გადაზიდვების დროს: ა შეფუთვის ჯგუფი აფეთქების ტემპერატურა საწყისი დუღილის ტემპერატურა I -- < 350C IIა < 230C >350C IIIა >230C <600C >350C იხილეთ აგრეთვე 2.2.3.1.4 ქვეპუნქტი. (ა) დამატებით რისკ(ებ)თან დაკავშირებული სითხეების შემთხვევაში, მხედველობაში უნდა იქნეს მიღებული შეფუთვის ჯგუფი დამატებითი რისკ(ებ)ის სიმძიმის მიხედვით; შესაბამისად კლასიფიკაცია და შეფუთვის ჯგუფი განისაზღვრება 2.1.3.10 პუნქტში გათვალისწინებული საშიშროებების პრიორიტეტების ცხრილის მიხედვით. 198 2.2.3.1.4 ბლანტი ადვილაალებადი სითხეები, როგორიცაა საღებავები, ემალი, ლაქი, ოლიფა, წებო და საპრიალებელი მასალა, რომლისთვსიაც დამახასიათებელია არანაკლებ 230C აფეთქების ტემპერატურა, შესაძლებელია წარმოდგენილი ქნას III შეფუთვის ჯგუფში ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 32.3 ქვეპუნქტით გათვალისწინებული პროცედურების შესაბამისად იმ პირობით, თუ: (ბ) სიბლანტე2 და აფეთქების წარმოდგენილ მაჩვენებლებს: ტემპერატურა შეესაბამება შემდეგ ცხრილში კინემატიკური სიბლანტე (ექსტრაპოლირებული) ν (ნულთან მიახლოებული დაძვრის სიჩქარეზე) მმ2/წმ 230C-ზე დინების ჭავლის აფეთქების ტემპერატურა სიჩქარე t დიამეტრი წამებში (მმ) 20 < ν < 80 20 < t < 60 4 17-ზე მაღალი 80 < ν < 135 60 < t < 100 4 10-ზე მაღალი 135 < ν < 220 20 < t < 32 6 5-ზე მაღალი 220 < ν < 300 32 < t < 44 6 -1-ზე მაღალი 300 < ν < 700 44 < t < 100 6 -5-ზე მაღალი 700 < ν 100 < t 6 -5 და დაბალი C-ში 0 (ბ) სუფთა გამხსნელის მაცალკევებელი შრის 3%-ზე ნაკლები გამოიყოფა გამხსნელის გამოყოფაზე ჩატარებულ ცდაში; (გ) ნარევი ან ნებისმიერი გამოყოფილი გამხსნელი არ აკმაყოფილებს 6.1 კლასით ან მე-8 კლასით გათვალისწინებულ კრიტერიუმებს; (დ) ნივთიერებები შეფუთულია არაუმეტეს 450 ლიტრის ტევადობის ჭურჭლებში. შენიშვნა: წინამდებარე დებულებები არ ვრცელდება იმ ნარევებზე, რომლებიც შეიცავს არაუმეტეს 20% ნიტროცელულოზას, რომლის აზოტის შემცველობაც არ აღემატება 12.6%-ს, მშრალი ნივთიერების მასის მიხედვით. ნარევები, რომლებიც შეიცავს 20%-ზე მეტ, მაგრამ 55%-ზე ნაკლებ ნიტროცელულოზას, რომლის აზოტის შემცველობაც არ აღემატება 12.6%-ს, მშრალი ნივთიერების მასის მიხედვით, წარმოადგენს გაეროს #2059 მიკუთვნებულ ნივთიერებებს. სიბლანტის განმარტება: იმ შემთხვევებში, როდესაც წარმოდგენილი ნივთიერება არ ექვემდებარება დადგენილ წესებს, ან როდესაც სიბლანტის განმარტებისას არ არის ხელსაყრელი დინების ძაბრის მეთოდის გამოყენება, ნივთიერების დინამიკური სიბლანტის კოეფიციენტის განსაზღვრის მიზნით გამოყენებულ უნდა იქნეს დაძვრის გარდამავალი სიჩქარის მქონე ვისკოზიმეტრი 230C ტემპერატურაზე, დაძვრის სხვადასხვა სიჩქარეებზე. მიღებული მნიშვნელობებით შედგება ცხრილი დაძვრის სიჩქარესთან დაკავშირებით, რის შემდეგაც ადგილი აქვს ექსტრაპოლირებას ნულოვანი დაძვრის სიჩქარეზე. აღნიშნულის შედეგად მიიღება დინამიკური სიბლანტე, რაც იყოფა სიმკვრივეების მიხედვით და წარმოადგენს აშკარა კინემატიკურ სიბლანტეს თითქმის ნულოვანი დაძვრის სიჩქარეზე. 2 199 ნარევები, რომელთა აფეთქების ტემპერატურა არ აღემატება 230C-ს და შეიცავს: - 55%-ზე მეტ ნიტროცელულოზას, მიუხედავად მათი აზოტის შემცველობისა; ან - არაუმეტეს 55% ნიტროცელულოზას, რომლის აზოტის შემცველობაც არ აღემატება 12.6%-ს, მშრალი ნივთიერების მასის მიხედვით. წარმოადგენს პირველი კლასის ნივთიერებებს (გაეროს #0340 ან 0342) ან 4.1 კლასის ნივთიერებებს (გაეროს #2555, 2556 ან 2557). 2.2.3.1.5 ბლანტი სითხეები: - რომლებსაც ახასიათებთ 230C ან მეტი აფეთქების ტემპერატურა და 600C-ზე ნაკლები ან ტოლი აფეთქების ტემპერატურა; - არ არის ტოქსიკური, კოროზიული ან გარემოსთვის სახიფათო; - შეიცავს არაუმეტეს 20% ნიტროცელულოზას იმ პირობით, თუ ნიტროცელულოზა შეიცავს არაუმეტეს 12.6% აზოტს მშრალი ნივთიერების მასის მიხედვით; და - შეფუთულია არაუმეტეს 450 ლიტრ მოცულობის შეფუთვაში. არ ექვემდებარება ADR-ით გათვალისწინებულ პირობებს იმ შემთხვევაში, თუ: 2.2.3.1.6 - ხსნარის გამოყოფაზე ჩატარებულ ცდაში (იხილეთ ცდებისა და კრიტერიუმების სახელმძღვალოს III ნაწილის 32.5.1 ქვეპუნქტი), ხსნარის გამოყოფილი შრის სიმაღლე ნაკლებია მთლიანი სიმაღლის 3%-ზე; და - დინების სიჩქარე სიბლანტის ცდაში (იხილეთ ცდებისა და კრიტერიუმების სახელმძღვალოს III ნაწილის 35.4.3 ქვეპუნქტი), რა შემთხევვაშიც ჭავლი დიამეტრი შეადგენს 6 მმ-ს, ტოლია ან მეტია (ა) 60 წამზე; ან (ბ) 40 წამზე, თუ ბლანტი სითხე შეიცავს მე-3 კლასით გათვალისწინებული ნივთიერებების არაუმეტეს 60%-ს. იმ შემთხვევაში, თუ დანამატების შეტანის შედეგად, მე-3 კლასით გათვალისწინებული ნივთიერებები მოხვდება რისკის იმ კატეგორიაში, რომლებიც განსხვავდება 3.2 თავის A ცხრილში დასახელებით მითითებული ნივთიერებების კატეგორიისგან, აღნიშნული ნარევები ან ხსნარები განეკუთვნება იმ პოზიციებს, რომელზეც ხდება მათი კლასიფიცირება მათი საშიშროების ფაქტიური დონის მიხედვით. შენიშვნა: ხსნარებისა და ნარევების კლასიფიკაციასთან დაკავშირებით (როგორიცაა პრეპარატები და ნარჩენები), იხილეთ აგრეთვე 2.1.3 პუნქტი. 2.2.3.1.7 2.3.3.1 და 2.3.4 პუნქტებში გათვალისწინებული საცდელი პროცედურების, ასევე 2.2.3.1.1 ქვეპუნქტში მოყვანილი კრიტერიუმების საფუძველზე, შესაძლებელია ასევე განისაზღვროს ის ფაქტი, არის თუ არა დასახელებით მითითებული ხსნარისა თუ ნარევის არსი იმ სახის ან შეიცავს თუ არა ისეთ დასახელებით მითითებულ ნივთიერებას, რომ აღნიშნული ხსნარი ან ნარევი არ დაექვემდებაროს მოცემული კლასით გათვალისწინებულ მოქმედ დებულებებს (იხილეთ აგრეთვე 2.1.3 პუნქტი). 200 2.2.3.2 ნივთიერებები, რომლებიც არ დაიშვება გადაზიდვებზე 2.2.3.2.1 მე-3 კლასით გათვალისწინებული ნივთიერებები, რომლებიც უზრუნველყოფს პეროქსიდების ადვილად წარმოქმნას (როგორც ეს ხდება ეთერებისა თუ გარკვეული ჰეტეროციკლური ჟანგბადის შემცველი ნივთიერებების შემთხვევაში), არ დაიშვება გადაზიდვებზე, თუ მათი პეროქსიდის შემცველობა, რომელიც გამოითვლება წყალბადის პეროქსიდის სახით (H2O2), აღემატება 0.3%-ს. პეროქსიდის შემცველობა განისაზღვრება 2.3.3.3 პუნქტის შესაბამისად. 2.2.3.2.2 მე-3 კლასით გათვალისწინებული, ქიმიურად არასტაბილური ნივთიერებები არ დაიშვება გადაზიდვებზე, სანამ არ მოხდება შესაბამისი ზომების მიღება გადაზიდვების დროს მათი სახიფათო დაშლისა თუ პოლიმერიზაციის პრევენციის მიზნით. აღნიშნულიდან გამომდინარე, უნდა მოხდეს იმ ფაქტის უზრუნველყოფა, რომ ჭურჭელი და ცისტერნები არ შეიცავდეს ზემოაღნიშნული რეაქციების გამომწვევ რაიმე ნივთიერებას. 2.2.3.2.3 გადაზიდვებზე არ დაიშვება თხევადი დესენსიბილიზებული ფეთქებადი ნივთიერებები, რომლებიც წარმოდგენილია მე-3 კლასის ნივთიერებების სახით, გარდა 3.2 თავის A ცხრილში მითითებული ნივთიერებებისა. 201 2.2.3.3 ერთობლივი პოზიციების ჩამონათვალი ადვილაალებადი სითხეები 1133 1136 1139 F1 1169 1197 1210 1210 1263 1263 1266 1293 1306 1866 1999 3065 1224 1268 1268 1987 1989 3271 3272 3295 3336 3336 1993 დამატებითი რისკის გარეშე F მომატებულ F2 3256 სითხეები მომატებულ ტემპერატურაზე, თხევადი, ადვილაალებადი N.O.S. 600C-ზე მაღალი აფეთქების ტემპერატურით, რომლის გადაზიდვაც ხდება მისი აფეთქების ტემპერატურის თანაბარ ან უფრო მაღალ ტემპერატურაზე F3 3269 3473 3473 3473 პოლიეთერის ფისის კომპლექტი საწვავი ელემენტის ბალონები ან აღჭურვილობაში წარმოდგენილი საწვავი ელემენტის ბალონები ან აღჭურვილობასთან ერთად შეფუთული საწვავი ელემენტის ბალონები ტემპერატურაზე ნაკეთობები ადვილაალებადი სითხის შემცველი წებო ქვანახშირის დისტილატები, ადვილაალებადი შემომგარსველი ხსნარები (შეიცავს ზედაპირების დამუშავებისა თუ დაფარვისთვის განკუთვნილ ხსნარებს, რომლებიც გამოიყენება სამრეწველო ან სხვა მიზნებისთვის, როგორიცაა ავტოსატრანსპორტო საშუალებების, დოლურებისა თუ ლილვების ამოსაგებად განკუთვნილი დაგრუნტვა) არომატიზებული, თხევადი ექსტრაქტები არომატული თხევადი ექსტრაქტები საბეჭდი მელანი, ადვილაალებადი ან საბეჭდ მელანთან დაკავშირებით გამოსაყენებელი მასალა (რაც მოიცავს საბეჭდი მელნის გამხსნელ ან გასაზავებელ ნარევს), ადვილაალებადი საღებავი (რაც მოიცავს საღებავს, ლაქს, ემალს, საღებავ ნივთიერებას, შელაკს, გასალაქ, მოსაპრიალებელ მასალას, თხევად შემავსებელსა და თხევადი ლაქის ბაზას) ან შესაღები მასალა (რაც მოიცავს საღებავის გამხსნელ ან გასაზავებელ ნარევს) პარფიუმერული პროდუქცია ადვილაალებადი გამხსნელებით ნაყენები, სამედიცინო ხის დამცავები, თხევადი ფისის ხსნარი, ადვილაალებადი გუდრონები, თხევადი, თხევადი ბითუმი და გათხევადებული ბითუმების ჩათვლით ალკოჰოლური სასმელები თხევადი კეტონები, N.O.S. ნავთობის დისტილატები, N.O.S. ან ნავთობპროდუქტები, N.O.S. სპირტები, N.O.S. ალდეჰიდები, N.O.S. ტერფენის ნახშირბადები, N.O.S. ეთერები, N.O.S. ნახშირწყალბადები, თხევადი, N.O.S. მერკაპტანი, თხევადი, ადვილაალებადი, N.O.S., ან მერკაპტანის ნარევი, თხევადი, ადვილაალებადი, N.O.S. ადვილაალებადი სითხეები, N.O.S. (გაგრძელება იხილეთ მომდევნო გვერდზე) 202 2.2.3.3 ერთობლივი პოზიციების ჩამონათვალი (გაგრძელება) FT1 ტოქსიკური FT FT2 პესტიციდი (f.p<230C) 1228 1228 1286 1988 2478 2478 3248 3273 1992 მერკაპტანები, თხევადი, ადვილაალებადი, ტოქსიკური, N.O.S., ან მერკაპტანის ნარევი, თხევადი, ადვილაალებადი, ტოქსიკური, N.O.S. სპირტები, ადვილაალებადი, ტოქსიკური, N.O.S. ალდეჰიდები, ადვილაალებადი, ტოქსიკური, N.O.S. იზოციანატები, ადვილაალებადი, ტოქსიკური, N.O.S., ან იზოციანატის ხსნარი, ადვილაალებადი, ტოქსიკური, N.O.S. სამკურნალო პრეპარატი, თხევადი ადვილაალებადი, ტოქსიკური, N.O.S. ნიტრილები, ადვილაალებადი, ტოქსიკური, N.O.S. ადვილაალებადი სითხე, ტოქსიკური, N.O.S. 2758 2760 2762 2764 2772 2776 2778 2780 2782 2784 2787 3024 3346 3350 3021 კარბამატის პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური დარიშხანის პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური ქლორორგანული პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური ტრიაზინის პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური დითიოკარბამატის პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური სპილენძის შემცველი პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური ვერცხლისწყლის შემცველი პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური შემცვლელი ნიტროფენოლის პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური დიპირიდილის პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური ფოსფორორგანული პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური კალაორგანული პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური კუმარინის წარმოებული პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური ფენოქსიძმარმჟავას წარმოებული პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური პირეთროიდული პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური პესტიციდი, თხევადი, ადვილაალებადი, ტოქსიკური, N.O.S. შენიშვნა: პესტიციდების კლასიფიკაცია ერთ-ერთ პოზიციაზე უნდა განხორციელდეს აქტიური კომპონენტის, პესტიციდის ფიზიკური მდგომარეობისა და იმ ნებისმიერი დამატებითი რისკის საფუძველზე, რომელიც შეიძლება გამოიწვიოს 3469 2733 2733 2985 3274 2924 საღებავი, ადვილაალებადი, კოროზიული (რაც მოიცავს საღებავს, ლაქს, ემალს, საღებავ ნივთიერებას, შელაკს, გასალაქ, მოსაპრიალებელ მასალას, თხევად შემავსებელსა და თხევადი ლაქის ბაზას) ან შესაღები მასალა, ადვილაალებადი, კოროზიული (რაც მოიცავს საღებავის გამხსნელ ან შემამცირებელ ნარევს) ამინები, ადვილაალებადი, კოროზიული, N.O.S., ან პოლიამინები, ადვილაალებადი, კოროზიული, N.O.S. ქლორსილანები, ადვილაალებადი, კოროზიული, N.O.S. ალკოჰოლატის ხსნარი, N.O.S., სპირტში ადვილაალებადი სითხე, კოროზიული, N.O.S. 3286 ადვილაალებადი სითხე, ტოქსიკური, კოროზიული, N.O.S. 3343 ნიტროგლიცერინის ნარევი, დესენსიბილიზებული, თხევადი, ადვილაალებადი, N.O.S. გლიცერინის არაუმეტეს 30% მასური წილით ნიტროგლიცერინის ნარევი, დესენსიბილიზებული, თხევადი, N.O.S. გლიცერინის არაუმეტეს 30% მასური წილით დესენსიბილიზებული ფეთქებადი ნივთიერება, თხევადი, N.O.S. კოროზიული 3469 FC ტოქსიკური, კოროზიული თხევადი დესენსიბილიზებული ფეთქებადი ნივთიერება FTC 3357 D 3376 203 2.2.41 კლასი 4.1 ადვილაალებადი მყარი ნივთიერებები, თვითრეაქტიული ნივთიერებები და მყარი დესენსიბილიზებული ფეთქებადი ნივთიერებები 2.2.41.1 კრიტერიუმები 2.2.41.1.1 4.1 კლასის დასახელებაში შედის ადვილაალებადი ნივთიერებები და ნაკეთობები, დესენსიბილიზებული ფეთქებადი ნივთიერებები, რომლებიც წარმოადგენს მყარ ნივთიერებებს 1.2.1 პუნქტში მოცემული „მყარი ნივთიერების“ განმარტების (ა) ქვეპუნქტის შესაბამისად და თვითრეაქტიულ თხევად ან მყარ ნივთიერებებს. შემდეგი ნივთიერებები განეკუთვნება 4.1 კლასს: 2.2.41.1.2 - ადვილაალებადი მყარი ნივთიერებები და ნაკეთობები (იხილეთ პუნქტები 2.2.41.1.3-დან 2.2.41.1.8-მდე); - თვითრეაქტიული მყარი ნივთიერებები ან ნაკეთობები (იხილეთ პუნქტები 2.2.41.1.9-დან 2.2.41.1.17-მდე); - მყარი დესენსიბილიზებული ფეთქებადი ნივთიერებები (იხილეთ პუნქტი 2.2.41.1.18); - თვითრეაქტიულ ნივთიერებებთან დაკავშირებული ნივთიერებები (იხილეთ პუნქტი 2.2.41.1.19). 4.1 კლასის ნივთიერებები და ნაკეთობები იყოფა შემდეგნაირად: F ადვილაალებადი მყარი ნივთიერებები, დამატებითი რისკის გარეშე: F1 F2 F3 ორგანული; ორგანული, მდნარი; არაორგანული; FO ადვილაალებადი მყარი ნივთიერებები, მჟანგავი; FT ადვილაალებადი მყარი ნივთიერებები, ტოქსიკური: FT1 FT2 FC ორგანული, ტოქსიკური; არაორგანული, ტოქსიკური; ადვილაალებადი მყარი ნივთიერებები, კოროზიული: FC1 FC2 ორგანული, კოროზიული; არაორგანული, კოროზიული; D მყარი, დესენსიბილიზებული ფეთქებადი ნივთიერებები, დამატებითი რისკის გარეშე; DT მყარი, დესენსიბილიზებული ფეთქებადი ნივთიერებები, ტოქსიკური; SR თვითრეაქტიული ნივთიერებები: SR1 SR2 არ საჭიროებს ტემპერატურის დარეგულირებას; საჭიროებს ტემპერატურის რეგულირებას. 204 ადვილაალებადი მყარი ნივთიერებები განმარტება და თვისებები 2.2.41.1.3 ადვილაალებადი მყარი ნივთიერებები წარმოადგენს ადვილად წვად მყარ ნივთიერებებსა და იმ მყარ ნივთიერებებს, რომელთაც შეუძლიათ გამოიწვიონ ხანძარი ხახუნის შედეგად. ადვილად წვადი მყარი ნივთიერებები წარმოადგენს ფხვიერ, გრანულირებულ ან ბლანტ ნივთიერებებს, რომლებიც ითვლება სახიფათოდ იმ შემთხვევაში, თუ მათ შეუძლიათ ადვილადაალება აალების წყაროსთან ხანმოკლე კონტაქტისას, როგორიცაა ანთებული ასანთი და იმ შემთხვევაში, თუ ალი სწრაფად ვრცელდება. საშიშროება შესაძლებელია წარმოიშვას არა მხოლოდ ხანძრისგან, არამედ აგრეთვე ტოქსიკური წვის პროდუქტებისგან. განსაკუთრებით სახიფათოა ლითონის ფხვნილები ხანძრის ჩაქრობის სირთულის გამო მაშინ, როდესაც ჩვეულებრივმა ცეცხლმაქრმა საშუალებებმა, როგორიცაა ნახშირორჟანგი ან წყალი, შესაძლებელია გაზარდოს საშიშროება. კლასიფიკაცია 2.2.41.1.4 3.2 თავის A ცხრილში მოცემულია 4.1 კლასის ადვილაალებადი მყარი ნივთიერებების სახით კლასიფიცირებული ნივთიერებები და ნაკეთობები. იმ ორგანული ნივთიერებებისა და ნაკეთობების, რომლებიც არ არის მოხსენებული 3.2 თავის A ცხრილში დასახელებით, მიკუთვნება 2.2.41.3 ქვეპუნქტის შესაბამის პოზიციას 2.1 თავით გათვალისწინებული დებულებების შესაბამისად, შესაძლებელია დაეფუძნოს არსებულ გამოცდილებას ან საცდელი პროცედურების შედეგებს ცდებისა და კრიტერიუმების სახელმძღვანელოს 33.2.1 პუნქტის III ნაწილის თანახმად. იმ არაორგანული ნივთიერებების მიკუთვნება, რომლებიც არ არის მოხსენებული დასახელებით, უნდა დაეფუძნოს საცდელი პროცედურების შედეგებს ცდებისა და კრიტერიუმების სახელმძღვანელოს 33.2.1 პუნქტის III ნაწილის თანახმად; ასევე მხედველობაში უნდა იქნეს მიღებული გამოცდილება, რაც უზრუნველყოფს კიდევ უფრო მკაცრ კლასიფიკაციას. 2.2.41.1.5 იმ შემთხვევაში, თუ ნივთიერებები, რომლებიც არ არის მითითებული დასახელებით, მიეკუთვნება 2.2.41.3 ქვეპუნქტში წარმოდგენილი პოზიციებიდან ერთ-ერთს საცდელი პროცედურების საფუძველზე ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.2.1 ქვეპუნქტის შესაბამისად, გამოიყენება შემდეგი კრიტერიუმები: (ა) ლითონის ფხვნილებისა თუ ლითონის შენადნობების გარდა, ფხვნილისებრი, გრანულირებული ან ბლანტი ნივთიერებების ფხვნილები კლასიფიცირდება, როგორც 4.1 კლასის ადვილაალებადი ნივთიერებები, იმ შემთხვევაში, თუ ისინი შესაძლებელია აალდეს ადვილაალების წყაროსთან (მაგალითად, ანთებულ ასანთთან) ხანმოკლე შეხებისას ან თუ, აალების შემთხვევაში, ალი გავრცელდება სწრაფად, წვის დრო 45 წამზე ნაკლებია 10 მმ გაანგარიშებულ მანძილზე ან წვის სისწრაფე აღემატება 2.2 მმ/წმ-ს; (ბ) ლითონის ფხვნილები ან 4.1 კლასში კლასიფიცირებული ლითონის შენადნობების ფხვნილები იმ შემთხვევაში, თუ ისინი შეიძლება აალდეს ალით და რეაქცია გავრცელდეს ნიმუშის მთელ სიგრძეზე 10 წუთში ან უფრო ნაკლებ პერიოდში. 205 მყარი ნივთიერებები, რომელთაც შეუძლია ხანძრის წარმოშობა ხახუნის შედეგად, კლასიფიცირდება 4.1 პუნქტში არსებულ პოზიციებთან ანალოგიით (მაგალითად, ასანთები) ან ნებისმიერი შესაბამისი სპეციალური დებულების თანახმად. 2.2.41.1.6 ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.2.1 პუნქტისა და 2.2.41.1.4 და 2.2.41.1.5 ქვეპუნქტებში გათვალისწინებული კრიტერიუმების შესაბამისად საცდელი პროცედურის საფუძველზე, შესაძლებელია აგრეთვე განისაზღვროს, არის თუ არა დასახელებით მითითებული ნივთიერების ხასიათი იმგვარი, რომ ნივთიერება არ დაექვემდებაროს აღნიშნულ კლასთან დაკავშირებით მოქმედ დებულებებს. 2.2.41.1.7 იმ შემთხვევაში, თუ 4.1 კლასში შემავალი ნივთიერებები, მასში შეტანილი დანამატების შედეგად, მიეკუთვნება რისკების სხვადასხვა კატეგორიებს, რომელთაც მიეკუთვნება 3.2 თავის A ცხრილში სახელწოდებით მითითებული ნივთიერებები, აღნიშნული ნარევები კლასიფიცირდება იმ პოზიციებზე, რომელთა მიმართაც ხდება მათი მიკუთვნება მათი საშიშროების რეალური დონის მიხედვით. შენიშვნა: ხსნარებისა და ნარევების (როგორიცაა პრეპარატები და ნარჩენები) კლასიფიკაციისთვის იხილეთ აგრეთვე 2.1.3 პუნქტი. მიკუთვნება შეფუთვის ჯგუფებზე 2.2.41.1.8 3.2. თავის A ცხრილის სხვადასხვა პოზიციებზე კლასიფიცირებული ადვილაალებადი მყარი ნივთიერებები მიეკუთვნება II ან III შეფუთვის ჯგუფებს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.2.1 ქვეპუნქტში გათვალისწინებული პროცედურების საფუძველზე, შემდეგი კრიტერიუმების თანახმად: (ა) ადვილაალებადი მყარი ნივთიერებები, რომელთა წვის დრო ცდის ჩატარებისას შეადგენს 45 წამზე ნაკლებს 100 მმ გაანგარიშებულ მანძილზე, შესაძლებელია განეკუთვნოს: II შეფუთვის ჯგუფს: იმ შემთხვევაში, თუ ალი გადავა დასველებულ ზონაზე; III შეფუთვის ჯგუფს: იმ შემთხვევაში, თუ დასველებული ზონა შეაჩერებს ალს მინიმუმ ოთხი წუთით; (ბ) ლითონის ფხვნილები ან ლითონის შენადნობების ფხვნილები მიეკუთვნება: II შეფუთვის ჯგუფს: იმ შემთხვევაში, თუ ცდის ჩატარებისას, რეაქცია გავრცელდება ნიმუშის მთელ სიგრძეზე ხუთ წუთში ან უფრო ნაკლებ დროში; III შეფუთვის ჯგუფს: ცდის ჩატარებისას, რეაქცია ვრცელდება ნიმუშის მთელ სიგრძეზე ხუთ წუთზე მეტ ხანს. მყარი ნივთიერებების შემთხვევაში, რომელმაც შეიძლება გამოიწვიოს ხანძარი ხახუნის შედეგად, შეფუთვის ჯგუფი შესაძლებელია კლასიფიცირდეს ანალოგიურად არსებულ პოზიციებზე ან ნებისმიერი სახის სპეციალური დებულების შესაბამისად. თვითრეაქტიული ნივთიერებები განმარტებები 2.2.41.1.9 ADR-ის მიზნებიდან გამომდინარე, თვითრეაქტიული ნივთიერებები წარმოადგენს თერმულად არასტაბილურ ნივთიერებებს, რომლებიც ექვემდებარება მძლავრ 206 ეგზოთერმულ დაშლას ჟანგბადის (ჰაერის) მონაწილეობის გარეშეც კი. ნივთიერებები არ ჩაითვლება 4.1 კლასის თვითრეაქტიულ ნივთიერებებად იმ შემთხვევაში, თუ: (ა) ისინი წარმოადგენს ფეთქებადს პირველი კლასის კრიტერიუმების შესაბამისად; (ბ) ისინი წარმოადგენს მჟანგავ ნივთიერებებს 5.1 კლასის კლასიფიკაციის პროცედურების შესაბამისად (იხილეთ 2.2.51.1 პუნქტი), გარდა იმ მჟანგავი ნივთიერებების ნარევებისა, რომლებიც შეიცავს 5% ან უფრო მეტ წვად ორგანულ ნივთიერებებს და ექვემდებარება მე-2 შენიშვნაში განსაზღვრულ კლასიფიცირების პროცედურას; (გ) ისინი წარმოადგენს ორგანულ პეროქსიდებს 5.2 კლასის კრიტერიუმების თანახმად (იხილეთ 2.2.52.1 პუნქტი); (დ) მათი დაშლის სითბო ნაკლებია 300 ჯ/გ-ზე; ან (ე) მათი თვითაჩქარებული დაშლის ტემპერატურა (იხილეთ ქვემოთ მოყვანილი მე3 შენიშვნა) აღემატება 750C-ს 50 კგ შეფუთვაზე. შენიშვნა 1: დაშლის სითბო შესაძლებელია განისაზღვროს ნებისმიერი სახის საერთაშორისო დონეზე აღიარებული მეთოდის გამოყენებით, მაგალითად, დიფერენცირებული სკანირების კალორიმეტრისა და ადიაბეტური კალორიმეტრის გამოყენებით. შენიშვნა 2: მჟანგავი ნივთიერებების ნარევები, რომლებიც აკმაყოფილებს 5.1 კრიტერიუმს და შეიცავს 5% ან უფრო მეტ საწვავ ორგანულ ნივთიერებას, რომლებიც ვერ აკმაყოფილებს ზემოაღნიშნულ (ა), (გ), (დ) და (ე) ქვეპუნქტებში წარმოდგენილ კრიტერიუმებს, დაექვემდებარება თვითრეაქტიული ნივთიერების კლასიფიცირების პროცედურას. ნარევი, რომელიც ასახავს B ან F ტიპის თვითრეაქტიული ნივთიერების მახასიათებლებს, კლასიფიცირდება 4.1 კლასის თვითრეაქტიული ნივთიერების სახით. ნარევი, რომელიც ასახავს G ტიპის თვითრეაქტიული ნივთიერების მახასიათებლებს, განიხილება 5.1 კლასის ნივთერებების სახით კლასიფიკაციისთვის (იხილეთ 2.2.51.1 პუნქტი), ცდებისა და კრიტერიუმების სახელმძღვანელოს II ნაწილის 20.4.3 (ზ) ქვეპუნქტის თანახმად. შენიშვნა 3: თვითაჩქარებული დაშლის ტემპერატურა წარმოადგენს უმდაბლეს ტემპერატურას, რომელზეც შესაძლებელია თავი იჩინოს ტარაში წარმოდგენილი ნივთიერებების თვითაჩქარებულმა დაშლამ, გადაზიდვების დროს მათი გამოყენების შემთხვევაში. თვითაჩქარებული დაშლის ტემპერატურის განსაზღვრებასთან დაკავშირებული მოთხოვნები წარმოდგენილია ცდებისა და კრიტერიუმების სახელმძღვანელოს II ნაწილის მე-20 თავსა და 28.4 კარში. შენიშვნა 4: ნებისმიერი ნივთიერება, რომელიც ასახავს თვითრეაქტიული ნივთიერების მახასიათებლებს, კლასიფიცირდება აღნიშნული სახით იმ შემთხვევაშიც კი, თუ აღნიშნული ნივთიერებები იძლევა ცდის დადებით შედეგს 2.2.42.1.5 ქვეპუნქტის შესაბამისად 4.2 კლასში გათვალისწინებულ საგანთან დაკავშირებით. თვისებები 207 2.2.41.1.10 თვითრეაქტიული ნივთიერებების დაშლის ინიცირება შესაძლებელია მოახდინოს სითბომ, კონტაქტური აპარატის დაბინძურებასთან (მაგალითად, მჟავებთან, მძიმე ლითონის ნარევებთან, ბაზებთან) შეხებით, ხახუნითა თუ დარტყმით. დაშლის სიჩქარე იზრდება ტემპერატურის ზრდასთან ერთად და განსხვავებულია ნივთიერებების მიხედვით. დაშლამ, განსაკუთრებით იმ შემთხვევაში, თუ ადგილი არ აქვს აალებას, შეიძლება გამოიწვიოს ტოქსიკური აირების ან ორთქლის განვითარება. ცალკეულ თვითრეაქტიულ ნივთიერებებთან დაკავშირებით უნდა მოხდეს ტემპერატურის რეგულირება. ზოგიერთი თვითრეაქტიული ნივთიერება შესაძლებელია დაიშალოს აფეთქებით, განსაკუთრებით თუ ისინი მოთავსებულია დახურულ ჭურჭელში. აღნიშნული მახასიათებლის შეცვლა შესაძლებელია გასაზავებელი ნივთიერების დამატების გზით ან შესაბამისი ტარის გამოყენებით. გარკვეული თვითრეაქტიული ნივთიერებები იწვება ინტენსიურად. თვითრეაქტიულ ნივთიერებებში შედის, მაგალითად, ქვემოთ ჩამოთვლილი ტიპების ზოგიერთი ნარევი: ალიფატიკური აზონარევები (-C-N=N-C-); ორგანული აზიდები (-C-N3); დიაზონის მარილები (-CN2+Z-) N-ნიტროზონარევები (-N-N=O); და არომატული სულფოჰიდრაზიდები (-SO2-NH-NH2) აღნიშნული სია არ არის ამომწურავი და სხვა რეაქტიული ჯგუფებისა და ნივთიერებების ზოგიერთ ნარევს შესაძლებელია აღენიშნოთ მსგავსი თვისებები. კლასიფიკაცია 2.2.41.1.11 თვითრეაქტიული ნივთიერებები იყოფა შვიდ ტიპად მათ მიერ წარმოდგენილი საფრთხის ხარისხის მიხედვით. თვითრეაქტიული ნივთიერებების ტიპები იცვლება A ტიპიდან, რომელიც არ დაიშვება იმ ტარაში გადაზიდვაზე, რომელშიც განხორციელდა მისი გამოცდა, G ტიპამდე, რომელიც არ ექვემდებარება 4.1 კლასის თვითრეაქტიულ ნივთიერებებთან დაკავშირებით არსებულ დებულებებს. B-F ტიპების კლასიფიკაცია პირდაპირ კავშირშია ერთ ტარაში დაშვებულ მაქსიმალურ ოდენობასთან. პრინციპები, რომლებიც გამოიყენება კლასიფიკაციისთვის, ასევე მოქმედი კლასიფიკაციის პროცედურები, საცდელი მეთოდები და კრიტერიუმები, ასევე შესაბამისი ცდის ოქმის ნიმუში მოცემულია ცდებისა და კრიტერიუმების სახელმძღვანელოს II ნაწილში. 2.2.41.1.12 თვითრეაქტიული ნივთიერებები, რომელთა კლასიფიკაციაც უკვე განხორციელდა და უკვე დაშვებულია ტარაში გადაზიდვებზე, წარმოდგენილია 2.2.41.4 პუნქტში; თვითრეაქტიული ნივთიერებები, რომლებიც უკვე დაშვებულია გადაზიდვებზე მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერში, გათვალისწინებულია 4.1.4.2 პუნქტში, შეფუთვის ინსტრუქცია IBC20 და ცისტერნებში გადაზიდვაზე უკვე დაშვებული თვითრეაქტიული ნივთიერებები 4.2 თავის შესაბამისად, წარმოდგენილია 4.2.5.2 პუნქტში - ინსტრუქცია T23 გადამზიდ ცისნტერნებთან დაკავშირებით. ყოველი ზემოაღნიშნული, გადაზიდვებზე დაშვებული ნივთიერება მიეკუთვნება 3.2 თავის A ცხრილში გათვალისწინებულ გენერიულ პოზიციას (გაეროს №3221-დან 3240-მდე), ასევე წარმოდგენილია შესაბამისი დამატებითი რისკები და სატრანსპორტო ინფორმაციის შემცველი შენიშვნები. 208 ერთობლივი პოზიციები ითვალისწინებს შემდეგს: - B-F ტიპების თვითრეაქტიული ნივთიერებები, იხილეთ ზემოაღნიშნული 2.2.41.1.11 ქვეპუნქტი; - ფიზიკური მდგომარეობა (თხევადი/მყარი); და - ტემპერატურის რეგულირება (საჭიროების შემთხვევაში), იხილეთ ქვემოთ წარმოდგენილი 2.2.41.1.17 ქვეპუნქტი. 2.2.41.4 პუნქტში წარმოდგენილი თვითრეაქტიული ნივთიერებების კლასიფიკაცია ხორციელდება ტექნიკურად სუფთა ნივთიერების საფუძველზე (გარდა იმ შემთხვევებისა, როდესაც კონცენტრაცია ნაკლებია 100%-ზე). 2.2.41.1.13 თვითრეაქტიული ნივთიერებების კლასიფიკაცია, რომელიც არ არის წარმოდგენილი 2.2.41.4, 4.1.4.2 პუნქტებში წარმოდგენილ IBC520 შეფუთვის ინსტრუქციასა თუ 4.2.5.2 პუნქტში წარმოდგენილ TC23 ინსტრუქციაში გადამზიდ ცისტერნებთან დაკავშირებით და მიკუთვნება ერთობლივ პოზიციაზე ხორციელდება წარმოშობის ქვეყნის კომპეტენტური ორგანოს მიერ ცდების ოქმის საფუძველზე. ოფიციალური დასტურის შესახებ განცხადება უნდა შეიცავდეს კლასიფიკაციასა და გადაზიდვების შესაბამის პირობებს. იმ შემთხვევაში, თუ წარმოშობის ქვეყანა არ წარმოადგენს ADR-ის ხელშემკვრელ მხარეს, კლასიფიკაცია და გადაზიდვის პირობები აღიარებულ უნდა იქნეს გადაზიდვების მარშრუტზე ADR-ის პირველი ხელშემკვრელი მხარის კომპეტენტური ორგანოს მიერ. 2.2.41.1.14 ზოგიერთ თვითრეაქტიულ ნივთიერებას შესაძლებელია დაემატოს ისეთი გამააქტიურებელი ნივთიერებები, როგორიცაა თუთიის ნარევები, მათი რეაქტიულობის შეცვლის მიზნით. გამააქტიურებელი ნივთიერების როგორც ტიპის, ასევე კონცენტრაციის მიხედვით, აღნიშნულმა შესაძლებელია გამოიწვიოს თერმოსტაბილურობის დაქვეითება და ცვლილებები ფეთქებად თვისებებეში. რომელიმე აღნიშნული თვისების შეცვლის შემთხვევაში, ახალი შემადგენლობა შეფასდება კლასიფიკაციის პროცედურის შესაბამისად. 2.2.41.1.15 თვითრეაქტიული ნივთიერებების ნიმუშები ან თვითრეაქტიული ნივთიერებების შემადგენლობები, რომლებიც არ არის წარმოდგენილი 2.2.41.4 პუნქტში, რომელთან დაკავშირებითაც არ არის მითითებული ცდების შედეგების შესახებ სრული ინფორმაცია და რომელთა გადაზიდვაც უნდა მოხდეს შემდგომი ცდების ან შეფასებების განხორციელების მიზნით, განეკუთვნება C ტიპის თვითრეაქტიულ ნივთიერებებთან დაკავშირებით არსებული შესაბამისი პოზიციებიდან ერთ-ერთს, შემდეგი პირობების დაკმაყოფილების შემთხვევაში: - ხელთ არებული ინფორმაცია მიუთითებს, რომ ნიმუში არ შეიძლება იყოს უფრო სახიფათო, ვიდრე B ტიპის თვითრეაქტიული ნივთიერებებია; - ნიმუში შეფუთულია OP2 შეფუთვის მეთოდის შესაბამისად და რაოდენობა ყოველ სატრანსპორტო ერთეულზე შემოიფარგლება 10 კგ-ით; - ხელთ არსებული ინფორმაცია მიუთითებს, რომ საკონტროლო ტემპერატურა, ასეთის არსებობის შემთხვევაში, საკმარისად დაბალია ნებისმიერი სახის სახიფათო დაშლის პრევენციისათვის და საკმარისად მაღალია ნებისმიერი სახიფათო ფაზების გაყოფის პრევენციისთვის. 209 დესენსიბილიზაცია 2.2.41.1.16 გადაზიდვების დროს უსაფრთხოების უზრუნველყოფის მიზნით, თვითრეაქტიული ნივთიერებების დესენსიბილიზაცია ხშირ შემთხვევაში გამხსნელის გამოყენებით ხდება. იმ შემთხვევაში, თუ მითითებულია ნივთიერების პროცენტული შემცველობა, აღნიშნული გულისხმობს ნივთიერების პროცენტულ შემცველობას მასის მიხედვით, დამრგვალებულს უახლოეს მთლიან ციფრამდე. გამხსნელის გამოყენების შემთხვევაში, თვითრეაქტიული ნივთიერებების გამოცდა უნდა მოხდეს გამხსნელით იმ კონცენტრაციასა და ფორმით, რომელიც გამოიყენება გადაზიდვების დროს. დაუშვებელია იმ გამხსნელების გამოყენება, რომლებმაც შესაძლებელია ხელი შეუწყონ თვითრეაქტიული ნივთიერების სახიფათო კონცენტრაციის წარმოშობას იმ შემთხვევაში, თუ ადგილი აქვს ნივთიერების გაჟონვას ტარიდან. ნებისმიერი გამხსნელი უნდა იყოს თვითრეაქტიულ ნივთიერებასთან შეთავსებადი. აღნიშნულთან დაკავშირებით, შეთავსებადი ნივთიერებები წარმოადგენს იმ მყარ ან თხევად ნივთიერებებს, რომელთაც არ გააჩნიათ ნეგატიური ზემოქმედება თვითრეაქტიული ნივთიერების თერმულ სტაბილურობასა და საშიშროების ტიპზე. თხევად გამხსნელებს იმ შემადგენლობაში, რომელიც საჭიროებს ტემპერატურის რეგულირებას (იხილეთ 2.2.41.1.14 ქვეპუნქტი), უნდა აღენიშნოთ მინიმუმ 600C დუღილის ტემპერატურა და არანაკლებ 50C აფეთქების ტემპერატურა. სითხის დუღილის ტემპერატურა უნდა შეადგენდეს მინიმუმ 500C-ს და მაღალი უნდა იყოს თვითრეაქტიული ნივთიერების საკონტროლო ტემპერატურაზე. ტემპერატურის რეგულირებასთან დაკავშირებული მოთხოვნები 2.2.41.1.17 ზოგიერთი თვითრეაქტიული ნივთიერების გადაზიდვა დაშვებულია მხოლოდ ტემპერატურის რეგულირების პირობებში. საკონტროლო ტემპერატურა წარმოადგენს მაქსიმალურ ტემპერატურას, რომელზეც ხორციელდება თვითრეაქტიული ნივთიერებების უსაფრთხო გადაზიდვა. ნავარაუდევია, რომ შეფუთვის უშუალო სიახლოვეს არსებული ტემპერატურა აღემატება მხოლოდ 550C-ს გადაზიდვების დროს 24-საათიან პერიოდში შედარებით მოკლე დროის შემთხვევაში. ტემპერატურის რეგულირების შესაძლებლობის არარსებობის შემთხვევაში, შესაძლებელია აუცილებელი გახდეს გადაუდებელი პროცედურების სისრულეში მოყვანა. ავარიული ტემპერატურა წარმოადგენს ტემპერატურას, რომელზეც უნდა განხორციელდეს აღნიშნული პროცედურები. საკონტროლო და ავარიული ტემპერატურები გამოითვლება თვითაჩქარებული დაშლის ტემპერატურიდან (იხილეთ ცხრილი 1). თვითაჩქარებული დაშლის ტემპერატურა განისაზღვრება იმისათვის, რომ დადგინდეს ექვემდებარება თუ არა ნივთიერება ტემპერატურის რეგულირებას გადაზიდვების დროს. თვითაჩქარებული დაშლის ტემპერატურის განსაზღვრებასთან დაკავშირებული დებულებები წარმოდგენილია ცდებისა და კრიტერიუმების სახელმძღვანელოს II ნაწილის მე-20 თავსა და 28.4 კარში. 210 ცხრილი 1: საკონტროლო და ავარიული ტემპერატურების განსაზღვრა ჭურჭლის ტიპი ცალკეული ტარა და მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი თვითაჩქარებული დაშლის ტემპერატურაა 200C ან უფრო ნაკლები 200C-ზე მეტი, მაგრამ 350C-ზე ნაკლები 350C-ზე მეტი ცისტერნები არაუმეტეს 500C ტემპერატურისა საკონტროლო ტემპერატურა ავარიული ტემპერატურა 200C თვითაჩქარებული დაშლის ტემპერატურაზე დაბლა 150C თვითაჩქარებული დაშლის ტემპერატურაზე დაბლა 100C თვითაჩქარებული დაშლის ტემპერატურაზე დაბლა 100C თვითაჩქარებული დაშლის ტემპერატურაზე დაბლა 100C თვითაჩქარებული დაშლის ტემპერატურაზე დაბლა 100C თვითაჩქარებული დაშლის ტემპერატურაზე დაბლა 50C თვითაჩქარებული დაშლის ტემპერატურაზე დაბლა 50C თვითაჩქარებული დაშლის ტემპერატურაზე დაბლა იმ ნივთიერების თვითაჩქარებული დაშლის ტემპერატურა, რომელიც შეფუთულია გადასაზიდად. ა თვითრეაქტიული ნივთიერებები, რომელთა თვითაჩქარებული დაშლის ტემპერატურა არ აღემატება 550C-ს, ექვემდებარება ტემპერატურის რეგულირებას გადაზიდვის დროს. საჭიროების შემთხვევაში 2.2.41.4 პუნქტში წარმოდგენილია საკონტროლო და ავარიული ტემპერატურების ჩამონათვალი. გადაზიდვების დროს ფაქტიური ტემპერატურა შესაძლებელია იყოს საკონტროლო ტემპერატურაზე დაბალი, თუმცა ის ისე უნდა შეირჩეს, რომ უზრუნველყოფილი იქნეს ფაზების სახიფათო გაყოფის პრევენცია. მყარი დესენსიბილიზებული ფეთქებადი ნივთიერებები 2.2.41.1.18 მყარი დესენსიბილიზებული ფეთქებადი ნივთიერებები წარმოადგენს ნივთიერებებს, რომლებიც სველდება წყლითა თუ სპირტით და იხსნება სხვა ნივთიერებებთან ერთად, რათა ჩაახშოს მათი ფეთქებადი თვისებები. აღნიშნული სახის პოზიციებს 3.2 თავის A ცხრილში წარმოადგენს: გაეროს ნომერები 1310, 1320, 1321, 1322, 1336, 1337, 1344, 1347, 1348, 1349, 1354, 1355, , 1356, 1357, 1517, 1571, 2555, 2556, 2557, 2852, 2907, 3317, 3319, 3344, 3364, 3365, 3366, 3367, 3368, 3369, 3370, 3376, 3380 და 3474. თვითრეაქტიულ ნივთიერებებთან დაკავშირებული ნივთიერებები 2.2.41.1.19 ნივთიერებები, რომლებიც: (ა) დროებით იქნა მიღებული პირველ კლასში ცდების პირველი და მე-2 სერიების თანახმად, თუმცა გამოირიცხება პირველი კლასიდან, ცდების მე-6 სერიების საფუძველზე; (ბ) არ წარმოადგენს ნივთიერებებს; (გ) არ წარმოადგენს 5.1 ან 5.2 კლასით გათვალისწინებულ ნივთიერებებს; 4.1 კლასით გათვალისწინებულ აგრეთვე მიეკუთვნება 4.1 კლასს. აღნიშნული წარმოადგენს გაეროს #2956, 3241, 3242 და 3251. 211 თვითრეაქტიულ ნივთიერებების პოზიციებს 2.2.41.2 ნივთიერებები, რომლებიც არ დაიშვება გადაზიდვებზე 2.2.41.2.1 4.1 კლასით გათვალისწინებული ქიმიურად არასტაბილური ნივთიერებები არ დაიშვება გადაზიდვებზე, თუ არ განხორციელდება შესაბამისი ღონისძიებები გადაზიდვების დროს მათი სახიფათო დაშლის ან პოლიმერიზაციის პრევენციის მიზნით. აღნიშნულთან დაკავშირებით, განსაკუთრებით ყურადღება უნდა მიექცეს იმ ფაქტის უზრუნველყოფას, რომ ჭურჭელი და ცისტერნები არ შეიცავდეს აღნიშნული რეაქციების გამომწვევ რაიმე ნივთიერებას. 2.2.41.2.2 ადვილაალებადი, მჟანგავი მყარი ნივთიერებები, რომელთაც მინიჭებული აქვთ გაეროს #3097, არ დაიშვება გადაზიდვებზე, თუ ისინი არ აკმაყოფილებს პირველი კლასის მოთხოვნებს (იხილეთ აგრეთვე პუნქტი 2.1.3.7). 2.2.41.2.3 შემდეგი ნივთიერებები არ დაიშვება გადაზიდვებზე: - A ტიპის თვითრეაქტიული ნივთიერებები (იხილეთ ტესტებისა კრიტერიუმების სახელმძღვანელოს II ნაწილის 20.4.2(ა) პუნქტი); - ფოსფორის სულფიდები, რომლებიც არ არის თავისუფალი ყვითელი და თეთრი ფოსფორისგან; - მყარი დესენსიბილიზებული ფეთქებადი ნივთიერებები, გარდა 3.2 თავის A ცხრილში ჩამოთვლილი ნივთიერებებისა; - არაორგანული, ადვილაალებადი ნივთიერებები მდნარ მდგომარეობაში, გაეროს #2448 - გოგირდი, მდნარი - გარდა. 212 და 2.2.41.3 ერთობლივი პოზიციების ჩამონათვალი 3175 1353 1353 1325 ადვილაალებადი სითხეების შემცველი მყარი ფორმები, N.O.S. ნიტრატების დაბალი შემცველობის მქონე ნიტროცელულოზით გაჟღენთილი ბოჭკოები, N.O.S. ან ნიტრატების დაბალი შემცველობის მქონე ნიტროცელულოზით გაჟღენთილი ქსოვილები, N.O.S. ადვილაალებადი მყარი ნივთიერება, ორგანული, N.O.S. 3176 ადვილაალებადი მყარი ნივთიერება, ორგანული, მდნარი, N.O.S. 3089 3181 3182 3178 ლითონის ფხვნილი, ადვილაალებადი, N.O.S.ა ბ ლითონის მარილები ან ორგანული ნარევები, ადვილაალებადი, N.O.S. ლითონის ჰიდრიდები, ადვილაალებადი, N.O.S.გ ადვილაალებადი მყარი ნივთიერება, არაორგანული, N.O.S. 3097 ადვილაალებადი მყარი ნივთიერება, მჟანგავი, N.O.S. (არ არის დაშვებული, პუნქტი 2.2.41.2.2) 2926 ადვილაალებადი მყარი ნივთიერება, ტოქსიკური. ორგანული, N.O.S. 3179 ადვილაალებადი მყარი ნივთიერება, ტოქსიკური, არაორგანული, N.O.S. FC1 2925 ადვილაალებადი მყარი ნივთიერება, კოროზიული, ორგანული, N.O.S. არაორგანული FC2 3180 ადვილაალებადი მყარი ნივთიერება, კოროზიული, არაორგანული, N.O.S. 3319 ნიტროგლიცერინის ნარევი, დესენსიბილიზებული, მყარი N.O.S. ნიტროგლიცერინის 2%-ზე მეტი, თუმცა 10%-ზე ნაკლები მასური წილით პენტაერითრიტის ტეტრანიტრატის (პენტაერითრიტის ტეტრანიტრატი, პეტნ) ნარევი, დესენსიბილიზებული, მყარი, პენტაერითრიტის ტეტრანიტრატის 10%-ზე მეტი, თუმცა 20%-ზე ნაკლები მასური წილით დესენსიბილიზებული ფეთქებადი ნივთიერება, მყარი, N.O.S. ორგანული F1 ორგანული მდნარი დამატებითი რისკის გარეშე F2 არაორგანული F3 ადვილაალებადი მყარი ნივთიერებები მჟანგავი FO3 ორგანული ტოქსიკური FT FT1 არაორგანული FT2 ორგანული კოროზიული FC დამატებითი რისკის გარეშე D მყარი დესენსიბილიზებული ფეთქებადი ნივთიერებები 3344 3380 ტოქსიკური არ საჭიროებს ტემპერატურის დარეგულირებას DT SR1 თვითრეაქტიული ნივთიერებები SR საჭიროებს ტემპერატურის დარეგულირებას SR2 გადაზიდვებზე დაიშვება მხოლოდ გათვალისწინებული ნივთიერებები. 3.2 თავის A ცხრილში 4.1. კლასის ნივთიერებების 3221 3222 3223 3224 3225 3226 3227 3228 3229 3230 A ტიპის თვითრეაქტიული სითხე A ტიპის თვითრეაქტიული მყარი ნივთიერება B ტიპის თვითრეაქტიული სითხე B ტიპის თვითრეაქტიული მყარი ნივთიერება C ტიპის თვითრეაქტიული სითხე C ტიპის თვითრეაქტიული მყარი ნივთიერება D ტიპის თვითრეაქტიული სითხე D ტიპის თვითრეაქტიული მყარი ნივთიერება E ტიპის თვითრეაქტიული სითხე E ტიპის თვითრეაქტიული მყარი ნივთიერება F ტიპის თვითრეაქტიული სითხე F ტიპის თვითრეაქტიული მყარი ნივთიერება G ტიპის თვითრეაქტიული სითხე G ტიპის თვითრეაქტიული მყარი ნივთიერება არ დაიშვება გადაზიდვებზე იხილეთ 2.2.41.2.3 ქვეპუნქტი 3231 3232 3233 3234 3235 3236 3237 3238 3239 3240 B ტიპის თვითრეაქტიული სითხე, დარეგულირებული ტემპერატურით B ტიპის თვითრეაქტიული მყარი ნივთიერება, დარეგულირებული ტემპერატურით C ტიპის თვითრეაქტიული სითხე, დარეგულირებული ტემპერატურით C ტიპის თვითრეაქტიული მყარი ნივთიერება, დარეგულირებული ტემპერატურით D ტიპის თვითრეაქტიული სითხე, დარეგულირებული ტემპერატურით D ტიპის თვითრეაქტიული მყარი ნივთიერება, დარეგულირებული ტემპერატურით E ტიპის თვითრეაქტიული სითხე, დარეგულირებული ტემპერატურით E ტიპის თვითრეაქტიული მყარი ნივთიერება, დარეგულირებული ტემპერატურით F ტიპის თვითრეაქტიული სითხე, დარეგულირებული ტემპერატურით F ტიპის თვითრეაქტიული მყარი ნივთიერება, დარეგულირებული ტემპერატურით არ ექვემდებარება 4.1. კლასთან დაკავშირებით მოქმედ დებულებებს იხილეთ 2.2.41.2.3 ქვეპუნქტი ლითონები და ლითონის შენადნობები, წარმოდგენილი ფხვნილისებრი ან სხვა ადვილაალებადი ფორმით, რაც ხელს უწყობს თვითაალებას, წარმოადგენს 4.2 კლასის ნივთიერებებს. ა 213 სახით ლითონები და ლითონის შენადნობები, წარმოდგენილი ფხვნილისებრი ან სხვა ადვილაალებადი ფორმით, რომელიც წყალთან შეხებისას გამოჰყოფს ადვილაალებად აირებს, წარმოადგენს 4.3 კლასის ნივთიერებებს. გ ლითონის ჰიდრიდები, რომლებიც წყალთან შეხებისას, გამოჰყოფს ადვილაალებად აირებს, წარმოადგენს 4.3 კლასის ნივთიერებებს. ალუმინის ბორჰიდრიდი ან ალუმინის ბორჰიდრიდი მოწყობილობაში წარმოადგენს 4.2 კლასის ნივთიერებებს, გაეროს ნომრით 2870. ბ 2.2.41.2 ტარაში გადასაზიდი თვითრეაქტიული ნივთიერებების ჩამონათვალი, რომელთა კლასიფიკაცია განხორციელდა ახლახანს შესაბამის პოზიციებზე სვეტში „შეფუთვის მეთოდი“, კოდები “OP1”-დან “OP8”-მდე მიეკუთვნებათ P520 შეფუთვის ინსტრუქციის 4.1.4.1 პუნქტში გათვალისწინებულ შეფუთვის მეთოდებს (იხილეთ აგრეთვე 4.1.7.1 პუნქტი), გადასაზიდი თვითრეაქტიული ნივთიერებები უნდა პასუხობდეს კლასიფიკაციისა და საკონტროლო და ავარიული ტემპერატურების ჩამოთვლილ მოთხოვნებს (რომლებიც განისაზღვრება თვითაჩქარებული დაშლის ტემპერატურის საფუძველზე). მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებში დაშვებულ ნივთიერებებთან დაკავშირებით, იხილეთ IBC520 შეფუთვის ინსტრუქციის 4.1.4.1 პუნქტი, ხოლო ცისტერნებში 4.2 თავის თანახმად დაშვებულ ნივთიერებებთან დაკავშირებით, იხილეთ გადამზიდი ცისტერნების შესახებ T23 ინსტრუქციის 4.2.5.2 პუნქტი. შენიშვნა: მოცემულ ცხრილში გათვალისწინებული კლასიფიკაცია განისაზღვრება ტექნიკურად სუფთა ნივთიერების შესაბამისად (გარდა იმ შემთხვევებისა, როდესაც გათვალისწინებულია 100%-ზე ნაკლები კონცენტრაცია). სხვა კონცენტრაციებთან დაკავშირებით, შესაძლებელია ნივთიერებების კლასიფიცირება სხვადასხვა სახით, ცდებისა და კრიტერიუმების სახელმძღვანელოს II ნაწილსა და 2.2.41.1.17 ქვეპუნქტში გათვალისწინებული პროცედურების შესაბამისად. 214 თვითრეაქტიული ნივთიერება კონცენტრ აცია (%) შეფუთვის მეთოდი აცეტონ-პიროგალოლის სოპოლიმერი 2-დიაზო-1-ნაფტოლ5-სულფონატი აზოდიკარბონამიდი, B ტიპის შემადგენლობა, დარეგულირებული ტემპერატურით აზოდიკარბონამიდი, C ტიპის შემადგენლობა აზოდიკარბონამიდი, C ტიპის შემადგენლობა, დარეგულირებული ტემპერატურით აზოდიკარბონამიდი, D ტიპის შემადგენლობა აზოდიკარბონამიდი, D ტიპის შემადგენლობა, დარეგულირებული ტემპერატურით 2.2’-აზოდი(2,4-დიმეთილ-4მეტოქსი-ველერონიტრილი) 2.2’-აზოდი(2,4-დიმეთილველერონიტრილი) 2.2’-აზოდი(ეთილ-2-მეთილპროპიონატი) 1,1-აზოდი (ჰექსაჰიდრობენზონიტრილი) 2,2’-აზოდი(იზობუთირონიტრილი) 2,2’-აზოდი(იზობუთირონიტრილი) წყლის ბაზაზე დამზადებული პასტის სახით 2,2’-აზოდი (2მეთილბუთირონიტრილი) ბენზოლ-1,3-დისულფონილ ჰიდრაზიდი, პასტის სახით ბენზოლსულფონილჰიდრაზიდი 4-(ბენზილ(ეთილ)ამინო)-3-ეტოქსიბენზოდიაზონის თუთიის ქლორიდი 4-(ბენზილ(ეთილ)ამინო)-3-ეტოქსიბენზოდიაზონის თუთიის ქლორიდი 3-ქლორო-4დიეთილამინობენზოლი-დიაზონის თუთიის ქლორიდი 2-დიაზო-1-ნაფტოლ-4სულფონილქლორიდი 2-დიაზო-1-ნაფტოლ-5სულფონილქლორიდი 2-დიაზო-1-ნაფტოლ სულფონმჟავას ეთერის ნარევი, ტიპი D 100 თვითრეაქტიული ნივთიერება საკონტროლო ტემპერატურა (0C) ავარიული ტემპერატურა (0C) შენიშვნები OP8 გაეროს გენერიული პოზიცია 3228 <100 OP5 3232 (1) (2) <100 OP6 3224 (3) <100 OP6 3224 (4) <100 OP7 3226 (5) <100 OP7 3236 (6) 100 OP7 -5 +5 3236 100 OP7 +10 +15 3236 100 OP7 +20 +25 3235 100 OP7 100 <50% OP6 OP6 +40 +45 3234 3224 100 OP7 +35 +40 3236 52 OP7 3226 100 100 OP7 OP7 3226 3226 100 OP7 100 OP7 3226 100 OP5 3222 (2) 100 OP5 3222 (2) <100 OP7 3226 (9) კონცენტრ აცია (%) შეფუთვის მეთოდი გაეროს გენერიული შენიშვნები 3226 +40 საკონტროლო ტემპერატურა 215 +45 ავარიული ტემპერატურა 3236 2,5-დიბუტოქსი-4-(4მორფოლინილ)-ბენზოლდიაზონი, ტეტრაქლორცინკატი (2:1) 2,5-დიეტოქსი-4-მორფოლინობენზოდიაზონის თუთიის ქლორიდი 2,5-დიეტოქსი-4-მორფოლინობენზოლდიაზონის თუთიის ქლორიდი 2,5-დიეტოქსი-4-მორფოლინობენზოლდიაზონის ტეტრაფტორობორატი 2,5-დიეტოქსი-4-(4-მორფოლინილ)ბენზოლდიაზონის სულფატი 2,5-დიეტოქსი-4(ფენილსულფონილ)ბენზოლდიაზონის თუთიის ქლორიდი დიეთილენგლიკოლ ბის (ალილკარბონატი) +დიიზოპროპილ-პეროქსიდიკარბონატი 2,5-დიმეტოქსი-4-(4-მეთილფენილსულფონილ)ბენზოლდიაზონის თუთიის ქლორიდი 4-(დიმეთილამინო)ბენზოლდიაზონის ტრიქლოროცინკატი (-1) 4-დიმეთილამინო-6-(2დიმეთილამინოეტოქსი) ტოლუოლ2-დიაზონის თუთიის ქლორიდი ნ,ნ’-დინიტროზო-ნ,ნ’-დიმეთილ ტერეფტალამიდი, პასტის სახით ნ,ნ’-დინიტროზოპენტამეთილენტეტრამინი ბიფენილოქრიდ-4,4’დისულფონილჰიდრაზიდი 4-დიპროპილამინობენზოლდიაზონის თუთიის ქლორიდი 2-(ნ,ნ’-ეთილოქსიკარბონილფენილამინო)-3-მეტოქსი-4-(ნმეთილ-ნ-ციკლოჰექსილამინო) ბენზოდიაზონის თუთიის ქლორიდი 2-(ნ,ნ’-ეთილოქსიკარბონილფენილამინო)-3-მეტოქსი-4-(ნმეთილ-ნ-ციკლოჰექსილამინო) ბენზოდიაზონის თუთიის ქლორიდი ნ-ფორმილ-2-(ნიტრომეთილენ)-1,3პერჰიდროთიაზინი თვითრეაქტიული ნივთიერება (0C) (0C) პოზიცია 3228 100 OP8 67-100 OP7 +35 +40 3236 66 OP7 +40 +45 3236 67-100 OP7 +30 +35 3236 100 OP7 67 OP7 +40 +45 3236 >88+<12 OP8 -10 0 3237 79 OP7 +40 +45 3236 100 OP8 100 OP7 72 OP6 3224 82 OP6 3224 100 OP7 3226 100 OP7 3226 63-92 OP7 +40 +45 3236 62 OP7 +35 +40 3236 100 OP7 +45 +50 3236 კონცენტრ აცია (%) შეფუთვის მეთოდი საკონტროლო ტემპერატურა ავარიული ტემპერატურა გაეროს გენერიული 3226 3228 +40 216 +45 3236 (7) შენიშვნები 2-(2-ჰიდროქსიეტოქსი)-1(პიროლიდინილ-1)ბენზოლ-4დიაზონის თუთიის ქლორიდი 3-(2-ჰიდროქსიეტოქსი)-4(პიროლიდინი-1ლ)ბენზოლ-4დიაზონის თუთიის ქლორიდი 2-(ნ,ნ’მეთილამინოეთილკარბონილ)-4(3,4დიმეთილფენილსულფონილ)ბენზო დიაზონის ჰიდროგენსულფატი 4მეთილბენზონილსულფონილჰიდრ აზიდი 3-მეთილ-4-(პიროლიდინ-1-ილ) ბენზილდიაზონის ტეტრაფტორობორატი 4-ნიტროზოფენოლი თვითრეაქტიული სითხე, ნიმუში თვითრეაქტიული სითხე, ნიმუში, დარეგულირებული ტემპერატურით თვითრეაქტიული მყარი ნივთიერება, ნიმუში თვითრეაქტიული მყარი ნივთიერება, ნიმუში, დარეგულირებული ტემპერატურით ნატრიუმის 2-დიაზო-1-ნაფტოლ-4სულფონატი ნატრიუმის 2-დიაზო-1-ნაფტოლ-5სულფონატი ტეტრამინპალადიუმ (II) ნიტრატი 100 OP7 (0C) +45 (0C) +50 პოზიცია 3236 100 OP7 +40 +45 3236 96 OP7 +45 +50 3236 100 OP7 95 OP6 +45 +50 3234 100 OP7 OP2 OP2 +35 +40 3236 3223 3233 (8) (8) OP2 3224 (8) OP2 3234 (8) 100 OP7 3226 100 OP7 3226 100 OP6 3226 +30 +35 3234 შენიშვნები (1) აზოდიკარბონამიდის შემადგენლობები აკმაყოფილებს ცდებისა და კრიტერიუმების სახელმძღვანელოს 20.4.2(ბ) პუნქტით გათვალისწინებულ კრიტერიუმებს. საკონტროლო და ავარიული ტემპერატურები განისაზღვრება 2.2.41.2.17 პუნქტში წარმოდგენილი პროცედურების მიხედვით. (2) საჭიროა დამატებითი უსაფრთხოების ნიშნის „ფეთქებადი ნივთიერება“ მითითება (ნიმუში #1, იხილეთ ქვეპუნქტი 5.2.2.2.2). (3) აზოდიკარბონამიდის შემადგენლობები აკმაყოფილებს ცდებისა კრიტერიუმების სახელმძღვანელოს 20.4.2(გ) პუნქტის მოთხოვნებს. (4) აზოდიკარბონამიდის შემადგენლობები აკმაყოფილებს ცდებისა და კრიტერიუმების სახელმძღვანელოს 20.4.2(გ) პუნქტის მოთხოვნებს. საკონტროლო და ავარიული ტემპერატურები განისაზღვრება 2.2.41.1.17 ქვეპუნქტში მოყვანილი პროცედურის შესაბამისად. (5) აზოდიკარბონამიდის შემადგენლობები აკმაყოფილებს ცდებისა კრიტერიუმების სახელმძღვანელოს 20.4.2(დ) პუნქტის მოთხოვნებს. 217 და და (6) აზოდიკარბონამიდის შემადგენლობები აკმაყოფილებს ცდებისა და კრიტერიუმების სახელმძღვანელოს 20.4.2(დ) პუნქტის მოთხოვნებს. საკონტროლო და ავარიული ტემპერატურები განისაზღვრება 2.2.41.1.17 პუნქტში მოყვანილი პროცედურის შესაბამისად. (7) შეთავსებად გამხსნელთან ერთად წარმოდგენის არანაკლებ 1500C დუღილის ტემპერატურა. (8) იხილეთ 2.2.41.1.15 პუნქტი. (9) აღნიშნული პოზიცია გამოიყენება 2-დიაზო-1-ნაფტოლ-4-სულფონმჟავისა და 2-დიაზო-1-ნაფტოლ-5-სულფონმჟავის ეთერების ნარევებთან, რაც აკმაყოფილებს ცდებისა და კრიტერიუმების სახელმძღვანელოს 20.4.2(დ) პუნქტს. 218 შემთხვევაში, გააჩნია 2.2.42 კლასი 4.2 თვითაალების გამომწვევი ნივთიერებები 2.2.42.1 კრიტერიუმები 2.2.42.1.1 4.2 კლასის სახელწოდებაში შედის - პიროფორული ნივთიერებები, ეს არის ნივთიერებები, ნარევებისა და ხსნარების ჩათვლით (წარმოდგენილი თხევადსა თუ მყარ მდგომარეობაში), რომლებიც მცირე რაოდენობის შემთხვევაშიც კი ახდენენ აალებას ჰაერთან შეხებისას ხუთი წუთის განმავლობაში. აღნიშნულს წარმოადგენს 4.2 კლასით გათვალისწინებული, თვითაალების უნარის მქონე ნივთიერებები; და - თვითთბობადი ნივთიერებები და ნაკეთობები - ეს არის ნივთიერებები და ნაკეთობები, ნარევებისა და ხსნარების ჩათვლით, რომლებიც, ჰაერთან შეხებისას, ენერგიის მიწოდების გარეშე, იწვევს თვითთბობას. აღნიშნული ნივთიერებები აალდებიან მხოლოდ დიდი ოდენობებით წარმოდგენისას (კილოგრამები) და მხოლოდ ხანგრძლივი პერიოდის შემდეგ (საათები ან დღეები). 2.2.42.1.2 4.2 კლასის ნივთიერებები და ნაკეთობები იყოფა შემდეგი სახით: S თვითაალების გამომწვევი ნივთიერებები, დამატებითი რისკის გარეშე: S1 S2 S3 S4 S5 ორგანული, თხევადი ორგანული, მყარი არაორგანული, თხევადი არაორგანული, მყარი ლითონორგანული SW თვითაალების გამომწვევი ნივთიერებები, რომლებიც, წყალთან შეხებისას, გამოჰყოფს ადვილაალებად აირებს; SO თვითაალების გამომწვევი ნივთიერებები, მჟანგავი; ST თვითაალების გამომწვევი ნივთიერებები, ტოქსიკური: ST1 ST2 ST3 ST4 SC ორგანული, ტოქსიკური, თხევადი; ორგანული, ტოქსიკური, მყარი არაორგანული, ტოქსიკური, თხევადი; არაორგანული, ტოქსიკური, მყარი; თვითაალების გამომწვევი ნივთიერებები, კოროზიული SC1 SC2 SC3 SC4 ორგანული, კოროზიული, თხევადი; ორგანული, კოროზიული, მყარი; არაორგანული, კოროზიული, თხევადი; არაორგანული, კოროზიული, მყარი. თვისებები 2.2.42.1.3 ნივთიერებების თვითთბობა წარმოადგენს პროცესს, სადაც აღნიშნული ნივთიერების ეტაპობრივი რეაქცია ჟანგბადთან (ჰაერში) წარმოშობს სითბოს. იმ შემთხვევაში, თუ სითბოს წარმოშობის სიჩქარე აღემატება სითბოს დაკარგვის სიჩქარეს, მაშინ ნივთიერების ტემპერატურა აიწევს, ხოლო ინდუქციის პერიოდის შემდეგ, შესაძლებელია გამოიწვიოს თვითაალება და წვა. 219 კლასიფიკაცია 2.2.42.1.4 4.2 კლასში კლასიფიცირებული ნივთიერებებისა და ნაკეთობების ჩამონათვალი მოცემულია 3.2 თავის ა ცხრილში. იმ ნივთიერებებისა და ნაკეთობების მიკუთვნება, რომლებიც არ არის მითითებული დასახელებით 3.2 თავის A ცხრილში 2.2.42.3 პუნქტის შესაბამის კონკრეტულ N.O.S. პოზიციაზე, 2.1 თავის დებულებების შესაბამისად შესაძლებელია დაეფუძნოს არსებულ გამოცდილებასა და გამოცდების შედეგებს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.3 კარის შესაბამისად. 4.2 კლასის ერთობლივ N.O.S. პოზიციებზე მიკუთვნება ემყარება ცდების პროცედურების შედეგებს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.3 კარის შესაბამისად; ასევე მხედველობაში უნდა იქნეს მიღებული არსებული გამოცდილება, თუ ის უზრუნველყოფს კიდევ უფრო მკაცრ კლასიფიკაციას. 2.2.42.1.5 იმ შემთხვევაში, თუ ის ნივთიერებები და ნაკეთობები, რომლებიც არ არის მითითებული დასახელებით, კლასიფიცირდება 2.2.42.2 პუნქტში ჩამოთვლილი პოზიციებიდან რომელიმეში, ცდების პროცედურების საფუძველზე, ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.3 კარის შესაბამისად, გამოიყენება შემდეგი კრიტერიუმები: (ა) თვითაალების გამომწვევი (პიროფორული) მყარი ნივთიერებები კლასიფიცირდება 4.2 კლასში, როდესაც ისინი ალდებიან 1 მეტრის სიმაღლიდან ვარდნისას ან ხუთი წუთის განმავლობაში; (ბ) თვითაალების გამომწვევი (პიროფორული) კლასიფიცირდება 4.2 კლასში იმ შემთხვევაში, თუ (გ) მყარი ნივთიერებები (i) ინერტულ გადამზიდში ჩასხმისას, ისინი აალდებიან ხუთი წუთის განმავლობაში, ან (ii) ცდის უარყოფითი შედეგით დასრულების შემთხვევაში (i) ქვეპუნქტის შესაბამისად, როდესაც ისხმევა მშრალ, გაფილტრულ, დაჭმუჭნულ ფურცელზე (ვატმანის #3 ფილტრი), ისინი აალდებიან ან ადგილი აქვს მათ დანახშირბადებას ხუთი წუთის განმავლობაში; ნივთიერებები, რომლებთან დაკავშირებითაც, 10 სმ კუბურ ნიმუშში, 1400C საცდელ ტემპერატურაზე, აღინიშნება თვითაალება ან ტემპერატურის ზრდა 2000C-მდე 24 საათის განმავლობაში, კლასიფიცირდება 4.2 კლასში. აღნიშნული კრიტერიუმი განისაზღვრება ხის ნახშირის თვითაალების ტემპერატურის მიხედვით, რომელიც შეადგენს 500C-ს 27მ2 კუბური ნიმუშის შემთხვევაში. ნივთიერებები, რომელთა თვითაალების ტემპერატურა აღემატება 500C-ს 27მ3 მოცულობაზე, არ მიეკუთვნება 4.2 კლასს. შენიშვნა 1: შეფუთვებში გადატანილი ნივთიერებები, რომელთა მოცულობაც არ აღემატება 3მ3, თავისუფლდება 4.2 კლასის მოთხოვნებისგან, თუ 10 სმ კუბური ნიმუშის 1200C-ზე ცდისას, თავს არ იჩენს არც თვითაალება და არც ტემპერატურის მომატება 1800C-ზე მეტად 24 საათის განმავლობაში. შენიშვნა 2: შეფუთვებში გადატანილი ნივთიერებები, რომელთა მოცულობაც არ აღემატება 450 ლიტრს, თავისუფლდება 4.2 კლასის მოთხოვნებისგან, თუ 10 სმ კუბური ნიმუშის 1000C-ზე ცდისას, თავს არ იჩენს არც თვითაალება და არც ტემპერატურის მომატება 1600C-ზე მეტად 24 საათის განმავლობაში. 220 შენიშვნა 3: ვინაიდან ლითონორგანული ნივთიერებების კლასიფიცირება შესაძლებელია 4.2 ან 4.3 კლასებში დამატებით საშიშროებასთან ერთად, რაც დამოკიდებულია მათ თვისებებზე, აღნიშნულ ნივთიერებებთან დაკავშირებით 2.3.5 პუნქტში მოცემულია სპეციალური კლასიფიკაციის სქემა. 2.2.42.1.6 იმ შემთხვევაში, თუ 4.2 კლასის ნივთიერებები, მათში დანამატების შეტანის შემდეგ, მოხვდებიან საშიშროების სხვადასხვა კატეგორიებში, რომელთაც მიეკუთვნებათ 3.2 თავის A ცხრილში დასახელებით მითითებული ნივთიერებები, აღნიშნული ნარევების კლასიფიკაცია მოხდება იმ პოზიციებზე, რომელთაც ისინი მიეკუთვნება მათი საშიშროების ფაქტიური ხარისხის საფუძველზე. შენიშვნა: ხსნარებისა და ნარევების (როგორიცაა პრეპარატები და ნარჩენები) კლასიფიკაციასთან დაკავშირებით იხილეთ აგრეთვე 2.1.3 პუნქტი. 2.2.42.1.7 ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.3 კარში გათვალისწინებული საცდელი პროცედურებისა და 2.2.42.1.5 ქვეპუნქტში მოყვანილი კრიტერიუმების საფუძველზე შესაძლებელია ასევე განისაზღვროს, არის თუ არა რომელიმე, დასახელებით მითითებული ნივთიერების მახასიათებელი ისეთი სახის, რომ აღნიშნული ნივთიერებაზე არ ვრცელდებოდეს მოცემული კლასის დებულებები. მიკუთვნება შესაბამის შეფუთვის ჯგუფებზე 2.2.42.1.8 3.2 თავის A ცხრილში სხვადასხვა პოზიციებზე კლასიფიცირებული ნივთიერებები და ნაკეთობები მიეკუთვნება I, II ან III შეფუთვის ჯგუფებს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.3 კარით გათვალისწინებული ცდების პროცედურების საფუძველზე, შემდეგი კრიტერიუმების შესაბამისად: (ა) თვითაალების გამომწვევი (პიროფორული) ნივთიერებების მიკუთვნება უნდა მოხდეს I შეფუთვის ჯგუფზე; (ბ) თვითთბობადი ნივთიერებებისა და ნაკეთობების, რომლებთან 3 0 დაკავშირებითაც 2.5 სმ ნიმუშში,140 C საცდელ ტემპერატურაზე, აღინიშნება თვითაალება ან ტემპერატურის ზრდა 2000C-ზე ზემოთ 24 საათის განმავლობაში, მიკუთვნება უნდა მოხდეს II შეფუთვის ჯგუფზე; ნივთიერებების, რომელთა თვითაალების ტემპერატურა აღემატება 500C-ს 450 ლიტრ მოცულობაზე, მიკუთვნება დაუშვებელია II შეფუთვის ჯგუფზე. (გ) 2.2.42.2 თვითთბობის უმნიშვნელო შესაძლებლობის მქონე ნივთიერებების, 3 რომლებთან დაკავშირებითაც 25 სმ ნიმუშში (ბ) ქვეპუნქტში მოყვანილი თვისებები არ აღინიშნება მოცემულ პირობებში, თუმცა რომლებთან დაკავშირებითაც 10 სმ3 ნიმუშში 1400C საცდელ ტემპერატურაზე აღინიშნება თვითაალება ან ტემპერატურის ზრდა 2000C-ზე ზემოთ 24 საათის განმავლობაში, მიკუთვნება უნდა მოხდეს III შეფუთვის ჯგუფში. ნივთიერებები, რომლებიც არ დაიშვება გადაზიდვებზე შემდეგი ნივთიერებები არ დაიშვება გადაზიდვებზე: - გაეროს #3255 - მესამეული ბუთილის ჰიპოქლორიტი; და - თვითთბობადი, მჟანგავი მყარი ნივთიერებები, რომელთაც მინიჭებული აქვთ გაეროს #3127, გარდა იმ შემთხვევებისა, როდესაც ისინი აკმაყოფილებს პირველი კლასის მოთხოვნებს (იხილეთ 2.1.3.7 პუნქტი). 221 2.2.42.3 ერთობლივი პოზიციების ჩამონათვალი თვითაალების გამომწვევი ნივთიერებები 2845 3183 პიროფორული სითხე, ორგანული, N.O.S. თვითთბობადი სითხე, ორგანული, N.O.S. 1373 2006 3313 2846 3008 ბოჭკოები ან ქსოვილები, ცხოველური, მცენარეული ან სინთეტიკური, N.O.S. ზეთით პლასტმასი ნიტროცელულოზის ბაზაზე, თვითთბობადი, N.O.S. ორგანული პიგმენტები, თვითთბობადი პიროფორული მყარი ნივთიერება, ორგანული, N.O.S. თვითთბობადი მყარი ნივთიერება, ორგანული, N.O.S. 3194 3186 პიროფორული სითხე, არაორგანული, N.O.S. თვითთბობადი სითხე, არაორგანული, N.O.S. 1383 1383 1378 2881 3205 3200 3190 პიროფორული ლითონი, N.O.S. ან პიროფორული შენადნობი, N.O.S. ლითონის კატალიზატორი, დასველებული, სითხის ხილული ჭარბი რაოდენობით ლითონის კატალიზატორი, მშრალი ლითონის ფხვნილი, თვითთბობადი, N.O.S. ტუტე-მიწა ლითონების ალკოჰოლატები, N.O.S. პიროფორული მყარი ნივთიერება, არაორგანული, N.O.S. თვითთბობადი მყარი ნივთიერება, არაორგანული, N.O.S. 3392 3391 3400 ლითონორგანული ნივთიერება, თხევადი, პიროფორული ლითონორგანული ნივთიერება, მყარი, პიროფორული ლითონორგანული ნივთიერება, მყარი, თვითთბობადი 3394 3393 ლითონორგანული ნივთიერება, თხევადი, პიროფორული, წყალზე რეაგირებადი ლითონორგანული ნივთიერება, მყარი, პიროფორული, წყალზე რეაგირებადი 3127 თვითთბობადი მყარი ნივთიერება, მჟანგავი, N.O.S. (არ დაიშვება, იხილეთ 2.2.42.2 პუნქტი) სითხე ST1 მყარი ნივთიერება ST2 3184 თვითთბობადი სითხე, ტოქსიკური, ორგანული, N.O.S. 3128 თვითთბობადი მყარი ნივთიერება, ტოქსიკური, ორგანული, N.O.S. სითხე ST3 მყარი ნივთიერება ST4 3187 თვითთბობადი სითხე, ტოქსიკური, არაორგანული, N.O.S. 3191 თვითთბობადი მყარი ნივთიერება, ტოქსიკური, არაორგანული, N.O.S. 3185 თვითთბობადი სითხე, კოროზიული, ორგანული, N.O.S. 3126 თვითთბობადი მყარი ნივთიერება, კოროზიული, ორგანული, N.O.S. 3188 თვითთბობადი სითხე, კოროზიული, არაორგანული, N.O.S. 3206 3192 ტუტე ლითონების ალკოჰოლატები, თვითთბობადი, კოროზიული, N.O.S. თვითთბობადი მყარი ნივთიერება, კოროზიული, არაორგანული, N.O.S. სითხე S1 ორგანული მყარი ნივთიერება S2 დამატებითი რისკის გარეშე S სითხე S3 არაორგანული მყარი ნივთიერება S4 ლითონორგანული S5 წყალზე რეაგირებადი SW მჟანგავი SO ორგანული ტოქსიკური ST არაორგანული ორგანული სითხე SC1 მყარი ნივთიერება SC2 კოროზიული SC სითხე SC3 არაორგანული მყარი ნივთიერება SC4 3189ა ლითონის მტვერი ან ფხვნილი, არატოქსიკური, წარმოდგენილი არა-თვითაალებადი ფორმით, რომელიც, მიუხედავად ყოველივე აღნიშნულისა, წყალთა შეხებისას, გამოყოფს ადვილაალებად აირებს, წარმოადენს 4.3 კლასის ნივთიერებებს. ა 222 2.2.43 კლასი 4.3 ნივთიერებები, ადვილაალებად აირებს 2.2.43.1 კრიტერიუმები 2.2.43.1.1 4.3 კლასის დასახელებაში გათვალისწინებულია ის ნივთიერებები, რომლებიც რეაქციაში შედის წყალთან შეხებისას, რათა გამოყოს ადვილაალებადი აირები, გააჩნიათ ფეთქებადი ნარევების წარმოქმნის უნარი ჰაერთან, ასევე აღნიშნული ნივთიერებების შემცველი ნაკეთობები. 2.2.43.1.2 4.3 კლასის ნივთიერებები და ნაკეთობები იყოფა შემდეგნაირად: W რომლებიც წყალთან შეხებისას, გამოყოფს ნივთიერებები, რომლებიც წყალთან შეხებისას, გამოყოფს ადვილაალებად აირებს, დამატებითი რისკის გარეშე, ასევე აღნიშნული ნივთიერებების შემცველი ნაკეთობები; W1 W2 W3 თხევადი; მყარი; ნაკეთობები; WF1 ნივთიერებები, რომლებიც წყალთან შეხებისას, გამოყოფს ადვილაალებად აირებს, თხევადი, ადვილაალებადი; WF2 ნივთიერებები, რომლებიც წყალთან შეხებისას, გამოყოფს ადვილაალებად აირებს, მყარი, ადვილაალებადი; WS ნივთიერებები, რომლებიც წყალთან შეხებისას, გამოყოფს ადვილაალებად აირებს, მჟანგავი, მყარი; WT ნივთიერებები, რომლებიც წყალთან შეხებისას, გამოყოფს ადვილაალებად აირებს, ტოქსიკური: WT1 WT2 WC ნივთიერებები, რომლებიც წყალთან შეხებისას, გამოყოფს ადვილაალებად აირებს, კოროზიული: WC1 WC2 WFC თხევადი; მყარი; თხევადი; მყარი; ნივთიერებები, რომლებიც წყალთან შეხებისას, გამოყოფს ადვილაალებად აირებს, ადვილაალებადი, კოროზიული. თვისებები 2.2.43.1.3 ზოგიერთ ნივთიერებას წყალთან შეხებისას შეუძლია გამოყოს ადვილაალებადი აირები, რომელთა საფუძველზეც შესაძლებელია წარმოიქმნას ფეთქებადი ნარევები ჰაერთან. აღნიშნული ნარევები წარმოადგენს ადვილაალებადს აალების ჩვეულებრივი წყაროს მიერ, მაგალითად, ღია ცეცხლი, ნაპერწკლებიანი ხელის იარაღები თუ დაუცველი ელექტრო ნათურები. ქვემოთ წარმოდგენილ 2.2.43.1.4 ქვეპუნქტში მოყვანილი ცდების მეთოდი გამოიყენება იმ ფაქტის განსაზღვრის მიზნით, ახდენს თუ არა ნივთიერების წყალთან რეაქციაში შესვლა იმ აირების სახიფათო რაოდენობით გამოყოფას, რომლებიც შესაძლებელია აალდეს. აღნიშნული ცდის მეთოდი არ გამოიყენება პიროფორულ ნივთიერებებთან დაკავშირებით. 223 კლასიფიკაცია 2.2.43.1.4 4.3 კლასში კლასიფიცირებული ნივთიერებებისა და ნაკეთობების ჩამონათვალი მოცემულია 3.2 თავის A ცხრილში. იმ ნივთიერებებისა და ნაკეთობების კლასიფიკაცია, რომლებიც არ არის მითითებული დასახელებით 3.2 თავის A ცხრილში 2.2.43.3 პუნქტის შესაბამისი პოზიციაზე, 2.1 თავის დებულებების თანახმად შესაძლებელია დაემყაროს არსებულ გამოცდილებასა და ცდების შედეგებს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.4 კარის შესაბამისად; ასევე მხედველობაში უნდა იქნეს მიღებული გამოცდილება, თუ ის უზრუნველყოფს კიდევ უფრო მკაცრ კლასიფიკაციას. 2.2.43.1.5 იმ შემთხვევაში, თუ ის ნივთიერებები და ნაკეთობები, რომლებიც არ არის მითითებული დასახელებით, კლასიფიცირდება 2.2.43.3 პუნქტში ჩამოთვლილი პოზიციებიდან რომელიმეში, ცდების პროცედურების საფუძველზე, ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.4 კარის შესაბამისად, გამოიყენება შემდეგი კრიტერიუმები: ნივთიერება მიეკუთვნება 4.3 კლასს იმ შემთხვევაში, თუ (ა) გამოყოფილი აირის თვითაალება მოხდება ცდის რომელიმე ეტაპზე; ან; (ბ) ადგილი აქვს ადვილაალებადი აირების გამოყოფას 1 ლიტრზე მეტი სიჩქარით საცდელი ნივთიერების ერთ კილოგრამზე საათში. შენიშვნა: ვინაიდან ლითონორგანული ნივთიერებების კლასიფიკაცია შესაძლებელია 4.2 ან 4.3 კლასებში დამატებით საშიშროებასთან ერთად, რაც დამოკიდებულია მათ თვისებებზე, აღნიშნულ ნივთიერებებთან დაკავშირებით მოცემულია სპეციალური კლასიფიკაციის სქემა 2.3.5 პუნქტში. 2.2.43.1.6 იმ შემთხვევაში, თუ 4.3 კლასის ნივთიერებები, მათში დანამატების შეტანის შედეგად, მოხვდება საშიშროების სხვადასხვა კატეგორიებში, რომელთაც მიეკუთვნებათ 3.2 თავის A ცხრილში დასახელებით მითითებული ნივთიერებები, აღნიშნული ნარევების კლასიფიკაცია მოხდება იმ პოზიციებზე, რომელთაც ისინი მიეკუთვნება მათი საშიშროების რეალური ხარისხის მიხედვით. შენიშვნა: ხსნარებისა და ნარევების (როგორიცაა პრეპარატები და ნარჩენები) კლასიფიკაციასთან დაკავშირებით იხილეთ აგრეთვე 2.1.3 პუნქტი. 2.2.43.1.7 ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.4 კარში გათვალისწინებული ცდების პროცედურებისა და 2.2.43.1.5 ქვეპუნქტში მოყვანილი კრიტერიუმების საფუძველზე შესაძლებელია ასევე განისაზღვროს, არის თუ არა რომელიმე, დასახელებით მითითებული ნივთიერების მახასიათებელი ისეთი სახის, რომ აღნიშნული ნივთიერებაზე არ გავრცელდეს მოცემული კლასის დებულებები. მიკუთვნება შესაბამის შეფუთვის ჯგუფებზე 2.2.43.1.8 3.2 თავის A ცხრილში სხვადასხვა პოზიციებზე კლასიფიცირებული ნივთიერებები და ნაკეთობები მიეკუთვნება I, II ან III შეფუთვის ჯგუფებს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.4 კარით გათვალისწინებული საცდელი პროცედურების მიხედვით, შემდეგი კრიტერიუმების შესაბამისად: (ა) I შეფუთვის დაკავშირებით, ჯგუფი განისაზღვრება ნებისმიერ ნივთიერებასთან რომელიც მძლავრად რეაგირებს წყალთან გარემოს 224 ტემპერატურაზე და ზოგადად ავლენს ტენდენციას თვითაალების უნარის მქონე აირის გამოყოფისკენ ან ნივთიერებასთან, რომელიც ადვილად შედის რეაქციაში წყალთან გარემოს ტემპერატურაზე, რის შედეგადაც გამოყოფილი ადვილაალებადი აირის სიჩქარე შეადგენს ან აღემატება 10 ლიტრს ნივთიერების ყოველ კილოგრამზე ერთ წუთზე; 2.2.43.2 (ბ) II შეფუთვის ჯგუფი განისაზღვრება ნებისმიერ ნივთიერებასთან დაკავშირებით, რომელიც ადვილად შედის რეაქციაში წყალთან გარემოს ტემპერატურაზე, რის შედეგადაც გამოყოფილი ადვილაალებადი აირის სიჩქარე შეადგენს ან აღემატება 20 ლიტრს ნივთიერების ყოველ კილოგრამზე საათში და რომელიც ვერ აკმაყოფილებს I შეფუთვის ჯგუფთან დაკავშირებით არსებულ კრიტერიუმებს; (გ) III შეფუთვის ჯგუფი განისაზღვრება ნებისმიერ ნივთიერებასთან დაკავშირებით, რომელიც ნელა შედის რეაქციაში წყალთან გარემოს ტემპერატურაზე, რის შედეგადაც გამოყოფილი ადვილაალებადი აირის მაქსიმალური სიჩქარე შეადგენს ან აღემატება 1 ლიტრს ნივთიერების ყოველ კილოგრამზე საათში და რომელიც ვერ აკმაყოფილებს I ან II შეფუთვის ჯგუფებთან დაკავშირებით არსებულ კრიტერიუმებს. ნივთიერებები, რომლებიც არ დაიშვება გადაზიდვებზე გადაზიდვებზე არ დაიშვება წყალზე რეაგირებადი მყარი, მჟანგავი ნივთიერებები, რომელთაც მინიჭებული აქვთ გაეროს № 3133, გარდა იმ შემთხვევებისა, თუ ისინი აკმაყოფილებს პირველი კლასის მოთხოვნებს (იხილეთ 2.1.3.7 პუნქტი). 225 2.2.43.3 ერთობლივი პოზიციების ჩამონათვალი ნივთიერებები, რომლებიც წყალთან შეხებისას, გამოყოფენ ადვილაალებად აირებს დამატებითი საშიშროების გარეშე W თხევადი W1 მყარი W2ა ნაკეთობები W3 1389 1391 1391 1392 1420 1421 1422 3398 3148 ტუტე ლითონის ამალგამი, თხევადი დისპერსიული ტუტე ლითონი ან დისპერსიული ტუტე-მიწა ლითონი დამიწებული ტუტე ლითონის ამალგამი კალიუმის ლითონის შენადნობები, თხევადი ტუტე ლითონის შენადნობი, თხევადი, N.O.S. კალიუმ-ნატრიუმის შენადნობები, თხევადი ლითონორგანული ნივთიერება, თხევადი, წყალთან რეაგირებადი წყალთან რეაგირებადი სითხე, N.O.S. 1390 3401 3402 3170 3170 3403 3404 1393 1409 3208 3395 2813 ტუტე ლითონების ამიდები ტუტე ლითონის ამალგამი, მყარი ტუტე-მიწა ლითონის ამალგამი, მყარი ალუმინის მდნარი თანაპროდუქტები, ან ალუმინის გადამდნარი თანაპროდუქტები კალიუმ-ლითონის შენადნობები, მყარი კალიუმ-ნატრიუმის შენადნობები, მყარი ტუტე-მიწა ლითონის შენადნობები, N.O.S. ლითონის ჰიდრიდები, წყალთან რეაგირებადი, N.O.S. ლითონის ნივთიერება, წყალთან რეაგირებადი, N.O.S. ლითონორგანული ნივთიერება, მყარი, წყალთან რეაგირებადი წყალთან რეაგირებადი მყარი ნივთიერება, N.O.S. 3292 3292 ნატრიუმის შემცველი ბატარეები, ან ნატრიუმის შემცველი ელემენტები სითხეები, ადვილაალებადი WF1 3482 3482 3399 დისპერსიული ტუტე ლითონი, ადვილაალებადი ან დისპერსიული ტუტე-მიწა ლითონი, ადვილაალებადი ლითონორგანული ნივთიერება, თხევადი, წყალთან რეაგირებადი, ადვილაალებადი მყარი ნივთიერებები, ადვილაალებადი WF2 3396 3132 ლითონორგანული ნივთიერება, მყარი, წყალთან რეაგირებადი, ადვილაალებადი წყალთან რეაგირებადი მყარი ნივთიერება, ადვილაალებადი, N.O.S. 3397 3209 3135 ლითონორგანული ნივთიერება, მყარი, წყალთან რეაგირებადი, თვითთბობადი ლითონის ნივთიერება, წყალთან რეაგირებადი, თვითთბობადი, N.O.S. წყალთან რეაგირებადი მყარი ნივთიერება, თვითთბობადი, N.O.S. 3133 წყალთან რეაგირებადი მყარი ნივთიერება, მჟანგავი, N.O.S. (არ არის დაშვებული, იხილეთ 2.2.43.2 პუნქტი) 3130 წყალთან რეაგირებადი სითხე, ტოქსიკური, N.O.S. მყარი ნივთიერებები, თვითთბობადი მყარი ნივთიერებები, მჟანგავი ტოქსიკური WT კოროზიული WC WSბ WO სითხე WT1 მყარი ნივთიერება WT2 3134 წყალთან რეაგირებადი მყარი ნივთიერება, ტოქსიკური, N.O.S. სითხე WC1 3129 წყალთან რეაგირებადი სითხე, კოროზიული, N.O.S. მყარი ნივთიერება WC2 3131 წყალთან რეაგირებადი მყარი ნივთიერება, კოროზიული, N.O.S. ადვილაალებადი, კოროზიული WFCგ 2988 ქლორსილანები, წყალთან რეაგირებადი, ადვილაალებადი, კოროზიული, N.O.S. (აღნიშნული კლასიფიკაციის კოდით არ არის წარმოდგენილი რაიმე სხვა ერთობლივი პოზიცია, საჭიროების შემთხვევაში კლასიფიკაცია ამა თუ იმ ერთობლივ პოზიციაზე რომელიმე კლასიფიკაციის კოდით განისაზღვრება 2.1.3.10 პუნქტში გათვალისწინებული საშიშროებების პრიორიტეტულობის ცხრილის შესაბამისად) 226 ლითონები ან ლითონის შენადნობები, რომლებიც, წყალთან შეხებისას, არ გამოყოფს ადვილაალებად აირებს და არ წარმოადგენს პიროფორულს ან თვითთბობადს, თუმცა ატარებს ადვილაალებად ხასიათს, წარმოადგენს 4.1 კლასის ნივთიერებებს. ტუტე-მიწა ლითონები და ტუტე-მიწა ლითონების შენადნობები პიროფორული ფორმით წარმოადგენს 4.2 კლასის ნივთიერებებს. ლითონის მტვერი და ფხვნილი პიროფორული ფორმით, წარმოადგენს 4.2 კლასის ნივთიერებებს. ლითონები და ლითონის შენადნობები პიროფორული ფორმით წარმოადგენს 4.2 კლასის ნივთიერებებს. ფოსფორის ნარევები მძიმე ლითონებით, როგორიცაა რკინა, სპილენძი და ა.შ. ექვემდებარება ADR-ით გათვალიწინებულ დებულებებს. ბ ლითონები და ლითონის შენადნობები პიროფორული ფორმით წარმოადგენს 4.2 კლასის ნივთიერებებს. გ ქლორსილანები, რომელთა აფეთქების ტემპერატურა 230C-ზე ნაკლებია და რომლებიც, წყალთან შეხებისას, არ გამოყოფს ადვილაალებად აირებს, წარმოადგენს მე-3 კლასის ნივთიერებებს. ქლორსილანები, რომელთა აფეთქების ტემპერატურა შეადგენს ან აღემატება 230C-ს და რომლებიც, წყალთან შეხებისას, არ გამოყოფს ადვილაალებად აირებს, წარმოადგენს მე-8 კლასის ნივთიერებებს. ა 227 2.2.51 კლასი 5.1 2.2.51.1. კრიტერიუმები 2.2.51.1.1 5.1 კლასის სახელწოდებაში შედის ნივთიერებები, რომლებსაც ისე, რომ თავად არ წარმოადგენდეს აალებადს, შეუძლია, ზოგადად ჟანგბადის გამომუშავებით, გამოიწვიოს ან ხელი შეუწყოს სხვა მასალებისა და აღნიშნული ნივთიერებების შემცველი ნაკეთობების აალებას. 2.2.51.1.2 5.1 კლასის ნივთიერებები და აღნიშნული ნივთიერებების შემცველი მასალები იყოფა შემდეგნაირად: O მჟანგავი ნივთიერებები მჟანგავი ნივთიერებები, დამატებითი ნივთიერებების შემცველი ნაკეთობები; O1 O2 O3 რისკის გარეშე და აღნიშნული შეხებისას, გამოყოფს თხევადი; მყარი; ნაკეთობები; OF მჟანგავი ნივთიერებები, მყარი, ადვილაალებადი; OS მჟანგავი ნივთიერებები, მყარი, თვითთბობადი; OW მჟანგავი ნივთიერებები, ადვილაალებად აირებს; OT მჟანგავი ნივთიერებები, ტოქსიკური: OC OT1 თხევადი; OT2 მყარი; მჟანგავი ნივთიერებები, კოროზიული: OTC OC1 თხევადი; OC2 მყარი; მჟანგავი ნივთიერებები, ტოქსიკური, კოროზიული. რომლებიც წყალთან 2.2.51.1.3 5.1 კლასში კლასიფიცირებული ნივთიერებებისა და ნაკეთობების ჩამონათვალი მოცემულია 3.2 თავის A ცხრილში. იმ ნივთიერებებისა და ნაკეთობების კლასიფიკაცია, რომლებიც არ არის მითითებული დასახელებით 3.2 თავის A ცხრილში 2.2.51.3 პუნქტის შესაბამის პოზიციაზე, 2.1 თავის დებულებების თანახმად შესაძლებელია დაეფუძნოს ქვემოთ წარმოდგენილ 2.2.51.1.6-2.2.51.1.9 პუნქტებსა და აგრეთვე ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.4 კარში მოყვანილ ცდებს, მეთოდებსა და კრიტერიუმებს. ცდების შედეგებსა და პრაქტიკულ გამოცდილებას შორის შეუსაბამობის არსებობის შემთხვევაში, უპირატესობა მიენიჭება პრაქტიკული გამოცდილების საფუძველზე მიღებულ გადაწყვეტილებებს ცდების შედეგებთან შედარებით. 2.2.51.1.4 იმ შემთხვევაში, თუ 5.1 კლასის ნივთიერებები, მათში დანამატების შეტანის შედეგად, მოხვდებიან საფრთხის სხვადასხვა კატეგორიაში, რომელთაც მიეკუთვნება 3.2 თავის A ცხრილში დასახელებით მითითებული ნივთიერებები, აღნიშნული ნარევების კლასიფიკაცია მოხდება იმ პოზიციებზე, რომელთაც ისინი მიეკუთვნება მათ მიერ წარმოსდგენილი საფრთხის ფაქტიური ხარისხის მიხედვით. 228 შენიშვნა: ხსნარებისა და ნარევების (როგორიცაა პრეპარატები და ნარჩენები) კლასიფიკაციასთან დაკავშირებით იხილეთ აგრეთვე 2.1.3 პუნქტი. 2.2.51.1.5 ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 33.4 კარში გათვალისწინებული საცდელი პროცედურებისა და 2.2.51.1.6-2.2.51.19 ქვეპუნქტებში მოყვანილი კრიტერიუმების საფუძველზე შესაძლებელია ასევე განისაზღვროს, არის თუ არა რომელიმე, 3.2 თავის A ცხრილში დასახელებით მითითებული ნივთიერების მახასიათებელი ისეთი სახის, რომ აღნიშნულ ნივთიერებაზე არ გავრცელდეს მოცემული კლასის დებულებები. მჟანგავი მყარი ნივთიერებები კლასიფიკაცია 2.2.51.1.6 იმ შემთხვევაში, თუ ის მჟანგავი მყარი ნივთიერებები, რომლებიც 3.2 თავის A ცხრილში არ არის მითითებული დასახელებით, განეკუთვნება 2.2.51.3 პუნქტში წარმოდგენილი პოზიციიდან ერთ-ერთს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 34.4.1 პუნქტში (ცდა 0.1) ან 34.4.3 პუნქტში (ცდა 0.3) გათვალისწინებული ცდების პროცედურების შესაბამისად, გამოიყენება შემდეგი კრიტერიუმები: (ა) 0.1 ცდის შემთხვევაში - მყარი ნივთიერება უნდა მიეკუთვნოს 5.1 კლასს იმ შემთხვევაში, თუ 4:1 ან 1:1 კოეფიციენტით (მასის მიხედვით) ნიმუშიცელულოზის სახით წარმოდგენისას, იგი აალდება ან იწვის ან ავლენს წვის საშუალო ხანგრძლივობას, რაც ტოლია ან ნაკლებია კალიუმის ბრომატისა და ცელულოზის 3:7 კოეფიციენტის ნარევის (მასის მიხედვით) შემთხვევაში საჭირო წვის საშუალო ხანგრძლივობაზე; ან (ბ) 0.3 ცდის შემთხვევაში - მყარი ნივთიერება უნდა მიეკუთვნოს 5.1 კლასს იმ შემთხვევაში, თუ 4:1 ან 1:1 კოეფიციენტით (მასის მიხედვით) ნიმუშიცელულოზის სახით წარმოდგენისას, იგი ავლენს წვის საშუალო ხანგრძლივობას, რაც ტოლია ან მეტია კალციუმის ზეჟანგის და ცელულოზის 1:2 კოეფიციენტის ნარევის (მასის მიხედვით) შემთხვევაში საჭირო წვის საშუალო ხანგრძლივობაზე. მიკუთვნება შესაბამის შეფუთვის ჯგუფებზე 2.2.51.1.7 3.2 თავის A ცხრილში სხვადასხვა პოზიციებზე კლასიფიცირებული მჟანგავი მყარი ნივთიერებები მიეკუთვნება I, II ან III შეფუთვის ჯგუფებს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 34.4.1 პუნქტში (ცდა 0.1) ან 34.4.3 პუნქტში (ცდა 0.3) გათვალისწინებული საცდელი პროცედურების მიხედვით, შემდეგი კრიტერიუმების შესაბამისად: (ა) 0.1 ცდა (i) I შეფუთვის ჯგუფი: ნებისმიერი ნივთიერების, რომელიც ნიმუშიცელულოზის 4:1 ან 1:1 კოეფიციენტით (მასის მიხედვით) გამოცდისას, წვის საშუალო ხანგრძლივობა ნაკლებია კალიუმის ბრომატისა და ცელულოზის 3:2 კოეფიციენტის ნარევის (მასის მიხედვით) წვის საშუალო ხანგრძლივობაზე; 229 (ბ) (ii) II შეფუთვის ჯგუფი: ნებისმიერი ნივთიერების, რომელიც ნიმუშიცელულოზის 4:1 ან 1:1 კოეფიციენტით (მასის მიხედვით) გამოცდისას, წვის საშუალო ხანგრძლივობა თანაბარია ან ნაკლებია კალიუმის ბრომატისა და ცელულოზის 2:3 კოეფიციენტის ნარევის (მასის მიხედვით) წვის საშუალო ხანგრძლივობაზე და ვერ აკმაყოფილებს I შეფუთვის ჯგუფთან დაკავშირებით არსებულ კრიტერიუმებს; (iii) III შეფუთვის ჯგუფი: ნებისმიერი ნივთიერების, რომელიც ნიმუშიცელულოზის 4:1 ან 1:1 კოეფიციენტით (მასის მიხედვით) გამოცდისას, წვის საშუალო ხანგრძლივობა თანაბარია ან ნაკლებია კალიუმის ბრომატისა და ცელულოზის 3:7 კოეფიციენტის ნარევის (მასის მიხედვით) წვის საშუალო ხანგრძლივობაზე და ვერ აკმაყოფილებს I და II შეფუთვის ჯგუფებთან დაკავშირებით არსებულ კრიტერიუმებს. 0.1 ცდა (i) I შეფუთვის ჯგუფი: ნებისმიერი ნივთიერების, რომელიც ნიმუშიცელულოზის 4:1 ან 1:1 კოეფიციენტით (მასის მიხედვით) გამოცდისას, წვის საშუალო ხანგრძლივობა ნაკლებია კალციუმის ზეჟანგისა და ცელულოზის 3:1 კოეფიციენტის ნარევის (მასის მიხედვით) წვის საშუალო ხანგრძლივობაზე; (ii) II შეფუთვის ჯგუფი: ნებისმიერი ნივთიერების, რომელიც ნიმუშიცელულოზის 4:1 ან 1:1 კოეფიციენტით (მასის მიხედვით) გამოცდისას, წვის საშუალო ხანგრძლივობა თანაბარია ან ნაკლებია კალციუმის ზეჟანგისა და ცელულოზის 1:1 კოეფიციენტის ნარევის (მასის მიხედვით) წვის საშუალო ხანგრძლივობაზე და ვერ აკმაყოფილებს I შეფუთვის ჯგუფთან დაკავშირებით არსებულ კრიტერიუმებს; (iii) III შეფუთვის ჯგუფი: ნებისმიერი ნივთიერების, რომელიც ნიმუშიცელულოზის 4:1 ან 1:1 კოეფიციენტით (მასის მიხედვით) გამოცდისას, წვის საშუალო ხანგრძლივობა თანაბარია ან ნაკლებია კალციუმის ზეჟანგისა და ცელულოზის 1:2 კოეფიციენტის ნარევის (მასის მიხედვით) წვის საშუალო ხანგრძლივობაზე და ვერ აკმაყოფილებს I და II შეფუთვის ჯგუფებთან დაკავშირებით არსებულ კრიტერიუმებს. მჟანგავი სითხეები კლასიფიკაცია 2.2.51.1.8 იმ შემთხვევაში, თუ ის მჟანგავი სითხეები, რომლებიც 3.2 თავის A ცხრილში არ არის მითითებული დასახელებით, განეკუთვნება 2.2.51.3 პუნქტში მოყვანილი პოზიციიდან რომელიმეს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 34.4.2 პუნქტში გათვალისწინებული ცდების პროცედურების შესაბამისად, გამოიყენება შემდეგი კრიტერიუმები: თხევადი ნივთიერება უნდა მიეკუთვნოს 5.1 კლასს იმ შემთხვევაში, თუ 1:1 კოეფიციენტით (მასის მიხედვით) გამოცდილი ნივთიერებისა და ცელულოზის სახით წარმოდგენისას, იგი გამოავლენს 2070 კპა ან უფრო მეტ მანომეტრულ მაქსიმალურ წნევას, ხოლო წნევის გაზრდის საშუალო დრო თანაბარია ან ნაკლებია 1:1 230 თანაფარდობით წარმოდგენილი 65% აზოტმჟავისა და ცელულოზის წყალხსნარის, მასის მიხედვით, წნევის ზრდის საშუალო დროზე. მიკუთვნება შესაბამის შეფუთვის ჯგუფებზე 2.2.51.1.9 3.2 თავის A ცხრილში სხვადასხვა პოზიციებზე კლასიფიცირებული მჟანგავი სითხეები მიეკუთვნება I, II ან III შეფუთვის ჯგუფებს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 34.4.2 კარით გათვალისწინებული საცდელი პროცედურების მიხედვით, შემდეგი კრიტერიუმების შესაბამისად: (ა) I შეფუთვის ჯგუფი: ნებისმიერი ნივთიერება, რომელიც ნივთიერებისა და ცელულოზის 1:1 თანაფარდობის ნარევის, მასის მიხედვით, სახით წარმოდგენისას, ხასიათდება თვითაალებით; ან ნივთიერებისა და ცელულოზის 1:1 თანაფარდობის ნარევის, მასის მიხედვით, წნევის მომატების საშუალო დრო ნაკლებია ქლორხსნარისა და ცელულოზის 50%-იანი 1:1 თანაფარდობის ხსნარის, მასის მიხედვით, წნევის მომატების საშუალო დროზე; (ბ) II შეფუთვის ჯგუფი: ნებისმიერი ნივთიერება, რომელიც ნივთიერებისა და ცელულოზის 1:1 თანაფარდობის ნარევის, მასის მიხედვით, სახით წარმოდგენისას, ხასიათდება 40%-იანი ნატრიუმ-ქლორის წყალხსნარისა და ცელულოზის 1:1 თანაფარდობის მქონე ნარევის, მასის მიხედვით, წნევის მომატების საშუალო დროის თანაბარ ან ნაკლებ წნევის მომატების საშუალო დროზე, და ვერ აკმაყოფილებს I შეფუთვის ჯგუფთან დაკავშირებით არსებულ კრიტერიუმებს; (გ) III შეფუთვის ჯგუფი: ნებისმიერი ნივთიერება, რომელიც ნივთიერებისა და ცელულოზის 1:1 თანაფარდობის ნარევის, მასის მიხედვით, სახით წარმოდგენისას, ხასიათდება 65%-იანი აზოტმჟავის წყალხსნარისა და ცელულოზის 1:1 თანაფარდობის მქონე ნარევის, მასის მიხედვით, წნევის მომატების საშუალო დროის თანაბარ ან ნაკლებ წნევის მომატების საშუალო დროს, და ვერ აკმაყოფილებს I და II შეფუთვის ჯგუფებთან დაკავშირებით არსებულ კრიტერიუმებს. 2.2.51.2 ნივთიერებები, რომლებიც არ დაიშვება გადაზიდვებზე 2.2.51.2.1 5.1 კლასის ქიმიურად არასტაბილური ნივთიერებები არ დაიშვება გადაზიდვებზე, სანამ არ მოხდება შესაბამისი ღონისძიებების მიღება გადაზიდვების დროს მათი სახიფათო დაშლის ან პოლიმერიზაციის პრევენციის მიზნით. აღნიშნულთან დაკავშირებით განსაკუთრებული სიფრთხილის ზომები უნდა იქნეს დაცული იმ ფაქტის უზრუნველსაყოფად, რომ ჭურჭელი ან ცისტერნები არ შეიცავდეს რაიმე ისეთ ნივთიერებას, რომელმაც შეიძლება გამოიწვიოს აღნიშნული რეაქციები. 2.2.51.2.2 გადაზიდვაზე არ დაიშვება შემდეგი ნივთიერებები და ნარევები: - მჟანგავი, თვითთბობადი მყარი ნივთიერებები, გაეროს N3100, მჟანგავი, წყალთან რეაგირებადი მყარი ნივთიერებები, გაეროს N3121 და მჟანგავი, ადვილაალებადი მყარი ნივთიერებები, გაეროს N3137, თუ ისინი ვერ აკმაყოფილებს პირველი კლასით გათვალისწინებულ მოთხოვნებს (იხილეთ აგრეთვე პუნქტი 2.1.3.7); 231 - წყალბადის პეროქსიდი, არასტაბილიზებული ან წყალბადის პეროქსიდის წყალხსნარები, არასტაბილიზებული, რომელიც შეიცავს 60%-ზე მეტი წყალბადის პეროქსიდს, - აალებადი მინარევების შემცველი ტეტრანიტრომეთანი; - ქლორმჟავას ხსნარები, რომლებიც შეიცავს 72%-ზე მეტ (მასის მიხედვით) მჟავას ან ქლორმჟავას ნარევები ნებისმიერ სითხესთან ერთად, გარდა წყლისა; - ქლორმჟავას ხსნარი, რომელიც შეიცავს 10%-ზე მეტ ქლორმჟავას ან ქლორმჟავას ნარევებს ნებისმიერ სითხესთან ერთად, გარდა წყლისა; - ჰალოგენიზებული ფტორის ნარევები გარდა 5.1 კლასით გათვალისწინებული გაეროს N1745 - ბრომის პენტაფტორიდი; N1746 - ბრომის ტრიფტორიდი და 2495 იოდის პენტაფტორიდი, ასევე მე-2 კლასით გათვალისწინებული გაეროს N1749 ქლორის ტრიფტორიდი და 2548 - ქლორის პენტაფტორიდი. - ამონიუმის ქლორატი და მისი წყალხსნარები, ასევე ქლორატის ნარევები ამონიუმის მარილთან ერთად; - ამონიუმის ქლორიტი და მისი წყალხსნარები, ასევე ქლორიტის ნარევები ამონიუმის მარილთან ერთად; - ჰიპოქლორიტის ნარევები ამონიუმის მარილთან ერთად; - ამონიუმის ბრომატი და მისი წყალხსნარები, ასევე ბრომატის ნარევები ამონიუმის მარილთან ერთად; - ამონიუმის პერმანგანატი და მისი წყალხსნარები, ასევე პერმანგანატის ნარევები ამონიუმის მარილთან ერთად; - 0.2% წვადი ნივთიერებების (მათ შორის ნებისმიერი ორგანული ნივთიერების, რომლის გაანგარიშებაც ხდება ნახშირბადის სახით) შემცველი ამონიუმის ნიტრატი, თუ ის არ წარმოადგენს პირველი კლასით გათვალისწინებული ნივთიერებისა თუ ნაკეთობის კომპონენტს; - ამონიუმის ნიტრატის შემცველი სასუქები (ამონიუმის ნიტრატის შემადგენლობის განსაზღვრისას, ნიტრატის ყველა იონი, რომლებთან დაკავშირებითაც ამონიუმის იონების მოლეკულური ეკვივალენტი წარმოდგენილია ნარევში, გაანგარიშდება ამონიუმის ნიტრატის სახით) ან წვადი ნივთიერებების შემცველი სასუქები, რომლებიც აღემატება 307-ე სპეციალურ დებულებაში წარმოდგენილ მნიშვნელობებს, გარდა პირველი კლასით დაშვებული პირობებისა; - ამონიუმის ნიტრიტი და მისი წყალხსნარები, ასევე არაორგანული ნიტრიტის ნარევები ამონიუმის მარილთან ერთად; - კალიუმის ნიტრატის, ნატრიუმის ნიტრიტისა და ამონიუმის მარილის ნარევები. 232 2.2.51.3 ერთობლივი პოზიციების ჩამონათვალი მჟანგავი ნივთიერებები დამატებითი საშიშროების გარეშე O თხევადი O1 მყარი O2 ნაკეთობები O3 მყარი ნივთიერებები ადვილაალებადი OF მყარი ნივთიერებები თვითთბობადი OS მყარი ნივთიერებები წყალთან რეაგირებადი OW ტოქსიკური OT სითხე კოროზიული OC ტოქსიკური, კოროზიული არაორგანული წყალხსნარის ქლორატები, N.O.S. არაორგანული წყალხსნარის პერქლორატები, N.O.S. არაორგანული წყალხსნარის ბრომატები, N.O.S. არაორგანული წყალხსნარის პერმანგანატები, N.O.S. არაორგანული წყალხსნარის პერსულფატები, N.O.S. არაორგანული წყალხსნარის ნიტრატები, N.O.S. არაორგანული წყალხსნარის ნიტრიტები, N.O.S. მჟანგავი სითხე, N.O.S. 1450 1461 1462 1477 1481 1482 1483 2627 3212 3215 1479 არაორგანული ბრომატები, N.O.S. არაორგანული ქლორატები, N.O.S. არაორგანული ქლორიტები, N.O.S. არაორგანული ნიტრატები, N.O.S. არაორგანული პერქლორატები, N.O.S. არაორგანული პერმანგანატები, N.O.S. არაორგანული პეროქსიდები, N.O.S. არაორგანული ნიტრიტები, N.O.S. არაორგანული ჰიპოქლორიტები, N.O.S. არაორგანული პერსულფატები, N.O.S. მჟანგავი მყარი ნივთიერება, N.O.S. 3356 ჟანგბადის გენერატორი, ქიმიური 3137 მჟანგავი მყარი ნივთიერება, ადვილაალებადი N.O.S. (არ არის დაშვებული, იხილეთ 2.2.51.2 პუნქტი) 3100 მჟანგავი მყარი ნივთიერება, თვითთბობადი, N.O.S. (არ არის დაშვებული, იხილეთ 2.2.51.2 პუნქტი) 3121 მჟანგავი მყარი ნივთიერება, წყალთან რეაგირებადი, N.O.S. (არ არის დაშვებული, იხილეთ 2.2.51.2 პუნქტი) 3099 მჟანგავი სითხე, ტოქსიკური, N.O.S. 3087 მჟანგავი მყარი ნივთიერება, ტოქსიკური, N.O.S. 3098 მჟანგავი სითხე, კოროზიული, N.O.S. 3085 მჟანგავი მყარი ნივთიერება, კოროზიული, N.O.S. OT1 მყარი ნივთიერება OT2 სითხე 3210 3211 3213 3214 3216 3218 3219 3139 OC1 მყარი ნივთიერება OC2 OTC (აღნიშნული კლასიფიკაციის კოდით არ არის წარმოდგენილი რაიმე სხვა ერთობლივი პოზიცია, საჭიროების შემთხვევაში კლასიფიკაცია ამა თუ იმ ერთობლივ პოზიციაზე რომელიმე კლასიფიკაციის კოდით განისაზღვრება 2.1.3.10 პუნქტში გათვალისწინებული საშიშროებების პრიორიტეტულობის ცხრილის შესაბამისად) 233 2.2.52 კლასი 5.2 ორგანული პეროქსიდები 2.2.52.1 კრიტერიუმები 2.2.52.1.1 5.2 კლასის სახელწოდებაში შედის ორგანული პეროქსიდები და ორგანული პეროქსიდის შემადგენლობები. 2.2.52.1.2 5.2 კლასი ნივთიერებები იყოფა შემდეგი სახით: P1 ორგანული პეროქსიდები, დარეგულირებას; P2 ორგანული პეროქსიდები, დარეგულირებას. რომლებიც რომლებიც არ საჭიროებს ტემპერატურის საჭიროებს ტემპერატურის განმარტება 2.2.52.1.3 ორგანული პეროქსიდები წარმოადგენს ორგანულ ნივთიერებებს, რომლებიც შეიცავს ორვალენტიან სტრუქტურას -O-O- და ითვლება წყალბადის პეროქსიდის წარმოებულად, სადაც ერთ-ერთი ან ორივე წყალბადის ატომი იცვლება ორგანული რადიკალებით. თვისებები 2.2.52.1.4 ორგანული პეროქსიდები უზრუნველყოფს ეგზოთერმულ დაშლას ნორმალურ ან მაღალ ტემპერატურაზე. დაშლა შესაძლებელია დაიწყოს სითბოს ზემოქმედების ქვეშ, ნარჩენებთან შეხებისას (მაგალითად, მჟავებთან, მძიმე ლითონის ნაერთებთან, ამინებთან) ხახუნისა თუ დარტყმის შედეგად. დაშლის სიჩქარე იზრდება ტემპერატურის ზრდასთან ერთად და განსხვავდება ორგანული პეროქსიდების შემადგენლობების მიხედვით. დაშლამ შეიძლება გამოიწვიოს საზიანო ან ადვილაალებადი აირებისა თუ ორთქლის წარმოშობა. ცალკეულ ორგანულ პეროქსიდთან დაკავშირებით უნდა მოხდეს ტემპერატურის დარეგულირება გადაზიდვების დროს. ზოგიერთი ორგანული პეროქსიდი შესაძლებელია დაიშალოს აფეთქებით, განსაკუთრებით თუ ისინი მოთავსებულია დახურულ სივრცეში. აღნიშნული მახასიათებლის შეცვლა შესაძლებელია გამაზავებელი ნივთიერების დამატებით ან შესაბამისი ტარის გამოყენებით. ბევრი ორგანული პეროქსიდი იწვის ინტენსიურად. თავიდან უნდა იქნეს არიდებული ორგანული პეროქსიდის შეხება თვალთან. ზოგიერთი ორგანული პეროქსიდი იწვევს თვალის რქოვანას სერიოზულ დაზიანებას, ხანმოკლე შეხების შემთხვევაშიც კი, ან წვავს კანს. შენიშვნა: ორგანული პეროქსიდების აალებადობის განმსაზღვრელი ცდების მეთოდები მოყვანილია ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 32.4 კარში. ვინაიდან ორგანულმა პეროქსიდებმა შესაძლებელია გამოიწვიოს მძლავრი რეაქცია გახურების შემთხვევაში, მათი აფეთქების ტემპერატურის განსაზღვრის მიზნით რეკომენდებულია მცირე ზომის ნიმუშების შერჩევა, რაც აღწერილია ISO 3679:1983 სტანდარტში. კლასიფიკაცია 2.2.52.1.5 ორგანული პეროქსიდები კლასიფიცირდება 5.2 კლასში, გარდა იმ შემთხვევებისა, როდესაც ორგანული პეროქსიდის შემადგენლობაში წარმოდგენილია: (ა) არაუმეტეს 1.0% ორგანული პეროქსიდისგან თავისუფალი ჟანგბადი იმ შემთხვევაში, თუ შეიცავს არაუმეტეს 1.0% წყალბადის პეროქსიდს; 234 (ბ) არაუმეტეს 0.5% ორგანული პეროქსიდისგან თავისუფალი ჟანგბადი იმ შემთხვევაში, თუ შეიცავს 1.0%-ზე მეტ, თუმცა 7.0%-ზე ნაკლებ წყალბადის პეროქსიდს. შენიშვნა: ორგანული პეროქსიდის შემადგენლობაში (%) არსებული თავისუფალი ჟანგბადი წარმოდგენილია შემდეგი ფორმულით: 16 x ∑ (ni x co/mi) სადაც: ni = პეროქსიდის ჯგუფების რაოდენობა i ორგანული პეროქსიდის ყოველ მოლეკულაზე; ci = i ორგანული პეროქსიდის კონცენტრაცია (მასა %); და mi = i ორგანული პეროქსიდის მოლეკულური მასა. 2.2.52.1.6 ორგანული პეროქსიდები იყოფა შვიდ ტიპად მათ მიერ წარმოდგენილი საშიშროების ხარისხის მიხედვით. ორგანული პეროქსიდების ტიპები იცვლება A ტიპიდან, რომელიც არ დაიშვება გადაზიდვებზე იმ ტარაში, რომელშიც განხორციელდა მისი გამოცდა, G ტიპამდე, რომელიც არ ექვემდებარება 5.2 კლასის დებულებებს. B-F ტიპების კლასიფიკაცია პირდაპირ კავშირშია ერთ ტარაში დაშვებულ მაქსიმალურ ოდენობასთან. პრინციპები, რომლებიც გამოიყენება იმ ნივთიერებების კლასიფიკაციისთვის, რომლებიც არ არის წარმოდგენილი 2.2.52.4 პუნქტში, მოყვანილია ცდებისა და კრიტერიუმების სახელმძღვანელოს II ნაწილში. 2.2.52.1.7 ორგანული პეროქსიდები, რომელთა კლასიფიკაციაც უკვე განხორციელდა და უკვე დაშვებულია გადაზიდვებზე ტარაში, წარმოდგენილია 2.2.52.4 პუნქტში; ორგანული პეროქსიდები, რომლებიც უკვე დაშვებულია გადაზიდვებზე მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებში, გათვალისწინებულია 4.1.4.2 პუნქტში, IBC20 შეფუთვის ინსტრუქციაში და 4.2 და 4.3 თავების შესაბამისად ცისტერნებში გადაზიდვებზე უკვე დაშვებული ორგანული პეროქსიდები, წარმოდგენილია 4.2.5.2 პუნქტში - T23 ინსტრუქციაში გადამზიდ ცისტერნებთან დაკავშირებით. ყოველი ზემოაღნიშნული დაშვებული ნივთიერება მიეკუთვნება 3.2 თავის A ცხრილში გათვალისწინებულ გენერიულ პოზიციას (გაეროს №3101-დან 3120-მდე), ასევე წარმოდგენილია შესაბამისი დამატებითი რისკები და სატრანსპორტო ინფორმაციის შემცველი შენიშვნები. აღნიშნულ გენერიულ პოზიციებზე გათვალისწინებულია: - B-F ტიპის ორგანული პეროქსიდები (იხილეთ ზემოაღნიშნული 2.2.52.1.6 ქვეპუნქტი); - ფიზიკური მდგომარეობა (თხევადი/მყარი); და - ტემპერატურის რეგულირება (საჭიროების შემთხვევაში), იხილეთ 2.2.52.1.15დან 2.2.52.1.8 ქვეპუნქტები. მოცემული შემადგენლობის ნარევების კლასიფიკაცია შესაძლებელია ორგანული პეროქსიდების ყველაზე სახიფათო კომპონენტის ტიპის სახით და შესაძლებელია გადაზიდულ იქნეს აღნიშნულ ტიპთან დაკავშირებით განსაზღვრული გადაზიდვის პირობების შესაბამისად. თუმცა, ვინაიდან ორ სტაბილურ კომპონენტს შეუძლია წარმოქმნას თერმულად ნაკლებად სტაბილური ნარევი, უნდა განისაზღვროს ნარევის 235 თვითაჩქარებული დაშლის ტემპერატურა (თადტ) და, აუცილებლობის შემთხვევაში, თვითაჩქარებული დაშლის ტემპერატურის საფუძველზე მიღებული საკონტროლო და ავარიული ტემპერატურებიც, 2.2.52.1.16 ქვეპუნქტის შესაბამისად. 2.2.52.1.8 ორგანული პეროქსიდების, ორგანული პეროქსიდების შემადგენლობებისა თუ ნარევების, რომლებიც არ არის წარმოდგენილი 2.2.52.4, 4.1.4.2 პუნქტებში, IBC520 შეფუთვის ინსტრუქციასა თუ 4.2.5.2 პუნქტში, TC23 ინსტრუქციაში გადამზიდ ცისტერნებთან დაკავშირებით, კლასიფიცირება ერთობლივ პოზიციაზე ხორციელდება წარმოშობის ქვეყნის კომპეტენტური ორგანოს მიერ. ოფიციალური დასტურის შესახებ განცხადება უნდა ითვალისწინებდეს კლასიფიკაციასა და გადაზიდვების შესაბამის პირობებს. იმ შემთხვევაში, თუ წარმოშობის ქვეყანა არ წარმოადგენს ADR-ის ხელშემკვრელ მხარეს, კლასიფიკაცია და გადაზიდვის პირობები აღიარებულ უნდა იქნეს გადაზიდვების მარშრუტზე ADR-ის პირველი ხელშემკვრელი მხარის კომპეტენტური ორგანოს მიერ. 2.2.52.1.9 ორგანული პეროქსიდების ნიმუშები ან ორგანული პეროქსიდების შემადგენლობები, რომლებიც არ არის წარმოდგენილი 2.2.52.4 პუნქტში, რომლებთან დაკავშირებითაც არ არის მოცემული ცდების შედეგების შესახებ სრული ინფორმაცია და რომელთა გადაზიდვაც უნდა მოხდეს შემდგომი ცდების ან შეფასებების განსახორციელებლად, განეკუთვნება C ტიპის ორგანულ პეროქსიდებთან დაკავშირებული შესაბამისი პოზიციებიდან ერთ-ერთს იმ პირობით, თუ დაკმაყოფილდება შემდეგი პირობები: - ხელთ არებული მონაცემები მიუთითებს, რომ ნიმუში არ შეიძლება იყოს უფრო სახიფათო, ვიდრე B ტიპის ორგანული პეროქსიდები; - ნიმუში შეფუთულია OP2 შეფუთვის მეთოდის შესაბამისად და რაოდენობა ყოველ სატრანსპორტო ერთეულზე შემოიფარგლება 10 კგ-ით; - ხელთ არსებული ინფორმაცია მიუთითებს, რომ საკონტროლო ტემპერატურა, ასეთის არსებობის შემთხვევაში, საკმარისად დაბალია ნებისმიერი სახიფათო დაშლის პრევენციისათვის და საკმარისად მაღალია ნებისმიერი სახიფათო ფაზების გაყოფის პრევენციისთვის. ორგანული პეროქსიდების დესენსიბილიზაცია 2.2.52.1.10 გადაზიდვების დროს უსაფრთხოების უზრუნველყოფის მიზნით, ორგანული პეროქსიდები ხშირ შემთხვევაში დესენსიბილიზდება ორგანული სითხეებისა თუ მყარი ნივთიერებების, არაორგანული მყარი ნივთიერებებისა თუ წყლების გამოყენებით. იმ შემთხვევაში, თუ მითითებულია ნივთიერების პროცენტული შემცველობა, აღნიშნული გულისხმობს ნივთიერების პროცენტულ შემცველობას მასის მიხედვით, დამრგვალებულს უახლოეს მთლიან ციფრამდე. ზოგადად, დესენსიბილიზაცია ხორციელდება ისეთი სახით, რომ ორგანული პეროქსიდების გაჟონვის შემთხვევაში, მის კონცენტრაციამ არ მიაღწიოს სახიფათო მოცულობას. 2.2.52.1.11 თუ სხვაგვარად არ არის წარმოდგენილი ორგანული პეროქსიდების კონკრეტულ შემადგენლობასთან დაკავშირებით, დესენსიბილიზაციასთან დაკავშირებულ გამხსნელებთან გამოიყენება შემდეგი განმარტება (განმარტებები): - A ტიპის გამხსნელები წარმოადგენს ორგანულ სითხეებს, რომლებიც ეთავსება ორგანულ პეროქსიდს და რომლებსაც გააჩნიათ არანაკლებ 1500C დუღილის 236 ტემპერატურა. A ტიპის გამხსნელები შესაძლებელია გამოყენებულ იქნეს ყველა ორგანული პეროქსიდის დესენსიბილიზაციისთვის; - B ტიპის გამხსნელები წარმოადგენს ორგანულ სითხეებს, რომლებიც ეთავსება ორგანულ პეროქსიდს და რომლებსაც გააჩნიათ 1500C-ზე დაბალი, თუმცა 600Cზე მაღალი დუღილის ტემპერატურა და არანაკლებ 50C აფეთქების ტემპერატურა. B ტიპის გამხსნელები შესაძლებელია გამოყენებულ იქნეს ყველა ორგანული პეროქსიდის დესენსიბილიზაციისთვის იმ პირობით, თუ სითხის დუღილის ტემპერატურა მინიმუმ 600C-ით მაღალი იქნება თვითმაჩქარებელი დაშლის ტემპერატურაზე 50 კგ შეფუთვაში. 2.2.52.1.12 გამხსნელები, რომლებიც არ მიეკუთვნება A ან B ტიპს, შესაძლებელია დამატებულ იქნეს ორგანული პეროქსიდის შემადგენლობაში 2.2.52.4 პუნქტში მითითებული სახით, იმ პირობით, თუ ისინი ეთავსება აღნიშნულ შემადგენლობას. თუმცა აღნიშნული A ან B ტიპის გამხსნელის სრულად ან ნაწილობრივ შეცვლა სხვა, განსხვავებული თვისებების მქონე გამხსნელით საჭიროების ორგანული პეროქსიდის შემადგენლობის გადასინჯვას 5.2 კლასთან დაკავშირებით დაშვებული ჩვეულებრივი პროცედურების შესაბამისად. 2.2.52.1.13 წყლის გამოყენება შესაძლებელია ორგანული პეროქსიდების დესენსიბილიზაციისთვის, რომლებიც წარმოდგენილია 2.2.52.4 პუნქტში ან კომპეტენტური ორგანოს გადაწყვეტილებაში 2.2.52.1.8 ქვეპუნქტის შესაბამისად, მითითებებით „წყალთან“ ან „როგორც გამძლე დისპერსია წყალში“. ორგანული პეროქსიდების ნიმუშებისა თუ ორგანული პეროქსიდების შემადგენლობების, რომელთა ჩამონათვალის არ არის მოცემულია 2.2.52.4 პუნქტში, დესენსიბილიზაცია შესაძლებელია განხორციელდეს წყლით იმ პირობით, რომ დაკმაყოფილდება 2.2.52.1.9 ქვეპუნქტის მოთხოვნები. 2.2.52.1.14 ორგანული და არაორგანული მყარი ნივთიერებები შესაძლებელია გამოყენებულ იქნეს ორგანული პეროქსიდების დესენსიბილიზაციისთვის მათი შეთავსებადობის დაცვით. შეთავსებადია ის სითხეები და მყარი ნივთიერებები, რომელთაც არ გააჩნიათ უარყოფითი ზემოქმედება ორგანული პეროქსიდის შემადგენლობის თერმულ სტაბილურობასა და საშიშროების ტიპზე. ტემპერატურის რეგულირებასთან დაკავშირებული მოთხოვნები 2.2.52.1.15 ზოგიერთი ორგანული პეროქსიდის გადაზიდვა დაშვებულია მხოლოდ დარეგულირებული ტემპერატურის პირობებში. საკონტროლო ტემპერატურა წარმოადგენს მაქსიმალურ ტემპერატურას, რომელზეც შესაძლებელია ორგანული პეროქსიდის უსაფრთხო გადაზიდვა. როგორც ვარაუდობენ, რომ შეფუთვის უშუალო სიახლოვეს არსებული ტემპერატურა აღემატება 550C-ს გადაზიდვების დროს მხოლოდ შედარებით მოკლე დროის შემთხვევაში 24-საათიან პერიოდში. ტემპერატურის რეგულირების შესაძლებლობის დაკარგვის შემთხვევაში, შესაძლებელია აუცილებელი გახდეს გადაუდებელი პროცედურების სისრულეში მოყვანა. ავარიული ტემპერატურა წარმოადგენს ტემპერატურას, რომელზეც სრულდება აღნიშნული პროცედურები. 2.2.52.1.16 საკონტროლო და ავარიული ტემპერატურები წარმოიქმნება თვითაჩქარებული დაშლის ტემპერატურიდან, რომელიც განისაზღვრება, როგორც უმდაბლესი ტემპერატურა, რომელზეც ადგილი აქვს გადაზიდვების დროს გამოყენებულ ტარაში 237 წარმოდგენილი ნივთიერების თვითაჩქარებულ დაშლას (იხილეთ ცხრილი 1). თვითაჩქარებული დაშლის ტემპერატურა უნდა განისაზღვროს იმისათვის, რომ გადაწყდეს ექვემდებარება თუ არა ნივთიერება ტემპერატურის რეგულირებას გადაზიდვების დროს. თვითაჩქარებული დაშლის ტემპერატურის განაზღვრებასთან დაკავშირებული დებულებები წარმოდგენილია ცდებისა და კრიტერიუმების სახელმძღვანელოს II ნაწილის მე-20 თავსა და 28.4 კარში. ცხრილი 1: საკონტროლო და ავარიული ტემპერატურების განსაზღვრა ჭურჭლის ტიპი ცალკეული ტარა და მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერი თვითაჩქარებული დაშლის ტემპერატურაა 200C ან უფრო ნაკლები 200C-ზე მეტი, მაგრამ 350C-ზე ნაკლები 350C-ზე მეტი ცისტერნები არაუმეტეს 500C ტემპერატურისა საკონტროლო ტემპერატურა ავარიული ტემპერატურა 200C თვითაჩქარებულ დაშლის ტემპერატურაზე ქვემოთ 150C თვითაჩქარებულ დაშლის ტემპერატურაზე ქვემოთ 100C თვითაჩქარებულ დაშლის ტემპერატურაზე ქვემოთ 100C თვითაჩქარებულ დაშლის ტემპერატურაზე ქვემოთ 100C თვითაჩქარებულ დაშლის ტემპერატურაზე ქვემოთ 100C თვითაჩქარებულ დაშლის ტემპერატურაზე ქვემოთ 50C თვითაჩქარებულ დაშლის ტემპერატურაზე ქვემოთ 50C თვითაჩქარებულ დაშლის ტემპერატურაზე ქვემოთ იმ ნივთიერების თვითაჩქარებული დაშლის ტემპერატურა, რომელიც შეფუთულია გადასაზიდად. ა 2.2.52.1.17 შემდეგი ორგანული პეროქსიდები ექვემდებარება ტემპერატურის რეგულირებას გადაზიდვების დროს: - B და C ტიპის ორგანული პეროქსიდები < 500C თვითაჩქარებული დაშლის ტემპერატურით; - D ტიპის ორგანული პეროქსიდის, რომელიც ავლენს საშუალო ეფექტს, როდესაც გახურდება დახურულ სივრცეში < 500C თვითაჩქარებული დაშლის ტემპერატურით ან ავლენს დაბალ ან არანაირ ეფექტს, როდესაც გახურდება დახურულ სივრცეში < 450C თვითაჩქარებული დაშლის ტემპერატურით; - E და F ტიპის ორგანული პეროქსიდები, < 450C თვითაჩქარებული დაშლის ტემპერატურით. შენიშვნა: დახურულ სივრცეში სითბოს ეფექტების განსაზღვრასთან დაკავშირებული დებულებები წარმოდგენილია ცდებისა და კრიტერიუმების სახელმძღვანელოს II ნაწილის მე-20 კარისა და 28.4 ქვეკარში. 2.2.52.1.18 აუცილებლობის შემთხვევაში, საკონტროლო და ავარიული ტემპერატურები წარმოდგენილია 2.2.52.4 პუნქტში. გადაზიდვების დროს არსებული ფაქტიური ტემპერატურა შესაძლებელია იყოს საკონტროლო ტემპერატურაზე დაბალი, თუმცა მისი შერჩევა უნდა მოხდეს ისე, რომ უზრუნველყოფილი იქნეს ფაზების სახიფათო გაყოფის პრევენცია. 2.2.52.2 ნივთიერებები, რომლებიც არ დაიშვება გადაზიდვებზე 238 A ტიპის ორგანული პეროქსიდები არ დაიშვება გადაზიდვებზე 5.2 კლასის დებულებების თანახმად (იხილეთ ცდებისა და კრიტერიუმების სახელმძღვანელოს II ნაწილის 20.4.3(ა) პუნქტი). 2.2.41.3 ერთობლივი პოზიციების ჩამონათვალი ორგანული პეროქსიდები არ საჭიროებს ტემპერატურის დარეგულირებას საჭიროებს ტემპერატურის კონტროლს 2.2.52.4 P1 P2 3101 3102 3103 3104 3105 3106 3107 3108 3109 3110 A ტიპის ორგანული პეროქსიდი, თხევადი A ტიპის ორგანული პეროქსიდი, მყარი B ტიპის ორგანული პეროქსიდი, თხევადი B ტიპის ორგანული პეროქსიდი, მყარი C ტიპის ორგანული პეროქსიდი, თხევადი C ტიპის ორგანული პეროქსიდი, მყარი D ტიპის ორგანული პეროქსიდი, თხევადი D ტიპის ორგანული პეროქსიდი, მყარი E ტიპის ორგანული პეროქსიდი, თხევადი E ტიპის ორგანული პეროქსიდი, მყარი F ტიპის ორგანული პეროქსიდი, თხევადი F ტიპის ორგანული პეროქსიდი, მყარი G ტიპის ორგანული პეროქსიდი, თხევადი G ტიპის ორგანული პეროქსიდი, მყარი არ დაიშვება გადაზიდვებზე იხილეთ 2.2.52.2 პუნქტი 3111 3112 3113 3114 3115 3116 3117 3118 3119 3120 B ტიპის ორგანული პეროქსიდი, თხევადი, დარეგულირებული ტემპერატურით B ტიპის ორგანული პეროქსიდი, მყარი, დარეგულირებული ტემპერატურით C ტიპის ორგანული პეროქსიდი, თხევადი, დარეგულირებული ტემპერატურით C ტიპის ორგანული პეროქსიდი, მყარი, დარეგულირებული ტემპერატურით D ტიპის ორგანული პეროქსიდი, თხევადი, დარეგულირებული ტემპერატურით D ტიპის ორგანული პეროქსიდი, მყარი, დარეგულირებული ტემპერატურით E ტიპის ორგანული პეროქსიდი, თხევადი, დარეგულირებული ტემპერატურით E ტიპის ორგანული პეროქსიდი, მყარი, დარეგულირებული ტემპერატურით F ტიპის ორგანული პეროქსიდი, თხევადი, დარეგულირებული ტემპერატურით F ტიპის ორგანული პეროქსიდი, მყარი, დარეგულირებული ტემპერატურით არ ექვემდებარება 5.2. კლასთან დაკავშირებით მოქმედ დებულებებს იხილეთ 2.2.52.1.6 ქვეპუნქტი შეფუთვებში პოზიციების მიხედვით ახლახანს კლასიფიცირებული ორგანული პეროქსიდების ჩამონათვალი სვეტში „შეფუთვის მეთოდი“, “OP1”-დან “OP8”-მდე კოდები მიეკუთვნება P520 შეფუთვის ინსტრუქციის 4.1.4.1 პუნქტში გათვალისწინებულ შეფუთვის მეთოდებს (იხილეთ აგრეთვე 4.1.7.1 პუნქტი). გადასაზიდი ორგანული პეროქსიდები უნდა აკმაყოფილებდეს კლასიფიკაციასა და საკონტროლო და ავარიულ ტემპერატურასთან დაკავშირებით წარმოდგენილ მოთხოვნებს (რომლებიც განისაზღვრება თვითაჩქარებული დაშლის ტემპერატურის საფუძველზე). მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებში დაშვებულ ნივთიერებებთან დაკავშირებით იხილეთ IBC520 შეფუთვის ინსტრუქციის 4.1.4.2 პუნქტი, ხოლო ცისტერნებში 4.2 და 4.3 თავების თანახმად დაშვებულ ნივთიერებებთან დაკავშირებით, იხილეთ გადამზიდი ცისტერნების შესახებ T23 ინსტრუქციის 4.2.5.2 პუნქტი. 239 ორგანული პეროქსიდი აცეტილაცეტონის პეროქსიდი “ აცეტილ ციკლოჰექსანსულფონილის პეროქსიდი “ მესამეული ამილის ჰიდროპეროქსიდი მესამეული ამილის პეროქსიაცეტატი მესამეული ამილის პეროქსიბენზოატი მესამეული ამილის პეროქსი-2ეთილჰექსანოატი მესამეული ამილის პეროქსიიზოპროპილკარბონატი მესამეული ამილის პეროქსიდეოდეკანოატი “ მესამეული ამილის პეროქსიპივალატი მესამეული ამილის პეროქსი-3,5,5,ტრიმეთილჰექსანოატი მესამეული ბუთილის კუმილის პეროქსიდი “ ნ-ბუთილ-4,4-დი-(მესამეული ბუთილპეროქსი)ველერატი “ მესამეული ბუთილის ჰიდროპეროქსიდი “ “ “ მესამეული ბუთილის ჰიდროპეროქსიდ+დიმესამეული ბუთილპეროქსიდი მესამეული ბუთილ მონოპეროქსიმალეატი “ “ “ მესამეული ბუთილის პეროქსიაცეტატი “ “ მესამეული ბუთილის პეროქსიბენზოატი “ “ მესამეული ბუთილის პეროქსიბუთილ ფუმარატი კონცენტრა ცია (%) < 42 < 32 პასტის სახით < 82 <32 <88 <62 < 100 < 100 <77 <77 <47 <77 <100 A ტიპის გამხსნე ლი (%) > 48 B ტიპის გამხსნე ლი (%)1) >52-100 <52 < 52 <52 პასტის სახით >52-77 >32-52 < 32 >77-100 >52-77 <52 <52 წყალი შეფუთვის მეთოდი >8 OP7 OP7 > 12 >68 >6 >38 >6 >23 საკონტროლო ტემპერატურა (0C) ავარიული ტემპერატურა (0C) რაოდენობა (გენერიული პოზიციები) 3105 3106 დამატებითი რისკები და შენიშვნები 2) 20) OP4 -10 0 3112 3) OP7 OP8 OP7 OP5 OP7 -10 0 +20 +25 3115 3107 3105 3103 3115 OP5 > 23 OP7 OP8 OP5 OP7 >53 >23 >42-100 <52 >52-100 <52 >79-90 <80 < 79 < 72 <82+>9 ინერტული მყარი ნივთიერება >48 >48 > 10 >20 >14 >28 >7 >48 >48 >23 >48 >68 >23 >48 >48 240 3103 0 0 +10 +10 +10 +15 3115 3119 3113 3105 OP8 OP8 OP5 3107 3108 3103 OP8 OP5 OP7 OP8 OP8 OP5 3108 3103 3105 3107 3109 3103 OP5 OP6 OP8 OP8 3102 3103 3108 3108 3) OP5 OP6 OP8 OP5 OP7 OP7 OP7 3101 3103 3109 3103 3105 3106 3105 3) 13) 4) 13) 13) 23) 13) 13) ორგანული პეროქსიდი კონცენტრა ცია (%) მესამეული ბუთილის პეროქსიკროტონატი მესამეული ბუთილის პეროქსიდიეთილაცეტატი მესამეული ბუთილის პეროქსი-2ეთილჰექსანოატი “ “ “ მესამეული ბუთილის პეროქსი-2ეთილჰექსანოატი + 2,2-დი-(მესამეული ბუთილპეროქსი)ბუტანი “ მესამეული ბუთილის პეროქსი-2ეთილჰექსილკარბონატი მესამეული ბუთილის პეროქსიიზობუტირატი “ მესამეული ბუთილის პეროქსიიზოპროპილკარბონატი 1-(2-მესამეული-ბუთილპეროქსი იზოპროპილი)-3- იზოპროპილენბენზოლი “ მესამეული ბუთილის პეროქსი-2მეთილბენზოატი მესამეული ბუთილის პეროქსინეოდეკანოატი “ “ <77 <100 “ A ტიპის გამხსნე ლი (%) >23 B ტიპის გამხსნე ლი (%)1) ინერტული მყარი ნივთიერება >52-100 >32-52 <52 <32 <12+<14 >48 >48 >68 >14 >60 წყალი შეფუთვის მეთოდი საკონტროლო ტემპერატურა (0C) ავარიული ტემპერატურა (0C) OP7 OP5 +20 +25 რაოდენობა (გენერიული პოზიციები) 3105 3113 OP6 +20 +25 3113 OP8 OP8 OP8 OP7 +30 +20 +40 +35 +25 +45 3117 3118 3119 3106 <31+<36 < 100 >33 OP7 OP7 +35 +40 3115 3105 >52-77 <52 <77 >23 >48 +15 +15 +20 +20 >23 OP5 OP8 OP5 3111 3115 3103 <77 >23 OP7 3105 OP8 OP5 3108 3103 <42 < 100 >58 >77-100 <77 <52 >23 სტაბილური დისპერსიის სახით წყალში < 42 OP7 OP7 OP8 -5 0 0 +5 +10 +10 3115 3115 3119 OP8 0 +10 3118 OP8 OP7 0 0 +10 +10 3119 3115 OP8 0 +10 3117 OP5 OP7 OP8 0 0 +30 +10 +10 +35 3113 3115 3119 სტაბილური დისპერსიის სახით წყალში (გაყინული) “ მესამეული ბუთილის პეროქსინეოჰეპტანოატი “ <32 <77 >68 >23 <42 სტაბილური დისპერსიის სახით წყალში მესამეული ბუთილის პეროქსიპივალატი “ “ >67-77 >27-67 <27 >23 >33 >73 241 დამატებითი რისკები და შენიშვნები 3) ორგანული პეროქსიდი მესამეული ბუთილპეროქსი სტეარილკარბონატი მესამეული ბუთილპეროქსი-3,5,5ტრიმეთილჰექსანოატი “ “ 3-ქლორპეროქსიბენზოატის მჟავა “ “ კუმილის ჰიდროპეროქსიდი “ კუმილის პეროქსინეოდეკანოატი “ “ კონცენტრა ცია (%) <100 OP7 რაოდენობა (გენერიული პოზიციები) 3106 >32-100 OP7 3105 OP7 OP8 OP1 OP7 OP7 OP8 OP8 OP7 OP7 OP8 3106 3109 3102 3106 3106 3107 3109 3115 3115 3119 <42 <32 >57-86 <57 < 77 >90-98 <90 <87 <77 < 52 A ტიპის გამხსნე ლი (%) B ტიპის გამხსნე ლი (%)1) ინერტული მყარი ნივთიერება წყალი >58 >68 >14 >3 >6 >40 >17 <10 >10 >13 >23 შეფუთვის მეთოდი საკონტროლო ტემპერატურა (0C) ავარიული ტემპერატურა (0C) -10 -10 -10 0 0 0 -10 -5 0 +5 დამატებითი რისკები და შენიშვნები 3) 13) 13) 18) სტაბილური დისპერსიის სახით წყალში კუმილის პეროქსინეოჰეპტანოატი კუმილის პეროქსიპივალატი ციკლოჰექსანონის პეროქსიდ(ებ)ი “ “ “ ({3R-(3R,5aS,6S, 8aS,9R,10R,12S,12aR**)}დეკაჰიდრო-10-მეტოქსი-3,6,9-ტრიმეთილ3,12-ეპოქსი-12H-პირანო[4,3-j]-1,2ბენზოდიოქსეპინი დიაცეტონის სპირტის პეროქსიდი დიაცეტილის პეროქსიდი დი-მესამეული-ამილის პეროქსიდი 2,2-დი-(მესამეული-ამილპეროქსი)ბუტანი 1,1-დი-(მესამეული-ამილპეროქსი) ციკლოჰექსანი “ “ “ “ “ “ <77 <77 <91 <72 <72 პასტის სახით <32 <100 <57 <27 <100 <57 <82 >51-100 >77-94 <77 <62 >52-62 პასტის სახით >35-52 >23 >23 >9 >28 OP7 OP7 OP6 OP7 OP7 >68 >8 >43 >18 <48 >6 >23 >10 >28 >48 242 13) 5) 5)20) ამოღებული 3106 29) 3115 3115 3107 3105 3103 6) 7)13) OP2 OP4 OP6 OP7 3102 3102 3104 3106 3) 3) OP7 3106 20) OP7 3106 OP7 >26 >73 3115 3115 3104 3105 3106 OP7 OP7 OP8 OP7 OP6 +40 +20 +45 +25 ორგანული პეროქსიდი “ “ “ “ კონცენტრა ცია (%) >36-42 <56.5 პასტის სახით <52 პასტის სახით <42 A ტიპის გამხსნე ლი (%) >18 B ტიპის გამხსნე ლი (%)1) ინერტული მყარი ნივთიერება წყალი შეფუთვის მეთოდი საკონტროლო ტემპერატურა (0C) ავარიული ტემპერატურა (0C) <40 >15 OP8 OP8 რაოდენობა (გენერიული პოზიციები) 3107 3108 OP8 3108 OP8 3109 დამატებითი რისკები და შენიშვნები 20) სტაბილური დისპერსიის სახით წყალში “ დი-(4-მესამეული-ბუთილციკლოჰექსილ) პეროქსიდიკარბონატი “ <35 <100 >65 <42 OP6 +30 +35 ამოღებული 3114 OP8 +30 +35 3119 29) სტაბილური დისპერსიის სახით წყალში დი-მესამეული-ბუთილის პეროქსიდი “ დი-მესამეული-ბუთილის პეროქსიაზელატი 2,2-დი-(მესამეული-ბუთილპეროქსი) ბუტანი 1,6-დი-(მესამეული ბუთილპეროქსიკარბონილოქსი) ჰექსანი 1,1-დი-(მესამეული ბუთილპეროქსი) ციკლოჰექსანი “ “ “ “ “ “ “ 1,1-დი-(მესამეული ბუთილპეროქსი) ციკლოჰექსანი + მესამეული ბუთილპეროქსი2-ეთილჰექსანოატი დი-ნ-ბუთილის პეროქსიდიკარბონატი „ “ >52-100 <52 <52 <52 <72 >48 >48 >48 >28 >80-100 <72 >52-80 >42-52 <42 <42 <27 <13 <43+<16 >27-52 <27 <42 >28 >20 >48 >13 >58 >25 >13 >41 >45 >74 >48 >73 OP8 OP8 OP7 OP6 OP5 3107 3109 3105 3103 3103 OP5 3101 3) OP5 OP5 OP7 OP7 OP8 OP8 OP8 OP7 3103 3103 3105 3106 3109 3107 3109 3105 30) OP7 OP8 OP8 -15 -10 -15 -5 0 -5 3115 3117 3118 OP4 -20 -10 3113 სტაბილური დისპერსიის სახით წყალში (გაყინული) დო-მეორეული-ბუთილის >52-100 243 25) 21) ორგანული პეროქსიდი პეროქსიდიკარბონატი “ დი-(მესამეულიბუთილპეროქსიიზოპროპილი) ბენზოლ(ებ)ი “ დი-(მესამეული-ბუთილპეროქსი)ფტალატი “ “ 2,2-დი-(მესამეული-ბუთილპეროქსი) პროპანი “ 1,1-დი-(მესამეული-ბუთილპეროქსი)-3,3,5ტრიმეთილციკლოჰექსანი “ “ “ “ “ “ დიცეტილის პეროქსიდიკარბონატი “ დი-4-ქლორბენზოილის პეროქსიდი “ “ დიკუმილის პეროქსიდი “ დიციკლოჰექსილის პეროქსიდიკარბონატი “ “ დიდეკანოილის პეროქსიდი 2,2-დი-(4,4-დი(მესამეული-ბუთილპეროქსი) ციკლოჰექსილ) პროპანი “ დი-2,4-დიქლორბენზოილის პეროქსიდი “ კონცენტრა ცია (%) A ტიპის გამხსნე ლი (%) <52 >42-100 <42 >42-52 <52 პასტის სახით <42 <52 <42 >90-100 <90 >57-90 <77 <57 <57 <32 <100 <42 B ტიპის გამხსნე ლი (%)1) ინერტული მყარი ნივთიერება წყალი >48 <57 საკონტროლო ტემპერატურა (0C) ავარიული ტემპერატურა (0C) რაოდენობა (გენერიული პოზიციები) OP7 OP7 -15 -5 3115 3106 >58 >48 >58 >48 >13 >45 >10 >10 >23 >43 >43 >26 >42 სტაბილური დისპერსიის სახით წყალში <77 <52 პასტის სახით <32 >52-100 <52 >91-100 <91 <42 >23 ამოღებული 3105 3106 OP8 OP7 OP7 OP5 3107 3105 3106 3101 OP5 OP5 OP5 OP8 OP8 OP8 OP7 OP8 3103 3103 3103 3110 3107 3107 3116 3119 30) 3102 3106 3) 20) ამოღებული 3110 ამოღებული 3112 3114 3119 29) 12) 29) 3) +30 +30 +35 +35 OP5 OP7 OP8 >48 >9 <100 <42 >58 >78 >23 244 დამატებითი რისკები და შენიშვნები OP7 OP7 >68 სტაბილური დისპერსიის სახით წყალში <22 <77 <52 პასტის სახით შეფუთვის მეთოდი OP3 OP5 OP8 +10 +10 +15 +15 +15 +20 OP6 OP7 +30 +35 OP8 OP5 OP8 +20 +25 29) 20) 3) 3114 3106 3107 3102 3118 3) ორგანული პეროქსიდი “ კონცენტრა ცია (%) A ტიპის გამხსნე ლი (%) B ტიპის გამხსნე ლი (%)1) ინერტული მყარი ნივთიერება წყალი <52 პასტის შეფუთვის მეთოდი საკონტროლო ტემპერატურა (0C) ავარიული ტემპერატურა (0C) რაოდენობა (გენერიული პოზიციები) 3106 OP7 OP5 OP7 OP8 -10 -20 -15 -15 0 -10 -5 -5 3115 3113 3115 3119 OP8 -15 -5 3120 OP7 დამატებითი რისკები და შენიშვნები სახით სილიკონის ზეთთან ერთად დი-(2-ეტოქსიეთილ) პეროქსიდიკარბონატი დი-(2-ეთილჰექსილ) პეროქსიდიკარბონატი “ “ <52 >77-100 <77 <62 >48 >23 სტაბილური დისპერსიის სახით წყალში “ 2,2-დიჰიდროპეროქსიპროპანი დი(1-ჰიდროქსიციკლოჰექსილ) პეროქსიდი დიიზობუტირილის პეროქსიდი “ დიიზოპროპილბენზოლის დიჰიდროპეროქსიდი დიიზოპროპილის პეროქსიდიკარბონატი “ “ დილაუროილის პეროქსიდი “ <52 სტაბილური დისპერსიის სახით წყალში (გაყინული) <27 <100 >32-52 <32 <82 >52-100 <52 <28 <100 <42 >73 >48 >68 >5 >5 >48 >72 OP5 OP7 OP5 OP7 OP7 -20 -20 -10 -10 3102 3106 3111 3115 3106 3) 3) OP2 OP7 OP7 OP7 OP8 -15 -20 -15 -5 -10 -5 3112 3115 3115 3106 3109 OP7 -5 +5 3115 OP5 OP7 +30 +35 +35 +40 3112 3115 3) 24) სტაბილური დისპერსიის სახით წყალში დი-(3-მეტოქსიბუთილ) პეროქსიდიკარბონატი დი-(2-მეთილბენზოილ) პეროქსიდი დი(3-მეთილბენზოილ) პეროქსიდი+ბენზოილი (3-მეთილბენზოილ) პეროქსიდი+ დიბენზოილის პეროქსიდი დი-(4-მეთილბენზოილ) პეროქსიდი <52 >48 <87 <20+<18+<4 >58 >13 <52 პასტის OP7 3106 OP5 3102 OP7 OP5 3106 3104 3) სახით სილიკონის ზეთთან ერთად 2,5-დიმეთილ-2,5-დი(ბენზოილპეროქსი)ჰექსანი “ “ >82-100 <82 <82 >18 >18 245 3) ორგანული პეროქსიდი 2,5-დიმეთილ-2,5-დი-(მესამეულიბუთილპეროქსი)ჰექსანი “ “ “ “ 2,5-დიმეთილ-2,5-დი-(მესამეულიბუთილპეროქსი)ჰექსინი-3 “ “ 2,5-დიმეთილ-2,5-დი(2ეთილჰექსანოილპეროქსი)ჰექსანი 2,5-დიმეთილ-2,5-დიჰიდროპეროქსიჰექსანი 2,5-დიმეთილ-2,5-დი-(3,5.5ტრიმეთილჰექსანოილპეროქსი) ჰექსანი 1,1-დიმეთილ-3-ჰიდროქსიბუთილ პეროქსინეოჰეპტანოატი დიმერისტილის პეროქსიდიკარბონატი “ კონცენტრა ცია (%) A ტიპის გამხსნე ლი (%) B ტიპის გამხსნე ლი (%)1) ინერტული მყარი ნივთიერება წყალი >90-100 >52-90 <77 <52 <47 პასტის სახით >86-100 >10 >52-86 <52 <100 >14 >23 >48 >48 >18 შეფუთვის მეთოდი საკონტროლო ტემპერატურა (0C) OP5 რაოდენობა (გენერიული პოზიციები) 3103 OP7 OP8 OP8 OP8 3105 3108 3109 3108 OP5 3101 3) OP5 OP7 OP5 3103 3106 3113 26) +20 ავარიული ტემპერატურა (0C) +25 <82 <77 >23 OP6 OP7 <52 >48 OP8 0 +10 3117 OP7 OP8 +20 +20 +25 +25 3116 3119 OP7 -10 0 3115 OP7 OP5 OP5 OP7 OP8 OP3 OP5 OP4 OP7 OP7 OP8 0 +10 +10 +15 3116 3114 3102 3106 3117 3113 3113 3102 3116 3115 3119 OP8 OP8 OP7 <100 <42 დამატებითი რისკები და შენიშვნები 3104 3105 სტაბილური დისპერსიის სახით წყალში დი-(2-ნეოდეკანოილპეროქსიიზოპროპილ) ბენზოლი დი-ნ-ნონანოილის პეროქსიდი დი-ნ-ოქტანოილის პეროქსიდი დი-(2-ფენოქსიეთილ) პეროქსიდიკარბონატი “ დოპროპიონილის პეროქსიდი დი-ნ-პროპილის პეროქსიდიკარბონატი “ დიზუქცინის მჟავის პეროქსიდი “ დი-(3,5,5-ტრიმეთილჰექსანოილ) პეროქსიდი “ <52 <100 <100 >85-100 <85 <27 <100 <77 >72-100 <72 >52-82 <52 >48 >15 >73 >23 >28 >18 +15 -25 -20 +20 -15 -10 +10 0 +10 +15 +10 +15 +10 +20 +15 +25 სტაბილური დისპერსიის სახით წყალში “ “ ეთილ 3,3-დი-(მესამეული-ამილპეროქსი) ბუტირატი >38-52 <38 <67 >48 >62 >33 >48 246 3119 3119 3105 3) 3) 17) ორგანული პეროქსიდი კონცენტრა ცია (%) A ტიპის გამხსნე ლი (%) ეთილ 3,3-დი-(მესამეული-ბუთილპეროქსი) ბუტირატი “ “ 1-(2-ეთილჰექსანოილპეროქსი)-1,3დიმეთილბუტილ პეროქსიპივალატი >77-100 <77 <52 <52 >23 მესამეული ჰექსილპეროქსინეოდეკანოატი მესამეული ჰექსილპეროქსიპივალატი 3-ჰიდროქსი-1,1-დიმეთილბუტილ პეროქსინეოდეკანოატი “ “ <71 <72 <77 >29 <52 <52 B ტიპის გამხსნე ლი (%)1) ინერტული მყარი ნივთიერება OP5 რაოდენობა (გენერიული პოზიციები) 3103 OP7 OP7 OP7 -20 -10 3105 3106 3115 OP7 OP7 OP7 0 +10 -5 +10 +15 +5 3115 3115 3115 >48 OP8 OP8 -5 -5 +5 +5 3117 3119 >38 OP7 -20 -10 3115 OP5 -20 -10 3111 3) 3109 3105 3109 3115 3101 13) 13) 27) >48 >45 >10 >28 >23 წყალი შეფუთვის მეთოდი საკონტროლო ტემპერატურა (0C) ავარიული ტემპერატურა (0C) დამატებითი რისკები და შენიშვნები სტაბილური დისპერსიის სახით წყალში იზოპროპილის მეორეული ბუთილ პეროქსიდიკარბონატი+დი-მეორეულიბუთილ პეროქსიდიკარბონატი+დიიზოპროპილ პეროქსიდიკარბონატი “ იზოპროპილკუმილ ჰიდროპეროქსიდი პ-მენთილჰიდროპეროქსიდი “ მეთილციკლოჰექსანონის პეროქსიდ(ებ)ი მეთილეთილკეტონის პეროქსიდ(ებ)ი “ “ მეთილიზობუთილკეტონის პეროქსიდ(ებ)ი მეთილ იზოპროპილ კეტონის პეროქსიდ(ებ)ი <32+<15-18 <12-15 <52+<28+<2 2 <72 >72-100 <72 <67 იხილეთ შენიშვნა 8) იხილეთ შენიშვნა 9) იხილეთ შენიშვნა 10) <62 იხილეთ შენიშვნა 31) >28 >48 OP8 OP7 OP8 OP7 OP5 >55 OP7 3105 9) >60 OP8 3107 10) >19 >70 OP7 OP8 3105 3109 22) 31) OP2 OP2 3103 3113 11) 11) OP2 OP2 3104 3114 11) 11) >28 >33 ორგანული პეროქსიდი, თხევადი, ნიმუში ორგანული პეროქსიდი, თხევადი, ნიმუში, დარეგულირებული ტემპერატურით ორგანული პეროქსიდი, მყარი, ნიმუში ორგანული პეროქსიდი, მყარი, ნიმუში, დარეგულირებული ტემპერატურით 247 +35 +40 3)8)13) ორგანული პეროქსიდი კონცენტრა ცია (%) A ტიპის გამხსნე ლი (%) B ტიპის გამხსნე ლი (%)1) ინერტული მყარი ნივთიერება 3,3,5,7,7-პენტამეთილ-1,2,4-ტრიოქსეფანი პეროქსიაცეტილის მჟავა, D ტიპი, სტაბილიზებული პეროქსიაცეტილის მჟავა, E ტიპი, სტაბილიზებული <100 <43 OP8 OP7 რაოდენობა (გენერიული პოზიციები) 3107 3105 <43 OP8 3107 13)15)19) პეროქსიაცეტილის მჟავა, F ტიპი, სტაბილიზებული პეროქსილაურილის მჟავა პინანილის ჰიდროპეროქსიდი “ პოლიეთერის პოლი-ტერტ-ბუთილპეროქსიკარბონატი 1,1,3,3-ტეტრამეთილბუთილის ჰიდროპეროქსიდი 1,1,3,3-ტეტრამეთილბუთილის პეროქსი-2ეთილჰექსანოატი 1,1,3,3-ტეტრამეთილბუთილის პეროქსინეოდეკამოატი “ <43 OP8 3109 13)16)19) <100 >56-100 <56 <52 OP8 OP7 OP8 OP8 >44 >48 წყალი შეფუთვის მეთოდი საკონტროლო ტემპერატურა (0C) +35 ავარიული ტემპერატურა (0C) +40 3118 3105 3109 3107 <100 OP7 <100 OP7 +15 +20 3115 OP7 -5 +5 3115 OP8 -5 +5 3119 OP7 0 +10 3115 <72 >28 <52 დამატებითი რისკები და შენიშვნები 13)14)19) 13) 3105 სტაბილური დისპერსიის სახით წყალში 1,1,3,3-ტეტრამეთილბუთილის პეროქსიპივალატი 3,6,9-ტრიეთილ-3,6,9-ტრიმეთილ-1,4,7 ტრიპეროქსონანი 3,6,9-ტრიეთილ-3,6,9-ტრიმეთილ-1,4,7 ტრიპეროქსონანი <77 >23 <17 >18 <42 >58 >65 248 OP8 3110 OP7 3105 28) შენიშვნები (გათვალისწინებულია 2.2.52.4 პუნქტში წარმოდგენილი ცხრილის ბოლო სვეტში): 1) B ტიპის გამხსნელის შეცვლა ყოველთვის შესაძლებელია A ტიპის გამხსნელით. B ტიპის გამხსნელის დუღილის ტემპერატურა მინიმუმ 600C-ით მაღალი უნდა იყოს ორგანული პეროქსიდის თვითაჩქარებული დაშლის ტემპერატურაზე. 2) თავისუფალი ჟანგბადი <4.7%. 3) საჭიროა დამატებითი საშიშროების მაუწყებელი ნიშანი „ფეთქებადი ნივთიერება“ (ნიმუში №1. იხილეთ 5.2.2.2.2 ქვეპუნქტი). 4) გამხსნელი შეიძლება შეიცვალოს დი-მესამეული-ბუთილის პეროქსიდით. 5) თავისუფალი ჟანგბადი <9%. 6) <9% წყალბადის პეროქსიდით, თავისუფალი ჟანგბადი <10%. 7) დაშვებულია მხოლოდ არალითონის ტარა. 8) თავისუფალი ჟანგბადი >10% და <10.7%, წყლით ან წყლის გარეშე. 9) თავისუფალი ჟანგბადი <10%, წყლით ან წყლის გარეშე. 10) თავისუფალი ჟანგბადი <8.2%, წყლით ან წყლის გარეშე. 11) იხილეთ 2.2.52.1.9 ქვეპუნქტი. 12) 2000 კგ-მდე ერთ ჭურჭელზე, რომელიც მიეკუთვნება F ტიპის ორგანულ პეროქსიდს, მასშტაბური ცდების საფუძველზე. 13) საჭიროა დამატებითი საშიშროების მაუწყებელი ნიშანი „კოროზიული“ (ნიმუში №8. იხილეთ 5.2.2.2.2 ქვეპუნქტი). 14) პეროქსიაცეტილის მჟავის შემადგენლობები, რომლებიც აკმაყოფილებს ცდებისა და კრიტერიუმების სახელმძღვანელოს 20.4.3(დ) პუნქტის კრიტერიუმებს. 15) პეროქსიაცეტილის მჟავის შემადგენლობები, რომლებიც აკმაყოფილებს ცდებისა და კრიტერიუმების სახელმძღვანელოს 20.4.3(ე) პუნქტის კრიტერიუმებს. 16) პეროქსიაცეტილის მჟავის შემადგენლობები, რომლებიც აკმაყოფილებს ცდებისა და კრიტერიუმების სახელმძღვანელოს 20.4.3(ვ) პუნქტის კრიტერიუმებს. 17) აღნიშნულ ორგანულ სტაბილურობას. 18) საჭირო არ არის დამატებითი საშიშროების მაუწყებელი ნიშანი „კოროზიული“ (ნიმუში №8. იხილეთ 5.2.2.2.2 ქვეპუნქტი) 80%-ზე დაბალ კონცენტრაციაზე. 19) წყალბადის პეროქსიდის, წყლისა და მჟავ(ებ)ის ნარევები. 20) A ტიპის გამხსნელთან ერთად, წყლით ან წყლის გარეშე. 21) მასის მიხედვით >25% A ტიპის გამხსნელთან ერთად, და გარდა ამისა, ეთილბენზოლთან ერთად. 22) მასის მიხედვით >19% A ტიპის მეთილიზობუთილკეტონთან ერთად. 23) <6% ბი-მესამეული-ბუთილის პეროქსიდთან ერთად. პეროქსიდზე წყლის დამატება გამხსნელთან 249 შეამცირებს ერთად, და მის თერმულ გარდა ამისა, 24) <8% 1-იზოპროპილჰიდროპეროქსი-4-იზოპროპილჰიდროქსიბენზოლთან ერთად. 25) B ტიპის გამხსნელი >1100C დუღილის ტემპერატურით. 26) <0.5% ჰიდროქსიპეროქსიდის შემცველობით. 27) 56%-ზე მეტი კონცენტრაციების შემთხვევაში, საჭიროა დამატებითი მაუწყებელი ნიშანი „კოროზიული“ (ნიმუში №8. იხილეთ 5.2.2.2.2 ქვეპუნქტი). 28) თავისუფალი აქტიური ჟანგბადი <7.6 A ტიპის გამხსნელში, რომელსაც გააჩნია 95% აორთქლების ტემპერატურა 200-2600C დიაპაზონზე. 29) არ ექვემდებარება 5.2 კლასთან დაკავშირებით ADR-ის მოთხოვნებს. 30) B ტიპის გამხსნელი >1300C დუღილის ტემპერატურით. 31) აქტიური ჟანგბადი <6.7%. 250 საშიშროების 2.2.61 კლასი 6.1 ტოქსიკური ნივთიერებები 2.2.61.1 კრიტერიუმები 2.2.61.1.1 6.1 კლასის სახელწოდება მოიცავს იმ ნივთიერებებს, რომლებთან დაკავშირებითაც არსებული გამოცდილების მიხედვითა თუ ცხოველებზე ჩატარებული ექსპერიმენტების საფუძველზე, ცნობილია, რომ შედარებით მცირე ოდენობებით წარმოდგენისას მათ შეუძლიათ ცალკეული მოქმედებით ან ხანმოკლე მოქმედებით ზიანი მიაყენონ ადამიანთა ჯანმრთელობას ან აღმოჩნდნენ გარდაცვალების მიზეზი მათი შესუნთქვის, კანისმიერი შეწოვის ან გადაყლაპვის შემთხვევაში. შენიშვნა: აღნიშნულ კლასს უნდა განეკუთვნოს გენეტიკურად მოდიფიცირებული მიკროორგანიზმები და ორგანიზმები, იმ შემთხვევაში, თუ ისინი აკმაყოფილებს აღნიშნულ კლასთან დაკავშირებულ პირობებს. 2.2.61.1.2 6.1 კლასის ნივთიერებები იყოფა შემდეგნაირად: T ტოქსიკური ნივთიერებები დამატებითი საშიშროების გარეშე; T1 T2 T3 T4 T5 T6 T7 T8 T9 TF ტოქსიკური ნივთიერებები, ადვილაალებადი: TF1 TF2 TF3 TS ორგანული, თხევადი, ორგანული, მყარი; ლითონორგანული ნივთიერებები; არაორგანული, თხევადი; არაორგანული, მყარი; თხევადი, რომელიც გამოიყენება პესტიციდების სახით; მყარი, რომელიც გამოიყენება პესტიციდების სახით; ნიმუშები; სხვა ტოქსიკური ნივთიერებები; თხევადი; თხევადი, რომელიც გამოიყენება პესტიციდების სახით; მყარი; ტოქსიკური ნივთიერებები, თვით-მთბობი, მყარი; TW ტოქსიკური ნივთიერებები, ადვილაალებად აირებს; TW1 TW2 TO თხევადი; მყარი; ტოქსიკური ნივთიერებები, მჟანგავი: TO1 TO2 TC რომლებიც თხევადი; მყარი; ტოქსიკური ნივთიერებები, კოროზიული: TC1 TC2 TC3 TC4 ორგანული, თხევადი; ორგანული, მყარი; არაორგანული, თხევადი; არაორგანული, მყარი; 251 წყალთან შეხებისას გამოჰყოფს TFC ტოქსიკური ნივთიერებები, ადვილაალებადი, კოროზიული; TFW ტოქსიკური ნივთიერებები, ადვილაალებადი, რომლებიც წყალთან შეხებისას, გამოჰყოფს ადვილაალებად აირებს. განმარტებები 2.2.61.1.3 ADR-ით გათვალისწინებულ მიზნებთან დაკავშირებით: LD50 (საშუალო ლეთალური დოზა) მწვავე პერორალური ტოქსიკურობისთვის - წარმოადგენს ნივთიერების სტატისტიკურად მიღებულ ერთეულ დოზას, რომელსაც, როგორც ვარაუდობენ, შეუძლია გამოიწვიოს გარდაცვალება ახალგაზრდა, ზრდასრული თეთრი ვირთხების 50 პროცენტში, პერორალური გზით მიღების შემთხვევაში 14 დღის განმავლობაში. LD50 მნიშვნელობა გამოიხატება, როგორც საცდელი ნივთიერების მასის დამოკიდებულება საცდელი ცხოველის მასაზე (მგ/კგ); LD50 მწვავე კანისმიერი ტოქსიკურობისთვის - წარმოადგენს ნივთიერების დოზას, რომელიც 24 საათის განმავლობაში ალბინოსი ბოცვრების შიშველ კანთან უწყვეტი კონტაქტით მიღების შემთხვევაში, დიდი ალბათობით გამოიწვევს გარდაცვალებას, ცდების ქვეშ მყოფი ცხოველების ნახევარში 14 დღის განმავლობაში. ცდების ქვეშ მყოფი ცხოველების რაოდენობა უნდა იყოს საკმარისი სტატისტიკურად მნიშვნელოვანი შედეგის მისაღებად და უნდა აკმაყოფილებდეს კარგ ფარმაკოლოგიურ პრაქტიკას. შედეგები გამოისახება მილიგარმებში სხეულის მასის ყოველ კგ-ზე. LC50 მწვავე საინჰალაციო ტოქსიკურობისთვის - წარმოადგენს ორთქლის, ნისლისა თუ მტვრის კონცენტრაციას, რომლის უწყვეტმა შესუნთქვამ როგორც მამალ, ასევე დედალ ახალგაზრდა, ზრდასრულ თეთრ ვირთხებში ერთი საათის განმავლობაში, დიდი ალბათობაა რომ გამოიწვიოს გარდაცვალება ცდების ქვეშ მყოფი ცხოველების ნახევარში 14 დღის განმავლობაში. მყარი ნივთიერების გამოცდა უნდა მოხდეს იმ შემთხვევაში, თუ მისი საერთო მასის მინიმუმ 10% (მასის მიხედვით) სავარაუდოდ შედგება მტვრისგან, რომელსაც შეუძლია სუნთქვის ორგანოებში მოხვედრა, მაგალითად, თუ ნაწილაკების აეროდინამიკური დიამეტრი შეადგენს 10მკმ-ს ან ნაკლებს. თხევად ნივთიერებებზე ცდა ხორციელდება იმ შემთხვევაში, თუ არსებობს ნისლის წარმოშობის ალბათობა სატრანსპორტო საცავიდან მისი გაჟონვის შემთხვევაში. საინჰალაციო ტოქსიკურობასთან დაკავშირებით მომზადებული ნიმუშების 90%-ზე (მასის მიხედვით) მეტი როგორც მყარი, ასევე თხევადი ნივთიერებების გამოცდა უნდა შედგებოდეს იმ ნაწილაკებისგან, რომელთაც შეუძლიათ სასუნთქ ორგანოებში მოხვედრა, როგორც ეს ზემოთ არის აღწერილი. შედეგები გამოისახება მილიგრამებში ჰაერის ყოველ ლიტრზე მტვრისა და ნისლის შემთხვევაში ან მილილიტრებში ჰაერის ყოველ კუბურ მეტრზე (ნაწილები ყოველ მილიონზე) ორთქლის შემთხვევაში. კლასიფიკაცია და შეფუთვის ჯგუფებზე მიკუთვნება 2.2.61.1.4 6.1 კლასის ნივთიერებები კლასიფიცირდება სამ შეფუთვის ჯგუფად გადაზიდვების დროს მათ მიერ წარმოდგენილი საშიშროების ხარისხის მიხდევით: I შეფუთვის ჯგუფი ძლიერტოქსიკური ნივთიერებები II შეფუთვის ჯგუფი: ტოქსიკური ნივთიერებები III შეფუთვის ჯგუფი: სუსტად ტოქსიკური ნივთიერებები 252 2.2.61.1.5 6.1 კლასში კლასიფიცირებული ნივთიერებები, ნარევები, ხნარები და ნაკეთობები მოყვანილია 3.2 თავის A ცხრილში. ნივთიერებების, ნარევებისა და ხსნარების, რომლებიც არ არის მითითებული დასახელებით 3.2 თავის A ცხრილში კლასიფიკაცია 2.2.61.3 პუნქტის შესაბამის პოზიციასა და შესაბამის ჯგუფში 2.1 თავის დებულებების თანახმად ხორციელდება 2.2.61.1.6-დან 2.2.61.1.11 ქვეპუნქტებში წარმოდგენილ კრიტერიუმებში. 2.2.61.1.6 ტოქსიკურობის ხარისხის შესაფასებლად, მხედველობაში უნდა იქნეს მიღებული ადამიანთა მოწამვლის უბედურ შემთხვევებთან დაკავშირებით არსებული გამოცდილება, ასევე კონკრეტული ნივთიერებების სპეციალური მახასიათებლები: თხევადი მდგომარეობა, მაღალი აქროლადობა, კანისმიერი შეწოვის ნებისმიერი ალბათობა და სპეციალური ბიოლოგიური ეფექტები. 2.2.61.1.7 ადამიანებზე დაკვირვებების არარსებობის შემთხვევაში, ტოქსიკურობის ხარისხი უნდა შეფასდეს ცხოველებზე ჩატარებული ექსპერიმენტების შედეგად მიღებული მონაცემების გამოყენებით, ქვემოთ წარმოდგენილი ცხრილის შესაბამისად: შეფუთვის ჯგუფი პერორალური ტოქსიკურობა LD50 (მგ/კგ) კანისმიერი ტოქსიკურობა LD50 (მგ/კგ) საინჰალაციო ტოქსიკურობა მტვრისა და ნისლის მიერ LC50 (მგ/ლ) I <5 <50 <0.2 II >5 და <50 >50 და <200 >0.2 და <2 სუსტად ტოქსიკური IIIა >50 და <300 >200 და <1 000 >2 და <4 ა ცრემლსადენი აიროვანი ნივთიერებები გათვალისწინებული უნდა იქნეს II შეფუთვის ჯგუფში იმ შემთხვევაშიც კი, თუ მათ ტოქსიკურობასთან დაკავშირებული მონაცემები შეესაბამება III შეფუთვის ჯგუფის კრიტერიუმებს. ძლიერტოქსიკური ტოქსიკური 2.2.61.1.7.1 იმ შემთხვევაში, თუ ნივთიერება ავლენს ტოქსიკურობას სხვადასხვა ხარისხით ორი ან რამდენიმე სახეობის ურთიერთქმედებასთან დაკავშირებით, მისი კლასიფიცირება უნდა მოხდეს მაღალტოქსიკურობის საფეხურზე. 2.2.61.1.7.2 ნივთიერებების, რომლებიც აკმაყოფილებს მე-8 კლასის მოთხოვნებს და ხასიათდება მტვრითა და ნისლით გამოწვეული საინჰალაციო ტოქსიკურობით (LC50), რაც განაპირობებს მათ მიკუთვნებას I შეფუთვის ჯგუფზე, კლასიფიკაცია უნდა მოხდეს მხოლოდ 6.1 კლასში მხოლოდ იმ შემთხვევაში, თუ მათი პერორალური მიღებისა თუ კანისმიერი შეხების შედეგად გამოწვეული ტოქსიკურობა წარმოდგენილია მინიმუმ I ან II შეფუთვის ჯგუფების დიაპაზონში. წინააღმდეგ შემთხვევაში მე-8 კლასზე მიკუთვნება უნდა განხორციელდეს აუცილებლობიდან გამომდინარე (იხილეთ 2.2.8.1.5 ქვეპუნქტი). 2.2.61.7.1.3 მტვრისა და ნისლის საინჰალაციო ტოქსიკურობასთან დაკავშირებული კრიტერიუმები ეფუძნება LC50 მონაცემებს ერთი საათის განმავლობაში შესუნთქვის შემთხვევაში და თუ ასეთი ინფორმაცია არსებობს, უნდა მოხდეს მისი გამოყენება. თუმცა თუ ცნობილია მხოლოდ LC50 მონაცემები 4 საათის განმავლობაში შესუნთქვასთან დაკავშირებით, აღნიშნული ციფრები შესაძლებელია გამრავლდეს ოთხზე და ზემოაღნიშნული კრიტერიუმების შემცვლელი ნამრავლი ანუ LC50 მნიშვნელობა გამრავლებული ოთხზე (4 საათზე) განხილულ უნდა იქნეს, როგორც LC50-ის (1 საათი) ეკვივალენტი. 253 ორთქლების საინჰალაციო ტოქსიკურობა 2.2.61.1.8 ტოქსიკური ორთქლების გამომყოფი სითხეების კლასიფიკაცია უნდა მოხდეს ჯგუფებად, სადაც „V“ წარმოადგენს ნაჯერი ორთქლის კონცენტრაციას (ჰაერის მლ/მ3ში) 200C ტემპერატურასა და სტანდარტულ ატმოსფერულ წნევაზე: ძლიერტოქსიკური ტოქსიკური სუსტად ტოქსიკური შეფუთვის ჯგუფი I II IIIა თუ V > 10 LC50 და LC50 < 1 000 მლ/მ3 თუ V > LC50 და LC50 < 3 000 მლ/მ3 და I შეფუთვის ჯგუფის კრიტერიუმები არ არის დაკმაყოფილებული თუ V > 1/5 LC50 და LC50 < 5 000 მლ/მ3 და I და II შეფუთვის ჯგუფების კრიტერიუმები არ არის დაკმაყოფილებული ცრემლსადენი აიროვანი ნივთიერებები გათვალისწინებული უნდა იქნეს II შეფუთვის ჯგუფში იმ შემთხვევაშიც კი, თუ მათ ტოქსიკურობასთან დაკავშირებული მონაცემები შეესაბამება III შეფუთვის ჯგუფის კრიტერიუმებს. ა აღნიშნული ორთქლების საინჰალაციო ტოქსიკურობასთან დაკავშირებული კრიტერიუმები დამყარებულია LC50 მონაცემებზე ერთი საათის განამვლობაში მიღების შემთხვევაში, და როდესაც წარმოდგენილია ამგვარი ინფორმაცია, ისინი უნდა იქნეს გამოყენებული. თუმცა, თუ ცნობილია მხოლოდ 4 საათის განმავლობაში ორთქლის შესუნთქვასთან დაკავშირებული LC50 მონაცემები, მაშინ აღნიშნული ციფრი შესაძლებელია გამრავლდეს ორზე და ზემოაღნიშნული კრიტერიუმების შემცვლელი ნამრავლი ანუ LC50 (4 საათი) X 2 განხილულ უნდა იქნეს, როგორც LC50-ის (1 საათი) ეკვივალენტი. მოცემულ სურათზე კრიტერიუმები გამოსახულია გრაფიკული ფორმით, კლასიფიკაციის გამარტივების მიზნით. თუმცა გრაფების გამოყენებასთან დაკავშირებული მიახლოებული სიდიდეების არსებობის მიზეზით, ნივთიერებები, რომლებიც წარმოდგენილია ჯგუფის საზღვრებზე ან მახლობლად უნდა შემოწმდეს ციფრობრივი კრიტერიუმების გამოყენებით. 254 ჯგუფის საზღვრები - ორთქლების საინჰალაციო ტოქსიკურობა 10 000 არ წარმოადგენს საშიშროებას III შეფუთვის ჯგუფი ტრანსპორტირებისთვის II შეფუთვის ჯგუფი LC50 მლ/მ3 1 000 I შეფუთვის ჯგუფი 100 10 აორთქლებადობა მლ/მ3 სითხეების ნარევები 2.2.61.1.9 იმ სითხეების ნარევები, რომლებიც ხასიათდება ტოქსიკურობით შესუნთქვისას, კლასიფიცირდება შეფუთვის ჯგუფებში შემდეგი კრიტერიუმების შესაბამისად: 2.2.61.1.9.1 იმ შემთხვევაში, თუ LC50 ცნობილია ნარევის ყოველ ტოქსიკურ ნივთიერებასთან დაკავშირებით, შეფუთვის ჯგუფი შესაძლებელია განისაზღვროს შემდეგნაირად: (ა) ნარევის LC50 გამოთვლა ხდება შემდეგი ფორმულით: LC50 (ნარევი) = სადაც 1 1 . 𝑓𝑖 𝐿𝐶50𝑖 fi = ნარევის i კომპონენტის მოლური წილი � LC50i = i კომპონენტის საშუალო ლეთალური კონცენტრაცია მლ/მ3-ში. (ბ) ნარევის ყოველი კომპონენტის აქროლადობის გამოთვლა ხდება შემდეგი ფორმულის მიხედვით: 255 (მლ/მ3) სადაც: Pi = i კომპონენტის პარციალური სტანდარტულ ატმოსფერულ წნევაზე. (გ) წნევა კლა-ში 200C-სა და აქროლადობის კოეფიციენტის გამოთვლა LC50-ზე ხდება შემდეგი ფორმულით: R= 𝑛 � 𝑖+1 Vi 𝐿𝐶50𝑖 (დ) LC50-სა (ნარევი) და R-სთან დაკავშირებით გაანგარიშებული მნიშვნელობები გამოიყენება ნარევის შეფუთვის ჯგუფის განსაზღვრის მიზნით: I შეფუთვის ჯგუფი R > 10 და LC50 (ნარევი) < 1 000 მლ/მ3 ; II შეფუთვის ჯგუფი R > 1 და LC50 (ნარევი) < 3 000 მლ/მ3, იმ შემთხვევაში, თუ ნარევი არ აკმაყოფილებს I შეფუთვის ჯგუფის კრიტერიუმებს; III შეფუთვის ჯგუფი R > 1/5 და LC50 (ნარევი) < 5 000 მლ/მ3, იმ შემთხვევაში, თუ ნარევი არ აკმაყოფილებს I და II შეფუთვის ჯგუფების კრიტერიუმებს. 2.2.61.1.9.2 ნივთიერებების ტოქსიკური კომპონენტების შესახებ LC50 მონაცემების არ არსებობის შემთხვევაში, ნარევი შესაძლებელია მიეკუთვნოს ამა თუ იმ ჯგუფს შემდეგი გამარტივებული ზღვრული ტოქსიკურობის ცდების საფუძველზე. აღნიშნული ზღვრული ცდების გამოყენების შემთხვევაში, განისაზღვრება და გამოიყენება ყველაზე შემზღუდავი ჯგუფი ნარევების გადასაზიდად. 2.2.61.1.9.3 ნარევი განეკუთვნება I შეფუთვის ჯგუფს მხოლოდ იმ შემთხვევაში, თუ ის აკმაყოფილებს ქვემოთ მოყვანილ ორივე კრიტერიუმს: (ა) თხევადი ნარევის ნიმუში ორთქლდება და იხსნება ჰაერში, რათა წარმოქმნას ჰაერში 1 000 მლ/მ3 აორთქლებული ნარევის საცდელი გარემო. ათი თეთრი ვირთხა (5 მამალი და 5 დედალი) მოთავსებულ იქნა საცდელ გარემოში 1 საათის განმავლობაში და იმყოფებოდნენ დაკვირვების ქვეშ 14 დღის განმავლობაში. იმ შემთხვევაში, თუ აღნიშნული 14-დღიანი პერიოდის მანძილზე გარდაიცვლება ხუთი ან მეტი ცხოველი, სავარაუდოდ მოცემულ ნარევს აღენიშნება 1 000 მლ/მ3 ტოლი ან ნაკლები LC50; (ბ) თხევად ნარევთან წონასწორობაში მყოფი ორთქლის ნიმუში გაიხსნა ჰაერის 9 თანაბარ მოცულობასთან საცდელი გარემოს ფორმირების მიზნით. ათი თეთრი ვირთხა (5 მამალი და 5 დედალი) მოთავსებულ იქნა საცდელ გარემოში 1 საათის განმავლობაში და იმყოფებოდნენ დაკვირვების ქვეშ 14 დღის განმავლობაში. იმ შემთხვევაში, თუ აღნიშნული 14-დღიანი პერიოდის მანძილზე გარდაიცვლება ხუთი ან მეტი ცხოველი, მაშინ ვარაუდობენ, რომ ნარევს გააჩნია LC50 ნარევის თანაბარი ან 10-ჯერ მეტი აქროლადობა. 256 2.2.61.1.9.4 ნარევი განეკუთვნება II შეფუთვის ჯგუფს მხოლოდ იმ შემთხვევაში, თუ ის აკმაყოფილებს ქვემოთ მოყვანილ კრიტერიუმებს, თუმცა არ პასუხობს I შეფუთვის ჯგუფის კრიტერიუმებს: (ა) თხევადი ნარევის ნიმუში ორთქლდება და იხსნება ჰაერში, რათა წარმოქმნას ჰაერში 3 000 მლ/მ3 აორთქლებული ნარევის საცდელი გარემო. ათი თეთრი ვირთხა (5 მამალი და 5 დედალი) მოთავსებულ იქნა საცდელ გარემოში 1 საათის განმავლობაში და იმყოფებოდნენ დაკვირვების ქვეშ 14 დღის განმავლობაში. იმ შემთხვევაში, თუ აღნიშნული 14-დღიანი პერიოდის მანძილზე გარდაიცვლება ხუთი ან მეტი ცხოველი, სავარაუდოდ მოცემულ ნარევს აღენიშნება 3 000 მლ/მ3 ტოლი ან ნაკლები LC50; (ბ) თხევად ნარევთან წონასწორობაში მყოფი ორთქლის ნიმუში გაიხსნა ჰაერის 9 თანაბარ მოცულობასთან საცდელი გარემოს ფორმირების მიზნით. ათი თეთრი ვირთხა (5 მამალი და 5 დედალი) მოთავსებულ იქნა საცდელ გარემოში 1 საათის განმავლობაში და იმყოფებოდნენ დაკვირვების ქვეშ 14 დღის განმავლობაში. იმ შემთხვევაში, თუ აღნიშნული 14-დღიანი პერიოდის მანძილზე გარდაიცვლება ხუთი ან მეტი ცხოველი, მაშინ ვარაუდობენ, რომ ნარევს გააჩნია LC50 ნარევის თანაბარი ან მეტი აქროლადობა. 2.2.61.1.9.5 ნარევი განეკუთვნება III შეფუთვის ჯგუფს მხოლოდ იმ შემთხვევაში, თუ ის აკმაყოფილებს ქვემოთ მოყვანილ კრიტერიუმებს, თუმცა არ პასუხობს I და II შეფუთვის ჯგუფების კრიტერიუმებს: (ა) თხევადი ნარევის ნიმუში ორთქლდება და იხსნება ჰაერში, რათა წარმოქმნას ჰაერში 5 000 მლ/მ3 აორთქლებული ნარევის საცდელი გარემო. ათი თეთრი ვირთხა (5 მამალი და 5 დედალი) მოთავსებულ იქნა საცდელ გარემოში 1 საათის განმავლობაში და იმყოფებოდნენ დაკვირვების ქვეშ 14 დღის განმავლობაში. იმ შემთხვევაში, თუ აღნიშნული 14-დღიანი პერიოდის მანძილზე გარდაიცვლება ხუთი ან მეტი ცხოველი, სავარაუდოდ მოცემულ ნარევს აღენიშნება 5 000 მლ/მ3 ტოლი ან ნაკლები LC50; (ბ) სითხის ნარევის ორთქლის კონცენტრაცია (აქროლადობა) გაიზომება და იმ შემთხვევაში, თუ ორთქლის კონცენტრაცია ტოლია ან მეტია 1 000 მლ/მ3-ზე, მაშინ ვარაუდობენ, რომ ნარევს გააჩნია LC50 ნარევის თანაბარი ან 1/5 მეტი აქროლადობა. ნარევების პერორალური და კანისმიერი ტოქსიკურობის განმსაზღვრელი მეთოდები 2.2.61.1.10 პერორალური და კანისმიერი ტოქსიკურობის კრიტერიუმების თანახმად (იხილეთ 2.2.61.1.3 ქვეპუნქტი) შესაბამისი შეფუთვის ჯგუფების 6.1 კლასში კლასიფიცირებისა და მიკუთვნების შემთხვევაში, აუცილებელია განისაზღვროს ნარევის LD50 მწვავე ტოქსიკურობასთან დაკავშირებით. 2.2.61.1.10.1 იმ შემთხვევაში, თუ ნარევი შეიცავს მხოლოდ ერთ აქტიურ ნივთიერებას, და აღნიშნული კომპონენტის LD50 ცნობილია, მწვავე პერორალური და კანისმიერი ტოქსიკურობის შესახებ გადაზიდვას დაქვემდებარებული ფაქტიურ ნარევთან დაკავშირებით არსებული საიმედო ინფორმაციის არარსებობის შემთხვევაში, პერორალური და კანისმიერი LD50 შესაძლებელია მიღებულ იქნეს შემდეგი მეთოდის საშუალებით: 257 LD50 პრეპარატის მნიშვნელობა = აქტიური ნივთიერების LD50 მნიშვნელობა X 100 აქტიური ნივთიერების პროცენტული შემადგენლობა მასის მიხედვით 2.2.61.1.10.2 იმ შემთხვევაში, თუ ნარევი შეიცავს ერთზე მეტ აქტიურ კომპონენტს, მისი პერორალური ან კანისმიერი LD50 განსაზღვრა შესაძლებელია სამი შესაძლო მიდგომით. უპირატეს მეთოდს წარმოადგენს საიმედო მონაცემების მიღება გადასაზიდი ფაქტიური ნარევის მწვავე პერორალური და კანისმიერი ტოქსიკურობის შესახებ, ხოლო იმ შემთხვევაში, თუ შეუძლებელია საიმედო, ზუსტი მონაცემების მიღება, მაშინ შესაძლებელია განხორციელდეს ქვემოთ წარმოდგენილი ერთ-ერთი მეთოდი: (ა) მოახდინეთ შემადგენლობის კლასიფიცირება ნარევის ყველაზე სახიფათო კომპონენტის შესაბამისად ისე, რომ აღნიშნული კომპონენტი წარმოდგენილი ყოფილიყო ყველა აქტიური კომპონენტის საერთო კონცენტრაციის თანაბარი იმავე კონცენტრაციით: (ბ) გამოიყენეთ შემდეგი ფორმულა: სადაც: C = A, B, ...... Z კომპონენტების პროცენტულ კონცენტრაციას ნარევში; T = A, B, ...... Z კომპონენტების პერორალურ LD50 მნიშვნელობებს; TM = ნარევის პერორალურ LD50 მნიშვნელობას; შენიშვნა: ამ ფორმულის გამოყენება ასევე შესაძლებელია კანისმიერ ტოქსიკურობასთან დაკავშირებით იმ პირობით, რომ აღნიშნული ინფორმაცია არსებობს ყველა კომპონენტის ერთსა და იმავე სახეობებთან დაკავშირებით. მოცემული ფორმულის გამოყენება არ ითვალისწინებს პოტენცირებისა თუ დაცვის რაიმე გამოვლინებას. პესტიციდების კლასიფიკაცია 2.2.61.1.11 ყველა აქტიური პესტიციდური ნივთიერება და მათი პრეპარატები, რომლებთან დაკავშირებითაც ცნობილია LC50 და/ან LD50 მნიშვნელობები და რომლებიც კლასიფიცირებულია 6.1 კლასში, კლასიფიცირებულ უნდა იქნეს შესაბამისი შეფუთვის ჯგუფში 2.2.61.1.6-დან 2.2.61.1.9 ქვეპუნქტებში გათვალისწინებული კრიტერიუმების შესაბამისად. ნივთიერებები და პრეპარატები, რომლებიც ხასიათდება დამატებითი საშიშროებებით, კლასიფიცირდება 2.1.3.10 პუნქტში წარმოდგენილი სახიფათო თვისებების პრიორიტეტების ცხრილის შესაბამისად და მიეკუთვნება შესაბამის შეფუთვის ჯგუფებს. 2.2.61.1.11.1 იმ შემთხვევაში, თუ პესტიციდური პრეპარატის პერორალური და კანისმიერი LD50 მნიშვნელობა უცნობია, მაგრამ ცნობილია მისი აქტიური ნივთიერებ(ებ)ის LD50 მნიშვნელობა, პრეპარატის LD50 მნიშვნელობა შესაძლებელია მიღებულ იქნეს 2.2.61.1.10 ქვეპუნქტში მოყვანილი პროცედურების გამოყენებით. შენიშვნა: გავრცელებული პესტიციდების რაოდენობასთან დაკავშირებით LD50 ტოქსიკურობის შესახებ მონაცემები შესაძლებელია მიღებულ იქნეს დოკუმენტის „პესტიციდების კლასიფიკაცია მსოფლიო ჯანდაცვის ორგანიზაციის მიერ 258 რეკომენდებული გზით საშიშროებების მიხედვით და კლასიფიკაციასთან დაკავშირებული მითითებები“ ყველაზე თანამედროვე გამოცემიდან, რომელიც ხელმისაწვდომია მსოფლიო ჯანდაცვის ორგანიზაციის (WHO), მდებარე მისამართზე: შვეიცარია, 1211 ჟენევა 27, ქიმიური უსაფრთხოების საერთაშორისო პროგრამიდან. ვინაიდან აღნიშნული დოკუმენტის გამოყენება შესაძლებელია პესტიციდებთან დაკავშირებული LD50 მონაცემების წყაროს სახით, მისი კლასიფიკაციის სისტემის გამოყენება დაუშვებელია პესტიციდების კლასიფიკაციისას გადაზიდვების მიზნით ან მათი მიკუთვნებისას შესაბამის შეფუთვის ჯგუფებზე, აღნიშნული მიზნები განხორციელებულ უნდა იქნეს ADR-ის მოთხოვნების შესაბამისად. 2.2.61.1.11.2 პესტიციდების გადაზიდვისას გამოყენებული სათანადო გადაზიდვის დასახელება შერჩეულ უნდა იქნეს პესტიციდის აქტიური კომპონენტის, ფიზიკური მდგომარეობისა იმ ნებისმიერი დამატებითი საშიშროების საფუძველზე, რომელიც შესაძლებელია გამოვლინდეს მის მიერ (იხილეთ 3.1.2 პუნქტი). 2.2.61.1.2 იმ შემთხვევაში, თუ დანამატების შეტანის შემდეგ 6.1 კლასის ნივთიერებები მოხვდება საშიშროებების სხვადასხვა კატეგორიაში, რომლებიც განსხვავდება ის საშიშროებების კატეგორიებისგან, რომელთაც მიეკუთვნებათ 3.2 თავის A ცხრილში დასახელებით მითითებული ნივთიერებები, აღნიშნული ნარევებისა თუ ნივთიერებების მიკუთვნება უნდა მოხდეს იმ პოზიციებზე, რომელსაც ისინი განეკუთვნება მათი საშიშროების ფაქტიური ხარისხის საფუძველზე. შენიშვნა: ხსნარებისა და ნარევების (როგორიცაა პრეპარატები და ნარჩენები) კლასიფიკაციასთან დაკავშირებით, იხილეთ 2.1.3 პუნქტი. 2.2.61.1.13 2.2.61.1.6-დან 2.2.61.1.11 ქვეპუნქტებით გათვალისწინებული კრიტერიუმების საფუძველზე, შესაძლებელია აგრეთვე განისაზღვროს წარმოადგენს თუ არა ნებისმიერი ნივთიერებისა თუ ნარევის თვისებები, რომლებიც მითითებულია დასახელებით ან შეიცავს დასახელებით მითითებულ ნებისმიერ ნივთიერებას, იმ სახის, რომ აღნიშნულ ხსნარსა თუ ნარევზე არ გავრცელდეს ამ კლასთან დაკავშირებით დადგენილი მოთხოვნები. 2.2.61.1.14 ნივთიერებები, ხსნარები და ნარევები, პესტიციდების სახით გამოყენებული ნივთიერებებისა და პრეპარატების გარდა, რომლებიც ვერ აკმაყოფილებს 67/548/EEC4 ან 1999/45/EC4 დირექტივებს, მათში შეტანილ ცვლილებებთან ერთად, კრიტერიუმებს და ამის გამო არ არის კლასიფიცირებული, როგორც მაღალტოქსიკური, ტოქსიკური ან საზიანო აღნიშნული დირექტივების, მათში შეტანილ ცვლილებებთან ერთად, შესაბამისად, შესაძლებელია განხილულ იქნეს, როგორც ნივთიერებები, რომლებიც არ მიეკუთვნება 6.1 კლასს. 2.2.61.2 ნივთიერებები, რომლებიც არ დაიშვება გადაზიდვებზე 2.2.61.2.1 6.1 კლასით გათვალისწინებული ქიმიურად არასტაბილური ნივთიერებები არ დაიშვება გადაზიდვებზე, სანამ არ განხორციელდება შესაბამისი ზომები მათი სახიფათო დაშლისა თუ პოლიმერიზაციის პრევენციის მიზნით გადაზიდვების დროს. აღნიშნულიდან გამომდინარე, უნდა მოხდეს იმ ფაქტის უზრუნველყოფა, რომ ჭურჭელი და ცისტერნები არ შეიცავდეს აღნიშნული რეაქციების გამომწვევ რაიმე ნივთიერებას (ნივთიერებებს). 2.2.61.2.2 შემდეგი ნივთიერებები და ნარევები არ დაიშვება გადაზიდვებზე: 259 - წყალბადის ციანიდი, უწყლო ან ხსნარში, რომელიც ვერ აკმაყოფილებს გაეროს ნომრებით 1051, 1613, 1614 და 3294 გათვალისწინებულ აღწერილობებს; - ლითონის კარბონილები, რომელთა აფეთქების ტემპერატურა 230C-ზე ნაკლებია, გარდა გაეროს ნომრებისა 1259 - ნიკელის კარბონილი და 1994 რკინის პენტაკარბონილი; - 2,3,7,8-ტეტრაქლოროდიბენზო-პარა-დიოქსინი კონცენტრაციებში, რომლებიც ითვლება ძლიერტოქსიკურად 2.2.61.1.7 ქვეპუნქტში გათვალისწინებული კრიტერიუმების შესაბამისად; - გაეროს № 2249 - დიქლოროდიმეთილის ეთერი, სიმეტრიული; - ფოსფიდების პრეპარატები დანამატების გარეშე, რომლებიც ტოქსიკური, ადვილაალებადი აირების გამოყოფის ინჰიბირებას. ახდენენ საბჭოს 1967 წლის 27 ივნისის 67/548/EEC დირექტივა სახიფათო ნივთიერებების კლასიფიკაციასთან, შეფუთვასა და მარკირებასთან დაკავშირებული კანონების, განაწესებისა და ადმინისტრაციული დებულებების მიახლოვების შესახებ (ევროპული გაერთიანების ოფიციალური ჟურნალი №L196, 16.08.1967 წ). 3 ევროპარლამენტისა და საბჭოს 1999 წლის 31 მაისის 1999/45/EC დირექტივა სახიფათო პრეპარატების კლასიფიკაციასთან, შეფუთვასა და მარკირებასთან დაკავშირებული წევრი სახელმწიფოების შესახებ კანონების, განაწესებისა და ადმინისტრაციული დებულებების მიახლოების შესახებ (ევროპული გაერთიანების ოფიციალური ჟურნალი №L200, 1999 წლის 30 ივლისი). 4 260 2.2.61.3 ერთობლივი პოზიციების ჩამონათვალი ტოქსიკური ნივთიერებები დამატებითი რისკ(ებ)ის გარეშე თხევადია T1 ორგანული 1583 1602 1602 1693 1851 2206 2206 3140 3140 3142 3144 3144 3172 3276 3278 3381 2810 ქლოროპიკრინის ნარევი, N.O.S. საღებავი, თხევადი, ტოქსიკური, N.O.S. ან ნახევრად საღებავი, თხევადი, ტოქსიკური, N.O.S. ცრემლსადენი აირის ნივთიერება, თხევადი, N.O.S. სამკურნალო პრეპარატი, თხევადი, ტოქსიკური, N.O.S. იზოციანატები, ტოქსიკური, N.O.S. ან იზოციანატის ხსნარი, ტოქსიკური, N.O.S. ალკალოიდები, თხევადი, N.O.S. ან ალკალოიდის მარილები, თხევადი, N.O.S. სადეზინფექციო საშუალება, თხევადი, ტოქსიკური, N.O.S. ნიკოტინის ნაერთი,თხევადი, N.O.S. ან ნიკოტინის პრეპარატი, თხევადი, N.O.S. ტოქსინები, ამოღებული ცოცხალი ორგანიზმებიდან, თხევადი, N.O.S. ნიტრილები, ტოქსიკური, თხევადი, N.O.S. ორგანული ფოსფორის ნაერთი, ტოქსიკური, თხევადი, N.O.S. ტოქსიკური სითხის ინჰალაციისას, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 200 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 500 LC50 ტოქსიკური სითხის ინჰალაციისას, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 1000 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 10 LC50 ტოქსიკური სითხე, ორგანული N.O.S. 1544 1544 1601 1655 1655 3448 3143 3143 3462 3249 3464 3439 2811 ალკალოიდები, მყარი, N.O.S. ან ალკალოიდური მარილები, მყარი, N.O.S. სადეზინფექციო საშუალებები, მყარი, ტოქსიკური, N.O.S. ნიკოტინის ნაერთი, მყარი, N.O.S. ან ნიკოტინის პრეპარატი, მყარი, N.O.S. ცრემლსადენი აირის ნივთიერება, მყარი, N.O.S. საღებავი, მყარი, ტოქსიკური, N.O.S. ან ნახევრად საღებავი, მყარი, ტოქსიკური, N.O.S. ტოქსინები, ამოღებული ცოცხალი ორგანიზმებიდან, მყარი, N.O.S. სამკურნალო პრეპარატი, მყარი, ტოქსიკური, N.O.S. ორგანული ფოსფორის ნაერთი, ტოქსიკური, მყარი, N.O.S. ნიტრილები, ტოქსიკური, მყარი, N.O.S. ტოქსიკური მყარი ნივთიერება, ორგანული N.O.S. 2026 2788 3146 3280 3465 3281 3466 3282 3467 ფენილ-ვერცხლისწყლის ნაერთი, N.O.S. კალა-ორგანული ნაერთი, თხევადი, N.O.S. კალა-ორგანული ნაერთი, მყარი, N.O.S. დარიშხან-ორგანული ნაერთი, თხევადი, N.O.S. დარიშხან-ორგანული ნაერთი, მყარი, N.O.S. ლითონის კარბონილები, თხევადი, N.O.S. ლითონის კარბონილები, მყარი, N.O.S. ლითონორგანული ნაერთი, ტოქსიკური, თხევადი, N.O.S. ლითონორგანული ნაერთი, ტოქსიკური, მყარი, N.O.S. 3382 მყარი ა, ბ ლითონორგანულიგ, დ T2 T3 (გაგრძელება მომდევნო გვერდზე) პესტიციდების სახით გამოყენებული, ალკალოიდებისა თუ ნიკოტინის შემცველი ნივთიერებები და პრეპარატები კლასიფიცირდება გაეროს №2588 - პესტიციდები, მყარი, ტოქსიკური, N.O.S., გაეროს № - პესტიციდები, თხევადი, ტოქსიკური, N.O.S. ან გაეროს №2903 - პესტიციდები, თხევადი, ტოქსიკური, ადვილაალებადი, N.O.S. ა აქტიური ნივთიერებები და ფხვნილები ან ნივთიერებების ნაერთები, რომლებიც გათვალისწინებულია ლაბორატორიული და ექსპერიმენტული მიზნებისთვის და ფარმაცევტული პროდუქციის წარმოებისთვის სხვა ნივთიერებებთან ერთად, რომლებიც კლასიფიცირდება მათი ტოქსიკურობის შესაბამისად (იხილეთ 2.2.61.1.7-დან 2.2.61.1.11 პუნქტამდე). ნ თვით-თბობადი ნივთიერებები, სუსტად ტოქსიკური და თვითაალებადი ლითონორგანული ნაერთები, წარმოადგენს 4.2 კლასის ნივთიერებებს. გ წყალზე რეაგირებადი ნივთიერებები, სუსტად ტოქსიკური და წყალზე რეაგირებადი ლითონორგანული ნაერთები, წარმოადგენს 4.3 კლასის ნივთიერებას. დ 261 2.2.61.3 ერთობლივი პოზიციების ჩამონათვალი (გაგრძელება) ტოქსიკური ნივთიერებები დამატებითი რისკ(ებ)ის გარეშე (გაგრძელება) 1556 თხევადიე T4 1935 2024 3141 3440 3381 3382 არაორგანული 3287 1549 1557 მყარი ვ.ზ სითხე თ T5 T6 პესტიციდები (გაგრძელება მომდევნო გვერდზე) დარიშხანის ნაერთი, თხევადი, N.O.S. არაორგანული, შეიცავს: არსენატებს, N.O.S. არსენიტებს, N.O.S. და დარიშხანის სულფიდებს, N.O.S. ციანიდის ხსნარი, N.O.S. ვერცხლისწყლის ნაერთი, თხევადი, N.O.S. სტიბიუმის ნაერთი, არაორგანული, თხევადი, N.O.S. სელენის ნაერთი, თხევადი, N.O.S. ტოქსიკური სითხის ინჰალაციისას, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 200 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 500 LC50 ტოქსიკური სითხის ინჰალაციისას, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 1000 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 10 LC50 ტოქსიკური სითხე, არაორგანული N.O.S. 1564 1566 1588 1707 2025 2291 2570 2630 2856 3283 3284 3285 3288 სტიბიუმის ნაერთი, არაორგანული, მყარი, N.O.S. დარიშხანის ნაერთი, მყარი, N.O.S. არაორგანული, შეიცავს: არსენატებს, N.O.S. არსენიტებს, N.O.S. და დარიშხანის სულფიდებს, N.O.S. ბარიუმის ნაერთი, N.O.S. ბერილიუმის ნაერთი, N.O.S. ციანიდები, არაორგანული, მყარი, N.O.S. ტალიუმის ნაერთი, N.O.S. ვერცხლისწყლის ნაერთი, თხევადი. N.O.S. ტყვიის ნაერთი, ხსნადი, N.O.S. კადმიუმის ნაერთი სელენატები ან სელენიტები ფტორსილიკატები, N.O.S. ტელურიუმის ნაერთი, N.O.S. ვანადიუმის ნაერთი, N.O.S. ტოქსიკური მყარი ნივთიერება, არაორგანული, N.O.S. 2992 2994 2996 2998 3006 3010 3012 3014 3016 3018 3020 3026 3348 3352 2902 კარბამატის პესტიციდი, თხევადი, N.O.S. დარიშხანის პესტიციდი, თხევადი, ტოქსიკური ქლორორგანული პესტიციდი, თხევადი, ტოქსიკური ტრიაზინის პესტიციდი, თხევადი, ტოქსიკური თიოკარბამატის პესტიციდი, თხევადი, ტოქსიკური სპილენძის შემცველი პესტიციდი, თხევადი, ტოქსიკური ვერცხლისწყლის შემცველი პესტიციდი, თხევადი, ტოქსიკური შემცვლელი ნიტროფენოლის პესტიციდი, თხევადი, ტოქსიკური ბიპირიდილიუმის პესტიციდი, თხევადი, ტოქსიკური ფოსფორორგანული პესტიციდი, თხევადი, ტოქსიკური კალა-ორგანული პესტიციდი, თხევადი, ტოქსიკური კუმარინის წარმოებულის პესტიციდი, თხევადი, ტოქსიკური ფენოქსიაცეტილის მჟავის წარმოებული პესტიციდი, თხევადი, ტოქსიკური პირეთღოიდის პესტიციდი, თხევადი, ტოქსიკური პესტიციდი, თხევადი, ტოქსიკური, N.O.S. ე ვერცხლიწყლის ფულმინატი, დასველებული, წყლის ან სპირტისა და წყლის ნარევის არანაკლებ 20% მასური წილთ, წარმოადგენს პირველი კლასის ნივთიერებას, გაეროს ნომრით 0135. ვ ADR-ის დებულებები არ მოქმედებს ფეროციანიდებთან, ფერიციანიდებთან, ტუტე თიოციანატებთან და ამონიუმის თიოციანატებთან დაკავშირებით. ADR-ის დებულებები არ მოქმედებს ტყვიის მარილებთან და ტყვიის პიგმენტებთან დაკავშირებით, რომლებიც 1:1,000 თანაფარდობით შერევისას 0.07მ ქლორწყალბადის მჟავასთან და ერთი საათის განმავლობაში 230C + 20C შერევისას, ავლენს 5% ან ნაკლებ ხსნადობის უნარს. ზ ADR-ის დებულებები არ მოქმედებს ამ პესტიციდებით გაჟღენთილ ნაკეთობებთან დაკავშირებით, როგორიცაა მუყაოს ფირფიტები, ქაღალდის ლენტები, ბამბის ტამპონები, პლასტმასის მასალის შრეები, ჰერმეტულად დახურულ შეფუთვებში. თ 262 2.2.61.3 ერთობლივი პოზიციების ჩამონათვალი (გაგრძელება) ტოქსიკური ნივთიერებები დამატებითი რისკ(ებ)ის გარეშე (გაგრძელება) პესტიციდები (გაგრძელება) მყარით ნიმუშები T7 2757 2759 2761 2763 2771 2775 2777 2779 2781 2783 2786 3027 3048 3345 3349 2588 კარბამატის პესტიციდი, მყარი, ტოქსიკური დარიშხანის შემცველი პესტიციდი, მყარი, ტოქსიკური ქლოროორგანული პესტიციდი, მყარი, ტოქსიკური ტრიაზინის პესტიციდი, მყარი, ტოქსიკური თიოკარბამატის პესტიციდი, მყარი, ტოქსიკური სპილენძის შემცველი პესტიციდი, მყარი, ტოქსიკური ვერცხლისწყლის შემცველი პესტიციდი, მყარი, ტოქსიკური შეცვლილი ნიტროფენოლის პესტიციდი, მყარი, ტოქსიკური ბიპირიდილიუმის პესტიციდი, მყარი, ტოქსიკური ფოსფორორგანული პესტიციდი, მყარი, ტოქსიკური კალა-ორგანული პესტიციდი, მყარი, ტოქსიკური კუმარინის წარმოებულის პესტიციდი, მყარი, ტოქსიკური ალუმინის ფოსფიდის პესტიციდი ფენოქსიაცეტილმჟავის წარმოებულის პესტიციდი, მყარი, ტოქსიკური პირეთროიდის პესტიციდი, მყარი, ტოქსიკური პესტიციდი, მყარი, ტოქსიკური, N.O.S. 3315 ქიმიური ნიმუში, ტოქსიკური 3243 ტოქსიკური სითხის შემცველი მყარი ნივთიერებები, N.O.S. T8 სხვა ტოქსიკური ნივთიერებებიი T9 ტოქსიკური ნივთიერებები დამატებით რისკ(ებ)თან ერთად თხევადი კ,ლ TF1 ადვილაალებადი TF 3071 3071 3080 3080 3275 3279 3383 3384 2929 მერკაპტანები, თხევადი, ტოქსიკური, ადვილაალებადი, N.O.S. მერკაპტანის ნარევი, თხევადი, ტოქსიკური, ადვილაალებადი, N.O.S. იზოციანატები, ტოქსიკური, ადვილაალებადი, N.O.S. ან იზოციანატის ხსნარი, ტოქსიკური, ადვილაალებადი, N.O.S. ნიტრილები, ტოქსიკური, ადვილაალებადი, N.O.S. ფოსფორორგანული ნაერთი, ტოქსიკური, ადვილაალებადი, N.O.S. ტოქსიკური სითხის ინჰალაციისას, ადვილაალებადი N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 200 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 500 LC50 ტოქსიკური სითხის ინჰალაციისას, ადვილაალებადი, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 1000 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 10 LC50 ტოქსიკური სითხე, ადვილაალებადი, ორგანული N.O.S. (გაგრძელება მომდევნო გვერდზე) ADR-ის დებულებები არ მოქმედებს ამ პესტიციდებით გაჟღენთილ ნაკეთობებთან დაკავშირებით, როგორიცაა მუყაოს ფირფიტები, ქაღალდის ლენტები, ბამბის ტამპონები, პლასტმასის მასალის შრეები, ჰერმეტულად დახურულ შეფუთვებში. ი მყარი ნივთიერებების ნარევები, რომლებიც არ ექვემდებარება ADR-ის დებულებებს, ასევე ტოქსიკური სითხეების ნარევები შესაძლებელია გადატანილ იქნეს გაეროს ნომრით 3243, მათთან დაკავშირებით 6.1 კლასის კრიტერიუმების გამოყენების გარეშე იმ პირობით, რომ ნივთიერების დატვირთვისა თუ ტარის, კონტეინერისა თუ ავტოსატრანსპორტო ერთეულის დახურვის მომენტისთვის არ შეინიშნება სითხის გაჟონვის ხილული კვალი. ყოველი ტარა უნდა შეესაბამებოდეს კოსტრუქციის ტიპს, რომელმაც გაიარა გამოცდა გაჟონვაზე II შეფუთვის ჯგუფის დონეზე. აღნიშნული პოზიცია არ უნდა იქნეს გამოყენებული I შეფუთვის ჯგუფში გათვალისწინებული სითხის შემცველ მყარ ნივთიერებებთან დაკავშირებით. კ ძლიერტოქსიკური ან ტოქსიკური, ადვილაალებადი სითხეები, რომელთა აფეთქების ტემპერატურა არ აღემატება 230Cს, წარმოადგენს მე-3 კლასის ნივთიერებებს, გარდა იმ ნივთიერებებისა, რომლებიც წარმოადგენს ძლიერტოქსიკურს ინჰალაციის შემთხვევაში, 2.2.61.1.4-2.2.61.1.9 ქვეპუნქტების შესაბამისად. სითხეები, რომლებიც წარმოადგენს ძლიერტოქსიკურს ინჰალაციის შემთხვევაში, მითიტებულია როგორც „ძლიერტოქსიკური ინჰალაციის შემთხვევაში“ (2) სვეტით გათვალისწინებულ მათ შესაბამის გადაზიდვის დასახელებაში ან 3.2 თავის A ცხრილის (6) სვეტის 354-ე სპეციალური დებულებებით. ლ ადვილაალებადი სითხეები, სუსტად ტოქსიკური, პესტიციდების სახით გამოყენებული ნივთიერებებისა და პრეპარატების გარდა, რომელთა აფეთქების ტემპერატურა მერყეობს 230C-და 600C-ის ჩათვლით, წარმოადგენს მე-3 კლასში შემავალ ნივთიერებებს. თ 263 2.2.61.3 ერთობლივი პოზიციების ჩამონათვალი (გაგრძელება) ტოქსიკური ნივთიერებები დამატებით რისკ(ებ)თან ერთად (გაგრძელება) ადვილაალებადი (გაგრძელება) პესტიციდები, თხევადი TF2 (აფეთქების ტემპერატურა არანაკლებია 230C-ზე მყარი მყარი, თვითთბობადი ნივთიერებაგ TS თხევადი TF3 TW1 2991 2993 2995 2997 3005 3009 3011 3013 3015 3017 3019 3025 3347 3351 2903 კარბამატის პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი დარიშხანის შემცველი პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი ქლოროორგანული პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი ტრიაზინის პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი თიოკარბამატის პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი სპილენძის შემცველი პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი ვერცხლისწყლის შემცველი პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი შეცვლილი ნიტროფენოლის პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი ბიპირიდილიუმის პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი ფოსფორორგანული პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი კალა-ორგანული პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი კუმარინის წარმოებულის პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი ფენოქსიაცეტილმჟავის წარმოებულის პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი პირეთროიდის პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი პესტიციდი, თხევადი, ტოქსიკური, ადვილაალებადი, N.O.S. 1700 2930 ცრემლსადენი აირის ნათურები ტოქსიკური მყარი ნივთიერება, ადვილაალებადი, ორგანული, N.O.S. 3124 ტოქსიკური მყარი ნივთიერება, თვითმთბობი, N.O.S. 3385 3123 ტოქსიკური სითხის ინჰალაციისას, წყალზე რეაგირებადი, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 200 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 500 LC50 ტოქსიკური სითხის ინჰალაციისას, წყალზე რეაგირებადი, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 1000 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 10 LC50 ტოქსიკური თხევადი ნივთიერება, წყალზე რეაგირებადი, N.O.S. 3125 ტოქსიკური მყარი ნივთიერება, წყალზე რეაგირებადი, N.O.S. 3387 3122 ტოქსიკური სითხის ინჰალაციისას, მჟანგავი, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 200 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 500 LC50 ტოქსიკური სითხის ინჰალაციისას, მჟანგავი, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 1000 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 10 LC50 ტოქსიკური თხევადი ნივთიერება, მჟანგავი, N.O.S. 3086 ტოქსიკური მყარი ნივთიერება, ჟანგავი, N.O.S. 3277 3361 3389 2927 ქლორფორმატები, ტოქსიკური, კოროზიული, N.O.S. ქლორსილანები, ტოქსიკური, კოროზიული, N.O.S. ტოქსიკური სითხის ინჰალაციისას, კოროზიული, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 200 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 500 LC50 ტოქსიკური სითხის ინჰალაციისას, კოროზიული, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 1000 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 10 LC50 ტოქსიკური თხევადი ნივთიერება, კოროზიული, ორგანული, N.O.S. 2928 ტოქსიკური მყარი ნივთიერება, კოროზიული, ორგანული, N.O.S. 3386 წყალზე რეაგირებადიდ TW მყარიო TW2 თხევადი TO1 3388 მჟანგავიმ TO მყარი TO2 თხევადი TC1 კოროზიულინ TC 3390 მყარი TC2 (გაგრძელება მომდევნო გვერდზე) გ თვითთბობადი ნივთიერებები, სუსტად ტოქსიკური და თვითაალებადი ლითონორგანული ნაერთები, წარმოადგენს 4.2 კლასის ნივთიერებებს. დ წყალზე რეაგირებადი ნივთიერებები, სუსტად ტოქსიკური და წყალზე რეაგირებადი ლითონორგანული ნაერთები, წარმოადგენს 4.3 კლასის ნივთიერებებს. მ მჟანგავი ნივთიერებები, სუსტად ტოქსიკური, წარმოადგენს 5.1 კლასის ნივთიერებებს. ნ სუსტად ტოქსიკური და სუსტად კოროზიული ნივთიერებები წარმოადგენს მე-8 კლასის ნივთიერებებს. ო ლითონის ფოსფიდები, რომლებიც განეკუთვნება გაეროს ნომრებს 1360, 1397, 1432, 1714, 2011 და 2013, წარმოადგენს 4.3 კლასის ნივთიერებებს. 264 2.2.61.3 ერთობლივი პოზიციების ჩამონათვალი (გაგრძელება) ტოქსიკური ნივთიერებები დამატებით რისკ(ებ)თან ერთად (გაგრძელება) კოროზიულინ TC (გაგრძელება) 3389 3289 ტოქსიკური სითხის ინჰალაციისას, კოროზიული, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 200 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 500 LC50 ტოქსიკური სითხის ინჰალაციისას, კოროზიული, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 1000 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 10 LC50 ტოქსიკური თხევადი ნივთიერება, კოროზიული, N.O.S. 3290 ტოქსიკური მყარი ნივთიერება, კოროზიული, არაორგანული, N.O.S. 2742 3362 3488 ქლორფორმატები, ტოქსიკური, კოროზიული, ადვილაალებადი, N.O.S. ქლოროსილანები, ტოქსიკური, კოროზიული, ადვილაალებადი, N.O.S. ტოქსიკური სითხის ინჰალაციისას, ადვილაალებადი, კოროზიული, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 200 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 500 LC50 ტოქსიკური სითხის ინჰალაციისას, ადვილაალებადი, კოროზიული, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 1000 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 10 LC50 3390 თხევადი TC3 არაორგანული მყარი ადვილაალებადი, კოროზიული TFC TC4 3489 3490 ადვილაალებადი, წყალზე რეაგირებადი TFW ნ 3491 ტოქსიკური სითხის ინჰალაციისას, წყალზე რეაგირებადი, ადვილაალებადი, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 200 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 500 LC50 ტოქსიკური სითხის ინჰალაციისას, წყალზე რეაგირებადი, ადვილაალებადი, N.O.S. რომლის საინჰალაციო ტოქსიკურობა ნაკლებია ან ტოლია 1000 მლ/ლ3, ხოლო ნაჯერი ორთქლის კონცენტრაცია მეტია ან ტოლია 10 LC50 სუსტად ტოქსიკური და სუსტად კოროზიული ნივთიერებები წარმოადგენს მე-8 კლასის ნივთიერებებს. 265 2.2.62 კლასი 6.2 ინფექციური ნივთიერებები 2.2.62.1 კრიტერიუმები 2.2.62.1.1 6.2 კლასის სახელწოდებაში გათვალისწინებულია ინფექციური ნივთიერებები. ADRის მიზნებიდან გამომდინარე, ინფექციური ნივთიერებები წარმოადგენს ნივთიერებებს, რომელიც ცნობილია ან არსებობს საფუძლიანი ვარაუდი, რომ შეიცავს პათოგენებს. პათოგენები განისაზღვრება, როგორც მიკროორგანიზმები (მათ შორის ბაქტერიები, ვირუსები, რიკეტსიები, პარაზიტები, სოკოები) და სხვა ინფექციური საშუალებები, როგორიცაა პრიონები, რომელთაც შეუძლიათ გამოიწვიონ დაავადებები ადამიანებსა თუ ცხოველებში. შენიშვნა 1: აღნიშნულ კლასს უნდა მიეკუთვნოს გენეტიკურად მოდიფიცირებული მიკროორგანიზმები და ორგანიზმები, ბიოლოგიური პროდუქტები, სადიაგნოსტიკო ნიმუშები და დაინფიცირებული ცოცხალი ცხოველები იმ შემთხვევაში, თუ ისინი აკმაყოფილებს აღნიშნულ კლასთან დაკავშირებით არსებულ მოთხოვნებს. შენიშვნა 2: მცენარეული, ცხოველური ან ბაქტერიული წარმოშობის ტოქსინები, რომლებიც არ შეიცავს არავითარ ინფექციურ ნივთიერებასა თუ ორგანიზმს, ან არ არის წარმოდგენილი მათში, წარმოადგენს 6.2 კლასის ნივთიერებებს, გაეროს N3172 და 3642. 2.2.62.1.2 6.2 კლასის ნივთიერებები იყოფა შემდეგნაირად: I1 ადამიანებისთვის სახიფათო ინფექციური ნივთიერებები; I2 მხოლოდ ცხოველებისთვის სახიფათო ინფექციური ნივთიერებები; I3 კლინიკური ნარჩენები; I4 ბიოლოგიური ნივთიერებები. განმარტებები 22.2.62.1.3 ADR-ის მიზნებიდან გამომდინარე, „ბიოლოგიური პროდუქტები“ ნიშნავს პროდუქტებს, რომლებიც მიიღება იმ ცოცხალი ორგანიზმებიდან, რომელთა წარმოებაც და გავრცელებაც განხორციელდა შესაბამისი ეროვნული ორგანოს მოთხოვნების შესაბამისად, რომელსაც შესაძლებელია გააჩნდეთ სპეციალური სალიცენზიო მოთხოვნები და რომლებიც გამოიყენება როგორც ადამიანებსა თუ ცხოველებში დაავადების პრევენციისთვის, განკურნებისა თუ დიაგნოსტირებისთვის, ასევე აღნიშნულთან დაკავშირებული განვითარების, საექსპერიმენტო ან საკვლევი მიზნებისთვის. ისინი ითვალისწინებს, თუმცა არ შემოიფარგლება მოხმარებისთვის მზა ან დაუსრულებელ პროდუქტებს, როგორიცაა, მაგალითად ვაქცინები. „კულტურები“ წარმოადგენს პროცესის შედეგს, რომლის გზითაც პათოგენები თვითნებურად მრავლდება. აღნიშნული განმარტება არ ითვალისწინებს ადამიანი ან ცხოველი პაციენტებების ნიმუშს, რაც განმარტებულია წინამდებარე პუნქტში; „სამედიცინო ან კლინიკური ნარჩენები“ ნიშნავს ცხოველებისა თუ ადამიანების სამედიცინო მკურნალობის შედეგად, ასევე ბიოკვლევების შედეგად წარმოშობილ ნარჩენებს; 266 „პაციენტისგან აღებული ნიმუშები“ ნიშნავს ადამიანურ ან ცხოველურ მასალას, რომლებიც აღებულ იქნა უშუალოდ ადამიანებისა თუ ცხოველებისგან, რაც ითვალისწინებს, თუმცა არ შემოიფარგლება ექსკრემენტებით, სეკრეციის პროდუქტებით, სისხლითა და მისი კომპონენტებით, ქსოვილებითა და ქსოვილის სითხის ტამპონით, ასევე სხეულის ორგანოებით, რომელთა გადაზიდვაც ხორციელდება ისეთი მიზნებისთვის, როგორიცაა კვლევა, დიაგნოსტიკა, კვლევითი საქმიანობა, დაავადების მკურნალობა ან პროფილაქტიკა. კლასიფიკაცია 2.2.62.1.4 ინფექციური ნივთიერებების კლასიფიკაცია უნდა მოხდეს 6.2 კლასში და მიეკუთვნოს გაეროს N2814, 2900, 3291 ან 3373, კონკრეტული შემთხვევიდან გამომდინარე. ინფექციური დაავადებები იყოფა შემდეგ კატეგორიებად: 2.2.62.1.4.1 ა კატეგორია: ინფექციური ნივთიერება, რომლის გადაზიდვაც ხდება ისეთი სახით, რომ მისი ზემოქმედების შემთხვევაში, შეუძლია გამოიწვიოს მუდმივი ქმედუუნარობა, სიცოცხლისთვის სახიფათო ან ფატალური დაავადება ჯანმრთელ ადამიანებსა და ცხოველებში. ზემოაღნიშნული ნივთიერებების საჩვენებელი ნიმუშები, რომლებიც აკმაყოფილებს მოცემულ კრიტერიუმებს, წარმოდგენილია წინამდებარე პუნქტის ცხრილში. შენიშვნა: ზემოქმედებას ადგილი აქვს მაშინ, როდესაც ხდება ინფექციური ნივთიერების გამოსვლა მისი დამცავი შეფუთვის გარეთ, რასაც მოჰყვება მისი ფიზიკური შეხება ადამიანებსა თუ ცხოველებთან. (ა) (ბ) ინფექციური დაავადებები, რომლებიც პასუხობს აღნიშნულ კრიტერიუმებს და იწვევს დაავადებას ადამიანებში ან როგორც ადამიანებში, ასევე ცხოველებში, განეკუთვნება გაეროს N2814, ხოლო ინფექციური ნივთიერებები, რომლებიც იწვევს დაავადებას მხოლოდ ცხოველებში, მიეკუთვნება გაეროს N2900. გაეროს ნომრების 2814 და 2900 მინიჭება შესაძლებელია მხოლოდ ავადმყოფობის ისტორიიდან ცნობილი მონაცემებისა და ადამიანისა თუ ცხოველის წყაროს დაავადებების სიმპტომების, ადგილობრივი ეპიდემიური პირობების შესახებ ინფორმაციისა და სპეციალისტის დასკვნის გათვალისწინებით ადამიანისა თუ ცხოველის წყაროს ინდივიდუალურ მდგომარეობასთან დაკავშირებით. შენიშვნა 1: გადაზიდვის შესაბამისი დასახელება გაეროს N2814 დაკავშირებით არის „ადამიანებისთვის სახიფათო ინფექციური დაავადებები“. გადაზიდვის შესაბამისი დასახელება გაეროს N2900 დაკავშირებით არის „მხოლოდ ცხოველებისთვის სახიფათო ინფექციური დაავადებები“. შენიშვნა 2: ქვემოთ წარმოდგენილი ცხრილი არ არის ამომწურავი. ინფექციური დაავადებები, ახალი ან განვითარებადი პათოგენური ორგანიზმების ჩათვლით, რომლებიც არ არის გათვალისწინებული ცხრილში, თუმცა აკმაყოფილებს იგივე კრიტერიუმებს, უნდა განეკუთვნოს ა კატეგორიას. გარდა ამისა, იმ შემთხვევაში, თუ არსებობს ეჭვი იმასთან დაკავშირებით, აკმაყოფილებს თუ არა ესა თუ ის ნივთიერება აღნიშნულ კრიტერიუმებს, მაშინ მოხდება მისი გათვალისწინება ა კატეგორიაში. შენიშვნა 3: ქვემოთ წარმოდგენილ ცხრილში, კურსივი შრიფტით მითითებული მიკროორგანიზმები წარმოადგენს ბაქტერიებს, მიკროპლაზმებს, რიკეტსიებსა თუ სოკოებს. 267 ა კატეგორიაში ნებისმიერი ფორმით გათვალისწინებული ინფექციური ნივთიერებების საჩვენებელი ნიმუშები, თუ სხვა რამ არ არის მითითებული (2.2.61.1.4.1) გაეროს ნომერი და მიკოორგანიზმი დასახელება გაეროს N2814 Bacillus anthracis (მხოლოდ კულტურები) ადამიანებისთვის Brucella abortus (მხოლოდ კულტურები) სახიფათო Brucella melitensis (მხოლოდ კულტურები) ინფექციური Brucella suis (მხოლოდ კულტურები) ნივთიერებები Burkholderia mallei – Pseudomonas mallei – ქოთაო (მხოლოდ კულტურები) Burkholderia pseudomallei – Pseudomonas pseudomallei (მხოლოდ კულტურები) Chlamydia psittaci - ფრინველის შტამები (მხოლოდ კულტურები) Clostridium botulinum (მხოლოდ კულტურები) Coccidiodes immitis (მხოლოდ კულტურები) Coxiella burnetii (მხოლოდ კულტურები) ყირიმ-კონგოს ჰემორაგიული ცხელების ვირუსი დენგეს ვირუსი (მხოლოდ კულტურები) აღმოსავლური ცხენის ენცეფალიტის ვირუსი (მხოლოდ კულტურები) Escherichia Coli ვეროტოქსინის (მხოლოდ კულტურები)ა ებოლას ვირუსი ფლექსალის ვირუსი Francisella tularensis (მხოლოდ კულტურები) გუანარიტოს ვირუსი ჰანტაანის ვირუსი ჰანტავირუსი, რომელიც იწვევს ჰემორაგიულ ცხელებას, თირკმლის სინდრომთან ერთად ჰენდრას ვირუსი ბ ჰეპატიტის ვირუსი (მხოლოდ კულტურები) ბ ჰერპესის ვირუსი (მხოლოდ კულტურები) ადამიანის იმუნოდეფიციტის ვირუსი (მხოლოდ კულტურები) მაღალპათოგენური ფრინველის გრიპის ვირუსი (მხოლოდ კულტურები) იაპონური ენცეფალიტის ვირუსი (მხოლოდ კულტურები) ჰუნინის ვირუსი კიასანურის ტყის დაავადების ვირუსი ლასას ვირუსი მაჩუპოს ვირუსი მარბურგის ვირუსი მაიმუნის ყვავილის ვირუსი Mycobacterium tuberculosis (მხოლოდ კულტურები)ა ნიპაჰის ვირუსი ომსკის ჰემორაგიული ცხელების ვირუსი პოლიომელიტის ვირუსი უპირატესად იმ შემთხვევებში, როდესაც კულტურები გათვალისწინებულია სადიაგნოსტიკო ან კლინიკური მიზნებისთვის, მათი კლასიფიკაცია შესაძლებელია ბ კატეგორიის ინფექციური ნივთიერებების სახით. ა 268 ა კატეგორიაში ნებისმიერი ფორმით გათვალისწინებული ინფექციური ნივთიერებების საჩვენებელი ნიმუშები, თუ სხვა რამ არ არის მითითებული (2.2.61.1.4.1) გაეროს ნომერი და მიკოორგანიზმი დასახელება გაეროს N2814 ცოფის ვირუსი (მხოლოდ კულტურები) ადამიანებისთვის Rickettsia prowazekii (მხოლოდ კულტურები) სახიფათო Rickettsia ricketsii (მხოლოდ კულტურები) ინფექციური რიფტ-ვალის ცხელების ვირუსი (მხოლოდ კულტურები) ნივთიერებები რუსული გაზაფხული-ზაფხულის ენცეფალიტის ვირუსი (მხოლოდ კულტურები) საბიას ვირუსი Shigella-dysenteriae, პირველი ტიპი (მხოლოდ კულტურები)ა ტკიპის ენცეფალიტის ვირუსი (მხოლოდ კულტურები) ადამიანის ყვავილის ვირუსი ვენესუელური ცხენის ენცეფალიტის ვირუსი (მხოლოდ კულტურები) დასავლეთ ნილოსის ვირუსი (მხოლოდ კულტურები) ყვითელი ცხელების ვირუსი (მხოლოდ კულტურები) Yersinia pestis (მხოლოდ კულტურები) ა კატეგორიაში ნებისმიერი ფორმით გათვალისწინებული ინფექციური ნივთიერებების საჩვენებელი ნიმუშები, თუ სხვა რამ არ არის მითითებული (2.2.61.1.4.1) გაეროს ნომერი და მიკოორგანიზმი დასახელება გაეროს N2900 აფრიკული ღორის ცხელების ვირუსი (მხოლოდ კულტურები) მხოლოდ ფრინველის პარამიქსოვირუსი, პირველი ტიპი - ნიუკასლის დაავადების ცხოველებისთვის ვირუსი (მხოლოდ კულტურები) სახიფათო კლასიკური ღორის ცხელების ვირუსი (მხოლოდ კულტურები) ინფექციური თურქული ვირუსი (მხოლოდ კულტურები) ნივთიერებები კანის აქტინომიკოზის ვირუსი (მხოლოდ კულტურები) Mycoplasma myocides – მსხვილფეხა პირუტყვის კონტაგიოზური წვრილფეხა მცოხნელი ცხოველების ჭირის ვირუსი (მხოლოდ კულტურები) მსხვილფეხა რქოსანი ცხოველების ჭირის ვირუსი (მხოლოდ კულტურები) ცხვრის ყვავილის ვირუსი (მხოლოდ კულტურები) თხის ყვავილის ვირუსი (მხოლოდ კულტურები) ღორის ვეზიკულური დაავადების ვირუსი (მხოლოდ კულტურები) ვეზიკულური სტომატიტის ვირუსი (მხოლოდ კულტურები) უპირატესად იმ შემთხვევებში, როდესაც კულტურები გათვალისწინებულია სადიაგნოსტიკო ან კლინიკური მიზნებისთვის, მათი კლასიფიკაცია შესაძლებელია ბ კატეგორიის ინფექციური ნივთიერებების სახით. ა 269 2.2.62.1.4.2 ბ კატეგორია: ინფექციური ნივთიერება, რომელიც ვერ აკმაყოფილებს ა კატეგორიაზე მისაკუთვნებლად განსაზღვრულ კრიტერიუმებს. ბ კატეგორიაში წარმოდგენილი ინფექციურ ნივთიერებებს უნდა მიენიჭოთ გაეროს №337. შენიშვნა: გაეროს №3373 სათანადო გადაზიდვის სახელწოდებას წარმოადგენს „ბიოლოგიური ნივთიერება, ბ კატეგორია“. 2.2.62.1.5 გამონაკლისები 2.2.62.1.5.1 ADR-ის დებულებები არ ვრცელდება იმ ნივთიერებებზე, რომლებიც არ შეიცავს ინფექციურ ნივთიერებებს ან ნივთიერებებზე, რომლებიც სავარაუდოდ არ იწვევს დაავადებას ადამიანებსა თუ ცხოველებში, იმ შემთხვევების გარდა, როდესაც ისინი აკმაყოფილებს ნებისმიერ სხვა კლასზე მიკუთვნებასთან დაკავშირებულ კრიტერიუმებს. 2.2.62.1.5.2 ADR-ის დებულებები არ ვრცელდება იმ მიკროორგანიზმების შემცველ ნივთიერებებზე, რომლებიც არ ატარებს პათოგენურ ხასიათს ადამიანებისა თუ ცხოველების მიმართ, იმ შემთხვევების გარდა, როდესაც ისინი აკმაყოფილებს ნებისმიერ სხვა კლასზე მიკუთვნებასთან დაკავშირებულ კრიტერიუმებს. 2.2.62.1.5.3 ADR-ის დებულებები არ ვრცელდება იმ ფორმით წარმოდგენილ ნივთიერებებზე, რომ მათში ნებისმიერი წარმოდგენილი პათოგენური ორგანიზმი იყოს განეიტრალებული ან გაუაქტიურებელი ისე, რომ აღარ წარმოადგინოს საშიშროება ჯანმრთელობისთვის, იმ შემთხვევების გარდა, როდესაც ისინი აკმაყოფილებს ნებისმიერ სხვა კლასზე მიკუთვნებასთან დაკავშირებულ კრიტერიუმებს. შენიშვნა: სამედიცინო აღჭურვილობა, რომელიც ამოტუმბულია ყოველგვარი თავისუფალი სითხე, ითვლება, რომ აკმაყოფილებს წინამდებარე პუნქტით გათვალისწინებულ მოთხოვნებს და არ ექვემდებარება ADR-ით გათვალისწინებულ დებულებებს. 2.2.62.1.5.4 ADR-ის დებულებები არ ვრცელდება იმ ნივთიერებებზე, რომელშიც პათოგენური ორგანიზმების კონცენტრაცია წარმოდგენილია იმ დონეზე, რომელიც გვხდება ბუნებაში და რომლებიც, როგორც მიაჩნიათ, არ წარმოადგენს ინფიცირების მნიშვნელოვან საშიშროებას იმ შემთხვევების გარდა, როდესაც ისინი აკმაყოფილებს ნებისმიერ სხვა კლასზე მიკუთვნებასთან დაკავშირებულ კრიტერიუმებს. 2.2.62.1.5.5 ADR-ის დებულებები არ ვრცელდება გამომშრალი სისხლის ნაცხზე, რომელიც აღებულია სისხლის წვეთების დაწვეთებით მააბსორბირებელ მასალაზე. 2.2.61.1.5.6 ADR-ის დებულებები არ ვრცელდება განავალში ფარულ სისხლდენაზე სკრინინგტესტის ნიმუშებზე. 2.2.62.1.5.7 ADR-ის დებულებები არ ვრცელდება სისხლსა თუ სისხლის კომპონენტებზე, რომლებიც აღებულია გადასხმის მიზნით ან გადასხმისა თუ ტრანსპლანტაციისთვის გამოსაყენებელი სისხლის პროდუქტების მოსამზადებლად, ასევე ტრანსპლანტაციისას გამოსაყენებელი ნებისმიერი ქსოვილისა თუ ორგანოსთვის, ასევე აღნიშნული მიზნებისთვის აღებულ ნიმუშებზე. 2.2.62.1.5.8 ADR-ის დებულებები არ ვრცელდება ადამიანებისა თუ ცხოველების ნიმუშებზე, რომლებთან დაკავშირებითაც არსებობს პათოგენური ორგანიზმების არსებობის ძალიან მცირე ალბათობა იმ შემთხვევაში, თუ ნიმუშების გადატანა ხორციელდება 270 ტარაში, რაც უზრუნველყოფს ნებისმიერი გაჟონვის პრევენციას და რომელზეც მითითებულია წარწერა „ადამიანისგან აღებული გამოთავისუფლებული ნიმუში“ ან „ცხოველისგან აღებული გამოთავისუფლებული ნიმუში“, კონკრეტული შემთხვევიდან გამომდინარე. ითვლება, რომ ტარა აკმაყოფილებს ზემოაღნიშნულ მოთხოვნებს იმ შემთხვევაში, თუ პასუხობს შემდეგ კრიტერიუმებს: (ა) ტარა შედგება სამი კომპონენტისგან: (i) (ii) (iii) ჰერმეტული პირველადი ჭურჭლ(ებ)ისგან; ჰერმეტული მეორადი ტარისგან; და მოცულობასთან, მასასა და სავარაუდო გამოყენებასთან დაკავშირებული სათანადო სიმძლავრის გარე შეფუთვისგან, რომლის მინიმუმ ერთ ზედაპირს გააჩნია სულ მცირე 10 მმ X 100 მმ ზომები. (ბ) სითხეების გადაზიდვის შემთხვევაში პირველად ჭურჭელსა (ჭურჭლებსა) და მეორად ტარას შორის უნდა განთავსდეს შიგთავსის აბსორბირებისთვის საკმარისი ოდენობის მააბსორბირებელი მასალა ისე, რომ გადაზიდვის დროს, თხევადი ნივთიერების გამოსვლამ ან გამოჟონვამ არ მიაღწიოს გარე შეფუთვას და არ გააუარესოს სადები მასალის მთლიანობა; (გ) იმ შემთხვევაში, თუ ერთ მეორად ტარაში განთავსებულია რამდენიმე მტვრევადი ჭურჭელი, მათი შეფუთვა უნდა მოხდეს ინდივიდუალურად ან განცალკევებით, რათა უზრუნველყოფილი იქნეს მათი ერთმანეთთან შეხების პრევენცია. შენიშვნა 1: ამა თუ იმ ნივთიერების წინამდებარე პუნქტისგან გათავისუფლებისთვის საჭიროა სპეციალისტის დასკვნა. აღნიშნული დასკვნა უნდა გაკეთდეს ავადმყოფობის ისტორიის შესახებ ცნობილი მონაცემების, სიმპტომებისა და წყაროს, როგორც ადამიანის, ასევე ცხოველის ინდივიდუალური მდგომარეობის, ასევე ადგილობრივი ენდემური პირობების შესახებ არსებული ინფორმაციის მიხედვით. ნიმუშების მაგალითები, რომლებიც შესაძლებელია გადაზიდულ იქნეს წინამდებარე პუნქტის შესაბამისად, მოიცავს სისხლისა თუ შარდის ანალიზებს ქოლესტერინის დონეების, სისხლში გლუკოზის შემცველობის დონეების, ჰორმონების დონეებისა თუ პროსტატის სპეციფიკური ანტისხეულების მონიტორინგისთვის; ანალიზებს, რომლებიც საჭიროა იმ არაინფექციური დაავადებების მქონე ადამიანებისა თუ ცხოველების ორგანოების, როგორიცაა გულის, ღვიძლისა თუ თირკმლის ფუნქციების მონიტორინგისთვის ან სამკურნალო პრეპარატების მონიტორინგისთვის; ანალიზებს, რომლებიც ტარდება სადაზღვევო ან სამუშაოზე აყვანის მიზნებისთვის და გათვალისწინებულია პრეპარატების ან ალკოჰოლის განსაზღვრისთვის; ორსულობის ტესტს; ბიოფსიებს კიბოს გამოსავლენად და ტესტებს ანტისხეულების გამოსავლენად ადამიანსა თუ ცხოველებში ინფექციასთან დაკავშირებული ნებისმიერი საშიშროების არარსებობისას (მაგალითად, როდესაც საუბარია ვაქცინური იმუნიტეტის შეფასებაზე, ავტოიმუნური დაავადების დიაგნოსტიკასა და ა.შ.). შენიშვნა 2: საჰაერო გადაზიდვების შემთხვევაში, ნიმუშებისთვის განკუთვნილი ტარა, რომელიც გათავისუფლებულია წინამდებარე პუნქტის მოქმედებისგან, უნდა აკმაყოფილებდეს (ა)-დან (გ) პუნქტებში მოყვანილ პირობებს. 2.2.62.1.5.9 გარდა შემდეგი გამონაკლისებისა: 271 (ა) სამედიცინო ნარჩენები (გაეროს №3291); (ბ) სამედიცინო მოწყობილობები ან აღჭურვილობა, რომლებიც დაბინძურებულია A კატეგორიის ინფექციური ნივთიერებებით (გაეროს №2814 ან გაეროს №2900); და (გ) სამედიცინო მოწყობილობები ან აღჭურვილობა, რომლებიც დაბინძურებულია იმ სხვა სახიფათო ტვირთით, რომელიც აკმაყოფილებს სხვა კლასის განსაზღვრებას, სამედიცინო მოწყობილობები ან აღჭურვილობა, რომლებიც პოტენციურად დაბინძურებულია ინფექციური ნივთიერებებით და რომელთა გადაზიდვაც ხორციელდება დეზინფექციის, დასუფთავების, სტერილიზაციის, შეკეთების ან აღჭურვილობის მდგომარეობის შეფასების მიზნით, არ ექვემდებარება ADR-ის მოქმედებას, გარდა წინამდებარე პუნქტით გათვალისწინებული დებულებებისა, რა შემთხვევაშიც ისინი შეფუთულია იმ სახით კონსტრუირებულ და დამზადებულ ტარაში, რომელიც გადაზიდვის ნორმალურ პირობებში, არ გატყდება, გაიხვრიტება ან მოხდება მისი შიგთავსის გაჟონვა. ტარა ისე უნდა იყოს კონსტრუირებული, რომ აკმაყოფილებდეს 6.1.4 ან 6.6.4 პუნქტებით გათვალისწინებულ მოთხოვნებს. აღნიშნული ტარა უნდა პასუხობდეს 4.1.1.1 და 4.1.1.2 პუნქტებით შეფუთვასთან დაკავშირებულ ზოგად მოთხოვნებს და უნდა შეეძლოს სამედიცინო მოწყობილობებისა და აღჭურვილობის შეკავება 1,2 მეტრის სიმაღლიდან გადმოვარდნის შემთხვევაში. ტარაზე წარმოდგენილი უნდა იქნეს აღნიშვნა „გამოყენებული სამედიცინო მოწყობილობა“ ან „გამოყენებული სამედიცინო აღჭურვილობა“. სატრანსპორტო პაკეტების გამოყენებისას, აღნიშნული პაკეტები ასევე უნდა აღინიშნოს იგივენაირად გარდა იმ შემთხვევისა, როდესაც ნაწერი რჩება ხილული. 2.2.62.1.6-2.2.62.1.8 2.2.62.1.9 (რეზერვირებულია). ბიოლოგიური პროდუქტები ADR-ის მიზნებიდან გამომდინარე, ბიოლოგიური პროდუქტები იყოფა შემდეგ ჯგუფებად: (ა) ბიოლოგიური პროდუქტები, რომლებიც დამზადებული და შეფუთულია შესაბამისი ეროვნული ორგანოების მოთხოვნების შესაბამისად და რომელთა გადაზიდვაც ხორციელდება საბოლოო შეფუთვისა თუ დისტრიბუციის მიზნით, ასევე სამედიცინო სპეციალისტებისა თუ კერძო პირების მიერ პირადი სამედიცინო-სანიტარული მიზნებისთვის გამოსაყენებლად. აღნიშნულ ჯგუფში შემავალი ნივთიერებები არ ექვემდებარება ADR-ის დებულებებს; (ბ) ბიოლოგიური პროდუქტები, რომლებიც არ შედის (ა) პუნქტში და როგორც ცნობილია ან როგორც საფუძვლიანად ვარაუდობენ შეიცავს ინფექციურ ნივთიერებებს და აკმაყოფილებს ა კატეგორიასა თუ ბ კატეგორიაში ჩართვასთან დაკავშირებულ კრიტერიუმებს. აღნიშნული ჯგუფის ნივთიერებებს ენიჭებათ გაეროს №2814, 2900 ან 3373, კონკრეტული შემთხვევიდან გამომდინარე. 272 შენიშვნა: ზოგიერთმა ლიცენზირებულმა ბიოლოგიურმა პროდუქტმა შესაძლებელია წარმოადგინოს ბიოლოგიური საშიშროება მხოლოდ მსოფლიოს გარკვეულ რეგიონებში. მოცემულ შემთხვევაში, კომპეტენტურ ორგანოს შეუძლია მოითხოვოს აღნიშნული პროდუქტების შესაბამისობა ინფექციურ ნივთიერებებთან დაკავშირებულ ადგილობრივ მოთხოვნებთან ან შეიძლება განსაზღვრონ სხვა სახის შეზღუდვები. 2.2.62.1.10 გენეტიკურად მოდიფიცირებული მიკროორგანიზმები და ორგანიზმები გენეტიკურად მოდიფიცირებული მიკროორგანიზმები, რომლებიც არ აკმაყოფილებს ინფექციურ ნივთიერებასთან დაკავშირებულ განმარტებას, კლასიფიცირდება 2.2.9 პუნქტის შესაბამისად. 2.2.62.1.11 სამედიცინო ან კლინიკური ნარჩენები 2.2.62.1.11.1 ა კატეგორიის ინფექციური ნივთიერებების შემცველ სამედიცინო თუ კლინიკური ნარჩენებს უნდა მიეკუთვნოს გაეროს №2814 ან გაეროს №2900, კონკრეტული შემთხვევიდან გამომდინარე. ბ კატეგორიაში შემავალი ინფექციური ნივთიერებების შემცველ სამედიცინო ან კლინიკური ნარჩენებს ენიჭებათ გაეროს №3291. შენიშვნა: 18 01 03 ნომერზე (ადამიანებისა თუ ცხოველების მკურნალობის და/ან შესაბამისი კვლევის ნარჩენები - ადამიანებში მშობიარობის, დიაგნოსტიკის, მკურნალობისა და დაავადების პრევენციასთან დაკავშირებული ნარჩენები ნარჩენები, რომელთა შეგროვება და გაუვნებელყოფა ექვემდებარება სპეციალურ მოთხოვნებს ინფექციის პრევენციის მიზნით) ან 18 02 02 ნომერზე (ადამიანებისა თუ ცხოველების მკურნალობის და/ან შესაბამისი კვლევის ნარჩენები - ცხოველებში ჩატარებული კვლევასთან, დიაგნოსტიკასთან, მკურნალობასა და დაავადების პრევენციასთან დაკავშირებული ნარჩენები - ნარჩენები, რომელთა შეგროვება და გაუვნებელყოფა ექვემდებარება სპეციალურ მოთხოვნებს ინფექციის პრევენციის მიზნით) განკუთვნილი სამედიცინო ან კლინიკური ნარჩენები, 2000/532/EC5 კომისიის გადაწყვეტილებაზე, შეტანილ ცვლილებებთან ერთად, დართული ნარჩენების ჩამონათვალის შესაბამისად, კლასიფიცირდება აღნიშნულ პუნქტში მოყვანილი დებულებების შესაბამისად, პაციენტის თუ ცხოველის სამედიცინო ან ვეტერინარული დიაგნოსტიკის საფუძველზე. 2.2.62.1.11.2 სამედიცინო ან კლინიკური ნარჩენები, რომელთან დაკავშირებითაც არსებობს საფუძვლიანი ვარაუდი, რომ ისინი შეიცავს ინფექციურ ნივთიერებებს, ენიჭებათ გაეროს №3291. ნომერის მიკუთვნების მიზნით, მხედველობაში უნდა იქნეს მიღებული საერთაშორისო, რეგიონალური ან ეროვნული ნარჩენების კატალოგები. შენიშვნა 1: გადაზიდვის შესაბამისი დასახელება გაეროს №3291 დაკავშირებით არის „კლინიკური ნარჩენები, დაუზუსტებელი, N.O.S.“ ან „(ბიო) სამედიცინო ნარჩენები, N.O.S.“ ან „დარეგულირებული სამედიცინო ნარჩენები, N.O.S.“. კომისიის 2000 წლის 3 მაისის 2000/532/EC გადაწყვეტილება, რომელიც ცვლის 94/3/EC გადაწყვეტილებას, რომელიც განსაზღვრავს ნარჩენების ჩამონათვალს ნარჩენების შესახებ საბჭოს 75/442/EEC დირექტივის 1(ა) მუხლის შესაბამისად (რომელიც შეცვლილ იქნა ევროპარლამენტისა და საბჭოს 2006/12/EC დირექტივით (ევროკავშირის ოფიციალური ჟურნალი №L114, 2006 წლის 27 აპრილი, გვ. 9) და საბჭოს 94/904/EC დირექტივა, რომელიც განსაზღვრავს სახიფათო ნარჩენების ჩამონათვალს სახიფათო ნარჩენების შესახებ საბჭოს 91/689/EEC დირექტივის 1(4) მუხლის თანახმად (ევროკავშირის ოფიციალური ჟურნალი №L226, 2000 წლის 6 სექტემბერი, გვ. 3). 5 273 შენიშვნა 2: ზემოთ მოყვანილი კლასიფიკაციის კრიტერიუმების მიუხედავად, 18 01 04 ნომერზე (ადამიანებისა თუ ცხოველების მკურნალობის და/ან შესაბამისი კვლევის ნარჩენები - ადამიანებში მშობიარობის, დიაგნოსტიკის, მკურნალობისა და დაავადების პრევენციასთან დაკავშირებული ნარჩენები - ნარჩენები, რომელთა შეგროვება და გაუვნებელყოფა არ ექვემდებარება სპეციალურ მოთხოვნებს ინფექციის პრევენციის მიზნით) ან 18 02 03 ნომერზე (ადამიანებისა თუ ცხოველების მკურნალობის და/ან შესაბამისი კვლევის ნარჩენები - ცხოველებში ჩატარებული კვლევასთან, დიაგნოსტიკასთან, მკურნალობასა და დაავადების პრევენციასთან დაკავშირებული ნარჩენები - ნარჩენები, რომელთა შეგროვება და გაუვნებელყოფა არ ექვემდებარება სპეციალურ მოთხოვნებს ინფექციის პრევენციის მიზნით) განკუთვნილი სამედიცინო ან კლინიკური ნარჩენები, 2000/532/EC5 კომისიის გადაწყვეტილებაზე, შეტანილ ცვლილებებთან ერთად, დართული ნარჩენების ჩამონათვალის შესაბამისად, არ ექვემდებარება ADR-ის დებულებებს. 2.2.62.1.11.3 ADR-ის დებულებები არ ვრცელდება დეაქტივირებულ სამედიცინო ან კლინიკურ ნარჩენებზე, რომლებიც ადრე შეიცავდნენ ინფექციურ ნივთიერებებს, იმ შემთხვევების გარდა, როდესაც ისინი აკმაყოფილებენ ნებისმიერ სხვა კლასზე მიკუთვნებასთან დაკავშირებულ კრიტერიუმებს. 2.2.62.1.11.4 სამედიცინო ან კლინიკური ნარჩენები, რომელთაც მინიჭებული აქვთ გაეროს №3291, განეკუთვნება II შეფუთვის ჯგუფს. 2.2.62.1.12 ინფიცირებული ცხოველები 2.2.62.1.12.1 გარდა იმ შემთხვევებისა, როდესაც ინფექციური ნივთიერების გადაზიდვა არ შეიძლება რაიმე სხვა საშუალებით, დაუშვებელია ცოცხალი ცხოველების გამოყენება აღნიშნული ნივთიერების გადასაზიდად. ცოცხალი ცხოველი, რომელიც განზრახ იქნა დაინფიცირებული და რომელთან დაკავშირებითაც ცნობილია ან ნავარაუდევია, რომ შეიცავს ინფექციურ ნივთიერებას, შესაძლებელია გადაყვანილი იქნეს მხოლოდ კომპეტენტური ორგანოს მიერ დამტკიცებული პირობებით.6 2.2.62.1.12.2 ცხოველურ წარმოშობის მასალებს, რომლებიც დასნებოვნებულ იქნა ა კატეგორიის პათოგენური ორგანიზმებით ან იმ პათოგენური ორგანიზმებით, რომელიც მიკუთვნებული იქნებოდა ა კატეგორიას კულტურის სახით, ენიჭებათ გაეროს №2814 ან 2900, კონკრეტული შემთხვევიდან გამომდინარე. ცხოველურ წარმოშობის მასალებს, რომლებიც დასნებოვნებულ იქნა ბ კატეგორიის პათოგენური ორგანიზმებით, იმ პათოგენური ორგანიზმების გარდა, რომელიც მიკუთვნებული იქნებოდა ა კატეგორიას კულტურის სახით, ენიჭებათ გაეროს 3373. 2.2.62.2 ნივთიერებების, რომლებიც არ დაიშვება გადაზიდვებზე ცოცხალი ხერხემლიანი ან უხერხემლო ცხოველების გამოყენება არ შეიძლება ინფექციური საშუალების გადაზიდვის მიზნით გარდა იმ შემთხვევისა, როდესაც შეუძლებელია ნივთიერების გადაზიდვა სხვა საშუალებით ან როდესაც აღნიშნული გადაზიდვა არ იქნა დამტკიცებული კომპეტენტური ორგანოს მიერ (იხილეთ 2.2.62.1.12.1 ქვეპუნქტი). ცოცხალი ცხოველების გადაყვანის მარეგულირებელი წესები წარმოდგენილია, მაგალითად, 1991 წლის 19 ნოემბრის 91/628/EEC დირექტივაში ტრასნპორტირების დროს ცხოველთა დაცვის შესახებ (ევროკავშირის ოფიციალური ჟურნალი №L340, 11.12.1991, გვ. 17) და ევროსაბჭოს (მინისტრთა კომიტეტის) რეკომენდაციებში ცხოველების გარკვეული სახეობების გადაყვანასთან დაკავშირებით. 6 274 2.2.62.3 ერთობლივი პოზიციების ჩამონათვალი ზემოქმედება ადამიანებზე I1 ზემოქმედება მხოლოდ ცხოველებზე I2 კლინიკური ნარჩენები ბიოლოგიური ნივთიერებები 2814 ადამიანებისთვის სახიფათო ინფექციური ნივთიერება 2900 მხოლოდ ცხოველებისთვის საზიანო სახიფათო ნივთიერება I3 3291 3291 3291 კლინიკური ნარჩენები, დაუზუსტებელი, N.O.S. (ბიო)სამედიცინო ნარჩენები, N.O.S. ან დარეგულირებული სამედიცინო ნარჩენები, N.O.S. I4 3373 ბიოლოგიური ნივთიერება, ბ კატეგორია 275 2.2.7 კლასი 7 რადიოაქტიური ნივთიერებები 2.2.7.1 განმარტებები 2.2.7.1.1 რადიოაქტიური ნივთიერება ნიშნავს რადიონუკლიდების შემცველ ნებისმიერ ნივთიერებას, რომელშიც აქტივობის კონცენტრაცია, ასევე ტვირთის სრული აქტივობა აღემატება 2.2.7.2.2.1-2.2.7.2.2.6 ქვეპუნქტებში გათვალისწინებულ მნიშვნელობებს. 2.2.7.1.2 რადიოაქტიური დაბინძურება რადიოაქტიური დაბინძურება ნიშნავს რადიოაქტიური ნივთიერების არსებობას ზედაპირზე 0.4 ბკ/სმ2-ზე მეტი რაოდენობებით ბეტა- და გამა-გამომსხივარებსა და დაბალი ტოქსიკურობის მქონე ალფა-გამომსხივარებისთვის ან 0.04 ბკ/სმ2 - ყველა სხვა ალფა-გამომსხივარისთვის. არაფიქსირებული რადიოაქტიური დაბინძურება დაბინძურებას, რომელიც შესაძლებელია გადაზიდვის ნორმალურ პირობებში. ფიქსირებული რადიოაქტიური ნიშნავს რადიოაქტიურ მოშორებულ იქნეს ზედაპირიდან დაბინძურება ნიშნავს არაფიქსირებულ რადიოაქტიური დაბინძურების საწინააღმდეგო ცნებას. 2.2.7.1.3 კონკრეტული ტერმინების განმარტება A1 და A2 A1 ნიშნავს სპეციალური ფორმის რადიოაქტიური მასალის აქტივობის მნიშვნელობას, რომელიც მოყვანილია 2.2.7.2.2.1 ქვეპუნქტში წარმოდგენილ ცხრილში ან განისაზღვრება 2.2.7.2.2.2 ქვეპუნქტით გათვალისწინებული დებულებების შესაბამისად და გამოიყენება აქტივობის ფარგლების განსაზღვრის მიზნით, ADR-ის მოთხოვნებთან დაკავშირებით. A2 ნიშნავს რადიოაქტიური მასალის აქტივობის მნიშვნელობას, გარდა იმ სპეციალური ფორმის რადიოაქტიური მასალისა, რომელიც მოყვანილია 2.2.7.2.2.1 ქვეპუნქტში წარმოდგენილ ცხრილში ან განისაზღვრება 2.2.7.2.2.2 ქვეპუნქტით გათვალისწინებული დებულებების შესაბამისად და გამოიყენება აქტივობის ფარგლების განსაზღვრის მიზნით, ADR-ის მოთხოვნებთან დაკავშირებით. გაყოფადი ნუკლიდები - ეს არის ურანი-233, ურანი-235, პლუტონიუმი-239 და პლუტონიუმი-241. გაყოფადი მასალა ნიშნავს ნებისმიერი გაყოფადი ნუკლიდების შემცველ მასალას. გაყოფადი მასალის განმარტებაში არ არის გათვალისწინებული (ა) გამოუსხივებელი ბუნებრივი ურანი ან გაღარიბებული ურანი; (ბ) მხოლოდ თერმულ რეაქტორებში გაღარიბებული ურანი; (გ) მასალა, რომლის გაყოფადი ნუკლიდების საერთო შემცველობა ნაკლებია 0.25 გრამზე; გამოსხივებული ბუნებრივი ურანი ან (დ) (ა), (ბ) და/ან (გ) ნებისმიერი კომბინაცია. აღნიშნული გამონაკლისები ძალაშია მხოლოდ იმ შემთხვევაში, თუ შეფუთვაში ან ტვირთში - შეუფუთავი სახით გადაზიდვისას - არ იქნება წარმოდგენილი რაიმე სხვა მასალა გაყოფადი ნუუკლიდებით. 276 დაბალდისპერსიული რადიოაქტიური მასალა ნიშნავს მყარ რადიოაქტიურ მასალას ან მყარ რადიოაქტიურ მასალას ჰერმეტულ კაფსულაში, რომელსაც აღენიშნება შეზღუდული დისპერსიულობა და არ არის წარმოდგენილი ფხვნილისებრი ფორმით. დაბალი სპეციფიური აქტივობის მქონე მასალა (LSA) ნიშნავს რადიოაქტიურ მასალას, რომელსაც მისი ბუნებიდან გამომდინარე, გააჩნია შეზღუდული კუთრი აქტივობა, ან რადიოაქტიურ მასალას, რომელთან დაკავშირებითაც გამოიყენება დადგენილი საშუალო კუთრი აქტივობის საზღვრები. დაბალის კუთრი აქტივობის მქონე მასალის გარე დამცავი მასალები არ უნდა იქნეს მხედველობაში მიღებული დადგენილი საშუალო კუთრი აქტივობის განსაზღვრისას. დაბალი ტოქსიკურობის მქონე ალფა-გამომსხივარები ნიშნავს: ბუნებრივ ურანს; გაღარიბებულ ურანს, ბუნებრივ თორიუმს, ურანი-235 ან ურანი-238; თიორიუმ-232; თიორიუმ-228 და თიორიუმ-230, როდესაც წარმოდგენილია მადნის ან ქიმიური კონცენტრანტების შემადგენლობაში; ან ალფა-გამომსხივარები 10 დღეზე ნაკლები ნახევრად გამოყოფის პერიოდით. სპეციალური ფორმის რადიოაქტიური მასალა ნიშნავს: (ა) არადისპერსიულ მყარ რადიოაქტიურ ნივთიერებას; ან (ბ) რადიოაქტიური მასალის შემცველ დახურულ კაფსულას. რადიონუკლიდის სპეციალური აქტივობა ნიშნავს აქტივობას აღნიშნული ნუკლეიდის ყოველ ერთეულ მასაზე, მასალის კუთრი აქტივობა ნიშნავს აქტივობას მასალის ყოველ ერთეულ მასაზე, რომელშიც რადიონუკლიდები არსებითად ერთგვაროვნად არის განაწილებული. ობიექტი რადიოაქტიურად დაბინძურებული ზედაპირით (SCO) ნიშნავს მყარ ობიექტს, რომელიც თავად არ ხასიათდება რადიოაქტიურობით, თუმცა რომლის ზედაპირებზე განაწილებულია რადიოაქტიური მასალა. გამოუსხივებელი თორიუმი ნიშნავს ყოველ გრამ თორიუმ-232-ზე არაუმეტეს 10-7 გ ურანი-233 შემცველ თორიუმს. გამოუსხივებელი ურანი ნიშნავს ყოველ გრამ ურანიუმ-235-ზე არაუმეტეს 2X103 ბკ პლუტონიუმის, ყოველ გრამ ურანიუმ-235-ზე არაუმეტეს 9X106 ბკ გაყოფის პროდუქტებისა და ყოველ გრამ ურანიუმ-235-ზე არაუმეტეს 5X10-3 გ ურანი-236 შემცველ ურანს. ურანიუმი - ბუნებრივი, გაღარიბებული, გამდიდრებული ნიშნავს შემდეგს: ბუნებრივი ურანი ნიშნავს ურანის იზოტოპების ბუნებრივი ნარევის (დაახლოებით 99.28% ურანიუმ-238 და 0.72 ურანიუმ-235 მასის მიხედვით) შემცველ ურანს (რომელიც შესაძლებელია იყოს ქიმიურად გამოყოფილი). გაღარიბებული ურანი ნიშნავს ბუნებრივ ურანთან შედარებით მასის მიხედვით ურანიუმ-235 უფრო ნაკლები პროცენტულობის შემცველ ურანს. გამდიდრებული ურანი ნიშნავს მასის მიხედვით 0.72%-ზე მეტი ურანი-235 პროცენტულობის შემცველ ურანს. 277 ყველა შემთხვევაში, წარმოდგენილია მასის მიხედვით ურანი-234 ძალიან მცირე პროცენტულობა. 2.2.7.2 კლასიფიკაცია 2.2.7.2.1 ზოგადი დებულებები 2.2.7.2.1.1 რადიოაქტიურ ნივთიერებებს უნდა მიენიჭოთ 2.2.7.2.1.1 ქვეპუნქტის ცხრილში მითითებული ერთ-ერთი გაეროს ნომერი, 2.2.7.2.2-2.2.7.2.5 ქვეპუნქტების შესაბამისად, 2.2.7.2.3 ქვეპუნქტით განსაზღვრული მასალის მახასიათებლების გათვალისწინებით. 278 ცხრილი 2.2.7.2.1.1 გაეროს ნომრების მიკუთვნება გამოთავისუფლებული შეფუთვები (1.7.1.5) გაეროს №2908 რადიოაქტიური მასალა, გამოთავისუფლებული შეფუთვა - ცარიელი შეფუთვა გაეროს №2909 რადიოაქტიური მასალა, გამოთავისუფლებული შეფუთვა - ბუნებრივი ურანისგან ან გაღარიბებული ურანისგან ან ბუნებრივი თორიუმისგან დამზადებული ნაკეთობები გაეროს №2910 რადიოაქტიური მასალა, გამოთავისუფლებული შეფუთვა - მასალის შეზღუდული ოდენობა გაეროს №2911 რადიოაქტიური მასალა, გამოთავისუფლებული შეფუთვა - ხელსაწყოები ან ნაკეთობები გაეროს №3507 ურანის ჰექსაფტორიდი, რადიოაქტიური მასალა, გამოთავისუფლებული შეფუთვა, 0.1 კგ-ზე ნაკლები შეფუთვაში, გაყოფადი ან გაყოფადი-გათავისუფლებულიბ,გ დაბალი კუთრი აქტივობის მქონე რადიოაქტიური მასალა (2.2.7.2.3.1) გაეროს №2912 რადიოაქტიური მასალა, დაბალი კუთრი აქტივობის (LSA-I), გაუყოფადი ან გაყოფადი - გამოთავისუფლებულიბ გაეროს №3321 რადიოაქტიური მასალა, დაბალი კუთრი აქტივობის (LSA-II), გაუყოფადი ან გაყოფადი - გამოთავისუფლებულიბ გაეროს №3322 რადიოაქტიური მასალა, დაბალი კუთრი აქტივობის (LSA-III), გაუყოფადი ან გაყოფადი - გამოთავისუფლებულიბ გაეროს №3324 რადიოაქტიური მასალა, დაბალი კუთრი აქტივობის (LSA-II), გაყოფადი გაეროს №3325 რადიოაქტიური მასალა, დაბალი კუთრი აქტივობის (LSA-III), გაყოფადი რადიოაქტიურად დაბინძურებული ზედაპირების მქონე ობიექტები (2.2.7.2.3.2) გაეროს №2913 რადიოაქტიური მასალა, რადიოაქტიურად დაბინძურებული ზედაპირების მქონე ობიექტები (SCO-I ან SCO-II), გაუყოფადი ან გაყოფადი - გამოთავისუფლებულიბ გაეროს №3326 რადიოაქტიური მასალა, რადიოაქტიურად დაბინძურებული ზედაპირების მქონე ობიექტები (SCO-I ან SCO-II), გაყოფადი A ტიპის შეფუთვები (2.2.7.2.4.4) გაეროს №2915 რადიოაქტიური მასალა, A ტიპის შეფუთვა, არა-საგანგებო ფორმის, გაუყოფადი ან გაყოფადი გამოთავისუფლებულიბ გაეროს №3327 რადიოაქტიური მასალა, A ტიპის შეფუთვა, გაყოფადი, არა-საგანგებო ფორმის გაეროს №3332 რადიოაქტიური მასალა, A ტიპის შეფუთვა, საგანგებო ფორმის, გაუყოფადი ან გაყოფადი გამოთავისუფლებულიბ გაეროს №3333 რადიოაქტიური მასალა, A ტიპის შეფუთვა, საგანგებო ფორმის, გაყოფადი B(U) ტიპის შეფუთვები (2.2.7.2.4.6) გაეროს №2916 რადიოაქტიური მასალა, B(U) ტიპის შეფუთვა, გაუყოფადი ან გაყოფადი - გამოთავისუფლებულიბ რადიოაქტიური მასალა, B(U) ტიპის შეფუთვა, გაყოფადი გაეროს №3328 B(M) ტიპის შეფუთვები (2.2.7.2.4.6) გაეროს №2917 რადიოაქტიური მასალა, B(M) ტიპის შეფუთვა, გაუყოფადი ან გაყოფადი - გამოთავისუფლებულიბ გაეროს №3329 რადიოაქტიური მასალა, B(M) ტიპის შეფუთვა, გაყოფადი C ტიპის შეფუთვები (2.2.7.2.4.6) გაეროს №3323 რადიოაქტიური მასალა, C ტიპის შეფუთვა, გაუყოფადი ან გაყოფადი - გამოთავისუფლებულიბ გაეროს №3330 რადიოაქტიური მასალა, C ტიპის შეფუთვა, გაყოფადი სპეციალური პირობები (2.2.7.2.5) გაეროს №2919 რადიოაქტიური მასალა, გადატანილი სპეციალური პირობების დაცვით, გაუყოფადი ან გაყოფადი გამოთავისუფლებულიბ გაეროს №3331 რადიოაქტიური მასალა, გადატანილი სპეციალური პირობების დაცვით, გაყოფადი სპეციალური პირობები (2.2.7.2.5) გაეროს №2977 რადიოაქტიური მასალა, ურანის ჰექსაფტორიდი, გაყოფადიბ გაეროს №2978 რადიოაქტიური მასალა, ურანის ჰექსაფტორიდი, გაუყოფადი ან გაყოფადი - გამოთავისუფლებული ურანის ჰექსაფტორიდი, რადიოაქტიური მასალა, გამოთავისუფლებული შეფუთვა, 0.1 კგ-ზე ნაკლები შეფუთვაში, გაეროს №3507 გაყოფადი ან გაყოფადი-გათავისუფლებულიბ,გ ა ბ გ შესაბამისი გადაზიდვის დასახელება წარმოდგენილია სვეტში „შესაბამისი გადაზიდვის დასახელება და აღწერილობა“ და შემოიფარგლება მთავრული ასოებით წარმოდგენილი ნაწილით. გაეროს ნომრების 2909, 2911, 2913 და 3326 შემთხვევაში, რომლებთან დაკავშირებითაც მითითებულია შესაბამისი გადაზიდვის დასახელებები და გამოყოფილი კავშირით „თუ“, გამოიყენება მხოლოდ შესაბამისი გადაზიდვის დასახელება. ტერმინი „გაყოფადი-გამოთავისუფლებული“ ვრცელდება მხოლოდ 2.2.7.2.3.5 ქვეპუნქტის თანახმად გამოთავისუფლებულ მასალაზე; გაეროს №3507 დაკავშირებით, იხილეთ 3.3 თავის 369-ე სპეციალური დებულება. 279 2.2.7.2.2 რადიონუკლიდებისთვის ძირითადი მნიშვნელობების განსაზღვრა 2.2.7.2.2.1 2.2.7.2.2.1 ცხრილში წარმოდგენილია შემდეგი ძირითადი მნიშვნელობები ცალკეულ რადიონუკლიდებთან დაკავშირებით: (ა) A1 და A2 თბკ-ში; (ბ) აქტივობის კონცენტრაცია გამონაკლისები, ბკ/გ-ში; და (გ) აქტივობის საზღვრები გამონაკლისები, ბკ-ში. იმ იმ მასალისთვის, რომელზეც ვრცელდება ტვირთისთვის რომელზეც ვრცელდება ცხრილი 2.2.7.2.2.1: ცალკეული რადიონუკლიდების ძირითადი მნიშვნელობები რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) Ac-225 (ა) 8x10-1 6x10-3 1x101 1x104 Ac-227 (ა) 9x10-1 9x10-5 1x101 1x103 Ac-228 6x10-1 5x10-1 1x101 1x106 Ag-105 2x100 2x100 1x102 1x106 Ag-108m (ა) 7x10-1 7x10--1 1x101 (ბ) 1x106 (ბ) Ag-110m (ა) 4x10-1 4x10--1 1x101 1x106 Ag-111 2x100 6x10-1 1x103 1x106 1x10-1 1x10--1 1x101 1x105 Am-241 1x101 1x10--3 1x100 1x104 Am-242m (ა) 1x101 1x10--3 1x100 (ბ) 1x104 (ბ) Am-243 (ა) 5x100 1x10--3 1x100 (ბ) 1x103 (ბ) Ar-37 4x101 4x101 1x106 1x108 Ar-39 4x101 2x101 1x107 1x104 Ar-41 3x10-1 3x10-1 1x102 1x109 As-72 3x10-1 3x10-1 1x101 1x105 As-73 4x101 4x101 1x103 1x107 As-74 1x100 9x10-1 1x101 1x106 აქტინიუმი (89) ვერცხლი (47) ალუმინი (13) Al-26 ამერიციუმი (95) არგონი (18) დარიშხანი (33) 280 რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) As-76 3x10 3x10 -1 1x102 1x105 As-77 2x101 7x10-1 1x103 1x106 2x101 5x10-1 1x103 1x107 Au-193 7x100 2x100 1x102 1x107 Au-194 1x100 1x100 1x101 1x106 Au-195 1x101 6x100 1x102 1x107 Au-198 1x100 6x10-1 1x102 1x106 Au-199 1x101 6x10-1 1x102 1x106 Ba-131 (ა) 2x100 2x100 1x102 1x106 Ba-133 3x100 3x100 1x102 1x106 Ba-131m 2x101 6x10-1 1x102 1x106 Ba-140 (ა) 5x10-1 3x10-1 1x101 (ბ) 1x105 (ბ) Be-7 2x101 2x101 1x103 1x107 Be-10 4x101 6x10-1 1x104 1x106 Bi-205 7x10-1 7x10-1 1x101 1x106 Bi-206 3x10-1 3x10-1 1x101 1x105 Bi-207 7x10-1 7x10-1 1x101 1x106 Bi-210 1x100 6x10-1 1x103 1x106 Bi-210m (ა) 6x10-1 2x10-2 1x101 1x105 Bi-212 (ა) 7x10-1 6x10-1 1x101 (ბ) 1x105 (ბ) Bk-247 8x100 8x10-4 1x100 1x104 Bk-249 (ა) 4x101 3x10-1 1x103 1x106 Br-76 4x10-1 4x10-1 1x101 1x105 Br-77 3x100 3x100 1x102 1x106 -1 ასტატინი (85) At-211 (ა) ოქრო (79) ბარიუმი (56) ბერილიუმი (4) ბისმუთი (83) ბერკელიუმი (97) ბრომი (35) 281 რადიონუკლიდი (ატომური ნომერი) Br-82 A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) 4x10 4x10 -1 1x101 1x106 -1 ნახშირბადი (6) C-11 1x100 6x10-1 1x101 1x106 C-14 4x101 3x100 1x104 1x107 Ca-41 შეუზღუდავი შეუზღუდავი 1x105 1x107 Ca-45 4x101 1x100 1x104 1x107 Ca-47 (ა) 3x100 3x10-1 1x101 1x106 Cd-109 3x101 2x100 1x104 1x106 Cd-113m 4x101 5x10-1 1x103 1x106 Cd-115 (ა) 3x100 4x10-1 1x102 1x106 Cd-115m 5x10-1 5x10-1 1x103 1x106 Ce-139 7x100 2x100 1x102 1x106 Ce-141 2x101 6x10-1 1x102 1x107 Ce-143 9x10-1 6x10-1 1x102 1x106 Ce-144 (ა) 2x10-1 2x10-1 1x102 (ბ) 1x105 (ბ) Cf-248 4x101 6x10-3 1x101 1x104 Cf-249 3x100 8x10-4 1x100 1x103 Cf-250 2x101 2x10-3 1x101 1x104 Cf-251 7x100 7x10-4 1x100 1x103 Cf-252 1x10-1 3x10-3 1x101 1x104 Cf-253 (ა) 4x101 4x10-2 1x102 1x105 Cf-254 1x10-3 1x10-3 1x100 1x103 Cl-36 1x101 6x10-1 1x104 1x106 Cl-38 2x10-1 2x10-1 1x101 1x105 კალციუმი (20) კადმიუმი (48) ცერიუმი (58) კალიფორნიუმი (98) ქლორინი 282 რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) Cm-240 4x101 2x10-2 1x102 1x105 Cm-241 2x100 1x100 1x102 1x106 Cm-242 4x101 1x10-2 1x102 1x105 Cm-243 9x100 1x10-3 1x100 1x104 Cm-244 2x101 2x10-3 1x101 1x104 Cm-245 9x100 9x10-4 1x100 1x103 Cm-246 9x100 9x10-4 1x100 1x103 Cm-247 (ა) 3x100 1x10-3 1x100 1x104 Cm-248 2x10-2 3x10-4 1x100 1x103 Co-55 5x10-1 5x10-1 1x101 1x106 Co-56 3x10-1 3x10-1 1x101 1x105 Co-57 1x101 1x101 1x102 1x106 Co-58 1x100 1x100 1x101 1x106 Co-58m 4x101 4x101 1x104 1x107 Co-60 4x10-1 4x10-1 1x101 1x105 3x101 3x101 1x103 1x107 Cs-129 4x100 4x100 1x102 1x105 Cs-131 3x101 3x101 1x103 1x106 Cs-132 1x100 1x100 1x101 1x105 Cs-134 7x10-1 7x10-1 1x101 1x104 Cs-134m 4x101 6x10-1 1x103 1x105 Cs-135 4x101 1x100 1x104 1x107 Cs-136 5x10-1 5x10-1 1x101 1x105 Cs-137 (ა) 2x100 6x10-1 1x101 (ბ) 1x104 (ბ) კიურიუმი (96) კობალტი (27) ქრომი (24) Cr-51 ცეზიუმი (55) 283 რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) Cu-62 6x100 1x100 1x102 1x106 Cu-67 1x101 7x10-1 1x102 1x106 Dy-159 2x101 2x101 1x103 1x107 Dy-165 9x10-1 6x10-1 1x103 1x106 Dy-166 (ა) 9x10-1 3x10-1 1x103 1x106 Er-169 4x101 1x100 1x104 1x107 Er-171 8x10-1 5x10-1 1x102 1x106 Eu-147 2x100 2x100 1x102 1x106 Eu-148 5x10-1 5x10-1 1x101 1x106 Eu-149 2x101 2x101 1x102 1x107 Eu-150 (ხანმოკლე 2x100 7x10-1 1x103 1x106 7x10-1 7x10-1 1x101 1x106 Eu-152 1x100 1x100 1x101 1x106 Eu-152m 8x10-1 8x10-1 1x102 1x106 Eu-154 9x10-1 6x10-1 1x101 1x106 Eu-155 2x101 3x100 1x102 1x107 Eu-156 7x10-1 7x10-1 1x101 1x106 1x100 6x10-1 1x101 1x106 Fe-52 (ა) 3x10-1 3x10-1 1x101 1x106 Fe-55 4x101 4x101 1x104 1x106 Fe-59 9x10-1 9x10-1 1x101 1x106 Fe-60 (ა) 4x101 2x10-1 1x102 1x105 Ga-67 7x100 3x100 1x102 1x106 Ga-68 5x10-1 5x10-1 1x101 1x105 სპილენძი (29) დისპროზიუმი (66) ერბიუმი (68) ევროპიუმი (63) სიცოცხლის მქონე) Eu-150 (ხანგრძლივი სიცოცხლის მქონე) ფტორი (9) F-18 რკინა (26) გალიუმი (31) 284 რადიონუკლიდი (ატომური ნომერი) Ga-72 A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) 4x10 4x10 -1 1x101 1x105 -1 გადოლინიუმი (64) Gd-146 (ა) 5x10-1 5x10-1 1x101 1x106 Gd-148 2x101 2x10-3 1x101 1x104 Gd-153 1x101 9x100 1x102 1x107 Gd-159 3x100 6x10-1 1x103 1x106 Ge-68 (ა) 5x10-1 5x10-1 1x101 1x105 Ge-71 4x101 4x101 1x104 1x108 Ge-77 3x10-1 3x10-1 1x101 1x105 Hf-172 (ა) 6x10-1 6x10-1 1x101 1x106 Hf-175 3x100 3x100 1x102 1x106 Hf-181 2x100 5x10-1 1x101 1x106 Hf-182 შეუზღუდავი შეუზღუდავი 1x102 1x106 Hg-194 (ა) 1x100 1x100 1x101 1x106 Hg-195m (ა) 3x100 7x10-1 1x102 1x106 Hg-197 2x101 1x101 1x102 1x107 Hg-197m 1x101 4x10-1 1x102 1x106 Hg-203 5x100 1x100 1x102 1x105 Ho-166 4x10-1 4x10-1 1x103 1x105 Ho-166m 6x10-1 5x10-1 1x101 1x106 I-123 6x100 3x100 1x102 1x107 I-124 1x100 1x100 1x101 1x106 I-125 2x101 3x100 1x103 1x106 I-126 2x100 1x100 1x102 1x106 I-129 შეუზღუდავი შეუზღუდავი 1x102 1x105 I-131 3x100 7x10-1 1x102 1x106 გერმანიუმი (32) ჰაფნიუმი (72) ვერცხლისწყალი (80) ჰოლმიუმი (67) იოდი (53) 285 რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) I-132 4x10 4x10 -1 1x101 1x105 I-133 7x10-1 6x10-1 1x101 1x106 I-134 3x10-1 3x10-1 1x101 1x105 I-135 (ა) 6x10-1 6x10-1 1x101 1x106 In-111 3x100 3x100 1x102 1x106 In-113m 4x100 2x100 1x102 1x106 In-114m (ა) 1x101 5x10-1 1x102 1x106 In-115m 7x100 1x100 1x102 1x106 Ir-189 (ა) 1x101 1x101 1x102 1x107 Ir-190 7x10-1 7x10-1 1x101 1x106 Ir-192 1x100 (გ) 6x10-1 1x101 1x104 Ir-194 3x10-1 3x10-1 1x102 1x105 K-40 9x10-1 9x10-1 1x102 1x106 K-42 2x10-1 2x10-1 1x102 1x106 K-43 7x10-1 6x10-1 1x101 1x106 Kr-79 4x100 2x100 1x103 1x105 Kr-81 4x101 4x101 1x104 1x107 Kr-85 1x101 1x101 1x105 1x104 Kr-85m 8x100 3x100 1x103 1x1010 Kr-87 2x10-1 2x10-1 1x102 1x109 La-137 3x101 6x100 1x103 1x107 La-140 4x10-1 4x10-1 1x101 1x105 Lu-172 6x10-1 6x10-1 1x101 1x106 Lu-173 8x100 8x100 1x102 1x107 Lu-174 9x100 9x100 1x102 1x107 -1 ინდიუმი (49) ირიდიუმი (77) კალიუმი (19) კრიპტონი (36) ლანთანი (57) ლუტეციუმი (71) 286 რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) Lu-174m 2x10 1 1x10 1 1x102 1x107 Lu-177 3x101 7x10-1 1x103 1x107 3x10-1 3x10-1 1x101 1x105 Mn-52 3x10-1 3x10-1 1x101 1x105 Mn-53 შეუზღუდავი შეუზღუდავი 1x104 1x109 Mn-54 1x100 1x100 1x101 1x106 Mn-56 3x10-1 3x10-1 1x101 1x105 Mo-93 4x101 2x101 1x103 1x108 Mo-99 (ა) 1x100 6x10-1 1x102 1x106 9x10-1 6x10-1 1x102 1x109 Na-22 5x10-1 5x10-1 1x101 1x106 Na-24 2x10-1 2x10-1 1x101 1x105 Nb-93m 4x101 3x101 1x104 1x107 Nb-94 7x10-1 7x10-1 1x101 1x106 Nb-95 1x100 1x100 1x101 1x106 Nb-97 9x10-1 6x10-1 1x101 1x106 Nd-147 6x100 6x10-1 1x102 1x106 Nd-149 6x10-1 5x10-1 1x102 1x106 Ni-59 შეუზღუდავი შეუზღუდავი 1x104 1x108 Ni-63 4x101 3x101 1x105 1x108 Ni-65 4x10-1 4x10-1 1x101 1x106 4x101 4x101 1x103 1x107 მაგნიუმი (12) Mg-28 (ა) მარგანეცი (25) მოლიბდენი (42) აზოტი (7) N-13 ნატრიუმი (11) ნიობიუმი (41) ნეოდიმიუმი (60) ნიკელი (28) ნეპტუნიუმი (93) Np-235 287 რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) 2x10 1 2x10 0 1x103 1x107 9x100 2x10-2 1x102 1x105 Np-237 2x101 2x10-3 1x100 (ბ) 1x103 (ბ) Np-239 7x100 4x10-1 1x102 1x107 Os-186 1x100 1x100 1x101 1x106 Os-191 1x101 2x100 1x102 1x107 Os-191m 4x101 3x101 1x103 1x107 Os-193 2x100 6x10-1 1x102 1x106 Os-194 (ა) 3x10-1 3x10-1 1x102 1x105 P-32 5x10-1 5x10-1 1x103 1x105 P-33 4x101 1x100 1x105 1x108 Pa-230 (ა) 2x100 7x10-2 1x101 1x106 Pa-231 4x100 4x10-4 1x100 1x103 Pa-233 5x100 7x10-1 1x102 1x107 Pb-201 1x100 1x100 1x101 1x106 Pb-202 4x101 2x101 1x103 1x106 Pb-203 4x100 3x100 1x102 1x106 Pb-205 შეუზღუდავი შეუზღუდავი 1x104 1x107 Pb-210 (ა) 1x100 5x10-2 1x101 (ბ) 1x104 (ბ) Pb-212 (ა) 7x10-1 2x10-1 1x101 (ბ) 1x105 (ბ) 4x101 4x101 1x103 1x108 Pd-107 შეუზღუდავი შეუზღუდავი 1x105 1x108 Pd-109 2x100 5x10-1 1x103 1x106 Pm-143 3x100 3x100 1x102 1x106 Pm-144 7x10-1 7x10-1 1x101 1x106 A1 A2 აქტივობის კონცენტრაცია აქტივობისზღვარი იმ Np-236 (ხანმოკლე სიცოცხლის მქონე) Np-236 (ხანგრძლივი სიცოცხლის მქონე) ოსმიუმი (76) ფოსფორი (15) პროტაქტინიუმი (91) ტყვია (82) პალადიუმი (46) Pd-103 (ა) პრომეთიუმი (61) რადიონუკლიდი 288 (ატომური ნომერი) (თბკ) (თბკ) იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) Pm-145 3x101 1x101 1x103 1x107 Pm-147 4x101 2x100 1x104 1x107 Pm-148m (ა) 8x10-1 7x10-1 1x101 1x106 Pm-149 2x100 6x10-1 1x103 1x106 Pm-151 2x100 6x10-1 1x102 1x106 4x101 2x10-2 1x101 1x104 Pr-142 4x10-1 4x10-1 1x102 1x105 Pr-143 3x100 6x10-1 1x104 1x106 Pt-188 (ა) 1x100 8x10-1 1x101 1x106 Pt-191 4x100 3x100 1x102 1x106 Pt-193 4x101 4x101 1x104 1x107 Pt-193m 4x101 5x10-1 1x103 1x107 Pt-195m 1x101 5x10-1 1x102 1x106 Pt-197 2x101 6x10-1 1x103 1x106 Pt-197m 1x101 6x10-1 1x102 1x106 Pu-236 3x101 3x10-3 1x101 1x104 Pu-237 2x101 2x101 1x103 1x107 Pu-238 1x101 1x10-3 1x100 1x104 Pu-239 1x101 1x10-3 1x100 1x104 Pu-240 1x101 1x10-3 1x100 1x103 Pu-241 (ა) 4x101 6x10-2 1x102 1x105 Pu-242 1x101 1x10-3 1x100 1x104 Pu-244 (ა) 4x10-1 1x10-3 1x100 1x104 Ra-223 (ა) 4x10-1 7x10-3 1x102 (ბ) 1x105 (ბ) Ra-224 (ა) 4x10-1 2x10-2 1x101 (ბ) 1x105 (ბ) Ra-225 (ა) 2x10-1 4x10-3 1x102 1x105 პოლონიუმი (84) Po-210 პრაზეოდიმიუმი (59) პლატინა (78) პლუტონიუმი (94) რადიუმი (88) 289 რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) Ra-226 (ა) 2x10 3x10 -3 1x101 (ბ) 1x104 (ბ) Ra-228 (ა) 6x10-1 2x10-2 1x101 (ბ) 1x105 (ბ) Rb-81 2x100 8x10-1 1x101 1x106 Rb-83 (ა) 2x100 2x100 1x102 1x106 Rb-84 1x100 1x100 1x101 1x106 Rb-86 5x10-1 5x10-1 1x102 1x105 Rb-87 შეუზღუდავი შეუზღუდავი 1x104 1x107 Rb (ბუნებრივი) შეუზღუდავი შეუზღუდავი 1x104 1x107 Re-184 1x100 1x100 1x101 1x106 Re-184m 3x100 1x100 1x102 1x106 Re-186 2x100 6x10-1 1x103 1x106 Re-187 შეუზღუდავი შეუზღუდავი 1x106 1x109 Re-188 4x10-1 4x10-1 1x102 1x105 Re-189 (ა) 3x100 6x10-1 1x102 1x106 შეუზღუდავი შეუზღუდავი 1x106 1x109 Rh-99 2x100 2x100 1x101 1x106 Rh-101 4x100 3x100 1x102 1x107 Rh-102 5x10-1 5x10-1 1x101 1x106 Rh-102m 2x100 2x100 1x102 1x106 Rh-103m 4x101 4x101 1x104 1x108 Rh-105 1x101 8x10-1 1x102 1x107 3x10-1 4x10-3 1x101 (ბ) 1x108 (ბ) Ru-97 5x100 5x100 1x102 1x107 Ru-103 (ა) 2x100 2x100 1x102 1x106 Ru-105 1x100 6x10-1 1x101 1x106 Ru-106 (ა) 2x10-1 2x10-1 1x102 (ბ) 1x105 (ბ) -1 რუბიდიუმი (37) რენიუმი (75) Re (ბუნებრივი) როდიუმი (45) რადონი (86) Rn-222 (ა) რუთენიუმი (44) 290 რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) 4x101 3x100 1x105 1x108 Sb-122 4x10-1 4x10-1 1x102 1x104 Sb-124 6x10-1 6x10-1 1x101 1x106 Sb-125 2x100 1x100 1x102 1x106 Sb-126 4x10-1 4x10-1 1x101 1x105 Sc-44 5x10-1 5x10-1 1x101 1x105 Sc-46 5x10-1 5x10-1 1x101 1x105 Sc-47 1x101 7x10-1 1x102 1x106 Sc-48 3x10-1 3x10-1 1x101 1x105 Se-75 3x100 3x100 1x102 1x106 Se-79 4x101 2x100 1x104 1x107 Si-31 6x10-1 6x10-1 1x103 1x106 Si-32 4x101 5x10-1 1x103 1x106 Sm-145 1x101 1x101 1x102 1x107 Sm-147 შეუზღუდავი შეუზღუდავი 1x101 1x104 Sm-151 4x101 1x101 1x104 1x108 Sm-153 9x100 6x10-1 1x102 1x106 Sn-113 (ა) 4x100 2x100 1x103 1x107 Sn-117m 7x100 4x10-1 1x102 1x106 Sn-119m 4x101 3x101 1x103 1x107 Sn-121 (ა) 4x101 9x10-1 1x103 1x107 Sn-123 8x10-1 6x10-1 1x103 1x106 Sn-125 4x10-1 4x10-1 1x102 1x105 Sn-126 (ა) 6x10-1 4x10-1 1x101 1x105 გოგირდი (16) S-35 სტიბიუმი (51) სკანდიუმი (21) სელენი (34) კრემნიუმი (14) სამარიუმი (62) კალა (50) 291 რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) Sr-82 (ა) 2x10-1 2x10-1 1x101 1x105 Sr-85 2x100 2x100 1x102 1x106 Sr-85m 5x100 5x100 1x102 1x107 Sr-87m 3x100 3x100 1x102 1x106 Sr-89 6x10-1 6x10-1 1x103 1x106 Sr-90 (ა) 3x10-1 3x10-1 1x102 (ბ) 1x104 (ბ) Sr-91 (ა) 3x10-1 3x10-1 1x101 1x105 Sr-92 (ა) 1x100 3x10-1 1x101 1x106 4x101 4x101 1x106 1x109 1x100 8x10-1 1x101 1x106 Ta-179 3x101 3x101 1x103 1x107 Ta-182 9x10-1 5x10-1 1x101 1x104 Tb-157 4x101 4x101 1x104 1x107 Tb-158 1x100 1x100 1x101 1x106 Tb-160 1x100 6x10-1 1x101 1x106 Tc-95m (ა) 2x100 2x100 1x101 1x106 Tc-96 4x10-1 4x10-1 1x101 1x106 Tc-96m (ა) 4x10-1 4x10-1 1x103 1x107 Tc-97 შეუზღუდავი შეუზღუდავი 1x103 1x108 Tc-97m 4x101 1x100 1x103 1x107 Tc-98 8x10-1 7x10-1 1x101 1x106 Tc-99 4x101 9x10-1 1x104 1x107 Tc-99m 1x101 4x100 1x102 1x107 Te-121 2x100 2x100 1x101 1x106 Te-121m 5x100 3x100 1x102 1x106 A1 A2 აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც აქტივობისზღვარი იმ ტვირთისთვის, სტრონციუმი (38) ტრიტიუმი (1) T(H-3) ტანტალი (73) Ta-178 (ხანგრძლივი სიცოცხლის მქონე) ტერბიუმი (65) ტექნეციუმი (43) ტელურიუმი (52) რადიონუკლიდი (ატომური ნომერი) 292 (თბკ) (თბკ) ვრცელდება გამონაკლისები (ბკ/გ) რომელზეც ვრცელდება გამონაკლისი (ბკ) Te-123m 8x100 1x100 1x102 1x107 Te-125m 2x101 9x10-1 1x102 1x107 Te-127 2x101 7x10-1 1x103 1x106 Te-127m (ა) 2x101 5x10-1 1x103 1x107 Te-129 7x10-1 6x10-1 1x102 1x106 Te-129m (ა) 8x10-1 4x10-1 1x103 1x106 Te-131m (ა) 7x10-1 5x10-1 1x101 1x106 Te-132(ა) 5x10-1 4x10-1 1x102 1x107 Th-227 1x101 5x10-3 1x101 1x104 Th-228 (ა) 5x10-1 1x10-3 1x100 (ბ) 1x104 (ბ) Th-229 5x100 5x10-4 1x100 (ბ) 1x103 (ბ) Th-230 1x101 1x10-3 1x100 1x104 Th-231 4x101 2x10-2 1x103 1x107 Th-232 შეუზღუდავი შეუზღუდავი 1x101 1x104 3x10-1 3x10-1 1x103 (ბ) 1x105 (ბ) შეუზღუდავი შეუზღუდავი 1x100 (ბ) 1x103 (ბ) 5x10-1 4x10-1 1x101 1x105 Tl-200 9x10-1 9x10-1 1x101 1x106 Tl-201 1x101 4x100 1x102 1x106 Tl-202 2x100 2x100 1x102 1x106 Tl-204 1x101 7x10-1 1x104 1x104 Tm-167 7x100 8x10-1 1x102 1x106 Tm-170 3x100 6x10-1 1x103 1x106 Tm-171 4x101 4x101 1x104 1x108 4x101 1x10-1 1x101 (ბ) 1x105 (ბ) 4x101 4x10-3 1x101 1x104 თორიუმი (90) Th-234 (ა) Th (ბუნებრივი) ტიტანი (22) Ti-44 (ა) თალიუმი (81) თულიუმი (69) ურანი (92) U-230 (სწრაფი თირკმლისმიერი შთანთქმა) (ა) (დ) U-230 (საშუალო თირკმლისმიერი შთანთქმა) (ა) (ე) რადიონუკლიდი (ატომური ნომერი) A1 A2 293 აქტივობის კონცენტრაცია აქტივობისზღვარი იმ (თბკ) (თბკ) იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) U-230 (ნელი თირკმლისმიერი შთანთქმა) (ა) (ვ) 3x101 3x10-3 1x101 1x104 U-232 (სწრაფი თირკმლისმიერი შთანთქმა) (დ) 4x101 1x10-2 1x100 (ბ) 1x103 (ბ) U-232 (საშუალო თირკმლისმიერი შთანთქმა) (ე) 4x101 7x10-3 1x101 1x104 U-232 (ნელი თირკმლისმიერი შთანთქმა) (ვ) 1x101 1x10-3 1x101 1x104 U-233 (სწრაფი თირკმლისმიერი შთანთქმა) (დ) 4x101 9x10-2 1x101 1x104 U-233 (საშუალო თირკმლისმიერი შთანთქმა) (ე) 4x101 2x10-2 1x102 1x105 U-233 (ნელი თირკმლისმიერი შთანთქმა) (ვ) 4x101 6x10-3 1x101 1x105 U-234 (სწრაფი თირკმლისმიერი შთანთქმა) (დ) 4x101 9x10-2 1x101 1x104 U-234 (საშუალო თირკმლისმიერი შთანთქმა) (ე) 4x101 2x10-2 1x102 1x105 U-234 (ნელი თირკმლისმიერი შთანთქმა) (ვ) 4x101 6x10-3 1x101 1x105 U-235 (ყველანაირი ტიპის თირკმლისმიერი შთანთქმა) (ა)(დ)(ე)(ვ) შეუზღუ დავი შეუზღუდ ავი 1x101 (ბ) 1x104 (ბ) U-236 (სწრაფი თირკმლისმიერი შთანთქმა) (დ) შეუზღუ დავი შეუზღუდ ავი 1x101 1x104 U-236 (საშუალო თირკმლისმიერი შთანთქმა) (ე) 4x101 2x10-2 1x102 1x105 U-236 (ნელი თირკმლისმიერი შთანთქმა) (ვ) 4x101 6x10-3 1x101 1x104 U-238 (ყველანაირი ტიპის თირკმლისმიერი შთანთქმა) (დ)(ე)(ვ) შეუზღუ დავი შეუზღუდ ავი 1x101 (ბ) 1x104 (ბ) U (ბუნებრივი) შეუზღუ დავი შეუზღუდ ავი 1x100 (ბ) 1x103 (ბ) U (გამდიდრებული 20%-მდე ან უფრო ნაკლებად) (ზ) შეუზღუ დავი შეუზღუდ ავი 1x100 1x103 U (გაღარიბებული) შეუზღუ დავი შეუზღუდ ავი 1x100 1x103 V-48 4x10-1 4x10-1 1x101 1x105 V-49 4x101 4x101 1x104 1x107 W-178 (ა) 9x100 5x100 1x101 1x106 W-181 3x101 3x101 1x103 1x107 W-185 4x101 8x10-1 1x104 1x107 W-187 2x100 6x10-1 1x102 1x106 W-188 (ა) 4x10-1 3x10-1 1x102 1x105 ვანადიუმი (23) ვოლფრამი (74) 294 რადიონუკლიდი (ატომური ნომერი) A1 A2 (თბკ) (თბკ) აქტივობის კონცენტრაცია იმ მასალითვის, რომელზეც ვრცელდება გამონაკლისები (ბკ/გ) აქტივობისზღვარი იმ ტვირთისთვის, რომელზეც ვრცელდება გამონაკლისი (ბკ) Xe-122 (ა) 4x10-1 4x10-1 1x102 1x109 Xe-123 2x100 7x10-1 1x102 1x109 Xe-127 4x100 2x100 1x103 1x105 Xe-131m 4x101 4x101 1x104 1x104 Xe-133 2x101 1x101 1x103 1x104 Xe-135 3x100 2x100 1x103 1x1010 Y-87 (ა) 1x100 1x100 1x101 1x106 Y-88 4x10-1 4x10-1 1x101 1x106 Y-90 3x10-1 3x10-1 1x103 1x105 Y-91 6x10-1 6x10-1 1x103 1x106 Y-91m 2x100 2x100 1x102 1x106 Y-92 2x10-1 2x10-1 1x102 1x105 Y-93 3x10-1 3x10-1 1x102 1x105 Yb-169 4x100 1x100 1x102 1x107 Yb-175 3x101 9x10-1 1x103 1x107 Zn-65 2x100 2x100 1x101 1x106 Zn-69 3x100 6x10-1 1x104 1x106 Zn-69m (ა) 3x100 6x10-1 1x102 1x106 Zr-88 3x100 3x100 1x102 1x106 Zr-93 შეუზღუდავი შეუზღუდავი 1x103 (ბ) 1x107 (ბ) Zr-95 (ა) 2x100 8x10-1 1x101 1x106 Zr-97 (ა) 4x10-1 4x10-1 1x101 (ბ) 1x106 (ბ) ქსენონი (54) იტრიუმი (39) იტერბიუმი (70) თუთია (30) ცირკონიუმი (40) (ა) A1 და/ან A2 მნიშვნელობები აღნიშნული მშობელი რადიონუკლიდებისთვის იმ სხვადასხვა რადიონუკლიდებისგან წარმოდგენილი შენატანების ჩათვლით, რომლისგანაც შედგება რადიოაქტიური დაშლის ჯაჭვი და რომელთა ნახევრად გამოყოფის პერიოდი ნაკლებია 10 დღეზე, წარმოდგენილია ქვემოთ: Mg-28 Ar-42 Ca-47 Ti-44 Al-28 K-42 Sc-47 Sc-44 295 Fe-52 Fe-60 Zn-69m Ge-68 Rb-83 Sr-82 Sr-90 Sr-91 Rs-92 Y-87 Zr-95 Zr-97 Mo-99 Tc-95m Tc-96m Ru-103 Ru-106 Pd-103 Ag-108m Ag-110m Cd-115 In-114m Sn-113 Sn-121m Sn-126 Te-118 Te-127m Te-129m Te-131m Te-132 I-135 Xe-122 Cs-137 Ba-131 Ba-140 Ce-144 Pm-148m Gd-146 Dy-166 Hf-172 W-178 W-188 Re-189 Os-194 Ir-189 Pt-188 Mn-52m Co-60m Zn-69 Ga-68 Kr-83m Rb-82 Y-90 Y-91m Y-92 Sr-87m Nb-95m Nb-97m, Nb-97 Tc-99m Tc-95 Tc-96 Rh-103m Rh-106 Rh-103m Ag-108 Ag-110 In-115m In-114 In-113m Sn-121 Sb-126m Sb-118 Te-127 Te-129 Te-131 I-132 Xe-135m I-122 Ba-137m Cs-131 La-140 Pr-144m, Pr-144 Pm-148 Eu-146 Ho-166 Lu-172 Ta-178 Re-188 Os-189m Ir-194 Os-189m Ir-188 296 Hg-194 Hg-195m Pb-210 Pb-212 Bi-210m Bi-212 At-211 Rn-222 Ra-223 Ra-224 Ra-225 Ra-226 Ra-228 Ac-225 Ac-227 Th-228 Th-234 Pa-230 U-230 U-235 Pu-241 Pu-244 Am-242m Am-243 Cm-247 Bk-249 Cf-253 (ბ) Au-194 Hg-195 Bi-210 Bi-212, Tl-208, Po-212 Tl-206 Tl-208, Po-212 Po-211 Po-218, Pb-214, At-218, Bi-214, Po-214 Rn-219, Po-215, Pb-211, Bi-211, Po-211, Tl-207 Rn-220, Po-216, Pb-212, Bi-212, Tl-208, Po-212 Ac-225, Fr-221, At-217, Bi-213, Tl-209, Po-213, Pb-209 Rn-222, Po-218, Pb-214, At-218, Bi-214, Po-214 Ac-228 Fr-221, At-217, Bi-213, Tl-209, Po-213, Pb-209 Fr-223 Ra-224, Rn-220, Po-216, Pb-212, Bi-212, Tl-208, Po-212 Pa-234m, Pa-234 Ac-226, Th-226, Fr-222, Ra-222, Rn-218, Po-214 Th-226, Ra-222, Rn-218, Po-214 Th-231 U-237 U-240, Np-240m Am-242, Np-238 Np-239 Pu-243 Am-245 Cm-249 მუდმივ თანასწორობაში წარმოდგენილი მშობელი ნუკლიდებისა და მათი მეორადი ნაწილაკების ჩამონათვალი მოცემულია შემდეგი სახით: Sr-90 Zr-93 Zr-97 Ru-106 Ag-108m Cs-137 Ce-144 Ba-140 Bi-212 Pb-210 Pb-212 Rn-222 Ra-223 Ra-224 Y-90 Nb-93m Nb-97 Rh-106 Ag-108 Ba-137m Pr-144 La-140 Tl-208 (0.36), Po-212 (0.64) Bi-210, Po-210 Bi-212, Tl-208 (0.36), Po-212 (0.64) Po-218, Pb-214, Bi-214, Po-214 Rn-219, Po-215, Pb-211, Bi-211, Tl-207 Rn-220, Po-216, Pb-212, Bi-212, Tl-208 (0.36), Po-212 (0.64) 297 Ra-226 Ra-228 Th-228 Th-229 Th-ბუნებრივი Th-234 U-230 U-232 U-235 U-238 U-ბუნებრივი Np-237 Am-242m Am-243 2.2.7.2.2.2 Rn-222, Po-218, Pb-214, Bi-214, Po-214, Pb-210, Bi-210, Po-210 Ac-228 Ra-224, Rn-220, Po-216, Pb-212, Bi-212, TL-208 (0.36) Po-212 (0.64) Ra-225, Ac-225, Fr-221, At-217, Bi-213, Po-213, Pb-209 Ra-228, Ac-228, Th-228, Ra-224, Rn-220, Po-216, Pb-212, Bi-212, l208 (0.36), Po-212 (0.64) Pa-234m Th-226, Ra-222, Rn-218, Po-214 Th-228, Ra-224, Rn-220, Po-216, Pb-212, Bi-212, Tl-208 (0.36), Po-212 (0.64) Th-231 Th-234, Pa-234m Th-234, Pa-234m, U-234, Th-230, Ra-226, Rn-222, Po-218, Pb-214, Bi-214, Po-214, Pb-210, Bi-210, Po-210 Pa-233 Am-242 Np-239 (გ) რაოდენობა შესაძლებელია განსაზღვრულ იქნეს დაშლის სიჩქარის გაზომვით ან გამოსხივების დონის გაანგარიშებით წყაროდან დადგენილ მანძილზე. (დ) აღნიშნული მნიშვნელობები გამოიყენება მხოლოდ ურანის ნაერთებთან დაკავშირებით, რომელიც იღებს ქიმიურ ფორმას - UF6, UO2F2 და UO2(NO3)2 გადაზიდვების როგორც ნორმალურ, ასევე ავარიულ პირობებში. (ე) აღნიშნული მნიშვნელობები გამოიყენება მხოლოდ ურანის ნაერთებთან დაკავშირებით, რომელიც იღებს ქიმიურ ფორმას - UO3, UF4, UCL4, ასევე ექვსვალენტიან ნაერთებთან დაკავშირებით, გადაზიდვების როგორც ნორმალურ, ასევე ავარიულ პირობებში. (ვ) აღნიშნული მნიშვნელობა გამოიყენება ურანის ყველა ნაერთთან დაკავშირებით, გარდა ზემოაღნიშნულ (დ) და (ე) პუნქტში მოყვანილი ნაერთებისა. (ზ) ეს მნიშვნელობა დაკავშირებით. გამოიყენება მხოლოდ არა-რადიაციულ ურანთან ცალკეული რადიონუკლიდების შემთხვევაში, (ა) რომლებიც არ არის ჩამოთვლილი 2.2.7.2.2.1 ცხრილში, 2.2.7.2.2.1 პუნქტში გათვალისწინებული რადიონუკლიდების ძირითადი მნიშვნელობები უნდა მოითხოვდეს მრავალმხრივ დამტკიცებას. აღნიშნული რადიონუკლიდების შემთხვევაში, გამონაკლისი მასალის აქტივობის კონცენტრაციის ზღვარი და გამონაკლისი ტვირთის აქტივობის ზღვარი უნდა დაანგარიშდეს „მაიონებელი გამოსხივებისგან დაცვისა და გამოსხივების წყაროების უსაფრთხოების შესახებ საერთაშორისო უსაფრთხოების სტანდარტებით“ გათვალისწინებული პრინციპების შესაბამისად, №115 უსაფრთხების სერიები, IEAE, ვენა (1996 წ.). 298 დასაშვებია A2 მნიშვნელობის გამოყენება, რომელიც გათვლილია დოზირების კოეფიციენტის გამოყენებაზე ფილტვის აბსორბციის შესაბამისი ტიპისთვის, რადიოლოგიური დაცვის საერთაშორისო კომისიის რეკომენდაციის მიხედვით იმ პირობით, რომ მხედველობაში იქნება მიღებული ყოველი ნუკლიდის ქიმიური ფორმა გადაზიდვის როგორც ნორმალურ, ასევე ავარიულ პირობებში. ალტერნატივის სახით, 2.2.7.2.2.2 პუნქტში წარმოდგენილი რადიონუკლიდების მნიშვნელობები შესაძლებელია გამოყენებულ იქნეს კომპეტენტური ორგანოს თანხმობის მიღების გარეშე. (ბ) იმ ინსტრუმენტებში ან ნაკეთობებში, რომლებიც შეიცავს რადიოაქტიურ მასალას ან რომლებიც წარმოადგენს ინსტრუმენტისა თუ სხვა საწარმოო ნაკეთობის შემადგენელ ნაწილს და აკმაყოფილებს 2.2.7.2.4.1.3 (გ) ქვეპუნქტით გათვალისწინებულ მოთხოვნებს, დაიშვება ძირითადი მნიშვნელობები იმ ალტერნატიული რადიონუკლიდებისთვის, რომლებიც მითითებულია 2.2.7.2.2.1 ცხრილში იმ ტვირთის აქტივობის ზღვართან დაკავშირებით, რომელზეც ვრცელდება გამონაკლისი და რომლებიც უნდა მოითხოვდეს მრავალმხრივ დამტკიცებას. ტვირთის აღნიშნული ალტერნატური აქტივობის კონცენტრაციის ზღვარი უნდა დაანგარიშდეს „მაიონებელი გამოსხივებისგან დაცვისა და გამოსხივების წყაროების უსაფრთხოების შესახებ საერთაშორისო უსაფრთხოების სტანდარტებით“ გათვალისწინებული პრინციპების შესაბამისად, №115 უსაფრთხების სერიები, IEAE, ვენა (1996 წ.). ცხრილი 2.2.7.2.2.2: ძირითადი რადიონუკლიდების მნიშვნელობები უცნობი რადიონუკლიდებისა თუ ნარევებისთვის რადიოაქტიური შემადგენლობა ცნობილია, რომ წარმოდგენილია მხოლოდ ბეტა ან გამა გამომსხივარი ნუკლიდები ცნობილია, რომ წარმოდგენილია ალფა-გამომსხივარი ნუკლიდები, თუმცა არა ნეიტრონების გამომსხივარები ცნობილია, რომ წარმოდგენილია ნუკლიდების გამომსხივარი ნეიტრონები ან შესაბამისი მონაცემები არ არის ხელმისაწვდომი 2.2.7.2.2.3 A1 A2 (თბკ) 0.1 (თბკ) 0.02 აქტივობის კონცენტრაციის ზღვარი გამონაკლისი მასალისთვის (ბკ/გ) 1 x 101 აქტოვობის ფარგლები გამონაკლისი ტვირთისთვის 0.2 9 x 10-5 1 x 10-1 1 x 103 0.001 9 x 10-5 1 x 10-1 1 x 103 (ბკ) 1 x 104 A1 და A2 მნიშვნელობების გაანგარიშებისას იმ რადიონუკლიდებისთვის, რომლებიც არ არის წარმოდგენილი 2.2.7.2.2.1 ქვეპუნქტში, რადიოაქტიური დაშლის ერთი ჯაჭვი, 299 რომელშიც რადიონუკლიდები წარმოდგენილია მათი ბუნებრივი პროპორციებით და რომელშიც არ არის წარმოდგენილი შვილობილი ნუკლიდი 10 დღეზე ხანგრძლივი ან მშობელი ნუკლიდის ნახევრად გამოყოფის პერიოდზე ხანგრძლივი ნახევრად გამოყოფის პერიოდი, განიხილება ერთ ნუკლიდად; გასათვალისწინებელი აქტივობა და A1 და A2 გამოსაყენებელი მნიშვნელობები უნდა შეესაბამებოდნენ აღნიშნული ჯაჭვის მშობელი ნუკლიდის აქტივობასა და მნიშვნელობას. ისეთი რადიოაქტიური დაშლის ჯაჭვების შემთხვევაში, რომელშიც შვილობილ ნუკლიდს გააჩნია 10 დღეზე ხანგრძლივი ან მშობელი ნუკლიდის ნახევრად გამოყოფის პერიოდზე ხანგრძლივი ნახევრად გამოყოფის პერიოდი, მაშინ მშობელი და აღნიშნული შვილობილი ნუკლიდები ჩაითვლება სხვადასხვა ნუკლიდების ნარევებად. 2.2.7.2.2.4 რადიონუკლიდების ნარევებთან დაკავშირებით, 2.2.7.2.2.1 ქვეპუნქტში გათვალისწინებული რადიონუკლიდების ძირითადი მნიშვნელობები შესაძლებელია განისაზღვროს შემდეგნაირად: სადაც, f(i) წარმოადგენს ნაერთში i რადიონუკლიდის აქტივობის წილს ან აქტივობის კონცენტრაციას. X(i) არის A1 ან A2 შესაბამისი მნიშვნელობები ან აქტივობის კონცენტრაცია გამონაკლის მასალასთან დაკავშირებით ან აქტივობის საზღვრები გამონაკლის ტვირთთან დაკავშირებით, რაც შეესაბამება i რადიონუკლიდის მნიშვნელობას; და Xm წარმოადგენს A1 ან A2 წარმოებულ მნიშვნელობას ან აქტივობის კონცენტრაციას გამონაკლის მასალასთან დაკავშირებით ან აქტივობის საზღვრებს გამონაკლის ტვირთთან დაკავშირებით, ნარევის შემთხვევაშi. 2.2.7.2.2.5 როდესაც თითოეული რადიონუკლიდის იდენტობა ცნობილია, თუმცა უცნობია ზოგიერთი რადიონუკლიდის ინდივიდუალური აქტივობა, შესაძლებელია რადიონუკლიდების დაჯგუფება და თითოეულ ჯგუფში წარმოდგენილ რადიონუკლიდებთან დაკავშირებით ყველაზე დაბალი მნიშვნელობა, შესაბამისად, შესაძლებელია გამოყენებულ იქნეს 2.2.7.2.2.4 და 2.2.7.2.4.4 ქვეპუნქტებში მოყვანილ ფორმულებში. ჯგუფები შესაძლებელია დაემყაროს სრულ ალფა-აქტივობას და სრულ ბეტა/გამა აქტივობას, თუ ისინი განსაზღვრულია ყველაზე დაბალი მნიშვნელობის გამოყენებით, შესაბამისად, ალფა-გამომოსხივარებისა თუ ბეტა/გამა გამომსხივარებისთვის. 2.2.7.2.2.6 ცალკეული რადიონუკლიდებისა თუ რადიონუკლიდების ნარევების შემთხვევაში, რომლებთან დაკავშირებითაც არ არის ხელმისაწვდომი შესაბამისი მონაცემები, გამოყენებულ უნდა იქნეს 2.2.7.2.2.2 ქვეპუნქტში მოყვანილი მნიშვნელობები. 2.2.7.2.3 მასალების სხვა მახასიათებლების განსაზღვრა 2.2.7.2.3.1 დაბალის სპეციფიკური აქტივობის მქონე მასალები (LSA) 2.2.7.2.3.1.1 (რეზერვირებულია) 300 2.2.7.2.3.1.2 LSA მასალები შედის სამი ჯგუფიდან ერთ-ერთში: (ა) (ბ) (გ) LSA-I (i) ურანისა და თორიუმის მადნები და აღნიშნული მადნების კონცენტრატები, ასევე სხვა, ბუნებრივი ნუკლიდების შემცველი მადნები, რომლებიც გათვალისწინებულია გადამუშავებისთვის აღნიშნული რადიონუკლიდების გამოყენების მიზნით; (ii) ბუნებრივი ურანი, გაღარიბებული ურანი, ბუნებრივი თორიუმი თუ მათი ნაერთები ან ნარევები, რომლებიც წარმოდგენილია არა-რადიაციული და მყარი ან თხევადი ფორმით; (iii) რადიოაქტიური მასალა, რომლისთვისაც A2 მნიშვნელობა არ იზღუდება. გაყოფადი მასალები შესაძლებელია გათვალისწინებული იქნეს იმ შემთხვევაში, თუ იქნება გამოთავისუფლებული 2.2.7.2.3.5 ქვეპუნქტის თანახმად; ან (iv) სხვა რადიოაქტიური მასალები, რომლებშიც აქტივობა ნაწილდება სრული მოცულობით და დადგენილი საშუალო სპეციფიკური აქტივობა არ აღემატება 30-ჯერ 2.2.7.2.2.1-დან 2.2.7.2.2.6 ქვეპუნქტამდე გათვალისწინებული აქტივობის კონცენტრაციასთან დაკავშირებულ მნუშვნელობებს, იმ გაყოფადი მასალების გარდა, რომლებიც არ ექვემდებარება გამოთავისუფლებას 2.2.7.2.3.5 ქვეპუნქტის თანახმად; LSA-II (i) წყალი 0.8 თბკ/ლ-მდე ტრიტიუმის კონცენტრაციით; ან (ii) სხვა რადიოაქტიური მასალები, რომლებშიც აქტივობა ნაწილდება სრული მოცულობით და დადგენილი საშუალო სპეციფიკური აქტივობა არ აღემატება 10-4 A2/გ-ს მყარი ნივთიერებებისა და აირების შემთხვევაში და 10-5 A2/გ-ს - თხევადი ნივთიერებების შემთხვევაში; LSA-III - მყარი ნივთიერებები (მაგალითად კონსოლიდირებული ნარჩენები, გააქტიურებული მასალები), გარდა ფხვნილებისა, რომლებიც აკმაყოფილებს 2.2.7.2.3.1.3 ქვეპუნქტში მოყვანილ მოთხოვნებს, რომელშიც: (i) რადიოაქტიური მასალა განაწილებულია მყარი ნივთიერებისა თუ მყარი ობიექტების ჯგუფის მთელ მოცულობაზე ან არსებითად ერთგვაროვნად არის განაწილებული მყარ, კომპაქტურ შემაკავშირებელ მასალაში (მაგალითად, ბეტონში, ბითუმში, კერამიკასა და ა.შ.); (ii) რადიოაქტიური მასალა შედარებით უხსნადია, ან სტრუქტურულად წარმოდგენილია შედარებით უხსნად მატრიცაში ისე, რომ შეფუთვის დაკარგვის შემთხვევაშიც კი, ყოველ შეფუთვაზე რადიოაქტიური მასალის დანაკარგი გამოტუტვის გზით შვიდი დღის განმავლობაში წყალში მოთავსებისას არ გადააჭარბებს 0.1 A2-ს; და (iii) მყარი ნივთიერების დადგენილი საშუალო კუთრი აქტივობა ნებისმიერი დამცავი მასალის გარეშე, არ აღემატება 2X10-3 A2/გ-ს. 301 2.2.7.2.3.1.3 LSA-III მასალა უნდა იყოს მყარი და ისე, რომ შეფუთვის სრული შიგთავსი რომ დაექვემდებაროს 2.2.7.2.3.1.4 ქვეპუნქტში გათვალისწინებულ ცდას, მისი მოქმედება წყალში არ უნდა აღემატებოდეს 0.1 A2-ს. 2.2.7.2.3.1.4 LSA-III მასალის გამოცდა უნდა მოხდეს შემდეგნაირად: მყარი მასალის ნიმუში, რომელიც წარმოადგენს შეფუთვის სრულ შიგთავსს, უნდა მოთავსდეს წყალში, გარემოს ტემპერატურაზე, 7 დღის განმავლობაში. ცდაში გამოსაყენებელი წყლის მოცულობა საკმარისი უნდა იყოს იმისათვის, რომ 7 დღის საცდელი პერიოდის დასასრულს არა-აბსორბირებული და არა-რეაქტიული წყლის დარჩენილი თავისუფალი მოცულობა შეადგენდეს თავად მყარი საცდელი ნიმუშის მინიმუმ 10%-ს. წყლის საწყისი pH უნდა იყოს 6-8, ხოლო მაქსიმალური გამტარობა - 1 მს/მ 200C ტემპერატურაზე. საცდელი ნიმუშის 7 დღის განმავლობაში ჩაძირვის შემდეგ იზომება წყლის თავისუფალი მოცულობის სრული მოქმედება. 2.2.7.2.3.1.5 2.2.7.2.3.1.4 ქვეპუნქტში გათვალისწინებულ სამუშაო სტანდარტებთან შესაბამისობის დემონსტრირება უნდა განხორციელდეს 6.4.12.1 და 6.4.12.2 პუნქტების შესაბამისად. 2.2.7.2.3.2 რადიოაქტიურად დაბინძურებული ზედაპირის მქონე ობიექტი (SCO) რადიოაქტიურად დაბინძურებული ზედაპირის მქონე ობიექტის კლასიფიცირება ხდება ორ ჯგუფად: (ა) SCO-I: მყარი ობიექტი, რომელზეც: (i) არაფიქსირებული რადიოაქტიური დაბინძურება მისაწვდომ ზედაპირზე, გაშუალედებული 300სმ2-ზე (ან ზედაპირის მთელ არეალზე, იმ შემთხვევაში, თუ მისი არეალი ნაკლებია 300 სმ2-ზე), არ აღემატება 4 ბკ/სმ2-ს ბეტა- და გამა გამომსხივარებისა და დაბალი ტოქსიკურობის მქონე ალფა-გამომსხივარისთვის, ან 0.4 ბკ/სმ2-ს - ყველა დანარჩენი ალფაგამომსხივარისთვის; და (ii) ფიქსირებული რადიოაქტიური დაბინძურება მისაწვდომ ზედაპირზე, გაშუალედებული 300სმ2-ზე (ან ზედაპირის მთელ არეალზე, იმ შემთხვევაში, თუ მისი არეალი ნაკლებია 300 სმ2-ზე), არ აღემატება 4X104 ბკ/სმ2-ს ბეტა- და გამა გამომსხივარებისა და დაბალი ტოქსიკურობის მქონე ალფა-გამომსხივარისთვის, ან 4X103 ბკ/სმ2-ს - ყველა დანარჩენი ალფა-გამომსხივარისთვის; და (iii) არაფიქსირებული რადიოაქტიური დაბინძურება პლუს ფიქსირებული რადიოაქტიური დაბინძურება მიუწვდომელ ზედაპირზე, 2 გაშუალედებული 300სმ -ზე (ან ზედაპირის მთელ არეალზე, იმ შემთხვევაში, თუ მისი არეალი ნაკლებია 300 სმ2-ზე), არ აღემატება 4X104 ბკ/სმ2-ს ბეტა- და გამა გამომსხივარებისა და დაბალი ტოქსიკურობის მქონე ალფა-გამომსხივარისთვის, ან 4X103 ბკ/სმ2-ს - ყველა დანარჩენი ალფა-გამომსხივარისთვის. (ბ) SCO-II: მყარი ობიექტი, რომელზეც ზედაპირის ფიქსირებული ან არაფიქსირებული რადიოაქტიური დაბინძურება აღემატება წინამდებარე (ა) პუნქტში მითითებულ SCO-I-სთვის დაშვებულ ფარგლებს და რომელზეც: 302 (i) არაფიქსირებული რადიოაქტიური დაბინძურება მისაწვდომ ზედაპირზე, გაშუალედებული 300სმ2-ზე (ან ზედაპირის მთელ არეალზე, იმ შემთხვევაში, თუ მისი არეალი ნაკლებია 300 სმ2-ზე), არ აღემატება 400 ბკ/სმ2-ს ბეტა- და გამა გამომსხივარებისა და დაბალი ტოქსიკურობის მქონე ალფა-გამომსხივარისთვის, ან 40 ბკ/სმ2-ს - ყველა დანარჩენი ალფაგამომსხივარისთვის; და (ii) ფიქსირებული რადიოაქტიური დაბინძურება მისაწვდომ ზედაპირზე, გაშუალედებული 300სმ2-ზე (ან ზედაპირის მთელ არეალზე, იმ შემთხვევაში, თუ მისი არეალი ნაკლებია 300 სმ2-ზე), არ აღემატება 8 X105 ბკ/სმ2-ს ბეტა- და გამა გამომსხივარებისა და დაბალი ტოქსიკურობის მქონე ალფა-გამომსხივარისთვის, ან 5X104 ბკ/სმ2-ს - ყველა დანარჩენი ალფა-გამომსხივარისთვის; და (iii) არაფიქსირებული რადიოაქტიური დაბინძურება პლიუს ფიქსირებული რადიოაქტიური დაბინძურება მიუწვდომელ ზედაპირზე, გაშუალედებული 300სმ2-ზე (ან ზედაპირის მთელ არეალზე, იმ შემთხვევაში, თუ მისი არეალი ნაკლებია 300 სმ2-ზე), არ აღემატება 8X105 ბკ/სმ2-ს ბეტა- და გამა გამომსხივარებისა და დაბალი ტოქსიკურობის მქონე ალფა-გამომსხივარისთვის, ან 8X104 ბკ/სმ2-ს - ყველა დანარჩენი ალფა-გამომსხივარისთვის. 2.2.7.2.3.3 სპეციალური ფორმის რადიოაქტიური მასალა 2.2.7.2.3.3.1 სპეციალური ფორმის რადიოაქტიური მასალა უნდა იყოს მინიმუმ ერთი, არანაკლებ 5 მმ ზომის. იმ შემთხვევაში, თუ სპეციალური ფორმის რადიოაქტიური მასალის ნაწილის სახით წარმოდგენილია ჰერმეტული კაფსულა, კაფსულის დამზადება უნდა მოხდეს იმ სახით, რომ მისი გახსნა შესაძლებელი იყოს მხოლოდ მისი განადგურებით. სპეციალური ფორმის რადიოაქტიური მასალის კონსტრუქცია საჭიროებს ცალმხრივ დამტკიცებას. 2.2.7.2.3.3.2 სპეციალური ფორმის რადიოაქტიურ მასალას უნდა ჰქონდეს ისეთი თვისებები ან ისე უნდა იყოს კონსტრუირებული, რომ 2.2.7.2.3.3.4-დან 2.2.7.2.3.3.8 პუნქტებში გათვალისწინებული ცდებისას, აკმაყოფილებდეს შემდეგ მოთხოვნებს: (ა) ის არ უნდა იმტვრეოდეს ან იმსხვრეოდეს შესაბამის 2.2.7.2.3.3.5 (ა), (ბ), (გ) და 2.2.7.2.3.3.6 (ა) ქვეპუნქტებში გათვალისწინებულ შეჯახებაზე, დარტყმასა თუ მოხრაზე განხორციელებული ცდების დროს; (ბ) ის არ უნდა დნებოდეს ან იშლებოდეს შესაბამის 2.2.7.2.3.3.5 (დ) ან 2.2.7.2.3.3.6 (ბ) ქვეპუნქტებში გათვალისწინებულ გაცხელებაზე ჩატარებული ცდების დროს; და (დ) წყალში აქტივობა 2.2.7.2.3.3.7 და 2.2.7.2.3.3.8 ქვეპუნქტებში გათვალისწინებულ გამოტუტვაზე ჩატარებული ცდების დროს, არ უნდა აღემატებოდეს 2 კბკ-ს, ან ალტერნატიულად დახურული წყაროებისთვის, გაჟონვის ხარისხი ISO 9978:1992 სტანდარტში - „რადიაციული დაცვა - დახურული რადიოაქტიური წყაროები - გაჟონვის ტესტირების მეთოდები“ გათვალისწინებული მოცულობითი გაჟონვის შეფასების ცდასთან დაკავშირებით არ უნდა აღემატებოდეს კომპეტენტური ორგანოს მიერ დადგენილ შესაბამის დასაშვებ ზღვარს. 303 2.2.7.2.3.3.3 იმ სამუშაო სტანდარტებთან, რომლებიც გათვალისწინებულია 2.2.7.2.3.3.2 ქვეპუნქტში, შესაბამისობის დემონსტრირება უნდა მოხდეს 6.4.12.1. და 6.4.12.2 პუნქტების შესაბამისად. 2.2.7.2.3.3.4 ნიმუშები, რომლებიც შეიცავს ან ახდენს სპეციალური ფორმის რადიოაქტიური მასალების იმიტირებას, უნდა დაექვემდებაროს შეჯახების, დარტყმის, დახრისა და გახურების ცდებს, რაც წარმოდგენილია 2.2.7.2.3.3.5 ქვეპუნქტში ან 2.2.7.2.3.3.6 ქვეპუნქტში დაშვებულ ალტერნატიულ ცდებს. თითოეული აღნიშნული ცდისთვის შესაძლებელია გამოყენებულ იქნეს სხვადასხვა ნიმუში. ყოველი ცდის შემდგომ უნდა განხორცილედეს ნიმუშის გამოტუტვის შეფასება ან ცდა მოცულობით გაჟონვაზე იმ მეთოდით, რომელიც 2.2.7.2.3.3.7 ქვეპუნქტში მყარ დაშლად მასალასთან დაკავშირებით მოყვანილ მეთოდებზე ან 2.2.7.2.3.3.8 ქვეპუნქტში კაფსულაში წარმოდგენილ მასალებთან დაკავშირებულ მეთოდებზე არანაკლებ მგრძნობიარეა. 2.2.7.2.3.3.5 შესაბამისი ცდის მეთოდებია: (ა) ცდა შეჯახებაზე: ნიმუში უნდა ჩამოვარდეს სამიზნეზე 9 მეტრის სიმაღლიდან. სამიზნე განისაზღვრება 6.4.14 პუნქტის მიხედვით; (ბ) ცდა დარტყმაზე: ნიმუში უნდა განთავსდეს ტყვიის ფურცელზე, რომელიც გამაგრებულია გლუვი მყარი ზედაპირით და მასზე დარტყმა ხდება რბილი ფოლადის ძელის ბრტყელი მხრიდან ისე, რომ გამოიწვიოს 1 მეტრის სიმაღლიდან 1.4 კგ თავისუფალი ვარდნის შედეგად გამოწვეული შეჯახების ეკვივალენტური შეჯახება. ძელის ყველაზე დაბალი ნაწილი უნდა იყოს 25 მმ დიამეტრის (3.0+0.3) მმ რადიუსის მქონე მომრგვალებული კიდეებით. ვიკერსის შკალით 3.5-დან 4.5-მდე სიმაგრის ნომრებისა და არაუმეტეს 25 მმ სისქის მქონე ტყვიამ უნდა დაფაროს იმაზე დიდი არეალი, ვიდრე ნიმუშით არის დაფარული. ყოველი შეჯახებისას გამოყენებულ უნდა იქნეს ტყვიის ახალი ზედაპირი. ძელის დარტყმა ისე უნდა მოხდეს ნიმუშზე, რომ გამოიწვიოს მაქსიმალური ზიანი; (გ) ცდა მოხრაზე: აღნიშნული ცდა შესაძლებელია განხორციელდეს მხოლოდ გრძელი, თხელი წყაროების მიმართ, რომელთაც გააჩნიათ როგორც 10 სმ მინიმალური სიგრძე, ასევე არანაკლებ 10 კოეფიციენტის მქონე მინიმალური სიგანე. ნიმუშები მყარად უნდა დამაგრდეს ჰორიზონტალურ მდგომარეობაში ისე, რომ მისი სიგრძის ნახევარი გამოწეული იყოს მოჭერის ადგილის ფარგლებიდან. ნიმუშების ორიენტაცია უნდა იყოს ისე, რომ ნიმუშებმა განიცადონ მაქსიმალური ზიანი ფოლადის ძელის ბრტყელი ზედაპირით მისი თავისუფალ ბოლოზე მიყენებული დარტყმისას. ძელმა უნდა დაარტყას ნიმუშს ისე, რომ უზრუნველყოს 1 მეტრის სიმაღლიდან 1.4 კგ თავისუფალი ვერტიკალური ვარდნით გამოწვეული შეჯახების ეკვივალენტური შეჯახება. ძელის ყველაზე დაბალი ნაწილი უნდა იყოს 25 მმ დიამეტრის (3.0+0.3) მმ რადიუსის მქონე მომრგვალებული კიდეებით; (დ) ცდა გახურებაზე: ნიმუშები უნდა გახურდეს ჰაერში 8000C ტემპერატურაზე და გაჩერდეს აღნიშნულ ტემპერატურაზე 10 წუთის განმავლობაში, შემდგომ ამისა კი დასაშვებია მისი გაგრილება. 2.2.7.2.3.3.6 ნიმუშები, რომლებიც შეიცავს ან ახდენს ჰერმეტულ კაფსულაში მოთავსებული რადიოაქტიური მასალების იმიტირებას, შესაძლებელია გათავისუფლდეს შემდეგი ცდებისგან: 304 (ა) 2.2.7.2.3.3.5 (ა) და (ბ) ქვეპუნქტებში გათვალისწინებული ცდები იმ პირობით, რომ ნიმუშები აღნიშნულის ნაცვლად ექვემდებარება ISO 2919:2012 სტანდარტით - „რადიაციული დაცვა - დახურული რადიოაქტიური წყაროები - ზოგადი მოთხოვნები და კლასიფიკაცია“ გათვალისწინებულ ცდას შეჯახებაზე: (i) მე-4 კლასის ცდას შეჯახებაზე, თუ სპეციალური ფორმის რადიოაქტიური მასალა ტოლია ან ნაკლებია 200 გრ-ზე; (ii) მე-5 კლასის ცდას შეჯახებაზე, თუ სპეციალური ფორმის რადიოაქტიური მასალა ტოლია ან მეტია 200 გრ-ზე, თუმცა ნაკლებია 500 გრ-ზე; (ბ) 2.2.7.2.3.3.5 (დ) ქვეპუნქტში გათვალისწინებული ცდები იმ პირობით, რომ აღნიშნულის ნაცვლად ისინი ექვემდებარება მე-6 კლასის ცდას ტემპერატურაზე, რაც გათვალისწინებულია ISO 2919:1999 სტანდარტით - „რადიაციული დაცვა დახურული რადიოაქტიური წყაროები - ზოგადი მოთხოვნები და კლასიფიკაცია“; ან 2.2.7.2.3.3.7 იმ ნიმუშებისთვის, რომლებიც შედგება ან ახდენს დაშლადი მყარი მასალის იმიტირებას, გამოტუტვაზე შეფასება ტარდება შემდეგნაირად: (ა) ნიმუშები უნდა მოთავსდეს წყალში გარემოს ტემპერატურაზე, 7 დღე-ღამის განმავლობაში. ცდაში გამოსაყენებელი წყლის მოცულობა საკმარისი უნდა იყოს იმისათვის, რომ 7 დღე-ღამის საცდელი პერიოდის დასასრულს არააბსორბირებული და არა-რეაქტიული წყლის დარჩენილი თავისუფალი მოცულობა შეადგენდეს თავად მყარი საცდელი ნიმუშის მინიმუმ 10%-ს. წყლის საწყისი pH უნდა იყოს 6-8, ხოლო მაქსიმალური გამტარობა - 1 მკმ/მ 200C ტემპერატურაზე; (ბ) ნიმუშებთან წარმოდგენილი წყალი უნდა გახურდეს (50+5)0C ტემპერატურაზე და შეინარჩუნოს აღნიშნული ტემპერატურა 4 საათის განმავლობაში; (გ) შემდგომ ამისა განისაზღვრება წყლის აქტივობა; (დ) შემდეგ ნიმუშები უნდა შეინახოს მინიმუმ 7 დღე-ღამის განმავლობაში უძრავ ჰაერში არანაკლებ 300C ტემპერატურასა და არანაკლებ 90% ფარდობით ტენიანობაზე; (ე) შემდგომ ამისა ნიმუშები უნდა მოთავსდეს ზემოაღნიშნული (ა) პუნქტის მსგავსი პარამეტრების მქონე წყალში; ნიმუშებთან წარმოდგენილი წყალი უნდა გახურდეს (50+5)0C ტემპერატურაზე და შეინარჩუნოს აღნიშნული ტემპერატურა 4 საათის განმავლობაში; (ვ) ამის შემდგომ განისაზღვრება წყლის აქტივობა. 2.2.7.2.3.3.8 იმ ნიმუშებთან დაკავშირებით, რომლებიც შეიცავს ან ახდენს ჰერმეტულ კაფსულაში მოთავსებული რადიოაქტიური მასალების იმიტირებას, უნდა განხორციელდეს გამოტუტვის შეფასება ან მოცულობითი გაჟონვის შეფასება შემდეგნაირად: (ა) გამოტუტვის შეფასება შედგება შემდეგი საფეხურებისგან: (i) ნიმუშები უნდა მოთავსდეს წყალში გარემოს ტემპერატურაზე. წყლის საწყისი pH უნდა იყოს 6-8, ხოლო მაქსიმალური გამტარობა - 1 მკმ/მ 200C ტემპერატურაზე; 305 (ii) ნიმუშებთან წარმოდგენილი წყალი უნდა გახურდეს (50+5)0C ტემპერატურაზე და შეინარჩუნოს აღნიშნული ტემპერატურა 4 საათის განმავლობაში; (iii) შემდგომ ამისა განისაზღვრება წყლის აქტივობა; (iv) შემდეგ ნიმუშები უნდა შეინახოს მინიმუმ 7 დღე-ღამის განმავლობაში უძრავ ჰაერში არანაკლებ 300C ტემპერატურასა და არანაკლებ 90% ფარდობით ტენიანობაზე; (v) (ბ) 2.2.7.2.3.4 და ბოლოს (i), (ii) და (iii) ქვეპუნქტებში მითითებული პროცესი უნდა განმეორდეს თავიდან. აღნიშნულის ნაცვლად ჩატარებული მოცულობითი გაჟონვის შეფასება უნდა შედგებოდეს ნებისმიერი, კომპეტენტური ორგანოს მიერ დამტკიცებული ცდისგან, რომელიც გათვალისწინებულია ISO 9978:1992 სტანდარტში „რადიაციული დაცვა - დახურული რადიოაქტიური წყაროები - საერთო მოთხოვნები და კლასიფიკაცია“. დაბალდისპერსიული რადიოაქტიური მასალა 2.2.7.2.3.4.1 დაბალდისპერსიული რადიოაქტიური მასალის კონსტრუქცია საჭიროებს მრავალმხრივ დასტურს. დაბალდისპერსიული რადიოაქტიური მასალა უნდა იყოს იმ სახის, რომ აღნიშნული რადიოაქტიური მასალის რაოდენობა შეფუთვაში, 6.4.8.14 პუნქტში მოყვანილი დებულებების გათვალისწინებით, უნდა აკმაყოფილებდეს შემდეგ მოთხოვნებს: (ა) გამოსხივების დონე დაუცველი რადიოაქტიური მასალიდან 3 მეტრის მანძილზე არ აღემატება 10 მზვ/სთ-ს; (ბ) 6.4.20.3 და 6.4.20.4 პუნქტებში გათვალისწინებული ცდების განხორციელებისას, 10 მკმ-მდე აეროდინამიკური ეკვივალენტური დიამეტრის მქონე აიროვანი და დანაწევრებული ფორმების გამოშვება ატმოსფეროში არ აჭარბებს 100A2-ს. ყოველი ცდის შემთხვევაში შესაძლებელია გამოყენებულ იქნეს განცალკევებული ნიმუში; და (გ) 2.2.7.2.3.1.4 ქვეპუნქტში გათვალისწინებული ცდების განხორციელებისას, აქტივობა წყალში არ აღემატება 100A2-ს. აღნიშნული ცდის განხორციელებისას, ზემოაღნიშნულ (ბ) პუნქტში მოყვანილი ცდების დაზიანების ეფექტები მხედველობაში უნდა იქნეს მიღებული. 2.2.7.2.3.4.2 დაბალდისპერსიული რადიოაქტიური მასალის გამოცდა უნდა განხორციელდეს შემდეგნაირად: ნიმუშები, რომლებიც შეიცავს ან ახდენს სპეციალური ფორმის რადიოაქტიური მასალების იმიტირებას, უნდა დაექვემდებაროს 6.4.20.3 პუნქტში მოყვანილ გაძლიერებულ თერმულ ცდას და 6.4.20.4 პუნქტში მოყვანილ ცდა შეჯახებაზე. თითოეული ცდისთვის შესაძლებელია გამოყენებულ იქნეს სხვადასხვა ნიმუში. ყოველი ცდის შემდეგ ნიმუშმა უნდა გაიაროს 2.2.7.2.3.1.4 ქვეპუნქტში წარმოდგენილი გამოცდა გამოტუტვაზე. ყოველი ცდის შემდეგ უნდა განისაზღვროს დაკმაყოფილდა თუ არა 2.2.7.2.3.4.1 ქვეპუნქტში წარმოდგენილი მოთხოვნები. 306 2.2.7.2.3.4.3 იმ სამუშაო სტანდარტებთან, რომლებიც გათვალისწინებულია 2.2.7.2.3.4.1 და 2.2.7.2.3.4.2 ქვეპუნქტებში, შესაბამისობის დემონსტრირება უნდა მოხდეს 6.4.12.1 და 6.4.12.2 პუნქტების შესაბამისად. 2.2.7.2.3.5 გაყოფადი მასალა გაყოფადი მასალისა და გაყოფადი მასალის შემცველი შეფუთვების კლასიფიკაცია უნდა მოხდეს 2.2.7.2.1.1 ცხრილში წარმოდგენილ შესაბამის პოზიციაზე სახელწოდებით „გაყოფადი“, თუ ისინი არ დაექვემდებარება გამოთავისუფლებას ქვემოთ წარმოგენილი (ა) ქვეპუნქტიდან (ვ) ქვეპუნქტის ნებისმიერი მოთხოვნით და თუ მათი გადაზიდვა არ მოხდება 7.5.11 CV33 (4.3) პუნქტის მოთხოვნების თანახმად. ყველა დებულება მოქმედებს მხოლოდ იმ შეფუთვაში წარმოდგენილ მასალასთან დაკავშირებით, რომელიც პასუხობს 6.4.7.2 პუნქტით გათვალისწინებულ მოთხოვნებს, თუ აღნიშნული დებულება კონკრეტულად არ უშვებს შეუფუთავ მასალას. 2.2.7.2.3.6 (ა) ურანი, რომლითაც გამდიდრებულია ურანი-235 მასის მიხედვით მაქსიმუმ 1%-მდე, ხოლო პლუტონისა და ურანი-233-ის მაქსიმალური შემცველობა არ აღემატება ურანი-235-ის მასის 1%-ს იმ პირობით, რომ გაყოფადი ნუკლიდები ნაწილდება არსებითად ერთგვაროვნად მასალის ფარგლებში. გარდა ამისა, იმ შემთხვევაში, თუ ურანი წარმოდგენილია ლითონის, ოქსიდის ან კარბიდის ფორმით, მაშინ არ შეიძლება მისი განლაგება ბადისებრი სახით; (ბ) ურანილნიტრატის თხევადი ხსნარები, რომლითაც გამდიდრებულია ურანი235 მასის მიხედვით მაქსიმუმ 2%-მდე, ხოლო პლუტონისა და ურანი-233-ის მაქსიმალური შემცველობა არ აღემატება ურანის მასის 0,002%-ს, ხოლო აზოტის მინიმალური ატომური დამოკიდებულება ურანთან (N/U) შეადგენს 2ს; (გ) ურანი, რომლითაც გამდიდრებულია ურანი-235 მასის მიხედვით მაქსიმუმ 5%-მდე იმ პირობით, რომ: (i) ყოველ შეფუთვაში წარმოდგენილია არაუმეტეს 3.5 გრ ურანი-235; (ii) პლუტონისა და ურანი-233-ის მაქსიმალური შემცველობა არ აღემატება ურანი-235-ის მასის 1%-ს ყოველ შეფუთვაზე; (iii) შეფუთვების გადაზიდვა ექვემდებარება ქვეპუნქტით გათვალისწინებულ ზღვარს. 7.5.11 CV33 (4.3) (გ) (დ) ყოველ შეფუთვაზე არაუმეტეს 2.0 გრ საერთო მასის მქონე გაყოფადი ნუკლიდები იმ პირობით, თუ შეფუთვების გადაზიდვა ექვემდებარება 7.5.11 CV33 (4.3) (დ) ქვეპუნქტით გათვალისწინებულ ზღვარს; (ე) არაუმეტეს 45 გრ საერთო მასის მქონე, შეფუთული ან შეუფუთავი გაყოფადი ნუკლიდები ექვემდებარება 7.5.11 CV33 (4.3) (დ) ქვეპუნქტით გათვალისწინებულ ზღვარს; (ვ) გაყოფადი მასალა, რომელიც აკმაყოფილებს 7.5.11 CV33 (4.3) (ბ) ქვეპუნქტით, 2.2.7.2.3.6 ქვეპუნქტითა და 5.1.5.2.1 პუნქტით გათვალისწინებულ მოთხოვნებს. გაყოფადი მასალა, რომელიც არ არის კლასიფიცირებული, როგორც „გაყოფადი“ 2.2.7.2.3.5 (ვ) ქვეპუნქტის თანახმად, უნდა იყოს ქვეკრიტიკული შეგროვების კონტროლის საჭიროების გარეშე შემდეგ პირობებში: 307 2.2.7.2.4 (ა) 6.4.11.1 (ა) პუნქტით გათვალისწინებული პირობები; (ბ) პირობები, რომლებიც შეესაბამება 6.4.11.12(ბ) და 6.4.11.13 (ბ) ქვეპუნქტებით გათვალისწინებულ შეფასების დებულებებს შეფუთვებთან დაკავშირებით. შეფუთვებისა თუ შეუფუთავი მასალების კლასიფიკაცია ერთ შეფუთვაში წარმოდგენილი რადიოაქტიური მასალის რაოდენობა არ უნდა აღემატებოდეს შეფუთვის ტიპებთან დაკავშირებით დადგენილ შესაბამის ფარგლებს, როგორც ეს ქვემოთაა მითითებული. 2.2.7.2.4.1 გამოთავისუფლებული შეფუთვის კლასიფიკაცია 2.2.7.2.4.1.1 შეფუთვის კლასიფიცირება შესაძლებელია გამოთავისუფლებული შეფუთვის სახით იმ შემთხვევაში, თუ აკმაყოფილებს შემდეგ პირობებს: (ა) იგი წარმოადგენს რადიოაქტიური მასალის შემცველ ცარიელ შეფუთვებს; (ბ) იგი შეიცავს ხელსაწყოებსა თუ ნაკეთობებს შეზღუდული ოდენობით, როგორც ეს 2.2.7.2.4.1.2 ცხრილის (2) და (3) სვეტებშია მითითებული; (გ) იგი შეიცავს ბუნებრივი ურანისგან, გაღარიბებული ურანისა თუ ბუნებრივი თორიუმისგან დამზადებულ ნაკეთობებს; (დ) იგი შეიცავს რადიოაქტიურ მასალას იმ ოდენობით, რომელიც არ აღემატება 2.2.7.2.4.1.2 ცხრილის (4) სვეტში მითითებულ ზღვარს; ან (ე) იგი შეიცავს 0.1 კგ-ზე ნაკლებ ურანის ჰექსაფტორიდს, რაც არ აღემატება 2.2.7.2.4.1.2 ცხრილის (4) სვეტში მითითებულ ზღვარს. 2.2.7.2.4.1.2 რადიოაქტიური მასალის შეფუთვების კლასიფიცირება შესაძლებელია გამოთავისუფლებული შეფუთვის სახით იმ პირობით, რომ მისი გარე ზედაპირის ნებისმიერ წერტილში გამოსხივების დონე არ აღემატება 5მკსვ/სთ-ს. ცხრილი 2.2.7.2.4.1.2: აქტივობის საზღვრები გამოთავისუფლებულ შეფუთვებთან დაკავშირებით შემცველობის ფიზიკური მდგომარეობა (1) მყარი მასალები სპეციალური ფორმის სხვა ფორმის სითხეები აირები ტრიტიუმი სპეციალური ფორმის სხვა ფორმის ა ხელსაწყოები ან ნაკეთობები საგნის საზღვრებია შეფუთვის საზღვრებია (2) (3) მასალები შეფუთვის საზღვრები (4) 10-2 A1 10-2 A2 10-3 A2 A1 A2 10-1 A2 10-3 A1 10-3 A2 10-4 A2 2 x 10-2 A2 10-3 A1 10-3 A2 2 x 10-1 A2 10-2 A1 10-2 A2 2 x 10-2 A2 10-3 A1 10-3 A2 რადიონუკლიდების ნარევებთან დაკავშირებით იხილეთ 2.2.7.2.2.4-დან 2.2.7.2.2.6 პუნქტამდე. 2.2.7.2.4.1.3 რადიოაქტიური მასალა, რომელიც თან ერთვის ან წარმოდგენილია ხელსაწყოსა თუ სხვა საწარმოო ნაკეთობის შემადგენელი ნაწილის სახით, შესაძლებელია კლასიფიცირებულ იქნეს გაეროს ნომრით 2911 - რადიოაქტიური მასალა, 308 გამოთავისუფლებული შეფუთვა - ხელსაწყოები თუ ნაკეთობები, მხოლოდ იმ შემთხვევაში, თუ: (ა) გამოსხივების დონე ნებისმიერი შეუფუთავი ხელსაწყოსა თუ ნაკეთობის გარე ზედაპირის ნებისმიერი წერტილიდან 10 სმ-ში არ აღემატება 0.1 მსვ/სთ-ს; ან (ბ) ყოველი ხელსაწყო ან საწარმოო ნაკეთობა ატარებს „რადიოაქტიური“ მის გარე ზედაპირზე, გარდა შემდეგისა: (i) მარკირებას რადიოლუმინესცენციური საფარის მქონე საათები და მოწყობილობები; (ii) სამომხმარებლო საქონელი, რომლებთან დაკავშირებითაც გაცემულია მარეგულირებელი დამტკიცება 1.7.1.4(ე) პუნქტის თანახმად ან თითოეული მათგანი არ აჭარბებს 2.2.7.2.2.1 ცხრილში (მე-5 სვეტში) მითითებულ გამოთავისუფლებულ ტვირთთან დაკავშირებით დადგენილ აქტივობის ფარგლებს იმ პირობით, რომ აღნიშნული საქონლის გადაზიდვა ხორციელდება იმ შეფუთვაში, რომლის შიდა ზედაპირზე მითითებულია მარკირება „რადიოაქტიური“ იმ სახით, რომ შეფუთვის გახსნისას თვალსაჩინო იყოს გაფრთხილება მასში რადიოაქტიური მასალის არსებობის შესახებ; და (iii) სხვა ხელსაწყოები ან ნაკეთობები, რომლებიც საკმაოდ პატარა იმისათვის, რომ მათზე განთავსდეს მარკირება „რადიოაქტიური“, მარკირება არ მოითხოვება იმ პირობით, რომ თუ გადაზიდვა მოხდება შეფუთვაში, რომლის შიდა ზედაპირზე წარმოდგენილი იქნება მარკირება „რადიოაქტიური“ ისე, რომ რადიოაქტიური მასალის არსებობის შესახებ გაფრთხილება თვალსაჩინო იყოს შეფუთვის გახსნისას. (გ) აქტიური მასალა სრულად არის დაფარული არააქტიური კომპონენტებით (მოწყობილობა, რომლის ერთადერთი ფუნქციაა მის შიგნით რადიოაქტიური მასალის განთავსება, არ განიხილება ხელსაწყოსა თუ საწარმოო ნაკეთობის სახით); და (დ) 2.2.7.2.4.1.2 ცხრილის მე-2 და მე-3 სვეტებში გათვალისწინებული საზღვრები დაკმაყოფილებულია ყოველ ინდივიდუალურ საგანსა და, შესაბამისად, ყოველ შეფუთვასთან დაკავშირებით. 2.2.7.2.4.1.4 იმ სახით წარმოდგენილი რადიოაქტიური მასალა, რომელიც მითითებულია 2.2.7.2.4.1.3 ქვეპუნქტსა და ახასიათებს ისეთი აქტივობა, რომელიც არ აღემატება 2.2.7.2.4.1.2 ქვეპუნქტის მე-4 სვეტში გათვალისწინებულ ფარგლებს, შესაძლებელია კლასიფიცირებული იქნეს გაეროს ნომრით 2910 - რადიოაქტიური მასალა, გამოთავისუფლებული პაკეტი - მასალების შეზღუდული რაოდენობა იმ პირობით, რომ: (ა) შეფუთვამ შეინახოს მისი ჩვეულებრივ პირობებში; და (ბ) შეფუთვაზე წარმოდგენილი იყოს მარკირება „რადიოაქტიური“: (i) რადიოაქტიური შემცველობა გადაზიდვის შეფუთვის შიდა ზედაპირზე იმ სახით, რომ შეფუთვის გახსნისას თვალსაჩინო იყოს გაფრთხილება მასში რადიოაქტიური მასალის არსებობის შესახებ; ან 309 (ii) შეფუთვის გარე ზედაპირზე, თუ მარკირება შეფუთვის შიდა ზედაპირზე პრაქტიკულად შეუძლებელი იქნება. 2.2.7.2.4.1.5 ურანის ჰექსაფტორიდი, რომელიც არ აღემატება 2.2.7.2.4.1.2 ცხრილის მე-4 სვეტით გათვალისწინებულ ზღვარს, შესაძლებელია კლასიფიცირებული იქნეს გაეროს ნომრით 3507 ურანის ჰექსაფტორიდი, რადიოაქტიური მასალა, გამოთავისუფლებული შეფუთვა, 0.1 კგ-ზე ნაკლები შეფუთვაში, გაყოფადი ან გაყოფადი-გათავისუფლებული იმ პირობით, რომ: (ა) ურანის ჰექსაფტორიდის მასა შეფუთვაში 0.1 კგ-ზე ნაკლებია; (ბ) 2.2.7.2.4.5.1 და 2.2.7.2.4.1.4 (ა) და (ბ) ქვეპუნქტებით გათვალისწინებული პირობები დაცულია. 2.2.7.2.4.1.6 ბუნებრივი ურანისგან, გაღარიბებული ურანისა თუ ბუნებრივი თორიუმისგან დამზადებული ნაკეთობები და ის ნაკეთობები, რომლის ერთადერთ რადიოაქტიურ მასალას წარმოადგენს გამოუსხივებელი ბუნებრივი ურანი, გამოუსხივებელი გაღარიბებული ურანი ან გამოუსხივებელი ბუნებრივი თორიუმი, შესაძლებელია კლასიფიცირებულ იქნეს გაეროს ნომრით 2909 - რადიოაქტიური მასალა, გამოთავისუფლებული შეფუთვა - ბუნებრივი ურანისგან ან გაღარიბებული ურანისგან ან ბუნებრივი თორიუმისგან დამზადებული ნაკეთობები, იმ პირობით, თუ ურანისა თუ თორიუმის გარე ზედაპირი დაფარულია არააქტიური, ლითონისა თუ სხვა გამძლე მასალისგან დამზადებული გარსით. 2.2.7.2.4.1.7 ცარიელი შეფუთვა, რომელიც ადრე შეიცავდა რადიოაქტიურ მასალას, შესაძლებელია კლასიფიცირებულ იქნეს გაეროს ნომრით 2908 - რადიოაქტიური მასალა, გამოთავისუფლებული შეფუთვა - ცარიელი შეფუთვა, მხოლოდ იმ შემთხვევაში, თუ: (ა) ის იმყოფება გამართულ მდგომარეობაში და საიმედოდ არის დახურული; (ბ) ურანისა თუ თორიუმის შემცველი ნებისმიერი დეტალის გარე ზედაპირის მის კონსტრუქციაში დაფარულია არააქტიური, ლითონისა თუ სხვა გამძლე მასალისგან დამზადებული გარსით; (გ) შიდა ზედაპირის არაფიქსირებული რადიოაქტიური დაბინძურების დონე, როდესაც მისი გაშუალება ხდება ნებისმიერი 300 სმ2-ხე მეტად, არ აღემატება: (დ) 2.2.7.2.4.2 (i) 400 ბკ/სმ2-დ ბეტა- და გამა-გამომსხივარების შემთხვევაში და დაბალი ტოქსიკურობის მქონე ალფა-გამომსხივარების შემთხვევაში; და (ii) 40 ბკ/სმ2-ს ყველა დანარჩენი ალფა-გამომსხივარის შემთხვევაში; და ნებისმიერი უსაფრთხოების ნიშანი, რომლებიც შესაძლებელია გამოსახული ყოფილიყო მასზე 5.2.2.1.11.1 ქვეპუნქტის შესაბამისად, აღარ არის თვალსაჩინო. დაბალი კუთრი აქტივობის მქონე (LSA) მასალის კლასიფიკაცია რადიოაქტიური მასალის კლასიფიცირება შესაძლებელია LSA მასალის სახით მხოლოდ იმ შემთხვევაში, თუ ის შეესაბამება 2.2.7.1.3 პუნქტში გათვალისწინებულ LSA-ს განმარტებას და აკმაყოფილებს 2.2.7.2.3.1, 4.1.9.2 და 7.5.11 CV33 (2) ქვეპუნქტებში გათვალისწინებულ პირობებს. 2.2.7.2.4.3 რადიოაქტიურად დაბინძურებული ზედაპირის მქონე ობიექტის (SCO) კლასიფიკაცია 310 რადიოაქტიური მასალის კლასიფიცირება შესაძლებელია SCO სახით იმ შემთხვევაში, თუ ის შეესაბამება 2.2.7.1.3 პუნქტში გათვალისწინებულ SCO-ს განმარტებას და აკმაყოფილებს 2.2.7.2.3.2, 4.1.9.2 და 7.5.11 CV33 (2) ქვეპუნქტებში გათვალისწინებულ პირობებს. 2.2.7.2.4.4 A ტიპის შეფუთვის სახით კლასიფიკაცია რადიოაქტიური მასალის შემცველი შეფუთვების კლასიფიკაცია შესაძლებელია A ტიპის შეფუთვებად შემდეგი პირობების დაკმაყოფილების შემთხვევაში: A ტიპის შეფუთვები არ უნდა ითვალისწინებდეს შემდეგ მნიშვნელობაზე მაღალ აქტივობას: (ა) სპეციალური ფორმის რადიოაქტიური მასალის შემთხვევაში - A1; (ბ) ყველა დანარჩენი რადიოაქტიური მასალის შემთხვევაში - A2. რადიონუკლიდების ნარევებთან დაკავშირებით, რომელთა შემადგენლობა და შესაბამისი აქტივობა ცნობილია, A ტიპის შეფუთვის რადიოაქტიურ შემადგენლობასთან დაკავშირებით გამოყენებულ უნდა იქნეს შემდეგი ფორმულა: სადაც 2.2.7.2.4.5 B(j) წარმოადგენს სპეციალური ფორმის რადიოაქტიური მასალის სახით წარმოდგენილი i რადიონუკლიდის აქტივობას; A1(i) წარმოადგენს A1 მნიშვნელობას i რადიონუკლიდისთვის; C(j) წარმოადგენს იმ მასალის სახით წარმოდგენილი j რადიონუკლიდის აქტივობას, რომელიც არ წარმოადგენს სპეციალური ფორმის რადიოაქტიურ მასალას; A2(j) წარმოადგენს A2 მნიშვნელობას j რადიონუკლიდისთვის. ურანის ჰექსაფტორიდის კლასიფიკაცია 2.2.7.2.4.5.1 ურანის ჰექსაფტორიდი მიეკუთვნება მხოლოდ (ა) გაეროს ნომერს 2977 - რადიოაქტიური მასალა, ურანის ჰექსაფტორიდი, გაყოფადი; (ბ) გაეროს ნომერს 2978 - რადიოაქტიური მასალა, ურანის ჰექსაფტორიდი გაუყოფადი ან გაყოფადი-გამოთავისუფლებული; ან (გ) გაეროს ნომერს 3507 - ურანის ჰექსაფტორიდი, რადიოაქტიური მასალა, გამოთავისუფლებული შეფუთვა, 0.1 კგ-ზე ნაკლები შეფუთვაში, გაყოფადი ან გაყოფადი-გათავისუფლებული. 2.2.7.2.4.5.2 ურანის ჰექსაფტორიდის შემცველი შეფუთვები არ უნდა აკმაყოფილებდეს შემდეგ მოთხოვნებს: (ა) გაეროს №2977 შემთხვევაში, ურანის ჰექსაფტორიდის მასა არ უნდა იყოს განსხვავებული შეფუთვის კონსტრუქციისთვის ნებადართული მასისგან, ხოლო 311 გაეროს №3507 შემთხვევაში, ურანის ჰექსაფტორიდის მასა უნდა იყოს 0.1 კგ-ზე ნაკლები; 2.2.7.2.4.6 (ბ) ურანის ჰექსაფტორიდის მასას, რომელიც აღემატება იმ მნიშვნელობას, რომელიც უზრუნველყოფდა 5%-ზე ნაკლებ შეუვსებელ მოცულობას შეფუთვის მაქსიმალურ ტემპერატურაზე, რომლებიც გათვალისწინებულია იმ საწარმოოს სისტემებისთვის, სადაც გამოყენებულ უნდა იქნეს აღნიშნული შეფუთვები; ან (გ) ურანის ჰექსაფტორიდი, რომელიც არ არის წარმოდგენილი მყარ მდგომარეობაში ან გააჩნია ატმოსფერულ წნევაზე მაღალი შიდა წნევა, როდესაც ხდება მისი წარდგენა გადაზიდვებისთვის. კლასიფიკაცია B(U) ტიპის, B(M) ტიპისა თუ C ტიპის შეფუთვების სახით. 2.2.7.2.4.6.1 შეფუთვები, რომლებიც არ არის კლასიფიცირებული სხვა სახით 2.2.7.2.4 (2.2.7.2.4.1დან 2.2.7.2.4.2.5-მდე) ქვეპუნქტში, კლასიფიცირებულ უნდა იქნეს კომპეტენტური ორგანოს მიერ კონსტრუქციის წარმოშობის ქვეყანაში გაცემული შეფუთვის გადაზიდვებზე დაშვების მოწმობის შესაბამისად. 2.2.7.2.4.6.2 B(U) ტიპის, B(M) ტიპისა თუ C ტიპის შეფუთვის შიგთავსი უნდა პასუხობდეს გადაზიდვებზე დაშვების მოწმობაში გათვალისწინებულ მოთხოვნებს. 2.2.7.2.5 სპეციალური პირობები რადიოქტიული მასალის კლასიფიცირება უნდა მოხდეს, როგორც სპეციალურ პირობებში ტრანსპორტირებადი, როდესაც ის ექვემდებარება გადაზიდვას 1.7.4 პუნქტის შესაბამისად. 312 2.2.8 მე-8 კლასი 2.2.8.1 კრიტერიუმები 2.2.8.1.1 მე-8 კლასის სახელწოდება მოიცავს იმ ნივთიერებებსა და აღნიშნული კლასის ნივთიერებების შემცველ ნაკეთობებს, რომლებიც ქიმიური თვისებების წყალობით მოქმედებენ კანისა თუ ლორწოვანი გარსის ეპითელურ ქსოვილზე - მათთან შეხების ან მათი გაჟონვის შემთხვევაში, აღნიშნულ ნივთიერებებს შეუძლიათ ზიანი მიაყენონ ან გაანადგურონ სხვა ტვირთი ან ავტოსატრანსპორტო საშუალებები. აღნიშნული კლასის სახელწოდება ასევე მოიცავს სხვა ნივთიერებებსაც, რომლებიც წარმოქმნის კოროზიულ სითხეებს მხოლოდ წყლის არსებობისას ან რომლებიც წარმოქმნის კოროზიულ ორთქლსა თუ ნისლს ჰაერის ბუნებრივი ტენის არსებობისას. 2.2.8.1.2 მე-8 კლასის ნივთიერებები და ნაკეთობები იყოფა შემდეგნაირად: C1-C10 კოროზიული ნივთიერებები კოროზიული ნივთიერებები დამატებითი საშიშროების აღნიშნული ნივთიერებების შემცველი ნაკეთობები; C1-C4 და მჟავას თვისებების მქონე ნივთიერებები: C1 C2 C3 C4 C5-C8 გარეშე არაორგანული, თხევადი; არაორგანული, მყარი; ორგანული, თხევადი, ორგანული, მყარი; ძირითადი ნივთიერებები: C5 C6 C7 C8 არაორგანული, თხევადი; არაორგანული, მყარი; ორგანული, თხევადი, ორგანული, მყარი; C9-C10 ძირითადი ნივთიერებები: C9 C10 თხევადი; მყარი; C11 ნაკეთობები; CF კოროზიული ნივთიერებები, ადვილაალებადი: CF1 CF2 CS კოროზიული ნივთიერებები, თვითთბობადი: CS1 CS2 CW თხევადი; მყარი; კოროზიული ნივთიერებები, რომლებიც წყალთან შეხებისას გამოყოფენ ადვილაალებად აირებს; CW1 CW2 CO თხევადი; მყარი; თხევადი; მყარი; კოროზიული ნივთიერებები, მჟანგავი: 313 CO1 CO2 CT თხევადი; მყარი; კოროზიული ნივთიერებები, ტოქსიკური და აღნიშნული ნივთიერებების შემცველი ნაკეთობები CT1 CT2 CT3 თხევადი; მყარი; ნაკეთობები; CFT კოროზიული ნივთიერებები, ადვილაალებადი, თხევადი, ტოქსიკური; COT კოროზიული ნივთიერებები, მჟანგავი, ტოქსიკური. კლასიფიკაცია და შეფუთვის ჯგუფებზე მიკუთვნება 2.2.8.1.3 მე-8 კლასის ნივთიერებები კლასიფიცირდება სამ შეფუთვის ჯგუფად გადაზიდვების დროს მათ მიერ წარმოდგენილი საშიშროების ხარისხის მიხედვით: I შეფუთვის ჯგუფი ძლიერკოროზიული ნივთიერებები II შეფუთვის ჯგუფი: კოროზიული ნივთიერებები III შეფუთვის ჯგუფი: სუსტად კოროზიული ნივთიერებები 2.2.8.1.4 მე-8 კლასში კლასიფიცირებული ნივთიერებებისა და ნაკეთობების ჩამონათვალი წარმოდგენილია 3.2 თავის A ცხრილში. ნივთიერებების განაწილება I, II და III შეფუთვის ჯგუფებში განხორციელდა არსებული გამოცდილების საფუძველზე, ისეთი დამატებითი ფაქტორების გათვალისწინებით, როგორიცაა შესუნთქვის საშიშროება (იხილეთ 2.2.8.1.5 ქვეპუნქტი) და წყალთან რეაგირება (სახიფათო დაშლის პროდუქტების წარმოქმნის ჩათვლით). 2.2.8.1.5 ესა თუ ის ნივთიერება ან პრეპარატი, რომელიც აკმაყოფილებს მე-8 კლასით გათვალისწინებულ კრიტერიუმებს და რომლის ტოქსიკურობის ხარისხის მტვრისა და ნისლის (LC50) შესუნთქვის შემთხვევაში წარმოდგენილია I ჯგუფის შეფუთვასთან დაკავშირებულ ფარგლებში, ხოლო მისი ტოქსიკურობის ხარისხი - პერორალური გადაყლაპვის ან კანთან შეხებისას, წარმოდგენილია მხოლოდ III ან უფრო დაბალი შეფუთვის ჯგუფის ფარგლებში, უნდა განაწილდეს მე-8 კლასში. 2.2.8.1.6 ნივთიერებები, ნარევების ჩათვლით, რომლებიც არ არის მითითებული დასახელებით 3.2 თავის A ცხრილში, შესაძლებელია მიეკუთვნონ 2.2.8.3 პუნქტის შესაბამის პოზიციასა და შესაბამის შეფუთვის ჯგუფს იმ შეხების ხანგრძლივობის საფუძველზე, რაც აუცილებელია ადამიანის კანის სისქის სრული შრის დაზიანებისთვის ქვემოთ გათვალისწინებული (ა)-დან (გ) პუნქტებში მოყვანილი კრიტერიუმების შესაბამისად. სითხეები და ის მყარი ნივთიერებები, რომლებიც შესაძლებელია გახდეს თხევადი გადაზიდვების დროს, რომლებთან დაკავშირებითაც ითვლება, რომ არ გამოიწვევს ადამიანის კანის ფენის მთლიანი სისქის დაზიანებას, კვლავ უნდა იქნეს განხილული მათი პოტენციალის გამო, როგორც კოროზიის გამომწვევი გარკვეული ლითონის ზედაპირებზე. შეფუთვის ჯგუფის განსაზღვრისას, მხედველობაში უნდა იქნეს მიღებული გამოცდილება აღნიშნული ნივთიერებების ზემოქმედებასთან დაკავშირებით ადამიანებზე უბედური შემთხვევების დროს. იმ შემთხვევაში, თუ აღნიშნული გამოცდილება არ არის წარმოდგენილი, ჯგუფებში განაწილება უნდა მოხდეს OECD ცდების პრინციპების შესახებ სახელმძღვანელოს 4047 და 4358 314 შესაბამისად განხორციელებული ექსპერიმენტებიდან მიღებული მონაცემების საფუძველზე. ნივთიერება, რომელიც განისაზღვრა, რომ არ წარმოადგენს კოროზიულს OECD ცდების პრინციპების შესახებ სახელმძღვანელოს 4309 და 43110 შესაბამისად, შესაძლებელია მიჩნეულ იქნეს რომ არ ახდენს კოროზიულ ზემოქმედებას კანზე ADRის მიზნებთან დაკავშირებით შემდგომი გამოცდის გარეშე. (ა) I შეფუთვის ჯგუფი განისაზღვრება იმ ნივთიერებებთან დაკავშირებით, რომლებიც იწვევს დაუზიანებელი კანის ქსოვილის სრული სისქის დაზიანებას 60 წუთამდე დაკვირვების პერიოდის განმავლობაში, რომლის ათვლაც იწყება სამწუთიანი ან უფრო ნაკლები ხანგრძლივობის ზემოქმედების შემდეგ; (ბ) II შეფუთვის ჯგუფი განისაზღვრება იმ ნივთიერებებთან დაკავშირებით, რომლებიც იწვევს დაუზიანებელი კანის ქსოვილის სრული სისქის დაზიანებას 14 დღემდე დაკვირვების პერიოდის განმავლობაში, რომლის ათვლაც იწყება 3 წუთზე მეტი, მაგრამ არა უმეტეს 60 წუთის ხანგრძლივობის ზემოქმედების შემდეგ; (გ) III შეფუთვის ჯგუფი განისაზღვრება იმ ნივთიერებებთან დაკავშირებით, რომლებიც: - იწვევს დაუზიანებელი კანის ქსოვილის სრული სისქის დაზიანებას 14 დღემდე დაკვირვების პერიოდის განმავლობაში, რომლის ათვლაც იწყება 60 წუთზე მეტი, მაგრამ არა უმეტეს 4 საათის ხანგრძლივობის ზემოქმედების შემდეგ; ან - არ მიიჩნევა დაუზიანებელი კანის სრული სისქის დაზიანების გამომწვევად, თუმცა ავლენს კოროზიის სიჩქარეს ფოლადისა თუ ალუმინის ზედაპირებზე 6.25 მმ-ზე მეტად წელიწადში 550C საცდელ ტემპერატურაზე, როდესაც ხდება მისი გამოცდა ორივე მასალაზე. ფოლადის გამოსაცდელად გამოიყენება S235JR+CR (1.0037, შესაბამისად St 37-2), S275J2G3+CR (1.0144, შესაბამისად St 44-3) ტიპი, ISO 3574 სტანდარტი, ერთიანი ნუმერაციის სისტემა. შენიშვნა: იმ შემთხვევაში, თუ ფოლადსა თუ ალუმინზე ჩატარებული საწყისი ცდა მიუთითებს, რომ ცდაში გამოყენებული ნივთიერება წარმოადგენს კოროზიულს, მაშინ დამატებითი ცდის ჩატარება სხვა ლითონზე არ არის საჭირო. OECD დირექტივა ქიმიური ნივთიერებების გამოცდასთან დაკავშირებით N404, „კანის მწვავე გაღიზიანება/კოროზია“, 2002 წ. 8 OECD დირექტივა ქიმიური ნივთიერებების გამოცდასთან დაკავშირებით N435, „In Vitro მემბრანული ბარიერის ცდის მეთოდი კანის კოროზიისთვის“, 2006 წ. 9 OECD დირექტივა ქიმიური ნივთიერებების გამოცდასთან დაკავშირებით N430, „In Vitro კანის კოროზია: კანისმიერ ელექტრო რეზისტენტობაზე ცდა“, 2004 წ. 10 OECD დირექტივა ქიმიური ნივთიერებების გამოცდასთან დაკავშირებით N431, „In Vitro კანის კოროზია: ადამიანის კანის ნიმუშზე ცდა“, 2004 წ. 7 315 ცხრილი 2.2.8.1.6: 2.2.8.1.6 პუნქტში წარმოდგენილი კრიტერიუმების შემაჯამებელი ცხრილი შეფუთვის ჯგუფი I II III III 2.2.8.1.7 გამოვლენის დრო <3 წთ >3წთ <1 სთ >1სთ <4 სთ - დაკვირვების დრო <60 წთ <14 დღე <14 დღე - ეფექტი დაუზიანებელი კანის სრული სისქის დაზიანება დაუზიანებელი კანის სრული სისქის დაზიანება დაუზიანებელი კანის სრული სისქის დაზიანება კოროზიის სიჩქარე როგორც ფოლადის, ასევე ალუმინის ზედაპირებზე აღემატება 6.25 მმ-ს წელიწადში 550C საცდელ ტემპერატურაზე, როდესაც ხდება მისი გამოცდა ორივე მასალაზე იმ შემთხვევაში, თუ დანამატების შეტანის შემდეგ მე-8 კლასის ნივთიერებები მოხვდება საშიშროებების სხვადასხვა კატეგორიაში, რომლებიც განსხვავდება ის საშიშროებების კატეგორიებისგან, რომელთაც მიეკუთვნებათ 3.2 თავის A ცხრილში სახელწოდებით მითითებული ნივთიერებები, აღნიშნული ნარევებისა თუ ნივთიერებების მიკუთვნება უნდა მოხდეს იმ პოზიციებზე, რომელსაც ისინი განეკუთვნებიან მათი საშიშროების ფაქტიური ხარისხის საფუძველზე. შენიშვნა: ხსნარებისა და ნარევების (როგორიცაა პრეპარატები და ნარჩენები) კლასიფიკაციასთან დაკავშირებით, იხილეთ 2.1.3 პუნქტი. 2.2.8.1.8 2.2.8.1.6 ქვეპუნქტით გათვალისწინებული კრიტერიუმების საფუძველზე, შესაძლებელია აგრეთვე განისაზღვროს წარმოადგენს თუ არა ნებისმიერი ნივთიერებისა თუ ნარევის თვისებები, რომლებიც მითითებულია დასახელებით ან შეიცავს სახელწოდებით მითითებულ ნებისმიერ ნივთიერებას, იმ სახის, რომ აღნიშნულ ხსნარსა თუ ნარევზე არ გავრცელდეს ამ კლასთან დაკავშირებით დადგენილი მოთხოვნები. 2.2.8.1.9 ნივთიერებები, ხსნარები და ნარევები, რომლებიც - ვერ აკმაყოფილებს 67/548/EEC3 ან 1999/45/EC4 დირექტივების, მათში შეტანილ ცვლილებებთან ერთად, კრიტერიუმებს და ამის გამო არაა კლასიფიცირებული, როგორც კოროზიული აღნიშნული დირექტივების, მათში შეტანილ ცვლილებებთან ერთად, შესაბამისად; და - არ ავლენს კოროზიულ ზემოქმედებას ფოლადსა თუ ალუმინზე; შესაძლებელია განხილულ იქნეს, როგორც ნივთიერებები, რომლებიც არ მიეკუთვნება მე-8 კლასს. საბჭოს 1967 წლის 27 ივნისის 67/548/EEC დირექტივა სახიფათო ნივთიერებების კლასიფიკაციასთან, შეფუთვასა და მარკირებასთან დაკავშირებულ კანონებთან, განაწესებსა და ადმინისტრაციულ დებულებებთან მიახლოვების შესახებ (ევროპული გაერთიანების ოფიციალური ჟურნალი №L196, 16.08.1967 წ). 4 ევროპარლამენტისა და საბჭოს 1999 წლის 31 მაისის 1999/45/EC დირექტივა სახიფათო პრეპარატების კლასიფიკაციასთან, შეფუთვასა და მარკირებასთან დაკავშირებული წევრი სახელმწიფოების შესახებ კანონებთან, განაწესებსა და ადმინისტრაციულ დებულებებთან მიახლოების შესახებ (ევროპული გაერთიანების ოფიციალური ჟურნალი №L200, 1999 წლის 30 ივლისი). 3 316 შენიშვნა: გაეროს ტიპიურ წესებში გათვალისწინებული გაეროს N1910 - კალციუმის ჟანგი და გაეროს N2812 - ნატრიუმის ალუმინატი, არ ექვემდებარება ADR-ის დებულებებს. 2.2.8.2 ნივთიერებები, რომლებიც არ დაიშვება გადაზიდვებზე 2.2.8.2.1 მე-8 კლასით გათვალისწინებული ქიმიურად არასტაბილური ნივთიერებები არ დაიშვება გადაზიდვებზე, სანამ არ განხორციელდება შესაბამისი ზომები მათი სახიფათო დაშლისა თუ პოლიმერიზაციის პრევენციის მიზნით გადაზიდვების დროს. აღნიშნულიდან გამომდინარე, უნდა მოხდეს იმ ფაქტის უზრუნველყოფა, რომ ჭურჭელი და ცისტერნები არ შეიცავდეს აღნიშნული რეაქციების გამომწვევ რაიმე ნივთიერებას. 2.2.8.2.2 შემდეგი ნივთიერებები და ნარევები არ დაიშვება გადაზიდვებზე: - გაეროს N1798 - აზოტისა და ქლორწყალბადის ნარევის მჟავა; - დამუშავებული გოგირდმჟავას ქიმიურად არასტაბილური ნარევები; - ნიტრირებული მჟავის ქიმიურად არასტაბილური ნარევები ან ნარჩენი გოგირდმჟავისა თუ აზოტმჟავის დენიტრირებული ნარევები; - მასის მიხედვით 72%-ზე მეტი სუფთა მჟავის შემცველი ქლორმჟავას წყლიანი ხსნარი ან ქლორმჟავას ნარევები ნებისმიერ სხვა სითხესთან, გარდა წყლისა. 317 2.2.8.3 ერთობლივი პოზიციების ჩამონათვალი კოროზიული ნივთიერებები დამატებითი რისკის გარეშე თხევადი C1 არაორგანული მყარი C2 მჟავა C1-C4 თხევადი C3 ორგანული მყარი C4 თხევადი C5 არაორგანული მყარი C6 თხევადი C7 ძირითადი C5-C8 ორგანული მყარი C8 თხევადი C9 სხვა კოროზიული ნივთიერებები C9-C10 მყარია ნაკეთობები C11 (გაგრძელება მომდევნო გვერდზე) C10 2584 2584 2693 2837 3264 ალკილსულფონმჟავები, თხევადი, 5%-ზე მეტი თავისუფალი გოგირდმჟავით, ან არილსულფონმჟავები, თხევადი, 5%-ზე მეტი თავისუფალი გოგირდმჟავით ბისულფიტები, წყალხსნარი, N.O.S. ბისულფატები, წყალხსნარი კოროზიული თხევადი ნივთიერება, მჟავური, არაორგანული, N.O.S. 1740 2583 2583 3260 ჰიდროდიფტორიდები, მყარი, N.O.S. ალკილსულფონმჟავები, მყარი, 5%-ზე მეტი თავისუფალი გოგირდმჟავით, ან არილსულფონმჟავები, მყარი, 5%-ზე მეტი თავისუფალი გოგირდმჟავით კოროზიული მყარი ნივთიერება, მჟავური, არაორგანული, N.O.S. 2586 2586 2987 3145 3265 ალკილსულფონმჟავები, თხევადი, არაუმეტეს 5% თავისუფალი გოგირდმჟავით, ან არილსულფონმჟავები, თხევადი, არაუმეტეს 5% თავისუფალი გოგირდმჟავით ქლორსილანები, კოროზიული, N.O.S. ალკილფენოლები, თხევადი, N.O.S. (C2-C12 ჰომოლოგების ჩათვლით) კოროზიული თხევადი ნივთიერება, მჟავური, ორგანული, N.O.S. 2430 2585 2585 3261 ალკილფენოლები, მყარი, N.O.S. (C2-C12 ჰომოლოგების ჩათვლით) ალკილსულფონმჟავები, მყარი, არაუმეტეს 5% თავისუფალი გოგირდმჟავით, ან არილსულფონმჟავები, მყარი, არაუმეტეს 5% თავისუფალი გოგირდმჟავით კოროზიული მყარი ნივთიერება, მჟავური, ორგანული, N.O.S. 1719 2797 3266 მწვავე ტუტოვანი სითხე, N.O.S. ბატარეის სითხე, ტუტე კოროზიული სითხე, ძირითადი, არაორგანული, N.O.S. 3262 კოროზიული მყარი ნივთიერება, ძირითადი, არაორგანული, N.O.S. 2735 2735 3267 ამინები, თხევადი, კოროზიული, N.O.S. ან პოლიამინები, თხევადი, კოროზიული, N.O.S. კოროზიული თხევადი ნივთიერება, ძირითადი, ორგანული, N.O.S. 3259 3259 3263 ამინები, მყარი, კოროზიული, N.O.S. ან პოლიამინები, მყარი, კოროზიული, N.O.S. კოროზიული მყარი ნივთიერება, ძირითადი, ორგანული, N.O.S. 1903 2801 2801 3066 3066 1760 სადეზინფექციო საშუალება, თხევადი, კოროზიული, N.O.S. საღებავი, თხევადი, კოროზიული, N.O.S. საღებავის ნახევარპროდუქტი, თხევადი, კოროზიული, N.O.S. საღებავი (რაც მოიცავს საღებავს, ლაქს, ემალს, საღებავ ნივთიერებას, შელაკს, გასალაქ, მოსაპრიალებელ მასალას, თხევად შემავსებელსა და თხევადი ლაქის ბაზას) ან შესაღები მასალა (რაც მოიცავს საღებავის გამხსნელ ან შემამცირებელ ნარევს) კოროზიული თხევადი ნივთიერება, N.O.S. 3147 3147 3244 1759 საღებავი, მყარი, კოროზიული, N.O.S. ან საღებავის ნახევარპროდუქტი, მყარი, კოროზიული, N.O.S. კოროზიული სითხის შემცველი მყარი ნივთიერებები, N.O.S. კოროზიული მყარი ნივთიერება, N.O.S. 2794 2795 2800 3028 1774 2028 3477 3477 ბატარეები, სველი, შევსებული მჟავით, განკუთვნილი ელექტრო აკუმულატორისთვის ბატარეები, სველი, შევსებული ტუტით, განკუთვნილი ელექტრო აკუმულატორისთვის ბატარეები, სველი, არა-გადაღვრადი, განკუთვნილი ელექტრო აკუმულატორისთვის ბატარეები, მშრალი, შეიცავს კალიუმის ჰიდროჟანგს, მყარს, განკუთვნილი ელექტრო აკუმულატორისთვის ცეცხლმაქრის მუხტები, კოროზიული სითხე ბომბები, კვამლსადენი, არაფეთქებადი, კოროზიულ სითხესთან ერთად, მაინიცირებელი მოწყობილობის გარეშე საწვავი ელემენტების ბალონები, რომელიც შეიცავს კოროზიულ ნივთიერებებს; ან აღჭურვილობაში წარმოდგენილი საწვავი ელემენტების ბალონები, რომელიც შეიცავს კოროზიულ ნივთიერებებს; ან აღჭურვილობასთან ერთად შეფუთული საწვავი ელემენტების ბალონები, რომელიც შეიცავს კოროზიულ ნივთიერებებს 3477 მყარი ნივთიერებების ნარევები, რომლებიც არ ექვემდებარება ADR-ის დებულებებს, ასევე კოროზიული ნივთიერებების ნარევები შესაძლებელია გადატანილ იქნეს გაეროს ნომრით 3244 ისე, რომ არ დაექვემდებაროს მე-8 კლასით გათვალისწინებულ კლასიფიკაციის კრიტერიუმებს იმ პირობით, რომ ნივთიერების დატვირთვისა თუ ტარის, კონტეინერისა თუ სატრანსპორტო ერთეულის დახურვის დროისთვის არ იქნება წარმოდგენილი თავისუფალი, ხილული სითხე. ყოველი ტარა უნდა აკმაყოფილებდეს იმ კონსტრუქციის ტიპს, რომელმაც გაიარა გამოცდა ჰერმეტულობაზე II შეფუთვის ჯგუფთან დაკავშირებით. ა 318 კოროზიული ნივთიერებები დამატებითი რისკ(ებ)ის გარეშე (გაგრძელება) 3470 2734 2734 2986 2920 საღებავი, კოროზიული, ადვილაალებადი (რაც მოიცავს საღებავს, ლაქს, ემალს, საღებავ ნივთიერებას, შელაკს, გასალაქ, მოსაპრიალებელ მასალას, თხევად შემავსებელსა და თხევადი ლაქის ბაზას) ან შესაღები მასალა, კოროზიული, ადვილაალებადი (რაც მოიცავს საღებავის გამხსნელ ან შემამცირებელ ნარევს) ამინები, თხევადი, კოროზიული, ადვილაალებადი, N.O.S. ან პოლიამინები, თხევადი, კოროზიული, ადვილაალებადი, N.O.S. ქლორსილანები, კოროზიული, ადვილაალებადი, N.O.S. კოროზიული თხევადი ნივთიერება, ადვილადდაალებადი, N.O.S. 2921 კოროზიული მყარი ნივთიერება, ადვილაალებადი, N.O.S. თხევადი CS1 3301 კოროზიული თხევადი ნივთიერება, თვითმთბობი, N.O.S. მყარი 3095 კოროზიული მყარი ნივთიერება, თვითმთბობი, N.O.S. 3094 კოროზიული თხევადი ნივთიერება, წყალზე რეაგირებადი N.O.S. 3096 კოროზიული მყარი ნივთიერება, წყალზე რეაგირებადი, N.O.S. 3093 კოროზიული თხევადი ნივთიერება, მჟანგავი, N.O.S. 3084 კოროზიული მყარი ნივთიერება, მჟანგავი, N.O.S. 3471 2922 ჰიდროფტორიდების ხსნარი, N.O.S. კოროზიული თხევადი ნივთიერება, ტოქსიკური, N.O.S. 2923 კოროზიული მყარი ნივთიერება, ტოქსიკური, N.O.S. 3506 ვერცხლისწყალი, რომელსაც შეიცავს საწარმოო ნაკეთობები თხევადი CF1 3470 ადვილაალებადიბ CF მყარი თვითმთბობი CS CF2 CS2 თხევადიბ CW1 წყალზე რეაგირებადი CW მყარი CW2 თხევადი CO1 მჟანგავი CO მყარი CO2 თხევადიე CT1 ტოქსიკური CT დ მყარიე CT2 ნაკეთობები CT3 ადვილაალებადი, თხევადი, ტოქსიკურიდ CFT მჟანგავი, ტოქსიკურიდ, ე COT აღნიშნული კლასიფიკაციის კოდით არ არის წარმოდგენილი რაიმე სხვა ერთობლივი პოზიცია; საჭიროების შემთხვევაში კლასიფიკაცია ამა თუ იმ ერთობლივ პოზიციაზე რომელიმე კლასიფიკაციის კოდით განისაზღვრება 2.1.3.10 პუნქტში გათვალისწინებული საშიშროებების პრიორიტეტულობის ცხრილის შესაბამისად აღნიშნული კლასიფიკაციის კოდით არ არის წარმოდგენილი რაიმე სხვა ერთობლივი პოზიცია; საჭიროების შემთხვევაში კლასიფიკაცია ამა თუ იმ ერთობლივ პოზიციაზე რომელიმე კლასიფიკაციის კოდით განისაზღვრება 2.1.3.10 პუნქტში გათვალისწინებული საშიშროებების პრიორიტეტულობის ცხრილის შესაბამისად ქლორსილანები, რომლებიც წყალთან ან ნესტიან ჰაერთან შეხებისას გამოყოფს ადვილაალებად აირებს, წარმოადგენს 4.3 კლასის ნივთიერებებს. გ უპირატესად ტოქსიკური თვისებების მქონე ქლორფორმიატები წარმოადგენს 6.1 კლასის ნივთიერებებს. დ კოროზიული ნივთიერებები, რომლებისთვისაც დამახასიათებელია ძლიერტოქსიკურობა ინჰალაციისას, როგორც ეს განსაზღვრულია 2.2.61.1.4-დან 2.2.61.1.9 პუნქტებში, წარმოადგენს 6.1 კლასის ნივთიერებებს. ე გაეროს N2505 - ამონიუმის ფტორიდი, გაეროს N1812 - კალიუმის ფტორიდი, მყარი, გაეროს N1690 ნატრიუმის ფტორიდი, მყარი, გაეროს N2674 - ნატრიუმის ფტორსილიკატი, გაეროს N2856 ფტორსილიკატები N.O.S. გაეროს N3415 - ნატრიუმის ფტორიდის ხსნარი და გაეროს N3422 - კალიუმის ფტორიდის ხსნარი წარმოადგენენ 6.1 კლასის ნივთიერებებს. ბ 319 2.2.9 მე-9 კლასი სხვადასხვა სახიფათო ნივთიერებები და ნაკეთობები 2.2.9.1 კრიტერიუმები 2.2.9.1.1 მე-9 კლასის სახელწოდებაში შედის ის ნივთიერებები და ნაკეთობები, რომლებიც, გადაზიდვის დროს, წარმოადგენს ისეთ საშიშროებას, რომელიც არ არის გათვალისწინებული სხვა კლასების სახელწოდებაში. 2.2.9.1.2 მე-9 კლასის ნივთიერებები და ნაკეთობები იყოფა შემდეგნაიორად: M1 ნივთიერებები, რომლებმაც წვრილი მტვრის შესაძლებელია შეუქმნას საფრთხე ჯანმრთელობას; სახით შესუნთქვისას, M2 ნივთიერებები და აპარატურა, რომლებმაც შესაძლებელია წარმოქმნას დიოქსინები; ხანძრის შემთხვევაში, M3 ნივთიერებები, რომლებიც გამოჰყოფს ადვილაალებად ორთქლს; M4 ლითიუმის ბატარეები; M5 სამაშველო მოწყობილობები; M6-M8 გარემოსთვის სახიფათო ნივთიერებები: M6 M7 M8 წყლის გარემოს გამაბინძურებელი ნივთიერებები, თხევადი; წყლის გარემოს გამაბინძურებელი ნივთიერებები, მყარი; გენეტიკურად მოდიფიცირებული მიკროორგანიზმები ორგანიზმები; და M9-M10 ნივთიერებები მომატებულ ტემპერატურაზე: M9 თხევადი ნივთიერებები; M10 მყარი ნივთიერებები; M11 სხვა ნივთიერებები, რომლებიც წარმოადგენს საშიშროებას გადაზიდვების განმავლობაში, თუმცა ვერ აკმაყოფილებს სხვა კლასთან დაკავშირებულ განმარტებებს. განმარტებები და კლასიფიკაცია 2.2.9.1.3 მე-9 კლასში კლასიფიცირებული ნივთიერებებისა და ნაკეთობების ჩამონათვალი წარმოდგენილია 3.2 თავის A ცხრილში. იმ ნივთიერებებისა და ნაკეთობების მიკუთვნება, რომლებიც არ არის მითითებული სახელწოდებით 3.2 თავის A ცხრილში აღნიშნული ცხრილისა თუ 2.2.9.3 პუნქტის შესაბამის პოზიციაზე, უნდა განხორციელდეს ქვემოთ წარმოდგენილი 2.2.9.1.4-დან 2.2.9.1.14 ქვეპუნქტების შესაბამისად. ნივთიერებები, რომლებიც წვრილი მტვრის სახით შესუნთქვისას, საფრთხეს უქმნის ჯანმრთელობას 2.2.9.1.4 ის ნივთიერებები, რომლებიც წვრილი მტვრის სახით შესუნთქვისას, საფრთხეს უქმნის ჯანმრთელობას, მოიცავს აზბესტსა და აზბესტის შემცველ ნარევებს. ნივთიერებები და აპარატურა, რომლებმაც ხანძრის შემთხვევაში შესაძლებელია წარმოქმნას დიოქსინები 320 2.2.9.1.5 ის ნივთიერებები და აპარატურა, რომლებმაც ხანძრის შემთხვევისას შესაძლებელია წარმოქმნან დიოქსინები, მოიცავენ პოლიქლორირებულ ბიფენილებს (პქბ) და ტერფენილებს (პქტ), ასევე პოლიჰალოგენირებულ ბიფენილებსა და ტერფენილებს და აღნიშნული ნივთიერებების შემცველ ნარევებს, ასევე აღნიშნული ნივთიერებებისა და ნარევების შემცველი აპარატურა, როგორიცაა ტრანსფორმატორები, კონდენსატორები და მოწყობილობები. შენიშვნა: ADR-ის დებულებები არ ვრცელდება იმ ნარევებზე, რომლებიც შეიცავს არაუმეტეს 50 მგ/კგ პოლიქლორირებულ ბიფენილსა თუ ტერფენილს. ნივთიერებები, რომლებიც გამოყოფს ადვილაალებად ორთქლს 2.2.9.1.6 ადვილაალებადი ორთქლის გამომყოფი ნივთიერებები შეიცავს ადვილაალებადი სითხეების შემცველ პოლიმერებს, რომელთა აფეთქების ტემპერატურა არ აღემატება 550C-ს. ლითიუმის ბატარეები 2.2.9.1.7 ელემენტებსა და ბატარეებს, აღჭურვილობაში წარმოდგენილ ელემენტებსა და ბატარეებს ან აღჭურვილობასთან ერთად შეფუთულ ელემენტებსა და ბატარეებს, რომლებიც შეიცავს ლითიუმს ნებისმიერი ფორმით, შესაძლებელია მიენიჭოთ გაეროს №3090, 3091, 3480 ან 3481, კონკრეტული შემთხვევიდან გამომდინარე. მათი გადაზიდვა შესაძლებელია განხორციელდეს მოცემულ პოზიციებზე იმ შემთხვევაში, თუ ისინი პასუხობენ შემდეგ დებულებებს: (ა) ყოველი ელემენტი ან ყოველი ბატარეა არის იმ ტიპის, რომელთან დაკავშირებითაც დამტკიცებულია, რომ აკმაყოფილებს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 38.3 ქვეპუნქტით გათვალისწინებული ყოველი გამოცდის მოთხოვნებს; შენიშვნა: ბატარეები უნდა იყოს იმ ტიპის, რომელთან დაკავშირებითაც დამტკიცებულია, რომ აკმაყოფილებს ცდებისა და კრიტერიუმების სახელმძღვანელოს III ნაწილის 38.3 ქვეპუნქტით გათვალისწინებული ყოველი გამოცდის მოთხოვნებს იმის მიუხედავად, არის თუ არა მათ შემადგენლობაში შემავალი ელემენტების ტიპი დამტკიცებული. (ბ) ყოველი ელემენტი და ყოველი ბატარეა შეიცავს უსაფრთხოების სავენტილაციო მოწყობილობას ან არის კონსტრუირებული იმ სახით, რომ გამორიცხოს დაზიანების შესაძლებლობა გადაზიდვის ჩვეულებრივ პირობებში; (გ) ყოველი ელემენტი და ყოველი ბატარეა აღჭურვილია გარეშე მოკლე შერთვის თავიდან აცილების ეფექტური საშუალებებით; (დ) ელემენტების ან პარალელურად დაკავშირებული რიგი ელემენტების შემცველი ყოველი ბატარეა აღჭურვილია ეფექტური საშუალებებით, რომლებიც აუცილებელია სახიფათო უკუნაკადის (მაგალითად, დიოდების, დნობადი მცველების და ა.შ.) თავიდან ასაცილებლად; (ე) ელემენტები და ბატარეები უნდა დამზადდეს ხარისხის მართვის პროგრამის შესაბამისად, რომელიც ითვალისწინებს შემდეგს: 321 (i) პერსონალის საორგანიზაციო სტრუქტურისა და პასუხისმგებლობის აღწერილობა კონსტრუირებისა და პროდუქციის წარმოების ხარისხთან დაკავშირებით; (ii) შესაბამისი ინსტრუქციები შემოწმებასა და გამოცდასთან, ხარისხის კონტროლთან, ხარისხის გარანტიასა და ტექნოლოგიურ პროცესებთან დაკავშირებით, რომლებიც იქნება გამოყენებული; (iii) ტექნოლოგიური კონტროლის პროცედურები, რომლებიც უნდა ითვალისწინებდეს შესაბამის ღონისძიებებს ელემენტების წარმოების პროცესში მოკლე შერთვის შემთხვევების პრევენციისთვის; (iv) ხარისხის შესახებ მონაცემების რეგისტრაცია, მაგალითად, შემოწმების ანგარიშების, გამოცდის შესახებ მონაცემების, დაკალიბრების მონაცემებისა და მოწმობების სახით. გამოცდის შესახებ მონაცემები უნდა იქნეს დაცული და წარდგენილი კომპეტენტური ორგანოს მიმართ მისი მოთხოვნისამებრ; (v) ხელმძღვანელობის მიერ მიმოხილვა ხარისხის მართვის პროგრამების ეფექტური შესრულების უზრუნველყოფის მიზნით; (vi) დოკუმენტაციის კონტროლისა და მათი მიმოხილვის პროცესი; (vii) იმ ელემენტებისა და ბატარეების შემოწმების საშუალებები, რომლებიც არ აკმაყოფილებს ზემოაღნიშნული (ა) ქვეპუნქტის თანახმად გამოცდილ ტიპს; (viii) პროფესიული მომზადების პროგრამები და კვალიფიკაციის ამაღლების პროცედურები შესაბამისი პერსონალისთვის; და (ix) საბოლოო პროდუქტთან დაკავშირებით დაზიანების არარსებობის უზრუნველყოფის პროცედურები. შენიშვნა: შესაძლებელია მიღებულ იქნეს შიდა ხარისხის მართვის პროგრამები. მესამე მხარეების სერტიფიცირება არ მოითხოვება, თუმცა ზემოაღნიშნული (i)(ix) ქვეპუნქტებში ჩამოთვლილი პროცედურები ჯეროვნად უნდა იქნეს რეგისტრირებული და შესრულებული. აღნიშნული ხარისხის მართვის პროგრამის ერთი ასლი უნდა გადაეცეს კომპეტენტურ ორგანოს მისი მოთხოვნისთანავე. ლითიუმის ბატარეები არ ექვემდებარება ADR-ით გათვალისწინებულ დებულებებს იმ შემთხვევაში, თუ ისინი აკმაყოფილებს 3.3 თავის 188-ე სპეციალური დებულებით გათვალისწინებულ მოთხოვნებს. შენიშვნა: პოზიცია - გაეროს №3171 - ბატარეებზე მომუშავე ავტოსატრანსპორტო საშუალება ან გაეროს №3171 - ბატარეებზე მომუშავე აღჭურვილობა, გამოიყენება მხოლოდ იმ სატრანსპორტო საშუალებებთან დაკავშირებით, რომლებიც მუშაობს მხოლოდ თხევადი ელემენტების ბატარეებზე, ნატრიუმის ბატარეებზე, ლითიუმის ლითონის ბატარეებზე ან ლითიუმის იონის ბატარეებზე, ასევე იმ აღჭურვილობებთან დაკავშირებით, რომლებიც მუშაობს თხევადი ელემენტების ბატარეებზე ან ნატრიუმის ბატარეებზე, რომლის გადაზიდვაც ხდება მათზე უკვე დამონტაჟებული აღნიშნული სახის ბატარეებთან ერთად. 322 წინამდებარე გაეროს ნომრით გათვალისწინებული მიზნებისთვის, სატრანსპორტო საშუალებები წარმოადგენს თვითმავალ მოწყობილობას, რომელიც გათვალისწინებულია ერთი ან ერთზე მეტი ადამიანის გადასაყვანად ან ტვირთის გადასაზიდად. აღნიშნული სატრანსპორტო საშუალების მაგალითებს წარმოადგენს ელექტროავტომობილები, მოტოციკლები, სკუტერები, სამ- და ოთხთვლიანი სატრანსპორტო საშუალებები ან მოტოციკლები, ელექტროველოსიპედები, ინვალიდის ეტლები, ბაღის ტრაქტორები, ნავები და საფრენი აპარატები. აღჭურვილობის მაგალითებია გაზონის საკრეჭი მანქანები, საწმენდი მანქანები ან ნავების ან საჰაერო ხომალდების მაკეტები. აღჭურვილობა, რომელიც მუშაობს ლითიუმის ლითონის ბატარეებზე ან ლითიუმის იონის ბატარეებზე, ექვემდებარება გადაზიდვას გაეროს ნომრით 3091 - ლითიუმის ლითონის ბატარეები, წარმოდგენილი აღჭურვილობაში ან გაეროს ნომრით 3091 - ლითიუმის ლითონის ბატარეები, შეფუთული აღჭურვილობასთან ერთად ან გაეროს ნომრით 3481 - ლითიუმის იონის ბატარეები წარმოდგენილი აღჭურვილობაში ან გაეროს ნომრით 3481 - ლითიუმის იონის ბატარეები, შეფუთული აღჭურვილობასთან ერთად, კონკრეტული შემთხვევიდან გამომდინარე. ჰიბრიდული ელექტრომობილები, რომლებთან დაკავშირებითაც გამოიყენება როგორც შიგა წვის ძრავი, ასევე თხევადი ელემენტების ბატარეები, ნატრიუმის ბატარეები, ლითიუმის ლითონის ბატარეები ან ლითიუმის იონის ბატარეები, და რომელთა გადაყვანაც ხორციელდება დამონტაჟებულ ბატარეებთან ერთად, კლასიფიცირებული უნდა იქნეს გაეროს ნომრით 3166 – ადვილაალებად აირზე მომუშავე ავტოსატრანსპორტო საშუალება ან გაეროს ნომრით 3166 - ადვილაალებად სითხეზე მომუშავე ავტოსატრანსპორტო საშუალება, კონკრეტული შემთხვევიდან გამომდინარე. სატრანსოორტო საშუალებები, რომლებიც შეიცავს საწვავ ელემენტს, კლასიფიცირებული უნდა იქნეს გაეროს ნომრით 3166 - ადვილაალებადი აირის შემცველ საწვავ ელემენტებზე მომუშავე ავტოსატრანსპორტო საშუალება ან გაეროს ნომრით 3166 - ადვილაალებადი სითხის შემცველ საწვავ ელემენტებზე მომუშავე ავტოსატრანსპორტო საშუალება, კონკრეტული შემთხვევიდან გამომდინარე. სამაშველო მოწყობილობები 2.2.9.1.8 სამაშველო მოწყობილობები ითვალისწინებს სამაშველო მოწყობილობებსა და ავტოსატრანსპორტო საშუალებების კომპონენტებს, რომლებიც შეესაბამება 3.3 თავის 235-ე ან 296-ე სპეციალური დებულებებით გათვალისწინებულ აღწერილობებს. გარემოსთვის სახიფათო ნივთიერებები 2.2.9.1.9 (ამოღებულია) წყლის გარემოს გამაბინძურებელი ნივთიერებები 2.2.9.1.10 გარემოსთვის (წყლის გარემოსთვის) სახიფათო ნივთიერებები 2.2.9.1.10.1 ზოგადი განმარტებანი 2.2.9.1.10.1.1 გარემოსთვის სახიფათო ნივთიერებები მოიცავს, კონკრეტულად, წყლის გარემოს გამაბინძურებელ თხევად ან მყარ ნივთიერებებსა და აღნიშნული ნივთიერებების ხსნარებსა და ნარევებს (როგორიცაა პრეპარატები და ნაჩენები). 323 2.2.9.1.10 პუნქტის მიზნებისთვის, „ნივთიერება“ ნიშნავს ქიმიურ ელემენტებსა და მის შენაერთებს ბუნებრივ მდგომარეობაში ან მიღებულს ნებისმიერი საწარმოო პროცესის შედეგად, ნებისმიერი დანამატის ჩათვლით, რაც აუცილებელია პროდუქტისა და იმ ნებისმიერი მინარევის სტაბილურობის შესანარჩუნებლად, რომლებიც წარმოიქმნება გამოყენებული პროცესის შედეგად, თუმცა გამორიცხავს ნებისმიერ გამხსნელს, რომლის გამოყოფაც შესაძლებელია ნივთიერების სტაბილურობის ზემოქმედების მოხდენისა თუ მისი შემადგენლობის შეცვლის გარეშე. 2.2.9.1.10.1.2 წყლის გარემოში შესაძლებელია იგულისხმებოდეს წყლის ორგანიზმები, რომლებიც ცხოვრობენ წყალსა და წყლის ეკოსისტემაში, რომლის ნაწილსაც წარმოადგენენ.11 შესაბამისად, საშიშროება განისაზღვრება მოცემული ნივთიერებისა თუ ნარევის ტოქსიკურობის საფუძველზე წყლის გარემოში, თუმცა აღნიშნული შესაძლებელია შეიცვალოს დეგრადაციისა და ბიოაკუმულაციური ქცევის შესახებ დამატებითი ინფორმაციით. 2.2.9.1.10.1.3 მიუხედავად იმისა, რომ ქვემოთ წარმოდგენილი კლასიფიკაციის პროცედურა გათვალისწინებულია ყველა ნივთიერებასა და ნარევზე, აღიარებულია, რომ ზოგიერთ შემთხვევაში, მაგალითად, ლითონებისა თუ ცუდად ხსნადი არაორგანული ნაერთების შემთხვევაში, აუცილებელი იქნება სპეციალური მითითებები.12 2.2.9.1.10.1.4 წინამდებარე კარში გამოყენებულ შემოკლებებსა თუ ტერმინებთან დაკავშირებით გამოიყენება შემდეგი განმარტებები: - BCF: ბიოკონცენტრაციის ფაქტორი; - BOD: ბიოქიმიური მოთხოვნა ჟანგბადზე; - COD: ქიმიური მოთხოვნა ჟანგბადზე; - GLP: კარგი ლაბორატორიული პრაქტიკა; - ECX: კონცენტრაცია ასოცირებული X% რეაქციასთან; - EC50: ნივთიერების ეფექტური კონცენტრაცია, რომელიც იწვევს მაქსიმალური რეაქციის 50%-ს; - ErC50: EC50 ზრდის შემცირების პირობებში; - Kow: ოქტანოლის/წყლის განაწილების კოეფიციენტი; - LC50 (50% ლეთალური კონცენტრაცია): ნივთიერების კონცენტრაცია წყალში, რომელიც იწვევს გარდაცვალებას საცდელი ცხოველების ჯგუფის 50%-ში (ნახევარში); - L(E)C50: LC50 ან EC50; აღნიშნული განმარტებები არ გამოიყენება წყლის იმ გამაბინძურებელ საშუალებებთან დაკავშირებით, რომელთა მიმართაც შესაძლებელია თავი იჩინოს მათი მოქმედების აუცილებლობამ, რომელიც ტოვებს წყლის გარემოს საზღვრებს, როგორიცაა ზემოქმედება ადამიანთა ჯანმრთელობაზე და ა.შ. 11 12 აღნიშნული შეგიძლიათ მოიძიოთ GHS-ს მე-10 დანართში. 324 - NOEC (კონცენტრაცია, რომელიც არ იწვევს ხილულ ეფექტს): ექსპერიმენტული კონცენტრაცია, რომელიც უმდაბლესი ექსპერიმენტული კონცენტრაციის ქვემოთ იწვევს სტატისტიკურად მნიშვნელოვან უარყოფით ეფექტს. NOEC არ იწვევს სტატისტიკურად მნიშვნელოვან უარყოფით ეფექტს კონტროლთან შედარებით; - OECD ცდების პრინციპების შესახებ სახელმძღვანელო: ეკონომიკური თანამშრომლობისა და განვითარების ორგანიზაციის (OECD) მიერ გამოქვეყნებული საცდელი მითითებები. 2.2.9.1.10.2 განმარტებები და მონაცემებთან დაკავშირებული მოთხოვნები 2.2.9.1.10.2.1 გარემოსთვის (წყლის გარემოსთვის) სახიფათო ნივთიერებების კლასიფიკაციის ძირითად ელემენტებს წარმოადგენს: (ა) წყლის გარემოში მწვავე ტოქსიკურობა; (ბ) წყლის გარემოში ქრონიკული ტოქსიკურობა; (გ) ფაქტიური ბიოაკუმულაცია ან მისი პოტენციალი; და (დ) ორგანულ ქიმიურ ნივთიერებებთან (ბიოლოგიური ან არაბიოლოგიური). დაკავშირებული დეგრადაცია 2.2.9.1.10.2.2 მიუხედავად იმისა, რომ უპირატესობა ენიჭება საერთაშორისო დონეზე შეთანხმებული საცდელი მეთოდების საფუძველზე მიღებულ მონაცემებს, პრაქტიკაში შესაძლებელია ასევე გამოყენებულ იქნეს ეროვნული მეთოდების საფუძველზე მიღებული მონაცემები, თუ ასეთი მეთოდები მიიჩნევა ეკვივალენტურად. ზოგადად, დადგენილია, რომ მტკნარი წყლისა და ზღვის სახეობების ტოქსიკურობის შესახებ მონაცემები შესაძლებელია განხილულ იქნეს, როგორც ეკვივალენტური მონაცემები და აღნიშნული მონაცემები უმჯობესია მიღებულ იქნეს OECD საცდელი მითითებების ან შესაბამისი მეთოდების გამოყენებით კარგი ლაბორატორიული პრაქტიკის (GLP) პრინციპების შესაბამისად. თუ ასეთი მონაცემები არ არის ხელმისაწვდომი, კლასიფიკაცია შესაძლებელია დაეფუძნოს ხელთ არსებულ საუკეთესო მონაცემებს. 2.2.9.1.10.2.3 წყლის გარემოში მწვავე ტოქსიკურობა ნიშნავს ნივთიერების საკუთარ თვისებას მიაყენოს ზიანი წყლის გარემოში ორგანიზმს აღნიშნულ ნივთიერებაზე ხანმოკლე ზემოქმედებისას. მწვავე (ხანმოკლე) საშიშროება, კლასიფიკაციის მიზნებთან დაკავშირებით, ნიშნავს ქიმიური ნივთიერების საშიშროებას, განპირობებულს მისი მწვავე ტოქსიკურობით ორგანიზმზე აღნიშნულ ქიმიურ ნივთიერებაზე წყლის გარემოში ხანმოკლე ზემოქმედების განმავლობაში. წყლის გარემოში მწვავე ტოქსიკურობა ჩვეულებრივ განისაზღვრება LC50 მნიშნელობის გამოყენებით თევზების შემთხვევაში 96-საათიანი ზემოქმედებისას (OECD ცდების პრინციპების შესახებ სახელმძღვანელო 203 ან ეკვივალენტური მეთოდი), EC50 მნიშვნელობა კიბოსებრთა შემთხვევაში 48-საათიანი ზემოქმედებისას (OECD ცდების პრინციპების შესახებ სახელმძღვანელო 202 ან ეკვივალენტური მეთოდი) და/ან EC50 მნიშვნელობა წყალმცენარეების შემთხვევაში 72 ან 96-საათიანი ზემოქმედებისას (OECD ცდების პრინციპების შესახებ სახელმძღვანელო 201 ან 325 ეკვივალენტური მეთოდი). აღნიშნული სახეობები განიხილება სუროგატების სახით ყველა წყლის ორგანიზმისთვის და მონაცემები სხვა სახეობებთან დაკავშირებით, როგორიცაა ლემნა, შესაძლებელია ასევე განიხილოს იმ შემთხვევაში, თუ საცდელი მეთოდოლოგია შეესაბამება. 2.2.9.1.10.2.4 წყლის გარემოში ქრონიკული ტოქსიკურობა ნიშნავს ნივთიერების საკუთარ თვისებას გამოიწვიოს უარყოფითი ეფექტები წყლის ორგანიზმებზე აღნიშნულ ორგანიზმებზე ზემოქმედებისას, რომლებიც განისაზღვრება ორგანიზმის სიცოცხლის ციკლთან დაკავშირებით. ხანგრძლივი საშიშროება, კლასიფიკაციის მიზნებთან დაკავშირებით, ნიშნავს ქიმიური ნივთიერების საშიშროებას, რომელიც გამოწვეულია მისი ქრონიკული ტოქსიკურობით წყლის გარემოში ხანგრძლივი ზემოქმედების შედეგად. ქრონიკული ტოქსიკურობის შესახებ მონაცემები ნაკლებად ხელმისაწვდომია მწვავე ტოქსიკურობის შესახებ მონაცემებთან შედარებით და შესაბამისი ცდების პროცედურები ნაკლებად სტანდარტიზებულია. OECD ცდების პრინციპების შესახებ სახელმძღვანელო 210-ის (თევზების სიცოცხლის ადრეული სტადია) ან 211-ის (დაფნიას გამრავლება) და 201-ის (წყალმცენარეების შენელებული ზრდა) თანახმად დამუშავებული მონაცემები შესაძლებელია დაშვებული იყოს გამოსაყენებლად. ასევე შესაძლებელია გამოყენებულ იქნეს სხვა მოქმედი და საერთაშორისოდ მიღებული ცდები. უნდა მოხდეს NOEC ან სხვა ეკვივალენტური ECX შესახებ არსებული მონაცემების გამოყენება. 2.2.9.1.10.2.5 ბიოაკუმულაცია ნიშნავს ორგანიზმში ზემოქმედების ყოველგვარი საშუალებით (მაგალითად, ჰაერის, წყლის, ნარჩენების/ნიადაგისა და საკვების გზით) ნებისმიერი ნივთიერების მიღების, ტრანსფორმირებისა თუ ელიმინაციის სუფთა შედეგს. ბიოაკუმულაციის შესაძლებლობა ჩვეულებრივ განისაზღვრება ოქტანოლის/წყლის დაყოფის კოეფიციენტის გამოყენებით, რომელიც ჩვეულებრივ გამოისახება, როგორც ლოგარითმი Kow და განისაზღვრება OECD ცდების პრინციპების შესახებ სახელმძღვანელო 107-ისა თუ 117-ის შესაბამისად. მიუხედავად იმისა, რომ აღნიშნული კოეფიციენტი წარმოადგენს ბიოაკუმულაციის შესაძლებლობას, ექსპერიმენტულად განსაზღვრული ბიოკონცენტრაციის ფაქტორი (BCF) უზრუნველყოფს კიდევ უფრო ზუსტ მაჩვენებლებს და, მისი ხელმისაწვდომობის შემთხვევაში, უნდა მიენიჭოთ უპირატესობა. ბიოკონცენტრაციის ფაქტორი უნდა განისაზღვროს OECD ცდების პრინციპების შესახებ სახელმძღვანელო 305-ის შესაბამისად. 2.2.9.1.10.2.6 დეგრადაცია ნიშნავს ორგანული მოლეკულების დაშლას უფრო მცირე მოლეკულებად და საბოლოოდ კი - ნახშირბადის დიოქსიდად, წყლად და მარილად. გარემოში დეგრადაცია შესაძლებელია იყოს ბიოლოგიური ან არაბიოლოგიური (მაგალითად, ჰიდროლიზი) და გამოყენებული კრიტერიუმები ასახავს აღნიშნულ ფაქტს. სწრაფი ბიოლოგიური დეგრადაცია განისაზღვრება ყველაზე ადვილად OECD ცდების პრინციპების შესახებ სახელმძღვანელო 301-ის ბიოდეგრადირების ცდების (A-F) გამოყენებით. აღნიშნულ ცდებთან დაკავშირებით მიღებული სწრაფი დეგრადირების მაჩვენებლები შესაძლებელია ჩაითვალოს მოქმედად გარემოს უმეტესი ტიპებისთვის. აღნიშნული ცდები ხორციელდება მტკნარ წყალში და შესაბამისად ასევე გათვალისწინებულია ის შედეგები, რომლებიც მიღებულია OECD 326 ცდების პრინციპების შესახებ სახელმძღვანელო 306-ის შესაბამისად, რომელიც ყველაზე მეტად შეესაბამება ზღვის გარემოს. იმ შემთხვევაში, თუ აღნიშნული მონაცემები არ არის წარმოდგენილი, სწრაფი დეგრადაციის მაჩვენებლად განისაზღვრება BOD(5 დღე)/COD კოეფიციენტი >0.5. არაბიოლოგიური დეგრადაცია, მაგალითად ჰიდროლიზი, როგორც ბიოლოგიური, ასევე არაბიოლოგიური პირველადი დეგრადაცია, დეგრადაცია უწყლო გარემოში და დამტკიცებული სწრაფი დეგრადაცია გარემოში შესაძლებელია ასევე მხედველობაში იქნეს მიღებული სწრაფი დეგრადირების განსაზღვრისას13. ნივთიერებები განიხილება სწრაფად დეგრადირებადად გარემოში იმ შემთხვევაში, თუ აკმაყოფილებს შემდეგ კრიტერიუმებს: (ა) თუ სწრაფ ბიოდეგრადაციაზე 28-დღიანი კვლევების შედეგად მიიღწევა დეგრადაციის შემდეგი დონეები: (i) გახსნილ ორგანულ ნახშირბადზე დაფუძნებული ცდები: 70%; (ii) ჟანგბადის დანაკარგსა თუ ნახშირბადის დიოქსიდის გამოყოფაზე დაფუძნებული ტესტები: თეორიული მაქსიმუმის 60%. ბიოდეგრადაციის აღნიშნული დონეები მიიღწევა ბიოდეგრადაციის დაწყებიდან 10 დღის განმავლობაში, რომლისთვისაც მიღებულია ის მომენტი, როდესაც მიიღწევა ნივთიერების 10%-ის დეგრადირება გარდა იმ შემთხვევისა, როდესაც ნივთიერება განსაზღვრულია, როგორც რთული, მრავალკომპონენტიანი ნივთიერება სტრუქტურულად მსგავსი ელემენტებით. მოცემულ შემთხვევაში და საკმარისი საფუძლების არსებობისას, შესაძლებელია უარყოფილი იქნეს 10-დღიანი ფანჯრის გამოყენება და აუცილებელი დონის მისაღწევად განისაზღვროს 28 დღე14; ან (ბ) იმ შემთხვევებში, როდესაც ხელმისაწვდომია მხოლოდ BOD ან COD მონაცემები, BOD5/COD კოეფიციენტი შეადგენს > 0,5; ან (გ) თუ არსებობს სხვა დამაჯერებელი მეცნიერული მტკიცებულება, რომელიც ადასტურებს, რომ ნივთიერებებისა და ნაერთების დეგრადირება (ბიოლოგიურად და/ან არაბიოლოგიურად) შესაძლებელია წყლის გარემოში 70%-ზე მაღალ დონეზე 28-დღიანი პერიოდის განმავლობაში. 2.2.9.1.10.3 ნივთიერებების კლასიფიკაციის კატეგორიები და კრიტერიუმები 2.2.9.1.10.3.1 ნივთიერებების კლასიფიკაცია უნდა მოხდეს, როგორც „გარემოსთვის (წყლის გარემოსთვის) სახიფათო ნივთიერებები“ იმ შემთხვევაში, თუ ისინი აკმაყოფილებს მწვავე ტოქსიკურობა 1-ის, ქრონიკული ტოქსიკურობა 1-ისა და ქრონიკული ტოქსიკურობა 2-ის კრიტერიუმებს 2.2.9.1.10.3.1 ცხრილის შესაბამისად. აღნიშნული კრიტერიუმები დეტალურად აღწერს კლასიფიკაციის კატეგორიებს. ისინი დიაგრამის სახით წარმოდგენილია 2.2.9.1.10.3.2 ცხრილში. სპეციალური მითითებები მონაცემთა ინტერპრეტაციის შესახებ წარმოდგენილია 4.1 თავსა და GHS-ის მე-9 დანართში. 13 14 იხილეთ 4.1 თავი და GHS-ს მე-9 დანართის A9.4.2.2.3 პუნქტი. 327 (ა) ცხრილი 2.2.9.1.10.3.1: წყლის გარემოსთვის სახიფათო ნივთიერებების კატეგორიები (იხილეთ პირველი შენიშვნა) მწვავე (ხანმოკლე) საშიშროება წყლის გარემოში კატეგორია - მწვავე ტოქსიკურობა 1: (იხილეთ მე-2 შენიშვნა) LC50 96-საათიანი მოქმედებისას (თევზების შემთხვევაში) EC50 48-საათიანი მოქმედებისას (კიბოსებრთა შემთხვევაში) ErC50 72 ან 96-საათიანი მოქმედებისას (წყალმცენარეების ან სხვა წყალში ზრდადი მცენარეების შემთხვევაში) (ბ) < 1მგ/ლ და/ან < 1 მგ/ლ და/ან < 1 მგ/ლ (იხილეთ მე-3 შენიშვნა) ხანგრძლივი საშიშროება წყლის გარემოში (იხილეთ სურათი 2.2.9.1.10.3.1) (i) ნივთიერებები, რომელთაც არ შეუძლიათ სწრაფად დეგრადირება (იხილეთ მე-4 შენიშვნა) და რომლებთან დაკავშირებითაც წარმოდგენილია შესაბამისი მონაცემები ქრონიკული ტოქსიკურობის შესახებ კატეგორია - ქრონიკული ტოქსიკურობა 1: (იხილეთ მე-2 შენიშვნა) ქრონიკული ტოქსიკურობა NOEC ან ECX (თევზების შემთხვევაში) ქრონიკული ტოქსიკურობა NOEC ან ECX (კიბოსებრთა შემთხვევაში) ქრონიკული ტოქსიკურობა NOEC ან ECX (წყალმცენარეების ან სხვა წყალში ზრდადი მცენარეების შემთხვევაში) კატეგორია - ქრონიკული ტოქსიკურობა 2: ქრონიკული ტოქსიკურობა NOEC ან ECX (თევზების შემთხვევაში) ქრონიკული ტოქსიკურობა NOEC ან ECX (კიბოსებრთა შემთხვევაში) ქრონიკული ტოქსიკურობა NOEC ან ECX (წყალმცენარეების ან სხვა წყალში ზრდადი მცენარეების შემთხვევაში) < 0.1მგ/ლ და/ან < 0.1 მგ/ლ და/ან < 0.1 მგ/ლ < 1მგ/ლ და/ან < 1 მგ/ლ და/ან < 1 მგ/ლ (ii) ნივთიერებები, რომელთაც შეუძლიათ სწრაფად დეგრადირება და რომლებთან დაკავშირებითაც წარმოდგენილია შესაბამისი მონაცემები ქრონიკული ტოქსიკურობის შესახებ კატეგორია - ქრონიკული ტოქსიკურობა 1: (იხილეთ მე-2 შენიშვნა) ქრონიკული ტოქსიკურობა NOEC ან ECX (თევზების შემთხვევაში) ქრონიკული ტოქსიკურობა NOEC ან ECX (კიბოსებრთა შემთხვევაში) ქრონიკული ტოქსიკურობა NOEC ან ECX (წყალმცენარეების ან სხვა წყალში ზრდადი მცენარეების შემთხვევაში) კატეგორია - ქრონიკული ტოქსიკურობა 2: ქრონიკული ტოქსიკურობა NOEC ან ECX (თევზების შემთხვევაში) ქრონიკული ტოქსიკურობა NOEC ან ECX (კიბოსებრთა შემთხვევაში) ქრონიკული ტოქსიკურობა NOEC ან ECX (წყალმცენარეების ან სხვა წყალში ზრდადი მცენარეების შემთხვევაში) < 0.01მგ/ლ და/ან < 0.01 მგ/ლ და/ან < 0.01 მგ/ლ < 0.1მგ/ლ და/ან < 0.1 მგ/ლ და/ან < 0.1 მგ/ლ (iii) ნივთიერებები, რომლებთან დაკავშირებითაც არ არის წარმოდგენილი შესაბამისი მონაცემები ქრონიკული ტოქსიკურობის შესახებ კატეგორია - ქრონიკული ტოქსიკურობა 1: (იხილეთ მე-2 შენიშვნა) LC50 96-საათიანი მოქმედებისას (თევზების შემთხვევაში) < 1მგ/ლ და/ან EC50 48-საათიანი მოქმედებისას (კიბოსებრთა შემთხვევაში) < 1 მგ/ლ და/ან ErC50 72 ან 96-საათიანი მოქმედებისას (წყალმცენარეების ან სხვა წყალში < 1 მგ/ლ (იხილეთ მე-3 შენიშვნა) ზრდადი მცენარეების შემთხვევაში) და ნივთიერებას არ შეუძლია სწრაფად დეგრადირება და/ან რომლის ექსპერიმენტულად განსაზღვრული BCF შეადგენს > 500 (ან ლოგარითმის Kow > 4 არარსებობის შემთხვევაში) (იხილეთ მე-4 და მე-5 შენიშვნები). კატეგორია - ქრონიკული ტოქსიკურობა 2: LC50 96-საათიანი მოქმედებისას (თევზების შემთხვევაში) > 1, მაგრამ < 10 მგ/ლ და/ან EC50 48-საათიანი მოქმედებისას (კიბოსებრთა შემთხვევაში) > 1, მაგრამ < 10 მგ/ლ და/ან ErC50 72 ან 96-საათიანი მოქმედებისას (წყალმცენარეების ან სხვა წყალში > 1, მაგრამ < 10 მგ/ლ და/ან ზრდადი მცენარეების შემთხვევაში) (იხილეთ მე-3 შენიშვნა) და ნივთიერებას არ შეუძლია სწრაფად დეგრადირება და/ან რომლის ექსპერიმენტულად განსაზღვრული BCF შეადგენს > 500 (ან ლოგარითმის Kow > 4 არარსებობის შემთხვევაში) (იხილეთ მე-4 და მე-5 შენიშვნები). 328 შენიშვნა 1: ისეთ ორგანიზმებზე, როგორიცაა თევზები, კიბოსებრთა სახეობები და წყალმცენარეები განხორციელდა ცდები სუროგატი სახეობების სახით, რომლებიც მოიცავს ტროპიკული დონეებისა და ტაქსონების ვრცელ არეალს, ხოლო საცდელი მეთოდები ძალზედ სტანდარტიზებულია. ასევე შესაძლებელია მხედველობაში იქნეს მიღებული სხვა ორგანიზმების შესახებ არსებული მონაცემები, თუმცა იმ პირობით, რომ ისინი უნდა წარმოადგენდნენ ეკვივალენტურ სახეობებსა და ცდის პარამეტრებს. შენიშვნა 2: ნივთიერებების მწვავე ტოქსიკურობა 1-ისა და/ან ქრონიკული ტოქსიკურობა 2-ის კატეგორიებში კლასიფიცირებისას, ამავდროულად აუცილებელია შესაბამისი M ფაქტორის მითითება (იხილეთ 2.2.9.1.10.4.6.4 ქვეპუნქტი) შეჯამების მეთოდის გამოსაყენებლად. შენიშვნა 3: იმ შემთხვევებში, როდესაც წყალმცენარეების ტოქსიკურობა ErC50 (=EC50 (ზრდის სიჩქარე)) მცირდება 100-ჯერ მომდევნო ყველაზე მგრძნობიარე სახეობებთან შედარებით და ხელს უწყობს საშიშროებების კლასიფიცირებას კონკრეტულად აღნიშნული ზემოქმედების საფუძველზე, გათვალისწინებულ უნდა იქნეს იმ ფაქტზე, წარმოადგენს თუ არა აღნიშნული ტოქსიკურობა დამახასიათებელს წყალმცენარეებისთვის. როდესაც შესაძლებელია იმის დამტკიცება, რომ ეს ასე არ არის, აუცილებელია პროფესიონალური დასკვნის გამოყენება იმ ფაქტის განსაზღრისას საჭიროა თუ არა კლასიფიკაციის გამოყენება. კლასიფიკაცია უნდა დაეფუძნოს ErC50-ს. იმ შემთხვევებში, როდესაც EC50-ის საფუძველი არ არის მითითებული და არავითარი ErC50 არ არის აღრიცხული, კლასიფიკაცია უნდა დაეფუძნოს არსებულ ყველაზე დაბალ EC50 მნიშნელობას. შენიშვნა 4: სწრაფი დეგრადირების შესაძლებლობის არარსებობა ეფუძნება სწრაფი ბიოდეგრადირების პოტენციალის არქონას ან სწრაფი დეგრადაციის შესაძლებლობის არქონის სხვა მტკიცებულებებს. იმ შემთხვევაში, თუ ხელმისაწვდომი არ არის სასარგებლო მონაცემები დეგრადირების შესახებ, მიღებული როგორც ექპერიმენტული გზით, ასევე შეფასების გზით, ნივთიერება უნდა ჩაითვალოს, როგორც სწრაფი დეგრადირების შესაძლებლობის არმქონე. შენიშვნა 5: ბიოაკუმულაციის პოტენციალი, რომელიც დაფუძნებულია ექსპერიმენტული გზით მიღებულ BCF > 500 მნიშნელობაზე ან; მისი არარსებობისას, ლოგარითმი Kow >4 მნიშვნელობაზე იმ პირობით, რომ ლოგარითმი Kow წარმოადგენს ნივთიერების ბიოაკუმულაციის პოტენციალის სათანადო აღმწერს. გაანგარიშებულ ლოგარითმი Kow მნიშნელობებს ენიჭებათ უპირატესობა შეფასებულ მნიშვნელობებთან შედარებით, ხოლო გაანგარიშებულ BCF მნიშვნელობებს ენიჭებათ უპირატესობა Kow მნიშვნელობებთან შედარებით. 329 სურათი 2.2.9.1.10.3.1: იმ ნივთიერებებთან დაკავშირებული კატეგორიები, რომლებიც ხასიათდება ხანგრძლივი საშიშროებით წყლის გარემოში არის თუ არა საკმარისი მონაცემები ქრონიკული ტოქსიკურობის შესახებ სამივე ტროფიკული დონისთვის? იხილეთ 2.2.9.1.10.3.1 ცხრილის მე- დიახ კლასიფიცირება 2.2.9.1.10.3.1 (ბ)(i) ან 2.2.9.1.10.3.1 (ბ) (ii) ცხრილებში გათვალისწინებული კრიტერიუმების შესაბამისად, სწრაფი დეგრადაციის შესახებ არსებული ინფორმაციის საფუძველზე. არა ორივეს შეფასება: (ა) 2.2.9.1.10.3.1 (ბ)(i) ან 2.2.9.1.10.3.1 (ბ) (ii) ცხრილებში გათვალისწინებული კრიტერიუმების შესაბამისად (სწრაფი დეგრადაციის შესახებ არსებული ინფორმაციის საფუძველზე), და (ბ) (იმ შემთხვევაში, თუ წარმოდგენილია საკმარისი მონაცემები მწვავე ტოქსიკურობის შესახებ სხვა ტროფიკულ დონესთან (დონეებთან) დაკავშირებით) 2.2.9.1.10.3.1 (ბ) (iii) ცხრილში გათვალისწინებული კრიტერიუმების შესაბამისად, და კლასიფიცირება განხორციელდება ყველაზე მკაცრი შედეგის საფუძველზე. დიახ არის თუ არა საკმარისი მონაცემები ქრონიკული ტოქსიკურობის შესახებ ერთი ან ორი დონისთვის? არა არის თუ არა საკმარისი მონაცემები მწვავე ტოქსიკურობის შესახებ? 2.2.9.1.10.3.2 დიახ კლასიფიცირება 2.2.9.1.10.3.1 (ბ)(iii) ცხრილში გათვალისწინებული კრიტერიუმების შესაბამისად. ქვემოთ წარმოდგენილ 2.2.9.1.10.3.2 ცხრილში გათვალისწინებული კლასიფიკაციის სქემა აჯამებს ნივთიერებებთან დაკავშირებულ კლასიფიკაციის კრიტერიუმებს. ცხრილი 2.2.9.1.10.3.2: იმ ნივთიერებებთან დაკავშირებული კლასიფიკაციის სქემა, რომლებიც წარმოადგენს საშიშროებას წყლის გარემოსთვის მწვავე საშიშროება (იხილეთ პირველი შენიშვნა) კლასიფიკაციის კატეგორიები ხანგრძლივი საშიშროება (იხილეთ მე-2 შენიშვნა) წარმოდგენილია საკმარისი მონაცემები ქრონიკული წარმოდგენილი არ არის ტოქსიკურობის შესახებ საკმარისი მონაცემები ქრონიკული ტოქსიკურობის ნივთიერებები, ნივთიერებები, შესახებ რომელთაც არ გააჩნიათ რომელთაც გააჩნიათ (იხილეთ პირველი შენიშვნა) სწრაფი დეგრადირების სწრაფი დეგრადირების უნარი უნარი 330 კატეგორია: მწვავე ტოქსიკურობა 1 L(E)C50 < 1.00 (იხილეთ მე-3 შენიშვნა) (იხილეთ მე-3 შენიშვნა) კატეგორია: ქრონიკული ტოქსიკურობა 1 NOEC ან ECX < 0.1 კატეგორია: ქრონიკული ტოქსიკურობა 1 NOEC ან ECX < 0.01 კატეგორია: ქრონიკული ტოქსიკურობა 2 0.1 < NOEC ან ECX < 1 კატეგორია: ქრონიკული ტოქსიკურობა 2 0.01 < NOEC ან ECX < 0.1 კატეგორია: ქრონიკული ტოქსიკურობა 1 L(E)C50 < 1.00 და სწრაფი დეგრადირების უნარის არქონა და/ან BCF > 500 ან, მისი არარსებობის შემთხვევაში, ლოგარითმი Kow > 4 კატეგორია: ქრონიკული ტოქსიკურობა 2 1.00 < L(E)C50 < 10.0 და სწრაფი დეგრადირების უნარის არქონა და/ან BCF > 500 ან, მისი არარსებობის შემთხვევაში, ლოგარითმი Kow > 4 შენიშვნა 1: მწვავე ტოქსიკურობის დიაპაზონი, რომელიც ეფუძნება L(E)C50 მნიშვნელობებს მგ/ლ-ში თევზთან, კიბოსებრ სახეობებსა და/ან წყალმცენარეებთან ან სხვა სახის წყალში ზრდად მცენარეებთან დაკავშირებით (ან რაოდენობრივი დამოკიდებილების „სტრუქტურა-აქტივობის“ (QSAR) შეფასება იმ შემთხვევაში, თუ არ არის წარმოდგენილი ექსპერიმენტული მონაცემები15). შენიშვნა 2: ნივთიერებების კლასიფიცირება ხდება სხვადასხვა ქრონიკულ კატეგორიებში, თუ არ არის წარმოდგენილი საკმარისი მონაცემები ქრონიკული ტოქსიკურობის შესახებ სამივე ტროფიკული დონისთვის წყალში ხსნადობაზე მაღალი ან 1 მგ/ლ-ზე მაღალი კონცენტრაციისას („საკმარისი“ ნიშნავს იმ ფაქტს, რომ მონაცემები საკმარისად ითვალისწინებს შესაბამის მაჩვენელბლებს. ზოგადად, აღნიშნულში უნდა იგულისხმებოდეს ცდების დროს გაანგარიშებული მონაცემები, თუმცა არასაჭირო ცდების განხორციელების თავიდან ასაცილებლად, შესაძლებელია ასევე ყოველ კონკრეტულ შემთხვევაში გამოყენებულ იქნეს შეფასებული მონაცემები, მაგალითად (Q)SAR, ან თვალსაჩინო შემთხვევებისთვის - ექსპერტთა დასკვნა). შენიშვნა 3: ქრონიკული ტოქსიკურობის დიაპაზონი, რომელიც დაფუძნებულია NOEC ან შესაბამის EC50 მნიშნელობებზე მგ/ლ-ში თევზებსა თუ კიბოსებრთა სხვა სახეობებთან დაკავშირებით ან ქრონიკული ტოქსიკურობის სხვა აღიარებულ მაჩვენებლებზე. 2.2.9.1.10.4 ნარევების კლასიფიკაციის კატეგორიები და კრიტერიუმები 2.2.9.1.10.4.1 ნარევების კლასიფიკაციის სისტემაში შედის ნივთიერებებთან დაკავშირებით გამოყენებული კლასიფიკაციის კატეგორიები, მათ შორის მწვავე ტოქსიკურობა 1-ის, ქრონიკული ტოქსიკურობა 1-სა და 2-ის კატეგორიები. წყლის გარემოში ნარევების საშიშროების კლასიფიცირების მიზნით ყოველგვარი ხელთ არსებული ინფორმაციის გამოსაყენებლად, შესაბამის შემთხვევებში ხდება შემდეგი ვარაუდების წარდგენა და გამოყენება: 331 15 სპეციალური მითითებები წარმოდგენილია 4.1 თავის 4.1.2.13 და GHS-ის A9.6 კარის მე-9 დანართში. ნარევების „შესაბამისი კომპონენტები“ გულისხმობს იმ კონცენტრაციით წარმოდგენილ კომპონენტებს, რომლებიც ტოლია ან აღემატება 0.1%-ს (მასის მიხედვით) მწვავე და/ან ქრონიკული ტოქსიკურობა 1-ის კატეგორიაში კლასიფიცირებულ კომპონენტებთან დაკავშირებით და ტოლია ან აღემატება 1%-ს სხვა კომპონენტებთან დაკავშირებით, თუ არ არსებობს ვარაუდის საფუძელი (მაგალითად, მაღალტოქსიკური კომპონენტების შემთხვევაში), რომ 0.1%-ზე ნაკლები კონცენტრაციით წარმოდგენილი კომპონენტი შესაძლებელია კვლავ იქნან გამოყენებულნი წყლის გარემოში საშიშროებებთან დაკავშირებით ნარევების კლასიფიცირებისას. 2.2.9.1.10.4.2 წყლის გარემოში საშიშროებების კლასიფიკაცია ხორციელდება სართულების პრინციპით და დამოკიდებულია თავად ნარევისა და მისი კომპონენტების შესახებ ხელთ არსებული ინფორმაციის ტიპზე. აღნიშნული სართულების პრინციპის ელემენტები მოიცავენ: (ა) ნარევების გამოცდაზე დაფუძნებულ კლასიფიკაციას; (ბ) ექსტრაპოლირების პრინციპზე დაფუძნებულ კლასიფიკაციას; (გ) „კლასიფიცირებული კომპონენტების შეჯამებისა“ და/ან „ადიტიურობის ფორმულის“ გამოყენებაზე. სურათი 2.2.9.1.10.4.2: ნარევების კლასიფიკაციის სართულოვანი მიდგომა მათი მწვავე და ხანგრძლივი საშიშროებების მიხედვით წყლის გარემოში ნარევების წყლის გარემოში ტოქსიკურობის გამოცდასთან დაკავშირებით არსებული მონაცემები, როგორც ერთი მთლიანობა არა საშიშროებების შეფასების მიზნით მსგავს ნარევებთან დაკავშირებით წარმოდგენილი საკმარისი მონაცემები დიახ არა ყველა შესაბამის კომპონენტთან დაკავშირებით წარმოდგენილი მონაცენები ტოქსიკურობის შესახებ წყლის გარემოში ან მონაცემები კლასიფიკაციის შესახებ არა გამოყენებულ უნდა იქნეს ცნობილი კომპონენტების საშიშროების შესახებ ხელთ არსებული მონაცემები დიახ დიახ გამოიყენება ექსტრაპოლირების პრინციპი (2.2.9.1.10.4.4) გამოიყენება შეჯამების მეთოდი (2.2.9.1.10.4.6.1დან 2.2.9.1.10.4.6.4 ქვეპუნქტამდე) შემდეგის გამოყენებით: (ა) ყველა კომპონენტის პროცენტული თანაფარდობა, რომელიც კლასიფიცირდება, როგორც „ქრონიკულად ტოქსიკური“; (ბ) იმ კომპონენტების პროცენტული თანაფარდობა, რომლებიც კლასიფიცირდება, როგორც „მწვავე ტოქსიკური“; (გ) მწვავე ტოქსიკური მონაცემების მქონე კომპონენტების პროცენტული თანაფარდობა: გამოიყენეთ ადიტიურობის ფორმულები (2.2.9.1.10.4.6.2) და გადაიყვანეთ მიღებული მნიშვნელობა L(E)C50 ან EqNOECm შესაბამის „მწვავე ტოქსიკურ“ ან „ქრონიკულად ტოქსიკურ“ კატეგორიაში. გამოიყენეთ შეჯამების მეთოდი და ადიტიურობის ფორმულა (2.2.9.1.10.4.6.1-დან 2.2.9.1.10.4.6.4 ქვეპუნქტამდე) და მიმართეთ 332 კლასიფიცირება მწვავე ხანგრძლივ საშიშროებასთან დაკავშირებით (2.2.9.1.10.4.3) კლასიფიცირება მწვავე/ხანგრძლივ საშიშროებასთან დაკავშირებით კლასიფიცირება მწვავე/ხანგრძლივ საშიშროებასთან დაკავშირებით კლასიფიცირება მწვავე/ხანგრძლივ საშიშროებასთან დაკავშირებით 2.2.9.1.10.4.6.5 ქვეპუნქტს 2.2.9.1.10.4.3 ნარევების კლასიფიკაცია, როდესაც ტოქსიკურობის წარმოდგენილია მთლიანად ნარევთან დაკავშირებით. შესახებ მონაცემები 2.2.9.1.10.4.3.1 იმ შემთხვევაში, თუ ცდა განხორციელდა მთლიანად ნარევზე წყლის გარემოში მისი ტოქსიკურობის განსაზღვრის მიზნით, აღნიშნული ინფორმაციის გამოყენება უნდა მოხდეს ნივთიერების კლასიფიკაციის მიზნით ნივთიერებებთან დაკავშირებით შეთანხმებული კრიტერიუმების შესაბამისად. როგორც წესი, კლასიფიკაცია ეფუძნება თევზების, კიბოსებრთა სახეობებისა და წყალმცენარეებთან/მცენარეებთან დაკავშირებულ მონაცემებს (იხილეთ 2.2.9.1.10.2.3 და 2.2.9.1.10.2.4 ქვეპუნქტები). იმ შემთხვევაში, თუ არ არის წარმოდგენილი საკმარისი მონაცემები მთლიანად ნარევის მწვავე ან ქრონიკულ ტოქსიკურობასთან დაკავშირებით, გამოიყენება „ექსტრაპოლირების პრინციპები“ ან „შეჯამების მეთოდი“ (იხილეთ 2.2.9.1.10.4.4-დან 2.2.9.1.10.4.6 ქვეპუნქტები). 2.2.9.1.10.4.3.2 ნივთიერებების ხანგრძლივი საშიშროების კლასიფიკაცია საჭიროებს დამატებით ინფორმაციას დეგრადირებისა და, გარკვეულ შემთხვევებში, ბიოაკუმულირების შესახებ. მთლიანად ნარევთან დაკავშირებით არ არის წარმოდგენილი მონაცემები დეგრადირებისა და ბიოაკუმულირების შესახებ. ცდების შედეგები ნარევების დეგრადირებისა და ბიოაკუმულირების შესახებ არ გამოიყენება, ვინაიდან, როგორც წესი, ძნელია მათი ინტერპრეტაცია, და აღნიშნულ ცდებს შესაძლებელია ჰქონდეთ მნიშნელობა მხოლოდ ცალკეულ ნივთიერებებთან დაკავშირებით. 2.2.9.1.10.4.3.3 მწვავე ტოქსიკურობა 1-ის კატეგორიაში კლასიფიცირება (ა) იმ შემთხვევაში, თუ წარმოდგენილია ცდების შედეგად მიღებული საკმარისი მონაცემები მწვავე ტოქსიკურობასთან დაკავშირებით (LC50 ან EC50) მთლიანი ნარევისთვის, რომლის თანახმად L(E)C50 < 1 მგ/ლ; მოახდინეთ ნარევის კლასიფიცირება მწვავე ტოქსიკურობა 1-ის კატეგორიაში 2.2.9.1.10.3.1 (ა) ცხრილის შესაბამისად; (ბ) იმ შემთხვევაში, თუ წარმოდგენილია საკმარისი მონაცემები მწვავე ტოქსიკურობასთან დაკავშირებით (LC50 ან EC50) მთლიანი ნარევისთვის, რომლის თანახმად L(E)C50 > 1 მგ/ლ ან წყალში ხსნადობის ზემოაღნიშნულ მაჩვენებელს; არ არის აუცილებელი მწვავე საშიშროების კლასიფიცირება ADR-ის შესაბამისად. კატეგორიაში ნარევის 2.2.9.1.10.4.3.4 ქრონიკული ტოქსიკურობა 1-სა და 2-ის კატეგორიებში ნარევების კლასიფიცირება (ა) იმ შემთხვევაში, თუ წარმოდგენილია ქრონიკული ტოქსიკურობის შესახებ საკმარისი მონაცემები (ECX ან NOEC) მთლიან ნარევთან დაკავშირებით, რომლის თანახმადაც იმ ნარევის ECX ან NOEC, რომელზეც ჩატარდა ცდა, < 1 მგ/ლ: 333 (ბ) (i) მოახდინეთ ნარევის კლასიფიკაცია ქრონიკული ტოქსიკურობა 1 ან 2ის კატეგორიაში 2.2.9.1.10.3.1(ბ) (ii) (სწრაფი დეგრადირების უნარის მქონე) ცხრილის შესაბამისად იმ შემთხვევაში, თუ ხელთ არსებული ინფორმაცია უზრუნველყოფს იმ დასკვნის გაკეთებას, რომ მოცემული ნარევი სწრაფად დეგრადირებადია; (ii) მოახდინეთ ნარევის კლასიფიკაცია ქრონიკული ტოქსიკურობა 1 ან 2ის კატეგორიაში ნებისმიერ სხვა შემთხვევაში 2.2.9.1.10.3.1(ბ) (i) (სწრაფი დეგრადირების უნარის არმქონე) ცხრილის შესაბამისად. იმ შემთხვევაში, თუ წარმოდგენილია საკმარისი მონაცემები ქრონიკულ ტოქსიკურობასთან დაკავშირებით (ECX ან NOEC) მთლიანი ნარევისთვის, რომლის თანახმად იმ ნარევის ECX ან NOEC, რომელზეც ჩატარდა ცდა, > 1 მგ/ლ ან წყალში ხსნადობის ზემოაღნიშნულ მაჩვენებელს; არ არის აუცილებელი ხანგრძლივი საშიშროების კატეგორიაში ნარევის კლასიფიცირება ADR-ის შესაბამისად. 2.2.9.1.10.4.4 ნარევების კლასიფიკაცია, როდესაც მთლიან ნარევთან დაკავშირებით არ არის წარმოდგენილი მონაცემები ტოქსიკურობის შესახებ: ექსტრაპოლირების პრინციპები 2.2.9.1.10.4.4.1 იმ შემთხვევაში, თუ თავად ნარევზე არ განხორციელებულა ცდა წყლის გარემოში მისი საშიშროების განსაზღვრის მიზნით, მაგრამ არსებობს საკმარისი მონაცემები ინდივიდუალური კომპონენტებისა და მსგავს, გამოცდილ ნარევებთან დაკავშირებით, აღნიშნული ნარევის საშიშროების სათანადოდ დასახასიათებლად, აღნიშნული მონაცემების გამოყენება მოხდება შემდეგი, შეთანხმებული ექსტრაპოლირების წესების შესაბამისად. აღნიშნული უზრუნველყოფს კლასიფიკაციის პროცესში დიდი მოცულობით ხელთ არსებული ინფორმაციის გამოყენების შესაძლებლობას ნარევების საშიშროებების დასახასიათებლად ცხოველებზე დამატებითი ცდების ჩატარების აუცილებლობის გარეშე. 2.2.9.1.10.4.4.2 გახსნა იმ შემთხვევაში, თუ ახალი ნარევი იქმნება საცდელი ნარევისა თუ ნივთიერების გახსნის შედეგად გამხსნელით, რომელიც კლასიფიცირებულია თანაბარი ან უფრო დაბალი საშიშროების კატეგორიაში წყლის გარემოში, ყველზე უმცირესი ტოქსიკურობის მქონე საწყის კომპონენტთან შედარებით და რომელიც, როგორც ვარაუდობენ, არ მოახდენს გავლენას სხვა კომპონენტების საშიშროებაზე წყლის გარემოში, შედეგად მიღებული ნაერთის კლასიფიცირება უნდა მოხდეს საწყისი საცდელი ნარევისა თუ ნივთიერების თანაბრად. ალტერნატივის სახით შესაძლებელია გამოყენებულ იქნეს 2.2.9.1.10.4.5 ქვეპუნქტში აღწერილი მეთოდი. 2.2.9.1.10.4.4.3 სხვაობა პროდუქციის პარტიებს შორის უნდა იქნეს ნავარაუდევი, რომ გამოცდილი პროდუქციის სერიის ტოქსიკურობა წყლის გარემოში არსებითად თანაბარია იგივე კომერციული პროდუქტის სხვა გამოუცდელი პროდუქციის სერიის ტოქსიკურობისა იმ შემთხვევაში, თუ იგი წარმოებულია იგივე მწარმოებლის მიერ ან მისი მეთვალყურეობის ქვეშ იმ შემთხვევების გარდა, როდესაც არსებობს საკმარისი მიზეზი იმ ფაქტის დასაჯერებლად, რომ წარმოდგენილია მნიშნელოვანი სხვაობა, რომელმაც შეცვალა 334 მოცემული გამოუცდელი პარტიის ტოქსიკურობა წყლის გარემოში. ამ შემთხვევაში, აუცილებელია ახალი კლასიფიკაციის განხორციელება. 2.2.9.1.10.4.4.4 იმ ნარევების კონცენტრაცია, რომლებიც კლასიფიცირებულია ყველაზე ტოქსიკურ კატეგორიებში (ქრონიკული ტოქსიკურობა 1 და მწვავე ტოქსიკურობა 1) იმ შემთხვევაში, თუ შემოწმებული ნარევი კლასიფიცირდება ქრონიკული ტოქსიკურობა 1-სა და /ან მწვავე ტოქსიკურობა 1-ის კატეგორიებში, ხოლოდ ნარევის კომპონენტების კონცენტრაცია, რომლებიც მიკუთვნებულია ზემოაღნიშნულ კატეგორიებს, ყველაზე კონცენტრირებული შეუმოწმებელი ნარევის კლასიფიკაცია უნდა მოხდეს იგივე კატეგორიაში, რომელშიც კლასიფიცირებულია საწყისი შემოწმებული ნარევი დამატებითი ტესტირების გარეშე. 2.2.9.1.10.4.4.5 ტოქსიკურობის ერთი კატეგორიის ფარგლებში ინტერპოლაცია იდენტური კომპონენტების მქონე სამი ნარევის (ა, ბ და გ) არსებობისას იმ შემთხვევაში, თუ ა და ბ ნარევებმა გაიარა გამოცდა და წარმოდგენილია ერთსა და იმავე ტოქსიკურობის კატეგორიაში, ხოლო შეუმოწმებელ გ ნარევს გააჩნია იგივე ტოქსიკოლოგიურად აქტიური კომპონენტები, როგორც ა და ბ ნარევებს, თუმცა გააჩნია ტოქსიკოლოგიურად აქტიური კომპონენტების კონცენტრაციები, რომლებიც წარმოადგენს შუალედურს ა და ბ ნარევებში წარმოდგენილ კონცენტრაციებთან დაკავშირებით, მაშინ ივარაუდება, რომ გ ნარევის იმყოფება იგივე კატეგორიაში, როგორც ა და ბ ნარევები. 2.2.9.1.10.4.4.6 არსებითად მსგავსი ნარევები (ა) წარმოდგენილია ორი ნარევი: (i) ა + ბ; (ii) გ + ბ; (ბ) ბ კომპონენტის კონცენტრაცია არსებითად მსგავსია ორივე ნარევისა; (გ) ა კომპონენტის კონცენტრაცია (i) ნარევში თანაბარია გ კომპონენტის კონცენტრაციისა (ii) ნარევში; (დ) წყლის გარემოში ა და გ ნარევების საშიშროების შესახებ მონაცემები ხელმისაწვდომი და არსებითად ეკვივალენტურია, ანუ ისინი წარმოდგენილია იგივე საშიშროების კატეგორიაში და არ არის მოსალოდნელი, რომ ზეგავლენას მოახდენს ბ ნარევის ტოქსიკურობაზე წყლის გარემოში. იმ შემთხვევაში, თუ (i) ან (ii) ნარევები უკვე კლასიფიცირებულია ცდებთან დაკავშირებული მონაცემების საფუძველზე, მაშინ სხვა ნარევი შესაძლებელია მიეკუთვნოს იგივე საშიშროების კატეგორიას. 2.2.9.1.10.4.5 ნარევების კლასიფიკაცია, როდესაც ტოქსიკურობის წარმოდგენილია ნარევის ყველა კომპონენტთან ან კომპონენტებთან დაკავშირებით. შესახებ მონაცემები მხოლოდ გარკვეულ 2.2.9.1.10.4.5.1 ნარევის კლასიფიკაცია ეფუძნება მისი კლასიფიცირებული კომპონენტების კონცენტრაციების შეჯამებას. იმ კომპონენტების პროცენტული თანაფარდობა, რომლებიც კლასიფიცირებულია, როგორც „მწვავე ტოქსიკური“ ან „ქრონიკულად 335 ტოქსიკური“, უშუალოდ იყენებს შეჯამების მეთოდს. დეტალური ინფორმაცია შეჯამების მეთოდის შესახებ აღწერილია 2.2.9.1.10.4.6.1-დან 2.2.9.1.10.4.6.4 ქვეპუნქტებში. 2.2.9.1.10.4.5.2 ნარევები შესაძლებელია შედგებოდეს როგორც ორივე კლასიფიცირებული კომპონენტის (მწვავე ტოქსიკურობა 1 და/ან მწვავე ტოქსიკურობა 1,2 კატეგორიები) კომბინაციისგან, ასევე იმ კომპონენტებისგან, რომლებთან დაკავშირებითაც ცდების განხორციელების გზით მიღებულია საკმარისი მონაცემები ტოქსიკურობის შესახებ. იმ შემთხვევაში, თუ წარმოდგენილია საკმარისი მონაცემები ნარევში ერთზე მეტი კომპონენტის ტოქსიკურობის შესახებ, აღნიშნული კომპონენტების კომბინირებული ტოქსიკურობის გაანგარიშება მოხდება შემდეგი (ა) ან (ბ) ადიტიურობის ფორმულის გამოყენებით, ტოქსიკურობის შესახებ მონაცემების ხასიათზე დაყრდნობით: (ა) წყლის გარემოში მწვავე ტოქსიკურობის საფუძველზე: სადაც: Ci = i კომპონენტის კონცენტრაცია (პროცენტული თანაფარდობა მასის მიხედვით); L(E)C50i = i კომპონენტის LC50 ან EC50 (მგ/ლ); n = კომპონენტების რაოდენობა, i მოქმედებს 1-დან n-მდე; ნაწილის L(E)C50, რომელთან L(E)C50m = ნარევის წარმოდგენილია ცდების მონაცემები; დაკავშირებითაც გაანგარიშებული ტოქსიკურობის გამოყენება უნდა მოხდეს ნარევის აღნიშნული ნაწილის მისაკუთვნებლად მწვავე საშიშროების კატეგორიისთვის, რომელიც შემდგომში გამოიყენება შეჯამების მეთოდში; (ბ) წყლის გარემოში ქრონიკული ტოქსიკურობის საფუძველზე: ∑Ci + ∑Cj = ∑ Ci +∑ Cj n NOECi n 0.1 ∙ NOECj EqNOECm . . . . სადაც: Ci = i კომპონენტის კონცენტრაცია (პროცენტული თანაფარდობა მასის მიხედვით), რომელიც მოიცავს სწრაფი დეგრადირების უნარის მქონე კომპონენტებს; Cj = j კომპონენტის კონცენტრაცია (პროცენტული თანაფარდობა მასის მიხედვით), რომელიც მოიცავს სწრაფი დეგრადირების უნარის არმქონე კომპონენტებს; NOECi = NOEC (ან ქრონიკული ტოქსიკურობის სხვა აღიარებული მაჩვენებლები), იმ i კომპონენტთან დაკავშირებით, რომელიც მოიცავს სწრაფი დეგრადირების უნარის მქონე კომპონენტებს, მგ/ლ-ში; 336 NOECj = NOEC (ან ქრონიკული ტოქსიკურობის სხვა აღიარებული მაჩვენებლები), იმ j კომპონენტთან დაკავშირებით, რომელიც მოიცავს სწრაფი დეგრადირების უნარის არმქონე კომპონენტებს, მგ/ლ-ში; n კომპონენტების რაოდენობა, i და j მოქმედებენ 1-დან n-მდე; = EqNOECm = ნარევის ნაწილის NOEC ეკვივალენტი, რომელთან დაკავშირებითაც წარმოდგენილია ცდების მონაცემები; აღნიშნული სახით ეკვივალენტური ტოქსიკურობა ასახავს იმ ფაქტს, რომ სწრაფი დეგრადირების უნარის არმქონე ნივთიერებები კლასიფიცირებულნი არიან საშიშროების კატეგორიაში, რომელიც ერთი დონით მაღლა დგას „სიმწვავის“ მიხედვით სწრაფად დეგრადირებულ ნივთიერებებთან შედარებით. გაანგარიშებული ეკვივალენტური ტოქსიკურობის გამოყენება უნდა მოხდეს ნარევის აღნიშნული ნაწილის მისაკუთვნებლად ხანგრძლივი საშიშროების კატეგორიისთვის, სწრაფად დეგრადირებად ნივთიერებებთან დაკავშირებით არსებული კრიტერიუმების შესაბამისად (ცხრილი 2.2.9.1.10.3.1(ბ)(ii)) რომელიც შემდგომში გამოიყენება შეჯამების მეთოდში. 2.2.9.1.10.4.5.3 იმ შემთხვევაში, თუ ნარევის ნაწილთან დაკავშირებით გამოიყენება ადიტიურობის ფორმულა, უმჯობესია ნარევის აღნიშნული ნაწილის ტოქსიკურობის გაანგარიშება მოხდეს ყოველი კომპონენტის ტოქსიკურობის მნიშვნელობების გამოყენებით, რომლებიც უკავშირდება ერთსა და იმავე ტაქსონომიურ ჯგუფებს (ანუ თევზებს, კიბოსებრთა სახეობებსა თუ წყალმცენარეებს) და შემდგომ ამისა გამოიყენება მიღებული ტოქსიკურობიდან უმაღლესი (ყველაზე დაბალი მნიშნელობა) (ანუ გამოიყენება სამი ჯგუფიდან ყველაზე მგრძნობიარე). თუმცა იმ შემთხვევაში, თუ ყოველი კომპონენტის ტოქსიკურობის შესახებ არსებული მონაცემები არ არის წარმოდგენილი იგივე ტაქსონომიურ ჯგუფში, ყოველი კომპონენტის ტოქსიკურობის მნიშვნელობის შერჩევა უნდა მოხდეს იგივე გზით, როგორც შეირჩევა ტოქსიკურობის მნიშვნელობები ნივთიერებების კლასიფიკაციასთან დაკავშირებით, ანუ გამოიყენება ყველაზე მაღალი ტოქსიკურობა (ყველაზე მგრძნობიარე საცდელი ორგანიზმიდან). შემდგომ ამისა გამოიყენება გაანგარიშებული მწვავე და ქრონიკული ტოქსიკურობა ნარევის აღნიშნული ნაწილის მწვავე ტოქსიკურობა 1-ისა და/ან ქრონიკული ტოქსიკურობა 1 ან 2-ის კატეგორიაში კლასიფიცირების მიზნით ნივთიერებებთან დაკავშირებით აღწერილი იგივე კრიტერიუმების გამოყენებით. 2.2.9.1.10.4.5.4 იმ შემთხვევაში, თუ ნარევი კლასიფიცირებულია ერთზე მეტი მეთოდით, გამოყენებულ უნდა იქნეს ყველაზე კონსერვატიული შედეგის მომცემი მეთოდი. 2.2.9.1.10.4.6 შეჯამების მეთოდი 2.2.9.1.10.4.6.1 კლასიფიკაციის პროცედურა როგორც წესი, ნარევების უფრო მკაცრი კალსიფიკაცია ცვლის ნაკლებად მკაცრ კლასიფიკაციას, მაგალითად, კლასიფიკაცია „ქრონიკული ტოქსიკურობა 1“ კატეგორიაში ცვლის კლასიფიკაციას „ქრონიკული ტოქსიკურობა 2“ კატეგორიაში. შედეგად, კლასიფიკაციის პროცედურა უკვე სრულდება იმ შემთხვევაში, თუ კლასიფიკაცია განხორციელდება „ქრონიკული ტოქსიკურობა 1“ კატეგორიაში. 337 შეუძლებელია კიდევ უფრო მკაცრი კლასიფიკაცია, ვიდრე „ქრონიკული ტოქსიკურობა 1“ კატეგორიაა; აღნიშნულიდან გამომდინარე არ არის აუცილებელი კლასიფიკაციის პროცედურის გაგრძელება. 2.2.9.1.10.4.6.2 კლასიფიკაცია „მწვავე ტოქსიკურობა 1“ კატეგორიაში 2.2.9.1.10.4.6.2.1 უპირველეს ყოვლისა განიხილება „მწვავე ტოქსიკურობა 1“ კატეგორიაში კლასიფიცირებული ყველა კომპონენტი. იმ შემთხვევაში, თუ აღნიშნული კომპონენტების კონცენტრაციების ჯამი (%-ში) აღემატება ან ტოლია 25%-სა, მაშინ მთლიანი ნარევის კლასიფიკაცია ხდება „მწვავე ტოქსიკურობა 1“ კატეგორიაში. თუ გაანგარიშების შედეგად ნარევის კლასიფიკაცია მოხდება „მწვავე ტოქსიკურობა 1“ კატეგორიაში, კლასიფიკაციის პროცესი სრულდება. 2.2.9.1.10.4.6.2.2 ნარევების კლასიფიკაცია მწვავე საშიშროებებთან დაკავშირებით კლასიფიცირებული კომპონენტების კონცენტრაციების შეჯამების საფუძველზე მოკლედ გამოსახულია ქვემოთ წარმოდგენილ 2.2.9.1.10.4.6.2.2 ცხრილში. ცხრილი 2.2.9.1.10.4.6.2.2: ნარევების კლასიფიკაცია მწვავე საშიშროებებთან დაკავშირებით კლასიფიცირებული კომპონენტების კონცენტრაციების შეჯამების საფუძველზე ა კლასიფიცირებული კომპონენტების კონცენტრაციების ჯამი (%-ში) შემდეგ კატეგორიაში კლასიფიცირებული ნარევი „მწვავე ტოქსიკურობა 1“ X Mა X > 25% „მწვავე ტოქსიკურობა 1“ M ფაქტორის განმარტებასთან დაკავშირებით, იხილეთ 2.2.9.1.10.4.6.4 ქვეპუნქტი. 2.2.9.1.10.4.6.3 კლასიფიკაცია „ქრონიკული ტოქსიკურობა 1 და 2“ კატეგორიაში 2.2.9.1.10.4.6.3.1 უპირველეს ყოვლისა განიხილება „ქრონიკული ტოქსიკურობა 1“ კატეგორიაში კლასიფიცირებული ყველა კომპონენტი. იმ შემთხვევაში, თუ აღნიშნული კომპონენტების კონცენტრაციების ჯამი (%-ში) აღემატება ან ტოლია 25%-სა, მაშინ მთლიანი ნარევის კლასიფიკაცია ხდება „ქრონიკული ტოქსიკურობა 1“ კატეგორიაში. თუ გაანგარიშების შედეგად ნარევის კლასიფიკაცია მოხდება „ქრონიკული ტოქსიკურობა 1“ კატეგორიაში, კლასიფიკაციის პროცესი სრულდება. 2.2.9.1.10.4.6.3.2 იმ შემთხვევაში, თუ ნარევი არ მიეკუთვნება „ქრონიკული ტოქსიკურობა 1“ კატეგორიას, განიხილება ნარევის კლასიფიკაცია „ქრონიკული ტოქსიკურობა 2“ კატეგორიაში. ნარევის კლასიფიკაცია უნდა მოხდეს „ქრონიკული ტოქსიკურობა 2“ კატეგორიაში იმ შემთხვევაში, თუ „ქრონიკული ტოქსიკურობა 1“ კატეგორიაში კლასიფიცირებული ყველა კომპონენტის კონცენტრაციის (%-ში) 10-ჯერადი ჯამს პლიუს „ქრონიკული ტოქსიკურობა 2“ კატეგორიაში კლასიფიცირებული ყველა კომპონენტის კონცენტრაციის (%-ში) ჯამი აღემატებია ან ტოლია 25%-სა. იმ შემთხვევაში, თუ გაანგარიშების შედეგს წარმოადგენს ნარევის „ქრონიკული ტოქსიკურობა 2“ კატეგორიაში კლასიფიკაცია, კლასიფიკაციის პროცესი სრულდება. 338 2.2.9.1.10.4.6.3.3 ნარევების კლასიფიკაცია ხანგრძლივ საშიშროებებთან დაკავშირებით კლასიფიცირებული კომპონენტების კონცენტრაციების შეჯამების საფუძველზე მოკლედ გამოსახულია ქვემოთ წარმოდგენილ 2.2.9.1.10.4.6.3.3 ცხრილში. ცხრილი 2.2.9.1.10.4.6.3.3: ნარევების კლასიფიკაცია ხანგრძლივ საშიშროებებთან დაკავშირებით კლასიფიცირებული კომპონენტების კონცენტრაციების შეჯამების საფუძველზე კლასიფიცირებული კომპონენტების შემდეგ კატეგორიაში კონცენტრაციების ჯამი (%-ში) კლასიფიცირებული ნარევი „ქრონიკული ტოქსიკურობა 1“ X Mა > 25% „ქრონიკული ტოქსიკურობა 1“ (M X 10 X „ქრონიკული ტოქსიკურობა 1“ + „ქრონიკული ტოქსიკურობა 2“ „ქრონიკული ტოქსიკურობა 2“ > 25% ა M ფაქტორის განმარტებასთან დაკავშირებით, იხილეთ 2.2.9.1.10.4.6.4 ქვეპუნქტი. 2.2.1.9.10.4.6.4 მაღალტოქსიკური კომპონენტების მქონე ნარევები „მწვავე ტოქსიკურობა 1“ ან „ქრონიკული ტოქსიკურობა 1“ კატეგორიაში გათვალისწინებულმა კომპონენტებმა, რომელთა მწვავე ტოქსიკურობა საყურადღებოდ ჩამოუვარდება 1მგ/ლ-ს და/ან ქრონიკული ტოქსიკურობა საყურადღებოდ ჩამოუვარდება 0.1 მგ/ლ-ს (იმ შემთხვევაში, თუ არ გააჩნია სწრაფი დეგრადირების უნარი) და 0.01 მგ/ლ-ს (იმ შემთხვევაში, თუ გააჩნია სწრაფი დეგრადირების უნარი), შესაძლებელია გავლენა მოახდინოს ნარევების ტოქსიკურობაზე და მათ ენიჭებათ უფრო დიდი მნიშვნელობა შეჯამების მეთოდის გამოყენებისას. იმ შემთხვევაში, თუ ნარევი შეიცავს „მწვავე ტოქსიკურობა 1“ ან „ქრონიკული ტოქსიკურობა 1“ კატეგორიაში კლასიფიცირებულ კომპონენტს, გამოყენებულ უნდა იქნეს 2.2.9.1.10.4.6.2 და 2.2.9.1.10.4.6.3 ქვეპუნქტებში აღწერილი სართულოვანი მიდგომა „მწვავე ტოქსიკურობა 1“ ან „ქრონიკული ტოქსიკურობა 1“ კატეგორიაში კლასიფიცირებული კომპონენტების კონცენტრაციების გამრავლების გზით შესაბამის ფაქტორზე, შეწონილი ჯამის მისაღებად, პროცენტების მარტივი დამატების ნაცვლად. აღნიშნული გულისხმობს, რომ 2.2.9.1.10.4.6.2.2 ცხრილის მარცხენა სვეტში წარმოდგენილ „მწვავე ტოქსიკურობა 1“ კატეგორიის კონცენტრაცია და 2.2.9.1.10.4.6.3.3 ცხრილის მარცხენა სვეტში წარმოდგენილი „ქრონიკული ტოქსიკურობა 1“ კატეგორიის კონცენტრაცია მრავლდება შესაბამის მამრავლ ფაქტორზე. აღნიშნულ კომპონენტებთან დაკავშირებით გამოსაყენებელი მამრავლი ფაქტორები განისაზღვრება ტოქსიკურობის მნიშვნელობის გამოყენებით, როგორც ეს მოკლედ არის წარმოდგენილი ქვემოთ მოყვანილ 2.2.9.1.10.4.6.4 ცხრილში. აღნიშნულიდან გამომდინარე, „მწვავე ტოქსიკურობა 1“ და/ან „ქრონიკული ტოქსიკურობა 1“ კატეგორიაში კლასიფიცირებული კომპონენტების შემცველი ნარევების კლასიფიცირებისთვის, კლასიფიკატორმა უნდა იცოდეს M ფაქტორის მნიშვნელობა შეჯამების მეთოდის გამოყენების მიზნით. ალტერნატივის სახით, შესაძლებელია გამოყენებულ იქნეს ადიტიურობის ფორმულა (იხილეთ 2.2.9.1.10.4.5.2 ქვეპუნქტი) იმ შემთხვევაში, თუ ნარევში წარმოდგენილი ყველა მაღალტოქსიკური კომპონენტის ტოქსიკურობის შესახებ წარმოდგენილია მონაცემები და არსებობს სარწმუნო მტკიცებულება იმისა, რომ ყველა დანარჩენი კომპონენტი - იმ კომპონენტების ჩათვლით, რომლებთან დაკავშირებითაც არ არის 339 წარმოდგენილი კონკრეტული მონაცემები მწვავე და/ან ქრონიკული ტოქსიკურობის შესახებ - წარმოადგენს დაბატოქსიკურ ან საერთოდ არ აღენიშნებათ ტოქსიკურობა და არ უწყობს ხელს მნიშნელოვნად ნარევის საშიშროების ზრდას გარემოს მიმართ. ცხრილი 2.2.9.1.10.4.6.4: ნარევების მაღალტოქსიკური კომპონენტების მამრავლი ფაქტორები მწვავე ტოქსიკურობა L(E)C50 მნიშვნელობა M ფაქტორი 0.1<L(E)C50<1 1 0.01<L(E)C50<0.1 10 0.001<L(E)C50<0.01 100 0.0001<L(E)C50<0.001 1 000 0.00001<L(E)C50<0.0001 10 000 (გააგრძელეთ ათჯერადი ინტერვალებით) ა ბ ქრონიკული ტოქსიკურობა NOEC მნიშვნელობა M ფაქტორი NRDა RDბ კომპონენტები კომპონენტები 0.01<NOEC<0.1 1 0.001<NOEC<0.01 10 1 0.0001<NOEC<0.001 100 10 0.00001<NOEC<0.0001 1 000 100 0.000001<NOEC<0.00001 10 000 1 000 (გააგრძელეთ ათჯერადი ინტერვალებით) სწრაფი დეგრადაციის უნარის არმქონე სწრაფი დეგრადაციის უნარის მქონე 2.2.9.1.10.4.6.5 იმ კომპონენტების შემცველი ნარევების კლასიფიკაცია, რომელთა შესახებაც არ არის წარმოდგენილი რაიმე სასარგებლო ინფორმაცია იმ შემთხვევაში, თუ ერთ ან რამდენიმე შესაბამის კომპონენტთან დაკავშირებით არ არის წარმოდგენილი წყლის გარემოში მწვავე და/ან ქრონიკული ტოქსიკურობის შესახებ რაიმე სასარგებლო ინფორმაცია, მიღებულ უნდა იქნეს დასკვნა, რომ აღნიშნული ნარევის მიკუთვნება შეუძლებელია (ა) განსაზღვრულ საშიშროების კატეგორიაზე (კატეგორიებზე). მოცემულ სიტუაციაში, ნარევების კლასიფიკაცია უნდა განხორციელდეს ცნობილი კომპონენტების მიხედვით და უნდა გაკეთდეს მხოლოდ შესაბამისი ჩანაწერი: „ნარევის x პროცენტი შედგება წყლის გარემოს მიმართ უცნობი საშიშროების მატარებელი კომპონენტ(ებ)ისგან“. 2.2.9.1.10.5 გარემოსთვის (წყლის გარემოსთვის) სახიფათო ნივთიერებების სახით 1272/2008/EC16 რეგლამენტის საფუძველზე კლასიფიცირებული ნივთიერებები ან ნარევები იმ შემთხვევაში, თუ წარმოდგენილი არ არის მონაცემები კლასიფიკაციის შესახებ 2.2.9.1.10.3 და 2.2.9.1.10.4 ქვეპუნქტებში გათვალისწინებული კრიტერიუმების შესაბამისად, ნივთიერება თუ ნაკეთობა: (ა) კლასიფიცირებულ უნდა იქნეს გარემოსთვის (წყლის გარემოსთვის) სახიფათო ნივთიერების სახით იმ შემთხვევაში, თუ მათი მიკუთვნება უნდა მომხდარიყო „წყლის მწვავე ტოქსიკურობა 1“, „წყლის ქრონიკული ტოქსიკურობა 1“ ან „წყლის ქრონიკული ტოქსიკურობა 2“ კატეგორიებში 1272/2008/EC16 რეგლამენტის საფუძველზე, ან თუ კვლავ შეესაბამება აღნიშნულ რეგლამენტს, R50, R50/53 ან R51/53 რისკის კლას(ებ)ში 67/548/EEC3 ან 199/45/EC4 დირექტივების შესაბამისად. 340 ევროპარლამენტისა და საბჭოს 2008 წლის 16 დეკემბრის 1272/2008/EC რეგლამენტი ნივთიერებებისა და ნარევების კლასიფიკაციის, მარკირებისა და შეფუთვის შესახებ (ევროკავშირის ოფიციალური ჟურნალი №L353, 2008 წლის 30 დეკემბერი). 3 საბჭოს 1967 წლის 27 ივნისის 67/548/EEC დირექტივა სახიფათო ნივთიერებების კლასიფიკაციასთან, შეფუთვასა და მარკირებასთან დაკავშირებულ კანონებთან, განაწესებსა და ადმინისტრაციულ დებულებეთან მიახლოვების შესახებ (ევროპული გაერთიანების ოფიციალური ჟურნალი №L196, 16.08.1967 წ,). 4 ევროპარლამენტისა და საბჭოს 1999 წლის 31 მაისის 1999/45/EC დირექტივა სახიფათო პრეპარატების კლასიფიკაციასთან, შეფუთვასა და მარკირებასთან დაკავშირებული წევრი სახელმწიფოების შესახებ კანონებთან, განაწესებსა და ადმინისტრაციულ დებულებებთან მიახლოების შესახებ (ევროპული გაერთიანების ოფიციალური ჟურნალი №L200, 1999 წლის 30 ივლისი). 16 (ბ) 2.2.9.1.10.6 შესაძლებელია მიჩნეულ იქნეს ნივთიერებად, რომელიც არ წარმოადგენს საშიშროებას გარემოსთვის (წყლის გარემოსთვის) იმ შემთხვევაში, თუ მათი მიკუთვნება არ უნდა მომხდარიყო აღნიშნული დირექტივებისა თუ რეგლამენტის თანახმად მითითებულ რისკის კლასსა თუ კატეგორიაზე. გარემოსთვის (წყლის გარემოსთვის) სახიფათო ნივთიერებების სახით კლასიფიცირებული ნივთიერებებისა და ნარევების მიკუთვნება 2.2.9.1.10.3, 2.2.9.1.10.4 ან 2.2.9.1.10.5 ქვეპუნქტების შესაბამისად გარემოსთვის (წყლის გარემოსთვის) სახიფათო ნივთიერებების სახით კლასიფიცირებული ნივთიერებები და ნარევები, რომლებიც არ არის კლასიფიცირებული ADR-ის თანახმად, უნდა მიეკუთვნონ: გაეროს N3077 - გარემოსთვის სახიფათო ნივთიერებები, მყარი, N.O.S. ან გაეროს N3082 - გარემოსთვის სახიფათო ნივთიერებები, თხევადი, N.O.S. მათი კლასიფიცირება უნდა მოხდეს III შეფუთვის ჯგუფში. გენეტიკურად მოდიფიცირებული მიკროორგანიზმები ან ორგანიზმები 2.2.9.1.11 გენეტიკურად მოდიფიცირებული მიკროორგანიზმები (გმმ) და გენეტიკურად მოდიფიცირებული ორგანიზმები (გმო) წარმოადგენს მიკროორგანიზმებსა და ორგანიზმებს, რომელთა გენეტიკური მასალა განზრახ იქნა შეცვლილი გენური ინჟინერიის საშუალებით იმ პროცესების გამოყენებით, რომლებიც არ ხდება ბუნებრივად. მათი კლასიფიცირება ხდება მე-9 კლასში (გაეროს N3245) იმ შემთხვევაში, თუ ისინი არ აკმაყოფილებს ტოქსიკური ნივთიერებებისა თუ ინფექციური ნივთიერებების განმარტებებს, თუმცა შეუძლია გამოიწვის ცხოველებში, მცენარეებსა თუ მიკრობიოლოგიურ ნივთიერებებში ისეთი ცვლილებები, რომლებიც არ წარმოადგენს ბუნებრივი გამრავლების შედეგებს. შენიშვნა 1: გმმ და გმო, რომლებიც ატარებს ინფექციურ ხასიათს, წარმოადგენს 6.2 კლასის ნივთიერებას გაეროს ნომრებით 2814, 2900 ან 3373. შენიშვნა 2: ADR-ის დებულებები არ ვრცელდება გმმ-სა თუ გმო-ზე იმ შემთხვევაში, თუ მათი გამოყენება ნებადართულია წარმოშობის, ტრანზიტისა და დანიშნულების ქვეყნების კომპეტენტური ორგანოების მიერ17. შენიშვნა 3: დაუშვებელია ცოცხალი ცხოველების გამოყენება მე-9 კლასში კლასიფიცირებული გენეტიკურად მოდიფიცირებული მიკროორგანიზმების გადასაზიდად, გარდა იმ შემთხვევებისა, როდესაც შეუძლებელია აღნიშნული ნივთიერებების გადატანა სხვა გზით. გენეტიკურად მოდიფიცირებული ცოცხალი 341 ცხოველების გადაყვანა უნდა განხორციელდეს წარმოშობისა და დანიშნულების ქვეყნების კომპეტენტური ორგანოების მიერ დადგენილი პირობებით. 2.2.9.1.12 (ამოღებულია) კონკრეტულად იხილეთ ევროპარლამენტისა და საბჭოს 2001/18/EC დირექტივის გ ნაწილი გენეტიკურად მოდიფიცირებული ორგანიზმების გარემოში წინასწარ, განზრახ გაშვების შესახებ, ასევე საბჭოს 90/220/EEC ანულირებული დირექტივა (ევროპული გაერთიანების ოფიციალური ჟურნალი №L106, 2001 წლის 17 აპრილი), სადაც მოყვანილია ევროპული გაერთიანების შემავალი ქვეყნებისთვის ნებართვის გაცემის პროცედურები. 17 მაღალი ტემპერატურის მქონე ნივთიერებები 2.2.9.1.13 მაღალი ტემპერატურის მქონე ნივთიერებები მოიცავს ნივთიერებებს, რომელთა გადაზიდვა ან გადასაზიდად გადაცემა ხორციელდება თხევად მდგომარეობაში 1000C ან უფრო მაღალ ტემპერატურაზე, ხოლო იმ შემთხვევაში, თუ მათ აღენიშნებათ აფეთქების ტემპერატურა, მათი აფეთქების ტემპერატურაზე დაბალ ტემპერატურაზე. ისინი ასევე გულისხმობს მყარ ნივთიერებებს, რომელთაც გადაზიდვაც ან გადასაზიდად გადაცემა ხორციელდება 2400C ან უფრო მაღალ ტემპერატურაზე. შენიშვნა: მაღალი ტემპერატურის მქონე ნივთიერებების კლასიფიცირება შესაძლებელია მე-9 კლასში მხოლოდ იმ შემთხვევაში, თუ ისინი არ აკმაყოფილებს ნებისმიერი სხვა კლასის კრიტერიუმებს. სხვა ნივთიერებები, რომლებიც წარმოადგენს საშიშროებას გადაზიდვების დროს, თუმცა არ აკმაყოფილებს სხვა კლასით გათვალისწინებულ განსაზღვრებებს. 2.2.9.1.14 ქვემოთ წარმოდგენილი სხვადასხვა ნივთიერებები, რომლებიც არ აკმაყოფილებენ სხვა კლასით გათვალისწინებულ განსაზღვრებებს, კლასიფიცირდება მე-9 კლასში: 600C-ზე დაბალი აფეთქების ტემპერატურის მქონე მყარი ამონიუმის ნარევები; უმნიშვნელო საშიშროების მქონე დითიონიტები; მაღალი აქროლადობის მქონე სითხეები; შხამიანი ორთქლის გამომყოფი ნივთიერებები; ალერგენების შემცველი ნივთიერებები; ქიმიური ნივთიერებების კომპლექტები და პირველადი დახმარების კომპლექტები; ორმაგი ელექტრო შრის ენერგომოცულობით) მქონე კონდენსატორები (0.3 ვტ/სთ-ზე მეტი შენიშვნა: ADR-ის დებულებები არ ვრცელდება შემდეგზე: გაეროს N1845 ნახშირბადის დიოქსიდი, მყარი (მშრალი ყინული),18 გაეროს N2071 - ამონიუმის ნიტრატის სასუქები, გაეროს N2216 თევზის საკვები (თევზის ნარჩენები), სტაბილიზებული, გაეროს N2807 - დამაგნიტებული მასალა, გაეროს N3166 შიგაწვის ძრავა ან 3166 - ადვილაალებად აირზე მომუშავე ავტოსატრანსპორტო საშუალებები ან 3166 - ადვილაალებად სითხეზე მომუშავე ავტოსატრანსპორტო საშუალებები ან 3166 - ადვილაალებადი აირის შემცველ საწვავ ელემენტებზე მომუშავე ძრავა ან 3166 - ადვილაალებადი სითხის შემცველ საწვავ ელემენტებზე 342 მომუშავე ძრავა ან 3166 - ადვილაალებადი აირის შემცველ საწვავ ელემენტებზე მომუშავე ავტოსატრანსპორტო საშუალებები ან 3166 - ადვილაალებადი აირის შემცველ სითხეზე მომუშავე ავტოსატრანსპორტო საშუალებები, გაეროს N3171 აკუმულატორის ბატარეებზე მომუშავე ავტოსატრანსპორტო საშუალებები ან 3171 აკუმულატორის ბატარეებზე მომუშავე აღჭურვილობა (თხევადი ელემენტების ბატარეები), გაეროს N3334 - სითხე, რომლის საჰაერო გზით გადაზიდვასაც არეგულირებს შესაბამისი წესები, N.O.S. გაეროს N3335 - მყარი ნივთიერებები, გაეროს №1845 - ნახშირბადის დიოქსიდი, მყარი (მშრალი ყონული), რომელიც გამოიყენება მაცივებელი საშუალების სახით, დაკავშირებით, იხილეთ 5.5.3 პუნქტი. 18 რომელთა საჰაერო გზით გადაზიდვასაც არეგულირებს შესაბამისი წესები, N.O.S. და გაეროს N3363 - სახიფათო ტვირთები იმ მოწყობილობებში ან სახიფათო ტვირთები იმ აპარატურაში, რომელთა ჩამონათვალიც მოცემულია გაეროს ტიპიურ დებულებებში. შეფუთვის ჯგუფზე მიკუთვნება 2.2.9.1.15 2.2.9.2 იმ შემთხვევაში, თუ მითითებულია 3.2 თავის A ცხრილის (4) სვეტში, მე-9 კლასით გათვალისწინებული ნივთიერებებისა და ნაკეთობების მიკუთვნება ხდება შემდეგ შეფუთვის ჯგუფებზე მათი საშიშროების ხარისხის მიხედვით: II შეფუთვის ჯგუფი: საშუალო ხარისხის საშიშროების მქონე ნივთიერებები III შეფუთვის ჯგუფი: დაბალი ხარისხის საშიშროების მქონე ნივთიერებები ნივთიერებები და ნაკეთობები, რომლებიც არ დაიშვება გადაზიდვებზე შემდეგი ნივთიერებები და ნაკეთობები არ დაიშვება გადაზიდვებზე: - ლითიუმის ბატარეები, რომლებიც არ აკმაყოფილებს 3.3 თავის 188-ე, 230-ე ან 636-ე სპეციალური დებულებებით გათვალისწინებულ შესაბამის პირობებს; - გაუსუფთავებელი, ცარიელი კონტეინერები იმ აპარატურისთვის, როგორიცაა ტრანსფორმატორები, კონდენსატორები და ჰიდრავლიკური მოწყობილობები, რომლებიც შეიცავს გაეროს N2315, 3151, 3152 ან 3432 მიკუთვნებულ ნივთიერებებს. 343 2.2.9.3 პოზიციების ჩამონათვალი ნივთიერებები, რომელთა შესუნთქვამ წვრილი მტვრის სახით შესაძლებელია საფრთხე შეუქმნას სიცოცხლეს M1 2212 2590 ცისფერი აზბესტი, ამფიბოლური კროციდოლიტი) აზბესტი, ქრიზოტილი ნივთიერებები და აპარატურა, რომელთაც, ხანძრის შემთხვევაში, შეუძლიათ წარმოქმნას დიოქსინები M2 2315 3432 3151 3151 3152 3152 პოლიქლორბიფენილები, თხევადი პოლიქლორბიფენილები, მყარი პოლიჰალოგენირებული ბიფენილები, თხევადი, ან პოლიჰალოგენირებული ტერფენილები, თხევადი პოლიჰალოგენირებული ბიფენილები, მყარი, ან პოლიჰალოგენირებული ტერფენილები, მყარი ადვილაალებადი ორთქლის გამომყოფი ნივთიერებები 2211 3314 პოლიმერული ნაწიბურები, გრანულირებული, გამოჰყოფს ადვილაალებად ორთქლს პლასტმასის დაყალიბების შენაერთი, ცომისებრი მასის სახით, ფურცლისა თუ გაჭიმული თოკის ფორმით, გამოყოფს ადვილაალებად ორთქლს 3090 3091 ლითიუმის ლითონის ბატარეები (ლითიუმის შენადნობისგან დამზადებული ბატარეების ჩათვლით) ლითიუმის ბატარეები M3 3091 M4 3480 3481 3481 სამაშველო საშუალებები 2990 3072 M5 (ამოზიტი, ტრემოლიტი, აქტინოლიტი, ანტროფილიტი, აღჭურვილობაში წარმოდგენილი ლითიუმის ლითონის ბატარეები (ლითიუმის შენადნობისგან დამზადებული ბატარეების ჩათვლით), ან აღჭურვილობასთან ერთად შეფუთული ლითიუმის ლითონის ბატარეები (ლითიუმის შენადნობისგან დამზადებული ბატარეების ჩათვლით) ლითიუმის იონის ბატარეები (ლითიუმის იონის პოლიმერული ბატარეების ჩათვლით) აღჭურვილობაში წარმოდგენილი ლითიუმის იონის ბატარეები (ლითიუმის იონის პოლიმერული ბატარეების ჩათვლით), ან აღჭურვილობასთან ერთად შეფუთული ლითიუმის იონის ბატარეები (ლითიუმის იონის პოლიმერული ბატარეების ჩათვლით) სამაშველო საშუალებები, თვით-ტუმბვადი სამაშველო საშუალებები, არა-თვითტუმბვადი, შეიცავს სახიფათო ტვირთებს აღჭურვილობის სახით უსაფრთხოების მოწყობილობები, ელექტრო ინიცირებით 3268 წყლის გარემოს გამაბინძურებელი თხევადი ნივთიერებები M6 გარემოსთვის სახიფათო ნივთიერებები წყლის გარემოს გამაბინძურებელი მყარი ნივთიერებები გენეტიკურად მოდიფიცირებული მიკროორგანიზმები და ორგანიზმები თხევადი გარემოსთვის სახიფათო ნივთიერება, თხევადი, N.O.S. 3077 გარემოსთვის სახიფათო ნივთიერება, მყარი, N.O.S. 3245 3245 გენეტიკურად მოდიფიცირებული მიკროორგანიზმები, ან გენეტიკურად მოდიფიცირებული ორგანიზმები 3257 მომატებული ტემპერატურის მქონე თხევადი ნივთიერება, N.O.S. 1000C ან უფრო მაღალ ტემპერატურაზე და მისი აფეთქების ტემპერატურის ქვემოთ(მდნარი ლითონის, მდნარი მარილებისა და ა.შ. ჩათვლით) 3258 მომატებული ტემპერატურის მქონე მყარი ნივთიერება, N.O.S. 2400C ან უფრო მაღალ ტემპერატურაზე M7 M8 M9 მომატებული ტემპერატურის მქონე ნივთიერებები მყარი 3082 M10 სხვა ნივთიერებები თუ ნაკეთობები, რომლებიც წარმოადგენს საშიშროებას გადაზიდვების დროს, თუმცა არ შეესაბამება სხვა კლასის განმარტებებს M11 წარმოდგენილი არ არის ერთობლივი პოზიცია. მე-9 კლასის დებულებებს ექვემდებარება მხოლოდ 3.2 თავის A ცხრილში გათვალისწინებული ნივთიერებები შემდეგი კლასიფიკაციის კოდის ქვეშ: 1841 1931 1941 1990 2969 2969 2969 2969 3316 3316 3359 3499 3508 3509 აცეტალდეჰიდის ამონიუმი თუთიის დითიონიტი (თუთიის ჰიდროსულფიტი) დიბრომდიფტორმეთანი ბენზალდეჰიდი კასტორის პარკოსანნი, ან კასტორის ფქვილი, ან კასტორის კოპტონი, ან კასტორის ფანტელები ქიმიური ნივთიერებების კომპლექტი, ან პირველადი დახმარების კომპლექტი ფუმიგირებული ერთეული კონდენსატორი, ორმაგი ელექტრო შრით (არაუმეტეს 0.3 ვტ/სთ ელექტრომოცულობით) კონდენსატორი, ასიმეტრიული ელექტრო შრით (0.3 ვტ/სთ-ზე მეტი ელექტრომოცულობით) წუნდებული, ცარიელი, გაუსუფთავებელი ტარა 344 თავი 2.3 გამოცდის მეთოდები 2.3.0 ზოგადი დებულებები თუ სხვა რამ არ არის გათვალისწინებული 2.2 თავსა თუ წინამდებარე თავში, სახიფათო ტვირთების კლასიფიკაციისთვის გამოსაყენებელი ცდების მეთოდები აღწერილია ცდებისა და კრიტერიუმების სახელმძღვანელოში. 2.3.1 A ტიპის ბრიზანტული ფეთქებადი ნივთიერებების გამოცდა ექსუდაციაზე 2.3.1.1 A ტიპის ბრიზანტული ფეთქებადი ნივთიერებები (გაეროს N0081) იმ შემთხვევაში, თუ შეიცავენ 40%-ზე მეტ თხევად აზოტის ეთერს, ცდებისა და კრიტერიუმების სახელმძღვანელოში განსაზღვრულ ცდებთან ერთად, უნდა დააკმაყოფილონ შემდეგი ცდა ექსუდაციაზე. 2.3.1.2 ექსუდაციაზე ბრიზანტული ფეთქებადი ნივთიერებების გამოსაცდელი აპარატი (სურათი 1-3) შედგება ღრუ ბრინჯაოს ცილინდრისგან. აღნიშნული ცილინდრი, რომლის ერთი ბოლოც დახურულია იგივე ლითონის ფირფიტით, გააჩნია 15,7 მმ შიდა დიამეტრი და 40 მმ სიღრმე. ცილინდრის გარშემო წარმოდგენილია 0.5 მმ დიამეტრის 20 ხვრელი (ხუთი ხვრელის ოთხი წყება). ბრინჯაოს დგუში 48 მმ სიგრძის ცილინდრული ნაწილითა და 52 მმ საერთო სიგრძით, სრიალდება ვერტიკალურად განთავსებულ ცილინდრში. 15.6 მმ დიამეტრის მქონე დგუში იტვირთება 2 220 გ მასით ისე, რომ ცილინდრის საფუძველზე გამოყოფილმა წნევამ შეადგინოს 120 კპა (1.20 ბარი). 2.3.1.3 ბრიზანტული ფეთქებადი ნივთიერების 5 გრ-დან 8 გრ წონის, 30 მმ სიგრძისა და 15 მმ დიამეტრის გასართი გახვეულია ძალიან თხელ ლითონის ბადეში და მოთავსებულია ცილინდრში; დგუში და მისი დატვირთვის მასა მოთავსებულია მასზე ისე, რომ ბრიზანტული ფეთქებადი ნივთიერება დაექვემდებაროს 120 კპა (1.20 ბარ) წნევას. ცილინდრის ხვრელის გარე ნახვრეტზე ზეთოვანი წვეთების (ნიტროგლიცერინის) გამოჩენისთვის საჭირო დრო აღნიშნულია. 2.3.1.4 ბრიზანტული ფეთქებადი ნივთიერება ითვლება დამაკმაყოფილებლად იმ შემთხვევაში, თუ სითხის პირველ ექსუდაციამდე გავა ხუთ წუთზე მეტი დრო; ცდები ჩატარებულ იქნა 150C-დან 250C ტემპერატურაზე. 345 ბრიზანტული ფეთქებადი ნივთიერებების გამოცდა ექსუდაციაზე სურათი 1: ზარის ფორმის ტვირთი 2200 გრ მასით, რომელსაც შეუძლია ჩამოკიდებულ იქნეს ბრინჯაოს დგუშიდან. სურათი 2: ცილინდრული ბრინჯაოს დგუში, ზომები გამოსახულია მმ-ში სურათი 3: ღრუ ბრინჯაოს ცილინდრი, დახურული ერთ ბოლოზე; გეგმა და დეტალების ზომები წარმოდგენილია მმ-ში სურათი 1-3 (1) 5 ხვრელის 4 რიგი 0.5N-ზე (2) სპილენძი (3) რკინის ფირფიტა ცენტრალური კონუსით შიდა მხარეზე; (4) 4 ნახვრეტი დაახლოებით 46x56 ზომის, განთავსებული პერიფერიული უბნის თანაბარ ინტერვალებზე. 346 2.3.2 4.1 კლასის ნიტროცელულოზას ნარევებთან დაკავშირებული ცდები 2.3.2.1 ნიტროცელულოზამ 1320C ტემპერატურაზე ნახევარი საათის განმავლობაში გახურებისას, არ უნდა გამოყოს ხილული მოყვითალო-ყავისფერი აზოტის ბოლი (აზოტის აირები). აალების ტემპერატურა უნდა იყოს 1800C-ზე მეტი. იხილეთ ქვემოთ მოყვანილი 2.3.2.3-2.3.2.8, 2.3.2.9(ა) და 2.3.2.10 პუნქტები. 2.3.2.2 3 გრამ პლასტიფიცირებულმა ნიტროცელულოზამ, 1320C ტემპერატურაზე ნახევარი საათის განმავლობაში გახურებისას, არ უნდა გამოყოს ხილული მოყვითალოყავისფერი აზოტის ბოლი (აზოტის აირები). აალების ტემპერატურა უნდა იყოს 1700Cზე მეტი. იხილეთ ქვემოთ მოყვანილი 2.3.2.3-2.3.2.8, 2.3.2.9(ბ) და 2.3.2.10 პუნქტები. 2.3.2.3 ქვემოთ წარმოდგენილი საცდელი პროცედურები გამოიყენება იმ შემთხვევაში, თუ ნივთიერებების საგზაო გადაზიდვებზე დაშვებასთან დაკავშირებით თავს იჩენს აზრთა სხვადასხვაობა. 2.3.2.4 იმ შემთხვევაში, თუ წინამდებარე პუნქტში ზემოთ აღწერილი სტაბილურობის პირობების შესამოწმებლად გამოიყენება სხვა მეთოდები ან საცდელი პროცედურები, აღნიშნულმა მეთოდებმა უნდა გამოიწვიონ იგივე შედეგები, რომელთა მიღწევაც შესაძლებელი იქნებოდა ქვემოთ მითითებული მეთოდების საფუძველზე. 2.3.2.5 ქვემოთ აღწერილი გახურების გზით სტაბილურობის ცდების განხორციელებისას, საცდელი ნიმუშის შემცველი ღუმელის ტემპერატურა არ უნდა გადაიხაროს 20C-ზე მეტად დადგენილი ტემპერატურიდან; 30-წუთიანი ან 30-წუთიანი ცდების დადგენილი ხანგრძლივობა უნდა იქნეს დაცული ორი წუთის სიზუსტით. ღუმელი უნდა იყოს იმ სახის, რომ საჭირო ტემპერატურა აღდგეს ნიმუშის მოთავსებიდან არაუმეტეს ხუთი წუთისა. 2.3.2.6 2.3.2.9 და 2.3.2.10 პუნქტებში აღწერილი ცდების ჩატარებამდე, ნიმუშების გამშრალება უნდა მოხდეს არანაკლებ 15 საათის განმავლობაში, გარემოს ტემპერატურაზე შენადნობი და გრანულირებული კალციუმის ქლორიდის შემცველ ვაკუუმურ საშრობში; ნივთიერების ნიმუში უნდა გავრცელდეს თხელი ფენის სახით; აღნიშნული მიზნით, ნივთიერებები, რომლებიც არ არის წარმოდგენილი არც ფხვნილისებრი და არც ბოჭკოვანი სახით, უნდა იყოს დამიწებული ან გაფხეკილი ან პატარა ნაჭრებად დაჭრილი. საშრობში წნევა დაყვანილ უნდა იქნეს 6.5 კპა (0.065 ბარზე) დაბლა. 2.3.2.7 ზემოაღნიშნულ 2.3.2.6 პუნქტში აღწერილი პირობებით გამშრალებამდე, 2.3.2.2 პუნქტით გათვალისწინებულმა ნივთიერებებმა უნდა გაიარონ წინასწარი გამშრალება კარგად ვენტილირებულ ღუმელში, რომლის ტემპერატურაც დაყენებულია 700C-ზე, სანამ ნივთიერება არ დაკარგავს მისი საწყისი მასის 0.3%-ს მეოთხედ საათში. 2.3.2.8 2.3.2.1 პუნქტში გათვალისწინებულმა სუსტად ნიტრირებულმა ნიტროცელულოზამ, უპირველეს ყოვლისა, უნდა გაიაროს თავდაპირველი გაშრობა წინამდებარე 2.3.2.7 პუნქტში მითითებული გზით; შემდგომ ამისა გაშრობის დასრულების მიზნით ნიტროცელულოზა უნდა მოთავსდეს მინიმუმ 15 საათის განმავლობაში კონცენტრირებული გოგირდმჟავის შემცველ საშრობში. 2.3.2.9 ცდა ქიმიურ სტაბილურობაზე გახურებისას (ა) ზემოაღნიშნულ 2.3.2.1 პუნქტში გათავლისწინებული ნივთიერებების გამოცდა 347 (i) ორი მინის საცდელი ტუბებიდან აღენიშნებათ შემდეგი ზომები: სიგრძე შიგა დიამეტრი კედლის სისქე თითოეულში, რომლებსაც 350 მმ 16 მმ 1.5 მმ მოათავსეს 1 გრამი კალციუმის ქლორიდზე გამომშრალი ნივთიერება (აუცილებლობის შემთხვევაში, გაშრობა უნდა განხორციელდეს ნივთიერების არაუმეტეს 0.05 გრამი წონის ნატეხებად შემცირების შემდეგ). ორივე საცდელი ტუბი, რომლებიც სრულად დაფარულია თავისუფლად მოსარგები სახურავით, თავსდება ისე ღუმელში, რომ მათი სიგრძის მინიმუმ ოთხი მეხუთედი ხილული დარჩეს და შენარჩუნდეს 1320C მუდმივ ტემპერატურაზე 30 წუთის განმავლობაში. ხორციელდება დაკვირვება იმასთან დაკავშირებით, მიმდინარეობს თუ არა აღნიშნული დროის განმავლობაში აზოტის აირების გამოყოფა მოყვითალოყავისფერი ბოლის ფორმით, რაც აშკარად თვალსაჩინოა თეთრ ფონზე; (ii) (ბ) 2.3.2.10 აღნიშნული ბოლის სტაბილურად; არარსებობისას, ნივთიერება ითვლება პლასტიფიცირებული ნიტროცელულოზას გამოცდა (იხილეთ 2.3.2.2 პუნქტი) (i) 3 გრამი პლასტიფიცირებული ნიტროცელულოზა მოათავსეს (ა) პუნქტში მითითებული ტუბების მსგავს მინის საცდელ ტუბებში, რომელიც შემდგომში გადატანილ იქნა 1320C მუდმივი ტემპერატურის მქონე ღუმელში; (ii) პლასტიფიცირებული ნიტროცელულოზას შემცველი საცდელი ტუბები ინახება ღუმელში ერთი საათის განმავლობაში. აღნიშნული დროის განმავლობაში არ უნდა გამოვლინდეს მოყვითალო-ყავისფერი ბოლი (აზოტის აირები). დაკვირვება და შეფასება ხორციელდება (ა) ქვეპუნქტში გათვალისწინებულისამებრ. აალების ტემპერატურა (იხილეთ 2.3.2.1 და 2.3.2.2 პუნქტები) (ა) აალების ტემპერატურა განისაზღვრება 0.2 გრამი ნივთიერების გახურებით, რომელიც მოთავსებულია ვუდის შენადნობის აბაზანაში ჩაშვებულ მინის საცდელ ტუბში. საცდელი ტუბის განთავსება ხდება აბაზანაში მას შემდეგ, რაც ეს უკანასკნელი მიაღწევს 1000C ტემპერატურას. შემდგომ ამისა აბაზანის ტემპერატურა თანდათან იზრდება 50C-ით ყოველ წუთში; (ბ) საცდელ ტუბებს უნდა ჰქონდეთ შემდეგი ზომები: სიგრძე 125 მმყტტიტ7 შიგა დიამეტრი 15 მმ კედლის სისქე 0.5 მმ და უნდა ჩაიძიროს 20 მმ სიღრმეში; 348 (გ) ცდა უნდა განმეორდეს სამჯერ, რის გამოც ყოველ ჯერზე აღინიშნება ტემპერატურა, რომელზეც ნივთიერების აალება, ანუ ნელი ან სწრაფი წვა, ადვილაალება ან დეტონაცია იჩენს თავს; (დ) აღნიშნულ სამ ცდაში ჩაწერილი ყველაზე დაბალი ტემპერატურა წარმოადგენს აალების ტემპერატურას. 2.3.3 3, 6.1 და 8 კლასების ადვილაალებად სითხეებთან დაკავშირებული ცდები 2.3.3.1 აფეთქების ტემპერატურის განსაზღვრა 2.3.3.1.1 ადვილაალებადი სითხეების აფეთქების ტემპერატურის შესაძლებელია გამოყენებულ იქნეს შემდეგი მეთოდები: განსაზღვრის მიზნით საერთაშორისო სტანდარტები: ISO 1516 (აფეთქების / აფეთქების არარსებობის განსაზღვრა - თანასწორ პირობებში დახურული ხუფის მეთოდი) ISO 1523 (აფეთქების ტემპერატურის განსაზღვრა - თანასწორ პირობებში დახურული ხუფის მეთოდი) ISO 2719 (აფეთქების ტემპერატურის განსაზღვრა - პენსკი-მარტენსის დახურული ხუფის მეთოდი) ISO 13736 (აფეთქების ტემპერატურის განსაზღვრა - აბელის დახურული ხუფის მეთოდი) ISO 3679 (აფეთქების ტემპერატურის განსაზღვრა - თანასწორ პირობებში დახურული ხუფის დაჩქარებული მეთოდი) ISO 3680 (აფეთქების / აფეთქების არარსებობის განსაზღვრა - თანასწორ პირობებში დახურული ხუფის დაჩქარებული მეთოდი) ეროვნული სტანდარტები: საერთაშორისო მასალების ცდების ამერიკული ასოციაცია, აშშ 19428-2959, პენსილვანია, დასავლეთ კონსჰოჰოკენი, საფოსტო ყუთი C700, ბარ ჰარბორ დრაივი 100 ASTM D3828-07a, აფეთქების ტემპერატურის სტანდარტული საცდელი მეთოდი მცირემასშტაბიანი დახურული ხუფის საცდელი ხელსაწყოს საშუალებით; ASTM D56-05, აფეთქების ტემპერატურის სტანდარტული საცდელი იარლიყის დახურული ხუფის საცდელი ხელსაწყოს საშუალებით; მეთოდი ASTM D3278-96(2004)e1, სითხეების აფეთქების ტემპერატურის სტანდარტული საცდელი მეთოდი მცირემასშტაბიანი დახურული ხუფის აპარატურის საშუალებით; ASTM D93-08, აფეთქების ტემპერატურის სტანდარტული საცდელი მეთოდი პენსკიმარტენსის დახურული ხუფის საცდელი ხელსაწყოს საშუალებით; ნორმალიზაციის ფრანგული ასოციაცია, AFNOR, ლა პლენ სენ-დენი სედექსი F-93571, პრეზანსის ქუჩა 11 ფრანგული სტანდარტი NF M 07-019 ფრანგული სტანდარტი NF M 07-011 / NF T 30-050 / NF T 66-009 349 ფრანგული სტანდარტი NF M 07-036 ნორმების გერმანული ინსტიტუტი, ბერლინი D-10787, ბურგგრაფენის ქუჩა 6 სტანდარტი DIN 51755 (აფეთქების ტემპერატურა 650C-ს ქვემოთ) მინისტრთა საბჭოს სტანდარტიზაციის სახელმწიფო კომიტეტი, RUS-113813, GSP, მოსკოვი, M-49, ლენინის პროსპექტი 9: GOST 12.1.044-84 2.3.3.1.2 საღებავების, წებოებისა და მსგავსი ბლანტი პროდუქტების, რომლებიც შეიცავს გამხსნელებს, აფეთქების ტემპერატურის განსაზღვრის მიზნით, გამოიყენება მხოლოდ ბლანტი სითხეების აფეთქების ტემპერატურის განსაზღვრისთვის სათანადო აპარატურა და საცდელი მეთოდები, შემდეგი სტანდარტების შესაბამისად: (ა) (ბ) (გ) (დ) საერთაშორისო სტანდარტი ISO 3679:1983; საერთაშორისო სტანდარტი ISO 3680:1983; საერთაშორისო სტანდარტი ISO 1523:1983; საერთაშორისო სტანდარტი EN ISO 13736 და EN ISO 2719, მეთოდი ბ. 2.3.3.1.3 2.3.3.1.1 პუნქტში ჩამოთვლილი სტანდარტები გამოიყენება მხოლოდ აღნიშნულ სტანდარტებში მითითებული აფეთქების ტემპერატურის დიაპაზონებისთვის. სტანდარტის შერჩევისას აუცილებელია მხედველობაში იქნეს მიღებული ქიმიური რეაქციის შესაძლებლობა ნივთიერებასა და ნიმუშის დამჭერს შორის. უსაფრთხოების ტექნიკის წესების თანახმად, აპარატურა უნდა მოთავსდეს ორპირი ქარისგან დაცულ ადგილზე. უსაფრთხოების მიზნით, გამოყენებულ უნდა იქნეს ის მეთოდი, რომელიც მიმართავს მცირე ზომის, დაახლოებით 2 მლ ნიმუშს, ორგანული პეროქსიდებისა და თვითრეაქტიული ნივთიერებების (ასევე ცნობილია, როგორც „ენერგეტიკული“ ნივთიერებები) ან ტოქსიკური ნივთიერებების გამოცდისთვის. 2.3.3.1.4 იმ შემთხვევაში, თუ აფეთქების ტემპერატურა, რომელიც განისაზღვრება არათანასწორობის მეთოდით, აღმოჩნდება 23+20C ან 60+20C, ის უნდა დამტკიცდეს ყოველ ტემპერატურის დიაპაზონთან დაკავშირებით შეთანასწორების მეთოდით. 2.3.3.1.5 იმ შემთხვევაში, თუ ადვილაალებადი სითხის კლასიფიკაციასთან დაკავშირებით წარმოიშვება აზრთა სხვადასხვაობა, მიიღება ტვირთგამგზავნის მიერ შემოთავაზებული კლასიფიკაცია იმ შემთხვევაში, თუ აფეთქების ტემპერატურის განსაზღვრის მიზნით საკონტროლო ცდით მიიღება შედეგი, რომელიც არ განსხვავდება 20C-ზე მეტად 2.2.3.1 პუნქტში გათვალისწინებული ტემპერატურის საზღვრებიდან (230C და 600C შესაბამისად). იმ შემთხვევაში, თუ სხვაობა 20C-ზე მეტია, აუცილებელია მეორე საკონტროლო ცდის განხორციელება და მიღებულ უნდა იქნეს ორივე საკონტროლო ცდის შედეგად მიღებული აფეთქების ტემპერატურის ყველაზე დაბალი მაჩვენებელი. 2.3.3.2 საწყისი დუღილის ტემპერატურის განსაზღვრა ადვილაალებადი სითხეების საწყისი დუღილის ტემპერატურის განსაზღვრის მიზნით შესაძლებელია გამოყენებულ იქნეს შემდეგი მეთოდები: საერთაშორისო სტანდარტები: ISO 3924 (ნავთობპროდუქტები - დუღილის დიაპაზონის განაწილების განსაზღვრა აირის ქრომატოგრაფიის მეთოდი) 350 ISO 4626 (აქროლადი ორგანული სითხეები - ნედლი მასალის სახით გამოყენებული ორგანული გამხსნელების დუღილის დიაპაზონის განსაზღვრა) ISO 3405 (ნავთობპროდუქტები მახასიათებლების განსაზღვრა) - ატმოსფერულ წნევაზე დისტილაციის ეროვნული სტანდარტები: საერთაშორისო მასალების ცდების ამერიკული ასოციაცია, აშშ 19428-2959, პენსილვანია, დასავლეთ კონსჰოჰოკენი, საფოსტო ყუთი C700, ბარ ჰარბორ დრაივი 100 ASTM D86-07a, ატმოსფერულ წნევაზე ნავთობპროდუქტების დისტილაციასთან დაკავშირებით სტანდარტული ცდის მეთოდი; ASTM D1078-05, აქროლადი ორგანული სითხეების დისტილაციის დიაპაზონთან დაკავშირებით სტანდარტული ცდის მეთოდი; დამატებითი მიღებული მეთოდები: ა.2 მეთოდი, როგორც ეს აღწერილია კომისიის დადგენილება (EC) N440/20081 დანართის A ნაწილში. 2.3.3.3 პეროქსიდის შემცველობის განსაზღვრის ცდა სითხის პეროქსიდის შემცველობის განსაზღვრის მიზნით გამოიყენება შემდეგი პროცედურა: ერლენმეიერის კოლბაში ათავსებენ ტიტრირებულ სითხეს p რაოდენობით (დაახლოებით 5 გრ, შეწონილი უახლოესი 0.01 გრამის სიზუსტით); რომელსაც ემატება 20სმ3 ძმრის ანჰიდრიდი და დაახლოებით 1 გრ მყარი, ფხვნილისებრი კალიუმის იოდიდი; კოლბას არხევენ და, 10 წუთის შემდეგ, აცხელებენ 3 წუთის განმავლობაში დაახლოებით 600C ტემპერატურაზე. 5 წუთის განმავლობაში ნარევი უნდა გაგრილდეს, რის შემდეგადაც ემატება 25 სმ3 წყალი. ამის შემდეგ მას აჩერებენ ნახევარი საათის განმავლობაში, რის შემდეგაც ადგილი აქვს გამოთავისუფლებული იოდის ტიტრირებას ნატრიუმის თიოსულფატის დეცინორმალური ხსნარის დახმარებით ინდიკატორის დამატების გარეშე; სრული გაუფერულება მიუთითებს რეაქციის დასასრულს. იმ შემთხვევაში, თუ n წარმოადგენს თიოსულფატის სმ3 საჭირო რიცხვს, ნიმუშში წარმოდგენილი პეროქსიდის პროცენტული თანაფარდობა (გაანგარიშებული, როგორც H2O2) მიიღება შემდეგი ფორმულით: 17n 100P 2.3.4 დენადობის განმსაზღვრელი ცდები სითხის, ბლანტი ან პასტის ნივთიერებებისა და ნარევების დენადობის განსაზღვრის მიზნით გამოყენებულ უნდა იქნეს შემდეგი საცდელი მეთოდი. კომისიის 2008 წლის 30 მაისის დადგენილება (EC) N440/2008, სადაც დადგენილია საცდელი მეთოდები ევროპარლამენტისა და საბჭოს დადგენილება (EC) N1907/2006-ის თანახმად ქიმიური ნივთიერებების რეგისტრაციის, შეფასების, ავტორიზაციისა და შეზღუდვის შესახებ (REACH) (ევროკავშირის ოფიციალური ჟურნალი, N L142, 31.05.2008 წ., გვ. 1-739 და N L143, 03.06.2008 წ. გვ. 55). 1 351 2.3.4.1 საცდელი აპარატურა ISO 2137:1985 სტანდარტის შესაბამისი კომერციული პენეტრომეტრი, 47.5 გ + 0.05 გ მიმმართველი ძელით; დურალუმინისგან დამზადებული გაცრითი დისკი კონუსურ ხვრელებსა და 102.5 გ + 0.05 გ მასასთან ერთად (იხილეთ სურათი 1); ნიმუშის მისაღებად 72 მმ-დან 80 მმ-დე შიგა დიამეტრის მქონე პენეტრაციული ჭურჭელი. 2.3.4.2 საცდელი პროცედურები ნიმუშს ასხავენ პენეტრაციულ ჭურჭელში გაზომვამდე არანაკლებ ნახევარი საათით ადრე. შემდეგ ჭურჭელი ჰერმეტულად იხურება და რჩება ამ მდგომარეობაში გაზომვამდე. ჰერმეტულად დახურულ პენეტრაციულ ჭურჭელში მოთავსებულ ნიმუშს ახურებენ 350C + 0.50C ტემპერატურაზე და ათავსებენ პენეტრომეტრის მაგიდაზე უშუალოდ გაზომვის წინ (არაუმეტეს ორი წუთისა). გაცრითი დისკის S წერტილი ეხება სითხის ზედაპირს და იზომება პენეტრაციის ხარისხი. 2.3.4.3 ცდების შედეგების შეფასება ნივთიერება წარმოადგენს პასტისებრს იმ შემთხვევაში, თუ S ცენტრის ნიმუშის ზედაპირზე შეხებისას, მრგვალშკალიანი ინდიკატორის მიერ მითითებული პენეტრაცია: (ა) 5 წმ + 0.1 წმ დატვირთვის დროის შემდეგ, შეადგენს 15.0მმ + 0.3 მმ-ზე ნაკლებს; ან (ბ) 5 წმ + 0.1 წმ დატვირთვის დროის შემდეგ, შეადგენს 15.0მმ + 0.3 მმ-ზე მეტს, თუმცა დამატებითი პენეტრაცია შემდგომი 55 წმ + 0.5 წმ შემდეგ ნაკლებია 5.0მმ + 0.5 მმ-ზე. შენიშვნა: დენადობის ტემპერატურის მქონე ნიმუშების შემთხვევაში, ხშირად შუძლებელია თანაბარი ზედაპირის უზრუნველყოფა პენეტრაციულ ჭურჭელში და, აღნიშნულიდან გამომდინარე, დამაკმაყოფილებელი საწყისი საზომი პირობების დადგენა S წერტილის შეხებასთან დაკავშირებით. გარდა ამისა, ზოგიერთ ნიმუშთან დაკავშირებით, გაცრითი დისკის მოქმედებას შეუძლია გამოიწვიოს ზედაპირის ელასტიური დეფორმაცია და, პირველი რამდენიმე წამის განმავლობაში, მოახდინოს კიდევ უფრო ღრმა პენეტრაციის იმიტირება. ყველა აღნიშნულ შემთხვევაში, ხელსაყრელი იქნება ზემოაღნიშნული (ბ) პუნქტის თანახმად შეფასების გაკეთება. 352 სურათი 1 - პენეტრომეტრი დაარეგულირეთ მასა 102.5გ+0.05გ-ზე წნეხილის ჩასმა მიუთითებელი ტოლერანტობა შეადგენს +0.1 მმ-ს 353 2.3.5 ლითონორგანული ნივთიერებების კლასიფიკაცია 4.2 და 4.3 კლასებში მათი თვისებებიდან გამომდინარე, როგორც ეს განსაზღვრულია ცდებისა და კრიტერიუმების სახელმძღვანელოს 33-ე კარის III ნაწილის ცდების N1-N5 შესაბამისად, ლითონორგანული ნივთიერებები შესაძლებელია კლასიფიცირებულ იქნან 4.2 ან 4.3 კლასში, შესაბამისად, 2.3.5 სურათზე წარმოდგენილი გადაწყვეტილების მიღების სქემის თანახმად. შენიშვნა 1: მათი სხვა თვისებებიდან და სახიფათო თვისებების პრიორიტეტულობის ცხრილიდან (იხილეთ 2.1.3.10 პუნქტი) გამომდინარე, ლითონორგანული ნივთიერებების კლასიფიკაცია უნდა მოხდეს სხვა კლასში, კონკრეტული სიტუაციიდან გამომდინარე. შენიშვნა 2: ლითონორგანული ნარევების შემცველი ადვილაალებადი ხსნარები, წარმოდგენილი იმ კონცენტრაციებით, რომლებიც არ იწვევს თვით-წვას ან, წყალთან შეხებისას, არ გამოყოფს ადვილაალებად აირებს სახიფათო ოდენობით, წარმოადგენს მე-3 კლასის ნივთიერებებს. 354 სურათი 2.3.5: მიღებული გადაწყვეტილებების სქემა ლითონორგანული ნივთიერებების 4.2 და 4.3ბ კლასებში კლასიფიცირების შესახებ ლითონორგანული ნივთიერება/შემადგენლობა/ხსნარია მყარი ლითონორგანული ნივთიერება, მყარი, პიროფორული გაეროს N3391 თხევადი ლითონორგანული ნივთიერება, თხევადი, პიროფორული გაეროს N3392 მყარი ლითონორგანული ნივთიერება, მყარი, პიროფორული, წყალზე რეაგირებადი გაეროს N3393 არა დიახ არის თუ არა ნივთიერება წყალზე რეაგირებადი ცდა N5 არის თუ არა ნივთიერება პიროფორული? ცდა N2 (მყარი ნივთიერებები) დიახ ლითონორგანული ნივთიერება, თხევადი, პიროფორული, წყალზე რეაგირებადი გაეროს N3394 თხევადი არა ლითონორგანული ნივთიერება, მყარი, წყალზე რეაგირებადი გაეროს N3395 არის თუ არა ნივთიერება ადვილაალებადი, მყარი? ცდა N1 დიახ ლითონორგანული ნივთიერება, მყარი, წყალზე რეაგირებადი, ადვილაალებადი გაეროს N3396 არა დიახ დიახ არის თუ არა ნივთიერება თვით-მთბობი? დიახ არის თუ არა ნივთიერება წყალზე რეაგირებადი ცდა N5 კლასი 4.3, PG I, II ან III, არის თუ არა ნივთიერება მყარი? არა არა შეიცავს თუ არა ნივთიერება <600C აფეთქების ტემპერატურის მქონე გამხსნელს? არა არის თუ არა ნივთიერება თვითმთბობი, მყარი? ცდა N4 დიახ ლითონორგანული ნივთიერება, მყარი, წყალზე რეაგირებადი, თვით-მთბობი გაეროს N3397 ლითონორგანული ნივთიერება, თხევადი, წყალზე რეაგირებადი გაეროს N3398 დიახ ლითონორგანული ნივთიერება, თხევადი, წყალზე რეაგირებადი, ადვილაალებადი გაეროს N3399 ლითონორგანული ნივთიერება, მყარი, თვით-თბობადი გაეროს N3400 არა არ არის აუცილებელი ნივთიერებების კლასიფიკაცია 4.2 ან 4.3 კლასში შესაბამის შემთხვევებში და სათანადო ცდებისას, რეაქციის თვისებების გათვალისწინებით, 6.1 და 8 კლასის თვისებები უნდა განიხილოს 2.1.3.10 პუნქტში მოყვანილი საშიშროებების პრიორიტეტულობის ცხრილის შესაბამისად. გ ცდების მეთოდები N1 და N5 შეგიძლიათ მოიძიოთ ცდებისა და კრიტერიუმების სახელმძღვანელოს, 33-ე კარის III ნაწილში. ა 355 ნაწილი 3 სახიფათო ტვირთების ჩამონათვალი, სპეციალური დებულებები და შეზღუდულ და გამოთავისუფლებულ რაოდენობებთან დაკავშირებული გამონაკლისები 356 თავი 3.1 ზოგადი დებულებები 3.1.1 შესავალი გარდა წინამდებარე ნაწილის ცხრილებში მითითებული ან მოყვანილი დებულებებისა, შესრულებული უნდა იქნეს ყოველი ნაწილის, თავის და/ან პუნქტის საერთო მოთხოვნები. აღნიშნული საერთო მოთხოვნები არ არის მოცემული ცხრილებში. იმ შემთხვევაში, თუ საერთო მოთხოვნა ეწინააღმდეგება სპეციალურ დებულებას, უპირატესობა ენიჭება ამ უკანასკნელს. 3.1.2 გადაზიდვის შესაბამისი დასახელება შენიშვნა: ნიმუშების გადაზიდვასთან დაკავშირებით გამოყენებული შესაბამისი დასახელებები იხილეთ 2.1.4.1 პუნქტში. გადაზიდვის 3.1.2.1 გადაზიდვის შესაბამისი დასახელება წარმოადგენს 3.2 თავის A ცხრილში მითითებული პოზიციის ნაწილს, რომელიც ყველაზე ზუსტად აღწერს ტვირთს და რომელიც მითითებულია მთავრული ასოებით (პლიუს ნებისმიერი ნომერი, ბერძნული ანბანის ასო, „მეორე-“, „მესამე-“ და ასოები „მ“, „ნ“, „ო“, „პ“, რომელიც წარმოადგენს დასახელების შემადგენელ ნაწილს). ძირითადი გადაზიდვის შესაბამისი დასახელების შემდეგ შესაძლებელია მითითებულ იქნეს ალტერნატიული გადაზიდვის შესაბამისი დასახელება [მაგალითად, ეთანოლი (ეთანოლის სპირტი)]. გადაზიდვის შესაბამისი დასახელების სახით არ უნდა იქნეს განხილული ნებისმიერი პოზიციის ნაწილი, რომელიც წარმოდგენილია პატარა ასოებით. 3.1.2.2 იმ შემთხვევაში, თუ კავშირები, როგორიცაა „და“ ან „ან“ მითითებულია პატარა ასოებით ან თუ დასახელების ნაწილები გამოყოფილია მძიმით, აუცილებელი არ არის სატრანსპორტო დოკუმენტსა თუ შეფუთვაზე მითითებული იქნეს პოზიციის სრული დასახელება. აღნიშნული განსაკუთრებით ეხება იმ შემთხვევას, როდესაც კონკრეტული გაეროს ნომრით წარმოდგენილია ზოგიერთი ცალკეული პოზიციის ჩამონათვალი. აღნიშნული პოზიციების გადაზიდვის შესაბამისი დასახელებების შერჩევის მაგალითებია: (ა) გაეროს N1057 - სანთებელები ან სანთებელის გასამართი ბალონები გადაზიდვის შესაბამისი დასახელება წარმოადგენს უფრო შესაფერისს შემდეგი შესაძლო კომბინაციებიდან სანთებელები; სანთებელის გასამართი ბალონები; (ბ) გაეროს N2973 - შავი ლითონების ნაბურღები, ნაპარსები, საბრუნები ან ნაჭრები, რომლებიც უზრუნველყოფს თვითთბობას. გადაზიდვის შესაბამისი დასახელება წარმოადგენს ყველაზე მეტად შესაფერისს შემდეგი კომბინაციებიდან: შავი ლითონების ნაბურღები შავი ლითონების ნაპარსები შავი ლითონების საბრუნები შავი ლითონების ნაჭრები 3.1.2.3 გადაზიდვის შესაბამისი დასახელება შესაძლებელია გამოყენებულ იქნეს როგორც მხოლობით, ასევე მრავლობით რიცხვში, კონკრეტული შემთხვევიდან გამომდინარე. 357 გარდა ამისა, როდესაც გადაზიდვის შესაბამისი დასახელებების ნაწილის სახით გამოიყენება განმსაზღვრელი სიტყვა, მათი თანმიმდევრობის მითითება დოკუმენტაციასა თუ შეფუთვაზე პირობითია. მაგალითად, „დიმეთილამინის წყალხსნარი“ შესაძლებელია მითითებული იყოს, როგორც „წყალხსნარი დიმეთილამინის“. შესაძლებელია გამოყენებული იქნეს 1-ლი კლასის ტვირთის კომერციული ან სამხედრო დასახელებები, რომელიც შეიცავს გადაზიდვის შესაბამის დასახელებას დამატებით აღწერილობასთან ერთად. 3.1.2.4 ბევრ ნივთიერებას გააჩნია როგორც თხევადი მდგომარეობის, ასევე მყარი მდგომარეობის შესაბამისი პოზიცია (იხილეთ თხევადი და მყარი ნივთიერებების განმარტებები 1.2.1 პუნქტში) ან მყარი მდგომარეობისა და ხსნარის შესაბამისი პოზიცია. მათ ენიჭებათ ცალკეული გაეროს ნომრები, რომლებიც არ არის აუცილებელი, რომ იყოს დალაგებული ზრდადობის წესის მიხედვით.1 3.1.2.5 გარდა იმ შემთხვევებისა, როდესაც 3.2 თავის A ცხრილში მითითებულ დასახელებაში უკვე გათვალისწინებულია მთავრული ასოები, გადაზიდვის შესაბამისი დასახელების ნაწილს უნდა დაემატოს განმსაზღვრელი სიტყვა „მდნარი“ იმ შემთხვევაში, თუ ნივთიერება, რომელიც წარმოადგენს მყარ ნივთიერებას 1.2.1 პუნქტში მოყვანილი განმარტების თანახმად, წარმოდგენილია გადაზიდვაზე მდნარ მდგომარეობაში (მაგალითად, ალკილფენოლი, მყარი, N.O.S., მდნარი). 3.1.2.6 იმ შემთხვევაში, თუ სიტყვა „სტაბილიზებული“, ნაბეჭდი მთავრული ასოებით, არ არის უკვე გათვალისწინებული 3.2 თავის A ცხრილის (სვეტში) მითითებულ დასახელებაში, მისი დამატება უნდა მოხდეს ნივთიერების გადაზიდვის შესაბამისი დასახელების შემადგენელი ნაწილის სახით, თვითრეაქტიული ნივთიერებებისა და ორგანული პეროქსიდების გამოკლებით, რომლებიც, სტაბილიზაციის გარეშე, არ დაიშვება გადაზიდვაზე 2.2.X.2 პუნქტის შესაბამისად იმის გამო, რომ მათ შეუძლია შევიდეს სახიფათო რეაქციაში გადაზიდვის ნორმალურ პირობებში (მაგალითად, „ტოქსიკური სითხე, ორგანული, N.O.S., სტაბილიზებული“). იმ შემთხვევაში, თუ აღნიშნული ნივთიერებების სტაბილიზაციისთვის ხორციელდება ტემპერატურის კონტროლი ნებისმიერი სახიფათო ჭარბი წნევის განვითარების პრევენციის მიზნით, მაშინ: (ა) სითხეების შემთხვევაში: როდესაც თადტ ნაკლებია ან ტოლია 500C-ზე, გამოიყენება 2.2.41.1.17 ქვეპუნქტის დებულებები, 7.2 თავის V8 სპეციალური დებულება, 8.5 თავის S4 სპეციალური დებულება და 9.6 თავის მოთხოვნები; მასიური ტვირთის საშუალო ტვირთამწეობისა და ცისტერნების გადაზიდვის შემთხვევაში გამოიყენება გაეროს N3239 დაკავშირებით მოქმედი დებულებები (იხილეთ, 4.1.7.2 პუნქტი, შეფუთვის ინსტრუქცია INC520 და 4.2.1.13 პუნქტი); (ბ) აირების შემთხვევაში: გადაზიდვის პირობები ექვემდებარება კომპეტენტური ორგანოს მიერ დამტკიცებას. უფრო დეტალური მონაცემები წარმოდგენილია ანბანური მაჩვენებლებით (3.2 თავის B ცხრილი), მაგალითად: ნიტროქსილოლები, თხევადი 6.1 1665 ნიტროქსილოლები, მყარი 6.1 3447 1 358 3.1.2.7 ჰიდრატების გადაზიდვა შესაძლებელია უწყლო ნივთიერებებთან დაკავშირებული გადაზიდვის შესაბამისი დასახელებით. 3.1.2.8 გენერიული და „არ არის მითითებული კონკრეტულად“ (N.O.S.) დასახელებები 3.1.2.8.1 გენერიული და „არ არის მითითებული კონკრეტულად“ გადაზიდვის შესაბამის დასახელებებს, რომელთა მინიჭებაც ხდება 3.2 თავის A ცხრილის (6) სვეტის 274 ან 318 დებულების თანახმად, უნდა დაემატოს ტვირთის ტექნიკური დასახელება, თუ ეროვნული კანონმდებლობა ან საერთაშორისო კონვენცია არ კრძალავს მის გახსნას იმ შემთხვევაში, თუ ლაპარაკია კონტროლირებულ ნივთიერებაზე. 1-ლი კლასის ფეთქებადი ნივთიერებების შემთხვევაში, სახიფათო ტვირთების აღწერილობას შესაძლებელია დაემატოს დამატებითი აღწერილობითი ტექსტი კომერციული ან სამხედრო დასახელებების მითითების მიზნით. ტექნიკური დასახელებების მითითება უნდა მოხდეს ფრჩხილებში უშუალოდ გადაზიდვის შესაბამისი დასახელების შემდეგ. საჭიროების შემთხვევაში შესაძლებელია აგრეთვე გამოყენებულ იქნეს ისეთი განსაზღვრებები, როგორიცაა „შეიცავს“ ან „შემცველი“ ან სხვა განმსაზღრველი სიტყვები, მაგალითად, „ნარევი“, „ხსნარი“ და ა.შ., ასევე შესაძლებელია გამოყენებულ იქნეს ტექნიკური კომპონენტის პროცენტული შემცველობა. მაგალითად, „გაეროს #1993 - ადვილაალებადი სითხე, N.O.S. (შეიცავს ქსილოლს და ბენზოლს), 3, II“. 3.1.2.8.1.1 ტექნიკური დასახელება უნდა იყოს აღიარებული ქიმიური დასახელება ან ბიოლოგიური დასახელება ან ნებისმიერი სხვა დასახელება, რომელიც ამჟამად გამოიყენება სამეცნიერო და ტექნიკურ სახელმძღვანელოებში, ჟურნალებსა და ტექსტებში. აღნიშნული მიზნით დაუშვებელია სავაჭრო დასახელების გამოყენება. პესტიციდების შემთხვევაში შესაძლებელია გამოყენებულ იქნეს მხოლოდ ISO საერთო სახელ(ებ)ი, სხვა სახელ(ებ)ი, რომელიც (რომლებიც) გათვალისწინებულია მსოფლიო ჯანდაცვის ორგანიზაციის (WHO) გამოცემაში - საშიშროებების მიხედვით პესტიციდების რეკომენდებული კლასიფიკაცია და კლასიფიკაციის პრინციპები ან აქტიური ნივთიერ(ებ)ის დასახელება (დასახელებები). 3.1.2.8.1.2 იმ შემთხვევაში, თუ სახიფათო ტვირთების ნარევი მიეკუთვნება „N.O.S.“ ან „გენერიულ“ პოზიციებს, რომელთა მიმართაც 3.2 თავის A ცხრილის (6) სვეტში გათვალისწინებულია სპეციალური დებულება 274, აუცილებელია არაუმეტეს ორი კომპონენტის მითითება, რომლებიც უმეტესწილად განაპირობებს ნარევების სახიფათო თვისებას ან თვისებებს, კონტროლირებადი ნივთიერებების გამოკლებით, როდესაც მათი გახსნა იკრძალება ეროვნული კანონმდებლობით ან საერთაშორისო კონვენციით. იმ შემთხვევაში, თუ ნარევის შემცველ შეფუთვაზე მითითებულია რაიმე დამატებითი საფრთხის აღმნიშვნელი ნიშანი, ფრჩხილებში წარმოდგენილი ორი ტექნიკური დასახელებიდან ერთ-ერთი უნდა იყოს იმ კომპონენტის დასახელება, რომელიც მოითხოვს აღნიშნული დამატებითი საფრთხის ნიშნის გამოყენებას. შენიშვნა: იხილეთ 5.4.1.2.2 პუნქტი. 3.1.2.8.1.3 აღნიშნული N.O.S. პოზიციებისთვის დამატებითი ტექნიკური დასახელების მქონე გადაზიდვის შესაბამისი დასახელების შერჩევის ამსახველი მაგალითებია: გაეროს N2920 გაეროს N3394 პესტიციდი, თხევადი, ტოქსიკური, N.O.S. (დრაზოქსოლონი) ლითონორგანული ნივთიერება, თხევადი, პიროფორული, წყალზე რეაგირებადი (ტრიმეთილგალიუმი). 359 3.1.3 ხსნარები ან ნარევები შენიშვნა: იმ შემთხვევაში, თუ ნივთიერება კონკრეტულად არის მითითებული დასახელებით 3.2 თავის A ცხრილში, მისი გადაზიდვისას გამოყენებულ უნდა იქნეს 3.2 თავის A ცხრილის (2) სვეტში მითითებული გადაზიდვის შესაბამისი დასახელება. აღნიშნული ნივთიერებები შესაძლებელია შეიცავდეს ტექნიკურ მინარევებს (მაგალითად, წარმოების პროცესის შედეგად წარმოშობილ მინარევებს) ან დანამატებს სტაბილურობის ან სხვა მიზნებისთვის, რაც გავლენას არ ახდენს მის კლასიფიკაციაზე. თუმცა დასახელებით მითითებული მინარევი, რომელიც შეიცავს ტექნიკურ მინარევებს ან დანამატებს სტაბილურობისა თუ სხვა მიზნებისთვის და გავლენას ახდენს მის კლასიფიკაციაზე, განხილულ უნდა იქნეს როგორც ხსნარი ან ნარევი (იხილეთ 2.1.3.3 პუნქტი). 3.1.3.1 ADR-ის პირობების არ ვრცელდება იმ ხსნარსა თუ ნარევზე იმ შემთხვევაში, თუ ხსნარისა თუ ნარევის მახასიათებლები, თვისებები, ფორმა ან ფიზიკური მდგომარეობა წარმოდგენილია იმ სახით, რომ ის არ აკმაყოფილებს კრიტერიუმებს, ადამიანთა გამოცდილების კრიტერიუმების ჩათვლით, ნებისმიერ კლასზე მისაკუთვნებლად. 3.1.3.2 ნივთიერება თუ ნარევი, რომელიც შედგება ცალკეული პრედომინანტური ნივთიერებისგან, რომელიც მითითებულია დასახელებით 3.2 თავის A ცხრილში და ერთი ან მეტი ნივთიერებისგან, რომელზეც არ ვრცელდება ADR-ის პირობები ან 3.2 თავის A ცხრილში დასახელებით მითითებული ერთი ან რამდენიმე ნივთიერების უმნიშვნელო რაოდენობა, უნდა მიეკუთვნოს შესაბამისი გაეროს ნომერი და 3.2 თავის A ცხრილში დასახელებით მითითებული პრედომინანტური ნივთიერების გადაზიდვის შესაბამისი დასახელება, შემდეგი შემთხვევების გარდა: (ა) (ბ) 3.1.3.3 3.2 თავის A ცხრილში დასახელებით არის მითითებული ხსნარები ან ნარევები; 3.2 თავის A ცხრილში დასახელებით მითითებული ნივთიერების სახელი და აღწერილობა კონკრეტულად მიუთითებს, რომ მათი გამოყენება ხდება მხოლოდ სუფთა ნივთიერებასთან დაკავშირებით; (გ) ხსნარისა თუ ნარევის კლასი, კლასიფიკაციის კოდი, შეფუთვის ჯგუფი ან ფიზიკური მდგომარეობა განსხვავდება 3.2 თავის A ცხრილში დასახელებით მითითებული ნივთიერებისგან; ან (დ) ხსნარისა თუ ნარევის სახიფათო მახასიათებლები და თვისებები იწვევს გადაუდებელი რეაგირების ზომების განხორციელებას, რომლებიც განსხვავდება 3.2 თავის A ცხრილში დასახელებით მითითებულ ნივთიერებებთან დაკავშირებით მოთხოვნილი ზომებისგან. კონკრეტული შემთხვევიდან გამომდინარე, გადაზიდვის შესაბამის დასახელებას უნდა დაემატოს ისეთი განმსაზღვრელი სიტყვა, როგორიცაა „ხსნარი“ ან „ნარევი“, მაგალითად „აცეტონის ხსნარი“. გარდა ამისა, ნარევისა თუ ხსნარის კონცენტრაცია შესაძლებელია ასევე მითითებულ იქნეს ნარევისა თუ ხსნარის ძირითადი აღწერილობის შემდეგ, მაგალითად, „აცეტონის 75% ხსნარი“. ხსნარი ან ნარევი, რომელიც 3.2 თავის A ცხრილში არ არის მითითებული დასახელებით ან რომელიც შედგება ორი ან მეტი სახიფათო ტვირთისგან, უნდა მიეკუთვნოს იმ პოზიციას, რომელსაც გააჩნია გადაზიდვის შესაბამისი დასახელება, აღწერილობა, კლასი, კლასიფიკაციის კოდი და შეფუთვის ჯგუფი, რაც ყველაზე მეტი სიზუსტით აღწერს მოცემულ ხსნარსა თუ ნარევს. 360 თავი 3.2 სახიფათო ტვირთების ჩამონათვალი 3.2.1 ცხრილი A: სახიფათო ტვირთების ჩამონათალი განმარტებანი როგორც წესი, აღნიშნული თავის ყოველი მწკრივი ეძღვნება კონკრეტული გაეროს ნომრით გათვალისწინებულ ნივთიერებას (ნივთიერებებსა) თუ ნაკეთობას (ნაკეთობებს). თუმცა იმ შემთხვევაში, თუ ერთსა და იმავე გაეროს ნომერს მიკუთვნებულ ნივთიერებებსა თუ ნაკეთობებს გააჩნიათ სხვადასხვა ქიმიური თვისებები, ფიზიკური თვისებები და/ან გადაზიდვის პირობები, აღნიშნული გაეროს ნომრისთვის შესაძლებელია გამოყენებულ იქნეს რამდენიმე თანმიმდევრული მწკრივი. A ცხრილის ყოველი სვეტი ეძღვნება საგანგებო საგანს, როგორც ეს მითითებულია ქვემოთ წარმოდგენილ განმარტებით შენიშვნებში. სვეტებისა და მწკრივების (უჯრის) კვეთა შეიცავს აღნიშნულ სვეტში მითითებული საგნის შესახებ ინფორმაციას, შესაბამის მწკრივში გათვალისწინებულ ნივთიერებასთან (ნივთიერებებთან) თუ ნაკეთობასთან (ნაკეთობებთან) დაკავშირებით: - პირველი ოთხი უჯრა განსაზღვრავს აღნიშნულ კლასს მიკუთვნებულ ნივთიერებას (ნივთიერებებსა) თუ ნაკეთობას (ნაკეთობებს) (აღნიშნულის შესახებ დამატებითი ინფორმაცია შესაძლებელია წარმოდგენილ იქნეს (6) სვეტში გათვალისწინებული სპეციალური დებულებებით); - მომდევნო უჯრებში მითითებულია მოქმედი სპეციალური დებულებები, სრული ინფორმაციის ან კოდის ფორმით. კოდები მიუთითებს დეტალურ ინფორმაციაზე, რომელთა მოძიებაც შესაძლებელია ქვემოთ წარმოდგენილ განმარტებით შენიშვნებში მითითებულ ნაწილში, თავში, კარსა და/ან ქვეკარში. ცარიელი უჯრა ნიშნავს, რომ არ არის წარმოდგენილი სპეციალური დებულება და მოქმედებს მხოლოდ საერთო მოთხოვნები ან რომ ძალაშია განმარტებით შენიშვნაში გადაზიდვასთან დაკავშირებით მითითებული შეზღუდვა. წინამდებარე ცხრილში გამოყენებისას, ასოებითა და ციფრებით გამოსახული კოდი, რომელიც იწყება ასოებით „SP“, ასახავს 3.3 თავით გათვალისწინებულ სპეციალურ დებულებას. მოქმედი საერთო მოთხოვნები არ არის მითითებული შესაბამის უჯრაში. ქვემოთ წარმოდგენილი განმარტებითი შენიშნები ყოველ სვეტთან დაკავშირებით მიუთითებს ნაწილ(ებ)ს, თავ(ებ)ს, კარ(ებ)ს და/ან ქვე-კარ(ებ)ს, რომლებშიც გათვალისწინებულია აღნიშნული საერთო მოთხოვნები. განმარტებითი შენიშნები ყოველი სვეტის მიხედვით: სვეტი (1) „გაეროს N“ აღნიშნულ სვეტში მიეკუთვნება: - მითითებულია გაეროს ნომერი, რომელიც სახიფათო ნივთიერებასა თუ ნაკეთობას იმ შემთხვევაში, თუ აღნიშნულ ნივთიერებასა თუ ნაკეთობას მინიჭებული აქვს საკუთარი კონკრეტული გაეროს N; ან 361 - სვეტი (2) განზოგადებულ ან N.O.S. პოზიციას, რომელთაც განეკუთვნება ის სახიფათო ნივთიერებები თუ ნაკეთობები, რომლებიც არ არის მითითებული დასახელებით, მე-2 ნაწილში გათვალისწინებული კრიტერიუმების შესაბამისად („მიღებული გადაწყვეტილებების სქემა“). „სახელი და აღწერილობა“ აღნიშნულ სვეტში მთავრული ასოებით წარმოდგენილია ნივთიერებისა თუ ნაკეთობის დასახელება, იმ შემთხვევაში, თუ ნივთიერებასა თუ ნაკეთობას მინიჭებული აქვს საკუთარი კონკრეტული გაეროს ნომერი, ან განზოგადებული თუ N.O.S. პოზიცია, რომლის მიკუთვნებაც მოხდა მე-2 ნაწილში გათვალისწინებული კრიტერიუმების შესაბამისად („მიღებული გადაწყვეტილებების სქემა“). აღნიშნული სახელის გამოყენება უნდა მოხდეს გადაზიდვის შესაბამისი დასახელების სახით ან, კონკრეტული შემთხვევიდან გამომდინარე, გადაზიდვის შესაბამისი დასახელების ნაწილის სახით (იხილეთ 3.1.2 პუნქტი გადაზიდვის შესაბამისი დასახელების შესახებ დამატებით მონაცემებთან დაკავშირებით). პატარა ასოებით მითითებული აღწერილობითი ტექსტი ემატება გადაზიდვის შესაბამის დასახელებას პოზიციის მოქმედების არეალის განმარტების მიზნით იმ შემთხვევაში, თუ ნივთიერებებისა თუ ნაკეთობების კლასიფიკაცია და/ან გადაზიდვის პირობები შესაძლებელია განსხვავებული იყოს გარკვეულ პირობებში. სვეტი (3ა) „კლასი“ აღნიშნული სვეტი მოიცავს კლასის ნომერს, რომლის დასახელებაშიც გათვალისწინებულია სახიფათო ნივთიერებები ან ნაკეთობები. ამ კლასის ნომრის მინიჭება ხდება მე-2 ნაწილში მოყვანილი პროცედურებისა და კრიტერიუმების შესაბამისად. სვეტი (3ბ) „კლასიფიკაციის კოდი“ აღნიშნულ კლასში შედის სახიფათო ნივთიერებებისა თუ ნაკეთობების კლასიფიკაციის კოდი. - 1-ლი კლასის სახიფათო ნივთიერებებსა თუ ნაკეთობებთან დაკავშირებით, კოდი შედგება ქვეკლასის ნომრისა და შეთავსებადობის ჯგუფის ასოსგან, რომლის მინიჭებაც ხდება 2.2.1.1.4 ქვეკლასით გათვალისწინებული პროცედურებისა და კრიტერიუმების შესაბამისად; - მე-2 კლასის სახიფათო ნივთიერებებსა თუ ნაკეთობებთან დაკავშირებით, კოდი შედგება ნომრისა და სახიფათო თვისებების აღმნიშვნელი ჯგუფისგან, რაც განმარტებულია 2.2.2.1.2 და 2.2.2.1.3 ქვეპუნქტებში; x = სახიფათო ნივთიერებებისა თუ ნაკეთობების კლასის ნომერი, აუცილებლობის შემთხვევაში, გამყოფი წერტილის გარეშე. 1 362 სვეტი (4) - 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 8 და 9 კლასებით გათვალისწინებულ სახიფათო ნივთიერებებსა და ნაკეთობებთან დაკავშირებული კოდების განმარტება მოცემულია 2.2.x.1.2 ქვეპუნქტში1; - მე-7 კლასის სახიფათო ნივთიერებებსა და ნაკეთობებს არ გააჩნიათ კლასიფიკაციის კოდი. „შეფუთვის ჯგუფი“ აღნიშნული სვეტი შეიცავს სახიფათო ნივთიერებაზე მინიჭებულ შეფუთვის ჯგუფის ნომერს (ნომრებს) (I, II, III). ამ შეფუთვის ჯგუფების მინიჭება ხდება მე-2 ნაწილით გათვალისწინებული პროცედურებისა და კრიტერიუმების საფუძველზე. შეფუთვის ჯგუფებს არ მიეკუთვნება გარკვეული ნაკეთობები და ნივთიერებები. სვეტი (5) „საშიშროების ნიშნები“ აღნიშნულ სვეტში მითითებულია საშიშროების ნიშნების/საინფორმაციო ტაბლოების ნიმუშის ნომერი (იხილეთ 5.2.2.2 და 5.3.1.7 პუნქტები), რომლებიც უნდა დამაგრდეს შეფუთვებზე, კონტეინერებზე, კონტეინერ-ცისტერნებზე, გადასატან ცისტერნებზე, მრავალელემენტიან აირის კონტეინერებსა და ავტოსატრანსპორტო საშუალებებზე. თუმცა მე-7 კლასის ნივთიერებებსა თუ ნაკეთობებთან დაკავშირებით, ნომერი „7X“ ნიშნავს ნიმუშის საშიშროების ნიშნის N7A, 7B ან 7C, შესაბამისი კატეგორიიდან გამომდინარე (იხილეთ 5.1.5.3.4 და 5.2.2.1.11.1 ქვეპუნქტები) ან საინფორმაციო ტაბლო N7D (იხილეთ 5.3.1.1.3 და 5.3.1.7.2 ქვეპუნქტები). საშიშროების ნიშნების/საინფორმაციო ტაბლოების მითითებასთან დაკავშირებული ზოგადი დებულებები (მაგალითად, ნიშნების ნომერი, მათი ადგილ-მდებარეობა) შეგიძლიათ მოიძიოთ 5.2.2.1 პუნქტში შეფუთვებთან დაკავშირებით და 5.3.1 პუნქტში კონტეინერებთან, კონტეინერ-ცისტერნებთან, მრავალელემენტიან აირის კონტეინერებთან, გადამზიდ ცისტერნებსა და ავტოსატრანსპორტო საშუალებებთან დაკავშირებით. შენიშვნა: (6) სვეტში მითითებულმა სპეციალურმა დებულებებმა შეიძლება შეცვალოს ზემოაღნიშნული, ნიშნების მითითებასთან დაკავშირებული დებულებები. სვეტი (6) „სპეციალური დებულებები“ ამ სვეტში მითითებულია სპეციალური დებულებების ციფრული კოდები, რომლებიც სისრულეში უნდა იქნეს მოყვანილი. აღნიშნული დებულებები მოიცავს საკითხების ფართო არეალს, განსაკუთრებით კი (1)-(5) სვეტებთან დაკავშირებულ საკითხებს (მაგალითად, გადაზიდვებთან დაკავშირებულ აკრძალვებს, მოთხოვნებისგან გათავისუფლებას, შესაბამისი სახიფათო ტვირთების გარკვეული ფორმების კლასიფიკაციასთან დაკავშირებულ განმარტებებს და დამატებით დებულებებს საშიშროების ნიშნების მითითებისა თუ მარკირების შესახებ) და ჩამოთვლილია 3.3 თავში დანომვრის წესით. იმ 363 შემთხვევაში, თუ (6) სვეტი ცარიელია, (1)-(5) სვეტებში წარმოდგენილ სახიფათო ტვირთებთან დაკავშირებით დაკავშირებით არ გამოიყენება სპეციალური დებულებები. სვეტი (7ა) „შეზღუდული ოდენობები“ აღნიშნულ სვეტში მითითებულია მაქსიმალური რაოდენობა სახიფათო ტვირთების გადასაზიდად განკუთვნილ ყოველ შიგა ტარასა თუ ნაკეთობაზე შეზღუდული ოდენობების სახით 3.4 თავის შესაბამისად. სვეტი (7ბ) „გამოთავისუფლებული ოდენობები“ ამ სვეტში მითითებულია ასოებით და ციფრებით გამოხატული კოდი, რომელსაც გააჩნია შემდეგი მნიშვნელობა: სვეტი (8) - „E0“ აღნიშნავს, რომ მოცემულ სახიფათო ტვირთებთან დაკავშირებით, რომლებიც შეფუთულია გამოთავისუფლებულ ოდენობებად, არ არსებობს რაიმე გამონაკლისი ADR_ის დებულებებიდან; - ყველა დანარჩენი ასოებით და ციფრებით გამოსახული კოდები, რომლებიც იწყება ასო „E“-თი, ნიშნავს, რომ ADR-ის დებულებები არ მოქმედებს იმ შემთხვევაში, თუ 3.5 თავში მითითებული პირობები შესრულებულია. „შეფუთვის ინსტრუქციები“ აღნიშნულ სვეტში მითითებულია შეფუთვის ინსტრუქციებში მითითებული ასოებითა და ციფრებით გამოსახული კოდები: - „P“ ასოთი დაწყებული ასოებითა და ციფრებით გამოხატული კოდები, რომლებიც ითვალისწინებს შეფუთვის ინსტრუქციებს ტარასა და ჭურჭელთან დაკავშირებით (გარდა მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებისა და მსხვილგაბარიტიანი შეფუთვებისა) ან „R“ ასოთი დაწყებული ასოებითა და ციფრებით გამოხატული კოდები, რომლებიც ითვალისწინებს შეფუთვის ინსტრუქციებს მსუბუქ ლითონის ტარასთან დაკავშირებით. აღნიშნული მოყვანილია 4.1.4.1 პუნქტში რიცხობრივი წესით და განსაზღვრავს გამოსაყენებლად ნებადართულ ტარასა და ჭურჭელს. მათში ასევე მითითებულია, 4.1.1, 4.1.2 და 4.1.3 პუნქტებით გათვალისწინებული საერთო შეფუთვის დებულებებიდან რომელი დებულება და 4.1.5, 4.1.6, 4.1.7, 4.1.8 და 4.1.9 პუნქტებით გათვალისწინებული სპეციალური შეფუთვის დებულებებიდან რომელი დებულება ექვემდებარება შესრულებას. იმ შემთხვევაში, თუ (8) სვეტი არ ითვალისწინებს „P“ ან „R“ ასოებით დაწყებულ კოდს, შესაბამისი სახიფათო ტვირთების გადატანა არ არის შესაძლებელი ტარაში; - „IBC“ ასოებით დაწყებული ასოებითა და ციფრებით გამოხატული კოდები, რომლებიც ითვალისწინებს შეფუთვის ინსტრუქციებს მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებთან დაკავშირებით. აღნიშნული მოყვანილია 4.1.4.2 პუნქტში 364 რიცხობრივი წესით და განსაზღვრავს გამოსაყენებლად ნებადართულ მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებს. მათში ასევე მითითებულია, 4.1.1, 4.1.2 და 4.1.3 პუნქტებით გათვალისწინებული საერთო შეფუთვის დებულებებიდან რომელი დებულება და 4.1.5, 4.1.6, 4.1.7, 4.1.8 და 4.1.9 პუნქტებით გათვალისწინებული სპეციალური შეფუთვის დებულებებიდან რომელი დებულება ექვემდებარება შესრულებას. იმ შემთხვევაში, თუ (8) სვეტი არ ითვალისწინებს „IBC“ ასოებით დაწყებულ კოდს, შესაბამისი სახიფათო ტვირთების გადატანა არ არის შესაძლებელი მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებში; - „LP“ ასოთი დაწყებული ასოებითა და ციფრებით გამოხატული კოდები, რომლებიც ითვალისწინებს შეფუთვის ინსტრუქციებს მსხვილგაბარიტიან ტარასთან დაკავშირებით. აღნიშნული მოყვანილია 4.1.4.3 პუნქტში რიცხობრივი წესით და განსაზღვრავს გამოსაყენებლად ნებადართულ მსხვილგაბარიტიან ტარას. მათში ასევე მითითებულია თუ 4.1.1, 4.1.2 და 4.1.3 პუნქტებით გათვალისწინებული საერთო შეფუთვის დებულებებიდან რომელი დებულება და 4.1.5, 4.1.6, 4.1.7, 4.1.8 და 4.1.9 პუნქტებით გათვალისწინებული სპეციალური შეფუთვის დებულებებიდან რომელი დებულება ექვემდებარება შესრულებას. იმ შემთხვევაში, თუ (8) სვეტი არ ითვალისწინებს „LP“ ასოებით დაწყებულ კოდს, შესაბამისი სახიფათო ტვირთების გადატანა არ არის შესაძლებელი მსხვილგაბარიტიან ტარაში; შენიშვნა: (9ა) სვეტში მითითებულმა სპეციალურმა შეფუთვის დებულებებმა შესაძლებელია შეცვალოს ზემოაღნიშნული შეფუთვის ინსტრუქცია. სვეტი (9ა) „შეფუთვის სპეციალური დებულებები“ აღნიშნულ სვეტში მითითებულია მოქმედი შეფუთვის სპეციალური დებულებებით გათვალისწინებული ასოებითა და ციფრებით გამოსახული კოდები: - „PP“ ან “RP” ასოებით დაწყებული ასოებითა და ციფრებით გამოხატული კოდები, რომლებიც ითვალისწინებს სპეციალური შეფუთვის დებულებებს ტარასა და ჭურჭელთან დაკავშირებით (გარდა მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებისა და მსხვილგაბარიტიანი შეფუთვებისა), რომლებიც დამატებით უნდა იქნეს შესრულებული. აღნიშნული დებულებები წარმოდგენილია 4.1.4.1 პუნქტში, (8) სვეტში მითითებული შესაბამისი შეფუთვის ინსტრუქციის ბოლოს („P“ ან “R” ასოებთან ერთად). იმ შემთხვევაში, თუ (9ა) სვეტი არ ითვალისწინებს „PP“ ან “RP” ასოებით დაწყებულ კოდს, არ გამოიყენება შესაბამისი შეფუთვის ინსტრუქციის ბოლოს ჩამოთვლილი სპეციალური შეფუთვის დებულებები; 365 სვეტი (9ბ) - „B“ ასოთი ან “BB” ასოებით დაწყებული ასოებითა და ციფრებით გამოხატული კოდები, რომლებიც ითვალისწინებს სპეციალური შეფუთვის დებულებებს მასიური ტვირთის საშუალო ტვირთამწეობის კონტეინერებთან დაკავშირებით, რომლებიც დამატებით უნდა შესრულდეს. აღნიშნული დებულებები წარმოდგენილია 4.1.4.2 პუნქტში, (8) სვეტში მითითებული შესაბამისი შეფუთვის ინსტრუქციის ბოლოს („IBC“ ასოებთან ერთად). იმ შემთხვევაში, თუ (9ა) სვეტი არ ითვალისწინებს „B“ ასოთი ან “BB” ასოებით დაწყებულ კოდს, არ გამოიყენება შესაბამისი შეფუთვის ინსტრუქციის ბოლოს ჩამოთვლილი სპეციალური შეფუთვის დებულებები; - „L“ ასოთი დაწყებული ასოებითა და ციფრებით გამოხატული კოდები, რომლებიც ითვალისწინებს სპეციალური შეფუთვის დებულებებს მსხვილგაბარიტიან ტარასთან დაკავშირებით, რომლებიც დამატებით უნდა შესრულდეს. აღნიშნული დებულებები წარმოდგენილია 4.1.4.3 პუნქტში, (8) სვეტში მითითებული შესაბამისი შეფუთვის ინსტრუქციის ბოლოს („LP“ ასოებთან ერთად). იმ შემთხვევაში, თუ (9ა) სვეტი არ ითვალისწინებს „L“ ასოთი დაწყებულ კოდს, არ გამოიყენება შესაბამისი შეფუთვის ინსტრუქციის ბოლოს ჩამოთვლილი სპეციალური შეფუთვის დებულებები. „შერეული შეფუთვის დებულებები“ - სვეტი (10) ამ სვეტში წარმოდგენილია მოქმედი შერეული შეფუთვის დებულებების „MP“ ასოებით დაწყებული ასოებითა და ციფრებით გამოხატული კოდები. აღნიშნული დებულებები ჩამოთვლილია 4.1.10 პუნქტში ნუმერაციული წესით. იმ შემთხვევაში, თუ (9ბ) სვეტი არ ითვალისწინებს „MP“ ასოებით დაწყებულ კოდს, გამოიყენება მხოლოდ საერთო მოთხოვნები (იხილეთ 4.1.1.5 და 4.1.1.6 პუნქტები). „გადამზიდ ცისტერნებსა და მასიური ტვირთის კონტეინერებთან დაკავშირებული ინსტრუქციები“ აღნიშნულ სვეტში მითითებულია 4.2.5.2.1-დან 4.2.5.2.4-მდე და 4.2.5.2.6 ქვეპუნქტების შესაბამისად გადასატანი ცისტერნების შესახებ ინსტრუქციის საფუძველზე მინიჭებული ასოებითა და ციფრებით გამოხატული კოდები. მოცემული ინსტრუქცია გადამზიდ ცისტერნებთან დაკავშირებით შეესაბამება ყველაზე ნაკლებად მკაცრ დებულებებს, რომლებიც მიღებულია გადამზიდ ცისტერნებში ნივთიერებების გადასაზიდად. სხვა გადამზიდი ცისტერნების ინსტრუქციების განმსაზღვრელი კოდები, რომლებიც ასევე ნებადართულია ნივთიერებების გადასაზიდად, წარმოდგენილია 4.2.5.2.5 ქვეპუნქტში. იმ შემთხვევაში, თუ კოდი საერთოდ არ არის მინიჭებული. გადაზიდვა გადამზიდ ცისტერნებში არ დაიშვება, თუ კომპეტენტური ორგანოს დასტური არ იქნა გაცემული, როგორც ეს გათვალისწინებულია 6.7.1.3 პუნქტში. 366 გადამზიდი ცისტერნების პროექტთან, კონსტრუქციასთან, აღჭურვილობასთან, ტიპის ოფიციალურ დამტკიცებასთან, გამოცდასა და მარკირებასთან დაკავშირებული საერთო მოთხოვნები წარმოდგენილია 6.7 თავში. გამოყენებასთან (მაგალითად, შევსებასთან) დაკავშირებული საერთო მოთხოვნები წარმოდგენილია 4.2.1-4.2.4 პუნქტებში. „(M)“ ასოს მითითება გულისხმობს, რომ ნივთიერებების გადაზიდვა შესაძლებელია გაეროს მრავალელემენტიან აირის კონტეინერებში. შენიშვნა: (11) სვეტში წარმოდგენილმა სპეციალურმა დებულებებმა შესაძლებელია შეცვალოს ზემოაღნიშნული მოთხოვნები. ამ სვეტში შესაძლებელია ასევე წარმოდგენილი იყოს „BK“ ასოებით დაწყებული ასოებითა და ციფრებით გამოხატული კოდები, რომლებიც ითვალისწინებს 6.11 თავში აღწერილ მასიური ტვირთის კონტეინერების ტიპებს და რომლებიც გამოიყენება მასიური ტვირთების გადასაზიდად 7.3.1.1 (ა) და 7.3.2 პუნქტების შესაბამისად. სვეტი (11) „გადამზიდ ცისტერნებსა და მასიური ტვირთის კონტეინერებთან დაკავშირებული სპეციალური დებულებები“ მოცემულ სვეტში გათვალისწინებულია გადამზიდი ცისტერნების სპეციალური დებულებების ასოებითა და ციფრებით გამოხატული კოდები, რომლებიც დამატებით უნდა შესრულდეს. აღნიშნული კოდები, რომლებიც იწყება „TP“ ასოებით, ითვალისწინებს სპეციალურ დებულებებს გადამზიდი ცისტერნების კონსტრუირებასა და გამოყენებასთან დაკავშირებით. ისინი წარმოდგენილია 4.2.5.3 პუნქტში. შენიშვნა: ტექნიკურ მოთხოვნებთან შესაბამისობის შემთხვევაში, აღნიშნული სპეციალური დებულებები გამოიყენება არა მხოლოდ (10) სვეტში მითითებულ გადამზიდ ცისტერნებთან დაკავშირებით, არამედ ასევე იმ გადამზიდ ცისტერნებთან დაკავშირებით, რომელთა გამოყენებაც ხდება 4.2.5.2.5 ქვეპუნქტის შესაბამისად. სვეტი (12) „ცისტერნის კოდები ADR-ის ცისტერნებთან დაკავშირებით“ აღნიშნულ სვეტში წარმოდგენილია ასოებითა და ციფრებით გამოხატული კოდი, რომელიც აღწერს ცისტერნის ტიპს 4.3.3.1.1 (მე-2 კლასით გათვალისწინებული აირების შემთხვევაში) ან 4.3.4.1.1 (3-9 კლასებით გათვალისწინებული ნივთიერებების შემთხვევაში) პუნქტების შესაბამისად. მოცემული ცისტერნის ტიპი შეესაბამება ყველაზე ნაკლებად მკაცრ დებულებებს ცისტერნების შესახებ, რომლებიც დადგენილია ADR-ის ცისტერნებში შესაბამისი ნივთიერებების გადასაზიდად. სხვა ნებადართული ცისტერნის ტიპების ამსახველი კოდები წარმოდგენილია 4.3.3.1.2 (მე-2 კლასით გათვალისწინებული აირების შემთხვევაში) ან 4.3.4.1.2 (3-9 კლასებით გათვალისწინებული ნივთიერებების შემთხვევაში) პუნქტებში. იმ შემთხვევაში, თუ კოდი არ არის მინიჭებული, ტვირთის გადაზიდვა ADR-ის ცისტერნებში არ დაიშვება. 367 იმ შემთხვევაში, თუ აღნიშნულ სვეტში მითითებულია ცისტერნის კოდი მყარ ნივთიერებებსა (S) და თხევად ნივთიერებებთან (L) დაკავშირებით, ეს ნიშნავს, რომ ამ ნივთიერების შეთავაზება ცისტერნებში გადასაზიდად შესაძლებელია მყარ ან თხევად (მდნარ) მდგომარეობაში. ზოგადად, აღნიშნული დებულება გამოიყენება იმ ნივთიერებებთან დაკავშირებით, რომელთა დნობის ტემპერატურა მერყეობს 200C-დან 1800C-მდე. იმ შემთხვევაში, თუ აღნიშნული სვეტის მყარი ნივთიერებებისთვის მითითებულია მხოლოდ თხევადი ნივთიერებებისთვის განკუთვნილი ცისტერნის კოდი (L), ეს ნიშნავს, რომ მოცემული ნივთიერების შეთავაზება ხდება ცისტერნებში გადასაზიდად მხოლოდ თხევად (მდნარ) მდგომარეობაში. კონსტრუირებასთან, აღჭურვილობასთან, ტიპის ოფიციალურ დამტკიცებასთან, გამოცდასა და მარკირებასთან დაკავშირებული საერთო მოთხოვნები, რომლებიც არ არის მითითებული ცისტერნის კოდში, წარმოდგენილია 6.8.1, 6.8.2, 6.8.3 და 6.8.5 პუნქტებში. გამოყენებასთან (მაგალითად, შევსების მაქსიმალურ ხარისხთან, მინიმალურ საცდელ წნევასთან) დაკავშირებული საერთო მოთხოვნები წარმოდგენილია 4.3.1-4.3.4 პუნქტებში. „(M)“ ასოს მითითება გულისხმობს, რომ ნივთიერების გადაზიდვა ასევე შესაძლებელია გაეროს ავტოსატრანსპორტო საშუალება-ბატარეებსა თუ მრავალელემენტიან აირის კონტეინერებში. ცისტერნის კოდის შემდეგ (+) ნიშნის მითითება გულისხმობს, რომ ცისტერნის ალტერნატიული გამოყენება დაშვებულია მხოლოდ იმ შემთხვევაში, როდესაც ეს გათვალისწინებულია ტიპის ოფიციალური დამტკიცების მოწმობაში. ბოჭკოებით გამაგრებული პლასტმასის ცისტერნებთან დაკავშირებით იხილეთ 4.4.1 პუნქტი და 6.9 თავი; ნარჩენების ვაკუუმურ ცისტერნებთან დაკავშირებით იხილეთ 4.5.1 პუნქტი და 6.10 თავი. შენიშვნა: (13) სვეტში წარმოდგენილმა სპეციალურმა დებულებებმა შესაძლებელია შეცვალოს ზემოაღნიშნული მოთხოვნები. თავი (13) „ADR-ის ცისტერნებთან დაკავშირებული სპეციალური დებულებები“ მოცემულ სვეტში გათვალისწინებულია ADR-ის ცისტერნებთან დაკავშირებული სპეციალური დებულებების ასოებით და ციფრებით გამოხატული კოდები, რომლებმაც ასევე უნდა შეასრულოს: - „TU“ ასოებით დაწყებული ასოებითა და ციფრებით გამოსახული კოდები ითვალისწინებს სპეციალურ დებულებებს აღნიშნული ცისტერნების გამოყენებასთან დაკავშირებით. ისინი წარმოდგენილია 4.3.5 პუნქტში; - „TC“ ასოებით დაწყებული ასოებითა და ციფრებით გამოსახული კოდები ითვალისწინებს სპეციალურ დებულებებს აღნიშნული 368 ცისტერნების კონსტრუირებასთან წარმოდგენილია 6.8.4(ა) პუნქტში; დაკავშირებით. ისინი - „TE“ ასოებით დაწყებული ასოებითა და ციფრებით გამოსახული კოდები ითვალისწინებს სპეციალურ დებულებებს აღნიშნული ცისტერნების აღჭურვილობის ელემენტებთან დაკავშირებით. ისინი წარმოდგენილია 6.8.4(ბ) პუნქტში; - „TA“ ასოებით დაწყებული ასოებითა და ციფრებით გამოსახული კოდები ითვალისწინებს სპეციალურ დებულებებს აღნიშნული ცისტერნების ტიპის ოფიციალურ დამტკიცებასთან დაკავშირებით. ისინი წარმოდგენილია 6.8.4(გ) პუნქტში; - „TT“ ასოებით დაწყებული ასოებითა და ციფრებით გამოსახული კოდები ითვალისწინებს სპეციალურ დებულებებს აღნიშნული ცისტერნების გამოცდასთან დაკავშირებით. ისინი წარმოდგენილია 6.8.4(დ) პუნქტში; - „TM“ ასოებით დაწყებული ასოებითა და ციფრებით გამოსახული კოდები ითვალისწინებს სპეციალურ დებულებებს აღნიშნული ცისტერნების მარკირებასთან დაკავშირებით. ისინი წარმოდგენილია 6.8.4(ე) პუნქტში. შენიშვნა: ტექნიკურ მოთხოვნებთან შესაბამისობის შემთხვევაში, აღნიშნული სპეციალური დებულებები გამოიყენება არა მხოლოდ (12) სვეტში მითითებულ ცისტერნებთან დაკავშირებით, არამედ ასევე იმ ცისტერნებთან დაკავშირებით, რომელთა გამოყენებაც შესაძლებელია 4.3.3.1.2 და 4.3.4.1.2 ქვეპუნქტებში გათვალისწინებული იერარქიის შესაბამისად. თავი (14) „ავტოსატრანსპორტო საშუალებები ცისტერნების გადასაზიდად“ აღნიშნულ სვეტში მითითებულია ავტოსატრანსპორტო საშუალების განმსაზღვრელი კოდი (მისაბმელების ან ნახევარმისაბმელების საწევარა ავტოსატრანსპორტო საშუალებების ჩათვლით) (იხილეთ 9.1.1 პუნქტი), რომლებიც გამოიყენება ნივთიერებების გადასაზიდად ცისტერნებში 7.4.2 პუნქტის შესაბამისად. ავტოსატრანსპორტო საშუალებების კონსტრუირებასა და დამტკიცებასთან დაკავშირებული მოთხოვნები წარმოდგენილია 9.1, 9.2 და 9.7 თავებში. თავი (15) „სატრანსპორტო კატეგორია / (გვირაბში გავლის შეზღუდვის კოდი)“ მოცემულ სვეტში უჯრის ზედა ნაწილში მითითებულია სატრანსპორტო კატეგორია, რომელსაც მიეკუთვნება ნივთიერება ან ნაკეთობა ყოველ სატრანსპორტო ერთეულში გადასაზიდ ოდენობებთან დაკავშირებული გამონაკლისების მიზნით (იხილეთ 1.1.3.6 პუნქტი). ამავე სვეტში უჯრის ქვედა ნაწილში ფრჩხილებში მითითებულია გვირაბში გავლის შეზღუდვის კოდი, რაც გულისხმობს საგზაო გვირაბებში გავლით ნივთიერებებისა თუ ნაკეთობების გადამტან ავტოსატრანსპორტო საშუალებების გავლასთან დაკავშირებულ შეზღუდვებს. ის წარმოდგენილია 8.6 თავში. იმ შემთხვევაში, თუ 369 გვირაბში გავლის შეზღუდვის კოდი არ არის მინიჭებული, ხდება ‘(-)’ ნიშნის მითითება. სვეტი (16) „სპეციალური შეფუთვები“ დებულებები გადაზიდვასთან დაკავშირებით - ამ სვეტში მითითებულია ტარაში გადაზიდვასთან დაკავშირებით მოქმედ სპეციალურ დებულებებში (ასეთის არსებობის შემთხვევაში) წარმოდგენილი „V“ ასოთი დაწყებული ასოებითა და ციფრებით გამოსახული კოდ(ებ)ი. მათი ჩამონათვალი მოცემულია 7.2.4 პუნქტში. ტარაში გადაზიდვასთან დაკავშირებული ზოგადი დებულებები წარმოდგენილია 7.1 და 7.2 თავებში. შენიშვნა: გარდა ამისა, (18) სვეტში მითითებული სპეციალური დებულებები დაცული უნდა იქნეს დატვირთვასთან, გადმოტვირთვასა და ტვირთის დამუშავებასთან დაკავშირებით. სვეტი (17) „სპეციალური დებულებები გადაზიდვასთან დაკავშირებით - საყარი ტვირთის გადაზიდვა“ ამ სვეტში მითითებულია საყარი ტვირთის გადაზიდვასთან დაკავშირებით მოქმედ დებულებებში წარმოდგენილი „VC“ ასოთი დაწყებული ასოებითა და ციფრებით გამოსახული კოდ(ებ)ი, ასევე „AP“ ასოთი დაწყებული ასოებითა და ციფრებით გამოსახული კოდ(ებ)ი. აღნიშნული დებულებები წარმოდგენილია 7.3.3 პუნქტში. იმ შემთხვევაში, თუ არ არის მითითებული კოდი ან მითითება კონკრეტულ პუნქტზე, საყარი ტვირთის გადაზიდვა არ დაიშვება. საყარი ტვირთის გადაზიდვასთან დაკავშირებული ზოგადი და დამატებითი დებულებები წარმოდგენილია 7.1 და 7.3 თავებში. შენიშვნა: გარდა ამისა, (18) სვეტში მითითებული სპეციალური დებულებები დაცული უნდა იქნეს დატვირთვასთან, გადმოტვირთვასა და ტვირთის დამუშავებასთან დაკავშირებით. სვეტი (18) „გადაზიდვასთან დაკავშირებული დატვირთვა და გადმოტვირთვა“ სპეციალური პირობები - ამ სვეტში წარმოდგენილია „CV“ ასოებით დაწყებული ასოებითა და ციფრებით გამოხატული კოდ(ებ)ი, რომლებიც გამოიყენება დატვირთვის, გადმოტვირთვისა და ტვირთის დამუშავების შესახებ არსებულ დებულებებთან დაკავშირებით. აღნიშნული დებულებები წარმოდგენილია 7.5.11 პუნქტში. იმ შემთხვევაში, თუ კოდი არ არის მოცემული, გამოიყენება მხოლოდ ზოგადი დებულებები (იხილეთ 7.5.17.5.10 პუნქტები). სვეტი (19) „გადაზიდვასთან ექსპლუატაცია“ დაკავშირებული სპეციალური დებულებები - ამ სვეტში წარმოდგენილია „S“ ასოთი დაწყებული ასოებითა და ციფრებით გამოხატული კოდ(ებ)ი, რომლებიც გამოიყენება 8.5 თავში ჩამოთვლილ ოპერაციების შესახებ მოქმედ დებულებებთან დაკავშირებით. აღნიშნული დებულებები გამოყენებულ უნდა იქნეს 8.1370 8.4 თავიების მოთხოვნებზე დამატებით, თუმცა 8.1-8.4 თავების მოთხოვნებთან შეუსაბამობის შემთხვევაში, უპირატესობა ენიჭება სპეციალურ დებულებებს. სვეტი (20) „საშიშროების საიდენტიფიკაციო ნომერი“ აღნიშნულ სვეტში გათვალისწინებულია ორ ან სამციფრიანი ნომერი (რომელთაც გარკვეულ შემთხვევებში წინ უძღვით ასო „X“) 2-9 კლასებით გათვალისწინებული ნივთიერებებისა და ნაკეთობების შემთხვევაში, ხოლო კლასიფიკაციის კოდს - 1-ლი კლასით გათვალისწინებული ნივთიერებებისა და ნაკეთობების შემთხვევაში (იხილეთ (3ბ) სვეტი). 5.3.2.1 პუნქტში აღწერილ შემთხვევებში, მოცემული ნიშანი წარმოდგენილია ნარინჯისფერი ნიშნის ზედა ნახევარში. საშიშროების საიდენტიფიკაციო ნომრების მნიშვნელობა განმარტებულია 5.3.2.3 პუნქტში. 371 372 ცხრილი A სახიფათო ტვირთების ჩამონათვალი 373 გაეროს № დასახელება და აღწერილობა 3.1.2 კლასი კლასიფ იკაციის კოდი შეფუთვ ის ჯგუფი საშიშროებ ის ნიშნები სპეციალური დებულებები შეზღუდული და გამოთავისუფლებ ული ოდენობები ტარა შეფუთვ ის ინსტრუ ქცია 4.1.4 სპეციალური დებულებები შეფუთვის შესახებ 4.1.4 დებულებები შერეული შეფუთვის შესახებ 4.1.10 (8) P112(ა) P112(ბ) P112(გ) P130 (9ა) PP26 (9ბ) MP20 PP67 L1 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 (2) ამონიუმის პიკრატი, მშრალი ან დასველებული, წყლის 10%-ზე ნაკლები მასური წილით ვაზნები იარაღისთვის, ფეთქებად მუხტთან ერთად (3ა) 1 (3ბ) 1.1D (4) (5) 1 (6) (7ა) 0 (7ბ) E0 1 1.1F 1 0 E0 0006 ვაზნები იარაღისთვის, ფეთქებად მუხტთან ერთად 1 1.1E 1 0 E0 P130 LP101 0007 ვაზნები იარაღისთვის, ფეთქებად მუხტთან ერთად 1 1.2F 1 0 E0 P130 0009 ცეცხლსასროლი საბრძოლო მასალა, ფეთქებადი, სამტვრევი ან სატყორცნი მუხტით ან მის გარეშე ცეცხლსასროლი საბრძოლო მასალა, ფეთქებადი, სამტვრევი ან სატყორცნი მუხტით ან მის გარეშე 1 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.3G 1 0 E0 P130 LP101 PP67 L1 MP23 0012 ვაზნები ინერტული ჭურვის მქონე იარაღისთვის ან ვაზნები მცირე ზომის სასროლი იარაღისთვის 1 1.4S 1.4 364 5 კგ E0 P130 MP23 MP24 0014 ვაზნები იარაღისთვის, ცარიელი ან ვაზნები მცირე ზომის სასროლი იარაღისთვის, ცარიელი ან ვაზნები ხელსაწყოებისთვის, ცარიელი კვამლის გამშვები საბრძოლო მასალა, ფეთქებადი, სამტვრევი ან სატყორცნი მუხტით ან მის გარეშე კვამლის გამშვები საბრძოლო მასალა, კოროზიული ნივთიერებების შემცველ ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე კვამლის გამშვები საბრძოლო მასალა, ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე კვამლის გამშვები საბრძოლო მასალა, კოროზიული ნივთიერებების შემცველ ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე საბრძოლო მასალა, ცრემლსადენი, ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე 1 1.4S 1.4 364 5 კგ E0 P130 MP23 MP24 1 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 1 1.2G 1 +8 0 E0 P130 LP101 PP67 L1 MP23 1 1.3G 1 0 E0 P130 LP101 PP67 L1 MP3 1 1.3G 1 +8 0 E0 P130 LP101 PP67 L1 MP3 1 1.2G 1 +6.1 +8 0 E0 P130 LP101 PP67 L1 MP3 0019 საბრძოლო მასალა, ცრემლსადენი, ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე 1 1.3G 1 +6.1 +8 0 E0 P130 LP101 PP67 L1 MP3 0020 საბრძოლო მასალა, ტოქსიკური, ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე საბრძოლო მასალა, ტოქსიკური, ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე შავი დენთი (თოფის წამალი), გრანულების ან ფხვნილის სახით 1 1.2K გადაზიდვა აკრძალულია 1 1.3K გადაზიდვა აკრძალულია 1 1.1D 1 0 E0 P113 PP50 MP20 MP24 0028 შავი დენთი (თოფის წამალი), შეკუმშული ან შავი ფხვნილი (თოფის წამალი), ქვეშებზე 1 1.1D 1 0 E0 P113 PP51 MP20 MP24 0029 დეტონატორები, არაელექტრო, ასაფეთქებელი სამუშაოებისთვის 1 1.1B 1 0 E0 P131 PP68 MP23 0030 დეტონატორები, ელექტრო, ასაფეთქებელი სამუშაოებისთვის 1 1.1B 1 0 E0 P131 (1) 0004 0005 0010 0015 0015 0016 0016 0018 0021 0027 374 MP23 MP21 MP23 MP23 გადამზიდი ცისტერნები და მასიური ტვირთის კონტეინერები ინსტრ სპეციალ უქციებ ური ი დებულე ბები 4.2.5.2.7 4.2.5.3 .3.2 (10) (11) ADR ცისტერნა ავტოსატრანსპ ორტო საშუალება ცისტერნის გადასაზიდად სატრანსპორტო კატეგორია (გვირაბში გავლის შეზღუდვის კოდი) სპეციალური დებულებები გადაზიდვასთან დაკავშირებით საყარი ტვირთის გადაზიდვა 7.3.3 დატვირთვა, გადმოტვირთვა და დამუშავება 7.5.11 ოპერაცია საშიშროე ბის საიდენტი ფიკაციო № 8.5 5.3.2.3 (17) (18) CV1 CV2 CV3 (19) S1 (20) V2 CV1 CV2 CV3 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 ცისტერნის კოდი სპეციალური დებულებები შეფუთვები 4.3 4.3.5, 6.8.4 9.1.1.2 1.1.3.6 (8.6) 7.2.4 (12) (13) (14) (15) 1 (B1000C) (16) V2 V3 1 (B1000C) გაეროს № დასახელებები და აღწერილობა 3.1.2 (1) 0004 (2) ამონიუმის პიკრატი, მშრალი ან დასველებული, წყლის 10%-ზე ნაკლები მასური წილით S1 0005 ვაზნები იარაღისთვის, ფეთქებად მუხტთან ერთად CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0006 ვაზნები იარაღისთვის, ფეთქებად მუხტთან ერთად S1 0007 ვაზნები იარაღისთვის, ფეთქებად მუხტთან ერთად S1 0009 S1 0010 ცეცხლსასროლი საბრძოლო მასალა, ფეთქებადი, სამტვრევი ან სატყორცნი მუხტით ან მის გარეშე ცეცხლსასროლი საბრძოლო მასალა, ფეთქებადი, სამტვრევი ან სატყორცნი მუხტით ან მის გარეშე CV1 CV2 CV3 CV1 CV2 CV3 S1 0012 S1 0014 CV1 CV2 CV3 CV1 CV2 CV3 S1 0015 S1 0015 CV1 CV2 CV3 CV1 CV2 CV3 S1 0016 S1 0016 CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV28 S1 0018 S1 0019 საბრძოლო მასალა, ცრემლსადენი, ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე გადაზიდვა აკრძალულია 0020 გადაზიდვა აკრძალულია 0021 საბრძოლო მასალა, ტოქსიკური, ფეთქებადი, სამტვრევი ან სატყორცნი მუხტით ან მათ გარეშე საბრძოლო მასალა, ტოქსიკური, ფეთქებადი, სამტვრევი ან სატყორცნი მუხტით ან მის გარეშე შავი დენთი (თოფის წამალი), გრანულების ან ფხვნილის სახით 4 (E) 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 1 (B1000C) V2 1 (C5000D) V2 1 (B1000C) V2 V3 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 ვაზნები ინერტული ჭურვის მქონე იარაღისთვის ან ვაზნები მცირე ზომის სასროლი იარაღისთვის ვაზნები იარაღისთვის, ცარიელი ან ვაზნები მცირე ზომის სასროლი იარაღისთვის, ცარიელი ან ვაზნები ხელსაწყოებისთვის, ცარიელი კვამლის გამშვები საბრძოლო მასალა, ფეთქებადი, სამტვრევი ან სატყორცნი მუხტით ან მის გარეშე კვამლის გამშვები საბრძოლო მასალა, კოროზიული ნივთიერებების შემცველ ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე კვამლის გამშვები საბრძოლო მასალა, ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე კვამლის გამშვები საბრძოლო მასალა, კოროზიული ნივთიერებების შემცველ ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე საბრძოლო მასალა, ცრემლსადენი, ფეთქებად, სამტვრევ ან სატყორცნ მუხტთან ერთად ან მის გარეშე CV1 CV2 CV3 CV1 CV2 CV3 S1 0027 S1 0028 შავი დენთი (თოფის წამალი), შეკუმშული ან შავი ფხვნილი (თოფის წამალი), ქვეშებზე CV1 CV2 CV3 CV1 CV2 CV3 S1 0029 დეტონატორები, არაელექტრო, ასაფეთქებელი სამუშაოებისთვის S1 0030 დეტონატორები, ელექტრო, ასაფეთქებელი სამუშაოებისთვის 375 გაეროს № დასახელება და აღწერილობა 3.1.2 კლასი კლასიფ იკაციის კოდი შეფუთვ ის ჯგუფი საშიშროებ ის ნიშნები სპეციალური დებულებები შეზღუდული და გამოთავისუფლებ ული ოდენობები ტარა 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 შეფუთვ ის ინსტრუ ქცია 4.1.4 სპეციალური დებულებები შეფუთვის შესახებ 4.1.4 დებულებები შერეული შეფუთვის შესახებ 4.1.10 (4) (5) 1 (6) (7ა) 0 (7ბ) E0 (8) P130 (9ა) (9ბ) MP23 (1) 0033 (2) ბომბები, ფეთქებადი მუხტით (3ა) 1 (3ბ) 1.1F 0034 ბომბები, ფეთქებადი მუხტით 1 1.1D 1 0 E0 P130 LP101 PP67 L1 MP21 0035 ბომბები, ფეთქებადი მუხტით 1 1.2D 1 0 E0 P130 LP101 PP67 L1 MP21 0037 ფოტოავიაბომბები 1 1.1F 1 0 E0 P130 0038 ფოტოავიაბომბები 1 1.2D 1 0 E0 P130 LP101 PP67 L1 MP21 0039 ფოტოავიაბომბები 1 1.2G 1 0 E0 P130 LP101 PP67 L1 MP23 0042 გამაძლიერებლები, დეტონატორის გარეშე 1 1.1D 1 0 E0 P132(ა) MP23 MP21 P132(ბ) 0043 ფეთქებადი მუხტები 1 1.1D 1 0 E0 P133 0044 კაფსულის ტიპის მილისი 1 1.4S 1.4 0 E0 P133 0048 ვაზნები, ფეთქებადი 1 1.1D 1 0 E0 P130 LP101 0049 ვაზნები, მანათობელი 1 1.1G 1 0 E0 P135 MP23 0050 ვაზნები, მანათობელი 1 1.3G 1 0 E0 P135 MP23 0054 ვაზნები, სასიგნალო 1 1.3G 1 0 E0 P135 MP23 MP24 0055 ვაზნის მასრები, ცარიელი, მილისით 1 1.4S 1.4 5 კგ E0 P136 MP23 0056 მუხტები, სიღრმისეული 1 1.1D 1 0 E0 P130 LP101 0059 კუმულაციური მუხტები, დეტონატორის გარეშე 1 1.1D 1 0 E0 P137 0060 დამატებითი მუხტები, ფეთქებადი 1 1.1D 1 0 E0 0065 მადეტონირებელი ზონარი, დრეკადი 1 1.1D 1 0 E0 P132(ა) P132(ბ ) P139 0066 ზონარი, მაალებელი 1 1.4G 1.4 0 E0 P140 MP23 0070 კაბელის საჭრისები, ფეთქებადი 1 1.4S 1.4 0 E0 P134 LP102 MP23 0072 ციკლოტრიმეთილენტრინიტრამინი (ციკლონიტი; ჰექსოგენი, RDX), დასველებული, არანაკლები 15% წყლის მასური წილით დეტონატორები საბრძოლო მასალისთვის 1 1.1D 1 0 E0 P112(ა) 1 1.1B 1 0 E0 P133 0073 376 364 266 PP69 MP21 MP23 MP24 PP67 L1 PP67 L1 PP70 MP21 MP21 MP21 MP21 PP71 PP72 PP45 MP21 MP20 MP23 გადამზიდი ცისტერნები და მასიური ტვირთის კონტეინერები ინსტრუ სპეციალ ქციები ური დებულე ბები 4.2.5.2.7. 4.2.5.3 3.2 (10) (11) ADR ცისტერნა ავტოსატრანსპ ორტო საშუალება ცისტერნის გადასაზიდად სატრანსპორტო კატეგორია (გვირაბში გავლის შეზღუდვის კოდი) ცისტერნის კოდი სპეციალური დებულებები 4.3 4.3.5, 6.8.4 9.1.1.2 (12) (13) (14) სპეციალური დებულებები გადაზიდვასთან დაკავშირებით შეფუთვები საყარი ტვირთის გადაზიდვა დატვირთვა, გადმოტვირთვა და დამუშავება 1.1.3.6 (8.6) 7.2.4 7.3.3 7.5.11 8.5 5.3.2.3 (15) 1 (B1000C) (16) V2 (17) (19) S1 (20) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 (18) CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (C5000D) V2 1 (C5000D) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 1 (B1000C) V2 2 (E) V2 4 (E) 1 (B1000C) V2 1 (B1000C) V2 ოპერაცია საშიშ როებ ის საიდე ნტიფ იკაცი ო№ გაერო ს№ დასახელებები და აღწერილობა 3.1.2 (1) 0033 (2) ბომბები, ფეთქებადი მუხტით S1 0034 ბომბები, ფეთქებადი მუხტით S1 0035 ბომბები, ფეთქებადი მუხტით S1 0037 ფოტოავიაბომბები S1 0038 ფოტოავიაბომბები CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0039 ფოტოავიაბომბები S1 0042 გამაძლიერებლები, დეტონატორის გარეშე S1 0043 ფეთქებადი მუხტები S1 0044 კაფსულის ტიპის მილისები S1 0048 მუხტები, ფეთქებადი S1 0049 ვაზნები, გასანათებელი S1 0050 ვაზნები, გასანათებელი S1 0054 ვაზნები, სასიგნალო S1 0055 ვაზნის მასრები, ცარიელი, მილისით S1 0056 მუხტები, სიღრმისეული S1 0059 კუმულაციური მუხტები, დეტონატორის გარეშე S1 0060 დამატებითი მუხტები, ფეთქებადი S1 0065 მადეტონირებელი ზონარი, დრეკადი S1 0066 ზონარი, მაალებელი S1 0070 კაბელის საჭრისები, ფეთქებადი S1 0072 ციკლოტრიმეთილენტრინიტრამინი (ციკლონიტი; ჰექსოგენი, RDX), დასველებული, არანაკლები 15% წყლის მასური წილით CV1 CV2 CV3 S1 0073 დეტონატორები საბრძოლო მასალისთვის 377 გაეროს № დასახელება და აღწერილობა კლასი კლასიფ იკაციის კოდი შეფუთვ ის ჯგუფი საშიშროებ ის ნიშნები სპეციალური დებულებები შეზღუდული და გამოთავისუფლებ ული ოდენობები ტარა 3.1.2 2.2 2.2 2.1.1.3 5.2.2 3.3 3.4.6 3.5.1.2 შეფუთვ ის ინსტრუ ქცია 4.1.4 (2) დიაზოდინიტროფენოლი, დასველებული, წყლის ან სპირტის და წყლის ნარევის არანაკლებ 40% მასური წილით დიეთილენგლიკოლდინიტრატი, დესენსიბილიზებული, არააქროლადი, წყალში უხსნადი ფლეგმატიზატორის არანაკლებ 25% მასური წილით დინიტროფენოლი, მშრალი ან დასველებული, წყლის არანაკლებ 15% მასური წილით (3ა) 1 (3ბ) 1.1A (4) (5) 1 (6) (7ა) 0 (7ბ) E0 P110(ბ) 1 1.1D 1 0 E0 P115 PP53 PP54 PP57 PP58 MP20 1 1.1D 1 +1,6 0 E0 P112(ა)P 112(ბ) P112(გ) PP26 MP20 დინიტროფენოლატები, ტუტე ლითონები, მშრალი ან დასველებული, წყლის არანაკლებ 15% მასიური წილით დინიტრორეზორცინოლი, მშრალი ან დასველებული, წყლის არანაკლებ 15% მასური წილით 1 1.3C 1 +1,6 0 E0 P114(ა) P114(ბ) PP26 MP20 1 1.1D 1 0 E0 P112(ა) P112(ბ) P112(გ) PP26 MP20 0079 ჰექსანიტრობიფენილამინი (დიპიკრილამინი; ჰექსილი) 1 1.1D 1 0 E0 P112(ბ) P112(გ) 0081 ფეთქებადი ნივთიერება, ბრიზანტული, A ტიპის 1 1.1D 1 0 E0 P116 PP263 PP66 MP20 0082 ფეთქებადი ნივთიერება, ბრიზანტული, B ტიპის 1 1.1D 1 0 E0 P116 PP61 PP62 MP20 ფეთქებადი ნივთიერება, ბრიზანტული, C ტიპის 1 1.1D 1.4 0 E0 IBC100 P116 B9 0083 0084 ფეთქებადი ნივთიერება, ბრიზანტული, D ტიპის 1 1.1D 1 0 E0 P116 MP20 0092 მანათობელი რაკეტები, სახმელეთო 1 1.3G 1 0 E0 P135 MP23 0093 მანათობელი რაკეტები, საავიაციო 1 1.3G 1 0 E0 P135 MP23 0094 დენთი პიროტექნიკული ნაკეთობებისთვის 1 1.1G 1 0 E0 P113 0099 ფეთქებადი ტორპედოები, დეტონატორის გარეშე, ნავთობის ჭებისთვის 1 1.1D 1.4 0 E0 P134 LP102 0101 სადგმული, არამადეტონირებელი 1 1.3G 1 0 E0 P140 PP74 PP75 MP23 0102 ზონარი (სადგმული), მადეტონირებელი, ლითონის გარსში 1 1.2 D 1 0 E0 P139 PP71 MP21 0103 სადგმული, მაალებელი, მილისებრი, ლითონის გარსში 1 1.4G 1,4 0 E0 P140 0104 1 1.4D 1,4 0 E0 P139 PP71 MP21 0105 ზონარი (სადგმული), მადეტონირებელი, სუსტი მოქმედების, ლითონის გარსში სადგმული, უსაფრთხო 1 1.4S 1.4 0 E0 P140 PP73 MP23 0106 მილები, მადეტონირებელი 1 1.1B 1 0 E0 P141 MP23 0107 მილები, მადეტონირებელი 1 1.2B 1 0 E0 P141 MP23 (1) 0074 0075 0076 0077 0078 378 სპეციალური დებულებები შეფუთვის შესახებ 4.1.4 დებულებები შერეული შეფუთვის შესახებ 4.1.10 (8) (9ა) PP42 (9ბ) MP20 MP20 MP20 PP49 MP20 MP21 MP23 გადამზიდი ცისტერნები და მასიური ტვირთის კონტეინერები ინსტრუ სპეცია ქციები ლური დებულ ებები 4.2.5.2.7. 4.2.5.3 3.2 (10) (11) ADR ცისტერნა ავტოსატრანსპ ორტო საშუალება ცისტერნის გადასაზიდად სატრანსპორტო კატეგორია (გვირაბში გავლის შეზღუდვის კოდი) სპეციალური დებულებები გადაზიდვასთან დაკავშირებით საყარი ტვირთის გადაზიდვა 7.3.3 დატვირთვა, გადმოტვირთვა და დამუშავება 7.5.11 ოპერაცია 8.5 5.3.2.3 (17) (18) (19) S1 (20) გაეროს № დასახელებები და აღწერილობა ცისტერნის კოდი სპეციალური დებულებები 4.3 4.3.5, 6.8.4 9.1.1.2 1.1.3.6 (8.6) 7.2.4 (12) (13) (14) (15) 0 (B) (16) V2 1 (B1000C) V2 CV1 CV2 CV3 S1 0075 1 (B1000C) V2 V3 S1 0076 1 (C 5000D) V2 V3 S1 0077 დინიტროფენოლატები, ტუტე ლითონები, მშრალი ან დასველებული, წყლის არანაკლებ 15% მასიური წილით 1 (B1000C) V2 V3 CV1 CV2 CV3 CV28 CV1 CV2 CV3 CV28 CV1 CV2 CV3 S1 0078 დინიტრორეზორცინოლი, მშრალი ან დასველებული, წყლის არანაკლებ 15% მასური წილით 1 (B1000C) V2 V3 CV1 CV2 CV3 S1 0079 ჰექსანიტრობიფენილამინი (დიპიკრილამინი; ჰექსილი) 1 (B1000C) V2 V3 V12 V2 V3 CV1 CV2 CV3 S1 0081 ფეთქებადი ნივთიერება, ბრიზანტული, A ტიპის CV1 CV2 CV3 S1 0082 ფეთქებადი ნივთიერება, ბრიზანტული, B ტიპის 1 (B1000C) V2 CV1 CV2 CV3 S1 0083 ფეთქებადი ნივთიერება, ბრიზანტული, C ტიპის 1 (B1000C) V2 S1 0084 ფეთქებადი ნივთიერება, ბრიზანტული, D ტიპის 1 (C 5000D) V2 S1 0092 მანათობელი რაკეტები, სახმელეთო 1 (C5000D) V2 V3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0093 მანათობელი რაკეტები, საავიაციო 1 (B5000C) V2 S1 0094 დენთი პიროტექნიკული ნაკეთობებისთვის 1 (B5000C) V2 S1 0099 ფეთქებადი ტორპედოები, დეტონატორის გარეშე, ნავთობის ჭებისთვის 1 (C5000D) V2 S1 0101 სადგმული, არამადეტონირებელი 1 (B1000C) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0102 ზონარი (სადგმული), მადეტონირებელი, ლითონის გარსში 2 (E) V2 CV1 CV2 CV3 S1 0103 სადგმული, მაალებელი, მილისებრი, ლითონის გარსში 2 (E) V2 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 CV1 CV2 CV3 S1 0104 ზონარი (სადგმული), მადეტონირებელი, სუსტი მოქმედების, ლითონის გარსში S1 0105 სადგმული, უსაფრთხო S1 0106 მილები, მადეტონირებელი S1 0107 მილები, მადეტონირებელი 1 (B1000C) შეფუთვები საშიშროე ბის საიდენტი ფიკაციო № 4 (E) 1 (B1000C) V2 1 (B1000C) V2 CV1 CV2 CV3 379 3.1.2 (1) 0074 (2) დიაზოდინიტროფენოლი, დასველებული, წყლის ან სპირტის და წყლის ნარევის არანაკლებ 40% მასური წილით დიეთილენგლიკოლდინიტრატი, დესენსიბილიზებული, არააქროლადი, წყალში უხსნადი ფლეგმატიზატორის არანაკლებ 25% მასური წილით დინიტროფენოლი, მშრალი ან დასველებული, წყლის არანაკლებ 15% მასური წილით qtrl$boqlbs Ar {006oqna, DCiSciJ It JS]|M Jq'Jb3 oloGtJ d8:cc8 d'an ?6UAO dl **loco .rreq$o a0o"qdobo 0t6r DA,E$6rf,rEqEb ro&lm&rrrm atausa .lr 3.t_2 (1) 0ll0 01 13 2.1.1 3 (2) (36) Ug0bid)Cbo, 36)rCOoJUq,o, bCq,ob G oJOJRob 1 0UJ6oq'6oO6obo0.6.- 01 l4 5.22 d (4) l4s oq)oo ggr6oq'6o6rtrobo0o6o- llA bur6oq'OCO6rb06o (OCO6Jt o6o), eJb$gCbUq'o,0Uq)ob 16 bJo6oob eJ fgq'ob 6lrtr6otr t6r6r3q,9b 3@/o-0rbg6o o6|rlec do6 33 3 4.6 e'cb"Jq,CaCbo Ed$bCb 4.1.10 (8) (9r) 0 EO P14l 26 0 EO 26 0 EO Pr lo(b) 0 EO P1 l2(r) Pll2(b) (7r) dooobo OCI$bCb 4r.4 (6) odldfu AC6c"Jen o88fs}3olt 4.1.4 | ACb?q'cbCbo 8mpo4.{t 3.s r.2 1,4 llA 6Ur60qOCO6Jbobo 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Jgttrojboq.o3bo, r6ro66r6gq'o, N.O S 5l 02 II 5l o2 III R00r 136 E2 5Ja E1 P002 MP2 ll TP33 B3 MP2 TI TP33 B4 MP2 IJ TP33 B4 MP2 B3 MP IO IBCO6 51 P002 rBc08 LP02 1484 1485 1486 3rq'rx;OoU brio0r6o Jrq'o36oU Cql06rOo Jrq)oC0ob boO6JOo R001 )l 02 5l o2 u lio E2 5l oTc m sJa EI u lJ8 E2 P002 IBCOS P002 IBCOS P002 IBCO8 Jrqo30ob 6o66r6nlrr q,r Olngf.Sanu o2 6oo6oootr 6J6mo 1488 JJq'oUAob 6o06oOo II 5t o2 3rq'og6ob Jgrijq'odr.l6o 5l 02 I1 5l tJo 3rq'opOoU Jgr60r661616o 5l o2 III 5.1 tJb 1491 3sq'og6oU J96oj|loqn )t 02 I -).r t492 Jrq'o30oU SC6UCq,grOo 51 02 III 5l o2 I] r489 1490 1493 3C6Obq'oU 60O6rOo B4 MPIO IJ TP33 B4 MPIO IJ TP33 lBc08 5l E2 P002 IBCOS tDc05 B4 IBCOS EO Pm2 51 E1 P503 dd MP2 TP33 MP2 TP33 MP2 IBCOS 5;A TP33 BK2 Rml lJ3 T1 BKI LPO2 1487 TP33 B3 MPIO TI TP33 B4 MPIO IJ TP33 B4 MP2 IJ TP33 B4 MP2 TI TP33 lBc08 LPO2 1494 r495 6rd6o3aob b600roo 6166og0oU jq'or!16o 5l 5l o2 II R001 51 lJb E2 P002 IBCOS o2 tI IJa E2 P002 I8C08 1496 646og0ob jq,o16o6o 5.1 o2 BKI BK2 II hb E2 Pm2 IBCO8 454 B4 MP2 T3 TP33 sR OClrJO66o €od\}Aftjo 600 bqCDe'cA, oot\!fr6dr AAA.ttsbQsA cq\)0@ .rr u\96rarJcx15o t J{06{r66 (0gor6!b&, nooiq?rn AabCqgooo 0r{DboQBrlDi6 a$}Aao6Cb.D $Oqrfr AirC6olJ c&lt l.lo qsl$bC(dC8o qs sq$C6qrSs trrrQ06o AC$etABdr Jc,{n) oaoSsoo oJ3JoBJbo Jp b$d6o l$Cr(a) A$0o6oi3r, ArqeaJgr6o€r a$C6iCN oN AD A$&JAJ6Obr 43 { 35.6E.4 911.2 r.r 3 6 (8.6) 724 (12) (13) (14) 05) (16) SCAV TI-r3 SCAV T1,B 3 (E) AT 2 SCAN ru3 AT TT,B AT 2 (E) 2 (18) vcl vc2 6/24 (1e) (20) (l) 50 t474 Ar66oUAoU VlI vcl vc2 cv24 s23 50 1475 tu66og0oU JC6Cq,06)Oo AP6 AP7 VII c,/24 50 vlI ql24 50 TU3 AT vcl vc2 3 (E) I SCAN TU3 AT SCAN TTB AT 2 6oO6rOCbo, J6r060r6Ugo, N.O S 1477 6o$t+rrgXbo, r6ro6gJ60q,o, N O S 50 t479 AJr60Jgo 6o3ooC6CbXbo, NO S 50 1479 05r66JAo 6ogooC6C09bo, N.O S 50 1479 0916613o 6o3oog6gb9bo, N.O S C\r24 v10 cv24 VII 6/24 (E) SCAV SCAV TLI3 TU3 TTB AT SCAN TTB AT TU3 2 V1I vc1 vc2 AP6 AP7 3 vcr vc2 (E) AP6 AP7 2 (E) c,/24 s23 50 1481 JCf)Cq,of)r0Cbo, r6Jo60rbUq'o, N O S al24 s23 50 t481 JC6dq,06JOCbo, r6to66rbgq,o, N,O S 50 1482 JC60r6ErbrOCbo, r6tortr6r63q,o. N O S cv24 50 1482 JC60rbAr6JOCbo, c,/24 50 1483 iC6oCUoeC0o, r6Jo66rbgq'o, N O.S 50 1483 JC6oCboeCoo, J6Jo66rbgq'o, N.O.S. ol24 50 1484 JrqloCAob b6oArOo cv24 50 1485 Jrq'o30ob Cq'06rOo a\/24 50 1486 Jrq,o0ooti 6006100 50 1487 J)q'oU0otr 6oO6JOobr pr 6166o90ob 6o(16o{.tob 6JF}mo 50 I48S Jrq)oUooL 6oO6oOo 50 1489 3rq'ogaob J36 jq'orgrgo 1490 JJq'o30ob JC66i6b)6rOo l49l 3tq,og0ob JS6ojlroq.oo 50 r492 3rq:o3dob Jgrlbgq'g160 c,/24 50 1493 3C60bq,oU 6oO6rOo 6/24 50 t494 6r06ouoob b600JOo 50 14% 6r06ogAob Cq'o(tiOo 50 1496 0rO6oCAoU Cq'm6ooo VI 3 (E) AT 2 s20 C\r24 (E) AT SCAN SCAN 3 (E) AT VII rE) SCAN TTB AT 3 (E) SCAV TU'3 SCAV TTR SCAV Tl-r3 2 (E) vlI AT 2 (E) VII AT 3 (E) AT vcl vc2 AP6 AP7 vcl vc2 AP6 AP7 vcl vc2 AP6 AP7 SCAV TLB AT 2 (E) VII vcl vc2 SCAV TL.r3 AT 2 (E) VII vcl vc2 SCAV TLB AT 2 (E) VII vcl vc2 SCAN TU3 2 (E) vlI c,/24 I vl0 c,/24 AP6 AP7 SCAV TU3 T1,B AT AT vcl vc2 TU3 AT SCAV TIR AT T'IR AT 2 (E) vll 2 VlI 2 (E s20 vcl vc2 AP6 AP7 vcl vc2 AP6 AP7 (E) SCAN s23 AP6 AP7 V1I (E) SCAV 6124 AP6 AP7 3 (E) 2 ol24 AP6 AP7 (E) SCAV 6166og0ob Jg6ojUopo AP6 AP7 (E) (2) 6oO6!Oo t477 (E) SCAV 312 AP6 AP7 (E) SCAN 532.3 (r7\ vcl vc2 AP6 AP7 VII 455 r6ro6r6r63q,o, N O S 0lcfut A$lDbCq'Jbi AD i{S060enbs l* rqdh JqJKA oJiod 8caJ.s Ja&n mStp d, t$adfxroo dJ tuAqoo tnCoorgurn ACb0earJbo ACtuefQflqn AD 0rAmicdfC$q'cb fqn cr($ob0oo Odt066C6o etr Ailraftr ooorioll, om30B bJfljo$q|Jft, aEb,Jq'chbo aCdrf,J(m 0mUo8di dcg3ol3(lj icrD ECbobCb dCL$Cb 4 t,4 4,t,4 4.1 10 4.25.2.7. (9r) (%) (10) (il) B3 MPIO T1 TP33 d, od$eJ 312 22 (r) 1498 t499 ooooJoo 6JO6.{Aob 6oo6)Oobr qgr 3rq,o30oU 2.1.1.3 5-22 33 346 (6) (7r) (3J) (3b) (4) (5) 5l 02 III 5t 6oO6rOoL 6r6Cao ET P002 5l 51 5Jo BK1 BK2 E1 EI 5Ja +6 I I502 6s6t6og0olr J96{q'o6r6o 1503 bJO60UAoU JC@J66JbJOo 1504 1505 5I 5l o2 51 o2 5l 02 6r06oUaob JC6oCtroeo 6rO60UAob JC6bgq'gJOo II 02 rI {25.3 P002 B3 TI MPIO TP33 BKI BK2 R00l 5l III Q2 qu60 cacDo LPO2 IBC08 b)oitoUAob 60O60Oo ITJCON qJb"q IBCO8 LPO2 l5m CGoCoo l2 t rzd) 5;O od\)(r)lJ R001 III 02 5.1 | 3.5.1. l2 D{NftoAo 0rr6J P002 B3 MPIO TI TP33 MP2 IJ TP33 MP2 T3 TP33 tBc08 R001 5l h6 E2 P002 IBCO6 5I lJb E2 5l 0 EO 51 s.lo EI P002 IBCO6 P003 MP2 IBCO5 III P002 B3 MPlO TI TP33 84 MP2 IJ TP33 B3 MPIO T1 IP33 IBCOS LP02 R00t 1506 UO6060oUAob Cq'o6rOo 51 o2 II 5t 1507 bO6060cUAoU 600610o 5l o2 III )l ho E2 P002 IBCOS E1 P002 IBCOS LP02 ts08 l5@ l5l0 b06o60oUAob JC6Cq'oi6JOo bd6060o3Aob JC6oCtroeo OCO6J6oO6moCor60 R00l 5l 02 I] 5l 02 II 5t l3b E2 I ol 0 EO "JO E1 6l 51 316br0oqnb $9rq'0rqnb JXr6ojlroq,o 5l opooolr r0o6og0otj 6006000 oc2 III 5l 02 II o2 0 t5 l4 oCoooU 6oO6rOo )l o2 II )l r5l5 ogooolr J360r661616o 51 o2 II 5r 1516 ogoooLr Jg6ojbogn 5l 02 II 5l l5 l7 6ori3o6o30ob Jo3dtar6o, qtb3Xqg0gqDUE olr r6r6rJgC0 2fflo dtb_q6o gocroo 4l t 4t JOC0060o163oe6o60, bOrboq,otrCbUq,o 6l n 6l Jq'JJgooeob 0J6oq'gbo, 0916o, N O.S t544 rq'3rq'ooq6bo, 0916o, N.O S. 16 rqrJcq'ooq.ooU 0r6oe,Obo, agrrtro. N O.S t544 rq'3rq'ooqrgbo, agulo, N.O S. 16 rqr3oq:ooqpob 0r6oq'3bo, 0p6o, N,O S 6l TP33 MP2 IJ T2 TP33 T2 6l E MP8 MP17 P002 B3 MP2 T1 IP33 B4 MPIO IJ TP33 B4 MP2 TP33 B4 MPIO TP33 MP2 TP33 R00l lao E2 lJ6 P002 E2 P002 IBCOS lJb E2 Pm2 IBCO8 ol lJ6 E2 lJo E2 354 0 EO P406 0 EO P@2 0 E5 MP2 IJ 43 43 PP26 TP33 MP2 MP8 MP17 T20 MPI8 T6 TP33 B4 MPIO ll TP33 B3 MPlO TI TP33 MPI5 n TP2 MPIO IJ MPI5 D P002 TP2 TP37 tBc07 500A E4 274 6l P002 IBCO6 43 II P002 IBCO6 274 6l P@2 IBCO8 5l Jq,JJq'ooe3bo, AgJ6o, N O.S $ P002 IBCOS 5l oJoooU Cq)o6JOo 1544 MP2 @9 51 t)lJ l54l P002 IBCO6 +8 1512 E2 rBc06 TOI +5 I t5l lJa Pm2 IBCO8 53a LI P002 IBCO8 LPO2 I545 r546 1547 lqtoq'o$ooocgo16rgo, b6rboq,oSgbgq,o 6l R001 TF l0O6q' E4 +3 r0o6oUAob r6bCbrOo 6l l) n J6oq'o60 ol TI II 6.1 P001 IBCO2 50OA E4 P002 B4 IBCOS o.t lLuttql E4 Pml IBCO2 456 TP33 TP2 DR OdrJO6 t$Offihf\Jo Slq6$(&BilsNS q6J€ao6C6@ &o@eD Ja{n AdsbC<tbobo qD rq$Cdx{+As 0tCt6al N tJ*ra66o aCkUABd Jat{n) ootro066 ctu tiitso66o Coolj (0306$A0 oi3qnb b.ltr6o oo(x1orft Aoboetrbobo atlC6r0c €o3roo ON $aa$,riour as ADaJa)oCb) 43 4 3 5,6.8 { (l2) (13) SCA\ TL]"3 SCAV SCAN TU3 TLB SCAV TU3 SCAN TTB 1.1.3.6 (&6) 7 2,1 (14) (ls) (16) AT AT 5.ll E5 (17\ (18) (19) (20) vcl vc2 (1) 3 (E) al24 50 1498 3 (E) vcl vc2 6/24 50 t49D AT AP5 AP7 6,t24 CV28 VII {E) vcr vc2 TTB c,/24 2 (E) V1I c,t24 I vl0 c'/24 SCAV TIJB SCAV TIR AT AT 3 vcl vc2 (E) AP6 AP7 2 (E) VlI ILJ"3 AT SCAN T1,B AT TU14 TUI5 AT s23 TE19 TE2I SCAI,I TU'3 vcl vc2 vcl vc2 2 (E) VII 50 1502 6JO609Aob 3C6Cq'n6rOo 50 1503 br06oUAob JCffrbbJ6JOo 1504 6JO6oCAob JC6oCboeo ol24 50 1505 6r06.rJ0ob JC6bUq,gJOo al24 50 r506 bO6r0600gOob Cq'c'6rOo (\24 50 1507 ti06060oCAob 6o0(6JOo 2 v11 vcl vc2 50 ls08 bg6o66o96ob Jg6Cq,o6JOo al24 s23 AP6 AP7 c,r24 I 5o cvl s9s14 b66o66ogOotr Jgrlojboq.oo 665 1510 0C0616o06oo0o16o 58 15ll J16br0oeolt $gJq,0Jeolt JC6oCboeo 6/24 50 1512 o3ooob JAo6oCAob 6006000 c{24 50 l5l3 ogooolr jq'o6rgo 50 l5l4 ouooob 6oO6JOo cvl3 cv28 g,/24 3 (E) SCAN TLB AT 2 (E) VII SCAV TIR AT 2 (E) VII AT 2 SCAN 6!06oCAob 6o0600o AP6 AP7 (B/D) AT 1500 s20 (E) LIOCH 56 AP6 AP7 3 (E) SCAV bJO6oC0ob 6oO6JOobJ (,r JJgoUAob AP6 AP7 (E) scAv (2) 6r06oCAob 6006rOo 6oo6root 6r6Cao 3 2 312 AP6 AP7 (E) AT AT 7 vc1 vc2 AP6 AP7 VII {E) SCAN TLT3 AT 2 (E) VII al24 50 l5l5 oUooob JC60J66J6JOo SCAN TI.-B AT 2 (E) vll al24 50 1516 o0ooob JC6oCboeo 1517 6or13m6op0ob Jo36rArOo, erbgCq'Cbgq'o, $gq,oU irisbtlg4b 2CPlo 0rbrtlo Soeoo r0C0060o163oe6o6o, tr6rboq'ot4bpq'o I sl4 tB) LlOCH TUI4 TUI5 AT TE19 TE21 S1OAH i cvl (c/D) 1 vl0 cvl (c/Et TUI5 TUI9 L4BH SCAH L4BH TUT5 TUI9 L4BH AT 2 (D/F} l54l s9sl4 6 1544 AT FL 2 AT 2 (D/E) L48H TUls tul9 AT 2 (DiE) cvl3 AP7 cv28 cvt3 D/'E) ru15 TU19 s9sl9 vcl vc2 vlI 60 1544 rqr3rqnoq.o3bo, 0916o, N O S 16 s9 1544 lq'3rqrooqrgbo, dgu6o, N O S 16 sq'3rq'oopolr 6s6oq,C0o, AgJ6o, N O S s2 s9 sl9 639 1545 Jq)oq)oSoooo0oJbrOo, bOi6oqob0bUq,o 59 S19 60 r546 J0oEcrJaob J6tr0bJOo s9 s19 60 1547 J60q)06o CV28 cvl3 cv28 CVI3 cv28 457 rg3Jq,oocQCbo, agr6o, N O S 16 rq'3rq,oopoU O;rtroq'g0o, 09160, N O S cv28 2 SCAX cv13 cv28 vll (E) TUI5 TU19 69 cv28 TUI5 TU19 SCAH s9sl4 cvl3 Jqtrr{s l* deM Jq$lr,S oJAod Joao &cgJ"rg dJ ts8.8&roo tsCoor<?i6o ob etr60bo oCbe"AUqb Ab Crh DarE Aptro8qd ?aacso OEJOB 3.12 0) 22 (2) rboq:o60U 30e6oCq,06oeo 1548 22 6!{'$t tAn 0di0c6qbo as arltlJ6o oodtorrr leD a,aoEa&Jbo 3.4.6 2.1.1.3 (3r) (30) (4) (t 61 T2 III 6l (6) (7r) | r;.' 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P002 59 EI P002 IBCO8 1870 l87l 1872- w2 4l TJ 5t oT2 n TP33 ll TI TP33 R00l 43 4l II 0 EO lJa E2 P,103 P4l 0 MP2 PP4O MPII IJ TP33 B3 MP2 TI TP33 MP3 T10 TPI MPlO TI TP33 IBCO4 )l EI +6 I P002 IBCOS LPO2 1873 5.1 I884 tl LPO2 3iqrq30ob bortr3oq6oq.oo 0o0Jbob 3oe6oeo MPIO IBCO6 br6oUAob Jr6bo o.l ocl 51 R00l 60 0 +8 T5 61 EO Ps02 EI Pm2 IBCOS r LP02 885 ol T2 tI ol 1885 61 TI I 6l R00l 500 a E4 tOOOrp u P002 P00l IBCO2 482 B4 MPIO TP33 IBCO8 MPI5 T7 TP2 sR odllJofiSr rood\trNarJo b\)laf})r"6,Jo 60m IrrEJogCbJ b!{sboaDa Crfrj0'66 .tu Ja|{n atrDcq$cbo 4.3 4.3.5.6J.{ 02) LI 5BN uhcoqJrto aobcq'fcbo aartoaorth$ J$6adr 91.12 l.t3 6 (8 6) 04) FL 6rqDtnq6r qD qDqCAACbr 7.2 1 7,3 3 7,5.11 06) (r7] (18) 2 2 LGBT s2 s20 1865 6-J6er]oq'6o6 (D/E) s2 s20 r866 gobob blrbr6o, rq6oq,Jrq,CbJ toltr s2 s20 r865 I I 2 s2 s20 33 1866 (DiE) s2 33 1866 3 (E) S2 tw 3 (E) S2 1866 3 vll 3 I cv28 AT 40 VI cv23 nn TU28 AT SGAH L4BH TUI5 TE19 AT 3 c'|24 cv28 I cv24 s20 cv13 cv28 s9 (B/E) SGAH L4BH ru15 TE19 L4BH TUI5 TE19 AT 2 (E) 2 (D/E) AT s20 2 (E) (E) L4DN(+) ellJ606J6o vcl vc2 (E) TLB b) 2 (E) (E) SGAN gsoononr, ooffi@.rr- r853 (E) AT 1853 30 AT SGAN (l) 33 s2 FL SGAV (20) 3 (D/E) SGAN (le) s2 s20 (D/E) FL LGBF 53:3 1863 FL FLlt N 33 FI Ll 5BN q'i rdCi6oqr$J s2 s20 (D/E) L4BN AJ$WCbo N @C 6C0JCf,iOU6rbC FL LGBF a)C6d) tsoJiom q{0o6o€J, 6'(paqbof,oUr (D,'E) LGBF ffiCb d tJyXeCSOo ACeUsSCbo (13) aD$arqco; (036.b8o 6!3qdt 0CtarqBo{, JF,{n) OdtJor66ob 2 (D/E) vct vc2 AP7 1869 1870 40 l87l 56 1872 558 1873 ;t;;,,Jfi ;;1,i1oin-o-'o'"'"or.rru 1884 br6og6olr gr66o bnbbooo6o CVI3 c!r28 s9 sl9 60 r885 cv13 cv28 s9 s19 60 1886 483 O$ooU o6UJ60o 484 A-DR OolrJO650 €odqjrtuBrJo fuo t\r&JD(S$ od$oi66ob ts{st('aw :rFt tsffI"q?,q"@ uJotrDsdoqjo NSF|C$ (AsdtNaao 8C\fqB.n JqAn) ACbK'CeJbo 43 4 35,68.{ 91,12 (12) (13) (14) L4BH TUI5 TEIg 1.1 3.6 (8.6) AT 724 ru15 TE19 AT N 7,5 t1 85 5.32.3 08) oe) (20) CVI3 (r) s9 60 1887 s9 60 r888 s9 s14 668 1889 0oJ6ob b6oaoeo AD A[arBaCbr 73i 0n v12 cvl3 (D/E) SlOAH LlOCH aBC6O6 aqjcr6o'aD, cv28 2 3 (D/E) TE19 TE2I cvl CVI3 L4BH ru15 TEl9 AT 2 LIOCH TUT4 TUI5 AT I TE19 TE2I SCAII SGAH L4BH c\28 cvl3 AT rul5 TElg AT s9 sl9 60 1891 uu^,q{)u ooooo(,o s9 sl4 6 1892 9ooq'qtojqorlrribo6o SS St9 & I894 s9 S19 60 s9 60 t897 OCO6rCq'o6CooqCbo 80 r898 J0COoq'oU 80 1902 q9*t*co"-Cr,qa;[ts;bdf$ 88 1903 80 1903 80 1903 88 1905 80 lqi6 80 lm7 cv28 cvl (D,C) TUI5 TE19 cvl3 cv28 vll 2 (Dto) CVl3 cv28 vll 2 (D/E) TUI5 TE19 cvl3 | | v12 (D/E) L4BN AT cv28 AT 3 AT AT L4BN s20 3 (E) v12 I vl0 AT s20 (E) AT SGAV AT L4BV(+) Arlt TEI I AT - 3 (E) I vcl vc2 AP7 (B/E) 2 (E) FL TT9 80 1908 80 1908 CV9 s2 s14 l9l I cv10 2 cv9 s2 s20 23 19t2 s20 22 1913 s2 30 L9t4 CV9 (c/r) FL 3 v12 (D/E) LGBF L48H FL TU15 TEIg S2 30 1915 s2 s9 sl9 63 l9l6 qpobori16o 3 'tA4 LGBF dq,06oOoU bU616o 1910 I (B/D) TUI9 oco; 6'o,''Ga'l, ooo3ocdu CVlO Rf,BN FL ooc3JQo, Ugq'g5ou fu€J vr2 I TA4 I uru-Jrq'coJ, 3:t1H3i"*'"',%bc (D) PIBN(M Nn C 2 (E) TEI I fJJq,CoJ, oocaJeo, .lomoboq@^ 2 (E) AT L4BN oo(roK,o 3 (D/E) L4BN gg6oqts366bq'o v12 (D/E) LlOBH ,r.dur,3oq)ouguq'ou JoQ6cuJ60o 3 (D/E) L4BN SIOAN 3l: CV28 TUl4rul5 eJslCe'OC0" eo ieOCrr,(<-"A, N aoarom bfn6o O0o6arf, A'ADb.eBr vt2 2 (D,E) L4BH 0A0f,cn kq06oo aCgfsRJbo "U.nq" W€lqoob A.aeytu 3 (D/E) 2 (D/E) vt2 cv13 cv28 48s go3q'o39jbs6o6o ilocoo aot$bcq$"e"r,@-- 0rcfnb t+ Jqrlb Jgurg ocguo! olOfttu Joan LftA6xD0b trjo0cq?6o OCtqfqqn qu dr boa6cbo On6o Da,ENOdJicgq'c8 UqD r{'CeebCbo ?e6ugo 0rQiotoao od,og6bao qD arbJ6,100d6od, omJo€ 22 (l 1917 l9l8 cooq,r36oq,r6o, bgronq,-tffi 3.3 21.13 (3r) (3b) (4) (s) 3 FI tII J [l otcrtocr.loq'goo96b@i- 3.4.5 | (6) do6 odsbCb 1.t.1 Ll.l0 €)- ab') E2 1920 t92l c#n a.Jacq Cbabo 4.2.5L7. 1253 32 (9r) (%) MPI9 (10) T4 TPI MP19 T2 TPI T4 TPI MPI9 T2 TPl MP2 Tl4 TP2 MP19 n TPI MPI4 IJ TP33 P001 IBCO2 EI Pml IBCO3 1919 l9Jo6 Coq&, R00l III FI ac8col€rl, l"t^.,. (7r) o8$ec AC6CCqn odJOeO LPOI aCooq'rJ6oq jOo, bOr6fio6]b,crt. 3 tt R00t lq, 3 E2 P00l IBCO2 6o6169bo 3 FI R001 II 5q' EI P001 IBCO3 LPOI ton t"q'coraosc,, uOlSiEiEFdG 3 FTI R00l 3 0 P00l EO + 6.1 t922 3 1923 \, \Joq/o(ruoou 1928 (roooeo cocbdo \929 lq' 3 +8 42 COoq)ob II FC s4 43 wFl E2 42 0 E2 III 43 0 EO 0 E2 +3 3rgogdoU qnooo6o6n 6rq,nl6lu Jo(,ooUUq,go0o) 42 s4 II 42 9 Mll III 9 I93l JoprtroUgqrgo6o) P00l IBCO2 II P4l0 tBc06 P&2 RR8 P410 MP2 MPI4 TP33 LPO6 Jb P002 B3 MPIO T1 TP33 Pl4 TI TP33 IBCOS 1932 LPO2 6o63o6og0ob 6rti8969bo 42 R00l S4 524 592 0 EI P002 IBCO8 LPO2 r935 61 R001 T4 274 0 L) MP8 i P00l 525 1935 1935 6l T4 no16ooob III T4 ol 274 MPIT | l@0q, E4 )z> 6l 274 P001 MPI5 IBCO2 5q' MPI9 IBCO3 Tll T7 8 LJ II lq' 8 1938 8 LJ III EI P00t P001 MPI5 n MPI9 'r7 IBCO2 1939 8 c2 II 8 c3 tII 8 136 1940 E2 l94t 9 Mll E2 LPOl R00l PW2 B4 MPlO P001 MP15 IBCO2 9 EI P00l LPO] t942 5l 02 5.1 306 EI P002 B3 t0 IBCOS 41 FI 4l 5;A EI PQ7 MPII R001 t945 41 tt 4l 2 EI P407 R001 486 Tll w2 T1 TP33 BK2 R00l ac TP' BKI LPO2 3oq"og0o) T] R001 6ll t944 TP2 TP33 IBCO8 8 TP2 R001 E2 IBCO2 8 TP2 TP28 LPOl t938 TP2 TP27 TP27 f,t 525 rra' Pll ADR od13glbJ- €Cd,\JsrdJJo 6'Jo t'rEUpq$J Odr00d,6ot od$c66 6 3a|{n 43 ***" I btc.-<"co" I I l.r s,os I (12) DArlrotoq|lA \!tudrJa4Jm UJC6"rq13.6"ACDJq,JACb"@ 9,1.1 2 1.13.6 (&6) (l 04) LCBF FL LGBF 7,2.4 -l15) 7.33 I I 5.31.3 (rn (18) (19) (20) (1) s2 s20 339 t9t7 s2 30 1918 s2 s20 339 1919 30 1920 s2 s22 336 1921 s2 s20 338 1922 40 1923 x323 1928 vt2 2 (D/E) LGBF FL FL rul4TUl5 FL I cvl3 (D/E) CV28 FL ffi 2 (D/E) AT 2 VI (D/E) LIODH FL 0 (D/E) TU22 TE2I TM2 vl s2 s20 2 (D/E) SCAV L4BH 1929 90 I931 n 1932 s9 s14 6 1935 go$oqrobbb6rrlo,NO- s9 sl9 60 93s 6orboqnb blr6rr+ro, N.OS S9 60 1935 0or6oeoU blr6r6o, Nbj 80 1938 ooo0oaloqrgrrr UIOIEi 80 1938 oooodosofo rsrlr b[6jEi- 80 1939 gob gmr6oU .3bob6.6ifo- (E) 80 1940 ooo6q'o3oq'olr 0g13r (E) 90 1941 eob6o0eoBOo6AC 50 1942 AT TUI4 TUI5 TEI9 TE21 VI 3 (E) vcl vc2 3 (E) vcl vc2 AT roeoouUq,tso0o) API I cvl (c7E) TUl5 TEIg AT TUI5 TE19 AT cvl3 L4BN 2 cvl3 (D/E) cv28 cv13 cv28 vt2 AT L4BN (E) AT vll (E) L4BN AT L4BN AT TT,IJ AT 0063oboUAoU 6JF,BC6Cbo 2 AT SCAN uooo (Jrq'ouirot cv28 (E) SGAV 09ooq'0lxb 40 AT SGAN L4BH ov*u'Ju'u lu{)u)oooooo (JJql3ouaob gogr!0o SGAN LlOCH @ vt2 2 (E) TE21 L4BH Cooq'rJoogJoo, UoJboq,obob 3 (D/E) LI5CH N nrC6506 I 2 (D/E) FI It ao3\J@ Itqr56o I $eotrpsr aot$h(SCb"ari1ffi arC6cir ob lveCboo Ec8CoRCbo (13) ffiCo 68da$&, tr0ern ACb{fAB.fJ Jc{n) 3 (E) VCI VC2 C\r24 AP6 AP7 /uu^,ur{JoouJ (E) 1944 (E) 1945 487 ruouu^,,-uurBoo0o (tio860o, 0J6Jobr o3 3oq'ogtso) DCr6.b a$bCqds qD WVCriq&bJ le JeDlh olofflJ oFcqa d, doao ?aoao JqDlbS [9dt6arJb t Jcoo{l9(6o ob 6oa6Cbo Aab?qtbCbo aotelcpOen qr 0i55 Ecgcoa 2.1 1.3 (3r) (36) (4) 522 (l s3fn'boqlbo, Obgor3o 1950 5A 22 33 3.{.6 (6) (7r) 190 lqr 327 1950 351 A08,Jq,cbCbo ECgflo8olt ECSUoA.ll JCTD ACbrbCb eJshb 4.1.4 4,t.4 4.1 10 2 (E) (9r) (%) P207 PP87 MP9 EO LPO2 l) P207 PP87 22 190 +5 I 327 2 1950 5F EO t2 P207 PP87 21 g 190 l: 2 3o6obopq,o +8 \zoubJSo 22 625 ls +5 I 327 50 2 v4 EO LPO2 L2 P207 PP87 136o$oq'gbo, 6ojbo3g6o 2 22 190 +6 1 327 I re EO t2 P207 PP87 I 'J"Joo, JOoo\5oUq,o 2 5TC IT 22 | lq' EO LPO2 12 P207 PP87 1200q, EO 2 1950 -v ", '\ uv\r, o' rcu(JJu(ror J(yJoq'JJq,CArC.oo, 2 Jo6otoCq,o 2L 190 +6 I 327 5TO l20aq' EO +8 u4 22 +5 I +6 I '\ r".,, u. IUUJJ('(J, oJJo6J3o, v _ Sooo'trcrJq)o 2 5TOC r951 190 1200q' EO EO zUdq) EO 1952 uJooo0mogJb0ou gooq,g6oU grb6ob ossoosq'o rooo, .16[f,]!1f, rqr3oqruqlbtpo, N O S 2 2 , 3A 2A, 2.2 n ITF 1955 o$3aa3q. roA;;6i;F;Qc616;:NbJ 0rtqOthoa 2 1200q' EO 327 IT PP87 LPO2 L2 P207 PP87 LP02 RR6 L2 P207 PP87 LPO2 L2 P207 PP87 LPO2 L2 P207 PP87 593 62 274 M}XJ MP9 MP9 MP9 MP9 MP9 RR6 LPO2 ffi 2 L2 P207 344 274 IF LPO2 RR6 1200q' 1200q, 0 EI 0 P203 EI P200 EO P200 EO P2m +2.1 1954 PP87 344 +8 2 w RR6 327 2.2 MP9 RR6 1200q' 327 MP9 RR6 62s +6 I +5 I +6 I l9s3 I) P207 u4 2l 5TFC I9s0 1950 LP02 344 +8 lgtioboeobo MP9 RR6 327 1950 MP9 RR6 I u4 1950 L2 MP9 TP5 MP9 (M) MP9 (M) MP9 (M) MP9 (M) MP9 (M) MP9 (M) MP9 (M) T50 62 23 274 P2m 1956 2 IA 22 ZWg P200 655 1957 2 1958 r,2_Qoje"oo_ r, I 2,IG6E;EJ;EG6; (dJ0%CbCq'o1060Rl14) 2 IF 62 2T 22 488 0 sz 0l) (10) RR6 LP02 344 1950 CbCbo 4.2l.2.7. RR6 62r 344 rg6mboqrgbo, I l 950 g LPO2 344 +8 1950 quto acqce RR6 344 1950 sco tiJS6 3' EO lq' 190 2 Coeoo RR6 327 +8 dt/+J 0C6'JJ{n ab) 344 r36oboqlbo,3o6obogq.- .ra|6d'mffib NCoqKdqo Acbrqnhoo d 22 Ar afrrclqo 0go6ordj od\)Cc 22 0!A$ft.{n 0fr$O6fobo Aqn cp06obCbo 1200q' EO P200 EI P200 MR BolrOO66J 8ld$orfuas uso'6Jd$ar6do 0fr$066d, 34bl$$0aqe (m.6sao al3qrrr 6On br8Jo{tbi a(l|J066 .'|J,nq., 4.3 utxtGq?tu Bcoor<.J6o@ J\)Soiqoj 9.1.1.2 (12) I 13.6 (8 6) 721 04) v14 I v14 7,33 85 tn (18) 3lt (le) (20) cv9 0) 1950 cvl2 cv9 I CV9 1950 cvl2 vt4 CV9 C'/12 I s2 cv9 (D) v14 I vl4 1950 cv9 r950 cvl2 cv9 (D) JC60toq'Cbo, Jo6 1950 S2 cvl2 3 (E) rgoob.q'g0o, Obgo[-- 1950 cvl2 (E) 2 lft a,Jd\J6 (E) (D) aot$bCq'CbCbo aD r$clq(r{\ror N b}{Dtos6r (16) 3 (E) 0)c6arJ dt lJve,Jqt tsolc@ uqffr oCEEsraCb A0bfq'CbCbo 4.35,6J 4 (,ffico oC'bq'JABdr Ja,qn) 1950 cvl2 "u, ^., ur{'Coo, OoJUoJU6o cv28 I vt4 (D) I (D) cvl2 I 950 @ 1950 r9Ooboq,gao, cv28 v14 cv9 cvl2 s2 I CV9 (D) I I vl4 1950 cvl2 TUI9 AT TA4 (c/E) AT v5 cv9 TU6 TA4 3 FL 1951 cvll cv9 G;N(M) TA4 TT9 r952 s2 st4 263 1953 ru6 s2 s20 23 954 I cv9 GBH(M) TA4 AT TA4 2 cvl0 s14 26 1955 20 1956 Oggaasq,o 23 957 eCo0C6oU0o, cv'35 I cv9 (c7D) cvl0 AT TT9 cxBN(M) c\86 cv9 (B/D) TA4 TT9 CV9 (E) FL TT9 cv10 c\86 cv9 2 (B/D) cv10 PxBN(lro TA4 TT9 .U6Q" cv36 (B/D) FL J6Ao6o, 6J6ogCb3q,n, 20 cvl0 CVIO cxBN(M) Jorimbogq,o l9s0 cv12 cv28 (c/E) GBH(M) )C6oboq,Cbo, OoCb JeAoqlJJq,C0Jeo, cv28 TA4 PXBN(T{) 1950 cv9 (D) PXBN 52 cv12 cv28 (D) 6o3tro3$il XQOoq'rJq'CbJKro cv28 AT (c/E) \,1/8 cv9 CVlO cv36 489 s2 s20 1958 rooojbl 60ff@Cq; 1z-po3q'oo- r, I Zt&O6Ds0;60;60 (oJ0o3CoCe,o Jo6ro R I l4) oecd Ad$vJq'cb eD r$Crto{il&> N aee 3(u|3 8cerys oJiofr$ d Jiqao ?6390 t rAoA6oCd NCooiqlclfo Abec(r3(m a5 ataaElo(frJBq$ o{r 6d6cbo &A$fro{n 0D6r ooqjo6fr8o qD ar&|c6o 0oo6odJ Jqn ocrcE!6c8o ocacos oa$ec dJ 3.t2 ,1 (1) 1959 l96l t962 r963 2.2 (3r) l, l-eotsOod)Cooq,96o lArgoggbgqn ioOn Rl132r) 2 3o16o, 5r6qgbgq,o, ob33rq.oo 2 gooq'g6o 2 5.22 (4) (s) 2F 33 316 (6) (h) 2.1 o65P3rrl o6';,ccqn ac8coaob fu.$ Ecu$,c$ ddshb 1,14 4.1,4 4tl0 4,25.2,7 4.25.3 c/d) (8) (9r) (|b) 00) (11) EO P2m MP9 (M) t0 P203 MP9 w5 I t2 s s.r. 0 ,J 3F 2 33q'og0o, 64ogbgq'o, obg3rqgo 2.1 t.3 2F 2.1 3A ltlCo6 q,Jdn ()6ltOFPJ jooCbo aceJe co$o 62 0 EO P200 MP9 (M) 593 1200q' E1 P203 MP9 n5 TP5 TP5 TP34 1964 6rb0ottr$9rq'btq.oob ror<rolr 6r6Cao, 2 0ggdB3q'o, N.O S 5 ;; IF 62 bibijootigJq'breob Jo6ob 61tr93o, 2 6robCaJeCbuq'o N O.S. 6oAo6oOJr A, AOl, ,lt02, A0, Al, Ab, 82, B J6 C 6r6Ca3bo 2F 274 0 EO 2AJ MP9 P200 MP9 583 (M) (M) T50 oJ2 @ t9(6 t7 1968 62 0giq'bieo, 0i3oJCbUqlo, obbCC6ogoqu6o roOo, 2l 2 6o3trop6-q W.O.S. 2 obbCCooooeg6o Jo6o, N O S 2T 2 22 0 EO 969 1970 I97l obobUOr60 2 0 EO P200 MP9 (M) 274 l20Aq, EI P200 MP9 (M) 0 EO P200 MP9 (M) T50 1200q' EI P203 MP9 T75 03o$o, 0ggddgq'o 16 bg69br6[oo6o, EO P200 MP9 (M) - 2 033ffi gq'o, 09ol6otr 0rqtq'o 090g6q,o0oo t972 MP9 | /t (M) T50 o)/ 2 593 1F 660 0 62 03o$o, 6rgo39bgqrn, b36Cb6o3o 1060, 0r6qgbgq'o, ob.64ro, -U6[IIE- 2 3F 2l 6@ EO 0gor6ob 0rqrq'o 0g0g39q'oboo 1973 3q'oO(,o96oOa3;r60b;GJ--Cq'o6,lC6OJgOo6Cor6oU 2 22 616Cao, n5 274 ffi 62 J6oJOo6o, AJoo3Cogq'o, oU6rqgo MP9 TP5 TP23 TP34 62 I P203 62 I200q' EI P200 MP9 62 I20Eq' EI P200 MP9 CAJC6rOC6oo, TP5 TP5 ggo609o16or6 s02) 1974 Cq'o6AogOo6b6oOa9orO" 1060 Rl28l) 1975 1argqgOgq,r- 2 24 Uoqgob eJ (,oJbooob 6v96o (rbogoU 9166oll qgr 2 oc 1976 lg[3o'60"Je'bco56o (a$',3cbcq'o rc,dn rt|cDo, AJoqCbCgo, ob6tpo 2.3 0 r982 J6sllJ6o OCo6rts0o60Cor6o (0r6o3gb9q,o,lo16o Ri{ P200 MP9 P2co MP9 +8 2 2A 22 62 I 200q' (M) T50 2 3A 22 345 1204q' 36 1978 EO +5 I o6JrOAob 616rno) t9n (M) T50 JbcrOoU Ji60oLJ EI P203 MP9 EO P200 MP9 T75 593 2 2 2l 22 490 oll oJ/ ffi 62 62 0 (M) T50 1200q, EI P200 MP9 (M) TP5 A-DR Od&66o vJ5Flr\)tlf*l OJo t\auJq$r 0rt\l0t fttu l* I l.ss,osl (12) (13) kBN(M) TA4 TT9 PTDN 9.1 1.2 1.13.6 (8.6) (14) (ls) FL blaal6(6o>3) 7.2,1 FL ll 7.33 V5 PrSN(M) PxBN FL PxBH(M) PXBN(M) kBN(lo PXBN TU19 crBN(M) 1963 s2 s20 23 1964 c!36 cv9 cvr0 s2 s20 23 l%5 CV9 s2 s17 223 19(6 sl4 26 1967 obbCC6o0o{9u6o roon, 6-3rro3gEca 20 1968 o6bgjgogoqrSrio ro6,0, N O^S. 23 1969 s20 22 t970 s2 s20 23 t971 s2 sl7 223 1972 20 1973 20 t974 CVIl I cv9 cvl0 cv36 3 cv9 cv10 c\,,36 2 cv9 (B/D) AT s2 CVIO c\86 cv9 3 (c/E) cvll s20 | c!86 | I TA4 FL TT9 ru18 2 (B/D) FL TA4 cv10 cv36 2 cv9 (B/D) cvll TT9 &BN(M) 22 cv9 2 FL TA4 s20 cvl0 (qE) TT9 1962 c\,'36 2 AT 'f A4 23 cv9 (c7D) TT9 l6fiffi[f,1ffi s2 s20 cvlt 2 (B/D) AT TA4 t-p-os6oosooq,3oo 1961 vf (B/D) TU6 TA4 TT9 I. Kl lJlJ) 223 cv9 (B/D) TA4 TT9 1959 cvl0 3 FL TUI8 0) 239 cv.t5 (c/E) FL r20l s2 s20 3,12 c\,86 AT TA4 TT9 (l9) s2 s17 cvll (B/D) TA4 5 32.3 c\,36 TT9 GBN(M) 8.5 cv10 2 TI9 TUI9 TA4 IF aD araJB:are, 7,5 (B/D) TA4 hBN qDoofr'or! 8a{6t(Qar 2 TA4 TT9 Q$tlbcqcCbo Ao rQ0$4j({F$o Is goJJom trr$)rio CB(xiodr 2 FL 0rt(,aft ob Ma"Jq)o (B,D) TUI8 hBN(M A$$00()lr'C&D A€erit ACtoeCABd da'{n) cdgoff | 'BJ}.!q-J6" rtu 3c4n {3 u\ltbJtrrJsllroo J\J0o.aftp (Sgo6rb8.' T/.4 AT c\86 cv9 3 (c/E) CVIO cv36 PxBN(lvf) TA4 AT TT9 3 cv9 (c/E) cvl0 cv:% I cv9 (D) PxBN(M PXBN PrBN(M) TA4 TUI9 TA4 AT AT cv9 cvl0 V5 CV9 TT9 cvll TA4 cv36 FL t975 C!v36 3 (c,'E) 3 (c7E) s14 cv10 2 CV9 (B/D) 20 1976 22 1977 rt'.6o, 6rg"33aggnpf,fiQl t978 J6nl16o 1982 OC06JtsOod)aCor6o (0rg"g6gq,6-565e p s20 s2 s20 cv10 c!36 PrBN(lrO TA4 TT9 AT (c/E) W8 cv9 cv10 c\,'36 491 20 t4) 0t5{x'1, Asbb0q'Cbl qD rq$06oqxlbs N 3qls aqD&€ acgJo,6 oJioff'|J dqAo l6uao ott NCootq'Jft, ACtu(cA'Cqn qD ob 6oa6Abo oi{ft araD0rfr?8qd 0rQtr'toeo od\)c66cao qa Uqn a,AEEa'6Cbo atrUitu 0oo6odt dcE.oorg drCtqc dl 3l: 22 22 33 1984 OFotsOo6ACoJbo (0r6q9bgqro ro6o R 23) I986 bJo6OCbo, Jegoq"JJq,COrAo, I986 bJoF)OCbo, r(Boq'rlq'Xbrqro, gojllo3g6o, bJo6ocbo, r(8oq'x,cbrpn, 2A 2 OoCt ;JU6o, bJo6OCbo, N O S (md)oCq'ott Fn I 5 (8) (%) (10) MP9 (M) T50 62 1204q' E1 P200 MP9 (M) MP7 T14 Pml MPIT MPI9 T1t MPI9 T7 EO lq' E2 5q' EI 3 274 06CEr 5OC 3 II FI IBCO3 )?! 3 3 u bJo6OCbo, N O S 3 lq, E2 P001 MPI9 g E2 Pml MPI9 3 601 IBCO2 640D Rm1 274 601 T7 | sq, P00l | IBCO3 n JqeSCJoeCbo, rego(t$q'XOrao, 1988 Oo3bom6,o, 3 3 itarlSnec0n, rgesc3oecbo,reooq'rle'coiqo--;CtnJ0;; 1988 3 274 0 EO FII P00t II FII ur 3 274 lq' E2 P00l 3 274 5q: EI MPI9 T4 1989 3 r. (oooJq"ou VbmJ 50C 3 OCAJJ6OU6JI'C ACOor I l0 3Jr-bg) 1989 FI 3 OCiilJ60U6rtC 16 JeCojOCbr I lO JJJ_b) FI I 3 274 0 II 3 274 g E3 E2 II 3 274 lo P00l Tll MPI9 n MP7 P00l MPIT MPI9 Tll EI T1 MPI9 T7 l9l 1992 9 Mll P00l MPI9 uvu,,q,rrq,ijoJK,o uoooc, T4 EI 0 EO Pmr FII 0 EO P001 rqr3oq'uq'3brpo boobg, t992 ;q6oq'uq'96sqn Uoobo, OoCUoJCF)o, N.O.S 6ojtro3grio, N.O.S. 3 JeBoq'JJgCbJeo boobg, NO S Fn 3 Je3oq,rrq'CbJeo UoobC, N.O.S. (errlotrq,otr S6cl31 5@C g90Jgf)6U6rbC reCtuO0br 110 b) 1993 T2 MP7 Tt4 lq' E2 16 I III 3 FI 3 3 C0Jr6OU6!tC 16 reCArOCbr lt0 5q> Pml P00l T14 274 0 lq' E3 E2 R00l P00l P001 MPI9 E MPT9 T7 3 274 601 trD 492 1qr E2 P001 IBCO2 R00l TP2 TP2 TPI TP28 MP7 MP17 Tll MPI9 T7 TPI TP27 TPI TP8 TP28 64K, u TP2 TP27 IBCO3 601 3 MP7 IBCO2 274 3 JJr_ oJ(ro boobC, N.O.S. (o6oCq,ob TPI TP6 MPIT Fn +6.1 r993 MPI5 MP17 +6 1 t992 r993 P001 R001 3 +5 3 TPI R001 II 3 ooduo336o, N o,s TPI TP29 tBc03 LPOl jq'odnlt6g6o, lr6rboq,obgbgg- TPI TP8 TP28 LPOI b96brq'q.o33oqn TPI TP8 TP28 IBCO3 1990 TPI TP27 IBCO2 3 TP2 TP27 TP28 R001 III TP2 TP27 MP19 P00l E2 1989 FI T14 R001 640D 3 MP7 IBCO3 540C "\ \uv,,\vuvt/, rr.v.r. u,nro)Jq)oo DocSJ ) TPI TP29 IBCO2 +6.1 1989 | rq'eg3oe3bo,NO^S' TPI TP8 MPIT +6.1 3 TP28 R001 Frl +o- I r*nq,Dq'9brqro, 6o3bo3soo, TPI TP28 LPOl 1988 TP1 TP8 3 III F1 TP2 TP27 TP28 640C 690Jr6g36rb9 r TP2 R001 601 bJo6OCbo, N.O.S. 1987 P001 ( 11) TP27 IBCO2 FI] 3 4.25.3 32 P200 +6. l oodbn3ud,.,, 4.25.2.7. EI 3 q,Jdn cb$o 4,1.4 (9r) IJJCON qcbcg (%) +6.1 OC0Jr6OU6rbC ACOor ll0 3Jr_tg) 1987 dCl$hb 1200q' +5 1 t7 d0.D 4 t.4 COoCAo 62 22 2A 3 N.O.S. 1985 (6) 2 l"r#?1;r;3;ro..-oo6coJ6o(oroqcbce,; 351 0CASoBdJ 7 (3r) 1983 345 oa\lr6c MP19 T7 TP1 TP8 TP28 sR cd\J065r {ddt$({fJ&! L$atuAJJa"6Oo 0.r{d5&n UArt$b.{$a (03o6rbao 600 U.ACb('cL) 0di00f,6 .t .ynq" aCb"<'c}Jbo 4.3 4 3.5,5J.4 (12) (13) PrBN(lO 91.12 1.1.3.6 (&6) (14) (15) AT LlOCH It BrqDtoABr 7 2,1 AT TUl4 TUI5 (18) FL FL 2 (D,/E} L4BH TUI5 FL 3 (dr0o3CbCq'o Jo6o R l33J) 20 t%4 cvl3 s2s22 336 1986 s2 s22 336 1986 s2 JO 1985 cv28 cvl3 cv28 vt2 cvl3 cv28 FL LIOCH ru14 TUl5 L4BH TUI5 s2 s20 3 FL vt2 S2 I cvl3 (C/E) FI 3 cvl3 FL cvl3 FL TUI4 TUI5 3 (E) FL I (c,€) FL I TE2I TE2I s2 36 1988 s2 s20 33 1989 s2 s20 33 1989 s2 s20 33 s2 30 JJJ-U) ru15 FL s2 s22 336 l99l 52 S22 336 1992 cv13 cv28 s2 s22 336 t9f2 rp3oq'sq'3brqn b"-bg, 6o3[fr?,n, CVI3 s2 36 t992 rq6oq'sq'gbrqro boobC, OmCUoJC6o, cvl3 cvl3 (D/E) (D/E) FL v12 cv28 I (D,€) LI5BN FL LGBF FL s2 s20 33 1993 s2 s20 33 1993 s2 s20 33 1943 2 (D/Et 2 (D/E) 493 I r990 CV28 2 reacaoa3oo, N.o s 'yE, 90 CV28 FL S6Ca; JJJ_tC) rq'qp3oqrgbo,N.o.s.1oao3q-.ugo-llj" )wu OCitJ60U6rtC J6) JqCOJOC0J I l0 1989 vl2 (c/E) TUI5 I rq'qg3oq.ogbo, N.O.S. (,r,r,.Cq,I[ 3 (D/E) TUI4 TUI5 1988 rq'p33oqXao,rp3q9nqil[ftf, 2 (D/E) AT 335 )uL OCdJr6OU6JbC ACOoJ I tO FL LGBV s2 s22 bJo6OCbo, N,O S 2 (D/E) LGBF 336 j I FI- LCBF s2 s22 cv28 (D/E) LI5BN bJod)O0bo, N.O.S. t%j7 cv28 v12 (D/E) L4BN t987 CV28 2 ru15 33 OCAJJ6OU6JIC (D/E) L4BN bJo6OCbo, N.O.S. ( 2 (D/E) L4BH uvu\/{Drq,Uor(,o, OoduoJJF,o, ocdJJ6ou6J$c ac FL L4BH -vi.,vuq. l7 s2 s20 (D/E) LIOCH (2\ t--3q'oo-r,Z,Z-6;og6;ea;;; FL LGBf LIOCH 1983 cvt0 (D/E) L4BH (1) 20 312 c\,'36 (D/E) LI 5BN (20) cv9 I TUI5 (le) cv9 (c,4) L4BH 5 32.3 cv10 cv35 3 (c7E) TE21 85 -116) 3 TT9 a$t$kgC6o Ar Jq$C6({nbr N tso&om b)3$n (c,c) TA4 DC6cf, lvpC60o ECsgoBCbo TA4 biarrod' {b oroqrf' ACktqB.ft JcrAn) TT9 PxBN(M) tJCC""q'aJ6.@ J\)SFfrJ b96'brq'qpg3oqro u\ - i v, /dv,. ueout,q{,xijouqro 0rctuJ F qd$bCeIbo as !e0t6({\*j JQDIh Jgdb acauo8 d, $r3ioo uJcaoig?tu ob boa6cbo ?ia3ao AJte?qroqb qD &aEnAdo€q|cb 0D6! 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0r&ErSdCEqS tutxto6o OodtConl, ac8uo,3 ob *t6 q&Jq,CACBo dC8goBolt ECI$hb 4.t.4 4.1 ,l onr}tJ (1) 2327 3.12 22 2.2 2.1.t.3 (2) (3r) (3b) (4) (s) 8 c7 III 3 66o09ooq'39jbr09ooq'g6qnr0o69bo Delatboqn 0.rrb6fu6o AD Uqn a{'C6ohbo 3 4.6 |t23.5.1. a,$.JeChbo AStJCqn odrortC bJCO6 ioocbo q?(ftt 4.25-L7. {.25.3 6gg6p3otr od$hb 4.1.t0 coso 3.2 (7b) (8) EI P00l (9J) (%) (10) (11) MP19 T4 TPI MPI9 T4 TP3 MP19 T2 TP33 MPI9 T2 TP2 MPIO TI TP2 MPI9 T4 TP2 MPI9 n TPl MP8 T20 TPI MPI9 T7 TPl MP7 Tl4 TP3 T20 TPI MP19 T4 TPI MP19 T4 TP33 MP9 T4 TP2 MPI9 T2 TP33 MP19 T4 IBCO3 LPOI 232A OooirCooq'3CCUJoCooq'C6olt eootoOoJ6JOo TI Rm1 III E1 P00l IBCO3 LPOI 2329 O6oACooq'EoUtsoOo 3 FI R001 IU 3 IBCO3 LPOI 2330 UbeAlr60 3 R00l FI 3 EI Pm1 IBCO3 LPOI 2331 ouooob Cqod)oeo, C09q'o 8 R00l c2 E1 P002 B3 IBCO8 LPOl 2332 J0Corq'eC3o(,olr oCbooo FI 3 R001 III 3 IBCO3 LPOl 2333 rq'oq,ou rocoioo rq'oq'$o6o 3 tll 6l FI II R00l PWI 3 +5 I o-l rBc02 354 0 EO +3 rgoqrgooq'ob gogrtro 23 2337 TI 3 rq'oq'ob 9o60o16o I1 MPIT 3 le 3 0 EO 0 EO IBCO2 J +6 I BC6oq'ob AJ6J$Or60 P&2 ol 6.1 354 P001 MPIT P@2 +3 2338 bC6brg6otsOod)oeo 2339 -b60aqcor6o .-------_----t-5 MP8 MPIT 3 E2 Pml IBCO2 tt II lq' R00l E2 P00l IBCO2 23& 2-bttro09ooq'9ooq'ob gqOo 3 R00l n 3 lq' E2 P00l IBCO2 234r I -b60A-3-ACooq,bUOr60 3 FI R001 III LI P00l IBCO3 LPOI 2342 b6o009ooq'36oJ1696o 3 tl Rml II lq, E2 P00l IBCO2 2343 2-brim0Jg6g16o 3 II 3 E2 P00l MP19 T4 TPI MPI9 T4 TPI MPI9 'r2 TP2 MPI9 T4 TPI MPI9 T4 TPI MP19 T4 TP] IBCO2 2344 6t9o0J6cr3169bo 3 II R00l 3 rq, E2 Pml IBCO2 2344 bt6oOJ16eS169bo 3 III TPI TP29 Rm1 Rm1 3 5q' trt P00l IBCO3 LPOI 234s 3-b6oAJ6clJo60 3 F1 II 3 lq' R00l E2 P00l IBCO2 234f oUoJbeoobo 3 FI R001 II Iq, E2 P00l IBCO2 2347 0UOoq,oU AC6J$OD6o 3 FI II lq, R001 E2 P001 IBCO2 Rml s16 mR oou566r €ofrbortua\h fuo t\fUiqnbr ulotrr8sdljo Odgd66ob Ar8q{fi BCbe"qBdJ Ja'(n) Axertbt.{'ia a.&J0r66 uhco{PJf,o {3 { 3.5,6 8 4 02) (13) d Ja{n bJoooie|Jlft, A'c6f|q'gCbo blA$boABJb$ ADJ€&)d,C&D J$CAa'ii$ r.r3.6 (&6) 721 (14) (15) (16) 3 vl2 TU15 TEI9 AT 2 7,5.11 (rn (18) 5.32 3 09) vl2 (20) (r) 80 2327 QFro0gooq,3gjUi09.oq'C6A6An6C6" 60 2328 06oACooq,SCCbrACooq'g6olr s9 (E) FL 3 cv28 eoobo0oJbJOo v12 S2 30 2329 O6oACooq'BoUtsoOo s2 30 2330 U6('ClJ6o 80 2331 ogooolr jq,ottroqpo. g$gq,o JO 2332 roCOrq'qo03o(,ob oCboAo s2 s19 336 2333 rq'oq'ob J0COJOo s2 s9 sl4 663 s2 sl9 336 2335 rq)oq)Cooq'ob CoCft) 336 2336 Jq)oq,ob goffioJOo s2 s9 sl4 663 z1J / 93boq'oU 0963rJ6r6o s2 s20 33 2338 bCbbo66oBOo60('0 s2 s20 33 2339 2-b6oObUoj6o s2 s20 33 2340 2-b6oACooq'Cooq,o! 3og6o (D/E) LGBF FL 3 vt2 (D/E) SGAV 3 (E) LGBF FL 3 AP7 v12 (D/E) LlOCH TUI5 LIOCH TUl4 TUI5 FL 2 cvl3 (D,T) FL TE19 TE2I L4BH TUI5 LIOCH TUI4 TUI5 LIOCH TUI4 TUI5 TEI9 TE2I CV28 I CVI (c/D) FL TE2I 2 cvl3 LGBF cv28 I cvl3 (cvE) FL cv28 I cvl (c,D) cvl3 CV28 FL 2 (D/E) LGBF FL 2 (D/E) LCBF FL 2 (D/E) LGBF FL 3 vt2 (D/E) LGBF FL 2 (D/E) LGBF FL 2 (D,€) LGBF FL 2 (D/E) FL LGBF FL 3 (D/E) v12 2 (D/E) LGBF FL 2 (D/E) FL rq,oq'JA06o cv13 cv28 (D/E) FL As r{ggdx,qnAr SrAAqbofEUr atr asqJE{Jbr (E) L4BH a6l$b0q'cbCbo lf goJ\]m N Lr$fn 0oo6oxfi 9 1.1.2 AT 8r$rxrb k{Efuo 0J8fsta0b L4BN USoAtrxaC bolt Ogrmrab.r 2 (D/E) 517 2341 I -0604-3-ACooq'0UdJ6o s2 s20 33 2342 b6o069ooqrJ6crJrfubo s2 s20 33 2343 2-b6mOJX6616o s2 s20 33 2344 b6oOJ6er3$3bo s2 30 2344 b6oAJ6adJbC0o s2 s20 33 2345 3-btim0Jr6mJo6o 52 S2O 33 2345 bgo,:6qnobo s2 s20 33 2347 bg@oq'oL AC6J$O16o qN$bcq|cb0 A$ lq$C.tr{nLt bJcrtul, N Jqe oajJoB tt$a6rr0b oJrOffiJ dJ rn 6cresbo .loao MOtp JeDlxA tsooo.q?lto ${sA'bo{n 0D.6s Odid06fobo qs aslfrJ6o Oooi6oxrr -a6Am6.tFn8o 312 (l) 2348 22 2.2 2.1.1.3 5.22 33 (3r) (36) (4) (t (6) 3 FI III 3 bpooq'ob JJ60qlr6gbo, U6lboq'cfbCbgq,- (7J) acaJoo l$flJorq?6o di oa\lec bCSUcB.fi dffiUo€d, dG6 ECbbCb &J$bCb 1,t.4 { 1.4 {.1.10 4.25L7. 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Tll 'tP2 E2 P00l MP19 T4 TPI MPI9 T4 TPI MPI9 T4 TPI MPI9 w TPI IBCO2 2373 eoCOoCUoACor60 3 R00l FI 1q' E2 P00l IBCO2 2374 3,3-eoCOoCboJ6c\JCEn 3 FI II R00l 3 IBCOz zJ/) (ncooqtucq,So(ro 3 R00l FI lq' E2 P00l IBCO2 R00l 518 ADR 0rt$066) Aorrr$AfjJo qjn uforq'c0r bqJr1frJor6oo Od{)gr66otr (ogdtiboo Sioq(fu dC$qCABdi Ja,{n) D4Sf$t({trA GdrS066 uJC,Jo{lJtu d Joqn a$"Je$cbo 4.3 435.531 02) u{Oorqt3m A'CoC('coCbo 0r(trt {RJEN6 qDJ€A.,6C&D J\l@otu aoeEs€Jbo bCn6., dgffErft 9,1r.2 r.r3.6 (&6) 7.2.4 04) (1s) (16) 3 vt2 03) LGBF FL A$OOo6o8J, FL (r7) (18) 2 (D/E) LGBF FL 3 vl2 (D/E) LGBF FL 2 (D/E) s 32.3 FL 2 (D/E) TU15 FL 2 cvl3 (D/E\ L4BN FL L4BN FL 09) (20) (l s2 39 2348 bCooq'otJ JJ6oq'JOCoo, UOrboq'obCbUq'o s2 s20 33 2350 bgooq'ogooq'olr gogrlo s2 s20 33 2351 o0ooq)ob 6oO6oOCbo s2 30 2351 bgooq'ob 6006oOCbo s2 s20 339 2352 bSooqjo6oq'ob gogrtro, s2 s20 338 IJ>J bSo06oq'Cq'od)oeo s2 sl9 336 2354 jq'o603ooq'gooq,ob go96o s2 s20 33 2356 2-Cq'o6J6oJ16o LGBF FI s2 83 2357 6o3q'oJgjboq's0o6o 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T4 TPI MPI9 T4 TPl MP19 T7 TPI MP19 T4 TPI II q 3 MPI9 T4 TPl R00l 2389 93616o 2390 2-ooerbUOJ60 3 FI 3 FI 0 II 3 II 3 E3 Pml lBc02 ooCQACooq,J6oJJ6Cbo 3 ooeS6c\]J6Cbo 3 FI MP7 T12 TP2 MPIT MPI9 T4 IPI MPI9 T4 TPI MPI9 T2 TPl MPI9 T4 TPl MPI9 T2 TPI MP19 n TP2 MP19 n ttl MPI9 T4 TPI MPI9 ^r7 TPI MPI9 E MP19 T4 TPI MP8 MP17 T1o TN R00r lq) E2 P00l IBCO2 2392 MP19 Rmt tDc02 2391 TP2 TP37 R001 IBCO2 2388 quco aca"(" 4.25.27. 2 (6) bJCO6 R00l 1,1-eoaCOoCboCor6o 2378 2380 N0corqlc6o q,CaoqThoo Co.D IBCO2 2377 ti{etrtxxAo 0rt\J06qbo SD tulkry6o oord,odt Uqn e{0ereCoo Rml IN 3 rBc03 LPOI 2393 obobgooq'ob go60or6o 3 F1 tq' Rmt E2 P0l IBCO2 2394 oboOgooq'olrJrict-o6i6o- 3 F1 5q' trt Pml IDCO3 LPOI zJ>) 2395 obobgoo6oq'jq'or6opo oCOJJooq,Jq'eCJoeo, bOrboq'obCbUq"o 3 FC Io R001 E2 +8 3 FTI E2 +6 I 2397 3 F1 I] P00l IBCO2 P00r IBCO2 3 E2 P00l IBCO2 2398 oCooqtou dClr)dCuq'o ouooq,ob CoC6o 2399 -0Cooq'Jo3C60eo5o 24co 2401 uuJrq,urroo Rml 3 lq> E2 P001 IBCOz 5 FC 3 FI II 3 E2 Rmr P00l +8 II Iq, IBCO2 J.rlC6oCQo60 6 R00l 3 0 +8 520 EO P00l MR OdrJO66r J3ofr\J|M t\otcsaiJdrtuo 600 l$oDqrD0$ tfartbtoQ'iA 0oli5@6 dt Jarqn l}J00orq?a6o Aftq'cb$o arA"\ra3rl"r.b a$oofr AC$ACABdr t JmoJq?6o omUpSCbo 9.r.1.2 1.1.3.6 (8.6) 7.2.1 (12) 03) (14) (15) (15) FL ItC,.Sn 8{$$(pBt { 3.5,6.8.4 (r7) (18) 2 2 FL CV l3 3 FL 2 (D/E) I48H I Ut) FL 2 cvl3 (D/E) LIOCH TUI4 TU15 FL cvl (D/E) FL cvl3 I FL 2 (D/E) LGBF FL 2 L4BH FL (l) s2 s20 33 2376 2,3-po3opr6crJot6r6o s2 s20 33 2377 I,l-eodCOoCltoCoJ60 s2 sl9 336 237a 2-qnagooqrraobolr JoCO06oO6,0qn s2 s20 338 2379 t,3-q.oo69ooq'bgooq,Mo6- s2 s20 33 2380 eoACooq'eoCOoC s2 s22 336 238r eoa0ooq'otJ buq)8oeo s2 s9 sl9 663 2382 qnagooq'3op6s$o s2 s20 338 2383 ('oJ6c|Joe'J006o s2 s20 JJ 2384 qn-6-Jttrrr3oq'ob 3og{tro s2 s20 a? 2385 C@oq'ob obobUOo6JOo 338 2386 l-9ooq'JoJg6oqn6o 33 2387 ts0o6bc6toq'o s2 s20 33 2388 g0060oq"Ooq,Cbo s2 s20 33 2389 996$o cv28 {D/El LGBF (20) cv28 2 TEI9 TE2I 3.12 (le) cv28 (D/E) LGBF llo 7 5.11 (D/E) L4BH (D,C) 2 (D/E) FL 2 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(9r) (%) MPI5 (10) 3&2 ouJq,.&oo, ouwo w2 OCOC-doflr q,ooo6ob r0tq,6r0o, 0916o 43 I 43 w2 r82 0 183 0 EO P{03 0 EO P403 506 3rq'ogdoU q'ooo6ob 096r 3404 3405 43 Jrq'opA-6JO6ogAob OgOipOooldiJg16; 0rr6ns0.b jq'o6s6o5 b[616- 5l 5l br6og0obJ9r6 jq'or6 j6;bbb6 jirn- w2 0 EO TP.{ I MPI4 IJ TP33 TP36 MP14 T1 TP33 TP36 MP2 T9 TP7 TP33 MP2 T9 TP7 TP33 MP2 T9 6r6rr3aou .19193q66DO;GG;; 3447 Cq,o6)Ootir eJ AJ6bog0ob jq,mrloqotr 6rt6CaoU bb6r6o 3&7 oTl lq' 5.1 sl oTl +6 I - 5l lq' II oTl 3408 3408 E2 3410 ;r;i:;'-''-orNt]()Qooou ro('ooJeo6oQob P504 )q) IBCO2 E2 P504 IBCO2 5l PWI +6 I IBCO2 5.1 E2 lo Ps04 IBCO2 III 5l oTl II ).1 5l oTl III 61 TI II ot 6.1 TI III 6l EI +ol o_l 6l JwouJWq,Ju qJrgJ, JoJbJJq,Cb lWo, AJ06Ja r6iU0C0CU 85% albgoo goqroo 8 II TI c3 for3rb 5l E2 P50{ IBCO2 5q' IBCO2 1000q, E4 P001 IBCO2 E1 P00l 6l $olb]3Xqrrb 6grgs, .16 J6JU0COCb 10yo furgr 8 P00l IBCO2 III II E4 EI P00l I8C02 8 E2 P001 III 8 5q' E1 P00l IBCO3 6t MP2 TP1 MP2 T4 MP2 MP2 MP2 TPI TPI TPI T4 T4 TPI T4 TPI MP2 TPI MPI5 T7 TP2 MPI9 T4 TPI MPI5 n TP2 MPI9 T7 TP2 MPI5 T7 TP2 MPI9 T4 TPI MP8 T14 TP2 Rmr T4 0 MPIT 3iq'og0oU 6or6oglolr bU6r6o 3413 6l T4 6l T4 1006q' III 6t E4 P00l r8c02 MPI5 Tll MPI9 T7 TP27 5q' IBCO3 3414 T4 LPOl 3413 3413 TP7 R00l l00dq' IBC02 34t2 T9 MP2 P50{ IBCO3 341 MP2 IBCO2 1o +6 I 3409 3412 II 5l 5l i Osoonb.rxqq;60"b blr6G; III ol jq'o6JoobJ eJ AJA6og0ob jq,nrrroqnb P403 IDCO2 5l III 5t bJFJ3ob bbbJ6o TP7 TP33 +6.1 3406 w7 T?33 T?36 IP33 43 3405 3406 w2 (1 1) T7 TDCOS 3401 1.25 3 2 6r6rtrnganb 6n-6nq,;GG;; ol TP2 TP28 LPOI R001 T4 0 E5 P001 MP8 Tl4 TP2 MPIT 34t4 6r66og0ob 6or6oqrolr bbEuno 6l 3414 6166o90olr gorbopob bGGi 6l II T4 u 6l 6l 1000q E4 P00l IBCO2 E1 Pml IBCO3 LPOI R00l 626 MP15 Tll MPI9 T7 TP27 TP2 TP28 627 628 ADR od\b666 €0rt'\J6od, trrdtuArJa|lqoo |l5a$q$o (83dqib0o A8C{f, &'qto orr{d66olt SDAobtoA$ odrd065ob J(!ao 43 { 3.5.6.8 4 9.1.1 2 (13) (14) L4BH TU15 TEI9 AT ru15 TEt9 SCAH L4BH L4BH l,lAd6sC bob aCbqUABob Jc,qn) Ur0r6o 1.r3.6 (8.6) AT 2 AT 7.33 vt2 L/4DH L4DH TUI4 TE2I TUI4 TE2I L4BH I rursrzu L4BH vll vu 2 (E) vll AT 2 (E) L4BH AT 3 (E) AT 2 (E) vlr 2 vl2 L4BH TUI5 TE19 L4BH 2 (D/E) ru15 TE19 AT AT TUI5 TE19 AT SGAII L4BH TUI5 AT L4BH rur5 TE19 SGAH CVI3 vcl vc2 cvl3 AP7 cv28 vll cv13 cv28 cv13 cv28 2 (E) 2 cvl3 AT L4BH TU15 TEI9 sGAt{ TUI5 TE19 L4BH 2 AT 2 CVI3 AP9 3421 86 342r 60 3422 80 3423 s9 sl9 50 3424 Ss 60 3424 80 3425 bb6rrio 3rqogOoU ggo6oqntr iA.Ongaob q.onbn66**J6rC$.eDdolj s9 a s9 60 3427 s9 s19 60 3428 s9 60 3429 s9 s19 60 3430 jUoq'66oqXbo, oe3rpo s9 sl9 60 3431 ,..v. ^ ,vuv v, ,u, sl9 90 3432 s9 60 3434 @ s9 s19 60 3436 ls3u"s6.o.66.."r,1if oif, f,ll$fr- 60 3437 60 3438 cvr3 ^,u()ta(r,logoo, otJoo cv28 cvr3 cv28 vll cvl3 cv28 vl1 CV13 cv28 2 (E) cvl VCl VC2 (D/E) AT 86 cv28 2 (E) (D/E) SGAH L4BH 3420 cv28 2 (D/E) TUI5 TEI9 80 cv28 vll wJrrqJJ3Ju | (D/E) AT 3419 CV13 I cv28 (D/E) SGAH L4BH 80 cv28 2 AT l,t-6"q,snq'sop-GnEif, IGGI CVI3 (E) ru15 TE19 3418 vlt 2 (E) SGAX L4BH 60 cvt3 2 AT jboq'oq,b6mloqn, dgffi cv28 AT TUI5 TEI9 34r7 cv28 TUI5 TE19 L4BH 60 cv28 (E) SGAH l6 to&loo.llr^ v12 AT 60 S9 vt2 Ar TUI5 TEI9 s9 s19 cvl3 TUI5TEI9 I SGAN L4BN 3415 cv28 (D/E) L4BH r) 60 CV28 2 (E) 2 (E) (20) s9 v12 AT AT (19) cv28 (E) SGAN L4BN (18) CVI3 cvl3 2 AT 53.23 M CV28 AT IIBN 85 7.5 (E) SGAN L4BN ll qD qtraf8r8Cbs (D/E) ru15 TEl9 tsoaiom oD€,cooodsar DqD$oqBr (16) 2 (D/E) q"lbuN'CbCoo qD re0C6.{r,6s dCtqJo6 Ar0go6a'3D, CBdorlt 721 2 (E) AT &,Cturr tft lv,q'Jfuo a 02) L4BH urco""qd"@ CVI3 tJ7 cv28 629 S9 Jq,gr-oCooq'bC6,boq'ob l$o66o, 0grrlo - 630 631 0{t dr ADIlbc($r N lq$Cifqhbr aqou | ,rcuxeoo Effic o€d, ?69 loru3er{n ttrar$6a{D t JCooq?& acku{uqnqD dr 6oAhbo 0s6r a)6,b€rt,3Sq'c0 ArasAt({eo Uqn o(6eebCbo go odgC66cbo Ab afrru6o O0.r6ootj ECAU dT lrlc0oi<? oe\J od\)CcCo CJCo oCoo qJoaq'lth bo 22 3462 3462 2.1.1. 1* 61 n66r6ot09boqr$, 0g 5.22 (4) I T2 d06r 33 {.1 I"u o60r6obACboeJ6, (6) 6l (7r) (76) (8) 210 0 E5 P002 3& ouJ3JU iJJtJU6o 210 6l T2 d;i;:l r;";t"*o 8 orcooo' o0cborc6o' Ltt 2 l0 5Jo EI II 8 ;;"#, ;;;""*"' 34r.s uouc)oo' ooduorsoo' (oJ6o0bJ606br6C 6l T2 61 T2 II 6.1 ogJoo, N O S TP33 B4 MPIO IJ TP33 B3 MPIO T1 TP33 MPI5 n TP2 MPI8 T6 IP33 B4 MPIO 13 TP33 B3 l0 TI TP33 MPI8 T6 TP33 P002 E2 P00l 0 E5 P002 IJ 51 IJ 43 500 0 E4 P002 IBCO8 43 274 I] 6l 274 III 6l ; E5 0 500 a l, PW2 B4 MPIO B3 MPIO T1 TP33 36 MPI8 lo TP33 TP33 IBCO8 TI P002 IBCO8 36 (lr) IBCOT 274 6l III o-l 6l 3465 T6 IBCO2 43 6l 3465 (%) MPIS R001 lq' T2 4 75.3 2 IBCOS 274 346,4 (9r) 5@a +3 6t 3454 4.2,5. IBCOT 274 3463 41.4 IBCO8 6l A9116o, N.O-S. { 2 (s) 6l II of,6J6obaCbo(,J6, 6o3bo0^goo,5goaoo9ry[pl*6r*_- bo AdlbCb 274 OoCtrobobo, acoeqllo EmflsAd, (30) OoCbobCoo, dO6J6o l$mNqiJ LPO2 6t R00l 6l IJ P002 562 q'ooo6ob 3r6bo6oq$n,4gr6,., 34{6 Nb_S. II 6l dUJ6o, N O S 61 274 6I 274 562 13 IBCOT s00 a P002 B4 MPIO DI l0 II TP33 MPI8 T6 TP33 TP33 IBCO8 EI 562 P002 IBCOS LPO2 3457 o]ro", N.oi.-"'" 3467 il:ff lis:r:t'"' 3457 oJron, N.oi. "' wur /v'tl' o'cu()Jzoo' orso''1 o'cGrc6 "" ""u' 'v^1 o'( {o()r3('o' 6l 6l IJ 6l 6l R00l 274 562 0 274 500 a E5 IBCOT E4 562 6l III 6t 274 P002 B4 TP33 IBCOS 3A EI s62 P002 B3 MPIO IBCO8 TI IP33 Tll TP2 TP27 LP02 3468 2 IF 2l R00l 321 0 EO 0 EO J)O MP9 3469 3 FC I 3 +8 632 163 367 MP7 MPIT DR c.trC06EJ taco""q'u,q"@ ffiC brCodr &,b M lviaoqJo 0d{)065clJ ,toao acars,3coo Acbcq{hao ao3{J@ Uqly9o 00o6orcfi IrqstoqB) {.3 13 5,63.1 (12) (13) SIOAH LIOCH ,.r.r., ru15 TE19 r.rr.6 (8.6) j 721 I SGAH L48H ru15 TEl9 SGAIJ TU15 TEIg L4BH 5323 (18) (le) cv1 (20) s9 s14 6 (17) cvl3 11) 3462 cvl3 cv28 2 (E) vcl vc2 CVl3 cv28 AP7 L4BN s9 s19 60 34f.2 rc -- 60 34f.2 s2 83 3463 s9 S14 6 3464 | | ;.i'o"ilcol',q',6,"a;#; :i 3:r*-*" 2 (DiE) SIOAH LIOCH ru14 TUl5 SGAX L4BH ru15 TE19 AT SGAH | ruls TEl9 AT L4BH SIOAH LlOCH AT CV1 (c,€) cvl3 cvl3 I (E) s9 s19 60 3464 s9 60 3464 s9 sl4 6 JS) s9s19 60 3465 s9 60 3465 59SI4 6 3466 60 36 60 3466 cv28 vcl VC2 cvl3 AP7 cv28 SGAH L4BH cvl (c/E) TUI5 TEIg 2 vl1 AT SGAH cvl3 CV28 2 cvl3 TUI4 TUI5 AT TEI9 TE21 AT TUI5 TE19 AT L48H I cvl 2 TUI4 TUI5 LIOCH TE19 TE2I SGAH L4BH ruts TEl9 SGAH L4BH TUI5 TEI9 AT CVI3 2 (D/E) 2 (E) s9 s19 cv28 vcl vc2 LvlJ | cv28 | AP7 I (c/E) AT AT cv13 cv28 vll (E) S1OAH CV28 (c./E) TUI5 TEI9 L4BH AP7 cvl cvl3 (q -' )y 5r4 | 66 | 3467 CV28 vll cvl3 s9 sl9 60 3467 s9 60 3467 cv28 vcl vc2 cvl3 AP7 cv28 2 cv9 (D) s2 s20 3468 cv10 c\86 LIrcH TUI4 TE2I FL I 52 S2O (c/E) 633 o0bt6o66s6g s. cv28 (D/E) (E) SIOAH LIOCH gotrgo6o6616gq, AT TE19 TE2I TUI5 TE19 gobg06m6Ar6Uq,o 6rC dgJ6o, N.O.S. cv28 cv13 SGAH L48H oocbo6cbo, cco6JAo m66t6ob03boqr6, 0g I TE19 TE2I TUI4 TUI5 bobCbo, CCO6JAo6,CbU JbobOCboeJ6, Agy<)o, cv28 2 (D/E) AT 85 7.5,1I vr0 (c,€) N qs Sr)aUnca0br 7.33 (16) AT dCt6!O6 Al@rJgarsAr 338 3469 Yw,wauaTdNUq,o bJcooo, dgJ6o, Jroooooq,Cbo, AgJ6)o, N O.S JJo6oboq,C6o, AUJ6o, N O S Dcrlxqlt c"tlbcqS" a"49xl@- lft Jqdb acgJ W)dit lob oad Odr Jo{n d 6oilCbo bIJOG<FJfo qaaoq'cbcoo a3tuq,Je6rqb qb 06 brarb€rillJ8qtb ?6J Aras6$.{n OdJOJdqbo q) Uqb atE'Ce'aCbo go atrlJ6o O6r'6odr a36aa4ob od$qcco BCOo$q? a0ooq€bb qlcbq$c EcEJpadt .ai5 dcfu0qb tBCOoiqlJ ecio oCSo 0d$h0 q'cacqrbC 60 ACBUsgolt 22 0 3469 2.1.1. (3r) brenbmo, I a.s.r 411 l2 (3b) (4) PC II 3 3.4 6 6ctbh0 (s) (6) (7r) 3 163 +8 s/ lq' (7b) 4.1.{ (9i) {.1.10 4.25. 4 2s.3 2 (%) MPI9 (10) (1 w 'tP2 IBCO2 l) TP8 TP28 3469 3 FC 3 163 +8 s/ tl P001 't4 MPI9 IBCO3 TPI TP29 R00l 3470 8 cFl II 163 +3 le E2 P001 MPI5 IBCO2 T1 TP2 TP8 TP28 3471 3471 $grc"btooor,l-d';;;i 8 cTl II 8 cTl III 8 +6 I lq' E2 8 E1 +6.1 3472 U'UUUJQO 8 c3 III P00l MP15 IBCO2 P00l MPI9 R00l s EI P00l MPI9 3474 srqtou 4l D 3 FI 3 g 4t EO 0 q 3 P406 E2 363 43 w3 43 328 334 Pml tBc02 &4 3476 5000q, EO P004 EO PW4 J6 50OA 3477 8 cll 8 lq' Jb 334 634 TPI T4 TPI P004 3475 II T4 LPOl R00l 3473 FI TP2 TPI IBCO3 IBCO3 3 n lJa PP48 MP2 MPI9 sR OdrJdr6s r6ort\grri6l, &600 t$A!Jq$r 0d\J066d, 0d$C6r6d, trlCcoiq?6o DQ\fst(eD Joao A0eJe'CbCoo e u{N$d'6oo urca.Dq.Jtr"@ &ceaftD t riidf,aD (b3d6$4.' oraqrn oC'b€ABdJ aarqn) lrqfroo q\loofEnD, OOodDd, SrAda\boir,%) AtAJto{Bt 4.3 (12) 4.35,6.8 { 9 Ll.2 blC6ei, lft AoU tvpC60n go3\Jm }F qb q!&A{Cbr I ll36(8.5) (13) 7.2.4 (r5) L4BH 733 7.5.t7 (r7) 5 3.23 (le) (20) s2 s20 338 (18) 2 (D/E) I 85 3469 QJJJSSo6CbCq,o OJbJq,r, L4BN FL vt2 3 (D/E) s2 38 3469 QJ3J30o6CbUq'o ArbJq,J, L4BN FL X93oq' CAJeo,Jo6otro0q,o (breCbJ AJAJoboC6Cbe,ob16 2 S2 (D/E) L4DH L4DH ru14 TE2l ru14 TE2t AT 2 (E) AT cvl3 cv28 3 cv l3 cv28 (E) L4BN AT 3 83 3470 86 3471 86 3471 Sgtebromoo,r-r^-^rlil 80 3472 J6o006ob AJJ3r, obCaJeo v12 (E) 3 (E) I (B) LGBF FL s2 3473 sl7 3474 s2 s20 3475 2 (D/E) 3 (E) v1 cv23 3 (E) 3476 3477 63s - '.,\". ^ ,JvvuJv ur {Jc{)J!oq)ou oobo3oCg6J0o bJC6dr ar$ocqc0$ qs r(,Bc6({xrbr N Jq'db Jg{fr3oJt scaJ t$ao06nCb otr,|J Jar$n o'3dJ ol, EfiCbo l,JCOorqlJFx' actqcauqn qD 0i6s $AD€,tPJgq,cb U{r cxmha&o ?6C 3o BCe6o€.'b LJ&G{IJ qyJ&JqDC&Cbo qrcbqtbc ACaCCgo AC€UsEofi od\J6cjb b 3.r.2 (1) Jo&1trffitbo oe\) lrJAo(lC 6do ocb qlc&J(-Jbc 60 1_25. 2 7,3 1.2.5.3 dCLrbCo omflo'Bdr ti ,, 3478 atArafboeo crrt0lr,6cbo qD artxrc(q., O8(6od, 22 2 t.t- 522 33 31.6 3 (3r) (30) 2 6F (4) (s) (6) 21 328 AdsbCb I';' t' 4.1.4 - (8) l2OAq, EO P004 zUoq) EO P004 0 EO P903 4 t,4 {.1 l0 2 (9r) (%) (10) (r l) 338 3479 2 2l 6F J26 339 3480 - .:...y.._ .,1-l- "osoog3oo lq,ooop(job 9 oobob Joq'oAC6Uq,o bJO j6CCbob M4 II 9 6J03e"oo) 188 230 P908 310 P909 348 LP9O3 376 LP9O4 377 3481 q"oooq0olr 9 636 M4 II 9 188 0 EO 230 P908 348 P909 376 LP9O3 377 LP9O4 360 34A2 636 wFl 182 +3 0 EO P402 0 E5 P602 r83 RR8 MP2 506 3€3 do-r3ob brg3r3ob r66oQffi!ffi i-- oJoCao, J(goq'JJq,CoJeo 6l TFl 61 +3 MP8 Tl4 TP2 Tr0 TP2 MPIT 34&1 3oq,6rboOoU ggsq,bGG;l- r(Roq'JJq,CbJeo, 37qo_b9 aXgo 3oe(tJboboU AJbU6o 0oe)oo 8 8 530 0 EO +3 MP8 +6.1 MPIT 3485 oc2 314 1Jo E2 JO EI +8 3486 3rggogOob 3oJojq'o6 006rqro, 3o6obogq,o, A166rA r6rU0COCU 5l oc2 III 51 314 +8 39olo P002 IBCO8 84 BI3 MP2 P002 83 813 LI MP2 84 B13 MP2 IBCO8 LPO2 34f7 R00t 5l oc2 3t4 +8 636 322 l;a E2 P002 IBCOS AIIROdSFSo €0d$0.ffi, ts0.ffirJrr60o l$foDq?os (B3o6i66o cd\y66dt dCt{UAOoti JarAn) Jo60o GdC066dt 30ao LboorqE6o ed"q'abobo 0Aart$toqD bJCOq t6tu SqnceD Jro0Ur&D 4.3s,68.4 (12) 9.t.t.2 (13) r.r.3.6 (86) (14) N ao$aJ@ UJgroo 724 (15) 06) 2 l{' A|00o6otD, 8Jaa"$o(6oBr es eseJbiaJe, IrQs$oqBt 1.3 0tC6aft k{06oo AJSaoSJEo e t$&{6o0 6d, o!3qrft 0n (B/D) 7.5.11 85 (t8) (19) cvl9 s2 l) 3478 6/12 2 cvl9 cvl2 (B,D) 3479 2 (E) 3480 2 (E) LIOBN G) TUI4 TE5Tli} FL 3481 I cv23 (B/E) s2 s20 x323 TM2 3482 6g6c6r6o, pobJg6b regoq'Jrq'CbJeo 16 OCOo_Aogr QobJC6bo3q'o q'o0060, LIrcH TUI4 TUI5 r(Boq'$q'Cbreo FL TE19 TE21 I cvl (c/D) FL I UVIS (c7D) s SGAN SGAN Tl-,:| TU3 TU3 AT AT AT cv28 2 (E) 6124 3 (E) 2 (E) 663 3483 52 SI4 886 34&r 58 3485 58 3486 58 34a7 cv13 cv28 TT6 LIOBH s2 s9 Sl4 clr24 c\3s vll 9,t24 cv3s 637 01060l, a$t$brct e"j@ tn Jqe JCDltr'So& 0d Jalsb ac@ t$en6c,Cb o{rn dr 6o6Cbo NJGDqtrn O5r &{gsat({|o ta03 o(igdiqbo Ar ao ar&'J6o 0g.!600l, BJooq" 2.1.1. 3 346 tbo qao!|q'CbCoo 0C6CCqb ac6,Jq$c affiosrn bo &J$bcb (3r) 5.1 (30) (4) (s) oc2 (6) III 5.1 314 oC6o t$m(D(? q*Jq${ 60 0CSUoBdr OdlbCb 3s.1 411 2 r) 34f? 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TP4 TP40 2 2 8F 8T 2l 0 2.2 274 +6 I 659 EO EO P206 PP89 MP9 T50 P206 PP89 MP9 T50 TP4 TP40 TP4 TP,IO 3503 Co0cr3-6o J6oeUCOo g66ob 3ooolo3q'o, N.O.S. ffi 2 8C 22 274 +8 659 0 EO P206 PP89 MP9 T50 TP4 TP40 3504 u _ -u ^,".,.,Yd()(, vuiljou d3co, rq3oq'lrqobreo, Oojbo3grio, N O.S 2 8TF 2l ;; +6 I 659 638 0 EO P206 PP89 MP9 T50 TP4 TP40 ^DR odS66J ucc."sc,6. ffi0 oC'baUq8rf, Ja|{rb) brraCfuo JiC'ScrtrD 0'3qyfr 0d$066ctJ t JC0osqU6o Joao AC8rqthbo al&ceTbd"@ (&3or9r8&r dcgflp'33e qgtbbry?bCo"q.r.@ a)Citc)| N oob 30&om N uqF 90 0co6oxfJ orAD$oQBJ 4.3 (12) SGAN 4.35,6.8.{ l.l 3.6 (86) _(13) (14) TU:l AT 7.21 (16) 3 (17) (18) 85 5323 (le) (20) C\r24 (E) 58 c!35 Ll5CH TUI4 TUI5 FL I TEI9 TE21 cvl (c/D) cvl3 3487 s2 s9 s14 63 s2 s9 s14 663 3489 s2 59 Sl4 623 3490 cv28 LIOCH TU14 TUI5 I TE19 TE2I (c/D) cvl3 CV28 L15CH 'rul4 ru15 FI- I TE19 TE2I cvl (cyD) cv13 cv28 LIOCH TUI4 TUI5 FL TE19 TE2I LIOCH TUl4 ru15 FL TE2I L4BH r I (c/D) ut) 3491 I (?E) cv13 cvl 3 (D/E) TUI5 FL 3 AT cv28 v12 (D,€) L4BN cvl3 3 16 C&C0AC0r 13br ADR-oU SGAV L4BN ,t vc2 cv13 AP7 CV28 0oo 3494 nr\)oSJoo ocQqo 6J3oobo, S2 36 3494 3o6o6eo3r6o 6Ceq'n O13o.6l, Jegoq,rrq,Cbreo, OojUo3gttro 86 3495 ;c;---------------------- 3496 brgloseoo, oo3eql-q,el]ffi1f,@el- 40 3497 40 3497 80 3498 L (D/E) AT 3 (E) \, 600o6eogJ6o 6oeq'" Otgoffi JeOoq)JJq)Coreo, gojlro.;316o 336 H AT AT 3494 s2 sl9 cv28 (E) SGAN s2 s22 CV28 FL -Lvcl vc2 API 2 (E) J6oq'ob tsCaoqro oosJ('o 4 (E) 3499 3 (c7E) AT cv9 cvl0 3 cv9 cv10 (B/D) AT 20 3s00 23 3501 3naryon,ro.ps36-96-fr-Jffi cvr2 c!86 cvt2 ffi cv9 I (c/D) cvl0 S2 -T- Codo36o J6oeUCOn gO6nt rqg3oq'rsq'3brqgo, N O S idl- 63Al- 3502 cvl2 c\,28 AT I (c./D) c\86 cv9 cvl0 3503 cvl2 (B/D) cv9 cvl0 cv12 c\r28 c\r35 639 3noos_an ro.qud6o$F@, Jooo.bocq)o, N.o.s. c\r35 FL 3504 3oaoson ro"qf 6n $6[o[ffi]- rQSoq'rJqcbjeo, Oojbo3g6o, N O S DCltxd as{$bCq'CbJ qD le0C6ogdJ N JCdb acau ofrrr Jcr(n l\*tr6oCb oan d 6dqbo ?6C ItsCoorq*Jl% oCtetQflqn qD ar8tb3olrJ8q'co uqn r{c&racao ACaCqEbCoo $, dx6r aeqcqih8o o8\)6cCo (l) 3505 l'" 3506 2.r.1. 522 UrSJ6aoo 6UCoobCb0ojr6A;E gC6,ObqnbngJq,o (30) 2 0C6"E; (4\ t' (s) 8FC 2.1 8 3507 6s9 8 +6 I 366 8l3:; I 8 0rbqor, ar0oor3obpgq,Cbgin Oiggo3i, 0 r J6-!c b$gCoo yo3Cq' 09ggogrS3. 0 +8 oa\) ac60qth asbaqD 6uCo oCEOoOrfr sJ6o bo &Abcb 4.1.4 EO Ao {.1 l0 1.2.5. 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